Content:

AS – Atmospheric Sciences

AS1.1 – Numerical weather prediction, data assimilation and ensemble forecasting

The next and final update to the deterministic Rapid Refresh, version 5 (RAPv5), and High-Resolution Rapid Refresh, version 4 (HRRRv4), is currently scheduled for an operational implementation at NOAA/NCEP in mid-2020. Numerous physics, dynamics and data assimilation changes are being included as part of this upgrade.  This presentation will discuss the scope of this implementation including  an emphasis on the development of an hourly-cycled regional 36-member storm-scale ensemble analysis system with demonstrated improvements to deterministic forecasts at the convective scale.  The design of this HRRR data assimilation system (HRRRDAS) will be motivated through choices to include multiple-scales of perturbations from both a global and this regional convection-allowing ensemble, scale-dependent use of different observation types in an Ensemble Kalman Filter and use of inflation to maintain ensemble spread.  While not included in the HRRRv4 operational implementation, an experimental storm-scale ensemble forecast system leveraging a subset of the 36 members will also be described.  Design of the HRRR ensemble (HRRRE) forecasts will be discussed including use of stochastic parameter perturbations across the single model physics suite along with comparisons to other storm-scale multi-model/physics ensemble designs highlighting both the benefits of this single-model/physics ensemble approach along with challenges in maintaining appropriate spread at longer forecast lengths.  This final configuration of the RAP/HRRR model systems will serve as an operational baseline for the transition to a regional FV3-based convection allowing application in a Unified Forecast System (UFS), known as the Rapid Refresh Forecast System (RRFS), and this transition will be described.

How to cite: Alexander, C.: Storm-Scale Ensemble Data Assimilation and Forecast Development for the High-Resolution Rapid Refresh (HRRR) and Future Applications in the Unified Forecast System, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22670, 2020.

EGU2020-2483 | Displays | AS1.1

Big Data Assimilation: Real-time Workflow for 30-second-update Forecasting and Perspectives toward DA-AI Integration

Takemasa Miyoshi, Takmi Honda, Shigenori Otsuka, Arata Amemiya, Yasumitsu Maejima, Yoshihiro Ishikawa, Hiromu Seko, Yoshito Yoshizaki, Naonori Ueda, Hirofumi Tomita, Yutaka Ishikawa, Shinsuke Satoh, Tomoo Ushio, Kana Koike, and Yasuhiko Nakada

The Japan’s Big Data Assimilation (BDA) project started in October 2013 and ended its 5.5-year period in March 2019. The direct follow-on project was accepted and started in April 2019 under the Japan Science and Technology Agency (JST) AIP (Advanced Intelligence Project) Acceleration Research, with emphases on the connection with AI technologies, in particular, an integration of DA and AI with high-performance computation (HPC). The BDA project aimed to fully take advantage of “big data” from advanced sensors such as the phased array weather radar (PAWR) and Himawari-8 geostationary satellite, which provide two orders of magnitude more data than the previous sensors. We have achieved successful case studies with newly-developed 30-second-update, 100-m-mesh numerical weather prediction (NWP) system based on the RIKEN’s SCALE model and local ensemble transform Kalman filter (LETKF) to assimilate PAWR in Osaka and Kobe. We have been actively developing the workflow for real-time weather forecasting in Tokyo in summer 2020. In addition, we developed two precipitation nowcasting systems with the every-30-second PAWR data: one with an optical-flow-based system, the other with a deep-learning-based system. We chose the convolutional Long Short Term Memory (Conv-LSTM) as a deep learning algorithm, and found it effective for precipitation nowcasting. The use of Conv-LSTM would lead to an integration of DA and AI with HPC. This presentation will include an overview of the BDA project toward a DA-AI-HPC integration under the new AIP Acceleration Research scheme, and recent progress of the project.

How to cite: Miyoshi, T., Honda, T., Otsuka, S., Amemiya, A., Maejima, Y., Ishikawa, Y., Seko, H., Yoshizaki, Y., Ueda, N., Tomita, H., Ishikawa, Y., Satoh, S., Ushio, T., Koike, K., and Nakada, Y.: Big Data Assimilation: Real-time Workflow for 30-second-update Forecasting and Perspectives toward DA-AI Integration, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2483, https://doi.org/10.5194/egusphere-egu2020-2483, 2020.

EGU2020-11232 | Displays | AS1.1

Representation of model error in convective scale data assimilation

Tijana Janjic, Yuefei Zeng, Alberto de Lozar, Yvonne Ruckstuhl, Ulrich Blahak, and Axel Seifert

Model error is one of major contributors to forecast uncertainty. In addition, statistical representations of possible model errors substantially affect the data assimilation results. We investigate variety of methods of taking into account model error in ensemble based convective scale data assimilation. This is done using the operational convection-permitting COSMO model and data assimilation system KENDA of German weather service, for a two-week convective period in May 2016 over Germany. Conventional and radar reflectivity observations are assimilated hourly by the LETKF. For example, to take into account the model error due to unresolved scales and processes, we use the additive noise with samples coming from the difference between high-resolution model run and low-resolution experiment. We compare this technique for assimilation of radar reflectivity data to other methods such as RTPS, warm bubble initialization, stochastic boundary layer perturbation and estimation of parameters. To further improve on additive noise technique, which consists of perturbing each ensemble member with a sample from a given distribution, we propose a more flexible approach in which the model error samples are treated as additional synthetic ensemble members that are used in the update step of data assimilation but are not forecasted. In this way, the rank of the model error covariance matrix can be chosen independently of the ensemble. This altered additive noise method is analyzed as well.

How to cite: Janjic, T., Zeng, Y., de Lozar, A., Ruckstuhl, Y., Blahak, U., and Seifert, A.: Representation of model error in convective scale data assimilation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11232, https://doi.org/10.5194/egusphere-egu2020-11232, 2020.

EGU2020-12103 | Displays | AS1.1

Inferring atmospheric dynamics from tracer observations in 4D-Var: flow-dependent aspects

Žiga Zaplotnik and Nedjeljka Žagar

In the operational NWP, the assimilation of ozone causes large wind and temperature analysis increments in the stratosphere to accommodate for the differences between background and observations. In such cases, unless the ozone feedback on dynamics is switched off, the strong-constraint 4D-Var internal dynamics without comprehensive bias correction makes spurious flow adjustments, especially in the regions with larger gradients in the tracer background field, and when there are insufficient constraints such as large background flow uncertainties and a lack of observations of dynamic variables. The wind-tracer feedback is also turned off for the aerosols and the trace gases. Thus, their useful information on the wind advection is not accounted for anywhere in the domain at any time instance. In this way, the tracer analysis quality is also deteriorated. Somewhat smarter, selective use of tracer information would be beneficial to alleviate unphysical analysis increments in certain regions and at the same time to retain the benefits of wind extraction in other areas.

Thus, we formulate the method for flow-dependent 4D-Var wind extraction, which switches the wind-tracer feedback on or off in the tracers’ tangent-linear model and wind adjoint model. The objective criterion for the selection is deduced from the ensemble of simulations and is based on the ratio of the tracer physical forcings’ uncertainty and the mean tracer advection rate. The numerical tests with an intermediate-complexity incremental 4D-Var system MADDAM show promising results for both wind and tracer analyses. We also demonstrate that the aerosols have theoretically an even larger potential as the carriers of the advection information than humidity due to larger relative spatial gradients, which are crucial for successful wind extraction. The flow-dependent wind extraction method is compared with the weak-constraint 4D-Var, where the tracer model error obtained from the ensemble implicitly controls the amount of wind-tracer coupling.

How to cite: Zaplotnik, Ž. and Žagar, N.: Inferring atmospheric dynamics from tracer observations in 4D-Var: flow-dependent aspects, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12103, https://doi.org/10.5194/egusphere-egu2020-12103, 2020.

This work is devoted to the urgent task of assessing regional flows of greenhouse gases from the Earth's surface according to satellite observations. The article presents the practical and theoretical results of the first year of study in the PhD program, later they will be included in the final dissertation. Flows will be estimated based on the observational data assimilation system for a three-dimensional model of diffusive transport of gas components in the atmosphere (MOZART-4). Model for Ozone and Associated Chemical Indicators, Version 4 (MOZART-4) is an autonomous global model for the transport of chemicals in the atmosphere.

The development of a modern system for the assimilation of real satellite data for assessing greenhouse gas sources is currently a very important theoretical and practical area in science. The ensemble approach is relevant and has great potential for using both stochastic and variational methods. In the process of implementation, this is an order of magnitude simpler, since there are no cumbersome matrix calculations using the model.

To solve the problem of estimating methane flows, the parameter estimation problem was solved: an algorithm for data assimilation was developed; the Kalman filter with the transformation of the local ensemble was used as the basis for it. Using an example of a model problem, an algorithm for estimating the concentration of a passive impurity and a parameter is developed. The case was also considered when only one parameter can be estimated in the assimilation system. In this case it is considered that at the forecasting stage the parameter does not change, and the calculations in accordance with the transport model are included in the operator H, for example, as in Feng (2009,2017). H is the observation operator; transfers predicted values to observation points (and observed variables). For example, for satellite methane data, H includes:

  1. a) interpolation to the observation point;
  2. b) vertical averaging (using the middle core);
  3. c) if the observation data is obtained from a large time interval, then the operator H also includes a forecast for the model in time.

Numerical experiments were carried out with model and real data. Using numerical experiments with the model, it was shown that a large problem (global) can be solved sequentially by subregion, independently in each subregion, which allowed the use of MPI and OpenMP.

How to cite: Platonova, M.: Data assimilation system for estimating methane flows using satellite data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-661, https://doi.org/10.5194/egusphere-egu2020-661, 2020.

EGU2020-4161 | Displays | AS1.1

Impact of FORMOSAT-7/COSMIC-2 RO on High-Resolution Hybrid 3DEnVar System at Central Weather Bureau of Taiwan

Jing-Shan Hong, Wen-Jou Chen, Ying-Jhen Chen, Siou-Ying Jiang, and Chin-Tzu Fong

The FORMOSAT-7/COSMIC-2 (simplified as FS-7/C-2 in the following descriptions) is the constellation of satellites for meteorology, ionosphere, climatology, and space weather research. FS-7/C-2 was a joint Taiwan-U.S. satellite mission that makes use of the radio occultation (RO) measurement technique. FORMOSAT-7 is the successor of FORMOSAT-3 which was launched in 2006. the FORMOSAT-3 RO data has been shown to be extremely valuable for numerical weather prediction, such as improving the prediction of tropical cyclogenesis and reducing the typhoon track error. The follow-on FS-7/C-2 mission was launched on 25 June 2019, and is currently going through preliminary testing and evaluation. After it is fully deployed, FS-7/C-2 is expected to provide 6,000 GNSS (Global Navigation Satellite System) RO profiles per day between 40S and 40N.  

In this study, we conduct a preliminary evaluation of FS-7/C-2 GNSS RO data on heavy precipitation events associated with typhoon and southwesterly monsoon flows based on the operational NWP system of the Central Weather Bureau (CWB) in Taiwan. The FS-7/C-2 GNSS RO data are assimilated using a dual-resolution hybrid 3DEnVare system with a 15-3 km nested-grid configuration. In the 15km resolution domain, flow-dependent background error covariances (BECs) derived from the perturbation of ensemble adjustment Kalman filter (EAKF), will be used to conduct hybrid 3DEnVar analysis. In the 3 km resolution domain, the 15 km resolution flow-dependent BECs will be inserted to the 3 km grid using a Dual-Resolution (DR) technique, and then combined with 3 km resolution static BECs, to perform the high-resolution 3DEnVar analysis. The performance of the CWB operational NWP system on quantitative precipitation forecast of significant precipitation events with and without the assimilation of FS-7/C-2 GNSS RO data will be evaluated.

How to cite: Hong, J.-S., Chen, W.-J., Chen, Y.-J., Jiang, S.-Y., and Fong, C.-T.: Impact of FORMOSAT-7/COSMIC-2 RO on High-Resolution Hybrid 3DEnVar System at Central Weather Bureau of Taiwan, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4161, https://doi.org/10.5194/egusphere-egu2020-4161, 2020.

Nowadays, the use of 4D-VAR assimilation technique has been investigated in several scientific papers with the aim of improving the localization and timing of precipitation in complex orography regions. The results show the positive impact in rainfall forecast but, the need to resolve the tangent linear and adjoint model makes the 4D-VAR computationally too expensive. Hence, it is used in operationally only in large forecast centres. To the aim of exploring a more reasonable method, a comparison between a cycling 3D-VAR, that needs less computational resources, and 4D-VAR techniques is performed for a severe weather event occurred in Central Italy. A cut-off low (992 hPa), located in western side of Sicily region, was associated with a strong south-easterly flow over Central Adriatic region, which supplied a large amount of warm and moist air. This mesoscale configuration, coupled with the Apennines mountain range that further increased the air column instability, produced heavy rainfall in Abruzzo region (Central Italy).

The numerical simulations are carried out using the Weather Research and Forecasting (WRF) model. In-situ surface and upper-air observations are assimilated in combination with radar reflectivity and radial velocity data over a high-resolution domain. Several experiments have been performed in order to evaluate the impact of 4D-VAR and cycling 3D-VAR in the precipitation forecast. In addition, a statistical analysis has been carried out to objectively compare the simulations. Two different verification approaches are used: Receiver Operating Characteristic (ROC) curve and Fraction Skill Score (FSS). Both statistical scores are calculated for different threshold values in the study area and in the sub-regions where the maximum rainfall occurred.

How to cite: Mazzarella, V. and Ferretti, R.: A comparison between 4D-VAR and cycling 3D-VAR methods for the simulation of a severe weather event in Central Italy. Preliminary results., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7228, https://doi.org/10.5194/egusphere-egu2020-7228, 2020.

EGU2020-6212 | Displays | AS1.1

NOAA’s Unified Forecast System for Sub-Seasonal Predictions: Development and operational implementation plans of Global Ensemble Forecast System v12 (GEFSv12) at NCEP

Ivanka Stajner, Vijay Tallapragada, Yuejian Zhu, Henrique Alves, Jeff McQueen, Tom Hamill, Jeff Whitaker, Georg Grell, and Jason Levit

NCEP has implemented the first version of the Finite Volume Cubed Sphere (FV3) dynamic core based Global Forecast System (GFS v15) into operations in June 2019, replacing the spectral model-based GFS. This is the first instantiation of NOAA's Unified Forecast System (UFS), which is being built as a comprehensive coupled Earth system model using modern tools and software infrastructure (e.g., NEMS, NUOPC, and ESMF) to support research and operations. Advancements in model physics and data assimilation are in development using CCPP and JEDI frameworks. Testing and evaluation of UFS are facilitated through the development of unified workflow and METplus capabilities. All these initiatives involve significant engagement with the research community, with emphasis on more efficient and streamlined transition of research advances to operations (R2O).

The next major operational upgrade towards UFS is for the Global Ensemble Forecast System (GEFSv12) planned for implementation later this year.  Compared to the currently operational GEFS, the next GEFS version 12 incorporates the following advances: the same FV3 based global model and UFS infrastructure as in GFS,  higher resolution (~25km), increased membership (31), GFSv15 physics, advanced stochastic physics perturbations (SKEB and SPPT), and 2-tiered SST approach using SST anomalies from CFSv2 as input.  For the first time, GEFSv12 will provide ensemble based operational weather predictions for sub-seasonal scales with daily 00z forecasts going out to 35 days. GEFSv12 also comes with 20-year reanalysis, 30-year reforecasts and 3-year retrospective forecasts to support stakeholder needs for calibration and validation.  In addition, GEFSv12 absorbs the global wave ensembles and aerosol capabilities (control member only) through one-way coupling, taking major steps towards building a unified system and simplifying NCEP’s production suite.

This presentation describes the design and development of GEFSv12 and discusses results from the evaluation of the retrospective and reforecast experiments.  Significant improvements were noted in both deterministic and probabilistic forecast metrics for several variables including 500 hPa geopotential height anomaly correction, 850 hPa temperature and winds, near surface variables, precipitation, tropical cyclone tracks and intensity, and modes of variability including MJO and NAO.  Substantial improvements were also noted in the performance of wave ensemble and aerosol predictions.

This presentation also describes NOAA’s efforts towards accelerating further development of fully coupled UFS consisting of six component models of the Earth system: the FV3 dynamical core for the atmosphere, MOM6 for the ocean, Noah MP for the land surface, GOCART for aerosols, CICE5/CICE6 for sea ice and WW3 for ocean surface waves.  Combined with data assimilation advances, an ambitious goal of unifying both the high-resolution deterministic (GFSv17) and probabilistic (GEFSv13) predictions for global medium range and sub-seasonal time scales is planned to significantly advance the global prediction capabilities at NCEP.

 

How to cite: Stajner, I., Tallapragada, V., Zhu, Y., Alves, H., McQueen, J., Hamill, T., Whitaker, J., Grell, G., and Levit, J.: NOAA’s Unified Forecast System for Sub-Seasonal Predictions: Development and operational implementation plans of Global Ensemble Forecast System v12 (GEFSv12) at NCEP, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6212, https://doi.org/10.5194/egusphere-egu2020-6212, 2020.

EGU2020-23 | Displays | AS1.1

The Common Community Physics Package (CCPP): bridging the gap between research and operations to improve U.S. numerical weather prediction capabilities

Dom Heinzeller, Grant Firl, Ligia Bernardet, Laurie Carson, Man Zhang, and Jack Kain

Improving numerical weather prediction systems depends critically on the ability to transition innovations from research to operations (R2O) and to provide feedback from operations to research (O2R). This R2O2R cycle, sometimes referred to as "crossing the valley of death", has long been identified as a major challenge for the U.S. weather enterprise.

As part of a broader effort to bridge this gap and advance U.S. weather prediction capabilities, the Developmental Testbed Center (DTC) with staff at NOAA and NCAR has developed the Common Community Physics Package (CCPP) for application in NOAA's Unified Forecasting System (UFS). The CCPP consists of a library of physical parameterizations and a framework, which interfaces the physics with atmospheric models based on metadata information and standardized interfaces. The CCPP physics library contains physical parameterizations from the current operational U.S. global, mesoscale and high-resolution models, future implementation candidates, and additional physics from NOAA, NCAR and other organizations. The range of physics options in the CCPP physics library enables the application of the UFS - as well as every other model using the CCPP - across scales, from now-casting to seasonal and from high-resolution regional to global ensembles.

While the initial development of the CCPP was centered around the FV3 (Finite-Volume Cubed-Sphere) dynamical core of the UFS, its focus has since widened. The CCPP is also used by the DTC Single Column Model to support a hierarchical testing strategy, and by the next generation NEPTUNE (Navy Environmental Prediction sysTem Utilizing the Numa corE) model of the Naval Research Laboratory. Further, and most importantly, NOAA and NCAR recently signed an agreement to jointly develop the CCPP framework as a single, standardized way to interface physics with their models of the atmosphere (and other compartments of the Earth system). This places the CCPP in the heart of several of the U.S. flagship models and opens the door for bringing innovations from a large research community into operations.

In this contribution, we will present a brief overview of the concept of the CCPP, its technical design and the requirements for parameterizations to be considered as CCPP-compliant. We will describe the integration of CCPP in the UFS and touch upon the challenges in creating a flexible modeling framework while maintaining high computational performance. We will also provide information on how to obtain, use and contribute to the CCPP, as well as on the future development of the CCPP framework and upcoming additions to the CCPP physics library.

How to cite: Heinzeller, D., Firl, G., Bernardet, L., Carson, L., Zhang, M., and Kain, J.: The Common Community Physics Package (CCPP): bridging the gap between research and operations to improve U.S. numerical weather prediction capabilities, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-23, https://doi.org/10.5194/egusphere-egu2020-23, 2020.

EGU2020-20855 | Displays | AS1.1

Ongoing Development and Applications of the Grell-Freitas Cumulus Parameterization

Georg Grell, Hannah Barnes, Saulo Freitas, and Haiqin Li

We will present some recent improvements to the GF parameterization. These include two features that were added to the Grell-Freitas (GF) Cumulus Parameterization to improve the representation of the particle size distribution and to allow parameterized deep convection to propagate. These also include the treatment of tracer transport, wet scavenging, and aqueous phase chemistry, and improvements on interactions with aerosols. A more complete implementation for transport and treatment of atmospheric composition variables was necessary to complement recent new developments at NOAA/ESRL coupling chemical modules within the NWP model.

Estimates of cloud water and ice crystal number concentrations are added to GF base on the water-friendly aerosol content, temperature, and the cloud water and ice crystal mixing ratios. This modification is designed to diminish the artificial modification of the particle size distribution that occurs when the single moment cumulus schemes are used with the double-moment microphysics schemes. Simulations demonstrate that the addition of GF ice number concentrations substantially increases ice content aloft in the tropics, which shifts the outgoing longwave radiation distribution towards colder brightness temperatures.

The key modification used to enable the propagation of parameterized deep convective is the addition of an advected scalar that represents the cloud base mass flux associated with GF downdrafts. Our implementation of this advected scalar allows the impact of downdrafts from previous time steps to foster propagation. Evaluation and tuning of the new downdraft mass advection term is ongoing.

How to cite: Grell, G., Barnes, H., Freitas, S., and Li, H.: Ongoing Development and Applications of the Grell-Freitas Cumulus Parameterization , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20855, https://doi.org/10.5194/egusphere-egu2020-20855, 2020.

A key and expensive part of coupled atmospheric chemistry-climate model simulations is the integration of gas phase chemistry, which involves dozens of species and hundreds of reactions. These species and reactions form a highly-coupled network of Differential Equations (DEs). There exists orders of magnitude variability in the lifetimes of the different species present in the atmosphere and so solving these DEs to obtain robust numerical solutions poses a “stiff problem”. With newer models having more species and increased complexity it is now becoming increasingly important to have chemistry solving schemes that reduce time but maintain accuracy.

A sound way to handle stiff systems is by using implicit DE solvers but the computational costs for such solvers are high due to internal iterative algorithms (e.g., Newton-Raphson (NR) methods). Here we propose an approach for implicit DE solvers that improves their convergence speed and robustness with relatively small modification in the code. We achieve this by using Quasi-Newton (QN) methods. We test our approach with numerical experiments on the UK Chemistry and Aerosol (UKCA) model, part of the UK Met Office Unified Model suite, run in both an idealized box-model environment and under realistic 3D atmospheric conditions. The box model tests reveal that the proposed method reduces the time spent in the solver routines significantly, with each QN call costing 27% of a call to the full NR routine. A series of experiments over a range of chemical environments was conducted with the box-model to find the optimal iteration steps to call the QN routine which result in the greatest reduction in the total number of NR iterations whilst minimising the chance of causing instabilities and maintaining solver accuracy. The 3D simulations show that our method for the chemistry solver, speeds up the chemistry routines by around 13%, resulting in a net improvement in overall run-time of the full model by approximately 3% with negligible loss in the accuracy (relative error of order 10-7) . The QN method also improves the robustness of the solver by significantly reducing (40% ) the number of grid cells which fail to converge hence avoiding unnecessary timestep adjustments. 

How to cite: Esenturk, E.: Improved numerical solvers for coupled chemistry-climate model simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20973, https://doi.org/10.5194/egusphere-egu2020-20973, 2020.

Canada’s west coast topography plays a crucial role for the local precipitation patterns, which are often shaped by orographic lifting on one side of the mountains, and rain shadows on the other side. The hydroelectric infrastructure in southwest British Columbia (BC) relies heavily on the abundant rainfall of the wet season, but long lasting and heavy precipitation can cause local flooding and make reliable precipitation forecasts crucial for resource management, risk assessment, and disaster mitigation.

This research evaluates hourly precipitation forecasts from the Weather Research and Forecasting (WRF) model over the complex terrain of southwest BC. The model data includes a full year of daily runs across three nested domains (27-9-3 km). A selection of different parameterizations is systematically varied, including microphysics, cumulus, turbulence, and land-surface parameterizations. The resulting over 100 model configurations are evaluated with observations from ground-based quality-controlled precipitation gauges. The individual model skill of the precipitation forecasts is assessed with respect to different accumulation windows, forecast horizons, grid resolutions, and precipitation intensities. Furthermore, the ensemble mean and spread provide insight to the general error growth for precipitation forecasts in WRF.

Cumulus and microphysics parameterizations together determine the total precipitation in numerical weather prediction models and this study confirms the expectation that the combination of those physics parameterizations is most decisive for the precipitation forecasts. However, the boundary-layer and land-surface parameterizations have a secondary effect on precipitation skill. The verification shows that the WSM5 microphysics parameterization yields surprisingly competitive verification scores when compared to more sophisticated and computationally expensive parameterizations. Although, the scale-aware Grell-Freitas cumulus parameterization performs better for summer-time convective precipitation, the conventional Kain-Fritsch parameterization performs better for winter-time frontal precipitation, which contributes to the majority of the annual rainfall in southwest BC.

Throughout a 3-day forecast horizon mean absolute errors are observed to grow by ~5% per forecast day. Furthermore, this study indicates that coarser resolutions suffer from larger total biases and larger random error components, however, they have slightly higher correlation coefficients. The mid-size 9-km domain yields the highest relative hit rate for significant and extreme precipitation. Verification metrics improve exponentially with longer accumulation windows: On one side, hourly precipitation values are highly prone to double-penalty issues (where a timing error can, for example, result in an over-forecast error in one hour and an under-forecast in a subsequent hour); on the other side, extended accumulation windows can compensate for timing errors, but lose information about short-term rain intensities.

How to cite: Jeworrek, J., West, G., and Stull, R.: Predictability of Precipitation in Complex Terrain using the WRF Model with Varying Physics Parameterizations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-599, https://doi.org/10.5194/egusphere-egu2020-599, 2020.

EGU2020-1026 | Displays | AS1.1

Evaluation of the performance of WRF model in extreme precipitation estimation concerning the changing model configuration and the spatial and temporal variations

Eren Duzenli, Heves Pilatin, Ismail Yucel, Berina M. Kilicarslan, and M. Tugrul Yilmaz

Global numerical weather prediction models (NWP) such as the European Centre for Medium-Range Weather Forecasts (ECMWF) and Global Forecast System (GFS) generate atmospheric data for the entire world. However, these models provide the data at large spatiotemporal resolutions because of computational limitations. Weather Research and Forecasting (WRF) Model is one of the models, which is capable of dynamically downscaling the NWP models’ output. In this study, all combinations of 4 microphysics and 3 cumulus parametrization schemes, 2 planetary boundary layers (PBL), 2 initial and lateral boundary conditions and 2 horizontal grid spacing (i.e., an ensemble consisting of 96 different scenarios) are simulated to measure the sensitivity of WRF-derived precipitation against different model configurations. The sensitivity analyses are performed for 4 separate events. These events are selected among the extreme precipitation events in the Mediterranean (MED) and eastern Black Sea (EBLS) regions. For each region, a summer and an autumn event are chosen. Here, the fundamental aim is to determine the spatiotemporal differences in WRF input parameters that yield better outcomes. A total of 72 hours simulations are started 24 hours before the event day to avoid spin-up time error. The model is adjusted to produce hourly precipitation outputs. The relative performance of scenarios is measured using Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS) method considering 5 categorical validation indices and 4 pairwise statistics calculated between the model estimations and the ground-based precipitation observations. According to the TOPSIS results, microphysics scheme, initial and lateral boundary condition, and horizontal grid spacing are substantially influential on WRF precipitation estimates, while cumulus parameterization has a comparatively low effect. The choice of PBL scheme is essential for the summer events, but the results of the autumn events are independent of PBL selection. WRF products are better for the events of the EBLS basin when ERA5 is used as the initial and lateral boundary condition. On the contrary, GFS is superior in the MED region. In terms of spatial resolution, 9 km horizontal grid spacing is commonly preferable for all the events rather than 3 km. Besides, the model underestimates the area-averaged precipitation amounts except for the MED-autumn incident. Still, the model is successful at catching the peak hours of all events. Moreover, the precipitation detection ability of WRF is better for the autumn months. The probability of detection index is higher than 0.5 at 35% of MED stations and 68% of EBLS stations for the autumn events. The local and convective summer events are investigated considering the event centers. Albeit relatively low relationships are defined for the MED-summer event, a statistically significant correlation is obtained between the central station of the EBLS-summer event and the closest grid for the predictions of 52 scenarios (i.e., 54% of the ensemble).

How to cite: Duzenli, E., Pilatin, H., Yucel, I., Kilicarslan, B. M., and Yilmaz, M. T.: Evaluation of the performance of WRF model in extreme precipitation estimation concerning the changing model configuration and the spatial and temporal variations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1026, https://doi.org/10.5194/egusphere-egu2020-1026, 2020.

EGU2020-22677 | Displays | AS1.1

Common evaluation/evolution of cloud-radiation processes from 25km S2S to 3km NWP

Stan Benjamin, Joseph Joseph Olson, Shan Sun, Georg Georg Grell, and Curtis Curtis Alexander

Subgrid-scale cloud representation and the closely related surface-energy balance continue to be a central challenge from subseasonal-to-seasonal models down to storm-scale models applied for forecast duration of only a few hours. Previously, NOAA/ESRL confirmed this issue from 3-km model (HRRR using WRF-ARW) for short-range forecasting including sub-grid-scale cloud representation up to a 25-km subseasonal model (FV3-GFS) testing a common suite of scale-aware physical parameterizations.  

In a major physics suite component -- modified representation of subgrid cloud water resulted in much improved agreement with radiation measurements as shown with 2018-2020 testing of the 3km HRRR model. Latest results will be shown using SURFRAD radiation and METAR ceiling observations, indicating much improved bias in downward solar radiation and in cloud location (via mean absolute error metric), as well as with 2m temperature and precipitation.

In addition, new evaluations with the same convection-allowing suite (“mesoscale” suite) of physical parameterizations revised further for subseasonal 30-day tests over summer and winter periods with the 25km NOAA FV3-GFS model. These results are compared with CERES-estimated cloud and downward solar radiation fields. The radiation results from this very preliminary subseasonal test with the ESRL-HRRR physics suite will be compared with previous subseasonal tests using the GFS physics suite and at different horizontal resolution.  This global application now confirms much better downward solar-radiation results over oceans for both January and June from a Nov-2019 version over a 2018 of the “mesoscale” suite.

Background: NOAA Earth System Research Laboratory, together with NCAR, has developed this parameterization suite (turbulent mixing, deep/shallow convection, 9-layer land/snow/vegetation/lake model) to improve PBL biases (temperature and moisture) including better representation of clouds and precipitation. This parameterization suite development has been accompanied by an effort for improved data assimilation of clouds, near-surface observations and radar for the atmosphere-land system.

Subgrid-scale cloud representation continues to be a central challenge from subseasonal-to-seasonal models down to storm-scale models applied for forecast duration of only a few hours.   Previously, NOAA/ESRL confirmed this issue from 3-km model (HRRR) for short-range forecasting including sub-grid-scale cloud representation up to a 60-km subseasonal model testing a common suite of scale-aware physical parameterizations.   Some progress has been made in 2018-2019 to substantially reduce cloud deficiency and excessive downward solar radiation at least over land areas.

Recent development and refinements to this common suite of physical parameterizations for scale-aware deep/shallow convection and boundary-layer mixing over this wide range of time and spatial scales will be reported in this presentation showing some progress. Evaluation of components of this suite is being evaluated for cloud/radiation (using SURFRAD, CERES, METAR ceiling) and near-surface (METAR, mesonet, aircraft, rawinsonde).

NOAA Earth System Research Laboratory, together with NCAR, has developed this parameterization suite (turbulent mixing, deep/shallow convection, 9-layer land/snow/vegetation model) to improve PBL biases (temperature and moisture) including better representation of clouds and precipitation. This parameterization suite development has been accompanied by an effort for improved data assimilation of clouds, near-surface observations and radar for the atmosphere-land system.  

The MYNN boundary-layer EDMF scheme (Olson, et al 2019), RUC land-surface model (Smirnova et al. 2016 MWR), Grell-Freitas scheme (2014, Atmos. Chem. Phys.), and aerosol-aware cloud microphysics (Thompson and Eidhammer 2015) have been applied and tested extensively for the NOAA hourly updated 3-km High-Resolution Rapid Refresh (HRRR) and 13-km Rapid Refresh model/assimilation systems over the United States and North America.   This mesoscale but also scale-aware suite is being tested,

How to cite: Benjamin, S., Joseph Olson, J., Sun, S., Georg Grell, G., and Curtis Alexander, C.: Common evaluation/evolution of cloud-radiation processes from 25km S2S to 3km NWP, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22677, https://doi.org/10.5194/egusphere-egu2020-22677, 2020.


Increases in extra-tropical numerical weather prediction (NWP) skill over the last decades have been well documented. The role of the Arctic, defined here as the area north of 60N, in driving (or slowing) this improvement has however not been systematically assessed. To investigate this question, spatial patterns of changes in medium-range forecast error of ECMWF’s Integrated Forecast System (IFS) are analysed both for deterministic and ensemble forecasts. The robustness of these patterns is evaluated by comparing results for different parameters and levels, and by comparing them with the respective changes in ERA5 forecasts, which are based on a ‘frozen’ model version. In this way the effect of different atmospheric variability on the estimation of skill improvement can be minimized. It is shown to what extent the strength of the polar vortex as measured by the Arctic and North-Atlantic Oscillation (AO, NAO) influences the magnitude of forecast errors. Results may indicate whether recent and future changes in these indices, possibly driven in part by sea-ice decline, could systematically affect the longer-term evolution of medium-range forecast skill.

How to cite: Haiden, T.: The role of arctic forecast errors in the evolution of northern extra-tropical forecast skill, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3606, https://doi.org/10.5194/egusphere-egu2020-3606, 2020.

EGU2020-6379 | Displays | AS1.1

Evaluation of NCEP next Global Ensemble Forecast System (GEFS v12)

Bing Fu, Yuejian Zhu, Xiaqiong Zhou, and Dingchen Hou

With the successful upgrade of its deterministic model GFS (v15) on June 12, 2019, NCEP has scheduled the implementation of its next Global Ensemble Forecast System (GEFS v12) in the summer of 2020. These two model upgrades on deterministic and ensemble forecast systems are substantially different from previous upgrades. A new dynamical core (FV3) is adopted for the first time in the NCEP operational models, replacing the previous spectral dynamical core. The previous 3-category Zhao-Carr microphysics scheme is also being replaced by a more advanced 6-category GFDL microphysics scheme. From an ensemble model perspective, the previous GEFS has already demonstrated great success in past decades for weather and week-2 prediction by providing reliable probabilistic forecasts. Recently, there has been a large demand for subseasonal prediction, and GEFS v12 forecasts will be extended to 35 days to cover this time range. To better represent large uncertainties associated with this time scale, SPPT (stochastic physics perturbed tendency) and SKEB (stochastic kinetic energy backscatter) stochastic schemes are taking the place of the original STTP (stochastic total tendency perturbation), and a prescribed SST generated from combination of NSST and bias corrected CFS forecasts is also applied to simulate the sub-seasonal variation of SST forcing.    

As a major system upgrade,  a 2.5-year retrospective run of GEFS v12 is carried out to evaluate the model performance. A 30-year reforecast will be provided to stakeholders and the public to calibrate the forecast. The improvement of predictability and prediction skill will be studied through various measurements across tropical to extratropical areas in terms of deterministic (ensemble mean) and probabilistic (ensemble distribution) forecasts. The characteristics of model systematic error will be identified from comparing the major changes of the two state-of-art ensemble systems. As GEFS serves the most crucial model guidance for 5-7 day hurricane forecasts in support of the NHC (National Hurricane Center) and other customers, model capability in predicting tropical cyclone track and intensity is also examined from the retrospective runs. The results show there are significant improvements for tropical cyclone track forecast in North Atlantic and the western North Pacific, in particular, the intensity forecast is improved remarkably in all the basins.

How to cite: Fu, B., Zhu, Y., Zhou, X., and Hou, D.: Evaluation of NCEP next Global Ensemble Forecast System (GEFS v12), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6379, https://doi.org/10.5194/egusphere-egu2020-6379, 2020.

EGU2020-7354 | Displays | AS1.1

Predictive skill of atmospheric rivers in the Iberian Peninsula

Alexandre M. Ramos, Pedro M. Sousa, Emanuel Dutra, and Ricardo M. Trigo

In recent years a strong relationship has been found between Atmospheric Rivers (ARs) and extreme precipitation and floods across western Europe, with some regions having 8 of their top 10 annual maxima precipitation events related to ARs. In the case of the Iberian Peninsula, the association between ARs and extreme precipitation days has also been well documented, particularly for western Iberia river basins.

Since ARs are often associated with high impact weather, it is important to study their medium-range predictability. Here we perform such an assessment using the ECMWF ensemble forecasts up to 15 days, for events that made landfall in western Iberian Peninsula during the winters spanning between 2012/2013 and 2015/16. IVT and precipitation from the 51 ensemble members of the ECMWF Integrated Forecasting System (IFS) ensemble (ENS) were processed over a domain including western Europe and contiguous North Atlantic Ocean.

Metrics concerning the ARs location, intensity and orientation were computed, in order to compare the predictive skill (for different prediction lead times) of IVT and precipitation analyses in the IFS. We considered several regional boxes over Western Iberia, where the presence of ARs is detected in analysis/forecasts, enabling the construction of contingency tables and probabilistic evaluation for further objective verification of forecast accuracy. Our results indicate that the ENS forecasts have skill to detect upcoming ARs events, which can be particularly useful to improve the prediction of associated hydrometeorological extremes. We also characterized how the ENS dispersion and confidence curves change with increasing forecast lead times for each sub-domain. We employed the standard ROC analysis to evaluate the probabilistic component of these predictions showing that for short lead times precipitation forecasts are more accurate than IVT forecasts, while for longer lead times this result is reversed (~10 days). Furthermore, we show that this reversal occurs at shorter lead times in areas where the ARs contribution is more relevant for winter precipitation totals (e.g. northwestern Iberia).

 

Acknowledgements

The work done was supported by the project Landslide Early Warning soft technology prototype to improve community resilience and adaptation to environmental change (BeSafeSlide) funded by Fundação para a Ciência e a Tecnologia, Portugal (FCT, PTDC/GES-AMB/30052/2017). A.M.R. was also supported by the Scientific Employment Stimulus 2017 from FCT (CEECIND/00027/2017).

How to cite: Ramos, A. M., Sousa, P. M., Dutra, E., and Trigo, R. M.: Predictive skill of atmospheric rivers in the Iberian Peninsula , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7354, https://doi.org/10.5194/egusphere-egu2020-7354, 2020.

Security against extreme rainfall events is a basic need for social and economic development. The climate projections suggest a changing world in the rainfall patterns, forecasting increasingly extreme rainfall and droughts events; nevertheless, there is a lot of uncertainty in the future hydrologic cycle of the basins, where rainfall is the more complicated weather phenomena to predict. To deal with this difficulty, process such as assimilation, a better description of weather phenomena and the use of ensembles have been developed. Such technologic advances have resulted in the use of Numerical Weather Prediction Models (NWP) and its chain with Ensemble Prediction Systems (EPS), which have been recognized as valuable tools for a good Warning System.

Currently, Mexico City is one of the largest metropolis of the world with more than 22 million of inhabitants and serious difficulties oh hydraulic infrastructure. The city depends completely on the sewage system to prevent and mitigate floods. For these reasons, this work proposes to evaluate the deterministic and meteorological ensemble precipitation forecasts issued by the European Centre for Medium Range Weather Forecasting (ECMWF) for two study cases: 1) Mexico Valley Basin and 2) Mexico City. For study case 1, the precipitation forecasts were compared against 24 hours accumulated observed rainfall, issued by CLICOM System (clicom-mex.cicese.mx) and for 2007 to 2014 period time. For study case 2, the forecast were compared against observed real-time precipitation data issued by the Hydrological Observatory of Engineering Institute (OHIIUNAM), using a lead-time and time step of 90 hours and 6 hours respectively; and carried out for the rainy season of years 2017 and 2018. For this, deterministic and probabilistic verification metrics were applied (Relative Operating Characteristic, Reliability Diagram and the Brier Score) in order to measure the quality and performance of the forecasts products and its potential use for floods prediction in Mexico City.

The evaluation of the results shows that the observed events are within the range of the probability distribution, which means that the EPS constitutes a good representation of the possible atmospheric scenarios along the time horizon. Metrics establish a greater reliability for forecast in the range of 2 to 10 mm of accumulated rainfall in 24 hours; in the other hand, there is a good discrimination and accuracy of observed and unobserved events of accumulated precipitation of 1 mm in 6 hours.

How to cite: López López, M. R. and Pedrozo-Acuña, A.: Verification of Probabilistic Precipitation Forecasts in Metropolitan Area of Valley of Mexico Using the ECMWF Ensemble Prediction System, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12046, https://doi.org/10.5194/egusphere-egu2020-12046, 2020.

EGU2020-273 | Displays | AS1.1

Sampling errors on convective scales: What can we learn from a 1000-member ensemble?

Tobias Necker, Martin Weissmann, Yvonne Ruckstuhl, Juan Ruiz, Takemasa Miyoshi, and Jeffrey Anderson

Current regional forecasting systems particularly aim at the forecast of convective events and related hazards. Most weather centers apply high-resolution ensemble forecasts that resolve convection explicitly but can only afford a limited ensemble size of less than 100 members. Given that the degrees of freedom of atmospheric models are several magnitudes higher implies sampling errors. Sampling errors and fast error growth on convective scales in turn lead to a low predictability. Consequently, improving initial conditions and subsequent forecasts requires a better understanding of error correlations in both space and time.
For this purpose, we conducted the first convective-scale 1000-member ensemble simulation over central Europe. Several 1000-member ensemble forecasts are investigated during a high impact weather period in summer 2016 using ensemble sensitivity analysis. Spatial and spatiotemporal correlations are used to quantify sampling errors on convective scales. Correlations of the 1000-member ensemble forecast serve as truth to assess the performance of different localization approaches. Those approaches include a standard distance-based localization technique and a statistical sampling error correction method as proposed by Anderson (2012). Our study highlights advantages and disadvantages of existing methods and emphasises the need of different localization approaches for different scales and variables. Several results are published in Necker et al (2020a) and (2020b).

How to cite: Necker, T., Weissmann, M., Ruckstuhl, Y., Ruiz, J., Miyoshi, T., and Anderson, J.: Sampling errors on convective scales: What can we learn from a 1000-member ensemble?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-273, https://doi.org/10.5194/egusphere-egu2020-273, 2020.

EGU2020-15852 | Displays | AS1.1

Evaluation of near-surface temperature forecasts against super-site observations

Polly Schmederer, Irina Sandu, Thomas Haiden, Anton Beljaars, Martin Leutbecher, and Claudia Becker

ECMWF’s medium-range forecasts of near-surface weather parameters, such as 2 m temperature, humidity and 10 m wind speed, have become more skilful over the years, following the trend of improvements in the forecast skill of upper-air fields. However, they are still affected by systematic errors which have proved difficult to eliminate. Systematic forecast errors in temperature and humidity near the surface can be better understood by also examining errors higher up in the atmospheric boundary layer and in the soil. Meteorological observatories, also known as super-sites, provide long-term observational records of such vertical profiles. ECMWF started to use data from super-sites more systematically to evaluate the quality of forecasts in the lowest part of the atmosphere (up to 100m) and in the soil, in an attempt to disentangle sources of forecast error in near-surface weather parameters. Findings for 2-metre temperature errors in ECMWF forecasts at European super-sites suggest that the errors are partly the result of the model exchanging too much energy between the atmosphere and the land. However, the influence of other factors, such as errors resulting from the representation of vegetation in semi-arid areas and from small-scale variations in vegetation and soil type near measurement stations, mean that it is difficult to adjust the energy exchange in a way which leads to an overall error reduction on the European scale.

How to cite: Schmederer, P., Sandu, I., Haiden, T., Beljaars, A., Leutbecher, M., and Becker, C.: Evaluation of near-surface temperature forecasts against super-site observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15852, https://doi.org/10.5194/egusphere-egu2020-15852, 2020.

The main goal of the ECMWF Special Project SPITCAPE is to understand the information content of the current ensemble systems both at global and meso scales in re-forecasting past high-impact weather events. In particular one of the main questions addressed in the project is: what is the added value of running a high-resolution (namely convection-permitting) ensembles for high-impact weather events with respect to global ones?
Running operational Ensemble Prediction Systems (EPS) at the convection-permitting (CP) scale is currently on the agenda at a number of European weather forecasting services and research centres: UK Met Office, Météo France and DWD to mention a few. Moreover, in the framework of the activities of the forthcoming ItaliaMeteo agency, it is foreseen the development of a regional EPS at CP scale for the Italian domain.
Recently, it has been demonstrated that the baseline approach of dynamical downscaling using CP models nested in a global ensemble with a coarser horizontal resolution (e.g. 20 km) provides valuable information. Since the introduction of the IFS model cycle 41r2 in March 2016, the horizontal resolution of the ECMWF ensemble forecasts (ENS) is about 18 km and it is planned to be further increased up to 10 km in the next future
(after the installation of the new supercomputer in the Bologna data center). Thus, these higher-resolution global ENS data allow us to estimate the technical feasibility and value of the simple dynamical downscaling method to initialise limited-area and CP models (the WRF-ARW, MESO-NH and MOLOCH models in the present case) directly nested in the new ECMWF global ensemble.
We applied this pragmatic approach in re-forecasting two high-impact weather events occurred in Italy in recent years (the Cinque Terre flooding occurred in October 2011 and the flash flood of Genoa in November 2011) with the ENS global forecasts and the data produced with the WRF-ARW, MESO-NH and MOLOCH models. The skills of the forecasts in the short-range are evaluated in terms of Probability of Precipitation exceeding predefined rainfall thresholds. In the medium-range we report and discuss the forecast uncertainty (i.e. ensemble spread) of ENS at different starting dates. Besides the fact that both global and regional model data under-estimate rainfall maxima in the area of interest, results demonstrate that CP ensemble forecasts provide better predictions regarding the occurrence of extreme precipitations and the area most likely affected.
The comparison among results obtained with regional models contribute to the debate regarding the reliability of these models and their strengths and weaknesses with respect to: (I) the accuracy of the results for the two events considered, (II) the integration with ECMWF products, (III) the ease of implementation and (IV) the computational costs in view of a potential use for operational forecasting activities.

How to cite: Capecchi, V. and Gozzini, B.: Evaluating current convection-permitting ensembles for past high-impact weather events in Italy: results from the SPITCAPE Special Project, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18941, https://doi.org/10.5194/egusphere-egu2020-18941, 2020.

The Marine Meteorology Division of the U.S. Naval Research Laboratory (NRL) has developed and transitioned a 3DVAR reflectivity data assimilation (DA) system into operations at Fleet Numerical Meteorology and Oceanography Center (FNMOC), located in Monterey, California.  The system assimilates hourly, volumetric, radar reflectivity data into the Coupled Ocean/Atmosphere Mesoscale Prediction System (COAMPS®)1 high-resolution NWP model within the ship-following COAMPS – On demand System (COAMPS-OS®)1.  Both Next-Generation Radar (NEXRAD) land-based radar data and U.S. Navy shipboard SPS-48/Hazardous Weather Detection and Display Capability (HWDDC) radar data are assimilated depending on their data coverage provided to the COAMPS® nested grids. The SPS-48/HWDDC units are installed on eighteen U.S. Navy aircraft carriers and amphibious assault ships, and when underway on a mission, the available units automatically transmit compressed, radar data files to FNMOC near the top of the hour.  Through previously reported NRL and FNMOC demonstrations, and more recent operationally testing at FNMOC, the COAMPS-OS® radar DA system’s nowcasting products have demonstrated their ability to provide improved predictions of precipitation events out to at least 6 hour forecasts compared to 3DVAR conventional DA into COAMPS® alone.  Shipboard SPS-48/HWDDC radar data and their assimilation into COAMPS-OS® at FNMOC provide critical environmental awareness in the data sparse oceanic regions of the world that the Navy warfighter encounters.

The SPS-48 radar is a S-band, phased-array, azimuthally scanning, air-search radar that scans electronically in elevation and completes a volume scan in four seconds. The HWDDC combines the volume scans into motion-compensated, one-minute composites with limited clutter filtering applied. The SPS-48 beams are combined to yield full PPI scans at 22 different elevation angles ranging from 0.1° to 24°. The azimuthal resolution of the data is 1° and the range resolution is 1 km. The maximum range for reflectivity (radial velocity) data is 250 (81) km.  The Doppler data are only produced for the lowest three elevation scans whereas reflectivity data are produced for all elevation scans; all these data are archived in Universal Format and compressed before dissemination to FNMOC.   Owing to the limited HWDDC Doppler data both in range and elevation, and the single-polarization of the SPS-48 radar waveform, reflectivity data quality control is particularly challenging.  New algorithms have been developed to handle sea clutter and constant power function artifacts, such as bullseyes and sun strobes.  There are two algorithms for sea clutter; the first one deals with anomolus propagation sea clutter caused by sea-water evaporation into the atmospheric surface layer, and the second one deals with the more widespread and distant sea clutter due to surface-based and elevated electromagnetic ducts resulting from trapped moist air under temperature inversions often encountered off the coasts of California and the Arabian Gulf region.  An overview of the ship-following COAMPS-OS® radar data quality control and assimilation system will be presented along with examples of quality controlled SPS-48/HWDDC radar data and the impact on COAMPS® forecast skill scores.

 

1 COAMPS and COAMPS-OS are registered trademarks of the U.S. Naval Research Laboratory

How to cite: Harasti, P.: Quality Control of Sea Clutter and Constant Power Function Artifacts for Operational U.S. Navy Shipboard Radar Data Assimilation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11989, https://doi.org/10.5194/egusphere-egu2020-11989, 2020.

EGU2020-6451 | Displays | AS1.1

Development of 10-minute interval analysis and prediction system in KMA

Minyou Kim, Keunhee Lee, and Yong Hee Lee

To be well prepared for rapidly-developing meteorological hazards in advance, quick and qualified information on real-time and very-short range (within 6 hours) forecasts is required. KLAPS (Korea Local Analysis and Prediction System) was developed for the operational very-short range forecasts in KMA (Korea Meteorological Administration), based on the LAPS (Local Analysis and Prediction System) from NOAA and WRF from NCAR in 2009. Recently, KLAPS is updated to use new observation datasets and physics schemes from KIM (Korea Integrated Model) to improve its very-short range precipitation forecast skills. New observation data sources (geostationary satellite, RADAR, ground-based GNSS(Global Navigation Satellite System), ceilometer, local radiosonde, etc.) are ingested into KLAPS in real-time to resolve rapidly developing mesoscale systems. Physics schemes (WDM7, KSAS(Kiaps SAS), RRTMG, Shing-Hong PBL, etc.) based on KIM physics package are implemented in KLAPS to support the high-resolution physics. The new KLAPS is now operated in 10-minute interval, so that it could provide 10-minute interval precipitation forecasts to the public(www.weather.go.kr) every 10 minutes. The advantages of 10-minute interval analysis and forecast system will be presented.

How to cite: Kim, M., Lee, K., and Lee, Y. H.: Development of 10-minute interval analysis and prediction system in KMA, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6451, https://doi.org/10.5194/egusphere-egu2020-6451, 2020.

Heavy precipitation forecast remains one of the biggest problems in numerical weather prediction. Modern remote sensing systems allow tracking of rapidly developing convective processes and provide additional data for numerical weather models practically in real time. Assimilation of Doppler weather radar data also allows to specify the position and intensity of convective processes in atmospheric numerical models.

The primary objective of this study is to evaluate the impact of Doppler  radar reflectivity and velocity assimilation in the WRF-ARW mesoscale model for the territory of Belarus in different seasons of the year. Specifically, we focus on the short-range numerical forecasting of mesoscale convective systems passage over the territory of Belarus in 2017-2019 with assimilated radar data.

Proceeding with weather radar observations available for our cases, we first perform the necessary processing of the raw radar data to eliminate noise, reflections and other kinds of clutter. For identification of non-meteorological noise fuzzy echo classification was used. Then we use the WRF-DA (3D-Var) system to assimilate the processed radar observations from 3 Belarusian Doppler weather radar in the WRF model. Assimilating both radar reflectivity and radial velocity data in the model we aim to better represent not only the distribution of clouds and their moisture content, but also the detailed dynamical aspects of convective circulation. Finally, we analyze WRF modelling output obtained with assimilated radar data and compare it with available meteorological observations and with other model runs (including control runs with no data assimilation or with assimilation of conventional weather stations data only), paying special attention to the accuracy of precipitation forecast 12 hours in advance.

How to cite: Zaiko, P., Barodka, S., and Krasouski, A.: Impact of Doppler radar reflectivity and velocity data assimilation on the quality of precipitation forecasting in Belarus in different seasons, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-779, https://doi.org/10.5194/egusphere-egu2020-779, 2020.

EGU2020-1949 | Displays | AS1.1

Assessments of Assimilation of TEMPEST-D into the NCEP Global Forecast System

Ting-Chi Wu, Milija Zupanski, Lewis Grasso, James Fluke, Heather Cronk, Anton Kliewer, Richard Schulte, Wesley Berg, Christian Kummerow, Philip Partain, and Steven Miller

Unlike large, expensive, and high-risk operational satellites, small/cube satellites (SmallSats) are a small, inexpensive, and a low-risk type of satellite. As a NOAA Cooperative Institute with specialties in satellite data processing and data assimilation, CIRA is funded by a Technology Maturation Program (TMP) research project to help NOAA exploit upcoming constellation of SmallSats to be considered for use in operations. In this research, a CSU-led technology demonstration mission entitled “the Temporal Experiment for Storms and Tropical System - Demonstration (TEMPTEST-D)” is used as an example to explore quick and agile methodologies to entrain SmallSats into the NOAA processing stream. Specifically, a workflow that enables TEMPEST-D data for assimilation into the NCEP Global Forecast System (GFS) with Finite-Volume Cube-Sphered (FV3) dycore (FV3GFS) under the Gridpoint Statistical Interpolation (GSI) based hybrid 4DEnVar system is established.

One objective of this TMP research project is to assess the impact of SmallSat data on NOAA modeling and assimilation systems used in operations. We begin by asking whether the use of TEMPEST-D data is as good as the use of those obtained from well-established operational satellite sensors. Since the radiometric specification of TEMPEST-D is similar to the Microwave Humidity Sounder (MHS), we address the above question by directly comparing the following three cycled FV3GFS data assimilation and forecasting experiments: 1) the control experiment, which includes all routinely assimilated observations, but only assimilates MHS from the NOAA-19 and MetOp-B platforms, 2) the AddMHS experiment, which is the control plus MHS from the MetOp-A platform, and 3) the AddTEMPEST experiment, which is the control plus TEMPEST-D.

By differentiating the AddMHS and AddTEMPEST experiments against the control experiment, we will be able to demonstrate that a cost-effective TEMPEST-D is as beneficial as a well-established operational satellite like MHS, in terms of aiding operational global weather forecasting. In addition, results from this research offers implications of the utility of a constellation of SmallSats microwave radiometers for global weather forecasting.  

How to cite: Wu, T.-C., Zupanski, M., Grasso, L., Fluke, J., Cronk, H., Kliewer, A., Schulte, R., Berg, W., Kummerow, C., Partain, P., and Miller, S.: Assessments of Assimilation of TEMPEST-D into the NCEP Global Forecast System, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1949, https://doi.org/10.5194/egusphere-egu2020-1949, 2020.

High frequency (20 Hz) aircraft observations from the Government Flying Service of the Hong Kong Government, penetrating a tropical cyclone (TC) at low altitude over the South China Sea had an extremely inhomogeneous distribution. Today the remoting observations have been widely used, but our work demonstrates aircraft observations still play an important role in TCs forecasts.

To investigate an effective scheme for assimilating inhomogeneous aircraft observations, a multigrid 3D variation (m3DVAR) system, with the assistance of a bogus vortex, was employed. Track and intensity forecasts were improved by assimilating aircraft observations and bogus data. The assimilation of pressure (horizontal wind) was also found mainly to contribute to the large magnitude (sophisticated distribution) of increments.

These aircraft observations were also thinned by arithmetic means over different time intervals to identify structures of tropical cyclone at different scales. It is found that the thinning process can reduce serial correlation in observational errors and enhance the representation of aircraft observations. The changes in dynamic structures indicate that the imbalance generated from assimilating aircraft observations at the sub-grid scale can be alleviated by using longer time intervals of the arithmetic mean. Assimilating aircraft observations at the grid scale achieves optimal forecasts based on verifications against independent observations and investigations of environmental and ventilation flows.

In fact, the west Pacific had access to aircraft observations but these observations stopped in 1987. We hope we can call attentions of governors and scientists to reboot in situ observations on aircraft platform in the west Pacific by disseminating our results. This can be a significant benefit to improving the regional real-time forecasts and understanding the climate variabilities of TCs. We already had two publications related to the assimilation of aircraft observations (Gao et al., 2019; Gao et al., 2019).

 

References:

Gao, Y, Xiao, H, Chan, PW, Hon, Kai kwong, Wan, Q, Ding, W. Application of the multigrid 3D variation method to a combination of aircraft observations and bogus data for Typhoon Nida (2016). Meteorol Appl. 2019; 26: 312– 323. https://doi.org/10.1002/met.1764.

 

Gao, Y.; Xiao, H.; Jiang, D.; Wan, Q.; Chan, P.W.; Hon, K.K.; Deng, G. Impacts of Thinning Aircraft Observations on Data Assimilation and Its Prediction during Typhoon Nida (2016). Atmosphere 2019, 10, 754. https://doi.org/10.3390/atmos10120754.

How to cite: Gao, Y.: Assimilation of aircraft observations in the South China Sea to improve forecasts of tropical cyclones, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2370, https://doi.org/10.5194/egusphere-egu2020-2370, 2020.

To facilitate the future inclusion of aerosol-radiation interactions in the regional operational Numerical Weather Prediction (NWP) system – RMAPS-ST (adapted from Weather Research and Forecasting, WRF) at Institute of Urban Meteorology (IUM), China Meteorological Administration (CMA), the impacts of aerosol-radiation interactions on the forecast of surface radiation and meteorological parameters during a heavy pollution event (December 6th -10th, 2015) over northern China were investigated. The aerosol information was simulated by RMAPS-Chem (adapted from WRF model coupled with Chemistry, WRF-Chem) and then offline-coupled into Rapid Radiative Transfer Model for General Circulation Models (RRTMG) radiation scheme of WRF to enable the aerosol-radiation feedback in the forecast. To ensure the accuracy of high-frequent (hourly) updated aerosol optical depth (AOD) field, the temporal variations of simulated AOD at 550nm were evaluated against satellite and in-situ observation, which showed great consistency. Further comparison of PM2.5 with in-situ observation showed WRF-Chem reasonably captured the PM2.5 field in terms of spatial distribution and magnitude, with the correlation coefficients of 0.85, 0.89 and 0.76 at Beijing, Shijiazhuang and Tianjin, respectively. Forecasts with/without the hourly aerosol information were conducted further, and the differences of surface radiation, energy budget, and meteorological parameters were evaluated against surface and sounding observations. The offline-coupling simulation (with aerosol-radiation interaction active) showed a remarkable decrease of downward shortwave (SW) radiation reaching surface, thus helps to reduce the overestimated SW radiation during daytime. The simulated surface radiation budget has also been improved, with the biases of net surface radiation decreased by 85.3%, 50.0%, 35.4%, and 44.1% during daytime at Beijing, Tianjin, Taiyuan and Jinan respectively, accompanied by the reduction of sensible (16.1 W m−2, 18.5%) and latent (6.8 W m−2, 13.4%) heat fluxes emitted by the surface at noon-time. In addition, the cooling of 2-m temperature (~0.40 °C) and the decrease of horizontal wind speed near surface (~0.08 m s-1) caused by aerosol-radiation interaction over northern China helped to reduce the bias by ~73.9% and ~7.8% respectively, particularly during daytime. Further comparison indicated that the simulation implemented AOD could better capture the vertical structure of atmospheric wind. Accompanied with the lower planetary boundary layer and the increased atmospheric stability, both U and V wind at 850hPa showed the convergence which were unfavorable for pollutants dispersion. Since RMPAS-ST provides meteorological initial condition for RMPS-Chem, the changes of meteorology introduced by aerosol-radiation interaction would routinely impact the simulations of pollutants. These results demonstrated the profound influence of aerosol-radiation interactions on the improvement of predictive accuracy and the potential prospects to offline couple near-real-time aerosol information in regional RMAPS-ST NWP in northern China.

How to cite: Yang, Y., Chen, D., and Zhao, X.: Impacts of aerosol-radiation interaction on meteorological forecast over northern China by offline coupling the WRF-Chem simulated AOD into WRF: a case study during a heavy pollution event, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2354, https://doi.org/10.5194/egusphere-egu2020-2354, 2020.

EGU2020-7244 | Displays | AS1.1

Improving Operational Numerical Prediction of Afternoon Thunderstorms over Taiwan through Surface Data Assimilation

I-Han Chen, Jing-Shan Hong, Ya-Ting Tsai, and Chin-Tzu Fong

Taiwan, a subtropical island with steep mountains, is influenced by diverse weather systems, including typhoons, monsoons, frontal, and convective systems. Of these, the prediction of deep, moist convection here is particularly challenging due to complex topography and apparent landsea contrast. This study explored the benefits of assimilating surface observations on prediction of afternoon thunderstorms using a 2-km resolution WRF and WRFDA model system with rapid update cycles. Consecutive afternoon thunderstorm events during 30 June to 08 July 2017 are selected. Five experiments, consisting of 240 continuous cycles are designed to evaluate the data assimilation strategy and observation impact. Statistical results show that assimilating surface observations systematically improves the accuracy of wind and temperature prediction near the surface. Also, assimilating surface observations alone in one-hour intervals improves model quantitative precipitation forecast (QPF) skill, extending the forecast lead time in the morning. Furthermore, radar data assimilation can benefit by the additional assimilation of surface observations, particularly for improving the model QPF skill for large rainfall thresholds. An afternoon thunderstorm event that occurred on 06 July 2017 is further examined. By assimilating surface and radar observations, the model is able to capture the timing and location of the convection. Consequently, the accuracy of the predicted cold pool and outflow boundary is improved, when compared to the surface observations.

How to cite: Chen, I.-H., Hong, J.-S., Tsai, Y.-T., and Fong, C.-T.: Improving Operational Numerical Prediction of Afternoon Thunderstorms over Taiwan through Surface Data Assimilation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7244, https://doi.org/10.5194/egusphere-egu2020-7244, 2020.

EGU2020-4149 | Displays | AS1.1

A Methodology for Optimizing Numerical Weather Prediction Models

Rafaella - Eleni Sotiropoulou, Ioannis Stergiou, and Efthimios Tagaris

Optimizing the performance of numerical weather prediction models is a very complicated process due to the numerous parameterization choices provided to the user. In addition, improving the predictability of one model’s variable (e.g., temperature) does not necessarily imply the improvement of another (e.g., precipitation). In this work the Technique of Preference by Similarity to the Ideal Solution (TOPSIS) is suggested as a method to optimize the performance of a numerical weather prediction model. TOPSIS provides the ability of using multiple statistical measures as ranking criteria for multiple forecasting variables. The Weather Research and Forecasting model (WRF) is used here for application of TOPSIS in order to optimize the model’s performance by the combined assessment of temperature and precipitation over Europe. Six ensembles optimize model’s physics performance (i.e., microphysics, planetary boundary layer, cumulus scheme, Long–and Short– wave and Land Surface schemes). The best performing option for each ensemble is selected by using multiple statistical criteria as input for the TOPSIS method, based on the integration of entropy weights. The method adopted here illustrates the importance of an integrated evaluation of weather prediction models’ performance and suggests a pathway for its improvement.

Acknowledgments LIFE CLIMATREE project “A novel approach for accounting & monitoring carbon sequestration of tree crops and their potential as carbon sink areas” (LIFE14 CCM/GR/000635).

How to cite: Sotiropoulou, R.-E., Stergiou, I., and Tagaris, E.: A Methodology for Optimizing Numerical Weather Prediction Models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4149, https://doi.org/10.5194/egusphere-egu2020-4149, 2020.

Low-level wind shear could occur not only in rainy weather conditions but also in non-rainy weather conditions, which is dangerous to aircraft safety for its rapid changes in wind direction or velocity. Recently, dry wind shear occurred in non-rainy condition has drawn more and more attention. Rain-detecting Doppler radar has no capabilities in detecting dry wind shear occurred in non-rainy condition, while Doppler Lidar observations with higher spatial and temporal resolution provide valuable information for dry wind shear. For this, considering dry wind shear cases reported by pilots at Lanzhou Zhongchuan International Airport as study object, lidar observations (radial velocities) were assimilated along with surface data to improve the prediction skill of dry wind shear events.

All experiments were conducted with Weather Research and Forecasting (WRF) model and its three-dimensional variational (3D-VAR) system. Three-nested domains were employed with 1-km horizontal resolution in the innermost domain. The model was derived by the NCEP FNL data. Lidar data was processed and only assimilated in the innermost domain. Experimental results show that the low-level wind shear can not be found in the experimental results without lidar data assimilation, while lidar data assimilation experiment successfully represented wind shear small-scale characteristics and simulated radial wind pattern was close to lidar observation. In addition, assimilation cycles with short time intervals effectively improved simulation accuracy of wind shear events.

How to cite: Li, L. and Shao, A.: Impact of Lidar Data Assimilation on Analysis and Prediction of Low-level Wind Shears at Lanzhou Zhongchuan International Airport, China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5030, https://doi.org/10.5194/egusphere-egu2020-5030, 2020.

Lacking of high-resolution observations over oceans is one of the major problems for the numerical simulation of the tropical cyclones (TC), especially for the tropical cyclone inner-core structure’s simulation. Satellite observations plays an important role in improving the forecast skills of numerical weather prediction (NWP) systems. Many studies have suggested that the assimilation of satellite radiance data can substantially improve the numerical weather forecast skills for global model. However, the performance of satellite radiance data assimilation in limited-area modeling systems is still controversial.

This study attempts to investigate the impact of assimilation of the Advanced Technology Microwave Sounder (ATMS) satellite radiances data and its role to improve the model initial condition and forecast of typhoon LEKIMA(2019) using a regional mesoscale model. In this study, detailed analysis of the data impact will be presented, also the results from different data assimilation methods and different data usage schemes will be discussed.

How to cite: Zhang, L. and Chen, B.: Improving numerical simulation of typhoon LEKIMA(2019) through assimilating ATMS radiance data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6256, https://doi.org/10.5194/egusphere-egu2020-6256, 2020.

EGU2020-4327 | Displays | AS1.1

Improve Tropical Cyclone Prediction of TWRF with the Application of Advanced Observation Data

Der-Song Chen, Ling-Feng Hsiao, Jia-Hong Xie, Jing-Shan Hong, Chin-Tzu Fong, and Tien-Chiang Yeh

With violent wind and severe rainfall, the tropical cyclone is one of the most disastrous weather systems over ocean and the coastal area. To provide accurate tropical cyclone (TC) track and intensity forecasts is one of the most important tasks of the national weather service of countries affected. Taiwan is one of the areas frequently influenced by tropical cyclones. Improving the tropical cyclone forecast is the highest priority task of Taiwan’s Central Weather Bureau (CWB).

Recent improvement of the TC forecast is due to the improvement of the numerical weather prediction. A version of the Advanced Research Weather Research and Forecasting Model (WRF), named TWRF (Typhoon WRF), was developed and implemented in CWB for operational TC forecasting from 2011. During the years, partial update cycling, cyclone bogus scheme, relocation scheme, 3DVAR with outer loop, analysis blending scheme, new trigger Kain–Fritsch cumulus scheme, and so on have been studied and applied in TWRF (Hsiao et al. 2010, 2012, 2015) to improve the model. We also improved the model by changing the TWRF configuration from a triple nested to a double nested grid and increasing the model resolution from 45/15/5 km 45-levels to 15/3 km 52-levels from 2016. Results showed increasing the model resolution improving the track, intensity and rainfall forecast. However, The averaged 24/48/72 hours TC track forecast errors of TWRF are 91/147/223, 84/133/197, 74/127/215, 64/122/202, 70/120/194 and 70/122/180 km in year 2014, 2015, 2016, 2017, 2018 and 2019 respectively.

In this study, WRF Four-dimensional data assimilation (FDDA) is adopted to assimilate the temperature, pressure, water vapor content which processed from the FORMOSAT-7 constellation, high-temporal frequency atmospheric motion vector (AMV) retrieved from Himawari-8 satellite images and radar data to generate a model balanced TC structure and thermodynamic state at the initial time. The specific goal is to improve the track, structure and intensity prediction of TCs and their associated rainfall distribution in Taiwan. The detail will be presented in the conference.

Keywords: tropical cyclone, Himawari-8 AMV, Four-dimensional data assimilation, FORMOSAT-7, radar data.

Corresponding author address:

Der-Song Chen,  song@cwb.gov.tw

Central Weather Bureau, 64 Gongyuan Rd., Taipei, Taiwan, R.O.C., 10048.

How to cite: Chen, D.-S., Hsiao, L.-F., Xie, J.-H., Hong, J.-S., Fong, C.-T., and Yeh, T.-C.: Improve Tropical Cyclone Prediction of TWRF with the Application of Advanced Observation Data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4327, https://doi.org/10.5194/egusphere-egu2020-4327, 2020.

The system of multigrid NLS-4DVar data assimilation for Numerical Weather Prediction (SNAP) is established, building upon the multigrid NLS-4DVar assimilation scheme, the operational Gridpoint Statistical Interpolation (GSI)-based data-processing and observation operator and widely used numerical forecast model WRF (easily replaced by others global/regional model). The multigrid assimilation framework can adequately correct errors from large to small scales to achieve higher assimilation accuracy. Meanwhile, the multigrid strategy can accelerate iteration solution improving the computational efficiency. NLS-4DVar, as an advanced 4DEnVar method, employs the Gauss-Newton iterative method to handle the nonlinear of the 4DVar cost function and provides the flow-dependent background error covariance, which both contribute to the assimilation accuracy. The efficient local correlation matrix decomposition approach and its application in the fast localization scheme of NLS-4DVar and obviating the need of the tangent linear and adjoint model further improve the computational efficiency. The numerical forecast model of SNAP is any optional global/regional model, which makes the application of SNAP very flexible. The analysis variables of SNAP are rather the model state variables than the control variables adopted in the usual 4DVar system. The data-processing and observation operator modules are used from the National Centers for Environmental Prediction (NCEP) operational GSI analysis system, prominent in the various observation operators and the ability to assimilate multi-source observations. Currently, we have achieved the assimilation of conventional observations and we will continue to improve the assimilation of radar and satellite observations in the future. The performance of SNAP was investigated assimilating conventional observations used for the generation of the operational global atmospheric reanalysis product (CRA-40) by the National Meteorological Information Center of China Meteorological Administration. Cyclic assimilation experiments with two windows, which is 6-h for each window, are designed. The results of numerical experiments show that SNAP can absorb observations, improve initial field, and then improve precipitation forecast.

How to cite: Zhang, H. and Tian, X.: System of Multigrid NLS-4DVar Data Assimilation for Numerical Weather Prediction (SNAP):System Formulation and Preliminary Evaluation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3812, https://doi.org/10.5194/egusphere-egu2020-3812, 2020.

EGU2020-7629 | Displays | AS1.1

Radar and lightning data assimilation: the impact of different setting options discussed for a heavy precipitation event occurred in Italy.

Rosa Claudia Torcasio, Stefano Federico, Silvia Puca, Marco Petracca, Gianfranco Vulpiani, Luca Baldini, and Stefano Dietrich

The forecast of severe events at the local scale still remains challenging because of the multitude of physical processes involved on a wide range of scales. Improving the initial conditions (IC) of numerical weather prediction (NWP) models is a key point for good forecasting. Since limited-area models are nowadays operational at the kilometric scale (< 5 km), the assimilation of data from high-resolution space-time observations is crucial to correctly represent the state of the atmosphere at local scale.

Radar and lightning data are both useful to improve the IC of NWP models for several reasons. Radar data is available with a high spatio-temporal resolution and provides information on hydrometeors and wind, while lightning data locates convection both spatially and temporally accurate.

Recently, Federico et al. (2019) studied the impact of radar reflectivity factor and lightning data assimilation on the Very Short-Term Forecast (VSF) of the RAMS@ISAC NWP model for two intense precipitation events over Italy. They found that, despite an improvement of the rainfall VSF due to the assimilation of lightning and radar reflectivity factor data, the usefulness of the procedure is partially limited by the increase in false alarms, especially in case of high precipitation rates (> 50 mm/3h).

In this work, we apply the methodology proposed by Federico et al. (2019) to an intense precipitation event occurred in Italy in November 2019. The RAMS@ISAC meteorological model is used here, with a horizontal resolution of 3km.

RAMS@ISAC is initialized by a 3D-Var data assimilation scheme that uses both lightning and radar reflectivity factor data. Different 3D-Var data assimilation scheme settings are used to produce different ICs for the RAMS@ISAC model for the specific case.  The sensitivity of the precipitation field prediction to changes in these ICs will be discussed.

Keywords: lightning data assimilation, radar reflectivity factor data assimilation, very short-term forecast, numerical weather prediction

Reference

Federico, S., Torcasio, R. C., Avolio, E., Caumont, O., Montopoli, M., Baldini, L., Vulpiani, G., and Dietrich, S.: The impact of lightning and radar reflectivity factor data assimilation on the very short-term rainfall forecasts of RAMS@ISAC: application to two case studies in Italy, Nat. Hazards Earth Syst. Sci., 19, 1839–1864, https://doi.org/10.5194/nhess-19-1839-2019, 2019.

How to cite: Torcasio, R. C., Federico, S., Puca, S., Petracca, M., Vulpiani, G., Baldini, L., and Dietrich, S.: Radar and lightning data assimilation: the impact of different setting options discussed for a heavy precipitation event occurred in Italy., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7629, https://doi.org/10.5194/egusphere-egu2020-7629, 2020.

EGU2020-6752 | Displays | AS1.1

Impact of MODIS land cover data on surface predictions over Taiwan in the FV3GFS model

Ling-Feng Hsiao and Feng-Ju Wang

The global numerical weather prediction (NWP) system based on the FV3GFS model jointly developed by U.S. National Centers for Environmental Prediction (NCEP) and Geophysical Fluid Dynamics Laboratory (GFDL) has been implemented in the Taiwan’s Central Weather Bureau (CWB) forecast system for the next generation global NWP operations. Currently, NCEP FV3GFS model provides land use dataset retrieved from Moderate Resolution Imaging Spectroradiometer (MODIS) satellite observations. The MODIS 20-category data is composed of roughly 12 km resolution data elements. However, the modified of the 20-class MODIS land cover dataset with a resolution of 500 m which defined by the International Geosphere-Biosphere Program (IGBP) is provided by WRF model. A significant difference between these two datasets is MODIS data from NCEP FV3GFS as being extremely urbanized in western Taiwan. In a case of weaker synoptic-scale forcing, the modified MODIS land cover dataset from WRF model result in a larger improvement in 2-m temperature and 2-m mixing ratio when compare to the surface observations over Taiwan. The reason results from the overestimation of urban area in NCEP FV3GFS model, which contains previous and low-resolution MODIS dataset. Moreover, there is a bias reduction in 10-m wind speed as well as thermal effects. The detailed results will be presented in the conference.

How to cite: Hsiao, L.-F. and Wang, F.-J.: Impact of MODIS land cover data on surface predictions over Taiwan in the FV3GFS model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6752, https://doi.org/10.5194/egusphere-egu2020-6752, 2020.

EGU2020-12466 | Displays | AS1.1

Recent and potential future evolution of practical predictability across scales

Nedjeljka Žagar and Istvan Szunyogh

In this talk we use the data from an operational ensemble prediction system to investigate recent developments in practical predictability across scales. Furthermore, we separate the estimated forecast error data into components representing the two dominant regimes in the atmosphere, the Rossby and inertia-gravity regimes. The latter is used to discuss aspects of tropical predictability.

We define the practical predictability limit of a meteorological field (e.g., meridional wind at 500 hPa) or of a variability mode (e.g., the equatorial Kelvin wave) by the forecast time at which the root mean square (rms) forecast error normalized by its saturation value reaches a prescribed threshold value (e.g., 60%).

The investigative technique fits a parametric function to the curve that describes the growth of the rms error of the forecasts with forecast time for a sample of forecasts. The parametric model describes the functional dependence of the magnitude of the forecast error on the magnitude of the initial error. Thus, it can be used for the estimation of the forecast error reduction that can be achieved by reducing the magnitude of the analysis error by a presumed percentage. Likewise, it can be used for the quantitative attribution of the forecast improvements between the years to analysis or model improvements.

The calculations are carried out for the different spatial scales and the two regimes separately.

How to cite: Žagar, N. and Szunyogh, I.: Recent and potential future evolution of practical predictability across scales , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12466, https://doi.org/10.5194/egusphere-egu2020-12466, 2020.

EGU2020-11997 | Displays | AS1.1

Uncertainties in forecasting orographic flows

Haraldur Ólafsson

The accuracy of a large set of high-resolution wind speed forecasts with different lead times is assessed for different parts of orographic flows, including upstream blockings, gap winds, corner winds, wakes and downslope winds.  The by far largest errors are in areas of downslope windstorms, but there are also considerable errors in the other parts of orographic disturbances to the flow and they are greater than in non-orographic flows in the same region.  The errors are discussed in view of the different dynamics and kinematics of the flows.  They are partly related to intermittency of i.e. gravity waves as well as strong spatial gradients in the wind field.

How to cite: Ólafsson, H.: Uncertainties in forecasting orographic flows, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11997, https://doi.org/10.5194/egusphere-egu2020-11997, 2020.

EGU2020-22110 | Displays | AS1.1

Changes in land surface and weather forecasting

Iman Rousta and Haraldur Ólafsson

The Normalized Difference Vegetation Index (NDVI) has been retrieved and analyzed for Iceland.  There are only limited trends in the total integrated NDVI in the period 2001 - 2018.  However, there is a positive trend in recent decades in the occurrence of signal corresponding to woodland and forests.   Locally, there may however be great changes; some small deserts have turned green and systematic planting of trees in certain regions is well detectable. The impact, and the driver of these changes are discussed in the context of climate and the implication for thermally driven weather systems and local weather forecasting is explained. 

How to cite: Rousta, I. and Ólafsson, H.: Changes in land surface and weather forecasting, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22110, https://doi.org/10.5194/egusphere-egu2020-22110, 2020.

The COSMO-D2-EPS ensemble is running operationally at DWD at a resolution of 2.2 km. In the framework of the transition from the COSMO to the ICON model for the limited-area applications, the ICON-D2-EPS ensemble is starting its pre-operational phase. Therefore, the perturbation strategy developed for COSMO-D2-EPS is adapted to the new ensemble.
In this work, the focus is on the initial conditions, which are provided by the first 20 analyses generated by a LETKF ensemble data assimilation system (KENDA).
The KENDA analyses present the advantage of providing perturbed initial conditions to the convection-permitting ensemble, where the perturbations contain also the information on the convection-permitting scale uncertainties. On the other hand, the KENDA analyses are optimised for the purpose of data assimilation. The ensemble of analyses which is the most suitable for initialising the next data assimilation cycle may not be the same which is the most suitable for initialising the weather forecast ensemble, e.g. in terms of spread.

The analyses generated by the KENDA cycle are evaluated from the point of view of their usage for ensemble forecasting initialisation. Their spread is computed for different variables, assessing also how it varies with the spatial scale and with the weather situation. Furthermore, the spread is compared to the error of the analyses and of the forecasts, in order to assess the ability of the analyses to describe the initial condition uncertainty. 
The growth of the differences between the members during the first hours of the forecasts is studied as well, in dependence on the weather situation.

The final aim of this work is to identify possible improvements for deriving the ensemble initial conditions from the KENDA analyses.

How to cite: Marsigli, C.: On the initial conditions of the ICON-D2-EPS ensemble: An analysis in terms of spread and skill., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10803, https://doi.org/10.5194/egusphere-egu2020-10803, 2020.

EGU2020-18197 | Displays | AS1.1

Ensemble prediction with OpenIFS

Pirkka Ollinaho
Probabilistic forecasts provide information on how predictions of the atmospheric evolution may differ from the best guess solution provided by a deterministic forecast. Ensemble prediction systems generate this information through assessing uncertainties in both the model initial state and the model itself. In order to open up ensemble prediction research for a wider research community, we have recreated all 50+1 operational ECMWF ensemble initial states for OpenIFS. The data set covers one year (December 2016 to November 2017) twice a day. A range of model resolutions are provided to cover different research needs (TL159, TL399 and TL639). The probabilistic skill of OpenIFS ensembles using these initial states is showcased. A case study of typhoon Damrey, which severely affected Vietnam in 2017, will also be presented.

How to cite: Ollinaho, P.: Ensemble prediction with OpenIFS, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18197, https://doi.org/10.5194/egusphere-egu2020-18197, 2020.

EGU2020-14316 | Displays | AS1.1

Evaluating the ability of a microwave radiometer and wrf to detect and simulate in-cloud icing conditions

Jose Luis Sanchez, Pablo Melcon, Guillermo Merida, Andres Merino, Eduardo Garcia-Ortega, Jose Luis Marcos, Laura Lopez, Laura Sanchez-Muñoz, Francisco Valero, Javier Fernandez, Pedro Bolgiani, Maria Luisa Martin, Sergio Fernandez-Gonzalez, and Andres Navarro

Icing occurs when an unheated solid structure is exposed to liquid cloud droplets at temperatures below the freezing point. Supercooled liquid water (SLW) in the atmosphere can persist in a physically metastable state until coming into contact with a solid object “In-cloud icing” occurs when super cooled liquid droplets (SLD) like clouds collide with a structure or object and freezes.

Atmospheric icing prediction has gain attention in the last years. Despite the progress made in meteorology, both weather forecasting modelling and atmospheric observations through advanced experimental technologies, there are still limitations in the accurate forecast and detection of icing conditions. The GFA‐ULE group has carried out some NWPs. In a previous work, we investigated the capability of the Weather Research and Forecasting model to detect regions containing supercooled cloud drops, proposing a multiphysics ensemble approach. Four microphysics and two planetary boundary layer schemes were used. Morrison and Goddard parameterizations with the YSU scheme, yielded superior results in evaluating the presence of liquid water content.

Concerning the remote detection of icing conditions, some European research centres (i.e. DLR, CIRA, ONERA, INCAS) as well as University of Leon (GFA-ULE) already have nowcasting or forecasting activities for detection of clouds and icing conditions. In this work a multichannel, microwave radiometer (MMWR) was used to detect the appearance of SLW. Consequently, we present both comparison between indirect detection of SLW and the output obtained by WRF with the two combination of parametrizations selected.

In our work we have taken into account:

The results show a good concordance between the number of events found by the MMWR and the result of the two numerical modeling performed. Therefore, everything seems to indicate that indirect detection by MMWR can be an accurate technology to detect the appearance of SLW and that the models can be qualitatively validated.

Acknowledgments: Data support came from the Atmospheric Physics Group, IMA, University of León, Spain, and the National Institute of  Aerospace Technology (INTA). This research was carried out in the framework of the SAFEFLIGHT project, financed by MINECO (CGL2016‐78702) and LE240P18 project (Junta de Castilla y León). We also thank R. Weigand for computer support.

How to cite: Sanchez, J. L., Melcon, P., Merida, G., Merino, A., Garcia-Ortega, E., Marcos, J. L., Lopez, L., Sanchez-Muñoz, L., Valero, F., Fernandez, J., Bolgiani, P., Martin, M. L., Fernandez-Gonzalez, S., and Navarro, A.: Evaluating the ability of a microwave radiometer and wrf to detect and simulate in-cloud icing conditions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14316, https://doi.org/10.5194/egusphere-egu2020-14316, 2020.

In this study, Korea Rapid Developing Thunderstorms (K-RDT) product from geostationary meteorological satellite which represents developing stage of convective cells is nudged to the Simplified Arakawa Schubert (SAS) deep convection scheme using a simple nudging technique in order to improve prediction skill of a heavy rainfall caused by mesoscale convective system over South Korea in the short-term forecast. Impact of the K-RDT information is investigated on the Global/Regional Integrated Model system (GRIMs) regional model program (RMP) system. For the selected heavy rainfall cases, the control run without nudging and two nudging experiments with different nudging period are performed. Although the simulated precipitations in the nudging experiments tend to depend on the distribution of convective cells detected in the K-RDT algorithm, the nudging experiment shows improved precipitation forecast than the control experiment. Particularly, the experiment with nudging for longer time produces better prediction skill. The results present that the small-scale convective cells from the K-RDT which are detected with a 1-km resolution have clear impacts to large-scale atmospheric fields. Therefore, it is suggested that utilizing small-scale information of convective system in the numerical weather prediction can have critical impact to improve forecast skill when the model system, which cannot properly represent sub-grid scale convections.

How to cite: Yeo, N., Chang, E.-C., and Min, K.-H.: Impact of the Korea Rapid Developing Thunderstorms (K-RDT) product nudging to the convective parameterization over the Korean Peninsula, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20986, https://doi.org/10.5194/egusphere-egu2020-20986, 2020.

EGU2020-4151 | Displays | AS1.1

WRF forecast sensitivity to spatial resolution

Efthimios Tagaris, Ioannis Stergiou, and Rafaella-Eleni Sotiropoulou

The Weather Research and Forecasting (WRF) model dynamically downscales NCEP FNL Operational Global Analysis data in order to assess the grid size resolution effect on the simulated variables. Simulations where conducted over Europe for the year 2015 using 36km, 12km and 4km grid size resolutions. The sensitivity analysis assesses the grid size resolution effect on the simulated mean, maximum and minimum daily temperatures as well as precipitation. The simulated data are evaluated using reanalysis dataset. The statistical variables used are the bias, mean absolute error, root mean square error and the index of agreement for each grid cell. Results show that model performance for mean and maximum temperature, is better when increasing the spatial resolution from 36Km to 12Km but no significant change is found when the spatial resolution is further increased to 4Km, in general. In addition, model performance for minimum temperatures and precipitation does not change significantly when moving to higher spatial resolution grids (i.e., 12Km and 4Km) compared to the 36Km domain,

Acknowledgments LIFE CLIMATREE project “A novel approach for accounting & monitoring carbon sequestration of tree crops and their potential as carbon sink areas” (LIFE14 CCM/GR/000635).

How to cite: Tagaris, E., Stergiou, I., and Sotiropoulou, R.-E.: WRF forecast sensitivity to spatial resolution, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4151, https://doi.org/10.5194/egusphere-egu2020-4151, 2020.

A new scale-adaptive three-dimensional (3D) turbulent kinetic energy (TKE) subgrid mixing scheme is developed using the Advanced Research version of the Weather Research and Forecasting Model (WRF-ARW) to address the gray-zone problem in the parameterization of subgrid turbulent mixing. This scheme is based on the full 3D TKE prognostic equation and combines the horizontal and vertical subgrid turbulent mixing into a single energetically consistent framework.

A series of real tropical cyclone(TC) simulations with varying horizontal resolutions from 9km to 1km are carried out to compare the performance of the 3D mixing scheme and the conventional 1D planetary boundary layer (PBL) schemes to the observations, including conventional ones such as radiosonde and surface synoptic observations, as well as intensive ones obtained during the landfall of TC, such as mobile boundary layer wind profiler and Dual-pol Doppler Radar. This study aims to determine if the new scheme performs appropriate on TC simulation, and to evaluate the sensitivity of TC simulation to boundary layer schemes.

How to cite: liu, M. and Zhang, X.: Application of a new scale-aware three-dimensional subgrid mixing parameterization on the simulations of tropical cyclone, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6581, https://doi.org/10.5194/egusphere-egu2020-6581, 2020.

  A crucial step of the application of WRF in regional climate research is selection of the proper combinations of physical parameterizations. In this study, we performed experiments in WRF to assess the predict skill of various parametrization schemes sets in simulating precipitation, temperature over the Haihe river basin. The experiments driven by ERA-INTERIM reanalysis data are performed for a period of summer (1 June to 31 August, 2016) in this domain with 13 km grid spacing. Fifty-eight members of physics combinations thoroughly covering five types of physics options are assessed against the available observational data by utilizing the multivariable integrated evaluation (MVIE) method. It is deduced that the best performing setup consists of CAM5.1 microphysics, MRF PBL, BMJ Cumulus, CAM Longwave/Shortwave radiation, and Noah Land Surface schemes. To identify the robustness of the optimal scheme set, the vector field evaluation (VFE) diagram for displaying all simulations reveals that the optimal one is distinguished from others by higher vector field similarity coefficient(Rν), smaller root mean square vector deviation(RMSVD). The model deviations spatially for the precipitation show a promising tendency that a strong overestimation about 5 mm/day for the default configuration evolves small biases of the optimal setup with a range between -1 and 1 mm/day, and the surface temperature forecasts have improved to some extent although not significant as that of precipitation. The temporally analysis of the spatial average of all simulations exhibits that for temperature the optimal setup is more approaching to the observational data, but for precipitation no remarkable difference between all simulation and the observations. Further analysis of the sensitivities of model output to different types of physics option suggests that, microphysics, PBL, and Cumulus schemes have more significant impact on the model performances measured by a multivariable integrated evaluation index (MIEI) than radiation scheme and Land Surface schemes.

How to cite: Dai, D.: Evaluation of the WRF Physics Ensemble using Multivariable Integrated Evaluation Approach over Haihe river basin in north China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8832, https://doi.org/10.5194/egusphere-egu2020-8832, 2020.

The weather forecast of good quality is essential for the humans living and operating in the Bulgarian Antarctic Base. The numerical weather prediction models in southern high latitude regions still need improvement as the user community is limited, little test cases are documented and validation data are scarce. Not lastly, the challenge of distributing the output results under poor internet conditions has to be addressed.

The Bulgarian Antarctic Base (BAB) is located on the Livingstone Island coast at 62⁰S and 60⁰W. The influence of the Southern ocean is significant, thus important to be correctly taken into account in the numerical forecast. The modeling system is based on the WRF model, configured in three nested domains down to 1 km horizontal resolution, centered in BAB. The main objective of the study is to quantify the Sea Surface Temperature (SST) impact and to recommend the frequency and way to perform measurements of the SST near the base. The focus is on prediction of right initial time and period of “bad” weather events like storms, frontal zones, and severe winds. Several test cases are considered with available measurements of temperature, pressure and wind speed in BAB during the summer season in 2017. The numerical 3 days forecast is performed and the model skill to capture the basic meteorological events in this period is discussed. Sensitivity experiments to SST values in the nearby marine area are concluded and the SST influence on the model forecast quality is analyzed.

How to cite: Chtirkova, B. and Peneva, E.: The impact of SST on the weather forecast quality in the Bulgarian Antarctic Base area on Livingstone Island, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9347, https://doi.org/10.5194/egusphere-egu2020-9347, 2020.

EGU2020-10163 | Displays | AS1.1

Convection is key to better polar low forecasts

Matilda Hallerstig, Linus Magnusson, and Erik Kolstad

ECMWF HRES and Arome Arctic are the operational Numerical Weather Prediction models that forecasters in northern Norway use to predict Polar lows in the Nordic and Barents Seas. These type of lows are small, but intense mesoscale cyclones with strong, gusty winds and heavy snow showers. They cause hazards like icing, turbulence, high waves and avalanches that threaten offshore activity and coastal societies in the area. Due to their small size and rapid development, medium range global models with coarser resolutions such as ECMWF have not been able to represent them properly. This was only possible with short range high resolution regional models like Arome. When ECMWF introduced their new HRES deterministic model with 9 km grid spacing, the potential for more precise polar low forecasts increased. Here we use case studies and sensitivity tests to examine the ability of ECMWF HRES to represent polar lows. We also evaluate what added value the Arome Arctic model with 2.5 km grid spacing gives. For verification, we use coastal meteorological stations and scatterometer winds. We found that convection has a greater impact on model performance than horizontal resolution. We also see that Arome Arctic produces higher wind speeds than ECMWF HRES. To improve performance during polar lows for models with a horizontal grid spacing less than 10 km, it is therefore more important to improve the understanding and formulation of convective processes rather than simply increasing horizontal resolution.

How to cite: Hallerstig, M., Magnusson, L., and Kolstad, E.: Convection is key to better polar low forecasts, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10163, https://doi.org/10.5194/egusphere-egu2020-10163, 2020.

EGU2020-10586 | Displays | AS1.1

Sensitivity analysis to physical parameterizations schemes applied for wind forecasting

Andrés Merino, Guillermo Mérida, Pablo Melcón, Laura López, José Luis Marcos, Carmen Victoria Romo, Neves Seoane, Andrés Navarro, Eduardo García-Ortega, and José Luis Sánchez Gómez

The airborne research center called CIAR is placed in the airfield of Rozas (Lugo, Spain). It is a center for experimentation and development of new Unmanned Aerial Vehicles. Since you need to have a good planning of the flights of the prototypes, it is necessary to have a good prediction of the wind at different levels of height.

To obtain a reliable database for wind at different vertical levels, three types of instruments have been used: anemometers installed at 10 meters high to determine surface wind, a sodar for levels below 150 meters and a wind radar for those between 200 and 3000 m high above the CIAR level.

Concerning the mesoscale modelling: we have used the WRF with 48 sigma levels and horizontal resolution of up to 3 x 3 km. Therefore, we have applied multiphysics ensemble techniques. Five combinations of microphysics schemes (AEROSOL THOMPSON, MORRISON 2 MOMENTS, THOMPSON, GODDARD and WRF 2 MOMENTS), three of PBL (MYNN3, YSU and MYJ), and two of Surface (NOAA and RUC) have been selected.

Once the wind data databases were obtained, by means of the different instrumentation indicated above, it has been compared with each of the 20 WRF scenarios. To visualize the results, Taylor diagrams have been used for the different heights.

In summary, some conclusions have been found:

  1. It’s necessary distinguish between low levels and those of slightly higher heights. On the surface, the scenarios with the PBL parameterizations called YSU and MYNN3 show better results.
  2. It seems that the microphysics schemes settings have a less importance in wind forecast, which is consistent with the physical interpretation.
  3. Above 200 meter, the 20 scenarios behave more satisfactorily with excellent correlation coefficients and low standard deviations

Acknowledgment

Data support came from the Atmospheric Physics Group, IMA, University of León, Spain, and the National Institute of Aerospace Technology (INTA). This research was carried out in the framework of the SAFEFLIGHT project, financed by MINECO (CGL2016‐78702) and LE240P18 project (Junta de Castilla y León). We also thank R. Weigand for computer support to the research group.

How to cite: Merino, A., Mérida, G., Melcón, P., López, L., Marcos, J. L., Romo, C. V., Seoane, N., Navarro, A., García-Ortega, E., and Sánchez Gómez, J. L.: Sensitivity analysis to physical parameterizations schemes applied for wind forecasting, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10586, https://doi.org/10.5194/egusphere-egu2020-10586, 2020.

EGU2020-12249 | Displays | AS1.1

Effects of Trees on Pedestrian Wind Comfort in an Urban Area Using a CFD model

Geon Kang and Jae-Jin Kim

This study investigated the effects of trees on the pedestrian wind comfort in the Pukyong National University (PKNU) campus. For this, we implemented the tree’s drag parameterization scheme to a computational fluid dynamics (CFD) model and validated the simulated results against a field measurement. The CFD model well reproduced the measured wind speeds and TKEs in the downwind region of the trees, indicating successful implementation of the tree drag parameterization schemes. Besides, we compared the wind speeds, wind directions, and temperatures simulated by the CFD model coupled to the local data assimilation and prediction system (LDAPS), one of the numerical weather prediction models operated by the Korean Meteorological Administration (KMA) to those observed at the automated weather station (AWS). We performed the simulations for one week (00 UTC 2 – 23 UTC 9 August 2015). The LDAPS overestimated the observed wind speeds (RMSE = 1.81 m s–1), and the CFD model markedly improved the wind speed RMSE (1.16 m s–1). We applied the CFD model to the simulations of the trees' effects on pedestrian wind comfort in the PKNU campus in views of wind comfort criteria based on the Beaufort wind force scale (BWS). We will present the trees' effects on pedestrian wind comfort in the PKNU campus in detail.

How to cite: Kang, G. and Kim, J.-J.: Effects of Trees on Pedestrian Wind Comfort in an Urban Area Using a CFD model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12249, https://doi.org/10.5194/egusphere-egu2020-12249, 2020.

EGU2020-19593 | Displays | AS1.1

Impact of improved Ocean initial condition in Climate Forecast System (CFSv2) Hindcast run

Samir Pokhrel, Hasibur Rahaman, Hemantkumar Chaudhari, Subodh Kumar Saha, and Anupam Hazra

IITM provides seasonal monsoon rainfall forecast using modified CGCM CFSv2. The present operational CFSv2 initilized with the INCOIS-GODAS ocean analysis based on MOM4p0d and 3DVar assimilation schemes. Recently new Ocean analysis GODAS-Mom4p1 using Moduler Ocean Model (MOM) upgraded physical model MOM4p1 is generated. This analysis has shown improvement in terms of subsurface temperature, salinity , current as well as sea surface temperature (SST), sea surface salinity (SSS) and surface currents over the Indian Ocean domain with respect to present operational INCOIS-GODAS analysis (Rahaman et al. 2017;Rahman et al. 2019). This newly generated ocean analysis is used to initialize NCEP Climate Forecast System (CFSv2) for the retrospective run from 2011 to 2018. The simulated coupled run has shown improvement in both oceanic as well atmospheric parameters. The more realistic nature of coupled simulations across the atmosphere and ocean may be promising to get better forecast skill.

How to cite: Pokhrel, S., Rahaman, H., Chaudhari, H., Saha, S. K., and Hazra, A.: Impact of improved Ocean initial condition in Climate Forecast System (CFSv2) Hindcast run, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19593, https://doi.org/10.5194/egusphere-egu2020-19593, 2020.

EGU2020-22093 | Displays | AS1.1

Engaging the Community in the Development of Physics for NWP Models

Ligia Bernardet, Grant Firl, Dom Heinzeller, Laurie Carson, Xia Sun, Linlin Pan, and Man Zhang

Contributions from the community (national laboratories, universities, and private companies) have the potential to improve operational numerical models and translate to better forecasts. However, researchers often have difficulty learning about the most pressing forecast biases that need to be addressed, running operational models, and funneling their developments onto the research-to-operations process. Common impediments are lack of access to current and portable model code, insufficient documentation and support, difficulty in finding information about forecast shortcomings and systematic errors, and unclear processes to contribute code back to operational centers. 

The U.S. Developmental Testbed Center (DTC) has the mission of connecting the research and operational Numerical Weather Prediction (NWP) communities. Specifically in the field of model physics, the DTC works on several fronts to foster the engagement of community developers with the Unified Forecast System (UFS) employed by the U.S. National Oceanic and Atmospheric Administration (NOAA).  As a foundational step, the UFS’ operational and developmental physical parameterizations and suites are now publicly distributed through the Common Community Physics Package (CCPP), a library of physics schemes and associated framework that enables their use with various models. The CCPP can be used for physics experimentation and development in a hierarchical fashion, with hosts ranging in complexity from a single-column model driven by experimental case studies to fully coupled Earth system models. This hierarchical capability facilitates the isolation of non-linear processes prior to their integration in complex systems. 

The first public release of a NOAA Unified Forecast System (UFS) application is expected for February 2020, with a focus on the Medium-Range Weather Application. This global configuration uses the CCPP and will be documented and supported to the community. To accompany future public releases, the DTC is creating a catalog of case studies to exemplify the most prominent model biases identified by the US National Weather Service. The case studies will be made available to the community, who will be able to rerun the cases, to test their innovations and document model improvements. 

In this poster we will summarize how we are using the UFS public release, the single-column model, the CCPP, and the incipient catalog of code studies to create stronger connections among the groups that diagnose, develop, and produce predictions using physics suites.

How to cite: Bernardet, L., Firl, G., Heinzeller, D., Carson, L., Sun, X., Pan, L., and Zhang, M.: Engaging the Community in the Development of Physics for NWP Models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22093, https://doi.org/10.5194/egusphere-egu2020-22093, 2020.

EGU2020-21924 | Displays | AS1.1

Improvements to melting snow behavior in an NWP bulk microphysics scheme

Emilie C. Iversen, Gregory Thompson, and Bjørn Egil Nygaard

Snow falling into a melting layer will eventually consist of a fraction of meltwater and hence change its characteristics in terms of size, shape, density, fall speed and stickiness. Given that these characteristics contribute to determine the phase and amount of precipitation reaching the ground, precisely predicting such are important in order to obtain accurate weather forecasts for which society depends on. For example, in hydrological modelling precipitation phase at the surface is a first-order driver of hydrological processes in a water shed. Also, melting snow exerts a possible threat to critical infrastructure because the wet, sticky snow may adhere to the structures and form heavy ice sleeves.

Most widely used bulk microphysical parameterization schemes part of numerical weather prediction models represent only purely solid or liquid hydrometeors, and so melting particle characteristics are either ignored or represented by parent species with simple conditions for behavior in the melting layer. The Thompson microphysics scheme is explicitly developed for forecasting winter conditions in real-time as part of the WRF model, and to maintain computational performance, the introduction of additional prognostic variables is undesirable. This research aims at improving the Thompson scheme with respect to melting snow characteristics using a physically based approximation for the snowflake melted fraction, as well as a new definition of melting level and melting particle fall velocity. A real 3D WRF case is set up to compare with in-situ measurements of hydrometeor size and fall velocity from a disdrometer and a vertically pointing Doppler radar deployed during the Olympic Mountain Experiment (OLYMPEX). The modified microphysics scheme is able to replicate the bimodal distribution of fall speed – diameter relations typical of mixed precipitation seen in disdrometer data, as well as the non-linear increase in snow fall speed with melted fraction through the melting layer.

How to cite: Iversen, E. C., Thompson, G., and Nygaard, B. E.: Improvements to melting snow behavior in an NWP bulk microphysics scheme, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21924, https://doi.org/10.5194/egusphere-egu2020-21924, 2020.

EGU2020-6352 | Displays | AS1.1

The impact of vertical resolution on tropical cyclone simulation

Wei Huang, Mengjuan Liu, Xu Zhang, and Jian-wen Bao

It is well known that horizontal resolution has a great deal of impact on tropical cyclone simulations using numerical weather prediction models.  It is relatively less discussed in the literature how vertical resolution affects the solution convergence of tropical cyclone simulations.  In this study, the resolved kinetic energy spectrum, the Richardson number probability density function and resolved flow features are used as metrics to examine the behavior of solution convergence in tropical cyclone simulations using the Weather and Forecast Model (WRF).  It is found that for convective-scale simulations of a real tropical cyclone case with 3-km horizontal resolution, the model solution does not converge until a vertically stretched vertical resolution approaches 200 layers or more.  The results from this study confirm the results from a few previous studies that the subgrid turbulent mixing, particularly, the vertical mixing, plays a significant role in the behavior of model solution convergence with respect to vertical resolution.  They also provide a basis for the vertical grid configuration selection for the operational tropical cyclone model of Shanghai Meteorological Service.

How to cite: Huang, W., Liu, M., Zhang, X., and Bao, J.: The impact of vertical resolution on tropical cyclone simulation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6352, https://doi.org/10.5194/egusphere-egu2020-6352, 2020.

EGU2020-5337 | Displays | AS1.1

Evaluation of scale-aware convection schemes at the kilometer-scale resolution

Xu Zhang, Jian-Wen Bao, and Baode Chen

Numerical weather predictions (NWP) models are increasingly run using kilometer-scale horizontal grid spacing at which convection is partially resolved and the use of a subgrid convection parameterization scheme is still required. Traditionally, subgrid deep convection has been represented by mass flux-based convection parameterizations based on the ensemble-mean closure concept. Recently, a great effort has been made to develop scale-aware subgrid convection schemes that can be used in kilometer-scale NWP models. However, direct evaluation of these schemes is rarely done using coarse-grained large-eddy simulation (LES).

In this study, an idealized LES of deep moist convection is performed to assess the performance of three widely-used scale-aware subgrid convection schemes in the Weather Research and Forecast (WRF) model that is run at 3-km horizontal resolution. It is found that the simulations using the three schemes not only differ from each other but also do not converge to the coarse-grained LES, indicating that further investigation is required as to what “scale-awareness” means in theory and practice.

How to cite: Zhang, X., Bao, J.-W., and Chen, B.: Evaluation of scale-aware convection schemes at the kilometer-scale resolution, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5337, https://doi.org/10.5194/egusphere-egu2020-5337, 2020.

EGU2020-10827 | Displays | AS1.1

The use of multidimensional Langevin processes for stochastic uncertainty quantification in the NOAA Unified Forecast System (UFS)

Jian-Wen Bao, Sara Michelson, Lisa Bengtsson, Philip Pegion, Jeffrey Whitaker, and Cécile Penland

Modern numerical weather prediction (NWP) model forecasts for various applications require not only high-quality deterministic forecasts, but also information about forecast uncertainty.  An ensemble forecast is commonly used to provide an estimation of forecast uncertainty.  Since a great deal of the forecast uncertainty comes from dynamical processes not resolved or explicitly represented by NWP models, there is a need to correctly quantify and simulate NWP model uncertainty for an ensemble forecast to be useful and reliable.

We present an overview of a theoretical framework for simulating the uncertainty in unresolved physics in the NOAA Unified Forecast System (UFS).  This framework is derived from the connection in mathematical physics between the Mori-Zwanzig formalism and multidimensional Langevin processes.  It follows the correspondence principle, a philosophical guideline for new theory development, such that it can be shown that the previously implemented stochastic uncertainty quantification schemes in the UFS are particular cases of this framework.  We will show an example of how we have used this framework to develop a new process-level stochastic uncertainty quantification scheme in the UFS.  We will also present a preliminary performance comparison of these previously-implemented schemes with the newly-developed process-level scheme in the UFS ensemble predictions on short, medium and sub-seasonal time scales.

How to cite: Bao, J.-W., Michelson, S., Bengtsson, L., Pegion, P., Whitaker, J., and Penland, C.: The use of multidimensional Langevin processes for stochastic uncertainty quantification in the NOAA Unified Forecast System (UFS), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10827, https://doi.org/10.5194/egusphere-egu2020-10827, 2020.

EGU2020-10896 | Displays | AS1.1

The Impact of Predator-Prey Processes in Bulk Microphysics Schemes on Simulated Aerosol-Cloud Interaction

Evelyn Grell, Jian-Wen Bao, and Sara Michelson

In bulk microphysics schemes, the behavior of the multiple processes that compete for cloud water and ice can be likened to the predator-prey relationship seen in the natural world. These processes provide compensatory feedback between production processes of precipitating hydrometeors.

In this presentation, we demonstrate the sensitivity of the predator-prey processes in two commonly-used microphysics schemes of the Weather Research and Forecasting Model (WRF) to perturbations in aerosol loading, using the simulations of an idealized 2-D squall line and idealized shallow convection in the marine boundary layer. Diagnoses of the parameterized pathways for hydrometeor production microphysics budget analysis reveal that the compensatory feedback associated with the predator-prey processes are quite similar between the schemes. Overall, the compensatory feedback makes the response of a scheme to perturbations in aerosol loading smaller than the differences between the two schemes with the same aerosol loading. This indicates that there remains great uncertainty in modeling the aerosol-cloud interaction in weather and climate models. Alleviating this uncertainty requires better microphysics parameterizations as well as better observations of cloud microphysical properties.

How to cite: Grell, E., Bao, J.-W., and Michelson, S.: The Impact of Predator-Prey Processes in Bulk Microphysics Schemes on Simulated Aerosol-Cloud Interaction, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10896, https://doi.org/10.5194/egusphere-egu2020-10896, 2020.

A new parameterization of the accretion of cloud water by snow for use in bulk microphysics schemes is derived by analytically solving the stochastic collection equation (SCE), where the theoretical collision efficiency for individual snowflake–cloud droplet pairs is applied. The snowflake shape is assumed to be nonspherical with the mass- and area-size relations suggested by an observational study. The performance of the new parameterization is compared to two parameterizations based on the continuous collection equation, one with the spherical shape assumption for snowflakes (SPH-CON), and the other with the nonspherical shape assumption employed in the new parameterization (NSP-CON). In box model simulations, only the new parameterization reproduces a relatively slow decrease in the cloud droplet number concentration which is predicted by the direct SCE solver. This results from considering the preferential collection of cloud droplets depending on their sizes in the new parameterization based on the SCE. In idealized squall-line simulations using a cloud-resolving model, the new parameterization predicts heavier precipitation in the convective core region compared to SPH-CON, and a broader area of the trailing stratiform rain compared to NSP-CON due to the horizontal advection of greater amount of snow in the upper layer. In the real-case simulations of a line-shaped mesoscale convective system that passed over the central Korean Peninsula, the new parameterization predicts higher frequencies of light precipitation rates and lower frequencies of heavy precipitation rates. The relatively large amount of upper-level snow in the new parameterization contributes to a broadening of the area with significant snow water path.

How to cite: Jin, H.-G. and Baik, J.-J.: A new parameterization of the accretion of cloud water by snow and its evaluation through simulations of mesoscale convective systems, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1994, https://doi.org/10.5194/egusphere-egu2020-1994, 2020.

Considering aerosol effects via microphysics parameterization is an imperative work in high-resolution numerical weather prediction. This paper uses two bulk microphysics parameterizations, Aerosol-Aware Thompson and CLR schemes, with the Weather and Research Forecast model to study the impacts of aerosols and microphysics scheme on an idealized supercell storm. Our results show that the implementation of aerosols can successfully modify the cloud droplet size and influence the subsequent warm-rain, mixed-phase, and accumulated precipitation. It implies that aerosols can make numerous differences to cloud microphysics properties and processes but the uncertainty in the magnitude of aerosol effects is huge because the two schemes are different from each other since the warm-rain process including CCN activation and rainwater formation. On the other hand, it is also found that the two schemes make tremendous differences in the rainfall pattern and storm dynamics due to the presence of graupel below the freezing level. The Thompson scheme has hail-like graupel which can fall below the freezing level to chill the air temperature effectively, intensify the downdraft, and enhance the uplifting on the front of cold pools. The mean graupel size represented by the two schemes plays a much more important role than the fall-speed formula for the dynamical feedbacks. Our results suggest that particle size is the core of a myriad of microphysics processes and highly associated with key cloud and dynamical signatures.

How to cite: Wu, W., Huang, W., and Chen, B.: A comparison study of aerosol impacts on idealized supercell between two bulk microphysics parameterizations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6235, https://doi.org/10.5194/egusphere-egu2020-6235, 2020.

EGU2020-6653 | Displays | AS1.1

Development of Customized Variable-Resolution CPAS for Meteorological Simulation

Louis Kwan Shu Tse, Ka Ki Ng, Yuk Sing Lui, Chi Chiu Cheung, Wai Nang Leung, and Yun Fat Lam

    The model performance and run-time are two major concerns in numerical weather prediction. Both are substantially dependent on the grid specification, in particular, the number of grids, resolution and coverage of the refinement regions. In the Model for Prediction Across Scales - Atmosphere (MPAS-A), unstructured Voronoi mesh is used and the infrastructure, particularly the dynamic core, is implemented to support this flexible topology. However, only several standard meshes are available for download while customization is not supported. Moreover, the use of a globally-constant time-step (determined by the smallest grid) poses challenges on high resolution forecast using meshes with large resolution variation due to impractically long-running time. A Customizable Unstructured Mesh Generation (CUMG) and Hierarchical Time-Stepping (HTS) was developed in the ClusterTech Platform for Atmospheric Simulation (CPAS), offering a potential path for high-resolution local/regional forecast in MPAS-A’s framework. The CUMG algorithm enables local mesh refinement in arbitrary shape using user-defined horizontal resolution at any desired locations. Meshes with large resolution variation, for example, ranging from 128 km to 1 km can be generated. The resulting meshes are 100% well-staggered, and zero obtuse Delaunay triangle is guaranteed. The CPAS provides a web-based graphical user interface and no coding is needed for specifying the refinements. In real simulations, grids are integrated in time with heterogenous time-step according to their cell spacings using HTS. It reduces the model run-time tremendously, particularly for meshes with large resolution variation. 

    In this study, a comparison on the mesh quality, efficiency and performance of a CPAS customized 128-to-1 km mesh to the MPAS-A standard 60-to-3 km mesh with and without HTS was performed. Three historical weather conditions over southern China in 2018 were selected to evaluate their performance: (i) passage of a cold front (ii) heavy rainfall and (iii) passage of a tropical cyclone. In general, the CPAS 128-to-1 km mesh was found to have better quality over the MPAS-A 60-to-3 km mesh, namely cell quality, angle-based triangle quality, and triangle quality. Moreover, using HTS, the benchmarked saving of the total run-time for the CPAS 128-to-1 km mesh and MPAS-A 60-to-3 km mesh are 56.8% (2.33x speedup) and 16.5% (1.20x speedup), respectively. Furthermore, the model results were validated through comparison with the National Centers for Environmental Prediction (NCEP) Final (FNL) Operational Global Analysis. The 5-day simulation results of various forecast variables within the area of interest (a lat-long box covering 3 km refinement region of the MPAS-A 60-to-3 km mesh) with and without HTS for both meshes show comparable performance in all cases. The promising model performance along with remarkable speedup indicates the validity and feasibility of high resolution local/regional forecast using customized global variable-resolution meshes in an operational manner. 

How to cite: Tse, L. K. S., Ng, K. K., Lui, Y. S., Cheung, C. C., Leung, W. N., and Lam, Y. F.: Development of Customized Variable-Resolution CPAS for Meteorological Simulation , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6653, https://doi.org/10.5194/egusphere-egu2020-6653, 2020.

The next generation of weather and climate models will have an unprecedented level of resolution and model complexity, while also increasing the requirements for calculation and memory speed. Reducing the accuracy of certain variables and using mixed precision methods in atmospheric models can greatly improve Computing and memory speed. However, in order to ensure the accuracy of the results, most models have over-designed numerical accuracy, which results in that occupied resources have being much larger than the required resources. Previous studies have shown that the necessary precision for an accurate weather model has clear scale dependence, with large spatial scales requiring higher precision than small scales. Even at large scales the necessary precision is far below that of double precision. However, it is difficult to find a guided method to assign different precisions to different variables, so that it can save unnecessary waste. This paper will take CESM1.2.1 as a research object to conduct a large number of tests to reduce accuracy, and propose a new discrimination method similar to the CFL criterion. This method can realize the correlation verification of a single variable, thereby determining which variables can use a lower level of precision without degrading the accuracy of the results.

How to cite: Lai, J.: A Guiding Principles for Choosing Numerical Precision in Atmospheric Model based on CESM, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13445, https://doi.org/10.5194/egusphere-egu2020-13445, 2020.

In order to provide multiple choices of dynamic cores for the next generation global numerical prediction system at Chinese Meteorological Administration (CMA), a Z-grid based dynamic core is under development. Among other important features of a Z-grid scheme, better dispersion relation, natural geostrophic adjustment and conservation attract numerical modeler’s interests. In this presentation, we will share the progress of such a development at CMA along with other dynamic cores, improving its accuracy on a sphere, efficient solvers and software design and implementation. We also developed some standard unit test cases for software reliability, which are also available and convenient for other dynamic cores. Some numerical experiment results will be presented as well.

How to cite: Xie, Y.: A Z-grid Based Dynamic Core for Global Numerical Prediction Model of Chinese Meteorological Agency, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21150, https://doi.org/10.5194/egusphere-egu2020-21150, 2020.

EGU2020-4005 | Displays | AS1.1

MPDATA method for non–uniform mesh

Xinpeng Yuan

 

MPDATA method for non–uniform mesh

 

Xinpeng Yuan

State Key Laboratory of Severe Weather, Chinese Academy of Meteorological Sciences,China 

Meteorological Administration, Beijing 100081, China 

 

Keyword: Atmospheric dynamics, MPDATA, non–uniform mesh, precision

Abstract: MPDATA[1,2](multidimensional positive definite advection transport algorithm) is proposed by Piotr K. Smolarkiewicz in 1983. This method is used to efficiently solve the advection transport problem of non-negative thermodynamic variables (such as liquid water or water vapor) in the atmospheric dynamics model. This method has been proved to be an effective numerical solution to the advection transport problem for uniform meshes. However, since there is no uniform mesh division on the sphere, the traditional MPDATA method is faced with the incompatibility problem for the non-uniform and quasi-uniform meshing of the sphere, resulting in the numerical algorithm failing to reach the designed second-order accuracy. Firstly, this paper analyzes the insufficiency of traditional MPDATA methods for non-uniform grids. That is, the incompatibility of the first-order numerical scheme and the approximation of boundary derivative.Then the MPDATA method suitable for non-uniform grid is proposed. According to the characteristics of non-uniform grid and the characteristics of well-balance[3] central grid point algorithm, the MPDATA method suitable for 1-d and 2-d complex grid structure is designed. The consistency and positivity of the algorithm are proved by mathematical analysis. Finally, the theoretical proof is verified by numerical simulation.

 

Reference

[1] Smolarkiewicz P. A Simple Positive Definite Advection Scheme with Small Implicit Diffusion[J]. Monthly Weather Review. 1983.

[2] Smolarkiewicz P K, Szmelter J. MPDATA: An edge-based unstructured-grid formulation[J]. Journal of Computational Physics. 2005, 206(2): 624-649.

[3] Kurganov A, Levy D. Central-Upwind Schemes for the Saint-Venant System[J]. ESAIM: Mathematical Modelling and Numerical Analysis. 2002, 36(3): 397-425.

 

How to cite: Yuan, X.: MPDATA method for non–uniform mesh, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4005, https://doi.org/10.5194/egusphere-egu2020-4005, 2020.

AS1.2 – Progress in weather and climate modelling: improved data assimilation, better models, and higher resolution simulations

EGU2020-17854 | Displays | AS1.2

Barotropic Instability of a Cyclone Core at Kilometer‐Scale Resolution

David Leutwyler and Christoph Schär

Secondary disturbances spawning frontal waves along the fronts of mature midlatitude low-pressure systems were identified decades ago from satellite images. While their development has been studied using analytical models, field campaigns (e.g. FASTEX) and re-analysis datasets, simulation of the phenomenon in state-of-the-art global weather and climate models so far remained unattainable.

Today's flagship supercomputers allow performing simulations at kilometer-scale resolution on computational domains covering the entire lifecycle of synoptic-scale systems and thus enable explicit representation of small-scale disturbances embedded in large-scale circulations. We demonstrate these capabilities in two different types of kilometer-scale simulations. The first is a 10-day-long near-global simulation of an idealized moist baroclinic wave, performed at 1 km grid spacing and employing 16,001 × 36,006 × 60 grid points. The second is a real-case simulation of an extratropical low-pressure system, driven by the European Centre for Medium-Range Weather Forecasts's operational analysis. At kilometer-scale resolution, both simulations display clear evidence of embedded mesoscale vortices spawning along frontal systems of mature extratropical cyclones. The vortices appearing in the real-case simulation can also be identified in satellite imagery of the system.

The simulated developments are due to a barotropic instability mechanism and driven by strong low-level horizontal wind shear. While the simulation of the frontal systems is amenable at model resolutions around 10–50 km, the instability mechanism itself relies on the representation of a narrow shear zone, requiring about 5 times finer resolution. Results suggest that the flow regimes suppressing or fostering barotropic vortices can coexist in the same synoptic system. Far away from the cyclone core, the instability is suppressed by deformation associated with the large-scale flow, while close to the mature cyclone core, the narrow frontal structure becomes unstable.

Leutwyler, D. and C. Schär (2019): Barotropic instability of a cyclone core at kilometer-scale resolution, J. Adv. Model. Earth Sy., 11.

How to cite: Leutwyler, D. and Schär, C.: Barotropic Instability of a Cyclone Core at Kilometer‐Scale Resolution, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17854, https://doi.org/10.5194/egusphere-egu2020-17854, 2020.

EGU2020-21769 | Displays | AS1.2

Evaluation of trends in extreme temperatures simulated by HighResMIP models across Europe

Gerard van der Schrier, Antonello Squintu, Else van den Besselaar, Eveline van der Linden, Enrico Scoccimarro, Christopher Roberts, Retish Senan, Dian Putrasahan, Malcolm Roberts, and Albert Klein Tank

The comparison of simulated climate with observed daily values allows to assess their reliability and the soundness of their projections on the climate of the future. Frequency and amplitude of extreme events are fundamental aspects that climate simulations need to reproduce. In this work six models developed within the High Resolution Model Intercomparison Project are compared over Europe with the homogenized version of the observational E-OBS gridded dataset. This is done by comparing averages, extremes and trends of the simulated summer maximum temperature and winter minimum temperatures with the observed ones.

Extreme values have been analyzed making use of indices based on the exceedances of percentile-based thresholds. Winter minimum temperatures are generally underestimated by models in their averages (down to -4 deg. C of difference over Italy and Norway) while simulated trends in averages and extreme values are found to be too warm on western Europe and too cold on eastern Europe (e.g. up to a difference of -4% per decade on the number of Cold Nights over Spain). On the other hand the models tend to underestimate summer maximum temperatures averages in Northern Europe and overestimate them in the Mediterranean areas (up to +5 deg. C over the Balkans). The simulated trends are too warm on the North West part and too cold on the South East part of Europe (down to -3%/dec. on the number of Warm Days over Italy and Western Balkans).

These results corroborate the findings of previous studies about the underestimation of the warming trends of summer temperatures in Southern Europe, where these are more intense and have more impacts.  A comparison of the high resolution models  with the corresponding version in CMIP5 has been performed comparing the absolute biases of extreme values trends. This has shown a slight improvement for the simulation of winter minimum temperatures, while no signs of significant progresses have been found for summer maximum temperatures.

How to cite: van der Schrier, G., Squintu, A., van den Besselaar, E., van der Linden, E., Scoccimarro, E., Roberts, C., Senan, R., Putrasahan, D., Roberts, M., and Klein Tank, A.: Evaluation of trends in extreme temperatures simulated by HighResMIP models across Europe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21769, https://doi.org/10.5194/egusphere-egu2020-21769, 2020.

EGU2020-1545 | Displays | AS1.2

Higher Vertical Resolution for Select Physical Processes in the Energy Exascale Earth System Model (E3SM)

Hsiang-He Lee, Peter Bogenschutz, and Takanobu Yamaguchi

EGU2020-10306 | Displays | AS1.2 | Highlight

Global climate simulations at 2.8 km on GPU with the ICON model

Xavier Lapillonne, William Sawyer, Philippe Marti, Valentin Clement, Remo Dietlicher, Luis Kornblueh, Sebastian Rast, Reiner Schnur, Monika Esch, Marco Giorgetta, Dmitry Alexeev, and Robert Pincus

The ICON modelling framework is a unified numerical weather and climate model used for applications ranging from operational numerical weather prediction to low and high resolution climate projection. In view of further pushing the frontier of possible applications and to make use of the latest evolution in hardware technologies, parts of the model were recently adapted to run on heterogeneous GPU system. This initial GPU port focus on components required for high-resolution climate application, and allow considering multi-years simulations at 2.8 km on the Piz Daint heterogeneous supercomputer. These simulations are planned as part of the QUIBICC project “The Quasi-Biennial Oscillation (QBO) in a changing climate”, which propose to investigate effects of climate change on the dynamics of the QBO.

Because of the low compute intensity of atmospheric model the cost of data transfer between CPU and GPU at every step of the time integration would be prohibitive if only some components would be ported to the accelerator. We therefore present a full port strategy where all components required for the simulations are running on the GPU. For the dynamics, most of the physical parameterizations and infrastructure code the OpenACC compiler directives are used. For the soil parameterization, a Fortran based domain specific language (DSL) the CLAW-DSL has been considered. We discuss the challenges associated to port a large community code, about 1 million lines of code, as well as to run simulations on large-scale system at 2.8 km horizontal resolution in terms of run time and I/O constraints. We show performance comparison of the full model on CPU and GPU, achieving a speed up factor of approximately 5x, as well as scaling results on up to 2000 GPU nodes. Finally we discuss challenges and planned development regarding performance portability and high level DSL which will be used with the ICON model in the near future.

How to cite: Lapillonne, X., Sawyer, W., Marti, P., Clement, V., Dietlicher, R., Kornblueh, L., Rast, S., Schnur, R., Esch, M., Giorgetta, M., Alexeev, D., and Pincus, R.: Global climate simulations at 2.8 km on GPU with the ICON model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10306, https://doi.org/10.5194/egusphere-egu2020-10306, 2020.

EGU2020-11447 | Displays | AS1.2

Does ocean resolution affect the rate of AMOC weakening?

Helene Hewitt, Laura Jackson, Malcolm Roberts, Dorotea Iovino, Torben Koenigk, Virna Meccia, Christopher Roberts, Yohan Ruprich-Robert, and Richard Wood

We examine the weakening of the Atlantic Meridional Overturning Circulation (AMOC) in response to increasing CO2 at different horizontal resolutions in HadGEM3-GC3.1 and in a small ensemble of models with differing resolutions. There is a strong influence of the ocean mean state on the AMOC weakening: models with a more saline western subpolar gyre have a greater formation of deep water there. This makes the AMOC more susceptible to weakening from an increase in CO2 since weakening ocean heat transports weaken the contrast between ocean and atmospheric temperatures and hence weaken the buoyancy loss. In models with a greater proportion of deep water formation further north (in the Greenland-Iceland-Norwegian basin), deep-water formation can be maintained by shifting further north to where there is a greater ocean-atmosphere temperature contrast.

We show that ocean horizontal resolution can have an impact on the mean state, and hence AMOC weakening. In the models examined, those with higher resolutions tend to have a more westerly path of the North Atlantic Current and hence greater impact of the warm, saline subtropical Atlantic waters on the western subpolar gyre. This results in greater dense water formation in the western subpolar gyre. Although there is some improvement of the higher resolution models over the lower resolution models in terms of the mean state, both still have biases and it is not clear which biases are the most important for influencing the AMOC strength and response to increasing CO2.

 

How to cite: Hewitt, H., Jackson, L., Roberts, M., Iovino, D., Koenigk, T., Meccia, V., Roberts, C., Ruprich-Robert, Y., and Wood, R.: Does ocean resolution affect the rate of AMOC weakening?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11447, https://doi.org/10.5194/egusphere-egu2020-11447, 2020.

Previous work showed that simulations of extratropical cyclones and their intensity are significantly impacted by model resolution. This might be explained by the impact of resolution on cloud diabatic processes occurring within the warm conveyor belt (WCB), as these are linked to the strength of cyclones. To investigate this link, we move gradually from very coarse (80km) to very fine resolution (2.5km) simulations and study if there is a systematic impact of resolution on the simulated WCB processes. For this purpose, we analyse ICON simulations in a regional North Atlatnic setup for a specific case from the NAWDEX campaign -  cyclone Vladiana - that occurred on 23rd September, 2016. Furthermore, we compare simulations with 1- and 2- moment cloud microphysics and with explicit and parametrized convection. From these simulations WCB trajectories are calculated over 48 hours by means of the Lagranto tool and 1-hourly model output to sample cloud diabatic processes within the WCB. We find a systematic increase in the number of WCB trajectories with finer resolution, which also ascent higher. Moreover, the fine-resolution simulations show a new class of anticyclonic trajectories that is absent in the low-resolution simulations. This effect becomes more pronounced when convection is represented explicitly, but is not strongly affected by the treatment of cloud microphysics. We diagnose the impact of increasing resolution on WCB in terms of changes in processes like updraft velocity, diabatic heating and modification of potential vorticity by total diabatic heating and individual diabatic processes.

How to cite: Choudhary, A. and Voigt, A.: Sensitivity of simulated warm conveyor belt associated with an extratropical cyclone to model resolution and treatment of cloud processes - a NAWDEX case study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21165, https://doi.org/10.5194/egusphere-egu2020-21165, 2020.

EGU2020-1725 | Displays | AS1.2

Ultra-high resolution global warming simulations conducted with CESM

Axel Timmermann, Sun-Seon Lee, and Jung-Eun Chu
To further improve our understanding of scale-interactions and key mechanisms leading to climate variability and extreme weather events, we conducted a series climate simulations using the ultrahigh-resolution Community Earth System Model (HR-CESM). The HR-CESM configuration uses a horizontal resolution of approximately 25 km for the atmospheric component and 10 km for the ocean. The simulations were carried out under present-day radiative forcing and for a variety of future greenhouse gas scenarios. This presentation highlights some key features of these simulations: the overall performance and important model biases, the representation of the Atlantic Meridional Overturning Circulation, tropical cyclone statistics, properties of sea-ice, the El Niño-Southern Oscillation, as well as their responses to future climate change. We will also present plans on how the data will be shared with the larger scientific community for further analysis and collaborative projects. 

How to cite: Timmermann, A., Lee, S.-S., and Chu, J.-E.: Ultra-high resolution global warming simulations conducted with CESM, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1725, https://doi.org/10.5194/egusphere-egu2020-1725, 2020.

EGU2020-2231 | Displays | AS1.2

Preliminary Results of Simulation of SOCRATES period with Global System for Atmospheric Modeling

Marat Khairoutdinov and Christopher Bretherton

The global version of the cloud-resolving System for Atmospheric Modeling (SAM) is used to simulate the global evolution of clouds and precipitation during the SOCRATES field campaign In Feb 2018 with particular focus on the Southern Ocean storm track region. The model has nonuniform horizontal resolution, which ranges from 4-km horizontal grid spacing over the Tropics up to 2-3 km isotropic grid-spacing over mid-latitudes. It includes a realistic topography and comprehensive land-surface model. The sea-surface temperature and sea ice are prescribed from observations. The results of two types of simulations are presented, weather-forecasting and observed-weather-nudged over 24-hour time scale; for the latter, hourly ERA5 reanalysis dataset is used. The cloud properties are compared to the SOCRATES observations. The sensitivity of the results to the choice of cloud microphysics, from simple single-moment to double-moment, is also discussed.

How to cite: Khairoutdinov, M. and Bretherton, C.: Preliminary Results of Simulation of SOCRATES period with Global System for Atmospheric Modeling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2231, https://doi.org/10.5194/egusphere-egu2020-2231, 2020.

EGU2020-20969 | Displays | AS1.2

Multi-fluid single-column modelling of Rayleigh-Bénard convection

Daniel Shipley, Hilary Weller, Peter Clark, and William McIntyre

Atmospheric convection remains one of the weakest parts of weather and climate models, especially in the tropics. As model resolutions increase, the assumptions underlying traditional convection parametrisations break down; however, we are still far from fully resolving all convective processes, showing a need for convection parametrisation well into the future.

A multi-fluid framework for parametrising convection has been proposed, based on conditionally filtering the Navier-Stokes equations. This results in a set of equations for multiple fluids, where each fluid has its own dynamic and thermodynamic fields. The approach is fully 3D and time-dependent, allowing for both convective memory and net mass transport due to convection. However, the approach differs from higher-order turbulence closures in that it attempts to capture the important coherent structures of convection via the partitioning into multiple fluids. In addition to the usual sub-filter fluxes, the equations contain terms involving the exchange of momentum, entropy, moisture, and tracers between different fluids. The problem of parametrising convection then becomes the problem of parametrising these exchange terms. This means that within this framework the convection is fundamentally a part of the dynamics: there is no separate “convection scheme" which is called by the dynamical core.

As a first step towards using this framework to parametrise atmospheric convection, we consider a highly simplified model: dry, 2D Rayleigh-Bénard convection in the Boussinesq limit. This model captures the essentials of buoyant convection, with additional symmetry constraints which help with building a parametrisation. In the single-column limit of the single-fluid case, no circulation can exist. This leads to a very poor solution, in particular vastly underestimating the heat transport.

In a two-fluid model, the separate dynamical fields for each fluid mean that a circulation can exist even at the coarsest resolutions. We show that a simple two-fluid single-column model can capture all the essentials of the horizontally-averaged time-mean high resolution solution, including the buoyancy, vertical velocity, and pressure profiles, as well as much better representation of the heat flux. We explore the consequences of different choices for the parametrisations of the exchange terms, showing that a good representation of volume, momentum, and buoyancy exchange, and of the pressure difference between the fluids, is required. For this simple case, this is achieved entirely without parametrisation of subfilter terms, showing that the multi-fluid approach is capturing the coherent structures of convection well.

How to cite: Shipley, D., Weller, H., Clark, P., and McIntyre, W.: Multi-fluid single-column modelling of Rayleigh-Bénard convection, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20969, https://doi.org/10.5194/egusphere-egu2020-20969, 2020.

With climate change and the conjoint challenges of food availability, clean water and geo-energy resources, our society is facing major challenges in the near future. These challenges are hard to address, because projections of Earth system change involve uncertainties that require quantification. Therefore, the Earth system science community tries to develop tools that provide decision-makers with the information required to effectively manage these issues.

The Advanced Earth System Modelling Capacity project (ESM) aims to enable such tools, investigating problems by looking at interactions between different Earth system components and improve their representation in numerical models. The project was funded by the German Helmholtz Association in April 2017 and involves eight research centers across Germany. The ultimate goal of the project is to represent the Earth system and how it changes with a world-leading modelling infrastructure that will support the process of developing solutions for the grand challenges we are facing.

The five different work packages of the project are working on topics such as enhancing the representation of Earth system model compartments, develop a flexible framework for coupling of Earth system model components, advance the Earth system data assimilation capacity, diagnose Earth system models, further develop cutting-edge frontier simulations, cross-scale modelling, and contribute to the shaping of a national strategy for Earth system modelling. The project also engages in training activities to educate and transfer knowledge to the next generation of scientists.

Since its initiation the project contributed with important results to several key model systems and platforms. In this presentation, we will highlight some current results and discuss advances in our Earth system modelling community and the way forward.

How to cite: Cristini, L. and the ESM Project Consortium: Advanced Earth System Modelling Capacity (ESM): Solving Grand Challenges by improving the representation of the components of the Earth system and their coupling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8322, https://doi.org/10.5194/egusphere-egu2020-8322, 2020.

A well-known drawback of Eulerian models is excessive numerical diffusion of the transported species. This applies to chemical species but also to water vapor. We present a new way of dealing with this problem in the vertical direction by using the Després and Lagoutière (1999) scheme – hereinafter DL99, a simple 1st-order advection scheme with antidiffusive properties. These authors have only studied this scheme in the context of 1d transport. Here we test the applicability of this scheme in atmospheric modelling by applying it to tracer transport in the vertical direction in idealized 2d (zonal-vertical) atmospheric circulations and quantify the gain compared to classical advection schemes.

In this idealized framework, we have tested the efficiency of DL99 in two cases representative of important situations for atmospheric transport :
- Formation of a thin plume from an initially thick column of tracer (e.g. volcanic plume, biomass burning plume etc.) under the effect of zonal wind shear in presence of large-scale variations in vertical wind
- Long-range advection of a thin polluted layer under the action of zonal wind in presence of large scale oscillations in the vertical wind.

In these idealized case studies, we show that using DL99 in the vertical direction yields dramatically improved performance compared to any other scheme we have tested, including the 3rd-Order Piecewise Parabolic Method (PPM). As an example, in a simulation with a vertical resolution of 500m and a zonal resolution of 25 km initialized by a 1000m-thick, zonally uniform layer of tracer, after being transported horizontally over 2000km over 48 hours by a uniform zonal wind ~11.5ms-1 together with an oscillating vertical wind of +-0.05ms-1, maximal tracer concentration at the end of the simulation with DL99 is 94% of its initial value instead of 51% with PPM, l2 relative error is 10% instead of 61%, and 92% of the tracer mass is still confined in the correct 1000m-thick envelope instead of 50%.

This and other numerical experiments shows that, by design, DL99 reduces numerical diffusion, but it also proves it to be able to preserve the areas of uniform tracer concentration even if these areas cover only a very small number of cells in the vertical direction. We argue that this unique set of properties, along with the simplicity of its formulation and its minimal computational cost make the DL99 an extremely attractive candidate for a robust and non-diffusive representation of vertical advection in Eulerian meteorological and chemistry-transport models. This scheme has been implemented in the state-of-the-art CHIMERE chemistry-transport model (Mailler et al., 2017), and we have shown that it brings a clear improvement in the representation of the structure of a volcanic plume from the Etna volcano (Lachâtre et al., 2020, Atmos. Chem. Phys.)

Main references:

Després, B., and F. Lagoutière, 1999, Un schéma non linéaire anti-dissipatif pour l'équation d'advection linéaire, Comptes Rendus de l’Académie des Sciences

How to cite: Mailler, S., Lachatre, M., and Menut, L.: Using an antidiffusive transport scheme for vertical transport: a promising path towards solving the long-standing problem of excessive vertical diffusion in Eulerian models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11706, https://doi.org/10.5194/egusphere-egu2020-11706, 2020.

EGU2020-14464 | Displays | AS1.2

Adaptive 2D shallow water simulation based on a MultiWavelet Discontinous Galerkin approach

Daniel Caviedes-Voullième, Nils Gerhard, Aleksey Sikstel, and Siegfried Müller

Shallow water modelling is a widely used for a vast range of applications in Hydraulics, Hydrology and Environmental Geosciences. It is at the core of most fluvial flood modelling approaches, and increasingly turning into the model of choice for urban flood modelling, coastal modelling and rainfall-runoff hydrological simulation. Shallow water solvers have significantly matured in the last decade, and currently, robust and accurate first-order solvers are widely available. Relevant developments have also been achieved in terms of higher order solvers, based on MUSCL and WENO reconstructions and on Discontinuous Galerkin (DG) schemes. Despite all this, applying shallow water solvers on realistic problems is constrained by the multiscale nature of environmental surface flows, in which flows in large domains are strongly affected by small-scale features of both the topography and the flow fields. This inherently multiscale problem naturally calls for a multiresolution modelling strategy, which is the topic of this contribution.

 

In this work, we explore the application of a multidimensional Discontinuous Galerkin scheme with dynamic mesh adaptivity driven by multiresolution analysis based on wavelets. The scheme harnesses the locality and high-order properties of DG, and makes use of an additional decomposition into the multiwavelet space driving a multiresolution analysis. By assessing the relevance of local features of the solution across scales, mesh adaptivity is triggered. In previous works, the general scheme has been presented and tested. Herein, we test the capabilities of the scheme on well-known benchmark problems for 2D shallow flows, including both laboratory and field scale flows.

 

The results clearly show that the scheme is capable of solving such problems with a high accuracy and that the dynamically adaptive mesh is capable of tracking physically-meaningful interfaces (wetting and drying fronts, transcritical shocks, rotating vortices) accurately. Moreover, the adaptive scheme is capable of providing very high spatial resolution where and when it is required, while keeping the computational cost orders of magnitude lower than what a uniform high resolution mesh would impose. In particular, the results suggest that this type of adaptive scheme produces more efficient meshes than alternative schemes. The results showcase some of the advantages of high-order solvers, especially when combined with adaptive schemes and are a proof-of-concept of the applicability of this type of solvers for realistic problems. Finally, the results also evidence the capability of the adaptive multiresolution strategy to transparently incorporate the properties of the underlying shallow water solver, allowing for improvements on the core scheme to always benefit the adaptive solution.

How to cite: Caviedes-Voullième, D., Gerhard, N., Sikstel, A., and Müller, S.: Adaptive 2D shallow water simulation based on a MultiWavelet Discontinous Galerkin approach, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14464, https://doi.org/10.5194/egusphere-egu2020-14464, 2020.

EGU2020-14970 | Displays | AS1.2

Stable Multiscale Discretizations of L2-Differential Complexes

Konrad Simon and Jörn Behrens

Global simulations over long time scales in climate sciences often require coarse grids due to computational constraints. This leaves dynamically important smaller scales unresolved. Thus the influence of small scale processes has to be taken care of by different means. State-of-the-art dynamical cores represent the influence of subscale processes typically via subscale parametrizations and often employ heuristic coupling of scales. This, however, unfortunately often lacks mathematical consistency. The aim of this work is to improve mathematical consistency of the upscaling process that transfers information from the subgrid to the coarse scales of the dynamical core and to largely extend the idea of adding subgrid correctors to basis functions for scalar and vector valued elements discretizing various function spaces.

Discussing prototypically the issue of weighted Hodge decompositions I will show that standard techniques on coarse meshes fail to find good projections in all parts of a modified de Rham complex if rough data is involved and discuss an idea of how to construct multiscale finite element (MsFEM) correctors to scalar and vector valued finite elements and, further, how to construct stable multiscale element pairings using the theory of finite element exterior calculus (FEEC). This can be seen as a meta-framework that contains the construction of standard MsFEMs [Efendiev2009, Graham2012]. Application examples here comprise porous media, elasticity, and fluid flow as well as electromagnetism in fine-scale and high-contrast media. I will provide the necessary theoretical background in homological algebra and differential geometry, and discuss a scalable MPI based implementation technique suitable for large clusters. Several computational examples will be shown. I may, if time permits, discuss some ideas from homogenisation theory to attack the problem of a proof of accuracy.

How to cite: Simon, K. and Behrens, J.: Stable Multiscale Discretizations of L2-Differential Complexes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14970, https://doi.org/10.5194/egusphere-egu2020-14970, 2020.

EGU2020-1328 | Displays | AS1.2

Exploring a Variable-Resolution Modeling Approach within a Global Nonhydrostatic Dynamical Core

Yihui Zhou, Yi Zhang, Zhuang Liu, Jian Li, and Rucong Yu

High-resolution numerical weather and climate models have a great advantage in both prediction and simulation for their ability to resolve small-scale systems, but suffer from expensive computational cost. The aim of this study is to explore a cost-effective variable-resolution modeling approach within a newly developed global nonhydrostatic dynamical core based on an unstructured mesh. We provide a size-controllable formulation of hierarchical refinement mode by an adapted density function for more realistic high-resolution simulations. The dynamical core is tested regarding both dry and moist atmosphere to evaluate variable-resolution simulations against quasi-uniform ones. In baroclinic wave tests, the variable-resolution model, which owns much less grid points, captures a comparable fine-scale fluid structure with the high-resolution quasi-uniform one in the refinement region. In the coarse region, the result of the variable-resolution simulation matches that of the low-resolution quasi-uniform one, which contributes to smaller global errors of the variable-resolution simulation. A series of sensitivity tests regarding parameters of the hierarchical refinement mode validate the high stability of the variable-resolution model to preserve the intensity and vertical structure of tropical cyclones moving through the transition zone. The variable-resolution modeling lays a strong foundation for potential improvement of regional high-resolution simulations.

How to cite: Zhou, Y., Zhang, Y., Liu, Z., Li, J., and Yu, R.: Exploring a Variable-Resolution Modeling Approach within a Global Nonhydrostatic Dynamical Core, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1328, https://doi.org/10.5194/egusphere-egu2020-1328, 2020.

EGU2020-10375 | Displays | AS1.2

The ERA5 Global Reanalysis: achieving a detailed record of the climate and weather for the past 70 years.

Hans Hersbach, Bill Bell, Paul Berrisford, Per Dahlgren, András Horányi, Joaquı́n Muñoz-Sabater, Julien Nicolas, Raluca Radu, Dinand Schepers, Adrian Simmons, and Cornel Soci

Reanalysis is a key contribution to the Copernicus Climate Change Service (C3S) that is implemented at the European Centre for Medium-Range Weather Forecasts (ECMWF) on behalf of the European Commission. The most recent ECMWF reanalysis, ERA5, provides hourly estimates of the global atmosphere, land surface and ocean waves at a horizontal resolution of 31km. Daily updates are provided with a latency of 5 days, while an extension back to 1950 is to be made available in the 2nd quarter of 2020.
ERA5 uses a 2016 version of the ECMWF numerical weather prediction model and data assimilation system (Integrated Forecasting System Cy41r2) to assimilate both in situ and satellite observations (95 billion for the period 1979 - 2019), many of which stem from reprocessed data records. The assimilation method includes a variational method for estimating observation biases that respects the heterogeneity within the observing system. Information on random uncertainties in the state estimates is provided by a 10-member ensemble of data assimilations at half the horizontal resolution (63km).
This presentation provides a concise overview of the ERA5 data assimilation system. A basic evaluation of characteristics and performance is presented, which includes an inter-comparison with other reanalysis products, such as its predecessor ERA-Interim and several major reanalyses produced elsewhere. Attention is given to the importance of the specification of the background error covariance matrix that determines the weight given to the model's first guess in the assimilation. In addition, a special focus will be on the back extension from 1950 to 1978, where the absence of satellite data prior to the 1970s puts a more demanding constraint on the data assimilation system.

How to cite: Hersbach, H., Bell, B., Berrisford, P., Dahlgren, P., Horányi, A., Muñoz-Sabater, J., Nicolas, J., Radu, R., Schepers, D., Simmons, A., and Soci, C.: The ERA5 Global Reanalysis: achieving a detailed record of the climate and weather for the past 70 years., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10375, https://doi.org/10.5194/egusphere-egu2020-10375, 2020.

EGU2020-3131 | Displays | AS1.2

Results from An Ensemble Reanalysis with the Community Earth System Model 2.1

Kevin Raeder, Jeffrey Anderson, TImothy Hoar, Nancy Collins, and Moha El Gharamti

The National Center for Atmospheric Research (NCAR) has recently released version 2.1 of the Community Earth System Model (CESM 2.1). A twenty-year, 80-member ensemble atmospheric reanalysis with 1-degree resolution in the CAM6 atmospheric model is being produced using NCAR’s Data Assimilation Research Testbed (DART) to support a variety of climate research goals. A standard configuration of CAM and the CLM5 land surface model will be coupled to a prescribed ocean and sea ice. Eventually, the reanalyisis will generate a final product that extends from 1999 to the present. Observations being assimilated include in situ observations used in the operational NCEP CFSR reanalysis along with GPS occultation observations and remote sensing temperature retrievals. The primary goal is to provide an ensemble of atmospheric forcing that can be used to generate additional ensemble reanalyses for other components of CESM including CLM, the POP and MOM6 ocean models, and the CICE sea ice model. Highlights of results from the first 10-years of the reanalysis will be presented. Results will include evaluation of short-term forecasts in observation space for root mean square error, ensemble spread, and ensemble consistency. In addition, key aspects of the atmospheric forcing files for other components of the climate system will be discussed. 

How to cite: Raeder, K., Anderson, J., Hoar, T., Collins, N., and El Gharamti, M.: Results from An Ensemble Reanalysis with the Community Earth System Model 2.1 , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3131, https://doi.org/10.5194/egusphere-egu2020-3131, 2020.

Under the Quantitative Observing System Assessment Program, the National Oceanic and Atmospheric Administration's (NOAA's) Atlantic Oceanographic and Meteorological Laboratory (AOML) is preparing to utilize the 9-km-resolution European Centre for Medium-Range Weather Forecasts (ECWMF) Cubic Octahedral grid global Nature Run (ECO1280) for observation simulation and conducting Observing System Simulation Experiments (OSSEs).   As part of the OSSE calibration, and before experiments can be run, it needs to be shown that the forecast model used in the OSSEs does not do a better job in predicting the Nature Run meteorology than it does in predicting the real world. Otherwise, the conclusions from the OSSEs in such a configuration may misstate the potential impact of a given instrument. In this presentation, the predictability of the new global OSSE system being developed at NOAA will be discussed. The NOAA/National Centers for Environmental Prediction (NCEP) Finite-Volume Cubed-Sphere Global Forecast System (FV3GFS) is used to test predictability over the first two months of ECO1280 (October-November 2015), comparing forecasts using simulated observations with added errors to real-world observations.  Only conventional observations will be utilized in both cases.  

How to cite: Casey, S., Cucurull, L., and Vidal, A.: Predictability of ECMWF Cubic Octahedral Nature Run (ECO1280) using Finite-Volume Cubed-Sphere Global Forecast System (FV3GFS) Compared to Real-World Predictability, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2012, https://doi.org/10.5194/egusphere-egu2020-2012, 2020.

EGU2020-17945 | Displays | AS1.2

The impact of NAWDEX dropsonde and extra radiosonde observations on forecast quality and tropopause structure

Matthias Schindler, Martin Weissmann, Andreas Schäfler, and Gabor Radnoti

Utilizing a multitude of in situ and remote sensing instruments, a comprehensive dataset was collected during the transatlantic field campaign NAWDEX in autumn 2016. Cycled data denial experiments with the global model of the ECMWF showed that additionally collected dropsonde and radiosonde observations contributed to a reduction in the short-range forecast error, with the most prominent error reductions being linked to Tropical Storm Karl, cyclones Matthew and Nicole and their subsequent interaction with the midlatitude waveguide. While the short-range forecast quality was improved, Schäfler et al. (2019, in review) demonstrated that ECMWF IFS analyses exhibit deficiencies in capturing observed wind speeds at and above the dynamical tropopause during NAWDEX. Therefore, data assimilation output from the ECMWF IFS is used to evaluate the observational influence on the tropopause. Statistics of data assimilation diagnostics such as the analysis increment and first guess departure will be assessed in observation space in a tropopause relative framework to quantify the impact of assimilated radiosonde observations on tropopause location and sharpness.

How to cite: Schindler, M., Weissmann, M., Schäfler, A., and Radnoti, G.: The impact of NAWDEX dropsonde and extra radiosonde observations on forecast quality and tropopause structure, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17945, https://doi.org/10.5194/egusphere-egu2020-17945, 2020.

EGU2020-18011 | Displays | AS1.2

A Model interface for ERA5

Inti Pelupessy, Maria Chertova, Gijs van den Oord, and Ben van Werkhoven

The ERA5 dataset provides a comprehensive view on recent climate data by assimilating vast amounts of historical observations into the ECMWF integrated forecast system, and as such establishing a reference point in the field of weather and climate modelling. The successor of ERA-interim is ubiquitous in the earth sciences, with applications such as boundary conditions for regional simulations, atmospheric forcings to ocean or land surface models, initial conditions to climate prediction experiments, etc.. The conventional workflow for such applications is to download the data, extract the necessary variables, optionally regrid or resample and save it in a model specific format. This procedure is time consuming, difficult to document properly and generates a lot of intermediate data of low reuse value. Here, we provide an alternative to this by wrapping access to the ERA5 dataset in a standardized OMUSE model interface. OMUSE is a Python framework for Earth System modelling, developed to simplify the use of simulation codes and enable new model couplings. Within OMUSE the ERA5 dataset is transparently accessed using the CDSAPI and the resulting interface is very much like an OMUSE interface for a simulation code. Data is pulled from the online climate data store only when needed and cached for later reuse. This approach simplifies the access and coupling of the ERA5 dataset with OMUSE model components and makes it trivially easy to repeat a model run with a different dataset or even replace it with a life model.

How to cite: Pelupessy, I., Chertova, M., van den Oord, G., and van Werkhoven, B.: A Model interface for ERA5, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18011, https://doi.org/10.5194/egusphere-egu2020-18011, 2020.

EGU2020-20536 | Displays | AS1.2

Next-generation geophysical modelling

Roman Nuterman, Dion Häfner, Markus Jochum, and Brian Vinter
So far, our pure Python, primitive equation ocean model Veros has been
about 50% slower than a corresponding Fortran implementation. But recent
benchmarks show that, thanks to a thriving scientific and machine
learning library ecosystem, tremendous speed-ups on GPU, and to a lesser
degree CPU, are within reach. On GPU, we find that the same model code
can reach a 2-5 times higher energy efficiency compared to a traditional
Fortran model.
We thus propose a new generation of geophysical models. One that
combines high-level abstractions and user friendliness on one hand, and
that leverages modern developments in high-performance computing on the
other hand.
We discuss what there is to gain from building models in high-level
programming languages, what we have achieved, and what the future holds
for us and the modelling community.

How to cite: Nuterman, R., Häfner, D., Jochum, M., and Vinter, B.: Next-generation geophysical modelling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20536, https://doi.org/10.5194/egusphere-egu2020-20536, 2020.

EGU2020-20598 | Displays | AS1.2

Effects of mesoscale ocean flows on multidecadal climate variability

André Jüling, Anna von der Heydt, and Henk Dijkstra
Climate variability on decadal to multidecadal time scales appears to be organized in pronounced patterns with clear expressions in sea surface temperature, such as the Pacific Multidecadal Variability and the Atlantic Multidecadal Variability. These patterns are now well studied both in observations and in global climate models and are important in the attribution of climate change. Results in CMIP5 models have indicated large biases in these patterns with consequences for ocean heat storage variability and eventually the global mean surface temperature.
We use two multi-century Community Earth System Model simulations at coarse (1°) and fine (0.1°) ocean model horizontal grid spacing and study the effect of the representation of mesoscale ocean flows on major patterns of multidecadal variability. We find that resolving mesoscale ocean flows both improves the characteristics of the modes of variability with respect to observations and increases the amplitude of the heat content variability in the individual ocean basins. However, the effect on the global mean surface temperature is relatively minor.

How to cite: Jüling, A., von der Heydt, A., and Dijkstra, H.: Effects of mesoscale ocean flows on multidecadal climate variability, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20598, https://doi.org/10.5194/egusphere-egu2020-20598, 2020.

Atmospheric rivers (ARs) are narrow, elongated, synoptic jets of water vapor that play important roles in the global water cycle and regional weather and climate extremes. Accurate climate projections of high impact global severe flood and drought events hinge on the climate models' ability to simulate and predict the AR phenomenon. This presentation will provide a systematic evaluation of the AR statistics and characteristics simulated by the GFDL new generation high resolution global climate model participating in the CMIP6 High Resolution Model Intercomparison Project (HiResMIP). The analyses include the historical period (1950-2014) compared against the ERA-Interim reanalysis results as well as future projections under global warming scenarios. The AR characteristics such as the spatial distribution, frequency, and intensity are explored in conjunction with large-scale circulation patterns such as the El Niño–Southern Oscillation, the Arctic Oscillation, and the Pacific-North-American teleconnections pattern. Potential changes in AR characteristics with global warming scenarios and their implications to weather and climate extremes will be discussed.

How to cite: Zhao, M.: Simulations of Atmospheric Rivers in GFDL New Generation High Resolution Global Climate Model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1596, https://doi.org/10.5194/egusphere-egu2020-1596, 2020.

The purpose of this study is to examine the impact of climate change on the changes on summer surface temperatures between present (2000-2010) and future (2050-2060) over the Arabian Peninsula and Kuwait. In this study, the influence of climate change in the Arabian Peninsula and especially in Kuwait was investigated by high resolution (36, 12, and 4 km grid spacing) dynamic downscaling from the Community Climate System Model CCSM4 using the WRF Weather Research and Forecasting model. The downscaling results were first validated by comparing National Centers for Environmental Prediction NCEP model outputs with the observational data. The global climate change dynamic downscaling model was run using WRF regional climate model simulations (2000-2010) and future projections (2050-2060). The influence of climate change in the Arabian Peninsula can be projected from the differences between the two period’s model simulations. The regional model simulations of the average maximum surface temperature in summertime predicted an increase from 1◦C to 3 ◦C over the summertime in Kuwait by midcentury.

 

How to cite: Alsarraf, H.: Projected climate change over Kuwait simulated using a WRF high resolution regional climate model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1867, https://doi.org/10.5194/egusphere-egu2020-1867, 2020.

EGU2020-1914 | Displays | AS1.2

East Asia Reanalysis System of CMA

Xudong Liang, Jingfang Yin, Yanxin Xie, and Feng Li

    The EARS (East Asia Reanalysis System) is a project of China Meteorological Administration for developing a high resolution regional atmospheric reanalysis dataset in the East Asia with higher quality for meso-scale weather system simulation and regional climate analysis. The reanalysis system was established with a domain covers the East Asia with horizontal resolution of 12km and some sub-domains with horizontal resolution of 3km. In EARS, besides the Global Communication System (GTS) shared observations, dense local observations such as the ground-based automatic observations, and weather radar data are used. New data assimilation operator for radar data was developed, and data assimilation methods for high-density surface observation were tested. Based on the observation dataset and reanalysis system, 10 years primary test reanalysis dataset was established. Verifications of the dataset indicate a better quality in comparison with global reanalysis data.

How to cite: Liang, X., Yin, J., Xie, Y., and Li, F.: East Asia Reanalysis System of CMA, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1914, https://doi.org/10.5194/egusphere-egu2020-1914, 2020.

The aim of this presentation is to compare the occurrence of discontinuities in the ozone concentration data from the MERRA-2, ERA-5 and JRA-55 reanalyse, with the help of the Pettitt homogeneity test. We distinguish between the significant and insignificant discontinuities, according to the relation between the dispersion and the average ozone values before and after the discontinuity.    This occurrence is important for trend analyses, because the presence of discontinuities influences the values of trends and their significance. Discontinuities arise from the changing in the assimilation procedure, introducing new observation to the reanalyse, and changing of data quality. We search for their spatial, temporal and geographical occurrence. There are differences among these reanalyses. In the case of the MERRA-2 data, the transition from SBUV to EOS Aura data in 2004 has great impact on discontinuity behaviour. The frequent occurrence of discontinuities is seen in the uppermost model layers. The uppermost MERRA-2 layer is 0.1 hPa, while for ERA-5 this layer is 1 hPa. So there are differences in the vertical distribution of discontinuities among the reanalyses. The ozone data with the strong occurrence of the significant discontinuities is not suitable for trend analyses.   

How to cite: Krizan, P.: Occurrence of discontinuities in the ozone concentration data from three reanalyses, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1942, https://doi.org/10.5194/egusphere-egu2020-1942, 2020.

EGU2020-3225 | Displays | AS1.2

High-resolution Simulations of a Hot-and-polluted Event with Detailed Local Climate Zone Information over the Greater Bay Area in South China

Junwen Chen, Chi-Yung Tam, Steve H.L. Yim, Meng Cai, Ran Wang, Xinwei Li, Chao Ren, Tuantuan Zhang, and Peng Gao

A new 10-type urban Local Climate Zone (LCZ) classification with 100-m resolution was developed, following the guidelines of the World Urban Database and Access Portal Tools (WUDAPT) over the Greater Bay Area (GBA). This LCZ dataset was incorporated into the Building Environment Parameterization (BEP)-Building Energy Model (BEM) multi-layer urban canopy scheme used by the Weather Research and Forecasting (WRF) model, with key parameters (such as fraction of impervious surface, building height/width, road width, air conditioning usage) determined from local building morphology and energy consumption patterns. The impacts of using such detailed 10-type LCZ, as compared to using remapped 3-type LCZ and using default WRF 1-type urban land cover were assessed, based on parallel integrations of the WRF system at 1-km resolution for a historical hot-and-polluted event over the GBA. It was found that the model surface temperature, air temperature, humidity and wind speed in the 10-type LCZ run were in closer agreement with in-situ observations, demonstrating the value of detailed urban LCZ data in improving the model performance. Smaller diurnal temperature range and higher nighttime temperature were found in the 10-type LCZ run compared to the 3-type LCZ and 1-type runs. Increased building height in the 10-type LCZ setting also reduces positive bias of wind speed in the lower planetary boundary layer at urban locations. The cold and dry biases over the non-urban areas in the 10-type LCZ run could be further reduced through considering updated land cover, soil type, soil hydraulic/thermal parameters, soil moisture/temperature. Owing to the improvement in capturing the urban meteorology, incorporating more detailed LCZ classification might also improve air-quality simulations. These findings should be relevant to the development of comprehensive, high-resolution earth system models, which are an indispensable tool for mitigation of and adaption to regional environmental and climate changes.

How to cite: Chen, J., Tam, C.-Y., Yim, S. H. L., Cai, M., Wang, R., Li, X., Ren, C., Zhang, T., and Gao, P.: High-resolution Simulations of a Hot-and-polluted Event with Detailed Local Climate Zone Information over the Greater Bay Area in South China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3225, https://doi.org/10.5194/egusphere-egu2020-3225, 2020.

EGU2020-4183 | Displays | AS1.2

A structure-preserving approximation of the discrete split rotating shallow water equations

Werner Bauer, Jörn Behrens, and Colin J. Cotter

We introduce an efficient split finite element (FE) discretization of a y-independent (slice) model of the rotating shallow water equations. The study of this slice model provides insight towards developing schemes for the full 2D case. Using the split Hamiltonian FE framework [1,2], we result in structure-preserving discretizations that are split into topological prognostic and metric-dependent closure equations. This splitting also accounts for the schemes' properties: the Poisson bracket is responsible for conserving energy (Hamiltonian) as well as mass, potential vorticity and enstrophy (Casimirs), independently from the realizations of the metric closure equations. The latter, in turn, determine accuracy, stability, convergence and discrete dispersion properties. We exploit this splitting to introduce structure-preserving approximations of the mass matrices in the metric equations avoiding to solve linear systems. We obtain a fully structure-preserving scheme with increased efficiency by a factor of two.

References

[1] Bauer, W. and Behrens, J. [2018], A structure-preserving split finite element discretization of the split wave equations, Applied Mathematics and Computation, 325, 375--400.

[2] Bauer, W., Behrens, J., Cotter, C.J. [2019], A structure-preserving split finite element discretization of the rotating shallow water equations in split Hamiltonian form, preprint: http://arxiv.org/abs/1912.10335.

How to cite: Bauer, W., Behrens, J., and Cotter, C. J.: A structure-preserving approximation of the discrete split rotating shallow water equations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4183, https://doi.org/10.5194/egusphere-egu2020-4183, 2020.

EGU2020-4579 | Displays | AS1.2

NH-GOMO, an efficient and easily portable non-hydrostatic ocean model

Qiang Tang, Xiaomeng Huang, and Xing Huang

Numerical simulation of nonlinear gravity internal waves with non-hydrostatic ocean models, especially these which using the terrain-following sigma-coordinate, is challenging. The expensive computation cost, which is caused by the dynamic pressure Poisson solver in cases using fine grid resolution in both directions (horizontal and vertical), is the main reason. A non-hydrostatic ocean model named NH-GOMO is constructed based on a partially implicit finite difference scheme for the dynamic pressure and adopts an idea of “decimation and interpolation”. A significant optimization for the pressure Poisson solver, which brings no obvious accuracy loss, is obtained with these technologies. The automatic parallel operator library named OpenArray is used as the bottom layer of this model and make it easy to transport between different computing platforms. Accuracy and efficiency have been validated by several ideal test cases.

How to cite: Tang, Q., Huang, X., and Huang, X.: NH-GOMO, an efficient and easily portable non-hydrostatic ocean model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4579, https://doi.org/10.5194/egusphere-egu2020-4579, 2020.

EGU2020-4751 | Displays | AS1.2

High-resolution simulations over a sub-kilometre scale valley during stable night conditions

Michiel de Bode, Pierre Roubin, Thierry Hedde, and Pierre Durand

Complex terrain creates many challenges for modelling aerologic phenomenon. Local variations can have drastic effects on airflows; a good representation of local orography is, therefore, crucial in models. While finer-resolution improves the orographic description in models, it creates a “grey zone” problem for boundary layer schemes. The grey zone, for PBL schemes, is where model-resolution comes close to the size of turbulent structures, leading to the structures being partly resolved and partly sub-grid scale. Research on the grey zone has focused mostly on daytime, neutral-to-unstable conditions. In thinner nocturnal stable layers, local processes become predominant, such as channelling, the simulation of which demands higher resolution in models.

In this research, we run a nested grid version of WRF with a resolution of the innermost domain at 111 m and the coarsest domain at 9 km. We focus on the 1 km wide pre-Alpine valley of Cadarache, a tributary of the Durance River. Previous simulations did not succeed in representing the valley with resolutions of 1 km. We test the indicative value of turbulent length-scales for decisions on the grey zone. Based on the KASCADE 2017 data of several sonic anemometers, placed along the valley thalweg, we determine the turbulent length scales to verify whether the turbulence remains sub-grid or not.

Our first results indicate that turbulent structures in this sub-kilometre scale valley remain well below the model resolution for night time conditions. First runs with 111 m resolution show realistic night time winds and produced the correct overall-structure in the valley. A general under prediction of 2 m-temperatures was found, especially during daytime. Further runs aim to improve forecast precision.  

How to cite: de Bode, M., Roubin, P., Hedde, T., and Durand, P.: High-resolution simulations over a sub-kilometre scale valley during stable night conditions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4751, https://doi.org/10.5194/egusphere-egu2020-4751, 2020.

EGU2020-5403 | Displays | AS1.2

An idealized Testbed for Radar Data Assimilation

Yuefei Zeng, Tijana Janjic, Alberto de Lozar, Ulrich Blahak, and Axel Seifert

 

 

How to cite: Zeng, Y., Janjic, T., de Lozar, A., Blahak, U., and Seifert, A.: An idealized Testbed for Radar Data Assimilation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5403, https://doi.org/10.5194/egusphere-egu2020-5403, 2020.

EGU2020-5583 | Displays | AS1.2

Evaluation of the University of Victoria Earth System Climate Model version 2.10 (UVic ESCM 2.10)

Nadine Mengis, David P. Keller, Andrew MacDougall, Michael Eby, Nesha Wright, Katrin J. Meissner, Andreas Oschlies, Andreas Schmittner, H. Damon Matthews, and Kirsten Zickfeld

The University of Victoria Earth system climate model of intermediate complexity has been a useful tool in recent assessments of long-term climate changes including paleo-climate modelling. Since the last official release of the UVic ESCM 2.9, and the two official updates during the last decade, a lot of model development has taken place in multiple groups. The new version 2.10 of the University of Victoria Earth System Climate Model (UVic ESCM), to be used in the 6th phase of the coupled model intercomparison project (CMIP6), presented here combines and brings together multiple model developments and new components that have taken place since the last official release of the model. To set the foundation of its use, we here describe the UVic ESCM 2.10 and evaluate results from transient historical simulations against observational data. We find that the UVic ESCM 2.10 is capable of reproducing well changes in historical temperature and carbon fluxes, as well as the spatial distribution of many ocean tracers, including temperature, salinity, phosphate and nitrate. This is connected to a good representation of ocean physical properties. For the moment, there remain biases in ocean alkalinity and dissolved inorganic carbon, which will be addressed in the next updates to the model.

How to cite: Mengis, N., Keller, D. P., MacDougall, A., Eby, M., Wright, N., Meissner, K. J., Oschlies, A., Schmittner, A., Matthews, H. D., and Zickfeld, K.: Evaluation of the University of Victoria Earth System Climate Model version 2.10 (UVic ESCM 2.10), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5583, https://doi.org/10.5194/egusphere-egu2020-5583, 2020.

EGU2020-8733 | Displays | AS1.2

Do high resolution GCMs overestimate precipitation over land?

Omar Müller, Pier Luigi Vidale, Patrick McGuire, Benoît Vannière, Reinhard Schiemann, and Daniele Peano

Previous studies showed that high resolution GCMs overestimate land precipitation when compared against gridded observations or reanalysis (Demory et al. 2014, Vannière et al. 2019). In particular, grid point models (eg. HadGEM3) show a significant increase of precipitation on regions dominated by complex orography, where the scarcity of gauge stations increase the uncertainty of gridded observations. The goal of this work is to assess the effect of such differences in precipitation on river discharge, considering it as an integrator of the water balance at catchment scale. A set of JULES and CLM simulations have been conducted turning rivers on with Total Runoff Integrating Pathways (TRIP) and the River Transport Model (RTM) respectively. The simulations form three ensembles for each land surface model (LSM) which main difference is given by the forcing dataset. The forcings are WFDEI (reanalysis), LR (~1° resolution in meteorological data from GCMs) and HR (~0.25° resolution in meteorological data from GCMs). These ensembles are evaluated in a set of 280 catchments distributed around the world.

In terms of correlation between simulated and observed river discharge observations, the results show that LSMs forced by reanalysis have higher performance than LSMs forced by GCMs as expected. In terms of biases, the river discharge is underestimated in eight out of eleven major basins when LSMs are forced by reanalysis. On those basins, the extra precipitation estimated by GCMs help to simulate an amount of river discharge closer to observations (Eg. Yenisey and Lena). Moreover, 37 small basins with a strong component of orographic precipitation over the Andes, the Rocky Mountains, the Alps and in the Maritime Continent were evaluated. In most cases HR offers notably better results than LR and WFDEI, suggesting that high resolution models produce orographic precipitation in the correct place and time.

In future works offline TRIP simulations will be carried out directly forced by runoff and subsurface runoff from GCMs. It will allow to discard errors in evapotranspiration produced by JULES or CLM when they are used to simulate river discharge. This work is part of the European Process-based climate sIMulation: AdVances in high resolution modelling and European climate Risk Assessment (PRIMAVERA) Project. PRIMAVERA is a collaboration between 19 funded by the European Union’s Horizon 2020 Research & Innovation Programme.

Demory, M. E., Vidale, P. L., Roberts, M. J., Berrisford, P., Strachan, J., Schiemann, R., & Mizielinski, M. S. (2014). The role of horizontal resolution in simulating drivers of the global hydrological cycle. CLIM DYNAM, 42(7-8), 2201-2225.

Vannière, B., Demory, M. E., Vidale, P. L., Schiemann, R., Roberts, M. J., Roberts, C. D., ... & Senan, R. (2018). Multi-model evaluation of the sensitivity of the global energy budget and hydrological cycle to resolution. CLIM DYNAM, 1-30.

How to cite: Müller, O., Vidale, P. L., McGuire, P., Vannière, B., Schiemann, R., and Peano, D.: Do high resolution GCMs overestimate precipitation over land?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8733, https://doi.org/10.5194/egusphere-egu2020-8733, 2020.

Neglecting subgrid-scale (SGS) variability can lead to substantial bias in calculations of microphysical process rates. The solution to the SGS variability bias problem lies in representing the variability using two-dimensional joint probability distribution functions (JPDFs) for the pairs of different microphysical variables. The JPDFs have also been shown to vary in the vertical: as a result their implementation in mesoscale models presents a challenging task.

We developed a more efficient formulation of cloud inhomogeneity by using a concept of “generic” JPDF. Using Large Eddy Simulation (LES) studies of shallow cumulus and cumulus congestus clouds we showed that JPDFs calculated based on datasets representing “typical” cloud types (“generic” JPDFs) provide good approximation of microphysical process rates. The generic JPDF, therefore, represent the cloud type in general, i.e. they do not depend on changing ambient conditions. The advantage of generic JPDFs is that they can be a-priory integrated and yield a one-dimensional variability factor (V-factor) specific for each cloud type. A quite accurate approximation of V-factors by an analytical function in the form of a 3rd order polynomial was obtained and can be easily implemented in mesoscale models.

How big is the effect of cloud inhomogeneity on precipitation? To answer this question we evaluated the effect of accounting for cloud inhomogeneity on precipitation in sensitivity simulations. In the shallow Cu case over the 24 hr simulation the surface precipitation increased by about 40% when inhomogeneity was accounted. In the congestus Cu case the increase in precipitation was even more significant: by more than 75% over only 8 hours since rain first appeared at the surface. The sensitivity experiments also revealed that most of the increase resulted from the augmented autoconversion process. The effect of modified by the V-factor accretion rates was much less significant, primarily, because of the nearly linear dependence of accretion on its parameters.  This shows importance of the most accurate formulation of the autoconversion process.

 

 

How to cite: Kogan, Y.: An efficient method to account for microphysical inhomogeneity in mesoscale models by using one-dimensional variability factor., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5951, https://doi.org/10.5194/egusphere-egu2020-5951, 2020.

A reliable simulation of the spatiotemporal characteristics of the meteorological field is of great significance for hydrological impact studies. To approach this target, a number of weather generators (WGs) have been developed over the past few decades. However, a detailed literature review shows that currently developed WGs are subject to one or several aspects of the following limitations: (1) low spatial and temporal resolutions to describe the real spatiotemporal dynamics of meteorological processes; 2) incapability to simulate a spatially coherent, temporally consistent, and physically meaningful meteorological field; and 3) inability to extend into the future in a climate change context. To tackle these problems, this study proposes some potential solutions: (1) using the multi-site multivariate WGs (MMWGs) to simulate the spatial, temporal, and inter-variable dependencies in the meteorological field; (2) coupling the MMWGs with the resampling-based algorithms to generate high-resolution spatiotemporal meteorological data; and (3) perturbing the parameters of the distribution and dependency models based on the future climate projection. A case study is carried out and shows that the proposed solutions are effective in addressing the aforementioned challenges. These findings could assist in developing high-resolution MMWGs for weather simulation and impact assessment.

How to cite: Li, X.: Challenges in constructing a high-resolution, multi-site, and multivariate weather generator and potential solutions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12075, https://doi.org/10.5194/egusphere-egu2020-12075, 2020.

EGU2020-6558 | Displays | AS1.2

An ensemble Kalman filter data assimilation system for the whole neutral atmosphere

Dai Koshin, Kaoru Sato, Kazuyuki Miyazaki, and Shingo Watanabe

A data assimilation system with a four-dimensional local ensemble transform Kalman filter (4D-LETKF) is developed to make a new analysis data for the atmosphere up to the lower thermosphere using the Japanese Atmospherics General Circulation model for Upper Atmosphere Research. The time period from 10 January 2017 to 20 February 2017, when an international radar network observation campaign was performed, is focused on. The model resolution is T42L124 which can resolve phenomena at synoptic and larger scales. A conventional observation dataset provided by National Centers for Environmental Prediction, PREPBUFR, and satellite temperature data from the Aura Microwave Limb Sounder (MLS) for the stratosphere and mesosphere are assimilated. First, the performance of the forecast model is improved by modifying the vertical profile of the horizontal diffusion coefficient and modifying the source intensity in the non-orographic gravity wave parameterization, by comparing it with radar wind observations in the mesosphere. Second, the MLS observational bias is estimated as a function of the month and latitude and removed before the data assimilation. Third, data assimilation parameters, such as the degree of gross error check, localization length, inflation factor, and assimilation window are optimized based on a series of sensitivity tests. The effect of increasing the ensemble member size is also examined. The obtained global data are evaluated by comparison with the Modern-Era Retrospective analysis for Research and Applications version 2 (MERRA-2) reanalysis data covering pressure levels up to 0.1 hPa and by the radar mesospheric observations which are not assimilated.

How to cite: Koshin, D., Sato, K., Miyazaki, K., and Watanabe, S.: An ensemble Kalman filter data assimilation system for the whole neutral atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6558, https://doi.org/10.5194/egusphere-egu2020-6558, 2020.

EGU2020-7881 | Displays | AS1.2

Ground-based CO2 monitoring network design over India to constrain the regional terrestrial fluxes

Nalini Krishnankutty, Sijikumar Sivaraman, Vinu Valsala, Yogesh Tiwari, and Radhika Ramachandran

The present study aims to design an optimal CO2 monitoring network over India to better constrain the Indian terrestrial surface fluxes using Lagrangian Particle Dispersion Model FLEXPART and Bayesian inversion methods. Prior and posterior cost functions are calculated using potential emission sensitivity from FLEXPART, prior flux uncertainties from CASA-GFED biosphere fluxes and CDIAC fossil fuel fluxes, and assumed uniform observational uncertainty of 2 ppm. A total of 73 regular grid cells are identified over the Indian land mass in 2°x2° latitude by longitude resolution assuming each cell can hold a potential site. Further, using incremental optimization methodology, the effectiveness of CO2 observations from these locations to reduce the Indian terrestrial flux uncertainty is quantified. The study is carried out in three parts. Firstly, we evaluated the existing stations over India in terms of reduction in uncertainty brought out by them in the surface flux estimation over the Indian landmass. This provides a unique opportunity for the representative stations to restart the observational programs based on their role in the flux estimation. In second part, we devised a methodology to design an extended network by adding a few more potential stations to the existing stations. Thirdly, we identified a completely new set of optimal stations for measuring atmospheric CO2 over India, which do not have any liabilities of pre-existing stations. The study depicts that the existing stations could bring down the uncertainty in the range of 18% to 36%. Among the existing stations, Kharagpur, Sagar, Shadnagar, Kodaikanal and Pondicherry are the best stations, which are indeed adding value to the CO2 flux inversions by reducing the uncertainty in the range of 4% to 13%. Addition of five new stations to the base network formed an extended network, which could reduce the uncertainty by an additional 15% for all the seasons reaching up to 45%. The new stations are mainly located over the east and north-east India with few exceptions during post-monsoon where stations are identified over the west and south India as well. The study identified 12 stations for each season and formed a ‘new network’ that could achieve the equivalent uncertainty reduction as compared with the 14 stations in the ‘extended network’. From this, an ‘optimal network’ and the best network consisting of 17 stations were identified that could best represent flux scenario and transport over India in all the four seasons. In northeast India, flux uncertainty is quite large, also the prevailing westerly wind in most parts of the year contributes to the surface CO2 signature of India to that location, demanding requirement of CO2 observations throughout the year. The study highlights a major zone of CO2 ‘observational void’ that exists in potential locations near east and northeast parts of India. Immediate requirement of CO2 monitoring initiative in these areas is highly recommended.

How to cite: Krishnankutty, N., Sivaraman, S., Valsala, V., Tiwari, Y., and Ramachandran, R.: Ground-based CO2 monitoring network design over India to constrain the regional terrestrial fluxes , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7881, https://doi.org/10.5194/egusphere-egu2020-7881, 2020.

EGU2020-8684 | Displays | AS1.2

A scale invariance criterion for geophysical fluids

Urs Schaefer-Rolffs

Scale invariance of geophysical fluids is investigated in terms of a scale invariance criterion. It was developed by Schaefer-Rolffs et al. (2015) based on the implication that each scale invariant subrange shall have its own criterion. Two particular cases are considered, namely the synoptic scales with a significant Coriolis term and a case at smaller scales where the anelastic approximation is valid. The first case is characterized by a constant enstrophy cascade, while in the second case small-scale fluctuations of density, pressure, and temperature are taken into account. In both cases, the respective scale invariance criteria are applied to simple parameterizations of turbulent diffusion. It is demonstrated that only dynamic approaches are scale invariant.

How to cite: Schaefer-Rolffs, U.: A scale invariance criterion for geophysical fluids, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8684, https://doi.org/10.5194/egusphere-egu2020-8684, 2020.

EGU2020-11976 | Displays | AS1.2

Mesoscale Modulation of Dissolved Oxygen in the Tropical Pacific

Yassir Eddebbar

The distribution of dissolved oxygen in the tropical Pacific acts as a major control on marine ecosystems habitats and the foraging range of tuna fiheries in this region. A basic understanding of processes driving the mean structure and variability of the oxygen minimum zones (OMZs) in this region, however, remains challenged by sparse observations and coarse model resolution. In this study, we examine the influence of mesoscale processes on equatorial Pacific oxygen distribution and variability, with a particular focus on tropical instability vortices (TIVs). We employ an eddy-resolving configuration of the Community Earth System Model (CESM) and Lagrangian analysis to evaluate the impacts and governing mechanisms by which TIVs influence oxygen distribution and budgets in this region. The westward seasonal propagation of TIVs from summer through winter is found to drive a deepening of the oxygen minima along the equatorial Pacific band (10oN-10oS), and thus a seasonal expansion of the equatorial oxygenated tongue separating the north and south tropical Pacific OMZs. Strong hemispheric asymmetry is evident in TIV impacts on oxygen due to relatively weaker TIV activity and less pronounced oxygen gradients south of the equator. Mechanisms governing TIV oxygenation of the upper equatorial Pacific include a complex interplay of physical and biogeochemical processes. Isopycnal displacements act in concert with vortex trapping and lateral stirring to mix oxygenated waters from the upper layers into the equatorial boundaries of the north and south tropical Pacific OMZs. TIV-induced advection and upwelling, on the other hand, intensifies nutrient supply and productivity, organic carbon export, and oxygen respiration demand at depth, thus acting (though only slightly) to counteract the physical effects. The influence of these processes varies with TIV phase, from vortex generation in the eastern Pacific through vortex dissipation in the west. TIVs are found to have a profound influence on upper equatorial Pacifc oxygen distribution and budget, with major implications for understanding the coupling between oxygen and ocean circulation, predicting marine ecosystem dynamics, and designing observation networks in this region.

How to cite: Eddebbar, Y.: Mesoscale Modulation of Dissolved Oxygen in the Tropical Pacific, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11976, https://doi.org/10.5194/egusphere-egu2020-11976, 2020.

In this study, we developed a new urban parameterization method of wind speeds. The parameterization method uses building morphology parameters (the volumetric fraction, the plane area fraction, and the average height of buildings) for three different areas. For this, we investigated the relationships between the wind speed change rates by buildings and the urban parameters in three target areas. Each target area includes an automated weather station (AWS) at its center. We conducted the multiple regression analysis to make look-up tables for the relationships between the wind speed change rates and the urban morphology parameters for 32 inflow directions in the target areas. For validation, we simulated the wind speeds at the AWSs using a CFD model coupled to the local data assimilation and prediction system (LDAPS), one of the operational numerical prediction systems of the Korean Meteorological Administration. The results showed that the estimated wind speeds at the AWSs in the three target areas were very similar to those simulated by the LDAPS-CFD coupled model as well as those observed at the AWSs.

How to cite: Wang, J.-W., Kim, J.-J., and Yang, H.-J.: Estimation of Wind Speeds in Urban Areas Using Look-up Tables for Wind-speed Change Rate Simulated by a CFD Model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12129, https://doi.org/10.5194/egusphere-egu2020-12129, 2020.

EGU2020-12626 | Displays | AS1.2

Introduction to A Regional Coupled Forecasting System

Mingkui Li and Shaoqing Zhang

A regional coupled prediction system for the Asia-Pacific area (AP-RCP) has been established. The AP-RCP system consists of WRF-ROMS (Weather Research and Forecast and Regional Ocean Model System) coupled models combined with local observing information through dynamically downscaling coupled data assimilation. The system generates 18-day atmospheric and oceanic environment forecasts on a daily quasi-operational schedule at Qingdao Pilot National Laboratory for Marine Science and Technology (QNLM). The AP-RCP system mainly includes 2 different coupled model resolutions: 27km WRF coupled with 9km ROMS, and 9km WRF coupled with 3km ROMS. This study evaluates the impact of enhancing coupled model resolution on the extended-range forecasts, focusing on forecasts of typhoon onset, and improved precipitation and typhoon intensity forecasts. Results show that enhancing coupled model resolution is a necessary step to realize the extended-range predictability of the atmosphere and ocean environmental conditions that include a plenty of local details. The next challenges include improving the planetary boundary physics and the representation of air-sea and air-land interactions when the model can resolve the kilometer or sub-kilometer processes.

How to cite: Li, M. and Zhang, S.: Introduction to A Regional Coupled Forecasting System, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12626, https://doi.org/10.5194/egusphere-egu2020-12626, 2020.

EGU2020-12907 | Displays | AS1.2

Korea Institute of Ocean Science & Technology Earth System Model and its simulation characteristics

Young Ho Kim, Gyundo Pak, Yign Noh, Myong-In Lee, Sang-Wook Yeh, Daehyun Kim, Sang-Yeob Kim, Joon-Lee Lee, Ho Jin Lee, Seung-Hwon Hyun, Kwang-Yeon Lee, and Jae-Hak Lee

In our presentation, we will show the performance of a new earth system model developed at the Korea Institute of Ocean Science and Technology (KIOST), called the KIOST-ESM. The KIOST-ESM is based on a low-resolution version of the Geophysical Fluid Dynamics Laboratory Climate Model version 2.5. The main changes made to the base model include using new cumulus convection and ocean mixed layer parameterization schemes, which improve the model fidelity significantly. In addition, the KIOST-ESM adopts dynamic vegetation and new soil respiration schemes in its land model component. The performance of the KIOST-ESM was assessed in pre-industrial and historical simulations that are made as part of its participation into Climate Model Intercomparison Project phase 6. The response of the earth system to increases in greenhouse gas concentrations were analyzed in the ScenarioMIP simulations. The KIOST-ESM exhibited superior performance compared to the base model in terms of the mean sea surface temperature over the Southern Ocean and over the cold tongue in the tropical Pacific. The KIOST-ESM can also simulate the dominant tropical variability in the intraseasonal (Madden-Julian Oscillation) and interannual (El Niño-Southern Oscillation) timescales more realistically than the base model. On the other hand, like many other contemporary ESMs, the KIOST-ESM showed notable cold bias in the Northern Hemisphere, and the so-called double-Intertropical Convergence Zone bias remains. The ScenarioMIP results confirm the global average surface atmospheric temperature responds to the CO2 concentration.

How to cite: Kim, Y. H., Pak, G., Noh, Y., Lee, M.-I., Yeh, S.-W., Kim, D., Kim, S.-Y., Lee, J.-L., Lee, H. J., Hyun, S.-H., Lee, K.-Y., and Lee, J.-H.: Korea Institute of Ocean Science & Technology Earth System Model and its simulation characteristics, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12907, https://doi.org/10.5194/egusphere-egu2020-12907, 2020.

EGU2020-13552 | Displays | AS1.2

Numerical Simulation of the Effects of Warm Temperature Perturbation on Mesoscale Vortex and Rainfall in Col Field

Yongqiang Jiang, Chaohui Chen, Hongrang He, Yudi Liu, Hong Huang, Xuezhong Wang, and Huawen Wang

The col field (a region between two lows and two highs in the isobaric surface) is a common pattern leading to the generation of mesoscale vortex and heavy rainfall in China. The mesoscale vortex usually forms near the col point and the dilatation axis of the col field in the low-level troposphere.

The Mesoscale model WRF was used to numerically simulate a rainfall process in col field. A temperature perturbation column (TPC) was introduced into the low-level col field near the col point, and the effects of TPC on mesoscale vortex and rainfall was analyzed.

It was shown that in the region of strong wind background, the TPC moves downstream and has little effect on the environment, while near the col point, the wind speed and the vertical wind shear are small, the TPC can stay in the col field for a long time, which can have a greater impact on the environment. The strong TPC near the col point can trigger the vortex. As the temperature of the air column increases, the pressure drops, leading to the low-level convergence and the upper-level divergence, and the low-level cyclonic vorticity form under the effect of ageostrophic winds, which is favor of the formation of mesoscale vortex in the weak wind field. The formation of vortex promotes the intensification of precipitation. The release of the latent heat of the condensation induced by the TPC makes a positive feedback for the mesoscale vortex. The southwestly low-level jet enhances through the thermodynamic action, resulting in convergence of the leeward low-level jet and increase of precipitation, and divergence of the upwind low-level jet and decrease of precipitation, respectively. The col field is a favorable circumstance for the formation of mesoscale vortex.

Acknowledgements. This research was supported by the National Natural Science Foundation of China (Grant Nos. 41975128 and 41275099).

How to cite: Jiang, Y., Chen, C., He, H., Liu, Y., Huang, H., Wang, X., and Wang, H.: Numerical Simulation of the Effects of Warm Temperature Perturbation on Mesoscale Vortex and Rainfall in Col Field, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13552, https://doi.org/10.5194/egusphere-egu2020-13552, 2020.

EGU2020-16687 | Displays | AS1.2

Three Dimensional Radiative Transfer in ICON-LEM

Fabian Jakub and Bernhard Mayer

How to cite: Jakub, F. and Mayer, B.: Three Dimensional Radiative Transfer in ICON-LEM, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16687, https://doi.org/10.5194/egusphere-egu2020-16687, 2020.

The assimilation of observations in local area models (LAMs) assures that the states of meteorological variables are as close to reality as possible. Water vapor is an important constituent in terms of cloud and precipitation formation. Its highly variable nature in space and time is often insufficiently represented in models.

The aim of our work is to improve the simulation of water vapour in the Weather Research and Forecasting model WRF by assimilation of different observations. At the current stage, temperature, relative humidity, and surface pressure derived from climate stations are applied as well as zenith total delay (ZTD) data from global navigation satellite system (GNSS) stations. We try to identify the best setup of assimilation parameters which all of them directly or indirectly influence water vapour simulations. We will show case studies of high-resolution WRF simulations (2.1 km) between 2016 and 2018 for different seasons in southwest Germany. The impact of assimilation (3D-VAR) of different variables, combinations of variables, background error option as well as the temporal resolution of assimilation is evaluated. We look at column values and also at profiles derived from radiosondes. Our results show a positive impact when assimilating measured data, but deteriorations are also possible. A distinct influence of assimilation is only apparent for a few time steps. If the temporal resolution of the assimilated variables is too coarse and there is no assimilation close to these time steps, the positive effect vanishes.

How to cite: Wagner, A., Fersch, B., Yuan, P., and Kunstmann, H.: The sensitivity of data assimilation on water vapour fields on convection-permitting WRF simulations over the GNSS Upper Rhine Graben Network (GURN), Germany, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18092, https://doi.org/10.5194/egusphere-egu2020-18092, 2020.

EGU2020-18216 | Displays | AS1.2

Sensitivity of the Atlantic Meridional Overturning Circulation to Model Resolution in CMIP6 HighResMIP Simulations

Dorotea Iovino, Malcolm J. Roberts, Laura C. Jackson, Christopher D. Roberts, Virna Meccia, David Docquier, Torben Koenigk, Pablo Ortega, Eduardo Moreno-Chamarro, Alessio Bellucci, Andrew Coward, Sybren Drijfhout, Eleftheria Exarchou, Oliver Gutjahr, Helene Hewitt, Katja Lohmann, Reinhard Schiemann, Jon Seddon, Laurent Terray, and Xiaobiao Xu and the iHESP group members

The Atlantic Meridional Overturning Circulation (AMOC) is a key component of the three-dimensional ocean circulation that transports warm and salty water northward, and exports cold and dense water from the Arctic southward.

The simulated AMOC in Coupled Model Intercomparison Project models (both coupled and ocean-only) has been studied extensively. However, correctly simulating the AMOC with these models remains a challenge for the climate modelling community. One model aspect that can affect the AMOC representation is the model resolution (i.e. grid spacing).

Here, we examine key aspects of the North Atlantic Ocean circulation using a multi-model, multi-resolution ensemble based on the CMIP6 HighResMIP coupled experiments. The AMOC and associated heat transport tend to become stronger as model resolution increases, particularly when the ocean resolution changes from non-eddying to eddy-present and eddy-rich. However, the circulation remains too shallow compared to observations for most models, and this, together with temperature biases, cause the northward heat transport to be too low for a given overturning strength.

In the period 2015-2050, the overturning circulation tends to decline more rapidly in the higher resolution models by more than 20% compared to the control state, which is related to both themean state and to the subpolar gyre contribution to deep water formation. The main part of the decline comes from the Florida Current component of the circulation.

How to cite: Iovino, D., Roberts, M. J., Jackson, L. C., Roberts, C. D., Meccia, V., Docquier, D., Koenigk, T., Ortega, P., Moreno-Chamarro, E., Bellucci, A., Coward, A., Drijfhout, S., Exarchou, E., Gutjahr, O., Hewitt, H., Lohmann, K., Schiemann, R., Seddon, J., Terray, L., and Xu, X. and the iHESP group members: Sensitivity of the Atlantic Meridional Overturning Circulation to Model Resolution in CMIP6 HighResMIP Simulations , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18216, https://doi.org/10.5194/egusphere-egu2020-18216, 2020.

EGU2020-18254 | Displays | AS1.2

Does accounting for the direct-radiative effect of prognostic aerosols improve 5-day temperature forecast of the ECMWF weather forecast model ?

Johannes Flemming, Alessio Bozzo, Jerome Barre, Richard Engelen, Sebastien Garrigues, Robin Hogan, Vincent Huijnen, Antje Inness, Zak Kipling, Mark Parrington, Samuel Remy, Ivan Tsonevsky, and Vincent-Herni Peuch

The Copernicus Atmosphere Monitoring Service (CAMS) produces operationally global 5-day forecast of atmospheric composition and the weather using ECMWF’s Integrated Forecasting System (IFS) since 2015.Beginning with a system upgrade in June 2018 (45r1), the ozone and aerosol fields have been used in the radiation scheme to account for their radiative impact in the global CAMS forecasts. This approach replaced an aerosol and ozone climatology, which had been used before and which is still used in ECMWF's operational high-resolution medium-range NWP forecasts. The CAMS forecast system, which runs at a resolution of about 40 km, is applied here as a test-bed to explore the importance of aerosol direct feedback in an operational configuration, which can guide developments on composition-weather feedbacks for ECMWF's medium-range, monthly and seasonal forecasts.

We will discuss the changes and improvements of temperature forecast errors (i) using typical NWP scores and (ii) by applying an event based approach that focuses on episodes of high aerosol burdens such as the transport of Sahara dust to Europe during the heatwave in June 2019. In more detail we will show to what extent the realism of the prognostic aerosol fields influences the temperature response by considering aerosol forecast which were, or were not, improved by data assimilation of aerosol optical depth at the start of the forecast. We will further demonstrate that the consistent updates of both the climatological and prognostic aerosol fields are an important prerequisite for a making progress.

How to cite: Flemming, J., Bozzo, A., Barre, J., Engelen, R., Garrigues, S., Hogan, R., Huijnen, V., Inness, A., Kipling, Z., Parrington, M., Remy, S., Tsonevsky, I., and Peuch, V.-H.: Does accounting for the direct-radiative effect of prognostic aerosols improve 5-day temperature forecast of the ECMWF weather forecast model ?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18254, https://doi.org/10.5194/egusphere-egu2020-18254, 2020.

EGU2020-19344 | Displays | AS1.2

Global simulations of the atmosphere at 1.45 km grid-spacing with the Integrated Forecasting System

Peter Düben, Nils Wedi, Sami Saarinen, and Christian Zeman

Global simulations with 1.45 km grid-spacing are presented that were performed with the Integrated Forecasting System (IFS) of the European Centre for Medium-Range Weather Forecasts (ECMWF). Simulations are uncoupled (without ocean, sea-ice or wave model), using 62 or 137 vertical levels and the full complexity of weather forecast simulations including recent date initial conditions, real-world topography, and state-of-the-art physical parametrizations and diabatic forcing including shallow convection, turbulent diffusion, radiation and five categories for the water substance (vapour, liquid, ice, rain, snow). Simulations are evaluated with regard to computational efficiency and model fidelity. Scaling results are presented that were performed on the fastest supercomputer in Europe - Piz Daint (Top 500, Nov 2018). Important choices for the model configuration at this unprecedented resolution for the IFS are discussed such as the use of hydrostatic and non-hydrostatic equations or the time resolution of physical phenomena which is defined by the length of the time step. 

Our simulations indicate that the IFS model — based on spectral transforms with a semi-implicit, semi-Lagrangian time-stepping scheme in contrast to more local discretization techniques — can provide a meaningful baseline reference for O(1) km global simulations.

How to cite: Düben, P., Wedi, N., Saarinen, S., and Zeman, C.: Global simulations of the atmosphere at 1.45 km grid-spacing with the Integrated Forecasting System, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19344, https://doi.org/10.5194/egusphere-egu2020-19344, 2020.

EGU2020-19869 | Displays | AS1.2

An enhanced river routing scheme for the closure of global water budget

Stefano Materia, Daniele Peano, Marianna Benassi, Tomas Lovato, Silvio Gualdi, Annalisa Cherchi, Andrea Alessandri, and Antonio Navarra

Large-scale river routing schemes are essential to close the hydrological cycle in fully coupled Earth System Models (ESMs). The availability of a realistic water flow is a powerful instrument to evaluate modeled land surface, a crucial component of the global climate whosproperties are often simplified by heavy parameterization, due to lack of process knowledge and validation data. We built up a new concept of river routing model, named HYDROS (HYdro-Dynamic ROuting Scheme), that replaces the present scheme embedded in the CMCC-CM2 global coupled model. The new scheme aims at overcoming one of the current major limitations, that is the use of time-independent flow velocities parameterized as a function of topography. Through the imposition of hydraulic equations, HYDROS defines a time-varying flow velocity associated with the amount of lateral runoff generated by the ESM's land component and the flow through the river system. Compared to the scheme currently in place, HYDROS show improvements in the simulation of mean annual discharge phase, especially for the Arctic rivers and the Amazon. In the Mississippi case, an extreme flood episode is better caught by the new representation, indicating that the improved flow velocity better catches the discharge peaks after extreme rainfalls. The new routing model is not able to improve the volumes of simulated river discharge, whose magnitude depends on the ability of the ESM land surface scheme to generate correct surface and sub-surface runoff. Once implemented in coupled mode, HYDROS will guarantee a plausible amount and timing of freshwater discharge into the global ocean, unveiling possible unresolved feedback mechanisms occurring in proximity of river mouths.

How to cite: Materia, S., Peano, D., Benassi, M., Lovato, T., Gualdi, S., Cherchi, A., Alessandri, A., and Navarra, A.: An enhanced river routing scheme for the closure of global water budget, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19869, https://doi.org/10.5194/egusphere-egu2020-19869, 2020.

EGU2020-22676 | Displays | AS1.2

Compatible finite element methods and parallel-in-time schemes for numerical weather prediction.

Jemma Shipton, Colin Cotter, Tom Bendall, Thomas Gibson, Lawrence Mitchell, David Ham, and Beth Wingate

I will describe Gusto, a dynamical core toolkit built on top of the Fire- drake finite element library; present recent results from a range of test cases and outline our plans for future code development.

Gusto uses compatible finite element methods, a form of mixed finite element methods (meaning that different finite element spaces are used for different fields) that allow the exact representation of the standard vector calculus identities div-curl=0 and curl-grad=0. The popularity of these methods for numerical weather prediction is due to the flexibility to run on non-orthogonal grid, thus avoiding the communication bottleneck at the poles, while retaining the necessary convergence and wave propagation prop- erties required for accuracy.

Although the flexibility of the compatible finite element spatial discreti- sation improves the parallel scalability of the model it does not solve the parallel scalability problem inherent in spatial domain decomposition: we need to find a way to perform parallel calculations in the time domain. Ex- ponential integrators, approximated by a near optimal rational expansion, offer a way to take large timesteps and form the basis for parallel timestep- ping schemes based on wave averaging. I will describe the progress we have made towards implementing these schemes in Gusto.

How to cite: Shipton, J., Cotter, C., Bendall, T., Gibson, T., Mitchell, L., Ham, D., and Wingate, B.: Compatible finite element methods and parallel-in-time schemes for numerical weather prediction., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22676, https://doi.org/10.5194/egusphere-egu2020-22676, 2020.

AS1.3 – Forecasting the weather

EGU2020-3521 | Displays | AS1.3 | Highlight

Analysis and nowcasting of deep convective systems over Germany in multi-source data

Isabella Zöbisch, Caroline Forster, Tobias Zinner, and Kathrin Wapler

By using a multi-source data set consisting of high resolution satellite, radar, lightning, and model data this study presents the analysis of characteristics of deep convective systems over Germany and first results of a new model to predict the remaining lifetime of existing thunderstorms. Contrary to previous studies, the analysis was performed for the full mixture of observed convective systems regardless of their organization type, since our focus is an operational forecasting environment where no simple method is available to differentiate organization types. Basis for the study are all deep convective cell detections in satellite data (using Cb-TRAM, Thunderstorm Tracking and Monitoring) in a five month period (June 2016, May, June, and July 2017, and June 2018). The lifetimes of all cells are normalized, averaged and separated into life cycle phases to investigate the behavior of the parameters from the different data sources during the detected lifetime. Furthermore, the thunderstorm cells are sorted by their lifetime to determine differences between the characteristics of long- and short-lived convective systems. Parameters with predictive skill are then combined with fuzzy logic to determine the actual stage of a thunderstorm, and to nowcast its remaining lifetime. It will be shown that the new lifetime prediction model contributes to an improvement of the thunderstorm nowcasting.

How to cite: Zöbisch, I., Forster, C., Zinner, T., and Wapler, K.: Analysis and nowcasting of deep convective systems over Germany in multi-source data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3521, https://doi.org/10.5194/egusphere-egu2020-3521, 2020.

EGU2020-1656 | Displays | AS1.3 | Highlight

Advances in the Study of Severe Convection Weather Nowcasting in Central China

Chunguang Cui, Yanjiao Xiao, Anwei Lai, and Muyun Du

Based on the characteristics of sudden and local, short life history, serious disasters and so on, the severe convection weather system is difficult to be captured by the conventional meteorological observation network, and is still challenging for catastrophic weather forecasting. In order to improve the service ability in strong weather monitoring and prediction, the following researches have been carried out recently: (1) The new mesocyclone and tornado vortex feature recognition algorithms are developed and proved to be successfully in identifying tornado vortex characteristics in more than a dozen tornado cases. Extracted from Doppler radar volume scan data, a number of parameters (exceed thirty) have been used in the research on the automatic recognition and warning technology of classified severe convective weather (downburst, tornado, hail and short-time strong precipitation). Based on large sample data and results of a variety of analysis methods, a thunderstorm winds Bayes discriminant model has also been established. The testing results show that its Heidke skill score is 0.836, along with the accuracy rate and hit rate are greater than 95%, and the empty rate is below 5%. (2) Rapid update cycle forecast system can effectively improve the quality of model initial values that is very suitable for short time forecast application. For the sake of improving severe thunderstorm prediction, a novel pseudo-observation and assimilation approach involving water vapor mass mixing ratio is proposed to better initialize numerical weather prediction (NWP) at convection-resolving scales. In addition, a new set of simplified and parameterized dual-polarization radar simulators for horizontal reflectivity (ZH), differential reflectivity (ZDR), specific difference phase (KDP), and correlation coefficient (ρHV) have been co-developed, and some preliminary data assimilation experiments have shown that the assimilation of dual polarization variables including differential reflectivity and specific difference phase in addition to radar radial velocity and horizontal reflectivity can help improve the accuracy of initial conditions for model hydrometer variables and ensuing model forecasts. (3) Although not yet mature enough for meteorological application, blending technology which is expected to overcome the deficiency of the quantitative precipitation (QPF) by a mesoscale NWP model for the short term at convective scales and the rapidly descending skill of rainfall forecast based on radar extrapolation method beyond the first few hours is under development and debugging, and also has potential in enhancing the ability of rainfall forecast within the nowcasting period. (4) The above methods and systems were applied and provided technical support for meteorological services during the 7th Wuhan World Military Games in 2019, and a good service effect had been achieved.

How to cite: Cui, C., Xiao, Y., Lai, A., and Du, M.: Advances in the Study of Severe Convection Weather Nowcasting in Central China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1656, https://doi.org/10.5194/egusphere-egu2020-1656, 2020.

EGU2020-5681 | Displays | AS1.3 | Highlight

Precipitation nowcasting using spatiotemporal models and volumetric radar data

Seppo Pulkkinen, Chandrasekaran Venkatachalam, and Annakaisa von Lerber

Nowcasts (short-range forecasts) of rainfall can be used for providing early warning of flash floods. Thus, they are of high societal importance especially in densely populated urban areas. Weather radars are ideally suited for this purpose due to their good spatial coverage and high spatial and temporal resolution (e.g. 1 km and 5 minutes).

A novel approach to radar-based rainfall nowcasting is proposed. The forecast model consists of two components: horizontal advection and temporal evolution of rainfall intensities. The advection velocities are estimated from radar-measured rain rate fields using a pattern matching method. A smooth advection field is obtained by interpolating the motion to areas with no precipitation. The extrapolation is done using a semi-Lagrangian scheme.

The temporal evolution of rainfall intensities is described in Lagrangian coordinates by using a spatiotemporal process model. Such models are ubiquitous in environmental and physical sciences. This study presents the first attempt to apply such a model to three-dimensional rainfall measurements to capture the vertical structure of rainfall processes. This is done by using a linear integro-differential equation with the Markovian assumption (i.e. the next time step depends conditionally on the previous one). Spatial dependencies are modeled via a convolution kernel. To reduce the dimensionality of the parameter estimation, the kernel is parametrized by a trivariate Gaussian function, and the model is formulated and implemented in the Fourier domain. Finally, the parameter estimation is done in the Bayesian framework by applying a Markov Chain Monte Carlo (MCMC) method with Gibbs sampling.

The operational feasibility of the proposed model is evaluated by using data from the NEXRAD WSR-88D radar deployed in Fort Worth, Texas. Measurements from 14 elevation angles are used by restricting the analyses to liquid precipitation below the melting layer. The data processing chain consists of 1) temporal interpolation within radar volumes, 2) clutter filtering, 3) attenuation correction, 4) melting layer detection, 5) polarimetric rain rate estimation based on reflectivity, specific differential phase and differential reflectivity and 6) interpolation to a three-dimensional grid.

The focus of the validation is on higher rain rates (> 5 mm/h) using 10 events during 2018-2019 with mixed convective and stratiform rainfall. Predicted rain rates from the nowcasting model are compared to observations from low-angle radar scans. Using standard verification scores (e.g. equitable threat score and mean absolute error), it is shown that for rainfall rates between 5-25 mm/h, the proposed method can yield up to 30% improvement compared to state of the art extrapolation nowcasting methods. This is attributed to using the spatiotemporal model and vertical profile information obtained from three-dimensional input data.

How to cite: Pulkkinen, S., Venkatachalam, C., and von Lerber, A.: Precipitation nowcasting using spatiotemporal models and volumetric radar data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5681, https://doi.org/10.5194/egusphere-egu2020-5681, 2020.

EGU2020-13272 | Displays | AS1.3 | Highlight

Nowcasting lightning during RELAMPAGO

Evan Ruzanski, Venkatachalam Chandrasekar, and Ivan Arias

The Remote Sensing of Electrification, Lightning, and Mesoscale/Microscale Processes with Adaptive Ground Observations (RELAMPAGO) international field campaign occurred June 1, 2018, to April 30, 2019. This campaign was comprised of more than 150 scientists from 10 organizations. Data was collected to investigate different phases of the life cycle of thunderstorms that occur in Argentina to better understand the physical mechanisms that cause the initiation and growth of organized convective systems in some of the most intense storms on the planet. The main focus of the project was to develop new conceptual models for forecasting extreme weather events that will hopefully lead to reductions in future loss of life and property.

This presentation shows the performance of a recently developed model for estimating ice mass aloft, a key component in the atmospheric electrification process, and a method for nowcasting lightning activity using C-band weather radar and Global Lightning Dataset (GLD360) data from RELAMPAGO. This nowcasting method uses a grid-based approach to make specific forecasts of lightning in space and time. The method estimates ice mass aloft in the region where electrification occurs using a numerical optimization approach to essentially reframe a simplified bulk microphysical model into a completely data-driven model. Previous results using WSR-88D S-band radar data in the United States showed that using this model significantly improved nowcasts of first-flash lightning occurrence versus the traditional weather radar-based ice mass estimator as well as using lightning flash-rate density directly.

How to cite: Ruzanski, E., Chandrasekar, V., and Arias, I.: Nowcasting lightning during RELAMPAGO, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13272, https://doi.org/10.5194/egusphere-egu2020-13272, 2020.

EGU2020-13376 | Displays | AS1.3

Comparing four radar rainfall nowcasting algorithms for 1481 events

Ruben Imhoff, Claudia Brauer, Aart Overeem, Albrecht Weerts, and Remko Uijlenhoet

Accurate and timely hydrological forecasts highly depend on their meteorological input. Current numerical weather predictions (NWP) do not have sufficiently high spatial and temporal resolutions for adequate use for short lead times (less than six hours ahead) in fast-responding mountainous, lowland and polder catchments. Therefore, radar rainfall nowcasting, the process of statistically extrapolating the most recent radar rainfall observation, is increasingly used. However, as most studies consist of analyses based on a relatively small sample of generally 2–15 events, best practices for the use and choice of these algorithms within operational forecasting systems are not yet available. In this study, we aim to determine the predictive skill of radar rainfall nowcasting algorithms for the short-term predictability of rainfall, in which we focus on different lowland catchments in the Netherlands. We concentrate particularly on the dependency of the forecast skill on catchment and environmental characteristics, such as event type and duration, seasonality, catchment size and location with regard to the radar location and prevailing wind direction. For this purpose, we performed a large-sample analysis of 1481 events spread over four event durations and twelve lowland catchments (6.5–957 km2). Four algorithms were tested and compared with Eulerian Persistence: Rainymotion Sparse and DenseRotation, pySTEPS deterministic and pySTEPS probabilistic with 20 ensemble members. Maximum skillful lead times increased for longer event durations, due to the more persistent character of these events. In all cases, pySTEPS deterministic attained the longest maximum skillful lead times: 25 min for 1-h, 39 min for 3-h, 56 min for 6-h and 116 min for 24-h durations. During winter, when more persistent stratiform precipitation is present, we found three times lower mean absolute errors than for nowcasts during summer with more convective precipitation. For the fractions skill score, higher skill was obtained with increasing grid cell sizes. This was advantageous for larger catchments, whereas some catchments became smaller than the grid size after upscaling. Catchment location mattered as well: up to two times higher skillful lead times were found downwind of the radars than upwind, given the prevailing wind direction. The pySTEPS algorithms outperformed Rainymotion benchmark algorithms due to rainfall field evolution estimations with cascade decomposition and an autoregressive model. We found that most errors still originate from growth and dissipation processes which are not or only partially (stochastically) accounted for.

How to cite: Imhoff, R., Brauer, C., Overeem, A., Weerts, A., and Uijlenhoet, R.: Comparing four radar rainfall nowcasting algorithms for 1481 events, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13376, https://doi.org/10.5194/egusphere-egu2020-13376, 2020.

This study uses C-band polarimetric radar (C-POL) measurements to classify the hydrometeors and retrieve rain drop size distributions (DSDs) during the IMFRE (Investigative Monsoon Frontal Rainfall Experiment) field campaign in central China.  Three types of precipitation in a Meiyu frontal heavy rainfall case are classified to further investigate the microphysical characteristics and processes based on C-POL observations and classified hydrometeors. When raindrops fall from the freezing level, collision–coalescence plays an equally important role as break-up and/or evaporation in stratiform regions, but is the dominant process for convective-related precipitation and is an attribute of intensive precipitation. There are more supercooled liquid water droplets above the freezing level in convective cores due to strong updrafts, which can bring more cloud droplets into the upper levels to help the formation of graupel and hail. To the best of our knowledge, this work is the first time that C-POL-classified hydrometeors and rain-parameter retrievals have been validated against in-situ aircraft and surface disdrometer measurements over the middle reaches of the Yangtze River Valley in central China, which will pave the way for future studies related to Meiyu frontal rainfall systems.

How to cite: Wang, B., Dong, X., Fu, Z., and Zhou, L.: Investigation of Hydrometeors Using a C-band Poloarimetric Radar and In-situ Measurements during IMFRE in Central China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1657, https://doi.org/10.5194/egusphere-egu2020-1657, 2020.

EGU2020-2512 | Displays | AS1.3

Vertical Structures of Typical Meiyu Precipitation Events Retrieved from GPM‐DPR

Yuting Sun, Xiquan Dong, Wenjun Cui, Zhimin Zhou, Zhikang Fu, Lingli Zhou, Yi Deng, and Chunguang Cui

The majority of heavy rainfall and flooding events in the central China during the Meiyu season are caused by the multi-scale monsoon frontal systems. However, there are limited studies of the vertical distributions of monsoon frontal rainfall. This work for the first time analyzed the vertical structures of the different stages of Meiyu precipitation systems over the Yangtze‐Huai River Valley in central China using measurements and retrievals from the Global Precipitation Measurement Mission Dual‐Frequency Precipitation Radar (GPM‐DPR) and Feng Yun satellites. GPM‐DPR retrieved near‐surface rain and drop size distributions were first validated against the surface disdrometer measurements and showed good agreement. Then we analyzed three cases from the Integrative Monsoon Frontal Rainfall Experiment to demonstrate the different characteristics of convective precipitation (CP) and stratiform precipitation (SP) in the developing, mature, and dissipating stages of the Meiyu precipitation systems, respectively. For statistical analysis, all Meiyu cases during the period 2016–2018 detected by GPM‐DPR were collected and classified into different types and stages. In the stratiform regions of Meiyu precipitation systems, coalescence slightly overwhelms break‐up and/or evaporation processes, but it was dominant in the convective regions when raindrops fall. There were large numbers of large ice particles during the developing stage due to strong updrafts and abundant moisture, whereas there were both large ice and liquid particles in the mature stage. The vertical structures of the SP examined in this study were similar to those over the ocean regions due to high relative humidity but different to the mountainous west regions of the USA. The findings of the stage‐dependent SP vertical structures provide better understanding of the evolution of monsoon frontal precipitation, as well as the associated microphysical properties, and provide insights to improve microphysical parameterization in future models.

How to cite: Sun, Y., Dong, X., Cui, W., Zhou, Z., Fu, Z., Zhou, L., Deng, Y., and Cui, C.: Vertical Structures of Typical Meiyu Precipitation Events Retrieved from GPM‐DPR, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2512, https://doi.org/10.5194/egusphere-egu2020-2512, 2020.

EGU2020-22584 | Displays | AS1.3 | Highlight

Recent developments in the INCA analysis and nowcasting system

Benedikt Bica, Jasmina Hadzimustafic, Aitor Atencia, Martin Kulmer, Brigitta Hollosi, Stefan Schneider, Alexander Kann, and Yong Wang

The high-resolution INCA system (Integrated Nowcasting through Comprehensive Analysis) provides gridded analyses and short-term forecasts of meteorological fields at a horizontal resolution of 1 km and at 5 to 60 min temporal resolution. After the nowcasting part, INCA fields are blended into AROME or a statistically optimized combination of NWP models, thus providing a seamless chain of forecasting fields at various scales. As an operational product of the national Austrian weather service (ZAMG), INCA is employed for a number of applications, such as for hydrological runoff modelling, severe weather warnings, in road safety, agriculture and in the renewable energy sector. The product development is embedded into the research activities of the last year period which, amongst others, included the development of new blending methods into the state of the art NWP models, a new approach for precipitation analysis and nowcasting as well as the evaluation of wind, temperature and humidity analyses at 100 m horizontal resolution. For precipitation, a new radar-raingauge merging algorithm has been developed, which is based on station density and radar minimum beam height. Precipitation nowcasting uses optical flow and nested subdomains for breaking down the displacement vectors to the target grid. In the sub-kilometer version, the improvements due to the topography-relevant features (i.e. altitude, slope) in Alpine areas are shown as well as the potential benefits of high resolution nowcasting in urban areas. The methods and related results will be presented along with a comprehensive verification.

How to cite: Bica, B., Hadzimustafic, J., Atencia, A., Kulmer, M., Hollosi, B., Schneider, S., Kann, A., and Wang, Y.: Recent developments in the INCA analysis and nowcasting system, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22584, https://doi.org/10.5194/egusphere-egu2020-22584, 2020.

EGU2020-5447 | Displays | AS1.3

Towards Operational Downscaling of Low Resolution Wind Fields using Neural Networks

Michael Kern, Kevin Höhlein, Timothy Hewson, and Rüdiger Westermann

Numerical weather prediction models with high resolution (of order kms or less) can deliver very accurate low-level winds. The problem is that one cannot afford to run simulations at very high resolution over global or other large domains for long periods because the computational power needed is prohibitive.

Instead, we propose using neural networks to downscale low-resolution wind-field simulations (input) to high-resolution fields (targets) to try to match a high-resolution simulation. Based on short-range forecasts of wind fields (at the 100m level) from the ECMWF ERA5 reanalysis, at 31km resolution, and the HRES (deterministic) model version, at 9km resolution, we explore two complementary approaches, in an initial “proof-of-concept” study.

In a first step, we evaluate the ability of U-Net-type convolutional neural networks to learn a one-to-one mapping of low-resolution input data to high-resolution simulation results. By creating a compressed feature-space representation of the data, networks of this kind manage to encode important flow characteristics of the input fields and assimilate information from additional data sources. Next to wind vector fields, we use topographical information to inform the network, at low and high resolution, and include additional parameters that strongly influence wind-field prediction in simulations, such as vertical stability (via the simple, compact metric of boundary layer height) and the land-sea mask. We thus infer weather-situation and location-dependent wind structures that could not be retrieved otherwise.

In some situations, however, it will be inappropriate to deliver only a single estimate for the high-resolution wind field. Especially in regions where topographic complexity fosters the emergence of complex wind patterns, a variety of different high-resolution estimates may be equally compatible with the low-resolution input, and with physical reasoning. In a second step, we therefore extend the learning task from optimizing deterministic one-to-one mappings to modelling the distribution of physically reasonable high-resolution wind-vector fields, conditioned on the given low-resolution input. Using the framework of conditional variational autoencoders, we realize a generative model, based on convolutional neural networks, which is able to learn the conditional distributions from data. Sampling multiple estimates of the high-resolution wind vector fields from the model enables us to explore multimodalities in the data and to infer uncertainties in the predictand.

In a future customer-oriented extension of this proof-of-concept work, we would envisage using a target resolution higher than 9km - say in the 1-4km range - to deliver much better representivity for users. Ensembles of low resolution input data could also be used, to deliver as output an “ensemble of ensembles”, to condense into a meaningful probabilistic format for users. The many exciting applications of this work (e.g. for wind power management) will be highlighted.

How to cite: Kern, M., Höhlein, K., Hewson, T., and Westermann, R.: Towards Operational Downscaling of Low Resolution Wind Fields using Neural Networks, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5447, https://doi.org/10.5194/egusphere-egu2020-5447, 2020.

EGU2020-10463 | Displays | AS1.3

Post-processing for NWP Outputs Based on Machine Learning for 2022 Winter Olympics Games over Complex Terrain

Kang Yanyan, Li Haochen, Xia Jiangjiang, and Zhang Yingxin

    Weather forecasts play an important role in the Olympic game,especially the mountain snow projects, which will help to find a "window period" for the game. The winter Olympics track is located on very complex terrain, and a detailed weather forecast is needed. A Post-processing method based on machine learning is used for the future-10-days weather prediction with 1-km spatial resolution and 1-hour temporal resolution, which can greatly improve accuracy and refinement of numerical weather prediction(NWP). The ECWMF/RMAPS model data and the automatic weather station data(AWS) from 2015-2018 are prepared for the training data and test data, included 48 features and 4 labels (the observed 2m temperature, relative humidity , 10m wind speed and wind direction ). The model data are grid point, while the AWS data are station point. We take the nearest 9 model point to predict the station point, instead of making an interpolation between the grid point and station point. Then the feature number will be 48*9 in dataset. The interpolation error from grid point to station is eliminated,and the spatial distribution is considered to some extent. Machine leaning method we used are SVM, Random Forest, Gradient Boosting Decision Tree(GBDT) and XGBoost. We find that XGBoost method performs best, slightly better than GBDT and Random Forest. It is noted that we did some feature engineering work before training, and we found that it’s not that the more features, the better the model, while 10 features are enough. Also there is an interesting thing that the features that closely related the labels values becomes less important as the forecast time increases,such as the model outputed 2m temperature, 10m wind speed and wind direction. While some features that forecasters don’t pay attention to become more important in the 6-10 days prediction, such as latent heat flux, snow depth and so on. So it’s necessary to train the model based on dynamic weight parameters for different forecast time. Through the post-processing based on the machine learning method, the forecast accuracy has been greatly improved compared with EC model. The averaged forecast accuracy of 0-10 days for 2m relative humidity, 10m wind speed and direction has been increased by almost 15%, and the temperature accuracy has been increased by 20%~40% ( 40% for 0-3 days, and the accuracy decreased with the forecast time ). 

How to cite: Yanyan, K., Haochen, L., Jiangjiang, X., and Yingxin, Z.: Post-processing for NWP Outputs Based on Machine Learning for 2022 Winter Olympics Games over Complex Terrain, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10463, https://doi.org/10.5194/egusphere-egu2020-10463, 2020.

EGU2020-15011 | Displays | AS1.3 | Highlight

Interactive 3D visual analysis in weather forecasting

Marc Rautenhaus, Timothy Hewson, Kameswar Rao Modali, Andreas Beckert, and Michael Kern

Visualization of numerical weather prediction data and atmospheric observations has always been an important and ubiquitous tool in weather forecasting. Visualization research has made much progress in recent years, in particular with respect to techniques for ensemble data, interactivity, 3D depiction, and feature-detection. Transfer of new techniques into weather forecasting, however, is slow.

In this contribution, we will discuss the potential of recent developments in 3D and ensemble visualization research for weather forecasting. We will introduce our work on 3D feature-detection methods for jet-stream and front features, which facilitate analysis of the evolution of jet-stream core lines and frontal surfaces in an (ensemble) forecast. The techniques have been integrated into the 3D visual ensemble analysis framework Met.3D (https://met3d.wavestoweather.de), in which they can be combined with traditional 2D depictions as well as further 3D visual elements and be displayed in an interactive 3D context. We will present and discuss 3D ensemble forecast products created with Met.3D based on forecast data from ECMWF and DWD, and demonstrate their use in the exploration of example cases including an extratropical transition over the North Atlantic and a European winter storm.

In addition, we will introduce new semi-operational 3D forecast products based on our techniques that we provide experimentally on the web, in order to gather user feedback and to initiate discussion about potential benefit of such products for operations.

How to cite: Rautenhaus, M., Hewson, T., Modali, K. R., Beckert, A., and Kern, M.: Interactive 3D visual analysis in weather forecasting, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15011, https://doi.org/10.5194/egusphere-egu2020-15011, 2020.

EGU2020-5031 | Displays | AS1.3

A High-Resolution, Model-Based Lightning Risk Map for Turkey

Mustafa Yağız Yılmaz, Ozan Mert Göktürk, and Güven Fidan

Lightning strikes from convective storms are a serious safety concern for public and businesses alike. Accurate assessment of local lightning risk is therefore crucial for various industries. However, it is usually not possible to obtain lightning climatologies with reasonable spatial detail, due to the scarcity of well distributed, long term observations. At this respect, meteorological models serve as a useful tool for creating lightning risk maps, provided that their output can be verified with available observations. In this study, a high resolution (3 km) lightning risk map has been constructed for Turkey, using output from Weather Research and Forecasting Model (WRF). The model was forced by the ECMWF’s ERA-5 reanalysis data, and run for the period of January 2014 – December 2018 (5 years). Simulations were conducted on high-performance computers offered by Amazon Web Services. Lightning flash rates were estimated from WRF output using the parameterization scheme proposed by McCaul et al. (2009). Model-derived lightning rates have been calibrated and validated by observed lightning data for the determined region. The spatial pattern and average rate of lightning flashes over the validation region have been found to agree reasonably well with available observations. The high resolution lightning risk map produced in this study is the first one for Turkey that is based on numerical modeling, and it will serve as an objective guidance for location-based lightning risk assessment in the country.

How to cite: Yılmaz, M. Y., Göktürk, O. M., and Fidan, G.: A High-Resolution, Model-Based Lightning Risk Map for Turkey, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5031, https://doi.org/10.5194/egusphere-egu2020-5031, 2020.

As the grid resolution continues to increase, it is essential to utilize more data to describe the occurrence and evolution of mesoscale system more precisely. Based on Local Analysis and Prediction System (LAPS), NCEP reanalysis data (FNL) is used as the background field. By improving and developing LAPS, a high spatial-temporal resolution mesoscale data is generated and a sample database is established by fusing a variety of observation data.

Moreover, the synoptic and physical variables that may affect the short- duration heavy precipitation are fully considered when establishing the diagnosis-statistical forecast model. After the calculation, three discriminant formulas of strong and weak precipitation, heavy precipitation classification I and II are obtained.

Furthermore, the grouping accuracy of the discriminant formula and Ts score were calculated, and after the independent sample test and typical case test, it can be concluded that these discriminant formulas can be used to distinguish strong and weak precipitation and heavy precipitation classification.

How to cite: Ke, D., Wang, X., and Cui, C.: Characteristics and classifications of short-duration heavy precipitation in mesoscale system evolution, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7810, https://doi.org/10.5194/egusphere-egu2020-7810, 2020.

EGU2020-1856 | Displays | AS1.3

Preliminary study on terrain uncertainty and its perturbing scheme

Li jun, Du jun, Liu yu, and Xu jianyu

1.Introduction

A key issue in developing the ensemble prediction technique is the recognition of uncertain factors in numerical forecasting and how to use appropriate perturbation techniques to reflect these uncertain processes and improve ensemble prediction levels.Plenty of corresponding perturbation techniques have been developed. Such as Initial uncertainty and model uncertainty,In addition to the influence of IC and model uncertainty ,precipitation is closely related to terrain.The influence of terrain on the heavy rain includes the following three aspects:(1) The terrain has significant effect on the climatic distribution of precipitation.(2)The windward slope and leeward slope and other dynamic effects generated by terrain impact the triggering and intensity of precipitation.(3)The thermal effect is triggered by the heating of land surface of terrain at different height and latent heat release when airflow rises ,and this thermal action makes mountain precipitation closely related to terrain distribution .What are the terrain uncertainties in the model?(1)Different vertical coordinate systems lead to significant differences in terrain treatment(2)The conversion from real terrain to model terrain is closely associated with the resolution of the model and different terrain interpolation schemes, and it affects the simulation results of precipitation .(3)Measuring error of real terrain, etc.In this report, A terrain perturbation scheme (ter) has been firstly incorporated into an ensemble prediction system (EPS) and preliminarily tested in the simulation of the extremely heavy rain event occurred on 21 July, 2012 in Beijing, along with other three perturbation schemes.

2.Case,data and schemes

(1)Case: Based on the extremely heavy rain case in Beijing on July 21,2012, maximum precipitation center more than 400mm.(2)Data: GEPS of NCEP were used as initial background fields and lateral boundary condition , surface and upper-level observation of GTS,Rain gauge etc.(3)Model: WRFv4.3, 9km horizontal resolution ,511*511 grid point, 51 vertical layers,KF Eta,WSM6,etc(4)Experiments schemes: Four different perturbation schemes were used in the experiments and six members in each experiment. Sch_1(IC) considered the IC uncertainty ,the parameterization schemes were same but IC/LBC came from different GEPS members. Sch_2(phy) considered the Phy uncertainty ,the IC/LBC were same but PHY schemes were comprised of different parameterization schemes. Sch_3-4(ter and icter) considered the terrain uncertainty ,the second aspect of terrain uncertainty was considered in this study. Two different model terrain smoothing schemes and 3 terrain interpolation schemes were used to reflect the forecast error caused by terrain height. Icter is the mixed scheme of ter and ic.

3.Preliminary test and results

(1)Precipitation is closely related to terrain, terrain uncertainties have significant effect on the intensity and falling area of precipitation.(2) Only a simple terrain perturbation can produce a significant forecast spread , and its ensemble mean forecast is also improved compared with control forecast. for this case, it has a slightly positive contribution to the spread and probability forecast of precipitation on the basis of not impacting the quality of ensemble mean forecast.(3) In this case, the magnitude of spread generated by the terrain perturbation scheme is significantly smaller than that generated by the initial perturbation and physics process perturbation schemes.

How to cite: jun, L., jun, D., yu, L., and jianyu, X.: Preliminary study on terrain uncertainty and its perturbing scheme, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1856, https://doi.org/10.5194/egusphere-egu2020-1856, 2020.

EGU2020-1293 | Displays | AS1.3

The variational echo tracking method and its application in convective storm nowcasting

Jiankun Wu, Mingxuan Chen, Rui Qin, Feng Gao, and Linye Song

The objective extrapolation forecast is the main method for 0-1 hour convective storm nowcasting. Radar echo extrapolation was performed by using the 6 minute interval radar mosaics obtained from the radar images of 8 multi-radars in Beijing-Tianjin-Hebei region. A comparative study of two extrapolated forecasts of eighteen typical convective precipitation events occurred in Beijing-Tianjin-Hebei region from 2016 to 2018 was conducted. Compared with the tracking radar echoes by correlation method, the variational echo tracking method utilizes variational technique to compute the motion vector fields, and uses two strict constraints to get a better motion vector field. The results indicated that the variational echo tracking method performed better in prediction of the radar echo pattern, echo location, and echo intensity at 30- and 60-min forecast lead times: 1) A comparative study of the two extrapolated forecasts of four precipitation events in Beijing-Tianjin-Hebei region was conducted. The result indicated that the radar echo location, the echo pattern and echo intensity produced by the variational echo tracking method were closer to the real observation within one hour. 2) Quantitative evaluation for the two extrapolated forecasts of the eighteen typical convective precipitation events was conducted. Compared with the tracking radar echoes by correlation method, the probability of detection and the critical success index of the 30- or 60-min extrapolated forecast produced by the variational echo tracking method were higher, meanwhile the false alarm rate was lower when the radar echo threshold was 35dBz and 45dBz. Also, a quantitative evaluation classified by the weather type indicated that the variational echo tracking method performed better than the tracking radar echoes by correlation method in most weather types.

How to cite: Wu, J., Chen, M., Qin, R., Gao, F., and Song, L.: The variational echo tracking method and its application in convective storm nowcasting, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1293, https://doi.org/10.5194/egusphere-egu2020-1293, 2020.

The Ili Valley is an area with frequent heavy rain in Xinjiang. In this paper, a heavy rainstorm process in this area on June 26, 2015 is taken as an example. The observational data and WRF high-resolution numerical simulation results are used to analyze the synoptic background and the process of the precipitation. The results show that: (1) The Central Asian low vortex and the upper-level jet provides a favorable circulation background for this heavy rain. Northerly winds and westerly winds forms a low-level convergence line in Ili Valley. (2) In addition to the convergence of low-level airflow, the uplifting effect of the terrain on the westerly winds also intensifies the low-level ascending motion. At the same time, the uplifting effect of the terrain on the northerly winds causes the middle-level ascending motion. After the low-level ascending motion is connected with that of the middle level, precipitation begins to occur. The convection further develops, superimposed with the upwards phase of upper-level wave, and the precipitation increases strongly. (3) Through spectral analysis methods, the characteristics of the upper-level wave are obtained, and the wave is an inertial gravity wave. It is further obtained from the mesoscale three-dimensional Eliassen-Palm (EP) flux that during the period of heavy precipitation, the energy of the upper-level inertial gravity wave is transported down to the low level of the precipitation area. (4) Convective instability plays an important role in the enhancement of the precipitation in the Ili Valley. The analysis of potential divergence further indicates that the convective instability in the precipitation area is mainly caused by the vertical shear part of potential divergence, while the divergence part of the potential divergence can strengthen the convective instability in the leeward slope of the terrain. It indicates that the dynamic and thermodynamic factors are coupled with each other, which affects the precipitation location, intensity and evolution.

How to cite: Huang, X. and Zhou, Y.: Numerical Simulation and Mechanism Analysis of an Extreme Precipitation in Ili Valley, Xinjiang, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1717, https://doi.org/10.5194/egusphere-egu2020-1717, 2020.

Central Asian Vortices (CAVs) are deep cyclonic systems that occur in the Central Asian and are identified at the 500 hPa level. CAVs are significantly associated with many convective events in the Xinjiang province. In order to strengthen the understanding of the mesoscale systems development mechanisms in torrential rain under the influence of CAVs, we analyzes the rainstorm process occurred in the Aksu region that is near the west of Tianshan Mountains, during June 17 to 18, 2013 basing on a variety of data. The results show that the precipitation process occurs under the background of the circulation of the two ridges in a trough over the middle and high latitudes, and the CAV provides favorable large-scale dynamic and water vapor conditions for this rainstorm. The convergence line is the important mesoscale system, which is formed by the superposition of the CAV circulation and the flow stream around the special topography of the west Tianshan Mountains. Due to the difference of thermal properties between the mountain and desert, the slope wind drives convergence line to move and the strong convection developed along the convergence line triggers strong precipitation in the Aksu region. The WRF is able to well simulate not only the location and intensity of the heavy rain but also the evolution of wind field. Preliminary analysis combined with observations and simulation data shows that under the blockage of west Tianshan Mountains, the south wind accumulates and convergences near the valley. As a result, a local convergence line is formed. Meanwhile, with the adjustment of the large-scale circulation situation, especially after the CAV moves to the vicinity of the Aksu area, one part of the westward flow that comes from the south of the vortex turns into northwest wind after crossing the west Tianshan Mountains, and the other part turns into the northeast wind after passing through the Yili Valley, these two flow aggravate the northerly airflow and enhance the intensity of convergence, thereby promote the formation of mesoscale convergence lines and strengthen it. The eastward airflow-induced water vapor accumulates in front of the southern foot of the Tianshan Mountains, and strengthens as the convergence line moves towards southeast with the enhancement of the valley wind at night. Accompanied with the convergence uplift, the accumulation of water vapor at the foot of the mountain promotes the release of unstable energy and brings heavy precipitation to the Aksu region.

How to cite: Guo, N. and Zhou, Y.: Analysis of a severe precipitation process in Aksu Area under the background of the Central Asian Vortex, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1718, https://doi.org/10.5194/egusphere-egu2020-1718, 2020.

During the Meiyu period, floods are prone to occur in the middle and lower reaches of the Yangtze River due to the highly concentrated and heavy rainfall, which caused huge life and economic losses. Based on numerical simulation by assimilating Doppler radar, radiosonde, and surface meteorological observations, the evolution mechanism for the initiation, development and decaying of a Meiyu frontal rainstorm that occurred from 4th to 5th July 2014 is analyzed in this study. Results show that the numerical experiment can well reproduce the temporal variability of heavy precipitation and successfully simulate accumulative precipitation and its evolution over the key rainstorm area. The simulated “rainbelt training” is consistent with observed “echo training” on both spatial structure and temporal evolution. The convective cells in the mesoscale convective belt propagated from southwest to northeast across the key rainstorm area, leading to large accumulative precipitation and rainstorm in this area. There existed convective instability in lower levels above the key rainstorm area, while strong ascending motion developed during period of heavy rainfall. Combined with abundant water vapor supply, the above condition was favorable for the formation and development of heavy rainfall. The Low level jet (LLJ) provided sufficient energy for the rainstorm system, and the low-level convergence intensified, which was an important reason for the maintenance of precipitation system and its eventual intensification to rainstorm. At its mature stage, the rainstorm system demonstrated vertically tilted structure with strong ascending motion in the key rainstorm area, which was favorable for the occurrence of heavy rainfall. In the decaying stage, unstable energy decreased, and the rainstorm no longer had sufficient energy to sustain. The rapid weakening of LLJ resulted in smaller energy supply to the convective system, and the stratification tended to be stable in the middle and lower levels. The ascending motion weakened correspondingly, which made it hard for the convective system to maintain.

How to cite: Li, H., Hu, Y., and Zhou, Z.: Analysis of the Evolution of a Meiyu Frontal Rainstorm Based on Doppler Radar Data Assimilation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1975, https://doi.org/10.5194/egusphere-egu2020-1975, 2020.

EGU2020-2285 | Displays | AS1.3

A numerical study of convection initiation in Southwestern Xinjiang, Northwest China

Jie Ming and Abuduwaili Abulikemu

Convection initiation (CI)  occurred near the oasis region surrounded by gobi desert in the Southwestern Xinjiang, Northwest China is investigated using a real-data, high-resolution Weather Research and Forecasting (WRF) simulation. Observations revealed that many CIs occurred successively near oasis region, some of which developed significantly in both size and intensity and eventually become a strong mesoscale convective system (MCS). The WRF simulation captured the general features of the CIs and MCS. Lagrangian vertical momentum budgets were conducted along the backward trajectories of air parcels within three convective cells. The total vertical acceleration was decomposed into dynamic and buoyant components. The results showed that the buoyant acceleration played a decisive role for about half of the air parcels during the CI, which was contributed by the dry air buoyancy. However, the dynamic acceleration mainly contributed during the CI for about one fourth of the air parcels. The dynamic acceleration can be further decomposed into five terms based on anelastic approximation. The positive dynamic acceleration was mainly caused by the vertical twisting term associated with the mid-level vertical shear, while the extension term contributed negatively to the dynamic acceleration. The other two terms related to horizontal curvature and height variation of density were negligibly small.

How to cite: Ming, J. and Abulikemu, A.: A numerical study of convection initiation in Southwestern Xinjiang, Northwest China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2285, https://doi.org/10.5194/egusphere-egu2020-2285, 2020.

Using hourly air pollutants concentration from six environmental monitor stations, meteorological data and wind profile radar data in winter during 2013-2015, the influences of shallow foehn on diffusion conditions and air pollution concentration over Urumqi were analyzed. The results showed the occurrence frequency of shallow foehn was 57.3% in Urumqi in winter. The flow depth, base height and top height of shallow foehn were about 1500 m, 600 m and 2100 m, respectively. The maximum mixing layer depth, the inversion depth, the temperature difference between the top and bottom of inversion layer on foehn days were 200 m lower, 344m thicker and 4.4℃ higher than the corresponding values on non-foehn days, respectively. However, the differences of wind speed and inversion intensity between on foehn days and on non-foehn days were slight. Also, the frequency of each pollution level on foehn days was higher than on non-foehn days with extra frequency of 18% from level Ⅲ to level Ⅵ. Moreover, there was foehn existence on days with air pollution level Ⅵ. Except for O3, the other five air pollutant concentrations at each environmental station on foen days were all higher than on non-foehn days but with similar diurnal variation. The spatial distributions of six air pollutants on foehn days and non-foehn days were almost same. Overall, the air quality at south urban area was relative excellent than other areas.

How to cite: keming, Z.: The Influence of Shallow Foehn on Atmospheric Diffusion Conditions and Air Quality over Urumqi in Winter, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2579, https://doi.org/10.5194/egusphere-egu2020-2579, 2020.

It is well known that climate changes sometimes may cause natural disasters,especially the disastrous weather days,as downpour,flood,landslide and mudslide,and their derivatives disasters not only have relationship with precipitation,but also,closely with rainfall intensity. In the practice of Xinjiang disaster prevention,it’s urgent to know the temporal and spatial distributions of precipitation intensity and the maximum of precipitation intensity in different recurrence periods. In this paper,based on the observed hourly precipitation data over 16 national-standard stations during May to September from 1991 to 2013 in Xinjiang,some large-scale,multisites and long-paying observed hourly precipitation data have been used firstly together with the methods of probability distributions,statistical tests,variant difference analysis and extreme value analysis,the temporal and spatial distributions and the diurnal variation of hourly rain in summer in Xinjiang have been analyzed. The results show that the hourly rain presents high frequency in northwest and low frequency in southeast of Xinjiang. The high value center of the frequency with hourly rainfall intensity over 0.1 mm·h-1 or 4 mm·h-1 both in Western Tianshan Mountains. The frequency of heavy rainfall is increasing in places such as Ruoqiang where rains less. The high frequent periods of heavy rainfall,with hourly rainfall intensity over 4 mm·h-1,are often occurred in the afternoon,and the first and second half of the night in Northern Xinjiang,while it occurs at night in Southern Xinjiang. The hourly rain frequencies share obviously different diurnal variation in all regions of Xinjiang,where the hourly rainfall is not well-distributed. The distribution characteristic of daily rain in Northern Tacheng and Altay Prefecture is bimodal and in the rest regions of Northern Xinjiang is unimodal. Nevertheless,in Southern Xinjiang,most are in bimodal distribution. The total frequency of hourly rainfall intensity larger than 0.1 mm·h-1 or 4.0 mm·h-1 in Northern and Southern Xinjiang both appears to be an evident increase trend,and it would increase more significance in Southern Xinjiang in the 2010s. The high value region of hourly rainfall intensity occurring once in 50 or 100 years,respectively 45 mm·h-1 and 50 mm·h-1,both is in the western Aksu.

How to cite: chunyan, C.: Temporal and spatial distributions of hourly rain intensity under the warm background in Xinjiang, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2592, https://doi.org/10.5194/egusphere-egu2020-2592, 2020.

Severe downslope wind triggered by the interaction between the gap jet and the asymmetrical topography in the Tianshan canyon which caused severe disasters of trains rolloverin the Turpan Depression in Xinjiang on February 28, 2007. To understand the mechanism of downslopewindstorm between the interaction of large-scale circulation background,mesoscale system and complex topography in this extreme windstorm.We use a WRF model to simulated it.Base on the mesoscale diagnostic analysis to simulative results,We propose a mechanism for the windstorm : Under the pressure gradient between north-south sides of the Tianshan Mountain, the air parcel climbs windward slope and flowsinto the Tianshan Gorge and then forms gap jet due to effect of narrow,the jet generated gravity waves forced by the asymmetric terrain of the Tianshan Canyon, and produces a lee waves in the leeward, which transmits the energy of the gap jet to the ground,andSevere downslope windstorm formed finally. In this process, the turbulence formed by the wave breaking and the critical layer absorb the upper layer energy downward, which strengthens the energy of the gap jet,and the atmospheric stability stratification exacerbates the sinking movement, which sinks energy to the ground.

How to cite: hao, T.: Mesoscale Analysis of Severe Downslope Windstorm Caused by Gap Jet in Tianshan Canyon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2794, https://doi.org/10.5194/egusphere-egu2020-2794, 2020.

In order to solve the problem of excessive energy dissipation near the sub-grid scale in numerical weather model, the Stochastic Kinetic Energy Backscatter (SKEB) method is introduced into the GRAPES-REPS regional ensemble prediction system, and the first-order autoregressive stochastic process is used in the horizontal direction. Calculate the random pattern obtained by spherical harmonic expansion in the direction, calculate the local dynamic energy dissipation rate caused by the numerical diffusion scheme, construct the random flow function forcing, and convert it into horizontal wind speed disturbance, compensate the dissipated kinetic energy, and carry out A 10-day ensemble prediction test and a randomized time and space scale sensitivity test in September and October 2018 (choose 1st, 7th, 13th, 19th, and 25th), and evaluate the test results. The main conclusions of the research work are as follows: By comparing the ensemble prediction results of the test using the SKEB method and the test without the SKEB method, the use of the SKEB scheme increases the large aerodynamic energy of the GRAPES regional model in the small and medium-scale region, and improves the GRAPES model to the actual atmosphere to some extent. The simulation ability of kinetic energy spectrum; the introduction of SKEB scheme in regional ensemble prediction can significantly improve the dispersion of U and V in horizontal wind field of regional model, and the problem of insufficient dispersion of large-scale dynamic energy dissipation rate in Qinghai-Tibet Plateau region is improved. The SKEB program has improved the forecasting skills to a certain extent, such as reducing the CRPS scores of the horizontal wind fields U and V, reducing the outliers scores of the horizontal wind field, temperature, and 10 m wind speed; the introduction of the SKEB method can improve the light rain. The precipitation probability prediction skill score, but the improvement of the score did not pass the significance test, so it is considered that the SKEB method is difficult to effectively improve the probability prediction technique of precipitation.

Sensitivity tests based on the SKEB method for five time scales of random pattern (1h, 3h, 6h, 9h and 12h of the time series τ) show that the ensemble prediction is sensitive to the five time scales of the stochastic model of the SKEB method. And the 12h experiment show the best performance than the others.

How to cite: Li, H. and Chen, J.: Sensitivity analysis of SKEB method in Regional ensemble forecast system GRAPES-REPS, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3444, https://doi.org/10.5194/egusphere-egu2020-3444, 2020.

EGU2020-4374 | Displays | AS1.3

Sensitivity of ensemble forecast verification to model bias

Jingzhuo Wang, Jing Chen, and Jun Du

        This study demonstrates how model bias can adversely affect the quality assessment of an ensemble prediction system (EPS) by verification metrics. A regional EPS [Global and Regional Assimilation and Prediction Enhanced System-Regional Ensemble Prediction System (GRAPES-REPS)] was verified over a period of one month over China. Three variables (500-hPa and 2-m temperatures, and 250-hPa wind) are selected to represent "strong" and "weak" bias situations. Ensemble spread and probabilistic forecasts are compared before and after a bias correction. The results show that the conclusions drawn from ensemble verification about the EPS are dramatically different with or without model bias. This is true for both ensemble spread and probabilistic forecasts. The GRAPES-REPS is severely underdispersive before the bias correction but becomes calibrated afterward, although the improvement in the spread' spatial structure is much less; the spread-skill relation is also improved. The probabilities become much sharper and almost perfectly reliable after the bias is removed. Therefore, it is necessary to remove forecast biases before an EPS can be accurately evaluated since an EPS deals only with random error but not systematic error. Only when an EPS has no or little forecast bias, can ensemble verification metrics reliably reveal the true quality of an EPS without removing forecast bias first. An implication is that EPS developers should not be expected to introduce methods to dramatically increase ensemble spread (either by perturbation method or statistical calibration) to achieve reliability. Instead, the preferred solution is to reduce model bias through prediction system developments and to focus on the quality of spread (not the quantity of spread). Forecast products should also be produced from the debiased but not the raw ensemble.

How to cite: Wang, J., Chen, J., and Du, J.: Sensitivity of ensemble forecast verification to model bias, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4374, https://doi.org/10.5194/egusphere-egu2020-4374, 2020.

EGU2020-4705 | Displays | AS1.3 | Highlight

Ensemble weather forecast of precipitation with a stochastic weather generator based on analogues circulation

Meriem Krouma, Pascal Yiou, Céline Déandréis, and Soulivanh Thao

Abstract

The aim of this study is to assess the skills of a stochastic weather generator (SWG) to forecast precipitation in Europe. The SWG is based on the random sampling of circulation analogues, which is a simple form of machine learning simulation. The SWG was developed and tested by Yiou and Déandréis (2019) to forecast daily average temperature and the NAO index. Ensemble forecasts with lead times from 5 to 80 days were evaluated with CRPSS scores against climatology and persistence forecasts. Reasonable scores were obtained up to 20 days.  In this study, we adapt the parameters of the analogue SWG to optimize the simulation of European precipitations. We then analyze the performance of this SWG for lead times of 2 to 20 days, with the forecast skill scores used by Yiou and Déandréis (2019). To achieve this objective, the SWG will use ECA&D precipitation data (Haylock. 2002), and the analogues of circulation will be computed from sea-level pressure (SLP) or geopotential heights (Z500) from the NCEP reanalysis. This provides 100-member ensemble forecasts on a daily time increment. We will evaluate the seasonal dependence of the forecast skills of precipitation and the conditional dependence to weather regimes. Comparisons with “real” medium range forecasts from the ECMWF will be performed.

References

Yiou, P., and Céline D.. Stochastic ensemble climate forecast with an analogue model. Geoscientific Model Development 12, 2 (2019): 723‑34.

Haylock, M. R. et al.. A European daily high-resolution gridded data set of surface temperature and precipitation for 1950-2006. J. Geophys. Res. - Atmospheres 113, D20 (2008): doi:10.1029/2008JD010201.

 

Acknowledge

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 813844.

How to cite: Krouma, M., Yiou, P., Déandréis, C., and Thao, S.: Ensemble weather forecast of precipitation with a stochastic weather generator based on analogues circulation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4705, https://doi.org/10.5194/egusphere-egu2020-4705, 2020.

EGU2020-5217 | Displays | AS1.3

Performance Evaluation of Cloud Analysis in GRAPES 3km Model over Northwest China

Xuwei Ren, Aimei Shao, Weicheng Liu, and Xiaoyan Chen

Cloud analysis module (GCAS) in GRAPES model can combine radar reflectivity data, satellite data and surface observations to provide there-dimensional cloud information. To show application effect of GCAS on 3-km resolution forecasts in arid and semi-arid areas of Northwest China, three sets of forecast experiments were conducted with GRAPES_Meso model, which includes control experiment (Con_exp), gcas experiment (Gcas_exp) and hot-start experiment (Hot_exp). The impact of cloud analysis on the prediction effect was investigated using 13 heavy rainfall cases and one month continuous experiments.

These experimental results show the use of cloud analysis can significantly improve forecasting skills of precipitation. Compared with hourly precipitation observations, Gcas_exp performed better than Con_exp and Hot_exp, which gets a higher threat scores of precipitation both for 13 cases and for one-month continuous experiments. Hot_exp presented an positive effect only in the first few hours. Oftentimes, Hot_exp got a worse forecast than Con_exp after the first several hours. In addition, gcas_exp has a positive effect on the prediction of 2m temperature, 10m wind and other variables, but forecasted composite reflectivity was stronger than its observations. Hot_exp can reduce this strength bias to some extent.

How to cite: Ren, X., Shao, A., Liu, W., and Chen, X.: Performance Evaluation of Cloud Analysis in GRAPES 3km Model over Northwest China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5217, https://doi.org/10.5194/egusphere-egu2020-5217, 2020.

 Based on conventional meteorological observation data and particulate matter monitoring data, combined with traceability of pollution sources, the main causes of sand-dust heavy pollution and the characteristics of dust transmission in eastern Qinghai in May 2019 were analyzed by using the principles of meteorology and trajectory analysis.The results show as following:The heavy dusty weather is mainly affected by the development of the enhanced low-slot eastward of Lake Baikal. The low-slots carry strong cold air moving eastward ,leading to heavy pollution in the eastern part of Qinghai. During the dusty weather, the cold air from the Hexi Corridor was poured into the eastern part of Qinghai from the valley . The dust from Gansu Province entered and then transported from east to west to easdtern Qinghai,causing pollution. The presence of the inversion layer stabilizes the atmospheric stratification in the eastern boundary layer of Qinghai, which is not conducive to the outward spread of pollutants caused by surface turbulence activities. The long-term maintenance of dust that cannot be diffused in time is the main cause of heavy pollution. In the early stage of sand and dust weather, the humidity conditions in the eastern part of Qinghai gradually deteriorated. Before the sand-dust occurred, the sensible heat on the ground increased significantly. The water vapor in the atmosphere weakened, the air was dry, and the water vapor condition, which is an important condition for the formation of sand and dust,was poor. The dust storm transmission route affecting the eastern part of Qinghai is transmitted from southeast to northwest. The mixed layer height and static weather index of the EC numerical forecasts have a good predictive indication during the process. The results of the trajectory analysis also indicate that the dusty weather in the eastern part of Qinghai (Xining, Haidong, etc.) was caused by backward irrigation of sandfrom the Hexi Corridor, and affected Haidong and Xining areas under the influence of the terrain.

How to cite: guo, X. and ma, Y.: Analysis of a typical heavy dust pollution weather in Semi-arid region- A Case Study in Eastern Qinghai , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5220, https://doi.org/10.5194/egusphere-egu2020-5220, 2020.

EGU2020-5333 | Displays | AS1.3

Analysis of a server convective rainstorm in the weak background

zhang yingxin and qin rui

Using conventional and unconventional meteorological observation dataes, RMAPS-NOW( RR4DVar cloud model), the severe convective rainstorm occurred over the Beijing-Tianjin-Hebei junction area on May 17, 2019 was analyzed. Taking the observation of  Tongzhou 101 farm rainstorm (17: 30-20h precipitation 179.1mm) as an example, the results showed that this server convective rainstorm took place under a weak background, (1) Boundary conditions : The Beijing-Tianjin-Hebei area had high temperature and high humidity. The θse energy front was located in the middle of Beijing-Tianjin-Hebei. The CAPE at Beijing Observatory reached 1113 J · Kg-1 at 08h, and correction value reached 2669 J · Kg-1 at 14h. Convection cloud streets appeared around 12 o'clock in the visible image of the Himawari-8 satellite; the southeast wind jet in the boundary layer provided sufficient water  for convection development; at 20 o'clock, sounding showed that the vertical wind shear of 0-6 km increased to 17.5 m · s-1. (2) Trigger conditions: The southeast wind at the rear of the offshore High merged with sea breeze and pushed inland, formed a local convergence line with the local southerly wind in the central part of Beijing, Tianjin, and Hebei, and convection occurred at the convergence line and the θse energy front. (3) Tongzhou heavy rain was caused by two convective cells. Cell 1 was generated at the convergence line and the θse front. It developed into a server storm within 1 hour, and the composite reflectivity was > 60dBz. Subsequently, at its downstream (northwest side, the leading airflow is the southeast airflow), Cell 2 developed rapidly, and the two Celles revolved, moved over Tongzhou successively, accompanied by heavy rainfall ,hail and strong winds. (4) RMAPS-NOW data can describe the refined process of cells formation and evolution, that is, the θse field in the Beijing-Tianjin-Hebei region is extremely uneven, even in the θse front area. In the boundary layer convergence line and θse high-energy region, the convective bubble stimulated the formation of cell 1, the airflow spined up, and the development of the convective cell was strengthened. Half an hour later, a single cell was gradually separated into two cells (cell 1 and cell 2) in the upper layer, and the updraft gradually separated from the center into two rotating oblique updrafts. Seen from the echo profile, the two cells were connected by a cloud bridge and rotated clockwise. The convergence line in the boundary connected the two cells and rotated organically.

How to cite: yingxin, Z. and rui, Q.: Analysis of a server convective rainstorm in the weak background, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5333, https://doi.org/10.5194/egusphere-egu2020-5333, 2020.

EGU2020-6348 | Displays | AS1.3

Application and Verification of the ECMWF Precipitation Type Forecast Product (PTYPE) in China

Quan Dong, Feng Zhang, Ning Hu, and Zhiping Zong

The ECMWF (European Centre for Medium-Range Weather Forecasts) precipitation type forecast products—PTYPE are verified using the weather observations of more than 2000 stations in China of the past three winter half years (October to next March). The products include the deterministic forecast from High-resolution model (HRE) and the probability forecast from ensemble prediction system (EPS). Based on the verification results, optimal probability thresholds approaches under criteria of TS maximization (TSmax), frequency match (Bias1) and HSS maximization (HSSmax) are used to improve the deterministic precipitation type forecast skill. The researched precipitation types include rain, sleet, snow and freezing rain.

The verification results show that the proportion correct of deterministic forecast of ECMWF high-resolution model is mostly larger than 90% and the TSs of rain and snow are high, next is freezing rain, and the TS of sleet is small indicating that the forecast skill of sleet is limited. The rain and snow separating line of deterministic forecasts show errors of a little south in short-range and more and more significant north following elongating lead times in medium-range. The area of sleet forecasts is smaller than observations and the freezing rain is bigger for the high-resolution deterministic forecast. The ensemble prediction system offsets these errors partly by probability forecast. The probability forecast of rain from the ensemble prediction system is smaller than the observation frequency and the probability forecast of snow is larger in short-range and smaller in medium-range than the observation frequency. However, there are some forecast skills for all of these probability forecasts. There are advantages of ensemble prediction system compared to the high-resolution deterministic model. For rain and snow, for some special cost/loss ratio events the EPS is better than the HRD. For sleet and freezing rain, the EPS is better than the HRD significantly, especially for the freezing rain.

The optimal thresholds of snow and freezing rain are largest which are about 50%~90%, decreasing with elongating lead times. The thresholds of rain are small which are about 10%~20%, increasing with elongating lead times. The thresholds of sleet are the smallest which are under 10%. The verifications show that the approach of optimal probability threshold based on EPS can improve the forecast skill of precipitation type. The proportion correct of HRD is about 92%. Bias1 and TSmax improve it and the improvement of HSSmax is the most significant which is about 94%. The HSS of HRD is about 0.77~0.65. Bias1 increases 0.02 and TSmax increases more. The improvement of HSSmax is the biggest which is about 0.81~0.68 and the increasing rate is around 4%. From the verifications of every kinds of precipitation types, it is demonstrated that the approach of optimal probability threshold improves the performance of rain and snow forecasts significantly compared to the HRD and decreases the forecast area and missing of freezing rain and sleet which are forecasted more areas and false alarms by the HRD.

Key words: ECMWF; ensemble prediction system;precipitation type forecast; approach of optimal probability threshold; verification

How to cite: Dong, Q., Zhang, F., Hu, N., and Zong, Z.: Application and Verification of the ECMWF Precipitation Type Forecast Product (PTYPE) in China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6348, https://doi.org/10.5194/egusphere-egu2020-6348, 2020.

In order to meet the high demand for advanced weather forecasts in the 2022 Olympic and Paralympic Winter Games, hourly wind observation data of some venues in Zhangjiakou City  is analyzed. Based on the specific gust characteristics in these venues, deviation of numerical weather prediction model is initially calculated to demonstrate the systematic bias of instantaneous wind speed forecasts derived from ECMWF. Additionally, a statistical down scaling method is further used by establishing the relationship between model forecasts and observation. Then independent samples are imported to the established equations to generate revised outputs. Tests show that the established equations have a better effect on forecasting the instantaneous wind speed than original model outputs and the corrected outputs have significantly better accuracy in predicting the instantaneous wind speed in the studied area.

How to cite: Li, J., Dong, Q., and Li, R.: Analysis of Gust Characteristics and Forecast Correction for the 2022 Olympic and Paralympic Winter Games in Zhangjiakou , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6627, https://doi.org/10.5194/egusphere-egu2020-6627, 2020.

EGU2020-8204 | Displays | AS1.3 | Highlight

MOSMIX-SNOW – A Model Output Statistics Product for Fresh Snow Forecasts at Mountain Locations

Andreas Lambert, Sebastian Trepte, and Franziska Ehrnsperger

Many Numerical Weather Prediction (NWP) models provide the parameter total snow depth as a Direct Model Output (DMO) surface variable. In mountain regions, however, the orographic flow modification significantly influences precipitation formation and preferential settling, leading to large model biases if DMO is directly compared to fresh snow point observations. Avalanche risk forecasts in turn require calibrated deterministic and probabilistic fresh snow forecasts, as the amount of fresh snow constitutes a crucial driver of avalanche risk.

In this study, MOSMIX-SNOW, a Model Output Statistics (MOS) product based on multiple linear regression is developed. Ground-based observations and operational forecast data of the two deterministic global NWP models ICON and ECMWF form the basis of the MOS system. MOSMIX-SNOW offers point forecasts for 20 deterministic as well as probabilistic forecast variables like the amount of fresh snow within 24h, the probability of more than 30cm of fresh snow within 24h and some basic variables like 2m temperature and dew point. The unique characteristic of MOSMIX-SNOW is the large number of observation-based, model-based and empirical predictors, which exceeds 200. Furthermore, a long historical data period of 9 years is applied for training of the MOS system. Thus, local orographic effects and large scale flow patterns are implicitly included in the MOS equations by a location and lead time specific choice of predictors. To avoid unrealistic jumps in the forecast, persistence predictors, which represent the forecast value of the previous forecast hour, are included in the MOS system. All forecasts feature a maximum lead time of +48h, have an hourly forecast resolution as well as update cycle and are available for about 15 mountain locations in the Bavarian Alps between 1100m and 2400m above sea level.

The verification analysis of the winter season 2018/19 shows that MOSMIX-SNOW forecasts offer a significantly higher forecast reliability than the raw ensemble of the regional NWP model COSMO-D2-EPS. The bias of the deterministic forecast parameters is smaller for MOSMIX-SNOW, especially for heavy snowfall events. MOSMIX-SNOW turned out to be a useful tool to support the avalanche risk forecasts on a daily basis during the snowy winter of 2018/19. Furthermore, the deterministic fresh snow forecast of MOSMIX-SNOW and other meteorological parameters like 2m-temperature serve as input for operational snowpack simulations. Measurement related noise and snow drift in the observations, however, are identified as an important source of uncertainty and the application of noise reduction techniques like a Savitzky-Golay filter are expected to have a beneficial impact on the forecast quality. MOSMIX-SNOW will become operational by end of 2020.

How to cite: Lambert, A., Trepte, S., and Ehrnsperger, F.: MOSMIX-SNOW – A Model Output Statistics Product for Fresh Snow Forecasts at Mountain Locations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8204, https://doi.org/10.5194/egusphere-egu2020-8204, 2020.

EGU2020-11429 | Displays | AS1.3 | Highlight

Impact of land surface processes on mesoscale convective initiation over Africa in ensemble model simulations: 3 Case studies using UKMO Unified Model

Semeena Valiyaveetil Shamsudheen, Christopher Taylor, and Andrew Hartley

Impact of land surface processes on mesoscale convective initiation over Africa in ensemble model simulations: 3 Case studies using UKMO Unified Model
V S Semeena1, C Taylor1 and A Hartley2
1. UK Centre for Ecology and Hydrology, Wallingford, Oxfordshire, OX10 8BB, UK
2. Met Office, FitzRoy Road, Exeter, Devon, EX1 3PB, UK

The populations of the developing world have a greater need for accurate weather predictions because national economies and personal livelihoods depend very heavily on weather-sensitive factors including agriculture, water resources and public health.   Climate related risk is an obstacle in improving food security and rural livelihood in Africa.   An effective system to provide reasonable forecast can have a great positive impact on the life quality in African continent.    Thus predicting an event with accuracy is essential to provide early warning of heavy rainfall and floods that may lead to loss of life and property. Past studies have shown the importance of the land surface on the development of African convective storms. Here we are using 72 hour ensemble model simulations to evaluate the representation of land and its influence on convection in forecast models.   
Three episodes of heavy rainfall events are identified over western and eastern African region over late springtime of 2019 for this study.   A heavy rainfall event is recorded over SW Mali on 25th April 2019 followed by the development of a convective system over northern Benin on 29th April 2019.   The latter one develops into a mesoscale system on 30th April extending up to western Nigeria and this convective initiation in the afternoon and development into a larger system by late evening continues until 3rd May.    Our eastern African case examines the daytime development of convective cells which develop over southern Sudan, and grow into a mesoscale system which crosses over to Congo by midnight.  17 ensemble members simulation of the UK Met Office Unified Model (UKMO-UM) that were run for a forecasting testbed within the African SWIFT (Science for Weather Information and Forecasting Techniques) is used to understand the role of land surface temperature (LST) and soil moisture (SM) in formation of mesoscale systems.  Single-model ensemble simulations of the UM in global domain at 0.2813 X 0.1875 degree longitude, latitude resolution and the regional convection permitting (CP) model in 2 different horizontal resolutions – 8.8km and 4.4km – are performed.   Results are compared with LST from Meteosat Second Generation (MSG) satellite data and precipitation data from Global Precipitation Measurements (GPM).   Both global and regional models capture the main features though the convective initiation takes place much earlier in the models than in reality.   We notice that the representation of rivers and wetlands in the global model affects the spatial patterns of surface fluxes, in turn introducing biases into the forecast.    Further comparison of surface fluxes in the ensemble simulations of these case studies with observed LST and SM illustrate the importance of land initialisation for short term forecasts. 

How to cite: Valiyaveetil Shamsudheen, S., Taylor, C., and Hartley, A.: Impact of land surface processes on mesoscale convective initiation over Africa in ensemble model simulations: 3 Case studies using UKMO Unified Model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11429, https://doi.org/10.5194/egusphere-egu2020-11429, 2020.

 The accurate tropical cyclone (TC) track forecast is necessary to mitigate and prepare significant damage. TC has been predicted by the numerical models, statistical models, and machine learning methods in previous researches. However, those models are separately used for TC track forecast, and historical data with satellite images were used as input variables for machine learning without forecast data from numerical models. In this study, we corrected the TC track forecast of a numerical model by artificial neural network (ANN). TCs that occurred from 2006 to 2015 over the western North Pacific were hindcasted by the Weather Research and Forecasting (WRF) model, and all categories of TCs except for tropical depression (i.e., tropical storm, severe tropical storm, and typhoon) from June to November were included in this study. We evaluated the performance of TC track forecast in terms of duration, translation speed, and direction compared with the best track data. The simulated positions of TCs at 24-hour, 48-hour, and 72-hour forecast lead time were used as variables for training and testing ANN. To optimize the number of neurons in ANN, simulated TCs were divided into two parts; TCs in 2006-2014 for ANN optimization and those in 2015 for a blind test. Also, the output selection method based on the forecast error of the WRF was applied to exclude the outlier of ANN results. By applying the output selection, the forecast error of ANN was further reduced than that of the WRF. As a result, ANN with the output selection method could improve TC track forecast by about 15% compared to the WRF. Also, the effect of ANN tended to increase when the forecast error of the WRF was large. The output selection method was particularly effective by excluding outliers of ANN results when the forecast error of the WRF was small.

※ This research was supported by Next-Generation Information Computing Development Program through the National Research Foundation of Korea(NRF) funded by the Ministry of Science, ICT (NRF-2016M3C4A7952637).

How to cite: Kim, K., Cha, D.-H., and Im, J.: Improvement of Tropical Cyclone Track Forecast over the Western North Pacific Using a Machine Learning Method, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13648, https://doi.org/10.5194/egusphere-egu2020-13648, 2020.

The aim of the work is to present simulation results of Weather Research and Forecasting (WRF) Model for high-resolution dynamical downscaling done over selected part of Poland. The research carried out a few unique simulations for selected days of the year 2019. For each model run different configuration of physical parameters (parametrization of boundary layer) were used. Additionally, two model runs were tested using the same configuration for physical parameterizations, but with two different spatial resolution. Additionally the sensitivity of the model in terms of spatial resolution was analyzed. Model was configured using two nested domains with 9 km and 3 km grid cell resolutions. All WRF simulations was simulated using GFS gribs with its initial time of 00 UTC. The results were compared with meteorological observations from meteorological stations. Results show high sensitivity of the obtained dynamical downscaling geophysical fields to the selected model configuration. High verifiability of air temperature forecasts was obtained using YSU and MYNN3 BL schemes. Mean Absolute Error (MAE) for temperature prediction has lower values in the summer season. Studies show the most optimal model configuration for BL for Poland area.

How to cite: Kendzierski, S.: A review of selected parameterization schemes of WRF model over Poland area in short-term weather forecast, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21736, https://doi.org/10.5194/egusphere-egu2020-21736, 2020.

AS1.9 – Subseasonal-to-Seasonal Prediction: meteorology and impacts

EGU2020-3951 | Displays | AS1.9

On the Resonances and Teleconnections of the North Atlantic and Madden-Julian Oscillations

Gilbert Brunet, Yosvany Martinez, Hai Lin, and Natacha Bernier

The key to better prediction of S2S variability and weather regimes in a changing climate lies with improved understanding of the fundamental nature of S2S phase space structure and associated predictability and dynamical processes. The latter can be decomposed into a finite number of relatively large-scale discrete-like Rossby waves with coherent space-time characteristics using Empirical Normal Mode (ENM) analysis. ENM analysis is based on principal component analysis, conservation laws and normal mode theories. These modes evolve in a complex manner through nonlinear interactions with themselves and transient eddies and weak dissipative processes. Within this atmospheric dynamic framework, we will discuss the teleconnections and the 35-day wave resonance of the North Atlantic Oscillation using recent diagnostics and numerical experiments.

References

Brunet, G. and J. Methven, 2018: Identifying wave processes associated with predictability across time scales: An empirical normal mode approach. Book chapter in Sub-seasonal to seasonal prediction: The gap between weather and climate forecasting. Editors A.W. Robertson and F. Vitart, Elsevier. p.1-42

Brunet, G. 1994:  Empirical normal mode analysis of atmospheric data. J. Atmos. Sci., 51, 932-952.

Lin, H., G. Brunet, and J. Derome, 2009: An observed connection between the North Atlantic Oscillation and the Madden-Julian Oscillation.  J. Climate, 22, 364-380.

Lin, H., G. Brunet and J. Derome 2007: Intraseasonal Variability in a Dry Atmospheric Model, J. Atmos. Sci., 64, 2442-2441.

How to cite: Brunet, G., Martinez, Y., Lin, H., and Bernier, N.: On the Resonances and Teleconnections of the North Atlantic and Madden-Julian Oscillations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3951, https://doi.org/10.5194/egusphere-egu2020-3951, 2020.

EGU2020-1580 | Displays | AS1.9

Predictable weather regimes at the S2S time scale

Nicola Cortesi, Veronica Torralba, Llorenç Lledó, Andrea Manrique-Suñén, Nube Gonzalez-Reviriego, Albert Soret, and Francisco J. Doblas-Reyes

State-of-the-art Subseasonal-to-Seasonal (S2S) forecast systems correctly simulate the main properties of weather regimes, like their spatial structures and their average frequencies. However, they are still unable to skillfully predict the observed frequencies of occurrence of weather regimes after the first ten days or so. Such a limitation severely restrict their application to develop climate service products, for example to forecast events with a strong impact on society, such as droughts, heat waves or cold spells.

This work describes two novel corrections that can be easily applied to any weather regime classification, to significantly enhance the S2S predictability of the frequencies of the weather regimes. The first one is based on the idea of weighting the daily observed anomaly fields of the variable used to cluster the atmospheric flow by the Anomaly Correlation Coefficient (ACC) of the same variable, just before clustering it. In this way, the clustering algorithm gives more importance to the areas where the forecast system is better in predicting the circulation variable. Thus, it is forced to generate the most predictable regimes. The second correction consists in the ACC weighting of the daily forecasted anomalies before the assignation of the daily fields to the observed regimes, to give more importance to the grid points where the forecast system has more skill. Hence, the forecasted time series of the regimes is more similar to the observed one.

Two sets of four regimes each were validated, one defined by k-means clustering of SLP from NCEP reanalysis over the Euro-Atlantic region during lasts 40-years (1979-2018) for October to March, and another for April to September. Forecasts proceed from the 2018 version of the Monthly Forecast System developed by the European Centre for Medium-Range Weather Forecasts (ECMWF-MFS). Predictability was measured in cross-validation by the Pearson correlations between the forecasted and observed weekly frequencies of occurrence of the regimes, for each of the 52 weekly start dates of the year separately and for a 20-years hindcast period (1998-2017).

Results show that with both corrections described above, Pearson correlations increase up to r = +0.5, depending on the start date and forecast time. Average increase over all start dates is of r = +0.2 at forecast days 12-18 and r = +0.3 at forecast days 19-25 and 26-32. The gain is spread quite evenly along the start dates of the year.

Beyond the Euro-Atlantic region, these two corrections can be easily transferred to any area of the world. They may be employed to correct seasonal predictions of weather regimes too (results in progress). Besides, their application is straightforward and provides a significant skill gain at a negligible computational cost for potentially all S2S forecast systems and regime classifications. We foresee that they might also benefit forecasts of atmospheric teleconnections. For all these reasons, we warmly recommend the S2S community to take advantage of this 'low-hanging fruit'.
 

How to cite: Cortesi, N., Torralba, V., Lledó, L., Manrique-Suñén, A., Gonzalez-Reviriego, N., Soret, A., and Doblas-Reyes, F. J.: Predictable weather regimes at the S2S time scale, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1580, https://doi.org/10.5194/egusphere-egu2020-1580, 2020.

EGU2020-11513 | Displays | AS1.9

The mutual impact of weather regimes and the stratospheric circulation on European surface weather

Christian M. Grams, Remo Beerli, Dominik Büeler, Daniela I. V. Domeisen, Lukas Papritz, and Heini Wernli

Extreme states of the winter stratosphere, such as sudden stratospheric warmings (SSWs) or an extremely strong stratospheric polar vortex (SPV), can affect surface weather over the North-Atlantic European region on subseasonal time scales. Here we investigate the occurrence of Atlantic-European weather regimes during different stratospheric conditions in winter and their link to large-scale weather events in European sub-regions. We further elucidate if the large-scale flow regime in the North Atlantic at SSW onset determines the subsequent downward impact.

Anomalous stratospheric conditions modulate the occurrence of weather regimes which project strongly onto the NAO and the likelihood of their associated weather events. In contrast weather regimes which do not project strongly onto the NAO are not affected by anomalous stratospheric conditions. These regimes provide pathways to unexpected weather events in extreme stratospheric polar vortex states. For example, Greenland blocking (GL) and the Atlantic Trough (AT) regime are the most frequent large-scale flow patterns following SSWs. While in Central Europe GL provides a pathway to cold and calm weather, AT provides a pathway to warm and windy weather. The latter weather conditions are usually not expected after an SSW. Furthermore, we find that a blocking situation over western Europe and the North Sea (European Blocking) at the time of the SSW onset favours the GL response and associated cold conditions over Europe. In contrast, an AT response and mild conditions are more likely if GL occurs already at SSW onset. An assessment of forecast performance in ECMWF extended-range reforecasts suggests that the model tends to forecast too cold conditions following weak SPV states.

In summary, weather regimes and their response to anomalous SPV states importantly modulate the stratospheric impact on European surface weather. In particular the tropospheric impact of SSW events critically depends on the tropospheric state during the onset of the SSW. We conclude that a correct representation of weather regime life cycles in numerical models could provide crucial guidance for subseasonal prediction.

 

References:

Beerli, R., and C. M. Grams, 2019: Stratospheric modulation of the large-scale circulation in the Atlantic–European region and its implications for surface weather events. Q.J.R. Meteorol. Soc., 145, 3732–3750, doi:10.1002/qj.3653.

Domeisen, D. I. V., C. M. Grams, and L. Papritz, 2020: The role of North Atlantic-European weather regimes in the surface impact of sudden stratospheric warming events. Weather and Climate Dynamics Discussions, 1–24, doi:https://doi.org/10.5194/wcd-2019-16.

How to cite: Grams, C. M., Beerli, R., Büeler, D., Domeisen, D. I. V., Papritz, L., and Wernli, H.: The mutual impact of weather regimes and the stratospheric circulation on European surface weather, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11513, https://doi.org/10.5194/egusphere-egu2020-11513, 2020.

The representation of upward and downward stratosphere-troposphere coupling and its influence on the teleconnections of the Madden Julian oscillation (MJO) to the European sector is examined in five subseasonal-to-seasonal (S2S) models. We show that while the models simulate a realistic stratospheric response to transient anomalies in troposphere, they overestimate the downward coupling. The models with a better stratospheric resolution capture a more realistic stratospheric response to the MJO, particularly after the first week of the integration. However, in all models examined here the connection between the MJO and vortex variability is weaker than that observed. Finally, we focus on the MJO-SSW teleconnection in the NCEP model, and specifically initializations during the MJO phase with enhanced convection in the west/central pacific (i.e. 6 and 7) that preceded observed SSW. The integrations that simulated a SSW (as observed) can be distinguished from those that failed to simulate a SSW by the realism of the Pacific response to MJO 6/7, with only the simulations that successfully simulate a SSW capturing the North Pacific low. Furthermore, only the simulations that capture the SSW, subsequently simulate a realistic surface response over the North Atlantic and Europe.

How to cite: Schwartz, C. and Garfinkel, C.: Troposphere-Stratosphere Coupling In S2S Models and Its Importance for a Realistic Extratropical Response to the Madden-Julian Oscillation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7171, https://doi.org/10.5194/egusphere-egu2020-7171, 2020.

EGU2020-8310 | Displays | AS1.9

How sensitive is the sub-seasonal prediction to the choice of dynamical cores in the atmospheric model?

Ha-Rim Kim, Baek-Min Kim, Sang-Yoon Jun, and Yong-Sang Choi

This study investigates the prediction skill of the sub-seasonal prediction model that can depend on the choice of dynamical cores: the finite volume (FV) dynamical core on a latitude-longitude grid system versus spectral element (SE) dynamical core on a cubed-sphere grid system. Recent researches showed that the SE dynamical core on a uniform grid system increases parallel scalability and removes the need for polar filters mitigating uncertainty in climate prediction, particularly for the Arctic region. However, it remains unclear whether the choice of dynamical cores can actually yield significant skill changes or not. To tackle this issue, we implemented a sub-seasonal prediction model based on the Community Atmospheric Model version 5 (CAM5) by incorporating the above two dynamical cores with virtually the same physics schemes. Sub-seasonal prediction skills of the SE dynamical core and FV dynamical core are verified with ERA-interim reanalysis during the early winter (November – December) and the late winter (January – February) from 2001/2002 to 2017/2018. The prediction skills of the two different dynamical cores were significantly different regardless of the virtually same physics schemes. In the ocean, the predictability of the SE dynamical core is similar to the FV dynamical core, mostly because of our simulation configuration imposing the same boundary and initial conditions at the surface. Notable differences in the one-month predictability between the two cores are found for the wintertime Arctic and mid-latitudes, particularly over North America and Eurasia continents. With the one-month lead, SE dynamical core exhibited higher predictability over North America in late winter, whereas the FV dynamical core showed relatively higher predictability in East Asia and Eurasia in early winter. One of the reasons for these differences may be the different manifestations of Arctic-midlatitudes linkage in the two dynamical cores; the SE dynamical core captures warmer Arctic and colder mid-latitudes relatively well than the FV dynamical core. Therefore, we conclude that the careful choice of dynamical cores of sub-seasonal prediction models is needed.

How to cite: Kim, H.-R., Kim, B.-M., Jun, S.-Y., and Choi, Y.-S.: How sensitive is the sub-seasonal prediction to the choice of dynamical cores in the atmospheric model?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8310, https://doi.org/10.5194/egusphere-egu2020-8310, 2020.

EGU2020-3565 | Displays | AS1.9

Impacts of ocean model resolution in S2S forecasts with the ECMWF coupled model

Chris Roberts, Frederic Vitart, Magdalena Balmaseda, and Franco Molteni

This study uses initialized forecasts to evaluate the wintertime North Atlantic response to an increase of ocean model resolution from ~100 km (LRO) to ~25 km (HRO) in the European Centre for Medium-Range Weather Forecasts Integrated Forecasting System (ECMWF-IFS). Importantly, the simulated impacts are timescale-dependent such that impacts in subseasonal and seasonal forecasts cannot be extrapolated from multidecadal climate experiments. In general, mean biases are reduced in HRO relative to LRO configurations and the impact is increased at longer lead times. At subseasonal to seasonal lead times, surface heating anomalies over the Gulf Stream are associated with local increases to the poleward heat flux associated with transient atmospheric eddies. In contrast, surface heating anomalies in climate experiments are balanced by changes to the time-mean surface winds that resemble the steady response under linear dynamics. Some aspects of air-sea interaction exhibit a clear improvement with increased resolution at all lead times. However, it is difficult to identify the impact of increased ocean eddy activity in the variability of the overlying atmosphere. In particular, atmospheric blocking and the intensity of the storm track respond more strongly to mean biases and thus have a larger response at longer lead times. Finally, increased ocean resolution drives improvements to subseasonal predictability over Europe. This increase in skill seems to be a result of improvements to the Madden Julian Oscillation and its associated teleconnections rather than changes to air-sea interaction in the North Atlantic region.

How to cite: Roberts, C., Vitart, F., Balmaseda, M., and Molteni, F.: Impacts of ocean model resolution in S2S forecasts with the ECMWF coupled model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3565, https://doi.org/10.5194/egusphere-egu2020-3565, 2020.

Convective-permitting modeling (CPM) yields step improvements in the representation of precipitation, as has been demonstrated in applications of numerical weather prediction and climate modeling. While CPM has been used in the context of historical climate simulations and climate change projections, its application to the sub-seasonal to seasonal (S2S) forecast timescale (weeks to months) is comparatively underexplored. New, long-term S2S reforecast products have recently been generated from operational global forecast models, for example as part of the S2S Project and North American Multimodel Ensemble (NMME). These are analogous to CMIP models used for climate change projection. It is now technically possible to dynamically downscale these reforecast data to CPM scale, to asess potential improvement in S2S forecast skill and create new S2S forecast metrics for extreme events. The Coordinated Regional Ensemble Downscaling Experiment (CORDEX) provides an existing robust community framework that can be leveraged to dynamically downscale S2S reforecast data, in a globally unified way. This overview presentation will highlight outcomes from a community discussion on this topic that took place at the 2019 Latsis Symposium "High-Resolution Climate Modeling: Perspectives and Challenges" at ETH Zurich, including a summary of the current state of the science, collective identification of research priorities, and proposed action items proceeding forward.

How to cite: Castro, C. L., Chang, H.-I., Prein, A. F., and Bukovsky, M.: Convective-Permitting Modeling for Retrospective Subseasonal-to-Seasonal (S2S) Forecasting Using the Framework of the Coordinated Regional Ensemble Downscaling Experiment (CORDEX) , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12667, https://doi.org/10.5194/egusphere-egu2020-12667, 2020.

EGU2020-3158 | Displays | AS1.9 | Highlight

Tropical cyclone activity prediction on subseasonal time-scales

Suzana Camargo, Chia-Ying Lee, Frederic Vitart, Adam Sobel, Michael Tippett, Shuguang Wang, and Joanne Camp

We will first examine the skill of probabilistic tropical cyclone (TC) occurrence and intensity (ACE - accumulated cyclone energy) predictions in the Subseasonal to Seasonal (S2S) dataset. We show that some of the models in the S2S dataset have skill in predicting TC occurrence 4 weeks in advance. In contrast, only one of the models (ECMWF) has skill in predicting the anomaly of TC occurrence from the seasonal climatology beyond week 1. For models with significant mean biases, calibrating the forecast can improve the models’ prediction skill. In contrast, for models with small mean biases, calibration does not guarantee an improvement in model skill as measured by the Brier Skill Score. 

We then focus only on the ECMWF model and using cluster analysis examine the sensitivity of the North Atlantic TC tracks biases to various factors, such as model resolution, lead time, and tracking. We also explore how well the ECMWF North Atlantic TC model tracks in each cluster simulate the known response to climate modes, such as ENSO and MJO. By applying simple bias corrections to each cluster of Atlantic TC tracks, we examine if we can improve the model skill in landfall prediction in the US and Caribbean.

How to cite: Camargo, S., Lee, C.-Y., Vitart, F., Sobel, A., Tippett, M., Wang, S., and Camp, J.: Tropical cyclone activity prediction on subseasonal time-scales, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3158, https://doi.org/10.5194/egusphere-egu2020-3158, 2020.

The main atmospheric teleconnection patterns in the Southern Hemisphere are the Southern Annular Mode (SAM) and the Pacific South American (PSA). The SAM has opposite atmospheric anomalies between high and middle latitudes and it is linked with the polar vortex intensity and jet streams. PSA shows a wavetrain pattern from tropical to the extratropical atmosphere over the South Pacific Ocean triggered by convection in the tropical Indian, Maritime Continent and tropical Pacific. These modes modulate the atmospheric circulation variability and have an influence on the precipitation over Southern Hemisphere continents, mainly in South America (SA). Global models are able to represent these modes in climate simulations of seasonal timescale. The objective of this study is to analyse these teleconnections in hindcasts of subseasonal timescale and the relations to precipitation anomalies over South America. Predictions in the subseasonal time scale of austral summer are very important for several sectors of Southeastern and Southern regions of SA, as these are very populated regions and have agriculture and the largest hydropower,  which are very much affected by precipitation extremes, both excess and lack of rain. Two models of the S2S project (ECMWF and NCEP) are used for the summer seasons of 1999 to 2011 and the patterns are compared to ERA5 reanalyses and GPCP data. EOF analyses of geopotential at 200 hPa and regression analyses against precipitation show the patterns and the influences over South America. The SAM pattern is represented in predictions of 1 to 4 weeks in advance, and PSA pattern, from 1 to 3 weeks in advance. Then, the atmospheric circulation and meteorological variables composites of extreme positive and negative amplitudes of SAM and PSA are analysed to interpret precipitation anomalies during these specific periods for predictions of weeks 2 and 3.

How to cite: Cavalcanti, I. and Barreto, N.: Teleconnection patterns in the Southern Hemisphere in subseasonal to seasonal models hindcasts and influences on South America, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2755, https://doi.org/10.5194/egusphere-egu2020-2755, 2020.

EGU2020-3533 | Displays | AS1.9 | Highlight

Subseasonal forecasts for humanitarian decision-making in Kenya: understanding forecast skill and the latest results from the S2S ForPAc real-time pilot study.

Dave MacLeod, Mary Kilavi, Emmah Mwangi, George Otieno, Richard Graham, and Martin Todd

In 2018 the long rains season in Kenya (March-May) was the wettest ever recorded. The country experienced several multi-day heavy rainfall episodes, leading to dam collapse, land and mudslides. 186 people died due to flooding and 300,000 were left displaced. 

The Kenya Meteorological Department issued several advisories during the season that warned of heavy rainfall events a few days before their occurrence. Ahead of this no warnings were given.

However subseasonal forecasts gave strong indications of the heaviest rainfall episodes, several weeks in advance. With this extra lead time, preparedness actions may have been taken in order to reduce flood risk and save lives. 

To this end, the ForPAc project (Toward Forecast-Based Preparedness Action) has been working in partnerships across Kenya and the UK to evaluate and build trust in subseasonal forecasts, and explore preparedness actions which could be taken in response. Most recently ForPAc has been granted access to real-time subseasonal data as part of phase two of the S2S pilot.

In this presentation we will first show analysis of the S2S hindcasts over East Africa, demonstrating the relatively high levels of subseasonal forecast skill and linking this to a strong MJO teleconnection that models capture relatively well.

In the second part we will describe work with stakeholders to co-design forecast products derived from the S2S data, concluding with a report on the forecasts for the ongoing 2020 long rains season and an evaluation of the way in which these have influenced disaster preparedness.

How to cite: MacLeod, D., Kilavi, M., Mwangi, E., Otieno, G., Graham, R., and Todd, M.: Subseasonal forecasts for humanitarian decision-making in Kenya: understanding forecast skill and the latest results from the S2S ForPAc real-time pilot study., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3533, https://doi.org/10.5194/egusphere-egu2020-3533, 2020.

EGU2020-15935 | Displays | AS1.9 | Highlight

An idealised economic assessment of a malaria early warning system based on S2S and seasonal forecasts

Adrian Tompkins, Francesca Di Giuseppe, Felipe De Jesus Colon Gonzalez, Christopher Barnard, and Pedro Maciel

EGU2020-17663 | Displays | AS1.9 | Highlight

A new approach to subseasonal multi-model forecasting: Online prediction with expert advice

David Brayshaw, Paula Gonzalez, and Florian Ziel

The benefits of multi-model combinations in climate forecasting have been previously introduced and described for different temporal scales (e.g., Siebert and Stephenson 2019, DelSole 2007, Sansom et al. 2013). Most typical combination methodologies involve weighting strategies that assign each model a constant factor, either uniformly or through a skill assessment. Given that the skill of the models can vary at different timescales, and for multiple reasons (for example, seasonally varying skill, or due to changes in the forecasting system), the fact that these weights remain constant introduces limitations.  

Within the realm of Machine Learning, a family of algorithms have been developed to perform ‘online prediction with expert advice’ (Cesa-Bianchi et al. 2006). These methods consider a set of weighted ‘experts’ (usually uniformly weighted at the start of the process) to produce subsequent predictions in which the combination or `mixture’ is updated to optimize a loss or skill function.  

These online forecasting methods potentially have several advantages for their use in climate prediction: 

  • The fact that the expert combination is updated in every forecast step allows the system to adjust in certain conditions (e.g., the ones mentioned above) to preserve skill; 
  • Since a different combination can be easily obtained for different quantiles of the predictand distribution, a robust system can be trained that maximizes skill for its full range. 
  • The risk of including incompetent or counterproductive experts is minimized by the fact that the mixture is able to adapt and discard them (or assign them minimal weights). 

Another potential application of these online prediction methods could be on the design of ‘seamless’ forecasting systems in the sub-seasonal to seasonal sense, which is of interest to several research projects such as S2S4E (https://s2s4e.eu/). For example, the system could be trained with a set of experts that include subsequent launches of a sub-seasonal forecast as well as prior launches of a seasonal forecast. If at any point there is useful information arising from the longer lead time seasonal forecast, the mixture would assign higher weights to it. 

A set of these online prediction methods have been tested within the S2S4E project and compared to more typical multi-model combination techniques to assess their usefulness for the prediction of country-level energy demand, and potentially other variables. Results show that these innovative methods exhibit significant skill improvements (higher than 5%) with respect to more standard techniques and to individual forecasting systems for lead weeks up to 4.  

How to cite: Brayshaw, D., Gonzalez, P., and Ziel, F.: A new approach to subseasonal multi-model forecasting: Online prediction with expert advice , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17663, https://doi.org/10.5194/egusphere-egu2020-17663, 2020.

EGU2020-6523 | Displays | AS1.9 | Highlight

Forecasting climate extremes to aid decisions on multi-week timescales

Catherine de Burgh-Day, Debbie Hudson, Oscar Alves, Morwenna Griffiths, Andrew Marshall, and Griffith Young

Extreme events such as droughts, heat waves and floods can have significant and long lasting financial, infrastructural and environmental impacts. While probabilistic seasonal outlooks are commonplace, there are relatively few probabilistic outlooks available on multiweek timescales. Additionally, many services focus on the middle of the distribution of possible outcomes – e.g., forecasts of probability of above or below median, or probability of mean conditions exceeding some threshold. These do not encompass the types of extreme events that can be the most damaging, such as several consecutive days of extreme heat, unusually large numbers of cold days in a season, or an extended period where rainfall is in the lowest decile of historical years.

Advance warning of extreme events that impact particular industries enable managers to put in place response measures which can help to reduce their losses. This can involve:

  • Active responses which aim to reduce the severity of the impact. For example, losses in dairy production due to extreme heat can be mitigated by adjusting grazing rotations such that cows are in shadier paddocks during these events
  • Defensive responses which aim to account for any losses incurred due to an event. For example, the purchase of new farm equipment can be deferred if a forecast extreme event indicates a likely unavoidable financial loss in the near future

To meet this need, the Australian Bureau of Meteorology is developing a suite of forecast products communicating risk of extreme events using data from the Bureau’s new seasonal forecasting system ACCESS-S. Each prototype forecast product is trialed with external users through a webpage to assess usefulness and popularity.

How to cite: de Burgh-Day, C., Hudson, D., Alves, O., Griffiths, M., Marshall, A., and Young, G.: Forecasting climate extremes to aid decisions on multi-week timescales, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6523, https://doi.org/10.5194/egusphere-egu2020-6523, 2020.

EGU2020-19129 | Displays | AS1.9 | Highlight

Understanding and forecasting the subseasonal meteorological drivers of the European electricity system in winter

Hannah Bloomfield, David Brayshaw, Andrew Charlton-Perez, Paula Gonzalez, and David Livings

Renewable electricity is a key enabling step to globally decarbonise the energy sector. Europe is at the forefront of renewable deployment and this has dramatically increased the weather sensitivity of the continent's power systems. Despite the importance of weather to energy systems, the meteorological drivers remain difficult to identify, and are poorly understood. This study presents a new and generally applicable approach, targeted circulation types (TCTs). In contrast to standard meteorological circulation typing methods, such as weather regimes, TCTs convolve the weather sensitivity of an impacted system of interest (in this case, the electricity system) with the intrinsic structures of the atmospheric circulation to identify its meteorological drivers.

A new, freely available, 38 year reanalysis-based reconstruction of daily electricity demand, wind power and solar power generation across Europe is created and used to identify the winter largescale circulation patterns of most interest to the European electricity grid. TCTs are shown to provide greater explanatory power for power system variability and extremes compared with standard weather regime analysis. Two new pairs of atmospheric patterns are highlighted, both of which have marked and extensive impacts on the European power system. The first pair resembles the meridional surface pressure dipole of the North Atlantic Oscillation, but shifted eastward into Europe and noticeably strengthened, while the second pair is weaker and corresponds to surface pressure anomalies over Central Southern and Eastern Europe. These patterns are shown to be robust features of the present-day European power system.

 The use of TCTs to increase the utility and skill of subseasonal forecasts during the winter season is discussed.  It is shown that TCTs provide additional useful information compared to standard grid-point or weather-regime techniques for applications in energy system forecasting and operations.

How to cite: Bloomfield, H., Brayshaw, D., Charlton-Perez, A., Gonzalez, P., and Livings, D.: Understanding and forecasting the subseasonal meteorological drivers of the European electricity system in winter, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19129, https://doi.org/10.5194/egusphere-egu2020-19129, 2020.

EGU2020-542 | Displays | AS1.9

Sub-seasonal Monsoon Onset forecasting over West Africa

Elisabeth Thompson, Caroline Wainwright, Linda Hirons, Felipe Marques de Andrade, and Steven Woolnough

Skilful onset forecasts are highly sought after in West Africa, due to the importance of monsoon onset for agriculture, disease prevalence and energy provision. With research on the sub-seasonal timescale bridging the gap between weather and seasonal forecasts, sub-seasonal forecasts may provide useful information in the period preceding monsoon onset. This study explores sub-seasonal monsoon onset forecasts over West Africa using three operational ensemble prediction systems (ECMWF, UKMO, and NCEP) from the Sub-seasonal to Seasonal (S2S) prediction project database in order to determine the spatial scale and lead time at which sub-seasonal forecasts can provide useful monsoon onset information. Current research and operational methods of determining onset are identified and compared. The effect of spatial averaging on onset forecasting and skill is explored by comparing regional [Coast, Forest, Transition and North] and local forecasts at 4 major cities over Ghana.

 

‘This work was supported by UK Research and Innovation as part of the Global Challenges Research Fund, African SWIFT programme, grant number NE/P021077/1’

How to cite: Thompson, E., Wainwright, C., Hirons, L., Marques de Andrade, F., and Woolnough, S.: Sub-seasonal Monsoon Onset forecasting over West Africa, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-542, https://doi.org/10.5194/egusphere-egu2020-542, 2020.

This study evaluated the basic performance of the subseasonal prediction using an ensemble hindcast runs for 20 years (1991-2010) produced by KMA GloSea5. The KMA GloSea5 is global prediction system for subseasonal-to-seasonal time scale, based on the fully-coupled atmosphere, land, ocean, and sea-ice model. To examine the fidelity of the system to reproduce and to forecast phenomena, this study focused on three important aspects: systematic biases of hindcast climatology, error diagnostics related to precipitation, and prediction skill of major climate variability. The major results show the overestimated precipitation over the western Pacific. Precipitation errors related to the enhanced convection processes, it leads to decreased incoming surface heat fluxes by clouds. As a result, SST can be decreased by cloud-radiation processes as well as ocean mixing processes. This study includes the evaluation and the identification of the systematic biases in the global prediction model. Also it focuses on the prediction skill of East Asian summer and winter monsoon with its interaction between tropics or arctic climate, which are major drivers of weather and climate variability in East Asia.

How to cite: Ham, S. and Jeong, Y.: Assessment of subseasonal prediction skill of the KMA GloSea5 hindcast experiment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4302, https://doi.org/10.5194/egusphere-egu2020-4302, 2020.

Using daily minimum temperature of 77 stations in Gansu in spring 1981-2018,temporal and spatial distribution characteristics of strong cold air are analyzed in spring in Gansu Province in the past 38 years. The frequency of strong cold air in spring in Gansu was the lowest in 1980s,it increased since the new century. Strong cold air in the whole province and Hedong area mainly appeared in March and April, The strong cold air in Hexi area is more than April and May. The frequency of strong cold air in Hexi area is two times of that in Hedong area. Using NCEP daily 500hPa height field data for 1981-2018 and quasi 150 day rhythm method, the prediction of extended period of the strong cold air in spring in Gansu province was studied. The threshold value of circulation similarity is determined , evaluation criteria and multiple screening are established. Developing  evaluation criteria and multilayer screening, and selecting 4 typical weather forecasts of strong cold air in spring in Gansu province by calculating similarity coefficients and determining thresholds. In the case of 4 typical fields being applied at the same time, the prediction accuracy is obviously improved, the null rate is reduced to zero, and the omission rate is greatly reduced, which provides a new idea for the extended forecast of the strong cold air in Gansu.

How to cite: Lin, S., Li, D., Lu, G., and Liu, W.: Application of quasi 150 day rhythm method in the prediction of strong cold air extension period in spring in Gansu Province, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4332, https://doi.org/10.5194/egusphere-egu2020-4332, 2020.

EGU2020-4337 | Displays | AS1.9

Sub-seasonal prediction of rainfall over the South China Sea and its surrounding areas during spring-summer transitional season

Qingquan Li, Juanhuai Wang, Song Yang, Fang Wang, Jie Wu, and Yamin Hu

        The sub-seasonal characteristics and prediction of rainfall over the South China Sea and surrounding areas during spring-summer transitional season (April-May-June) are investigated using a full set of hindcasts generated by the Dynamic Extended Range Forecast operational system version 2.0 (DERF2.0) of Beijing Climate Center, China Meteorological Administration. The onset and development of Asian summer monsoon and the seasonal migration of rain belt over East Asia can be well depicted by the model hindcasts at various leads. However, there exist considerable differences between model results and observations, and model biases depend not only on lead time, but also on the stage of monsoon evolution. In general, forecast skill drops with increasing lead time, but rises again after lead time becomes longer than 30 days, possibly associated with the effect of slowly-varying forcing or atmospheric variability. An abrupt turning point of bias development appears around mid-May, when bias growths of wind and precipitation exhibit significant changes over the northwestern Pacific and South Asia, especially over the Bay of Bengal and the South China Sea. This abrupt bias change is reasonably captured by the first two modes of multivariate empirical orthogonal function analysis, which reveals several important features associated with the bias change. This analysis may provide useful information for further improving model performance in sub-seasonal rainfall prediction.

How to cite: Li, Q., Wang, J., Yang, S., Wang, F., Wu, J., and Hu, Y.: Sub-seasonal prediction of rainfall over the South China Sea and its surrounding areas during spring-summer transitional season, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4337, https://doi.org/10.5194/egusphere-egu2020-4337, 2020.

EGU2020-5413 | Displays | AS1.9

Using a statistical model to verify warm conveyor belts in ECMWF’s sub-seasonal forecasts

Julian F. Quinting, Jan Wandel, Dominik Büeler, and Christian M. Grams

Rapidly ascending air streams in midlatitude cyclones – so-called warm conveyor belts (WCBs) – affect the lifecycle of blocking anticyclones. WCBs are usually identified by selecting coherent bundles of rapidly ascending trajectories. Their calculation, however, requires data at a high spatio-temporal resolution and is computationally expensive. To identify WCBs in expansive data sets such as ensemble reforecasts or climate model projections, alternative approaches are necessary. 


In this study we introduce a logistic regression model which is capable of identifying the inflow, ascent, and outflow phase of WCBs based on Eulerian input parameters. Validation against a Lagrangian-based dataset confirms that the logistic model is reliable in replicating the climatological frequency of WCBs as well as the footprints of WCBs at instantaneous time steps. 


Second, we employ the statistical model to verify the representation of WCBs in ECMWF’s sub-seasonal reforecasts. Overall the reforecasts depict frequencies of WCBs across seasons relatively well at all lead times. A correction of biases in the meteorological parameters for the logistic model partly removes existing biases in the reforecast WCB climatology. However, the bias-corrected  forecast skill still rapidly decays leaving useful skill only up to around day 8. These results corroborate that synoptic-scale activity might hinder accurate forecasts into sub-seasonal time scales for the extratropical large-scale circulation. Future work will elucidate if and in which situation poor skill for WCBs dilutes skill for Atlantic-European weather regimes on sub-seasonal time scales.

How to cite: Quinting, J. F., Wandel, J., Büeler, D., and Grams, C. M.: Using a statistical model to verify warm conveyor belts in ECMWF’s sub-seasonal forecasts, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5413, https://doi.org/10.5194/egusphere-egu2020-5413, 2020.

EGU2020-6838 | Displays | AS1.9

Enhanced extended-range predictability of the 2018 late-winter Eurasian cold spell due to the stratosphere

Lisa-Ann Kautz, Inna Polichtchouk, Thomas Birner, Hella Garny, and Joaquim Pinto

A severe cold spell with surface temperatures reaching 10 K below climatology hit Eurasia during late February/early March 2018. This cold spell was associated with a Scandinavian blocking pattern followed by an extreme negative North Atlantic Oscillation (NAO) phase. Here we explore the predictability of this cold spell/NAO event using ensemble forecasts from the Subseasonal-to-Seasonal (S2S) archive. We find that this event was predicted with the observed strength roughly 10 days in advance. However, the probability of occurrence of the cold spell was doubled up to 25 days in advance, when a sudden stratospheric warming (SSW) occurred. Our results indicate that the amplitude of the cold spell was increased by the regime shift to the negative NAO phase at the end of February, which was likely favored by the SSW. We quantify the contribution of the SSW to the enhanced extended-range forecast skill for this particular event by running forecast ensembles in which the evolution of the stratosphere is nudged to a) the observed evolution, and b) a time invariant state. In the experiment with the observed stratospheric evolution nudged, the probability of occurrence of a strong cold spell is enhanced to 45%, while it is at its climatological value of 5% when the stratosphere is nudged to a time invariant state. These results showing enhanced predictability of surface extremes following SSWs extend previous observational evidence, which is mostly based on composite analyses, to a single event. Our results support that it is the subsequent evolution throughout the lower stratosphere following the SSW, rather than the occurrence of the SSW itself, that is crucial in coupling to large-scale tropospheric flow patterns. However, we caution that probabilistic gain in predictability alone is insufficient to conclude about a causal link between the SSW and the cold spell event.

 

How to cite: Kautz, L.-A., Polichtchouk, I., Birner, T., Garny, H., and Pinto, J.: Enhanced extended-range predictability of the 2018 late-winter Eurasian cold spell due to the stratosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6838, https://doi.org/10.5194/egusphere-egu2020-6838, 2020.

EGU2020-21676 | Displays | AS1.9

Evaluation of systematic biases and skill of summer subseasonal forecasts in the ECMWF system

Frederico Johannsen, Emanuel Dutra, and Linus Magnusson

Subseasonal forecasts (ranging between 2 weeks and 2 months) have been the subject of attention in many operational weather forecasts centers and by the research community in recent years. This growing attention stems from the value of these forecasts for society and from the scientific challenges involved. The scientific challenges of capturing and representing key processes and teleconnections which are relevant at these scales are significant. One example is temperature extremes associated with weather extremes like heatwaves and droughts that can have severe consequences in nature and human health, among others. Some of the limitations in forecast skill arise from the limits of predictability of the chaotic earth system. Model error is also likely to play a relevant role. In this study, we investigate systematic model biases, their evolution with lead time and potential links with forecast skill.

This study assessed the skill and biases of the European Centre for Medium-Range Weather Forecasts (ECMWF) subseasonal forecast in predicting the daily temperature extremes in the Northern Hemisphere. These forecasts are from an experimental setup of ECMWF extended-range forecast system. The forecasts compromise 11 ensemble members with weekly starting dates between 9 April to 30 July extending up to 6 weeks lead with a 20-years hindcast period (1998-2017). The forecasts were performed by the coupled ECMWF systems with TcO199 horizontal resolution (about 50km) in the atmosphere and 1x1 degree ocean. A particular focus is given to Europe and to two other regions that were identified with large systematic errors. The data used in this work consisted of the daily maximum and minimum two-meter temperature, precipitation and other surface fluxes that are aggregated into weekly means and verified against ERA5. 

The evaluation of systematic biases in daily temperature extremes shows a clear increase with lead time, which is widespread on a hemispheric scale. The spatial patterns of model error growth with lead time are reasonably similar between daily maximum and minimum temperatures. However, the amplitude of the errors is remarkably different with general cold bias of daily maximum and warm bias of daily minimum that consistently grow with forecast lead time. Despite the consistent error growth with lead time, there are clear differences between the forecasts initialized in late Spring (April-May) and those in Summer (June-July). These biases are not fully collocated in two regions in the Northern Hemisphere showing the largest warm temperature biases: Central US and East of Caspian Sea. The warm biases are consistent with an underestimation of precipitation and dry soil moisture, compared to ERA5, but only over the East Caspian region.  Forecasts skill assessed via the anomaly correlation shows that the temperature forecasts are skillful up to week 2, with a drop in skill from week 3 onwards. This drop in skill is consistent over all the European domain. Similar results are found for precipitation, but with ACC at week 2 comparable with those of temperature at week 3. 

How to cite: Johannsen, F., Dutra, E., and Magnusson, L.: Evaluation of systematic biases and skill of summer subseasonal forecasts in the ECMWF system , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21676, https://doi.org/10.5194/egusphere-egu2020-21676, 2020.

EGU2020-20246 | Displays | AS1.9 | Highlight

Seasonal forecast of water resources over the Euro-Mediterranean region

Gildas Dayon, François Besson, Jean-Michel Soubeyroux, Chrisitian Viel, and Paola Marson

In the framework of the MEDSCOPE project, a forecasting chain is developed at Météo-France for hydrological long term predictions over the Euro-Mediterranean region, from one month up to seven months. This new prototype is based on the Météo-France System 6 global seasonal forecast system. Atmospheric forecasts are interpolated to 5.5 km and corrected by the statistical method ADAMONT using the UERRA regional atmospheric reanalysis as reference. These high resolution forecasts drive the physically-based model SURFEX coupled to CTRIP providing seasonal forecasts of surface variables : river discharges, soil wetness indices, snow water equivalent.

A forecast using the climatology (ESP approach) has been produced on the period 1993-2016. It is use to explore the sources of predictability in the different watersheds (Ebro, Po, Rhône). Predictability is mostly coming from the snow pack built during the winter and the soil moisture evolution in spring and summer. A hindcast on the period 1993-2016 is produced to assess the added value of the seasonal forecast compared to the climatology for the end-users in agriculture and energy.

How to cite: Dayon, G., Besson, F., Soubeyroux, J.-M., Viel, C., and Marson, P.: Seasonal forecast of water resources over the Euro-Mediterranean region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20246, https://doi.org/10.5194/egusphere-egu2020-20246, 2020.

EGU2020-19133 | Displays | AS1.9

Promising subseasonal forecasting results based on machine learning

Matti Kämäräinen

A purely statistical machine learning (ML) approach was applied to forecast near-surface temperature and precipitation anomalies over land areas in the Northern Hemisphere and Tropics. A high number of principal components (PCs) from the key variables, most importantly sea surface temperatures and the near-tropopause geopotential from reanalyses, was used as predictors to forecast the 2-weekly mean predictand anomalies in each location. Separate models were fitted for different seasons and lead times in the range of 1–6 weeks.

To select and weight the predictors and to reduce the risk of overfitting, such ML methods as least absolute shrinkage and selection operator (LASSO) regularization and ensembling based on random sampling of the predictor data were used in addition to the dimensionality reduction with PCs.


Skill analysis of the independent test sample results show that both the climatological and persistence reference forecasts were inferior compared to the ML approach on average, with all lead times, and in the majority of the target grid cells. Also, the ML approach achieved a skill that was generally comparable to the European Centre for Medium-Range Weather Forecasts (ECMWF) dynamical model.

 

Previously, these particular ML methods have been shown to work in a regional approach in Europe for seasonal time scales. According to the new results, they also work in the near-global domain and in the challenging subseasonal time scales.

How to cite: Kämäräinen, M.: Promising subseasonal forecasting results based on machine learning, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19133, https://doi.org/10.5194/egusphere-egu2020-19133, 2020.

EGU2020-18021 | Displays | AS1.9

Sub-seasonal prediction of Arctic sea ice concentration using time series forecasting technique

Baek-Min Kim, Ha-Rim Kim, Yong-Sang Choi, Yejin Lee, and Gun-Hwan Yang

Recently, many studies have highlighted the importance of the ability to predict the Arctic sea ice concentration in the sub-seasonal time scales. Notably, the Arctic sea ice concentration has a potential for skillful predictions through their long-term trend memory. Based on the long-term memory of Arctic sea ice concentration, we evaluate the predictability of Arctic sea ice concentration (SIC) by applying a time-series analysis technique of the Prophet model on sub-seasonal time scales. A Prophet is a recently introduced method as a statistical approach inspired by the nature of time series forecasted at Facebook and has not been applied to the prediction of Arctic SIC before. Sub-seasonal prediction skills of Arctic SIC in the Prophet model were compared with the NCEP Climate Forecast System Reforecast (CFS-Reforecast) model as a dynamical approach and verified with the satellite observation during wintertime from 2000 to 2018 for 1 to 8 weeks lead times. The result shows that the Prophet model exhibits much better skill than the NCEP CFS-Reforecast model in the climatology prediction except for the 1 to 3 weeks lead times, as the Prophet model has mainly the ability to capture the long-term trend. In the anomaly prediction, however, the NCEP CFS-Reforecast model is superior to the Prophet model in the prediction of sub-seasonal time scales, as the NCEP CFS-Reforecast captures more effectively the sub-seasonal transition of the underlying dynamical system. Therefore, even if the Prophet model has shown a useful skill in predicting the climatological Arctic SIC, there is still a need to improve the accuracy and robustness of the predictions in an anomalous Arctic SIC. Further, we suggest that the bias correction method is needed to improve the forecast skill of Arctic SIC using the time-series analysis technique, and it will be critical to advance the field of the Arctic SIC forecasting on the sub-seasonal time scales.

How to cite: Kim, B.-M., Kim, H.-R., Choi, Y.-S., Lee, Y., and Yang, G.-H.: Sub-seasonal prediction of Arctic sea ice concentration using time series forecasting technique, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18021, https://doi.org/10.5194/egusphere-egu2020-18021, 2020.

EGU2020-8775 | Displays | AS1.9

Analysis of the Dominant Spatial Patterns of Summer Precipitation and Circulation Characteristics in Northwest China

liwei liu, guoyang lu, dong wei, danhua li, xing wang, and fan wang

In recent years, the summer rainfall shows an increasing trend in Northwest China. Based on the NCEP/NCAR reanalysis data, the RESST data from NOAA and the precipitation data from 351 meteorological observation stations in Northwest China from 1981-2018, the dominant modes of summer precipitation anomalies, the corresponded circulation characteristic and the main influence systems were analyzed by diagnostic methods. There were three dominant EOF modes about summer rainfall, the first one showed the same anomaly in whole region, the second showed a inverse pattern between the east and west, and the third showed the opposite anomaly between the south and north. The variance contribution of the first mode accounted for 20% and the first mode was represented as the primary mode in the subsequent analysis. The high impact region of circulation which affected the precipitation in Northwest China was the middle and high latitudes area of Eurasia and the subtropical area: for the first mode’s positive phase, the 500hPa height field showed a "+ - +" distribution in the middle latitude of Eurasia, while on the 200hPa wind field, there was an anticyclone near the Ural and a cyclone near Lake Baikal, it also has an anticyclone on the Chinese mainland, this configuration will facilitates the strengthening of westerly jets. The tropical Pacific and the North Atlantic are the main external forcing signals of the circulation pattern: SST characteristics showed that the negative phase of the North Atlantic SST Tripole in spring, from winter of the previous year to summer of the current year, SST of the equatorial Middle East Pacific developed from warm to cold. The distribution of 500 hPa height field corresponding to the main mode of summer precipitation in Northwest China is similar to that of EU remote correlation type. An index(IHgt) was defined to reflect circulation patterns in mid-latitude and subtropical regions, when the index is positive/negative, most of the precipitation in northwest China is more/less. After 2000, the correlation between the two increased significantly. Given the performance of the IHgt index in describing the summer precipitation, it could be used as a good indicator in the monitoring and prediction of the summer precipitation in Northwest China.

How to cite: liu, L., lu, G., wei, D., li, D., wang, X., and wang, F.: Analysis of the Dominant Spatial Patterns of Summer Precipitation and Circulation Characteristics in Northwest China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8775, https://doi.org/10.5194/egusphere-egu2020-8775, 2020.

EGU2020-5619 | Displays | AS1.9

Heatwaves over Europe: Identification and connection to large-scale circulation

Emmanuel Rouges, Laura Ferranti, Holger Kantz, and Florian Pappenberger

                Heat waves have important impacts on society and our environment. In Europe for instance, the summer of 2003 caused upwards of 40000 fatalities. They also impact the crop production, ecosystems, and infrastructures. In a warming climate, heat wave intensity and frequency are likely to increase with potentially more dramatic consequences.

                Considering this, it is crucial to forecast such extreme events and therefore gain a better understanding of their triggering processes. The determination of these processes requires to identify heat wave patterns (timing and location) together with the correlated large-scale circulation patterns. This will enable to devise early warning systems, that could help mitigate the impact.

                This work is part of an ongoing PhD project focusing on improving the forecast of heat waves at sub-seasonal time scale. The main objectives are to evaluate the link between large scale weather patterns and severe warm events over Europe and measure current level of predictive skill. The first part will focus on defining an objective criteria to identify heat wave events in the ERA5 reanalaysis dataset from ECMWF. The identification of heat waves depends on three main criteria: temperature threshold, spatial and temporal extension. Meaning that the temperature should exceed a defined threshold over a large enough region and for a long enough period. We will consider daily means as well as maximum and minimum values of 2m temperature. We will identify the circulation patterns (persistent high pressure systems) associated with heat wave events and analyse the key differences with persistent high pressure systems that are not associated with heat waves.

                This work is part of the Climate Advanced Forecasting of sub-seasonal Extremes (CAFE) project, funded by the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grand agreement No 813844.

How to cite: Rouges, E., Ferranti, L., Kantz, H., and Pappenberger, F.: Heatwaves over Europe: Identification and connection to large-scale circulation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5619, https://doi.org/10.5194/egusphere-egu2020-5619, 2020.

EGU2020-11067 | Displays | AS1.9

Importance of Stratospheric Polar Vortex Events for Seasonal Predictability of Sea Level Pressure over the North Atlantic and Europe

Johanna Baehr, Simon Wett, Mikhail Dobrynin, and Daniela Domeisen

The downward influence of the stratosphere on the troposphere can be significant during boreal winter when the polar vortex is most variable, when major circulation changes in the stratosphere can impact the tropospheric flow. These strong and weak vortex events, the latter also referred to as Sudden Stratospheric Warmings (SSWs), are capable of influencing the tropospheric circulation down to the sea level on timescales from weeks to months. Thus, the occurrence of stratospheric polar vortex events influences the seasonal predictability of sea level pressure (SLP), which is, over the Atlantic sector, strongly linked to the North Atlantic oscillation (NAO).
We analyze the influence of the polar vortex on the seasonal predictability of SLP in a seasonal prediction system based on the mixed resolution configuration of the coupled Max-Planck-Institute Earth System Model (MPI-ESM), where we investigate a 30 member ensemble hindcast simulation covering 1982 -2016. Since the state of the polar vortex is predictable only a few weeks or even days ahead, the seasonal prediction system cannot exactly predict the day of occurrence of stratospheric events. However, making use of the large number of stratospheric polar vortex events in the ensemble hindcast simulation, we present a statistical analysis of the influence of a correct or incorrect prediction of the stratospheric vortex state on the seasonal predictability of SLP over the North Atlantic and Europe.

How to cite: Baehr, J., Wett, S., Dobrynin, M., and Domeisen, D.: Importance of Stratospheric Polar Vortex Events for Seasonal Predictability of Sea Level Pressure over the North Atlantic and Europe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11067, https://doi.org/10.5194/egusphere-egu2020-11067, 2020.

EGU2020-735 | Displays | AS1.9

Is Tuning of Auto-conversion Important for the Realistic Simulation of Indian Summer Monsoon Intraseasonal Oscillations and MJO in Coupled Climate Model?

Ushnanshu Dutta, Anupam Hazra, Hemantkumar Chaudhari, Subodh Kumar Saha, and Samir Pokhrel

 

 

How to cite: Dutta, U., Hazra, A., Chaudhari, H., Saha, S. K., and Pokhrel, S.: Is Tuning of Auto-conversion Important for the Realistic Simulation of Indian Summer Monsoon Intraseasonal Oscillations and MJO in Coupled Climate Model?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-735, https://doi.org/10.5194/egusphere-egu2020-735, 2020.

The WWRP/WCRP Sub-seasonal to Seasonal Prediction (S2S) database contains real-time and re-forecasts from 11 operational centres. Several S2S models are initialized frequently with a small ensemble size (e.g. 4 ensemble members every day). In order to inflate the ensemble size, real-time forecasts are produced by combining all the forecasts produced over a window of several days to produce a “lagged ensemble” in which ensemble members have different lead times. The other S2S models are initialized less frequently (e.g. once or twice a week) but with a large ensemble size (e.g. 51 members). This initialization strategy is referred to as “burst sampling”. Both strategies have advantages and inconvenience and it is not clear which strategy is optimal for sub-seasonal prediction. 
The ECMWF sub-seasonal forecasts are produced using the burst-sampling strategy: a 51-member ensemble is run twice a week (every Monday and Thursday). A large set of re-forecasts, run on a daily basis, have been produced to assess the potential benefit of replacing this current ensemble configuration by a lagged-ensemble approach. We are interested in answering the following two questions, if the current 51-member ensemble run twice a week is replaced by a sub-seasonal ensemble run every day with an ensemble size Ne:

• What is the minimum value of Ne so that there is a lagged ensemble forecast (Nd forecast days combined) which is at least as skilful as the current system on Mondays and Thursdays?

• For a given value of Ne, what is the optimal number Nd of forecast days to combine? Greater values of Nd produce larger lagged ensemble size, but also reduce the accuracy of the forecasts by adding ensemble members with older start dates. 

Results indicate that:

1. A lagged ensemble is more beneficial in the Tropics than in the Northern Extratropics particularly for shorter lead times (weeks 1 and 2).  

2. The minimum daily ensemble size to produce sub-seasonal forecasts (beyond week 1) at least as skilful as the current ECMWF forecasts on Mondays and Thursdays is Ne=20 with an optimal number of lag days Nd=3. The values of Ne (Nd) decrease (increase) with increased lead time. 

These results suggest that a lagged-ensemble could be a viable alternative to the current ensemble extended-range forecasting system at ECMWF. 

How to cite: Vitart, F.: Lagged ensemble vs burst sampling strategy for initializing sub-seasonal forecasts, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2680, https://doi.org/10.5194/egusphere-egu2020-2680, 2020.

EGU2020-1398 | Displays | AS1.9

Impact of atmospheric quasi-biweekly oscillation on the persistent heavy PM2.5 pollution over Beijing-Tianjin-Hebei region, China during winter

Libo Gao, Tijian Wang, Xuejuan Ren, Bingliang Zhuang, Shu Li, Ruan Yao, and Xiuqun Yang

In recent years, persistent heavy air pollution (PHP) events occurred frequently over the Beijing-Tianjin-Hebei (BTH) region in China, which posed a great threat to human health. The pollution was characterized by fine particulate matter smaller than 2.5 μm in diameter (PM2.5). This study investigates the evolution of PHP over the BTH region and its relation to the atmospheric quasi-biweekly oscillation in winters of 2013–2017. A PHP event is defined as three or more consecutive days with daily mean PM2.5 concentration exceeding 150 μg m-3. We observed a significant periodicity of 10–16 days of the PM2.5 concentration, which notably contributes to the occurrence of PHP. According to the quasi-biweekly variation of PM2.5, the life cycle of PHP events are divided into eight phases. The phase composites of circulation anomalies show that the atmospheric quasi-biweekly oscillation provides favorable conditions for the persistence of wintertime PM2.5 pollution. During the PHP events, the quasi-biweekly southerly anomalies prevail persistently over eastern China. The East Asian winter monsoon is weakened and more moisture is transported to the BTH region continuously. The anomalous warming in the lower troposphere indicates a stable stratification on the quasi-biweekly time scale. In the mid-troposphere, the oscillation of East Asian trough’s intensity is significantly correlated with the PHP events. Further lead-lag correlation analysis suggested that the quasi-biweekly oscillation of East Asian trough can be traced back to a precursor signal over northwestern Eurasia about 11 days earlier, through a southeastward wave train propagation. Therefore, the meteorological conditions conducive to PHP over the BTH region can be predicted on the quasi-biweekly time scale.

How to cite: Gao, L., Wang, T., Ren, X., Zhuang, B., Li, S., Yao, R., and Yang, X.: Impact of atmospheric quasi-biweekly oscillation on the persistent heavy PM2.5 pollution over Beijing-Tianjin-Hebei region, China during winter, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1398, https://doi.org/10.5194/egusphere-egu2020-1398, 2020.

EGU2020-1859 | Displays | AS1.9

Sub-seasonal precipitation forecast skills over China during the boreal summer monsoon

Yuan Li, Zhiyong Wu, Hai He, Qj Wang, Conrad Wasko, Tianyi Li, and Guihua Lu

Sub-seasonal precipitation forecasts during the boreal summer monsoon season are very valuable for flood and drought mitigation over China. Here, we evaluate the sub-seasonal precipitation forecast skills of 11 dynamic models from the Sub-seasonal to Seasonal (S2S) Prediction Project at various spatial and temporal scales. For ensemble mean forecasts, most models show significant correlations with observations at both grid and basin scales with lead time up to 2 weeks. When the lead time is beyond week-2, significant correlations are only observed over southeast and western China at the grid scale. Spatial aggregation helps improve week-3-4 average forecast skills at basin scales; significant correlations can be found for all hydroclimatic regions over China. For ensemble forecasts, most S2S models produce skilful forecasts at basin scale as measured by discrimination scores. Both the El Niño-Southern Oscillation (ENSO) and the Madden-Julian Oscillation (MJO) have an impact on precipitation forecast skills at week-3-4. In particular, forecast skill improvement is most pronounced when the forecasts are initialized during active MJO center located in Maritime Continent (Phase 4~5). The results here will help inform the usefulness of sub-seasonal forecasts for hydrological modelling for drought and flood mitigation.

How to cite: Li, Y., Wu, Z., He, H., Wang, Q., Wasko, C., Li, T., and Lu, G.: Sub-seasonal precipitation forecast skills over China during the boreal summer monsoon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1859, https://doi.org/10.5194/egusphere-egu2020-1859, 2020.

EGU2020-4059 | Displays | AS1.9

Simulating extreme precipitation over the Arabian Peninsula using a convective-permitting sub-seasonal reforecast product

Thang M. Luong, Christoforus Bayu Risanto, Hsin-I Chang, Hari Prasad Dasari, Raju Attada, Christopher L. Castro, and Ibrahim Hoteit

Despite being one of the driest places in the world, the Arabian Peninsula (AP) occasionally experiences extreme precipitation events associated with organized convections. On 25 November 2009, for instance, a cutoff low driven rainfall exceeding 140 mm over a 6-hour period triggered a flash flood event in Jeddah, Saudi Arabia, claiming hundreds of lives and substantially damaging infrastructure. Similar extreme precipitation events have occurred in subsequent years. To assess the potential predictability of extreme precipitation in the Arabian Peninsula, we perform retrospective forecast simulations for several extreme events occurring over the period 2000 to 2018, out to a sub-seasonal timescale (3-4 weeks). Using the Advanced Research version of Weather Research and Forecasting Model (WRF-ARW), we dynamically downscale 11 ensemble members of the European Centre for Medium-Range Weather Forecasts (ECMWF) sub-seasonal reforecasts at convective-permitting resolution (4 km). WRF simulated precipitation is evaluated against various precipitation products, including the Global Precipitation Measurement (GPM) system, Climate Prediction Center morphing technique (CMORPH), and the Saudi Ministry of Water and Electricity(MOWE) and the Presidency of Meteorology and Environment(PME) regional rain gauge measurements. The convective-permitting WRF simulations substantially improve the representation of precipitation relative to the ECMWF reforecast, in terms of spatial distribution and timing. A specific focus in the presentation of the results will be on the potential value added by the use of convective-permitting modeling (CPM) to forecasting extreme events at sub-seasonal timescales. The predictability of the synoptic pattern could be the key for CPM sub-seasonal-type forecast for the AP.

How to cite: Luong, T. M., Risanto, C. B., Chang, H.-I., Dasari, H. P., Attada, R., Castro, C. L., and Hoteit, I.: Simulating extreme precipitation over the Arabian Peninsula using a convective-permitting sub-seasonal reforecast product, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4059, https://doi.org/10.5194/egusphere-egu2020-4059, 2020.

EGU2020-2785 | Displays | AS1.9

Sub-seasonal prediction of the extreme weather conditions associated with the northeastern Australia floods in February 2019

Tim Cowan, Matthew Wheeler, Morwenna Griffiths, Catherine de Burgh-Day, and Matthew Hawcroft

In late January to early February 2019, wide-spread flooding, strong winds and relatively cold temperatures over the north-eastern Australian state of Queensland led to the loss of an estimated 625,000 cattle and 48,000 sheep. The system that caused these impacts was a quasi-stationary monsoon depression that lasted close to 10 days, bringing weekly rainfall totals above 1000 mm in some locations, maximum temperatures 8–12°C below average, and sustained wind speeds of 30-40 km/h. The same weather event caused inundation and damage to more than 3000 homes over the eastern Queensland coastal city of Townsville with an insurance cost of over $1.2 billion AUD (https://www.afr.com/companies/financial-services/insurers-reveal-townsville-flood-cost-warn-region-is-unprofitable-20190804-p52do5). Observations and reanalysis confirm that an active Madden-Julian Oscillation pulse stalled over the western Pacific during the period of the flooding. To the south, a blocking anticyclone over the northern Tasman Sea promoted onshore easterly flow, and with it, the relatively low apparent temperatures (Cowan et al. 2019).

In the days before the event, the Australian Bureau of Meteorology issued the monthly rainfall outlook for February which provided little indication of the upcoming extreme event. At the time of the event, there was a 50% chance of an El Niño developing during the boreal spring, meaning a tendency towards warmer and drier conditions across the northeast. Here we show that forecasts from the Bureau's newly developed dynamical subseasonal-to-seasonal (S2S) prediction system – Australian Community Climate Earth-System Simulator Seasonal version 1 (ACCESS-S1) – of the weekly-averaged conditions were more skilful. The ACCESS-S1 99-member ensemble forecast a more than doubling of the probability of extreme weekly rainfall totals a week prior to the floods, along with increased probabilities of extremely low maximum temperatures and high winds. Ensemble-mean weekly rainfall amounts, however, were considerably underestimated by ACCESS-S1, even in forecasts initialised at the start of the peak flooding week. This is consistent with other state-of-the-art dynamical S2S prediction systems. Yet one individual ensemble member of ACCESS-S1 managed to forecast close to 85% of the rainfall magnitude across the most heavily impacted region of northwest Queensland in a week 2 forecast. This suggests current S2S prediction systems like ACCESS-S1 are capable at getting close to predicting record-breaking events with at least one week's lead-time. It also appears that accurate prediction beyond two weeks (i.e., a week 3 forecast) of an event like the northern Queensland floods is more difficult to achieve.

Reference:

Cowan et al. (2019): Forecasting the extreme rainfall, low temperatures, and strong winds associated with the northern Queensland floods of February 2019, Weather and Climate Extremes, 26, 100232, https://doi.org/10.1016/j.wace.2019.100232.

How to cite: Cowan, T., Wheeler, M., Griffiths, M., de Burgh-Day, C., and Hawcroft, M.: Sub-seasonal prediction of the extreme weather conditions associated with the northeastern Australia floods in February 2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2785, https://doi.org/10.5194/egusphere-egu2020-2785, 2020.

The Quasi-Biweekly Oscillation (QBWO) mode with 10-20-day time scale over the tropical western Pacific (TWP) in boreal winter (December-February), characterized by westward-northwestward propagation from the dateline to the east coast of Philippines (EPH) identified by the first two EEOF modes, is investigated based on the daily mean OLR and ERA-Interim reanalysis datasets from 1979 to 2015. The suppressive (active) QBWO-related convection heating located near EPH at peak day (day 0), results in anomalous divergence (convergence) wind to the south of Japan at upper troposphere due to the heat release. The divergent circulations can advect climatological absolute vorticity, then leads to positive (negative) Rossby wave source, which could propagate eastward. Therefore, a Rossby wave train (RWT) with equivalent barotropical structure over Pacific originated from the south of Japan is observed one/two days later. This wave train propagates northeastward into Alaska and then southeastward into southern North America. The meridional wind associated with the cyclonic/anticyclonic anomalies of RWT advects climatological thermal condition dominating the local temperature tendency over North America. Thus, a significant warming (cooling) over central North America is found at day +4 consistent to the anomalous southerlies (northerlies). In addition, both the barotropical energy conversion (CK) and baroclinic energy conversion (CP) contribute to the RWT on a time scale of 10-20 days maintained against dissipation.

How to cite: Dong, Z. and Wang, L.: Quasi-Biweekly Oscillation over the tropical western Pacific in boreal winter: Its climate influences on North America, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3835, https://doi.org/10.5194/egusphere-egu2020-3835, 2020.

Subseasonal prediction skill of precipitation is typically low. Sometimes, however, forecasts are accurate and it would be useful to end-users to assess a priori if this might be the case. We use a 20-year hindcast data set of the ECMWF S2S prediction system and identify periods of high forecast confidence, evaluating model skill of precipitation forecasts for these periods compared to lower confidence predictions.

From reanalysis data, we derive a set of circulation patterns, called archetypes, that represent the broad-scale atmospheric circulation over Australia. These archetypes are combinations of ridges and troughs, and yield different precipitation patterns depending on the location of these features. In the literature, a typical application of circulation patterns is assigning daily reanalysis fields to the closest-matching pattern, thus obtaining conditional distributions of precipitation corresponding to key modes of atmospheric variability. A problem common to such analyses is that the precipitation distributions associated with the circulation patterns can be too similar; distinct distributions are required in order for the patterns to be useful in estimating precipitation. We show that by subsampling the archetype occurrences only when they are particularly well-matched to the underlying field, the conditional precipitation distributions become more distinct.

We subsample hindcast fields in the same way, obtaining a sample of periods when the model is confident about its prediction of the upcoming archetype. We then calculate model skill in predicting precipitation for three regions in southern Australia during such periods compared to when the model is not confident about the predicted archetype. Our results suggest that during periods of forecast confidence, precipitation skill is greater than normal for shorter leads (up to ten days) in two of the three regions (the Murray Basin and Western Tasmania). Skill for the third region (Southwest Western Australia) is greater during confident periods for lead times greater than one week, although this is marginal.

How to cite: Richardson, D., Risbey, J., and Monselesan, D.: Identifying periods of forecast model confidence for improved subseasonal prediction of precipitation in southern Australia, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1981, https://doi.org/10.5194/egusphere-egu2020-1981, 2020.

EGU2020-2454 | Displays | AS1.9

The influence of aggregation and statistical post-processing on the sub-seasonal predictability of European temperatures

Chiem van Straaten, Kirien Whan, Dim Coumou, Bart van den Hurk, and Maurice Schmeits

The succession of European surface weather patterns has limited predictability because disturbances quickly transfer to the large scale flow. Some aggregated statistic however, like the average temperature exceeding a threshold, can have extended predictability when adequate spatial scales, temporal scales and thresholds are chosen. This study benchmarks how the forecast skill horizon of probabilistic 2-meter temperature forecasts from the ECMWF sub-seasonal forecast system evolves with varying scales and thresholds. We apply temporal aggregation by rolling window averaging and spatial aggregation by hierarchical clustering. We verify 20 years of re-forecasts against the E-OBS data set and find that European predictability extends at maximum up to week 4. Simple aggregation and standard statistical post-processing extend the forecast skill horizon with two and three skillful days on average, respectively.
The intuitive notion that higher levels of aggregation capture the larger scale and lower frequency variability and therefore tap into an extended predictability, holds in many cases. However, we show that the effect can saturate and that regional optimums exist, beyond which extra aggregation reduces the forecast skill horizon. We expect that such windows of predictability result from specific physical mechanisms that only modulate and extend predictability locally. To optimize sub-seasonal forecasts for Europe, aggregation should in certain cases thus be limited.

How to cite: van Straaten, C., Whan, K., Coumou, D., van den Hurk, B., and Schmeits, M.: The influence of aggregation and statistical post-processing on the sub-seasonal predictability of European temperatures, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2454, https://doi.org/10.5194/egusphere-egu2020-2454, 2020.

Damages in cities resulting from climate change are made irregularly and untypically, thus difficult to predict due to heavily concentrated buildings and population, etc. This study aims to introduce the results of our Urban Climatic Environment Assessment Model System(Model System hereinafter) as well as its construction, which is designed to provide impact assessment of heat waves in cities, to reduce damages, and to build capacities against it.

Our Model System is based on the Unified Model(UM : an integrated model of Korea Meteorological Administration), and satellite data is necessary to verify the Model System. However, we have developed high resolution (10m ~ 100m) urban assessment model to analyze the impacts of heat waves in city of Gwangju to help local government by developing and implementing environmental policies. The outputs of our Model System will contribute to the decision making.

Following two approaches were considered for impact assesment. Firstly, high spatial resolution model (in 10m to 100m level) using ensemble and down-scaling techniques can help identification of vulnerable areas in the city. Also, analyzed data can be linked to local GIS and land use map for analysis and assessment of the heat waves, which enables to make 48h heat wave forecast.

Secondly, CFD micro-scale analysis using super-computer enables to analyze the vulnerable areas with components of : temperature, wind, humidity, solar radiation quantity, cloud cover, etc. Data achieved via our Model System will be used as objective and scientific basis for developing heat wave policies. It will also give guidance for heat wave early warning.

It is expected that local governments can utilize our Model System to identify and analyze patterns and characteristics of heat waves in the city, and make decisions and develop environment-related policies on the objective and scientific basis preemptive response for vulnerable areas in the region.

Keywords : heat waves, Urban Climatic Environment Assessment Model System, spatial resolution, ensemble average, down-scaling, CFD, micro-scale, Early warning system

 

* This research was supported by a grant from Research Program funded by International Climate & Environment Center(ICEC).

How to cite: Oh, B., Hwang, C., Yun, W., and Kim, J.: A Study on the Operation of Early Warning System for Heat Waves in Gwangju Based on the Urban Climatic Environment Assessment Model System, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3238, https://doi.org/10.5194/egusphere-egu2020-3238, 2020.

EGU2020-5662 | Displays | AS1.9

Flow-dependent sub-seasonal forecast skill for Atlantic-European weather regimes

Dominik Büeler, Julian F. Quinting, Jan Wandel, and Christian M. Grams

The continuous increase of computational power and improvement of numerical weather prediction systems in recent decades has allowed extending the operational weather forecast horizon into sub-seasonal time scales (10 – 60 days). On these scales, quasi-stationary, persistent, and recurrent large-scale flow patterns, so-called weather regimes, explain most of the regional surface weather variability and are thus of primary interest in sub-seasonal forecasting for the respective region. Here, we assess the skill of sub-seasonal reforecasts of the European Centre for Medium-Range Weather Forecasts (ECMWF) for predicting 7 year-round weather regimes in the Atlantic-European region. We primarily show that forecast skill considerably differs for different flow situations and seasons. We further elucidate the effect of model calibration on forecast skill: simply removing the model bias is shown to hardly affect and for some flow situations even reduce forecast skill, which indicates that flow-dependent model calibration techniques might be more useful for sub-seasonal weather regime forecasts. Finally, we give an outlook on how lower-frequency climate modes such as the stratospheric polar vortex as well as midlatitude synoptic-scale activity such as warm conveyor belts may enhance or dilute flow-dependent forecast skill.

How to cite: Büeler, D., Quinting, J. F., Wandel, J., and Grams, C. M.: Flow-dependent sub-seasonal forecast skill for Atlantic-European weather regimes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5662, https://doi.org/10.5194/egusphere-egu2020-5662, 2020.

How to cite: Strommen, K.: Jet Latitude Regimes and the Predictability of the North Atlantic Oscillation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5838, https://doi.org/10.5194/egusphere-egu2020-5838, 2020.

This study explores the spatial variations and physical mechanisms of 10–30-day rainfall anomalies over southeastern China based on daily station-observed rainfall data for the period 1979‒2015. Empirical orthogonal function analysis shows that the dominant spatial distribution of 10–30-day rainfall anomalies is a monopole pattern over the south of the middle and lower reaches of the Yangtze River Valley (SMLY). Lead-lag composites reveal that the evolution of such a monopole pattern depends on the coordinated influences of 10–30-day atmospheric intraseasonal oscillations (ISOs) from the tropics and mid-high latitudes. In the upper troposphere, the southeastward-propagating Rossby wave train from the mid-high latitudes, which presents as anomalous anticyclones and cyclones alternating over eastern Europe to the southeastern coastal area of China, induces strong ascents (descents) over the SMLY via vorticity advection. Circulation anomalies associated with tropical ISO over East Asia/Western North Pacific trigger a vertical cell with strong updraft (downdraft) over the SMLY and downdraft (updraft) to the south, further enhancing the ascents (descents) over the SMLY, forming the wet (dry) phases of 10–30-day rainfall anomalies. Moreover, due to the meridional non-uniformity of ISO-related diabatic heating along the Indian Ocean longitudes, an anticyclone (cyclone) is generated over the central Indian–northern Bay of Bengal, which tends to anchor the anomalous ascents (descents) over the SMLY through its interaction with the intraseasonal Rossby wave from mid-high latitudes, thus favoring the persistence of wet (dry) phases of the 10–30-day SMLY rainfall anomalies.  

How to cite: Li, J. and Mao, J.: Coordinated influences of the tropical and extratropical intraseasonal oscillations on the 10–30-day variability of the summer rainfall over southeastern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6438, https://doi.org/10.5194/egusphere-egu2020-6438, 2020.

EGU2020-9729 | Displays | AS1.9

Improving sea-ice cover and SST forecasts by sea-ice thickness initialization

Steffen Tietsche, Beena Balan Sarojini, Michael Mayer, Hao Zuo, Frederic Vitart, and Magdalena Balmaseda

A substantial amount of subseasonal-to-seasonal sea-ice variability is potentially predictable, but improved model biases and initialization techniques are needed to realize this potential. Forecasts for other Earth System components can be expected to benefit from improved sea-ice forecasts as well, because the presence of sea ice drastically alters exchanges of heat and momentum between the atmosphere and the ocean. Here, we present the impact of initializing subseasonal forecasts with observed sea-ice thickness. The newly developed sea-ice thickness data set CS2SMOS that we use is derived from radar altimetry and L-band radiance satellite observations. It allows for the first time a spatially complete view of pan-Arctic ice thickness on a near-daily basis during the freezing season. The ingestion of this data into the ECMWF ocean reanalysis system improves subseasonal forecasts of the Arctic ice edge during the melting season by up to 10%. Sea-surface temperature forecasts at high latitudes are also significantly improved during the melting season, because an improved prediction of ice-free date allows an improved forecast of the amount of seasonal warming. These results illustrate the potential for improving subseasonal-to-seasonal predictions by initializing the sea-ice thickness.

How to cite: Tietsche, S., Balan Sarojini, B., Mayer, M., Zuo, H., Vitart, F., and Balmaseda, M.: Improving sea-ice cover and SST forecasts by sea-ice thickness initialization, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9729, https://doi.org/10.5194/egusphere-egu2020-9729, 2020.

EGU2020-7924 | Displays | AS1.9 | Highlight

Relationship between meningitis occurrence and atmospheric conditions over the African meningitis belt

Cheikh Dione, Mame Diarra Diouf, Bob Alex Ogwang, Elijah Adesanya Adefisan, Steve Woolnough, Habib Senghor, and Linda Hirons

The alternation of seasons over tropical northern Africa is associated with the occurrence of devastating diseases such as meningitis, Lassa fever and malaria. These tropical diseases are associated with specific atmospheric conditions. Thus, meningitis is one of the most endemic diseases observed over this region with a prevalence period up to 7 months (December-June). Previous studies based on the link between atmospheric conditions and the occurrence of meningitis outbreaks have shown that this disease develops under dry and dusty atmospheric conditions which are difficult to represent in numerical weather and climate models. However, the onset, breakup, and sub-seasonal variability of meningitis outbreaks are not well documented. The objective of this study is to identify the local and synoptic drivers favoring the large occurrence of this disease over the meningitis belt in order to improve its predictability by numerical weather and climate models on intra-seasonal and seasonal timescales. This study focuses on two cases studies of meningitis epidemics over Niger in 2009 and 2015. The case study of 2009 started early with a duration of more than eight weeks. The second case study was shorter than the first one. It took three weeks and was observed at the end of the dry season. Based on ERA5 data, surface dust concentration observations and satellite data, a further analysis of the role of climate metrics on the triggering of meningitis epidemics on intra-seasonal timescales at local and large scale atmospheric conditions will be presented.

How to cite: Dione, C., Diouf, M. D., Ogwang, B. A., Adefisan, E. A., Woolnough, S., Senghor, H., and Hirons, L.: Relationship between meningitis occurrence and atmospheric conditions over the African meningitis belt, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7924, https://doi.org/10.5194/egusphere-egu2020-7924, 2020.

EGU2020-8907 | Displays | AS1.9 | Highlight

Climate Advanced Forecasting of sub-seasonal Extremes (CAFE), ITN Project

Alvaro Corral and the CAFE-H2020-MSCA-ITN Team

The CAFE Project is a Marie S. Curie Innovative-Training-Network (ITN) project funded by the EU. The ultimate goal of the CAFE project is to contribute to the improvement of sub-seasonal predictability of extreme weather events. This will be addressed through a structured and cross-disciplinary program, training 12 early stage researchers who undertake their PhD theses. CAFE brings together a team of co-supervisors with complementary expertise in climate science, meteorology, statistics and nonlinear physics.

The CAFE team comprises ten beneficiaries (seven academic centres, one governmental agency, one intergovernmental agency and one company: ARIA, CRM, CSIC, ECMWF, MeteoFrance, MPIPKS, PIK, TUBAF, UPC, UR) and ten partner organizations (CEA and Munich Re, among them).

CAFE research is organized into three main lines: Atmospheric and oceanic processes, Analysis of extremes, and Tools for predictability, all focused on the sub-seasonal time scale. This includes the study of Rossby wave packets, Madden-Julian oscillation, Lagrangian coherent structures, ENSO-related extreme weather anomalies, cascades of extreme events, extreme precipitation, large-scale atmospheric flow patterns, and stochastic weather generators, among other topics.

Information about the CAFE project will be updated at:

http://www.cafes2se-itn.eu/

https://twitter.com/CAFE_S2SExtrem

This project receives funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 813844.

How to cite: Corral, A. and the CAFE-H2020-MSCA-ITN Team: Climate Advanced Forecasting of sub-seasonal Extremes (CAFE), ITN Project, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8907, https://doi.org/10.5194/egusphere-egu2020-8907, 2020.

The Madden-Julian Oscillation (MJO) is a well-known source of predictability on sub-seasonal-to-seasonal (S2S) time scales and a major driver of intraseasonal weather variability around the globe. For example, the MJO’s interaction with and influence on daily regional weather in the Maritime Continent-Southeast Asia (MC-SEA) region is thought to be most pronounced during boreal winter (November through February), given that the amplitude of MJO activity is often much stronger during that period compared to other times of the year.

In this study, we examine the relationship of the MJO to eight weather regimes (WR) that have been previously defined for Singapore and the MC-SEA region using k-means clustering of daily sounding data from reanalysis. These weather regimes cover the whole annual cycle of rainfall with well-defined peak frequency times and mean spatial structures that correspond to the seasonal movement of the Inter-tropical Convergence Zone (ITCZ) across the Equator. Following previous work, we use a statistical method to compute the lagged relationship between each MJO phase and daily WR occurrence between December 1980 - November 2014 to quantify the change in the likelihood that a certain regime will occur relative to climatology, given an MJO phase in advance. Bimonthly analysis indicates that strong lag relationships exist between MJO phases and certain regimes in different two-month periods, thus giving potential predictability of the type of mean weekly weather in the MC-SEA up to 3-4 weeks ahead. In addition, we consider the modulation of the MJO-WR relationships stratified by the ENSO phase to determine whether the expected WR frequency response to MJO activity varies substantially in different background states.

How to cite: Hassim, M. E. and Lee, J.: The potential predictability of Singapore and Maritime Continent weather regimes in relation to the MJO and ENSO, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12422, https://doi.org/10.5194/egusphere-egu2020-12422, 2020.

EGU2020-15225 | Displays | AS1.9

Monitoring and predicting the outstanding 2017 drought in Spain

Miguel Ángel Torres Vázquez, Amar Halifa Marín, Juan Pedro Montávez, and Marco Turco

The increase in societal exposure and vulnerability to drought, call to move from post-crisis to pre-impact drought risk management. Accurate and timely information of evolving drought conditions is crucial to take early actions to avoid devastating long-term impacts. A previous study indicated that a statistical empirical method, the ensemble streamflow prediction system (ESP; an ensemble based on reordering historical data), represents a computationally fast alternative to dynamical prediction applications for drought prediction (Turco et al. 2017). Extending this work, here we present an assessment of the ability of the ESP method in predicting the drought of 2017 in Spain considering also the uncertainties coming from the observations. For this, four different datasets are used: that cover a period of 36 years (1981-2017) and with a spatial resolution of 0.25 x 0.25º based on observations of interpolated stations (E-OBS, AEMET), on reanalysis data (ERA5), and on combining stations and satellite data (CHIRPS). Meteorological droughts are defined using the Standardized Precipitation Index aggregated over the months April–September. All the datasets show a similar spatial pattern, with most of the domain suffering extreme drought conditions. In addition, the ESP system achieves reasonable skill in predicting this drought event 2 months in advance with, again, similar pattern among the different datasets. These results suggest the feasibility of the development of an operational early warning system, also considering that the data of CHIRPS and ERA5 are updated every month, i.e., that are available for near-real time applications.

 

References

Turco, M., et al. (2017). Summer drought predictability over Europe: empirical versus dynamical forecasts. Environmental Research Letters, 12(8), 084006.

 

Acknowledgments

The authors acknowledge the ACEX project (CGL2017-87921-R) of the Ministerio de Economía y Competitividad of Spain. AHM thanks his predoctoral contract FPU18/00824 to the Ministerio de Ciencia, Innovación y Universidades of Spain. M.T. has received funding from the Spanish Ministry of Science, Innovation and Universities through the project PREDFIRE (RTI2018-099711-J-I00).

How to cite: Torres Vázquez, M. Á., Halifa Marín, A., Montávez, J. P., and Turco, M.: Monitoring and predicting the outstanding 2017 drought in Spain, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15225, https://doi.org/10.5194/egusphere-egu2020-15225, 2020.

EGU2020-22137 | Displays | AS1.9 | Highlight

Subseasonal Forecasting of Aedes-borne Disease Transmission

Laurel DiSera, Angel Munoz, and Xandre Chourio

Aedes-borne diseases, such as dengue and chikungunya, are responsible for more than 50 million infections worldwide every year, with an overall increase of 30-fold in the last 50 years, mainly due to city population growth and more frequent travels. In the United States of America, the vast majority of Aedes-borne infections are imported from endemic regions by travelers, who can become new sources of mosquito infection once they are back in the country if the exposed population is susceptible to the disease, and if suitable environmental conditions for the mosquitoes and the virus are present. Since the susceptibility of the human population can be determined via periodic monitoring campaigns, environmental suitability for presence of mosquitoes and viruses becomes one of the most important pieces of information for decision makers in the health sector. Here, we develop a subseasonal to seasonal monitoring and forecasting system for environmental suitability of transmission of Aedes-borne diseases for the US, Central America, the Caribbean and northern South America, using multiple calibrated ento-epidemiological models, climate models, and quality-controlled temperature observations. We show that the predictive skill of this new system is higher than that of any of the individual models, and illustrate how a combination of deterministic and probabilistic forecasts can inform key prevention and control strategies.

How to cite: DiSera, L., Munoz, A., and Chourio, X.: Subseasonal Forecasting of Aedes-borne Disease Transmission, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22137, https://doi.org/10.5194/egusphere-egu2020-22137, 2020.

EGU2020-5358 | Displays | AS1.9 | Highlight

Quantifying the usefulness of European subseasonal forecasts using a real-world energy-sector framework

Joshua Dorrington, Isla Finney, Antje Weisheimer, and Tim Palmer

Increasingly, operational forecasting centres are producing sub-seasonal forecasts, targeted at lead times of 3-6 weeks. These aim to fill the gap between conventional 2-week weather forecasts and longer term seasonal outlooks. However it is often difficult for end-users to know how these sub-seasonal forecasts can be best utilised, and how skilful they are for predicting variables of real world interest.

Much prior work on sub-seasonal forecasts has focused on assessing skill scores for large-scale smooth fields of mid- or upper-tropospheric variables, or else has looked at heavily time-averaged quantities. How to extend the lessons of these studies to user applications is not always obvious.

We take a more applied approach, focused on the chaotic and variable weather of Western Europe. We use sub-seasonal temperature forecasts alongside real-world French energy price and demand data in order to directly calculate the financial value of subseasonal forecasts to users in the energy sector. Using this new, real-world framework we make an estimate of cost-loss ratios and so can compare to the results of a simpler potential economic value model.

 

How to cite: Dorrington, J., Finney, I., Weisheimer, A., and Palmer, T.: Quantifying the usefulness of European subseasonal forecasts using a real-world energy-sector framework, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5358, https://doi.org/10.5194/egusphere-egu2020-5358, 2020.

AS1.15 – Atmospheric Rossby waves and Jet Dynamics, and their Impacts on Weather and Climate events

Ray paths of stationary Rossby waves emanating from a local mid-latitude source are usually refracted equatorward. However, this general tendency for equatorward propagation is mitigated by the presence of a midlatitude jet which acts as a zonal waveguide. This opens the possibility for circum-global teleconnections and quasi-resonance, which suggests that the ability of a jet to guide a wave in the zonal direction is an important property.

This paper investigates waveguidability of idealized midlatitude jets in a barotropic model on the sphere. A forced-dissipative model configuration with a local source for Rossby waves is used in order to quantify waveguidability by diagnosing the latitudinal distribution of waviness in a longitudinal sector far downstream of the forcing. Systematic sensitivity experiments show that waveguidability increases smoothly with increasing jet amplitude and with decreasing jet width. This result is contrasted with the predictions from two idealized theoretical concepts based (1) on ray tracing as derived from WKB theory and (2) on a sharp jet with a zonally oriented front of potential vorticity. The existence of two so-called turning latitudes, which is the key diagnostic for a zonal waveguide according to ray tracing theory, turns out to be a poor predictor for the dependence of waveguidability on jet amplitude and jet width obtained in the numerical simulations. By contrast, the meridional gradient of potential vorticity correlates fairly well with the diagnosed waveguidability. The poor prediction from ray tracing is not surprising, because the underlying WKB assumptions are not satisfied in the current context.

How to cite: Wirth, V.: Waveguidability of idealized midlatitude jets and the limitations of ray tracing theory , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2585, https://doi.org/10.5194/egusphere-egu2020-2585, 2020.

EGU2020-7332 | Displays | AS1.15

Dynamical Evolution of Troughs and Ridges within Rossby Wave Packets: A Composite Study

Franziska Teubler and Michael Riemer

Rossby wave packets (RWPs) are a fundamental ingredient of midlatitude dynamics and organize the formation, propagation and decay of midlatitude weather systems. They may also constitute precursors to high-impact weather events. It is often expected that RWPs, as large-scale flow features obeying balanced dynamics, exhibit a large degree of predictability. Recent work, however, has shown that there is increased forecast uncertainty, in particular associated with the impact of moist processes, which may compromise medium-range predictability in the downstream region.

As a contribution to an improved understanding of these inherent uncertainties, we employ a quantitative potential vorticity (PV) – potential temperature framework to quantify different processes governing the evolution of troughs and ridges. This PV framework allows to fully separate the dynamics into four processes, namely the group propagation of Rossby waves, baroclinic growth, the impact of upper-tropospheric divergent flow, and direct diabatic PV modification.

The dynamical evolution of the amplitude of troughs and ridges within RWPs is examined from a composite perspective. The composite is based on the new ERA5 dataset and comprises 7164 RWPs. The direct diabatic contribution is estimated by the physical tendencies of the ‚Year of tropical convection‘ (YOTC) data. Additional to baroclinic downstream development, the composite analysis reveals a first-order impact of upper-level divergent flow for the amplification of ridges and the decay of troughs. We interpret divergent outflow as an indirect diabatic process associated with latent heat release below. Based on these results, we suggest extending the prevailing paradigm of downstream baroclinic development to include the systematic impact of moist processes. In the end potential implications for the predictability of RWPs are shown.

How to cite: Teubler, F. and Riemer, M.: Dynamical Evolution of Troughs and Ridges within Rossby Wave Packets: A Composite Study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7332, https://doi.org/10.5194/egusphere-egu2020-7332, 2020.

EGU2020-10398 | Displays | AS1.15

A more complete Rossby wave source

Wolfgang Wicker and Richard Greatbatch

Tropical convection drives extratropical variability on subseasonal to interannual time-scales by exciting Rossby wave trains in the upper troposphere. Traditionally the relevant Rossby wave source is considered to be the sum of vortex stretching and vorticity advection by the divergent horizontal flow ( - ∇·uχ (ζ+f) - uχ·∇ (ζ+f)). Since absolute vorticity is very small at the equator, the equatorward flanks of the upper tropospheric jets have been regarded the source region of Rossby wave trains. In these considerations vertical momentum advection is neglected, although, it is an important source for westerly momentum at the equator. The curl of vertical momentum advection is the sum of vertical vorticity advection and vortex tilting ( -  ω ζp - ωx vp + ωy up). These contributions are smaller than the traditional Rossby wave source in midlatidues by about one order of magnitude but they are of similar size in the tropics.

How to cite: Wicker, W. and Greatbatch, R.: A more complete Rossby wave source, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10398, https://doi.org/10.5194/egusphere-egu2020-10398, 2020.

Localised regions of negative potential vorticity (PV) are frequently seen on the equatorward flank of the upper-tropospheric jet streams in analysis and forecast products. Their positioning, on the anticyclonic side of the jet and often close to the jet core, suggest they are associated with an enhancement of jet stream maximum winds. Given that PV is generally positive in the northern hemisphere and is conserved under adiabatic conditions, the presence of negative PV is indicative of recent diabatic activity. However, little is understood on the mechanisms for its generation and subsequent lifecycle.

In this study, aircraft measurements from a recent field campaign are used to provide direct observational evidence for the presence of negative PV on the anticyclonic side of an upper-tropospheric jet. Theory is then developed to understand the process by which PV can turn negative. The key ingredient is diabatic heating in the presence of vertical wind shear, and the resulting PV anomalies are shown to always result from a flux of PV directed 'down the isentropic slope'. This explains why, for the typical situation of heating in a warm conveyor belt, negative PV values appear on the equatorward side of the upper-tropospheric jet stream close to the jet core. These ideas are illustrated with a semi-geostrophic model and the processes responsible for the observed negative PV are explored using an operational forecast model with online PV tracer diagnostics.

The diabatic influence on jet stream winds and shear is of interest because it is pertinent to the predictability of extreme jet stream events and associated flight-level turbulence, and is crucial to the propagation of Rossby waves at tropopause level, development of mid-latitude weather systems and their subsequent impacts at the surface.

How to cite: Harvey, B. and Methven, J.: Diabatic generation of negative potential vorticity and its impact on the jet stream, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19683, https://doi.org/10.5194/egusphere-egu2020-19683, 2020.

EGU2020-9290 | Displays | AS1.15

Local and remote Rossby wave responses to an anomalously dry or wet Australian continent

Olivia Martius, Kathrin Wehrli, and Sonia Seneviratne

An ensemble of CESM atmosphere only experiments with varying soil moisture anomalies over Australia (+1 , 0 ,-1 STD) is analysed with respect to the atmospheric response. Locally an intensification of the surface heat low and an upper-level anticyclone is found for the negative anomaly. The local response to the low soil moisture content is driven by increase sensible heat fluxes and associated positive near-surface temperature anomalies.

A remote response of the upper-level flow consists of a downstream Rossby wave train extending along the jet waveguide and an upstream response projecting upon the main mode of variability the southern annular. The downstream response is driven by linear wave dynamics while the upstream response is modulated by non-linear wave dynamics and associated eddy fluxes. The sensitivity of the response to the background flow, i.e., different phases of ENSO is explored.

How to cite: Martius, O., Wehrli, K., and Seneviratne, S.: Local and remote Rossby wave responses to an anomalously dry or wet Australian continent , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9290, https://doi.org/10.5194/egusphere-egu2020-9290, 2020.

EGU2020-17811 | Displays | AS1.15

The influence of Antarctic topography on jet streams and Rossby waves in the Southern Hemisphere.

Matthew Patterson, Tim Woollings, and Tom Bracegirdle

Eddy-driven jets are sustained through momentum transport by Rossby waves, which propagate along potential vorticity (PV) gradients. In the atmosphere, spatial variations in time-mean PV are mostly dominated by the variation of the Coriolis parameter with latitude. However, at high southern latitudes, a significant perturbation to the distribution and mixing of PV is provided by the Antarctic Plateau, which rises up to 4km above sea level. It is therefore possible that this orography affects Rossby wave propagation and hence affects the circulation in mid-latitudes.

We show through a set of semi-realistic and idealised experiments, that Antarctic topography plays a fundamental role in shaping the structure of the Southern Hemisphere extratropics. In particular, we perform runs with and without the Antarctic Plateau and demonstrate that the Plateau alters Rossby wave structure and propagation, thereby changing the momentum fluxes. Removal of the Plateau weakens the Indian Ocean jet and has a substantial effect on the flow downstream over the South Pacific. Here, the characteristic split jet pattern is destroyed and the flow at high latitudes stagnates. This also illustrates the prevalence of downstream development in the Southern Hemisphere and the strong connections between the flow over the South Pacific and Indian Oceans.   

How to cite: Patterson, M., Woollings, T., and Bracegirdle, T.: The influence of Antarctic topography on jet streams and Rossby waves in the Southern Hemisphere., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17811, https://doi.org/10.5194/egusphere-egu2020-17811, 2020.

EGU2020-341 | Displays | AS1.15

Effects of mean state of climate models on the response to prescribed forcing: Sensitivity experiments with the SPEEDY general circulation model.

Emanuele Di Carlo, Paolo Ruggieri, Paolo Davini, Stefano Tibaldi, and Susanna Corti

How to cite: Di Carlo, E., Ruggieri, P., Davini, P., Tibaldi, S., and Corti, S.: Effects of mean state of climate models on the response to prescribed forcing: Sensitivity experiments with the SPEEDY general circulation model., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-341, https://doi.org/10.5194/egusphere-egu2020-341, 2020.

EGU2020-22454 | Displays | AS1.15

Finding Dynamical Modes of Atmospheric Variability Using Conservation Properties

Dominic Jones, John Methven, Tom Frame, and Paul Berrisford

It is evident that persistent large-scale weather phenomena are an important factor in extreme seasonal climate; this has been especially true in boreal summers over the last two decades. Large, relatively slowly changing modes of variability on the mid-latitude jet are key to understanding high impact weather events. High monthly precipitation totals in the summer, for example, are linked to stationary Rossby wave patterns; stationary winter jet patterns can direct North Atlantic cyclones towards the UK and Europe. These wave patterns are often diagnosed but without a link to their phase speeds or dynamics.

To examine these slow modes we define an atmospheric background state as a function of isentropic and materially conserved co-ordinates (potential temperature and PV), resulting in a slowly changing, zonally symmetric background state. We then extract patterns of variability from the set of perturbations by employing an alternative Empirical Orthogonal Function (EOF) technique which utilizes a conserved wave activity as a weighted covariance. This results in statistical (EOF) patterns which possess an intrinsic dynamical phase speed and frequency, which are predicted from the conservation properties pseudomomentum and pseudoenergy. These statistical modes are a recombination of the dynamical normal modes in a system with quasi-linear dynamics.

We examine long runs with relaxation to unstable background jets but without orography, diurnal or seasonal effects, where large amplitude wave activity emerges. These simplified situations are used to test whether or not the predicted phase speeds from theory (given the structures found) matches with the observed phase speeds deduced from the principal component time series of the ENMs. Our hypothesis is that slow wave motion is explained by the structure and conservation properties of the modes. We are able to explore the dependence on the structures by varying the background state.

How to cite: Jones, D., Methven, J., Frame, T., and Berrisford, P.: Finding Dynamical Modes of Atmospheric Variability Using Conservation Properties, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22454, https://doi.org/10.5194/egusphere-egu2020-22454, 2020.

EGU2020-12114 | Displays | AS1.15

Why is there a Zonal Wave 3 pattern in the Southern Hemisphere extratropical circulation?

Rishav Goyal, Martin Jucker, Alex Sen Gupta, and Matthew England

Studies of the Southern Hemisphere (SH) extratropical circulation are dominated by investigations of the zonally symmetric component of the Southern Annular Modular (SAM). However, there are significant asymmetries embedded in the zonal flow. In particular, a zonal wave 3 (ZW3) pattern is one of the dominant features of the SH circulation on daily, seasonal and interannual timescales. While the ZW3 circulation has had significant impacts on meridional heat transport and Antarctic sea ice extent in recent years, the physical mechanisms responsible for its presence still remain elusive. In this study, we use the Community Earth System Model (CESM) to understand the mechanisms that give rise to and modulate the ZW3 pattern in the SH extratropics. We examine, among other things, the popular belief that the ZW3 pattern is present due to the existence of three separate land-masses in the SH, namely Australia, Africa and South America, and whether it is modulated by both the land-ocean contrast and tropical forcing.

How to cite: Goyal, R., Jucker, M., Sen Gupta, A., and England, M.: Why is there a Zonal Wave 3 pattern in the Southern Hemisphere extratropical circulation?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12114, https://doi.org/10.5194/egusphere-egu2020-12114, 2020.

EGU2020-17897 | Displays | AS1.15

The sensitivity of atmospheric blocking to changes in upstream latent heating

Stephan Pfahl, Daniel Steinfeld, Maxi Boettcher, and Richard Forbes

Recent climatological studies based on trajectory calculations have pointed to an important role of latent heating during cloud formation for the dynamics of blocking anti-cyclones. However, the causal relationship between latent heating and blocking formation has not yet been fully elucidated. To explicitly study this causal relationship, we perform sensitivity simulations of selected blocking events with a global weather prediction model in which we artificially eliminate latent heating in clouds upstream of the blocking anti-cyclones. This elimination has substantial effects on the upper-tropospheric circulation in all case studies, but there is also significant case-to-case variability: some blocking systems do not develop at all without upstream latent heating, while for others the amplitude of the blocking anticyclones is merely reduced. This strong influence of latent heating on the upper-level circulation is due to a combination of two effects: the direct injection of air masses with low potential vorticity (PV) into the upper troposphere in strongly ascending “warm conveyor belt” airstreams, and the indirect effect owing to the interaction of the associated divergent outflow with the upper-level PV structure. The important influence of diabatic heating demonstrated with these experiments suggests that an accurate parameterization of microphysical processes in weather prediction and climate models is crucial for adequately representing blocking dynamics.

How to cite: Pfahl, S., Steinfeld, D., Boettcher, M., and Forbes, R.: The sensitivity of atmospheric blocking to changes in upstream latent heating, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17897, https://doi.org/10.5194/egusphere-egu2020-17897, 2020.

EGU2020-3991 | Displays | AS1.15

Static Stability Associated with Southern Hemisphere Blocking Onsets

Li Dong and Stephen Colucci

The horizontal and temporal variation of static stability prior to blocking onset is characterized through composite analysis of blocking events in the Southern Hemisphere. It is found that a local minimum of static stability in the upper troposphere and on the tropopause is achieved over the block-onset region when blocking onset takes place. From the perspective of isentropic potential vorticity, blocking onset is accompanied by extratropical tropopause elevation and a local low isentropic potential vorticity anomaly that is formed right under the elevated tropopause. This low isentropic potential vorticity anomaly is coincident with a local minimum of static stability over the block-onset region. In addition, based on static stability budget analysis, it revealed that the decrease of static stability in the upper troposphere and on the tropopuase prior to blocking onset is attributable to horizontal advection of low static stability from subtropics to midlatitude as well as the stretching effect associated with upper-level convergence, with the horizontal advection forcing being the primary contributor. On the other hand, the vertical advection of static stability tends to oppose the decreasing static stability through advecting more stable air downward such that it stabilizes the local air over the block-onset region. Furthermore, the indirect and direct effect of latent heat to the local change of static stability over the block-onset region are also discussed, respectively.

How to cite: Dong, L. and Colucci, S.: Static Stability Associated with Southern Hemisphere Blocking Onsets, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3991, https://doi.org/10.5194/egusphere-egu2020-3991, 2020.

EGU2020-12356 | Displays | AS1.15

Atmospheric Blocking: The Impact of Topography in an Idealized General Circulation Model

Veeshan Narinesingh, James Booth, Spencer Clark, and Yi Ming

EGU2020-12992 | Displays | AS1.15

Investigating quasi-resonant Rossby waves with an idealized general circulation model

Todd Mooring and Marianna Linz

Petoukhov et al.’s (2013, PNAS) hypothesis of quasi-resonant Rossby waves as a mechanism for destructive weather extremes—both heat- and rain-related, observed and projected—has received a great deal of attention in recent years.  Most notably, it has been used for diagnostic studies of reanalysis products and full-physics atmospheric or coupled general circulation models. However, studies of this sort essentially assume (rather than test) the validity of the underlying theory.

Since the quasi-resonance theoretical arguments do not explicitly involve the full complexity of atmospheric physics, it ought to be possible to test them within the much simpler framework of an idealized general circulation model. By carefully constructing the forcing fields for such a model, we will achieve control of its zonal mean state and thus the waveguide properties of the zonal jet. We will explore the properties of the quasi-stationary Rossby waves in such simulations to test whether they have the properties predicted by Petoukhov et al. By testing this dynamical mechanism in a simplified model, we can better understand its applicability and limitations for investigations of future climate.

How to cite: Mooring, T. and Linz, M.: Investigating quasi-resonant Rossby waves with an idealized general circulation model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12992, https://doi.org/10.5194/egusphere-egu2020-12992, 2020.

EGU2020-13233 | Displays | AS1.15

Rossby wave packets associated with extreme precipitation events over Northern-Italy

Federico Grazzini, Georgios Fragkoulidis, Franziska Teubler, Volkmar Wirth, and George Craig

Several studies on extreme precipitation events (EPEs) in the alpine area reported, as the main triggering factor, a meridionally elongated upper-level trough (i.e., a breaking Rossby wave) as part of an incoming Rossby wave packet (RWP). In this work, we investigate a vast number of EPEs occurring between 1979 and 2015 in northern-central Italy. The EPEs are subdivided into three categories (Cat1, Cat2, Cat3) according to thermodynamic conditions over the affected region. The three categories do not only differ locally but also in the evolution of precursor RWPs. These differences cannot be solely explained by the apparent seasonality of the flow; therefore, the relevant physical processes in the RWP propagation of each case are further investigated. In particular, we show that RWPs associated with the strongest EPEs, namely the ones falling in Cat2, undergo a substantial amplification over the western N. Atlantic due to anomalous ridge-building two days before the event; arguably due to diabatic heating sources. This type of development induces a downstream trough which is highly effective in focusing water vapour transport towards the main orographic barriers of the Apennines and the Alps. Finally, we identify an increasing trend of water vapour transport over the western N. Atlantic which is likely associated with the observed increase in Cat2 and Cat3 events

How to cite: Grazzini, F., Fragkoulidis, G., Teubler, F., Wirth, V., and Craig, G.: Rossby wave packets associated with extreme precipitation events over Northern-Italy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13233, https://doi.org/10.5194/egusphere-egu2020-13233, 2020.

EGU2020-5168 | Displays | AS1.15

Are Recurrent Rossby wave packets linked to persistent extreme weather events in the Southern Hemisphere?

Syed Mubashshir Ali, Olivia Martius, and Matthias Röthlisberger

Synoptic-scale Rossby wave-packets have a recurrent pattern during several episodes of persistent surface weather which is termed as 'recurrent Rossby wave-packets' (RRWP). They result in a statistically significant increase in winter cold and summer hot spells over large areas of the Northern Hemisphere mid-latitudes.

We present a global climatology of the RRWPs to study its spatial and seasonal variation. We also investigate the link of RRWPs to persistent surface extremes in the Southern Hemisphere (SH).  We find that RRWPs result in a statistically significant increase in winter cold and summer hot spells over broad areas in Australia and South America. Furthermore, we discuss the effects of climatological oscillations (Madden Julian Oscillation, ENSO, etc) on influencing the RRWPs.

How to cite: Ali, S. M., Martius, O., and Röthlisberger, M.: Are Recurrent Rossby wave packets linked to persistent extreme weather events in the Southern Hemisphere?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5168, https://doi.org/10.5194/egusphere-egu2020-5168, 2020.

EGU2020-762 | Displays | AS1.15

The impact of southward propagation of the upper-tropospheric Rossby wave activity on the Red Sea trough

Zakieh Alizadeh, Alireza Mohebalhojeh, Farhang Ahmadi-Givi, Mohammad Mirzaei, and Sakineh Khansalari

The Red Sea Trough (RST) is an inverted trough of low-pressure system at lower tropospheric levels over the northeast Africa and the Red Sea. The previous research conducted on the RST suggests that when this system is activated, heavy rainfall occurs in large parts of the eastern Mediterranean and southwest Asia. The main aim of this article is to investigate the way Rossby wave activity at the upper level troposphere and its interaction with the lower tropospheric circulation activate the RST.

This study was carried out in three stages: first, the climatological behavior of RST in winter (December to February) was studied and then, cyclones were identified and tracked in the northeast Africa and the Red Sea using a cyclone tracking scheme. In the second stage, the Rossby wave activity flux at the 300 hPa level was considered in the region. Finally, the interaction between the wave activity flux and the RST was investigated. Two critical phases for the wave flux entering the region were considered. The critical positive (negative) phase corresponds to the month when on average the highest (lowest) values of the wave activity flux enter the northeast Africa and Red Sea regions. The results show that, during the critical positive phase, the RST strengthens and extends to the northeast of the Mediterranean Sea and cyclogenesis is increased in the northeast of Africa and especially in the northeast of the Red Sea.

With regard to the divergence of wave activity flux with an associated southward flux, the source of activity needed for cyclogenesis and reinforcement of the RST is provided by the North Atlantic storm track and the divergence core over the Mediterranean Sea. The results of the wave activity time series show that part of the activity from the northeast is integrated with the convergence core of the Mediterranean storm track, leading to enhancement of the cyclones in the northeast of the Red Sea and the extension of the RST to the northeast. But most of the activity joins the flux divergence core of the Mediterranean storm track in the west of the region and results in amplification of Sudan’s cyclones and activation of the RST along both the meridional and zonal directions; the important point to consider is that the wave activity flux entering the region is greater in the zonal direction. In addition to the southward propagation of the wave activity, the packets of flux convergence and divergence in the central North Atlantic are tilted in the southwest–northeast direction, indicating the dominance of anticyclonic Rossby wave breaking. Associated with the upper-level wave activity fluxes entering the region, there is jet enhancement and low-level cold advection from higher latitudes to the tropical and subtropical regions. The difference of RST between the critical positive and negative phases is turned out to be statistically significant with confidence levels of greater than 90%.

Keywords: Red Sea Trough, Northeast Africa and Red Sea cyclones, wave activity flux, critical positive and negative phases, Mediterranean storm track, North Atlantic storm track

How to cite: Alizadeh, Z., Mohebalhojeh, A., Ahmadi-Givi, F., Mirzaei, M., and Khansalari, S.: The impact of southward propagation of the upper-tropospheric Rossby wave activity on the Red Sea trough, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-762, https://doi.org/10.5194/egusphere-egu2020-762, 2020.

EGU2020-4364 | Displays | AS1.15

Atmospheric blocking modulates the odds of heavy precipitation over Pakistan

Nabeela Sadaf, Yanluan Lin, and Wenhao Dong

Floods or wet spells have increased over Pakistan in recent years, however a long-term classification of large-scale and synoptic-scale configuration for these events has been lacking. In this study, a total of 53 wet spells during the period of 1951-2015 over the core monsoon domain of Pakistan are identified. Based on daily geopotential height fields from NCEP/NCAR re-analysis, the dominant synoptic-scale systems, displaying distinct low-level circulation and moisture transport, are found during these wet spells over Pakistan. They are categorized as trough with low pressure system (LPS, 30 cases), trough without LPS (19 cases), and LPS only (4 cases) wet spells. Without the accompanying LPS over India, the trough tends to be deep and intrudes to south Pakistan with moisture transport mainly from Arabian Sea. In contrast, the trough is relatively shallow and interacts with presence of the LPS to steer moisture from the Bay of Bengal towards Pakistan. We found that subtropical trough associated with the blocking ridge over west Asia is an essential ingredient of wet spells over Pakistan. The patterns observed from wet spells over Pakistan are different from wet spells over the core monsoon domain of India, which is mainly dominated by LPS. The ridge development and blocking over Siberia is a precursor to wet spells over Pakistan and provides guidance for prediction.

 

How to cite: Sadaf, N., Lin, Y., and Dong, W.: Atmospheric blocking modulates the odds of heavy precipitation over Pakistan, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4364, https://doi.org/10.5194/egusphere-egu2020-4364, 2020.

Transient Rossby wave packets (RWPs) are a prominent feature of the synoptic to planetary upper-tropospheric flow at the mid-latitudes. This prompts the development of diagnostic methods to identify and investigate the spatiotemporal evolution of key RWP properties. Such properties include the RWP phase speed and group velocity, the diagnosis of which has so far remained non-local in space and/or time. To this end, a novel diagnostic approach is presented here, which is based on the analytic signal of upper-tropospheric meridional wind velocity and thus allows the evaluation of RWP properties locally in space and time. The detailed insight into these properties can be utilized toward a better understanding of the upper-tropospheric circulation, its interplay with local weather features, and its model representation. In particular, climatologies of RWP amplitude, wavenumber, phase speed, and group velocity are investigated using reanalysis data for the time period 1979 – 2018. Pronounced features of seasonal and interregional variability are highlighted. Moreover, the role of RWP amplitude and phase speed in the occurrence and duration of temperature extremes in Europe is explored. Finally, indications of systematic biases in medium-range forecasts of these fields suggest that a correct representation of the RWP evolution is crucial for the predictability of temperature extreme events.

How to cite: Fragkoulidis, G. and Wirth, V.: Local diagnostics of Rossby wave packet properties – Seasonal variability and their role in temperature extremes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5411, https://doi.org/10.5194/egusphere-egu2020-5411, 2020.

EGU2020-16147 | Displays | AS1.15

First hints for the influence of planetary waves on extreme temperature events with a focus on Bavaria and the Alpine Region

Dominik Laux, Lisa Küchelbacher, Sabine Wüst, and Michael Bittner

Planetary waves are global scale waves in the atmosphere, which mainly dominate the atmospheric circulation in mid latitudes. It is discussed whether planetary wave activity increases due to the decrease of the meridional temperature gradient between the equator and the pole. As a result, large-scale weather patterns in mid latitudes should change, leading to a change in the occurrence of extreme weather events.

In order to analyze whether the occurrence of extreme temperature events has already changed, an algorithm was developed that identifies extreme temperature events in ERA5 temperature data from 1979 to 2019 in different height levels (1000hPa – 1hPa). We analyze the occurrence frequency of extreme temperature events in mid latitudes of the Northern Hemisphere as well as in Bavaria and in the Alpine region. To relate changes in the occurrence of extreme temperature events to possible changes of the planetary wave activity, we use the so-called dynamic activity index (DAI), which is operationally derived from ERA reanalysis temperature data at DLR.

In the troposphere, our analyses show that the occurrence frequency of heat events increases whereas the opposite holds for cold events. This is consistent with the expected effect of increasing average temperatures on the occurrence frequency of extreme temperature events. In the stratosphere, however, we observe an increase of cold events and a constant number of heat events. We conclude that tropospheric and stratospheric driving factors for the occurrence of extreme temperature events differ. The stratospheric development can be explained by increasing planetary wave activity as it is deduced from the DAI.

This work received funding from the Bavarian State Ministry of the Environment and Consumer Protection.

How to cite: Laux, D., Küchelbacher, L., Wüst, S., and Bittner, M.: First hints for the influence of planetary waves on extreme temperature events with a focus on Bavaria and the Alpine Region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16147, https://doi.org/10.5194/egusphere-egu2020-16147, 2020.

EGU2020-758 | Displays | AS1.15

Links of Atmospheric Blocking to Temperature Extremes over Ukraine

Lidiia Popova and Inna Khomenko

Atmospheric blocking is a phenomenon in which a large, quasi-stationary anticyclone develops in the mid-latitudes and persists for several days or longer, blocking the ambient westerly winds and weather systems. Extremes on both ends of the temperature distribution are especially closely connected to atmospheric blocking (Brunner et al. 2017).

In this study the link between atmospheric blocking and Ukrainian cold and warm spells is investigated during winter and summertime in the period of 1991-2019 in order to provide better insight into the shifting role of blocking for extremes. Extreme temperatures are termed cold or warm spells if temperature stays outside the 10th to 90th percentile range at least six consecutive days. The detection of temperature extremes is based on daily minimum and maximum temperatures obtained for 12 meteorological stations that evenly cover territory of Ukraine. In the database obtained only the high-impact extreme temperature episodes are selected to be investigated in the further study.

The atmospheric blocking is detected on the basis of the daily 500 hPa geopotential height fields from the NCEP/NCAR reanalysis and potential temperature fields on the dynamical tropopause (PV = 2 PVU) obtained from ERA-Interim. In order to objectively diagnose atmospheric blocking two standard detection techniques are used. The first method utilizing the reversal of mid-latitude 500hPa geopotential height gradients was elaborated by Tibaldi and Molteni (1990) and detailed in Trigo et al. (2004), and the other one using reversal of potential temperature gradients was developed in Pelly and Hoskins (2003). These blocking detection algorithms identify fairly well the breaking of upper-level Rossby waves on 500 hPa height and on the dynamic tropopause, associated with onset of mid-latitude atmospheric blocking.

Up to 80% of winter cold and summer hot temperatures in Ukraine are associated with a collocated blocking. Large positive anomalies of 500 hPa geopotential height play a key role in maintaining prolonged extreme temperature spells and atmospheric blocking, though spell and blocking periods are much shorter than periods of positive anomalies. Spatio-temporal distribution of both indices are uneven, which meant that the wave-breaking process is not steady either at the 500 hPa surface or on the dynamical tropopause. Thus, during each episode the prolonged existence of ridges are maintained due not only to breaking of Rossby waves, but other mechanisms It should be mentioned that atmospheric blocking is more frequently revealed with the Tibaldi-Molteni indices than the Pelly-Hoskins ones, meaning that breaking of Rossby waves occurs more frequently at the 500 hPa geopotential height than on the tropopause.

How to cite: Popova, L. and Khomenko, I.: Links of Atmospheric Blocking to Temperature Extremes over Ukraine , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-758, https://doi.org/10.5194/egusphere-egu2020-758, 2020.

EGU2020-4574 | Displays | AS1.15 | Highlight

A Lagrangian analysis of upper-tropospheric anticyclones associated with heat waves in Europe

Philipp Zschenderlein, Stephan Pfahl, Heini Wernli, and Andreas H. Fink

Heat waves impose large impacts on various sectors. Meteorologically, these events are co-located to upper-tropospheric anticyclones. In order to elucidate the formation of these anticyclones and the role of diabatic processes, we trace air masses backwards from the upper-tropospheric anticyclones and quantify the diabatic heating in these air parcels. We analyse anticyclones that are connected to summer heat waves at the surface during the period 1979 – 2016 in different European regions. Around 25-45% of the air parcels are diabatically heated during the last three days prior to their arrival in the upper-tropospheric anticyclones and this amount increases to 35-50% for the last seven days. The influence of diabatic heating is larger for heat wave anticyclones in northern Europe and western Russia and smaller in southern Europe. Interestingly, the diabatic heating occurs in two geographically separated air streams. Three days prior to arrival, one heating branch (western branch) is located above the western North Atlantic and the other heating branch (eastern branch) is located to the southwest of the target upper-tropospheric anticyclone. The diabatic heating in the western branch is related to the warm conveyor belt of a North Atlantic cyclone upstream of the evolving upper-level ridge. In contrast, the eastern branch is diabatically heated by convection, as indicated by elevated mixed-layer convective available potential energy along the western side of the matured upper-level ridge. Central Europe is influenced by both branches, whereas western Russia is predominantly affected by the eastern branch. The formation of the upper-tropospheric anticyclone, and therefore of the heat wave, is highly depended on the western branch, whereas its maintenance is more affected by the eastern branch. For long-lasting heat waves, the western branch regenerates. The results from this study show that the dynamical processes leading to heat waves may be sensitive to small-scale microphysical and convective processes, whose accurate representation in models is thus supposed to be crucial for heat wave predictions on weather and climate time scales.

How to cite: Zschenderlein, P., Pfahl, S., Wernli, H., and Fink, A. H.: A Lagrangian analysis of upper-tropospheric anticyclones associated with heat waves in Europe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4574, https://doi.org/10.5194/egusphere-egu2020-4574, 2020.

EGU2020-15989 | Displays | AS1.15

Heatwaves and Predictability - the Role of Rossby Waves and Atmospheric Waveguides

Rachel White, Chloé Prodhomme, Georgios Fragkoulidis, Stefano Materia, and Constantin Ardilouze

Heat waves can have a devastating impact on human society and ecosystems, and thus improved understanding and predictability of such events would provide huge benefits. It has been shown previously that many extreme temperature events are associated with quasi-stationary, or recurrent, Rossby waves (hereafter QSWs). We show that these QSWs are often associated with atmospheric waveguides, providing some dynamical understanding of why such weather patterns persist. In the context of this framework, we study the subseasonal-to-seasonal (S2S) predictability of heatwaves, QSWs, and atmospheric waveguides. Operational seasonal forecasts can reproduce the observed climatological statistics of QSWs, and the observed connection between QSWs and extreme temperatures over Europe, although with some biases. To better understand the underlying dynamics of the seasonal forecast models, we explore whether such models are capable of reproducing the observed connection between QSWs and atmospheric waveguides,  linked to persistent, and thus high impact, extreme heat events. We examine the S2S predictability of atmospheric waveguides and high amplitude QSW events, to better understand the potential S2S predictability of heatwaves.

How to cite: White, R., Prodhomme, C., Fragkoulidis, G., Materia, S., and Ardilouze, C.: Heatwaves and Predictability - the Role of Rossby Waves and Atmospheric Waveguides, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15989, https://doi.org/10.5194/egusphere-egu2020-15989, 2020.

EGU2020-16003 | Displays | AS1.15

Wave-resonance fingerprint in the 2010 summer: a modelling experiment

Giorgia Di Capua, Kai Kornhuber, Eftychia Rousi, Sarah Sparrow, David Wallom, and Dim Coumou

Summer 2010 was characterized by two contemporaneous extreme events: the Russian heat wave and the Pakistan flood. Several studies have shown a link between the two events, and Quasi-Resonant Amplification (QRA) has been suggested as an atmosphere-dynamic mechanism leading to the anomalous wavy circulation pattern which connected both extremes. Here, we aim at reproducing the 2010 circulation conditions in the Northern Hemisphere by obtaining a large ensemble of simulations from the Weather@home project within climateprediction.net (CPDN). We identify those ensemble members exhibiting a specific latitudinal temperature profile characterised by amplified high-latitude land warming (QRA - fingerprint) and investigate their surface temperature and upper level circulation properties. We show that when the QRA - fingerprint is present, the mid-latitude circulation bears similar characteristics to those observed in the 2010 summer: hot temperatures over European Russia and a wavy pattern in the upper-tropospheric meridional winds. As temperature profiles are projected to become increasingly similar to the QRA-fingerprint under future emission scenarios, these results provide further evidence that high latitude warming might favour persistent surface weather in the mid-latitudes.

How to cite: Di Capua, G., Kornhuber, K., Rousi, E., Sparrow, S., Wallom, D., and Coumou, D.: Wave-resonance fingerprint in the 2010 summer: a modelling experiment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16003, https://doi.org/10.5194/egusphere-egu2020-16003, 2020.

EGU2020-9212 | Displays | AS1.15

A daily estimate of phase speed to explore the link between Arctic Amplification and Rossby waves

Jacopo Riboldi, François Lott, Fabio D'Andrea, and Gwendal RIvière

Rossby wave activity is intimately related to the day-to-day weather evolution over midlatitudes and to the occurrence of extreme events. Global warming trends may also affect their characteristics: for example, it has been hypothesized that Arctic warming with respect to midlatitudes, known as Arctic Amplification, may lead to a reduction in the speed of Rossby waves, to more frequent atmospheric blocking and to extreme temperature events over midlatitudes. Testing this hypothesis requires an estimate of the evolution and of the variability of phase speed in recent decades and in climate model simulations. However, measuring the phase speed of the global Rossby wave pattern is a complex task, as the midlatitude flow consists of a superposition of waves of different nature (e.g., planetary vs synoptic) across a broad range of wavenumbers and frequencies.

We propose here a framework, based on spectral analysis, to understand the variability of Rossby wave characteristics in reanalysis and their possible future changes. A novel, daily climatology of wave spectra based on gridded upper-level wind data is employed to study the evolution of Rossby wave phase speed over the Northern Hemisphere between March 1979 and November 2018. A global estimate of phase speed is obtained by doing a weighted average of the phase speed of each wave, with the associated spectral coefficients as weights.

Several insights about the drivers of phase speed variability at different time scales and their link with extreme temperature events can be gained from this diagnostic. 1) The occurrence of low phase speeds over Northern Hemisphere midlatitudes is related to a poleward displacement of blocking frequency maxima; conversely, the occurrence of high phase speed is related to blocking occurring at lower latitudes than usual. 2) Periods of low phase speed are associated with the occurrence of anomalous temperatures over Northern Hemisphere midlatitudes in winter, while this linkage is weaker during boreal summer. 3) No significant trend in phase speed has been observed during recent decades, despite the presence of Arctic Amplification. The absence of trend in phase speed is consistent with the evolution of the meridional geopotential gradient during recent decades. On the other hand, the high temporal resolution of the phase speed metric highlights the intraseasonal and interannual variability of Rossby wave propagation and points to 2009/10 as an extreme winter characterized by particularly low phase speed.

How to cite: Riboldi, J., Lott, F., D'Andrea, F., and RIvière, G.: A daily estimate of phase speed to explore the link between Arctic Amplification and Rossby waves, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9212, https://doi.org/10.5194/egusphere-egu2020-9212, 2020.

EGU2020-19980 | Displays | AS1.15

Rossby wave breaking through the 21st century in a global climate model

Kevin Bowley and Melissa Gervais

Rossby wave breaking on the dynamic tropopause (DT) occurs when synoptic-scale Rossby waves become highly amplified and undergo a breaking process.  This process can result in significant meridional transport of air masses resulting and intrusions of low latitude air poleward, high latitude air equatorward, or a combination of the two.  The ensuing modification of the troposphere and lower stratosphere in response to such events have been areas of considerable research due to their potential impacts on both high- and low-frequency mid- and high-latitude variability.  Furthermore, the processes and feedbacks associated with these events can result in notable changes to the jet structure and are frequently associated with atmospheric river events amongst other phenomena.  As such, the potential impacts of future changes in these events make them of considerable interest for identifying and studying in global climate model (GCM) simulations. 

Here, we apply a Rossby wave breaking identification scheme to three sets of 25-member Community Earth System Model simulations with prescribed sea surface temperature and sea ice conditions over the historical period (2010-2019), mid-Century (2050-2059) and late-Century (2090-2099).  This dataset represents a unique opportunity to study Rossby wave breaking processes in future climate simulations on a dynamically evolving surface rather than the more common pressure levels or isentropic levels as the DT is calculated for each of the CESM members.  Both anticyclonic and cyclonic Rossby wave breaking events are identified and tracked.  Events modeled in the historical period are compared to existing reanalysis data for the same period to explore the ability of the CESM model in this configuration to reproduce these events accurately.  Furthermore, the three periods of interest are examined to determine changes in the locations of Rossby wave breaking as well as the dynamic and thermodynamic characteristics of composited events. 

How to cite: Bowley, K. and Gervais, M.: Rossby wave breaking through the 21st century in a global climate model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19980, https://doi.org/10.5194/egusphere-egu2020-19980, 2020.

EGU2020-2424 | Displays | AS1.15 | Highlight

Size of the atmospheric blocking events: A scaling law and response to climate change

Pedram Hassanzadeh, Ebrahim Nabizadeh, Da Yang, Elizabeth Barnes, and Sandro Lubis

AS1.16 – The global monsoons in current, future and palaeoclimates and their role in extreme weather and climate events

EGU2020-3774 | Displays | AS1.16

A Review of Monsoon Responses to Warm Climates

Anji Seth, Alessandra Giannini, Maisa Rojas, Sara Rauscher, Simona Bordoni, Deepti Singh, and Suzana Camargo

Knowledge of how monsoons will respond to external forcings through the twenty-:rst century has been confounded by incomplete theories of tropical climate and insuZcient representation in climate models. This talk will overview recent insights from past warm climates and historical trends that can inform our understanding of monsoon evolution in the context of an emerging energetic framework. A theoretical framework interprets monsoons as an integral part of the global atmospheric overturning circulation, and associated energy, angular momentum, and moisture budgets, rather than regional land-sea breeze circulations. The discussion will include monsoon responses to (1) external forcing in paleoclimate records, (2) external forcing and internal variations in observed records, and (3) anthropogenic forcing in future projections. Lines of evidence from warm climate analogues indicate that while monsoons respond in globally coherent and predictable ways to orbital forcing and interhemispheric thermal gradients, there are differences in response to these forcings and also between land and ocean. Re:ning the energetic framework to incorporate zonal asymmetries will be critical to gain further insights into monsoon evolution at regional scales.

How to cite: Seth, A., Giannini, A., Rojas, M., Rauscher, S., Bordoni, S., Singh, D., and Camargo, S.: A Review of Monsoon Responses to Warm Climates, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3774, https://doi.org/10.5194/egusphere-egu2020-3774, 2020.

EGU2020-4052 | Displays | AS1.16

South Asian Summer Monsoon Variability and its teleconnections in CMIP6 Simulations

Ajayamohan Ravindran, Praveen Veluthedathekuzhiyil, and Sabeerali Cherumadanakadan Thelliyil

The mean and subseasonal monsoon variability is evaluated using simulations from 26 CMIP6 models in the present and future scenarios. In particular, the simulation of the monsoon trough, low pressure systems, and its relationship with seasonal rainfall, teleconnections with Pacific and Atlantic Oceans are analyzed, and the corresponding changes in the future scenario are investigated. Based on the fidelity of the model to simulate mean monsoon features, a set of models with good skill is identified. Selected good models are then used to analyze dynamical and teleconnection features. This study highlights and contrasts the performance of CMIP6 models in simulating various monsoon characteristics with CMIP5 models and further stresses the need for better water management strategies.

How to cite: Ravindran, A., Veluthedathekuzhiyil, P., and Cherumadanakadan Thelliyil, S.: South Asian Summer Monsoon Variability and its teleconnections in CMIP6 Simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4052, https://doi.org/10.5194/egusphere-egu2020-4052, 2020.

EGU2020-919 | Displays | AS1.16

Model performance in simulating the Global Monsoon: Skill evolution across CMIP generations
not presented

Luz Adriana Gómez, Carlos D. Hoyos, Diana Carolina Cruz, and Peter J. Webster

Improving projections of future changes in the global hydrological cycle is essential in order to understand the potential impacts of climate change and develop appropriate strategies of mitigation and adaptation to their socio-economics implications. This improvement requires a rigorous global climate model (GCM) evaluation, considering that several models often misrepresent fundamental processes of the global climate system. Recently, monsoons have been seen not just as independent systems that modulate the regional hydrology and climate but as a dominant global mode referred to as the Global Monsoon (GM). The GM is tied to global atmospheric circulation processes such as seasonal precipitation variations, the migration of the Inter-Tropical Convergence Zone (ITCZ), and the variability of the Hadley and Walker cells. Additionally, it can be seen as the response of the climate system to the annual solar radiation cycle. In this context, it is essential to consider not only regions with a marked seasonal change in the direction of surface winds but also the variation of precipitation in the tropics and subtropics. Reliable representations of its main characteristics are crucial for global simulations and climate change projections. 

This work assesses the ability of 64 GCMs part of three generations of the CMIP (phases 3, 5 and 6) simulating the most relevant characteristics of the global monsoon. Emphasis was placed on the GM domain and the two main modes of annual variation of precipitation and surface winds, referred to as Solstitial and Equinoctial modes. The GM wind domain and GM precipitation domain are well captured in most of the GCMs, and CMIP6 models show a significant improvement especially over the Asian-Australian monsoon (AAM) region. In order to evaluate the main modes of variability, we used projections of the model simulations onto the first two multivariate empirical orthogonal functions (MV-EOF) from observations. As a result, we find that in general, model performance is higher simulating the Solstitial mode compared to Equinoctial mode, but it has improved for both modes across the CMIP generations in terms of spatial variability and magnitude. Despite this, a regional analysis shows that performance over some regions, such as South America, does not exhibit significant improvement neither for the monsoon domain nor the annual variation modes.

We also considered the annual and seasonal mean of precipitation and surface winds, and we observed a notable improvement across CMIP generations to reproduce their spatial patterns of variability. However, biases of magnitude remain significant, mainly for global precipitation. Finally, it is relevant to point out that dispersion among GCMs was considerably reduced within CMIP6 and that we do not find a direct relationship between model performance and horizontal resolution. 

How to cite: Gómez, L. A., Hoyos, C. D., Cruz, D. C., and Webster, P. J.: Model performance in simulating the Global Monsoon: Skill evolution across CMIP generations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-919, https://doi.org/10.5194/egusphere-egu2020-919, 2020.

EGU2020-10044 | Displays | AS1.16

An idealised model of the Indian monsoon onset

Lucy Recchia, Stephen Griffiths, and Douglas Parker

The Indian monsoon is a seasonal large-scale circulation system with complex dynamical and thermodynamical interactions, the physics of which is not fully understood. In particular, the advance of the monsoon over India, propagating against the mean mid-level wind field, cannot be explained by simple moisture flux arguments. 

Here we introduce an idealised two-layer model of the moisture dynamics of monsoon onset, with simple and transparent physics, based on conservation laws applied to a vertical plane (which could represent a transect from northwest to southeast India). The model allows for moisture replenishment in the lower layer (corresponding to evaporation or a moist inflow), a flux of water vapour between the layers (corresponding to convection), and along-transect advection by prescribed upper and lower-layer flows. With idealised parameterisations of replenishment and convection, the model can be written as a pair of coupled partial differential equations, which permits both analytical and numerical solutions. When an equilibrium solution is perturbed by either a change in replenishment rate, convection strength, or winds, we observe the propagation of moisture fronts in both the upper and lower layers as the solution adjusts to a new equilibrium. When these moisture fronts propagate northwestwards against the upper-layer flow, they can be viewed as the monsoon onset. Taking advantage of the simplicity of the model, which allows a wide parameter regime to be investigated efficiently, we show how the onset speed depends on the assumed timescales of the parameterised convection and lower-layer replenishment, and that physically plausible parameterisations can lead to realistic onset speeds, even in this highly idealised model.

How to cite: Recchia, L., Griffiths, S., and Parker, D.: An idealised model of the Indian monsoon onset, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10044, https://doi.org/10.5194/egusphere-egu2020-10044, 2020.

EGU2020-376 | Displays | AS1.16

Increase in summer monsoon rains in northeast India during ENSO periods: a multiproxy analysis

Arvind Singh, Kiran Kumar Pullabotla, and Ramesh Rengaswamy

El-Niño Southern Oscillation (ENSO) affects Indian summer monsoon. Most of the worst droughts - the most recent being in 2009 - in India have been triggered by ENSO. But given the heterogeneity in rainfall patterns over India, we revisited ENSO influence on Indian summer monsoon. Our analysis based on multiple isotopic (proxy-based) and satellite data set shows significant variation in the spatiotemporal patterns of rainfall over the Indian subcontinent and adjoining oceans. We observed a weaker summer monsoon over central India and relatively stronger summer monsoon over northeast India during strong El-Niño events. Rainfall derived from isotope-enabled general circulation models reproduces weak and strong rainfall patterns during the El-Niño events over central India and northeast India, respectively. These model derived δ18Orain (oxygen isotopic composition of rainfall) variation over central India during ENSO events mimic the weaker rainfall conditions. However, significant changes in the model derived rainfall and associated δ18Orain is not observed over northeast India during ENSO events. Based on multiple data analysis, we infer that the long term variations (trends) in the Indian summer monsoon strength were controlled by the long term variation in ENSO during the last 50 years (1965 – 2013).

Since these observations were unprecedented and counterintuitive, we further verified our observations from the proxy records. Two speleothems (cave deposits) records from the central India and northeast India were analyzed for the rainfall variation and ENSO influence signatures. These paleo-proxy records showed a similar inverse relation of rainfall patterns over central India and northeast India during ENSO periods, confirming observed ENSO’s role on rainfall. Also, these proxy records showed a long-term pause in ENSO events or stronger La-Niña like conditions, which were persisted during 1625 – 1715 and favored stronger (weaker) rainfall over central India (northeast India).

How to cite: Singh, A., Pullabotla, K. K., and Rengaswamy, R.: Increase in summer monsoon rains in northeast India during ENSO periods: a multiproxy analysis, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-376, https://doi.org/10.5194/egusphere-egu2020-376, 2020.

Hydrological extremes have increased in recent decades and are expected to escalate in the future. This led to global and regional water stress and drought hazards. Further down in the chain it impacts on farming, pollution, ecosystem, and socio-economic conditions. A better understanding of both quantitative and qualitative assessment of drought under changing climate is very crucial for sustainable water security and management. In the present study, over different homogeneous regions of India, using 19 Global Climate Models (GCMs) and Regional Climate Models (RCMs) 21 simulations datasets, drought climatology is prepared. The changes in drought distribution and characteristics analyzed using density functions and its probability of occurrence associated with return period derived from Standardized Precipitation Index (SPI) and Standardized Potential Evapotranspiration Index (SPEI). Each model is evaluated for biases against Multi-Model Ensembles (MME) and observational datasets for the reference period 1976-2005. Uncertainties from various sources associated with intermodal variability, including drought type and threshold, were evaluated. Under high emission (RCP8.5) scenario, both the ensembles (GCM and RCM) are showing the consistent spatiotemporal variability of precipitation and potential evapotranspiration with noticeable differences in magnitude. Biases are reduced in RCM over GCM (ensemble) with respect to observations. Modeled SPI is showing enhanced wetness derived from increased precipitation, while SPEI is exhibiting the drying trend largely associated with enhanced potential evapotranspiration under warming climate. There is an increase in the drought severity and intensity with the same return period in the future epoch. The overall analysis suggests the water scarcity and enhanced drought risks over India under unrestricted anthropogenic warming scenario.

How to cite: Saharwardi, M. S. and Kumar, P.: Drought variability and projections over India under high emission scenario with uncertainty assessment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-52, https://doi.org/10.5194/egusphere-egu2020-52, 2020.

The northern and the southern modes are two distinct principle modes that dominate the winter mean surface air temperature (Ts) variations over East Asia (EA). The cold southern mode is represented by a significant cooling south of 45°N and is linked to La Niña events. An objective criterion, which could distinguish the spatial distributions and the maximum center of sea surface temperature anomaly (SSTA), is used to classify the La Niña events into two categories: mega-La Niña and equatorial La Niña. Their impacts are inspected onto the Ts southern mode. The mega-La Niña, featured by a significant K-shape warming in the western Pacific with the maximum SSTA cooling centered in the tropical central Pacific. As a response, an anomalous barotropic high is generated over North Pacific (NP) implying a weak zonal gradient between ocean and the EA continent, which induces a neutral Ts southern mode. The equatorial La Niña characterizes a significant cooling in the tropical eastern Pacific with convective descending motions shifting eastward to the east of the dateline. The resultant low-level circulation anomalies show an anomalous subtropical NP low and a gigantic abnormal EA continent high. The strong zonal gradient results in significant northerly anomalies over EA from 55°N to southeastern China. Over the mid-upper troposphere, the anomalous subtropical NP low extends westward to the Korean Peninsula, leading to a strengthened and southward shifted EA trough. Such abnormal circulation patterns favor the intrusion of cold air to southern EA and correspond to a strong Ts southern mode. The numerical results well validate the above processes and physical mechanisms. 

How to cite: Wu, Z.: Reexamining the Relationship of La Niña and the East Asian Winter Monsoon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-159, https://doi.org/10.5194/egusphere-egu2020-159, 2020.

The Sahel is the semi-arid, transitional region separating the Sahara Desert from humid equatorial Africa, i.e. the poleward-most region to which appreciable rains from the West African monsoon extend during northern summer.  The severe drought it experienced in the 1970s and 1980s was one of the 20th century's most striking (and devastating) hydroclimatic events worldwide.  In climate model simulations of future global warming, Sahelian rainfall does anything from intense drying to even greater wettening depending on which climate model is used.  In this talk, I present recent research on rainfall in the Sahel using the moist static energy (MSE) budget -- what are the physical factors that drive its variations, and how do we expect them to change as the planet warms --- and the extent to which inferences from the Sahel can or cannot extend to other regions and other external forcings.

Using climate model simulations both of Earth's present-day conditions and of future global warming, I show that the drying influence of the Sahara Desert is a dominant factor in present-day and that this influence is strengthened with warming due to an increasing difference in moisture between the desert and the Sahel.  This enhancement of an existing moisture (and energy) gradient is a robust response of the atmosphere to mean ocean surface warming and has a firm theoretical basis.  By comparing climate model simulations of the present-day Sahel climate to real-world observations, I argue that this Sahara-driven drying mechanism is overly strong in those models that dry the Sahel most in future simulations.  This response to mean warming of global sea surface temperatures (SSTs) is readily explained using the MSE budget, whereas the Sahel rainfall response to changes in the spatial pattern of SSTs (such as during the 1970s-80s drought) are more easily interpreted via the popular energetic framework for Intertropical Convergence Zone (ITCZ) shifts.  I discuss the interplay between these and other theoretical frameworks for forced monsoon rainfall changes in the Sahel and other monsoon regions and offer ideas for refining and extending those theories.

How to cite: Hill, S.: Forced monsoon rainfall changes and the moist static energy budget: the Sahel and elsewhere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11632, https://doi.org/10.5194/egusphere-egu2020-11632, 2020.

EGU2020-923 | Displays | AS1.16

Combined effects of anthropogenic aerosols and global warming on the South Asian Monsoon

Ayantika Dey Choudhury, Krishnan Raghavan, Manmeet Singh, Swapna Panickal, Sandeep Narayansetti, Prajeesh A.Gopinathan, and Ramesh Vellore

The South Asian monsoon (SAM) precipitation has been generally regarded to exhibit contrasting responses to greenhouse gas (GHG) and anthropogenic aerosol forcing, although it is not adequately clear as to how it might respond to the combined influence of GHG and aerosol forcing.  The present study examines the individual and combined effects of global warming and anthropogenic aerosols on the SAM based on a suite of numerical experiments conducted using the IITM Earth System Model version2 (IITM-ESMv2). Four sets of 50-year model integrations are performed using IITM-ESMv2 with different anthropogenic forcings 1) Pre-Industrial control, 2) anthropogenic aerosols of 2005 3) CO2 concentrations of 2005 4) anthropogenic aerosols and CO2 of 2005. In the experiment with the elevated CO2 level of 2005, an intensification of SAM precipitation and strengthening of large-scale monsoon cross-equatorial flow is noted relative to the PI-CTL run. In contrast, the experiment with elevated anthropogenic aerosols of 2005 shows a decrease of SAM precipitation and weakening of monsoon circulation relative to the PI-CTL run. A striking result emerging from this study is the strong suppression of SAM precipitation, pronounced weakening of the monsoon circulation and suppression of organized convection in response to the combined radiative effects of elevated CO2 and anthropogenic aerosols relative to the PI-CTL run. By diagnosing the model simulations it is noted that the radiative effects in the combined forcing experiment lead to a pronounced summer-time cooling of the NH as compared to the equatorial and southern oceans which are predominantly influenced by global warming, thereby creating a north-south differential radiative forcing over the Indian longitudes.  Additionally, the influence of absorbing aerosols over South and East Asia creates a surface radiation deficit over the region, stabilizes the lower troposphere, slows down the monsoon winds and reduces surface evaporation.  Although the anticyclones over the subtropical Indian Ocean intensify in the combined forcing experiment, the model simulation shows that much of the precipitation enhancement occurs to the south of the equator over the Indian Ocean whereas the moisture transport and convergence to the north of the equator is substantially reduced. Furthermore, the combined forcing experiment shows that anomalous large-scale descent over the subcontinent reinforces the suppression of organized convection giving rise to more intense breaks and weaker active spells in the southwest monsoon on sub-seasonal time-scales. This study hints that future decreases in NH aerosol emissions could potentially reverse the ongoing decreasing trend of the observed SAM precipitation since 1950s in a purely global warming environment.

How to cite: Dey Choudhury, A., Raghavan, K., Singh, M., Panickal, S., Narayansetti, S., A.Gopinathan, P., and Vellore, R.: Combined effects of anthropogenic aerosols and global warming on the South Asian Monsoon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-923, https://doi.org/10.5194/egusphere-egu2020-923, 2020.

EGU2020-5419 | Displays | AS1.16

Radiative effects of clouds and water vapor on the monsoon

Michael Byrne and Laure Zanna

Monsoons are summertime circulations shaping climates and societies across the tropics and subtropics. Here the radiative effects controlling the climatological monsoon and its response to climate change are investigated using idealized simulations. The influences of clouds, water vapor and CO2 on the monsoon are decomposed using the radiation-locking technique. Seasonal cloud and water vapor radiative effects strongly modulate the climatological monsoon, reducing net monsoon precipitation by approximately half. Warming and moistening of the monsoon by seasonal longwave cloud and water vapor effects are counteracted by a strong shortwave cloud effect. The shortwave cloud effect expedites monsoon onset by approximately 10 days, whereas longwave cloud and water vapor effects delay onset. A simple theory for monsoon onset relates monsoon onset to the efficiency of surface cooling. In climate change simulations the water vapor feedback and CO2 forcing have similar influences on the monsoon, warming the surface and moistening the region. In contrast, clouds have a negligible effect on surface temperature yet dominate the response of the monsoon circulation to climate change. The radiation-locking simulations and analyses advance understanding of how and why radiative processes influence the monsoon, and establish a new framework for interpreting monsoon--radiation coupling in observations, in state-of-the-art models and in different climate states. Moreover, sensitivities of the monsoon to the longwave cloud feedback are found to be similar over the seasonal cycle and under CO2 forcing, suggesting a potential emergent constraint for monsoons in a changing climate.

How to cite: Byrne, M. and Zanna, L.: Radiative effects of clouds and water vapor on the monsoon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5419, https://doi.org/10.5194/egusphere-egu2020-5419, 2020.

Tropical cyclones (TCs) in the western North Pacific (WNP) are modulated by large-scale circulation systems such monsoon trough, intraseasonal oscillation, teleconnection pattern, El Niño and Southern Oscillation, and some interdecadal oscillations. While the low-frequency, large-scale circulation produces a clustering effect on TCs, the latter in return leave marked footprints in climate mean state and variability because of large amplitudes in circulation and strong heating. In this study, we applied PV inversion technique to remove TCs from reanalysis and evaluate their contribution to mean circulation and climate variability. It is found that the mean climatological circulation (e.g., low-level monsoon trough and upper-tropospheric anticyclone) would be much weaker with TCs removed. Intraseasonal and interannual variance of certain variables could decrease by as much as 40–50 percent. An accompanied study indicated that TCs had slowed down the sea surface warming in the WNP for the past few decades because of TC-induced cooling. Our results suggest that TC effect has to be considered to understand the climate variability in the tropical atmosphere and ocean. The ensemble effect of TCs, at least in the statistical sense, has to be resolved in climate models to better simulate climate variability and produce more reliable climate projection in the TC-prone regions.

How to cite: Hsu, H.-H.: Footprints of Tropical Cyclones in WNP Summer Monsoon Variability, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13325, https://doi.org/10.5194/egusphere-egu2020-13325, 2020.

EGU2020-6488 | Displays | AS1.16

A reconstruction of the East Asian summer monsoon index over the half past millennium

Feng Shi, Hugues Goosse, Jianping Li, Fredrik Charpentier Ljungqvist, Sen Zhao, Ting Liu, Qiuzhen Yin, and Zhengtang Guo

The EASM largely determines variations in summer precipitation in the East Asian monsoon region where approximately one-quarter of the world’s population live. A reliable East Asian summer monsoon (EASM) index covering several centuries is important in order to understand EASM dynamics. The wind-field is frequently used to calculate the EASM index during the instrumental period. However, available climate proxy data rather respond to direct precipitation changes. A gridded extended summer (May–September, MJJAS) precipitation reconstruction for China covering AD 1470–2000 is used to indirectly reconstruct two types of EASM indices (defined by the strength of the 850hPa southwesterly winds and a north-south gradient of the zonal winds), using the negative correlation between the EASM index and summer (June–August, JJA) rainfall in the middle and lower reaches of the Yangtze River of China. The two EASM indices are validated by independent historical documentary data for eastern China. The physical processes ruling the EASM variability are explored, highlighting a baroclinic structure over the middle and lower reaches of the Yangtze River. It includes an anticyclonic circulation accompanied by high pressure anomalies in the lower troposphere and a cyclonic circulation with low pressure anomaly in the upper troposphere. This is associated with a decrease in atmospheric water vapor content (due to divergence), which will decrease summer rainfall in the region, and contribute to the strengthen of the EASM variability. The dominated and inter-annual component of the EASM variation is possibly linked to the ‘ENSO-like’ sea surface temperature according to a data assimilation experiment performed with the Community Earth System Model-Last Millennium Ensemble (CESM-LME) simulation.

How to cite: Shi, F., Goosse, H., Li, J., Ljungqvist, F. C., Zhao, S., Liu, T., Yin, Q., and Guo, Z.: A reconstruction of the East Asian summer monsoon index over the half past millennium, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6488, https://doi.org/10.5194/egusphere-egu2020-6488, 2020.

Austral wet season precipitation (October through March) in the subtropical parts of Brazil is related to the strength and position of the South American Convergence Zone (SACZ), one of the main features of the South American Monsoon System. The SACZ can be defined as the aggregation of individual tropical-extratropical (TE) cloud bands. Such TE cloud bands have deep convection and heavy rainfall linking the tropical convection over the Amazon rain forest to the mid-latitude weather systems in the Southern Ocean. Utilising a cloud band identification technique, which consists of an object-based algorithm that identifies TE interactions, we detected individual weather systems and explored their associated precipitation characteristics and changes since 1980. Each event is characterised by the total precipitation within the contour of the low-value OLR. For this, we considered three different datasets: observed precipitation from various weather stations over Brazil, gridded to a 0.25° lat/lon resolution; satellite-based rainfall from TRMM (version 3B42); and reanalysis-based precipitation from ERA5. Here we explore the spatial characteristics and associated precipitation statistics of the SACZ events identified through the proposed technique. The monthly spatial signature of the selected events is similar among the three data sources and corresponds to the SACZ location. The selected events account for 25% to 50% of the total monthly precipitation during the wet season, with the largest percentages occurring in December and January. Over South-eastern Brazil, we identified a reduction in the number of events and in total precipitation during these events, resulting in a reduction of their contribution to the total precipitation climatology during the last decade. The drying trends occur mostly in December; in January, the areas with reduced precipitation migrate northward and precipitation increases over Southern Brazil, suggesting that the poleward migration of the SACZ is more pronounced during these months. These results demonstrate the relationship between synoptic systems and the changes in the location of the SACZ described in recent studies. In the next steps, we will diagnose the reanalysed and climate-simulated circulations associated with these events, identifying possible mechanisms responsible for the poleward shift of the SACZ.

How to cite: Zilli, M. and Hart, N.: Synoptic climatology and changes in precipitation associated with the South Atlantic Convergence Zone utilising a cloud band identification technique, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11038, https://doi.org/10.5194/egusphere-egu2020-11038, 2020.

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Effects of the Tibetan Plateau on East Asian Summer Monsoon via Weakened Transient Eddies

Qiaoling Ren, Song Yang, Xinwen Jiang, Yang Zhang, and Zhenning Li

Previous studies have revealed that the Tibetan Plateau (TP) can weaken the high-frequency and low-frequency transient eddies (TE) transported along the westerly jet. Here the effects of TP on East Asian summer monsoon via weakened TE are investigated based on the simulations by the NCAR Community Earth System Model, in which a nudging method is used to amplify the TP’s inhibition of TE without changing the steady dynamic and thermodynamic effects of TP. Results reveal that the weakened TE by TP weaken the East Asian westerly jet (EAWJ) and shift the jet southward via transient vorticity flux. The southward EAWJ accompanied with reduced poleward transport of moisture by TE results in less rainfall in northern East Asia but more rainfall in southern East Asia, particularly in early summer when the EAWJ is stably located over the TP and the meridional gradient of water vapor is large. Furthermore, the anomalous precipitation can move the EAWJ further southward through the anomalous diabatic heating in early summer, forming a positive feedback. Therefore, the TP’s inhibition of TE can shift the East Asian rain belt southward, different from the TP’s steady forcing which favors a poleward shift of the rain belt. It is also demonstrated that the atmospheric internal variability can lead to the south-flood-north-drought pattern of summer rainfall change over East Asia, indicating the important role of TE in East Asian summer monsoon.

How to cite: Ren, Q., Yang, S., Jiang, X., Zhang, Y., and Li, Z.: Effects of the Tibetan Plateau on East Asian Summer Monsoon via Weakened Transient Eddies, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4341, https://doi.org/10.5194/egusphere-egu2020-4341, 2020.

models from phase 5 of the Coupled Model Intercomparison Project (CMIP5). sea surface temperature

How to cite: Gan, R.: Assessing the internal variability in multi-decadal trends of summer rainfall over East Asia-Northwest Pacific with a large ensemble of GCM simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1557, https://doi.org/10.5194/egusphere-egu2020-1557, 2020.

EGU2020-1819 | Displays | AS1.16

The relative roles of the South China Sea summer monsoon and ENSO in the Indian Ocean dipole development

Jianping Li, Yazhou Zhang, Jiaqing Xue, Fei Zheng, Renguang Wu, Kyung-Ja Ha, and Juang Feng

The influence of El Niño-Southern Oscillation (ENSO) on the Indian Ocean Dipole (IOD), a coupled ocean–atmosphere mode of interannual climate variability, has been widely investigated over recent decades. However, a latest study indicates that the South China Sea summer monsoon (SCSSM) might also be responsible for IOD formation. Furthermore, an abnormal SCSSM does not always coincide with ENSO during boreal summer (June–August, JJA); consequently, the individual and combined effects of the SCSSM and ENSO on the IOD remain elusive. This study shows that the amplitude of the IOD tends to be much stronger under the coexistence of SCSSM and ENSO than that under individual SCSSM or ENSO events during JJA and autumn. The findings also indicate that the SCSSM and ENSO play the dominant role around the eastern and western poles of the IOD, respectively. An anomalous local Hadley circulation closely related to the stronger SCSSM favors anomalous southeasterly of Sumatra and Java during JJA, which enhance oceanic upwelling and subsequently result in cooling of the sea surface temperature (SST) over this area. Similarly, it can be envisaged that the contemporaneous ENSO could influence JJA SST anomalies over the western Indian Ocean via the Walker circulation coupled with oceanic variations.

How to cite: Li, J., Zhang, Y., Xue, J., Zheng, F., Wu, R., Ha, K.-J., and Feng, J.: The relative roles of the South China Sea summer monsoon and ENSO in the Indian Ocean dipole development, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1819, https://doi.org/10.5194/egusphere-egu2020-1819, 2020.

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Statistics of Monsoon Low Pressure Systems in the Indian Subcontinent and Estimation of Related Extreme Rainfall Risk

Tresa Mary Thomas, Govindasamy Bala, and Srinivas Venkata Vemavarapu

Indian monsoon, which spans through the months of June-September, brings in copious rain for the agriculture dependent country India. Monsoon low pressure systems (LPS) are the major rain bearers during the season. Apart from being a lifeline, they are also cited as a cause of disastrous floods in the country. Various approaches have been attempted to locate and track these LPS. Inconsistency exists among  them in statistics of LPS not only for the historical period, but also in future projections of these systems. We have developed an improved tracking scheme in this study. . The new approach takes into consideration geopotential height anomaly condition and is  named Automated Tracking algorithm using geopotential criteria (ATAGC). The approach is validated by comparing characteristics of LPS identified by it with those identified in previous studies. On average, around 14 LPS  each year are identified by the new approach, which comprise 9 lows, 4 depressions and about one deep depression. Further, the annual average number for LPS days is estimated as 68. The LPS mostly form over north part of Bay of Bengal and move north-westwards. Synoptic Activity Index, which quantifies LPS risk at a location in terms of both frequency and intensity of the system, shows that locations in the coastal regions of central India are highly affected by LPS. But the effect in terms of extreme rainfall is not localized near  the coast. Even though contribution of LPS towards total monsoon rainfall and total extreme precipitation has been analyzed in previous studies, the risk in terms of extreme rainfall due to LPS has not been assessed. In this study, extreme rainfall risk map in terms of average extreme precipitation and 90 percentile precipitation observed at a location in the vicinity of an LPS is determined. An average extreme rainfall of 60-100mm/day and 90 percentile extreme rainfall of 150-250mm/day is estimated at many locations in Central Indian region due to LPS. While analyzing continuous spells of rainfall, it is found  that along with LPS, topography of a region has considerable effect on the duration of the spells.

How to cite: Thomas, T. M., Bala, G., and Venkata Vemavarapu, S.: Statistics of Monsoon Low Pressure Systems in the Indian Subcontinent and Estimation of Related Extreme Rainfall Risk, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1837, https://doi.org/10.5194/egusphere-egu2020-1837, 2020.

It is known that the existence of the Tibetan Plateau (TP) intensifies the Asian summer monsoon. However, is the current subtropical location of the TP optimal for energizing the monsoon? Would monsoon dynamics become simpler if the TP were located in the tropics? A series experiments with the NCAR CESM fully-coupled model show that a change in the current subtropical TP causes apparent responses in both divergent and rotational motions of the atmosphere in the tropics and higher latitudes, respectively. When the TP is moved southward, the atmospheric response is featured by more apparent thermally-driven and divergent part of atmospheric motion, and the tropical South Asian monsoon becomes stronger. However, the subtropical East Asian monsoon becomes weaker due to the intensify of Northwest Pacific subtropical high. In the experiments in which the TP is moved northward, the subtropical East Asian monsoon strengthens at some points but the tropical South Asian monsoon weakens. Besides, variations in the meridional position of the westerlies relative to the TP lead to anomalous distribution of precipitation in East Asia. In these latter experiments, the atmospheric response is apparently featured by rotational characteristics of the atmospheric motion.

Results also show that the meridional shift of the TP would also cause changes in the African summer monsoon, whose variability is closely linked to the variations of the Asian summer monsoon.

How to cite: Wang, J. and Yang, S.: Is the Current Subtropical Position of the Tibetan Plateau Optimal for Intensifying the Asian Monsoon?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2247, https://doi.org/10.5194/egusphere-egu2020-2247, 2020.

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Future changes of summer monsoon characteristics and evaporative demand over Asia in CMIP6 simulations

Kyung-Ja Ha, Suyeon Moon, Axel Timmermann, and Daeha Kim

Future greenhouse warming is expected to influence the character of global monsoon systems. However, large regional uncertainties still remain. Here we use 16 CMIP6 models to determine how the length of the summer rainy season and precipitation extremes over the Asian summer monsoon domain will change in response to greenhouse warming. Over East Asia the models simulate on average on the earlier onset and later retreat; whereas over India, the retreat will occur later. The model simulations also show an intensification of extreme rainfall events, as well as an increase of seasonal drought conditions. These results demonstrate the high volatility of the Asian summer monsoon systems and further highlight the need for improved water management strategies in this densely-populated part of the world.

How to cite: Ha, K.-J., Moon, S., Timmermann, A., and Kim, D.: Future changes of summer monsoon characteristics and evaporative demand over Asia in CMIP6 simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3269, https://doi.org/10.5194/egusphere-egu2020-3269, 2020.

EGU2020-3294 | Displays | AS1.16

Influence of the North Pacific Victoria mode on the Madden–Julian Oscillation

Tao Wen, Quanliang Chen, Jianping Li, Ruiqiang Ding, Yu-heng Tseng, and Zhaolu Hou

The influence of the North Pacific Victoria mode (VM) on the Madden–Julian Oscillation (MJO) are examined in this analysis. The results show that the February–April (FMA) VM had a significant influence on the development and propagation of the MJO over the equatorial central–western Pacific (ECWP) during spring (March–May) between 1979 and 2017. Specifically, MJO development was favored more by positive VM events than negative VM events. One probably description for these complicated connections is that the SST gradient anomalies associated with positive VM events enhance the convergence of low-level over the ECWP, which, combined with the warm SST anomalies (SSTAs) in the equatorial central Pacific that lead to a boost in the Kelvin wave anomalies, results in the enhanced MJO activity over the ECWP. These conclusions indicate that the VM is an important factor in MJO diversity.

How to cite: Wen, T., Chen, Q., Li, J., Ding, R., Tseng, Y., and Hou, Z.: Influence of the North Pacific Victoria mode on the Madden–Julian Oscillation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3294, https://doi.org/10.5194/egusphere-egu2020-3294, 2020.

EGU2020-3623 | Displays | AS1.16

The American Monsoon System in UKESM1 and HadGEM3

Jorge Luis García-Franco, Lesley Gray, and Scott Osprey

The American Monsoon System is the main source of rainfall for the tropical and sub-tropical Americas. CMIP6 climate model simulations from the MetOffice Hadley Centre (MOHC) models: HadGEMGC3.1 and the Earth System model UKESM1 were analyzed to evaluate the representation of this monsoon. Pre-industrial and historical experiments were compared to reanalyses and observations.  Several diagnostics, such as the Inter-tropical Convergence Zone (ITCZ) location, the Walker circulation and temperature and precipitation seasonal cycles in the American Monsoon System were assessed, as well as El Niño-Southern Oscillation teleconnections to the monsoon. 

These simulations reasonably represent the observed seasonal cycle of precipitation in the American Monsoon System. However, significant biases in the spatial distribution of rainfall in South America are evident. 
These biases in the South American Monsoon System are linked to temperature biases in the Amazon and Atlantic ITCZ biases. 
The midsummer drought regime in Central America, the Caribbean and southern Mexico is reproduced by all the simulations, although with a stronger intraseasonal cycle than observed.
The North American monsoon is relatively well represented by all the simulations, which is a noticeable improvement of these models compared to CMIP5. 

The overall performance of HadGEM3 at different horizontal resolutions was compared to that of UKESM1. 
This work evaluates the role of horizontal resolution and Earth System processes for monsoon representation which will be useful for interpreting scenario experiments or using CMIP6 runs for understanding variability and
teleconnections in this monsoon system.  

How to cite: García-Franco, J. L., Gray, L., and Osprey, S.: The American Monsoon System in UKESM1 and HadGEM3, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3623, https://doi.org/10.5194/egusphere-egu2020-3623, 2020.

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Analysis of the differences between the North Pacific Victoria and meridional modes

Kai Ji, Hongchao Zuo, Jianping Li, and Ruiqiang Ding

The Victoria mode (VM) and Pacific meridional mode (PMM) are the dominant SST modes over the North Pacific. Both are forced by a North Pacific Oscillation (NPO)-like extratropical atmospheric variability, and can act as a bridge (or conduit) through which North Pacific extratropical atmospheric variability influences ENSO. Consequently, the VM shares some resemblance with the PMM. However, the VM and PMM differ in terms of their spatial structure, temporal variations, and impacts on ENSO. In contrast to the local SST mode of the PMM in the subtropical northeast Pacific, the VM, as a basin-scale SST mode of the North Pacific basin, includes large-amplitude SSTAs over the northeast Pacific, the western North Pacific (WNP), and the high-latitude North Pacific. Results indicate that SLP anomalies associated with the VM are generally located west of those associated with the PMM. In addition, the VM has a unique temporal variability, independent of the PMM. Furthermore, the VM is more closely linked to ENSO than is the PMM, possibly because the VM combines the effects of the PMM and SSTAs in the WNP. Thus, the VM represents a more reliable precursor signal than the PMM for ENSO events and may have profound implications for ENSO prediction.

How to cite: Ji, K., Zuo, H., Li, J., and Ding, R.: Analysis of the differences between the North Pacific Victoria and meridional modes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3886, https://doi.org/10.5194/egusphere-egu2020-3886, 2020.

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Simulation of Monsoon trough and low pressure systems in CMIP6 models

Praveen Veluthedathekuzhiyil, Ajayamohan Ravindran, and Sabeerali Cherumadanakadan Thelliyil

Monsoon low pressure systems (LPS) contributes to more than half of the Indian monsoon rainfall. However most climate models fail to capture the characteristics of low pressure systems realistically. This aspect is scrutinized in a wide range of available CMIP6 model simulations using an objective LPS tracking algorithm. Broader features such as monsoon trough over which these systems forms are also analyzed. It has been found that, majority of the models fail to realistically represent these two important features. However few models that were able to capture these events in CMIP5 are able to simulate them in CMIP6 as well. We examine the dynamical features that lead to realistic simulation of LPS in these set of models. Selected good models are then used to study the characteristics of LPS in a future warming scenario. This study will help in judging the performance of models and for any future improvements.

How to cite: Veluthedathekuzhiyil, P., Ravindran, A., and Cherumadanakadan Thelliyil, S.: Simulation of Monsoon trough and low pressure systems in CMIP6 models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4049, https://doi.org/10.5194/egusphere-egu2020-4049, 2020.

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Role of friction and orography in the Asian-African monsoonal system

Giovanni Dalu, Marco Gaetani, Cyrille Flamant, and Marina Baldi

The West African monsoon (WAM) originates in the Gulf of Guinea when the intertropical convergence zone (ITCZ) makes its landfall; whilst, the south Asian monsoon (SAM) originates in the Indian ocean when the ITCZ crosses the equator. The monsoonal dynamics are here studied after landfall using Gill’s tropospheric model with an implanted Ekman frictional layer (EFL). Ekman pumping increases low level convergence, making the lower monsoonal cyclone deeper and more compact that the upper anticyclone, by transferring tropospheric vorticity into the EFL. In the upper troposphere, air particles spiral-out anticyclonically away from the monsoons, subsiding over the Tropical Atlantic, the Tropical Indian ocean, or transiting into the southern hemisphere across the equator. Whilst marine air particles spiral-in cyclonically towards the WAM or the SAM, the latter appears to be a preferred ending destination in the absence of orography. The Himalayas introduced as a barrier to the monsoonal winds, strengthen the tropospheric winds by tightening the isobars. The Somali mountains (SMs), introduced as a barrier to the Ekman winds, separates the WAM and the SAM catch basins; thus, the Atlantic air particles converge towards the WAM and the Indian ocean particles converge towards the SAM. The Indian Ghats (IGs), introduced as a semi-impermeable barrier to the Ekman winds, deflect the marine air particles originated in the western Indian ocean towards the south-eastern flank of the SAM. In short, an upper single anticyclone encircles both monsoons; the Himalayas strengthen the upper-level winds by increasing the pressure gradients; the SMs split the EFL cyclone, keeping the marine air particles to the west of SMs in the WAM basin and the particles to the east of SMs in the SAM basin; the IGs guides transmit the air particles, deflecting them towards Bangladesh.

How to cite: Dalu, G., Gaetani, M., Flamant, C., and Baldi, M.: Role of friction and orography in the Asian-African monsoonal system, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7619, https://doi.org/10.5194/egusphere-egu2020-7619, 2020.

Extreme weather creating a widespread humanitarian crisis over East Africa in recent decades. The seasonal cycle of precipitation over the Horn of Africa (HOA) shows bimodality with long rain and short rain. Most of the models fail to capture biannual rainfall seasonal cycles, due to circulation response to unrealistically dominate the annual mean. The Community Earth System Model (CESM) high-resolution model simulation has been employed to study the sensitivity. Precipitation distribution over HOA shows regional variations where most of the region show the bimodal distribution and the intrinsically complex. This bimodality is nominally associated with tropical rain belt, but topography and SST-forcing also play an important role in influencing the timing and intensity of seasonal rainfall. The results show that overall rainfall seasonality is increased, with intensification over high elevation. Precise representation of rainfall seasonal cycle over HOA adds confidence for future projected changes in seasonality. An important question is whether and how the seasonal cycle over HOA responds to anthropogenic forcing. We show that the future change in precipitation seasonal cycle and accumulation over HOA can be explained by the surface ocean process which module SSTs along the coastline of Somalia. The moisture convergence over low elevation land is basically regulated through the north-south SST gradient. In conclusion, future global warming leads to the intensified seasonal cycle of precipitation with a projected increase in the short rain season over east Africa. Further analysis demonstrates how topography modulates the seasonality of HOA.

How to cite: Kad, P. and Ha, K.-J.: Future change in precipitation seasonality over the Horn of Africa in high-resolution simulation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12782, https://doi.org/10.5194/egusphere-egu2020-12782, 2020.

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Uncertainty in aerosol radiative forcing impacts the simulated global monsoon in the 20th century

Andrew Turner, Jonathan Shonk, Laura Wilcox, Andrea Dittus, and Ed Hawkins

Anthropogenic aerosols are dominant drivers of historical monsoon rainfall change.  However, large uncertainties in the radiative forcing associated with anthropogenic aerosol emissions, and the dynamical response to this forcing, lead to uncertainty in the simulated monsoon response.  We use historical simulations in which aerosol emissions are scaled by factors from 0.2 to 1.5 to explore the monsoon sensitivity to aerosol forcing uncertainty (−0.3 W m−2 to −1.6 W m−2).  Hemispheric asymmetry in emissions generates a strong relationship between scaling factor and both hemispheric temperature contrast and meridional location of tropical rainfall.  Increasing the  scaling from 0.2 to 1.5 reduces the global monsoon area by 3% and the global monsoon intensity by 2% over 1950–2014, and changes the dominant influence on the 1950–1980 monsoon rainfall trend from greenhouse gas to aerosol.   Regionally, aerosol scaling has a pronounced effect on Northern Hemisphere monsoon rainfall.

How to cite: Turner, A., Shonk, J., Wilcox, L., Dittus, A., and Hawkins, E.: Uncertainty in aerosol radiative forcing impacts the simulated global monsoon in the 20th century, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16401, https://doi.org/10.5194/egusphere-egu2020-16401, 2020.

EGU2020-20285 | Displays | AS1.16

Abrupt transition in organized convection during the monsoon onset in central India and Climate change effect

Nitin Babu George, Elena Surovyatkina, Raghavan Krishnan, and Jürgen Kurths

The Indian summer monsoon (ISM) has profound impacts on the economy and society since it directly affects more than a billion people in the Indian subcontinent. The development of land-ocean thermal contrast during May and June creates meridional temperature and pressure gradients and sets up the ISM circulation. The ISM circulation comprises of two branches, the Arabian Sea (AS) branch that is associated with southwesterly winds blowing from the AS towards the Indian landmass; and the Bay of Bengal (BoB) branch characterized by cyclonic circulation extending from the BoB into central and north India. These two branches dictate the advance of the ISM.

Forecast of the ISM rainfall is challenging even though it has been a research question for many decades. The Indian Meteorological Department forecasts the onset of monsoon over the Kerala, in the south [1]. The recently developed tipping element approach [2] allows forecasting the onset and withdrawal of the monsoon over Central India. However, every state in India desperately needs both forecasts: the onset and withdrawal of the monsoon. Uncertainty and delays (eg. year 2019) in the advance and withdrawal of monsoon results in farmers losing their crop investment. Further, there is no clear consensus on the effect of global warming on the monsoon timing.

Here we explore climate change effects on the advance of the ISM onset towards central India analysing observational data of Outgoing Longwave Radiation (OLR), near-surface air temperature and wind. OLR is a proxy for organized deep tropical convection, wherein low values of OLR correspond to deep clouds with low cloud-top temperatures and high values of OLR correspond to scarcity of clouds.

We use the tipping element approach [2] to reveal tipping in spatially organized rainfall. We find two tipping elements appearing in the AS and the BoB prior to the onset of monsoon in central India (MOC). Maximum fluctuations in the OLR at the tipping elements near MOC indicate deep convection within the two branches of monsoon. The abrupt transition in the OLR at the tipping elements corresponds to the transition from pre-monsoon to monsoon in Central India. We observe an interplay between the temporal dynamics of OLR at these two regions, which indicate the MOC. In these two regions, during the pre-monsoon season the average OLR closely follow each other. Subsequently, the time series of OLR in these two regions diverge from each other, which indicates MOC.

Under climate change, the temporal dynamics of OLR at these two locations show that the transition from pre-monsoon to monsoon has changed from an abrupt transition to a gradual transition in the Bay of Bengal. Furthermore, we identify different spatial patterns of near-air surface temperature, OLR and wind for early, normal and late MOC. We use these patterns as indicators for forecasting advance of ISM.

NBG and ES acknowledge the support of the EPICC project (18_II_149_Global_A_Risikovorhersage) funded by BMU

 

[1] https://mausam.imd.gov.in/

[2] Stolbova, V., E. Surovyatkina, B. Bookhagen, and J. Kurths (2016). GRL 43, 1–9 [doi:10.1002/2016GL068392]

How to cite: George, N. B., Surovyatkina, E., Krishnan, R., and Kurths, J.: Abrupt transition in organized convection during the monsoon onset in central India and Climate change effect, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20285, https://doi.org/10.5194/egusphere-egu2020-20285, 2020.

In this study, we estimate the changes in extreme precipitation indices over the western North Pacific and East Asia region (WNP-EA) during the spring and Mei-yu seasons in the warmer climate. Our analyses are based on two high-resolution atmospheric general circulation model simulations. The high-resolution atmospheric Model (HiRAM) was used in a series of simulations, which were forced by 4 sets of sea surface temperature (SST) changes under Representative Concentration Pathways 8.5 (RCP8.5) scenario. The Database for Policy Decision-Making for Future Climate Change (d4PDF) consists of global warming simulation outputs from MRI-AGCM3.2 with large ensemble members and multiple SST warming scenarios.

In the spring season, the changes in the spatial pattern of SDII, RX1day, and PR99 demonstrate greater enhancement over the northern flank of the climatological rainy region in both HiRAM and d4PDF, implying a northward extension of spring rain band. Besides, the changes in probability distribution display a shifting tendency that heavier extreme events occur more frequently in the warmer climate. The above changes are larger than the internal variability and uncertainty associated with SST warming patterns, indicating the robustness of the projected enhancement in precipitation intensity in the WNP-EA region. The spatial pattern for changes in CDD and total rainfall occurrence are less consistent between two datasets. In the Mei-yu season, the tendency toward more frequent extreme events in the probability distributions are consistently found in HiRAM and d4PDF. However, the changes in the spatial pattern of all indices are less consistent between HiRAM and d4PDF, implying larger uncertainty in the projection of extreme precipitation in the Mei-yu period in the warmer climate.

How to cite: Chen, C.-A. and Hsu, H.-H.: Changes in spring and Mei-yu extreme precipitation in the Western North Pacific and East Asia in the warmer climate in two high-resolution AGCMs, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21514, https://doi.org/10.5194/egusphere-egu2020-21514, 2020.

EGU2020-2081 | Displays | AS1.16

A climate classification: Mediterranean, monsoon and westerlies climates

Xin-Gang Dai and Ping Wang

This study aims to develop a large-scale climate classification for investigating the mechanisms of global climate formation in the surface. There are three types of large-scale climates, i.e., monsoon, Mediterranean and westerlies, corresponding respectively to collocation of temperature and precipitation at in-phase, anti-phase and out of phase, during seasonal cycle. The first one is called proper collocation, and the latter two are named as improper collocation, hereafter. The collocations are coupled with different seasonal moisture transport pattern with moisture divergence. Northward/southward moisture transport accompanies a moisture convergence/divergence with more/less precipitation in the season leading to different climate type. As an example, the climate around Tibetan Plateau can be attributed to four regimes, i.e., East Asia monsoon, South Asia monsoon, Central Asia and westerlies regimes, despite of the Köppen climate classification. The Central Asia regime refers to the dry climate in middle and southern part of the area, while the dry land belt with the westerlies regime extends from northern Central Asia throughout the northwestern China. The proper collocation between temperature and precipitation leads to a warm-wet climate over monsoon zones in warm season (May-October), whereas the improper one leads a hot-dry climate in Mediterranean climate areas and the dry land with the westerlies climate regime. By contrast, a mild-wet climate is in Mediterranean or quasi-Mediterranean climate areas in comparison with cold-dry climate in Asian monsoon zone during cold season (November to April). The improper collocation results in land degradation or even desertification in Mediterranean climate areas and the dry land with the westerlies regime with insufficient precipitation and over-evenly distribution of the precipitation during seasonal cycle. The improper collocation is actually made by improper dynamical and thermal dynamical collocation in regional moisture circulation associated with seasonal change of mid-latitude stationary waves in wave number and phase, which is virtually forced by large mountains and land-sea thermal contrast in the surface. Besides, analysis manifests that there exists mutually engagement between the seasonal changes in some properties of the mean moisture flows over monsoon and non-monsoon areas across Tibetan Plateau in Eurasian continent. It implies a dynamical coupling existed in large-scale moisture patterns over the earth surface.

Keywords: Large-scale climate classification, monsoon, westerlies, Mediterranean climate, Tibetan Plateau

How to cite: Dai, X.-G. and Wang, P.: A climate classification: Mediterranean, monsoon and westerlies climates, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2081, https://doi.org/10.5194/egusphere-egu2020-2081, 2020.

The East Asian Summer Monsoon (EASM) is a crucial monsoon system that profoundly influences the summer climate in Southeast China (SEC). Classification of monsoon rainfall patterns is vital to physical diagnosis, rainfall prediction and identification of sites that are prone to rainfall-triggering floods. With the great endeavors on understanding the complexity of the EASM in the past decades, the traditionally accepted rainfall patterns in SEC and the relevant analyses appear outdated or even inadequate. Having highly-improved observations at hand helps update the monsoon rainfall patterns in SEC and the potential predictability.

The present study employs a nonlinear neural network classification technique, the Self-organizing map (SOM), to identify the rainfall patterns in SEC based on gauge data. Three distinct rain belts over the Huai River basin (HRB), lower Yangtze River basin (LYRB) and South Coast region (SCR) are found. Their subseasonal variability highly agrees with the stepwise progression of the East Asian Summer Monsoon (EASM) front in space and time. Analysis reveals that precipitation in the SCR and HRB rain belts undergo a regime shift after the mid-1990s, whereas the 1990s is the most active decade for the LYRB rain belt. These systematic changes are in abreast with similar changes in EASM and other climate events documented in the literature.

Additionally, a SOM-based algorithm is developed to further divide gauge stations into three groups featuring homogeneous rain belt patterns. Promising predictability of group-averaged daily rainfall is then achieved, with about 39% to 50% of the total variance explained by circulation-informed regression models, verified by both cross-validation and blind prediction. Through further diagnosis in the useful predictors, the western North Pacific subtropical high, blocking high anomalies over northeast China and the upper-level divergence over SEC, are found to best explain the variability of the rain belts. The proposed Russia-China wave pattern (western/central Russia → north of Tibetan Plateau → SEC) and teleconnection between the El Niño-Southern Oscillation and the rain belts also offer additional predictability. This study aims to set an updated benchmark on the summer monsoon rainfall patterns in SEC, from which the promising daily predictability and the informative circulation patterns are obtained. Findings from this work may also advance the understanding of the EASM rain belts, and offer insights to the source of bias for numerical simulations of daily summer monsoon rainfall in the region.

How to cite: Dai, L., Cheng, T. F., and Lu, M.: Classification and Diagnosis of Summer Monsoon Rainfall Patterns and their Potential Predictability in Southeast China , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2133, https://doi.org/10.5194/egusphere-egu2020-2133, 2020.

AS1.17 – Asian Monsoon dynamics and Atmospheric Composition

EGU2020-2778 | Displays | AS1.17

Asian summer monsoon Chemical and Climate Impact Project (ACCLIP): Highlights of multi-model pre-mission study

Doug Kinnison, Qing Liang, Laura Pan, Paul Newman, Elliot Atlas, Brian Toon, William Randel, Jim Bresch, Mian Chin, Simone Tilmes, Alma Hodzic, Shawn Honomichl, Leslie Lait, Ren Smith, Parker Case, Alfonso Saiz-Lopez, Luke Jones, Jerome Barre, and Johannes Flemming

This presentation reports the findings of a multi-model pre-mission study in preparation for an airborne field campaign to investigate the upper troposphere and lower stratosphere (UTLS) composition under the influence of the Asian summer monsoon (ASM). The NSF/NASA supported airborne study is planned for the western Pacific atmosphere during July-August 2020 using a base in Okinawa, Japan. The pre-mission study uses three chemistry-transport models (i.e., NASA GSFC GEOS5, NCAR WACCM, and ECMWF CAMS) to investigate transport patterns and gas and aerosol chemical composition in the campaign region UTLS during the 2019 ASM period. In addition, artificial surface tracers from the WRF model helped identify the locations and evolution of rapid convective uplifting from regional sources. The impact of one typhoon occurrence during this 2019 ASM period will be discussed. Together, the multi-model results support the hypotheses of the ACCLIP campaign which identifies the western Pacific as a significant pathway for reactive chemical pollutants and climate relevant emissions from the ASM to enter the global UTLS.

How to cite: Kinnison, D., Liang, Q., Pan, L., Newman, P., Atlas, E., Toon, B., Randel, W., Bresch, J., Chin, M., Tilmes, S., Hodzic, A., Honomichl, S., Lait, L., Smith, R., Case, P., Saiz-Lopez, A., Jones, L., Barre, J., and Flemming, J.: Asian summer monsoon Chemical and Climate Impact Project (ACCLIP): Highlights of multi-model pre-mission study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2778, https://doi.org/10.5194/egusphere-egu2020-2778, 2020.

EGU2020-6759 | Displays | AS1.17

The ATAL and its aerosol microphysical properties in the Asian Monsoon Anticyclone

Christoph Mahnke, Stephan Borrmann, Ralf Weigel, Francesco Cairo, Armin Afchine, Martina Krämer, Jean-Paul Vernier, and Terry Deshler

During the StratoClim 2017 measurement campaign in Nepal, within the Asian Monsoon Anticyclone (AMA), measurements of the aerosols’ microphysical properties up to UT/LS altitudes were successfully completed with a modified version of the commercially available (Droplet Measurement Technologies Inc.) aerosol spectrometer UHSAS-A. Technical rearrangements of parts of the UHSAS-A were developed and implemented, which improve the instrument’s measuring performance and extend its airborne application range from around 12 km altitude to the extreme ambient conditions in the stratosphere at heights of 20 km. The measurement techniques used for this purpose were characterized by laboratory experiments.

Within the AMA region, extreme values of the particle mixing ratio (PMR) ranging between 6 mg-1 and about 10000 mg-1 were found with the UHSAS-A (particle diameter range: 65 nm to 1000 nm). The median of the PMR for all research flights was about 1300 mg-1 close to the ground. Within tropospheric altitudes, the PMR was highly variable and median values between 70 mg-1 and 400 mg-1 were observed.  At levels of 370 K potential temperature, the median PMR maximally reaches about 700 mg-1 while the 1 Hz resolved measurements show values up to about 10000 mg-1. Between 450 K and 475 K, median PMR between 40 mg-1 and 50 mg-1 were observed. The aerosol size distributions (measured by the UHSAS-A) were extended by an additional diameter size bin obtained from the 4-channel Condensation Particle counting System (COPAS), i.e. for aerosol diameter between 10 nm and 65 nm.

The UHSAS-A measured aerosol particle size distributions were compared with balloon-borne measurements (by T. Deshler et al., Dep. of Atmospheric Science, University of Wyoming, USA) at altitudes of up to 20 km. These show that the size distributions measured during the StratoClim 2017 campaign fit well within the range of the balloon-borne measurements during the Asian Monsoon season over India (Hyderabad) in 2015 and the USA (Laramie) in 2013. Further analyses of measured particle size distributions by means of backscatter ratio show remarkable consistency with CALIOP satellite observations of the ATAL during the StratoClim mission period.

How to cite: Mahnke, C., Borrmann, S., Weigel, R., Cairo, F., Afchine, A., Krämer, M., Vernier, J.-P., and Deshler, T.: The ATAL and its aerosol microphysical properties in the Asian Monsoon Anticyclone, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6759, https://doi.org/10.5194/egusphere-egu2020-6759, 2020.

EGU2020-7585 | Displays | AS1.17 | Highlight

Solid ammonium nitrate aerosols: efficient ice nucleating particles in the upper troposphere during Asian monsoons investigated by aircraft, satellite and cloud-chamber

Michael Höpfner, Jörn Ungermann, Robert Wagner, Reinhold Spang, Martin Riese, Gabriele Stiller, Silvia Bucci, Felix Friedl-Vallon, Sören Johansson, Bernard Legras, Thomas Leisner, Ottmar Möhler, Rolf Müller, Tom Neubert, Johannes Orphal, Peter Preusse, Markus Rex, Harald Saathoff, Fred Stroh, and Ingo Wohltmann

Strong convection within the Asian monsoon system quickly transports polluted air masses from the boundary layer into the upper troposphere where secondary aerosol formation can take place. Here we present remote sensing observations by infrared limb sounding systems providing vertical and horizontal distributions of ammonia (NH3) and solid ammonium nitrate (AN) aerosol particles. Besides the identification of trace gases, characteristic signatures in the mid-infrared spectral region are used to infer information about composition and phase of the aerosol particles. We will show an analysis of AN and NH3 in the Asian monsoon upper troposphere from a combination of two satellite limb sounders, CRISTA on SPAS in August 1997 and MIPAS on Envisat, from 2002-2011.

In addition, limb-imaging measurements obtained with the GLORIA instrument on board the Geophysica high-altitude aircraft provided the opportunity to obtain vertical cross sections along the flight path of AN aerosol mass and NH3 volume mixing ratios during the Asian monsoon field campaign of the StratoClim project in summer 2017. We analysed the airborne dataset with the help of trajectory calculations combined with temporally and locally connected satellite data of nadir-pointing instruments, like IASI, to infer the distribution of NH3 in the lower troposphere, as well as geostationary satellites to deduce the presence of convective influence.

Further, we performed experiments at the AIDA cloud and aerosol chamber laboratory (a) to support the analysis of the aerosol infrared spectral signature in remote sensing, (b) to investigate the conditions leading to the unexpected solid phase of AN particles as well as, (c) to study their potential to act as ice nucleating particles.

How to cite: Höpfner, M., Ungermann, J., Wagner, R., Spang, R., Riese, M., Stiller, G., Bucci, S., Friedl-Vallon, F., Johansson, S., Legras, B., Leisner, T., Möhler, O., Müller, R., Neubert, T., Orphal, J., Preusse, P., Rex, M., Saathoff, H., Stroh, F., and Wohltmann, I.: Solid ammonium nitrate aerosols: efficient ice nucleating particles in the upper troposphere during Asian monsoons investigated by aircraft, satellite and cloud-chamber, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7585, https://doi.org/10.5194/egusphere-egu2020-7585, 2020.

EGU2020-9165 | Displays | AS1.17

Quantification of water vapour transport from the Asian monsoon to the stratosphere

Matthias Nützel, Aurélien Podglajen, Hella Garny, and Felix Ploeger

We use multiannual simulations with the chemistry-transport model CLaMS (Chemical Lagrangian Model of the Stratosphere) to analyze water vapour transport from the Asian monsoon region to the stratosphere. Further, we make comparisons of the transport characteristics from the Asian monsoon to the stratosphere with those of other source regions (e.g. from the tropics). In addition, we characterize the transport efficiency of the monsoon region compared to other source regions and bring our results into context with previous studies, which have focused on water vapour transport from the Asian monsoon to the stratosphere. These analyses are complementing the previously published work by Ploeger et al. (2017), who have analyzed mass transport from the Asian monsoon anticyclone to the stratosphere.

The presented findings have been recently published in Atmospheric Chemistry and Physics (Nützel et al., 2019).

 

References:

Ploeger, F., Konopka, P., Walker, K., and Riese, M.: Quantifying pollution transport from the Asian monsoon anticyclone into the lower stratosphere, Atmos. Chem. Phys., 17, 7055-7066, https://doi.org/10.5194/acp-17-7055-2017, 2017.

Nützel, M., Podglajen, A., Garny, H., and Ploeger, F.: Quantification of water vapour transport from the Asian monsoon to the stratosphere, Atmos. Chem. Phys., 19, 8947–8966, https://doi.org/10.5194/acp-19-8947-2019, 2019.

 

 

 

How to cite: Nützel, M., Podglajen, A., Garny, H., and Ploeger, F.: Quantification of water vapour transport from the Asian monsoon to the stratosphere , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9165, https://doi.org/10.5194/egusphere-egu2020-9165, 2020.

EGU2020-9949 | Displays | AS1.17 | Highlight

Chemical composition of the ATAL aerosol measured by in-situ particle mass spectrometry

Oliver Appel, Andreas Hünig, Antonis Dragoneas, Sergej Molleker, Frank Drewnick, and Stephan Borrmann

The Asian Tropopause Aerosol Layer (ATAL) has been found to be an aerosol layer with exceptionally high particle number concentrations in the UT/LS altitude range. During the StratoClim 2017 field campaign in Nepal we deployed the novel in-situ aerosol mass spectrometer ERICA (ERC Instrument for Chemical composition of Aerosols). It combines the methods of laser ablation mass spectrometry with flash vaporization/electron impact ionisation mass spectrometry in a single instrument to analyse the chemical composition of individual aerosol particles or small particle ensembles in the particle diameter range from 100 nm to 2 µm.

The quantitative analysis shows a strong contribution of ammonium nitrate (AN) to the ATAL aerosol concentration. In this layer, the AN concentrations can be as high as 1.5 µg per standard cubic meter. We present the vertical distribution of the mass concentrations of AN as well as other contributing species like sulphate and organics.

The single particle data from the laser ablation module of ERICA show a distinct particle type with nitrate and sulphate ions without the typical components of primary aerosol (soot, dust, metals) within the ATAL, indicating that a significant fraction of the ATAL aerosol consists of secondary particles formed in the upper troposphere.

How to cite: Appel, O., Hünig, A., Dragoneas, A., Molleker, S., Drewnick, F., and Borrmann, S.: Chemical composition of the ATAL aerosol measured by in-situ particle mass spectrometry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9949, https://doi.org/10.5194/egusphere-egu2020-9949, 2020.

EGU2020-11847 | Displays | AS1.17

The Influences of Climate Forcers and Agricultural Activities on the South Asian Summer Monsoon

Shradda Dhungel, Kostas Tsigaridis, and Susanne Bauer

South Asia is one of the most heavily populated regions in the world with about 1.7 billion inhabitants. The diversity of human activities in the region make delineating the sources and magnitude of regional emissions complex. The major combustion sources in South Asia – predominantly anthropogenic – include wildfires and the burning of agricultural residues, garbage, biofuels, and fossil fuels. But regional aerosol loading is also heavily influenced by natural aerosols, primarily dust transported from as far as the Arabian Peninsula. Past studies have examined how irrigation expansion along with greenhouse gas (GHG) forcing have altered the surface energy budget, thereby affecting the transport of water vapor and altering South Asian Summer Monsoon (SASM) rainfall variability. However, there are still limited modelling studies that consider anthropogenic effects from anthropogenic aerosol loading in combination with irrigation and GHGs and how these factors collectively induce variability in the SASM. Using the NASA GISS-E2.1 model, this study elucidates the role of intensive agricultural activities on SASM, both at the onset of the Green Revolution (i.e., 1960s) and at present, isolating the individual roles of irrigation, anthropogenic aerosols, and GHGs. Specifically, we examine the impacts on SASM by using sensitivity runs to quantify how anthropogenic emissions from agriculture, urbanization as well as long- and short-term forcers have affected SASM from 1960-2014 using prescribed- and coupled-ocean runs. Understanding the roles of each of these influences on SASM can help to develop more effective climate interventions in the region and predict how SASM will influence and interact with the changing regional and global climate.

How to cite: Dhungel, S., Tsigaridis, K., and Bauer, S.: The Influences of Climate Forcers and Agricultural Activities on the South Asian Summer Monsoon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11847, https://doi.org/10.5194/egusphere-egu2020-11847, 2020.

EGU2020-10483 | Displays | AS1.17

Impact of in-cloud OVOC chemistry on tropospheric ozone

Simon Rosanka and Domenico Taraborrelli

In-cloud aqueous-phase chemistry is known to decrease tropospheric ozone (O3) via O3+O2- with the major source of O2- being hydroperoxyl radicals (HO2). Therefore, tropospheric O3 is sensitive to aqueous-phase HOx (HOx=HO2+OH) chemistry. However, most global atmospheric models do not represent this sink reasonably well since they lack explicit representation of in-cloud aqueous-phase chemistry. In this study, a new detailed aqueous-phase mechanism for the oxidation of water soluble oxygenated volatile organic compounds (OVOCs) is developed, suitable for global scale modelling. This improves the representation of aqueous-phase HO2 and thus the removal of tropospheric O3. The mechanism focuses on OVOCs containing up to three-carbon atoms. A detailed box-model analysis under low and high NOx conditions is performed. Afterwards, the developed mechanism is implemented into the global atmospheric model ECHAM/MESSy (EMAC), which is capable to represent the described processes explicitly and integrates the corresponding ODE system with a Rosenbrock solver. EMAC is then used to estimate the global impact of the proposed mechanism with a focus on monsoon systems and biomass burning events. The implemented changes are evaluated using airborne campaign data like OMO for the Asian monsoon. The OVOC oxidation leads to an increase in ozone scavenging and a substantial reduction in tropospheric gas-phase chemical production of ozone. These changes in the free troposphere significantly reduce the modelled tropospheric ozone column, which is known to be overestimated by EMAC and global atmospheric models in general.

How to cite: Rosanka, S. and Taraborrelli, D.: Impact of in-cloud OVOC chemistry on tropospheric ozone, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10483, https://doi.org/10.5194/egusphere-egu2020-10483, 2020.

The Asian monsoon anticyclone is an important transport pathway for water vapor entering the global stratosphere. We use pentad-resolution gridded data from Aura Microwave Limb Sounder (MLS) satellite observations and CLaMS transport model simulations based on two atmospheric reanalyses to examine variations of water vapor in the lower stratosphere (100-68hPa) above the Asian summer monsoon during the warm seasons (May-September) of 2005 through 2017. Model outputs have been post-processed to facilitate direct comparison with MLS retrievals. A localized water vapor maximum is present in the upper troposphere and lower stratosphere above the Asian summer monsoon, with substantial interannual and intraseasonal variability superimposed on the mean seasonal cycle. The CLaMS simulations largely capture both the climatological distribution and variability of lower stratospheric water vapor but with a systematic moist bias, sharper spatial gradients, and larger variance in time relative to MLS. Applying principal component analysis to both vertical and horizontal variability of deseasonalized anomalies within this layer, we identify and describe the three leading modes of variability in lower stratospheric water vapor. The leading mode features regional-scale moistening or drying, with anomalies taking the same sign throughout the layer. Notably, cold point temperature anomalies are in phase with water vapor anomalies in the western part of the domain but out of phase in the eastern part of the domain, where the largest water vapor anomalies are located. The moist phase of this mode is also associated with systematically deeper convection through much of the monsoon domain. The second mode features a vertical dipole, with wet anomalies at 100 hPa (centered over the Persian Gulf but stretching across most of the domain) coupled with dry anomalies at 68 hPa and vice versa. This mode is linked to large anomalies in cold point temperature that span the southern part of the monsoon domain, with the moist phase at 100 hPa associated with warmer cold point temperatures. Warmer temperatures lead to negative anomalies in radiative heating in the lower stratosphere, which may in turn explain the dry anomalies at 68 hPa. The third mode features a horizontal dipole oriented east-to-west, with a deep layer of enhanced water vapor centered over the southeastern Tibetan Plateau coupled with dry anomalies in the west and vice versa. The moist phase of this mode is associated with more extensive cloud cover and deeper convection stretching across China from the eastern Tibetan Plateau. Cold point temperatures are colder and the upper-level monsoon anticyclone stronger in the eastern part of the domain, with opposing anomalies in the west. CLaMS is largely able to reproduce the first and third modes, but fails to capture the second mode and overemphasizes the importance of the third mode. Meanwhile, the monsoon season of 2017 emerges as a special case, with persistent large positive anomalies in lower stratospheric water vapor that are reproduced when CLaMS is driven using ERA-Interim but not when it is driven by MERRA-2. We discuss some possible explanations for these differences.

How to cite: Chen, J., Wright, J., Yan, X., and Konopka, P.: Water vapor variability in the Asian summer monsoon lower stratosphere from satellite observations and transport model simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21617, https://doi.org/10.5194/egusphere-egu2020-21617, 2020.

EGU2020-1389 | Displays | AS1.17

Variability of boreal spring Hadley circulation over the Asian monsoon domain and its relationship with tropical SST

Yaqi Wang, Juan Feng, Jianping Li, Ran An, and Lanning Wang

The variability of boreal spring Hadley circulation (HC) over the Asian monsoon domain over the last four decades is explored. The climatological distribution of the regional HC is symmetric of the equator, with the ascending branch around the equator and sinking branch around the subtropics in each hemisphere. The first dominant mode (EOF1) of the regional HC is equatorial asymmetric, with the main body in the Southern Hemisphere (SH) and the ascending branch to the north of the equator. This mode is mainly characterized by interannual variation and is related to El Niño-Southern Oscillation (ENSO). Significant negative sea surface temperature (SST) anomalies are observed over the tropical Indian Ocean (TIO) along with the development of La Niña events; however, the magnitude of SST anomalies in the southern Indian Ocean is greater than that in the northern counterpart, contributing to EOF1 formation. The spatial distribution of the second dominant mode (EOF2) is with the main body lying in the Northern Hemisphere (NH) and the ascending branch located to the south of the equator. The temporal variation of this mode is connected to the warming of the TIO. The warming rate of the southern TIO SST is faster than that in the northern counterpart, resulting in the southward migration of the rising branch. The above result indicates the critical role of the meridional distribution of SST on the variability of the regional HC.

How to cite: Wang, Y., Feng, J., Li, J., An, R., and Wang, L.: Variability of boreal spring Hadley circulation over the Asian monsoon domain and its relationship with tropical SST, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1389, https://doi.org/10.5194/egusphere-egu2020-1389, 2020.

EGU2020-3958 | Displays | AS1.17

Volcanic influence on STRATOCLIM aircraft observations 2017 in the Asian Monsoon, studies with the transient CCM EMAC

Christoph Brühl, Hans Schlager, Ralf Weigel, Oliver Appel, Stephan Borrmann, Jos Lelieveld, and Jennifer Schallock

Results from a transient 28 year simulation with the chemistry climate model EMAC with interactive modal aerosol scheme nudged to observed tropospheric meteorology (ERA-Interim) which includes about 500 volcanic SO2 injections are compared with in situ aircraft observations in the UT/LS in the Asian Monsoon anticyclone. Enhanced SO2 observed by STRATOMAS and enhanced sulfate aerosol observed by ERICA in the LS point to impact of several explosive eruptions of the Indonesian volcano Sinabung during summer 2017 seen by the OSIRIS satellite instrument. This is supported by freshly nucleated particles observed by COPAS in the UTLS. We present several sensitivity studies with EMAC with different assumptions on the injection patterns in comparison to the observations in July/August 2017.  
The monsoon dynamics distributes the volcanic material together with Asian pollution into the global lower stratosphere.

How to cite: Brühl, C., Schlager, H., Weigel, R., Appel, O., Borrmann, S., Lelieveld, J., and Schallock, J.: Volcanic influence on STRATOCLIM aircraft observations 2017 in the Asian Monsoon, studies with the transient CCM EMAC, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3958, https://doi.org/10.5194/egusphere-egu2020-3958, 2020.

We investigated the physical mechanism for late Indian Summer Monsoon onset over Kerala
(MOK). 14 early and 9 late onset years are selected based on the criteria when the onset is 5 days or
more prior and after normal onset date (i.e 1 st June according to India Meteorological Department)
respectively. Then, we perform composite analyses of mean May monthly and daily evolution during
early and late onset years to examine the differences in monsoon circulation features prior to the MOK.
We find that advection of Surface Air Temperature (SAT) from the northern to the southern China and
the eastern Tibetan Plateau (TP) plays an important role to modulate the MOK processes. In the late
onset years, more low-level jet (LLJ) from the Bay of Bengal (BOB) divert towards the east Asia before
the onset, which is due to an extension of the low sea level pressure and high SAT over the east Asia
(eastern TP, east-central China). This strengthens the low-level convergence and upper level divergence
over the eastern TP and southern China. As a result, a significant amount of moisture from the BOB
is transported towards the eastern TP and southern China. Thereby, a comparatively weaker LLJ and
deficit low-level moisture supply over the eastern BOB maintain the key roles in modulating the MOK
processes.

How to cite: Choudhury, D., Nath, D., and Chen, W.: The role of surface air temperature over the east Asia on the early and late Indian Summer Monsoon Onset over Kerala, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3820, https://doi.org/10.5194/egusphere-egu2020-3820, 2020.

EGU2020-6459 | Displays | AS1.17

Interaction between the Black Carbon Aerosol Warming Effect and East Asian Monsoon

Bingliang Zhuang, Tijian Wang, Shu Li, Min Xie, Mengmeng Li, Huimin Chen, Wen Wei, and Huijuan Lin

Black carbon aerosol (BC) has a significant influence on regional climate changes due to its warming effect. Such changes will feedback to BC loadings. Here, the interactions between the BC warming effect and East Asian monsoon (EAM) in both winter (EAWM) and summer (EASM) are investigated using a regional climate model RegCM4, which essentially captures the EAM features and the BC variations in China. The seasonal mean BC optical depth is 0.021 over East Asia during winter, which is 10.5% higher than that during summer. Nevertheless, the BCs direct radiative forcing is 32% stronger during summer (+1.85 W/m2). The BC direct effect would induce lower air to warm by 0.11-0.12 K, which causes an meridional circulation anomaly associated with a cyclone at 20-30 oN and southerly anomalies at 850 hPa over East Asia. Consequently, the EAM circulation is weakened during winter but enhanced during summer. Precipitation is likely increased, especially in south China during summer (by 3.73%). Compared to BC changes due to EAM interannual variations, BC changes due to its warming effect are as important, but weaker. BC surface concentrations are decreased by 1~3% during both winter and summer, by 1~3%, while the columnar BC is increased in south China during winter. During the strongest monsoon years, the BC loadings are higher at lower latitudes than those during the weakest years, resulting in more southerly meridional circulation anomalies and BC feedbacks during both winter and summer. However, the interactions between the BC warming effect and EAWM/EASM are more intense during the weakest monsoon years.

How to cite: Zhuang, B., Wang, T., Li, S., Xie, M., Li, M., Chen, H., Wei, W., and Lin, H.: Interaction between the Black Carbon Aerosol Warming Effect and East Asian Monsoon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6459, https://doi.org/10.5194/egusphere-egu2020-6459, 2020.

EGU2020-8599 | Displays | AS1.17

Characteristics of Hydrogen and Oxygen Isotopes and Water Vapor Sources in Atmospheric Precipitation in Subtropical Monsoon Islands

Jianhua Lai, Changyuan Tang, Yingjie Cao, and Guangli Liu

EGU2020-10709 | Displays | AS1.17

Deep convective influence on the UTLS composition in the Asian Monsoon Anticyclone region: 2017 StratoClim campaign results

Silvia Bucci, Bernard Legras, Pasquale Sellitto, Francesco D'Amato, Silvia Viciani, Alessio Montori, Alessio Chiarugi, Fabrizio Ravegnani, Alexey Ulanovsky, Francesco Cairo, and Fred Stroh

The StratoClim stratospheric aircraft campaign, taking place in summer over the Nepalese region, provided a wide dataset of observations of air composition inside the Asian Monsoon Anticyclone (AMA). To improve the understanding of the role of penetrating overshoot in the AMA region, we exploit the TRACZILLA Lagrangian simulations, computed on meteorological fields from ECMWF (ERA-Interim and ERA5) at 3h and 1h resolution and using both kinematic and diabatic vertical velocity approaches. The synergy with high-resolution observations of convective cloud top from the MSG1 and Himawari geostationary satellites is used to individuate the convective sources.

To evaluate the capability of the trajectory system to reproduce the transport in the UTLS we compare the simulations with the observed trace gases concentration. The ERA5 simulations appear to provide a higher consistency with observed data than ERA-Interim and show a better agreement between the diabatic and kinematic results. The best performance is given by the ERA5 with diabatic transport and, adopting this setting, we analyze the transport condition during the 8 flights of the campaign.

The aircraft sampled different convective plumes, often carrying pollutant compounds up to the UTLS level. The highest observed concentration of trace gases had been linked to fresh convective air (younger than a few days) coming from China, Pakistan and the North Indian region.

A vertical stratification is observed in the age of air: up to 15 km, the age of air is less than 3 days and these fresh air masses make up nearly the entire totality of the air composition. Above, a transition layer is identified between 15 km and 17 km (close to the tropopause), where the convective influence is still dominant and the ages range from one week to two. Finally, above this layer, the convective influence rapidly decreases toward zero and the mean air age increase to 20 days and more.

This study quantifies the contribution of direct injection of deep convection on the UTLS composition based on the aircraft measurements. Preliminary results of the upscale analysis based on the trajectories-satellites system will also be presented.

How to cite: Bucci, S., Legras, B., Sellitto, P., D'Amato, F., Viciani, S., Montori, A., Chiarugi, A., Ravegnani, F., Ulanovsky, A., Cairo, F., and Stroh, F.: Deep convective influence on the UTLS composition in the Asian Monsoon Anticyclone region: 2017 StratoClim campaign results, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10709, https://doi.org/10.5194/egusphere-egu2020-10709, 2020.

EGU2020-11055 | Displays | AS1.17

Radiative impacts of convective anvil outflow in the Asian monsoon region

Sylvia Sullivan, Aiko Voigt, Martina Krämer, Annette Miltenberger, Sergey Khaykin, and Christian Rolf

We investigate the radiative impacts of convectively detrained and in-situ formed ice crystals at uppermost altitudes with high-resolution ICON model runs in the Asian monsoon region. Radiatively, this area should be characterized by persistent longwave warming from thin and ubiquitous anvils and intermittent shortwave cooling from deep but infrequent convective systems. But how do different degrees of sophistication in the ice microphysics schemes modulate this picture? Three days coinciding with the StratoClim field campaign are simulated (6-9 August 2017), using two-moment microphysics, and in-situ ice water content (IWC) values and specific humidity profiles are used for validation. We calculate the shortwave and longwave radiative fluxes associated with IWC between 14 and 17 km over different timescales and examine the role of ambient dryness in anvil base radiative heating. We compare our results with the cloud-resolving Meso-NH simulation of Lee et al. ACP 2019 in which moist and ice layers were identified and tracked through the uppermost troposphere.

How to cite: Sullivan, S., Voigt, A., Krämer, M., Miltenberger, A., Khaykin, S., and Rolf, C.: Radiative impacts of convective anvil outflow in the Asian monsoon region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11055, https://doi.org/10.5194/egusphere-egu2020-11055, 2020.

EGU2020-10170 | Displays | AS1.17

Confinement of air in the Asian monsoon anticyclone and pathways of convective air to the stratosphere during summer season

Bernard Legras, Silvia Bucci, Sivan Chandra, and Ajil Kottayil

We study the confinement of the air inside the Asian monsoon anticyclone during summer using both kinematic and diabatic Lagrangian trajectories with ERA5 and ERA-Interim reanalysis, and observed clouds. The improved consistency of ERA5 is demonstrated. It is shown that the escape time from the anticyclone estimated to be 13 days is of the same order as the circulation time which implies weak confinement. Parcels found inside the anticyclone have been mostly detrained by convection above θ =364 K, by about 2.6%  of the high clouds over Asia, with a prevalence of continental sources which are located beneath. The Tibetan plateau is found to be the most efficient provider with 10% of its high clouds but this is entirely due to the higher level of cloud tops in this region, and not to any preferred path above.  Actually,  most parcels escape the plateau to rise. The mean trapping is shown to be described by a 1D model that combines a simple mean ascent and a constant erosion loss, without any need of a “chimney effect”. The vertical dilution is exponential with a e-folding scale of 15 K in potential temperature from 370 K onward. The mean age of parcels with respect to convection exhibits a minimum at the centre of the Asian monsoon anticyclone due to the permanent renewal by fresh convective air and largest values on the periphery as air spirals out.

The variability of the the confinement is strongly linked with the oscillations of the anticyclone between its Tibetan mode and its Iranian mode, and to break and active periods of monsoon rain. We show that this variability modulates also the moisture in the lower stratosphere with wet events following active convection and dry events following the breaks.

How to cite: Legras, B., Bucci, S., Chandra, S., and Kottayil, A.: Confinement of air in the Asian monsoon anticyclone and pathways of convective air to the stratosphere during summer season, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10170, https://doi.org/10.5194/egusphere-egu2020-10170, 2020.

The relation between the seesaw mode of the Interface between the Indian summer monsoon and East Asian summer monsoon (IIE) and the South China Sea summer monsoon trough (SCSSMT) and the Indian summer monsoon trough (ISMT) is investigated using two atmospheric reanalyses together with outgoing longwave radiation, sea surface temperature (SST), and gridded precipitation datasets. Canonical correlation analysis combined with empirical orthogonal functions, correlation, and composite analysis are employed. Results indicate that a stronger ISMT and SCSSMT resulting from colder SST over the tropical Indian Ocean and tropical east-central Pacific cause the IIE to deviate from its normal position in an anticlockwise direction, with a node at around 22°N. This leads to heavier than normal summer rainfall over the north-central Indian subcontinent and South China Sea, but weaker than normal from the low and middle reaches of the Yangtze River and South Korea to central Japan. A weaker ISMT and SCSSMT resulting from warmer SST over the tropical Indian Ocean and tropical east-central Pacific causes the IIE to deviate from its normal position in a clockwise direction, and the anomalous summer rainfall pattern is the opposite of that for the stronger troughs. Further analysis indicates that the SCSSMT plays a crucial role in the evolution of the IIE seesaw mode. The latitudinal difference between the IMST and SCSSMT may be one of the most important reasons for the formation of the IIE seesaw mode.

How to cite: Yang, R. W. and Wang, J.: Interannual variability of the seesaw mode of the interface between the Indian and East Asian summer monsoons, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21020, https://doi.org/10.5194/egusphere-egu2020-21020, 2020.

EGU2020-6606 | Displays | AS1.17

Pollution trace gas distributions in the Asian monsoon UTLS derived from measurements of the airborne imaging limb sounder GLORIA during the StratoClim campaign

Sören Johansson, Michael Höpfner, Felix Friedl-Vallon, Jörn Ungermann, Oliver Kirner, Silvia Bucci, Bernard Legras, Ingo Wohltmann, Gerald Wetzel, Norbert Glatthor, and Erik Kretschmer

We will present trace gas measurements obtained by the airborne imaging limb sounder GLORIA (Gimballed Limb Observer for Radiance Imaging of the Atmosphere) instrument that has been operated on the Geophysica research aircraft in area of the Indian subcontinent with basis in Kathmandu, Nepal during the StratoClim campaign in July/August 2017.
We will show retrievals of two-dimensional trace-gas distributions derived from GLORIA observations in the UTLS (Upper Troposphere Lower Stratosphere) region during the Asian monsoon. Targeted gases are, amongst others, O3, HNO3, PAN, C2H2, and HCOOH. We will present an analysis of retrieval performance including diagnostics of spatial resolution and an estimated error budget.
In our contribution, we compare these GLORIA measurements with results of the atmospheric models EMAC (ECHAM/MESSy Atmospheric Chemistry) and CAMS (Copernicus Atmosphere Monitoring Service) reanalysis and discuss the influence of non-methane volatile organic compound emissions by sensitivity simulations with the EMAC model. Using trajectories from the models ATLAS and TRACZILLA, measured pollution trace gas plumes are connected to possible sources of origin. Due to the high convective activity in the region of the Asian monsoon, both trajectory sets consider vertical transport by convection, however in a different manner.
We show that there are very delicate structures of pollutant trace gases in the Asian monsoon UTLS, and that atmospheric models have difficulties in reproducing these structures, which is likely to be caused by insufficient vertical transport from convection in meteorological fields or by missing sources in the emission inventories used by the models.

How to cite: Johansson, S., Höpfner, M., Friedl-Vallon, F., Ungermann, J., Kirner, O., Bucci, S., Legras, B., Wohltmann, I., Wetzel, G., Glatthor, N., and Kretschmer, E.: Pollution trace gas distributions in the Asian monsoon UTLS derived from measurements of the airborne imaging limb sounder GLORIA during the StratoClim campaign, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6606, https://doi.org/10.5194/egusphere-egu2020-6606, 2020.

While the monsoon onset is recognized as a rapid, substantial, and sustained increase in rainfall over large parts of south Asia, the withdrawal marks the return to dry conditions. Normally, the south Asian summer monsoon onset occurs around 1st June over extreme south of peninsular India, which gradually advances to extreme northwest of India by around 15th July. The withdrawal starts from northwest India from around 1st September and from extreme south peninsular India by around 30th September. The determinations of the onset and withdrawal dates of monsoon have great economic significance for this region as they influence many agriculture and water resource management decisions in one of the most highly populated regions of the world. Several studies involving global model simulations have shown that changing aerosol emissions could result in significant changes in the seasonal mean precipitation distribution over India. A few studies also show that presence of absorbing aerosols in the foothills of Himalayas and over the Tibetan plateau could increase the moisture convergence over India thereby causing an advancement and intensification of the monsoon precipitation. However, most of the previous studies, which investigated the impact of anthropogenic emissions on the monsoon, are limited to understanding the impact of various emission changes on the seasonal mean monsoon characteristics. In the present study, we try to understand the sensitivity of the onset and withdrawal period of the south Asian summer monsoon system to changes in anthropogenic emissions using a climate model (CESM1.2). We diagnose the onset and withdrawal of the south Asian monsoon by analyzing the variability in vertically integrated moisture transport (VIMT) over the south Asian region and following the definition of hydrologic onset and withdrawal index (HOWI) defined by Fasullo et al. (2002). We examined the effect of changing emissions anthropogenic aerosol, greenhouse gases and both on the onset and withdrawal of the south Asian summer monsoon system. Our preliminary results suggest that increases in the emissions of aerosols and greenhouse gases from anthropogenic sources from pre-industrial to present day could possibly result in significant delay in the onset and advancement in withdrawal of the south Asian summer monsoon system thereby shortening the length of the monsoon season. More results with greater detail will be presented.

How to cite: Mishra, S., Ganguly, D., and Sharma, P.: Investigating the sensitivity of the onset and withdrawal of the south Asian summer monsoon system to changes in anthropogenic emissions using a climate model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14786, https://doi.org/10.5194/egusphere-egu2020-14786, 2020.

EGU2020-19263 | Displays | AS1.17

Results from a comparison of HCN measurements and Lagrangian backtrajectory analyses in the Asian Summer Monsoon Anticyclone

Yun Li, Bärbel Vogel, Felix Plöger, Silvia Bucci, Bernard Legras, Silvia Viciani, Francesco D'Amato, and Fred Stroh

The StratoClim aircraft field campaign took place from Kathmandu, Nepal, in summer 2017 in
order to study the atmospheric composition, chemistry, and dynamics in the Asian Summer
Monsoon Anticyclone (ASMA) which is known to transport surface emissions to the mid-latitude
lower stratosphere and the stratosphere worldwide. Hydrogen cyanide (HCN) which is primarily
emitted from biomass burning and has a UTLS lifetime on the order of 1-2 years is a good tracer for
biomass burning import into the lower and free stratosphere.
HCN in the ASM Upper Troposphere and Lower Stratosphere (UTLS) was measured in-situ
employing the Chemical-Ionization Time-of-Flight Mass Spectrometer FUNMASS on board the
high-altitude research aircraft M55-Geophysica. The observed HCN mixing ratios in and above the
ASMA exhibit interesting vertical and horizontal signatures around the tropopause as well as in the
LS probably resulting from convective activity or air mass origin (AMO). We here compare
measured HCN to Lagrangian simulations by the ClaMS and TRACZILLA models which employ
two different approaches to represent higher-reaching convective events. The simulations succeed to
track some of the observed HCN features back to convective activity or AMO. The quality of the
reproduction and further outcomes on the atmospheric relevance will be discussed in the
presentation.

How to cite: Li, Y., Vogel, B., Plöger, F., Bucci, S., Legras, B., Viciani, S., D'Amato, F., and Stroh, F.: Results from a comparison of HCN measurements and Lagrangian backtrajectory analyses in the Asian Summer Monsoon Anticyclone, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19263, https://doi.org/10.5194/egusphere-egu2020-19263, 2020.

AS1.18 – Stratospheric Dynamics

EGU2020-866 | Displays | AS1.18

Variability of the North Atlantic response to sudden stratospheric warming events in a simplified atmospheric model

Hilla Afargan-Gerstman, Bernat Jiménez-Esteve, and Daniela I.V. Domeisen

Sudden stratospheric warming (SSW) events are often followed by a surface impact, most commonly by a negative phase of the North Atlantic Oscillation (NAO). Recent work has emphasized the large variability among the tropospheric response after these events, showing that only about two thirds of the SSWs are dominated by this canonical negative NAO response. In this study, we use an idealized atmospheric model forced with seasonally varying sea surface temperatures to examine the influence of the pre-existing tropospheric conditions on the North Atlantic response to stratospheric forcing. In the model, the negative phase of the NAO is found to be the most common response to SSWs, occurring after ~85% of the SSWs (under climatological SST forcing).  For the remaining ~15% of the SSW events, the response is associated with a positive phase of the NAO. In the search for the origin of the different tropospheric response in the North Atlantic, the role of synoptic wave propagation from the eastern Pacific on the downward response to SSWs is investigated. By systematically varying the strength of the North Pacific circulation, we are able to assess the sensitivity of the downward response to tropospheric variability in the Pacific, and shed light on its contribution to the persistence of the downward impact of SSWs in the idealized model.

How to cite: Afargan-Gerstman, H., Jiménez-Esteve, B., and Domeisen, D. I. V.: Variability of the North Atlantic response to sudden stratospheric warming events in a simplified atmospheric model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-866, https://doi.org/10.5194/egusphere-egu2020-866, 2020.

EGU2020-1925 | Displays | AS1.18

Polar vortex shape-transition during SSW depending on preceding NAO conditions

Hyesun Choi, Wookap Choi, Seong-Joong Kim, and Baek-Min Kim

Sudden stratospheric warming (SSW) characterized by a rapid increase in polar stratospheric temperature and an abrupt decrease in circumpolar westerly wind is accompanied by deformation in the shape of the polar vortex. The SSW type can be distinguished depending on the vortex shape. SSW events preceded by a displacement in polar vortex center are characterized by whether they retain their displaced form (displacement-displacement type) or split into two vortices (displacement-split type) after onset. Here, we show that existence of a polar vortex shape-transition during the course of the SSW life cycle can be attributable to the condition of North Atlantic Oscillation (NAO) preceding before onset: Positive NAO favors SSW of displacement-displacement type with no transition while negative NAO favors the displacement-split type. We show that, in positive NAO precondition, vertical flux of wave activity immediately before onset is mostly contributed only by wavenumber 1 component, which contrasts with the relatively stronger contribution of wavenumber 2 in negative NAO pre-condition. This study provides probability that the North Atlantic anomaly can induce a favorable condition for the development of small scale waves and lead to the occurrence of SSW type-transition. Whole Atmosphere Community Climate Model (WACCM) simulation results reproduce well the observational findings. Therefore, NAO can be regarded as a useful predictor for distinguishing the type of forthcoming SSW events.

 

How to cite: Choi, H., Choi, W., Kim, S.-J., and Kim, B.-M.: Polar vortex shape-transition during SSW depending on preceding NAO conditions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1925, https://doi.org/10.5194/egusphere-egu2020-1925, 2020.

Sudden Stratospheric Warming events (SSWs) are rapid disruptions of the Northern Hemisphere (NH) winter stratospheric polar vortex and represent the largest source of inter-annual variability in the NH winter stratosphere. They have been linked to winter surface climate anomalies such as cold snaps over North America and Eurasia. Representing these events accurately in large scale GCMs as well as developing a greater understanding of them is key to improving predictability of winter surface climate. A key component of a GCM is its representation of atmospheric chemistry. Chemical distributions are either prescribed or calculated interactively by coupling an atmospheric chemistry model to radiation and dynamical components, thus capturing any chemical dynamical feedback mechanisms but incurring significant running cost.

This work evaluates the impact of interactive chemistry when modelling SSW events and explores the feedback mechanisms between chemical distributions and stratospheric dynamical variability. Pre-industrial control runs from the MetOffice HadGEMGC3.1 model which prescribes chemical fields and UKESM1 which calculates trace gas concentration interactively are utilised. Over the whole season - The Earth System Model appears to suppress warmings while the model with prescribed physics overestimates their occurrence compared to reanalysis. The differing representation of the equatorial stratosphere appears to be partially responsible for this difference. Additionally we find that middle stratosphere equatorial ozone concentration in late NH summer is closely associated with SSW probability in the ensuing winter in UKESM1. Anomalously low ozone is generally associated with an elevated SSW rate. This implies a chemical-dynamical coupling between the equator and the vortex in this model which preliminary results suggest could be driven by chemical feedbacks influencing the state of the early winter Quasi Biennial Oscillation (QBO) and Semi-Annual Oscillation (SAO) in zonal winds which can alter the distribution of planetary wave propagation and breaking (the primary cause of SSWs). Further work will assess whether this phenomenon is observed in other GCMs and further explore the physical mechanisms responsible.

How to cite: Dimdore-Miles, O., Gray, L., and Osprey, S.: Dynamical-Chemical Feedbacks in General Circulation Models and Their Influence on Sudden Stratospheric Warming Events, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3471, https://doi.org/10.5194/egusphere-egu2020-3471, 2020.

Sudden stratospheric warmings (SSWs) are impressive events that occur in the winter hemisphere's polar stratosphere and are capable of producing temperature anomalies upwards of +50 degrees within a matter of days. While much work has been dedicated towards determining how SSWs occur and their ability to interact with the underlying troposphere, one under-explored aspect of SSWs is the role of radiation. Using a radiative transfer model and an energy budget analysis for distinct layers of the stratosphere, this work accounts for the radiative contribution to the removal of the anomalous energy associated with SSWs. In total, 19 events are investigated over the 1979-2016 period. This work reveals that in the absence of dynamical heating following major SSWs, longwave radiative cooling dominates and often results in a strong negative temperature anomaly. The stratospheric temperature change driven by the radiative cooling is characterized by an exponential decay of the temperature anomaly with an increasing e-folding time of 6.3 ± 2.6 to 21.6 ± 8.3 days from the upper to lower stratosphere. This work also demonstrates a negligible impact that water vapour and ozone have on the longwave and shortwave radiative heating rates during SSWs when the concentrations of these gases are perturbed from their climatological state.

How to cite: Bloxam, K.: Sudden Stratospheric Warmings - The Role of Radiation Revealed Through an Energy Budget Analysis, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5895, https://doi.org/10.5194/egusphere-egu2020-5895, 2020.

EGU2020-8339 | Displays | AS1.18

The downward propagation of split- and displacement-type SSWs in an idealised model

Ian White, Chaim Garfinkel, Edwin Gerber, and Martin Jucker

Sudden stratospheric warmings (SSWs) have a significant downward influence on the tropospheric circulation below, although the mechanisms governing this downward impact are not well understood. It is also not known if the type of SSW event – be them splits or displacements – play a role in determining the magnitude of the tropospheric response. We here examine the impacts of split- and displacement-type SSWs on the troposphere.

To do this, we use the recently developed model of an idealised moist atmosphere to impose zonally-asymmetric warming perturbations to the extratropical stratosphere, extending the work of a recent study by the authors in which a zonally-symmetric heating perturbation was imposed. This model of ‘intermediate complexity’ is particularly suited to this study as it incorporates the radiation scheme that is utilised by operational forecast systems, including both the ECMWF and NCEP. The radiation scheme also allows us to force the model with a realistic ozone profile, and thus to simulate realistic radiative timescales in the stratosphere. From a control run with a realistic climatology, we perform an ensemble of spin-off runs every January 1st with imposed high-latitude stratospheric heating perturbations of varying degrees of magnitude. The heating perturbation is switched on for a limited period of time to mimic the sudden nature of a SSW event and the troposphere is allowed to evolve freely. We compare the evolution of the tropospheric response to the forced split and displacement-type SSWs with free-running SSWs of the same type in the control run.

By modifying only the temperature tendency equation as opposed to the momentum budget, our experiments allow us to isolate the tropospheric response associated with changes in the polar-vortex strength (e.g., a direct or indirect modulation of planetary waves and synoptic waves), rather than due to any planetary-wave momentum torques that initially drive the SSW. Nevertheless, the imposition of wave-1 and wave-2 heating perturbations provide a more realistic post-onset SSW state than that which occurs in response to zonal-mean heating perturbations as performed in our previous study.

How to cite: White, I., Garfinkel, C., Gerber, E., and Jucker, M.: The downward propagation of split- and displacement-type SSWs in an idealised model , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8339, https://doi.org/10.5194/egusphere-egu2020-8339, 2020.

This study uses the stratosphere-resolved Whole Atmosphere Community Climate Model to demonstrate the “independent” and “dependent” topographic forcing from the topography of East Asia (EA) and North American (NA), and their “joint” forcing in the northern winter stratosphere. The mutual interference between the EA and NA forcing is also demonstrated. Specifically, without EA, an independent NA can also, like EA, induce a severe polar warming and weakening of the stratospheric polar vortex. While EA favors a displacement of the polar vortex toward Eurasia, NA favors a displacement toward the North America–Atlantic region. However, the independent-EA-forced weakening effect on the polar vortex can be largely decreased and changes to a location displacement when NA exists, and the interference the other way around is even more critical, being able to completely offset the independent-NA-forced effect, because EA can substantively obstruct NA’s effect on the tropospheric wave pattern over the Eurasia–Pacific region. The much stronger/weaker interference of EA/NA is associated with its stronger/weaker downstream weakening effect on the zonal flow that impinges on NA/EA. The mutual interference always tends to further destruct the upward wave fluxes over the eastern North Pacific and enhance the downward wave fluxes over NA. The overall changes in upward wave fluxes, as well as that in the Rossby stationary wavenumber responsible for the stratospheric changes, are related to changes in the zonal-mean flow pattern. The joint effects of EA and NA, rather than being a linear superimposition of their independent effects, are largely dominated by the effects of EA.

How to cite: Ren, R., Xia, X., and Rao, J.: Topographic forcing from East Asia and North America in the northern winter stratosphere and their mutual interference , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1392, https://doi.org/10.5194/egusphere-egu2020-1392, 2020.

EGU2020-13680 | Displays | AS1.18

Stratospheric influence on idealised baroclinic life cycles

Philip Rupp and Thomas Birner

The importance of understanding the dynamical coupling of troposphere and stratosphere to make accurate weather and climate predictions is well-known. Over the past years and decades various signatures of such a
coupling have been discovered. A very robust result, for example, seems to be an equatorward shift of the tropospheric eddy driven jet following sudden stratospheric warming events, where the westerly winds of the stratospheric polar vortex weaken or even reverse. However, many aspects of this fundamental coupling are still not fully understood and research on how the state of the stratosphere can influence the tropospheric circulation and what dynamical processes are involved is still ongoing.


An important such process arises due to the interaction of a sharp, localised maximum in potential vorticity gradient near the tropopause with baroclinic eddies in the troposphere. Here, we analyse the sensitivity of baroclinic wave development and evolution to changes of various basic state characteristics, by performing a series of idealised baroclinic eddy life cycle experiments. Special attention is paid to sensitivities associated with the dynamical state of the stratosphere. We find that the final (steady) state of the life cycle simulations corresponds to an equatorward shift of the tropospheric jet in cases where the initial conditions do not include a stratospheric polar vortex (such as following sudden warming events) compared to those that do. These results further support the idea that the stratospheric state can strongly influence tropospheric dynamics and, in particular, highlight the robustness of the jet shift response following sudden warmings, that can be seen in a range of observations and numerical model experiments.

How to cite: Rupp, P. and Birner, T.: Stratospheric influence on idealised baroclinic life cycles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13680, https://doi.org/10.5194/egusphere-egu2020-13680, 2020.

We present evidence that stratospheric sudden warmings (SSWs) are, on average, a threshold behavior of finite-amplitude Rossby waves arising from wave-mean flow interaction. Competition between an increasing wave activity and a decreasing zonal-mean zonal wind sets a limit to the upward wave activity flux of a stationary Rossby wave.  A rapid, spontaneous vortex breakdown occurs once the upwelling wave activity flux reaches the limit, or equivalently, once the zonal-mean zonal wind drops below a certain fraction of the wave-free, reference-state wind obtained from the zonalized quasigeostrophic potential vorticity.  This threshold faction is 0.5 in theory and about 0.3 in reanalyses.  We use the ratio of the zonal-mean zonal wind to the reference-state wind as a local, instantaneous measure of the proximity to vortex breakdown, i.e. preconditioning.  The ratio generally stays above the threshold during strong-vortex winters until a pronounced final warming, whereas during weak-vortex winters it approaches the threshold early in the season, culminating in a precipitous drop in midwinter as SSWs form. The essence of the threshold behavior is captured by a semiempirical 1D model of SSWs, analogous to the “traffic jam” model of Nakamura and Huang for atmospheric blocking. This model predicts salient features of SSWs including rapid vortex breakdown and downward migration of the wave activity/zonal wind anomalies, with analytical expressions for the respective timescales. Model’s response to a variety of transient wave forcing and damping is discussed.

 

 

 

 

How to cite: Nakamura, N.: Stratospheric sudden warming as a threshold behavior of Rossby waves, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3165, https://doi.org/10.5194/egusphere-egu2020-3165, 2020.

EGU2020-5635 | Displays | AS1.18

An evaluation of tropical waves and wave forcing of the QBO in the QBOi models

Laura Holt and Francois Lott and the QBOi Contributors

We analyze the stratospheric waves in models participating in phase 1 of the Stratosphere–troposphere Processes And their Role in Climate (SPARC) Quasi-Biennial Oscillation initiative (QBOi). All models have robust Kelvin and mixed Rossby-gravity wave modes in winds and temperatures at and represent them better than most of the Coupled Model Intercomparison Project Phase 5 (CMIP5) models. There is still some spread among the models, especially concerning the mixed Rossby-gravity waves. We attribute the variability in equatorial waves among the QBOi models in part to the varying horizontal and vertical resolutions, to systematic biases in zonal winds, and to the considerable variability in convectively coupled waves in the troposphere among the models: only roughly half of the QBOi models have realistic convectively coupled Kelvin waves and only a few models have convectively coupled mixed Rossby-gravity waves. The models with stronger convectively coupled waves produce larger zonal mean forcing due to resolved waves in the QBO region. Finally we evaluate the Eliassen-Palm (EP) flux and EP flux divergence of the resolved waves in the QBOi models. We find that there is a large spread in the forcing from resolved waves in the QBO region, and the resolved wave forcing has a robust correlation with model vertical resolution

How to cite: Holt, L. and Lott, F. and the QBOi Contributors: An evaluation of tropical waves and wave forcing of the QBO in the QBOi models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5635, https://doi.org/10.5194/egusphere-egu2020-5635, 2020.

EGU2020-14259 | Displays | AS1.18

Impact of the Quasi-Biennial Oscillation on the boreal winter tropospheric circulation in CMIP5/6 models

Jian Rao, Chaim Garfinkel, Ian White, and Chen Schwartz

Using 17 CMIP5/6 models with a spontaneously-generated quasi-biennial oscillation (QBO)-like phenomenon, this study explores and evaluates three dynamical pathways for impacts of the QBO on the troposphere: (i) the Holtan-Tan (HT) effect on the stratospheric polar vortex and the northern annular mode (NAM), (ii) the subtropical zonal wind downward arching over the Pacific, and (iii) changes in local convection over the Maritime Continent and Indo-Pacific Ocean. More than half of the models can reproduce at least one of the three pathways, but few models can reproduce all of the three routes. Firstly, most models are able to simulate a weakened polar vortex during easterly QBO (EQBO) winters, in agreement with the observed HT effect. However, the weakened polar vortex response during EQBO winters is underestimated or not present at all in other models, and hence the QBO → vortex → tropospheric NAM/AO chain is not simulated. For the second pathway associated with the downward arching of the QBO winds, seven models incorrectly or poorly simulate the extratropical easterly anomaly center over 20–40°N in the Pacific sector during EQBO, and hence the negative relative vorticity anomalies poleward of the easterly center is not resolved in those models, leading to an underestimated or incorrectly modelled height response over North Pacific. However the other ten do capture this effect. The third pathway is only observed in the Indo-Pacific Ocean, where the strong climatological deep convection and the warm pool are situated. Nine models can simulate the convection anomalies associated with the QBO over the Maritime Continent, which is likely caused by the near-tropopause low buoyancy frequency anomalies. No robust relationship between the QBO and El Niño–Southern Oscillation (ENSO) events can be established using the ERA-Interim reanalysis, and nine models consistently confirm little modulation of the ocean basin-wide Walker circulation and ENSO events by the QBO.

How to cite: Rao, J., Garfinkel, C., White, I., and Schwartz, C.: Impact of the Quasi-Biennial Oscillation on the boreal winter tropospheric circulation in CMIP5/6 models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14259, https://doi.org/10.5194/egusphere-egu2020-14259, 2020.

EGU2020-12880 | Displays | AS1.18

Artificial acceleration of the Brewer-Dobson circulation due to stratospheric cooling

Roland Eichinger and Petr Sacha

There is robust observational evidence that the troposphere is warming and the stratosphere is cooling in response to the radiative forcing of anthropogenic greenhouse gas (GHG) emissions. Temperature changes directly influence the vertical structure of the atmopshere. Numerous studies have analysed the thermal expansion of the troposphere, in particular the tropopause rise and its interaction with the Brewer-Dobson circulation (BDC). Stratospheric cooling, however, reduces the upward shift of pressure levels with increasing altitude so that it reverses sign at some height, leading to a downward shift of the middle to upper stratosphere. This "stratospheric shrinkage“ effect is a strong and robust feature of climate change and it is well documented through observations. Still, literature on this effect is relatively sparse and its impact on stratospheric dynamics is generally neglected.

In this study, we report and quantify the uncertainty in residual upward velocity (w*) trends that arises from the implicit neglection of stratospheric shrinkage in the data model request for the Chemistry-Climate Model Initiative part 1 (CCMI-1). Tropical w* is often taken as a proxy for diagnosing the BDC strength. In the data request, a constant scale height is assumed for conversion of w* from Pa/s to m/s . However, the scale height significantly decreases over time in the climate simulations as a result of stratospheric shrinkage.

We show that stratospheric cooling enhances the w* trends if the unit conversion is made with constant scale height, which can be misinterpreted as BDC acceleration. We quantify this effect to account for around 20% of the w* trend across the 21st century, consistently among the CCMI-1 climate projection simulations. Past studies that based w* trend analyses on these data therefore made a 20% error. Moreover, we call attention that other dynamical diagnostics are affected by the neglection of stratospheric shrinkage too and also the data requests of other multi-model assessments use the constant scale height assumtion for unit conversion in climate change simulations.

How to cite: Eichinger, R. and Sacha, P.: Artificial acceleration of the Brewer-Dobson circulation due to stratospheric cooling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12880, https://doi.org/10.5194/egusphere-egu2020-12880, 2020.

EGU2020-17508 | Displays | AS1.18

Reconciling the BDC response in climate models to the volcanic forcings with reanalyses

Mohamadou Diallo, Hella Garny, Roland Eichinger, Valentina Aquila, Manfred Ern, and Felix Ploeger

The stratospheric Brewer--Dobson circulation (BDC) is an important element of climate system as it determines the concentration of radiatively active trace gases like water vapor, ozone and aerosol above the tropopause. Climate models predict that increasing greenhouse gas levels speed up the stratospheric circulation. BDC changes is substantially modulated by different modes of climate variability (QBO, ENSO, solar cycle), including the volcanic aerosols. However, such variability is often not reliably included or represented in current climate model simulations, challenging the evaluation of models’ behavior against observations and constituting a major uncertainty in current climate simulations. 

Here, we investigate the main differences between the reanalysis and the CCMI/CMIP6 climate models’ response to stratospheric volcanic forcings regarding the depth/strength of the stratospheric BDC, with a focus on potential changes in the deep and shallow circulation branches. We also discuss the key reasons of the discrepancies (incl. uncertainties associated with volcanological forcing datasets and missing direct aerosol heating in the reanalysis) in the BDC response between reanalysis-driven and climate model simulations in the lower, mid and upper stratosphere. Finally, we assess the dynamical mechanisms involved in the volcanically-induced BDC changes to understand the opposite regime between lower, middle and upper stratosphere after the Mt Pinatubo eruption.

How to cite: Diallo, M., Garny, H., Eichinger, R., Aquila, V., Ern, M., and Ploeger, F.: Reconciling the BDC response in climate models to the volcanic forcings with reanalyses, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17508, https://doi.org/10.5194/egusphere-egu2020-17508, 2020.

EGU2020-2516 | Displays | AS1.18

Impact of solar cycle variation of UV radiation in the Northern Hemisphere winter polar troposphere

In-Sun Song, Jeong-Han Kim, and Geonhwa Jee

Solar cycle (SC) induces variations in the UV radiation. The UV variations change the ozone production rate in the middle atmosphere. Responses to the SC-induced variations occur mainly in the equatorial upper stratosphere and the lower mesosphere. It has been reported that zonal mean temperature difference is 1--2 K between solar maximum and minimum. The temperature variation in the equatorial upper stratosphere modifies the meridional temperature gradient between the equatorial region and winter polar region. Change in the temperature gradient induces difference in the strength of the stratospheric polar vortex, which accompanies change in poleward meridional mass circulations and as a result change in the horizontal distribution of the sea-level pressure (SLP) in the winter polar region. In the present study, this mechanism of SC-induced SLP variations in the Northern Hemisphere (NH) winter polar regions is examined using an idealized whole-atmosphere general circulation model. This global model covers from the ground to the lower thermosphere and includes gravity wave drag parameterization and realistic topography. This idealized model is driven by the zonally-averaged radiative equilibrium temperature, but it nevertheless simulates quite realistically atmospheric variabilities such as sudden stratospheric warmings and quasi-biennial oscillations. Perpetual January simulations for solar maximum and minimum show that this idealized model can reproduce the negative SLP anomaly in the NH polar regions in solar maximum, but the magnitude of the anomaly is weak compared with reanalysis studies. Mechanisms of this SLP anomaly are examined through planetary wave dynamics and gravity-wave processes.

How to cite: Song, I.-S., Kim, J.-H., and Jee, G.: Impact of solar cycle variation of UV radiation in the Northern Hemisphere winter polar troposphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2516, https://doi.org/10.5194/egusphere-egu2020-2516, 2020.

EGU2020-12888 | Displays | AS1.18

The stratospheric response and surface influence in a bias-corrected model.

Nicholas Tyrrell, Alexey Karpechko, and Sebastian Rast

We investigate the effect of systematic model biases on teleconnections influencing the Northern Hemisphere wintertime circulation. We perform a two-step nudging and bias-correcting scheme for the dynamic variables of the ECHAM6 atmospheric model to reduce errors in the model climatology relative to ERA-Interim. The developed scheme is efficient in removing errors in model’s climatology. In particular, large negative bias in December-February mean zonal stratospheric winds is reduced by up to 75%, significantly increasing the strength of the Northern Hemisphere wintertime stratospheric polar vortex. The bias-corrections are applied to the full atmosphere or stratosphere only.

We compare the response of bias-corrected and control runs to internal stratospheric variability and surface forcings that are important on seasonal timescales: Siberian snow cover in October; the Quasi-Biennial Oscillation (QBO); and ENSO. We find the bias-corrected model has the potential for a strengthened and more realistic response to the teleconnections, either in the stratospheric or surface response. In particular, the bias-corrected model has a strong QBO teleconnection which modulates the extratropical polar vortex and sea level pressure variability in a manner similar to that seen in observations. The Siberian snow forcing with the stratosphere-only bias-corrections also leads to an enhanced surface response relative to the control. The mechanism behind the sensitivity of the teleconnections to model biases is discussed.

How to cite: Tyrrell, N., Karpechko, A., and Rast, S.: The stratospheric response and surface influence in a bias-corrected model., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12888, https://doi.org/10.5194/egusphere-egu2020-12888, 2020.

EGU2020-187 | Displays | AS1.18

Measurement capabilities of strato-mesospheric winds in the Arctic region

Rita Edit Kajtár, Mathias Milz, Uwe Raffalski, and Jana Mendrok

There is a need for inferring mid-stratosphere to mid-mesosphere wind profiles between approximately 25 and 75 km altitude as a consequence of the relatively poor characterization of the complex atmospheric dynamics at these altitudes by the existing monitoring techniques. A better knowledge of the wind field could help improve the quality of global circulation models for this region of the atmosphere. Our goal is to measure strato-mesospheric horizontal wind profiles over the Arctic region. To this objective, we are using data from continuous measurements recorded for ozone chemistry monitoring purposes that have been ongoing since 2002 and from dedicated wind measurements recorded since 2014. An accurate interpretation of the wind patterns could give us an insight into past and present wind dynamics in the Arctic. For the measurements, we are using the ground-based millimeter-wave radiometer KIMRA [Raffalski et al., 2002] with a spectral range between 195-233GHz, situated at the Swedish Institute of Space Physics, in Kiruna, Sweden. Within KIMRA’s spectral range, the thermal emission spectrum of a strong ozone line at 231.3GHz has been used for ozone monitoring, and it might also be the most suitable to use for inferring wind speeds. It has both a strong contribution compared to other, secondary gases identified in this frequency region, and it has an enhanced spectral signature compared to the baseline effects induced by the radiometer itself. By determining the difference between the observed (wind-affected) and the simulated reference spectra (without wind), we can characterize the Doppler shift of the line with the help of our retrieval system and subsequently infer the speeds of the winds that induced the shift. The wind profile retrievals are performed with the Qpack2 package [Eriksson et al., 2005] for inverting the set of observations using an optimal estimation retrieval approach (OEM). The OEM provides the best solution given the measurements and their errors and the a priori knowledge and its errors. The a priori knowledge that we consider has been estimated from ERA5 re-analysis data downloaded from the Copernicus Climate Data Store. In connection with Qpack2, we use the Atmospheric Radiative Transfer Simulator (ARTS-2) [Bühler et al., 2018] as a forward model. We test the retrieval capabilities of strato-mesospheric horizontal wind profiles and assess if the retrieval can be performed with sufficient accuracy. In addition, we intend to evaluate the technical capabilities of KIMRA regarding possible improvements to the instrument’s performance. Besides the implementation of new hardware, we will analyze how adjusting certain parameters that currently limit its spectral resolution affects the sensitivity of the measurements. Furthermore, we will aim to decrease the intrinsic noise of the radiometer and increase its stability over time.

How to cite: Kajtár, R. E., Milz, M., Raffalski, U., and Mendrok, J.: Measurement capabilities of strato-mesospheric winds in the Arctic region , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-187, https://doi.org/10.5194/egusphere-egu2020-187, 2020.

EGU2020-295 | Displays | AS1.18

Dynamics of zonal mean characteristics of circulation in stratosphere and mesosphere in winter

Olga Zorkaltseva, Vladimir Mordvinov, Natalia Dombrovskaya, and Alexander Pogoreltsev

The model of the middle and upper atmosphere circulation (MUAM) and the data of the ERA-interim archive are used to study the mean zonal variations of wind velocity and temperature in the middle atmosphere. Comparison of model calculations and data of ERA-interim archives showed that the model adequately reproduces the main features of circulation processes in the winter stratosphere. The analysis of variations in the mean zonal characteristics of the atmosphere is show that synchronous variations there are in wind velocity and temperature in the stratosphere and mesosphere in the range of 10-30 days . These synchronous variations occupy long latitudinal zones horizontally (tens degree) and have a significant length vertically (tens km). The sign of the variations change horizontally in the region of jet streams (and does not change at the equator), and the vertical change of sign occurs in areas of the stratopause and the mesopause. The nature of  the variations practically does not depend on the phase of the quasi-biennial cycle in the Equatorial stratosphere. The variations are global scale and are reminiscent of the fluctuations in the meridional circulation cells. The dynamic processes of destruction of the polar vortex during sudden stratospheric warming are coordinated with these synchronous variations.

Acknowledgements. This work was supported by the Russian Science Foundation, project No. 19-77-00009.  The authors gratefully acknowledge the access to the ECMWF ERA-Interim.

How to cite: Zorkaltseva, O., Mordvinov, V., Dombrovskaya, N., and Pogoreltsev, A.: Dynamics of zonal mean characteristics of circulation in stratosphere and mesosphere in winter, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-295, https://doi.org/10.5194/egusphere-egu2020-295, 2020.

EGU2020-705 | Displays | AS1.18

Mechanisms and predictability of Sudden Stratospheric Warming in winter 2018

Irina Statnaia, Alexey Karpechko, and Heikki Järvinen

In this study, we investigate the Sudden Stratospheric Warming that took place on 12 February 2018 (SSW2018), its predictability and teleconnection with the Madden-Julian Oscillation (MJO) by analysing ECMWF ensemble forecast initialised on 1 February 2018. Several days prior to that date MJO was in Phase 6 and had a strong amplitude potentially contributing to triggering the SSW. Two wave trains can be identified in the upper troposphere over the northern Atlantic and Pacific regions. Starting from the 3 February, the amplitude of planetary wave with wavenumber 2 (PW2) started to increase and reached record high values, while the PW1 amplitude decreased.

In order to better understand the sources of uncertainties, we divided the forecast ensemble members into two groups. The first group predicted the SSW onset in time while the second group of ensemble members did not capture the wind reversal at 60°N 10 hPa. The results obtained with the ensemble forecast data were compared with the ECMWF’s reanalysis ERA-Interim (ERA-I). The analysis of the two groups of ensemble forecasts shows that in the first group of forecasts PW2 prevailed with ridges over the Ural and Alaska and troughs over the west Siberia and Canada, as observed. Instead, PW1 is seen in the second group of ensemble members with a broad ridge over Eurasia. Calculations of wave activity fluxes show that there is less zonal wave energy propagation in the second group compared to the first group and ERA-I over Eurasia, which can be associated with the errors in the forecasted location of the Ural high. There is also wave energy propagation towards an area of high pressure over Alaska, as seen in ERA-I. Here, wave energy propagation is similarly underestimated by both groups. Overall, the structure of the geopotential anomalies averaged for 5-7 February for the first group and ERA-I is more consistent with the climatological response from MJO phase 6 taken with lag 5-9 days than that in the second group.

How to cite: Statnaia, I., Karpechko, A., and Järvinen, H.: Mechanisms and predictability of Sudden Stratospheric Warming in winter 2018, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-705, https://doi.org/10.5194/egusphere-egu2020-705, 2020.

EGU2020-1390 | Displays | AS1.18

Interannual variations in Lower Stratospheric Ozone during the period 1984-2016

Jinpeng Lu, Fei Xie, Wenshou Tian, Jianping Li, Wuhu Feng, Martyn Chipperfield, Jiankai Zhang, and Xuan Ma

In this work we investigate interannual variations in lower stratospheric ozone from 1984 to 2016 based on a satellite-derived dataset and simulations from a chemical transport model. An empirical orthogonal function (EOF) analysis of ozone variations between 2000 and 2016 indicates that the first, second, and third EOF modes are related to the quasi-biennial oscillation (QBO), canonical El Niño–Southern Oscillation (ENSO), and ENSO Modoki events, respectively; these three leading EOFs capture nearly 80% of the variance. However, for the period 1984–2000, the first, second, and third modes are related to the QBO, ENSO Modoki, and canonical ENSO events, respectively. The explained variance of the second mode in relation to ENSO Modoki is nearly twice that of the third mode for canonical ENSO. Since the frequency of ENSO Modoki events was higher from 1984 to 2000 than after 2000, the Brewer–Dobson circulation anomalies related to ENSO Modoki were stronger during 1984–2000, which caused ENSO Modoki events to have a greater effect on lower stratospheric ozone before 2000 than after. Ozone anomalies associated with QBO, ENSO Modoki, and canonical ENSO events are largely caused by dynamic processes, and the effect of chemical processes on ozone anomalies is opposite to that of dynamic processes. Ozone anomalies related to dynamic processes are 3–4 times greater than those related to chemical processes.

How to cite: Lu, J., Xie, F., Tian, W., Li, J., Feng, W., Chipperfield, M., Zhang, J., and Ma, X.: Interannual variations in Lower Stratospheric Ozone during the period 1984-2016, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1390, https://doi.org/10.5194/egusphere-egu2020-1390, 2020.

EGU2020-1852 | Displays | AS1.18

Characteristics of the dynamical tropopause derived from satellite observations

Yixuan Shou, Feng Lu, and Shaowen Shou

                                                                                                                             Abstract

As the products of the complicated interactions and the kinematic, chemical and radiative balances between upper troposphere and lower stratosphere, dynamical tropopause is recognized as a key boundary of atmosphere closely related to weather and climate change. In this study, a high-spatio-temporal-resolution dynamical tropopause pressure estimation scheme based on the measurements from the Advanced Geostationary Radiation Imager boarded on the new generation geostationary satellite of China, FengYun-4A, is proposed. The implemented retrieval model is quantitative validated against ERA-Interim reanalysis dataset showing a high accuracy with the correlation coefficient of 0.9603 and root-mean-square-error of 42.96 hPa. The method is applied to a 1-year period starting in January 2018 over the east hemisphere. The geographic distributions and the seasonal cycle show that the dynamical tropopause height is varied with the latitudes and seasons which has the mean pressure of about 50 hPa over low latitudes and about 300 hPa over the high latitudes where the tropopause height reaches the minimum during March-May. Generally, the folds preferentially occur in the subtropics around 20-40º latitude where the upper fronts located. They are found to have potential connection with the rain band splitting during the Mei-Yu season in East Asia.

Keywords:Dynamic tropopause, FengYun-4 geostationary satellite, WV channels

How to cite: Shou, Y., Lu, F., and Shou, S.: Characteristics of the dynamical tropopause derived from satellite observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1852, https://doi.org/10.5194/egusphere-egu2020-1852, 2020.

EGU2020-2560 | Displays | AS1.18

The behavior of Graviy wave during the unusual QBO structure in 2015/2016

Haiyan Li and Qingxiang Li

We explored the gravity wave behavior and its role for the unusual QBO structure in 2015/2016 by analyzing the data of U.S. radiosonde with high vertical resolution over four equatorial stations from 1998 to 2017. The result implies that the gravity wave behavior should play an important role during the QBOW phase interrupted around 22 km in 2015/2016 winter. While the role of gravity wave was not as important as Kelvin waves during the prolonged and upward propagating westerly zonal wind around 27 km. The enhanced gravity wave may be generated by the instability of the stratospheric atmosphere rather than the tropospheric convection because the convection is weak during the unusual QBO structure over the four equatorial stations.

How to cite: Li, H. and Li, Q.: The behavior of Graviy wave during the unusual QBO structure in 2015/2016, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2560, https://doi.org/10.5194/egusphere-egu2020-2560, 2020.

EGU2020-5287 | Displays | AS1.18

Solar Influences on Stratospheric Circulation Patterns

Yonatan Givon and Chaim Garfinkel

The impact of the solar cycle on the NH winter stratospheric circulation is analyzed using
simulations of a Model of an idealized Moist Atmosphere (MiMA). By comparing solar minimum
periods to solar maximum periods, the solar impact on the stratosphere is evaluated: Solar
maximum periods are accompanied by warming of the tropics that extends into the midlatitudes
due to an altered Brewer Dobson Circulation. This warming of the subtropics and the altered
Brewer Dobson Circulation leads to an increase in zonal wind in midlatitudes, which is then
followed by a decrease in E-P flux convergence near the winter pole which extends the enhanced
westerlies to subpolar latitudes.
We use the transformed Eulerian mean framework to reveal the processes that lead to the
formation of this sub-polar zonal wind anomaly and its downward propagation from the top of the
stratosphere to the tropopause.

How to cite: Givon, Y. and Garfinkel, C.: Solar Influences on Stratospheric Circulation Patterns, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5287, https://doi.org/10.5194/egusphere-egu2020-5287, 2020.

EGU2020-5528 | Displays | AS1.18

A breakdown of the link between the Arctic and North Atlantic Oscillations in warm climate projections

Mostafa Hamouda, Claudia Pasquero, and Eli Tziperman
The North Atlantic Oscillation (NAO) and the Arctic Oscillation (AO) are climate variability modes significantly affecting temperature and precipitation variability in the mid-latitudes of the Northern hemisphere. In this study, we use both reanalysis data and model historical and warmer climate simulations to show that the relation between the two oscillations may change dramatically in a different climate. In the current climate, these two climate modes are highly correlated, as they are both strongly influenced by downward propagation of stratospheric anomalies into the troposphere. When considering a warmer climate scenario (RCP8.5 in the XXIII century), the correlation between NAO and AO drops significantly, revealing that they become two separate modes of variability. The stratosphere remains an important precursor for NAO, while the AO consistently precede stratospheric anomalies. The analysis suggests that these changes are owed to land-sea thermal contrast intensification in the Pacific region, which becomes more favorable for storm variability.

How to cite: Hamouda, M., Pasquero, C., and Tziperman, E.: A breakdown of the link between the Arctic and North Atlantic Oscillations in warm climate projections, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5528, https://doi.org/10.5194/egusphere-egu2020-5528, 2020.

EGU2020-6676 | Displays | AS1.18

The Efficiency of Upward Wave Propagation Near the Tropopause

Israel Weinberger, Chaim Garfinkel, and Thomas Birner

Recent work has highlighted that not all periods with anomalous heat flux at 100hPa were preceded by anomalous heat flux in the troposphere (Birner and Alberts 2017; White et al 2019; Camara et al 2019), and the goal of this work is to understand the factors that govern the efficiency of upward wave propagation near the tropopause. The index of refraction of Matsuno (1970) has been used to offer guidance on the direction of wave propagation within the stratosphere. Specifically, waves are preferentially refracted towards regions with a more positive index of refraction and ducted away from regions in which the index of refraction is more negative. However, the index of refraction was derived under the assumption that buoyancy frequency is constant at all height levels, which is clearly not true near the tropopause. This assumption allowed Matsuno to ignore certain height dependent buoyancy frequency terms, and here we explore the impact of these terms near the tropopause.

Using the dataset of the European Center for Medium-Range Weather Forecasts Reanalysis version 5 (ERA5) we defined 'transmitting' composites consisting of more efficient upward propagation events between 300hPa and 100hPa. Similarly, periods of less efficient upward propagation events between 300hPa and 100hPa are composited as 'decaying' events. We computed the index of refraction profile using a median, percentage of negative days and the trimmed mean (Wilks 2011), and also consider the terms neglected by Matsuno. We find that  the index of refraction can account for the difference between the decaying and transmitting composite.

How to cite: Weinberger, I., Garfinkel, C., and Birner, T.: The Efficiency of Upward Wave Propagation Near the Tropopause, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6676, https://doi.org/10.5194/egusphere-egu2020-6676, 2020.

EGU2020-7862 | Displays | AS1.18

Prospects for predicting the type and timing of the surface response after stratospheric events

Daniela Domeisen, Hilla Afargan-Gerstman, Johanna Baehr, Mikhail Dobrynin, Christian Grams, Peter Hitchcock, and Lukas Papritz

Extreme events in the stratosphere, so-called sudden stratospheric warming (SSW) events, can have a significant impact on surface weather. However, only about two thirds of SSW events have a surface impact, and the expected response is not always observed at the same time lag after the stratospheric event. In order to achieve skillful long-range predictions it will be necessary to understand the reasons for the presence or absence of a response, and to successfully predict the timing of the surface impact.
This contribution investigates several potential long-range predictors for the tropospheric response: the persistence of the lower stratospheric temperature signal, anomalous eddy driving in the east Pacific, as well as the North Atlantic weather regime present at the onset of the stratospheric event. All of these are found to help determine the type and timing of the tropospheric surface impact, and a strong potential for long-range predictability of several weeks based on these predictors is found over Europe.

How to cite: Domeisen, D., Afargan-Gerstman, H., Baehr, J., Dobrynin, M., Grams, C., Hitchcock, P., and Papritz, L.: Prospects for predicting the type and timing of the surface response after stratospheric events, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7862, https://doi.org/10.5194/egusphere-egu2020-7862, 2020.

EGU2020-8905 | Displays | AS1.18

A Method for Estimating the Evolution of Brewer-Dobson Circulation Upwelling

Edward Charlesworth, Felix Ploeger, Mohamadu Diallo, Thomas Birner, and Patrick Joeckel

Both theory and climate model results suggest that the Brewer-Dobson circulation should strengthen in the stratosphere with increasing greenhouse gas concentrations. Directly measuring the circulation strength is not possible, so verification of this sensitivity has been limited to indirect inferences from observed tracer fields of long-lived species. These methods, however, are complex and accumulation of the data required for them is difficult. When limiting discussion to the tropical lower stratosphere, ozone concentrations have shown to be consistent with an accelerating circulation. These measurements are particularly useful because of the long timeseries available from multiple datasets, but they have only been used for indirect investigations of the circulation strength, up until now.

In this work, we invert the ozone balance equation to solve for upwelling. By limiting the investigation to 70 hPa in the southern tropics and estimating upwelling anomalies from the long-term mean (and not the absolute value of upwelling) most chemical terms and both horizontal and vertical mixing can be neglected, and calculation of the remaining terms is straight-forward. To verify the validity of the method, a calculation of upwelling is performed using climate model data, from which a comparison of actual upwelling and upwelling from the inverse method can be made. The seasonal cycle of upwelling anomalies is compared to upwelling anomalies from reanalyses and model results, and trends and variability are discussed.

How to cite: Charlesworth, E., Ploeger, F., Diallo, M., Birner, T., and Joeckel, P.: A Method for Estimating the Evolution of Brewer-Dobson Circulation Upwelling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8905, https://doi.org/10.5194/egusphere-egu2020-8905, 2020.

EGU2020-9102 | Displays | AS1.18

Influence of sudden stratospheric warmings on the polar vortex enhancement related to energetic electron precipitation

Timo Asikainen, Antti Salminen, Ville Maliniemi, and Kalevi Mursula

The northern polar vortex experiences considerable inter-annual variability, which is also reflected to tropospheric weather. Recent research has established a link between polar vortex variations and energetic electron precipitation (EEP) from the near-Earth space into the polar atmosphere, which is mediated by EEP-induced chemical changes causing ozone loss in the mesosphere and stratosphere. However, the most dramatic changes in the polar vortex are due to sudden stratospheric warmings (SSW), a momentary breakdown of the polar vortex associated to enhanced planetary wave convergence and meridional circulation. Here we consider the influence of SSWs on the atmospheric response to EEP in 1957-2017 using combined ERA-40 and ERA-Interim re-analysis data and geomagnetic activity as a proxy of EEP. We find that the EEP-related enhancement of the polar vortex and other associated dynamical responses are seen only during winters when a SSW occurs, and that the EEP-related changes take place slightly before the SSW onset. We show that the atmospheric conditions preceding SSWs favor enhanced wave-mean-flow interaction, which can dynamically amplify the initial polar vortex enhancement caused by ozone loss. These results highlight the importance of considering SSWs and sufficient level of planetary wave activity as a necessary condition for observing the effects of EEP on the polar vortex dynamics.

How to cite: Asikainen, T., Salminen, A., Maliniemi, V., and Mursula, K.: Influence of sudden stratospheric warmings on the polar vortex enhancement related to energetic electron precipitation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9102, https://doi.org/10.5194/egusphere-egu2020-9102, 2020.

EGU2020-9118 | Displays | AS1.18

Coupling of Arctic ozone and stratospheric dynamics and its influence on surface climate: the role of CFC concentrations.

Marina Friedel, Gabriel Chiodo, Stefan Muthers, Julien Anet, Andrea Stenke, and Thomas Peter

Arctic stratospheric ozone has been shown to exert a statistically significant influence on Northern Hemispheric surface climate. This suggests that Arctic ozone is not only passively responding to dynamical variability in the stratosphere, but actively feeds back into the circulation through chemical and radiative processes. However, the extent and causality of the chemistry-dynamics coupling is still unknown. Since many state-of-the-art climate models lack a sufficient representation of ozone-dynamic feedbacks, a quantification of this coupling can be used to improve intra-seasonal weather and long-term climate forecasts.

We assess the importance of the ozone-dynamics coupling by performing simulations with and without interactive chemistry in two Chemistry Climate Models. The chemistry-dynamics coupling was examined in two different sets of time-slice simulations: one using pre-industrial, and one using year-2000 boundary conditions. We focus on the impact of sudden stratospheric warmings (SSW) and strong vortex events on stratosphere-troposphere coupling, since these go along with strong ozone anomalies and therefore an intensified ozone feedback.  We compare the runs with and without interactive chemistry.

For pre-industrial conditions, simulations without interactive ozone show a more intense and longer lasting surface signature of SSWs compared to simulations with interactive chemistry. Conversely, for year-2000 conditions, the opposite effect is found: interactive chemistry amplifies the surface signature of SSWs. Following these results, atmospheric CFC concentrations, which differ greatly in the pre-industrial and year-2000 runs, determine the sign of the ozone-circulation feedback, and thus have a strong impact on chemistry-climate coupling. Implications for modeling of stratosphere-troposphere coupling and future projections are discussed.

How to cite: Friedel, M., Chiodo, G., Muthers, S., Anet, J., Stenke, A., and Peter, T.: Coupling of Arctic ozone and stratospheric dynamics and its influence on surface climate: the role of CFC concentrations., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9118, https://doi.org/10.5194/egusphere-egu2020-9118, 2020.

EGU2020-9475 | Displays | AS1.18

Solar-related and internal drivers of the northern polar vortex

Antti Salminen, Timo Asikainen, Ville Maliniemi, and Kalevi Mursula

During the winter, a polar vortex, a strong westerly thermal wind, forms in the polar stratosphere. In the northern hemisphere the polar vortex varies significantly during and between winters. The Sun and the solar wind affect the polar vortex via two separate factors: electromagnetic radiation and energetic particle precipitation. Earlier studies have shown that increased energetic electron precipitation (EEP) decreases ozone in the polar upper atmosphere and strengthens the northern polar vortex, while solar irradiance affects temperature and ozone in the stratosphere directly at low latitudes and indirectly at high latitudes. In addition to the solar-related drivers, the northern polar vortex is also affected by different atmospheric internal factors such as Quasi-Biennial Oscillation (QBO), El-Nino Southern Oscillation (ENSO) and volcanic aerosols. Several studies have shown that the QBO modulates the effects that the solar-related drivers and ENSO cause to the polar vortex. In this study we examine and compare effects of the two solar-related drivers (solar radiation and EEP) and three atmospheric internal factors (QBO, ENSO and volcanic aerosols) on the polar vortex. We use multiple linear regression analysis to estimate the effects of each factor on temperature and zonal wind. We concentrate on the northern wintertime stratosphere and troposphere and examine the period of 1957-2017 using a combination of ERA-40 and ERA-Interim re-analysis data. We also study these effects separately in the two QBO phases. While we confirm that increased EEP is associated with a strengthened polar vortex, in accordance with the earlier studies, we further show that EEP is the largest and most significant factor among those studied affecting  the northern polar vortex variability. We also find that the EEP effect on polar vortex is particularly strong in the easterly phase of QBO while in the westerly phase the EEP effect is weakened and does not stand out from other effects.

How to cite: Salminen, A., Asikainen, T., Maliniemi, V., and Mursula, K.: Solar-related and internal drivers of the northern polar vortex, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9475, https://doi.org/10.5194/egusphere-egu2020-9475, 2020.

EGU2020-10591 | Displays | AS1.18

Variations in The Frequency of Sudden Stratospheric Warmings in CMIP5 and CMIP6

Zheng Wu and Thomas Reichler

The frequency of sudden stratospheric warming events (SSWs) is an essential characteristic of the coupled stratosphere-troposphere system. This study is motivated by the fact that many of the CMIP5 and CMIP6 climate models considerably over- or underestimate the observed SSW frequency. The goal is to understand the causes for the large intermodel spread in the number of SSWs and relate it to specific model configurations. To this end, various dynamical quantities associated with the simulation of SSWs are investigated. It is found that variations in the SSW frequency are closely related to the strength of the polar vortex and the stratospheric wave activity. While it is difficult to explain the variations in the strength of the polar vortex, the stratospheric wave activity is strongly influenced by the background state (i.e., zonal wind and index of refraction) of the lower stratosphere. An important regulator for the background is the extratropical tropopause temperature, which in turn is associated with the vertical model resolution. Low-resolution models tend to have large biases in simulating the location and temperature of the extratropical tropopause. The results indicate that the simulated SSW frequency is a useful metric for model performance, as the frequency is highly sensitive to a number of stratospheric and tropospheric factors.

How to cite: Wu, Z. and Reichler, T.: Variations in The Frequency of Sudden Stratospheric Warmings in CMIP5 and CMIP6, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10591, https://doi.org/10.5194/egusphere-egu2020-10591, 2020.

EGU2020-10766 | Displays | AS1.18

How turbulent mountain stress influences sudden stratospheric warming ocurrence in WACCM

Froila M. Palmeiro, Rolando R. Garcia, Natalia Calvo, David Barriopedro, and Bernat Jiménez-Esteve

The implementation of the Turbulent Mountain Stress (TMS) parametrization in the Whole Atmospheric Community Climate Model (WACCM) is found to be critical to obtain a realistic Sudden Stratospheric Warming (SSW) frequency in the Northern Hemisphere. Comparing two 50-year simluations, one with TMS (TMS-on) and one without (TMS-off) reveals lower than observed SSW frequency in TMS-off from December to February, while in March both simulations show SSW frequencies comparable to reanalysis. Meridional eddy heat fluxes in the lower stratosphere are stronger in TMS-on than in TMS-off, except in March. These differences are accompanied by increased orographic gravity wave drag (OGWD) in TMS-off that comes mainly from the Himalayas and the Rocky Mountains in response to stronger surface winds. Two different mechanisms of how planetary and GWs interact are identified in the simulations. In the lower stratosphere, enhanced dissipation of GWs in TMS-off modifies the subtropical jet and thus the conditions for refraction of planetary waves. In early winter, wave geometry diagnostics shows waveguides formation from 55N to 75N in TMS-on, enhancing wave propagation to the polar vortex. On the contrary, vertical propagation in TMS-off is in inhibited above the lower stratosphere and confined to latitudes south of 50N. Compensation between resolved and parametrized GWs is also observed, leading to weaker Eliassen-Palm flux divergence in response to stronger OGWD in TMS-off. In late winter, conditions for propagation are similar in both simulations by late winter, which explains the reduced TMS-off bias in the frequency of March SSWs.

How to cite: Palmeiro, F. M., Garcia, R. R., Calvo, N., Barriopedro, D., and Jiménez-Esteve, B.: How turbulent mountain stress influences sudden stratospheric warming ocurrence in WACCM, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10766, https://doi.org/10.5194/egusphere-egu2020-10766, 2020.

EGU2020-11839 | Displays | AS1.18

Uncertainty in the response of sudden stratospheric warmings and stratosphere- troposphere coupling to quadrupled CO2 concentrations in CMIP6 models

Blanca Ayarzagüena, Andrew J. Charlton-Pérez, Amy H. Butler, Peter Hitchcock, Isla R. Simpson, Lorenzo M. Polvani, Neal Butchart, Edwin P. Gerber, Lesley Gray, Birgit Hassler, Pu Lin, François Lott, Elisa Manzini, Ryo Mizuta, Clara Orbe, Scott Osprey, David Saint-Martin, Michael Sigmond, Masakazu Taguchi, and Evgeny Volodin and the DynVarMIP-SSW

Major sudden stratospheric warmings (SSWs), vortex formation and final breakdown dates are key highlight points of the stratospheric polar vortex. These phenomena are relevant for stratosphere-troposphere coupling, which explains the interest in understanding their future changes. However, up to now, there is not a clear consensus on which projected changes to the polar vortex are robust, particularly in the Northern Hemisphere, possibly due to short data record or relatively moderate CO2 forcing. The new simulations performed under the Coupled Model Intercomparison Project, Phase 6, together with the long daily data requirements of the DynVarMIP project in preindustrial and quadrupled CO2 (4xCO2 ) forcing simulations provide a new opportunity to revisit this topic by overcoming the limitations mentioned above.

In this study, we analyze this new model output to document the change, if any, in the frequency of SSWs under 4xCO2 forcing. Our analysis reveals a large disagreement across the models as to the sign of this change, even though most models show a statistically significant change. The models, however, are in good agreement as to the impact of SSWs over the North Atlantic: there is no indication of a change under 4xCO2 forcing. Over the Pacific, however, the change is more uncertain. Finally, the models show robust changes to the seasonal cycle in the stratosphere. Specifically, we find a longer duration of the stratospheric polar vortex, and thus a longer season of stratosphere-troposphere coupling.

How to cite: Ayarzagüena, B., Charlton-Pérez, A. J., Butler, A. H., Hitchcock, P., Simpson, I. R., Polvani, L. M., Butchart, N., Gerber, E. P., Gray, L., Hassler, B., Lin, P., Lott, F., Manzini, E., Mizuta, R., Orbe, C., Osprey, S., Saint-Martin, D., Sigmond, M., Taguchi, M., and Volodin, E. and the DynVarMIP-SSW: Uncertainty in the response of sudden stratospheric warmings and stratosphere- troposphere coupling to quadrupled CO2 concentrations in CMIP6 models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11839, https://doi.org/10.5194/egusphere-egu2020-11839, 2020.

EGU2020-13358 | Displays | AS1.18

Impact of stratospheric ozone on the subseasonal prediction skill in the Southern Hemisphere spring

Jiyoung Oh, Seok-Woo Son, and Bo-Reum Han

The Antarctic polar vortex and the associated ozone change have been recognized as a key factor that influences both local and large-scale circulations in the Southern Hemisphere (SH) extratropics. Their downward impacts are also evident in the subseasonal-to-seasonal (S2S) and long-term climate predictions especially in austral spring and summer. However, most operational S2S models, including the Global Seasonal Forecasting System version 5 (GloSea5), use climatological ozone and ignore time-varying ozone associated with polar vortex variability. This study explores the possible impact of stratospheric ozone on SH S2S prediction skill by conducting the two sets of reforecast experiments with the GloSea5. The reforecasts are initialized on 1st September of every year for the period of 2004-2018 with either climatological or observed ozone from the Stratospheric Water and OzOne Satellite Homogenized (SWOOSH) data. It turns out that the reforecasts with observed ozone have an improved prediction skill at 5- and 6-week lead forecasts than those with climatological ozone. The surface prediction skills also increase over the southern Australia and New Zealand. These results suggest that more realistic stratospheric ozone forcing could improve the SH prediction skill on subseasonal-to-seasonal timescale.

How to cite: Oh, J., Son, S.-W., and Han, B.-R.: Impact of stratospheric ozone on the subseasonal prediction skill in the Southern Hemisphere spring , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13358, https://doi.org/10.5194/egusphere-egu2020-13358, 2020.

EGU2020-13818 | Displays | AS1.18

Variability and changes of the stratospheric large scale circulation and possible consequences for ozone streamer events

Küchelbacher Lisa, Laux Dominik, and Michael Bittner

Planetary waves (PW) dominate the meridional Brewer-Dobson circulation in the stratosphere and therewith, the large-scale mass transport of ozone. As PW break, ozone poor air masses are irreversibly mixed into mid-latitudes. Due to the disproportionate warming of the North Pole, an increase in PW activity (PWA) is expected. This should also have consequences for ozone streamer events.

We derived the PWA of ERA 5 and Interim Reanalysis temperature from ground level up the mesosphere. We identify Ozone-streamer events with a statistical based approach on the basis of total column concentration measured by GOME-2. We deconvoluted the time series of the PWA and the ozone-streamer events with the empirical mode decomposition method (EMD). Moreover, we developed a simple spectral model of the meridional wind shear on the basis of PW. This model serves as a measure of the atmospheric instability in the stratosphere.

As we deconvolute the PWA with the EMD we find signatures of QBO, ENSO and solar cycles and quantify their contributions. As PW dominate the circulation in the stratosphere, it appears to be a coherent consequence that ozone streamers are modulated on the same time scales as the PWA.With the spectral model of the meridional wind shear we find regions in the atmosphere, where PW are most likely to break. As a result there is an increased meridional transport of air masses, in particular of ozone. This is why ozone streamers occur most frequently at the transition zones from ocean to continent; strongest from North Atlantic to Europe. Moreover, we find significant long-term trends of the PWA in the stratosphere. Due to the increase of the PWA in the stratosphere, ozone streamer events are likely to occur more often in the future.

How to cite: Lisa, K., Dominik, L., and Bittner, M.: Variability and changes of the stratospheric large scale circulation and possible consequences for ozone streamer events, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13818, https://doi.org/10.5194/egusphere-egu2020-13818, 2020.

EGU2020-15897 | Displays | AS1.18

The influence of the tropical troposphere on the QBO in model simulations

Federico Serva, Chiara Cagnazzo, Bo Christiansen, and Shuting Yang

How to cite: Serva, F., Cagnazzo, C., Christiansen, B., and Yang, S.: The influence of the tropical troposphere on the QBO in model simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15897, https://doi.org/10.5194/egusphere-egu2020-15897, 2020.

EGU2020-17139 | Displays | AS1.18

Influence of gravity wave drag parametrisations on the stratospheric circulation of seasonal ICON-NWP experiments

Raphael Köhler, Dörthe Handorf, Ralf Jaiser, Klaus Dethloff, Günther Zängl, Detlev Majewski, and Markus Rex

The stratospheric polar vortex is highly variable in winter and thus, models often struggle to capture its variability and strength. Yet, the influence of the stratosphere on the tropospheric circulation becomes highly important in Northern Hemisphere winter and is one of the main potential sources for subseasonal to seasonal prediction skill in mid latitudes. Mid-latitude extreme weather patterns in winter are often preceded by sudden stratospheric warmings (SSWs), which are the strongest manifestation of the coupling between stratosphere and troposphere. Misrepresentation of the SSW-frequency and stratospheric biases in models can therefore also cause biases in the troposphere.

In this context this work comprises the analysis of four seasonal ensemble experiments with a high-resolution, nonhydrostatic global atmospheric general circulation model in numerical weather prediction mode (ICON-NWP). The main focus thereby lies on the variability and strength of the stratospheric polar vortex. We identified the gravity wave drag parametrisations as one important factor influencing stratospheric dynamics. As the control experiment with default gravity wave drag settings exhibits an overestimated amount of SSWs and a weak stratospheric polar vortex, three sensitivity experiments with adjusted drag parametrisations were generated. Hence, the parametrisations for the non-orographic gravity wave drag and the subgrid‐scale orographic (SSO) drag were chosen with the goal of strengthening the stratospheric polar vortex. Biases to ERA-Interim are reduced with both adjustments, especially in high latitudes. Whereas the positive effect of the reduced non-orographic gravity wave drag is strongest in the mid-stratosphere in winter, the adjusted SSO-scheme primarily affects the troposphere by reducing mean sea level pressure biases in all months. A fourth experiment using both adjustments exhibits improvements in the troposphere and stratosphere. Although the stratospheric polar vortex in winter is strengthened in all sensitivity experiments, it is still simulated too weak compared to ERA-Interim. Further mechanisms causing this weakness are also investigated in this study.

How to cite: Köhler, R., Handorf, D., Jaiser, R., Dethloff, K., Zängl, G., Majewski, D., and Rex, M.: Influence of gravity wave drag parametrisations on the stratospheric circulation of seasonal ICON-NWP experiments, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17139, https://doi.org/10.5194/egusphere-egu2020-17139, 2020.

EGU2020-17338 | Displays | AS1.18

Evaluation of the Quasi-Biennial Oscillation in global climate models for the SPARC QBO-initiative

Andrew Bushell and Francois Lott and the QBOi Exp1+2 Paper Contributors

The Stratosphere-troposphere Processes And their Role in Climate (SPARC) Quasi-Biennial Oscillation initiative (QBOi) seeks to improve confidence in general circulation and earth system model (GCM and ESM) simulations of the QBO, a prominent feature of middle atmosphere tropical variability first identified nearly sixty years ago. Although only five out of 47 models contributing to the Coupled Model Intercomparison Project Phase 5 (CMIP5) had spontaneous QBOs, simulated QBOs are anticipated to be more common among CMIP6 models as more atmospheric GCMs are able to reproduce the phenomenon, both by ensuring adequate vertical resolution in the stratosphere and by parametrizing accelerations due to subgrid nonorographic gravity waves (NOGWs). The complexity of CMIP6 models and their forcing scenarios, however, is an obstacle to using the CMIP6 multimodel ensemble for analysis of modelling uncertainties that are specific to the QBO and its impacts. The QBOi multimodel ensemble represents an alternative approach in which modelling uncertainties related to the QBO are assessed by performing coordinated experiments with atmospheric GCMs that have simplified external forcings and boundary conditions, designed to characterize QBO representation and its response to idealised future climate scenarios. 

Results are presented from an analysis of QBOs in thirteen atmospheric GCMs forced with both observed and annually repeating sea surface temperatures (SSTs). Mean QBO periods in most of these models are close to, though shorter than, the period of 28 months observed in ERA-Interim. Amplitudes are within ±20% of the observed QBO amplitude at 10hPa, but typically about half of that observed at lower altitudes (50 and 70hPa). For almost all models the oscillation's amplitude profile shows an overall upward shift compared to reanalysis and its meridional extent is too narrow. Asymmetry in the duration of eastward and westward phases is reasonably well captured though not all models replicate the observed slowing as the westward shear descends. Westward phases are generally too weak, and most models have an eastward time mean wind bias throughout the depth of the QBO. Intercycle period variability is realistic and in some models is enhanced in the experiment with observed SSTs compared to the experiment with repeated annual cycle SSTs. Mean periods are also sensitive to this difference between SSTs but only when parametrized NOGW sources are coupled to tropospheric parameters and not prescribed with a fixed value. But, overall, modelled QBOs are very similar whether or not the prescribed SSTs vary interannually. A portrait of the overall ensemble performance is provided by a normalised grading of QBO metrics. To simulate a QBO all but one model used parametrized NOGWs, which provided the majority of the total wave forcing at altitudes above 70hPa in most models. Thus the representation of NOGWs either explicitly or through parametrization is still a major uncertainty underlying QBO simulation in these present-day experiments.

 

How to cite: Bushell, A. and Lott, F. and the QBOi Exp1+2 Paper Contributors: Evaluation of the Quasi-Biennial Oscillation in global climate models for the SPARC QBO-initiative, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17338, https://doi.org/10.5194/egusphere-egu2020-17338, 2020.

EGU2020-18795 | Displays | AS1.18

Response of the quasi-biennial oscillation to a warming climate in global climate models

Jadwiga Richter and Francois Lott and the QBOi contributors

We compare the response of the quasi-biennial oscillation (QBO) to a warming climate in eleven atmosphere general circulation models that performed time-slice simulations for present-day, doubled,  and  quadrupled CO2 climates.  No consistency was found among the models for the QBO period response, with the period decreasing by eight months in some models and lengthening by up to thirteen months in others in the doubled CO2  simulations.  In the quadruped CO2 simulations  a reduction in QBO period of 14 months was found in some models, whereas in several others the tropical oscillation no longer resembled the present day QBO, although could still be identified in the deseasonalized zonal mean zonal wind timeseries.  In contrast, all the models projected a decrease in the  QBO amplitude in a warmer climate with the largest relative decrease  near 60 hPa. In simulations with doubled and quadrupled CO2 the multi-model mean QBO amplitudes decreased by 36\% and 51\%, respectively. Across the  models the differences in the QBO period response were most strongly related to how the gravity wave momentum flux entering the stratosphere and tropical vertical residual velocity responded to the increases in CO2 amounts. Likewise it was found that the robust decrease in QBO amplitudes was correlated across the models to changes in vertical residual velocity, parameterized gravity wave momentum fluxes, and to some degree the resolved upward wave flux.  We argue that uncertainty in the representation of the parameterized gravity waves is the most likely cause of the spread among the eleven models in the QBO's response to climate change.

How to cite: Richter, J. and Lott, F. and the QBOi contributors: Response of the quasi-biennial oscillation to a warming climate in global climate models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18795, https://doi.org/10.5194/egusphere-egu2020-18795, 2020.

EGU2020-18870 | Displays | AS1.18

Measurement Study of Turbulence in a Tropopause Fold

Jens Söder, Michael Gerding, and Franz-Josef Lübken

Tropopause folds are known as regions of intense trace gas exchange between the troposphere and the stratosphere. They occur in upper-level fronts and it is known since the 1970s that turbulence plays a major role in their formation. However, only a limited number of turbulence measurements under these conditions exist. In this study, we present a turbulence sounding in an upper-level front measured with the balloon-borne instrument LITOS (Leibniz-Institute Turbulence Observations in the Stratosphere). This instrument infers turbulent kinetic energy dissipation rates from velocity fluctuations at the Taylor microscale. By using a radiosonde on board of the same balloon, we can observe wind fluctuations across multiple spatial scales.

In the classical picture of a tropopause fold from the 1970s, we expect turbulence to occur in both shear zones above and below the tropopause jet. For the time of our measurement on 06 August 2016, a similar turbulence distribution is expected due to low Richardson numbers in the respective areas shown by the ECMWF-IFS. Our in-situ turbulence measurement with LITOS, however, shows a different picture: we find turbulence to occur in the upper shear zone above the jet but not in the lower one located in the stratospheric intrusion. In our contribution, we will examine potential reasons for this difference between theoretical expectations and the observation. Furthermore, we will discuss possible implications of the lack of turbulence in the stratospheric intrusion on the exchange of trace gases across the tropopause.

How to cite: Söder, J., Gerding, M., and Lübken, F.-J.: Measurement Study of Turbulence in a Tropopause Fold, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18870, https://doi.org/10.5194/egusphere-egu2020-18870, 2020.

AS1.21 – Infrasound, acoustic-gravity waves, and atmospheric dynamics

EGU2020-7091 | Displays | AS1.21

The 2010 Haiti Earthquake Disaster: The ShakeMap that could have been...

Shahar Shani-Kadmiel, Gil Averbuch, Pieter Smets, Jelle Assink, and Läslo Evers

When an earthquake occurs, it is important to rapidly assess the severity of the consequences. The distribution of shaking intensity around the epicenter, known as the ShakeMap, is a key component in this process and is crucial for guiding first responders to the region. Whereas earthquake source characteristics, e.g., location and magnitude, can be rapidly determined using distant seismic stations, ground motion measurements from stations in the near-source region are needed to generate an adequate ShakeMap. When few or no seismometers exist in the region, ground motions are only estimated and the ShakeMap can be grossly inaccurate.

Besides seismic waves, earthquakes generate infrasound, i.e., inaudible acoustic waves in the atmosphere. Due to the low frequency nature of infrasound, and facilitated by waveguides in the atmosphere, signals propagate over long ranges with limited attenuation and are detected at ground-based stations. Here we show, that acousto-ShakeMaps, indicating the relative shaking intensity, can be rapidly generated using remotely detected infrasound. We illustrate this with infrasound from the 2010 Mw 7.0 Port-au-Prince, Haiti earthquake, detected in Bermuda, over 1700 km away from Haiti.

Such observations are made possible by: (1) An advanced array processing technique that enables the detection of coherent wavefronts, even when amplitudes are below the noise level, and (2) A backprojection technique that maps infrasound detections in time to their origin on the Earth's surface.

Infrasound measurements are conducted globally for the verification of the Comprehensive Nuclear-Test-Ban Treaty and together with regional infrasound networks allow for an unprecedented global coverage. This makes infrasound as an earthquake disaster mitigation technique feasible for the first time.

How to cite: Shani-Kadmiel, S., Averbuch, G., Smets, P., Assink, J., and Evers, L.: The 2010 Haiti Earthquake Disaster: The ShakeMap that could have been..., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7091, https://doi.org/10.5194/egusphere-egu2020-7091, 2020.

EGU2020-7484 | Displays | AS1.21

Seismo-acoustic ground coupling: Wave types, transfer efficiency, and near-surface structure

Florian Fuchs, Artemii Novoselov, and Götz Bokelmann

Pressure perturbations such as e.g. impulsive acoustic waves can couple into solid earth through the long-known phenomenom of seismo-acoustic coupling. Yet, the associated mechanisms are not always clear. Most studies investigate seismo-acoustic through low-frequency and high amplitude signals generated by e.g. natural or man-made explosions.

We conducted a small-scale field experiment with firecrackers as acoustic sources and hundred 3-component nodal geophones as receivers in a 20m diameter ring layout, some of them co-located with seismically decoupled Hyperion IFS-5111 infrasound sensors. This allowed us to investigate seismo-acousting coupling for higher frequencies and very small (meter scale) offsets.

The large receiver density enabled us to observe and distinguish different wave types induced by acoustic sources, including direct air waves, air-coupled Rayleigh waves, and possibly slow Biot waves. Having co-located seismic and pressure sensors additionally allowed us to investigate the coupling efficiency, which is in the order of 10-7 and thus similar to many of the low-frequency and large-offset studies. Furthermore, we can deduct soil properties such as rigidity, bulk modulus, and density from the co-located sensors, and efficiently infer near-surface (soil) properties using cheap acoustic sources.

How to cite: Fuchs, F., Novoselov, A., and Bokelmann, G.: Seismo-acoustic ground coupling: Wave types, transfer efficiency, and near-surface structure, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7484, https://doi.org/10.5194/egusphere-egu2020-7484, 2020.

EGU2020-3290 | Displays | AS1.21

Global Monitoring and Characterization of Infrasound Signatures by Large Fireballs

Christoph Pilger, Peter Gaebler, Patrick Hupe, Theresa Ott, and Esther Drolshagen

Large meteoroids can be registered in infrasound recordings during their entry into the Earth’s atmosphere. A comprehensive study of 10 large fireball events of the years 2018 and 2019 highlights their detection and characterization using global infrasound arrays of the International Monitoring System (IMS) of the Comprehensive Nuclear-Test-Ban Treaty (CTBT). The study focuses on the observation and event analysis of the fireballs to estimate their respective location, yield, trajectory, and entry behavior. Signal characteristics are derived by applying the Progressive Multi-Channel Correlation method as an array technique. The comparison of the events with a NASA reference database as well as the application of atmospheric propagation modeling allows to draw conclusions about infrasound-based detection capability, localization accuracy, yield estimation, and source characterization. The infrasound technique provides a time- and location-independent remote monitoring opportunity of impacting near-Earth objects (NEOs), either independent or complementary to other fireball observation methods. Additionally, insights about the detection and localization capability of IMS infrasound stations can be gained from using large fireballs as reference events, being of importance for the continuous monitoring and verification of atmospheric explosions in a CTBT context.

How to cite: Pilger, C., Gaebler, P., Hupe, P., Ott, T., and Drolshagen, E.: Global Monitoring and Characterization of Infrasound Signatures by Large Fireballs, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3290, https://doi.org/10.5194/egusphere-egu2020-3290, 2020.

EGU2020-20165 | Displays | AS1.21

The 2019 July Stromboli volcano paroxysm event: contribution of infrasound to the Volcanic Ash Advisory Centers

Emanuele Marchetti, Maurizio Ripepe, Alexis Le Pichon, Constantino Listowski, Lars Ceranna, Patrick Hupe, Christoph Pilger, Sandro Matos, Nicolau Wallenstein, Pierrick Mialle, and Philippe Hereil

With the advent of civil aviation and growth in air traffic, the problem of volcanic ash encounter has become an issue of importance as a prompt response to volcanic eruptions is required to mitigate the impact of the volcanic hazard on aviation. Many volcanoes worldwide are poorly monitored, and most of the time notifications of volcanic eruptions are reported mainly based on satellite observations or visual observations. Among ground-based volcano monitoring techniques, infrasound is the only one capable of detecting explosive eruptions from distances of thousands of kilometers. On July 3 and August 28, 2019, two paroxysmal explosions occurred at Stromboli volcano. The events, that are similar in terms of energy and size to the peak explosive activity reported historically for the volcano, produced a significant emission of scoria, bombs and lapilli, that affected the whole island and fed an eruptive column that rose almost 5 km above the volcano. The collapse of the eruptive column also produced pyroclastic flows along the Sciara del Fuoco, a sector collapse on the northern flank of the volcano.

Being one of the best-monitored volcanoes of the world, the 2019 Stromboli paroxysmal explosions were observed in real-time and Civil Protection procedures started immediately. However, notification to the Toulouse Volcanic Ash Advisory Centre (VAAC) was not automated, and the VAA was issued only long after the event occurrence. The two explosions produced infrasound signals that were detected by several infrasound stations as far as Norway (IS37, 3380 km) and Azores islands (IS42, 3530 km). Despite of the latency due to the propagation time, infrasound-based notification arrays precedes the Volcanic Ash Advisories (VAAs) issued by Toulouse VACC. Following the same procedure applied for the Volcano Information System developed in the framework of the ARISE project, we show how infrasound array analysis could allow automatic, near-real-time identification of these eruptions with timely reliable source information. We highlight the need for an integration of the CTBT IMS infrasound network with local and regional infrasound arrays capable of providing a timely early warning to VAACs. This study opens new perspectives in volcano monitoring and could represent, in the future, an efficient tool in supporting VAACs activity.

How to cite: Marchetti, E., Ripepe, M., Le Pichon, A., Listowski, C., Ceranna, L., Hupe, P., Pilger, C., Matos, S., Wallenstein, N., Mialle, P., and Hereil, P.: The 2019 July Stromboli volcano paroxysm event: contribution of infrasound to the Volcanic Ash Advisory Centers, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20165, https://doi.org/10.5194/egusphere-egu2020-20165, 2020.

EGU2020-18581 | Displays | AS1.21

Modelling infrasonic ocean ambient noise using NWP and lidar observations in southern Argentina

Lars Ceranna, Patrick Hupe, Marine de Carlo, and Alexis Le Pichon

In routine processing of infrasound data of the International Monitoring System, coherent ocean ambient noise with dominant frequencies ranging from 0.1 to 0.5 Hz appears in overlapping frequency bands. These signals, so-called microbaroms, originate from complex wave interactions. In this study, microbarom detections are used as calibration signals, and their amplitudes at the Argentinian infrasound station IS02 are modelled based on operational ocean wave interaction simulations and a semi-empirical attenuation relation. This relation strongly depends on the middle atmosphere (MA) dynamics. Previous studies have shown that the MA wind and temperature are not properly resolved in numerical weather prediction (NWP) models. Therefore, high-resolution soundings of the Compact Rayleigh Autonomous Lidar (CORAL) are incorporated in the modelling. The infrasound data are processed using the progressive Multi-Channel Correlation (PMCC) algorithm.

This sensitivity study focuses on one year of collocated infrasound and lidar measurements in southern Argentina. It highlights the seasonal effects of MA uncertainties on infrasound propagation and detections in 2018.

How to cite: Ceranna, L., Hupe, P., de Carlo, M., and Le Pichon, A.: Modelling infrasonic ocean ambient noise using NWP and lidar observations in southern Argentina, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18581, https://doi.org/10.5194/egusphere-egu2020-18581, 2020.

EGU2020-19035 | Displays | AS1.21

Semidiurnal tidal signatures in microbarom infrasound array measurements

Sven Peter Näsholm, Ekaterina Vorobeva, Alexis Le Pichon, Yvan J. Orsolini, Antoine L. Turquet, Robert E. Hibbins, Patrick J. Espy, Marine De Carlo, Jelle D. Assink, and Ismael Vera Rodriguez

Recent studies on infrasonic signatures related to atmospheric tides are mostly focused on stratospherically ducted infrasound or on tidal signatures in recorded infrasound signal power.

In the current work, we address microbarom infrasound ducted by mesosphere-lower thermosphere (MLT) waveguides and the associated infrasound apparent velocity (trace velocity) of arrivals at a ground-based array station in northern Norway.

A hypothesis is that the infrasound apparent velocity – which is related to the incidence angle of the wavefront impinging the station – is linked to the altitude of the final refraction of the infrasound waves. This altitude would be affected by the regional MLT tidal pattern.

We apply specialized beamforming and filtering recipes to highlight the MLT-ducted microbarom arrivals and we find semidiurnal patterns in the infrasound apparent velocity measurements.

How to cite: Näsholm, S. P., Vorobeva, E., Le Pichon, A., Orsolini, Y. J., Turquet, A. L., Hibbins, R. E., Espy, P. J., De Carlo, M., Assink, J. D., and Vera Rodriguez, I.: Semidiurnal tidal signatures in microbarom infrasound array measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19035, https://doi.org/10.5194/egusphere-egu2020-19035, 2020.

EGU2020-17475 | Displays | AS1.21

Global comparison between ocean ambient noise modelling and infrasound network observations

Marine De Carlo, Fabrice Ardhuin, Lars Ceranna, Patrick Hupe, Alexis Le Pichon, and Julien Vergoz

The International Monitoring System (IMS) of the Comprehensive Nuclear-Test-Ban Treaty Organization (CTBTO) may be used to detect atmospheric explosions and events of interest using infrasound technology. However, ambient noise may affect the detection performance of the station network, and particularly ocean noise known as microbarom, as previously shown by characterizing ambient noise through broadband array processing on IMS data. Indeed, ocean wave interactions generate acoustic noise almost continuously. In this study, we use wave action models and include bathymetry and source directivity effects to model the microbarom sources and perform a global comparison between the synthetic signals obtained from two-dimensional spectrum ocean wave products, and observations. With this study, it is expected to enhance the characterization of the ocean-atmosphere coupling and to discriminate the impact of different features to account for in models. In return, better knowledge of microbarom sources allows to better characterize explosive atmospheric events and to provide information about the middle atmosphere dynamics and disturbances that could be used as model constraints

How to cite: De Carlo, M., Ardhuin, F., Ceranna, L., Hupe, P., Le Pichon, A., and Vergoz, J.: Global comparison between ocean ambient noise modelling and infrasound network observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17475, https://doi.org/10.5194/egusphere-egu2020-17475, 2020.

EGU2020-8244 | Displays | AS1.21

Assimilation of atmospheric infrasound data to constrain tropospheric and stratospheric winds

Javier Amezcua, Peter Nasholm, Marten Blixt, and Andrew Charlton-Perez

We use acoustical infrasound from explosions to probe an atmospheric wind component from the ground up to stratospheric altitudes. Planned explosions of old ammunition in Finland generate transient infrasound waves that travel through the atmosphere. These waves are partially reflected back towards the ground from stratospheric levels, and are detected at a receiver station located in northern Norway at 178 km almost due North from the explosion site. The difference between the true horizontal direction towards the source and the back-azimuth direction of the incoming infrasound wave-fronts, in combination with the pulse propagation time, are exploited to provide an estimate of the average cross-wind component in the penetrated atmosphere. 
We perform offline assimilation experiments with an ensemble Kalman filter and these observations, using the ERA5 ensemble reanalysis atmospheric product as background (prior) for the wind at different vertical levels. Information from both sources is combined to obtain analysis (posterior) estimates of cross-winds at different vertical levels of the atmospheric slice between the explosion site and the recording station. The assimilation makes greatest impact at the 12-60 km levels, with some changes with respect to the prior of the order of 0.1-1.0 m/s, which is a magnitude larger than the typical standard deviation of the ERA5 background. The reduction of background variance in the higher levels often reached 2-5%. 
This is the first study demonstrating  techniques to implement assimilation of infrasound data into atmospheric models. It paves the way for further exploration in the use of infrasound  observations (especially natural and continuous sources) to probe the middle atmospheric dynamics and to assimilate these data into atmospheric model products.  

How to cite: Amezcua, J., Nasholm, P., Blixt, M., and Charlton-Perez, A.: Assimilation of atmospheric infrasound data to constrain tropospheric and stratospheric winds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8244, https://doi.org/10.5194/egusphere-egu2020-8244, 2020.

Observations of the ionosphere with the airglow, GPS-TEC, and HF radar techniques reveal a resonance-kind response of the middle and upper atmosphere to broad-band excitation by earthquakes, volcano eruptions, and convective storms. The resonances occur at such frequencies that an atmospheric wave, which is radiated at the ground level and is reflected from a turning point in the middle or upper atmosphere, upon return to the ground level satisfies boundary conditions on the ground. The "buoyancy" resonances (resonances of atmospheric gravity waves) with periods from several minutes and up to several hours arise in addition to well-known "acoustic" resonances with periods of about 3–4 minutes. The buoyancy resonances occur on the gravity branch of the dispersion relation for the acoustic-gravity waves. Infragravity waves in the ocean covering the same frequency band may serve as an efficient source of excitation of the buoyancy resonances. We have obtained dispersion relations for buoyancy resonances earlier. In this paper we investigate the influence of specific propagation characteristics of the gravity waves (their oblique propagation and dissipative attenuation) on conditions of their observation. We use  asymptotic (WKB and ray tracing) methods to investigate relationship between the gravity wave skip distance and the dimensions of typical infragravity wave packets in the oceans and find that conditions can be met for interaction of the same atmospheric wave packet with the same ocean wave packet. The dissipative attenuation eliminates some of the resonance modes, but still many of them remain intact. We use numerical solutions of the full wave equation to confirm results obtained by asymptotic methods. Calculations of this kind demonstrate a possibility of resonance-like behavior of the gravity waves in situations when partial reflections (caused by extrema of the refractive index) appear in addition to the total reflection. Unlike acoustic resonances, buoyancy resonances exhibit high sensitivity to the wind velocity profile and its variations. Non-stationarity of the atmosphere is an important factor limiting possibilities to observe the buoyancy resonances. Nevertheless, relatively low threshold for meeting all other conditions for their appearance and temporal/geographical diversity of the atmosphere makes it still quite probable to see their manifestations. The resonances correspond to most efficient coupling between the atmosphere and its lower boundary and are promising for detection of such coupling.

How to cite: Zabotin, N. and Godin, O.: Propagation factors influencing observations of resonances of atmospheric gravity waves, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3928, https://doi.org/10.5194/egusphere-egu2020-3928, 2020.

In the evening of 5 June 2019, a severe thunderstorm passed through the Netherlands. The storm was so extreme in the westernmost part of the country, that entire tree lines were blown over and tree trunks were severed. In residential communities, this extreme weather event lead to damage to real estate and cars. From preliminary analysis, it follows that the wind gusts that were responsible for the mentioned damage were caused by gravity waves that had been forced by the interaction of the surface weather with a strong inversion layer aloft.
 
In this work, we show a complimentary set of observations that include Doppler Radar and the Dutch microbarometer array network that are operated by the Royal Netherlands Meteorological Institute (KNMI). The radar measurements show wind gusts with speeds of over 125 km/h while the microbarometers measure associated pressure variations up to 8 hPa. The observations are compared with the non-hydrostatic HARMONIE weather forecast model.
 
The use of high-resolution observations and forecast modelling is important for Early Warning Centers that report on such severe weather outbreaks that can be disruptive for society.

How to cite: Assink, J.: Analysis of the severe weather outbreak of 5 June 2019 in The Netherlands, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19433, https://doi.org/10.5194/egusphere-egu2020-19433, 2020.

In the frame of the European H2020 project ARISE, a short wave infrared (SWIR) InGaAs camera has been operated at the Haute-Provence Observatory. This camera allows continuous observations during clear-sky nighttime of the OH airglow layer centered at 87 km. These observations were collocated with Rayleigh lidar measurements providing vertical temperature profiles from the lower stratosphere to the altitude of the OH layer around the mesopause. Spectral analysis of OH images and temperature fluctuations allows us to identify and characterize gravity waves, their activity observed from the OH camera and the lidar, appear to be modified with the presence of a temperature inversion described by this one.

How to cite: Le Du, T.: Gravity wave analysis using OH airglow and Rayleigh lidar at the Haute-Provence observatory, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22232, https://doi.org/10.5194/egusphere-egu2020-22232, 2020.

EGU2020-9822 | Displays | AS1.21

Resolving spatial dynamics at polar latitudes using the GROMOS-C radiometer on Svalbard and the Nordic meteor radar cluster

Gunter Stober, Franziska Schranz, Chris Hall, Alexander Kozlovsky, Mark Lester, Masaki Tsutsumi, Satonori Nozawa, Evgenia Belova, Johan Kero, Klemens Hocke, and Axel Murk

The middle polar atmosphere dynamics is driven by atmospheric waves from the planetary scale to small scale perturbation due to gravity waves. The different atmospheric waves are characterized by their temporal and spatial variability posing challenges to ground-based remote sensing techniques to disentangle and resolve the spatio-temporal ambiguity. Here we present two ground-based remote sensing techniques to resolving spatio-temporal variability at the polar middle atmosphere.

Since 2017 the GROMOS-C radiometer measures ozone and winds at NyÅlesund (78.9°N, 11.9°E) on Svalbard. The radiometer employs four beams in the cardinal directions at 22.5° elevation angle to retrieve ozone profiles and winds at altitudes between 30-75 km. the temporal resolution of the ozone retrievals is 30 minutes. Further, we obtain daily mean winds. Due to the high polar latitude the spatial separation between the beams at stratospheric altitudes covers several degrees in longitude to infer spatial gradients in the ozone densities and their perturbation due to planetary waves.

Another recently established ground-based remote sensing approach to retrieve the spatial characteristic at the mesosphere and lower thermosphere (MLT) is provided by the Nordic meteor radar cluster consisting of the meteor radars at Tromsø, Alta, Esrange, Sodankylä and on Svalbard. Since October 2019 horizontally resolved winds are obtained using a 3DVAR approach with a temporal resolution of 30 minutes and a vertical resolution of 2 km. Here we present preliminary results to infer horizontal wavelength spectra, the tidal variability as well as gravity activity of the winter season 2019/20.

Both datasets are of high value for data assimilation into weather forecast and reanalysis models or for cross-comparisons and validation of meteorological analysis systems (e.g. NAVGEM-HA).

How to cite: Stober, G., Schranz, F., Hall, C., Kozlovsky, A., Lester, M., Tsutsumi, M., Nozawa, S., Belova, E., Kero, J., Hocke, K., and Murk, A.: Resolving spatial dynamics at polar latitudes using the GROMOS-C radiometer on Svalbard and the Nordic meteor radar cluster, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9822, https://doi.org/10.5194/egusphere-egu2020-9822, 2020.

EGU2020-3260 | Displays | AS1.21

Comprehensive comparison of mesospheric wind from Fabry-Perot interferometer and meteor radar at King Sejong Station, Antarctica

Changsup Lee, Geonhwa Jee, Qian Wu, Jeong-Han Kim, Hosik Kam, and Yong Ha Kim

Neutral winds in the mesosphere and lower thermosphere (MLT) have been simultaneously observed by Fabry-Perot interferometer (FPI) and meteor radar (MR) at King Sejong Station (KSS), Antarctica from 2017. Because  the airglow emission height sensitively varies with a solar local time and a season, it is not possible to precisely determine what altitude airglow emission occurs from the traditional assumption of fixed airglow layers. Even though a few previous studies suggested representative heights of airglow emission such as OH band and 557.7 nm line, the true height information of these emission are still unknown. In this study, we try to figure out the temporal dependence of the airglow emissions using the KSS FPI and satellite (SABER/MLS) measurements. We also perform a direct comparison between the FPI and the meteor radar wind measurements considering time-varying airglow emission properties based on a correlation analysis. This study presents how the background wind structure can affect wind estimates from the airglow emissions.

How to cite: Lee, C., Jee, G., Wu, Q., Kim, J.-H., Kam, H., and Kim, Y. H.: Comprehensive comparison of mesospheric wind from Fabry-Perot interferometer and meteor radar at King Sejong Station, Antarctica, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3260, https://doi.org/10.5194/egusphere-egu2020-3260, 2020.

EGU2020-11725 | Displays | AS1.21

Intercomparisons Between Lidar and Satellite Instruments in the Middle Atmosphere

Robin Wing, Alain Hauchecorne, Philippe Keckhut, Sophie Godin-Beekmann, Sergey Khaykin, Milena Martic, Wolfgang Steinbrecht, Thomas J. McGee, John Sullivan, and Emily McCullough

The comparison of ground and ship-based lidar measurements of atmospheric temperature, ozone, and wind to similar measurements made from orbiting satellites is a unique challenge.   In this talk we will discuss general challenges associated with (i) determining coincidence by compensating for geographic and temporal offsets, (ii) satellite-lidar sampling errors, and (iii) comparing results made by different techniques. 

We will show that comparisons of absolute temperature improve when the ground based measurements are compared to a composite satellite profile, created by a weighted average of multiple profiles from one overpass, instead of comparing to the single satellite profile from the closest approach. 

We discuss the importance of including the variation between consecutive satellite profiles for a given overpass in addition to the given satellite instrument uncertainty when calculating the error budget of the comparisons, even when comparing to single satellite profiles. 

We demonstrate how comparing lidar and satellite measurements of events such as small-scale fast moving gravity waves over a particular geographic region can be affected by instrument averaging kernels.

Illustrative examples we will be showing include lidar measurements made during recent instrument validation campaigns at L’Observatoire de Haute Provence (OHP, 43.93 N, 5.71 E), La Réunion (21.17 S, 55.37 E), Hohenpeißenberg Meteorological Observatory (47.80 N, 11.00 E), and onboard the French Navy Research Ship Monge as well as satellite measurements from  the Microwave Limb Sounder (MLS), the Sounding of the Atmosphere by Broadband Emission Radiometry instrument (SABER), Global Ozone Monitoring by Occultation of Stars (GOMOS), and Atmospheric Dynamics Mission Aeolus (Aeolus).

How to cite: Wing, R., Hauchecorne, A., Keckhut, P., Godin-Beekmann, S., Khaykin, S., Martic, M., Steinbrecht, W., McGee, T. J., Sullivan, J., and McCullough, E.: Intercomparisons Between Lidar and Satellite Instruments in the Middle Atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11725, https://doi.org/10.5194/egusphere-egu2020-11725, 2020.

The dynamics of the middle atmosphere, between near ground lower troposphere and near Earth space thermosphere is submitted to strong disturbances which impact global circulation and are at the origin of uncertainties in climate and weather models. The lack of observations limits the ability to accurately reproduce these disturbances, while the considered altitude range increases for improving model predictions. Perturbations also affect climate change and environment hazards. ARISE (Atmospheric dynamics Research InfraStructure in Europe) objective is to develop a high resolution platform integrating the infrasound International Monitoring System for the verification of the Comprehensive nuclear-Test-Ban Treaty , the lidar Network for Detection of Atmospheric Composition Changes, associated with multi-instrument reference stations and satellite observations. The research is highly multidisciplinary to cover the full altitude range from polar to equatorial regions submitted to different processes. The main project results and perspectives will be presented. This concern the development of a pilot station for developing synergies, prototypes for improving instrument performances, new tools for applications related to weather and climate using both archived data for applications and near real time data, remote monitoring of extreme events such as volcanoes for civil aviation, stratospheric warming events, severe weather, meteo-tsunamis and meteorites for risk management.

How to cite: Blanc, E.: Dynamics of the middle atmosphere as observed by the ARISE project: scientific highlights and perspectives, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19524, https://doi.org/10.5194/egusphere-egu2020-19524, 2020.

EGU2020-446 | Displays | AS1.21

Identitification and tracking of storms via infrasound detections

Marcell Pásztor, Csenge Czanik, and István Bondár

One of the various sources of infrasound signals are lightnings in storms. These moving sources can be detected and tracked at infrasound arrays. We correlate lightning data from Blitzortung with the infrasound detections from the Hungarian infrasound station at Piszkes-teto (PSZI) that has been collecting data since May, 2017. The objective of this study is to track storms and to test the station's capability to detect thunderstorm signals. We invetsigate what conditions affect these detections; in what directions, distances and accuracy can we track storms. We also look at how various noise conditions influence the detection capability of the array.

How to cite: Pásztor, M., Czanik, C., and Bondár, I.: Identitification and tracking of storms via infrasound detections, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-446, https://doi.org/10.5194/egusphere-egu2020-446, 2020.

EGU2020-1610 | Displays | AS1.21

Global gravity wave detections at infrasound stations of the International Monitoring System

Patrick Hupe, Lars Ceranna, and Alexis Le Pichon

Atmospheric gravity waves (GWs) transport energy and momentum horizontally and vertically. The dissipation of GWs can modify the atmospheric circulation at different altitude layers. Knowledge about the occurrence of GWs is thus essential for Numerical Weather Prediction (NWP). However, uniform networks for global GW measurements are rare, and satellite observations generally allow to derive GW parameters in the middle and upper atmosphere only. The barometric sensors of the International Monitoring System (IMS) infrasound network can potentially fill this gap of global GW observations at the Earth’s surface. This infrasound network has been established for monitoring the atmosphere to verify compliance with the Comprehensive Nuclear-Test-Ban Treaty.
Two alternative configurations of the Progressive Multi-Channel Correlation Method (PMCC) are discussed for deriving GW detections from the differential pressure data. These configurations focus on GW frequencies equivalent to periods of between 5 min and 150 min. This range covers sources of deep convection, particularly in the tropics, whereas at mid-latitudes, GWs are hard to distinguish from other low-frequency signals, e.g. coherent wind noise. Challenges and perspectives of using the IMS infrasound data for deriving ground-based GW parameters useful for NWP will be discussed.

How to cite: Hupe, P., Ceranna, L., and Le Pichon, A.: Global gravity wave detections at infrasound stations of the International Monitoring System, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1610, https://doi.org/10.5194/egusphere-egu2020-1610, 2020.

Direct excitation of acoustic normal modes in horizontally stratified oceanic waveguides is negligible even for shallow earthquakes because of the disparity between velocities of seismic waves and the sound speed in the water column. T-phases, which propagate at the speed of sound in water, are often reported to originate in the open ocean in the vicinity of the epicenter of an underwater earthquake, even in the absence of prominent bathymetric features or significant seafloor roughness. This paper aims to evaluate the contribution of scattering by hydrodynamic waves into generation of abyssal T-waves. Ocean is modeled as a range-independent waveguide with superimposed volume inhomogeneities due to internal gravity waves and surface roughness due to wind waves and sea swell. Guided acoustic waves are excited by volume and surface scattering of ballistic body waves. The surface scattering mechanism is shown to explain key observational features of abyssal T-waves, including their ubiquity, low-frequency cutoff, presence on seafloor sensors, and weak dependence on the earthquake focus depth. On the other hand, volume scattering due to internal gravity waves proves to be ineffective in coupling the seismic sources to T-waves. The theory is extended to explore a possible role that scattering by gravity waves may play in excitation of infrasonic normal modes of tropospheric and stratospheric waveguides by underwater earthquakes. Model predictions are compared to observations [L. G. Evers, D. Brown, K. D. Heaney, J. D. Assink, P. S. M. Smets, and M. Snellen (2014), Geophys. Res. Lett., 41, 1644–1650] of infrasonic signals generated by the 2004 Macquarie Ridge earthquake.

How to cite: Godin, O.: Gravity waves as a mechanism of coupling oceanic and atmospheric acoustic waveguides to seismic sources, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1782, https://doi.org/10.5194/egusphere-egu2020-1782, 2020.

EGU2020-2582 | Displays | AS1.21

Short-duration infrasound signals observed at the array PVCI

Tereza Sindelarova, Csenge Czanik, Michal Kozubek, Katerina Podolska, Jiri Base, and Dan Kouba

We present the most interesting cases from observations of short-duration infrasound signals at the array PVCI (50.53°N 14.57°E).  The array is equipped with three sensors and it has an aperture of 200 m. The optimum detection range of the array is 0.02-4 Hz.

On 24 August 2016 at 01:36:32 UTC, a strong earthquake occurred in Central Italy; the epicentre was located at 42.75°N and 13.22°E. The azimuth from PVCI to the epicentre was 187° and the distance was 871 km. At 02:23-02:40 UTC, signals from the azimuths around 195° were recorded at the array. The time interval corresponds to the expected stratospheric signal arrival.

On 3 March 2016 at 21:51-21:53 UTC, PVCI registered signal from the azimuth of 199°. The signal elevation was 30-35°. We assume that the signal source was the bolide EN060316 that entered the atmosphere above Upper Austria and Bavaria. 

Two large accidental explosions occurred in the region recently; both of them were recorded by PVCI and other member stations of the CEEIN network. On 26-27 September 2017, an ammunition depot exploded in Kalynivka, Central Ukraine. Signals from the azimuths of 85-90° were recorded on 26 September 2017 at 21:02-21:05 UTC and at 23:16-23:21 UTC. On 1 September 2018 around 03:15 UTC, an explosion occurred in the refinery near Ingolstadt, Germany. A high amplitude signal arrived at PVCI at 03:30:48 UTC from the azimuth of 243°.

How to cite: Sindelarova, T., Czanik, C., Kozubek, M., Podolska, K., Base, J., and Kouba, D.: Short-duration infrasound signals observed at the array PVCI, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2582, https://doi.org/10.5194/egusphere-egu2020-2582, 2020.

Large aperture array of absolute micro‑barometers located in Western Czechia was used to register distinct infrasound pulses generated by thunderstorm activity. Only cases with a sufficient signal-to-noise ratio on all four micro‑barometers were selected for further processing. Using data from the European lightning detection network and electric field monitor, a corresponding flash was assigned to each set of signals. The position of the infrasound source was calculated from the time delay of signal arrival, assuming propagation of spherical waves from the source. The calculation includes changes in sound speed as a function of temperature variation with altitude. Wind speed value and its variance is also taken into account to estimate the uncertainties. The calculated vertical positions of the infrasound sources are located at the altitudes between 3‑6 km. The horizontal position for most of the selected cases corresponds to the horizontal position of the flash specified by lightning detection network. The recorded infrasound signals followed only intracloud (IC) or mixed (multiple IC+CG) lightning strokes. Thus, the sources of the analyzed infrasound events are most likely IC discharges.

How to cite: Rusz, J., Chum, J., and Baše, J.: Determining the position of the of thunder infrasound source using a large aperture micro barometer array, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2641, https://doi.org/10.5194/egusphere-egu2020-2641, 2020.

The mobile Infrasound Array of the Austrian National Data Centerwhich is a part of the Central and Eastern European Infrasound Network (CEEIN) was installed in a location south of Vienna in April 2019. There data will be collected till April 2020 and the analysis will be conducted using dtkGPMCC-Software which is included in the NDC-in-a-Box-Paketand provided by the Comprehensive Treaty Test Ban Organisation (CTBTO). Several challenges occurred due to the power supply with a fuel cell. After constant problems an upgrade was initialized in July 2019. Results of the analysis since beginning of deployment will be shown in the presentation. Detected signals will be compared both with ground truth information and with observations collected by other Infrasound-stations of CEEIN and IMS-station IS26 located in Germany. 

 

How to cite: Mitterbauer, U.: Running a temporary mobile Infrasound Array in Austria: Challenges and Detections, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22078, https://doi.org/10.5194/egusphere-egu2020-22078, 2020.

The monitoring network of the Kazakhstani Institute of Geophysical Researches includes seismic and infrasound arrays. The PMCC method helps identifying microseisms in seismic records and microbaroms in infrasound records effectively. Simulation of the microbarom strength, propagation path and signal attenuation are well developed for the moment, and for microseisms as well. However, the bathymetry effect on the source intensity shall be taken into account to model microseisms.

Results of the source parameter simulations and microbaroms and microseisms detections are compared at 7 Kazakhstani seismic and infrasound arrays. These comparisons are also carried out between collocated seismic and infrasound arrays. Similarities and differences between the reconstructed source regions of microseisms and microbaroms are discussed. Beside this study, the advantages of integrating the infrasound and seismic methods have been shown for studying seismoacoustic signals from severe storms.

How to cite: Smirnov, A. and Le Pichon, A.: Similarities and differences of microseism and microbarom source regions reconstructed from the seismo-acoustic Kazakhstani network, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2965, https://doi.org/10.5194/egusphere-egu2020-2965, 2020.

EGU2020-19317 | Displays | AS1.21

Evaluating microbarom source models using infrasound recorded on a stratospheric balloon

Alexis Le Pichon, Marine De Carlo, Daniel Bowman, and Fabrice Ardhuin

The global International Monitoring System (IMS) network continuously detects coherent ambient infrasound noise between 0.1 and 0.5 Hz. This noise, referred to as microbaroms, is generated by second order non-linear interaction of ocean waves. Various source models have been developed in earlier works; e.g. Brekhovskikh et al. (1973) and Ardhuin & Herbers (2013) who considered a source directivity effect in infinite depth ocean, and Waxler (2007) who investigated the radiation model in finite depth ocean from monopolar sources. De Carlo et al. (2020) proposed a two-dimensional energy spectrum ocean wave model accounting for bathymetry and source directivity effects. First comparisons between the observed and modelled directional microbarom amplitudes at IMS infrasound stations show first order agreement. In order to further evaluate these models, microbarom observations from the Carolina Infrasound secondary payload on board the NASA Ultra Long Duration Balloon flight in 2016 (Bowman and Lees, 2018), that flew over spatially extended microbarom source regions along the Antarctic Circumpolar Current, are compared with the modelled source energy flux. The simulated source strength power spectrum is integrated over an extended source region beneath the balloon and compared with the observed one. The relative importance of modelled source parameters (e.g. bathymetry, launching ray parameters) is assessed. In this presentation, we describe the infrasound observations on the balloon and the supporting microbarom source models, and discuss the implications of these results on the remote estimation of the acoustic energy flux from the ocean surface to the upper atmosphere.

How to cite: Le Pichon, A., De Carlo, M., Bowman, D., and Ardhuin, F.: Evaluating microbarom source models using infrasound recorded on a stratospheric balloon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19317, https://doi.org/10.5194/egusphere-egu2020-19317, 2020.

EGU2020-10156 | Displays | AS1.21

Location of Stromboli volcano July 2019 paroxysm event based on long-range infrasound detections in several IMS stations

Sandro Matos, Nicolau Wallenstein, Emanuele Marchetti, and Maurizio Ripepe

Stromboli is one of the most active volcanoes on Earth with a continuous explosive activity and persistent degassing since at least 3-7 AD (Rossi et al., 2000). Being an open conduit volcano, its spectacular basaltic explosions interspersed by lava fountains occurring every ≈10 minutes (Ripepe et al., 2002) make it probably the world's best-know and best-monitored volcano.

On 3rd July 2019 at the 14:45:43 UTC a paroxysmal explosion occurred with an ash column that rose almost 5 km above the volcano. This very strong explosive event was detected in several IMS infrasound stations, including IS42, located in the Azores islands in the middle of the North-Atlantic, at a distance of about 3,700 km.

We present the long-range infrasound detections that allowed us to locate the source based only in infrasound with an estimated error of less than 55 km from the ground truth event.

Keywords: Stromboli volcano, paroxysm, infrasound, IMS, IS42

How to cite: Matos, S., Wallenstein, N., Marchetti, E., and Ripepe, M.: Location of Stromboli volcano July 2019 paroxysm event based on long-range infrasound detections in several IMS stations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10156, https://doi.org/10.5194/egusphere-egu2020-10156, 2020.

EGU2020-5360 | Displays | AS1.21

On the infrasound array monitoring in Romania: reprocessing of the data recorded by the national infrasound network

Daniela Ghica, Mihaela Popa, and Constantin Ionescu

We present the results of the reprocessing a 10-year archive of waveform data recorded with the Romanian infrasound network, by using PMCC signal detector. Starting with 2009, three infrasound stations have been deployed on the Romanian territory by the National Institute for Earth Physics (NIEP): IPLOR 6-element array of 2.5 km aperture, in the central part of the country, BURARI 4-element research array of 1.2 km aperture, in the northern Romania, under the cooperation with Air Force Technical Application Center AFTAC (USA), and I67RO – a temporary PTS portable 4-element array of 0.9 km aperture, in western Romania, for two-year experiment (2016-2018), within a collaboration project with PTS/CTBTO. In 2019, BURARI station has been upgraded to 6-element array with a 0.7 km aperture.

Infrasound data are processed and analyzed on routinely basis at NIEP by using a duo of infrasound detection-oriented software – DTK-GPMCC and DTK-DIVA – packaged into CTBTO NDC-in-a-Box. Since October 2019, a new implementation of PMCC algorithm is available at NIEP, enabling the characterization of the coherent infrasound field in log-spaced frequency with one-third octave bands from 0.1 to 7 Hz. The full data set recorded with the Romanian infrasound stations has been reprocessed by applying the new PMCC algorithm.

The array monitoring performance resulted after the data reprocessing is investigated. Detection capability assessment, types of sources observed, as well the capacity of fusing the detections into support of understanding various infragenic sources are presented. A better characterization of the detected signals in the frequency-azimuth space or frequency trace-velocity space is clearly observed. Infrasonic signals generated by several relevant sources detected with the three arrays deployed on the Romanian territory are shown.

How to cite: Ghica, D., Popa, M., and Ionescu, C.: On the infrasound array monitoring in Romania: reprocessing of the data recorded by the national infrasound network, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5360, https://doi.org/10.5194/egusphere-egu2020-5360, 2020.

EGU2020-3895 | Displays | AS1.21

The Infrasound Network of Ukraine

Oleksandr Liashchuk, Yevhenii Kariahin, Leonid Kolesnykov, Yurii Andrushchenko, Ivan Tolchonov, and Anatolii Poikhalo

Geophysical monitoring observations in Ukraine are performed by the Main Center of Special Monitoring (MCSM), which is a part of the National Space Facilities Control and Test Center, State Space Agency of Ukraine. The MCSM ensures the implementation of the Ukrainian international obligations within the CTBT. It also provides prompt warning and response to emergencies, based on geophysical monitoring results, and runs continuous complex geophysical observations for scientific purposes. 

Infrasound monitoring is one of the types of geophysical monitoring, performed by the MCSM. The infrasound network of Ukraine consists of three observatories, which include mini-arrays of microbarographs (3-4 microbarographs). Standard geometric configuration for an array is a triangle. The aperture of arrays ranges between 200 and 900 meters. There are also three separate observation points, with the only one microbarograph in each. The spacing between these points is hundreds of kilometers. The entire infrasound network is in North-Western Ukraine. One more Ukrainian observatory based in the Antarctic, the Vernadsky Research Base. All microbarographs equipped with wind-protection systems. Microbarographs from the Soviet K-304 acoustic station (0.03-10 Hz, 100 Pa) are currently used in combination with a 4-channel 24-bit digitizer. Besides, Ukraine has created new models of microbarographs with similar technical characteristics. The scheduled upgrade of the sensors is currently underway. There are also plans for installing infrasound arrays in the Eastern and Southern Ukraine. Furthermore, for assessing the possibility of recording large-scale processes in the atmosphere, the pilot plant of the microbarographs on the seismic array nodes PS45 is scheduled for this year. In this case, the distance between the elements of the infrasound array will be around 3-4 kilometers.

Previously mentioned infrasound arrays recorded a wide range of technogenic and natural phenomena, which could be of interest to the scientific community. Among the technogenic ones are explosions at the military arsenals, gas pipeline explosions, plane crashes, and an enormous number of mining blasts. Infrasound signals have also been caused by natural events such as earthquakes, tsunamis, avalanches, hurricanes, thunderstorms, meteorite explosions.

Infrasound data is transmitted to the NDC for processing and storing, using the SeedLink protocol. Registration of the events and events-bulletin is done by an operational on-duty team 24/7. The government authorities responsible for safety are notified immediately in case of emergency events. Data processing realized by using Geotool and WinPMCC, as well as the own software. It also used data from the foreign infrasound arrays for analysis. The Memorandum with the Central and East European Infrasound Network was signed in 2019. For optimizing the on-duty team's, geophysicists-analysts', and experts' work, processing of the infrasound data in the MCSM, as an experiment, has been transferred to the internal MCSM cloud platform. It facilitated access to the information, provided equal opportunities for the processing, and allowed involving experts from other institutions. 

In the future, all of the above allows actively using the infrasound network of Ukraine for running global and regional monitoring and doing researches on the atmosphere and climate.

How to cite: Liashchuk, O., Kariahin, Y., Kolesnykov, L., Andrushchenko, Y., Tolchonov, I., and Poikhalo, A.: The Infrasound Network of Ukraine, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3895, https://doi.org/10.5194/egusphere-egu2020-3895, 2020.

Over the past two decades the German Aerospace Center (DLR) facility near Heilbronn, Germany, has conducted a considerable number of tests of the ARIANE-5 main engine. Infrasound signals from many of these tests (~40%) have been observed at IMS station IS26 at a distance of about 320 km in an easterly direction (99° east-southeast from North). Due to the prevailing weather pattern in Central Europe, nearly all detected tests occurred during the winter months from October to April, when the stratospheric wind points in an eastern direction, while it reverses during the summer season. Except for a single event in May 2012, the summer months (May through September) did not yield any infrasound signal detections from the engine tests. On the other hand, not all tests conducted in winter are observed either, while detection in the spring and fall equinox months of April and October must be considered to occur incidentally.
 
The large database of about 160 engine tests enables us to assess how well propagation modelling based on a standard atmospheric specification such as the ECMWF forecast model conforms with observed detections and non-detections.  While reversal of the stratospheric wind pattern in the summer season eliminates the stratospheric duct towards the eastern direction, the case of non-detections in the winter season may be of a more subtle nature. Besides increases in background noise levels due to heavy winds at the station, the fine structure of the stratospheric duct in the atmospheric model should determine the detection capability at IS26, which could be located inside or outside a shadow zone at a specific time. Ultimately, the standard atmospheric model used may not be an accurate description of the atmosphere in such cases either. This work on a controlled ground truth infrasound source will thus increase our understanding on the relationship between infrasound detection capabilities and atmospheric specifications over the seasons.

How to cite: Koch, K. and Pilger, C.: Infrasound signals from a ground-truth source and implications from atmospheric models: ARIANE engine tests in Southern Germany revisited, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9344, https://doi.org/10.5194/egusphere-egu2020-9344, 2020.

EGU2020-13599 | Displays | AS1.21

Infrasound from the North Korea underground explosion and subsequent collapse on 3 September 2017

Il-Young Che, Keehoon Kim, and Alexis Le Pichon

Strong ground motions induced by North Korea’s declared underground nuclear test in September 2017 and a subsequent subsurface collapse excited substantial and characteristic atmospheric acoustic waves (infrasound) that were detected by multiple stations at regional distances. Back-projection method is applied to the detected long-lasting coherent infrasound wavetrains related to the nuclear test. This allows to reconstruct source locations and reveals ground-to-air coupling in a large area over the northeast Korean Peninsula. To understand the excitation of atmospheric acoustic phases from the underground sources, full 3-D seismo-acoustic simulations are performed with pre-defined seismic moment tensor solutions of the underground sources. The simulations quantitatively predict the excitation of epicentral and diffracted acoustic phases developed by direct vertical ground motion at the immediate epicenter and by seismic surface waves propagating through high mountainous regions, respectively. In the atmosphere, the direct acoustic phases propagate spherically at the speed of sound, but the diffracted phases form inclined wavefronts in the atmosphere as the surface wave moves away from the epicenter. On a broad scale, the simulated acoustic coupling shows good agreement with the infrasound radiation patterns determined from the infrasound observations. Additional simulations for the subsequent subsurface collapse event show that an underground cavity collapse can be a potential mechanism for the production of low-frequency acoustic energy that is also detectable at regional distances. Finally, this study highlights the link between ground motions caused by underground sources and infrasound detection, further enabling infrasound as a depth discriminant for subsurface sources.

How to cite: Che, I.-Y., Kim, K., and Le Pichon, A.: Infrasound from the North Korea underground explosion and subsequent collapse on 3 September 2017, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13599, https://doi.org/10.5194/egusphere-egu2020-13599, 2020.

EGU2020-5055 | Displays | AS1.21

Polar Mesosphere Winter Echoes and their relation to infrasound

Evgenia Belova, Johan Kero, Sven Peter Näsholm, Ekaterina Vorobeva, Oleg A. Godin, and Victoria Barabash

Polar Mesosphere Winter Echoes (PMWE) are radar echoes that originate from the mesosphere at 50-80 km altitude and are observed with VHF radars during equinox and winter seasons. Strong PMWE are relatively rare phenomena, in most cases they are observed when the lower ionosphere displays high ionisation. Interpretations of observational results concerning PMWE are controversial and the origin of the echoes is still under debate. Especially intriguing is that in some cases of strong PMWE, the measured horizontal speeds of the radar reflecting structures can exceed 300 m/s. Radar reflection (scattering) by infrasound waves at frequencies below about 2 Hz was suggested in order to explain these observations. We will give recent examples of PMWE events of high horizontal speed as observed with the 52 MHz MST radar (ESRAD) located at Esrange (68°N, 21ºE) in northern Sweden. Together with this we will analyse infrasound measurements made at ground-based stations near Kiruna (67.5°N, 20.13ºE) and at the infrasound station IS37 (69°N, 18ºE) in Norway during these events. We discuss prospective relations between PMWE and the microbaroms that are generated by ocean swell in the North Atlantic.

How to cite: Belova, E., Kero, J., Näsholm, S. P., Vorobeva, E., Godin, O. A., and Barabash, V.: Polar Mesosphere Winter Echoes and their relation to infrasound, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5055, https://doi.org/10.5194/egusphere-egu2020-5055, 2020.

EGU2020-20269 | Displays | AS1.21

Climatology reflected by infrasound travel-times sampling the stratosphere in its transition between summer and winter

Ismael Vera Rodriguez, Sven Peter Näsholm, Antoine L. Turquet, and Läslo G. Evers

Like seismic waves traveling through the solid earth, infrasound waves traveling through the atmosphere are also sensitive to the medium properties – in particular to temperature and wind. The exploitation of this information is particularly interesting in regions and altitude ranges where other
measurements are sparse. In this work, we look at the climatology from first-arrival travel-times using a dataset of infrasound observations from northern Scandinavia, this is, in the context of stratospheric temperatures.

The same dataset has recently been exploited to estimate tropospheric and stratospheric cross-winds. This dataset spans 30 years and corresponds to explosions that are due to the destruction of ammunition at a military site in Finland conducted over the months of August and September; hence, it
covers the period of transition from summer to winter stratosphere. The transition between summer and winter stratosphere is clear in the data. However, a significant travel-time variation between years produces inconclusive results when inferring stratospheric temperature trends over the 30 years analyzed. Still, when comparing the travel-times against regional stratospheric temperatures represented in atmospheric re-analysis models, there is a correspondence between models and infrasound data.

How to cite: Vera Rodriguez, I., Näsholm, S. P., Turquet, A. L., and Evers, L. G.: Climatology reflected by infrasound travel-times sampling the stratosphere in its transition between summer and winter, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20269, https://doi.org/10.5194/egusphere-egu2020-20269, 2020.

EGU2020-10128 | Displays | AS1.21

Wind estimates in the mesosphere - lower thermosphere retrieved from infrasound data

Ekaterina Vorobeva, Sven Peter Näsholm, Patrick Espy, Yvan Orsolini, and Robert Hibbins

We analyze dataset of infrasound observations from surface military explosions in northern Finland which occur yearly in August and September since 1988. The transient nature of these events allows for identification of returns reflected (or scattered) both from stratospheric and from mesospheric - lower thermospheric (MLT) altitudes. The  infrasound data were recorded at Norwegian infrasound-array station around 200 km north of the explosion site. In this study, we use the measured travel-time and backazimuth deviation of the arriving infrasound wavefronts to estimate snapshots of the MLT cross-wind averaged along the propagation path. The spatial extent of that averaging process is explored, and the MLT wind estimates retrieved from infrasound data are presented and compared against high-top atmospheric model winds.

How to cite: Vorobeva, E., Näsholm, S. P., Espy, P., Orsolini, Y., and Hibbins, R.: Wind estimates in the mesosphere - lower thermosphere retrieved from infrasound data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10128, https://doi.org/10.5194/egusphere-egu2020-10128, 2020.

The atmosphere and ionosphere are a complex dynamic system, which is affected by sources, caused both by internal processes and external ones. It is known that atmospheric waves propagating from the troposphere to the upper atmosphere make a significant contribution to the state of this system. One of the regular sources of such waves are various tropospheric disturbances caused, for example, by meteorological processes. Numerical modeling is an effective tool for studying these processes and the effects they cause. However, a number of problems arise, while setting up numerical experiments. The first is that most atmospheric models use hydrostatic approximation (which does not allow the resolution of small-scale perturbations) and work for a limited range of heights (which does not allow studying the relationship between the lower and upper atmosphere). This demands an accurate selection of the model in accordance with the stated research goals. The second problem is the difficulty of direct definition of the wave tropospheric sources, that was mentioned before, due to the lack of experimental information for their detailed description. The authors proposed, researched and tested a way to solve this problem. It was shown that the solution of the problem of waves propagation from a certain tropospheric source is completely determined by the pressure field at the surface of the Earth. This work is devoted to solving various problems using this approach.

This study presents the results of calculations of the propagation of infrasound and internal gravity waves from tropospheric disturbances given by pressure variations at the surface of the Earth. The experimental data associated with various meteorological events and the passage of the solar terminator were obtained both directly - by a network of microbarographs in the studied region, and indirectly - based on the data from the LIDAR signal intensity and temperature changes in the coastal region. The calculations were done using the non-hydrostatic numerical model “AtmoSym”. The characteristics of atmospheric waves generated by such sources are estimated. The effect from a tropospheric sources on the state of the upper atmosphere and ionosphere is investigated. The physical processes that determine the change in atmospheric parameters are discussed.  It is shown that the main contribution from wave disturbances generated by meteorological sources belongs to infrasound. Infrasound and internal gravity waves can be sources of travelling wave packets and can also cause a sporadic E-layer.

The study was funded by RFBR and Kaliningrad region according to the research project  19-45-390005 (Y. Kurdyaeva) and  RFBR to the research project  18-05-00184 (O. Borchevkina).

How to cite: Kurdyaeva, Y., Borchevkina, O., and Kshevetskii, S.: Modeling the propagation of atmospheric waves from various tropospheric disturbances and studying their influence on the upper atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-459, https://doi.org/10.5194/egusphere-egu2020-459, 2020.

AS1.22 – Tropical Meteorology and Tropical Cyclones

EGU2020-12614 | Displays | AS1.22

Dropsonde Observations of Intense Typhoons in 2017 and 2018 in the T-PARCII Project

Kazuhisa Tsuboki, Hiroyuki Yamada, Tadayasu Ohigashi, Taro Shinoda, Kosuke Ito, Munehiko Yamaguchi, Tetsuo Nakazawa, Hisayuki Kubota, Yukihiro Takahashi, Nobuhiro Takahashi, Norio Nagahama, and Kensaku Shimizu

Typhoon is a tropical cyclone in the western North Pacific and the South China Sea. It is the most devastating weather system in East Asia. Strong winds and heavy rainfalls associated with a typhoon often cause severe disasters in these regions. There are many cases of typhoon disasters even in the recent decades in these regions. Furthermore, future projections of typhoon activity in the western North Pacific show that its maximum intensity will increase with the climate change. However, the historical data of typhoon (best track data) include large uncertainty after the US aircraft reconnaissance of typhoon was terminated in 1987. Another problem is that prediction of typhoon intensity has not been improved for the last few decades. To improve these problems, in situ observations of typhoon using an aircraft are indispensable. The T-PARCII (Tropical cyclone-Pacific Asian Research Campaign for Improvement of Intensity estimations/forecasts) project is aiming to improve estimations and forecasts of typhoon intensity as well as storm track forecasts.

In 2017, the T-PARCII team performed dropsonde observations of intense Typhoon Lan in collaboration with Taiwan DOTSTAR, which was the most intense typhoon in 2017 and caused huge disaster over the central Japan. It was categorized as a supertyphoon by JTWC and as a very intense and huge typhoon by JMA. Typhoon Lan moved northeastward to the east of the Okinawa main island and it was located around 23 N on 21 and 28 N on 22 October. In these two days, we made dropsonde observations at the center of the eye and in the surrounding area of the eyewall. The observations showed that the central pressure of Lan slightly increases from 926 hPa on 21 to 928 hPa on 22 October with the northward movement. On the other hand, The JMA best track data indicate that the central pressure decreases from 935 hPa on 21 to 915 hPa on 22 October. The observations also showed a significant double warm core structure in the eye and the maximum wind speed along the eyewall. The dropsonde data were used for forecast experiments. The result shows an improvement of typhoon track prediction.

The T-PARCII team also made aircraft observations of Typhoon Trami during the period from 25 to 28 September 2018 in collaboration with the SATREPS ULAT group and DOTSTAR. Trami was almost stationary during the period to the south of the Okinawa main island. Then, it moved northward and finally made a landfall over the central part of Japan. This also caused a big disaster and electricity was shut down for several days in the central part of Japan. Typhoon Trami showed a drastic change of intensity from 25 to 26 September with a large change of eye size from about a diameter of 60 km to 200 km. Dropsonde observations showed the change of central pressure and maximum wind speed as well as the thermodynamic structure of the eye.

How to cite: Tsuboki, K., Yamada, H., Ohigashi, T., Shinoda, T., Ito, K., Yamaguchi, M., Nakazawa, T., Kubota, H., Takahashi, Y., Takahashi, N., Nagahama, N., and Shimizu, K.: Dropsonde Observations of Intense Typhoons in 2017 and 2018 in the T-PARCII Project, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12614, https://doi.org/10.5194/egusphere-egu2020-12614, 2020.

EGU2020-3164 | Displays | AS1.22 | Highlight

Tropical cyclones and climate change: Recent results and uncertainties

Suzana Camargo, Chia-Ying Lee, Adam Sobel, and Michael Tippett

Here I will describe recent results on the influence of climate change on tropical cyclones (TC) using the Columbia Hazard (CHAZ) model. Using environmental conditions from reanalysis and climate models and a statistical-dynamical downscaling methodology (Lee et al. 2018), CHAZ generates synthetic TCs that can be used to analyze TC risk.  I will first discuss the current knowledge and uncertainties in TC frequency projections. Then I will present our recent projections on TC frequency using CHAZ. Focusing on the North Atlantic, I will finish by discussing how we can use a combination of observations, high-resolution models and CHAZ synthetic TCs in the historical period to inform the reliability of the models' TC frequency projections. 

Reference:

Lee, C.-Y., M.K. Tippett, A.H. Sobel, and S.J. Camargo, 2018. An environmentally forced tropical cyclone hazard model. J. Adv. Model. Earth Sys., 10, doi: 10.1002/2017MS001186.

How to cite: Camargo, S., Lee, C.-Y., Sobel, A., and Tippett, M.: Tropical cyclones and climate change: Recent results and uncertainties , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3164, https://doi.org/10.5194/egusphere-egu2020-3164, 2020.

EGU2020-18644 | Displays | AS1.22 | Highlight

An Environmental Explanation for the Recent Increase in Tropical Cyclone Intensification

Kieran Bhatia, Alex Baker, Gabriel Vecchi, Hiroyuki Murakami, James Kossin, Pier Luigi Vidale, Kevin Hodges, and Thomas Knutson

Tropical cyclone (TC) rapid intensification events are responsible for intensity forecasts with the highest errors, and hurricanes that rapidly intensify cause a disproportionate amount of the fatalities and damage from TCs. According to a recent study by Bhatia et al. (2019), natural variability cannot account for the recent (1982-2009), observed increase in the highest TC intensification rates in the Atlantic Basin. These results agree well with the main conclusions of Bhatia et al. (2018), which demonstrated climate change could significantly increase TC intensification rates worldwide by the end of 21st century.

Expanding on the work of Bhatia et al. (2018, 2019), TC intensification trends are analyzed for the period 1982-2017 using two observational datasets, the International Best-Track Archive for Climate Stewardship (IBTrACS) and the Advanced Dvorak Technique-HurricaneSatellite-B1 (ADT-HURSAT). The extended observational datasets confirm significant upward trends in intensifications metrics. To explore a physical explanation for the climate change response of TC intensification, we use ERA5 reanalysis data to calculate trends in the favorability of storm environments. When evaluating environmental data, we use 6-hour increments at specific annuli around already-formed storms in order to focus on synoptic conditions unique to storm evolution and not genesis. The robust trends in a 36-year times series and corresponding evolution of storm environments corroborates a climate change fingerprint on TC intensification.

How to cite: Bhatia, K., Baker, A., Vecchi, G., Murakami, H., Kossin, J., Vidale, P. L., Hodges, K., and Knutson, T.: An Environmental Explanation for the Recent Increase in Tropical Cyclone Intensification, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18644, https://doi.org/10.5194/egusphere-egu2020-18644, 2020.

EGU2020-1885 | Displays | AS1.22

Forecasting Hurricanes using Large-Ensemble Output

Jonathan Lin, Kerry Emanuel, and Jonathan Vigh

This paper describes the development of a model framework for Forecasts of Hurricanes using Large-ensemble Outputs (FHLO). Computationally inexpensive, FHLO quantifies the forecast uncertainty of a particular tropical cyclone (TC) through O(1000) ensemble members. The model framework consists of three components: (1) a track model that generates synthetic tracks from the TC tracks of an ensemble numerical weather prediction (NWP) model, (2) an intensity model that predicts the intensity along each synthetic track, and (3) a TC wind field model that estimates the time-varying twodimensional surface wind field. In this framework, we consider the evolution of a TC’s intensity and wind field as though it were embedded in a timeevolving environmental field. The environmental fields are derived from the forecast fields of ensemble NWP models, leading to probabilistic forecasts of track, intensity, and wind speed that incorporate the flow-dependent uncertainty. Each component of the model is evaluated using four years (2015- 2018) of TC forecasts in the Atlantic and Eastern Pacific basins. We show that the synthetic track algorithm can generate tracks that are statistically similar to those of the underlying global ensemble models. We show that FHLO produces competitive intensity forecasts, especially when considering probabilistic verification statistics. We also demonstrate the reliability and accuracy of the probabilistic wind forecasts. Limitations of the model framework are also discussed.

How to cite: Lin, J., Emanuel, K., and Vigh, J.: Forecasting Hurricanes using Large-Ensemble Output, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1885, https://doi.org/10.5194/egusphere-egu2020-1885, 2020.

EGU2020-2921 | Displays | AS1.22

Linking surface enthalpy fluxes to the forces driving the secondary circulation: towards a causal theory of tropical cyclone intensification

Remi Tailleux, Bethan Harris, Christopher Holloway, and Pier-Luigi Vidale

While it is well accepted that tropical cyclones (TCs) derive their energy from surface enthalpy fluxes over the ocean, there is still little understanding of the precise causes and effects by which the latter ends up as TC vortex kinetic energy. For example, Potential Intensity (PI) theory, which has been so far the main framework for predicting TC intensities, assumes a balance between the Carnot power input and the kinetic energy dissipated by surface friction, but says nothing of the detailed physical processes linking the two. A similar criticism pertains to the WISHE (Wind Induced Surface Heat Exchange) theory. To achieve a causal theory of TC intensification, the main difficulty is in linking the power input to kinetic energy production, rather than kinetic energy dissipation. Because kinetic energy is produced at the expense of available potential energy (APE), APE theory is arguably the most promising candidate framework for achieving a causal theory of TC intensification. However, in its current form, the usefulness of APE theory appears to be limited in a number of ways because of its reliance on a notional reference state of rest. First, APE production associated with standard reference states (i.e., horizontally averaged density field, density field of initial sounding, adiabatically sorted states, ...) is usually found to systematically overestimate the kinetic energy actually produced in ideal TC simulations, similarly as the Carnot theory of heat engines; moreover, the standard APE is only connected to vertical buoyancy forces, but says nothing of the radial forces required to drive the secondary circulation. To address these shortcomings, this work presents a new theory of available energy (AE) that is based on the use of an axisymmetric vortex reference state in gradient wind balance. This theory possesses the following advantages over previous frameworks:

 

  • The available energy (AE) thus constructed possesses both a mechanical and thermodynamic component. The thermodynamic component is analogous to the well-known Slantwise Convective Available Potential Energy (SCAPE), whereas the mechanical component is proportional to the anomalous azimuthal kinetic energy;
  • The rate of AE production by surface enthalpy fluxes is found to be a very accurate predictor of the amount of potential energy actually converted into kinetic energy in idealised TC simulations based on the Rotunno and Emanuel (1986) axisymmetric model, although a few exceptions are found for cold SSTs;
  • In addition to the expected thermodynamic efficiencies, the production term for AE also involves mechanical efficiencies predicting the fraction of the sinks/sources of angular momentum creating/destroying AE;
  • The AE is related to a generalised buoyancy/inertial force that has both vertical and horizontal components; at low levels, such a generalised force has radially inward and vertically upward components, as required to drive the expected secondary circulation.

The new theory, therefore, appears to possess all the ingredients to form the basis for a causal theory of TC intensification.

How to cite: Tailleux, R., Harris, B., Holloway, C., and Vidale, P.-L.: Linking surface enthalpy fluxes to the forces driving the secondary circulation: towards a causal theory of tropical cyclone intensification, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2921, https://doi.org/10.5194/egusphere-egu2020-2921, 2020.

EGU2020-19270 | Displays | AS1.22

The moisture budget of tropical cyclones: large scale environmental constraints and sensitivity to model horizontal resolution

Benoit Vanniere, Malcolm Roberts, Pier Luigi Vidale, Kevin Hodges, and Marie-Estelle Demory

Previous studies have shown that, the number, intensity and structure of simulated tropical cyclones (TC) in climate models get closer to the observations as the horizontal resolution is increased. However, the sensitivity of tropical cyclone precipitation and moisture budget to changes in resolution has received less attention. In this study, we use the five-model ensemble from project PRIMAVERA/HighResMIP to investigate the systematic changes associated with the water budget of tropical cyclones in a range of horizontal resolutions from 1º to 0.25º. Our results show that despite a large change in the distribution of TC intensity with resolution, the distribution of precipitation per TC does not change significantly. This result is explained by the large scale balance which characterises the moisture budget of TCs, i.e. radii of ~15º a scale that low and high resolution models represent equally well. The wind profile is found to converge between low and high resolutions for radii > 5º, resulting in a moisture flux convergence into the TC with similar magnitude at low and high resolutions. In contrast to precipitation per TC, the larger TC intensity at higher resolution is explained by the larger surface latent heat flux near the center of the storm, which leads to an increase in equivalent potential temperature and warmer core anomalies, despite representing a negligible contribution to the moisture budget. We discuss the complication arising from the choice of the tracking algorithm when assessing the impact of model resolution and the implications of such a constraint on the TC moisture budget in the context of climate change.

How to cite: Vanniere, B., Roberts, M., Vidale, P. L., Hodges, K., and Demory, M.-E.: The moisture budget of tropical cyclones: large scale environmental constraints and sensitivity to model horizontal resolution, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19270, https://doi.org/10.5194/egusphere-egu2020-19270, 2020.

EGU2020-12563 | Displays | AS1.22

Global assessment of linear and non-linear statistical-dynamical hindcast models of Tropical Cyclones intensity

Neetu Suresh, Lengaigne Matthieu, Vialard Jerome, Mangeas Morgan, Menkes Christophe, Suresh Iyyappan, Leloup Julie, and Knaff John

Tropical cyclones (hereafter TC) are amongst the most devastating natural phenomena for coastal regions worldwide. While there has been tremendous progress in forecasting TC tracks, intensity forecasts have been trailing behind. Most operational statistical-dynamical forecasts of TC intensity use linear regression techniques to relate the initial TC characteristics and most relevant large-scale environmental parameters along the TC track to the TC intensification rate. Historically, different operational prediction schemes have been developed independently for each TC-prone basin, making it difficult to compare skills between different TC basins. We have thus developed global TC intensity hindcasts using consistent predictors derived from a single atmospheric dataset over the same period. Linear hindcast schemes were built separately for each TC basin, based on multiple linear regression. They display comparable skill to previously-described similar hindcast schemes, and beat persistence by 20–40% in most basins, except in the North Atlantic and northern Indian Ocean, where the skill gain is only 10–25%. Most (60–80%) of the skill gain arises from the TC characteristics (intensity and its rate of change) at the beginning of the forecast, with a relative contribution from each environmental parameter that is strongly basin-dependent. Hindcast models built from climatological environmental predictors perform almost as well as using real-time values, which may allow to considerably simplify operational implementation in such models. Our results finally reveal that these models have 2 to 4 times less skill in hindcasting moderate (Category 2 and weaker) than in hindcasting strong TCs.

This last result suggests that linear models may not be sufficient for TC intensity hindcasts. Many physical processes involved in TCs intensification are indeed non-linear. We hence further investigated the benefits of non-linear statistical prediction schemes, using the same set of input parameters as for the linear models above. These schemes are based on either support vector machine (SVM) or artificial neural network algorithms. Contrary to linear schemes, which perform slightly better when trained individually over each TC basin, non-linear methods perform best when trained globally. Non-linear schemes improve TC intensity hindcasts relative to linear schemes in all TC-prone basins, especially SVM for which this improvement reaches ~10% globally, partly because they better use the non-seasonal variations of environmental predictors. The SVM scheme, in particular, partially corrects the tendency of the linear scheme to underperform for Category 2 and weaker TCs. Although the TC intensity hindcast skill improvements described above are an upper limit of what could be achieved operationally, it is comparable to that achieved by operational forecasts over the last 20 years. This improvement is sufficiently large to motivate more testing of non-linear methods for statistical TC intensity prediction at operational centres.

How to cite: Suresh, N., Matthieu, L., Jerome, V., Morgan, M., Christophe, M., Iyyappan, S., Julie, L., and John, K.: Global assessment of linear and non-linear statistical-dynamical hindcast models of Tropical Cyclones intensity, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12563, https://doi.org/10.5194/egusphere-egu2020-12563, 2020.

EGU2020-3136 | Displays | AS1.22

Dynamic Core of the MJO

Chidong Zhang and Ji-Eun Kim

This presentation introduces a theory in which the dynamic core of the MJO is described in terms of a harmonic oscillator that can be excited by stochastic forcing. The mechanism for selecting MJO scales comes from momentum damping. The resonant solution to the equation for a damped harmonic oscillator on an equatorial beta plane represents the equatorial Kelvin wave for small damping and large zonal wavenumbers and the MJO for large (3 – 5 days) damping and zonal wavenumber one. This theory demonstrates the distinction between the Kelvin wave and MJO and their continuous transition. In contrast to most other MJO theories that compete against each other, this theory embraces most other theories in that they provide possible sources of energy (forcing) to the dynamic core of the MJO.

How to cite: Zhang, C. and Kim, J.-E.: Dynamic Core of the MJO, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3136, https://doi.org/10.5194/egusphere-egu2020-3136, 2020.

EGU2020-6394 | Displays | AS1.22

Diversity of the Madden-Julian Oscillation

Guosen Chen, Bin Wang, and Fei Liu

Madden-Julian Oscillation (MJO) is the dominant mode of atmospheric intraseasonal variability and the cornerstone for subseasonal prediction of extreme weather events. Climate modeling and prediction of MJO remain a big challenge, partially due to lack of understanding the MJO diversity. Here, we delineate observed MJO diversity by cluster analysis of propagation patterns of MJO events, which reveals four archetypes: standing, jumping, slow eastward propagation, and fast eastward propagation. Each type of MJO exhibits distinctive east-west asymmetric circulation and thermodynamic structures. Tight coupling between the Kelvin wave response and major convection is unique for the propagating events (slow and fast propagations), while the strength and length of Kelvin wave response distinguish slow and fast propagations. The Pacific sea surface temperature anomalies can affect MJO diversity by modifying the Kelvin wave response and its coupling to MJO convection. An El Niño state tends to increase the zonal scale of Kelvin wave response, to amplify it, and to enhance its coupling to the convection, while a La Niña state tends to decrease the zonal scale of Kelvin wave response, to suppress it, and to weaken its coupling to the major convection. This effect of background sea surface temperature on the MJO diversity has been verified by using a theoretical model. The results shed light on the mechanisms responsible for MJO diversity and provide potential precursors for foreseeing MJO propagation.

How to cite: Chen, G., Wang, B., and Liu, F.: Diversity of the Madden-Julian Oscillation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6394, https://doi.org/10.5194/egusphere-egu2020-6394, 2020.

Large-scale convection associated with the Madden-Julian Oscillation (MJO) initiates over the Indian Ocean and propagates eastward across the Maritime Continent (MC) into the western Pacific. As an MJO enters the MC, it often weakens or completely dissipates due to complex interactions between the large-scale MJO and the MC landmass and its topography. This is referred to as the MC barrier effect, and it is responsible for the dissipation of 40-50% of observed MJO events. One of the main reasons for the MJO’s weakening and dissipation over the MC is the diurnal cycle (DC), one of the strongest modes of variability in the region. Due to the complex nature of the MJO and the MC’s complicated topography, the interaction between the DC and the MJO is not well understood.

In this study, we examine the MJO-induced variability of the DC of precipitation over the MC. We use gridded satellite precipitation products (TRMM 3B42 and GPM IMERG) to: (1) track the MJO convective envelope using the Large-scale Precipitation Tracking algorithm (LPT), (2) analyze the changes in the DC of precipitation over the MC relative to the passage of the MJO. We find that the presence of an MJO not only increases the amount of precipitation over the MC, but that the increase is more pronounced over water than over land. The results from observations are compared to those from two reanalysis datasets (ERA5, MERRA-2). The reanalysis datasets are then used to examine the dynamic and thermodynamic changes that drive the variability in the DC of precipitation relative to the MJO. In addition, we separate MJO events into two groups based on whether they cross the MC, and independently examine their influences on the evolution of the DC of precipitation.

How to cite: Savarin, A. and Chen, S.: MJO-Induced Variability of the Diurnal Cycle of Precipitation over the Maritime Continent , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19432, https://doi.org/10.5194/egusphere-egu2020-19432, 2020.

EGU2020-144 | Displays | AS1.22

Understanding the role of water vapor and temperature in easterly wave-related convection

Rosa Vargas Martes and Angel Adames Corraliza

Easterly Waves (EW) in the Pacific Ocean (PEW) and over Africa (AEW) account for a large fraction of rainfall variability in their respective regions. Although multiple studies have been conducted to better understand EWs, many questions remain regarding their structure, development, and coupling to deep convection. Recent studies have highlighted the relationship between water vapor and precipitation in tropical motion systems. However, EW have not been studied within this context. On the basis of Empirical Orthogonal Functions (EOFs) and a novel plume-buoyancy framework, the thermodynamic processes associated with EW-related convection are elucidated. A linear regression analysis reveals the relationship between temperature, moisture, and precipitation in EW. Temperature anomalies are found to be highly correlated in space and time with anomalies in specific humidity. However, this coupling between temperature and moisture is more robust in AEWs than PEWs. In PEWs moisture accounts for a larger fraction of precipitation variability. Results suggest that the convective coupling mechanism in AEW may differ from the coupling mechanism of PEWs.

How to cite: Vargas Martes, R. and Adames Corraliza, A.: Understanding the role of water vapor and temperature in easterly wave-related convection, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-144, https://doi.org/10.5194/egusphere-egu2020-144, 2020.

EGU2020-5230 | Displays | AS1.22

Airmass analysis of the processes driving the progression of the Indian summer monsoon

Ambrogio Volonté, Andrew G. Turner, and Arathy Menon

The Indian summer monsoon is a vital source of water and a cause of severe impacts for more than a billion people in the Indian subcontinent. The INCOMPASS project investigates the mechanisms driving its onset and progression through an observational field campaign supplemented by high-resolution numerical simulations for the 2016 season using UK Met Office models. A 4.4 km resolution convection-permitting limited-area model simulation (driven at its boundaries by a daily-initialised global model) is used in this study, and verified against observations, along with short-lead-time operational global forecasts.

These data show that the monsoon progression towards northwest India in June 2016 is a non-steady process, modulated by the interaction between moist low-level southwesterly flow from the Arabian Sea and a northwesterly incursion of descending dry air from western and central Asia. The location and extent of these two flows are closely linked to mid-latitude dynamics, through the southward propagation of potential vorticity streamers and the associated formation of cyclonic circulations in the region where the two air masses interact. Particular focus is devoted to the use of Lagrangian trajectories to characterise the evolution of the airstreams and complement the Eulerian monsoon progression analysis. The trajectories confirm that the interaction of the two airstreams is a primary driver of the general moistening of the troposphere associated with monsoon progression. They also indicate the occurrence of local diabatic processes along the airstreams, such as turbulent mixing and local evaporation from the Arabian Sea, in addition to moisture transport from remote sources.

In summary, this combined Eulerian-Lagrangian analysis reveals the non-steady nature of monsoon progression towards northwest India. This process is driven by the interaction of different air masses and influenced by a synergy of factors on a variety of scales, such as mid-latitude dynamics, transient weather systems and local diabatic processes.

This work has recently been accepted for publication on the Quarterly Journal of the Royal Meteorological Society.

How to cite: Volonté, A., Turner, A. G., and Menon, A.: Airmass analysis of the processes driving the progression of the Indian summer monsoon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5230, https://doi.org/10.5194/egusphere-egu2020-5230, 2020.

EGU2020-21506 | Displays | AS1.22

The vertical moisture structure and precipitation intensity distributions associated with tropical convective systems

Kathleen Schiro, Sylvia Sullivan, Jiabo Yin, and Pierre Gentine

In the tropics, the majority of high-intensity precipitation comes from the organization of multiple convective cells into mesoscale convective systems (MCS). Here, we use a synthesis of multi-decade satellite and reanalysis data to investigate relationships between the column water vapor content (CWVC), instability (CAPE), and precipitation from MCS. We find a linear relationship between MCS maximum precipitation intensity and CAPE and a sharp, nonlinear relationship between this maximum precipitation intensity and CWVC. The latter suggests that a deep layer of inflow to the MCS dominates buoyancy and precipitation production. From these multidecade data, we can also illustrate robust shifts in the probability distributions of precipitation intensity with the El Niño Southern Oscillation. El Niño-La Niña relative gains and losses in precipitation intensity can be understood with a vertical momentum budget and the role of environmental relative humidity and large-scale circulation therein. Understanding the associated vertical moisture structure and instability is essential to better predict future variability in tropical precipitation.

How to cite: Schiro, K., Sullivan, S., Yin, J., and Gentine, P.: The vertical moisture structure and precipitation intensity distributions associated with tropical convective systems, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21506, https://doi.org/10.5194/egusphere-egu2020-21506, 2020.

EGU2020-19042 | Displays | AS1.22

Self-aggregation conceptualized by cold pool organization

Silas Boye Nissen and Jan O. Haerter

In radiative-convective equilibrium (RCE) simulations, self-aggregation is the spontaneous emergence of one or several long-lasting convective clusters from an apparently homogenous atmosphere (Wing, 2019). This phenomenon may implicate the formation of tropical cyclones (Wing et al., 2016; Muller et al., 2018) and large-scale events such as the Madden-Julian Oscillation (Arnold et al., 2015; Satoh et al., 2016; Khairoutdinov et al., 2018). However, it remains poorly understood how cold pools (CPs) contribute to self-aggregation. Using a suite of cloud-resolving numerical simulations, we link the life-cycle and the spatial organization of CPs to the evolution of self-aggregation. By tracking CPs, we determine the maximal CP radius Rmax ≈ 20 km and show that cloud-free regions exceeding such radii always grow indefinitely. Besides, we identify a minimum CP radius Rmin ≈ 8 km below which CPs are too cold, hence negatively buoyant, to initialize new convective cells. Finally, we suggest a simple mathematical framework that describes a mechanism, where cloud-free areas are likely to form when CPs have small Rmax, whereas large Rmax hampers cavity formation. Our findings imply that interactions between CPs crucially control the dynamics of self-aggregation, and known feedbacks may only be required in stabilizing the final, fully-aggregated state.

How to cite: Nissen, S. B. and Haerter, J. O.: Self-aggregation conceptualized by cold pool organization, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19042, https://doi.org/10.5194/egusphere-egu2020-19042, 2020.

To explore the characteristics of the concentric eyewall of a typhoon during its formation and replacement processes, with Super Typhoon Muifa in 2011 as the example case, the Weather Research and Forecast (WRF) mode was used to carry out a numerical simulation to reproduce the entire formation and replacement processes of the concentric eyewall. The physical quantities such as the tangential wind speed, radar echo, radial wind speed, vertical wind speed, and potential vortex were diagnosed and analyzed. The results of the analysis show that the outward expansion of the isovelocity in the lower troposphere was the early signal of the formation of the outer eyewall. After the outer eyewall formed, there was a center of second-highest tangential wind speed in the corresponding area. The second-highest wind speed increased as the strength of the outer eyewall increased, and the position of the second-highest wind speed center was retracted with the retraction of the outer eyewall. The tangential wind speed of the moat area was smaller than that corresponding to the concentric eyewall and this feature gradually disappeared with the increase of the height. The echo in the moat area was weak, and this characteristic was particularly evident when the moat area was relatively wide and the outer eyewall was relatively strong. With the formation and development of the outer eyewall, the intensity of the inflow in the boundary layer corresponding to the inner eyewall was reduced, the intensity of the outflow in the upper layers declined, and the intensities of the inflow and outflow corresponding to the outer eyewall were enhanced. After the second outer eyewall matured, there was a significant inflow in the upper layer of the moat area. Once the outer eyewall formed, a large amount of hydrometeors appeared in the corresponding area, and there was a strong ascending motion inside that area. The strength of the ascending motion and the content of hydrometeors increased as the outer eyewall increased. When the moat area was relatively wide, the divergent airflow generated by the developed outer eyewall in the upper layer would produce a significant descending motion in the moat area.

How to cite: Liu, Y., Li, D., and Huang, L.: Characteristics of the Concentric Eyewall Structure of Super Typhoon Muifa during Its Formation and Replacement Processes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1436, https://doi.org/10.5194/egusphere-egu2020-1436, 2020.

EGU2020-2527 | Displays | AS1.22

Effect of ISO-SSE Interaction on the Rapid intensification of TS in the WNP Since the Late 1990s

Chi-Cherng Hong, Chih-Hua Tsou, Kuan-Chieh Chen, and Chi-Chun Chang

This study addressed the abrupt increase in the development speed of Tropical storms (TSs) to severe TSs ( Category 3, referred to as STS) in the western North Pacific (WNP) during the late 1990s. Although the annual mean number of TSs in the WNP exhibited an abrupt decrease in the late 1990s, the annual mean number of STs did not exhibit significant change. This caused the ratio of annual mean number of STSs to the total TSs number displayed an abrupt increase in the late 1990s. Our observations indicate that the mean lifetime of a STS during the post 1990s period was approximately 70 hours shorter than that in the pre-1990s period because of the northwestward shift of the mean TS genesis location in response to the mega-La Niña-like mean state change in the late 1990s. This indicated that the TSs have developed into STSs with a faster speed since the late 1990s. The eddy kinetic energy budget of synoptic-scale eddy (SSE) indicated that the enhancement of scale interaction of intraseasonal oscillation (ISO)−SSE played a critical role in accelerating the TS–to–STS development. A further diagnosis revealed that the increase of ISO–SSE interaction was attributed to the mega–La Niña–like mean state change. The mega–La Niña–like associated anticyclone anomaly and warm oceanic condition in the WNP substantially modified the mean TS genesis location (northwestward shift), enhanced the ISO magnitude, and shifted the ISO propagation northward, thereby amplifying the ISO–SSE interaction in the WNP in the late 1990s.

Key words: Tropical storm, abrupt increase,  Intraseasonal oscillation (ISO), ISO–SSE interaction

How to cite: Hong, C.-C., Tsou, C.-H., Chen, K.-C., and Chang, C.-C.: Effect of ISO-SSE Interaction on the Rapid intensification of TS in the WNP Since the Late 1990s , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2527, https://doi.org/10.5194/egusphere-egu2020-2527, 2020.

EGU2020-2552 | Displays | AS1.22

Tropical Cyclones in European Seasonal Forecast Models

Kevin Hodges, Daniel Befort, and Antje Weisheimer

This study assesses the representation of Tropical Cyclones (TC) in an ensemble of seasonal forecast models from five different centres (ECMWF, UK Met Office, DWD, CMCC, Météo-France). Northern Hemispheric Tropical Cyclones are identified using a widely applied objective Tropical Cyclone tracking algorithm based on relative vorticity fields. Analyses for three different aspects are carried out: 1) assessment of the skill of the ensemble to predict  the TC frequencies over different ocean basins, 2) analyse the dependency between the model's ability to represent TCs and large-scale biases and 3) assess the impact of stochastic physics and horizontal resolution on TC frequency.

For the July to October season all seasonal forecast models initialized in June are skilful in predicting the observed inter-annual variability of TC frequency over the North Atlantic (NA). Similarly, the models initialized in May show significant skill over the Western North Pacific (WNP) for the season from June to October. Further to these significant positive correlations over the NA, it is found that most models are also able to discriminate between inactive and active seasons over this region. However, despite these encouraging results, especially  for skill over the NA, most models suffer from large biases. These biases are not only related to biases in the large-scale circulation but also to the representation of intrinsic model uncertainties and the relatively coarse resolution of current seasonal forecasts. At ECMWF model uncertainty is accounted for by the use of stochastic physics, which has been shown to improve forecasts on seasonal time-scales in previous studies. Using a set of simulations conducted with the ECMWF SEAS5 model, the effects of stochastic physics and resolution on the representation of Tropical Cyclones on seasonal time-scales are assessed. Including stochastic physics increases the number of TCs over all ocean basins, but especially over the North Atlantic and Western North Pacific.

How to cite: Hodges, K., Befort, D., and Weisheimer, A.: Tropical Cyclones in European Seasonal Forecast Models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2552, https://doi.org/10.5194/egusphere-egu2020-2552, 2020.

Convective bursts have been linked to intensification of tropical cyclones [1]. We consider a possibility of convective bursts being triggered by aurorally-generated atmospheric gravity waves (AGWs) that may play a role in the intensification process of tropical cyclones [2]. A two-dimensional barotropic approximation is used to obtain asymptotic solutions representing propagation of vortex waves [3] launched in tropical cyclones by quasi-periodic convective bursts. The absorption of vortex waves by the mean flow and formation of the secondary eyewall lead to a process of an eyewall replacement cycle that is known to cause changes in tropical cyclone intensity [4]. Rapid intensification of hurricanes and typhoons from 1995-2018 is examined in the context of solar wind coupling to the magnetosphere-ionosphere-atmosphere (MIA) system. In support of recently published results [2] it is shown that rapid intensification of TCs tend to follow arrival of high-speed solar wind when the MIA coupling is strongest. The coupling generates internal gravity waves in the atmosphere that propagate from the high-latitude lower thermosphere both upward and downward. In the lower atmosphere, they can be ducted [5] and reach tropical troposphere. Despite their significantly reduced amplitude, but subject to amplification upon over-reflection in the upper troposphere, these AGWs can trigger/release moist instabilities leading to convection and latent heat release. A possibility of initiation of convective bursts by aurorally generated AGWs is investigated. Cases of rapid intensification of recent tropical cyclones provide further evidence to support the published results [2].

References

[1] Steranka et al., Mon. Weather Rev., 114, 1539-1546, 1986.

[2] Prikryl et al., J. Atmos. Sol.-Terr. Phys., 2019.

[3] Nikitina L.V., Campbell L.J., Stud. Appl. Math., 135, 377–446, 2015.

[4] Willoughby H.E., et al., J. Atmos. Sci., 39, 395–411, 1982.

[5] Mayr H.G., et al., J. Geophys. Res., 89, 10929–10959, 1984.

How to cite: Nikitina, L., Prikryl, P., and Zhang, S.-R.: Rapid intensification of tropical cyclones: Vortex waves seeded by aurorally-generated atmospheric gravity waves?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3137, https://doi.org/10.5194/egusphere-egu2020-3137, 2020.

EGU2020-3731 | Displays | AS1.22

Tropical Cyclone Precipitation in the AMIP Experiments of the Primavera Project

Wei Zhang, Gabriele Villarini, Enrico Scoccimarro, and Malcolm Roberts

This study examines the climatology and structure of precipitation associated with tropical cyclones based on the Atmospheric Model Intercomparison Project (AMIP) runs of the Process-based climate simulation: advances in high resolution modelling and European climate risk assessment (Primavera) Project during 1979-2014. We assess the role of spatial resolution in shaping tropical cyclone precipitation along with inter-model variability by evaluating climate models with a variety of dynamic cores and parameterization schemes. AMIP runs that prescribe historical sea surface temperatures and radiative forcings can well reproduce the observed spatial pattern of tropical cyclone precipitation climatology, with high-resolution performing better than low-resolution ones in the first order. Overall, the AMIP runs can also reproduce the fractional contribution of tropical cyclone precipitation to total precipitation in observations. Similar to tropical cyclone precipitation climatology, the factional contrition is better simulated by high-resolution models. All the models in the AMIP runs underestimate the observed composite tropical cyclone rainfall structure over both land and ocean, and we identify differences in this factor between high-resolution and low-resolution models. The underestimation of rainfall composites by the AMIP runs are also supported by the radial profile of tropical cyclone precipitation. This study shows that the high-resolution climate models can reproduce well the spatial pattern of tropical cyclone climatology and underestimate the composite rainfall structure, with increased spatial resolution that overall improves the performance of simulation.

How to cite: Zhang, W., Villarini, G., Scoccimarro, E., and Roberts, M.: Tropical Cyclone Precipitation in the AMIP Experiments of the Primavera Project, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3731, https://doi.org/10.5194/egusphere-egu2020-3731, 2020.

EGU2020-3788 | Displays | AS1.22

Sensitivity of precipitation and structure of Typhoon Hato to bulk and explicit spectral bin microphysics schemes

xiaodian shen, qimin cao, baolin jiang, wenshi lin, and lan zhang

This study simulated the evolution of Typhoon Hato (2017) with the Weather Research and Forecasting model using three bulk schemes and one bin scheme. It was found that the track of the typhoon was insensitive to the microphysics scheme, whereas the degree of correspondence between the simulated precipitation and cloud structure of the typhoon was closest to the observations when using the bin scheme. The different microphysical structure of the bin and three bulk schemes was reflected mainly in the cloud water and snow content. The three bulk schemes were found to produce more cloud water because the application of saturation adjustment condensed all the water vapor at the end of each time step. The production of more snow by the bin scheme could be attributed to several causes: (1) the calculations of cloud condensation nuclei size distributions and supersaturation at every grid point that cause small droplets to form at high levels, (2) different fall velocities of different sizes of particles that mean small particles remain at a significant height, (3) sufficient water vapor at high levels, and (4) smaller amounts of cloud water that reduce the rates of riming and conversion of snow to graupel. The distribution of hydrometeors affects the thermal and dynamical structure of the typhoon. The saturation adjustment hypothesis in the bulk schemes overestimates the condensate mass. Thus, the additional latent heat makes the typhoon structure warmer, which increases vertical velocity and enhances convective precipitation in the eyewall region.

How to cite: shen, X., cao, Q., jiang, B., lin, W., and zhang, L.: Sensitivity of precipitation and structure of Typhoon Hato to bulk and explicit spectral bin microphysics schemes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3788, https://doi.org/10.5194/egusphere-egu2020-3788, 2020.

EGU2020-738 | Displays | AS1.22

Meridional distribution of moisture transport associated to Tropical Cyclones

Daniele Peano, Enrico Scoccimarro, Alessio Bellucci, Malcolm Roberts, Annalisa Cherchi, Alessandro D'Anca, Fabrizio Antonio, Sandro Fiore, and Silvio Gualdi

Tropical cyclones (TCs) transport energy and moisture along their pathways interacting with the climate system and TCs activities are expected to extend further poleward during the 21st century.

For this reason, it is important to assess the ability of state-of-the-art climate models in reproducing an accurate meridional distribution of TCs as well as a reasonable meridional portrait of moisture transport associated with TCs.

Since high resolutions are required to reconstruct observed TCs activity, the present work is based on the simulations performed as part of HighResMIP in the framework of the community CMIP6 effort. To inspect this feature, two horizontal resolutions for each climate model are considered. Besides, the impact of boundary conditions, i.e. observed ocean surface state, is examined by considering both coupled and atmosphere-only configurations.

In the present work, the north Atlantic region is analyzed as a sample region, while the same approach is applied on a multi-basin basis. In the sample area, climate models present a good ability in reproducing the TCs distribution, with a general underestimation at lower latitudes and a slight overestimation at high-latitudes compared to observed TCs tracks (e.g. IBTRACK).

The meridional distribution of moisture transport associated with TCs is evaluated by considering the radial average of the integrated water vapor transport along the TC tracks. When compared to observation (IBTRACS and JRA-55 reanalysis), the simulated moisture transport associated with TCs displays reasonably good performance in atmosphere-only high-resolution models configuration. The interannual variability of water vapor associated with TCs, instead, is poorly represented in climate models.

Climate models in high-resolution configuration can then be used in estimating future TCs meridional distribution and changes in meridional moisture transport associated with TCs.

This effort is part of HighResMIP and it is developed in the framework of the EU-funded PRIMAVERA project.   

How to cite: Peano, D., Scoccimarro, E., Bellucci, A., Roberts, M., Cherchi, A., D'Anca, A., Antonio, F., Fiore, S., and Gualdi, S.: Meridional distribution of moisture transport associated to Tropical Cyclones, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-738, https://doi.org/10.5194/egusphere-egu2020-738, 2020.

Interannual variation of tropical cyclone (TC) landfall frequency is not consistent along the coast of East Asia, with large contrast of north and south East Asia coast regions in boreal summer. This study examines interannual variations of TC landfall frequency over north and south East Asia and identifies roles of the western North Pacific subtropical high (WNPSH) and TC genesis frequency associated with these variations. Although the total number of landing TC of north and south East Asia is similar, interannual variations of TC landfall frequency are relatively independent to each other, with the corresponding correlation coefficient north and south of 25°N is only –0.024 from 1979 to 2017. TC landfall over north East Asia is largely modulated by the circulation related to the WNPSH, while TC landfall in the south has no significant relationship with the WNPSH or other remote large-scale circulations. The WNPSH effectively regulates TC landfall in the north by modulating TC genesis east of the Philippines and steering flows. Nonetheless, the two factors have weak contradictory effects on TC landing in the south region. The frequency of TC genesis around the South China Sea directly connects to the TC landfall over south East Asia, which is modulated by the surrounding genesis environment, including relative humidity and relative vorticity. This work favors for a better understanding of the seasonal forecasts of TC landfall frequency and the subsequent climate service over East Asia.

How to cite: Lai, J., Li, C., and Lu, R.: Considerable differences of the interannual variations for the tropical cyclone landfall over north and south East Asia in summer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3982, https://doi.org/10.5194/egusphere-egu2020-3982, 2020.

This paper explores the modulation by Madden–Julian Oscillation (MJO) on tropical-cyclone (TC; hereafter, MJO TC) genesis over the Western North Pacific (WNP) and the South China Sea (SCS) under different El Niño Southern Oscillation (ENSO) conditions. Analyses used Joint Typhoon Warning Center (JTWC) Best Track data, the Real-Time Multivariate MJO (RMM) index, and European Center for Medium-Range Weather Forecasts (ECMWF) Interim (ERA-Interim) reanalysis data. Results showed that MJO has significant modulation on both SCS and WNP TC genesis in neutral years, with more (fewer) TCs forming during active (inactive) MJO phases. However, during El Niño and La Niña years, modulation over the two regions differs. Over the SCS, the modulation of TC genesis is strong in La Niña years, while it becomes weak in El Niño years. Over the WNP, MJO has stronger influence on TC genesis in El Niño years compared to that in La Niña years. Related Genesis Potential Index (GPI) analysis suggests that midlevel moisture is the primary factor for MJO modulation on SCS TC genesis in La Niña years, and vorticity is the secondary factor. Over the WNP, midlevel moisture is the dominant factor for MJO TC genesis modulation during El Niño years. The main reason is increased water-vapor transport from the Bay of Bengal associated with the active MJO phase related westerly wind anomalies; these features are a significant presence over the SCS during La Niña years, and over the WNP during El Niño years.

How to cite: Ye, C., Deng, L., Huang, W.-R., and Chen, J.: Comparison of Madden–Julian Oscillation Modulation on tropical-cyclone genesis over the South China Sea and Western North Pacific under different El Niño Southern Oscillation conditions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4286, https://doi.org/10.5194/egusphere-egu2020-4286, 2020.

EGU2020-4372 | Displays | AS1.22

Long-term change of tropical cyclones activity and its potential impacts on Vietnam

Thi Ngoc Huyen Ho, S.-Y. Simon Wang, Karthik Balaguru, Kyo-Sun Lim, and Jin-Ho Yoon

Tropical cyclones (TCs) are the most dangerous climatic events in Vietnam. Recently, most of the studies have focused on TCs frequency and intensity, yet the rainfall events caused by them have not been got adequate attention. We show here the long-term change of TCs activity developed in both the South China Sea and the Philippines Sea and estimated its potential impacts during the period of 1977 – 2016. The trend analysis reveals that TCs have not shown obvious variability in numbers and destructiveness ability, whereas the TCs-induced rainfall events and its spatial distribution exhibit more complex patterns in different parts of Vietnam. For example, increasing rainfall amounts in the northern part is likely caused by TCs despite the fact that the TCs frequency did not exhibit much of significant changes. Evaluating rainfall caused by TCs activity is of great practical significance for Vietnam. Our findings suggest that in addition to the TCs frequency and intensity, TCs-induced rainfall events should be considered and included in future preparedness and response plans both on regional and national scale.

How to cite: Ho, T. N. H., Wang, S.-Y. S., Balaguru, K., Lim, K.-S., and Yoon, J.-H.: Long-term change of tropical cyclones activity and its potential impacts on Vietnam, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4372, https://doi.org/10.5194/egusphere-egu2020-4372, 2020.

Two high-resolution climate models (the HiRAM and MRI-AGCM3.2) are used to simulate present-day western North Pacific (WNP) tropical cyclone (TC) activity and investigate the projected changes for the late 21st century. Compared toobservations, the models are able to realistically simulate many basic features of the WNP TC activity climatology. Future projections with the coupled model inter-comparison project phase 5 (CMIP5) under Representative Concentration Pathway (RCP) 8.5 scenario show a tendency for decreases in the number of WNP TCs, and of increases in the more intense TCs. It is unknown to what cause this inverse variation with number and intensity should be generally linked to similar large-scale environmental conditions. To examine the WNP TC genesis and intensity with environmental variables, we show that most of the current trend of decreasing genesis of TCs can be attributed to weakened dynamic environments and the current trend of increasing intensity of TCs might be linked to increased thermodynamic environments. Thus, the future climate warms under RCP 8.5 will likely lead to strong reductions in TC genesis frequency over the WNP, with project decreases of 36-63% by the end of the twenty-first century, but lead to greater TC intensities with rapid development of thermodynamic environments.

How to cite: Wu, L.: Changes in the Past and Projected Western North Pacific Tropical Cyclone Activity in a Warmed Climate, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7521, https://doi.org/10.5194/egusphere-egu2020-7521, 2020.

Numerous low and mid-level vortices are initiated respectively north and south of 15°N in West Africa and enter the North Atlantic where they may trigger cyclogenesis. Applying an objective vortex tracking algorithm on 38 years of meteorological re-analysis, this work investigates the vortex origin and their role in cyclogenesis with an emphasis on: (i) orography, (ii) seasonal variations and, (iii) merge between low and mid-level vortex tracks. North path vortices are mostly initiated downstream of Hoggar Mountains (5°E, 24°N) and south path vortices are mostly initiated downstream of Fouta Djallon Mountains (15°W, 10°N). About 55% of cyclogeneses in the Main Development Region (MDR: east of 60°W; 5 to 20°N) is associated with vortices initiated on the continent east of 10°W. MDR cyclonic activity is governed by seasonal and interannual variations of the local Genesis Potential Index (maximal in August-September) and not by the number of vortices entering the Ocean. North path vortices, which are more numerous in July, are thus less cyclogenetic compared to south path vortices that are more numerous in August-September. Considering together vortices initiated on the continent and near the coast, about 20% of the cyclogeneses are associated with merge of north and south path vortices and about 14% with north path vortices only. The remaining part is mostly associated with south path vortices. In addition, south path vortices with greater intensity and vertical development between Greenwich and the coast are more cyclogenetic.

How to cite: Duvel, J. P.: On vortices initiated over West Africa and their impact on North Atlantic tropical cyclones, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10844, https://doi.org/10.5194/egusphere-egu2020-10844, 2020.

The Weather Research and Forecast (WRF) models have been used to investigate the sensitivity of simulations of Typhoon Tembin (1214) to changes in three horizontal grid spacings of 12km, 8km, and 6km and the effect of the cold wake generated by the previous Typhoon Bolaven (1215). It was observed that Bolaven-generated cold wakes cooled up to 7 °C in the sea around the Korean Peninsula. There are many previous studies on track dynamics influenced by sea surface temperature (SST) gradient due to the cold wakes. However, the intensity and precipitation of the following tropical cyclone (TC) is not yet certain. Here we show that the effect of SST gradient on the following TC are examined with WRF models of varying resolutions using modified SST from observed real-time data of the Ieodo Ocean Research Station and the Yellow Sea buoy in Korea. In the track of TC, a higher resolution showed the faster and more eastward movement of TCs in all SST conditions. TC tends to move more eastward at all resolutions particularly when the cold wake is generated in the western region of TC. When there is no cold wake, the intensity of TC is very sensitive to the resolution of the experiment. If a cold wake is maintained on the western (eastern) sides, the intensity of TC is weaker(stronger) than no cold wake experiment and is less sensitive to differences in resolution. The precipitation rate of TCs in the cold wake of the eastern (western) region is lower (higher) than when there is no wake. As the aspect of horizontal resolutions, the precipitation rate of TC in higher resolution shows stronger than lower resolution. The TC-generated cold wake significantly affects intensity and movement in cold wake cases in the western region, regardless of the horizontal grid, for various reasons.

How to cite: Moon, M. and Ha, K.-J.: Effect of SST gradient caused by Typhoon-Generated Cold Wake on the Subsequent Typhoon Tembin in models of varying resolutions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12173, https://doi.org/10.5194/egusphere-egu2020-12173, 2020.

EGU2020-12834 | Displays | AS1.22

Asymmetric impact of CP ENSO on the significant reduction of tropical cyclone genesis frequency over the WNP since the late 1990s

Han-Kyoung Kim, Sang-Wook Yeh, Nam-Young Kang, and Byung-Kwon Moon

Tropical cyclone (TC) genesis frequency over the western North Pacific (WNP) is reduced significantly since the late 1990s, coinciding with a Pacific decadal oscillation (PDO) phase change from positive to negative. In this study, the underlying mechanism for this reduction is investigated through analysis of asymmetric central Pacific (CP) El Niño-Southern Oscillation (ENSO) properties induced by the negative PDO phase. Results suggest that the significant reduction is caused by asymmetric CP ENSO properties, in which the CP La Niña is more frequent than the CP El Niño during negative PDO phases; furthermore, stronger CP La Niña occurs during a negative PDO phase than during a positive PDO phase. CP La Niña (El Niño) events generate an anticyclonic (cyclonic) Rossby wave response over the eastern WNP, leading to a significant decrease (increase) in eastern WNP TC genesis. Therefore, more frequent CP La Niña events and the less frequent CP El Niño events reduce the eastern WNP mean TC genesis frequency during a negative PDO phase. In addition, stronger CP La Niña events during a negative PDO phase reinforce the reduction in eastern WNP TC genesis. The dependency of CP ENSO properties on the PDO phase is confirmed using a long-term climate model simulation, which supports our observational results. 

Acknowledgements: This work was supported by a National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT; No. 2019R1A2C1008549).

How to cite: Kim, H.-K., Yeh, S.-W., Kang, N.-Y., and Moon, B.-K.: Asymmetric impact of CP ENSO on the significant reduction of tropical cyclone genesis frequency over the WNP since the late 1990s, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12834, https://doi.org/10.5194/egusphere-egu2020-12834, 2020.

EGU2020-16658 | Displays | AS1.22

Structure and dynamics of a case-study monsoon depression in high-resolution numerical simulations using the Met Office Unified Model

Arathy Menon, Ambrogio Volonté, Andrew Turner, and Kieran Hunt

Monsoon depressions (MD) are synoptic-scale cyclonic vortices that form over the Bay of Bengal and propagate northwestward through the monsoon trough onto the Indian subcontinent, bringing substantial amounts of rainfall to central and northern India. Despite their importance, key questions on the mechanisms driving their generation and development are still open. In this study we inspect the structure and dynamics of a MD case study (1-10 July 2016) using a set of high-resolution simulations performed within the INCOMPASS project. The simulations are performed at a grid spacing of 17 km, 4.4 km and 1.5 km (with parametrised convection for the former experiment and explicit convection for the latter two). Initial results of this study show that the two higher-resolution simulations are more effective in resolving intense rainfall caused by deep convection, convergence lines and orographic enhancement. The evolution of the case-study MD can be divided into two stages: initially the MD is completely embedded in a close-to-saturated environment up to mid-troposphere, whilst in the following stage the intrusion of low-potential-temperature dry air at low- and mid-levels starts interacting with the MD. During this latter stage, the dry-air intrusion brings in low PV-air towards the centre of the depression. Further analysis of the case study takes advantage of a system-relative framework to look into detail at the time evolution of dynamic and thermodynamic parameters around the storm centre and at its small- and meso-scale structure. For example, the 1.5 km-spacing simulation enables us to highlight the presence of individual vorticity towers embedded within the MD. In summary, using a suite of high-resolution numerical simulations of a case-study MD, we are able to achieve a detailed understanding of its structure and dynamics, highlighting the processes driving its evolution.

How to cite: Menon, A., Volonté, A., Turner, A., and Hunt, K.: Structure and dynamics of a case-study monsoon depression in high-resolution numerical simulations using the Met Office Unified Model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16658, https://doi.org/10.5194/egusphere-egu2020-16658, 2020.

EGU2020-17026 | Displays | AS1.22

Disentangling the mechanisms of wave-convection coupling in the tropics

Corinna Hoose, Hyunju Jung, Peter Knippertz, Tijana Janjic, Yvonne Ruckstuhl, and Robert Redl

Tropical weather prediction remains one of the main challenges in atmospheric science due to a combination of insufficient observations, data assimilation algorithms optimized for midlatitudes and large model errors. Due to a strong dependency of many people in the tropics on rainfall variability, combined with a high vulnerability, improved precipitation forecasts have the potential to create substantial benefits in areas such as agriculture, water management, energy production and disease prevention.

Recent studies found that the coupling of equatorial waves to convection is key to improving weather forecasts in the tropics on the synoptic to subseasonal timescale but many models struggle to realistically represent this coupling. Here we use aquaplanet simulations with the ICOsahedral Nonhydrostatic (ICON) model with a 13 km horizontal grid spacing to study the underlying mechanisms of convectively coupled equatorial waves in an idealized framework. We filter the divergence at 200 hPa using a standard wave filtering tool tapering to zero that allows us to identify dynamical characteristics of convectively coupled waves in our simulations. To diagnose thermodynamical aspects of wave-convection couplings, we compare the obtained waves to the total precipitable water and analyze the spatial variance of the budget analysis for column-integrated moist static energy. The same filtering tool and diagnostics are carried out on a realistic ICON simulation with a 2.5 km horizontal grid spacing from the DYnamics of the Atmospheric general circulation Modeled On Non-hydrostatic Domains (DYAMOND) project.

In the future we plan to run and analyze idealized tropical channel simulations with 2.5 km horizontal resolution, i.e. using the same grid spacing as in the DYAMOND simulation. The comparison between the idealized and the realistic simulations identifies mechanisms of wave-convection coupling. In addition, we will apply this set of diagnostics to forecast experiments using different approaches of data assimilation.

 

How to cite: Hoose, C., Jung, H., Knippertz, P., Janjic, T., Ruckstuhl, Y., and Redl, R.: Disentangling the mechanisms of wave-convection coupling in the tropics, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17026, https://doi.org/10.5194/egusphere-egu2020-17026, 2020.

EGU2020-18988 | Displays | AS1.22

Quantifying Convective Aggregation using the Moist Tropical Margin’s Length

Julia Windmiller, David Leutwyler, and Tom Beucler
A peculiar feature of the tropical atmosphere is its tendency to be either rather moist or very dry. It has
been shown that the two states are separated by a sharp margin, well identified by the anti-mode of
the bimodal tropical column water vapor distribution (CWV). Despite recent progress in understanding
physical processes governing the spatio-temporal variability of CWV near the Equator, the behavior of
this meander remains elusive, and we lack a simple framework to understand the bimodality of tropical
CWV in observations. A tendency of the atmosphere to be either moist or dry can also be found in
idealized simulations of radiative-convective equilibrium (RCE). A number of studies assessing self-
aggregation of convection in RCE simulations have indicated that positive feedbacks between
radiation and moisture lead to spatially concentrated moisture in a small area of the computational
domain. As a result, RCE simulations also exhibit a bimodal distribution of CVW and a distinct moist
margin.
Motivated by theory originating from statistical physics, we argue that, in steady-state RCE, the length
of the margin separating moist and dry regions should minimize. Based on these ideas, we design a
diagnostic relating the moist margin length to the circumference of a defined equilibrium shape. Using
that Moist Margin Length Index (MMLi), we assess the evolution of self-aggregation in idealized
convection-resolving RCE simulations and contrast it to the oscillations of the Atlantic Inter-Tropical
Convergence Zone in the ERA5 reanalysis product.
We find that MMLi successfully describes aspects of convective organization not captured by more
traditional metrics of convective organization (e.g., the CVW's interquartile range) while offering a new
way to characterize the seasonal cycle of convective organization in the Atlantic ITCZ. Overall, our
new framework uses the moist meander margin to connect the observationally-motivated, object-
oriented view of convective organization with the processes driving the spatio-temporal evolution of
the CWV field. It can be broadly deployed across models and observations to lead further insight into
the bimodal nature of CWV while offering an efficient and visual way to quantify convective
organization.

How to cite: Windmiller, J., Leutwyler, D., and Beucler, T.: Quantifying Convective Aggregation using the Moist Tropical Margin’s Length, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18988, https://doi.org/10.5194/egusphere-egu2020-18988, 2020.

EGU2020-19806 | Displays | AS1.22

The dynamical composition of the Madden-Julian oscillation

José M. Castanheira and Carlos A. F. Marques

The Madden-Julian oscillation (MJO) is a major intraseasonal tropical atmospheric mode which modulates the precipitation in the Tropical Indian and Pacific  oceans. It is a large atmospheric convective system, dominated the zonal wave number one scale, that moves eastward from the east coast of Africa to eastern Pacific in a time scale of  30-70 days.

The MJO can have impact in global weather but is yet poorly simulated in most atmospheric circulation models. Therefore, it is important to understand the convective-dynamical nature of the MJO to understand the reasons for its poor representation in models.

Here we present a diagnostic study of the MJO by decomposing the circulation associated with a multivariate MJO index onto 3-Dimensional inertio-gravitic and Rossby modes, based on the ERA-I reanalysis. Results show that the main dynamical features of MJO are represented by  a combination of  Kelvin and the first (lr = 1) equatorial Rossby modes with zonal wavenumbers 1 to 4. The vertical structures of the waves correspond to a first baroclinic mode in the troposphere. Moreover, a space–time spectral analysis confirmed the existence of an eastward moving MJO signal in the equatorial Rossby modes.

Nonlinear interactions between the westward moving equatorial Rossby waves and eastward moving Kelvin waves may be the cause for the slow eastward progression of the MJO. 

How to cite: Castanheira, J. M. and Marques, C. A. F.: The dynamical composition of the Madden-Julian oscillation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19806, https://doi.org/10.5194/egusphere-egu2020-19806, 2020.

EGU2020-20548 | Displays | AS1.22

Impact of the current feedback on the representation of tropical cyclones in coupled models

Lisa Maillard, Julien Boucharel, Lionel Renault, and Thomas Arsouze

Tropical Cyclones (TCs) are among the most destructive natural phenomena on Earth and severely impact nearly a billion people. Coupled models have become a necessary tool to improve our knowledge on those natural hazards. Improving their ability to statistically represent TCs is of prior importance. In the present study, we investigate the impact of the mechanical interaction between the surface oceanic current and the atmosphere (i.e., the Current FeedBack, CFB) on the statistic of TCs in different basins. We perform sensitivity experiments using the EC-Earth model in its High-Resolution version (1/12˚), by switching on and off CFB. As CFB has been shown to strongly improve the realism of the oceanic circulation at both large scale and mesoscale, we expect an improvement, i.e., a better realism, of the statistical TCs representation when CFB is taken into account in the model. Improving coupled models will help design forecast schemes with lead times longer than those currently provided by operational forecasts centers.

How to cite: Maillard, L., Boucharel, J., Renault, L., and Arsouze, T.: Impact of the current feedback on the representation of tropical cyclones in coupled models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20548, https://doi.org/10.5194/egusphere-egu2020-20548, 2020.

This presentation will focus on simulations of the early stages of Hurricane Nadine (2012), which interacted with the SAL and never intensified beyond a minimal hurricane. Given the complexity of aerosol effects on cloud microphysics and radiation and their subsequent effects on deep convective clouds, there is a need to assess the combined microphysical and radiative effects of aerosols. We use the Goddard Space Flight Center version of the Weather Research and Forecasting model with interactive aerosol-cloud-radiation physics to study the influence of the SAL and other aerosols (sea salt and black/organic carbon) on Nadine via a series of model sensitivity runs. The results from the control experiment with all aerosols will be compared to the dropsonde and CPL aerosol lidar backscatter data collected during the NASA Hurricane and Severe Storm Sentinel (HS3) field campaign. Comparison of model results and dropsonde data shows evidence of the intrusion of Saharan air into the storm core. Simulation results also show the possible intrusion of biomass-burning aerosols that originated from forest fires in the Northwestern United States a few days before Nadine reached hurricane strength. In addition, we will also present results from three sets of 30-member ensemble simulations: 1) without aerosol coupling, 2) with all aerosols, and 3) with only dust aerosol, to study the aerosol impact on Nadine.

How to cite: Shi, J., Braun, S., Tao, Z., and Sippel, J.: Influence of Saharan Dust and Other Aerosols on Hurricane Nadine (2012) as Revealed by the Comparison of Ensemble Model Results and NASA HS3 Data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12456, https://doi.org/10.5194/egusphere-egu2020-12456, 2020.

The Quasi-Biweekly Oscillation (QBWO), with a period between the synoptic scale and the Madden Julian Oscillation (MJO), is an important component of tropical intraseasonal variability (ISV). While this mode has received a lot of attention over India (during the summer monsoon) and South China sea region, less attention has been paid on South-western Indian Ocean (SWIO). Apart from improving our understanding of ISV, this mode is important in the SWIO during boreal winter as this is an active basin for tropical cyclones (TC), and the QBWO significantly influences TCs. Here we study details of the genesis of the QBWO, its propagation, vertical structure and evolution. The data used comprises of NCEP-NCAR and ERA-interim reanalysis and NOAA outgoing longwave radiation (OLR) from 2000-2010. A composite analysis based on 10-30 day filtered data during the boreal winter reveals a well-organized convectively-coupled wave-train pattern, namely the QBWO, over the SWIO. It emerges from south of the equator (5S), between 50-80E, and then propagates south-westward. The horizontal structure exhibits a slight southwest-northeast tilt, but mainly longitudinal elongation. After arriving Madagascar, the system shows more pronounced southward migration. Further, negative (positive) OLR anomalies are tightly coupled with a cyclonic  (anticyclonic) circulation at 850 hPa. In the end, the QBWO with associated anomalous convection dies down near 40S, between 40-70E. Overall, over this oceanic basin, the QBWO has a period of approximately 18 days, wavelength of about 5000-6000 km, a southward (westward) phase speed of 1.9 (2.7)°/day and a near zero group velocity. Near equator, the system emerges with an equivalent barotropic structure. When mature with strongest convection around 10-20S, the system becomes weakly baroclinic, with relative vorticity anomaly changing sign near 400 hPa, and in the dying phase after 30S, the QBWO becomes equivalent barotropic again. Finally, the centres of relative vorticity and vertical motion near the equator are consistent with the characteristics of equatorial Rossby waves, whereas the cyclonic circulation is tightly coupled with anomalous convection as the wave moves away from the equator.

How to cite: Ghatak, S. and Sukhatme, J.: South-westward Propagating Quasi-biweekly Oscillation over South-western Indian Ocean during Boreal Winter, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1036, https://doi.org/10.5194/egusphere-egu2020-1036, 2020.

This study investigates the intensity change of binary tropical cyclones (TCs) under the influence of their mutual interaction in an idealized three-dimensional full-physics numerical model with a finest horizontal resolution of 3 km. The two identical TCs merge within the initial separation distance of 600 km.

Due to the interaction between binary TCs, the intensity evolution presents two weakening stages and an unchanged stage between them. Such intensity change of each one in binary TCs is correlated to the upper-layer vertical wind shear (VWS) caused by the other TC. During the first stage, the upper-layer anticyclone (ULA) of one TC results in the upper-layer VWS and ventilates the warm core of the other TC above the outflow layer, which causes the intensity of the binary TCs decreasing. During the second stage, as the ULA stretches downward and outward, the upper-layer VWS changes to the opposite direction, along with the intensity decreasing first and then increasing. Meanwhile, the intensity of the binary TCs stays unchanged. In the last stage, the binary TCs weaken again as the upper-layer VWS increases to some extent except the merging cases. When the two TCs approach each other before merging, the upper-layer VWS in one TC is almost caused by the upper-layer cyclone and outflow of the other, which induces highly asymmetric structure and weakens the vortex. In addition, the horizontal size of the ULA quantified by the Rossby radius of deformation seems to be a critical separation distance of binary TCs, exceeding which the VWS is small enough to influence the intensity.

How to cite: Liu, H.: Intensity Change of Binary Tropical Cyclones in an Idealized Three-Dimensional Model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1215, https://doi.org/10.5194/egusphere-egu2020-1215, 2020.

EGU2020-1704 | Displays | AS1.22

Inner-core dynamics during the rapid intensification of Hurricane Wilma (2005) with a steady radius of the maximum wind

Nannan Qin, Da-Lin Zhang, William Miller, and Chanh Kieu

Recent studies show that some hurricanes may undergo rapid intensification (RI) without contracting the radius of maximum wind (RMW). A cloud-resolving WRF-prediction of Hurricane Wilma (2005) is used herein to examine what controls the RMW contraction and how a hurricane could undergo RI without contraction. Results show that the processes controlling the RMW contraction are different within and above the planetary boundary layer (PBL). In the PBL, radial inflows contribute to contraction, with frictional dissipation acting as an inhibiting factor. Above the PBL, radial outflows and vertical motion govern the RMW contraction, with the former inhibiting it. A budget analysis of absolute angular momentum (AAM) shows that the radial AAM flux convergence is the major process accounting for the spinup of the maximum rotation, while the vertical flux divergence of AAM and the frictional sink in the PBL oppose the spinup. During the RI stage with no RMW contraction, the local AAM tendencies in the eyewall are smaller in magnitude and narrower in width than those during the contracting RI stage. In addition, the AAM following the time-dependent RMW decreases with time in the PBL and remains nearly constant aloft during the contracting stage, whereas it increases during the non-contracting stage. These results reveal different constraints for the RMW contraction and RI, and help explain why a hurricane vortex can still intensify after the RMW ceases contraction

How to cite: Qin, N., Zhang, D.-L., Miller, W., and Kieu, C.: Inner-core dynamics during the rapid intensification of Hurricane Wilma (2005) with a steady radius of the maximum wind, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1704, https://doi.org/10.5194/egusphere-egu2020-1704, 2020.

The western North Pacific (WNP) is one of the most active tropical cyclone (TC) regions, which can inflict enormous death and massive property damage to surrounding areas. Although many studies about tropical cyclone activities on multi-timescales have been done, most of them focus on the entire basin, variations within the basin deserve more investigations. Besides TC characteristics on different timescales, to investigate the impacts of environment variables on TC and provide informative factors for prediction is another concern in the research community. In this study, we adopt several data science techniques, including Gaussian kernel estimator, wavelet, cross-wavelet coherence and regression analyses, to explore the spatiotemporal variations of TC genesis and associated environmental conditions. Significant semiannual and annual variations of TC genesis have been found in the northern South China Sea (NSCS) and oceanic areas east of the Philippines (OAEP). In the southeast part of WNP (SEWNP), TC genesis shows prominent variations on ENSO time scale. With reconstructed TC series on those frequencies, we further quantify the influences of environmental variables on the primary TC signals over WNP. About 40% of the identified TC variance over NSCS and OAEP can be explained by variability in vertical shear of zonal wind and relative humidity. In the SEWNP, TC genesis reveals strong nonlinear and non-stationary relationships with vertical shear of zonal wind and absolute vorticity. Besides, A probabilistic clustering algorithm is used to describe the TC tracks in the WNP. The best track dataset from JMA is decomposed into three clusters based on genesis location and curvature. For each cluster, we analyze the relationships between TC properties, such as genesis location, trajectory and intensity, and associated environmental conditions using the self-organizing map. The spatial patterns of sea surface temperature have huge impacts on TC genesis location, while the trajectory is largely influenced by geopotential height.

How to cite: Xiong, R. and Lu, M.: Tropical cyclone genesis and trajectory characteristics in the western north Pacific, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2934, https://doi.org/10.5194/egusphere-egu2020-2934, 2020.

EGU2020-3277 | Displays | AS1.22

Coupled tropical cyclone seasonal forecasting system over the Northwest Pacific Ocean in NMEFC

Yunfei Zhang, Xiang Li, Tiejun Ling, Chenqi Wang, and Hongyu Qu

Tropical cyclone (TC) activity has significant seasonal, interannual and interdecadal variations. Accurate prediction of TC seasonal activities before the onset of the coming TC season (June-November) can provide sufficient time for the government and the public to prepare for tropical cyclone disasters and minimize risks and life losses.
Based on COAWST model, we developed a new regional coupled seasonal forecasting system for the Northwest Pacific Ocean including a series of technology improvements. The results of multi-year hindcast experiments show that the coupled seasonal forecasting system can effectively improve the tropical cyclone frequency and intensity forecast compared to the CFSv2 real-time seasonal forecast, especially the tropical cyclone frequency forecast of the TC exceeding the typhoon level, but there is still a certain gap between the results in the forecasting system and the observed TC frequency and intensity, which is mainly reflected in the fact that the forecasting season has a higher frequency of TCs and the peak of strong TCs is relatively weaker. This gap may be caused by the forecasting bias of the sea surface temperature.

How to cite: Zhang, Y., Li, X., Ling, T., Wang, C., and Qu, H.: Coupled tropical cyclone seasonal forecasting system over the Northwest Pacific Ocean in NMEFC, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3277, https://doi.org/10.5194/egusphere-egu2020-3277, 2020.

EGU2020-3772 | Displays | AS1.22

Prominent influence of salinity on Atlantic hurricane rapid intensification

Karthik Balaguru, Gregory Foltz, Ruby Leung, John Kaplan, Wenwei Xu, Nicolas Reul, and Bertrand Chapron

Rapid Intensification (RI) of hurricanes is difficult to predict and poses a formidable threat to coastal populations. While a warm upper-ocean is well-known to favor RI, the role of salinity is less clear. In this study, using a suite of observations, we demonstrate that the subsurface oceans' influence on Atlantic hurricane RI exhibits two regimes. In the western region, which includes the Gulf of Mexico and the western Caribbean Sea, temperature stratification plays an important role in hurricane RI with little impact from salinity. On the other hand, in the eastern region dominated by the Amazon-Orinoco plume, salinity stratification prominently impacts RI. While a weak temperature stratification aids cold wake reduction for hurricanes in the western region, a strong salinity stratification causes less hurricane-induced mixing and surface cooling in the eastern region. Finally, in both regions, the relevance of the cold wake, and consequently the ocean sub-surface, is enhanced during RI compared to weaker intensification.

How to cite: Balaguru, K., Foltz, G., Leung, R., Kaplan, J., Xu, W., Reul, N., and Chapron, B.: Prominent influence of salinity on Atlantic hurricane rapid intensification, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3772, https://doi.org/10.5194/egusphere-egu2020-3772, 2020.

The island of Sumatra is characterized by extremely high average precipitation accumulation dominated by a strong diurnal cycle of convection, which develops over steep its topography. As a result, the island often suffers from precipitation driven natural hazards, which account for more than 50% of all natural disasters. Such hazardous events inflict great socio-economic loss and damage.

This study addresses this topic via a synergistic methodology employing analysis of meteorological data (precipitation, surface winds) and three independent datasets of floods, in order to consistently analyze spatio-temporal variability in flooding events and the environmental conditions leading to them. Two flood databases were derived from crowd-sourcing: Twitter and local papers. Additionally, the database from Indonesian agency BNPB was used. All three datasets were analyzed independently for the 2014-2018 period. While not all floods are identified in every data base, the results obtained from our analyses agree for all key elements of this study, providing cross calibration and increasing confidence in our findings.

On a subseasonal time scale, the amount of rainfall over the island is variable as well and strongly modulated by eastward propagating modes of organized convection: the Madden-Julian Oscillations (MJO) and convectively coupled Kelvin waves (CCKW), both of which affect the local diurnal cycle through multi-scale processes. This study investigates the relationship between those two modes of organized convection and flooding in Sumatra using several data forms of flood validation. It is shown that CCKWs constitute a critical dynamical predictor for flood onset.

Although our results agree with importance of MJO, indicated by previous studies, we find that only about 27% of floods in Sumatra were immediately preceded by favorable MJO conditions and all of them were in fact also associated with a CCKW embedded within an envelope of enhanced MJO convection. This was the case during the flood in Padang on 31 May, 2017, when the MJO was active over the Indian Ocean but its enhanced precipitation had not yet reached Sumatra. Instead, a strong CCKW, which initiated over eastern Africa, brought anomalous precipitation exceeding 10 mm/day to Padang and triggered a flood.

Comprehensive analysis shows that nearly half of robust CCKW events, which propagated between 80E and 110E, were associated with floods in Sumatra. From a different perspective, nearly all of floods in Sumatra were preceded by anomalous precipitation associated with a CCKW and about 60% of floods in Sumatra were immediately preceded by a strong CCKW event. This percentage is substantially higher than for favorable MJO conditions, indicating stronger interaction of local convection with CCKWs. Even though CCKW activity is modulated by the MJO itself and more CCKWs are found when the MJO is active in the Indian Ocean, during analyzed 2014-2018 period nearly 30% were associated with CCKW alone. Therefore, this study shows that CCKWs are important contributor to extreme weather in Sumatra and constitute a potential source of predictability of such hazardous events.

How to cite: Baranowski, D.: Convectively coupled Kelvin waves contribution to hazardous weather in Sumatra., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6149, https://doi.org/10.5194/egusphere-egu2020-6149, 2020.

EGU2020-7306 | Displays | AS1.22

Assessing future hurricane risk in the Caribbean based on large-scale predictor fields

Peter Pfleiderer and Carl-Friedrich Schleußner

Hurricanes are the most damaging natural disasters in the Caribbean and global warming is expected to increase their impacts. It is well understood that tropical cyclones (TC) will intensify as sea surface temperatures warm and that the amount of precipitation brought by these TCs is going to increase with the water holding capacity of the atmosphere. However, for an assessment of future hurricane risk in the Caribbean it also important to better understand whether and how the overall frequency of tropical cyclones might change.

Projecting future tropical cyclone activity remains challenging because of the weak representation of tropical cyclones in most global circulation models. Here we want to overcome this shortcoming by estimating hurricane risk indirectly based on favorable climatic conditions in the region. These large-scale predictor fields are easier to model and therefore allow for an improved assessment of future hurricane risk.

We define hurricane risk as the accumulated energy that TCs produce in proximity of Caribbean islands. Using novel statistical methods, we identify regions of sea surface temperature, wind speeds and sea level pressure with predictive power for the next weeks hurricane activity. Based on these predictors we construct a classification model to estimate the probability of having TCs in proximity of islands and their strength for the following week. The expected value of seasonal hurricane risk based on these weekly probabilities shows high skill in reproducing the observational record.

Applying the same hurricane risk model to climate projections from global circulation models allows us to estimate future hurricane risk without relying on the ability of climate models to adequately represent tropical.

How to cite: Pfleiderer, P. and Schleußner, C.-F.: Assessing future hurricane risk in the Caribbean based on large-scale predictor fields, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7306, https://doi.org/10.5194/egusphere-egu2020-7306, 2020.

Extreme updrafts (stronger than 10 m s-1) have been observed in the tropical cyclone core region, which have profound implications to tropical cyclone intensification and structure change. Since extreme updrafts in the tropical cyclone are difficult to observe, their features and the associated mechanisms for formation and influences on tropical cyclones remain poorly understood. This study presents an analysis of extreme updrafts in a strong tropical cyclone that was simulated with the large-eddy simulation technique and the finest grid spacing of 37 meters. The simulated tropical cyclone experiences the vertical wind shear of about 5 m s-1 in a typical large-scale evironment in the western North Pacific. The simulated extreme updrafts in the inner core region exhibit the high frequency at the altitudes of ~ 750 m, 6.5 km and 13 km. The extreme updrafts in the inflow and outflow layers are closely associated with the Richardson Number of less than 0.25, indicating their relationship with severe turbulence caused by strong vertical wind shears. The extreme updrafts in the middle layer are associated with the strong convective activity. The details of the structures of the extreme updrafts are discussed.

How to cite: Wu, L.: Large-Eddy Simulation of Extreme Updrafts in the Tropical Cyclone Inner Core, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9581, https://doi.org/10.5194/egusphere-egu2020-9581, 2020.

A recently further refined hurricane warm core retrieval algorithm is applied to the NOAA-20 and S-NPP Advance Microwave Temperature Sounder (ATMS), the Advanced Microwave Sounding Unit-A (AMSU-A) and the Fengyun-3D (FY-3D) microwave temperature sounding instrument (MWTS) brightness temperature observations within and around Hurricanes and incorporated into A four-dimensional variational (4D-Var) vortex initialization (VI) system is developed for a nonhydrostatic axisymmetric numerical model with convection accounted for (the RE87 model). It is shown that the temporal evolution of the ATMS and AMSU-A derived maximum warm core temperature anomalies follow more closely with that of the minimum mean sea level pressure and slightly less closely with the maximum sustained wind, and the radii of the ATMS derived warm cores at 4 and 6 K compared favorably with the 34 kt and 50 kt wind radii during the entire life span of Hurricane Irma in 2017. The vertical extend of the warm core toward the lower levels increases with increasing intensity when Irma experiences a strong intensification due to an enhanced latent heat release associated with diabatic processes. The multi-polar-orbiting operational meteorological satellites can well capture the TC inner cores’ diurnal cycle with a maximum around midnight. A model fit to satellite microwave retrievals of tropical cyclone (TC) warm-core temperatures from the above mentioned three polar-orbiting satellites and and total precipitable water (TPW) Global Change Observation Mission  – Water Satellite 1 produced a significantly improved intensity forecast of Hurricane Florence (2018) and Typhoon Mangkhut (2018), with more realistic vertical structures of all model state variables (e.g., temperature, water vapor mixing ratio, liquid water content mixing ratio, tangential and radial wind components, and vertical velocity) are obtained when compared with a parallel run initialized simply by the European Centre for Medium-Range Weather Forecasts ERA5 reanalysis.

How to cite: Zou, X. and Tian, X.: Satellite Microwave TC Warm-core Retrieval for a 4D-Var Vortex Initialization Using a Nonhydrostatic Axisymmetric Model with Convection Accounted for, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13044, https://doi.org/10.5194/egusphere-egu2020-13044, 2020.

EGU2020-15555 | Displays | AS1.22

Hurricane Eye Morphology

Weicheng Ni, Ad Stoffelen, and Kaijun Ren

Among all kinds of natural disasters, hurricanes are regarded as one of the most destructive, which can cause tremendous losses to the global economic system and ecosystem every year. However, until now, there remain many issues unknown about hurricane dynamics, while hurricanes undergo amplification, shearing, eyewall replacements, diurnal influences, and so forth. Precise morphology parameters, extracted from high-resolution spaceborne Synthetic Aperture Radar (SAR) image, can play an essential role in further exploring and monitoring the hurricane dynamics. Moreover, these morphology parameters may help to build guidelines for the wind calibration of the more plentiful, but lower resolution scatterometer wind field data in hurricane events in order to better link scatterometer wind fields to hurricane categories. In this paper, we have developed a new method for extracting the hurricane eyes from C-band SAR data by constructing Gray Level-Gradient Co-occurrence Matrix (GLGCM) for each image. The hurricane eyewall (HE) area is determined with a 2-dimensional vector, which is automatically generated by maximizing the conditional entropy of HE area in GLGCM. Subsequently, we select the HE pixels based on minimizing the variance of normalized radar cross-section (NRCS) values of the pixel set chosen. The texture information of HE can be adequately preserved in this process. The experimental results prove the effectiveness of our method. Notably, the HE extracted with this automatic method is still in line with the visually observed eyewall even when the hurricane is weak or the eyewall is unclosed. Compared with the morphological analysis and wavelet analysis methods proposed in other papers, the approach developed here is able to accomplish in a simpler way with equally satisfying results. In conclusion, this study can provide a new choice for hurricane eye morphology extraction.

How to cite: Ni, W., Stoffelen, A., and Ren, K.: Hurricane Eye Morphology, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15555, https://doi.org/10.5194/egusphere-egu2020-15555, 2020.

Rapid intensification process (RI) still challenges the tropical cyclone (TC) intensity prediction. The convective structure evolution during RI process were explored by using the Himawari-8 satellite data in the western North Pacific. 39 TCs underwent at least one RI process during 2015-2017 and the RI-onset, RI-continue, and RI-end episodes were identified in each one of the RI events based on JTWC best track data.

The differences between the infrared channel and water vapor channel brightness temperature (IRWV) were calculated and the negative pixel values of IRWV were considered as deep convection areas. The radial and azimuthal profiles and the morphological features were extracted from 3-hour interval images and several key patterns and the rules considering the location, shapes, and magnitude of the IRWV were identified through the whole RI process. The composite analysis shows that each TC appears negative IRWV during the RI process, however, not all TCs demonstrate significant changes either in areas nor patterns, which indicate that the deep convection may not be a necessary condition for RI occurrence. Compared with the Non-RI cases, the development and maintenance of a good spin structure of the negative IRWV were considered as a crucial condition for the TC intensification. The RI-onset periods were mostly connected with the sudden change of IRWV and the inward movement to the inner-core area. The pinhole eye features were normally a sign of continue RI, while the appearance of big eye features, indicates the ending of RI process. It was suggested that the IRWV feature combined with the TC structure feature can be utilized to skillfully predict the episodes of RI. More RI events are expected to involved in the current study and a CART4.5 decision tree algorithm with the aforementioned rules was also under explored.

How to cite: Zhang, D. and Zhang, J.: Topical Cyclone Convection Structure Evolution during Rapid Intensification using Himawari-8 Satellite, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18605, https://doi.org/10.5194/egusphere-egu2020-18605, 2020.

EGU2020-20341 | Displays | AS1.22

Outgoing Long Wave Radiation Dipole of Tropical Cyclones

Mohan Smith and Ralf Toumi

Remote (r ≤ 1800km) outgoing longwave radiation (OLR) fields are investigated in observations, the ECMWF ensemble forecast and reanalysis data. A large scale dipole pattern of low and high fluxes are found in both the observations and model. Low OLR regions are positioned within the cyclone circulation and high OLR regions are found 500-1500km to the north west of the TC. The position of the high OLR region rotates anticlockwise about the TC center as the TC motion vector rotates clockwise from westward to eastward. There is a strong association between the low level wind divergence fields and the high OLR remote region. We propose this remote high OLR region is of interest regarding TC track forecasts. Sub-ensembles selected upon the location of the remote high OLR region improved track forecasts improved by 15\% at 6hrs lead time. This technique out performs those sub-ensembles selected by the inner 750km TC OLR signal, however the best skill improvement in the study selects sub-ensembles by a 3600x3600km TC centered OLR field.

How to cite: Smith, M. and Toumi, R.: Outgoing Long Wave Radiation Dipole of Tropical Cyclones, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20341, https://doi.org/10.5194/egusphere-egu2020-20341, 2020.

AS1.23 – Mid-latitude Cyclones and Storms: Diagnostics of Observed and Future Trends, and related Impacts

EGU2020-19711 | Displays | AS1.23 | Highlight

The response of the Northern Hemisphere storm tracks and jetstreams to climate change in the CMIP3, CMIP5, and CMIP6 climate models

Ben Harvey, Peter Cook, Len Shaffrey, and Reinhard Schiemann

Understanding and predicting how extratropical cyclones might respond to climate change is essential for assessing future weather risks and informing climate change adaptation strategies. Climate model simulations provide a vital component of this assessment, with the caveat that their representation of the present-day climate is adequate. In this study the representation of the NH storm tracks and jet streams and their responses to climate change are evaluated across the three major phases of the Coupled Model Intercomparison Project: CMIP3 (2007), CMIP5 (2012), and CMIP6 (2019). The aim is to quantity how present-day biases in the NH storm tracks and jet streams have evolved with model developments, and to further our understanding of their responses to climate change.

The spatial pattern of the present-day biases in CMIP3, CMIP5, and CMIP6 are similar. However, the magnitude of the biases in the CMIP6 models is substantially lower in the DJF North Atlantic storm track and jet stream than in the CMIP3 and CMIP5 models. In summer, the biases in the JJA North Atlantic and North Pacific storm tracks are also much reduced in the CMIP6 models. Despite this, the spatial pattern of the climate change response in the NH storm tracks and jet streams are similar across the CMIP3, CMIP5, and CMIP6 ensembles. The SSP2-4.5 scenario responses in the CMIP6 models are substantially larger than in the corresponding RCP4.5 CMIP5 models, consistent with the larger climate sensitivities of the CMIP6 models compared to CMIP5.

How to cite: Harvey, B., Cook, P., Shaffrey, L., and Schiemann, R.: The response of the Northern Hemisphere storm tracks and jetstreams to climate change in the CMIP3, CMIP5, and CMIP6 climate models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19711, https://doi.org/10.5194/egusphere-egu2020-19711, 2020.

EGU2020-3946 | Displays | AS1.23

Midlatitude cyclone processes as a key to understanding climate sensitivity

Daniel McCoy, Paul Field, Alejandro Bodas-Salcedo, Gregory Elsaesser, and Mark Zelinka

Global climate models (GCMs) differ greatly in their shortwave cloud feedback. One feature that is consistent across GCMs is a positive shortwave cloud feedback in the subtropics, and a negative shortwave cloud feedback across the midlatitudes. Confidence has grown in the mechanisms that lead to, and the strength of, the subtropical shortwave cloud feedback, but the midlatitude negative shortwave cloud feedback is not well-constrained or well-understood. It is critical to reduce uncertainty in midlatitude shortwave cloud feedback. A more positive midlatitude shortwave cloud feedback in the sixth coupled model intercomparison project (CMIP6) has been found to be one of the primary causes of the increased climate sensitivity of CMIP6 models relative to CMIP5. We show that changes in midlatitude cyclones in future climates are the primary cause of the negative shortwave cloud feedback and are thus key to understanding the high climate sensitivity in the most recent GCMs. Warming-induced changes in cloud liquid water path in midlatitude cyclones can almost entirely be explained by Clausius-Clapeyron increasing moisture convergence into cyclones. One concern with simulating midlatitude cyclones is the lack of predictive skill at low resolution. A more realistic relationship between moisture flux and cyclone liquid content is found at high horizontal resolution (∆x<25km), but the cloud feedback within cyclones can be explained by increased moisture convergence across low- and high-resolution models. Observations and models agree that the extratropical shortwave cloud feedback is moderated by precipitation processes in cyclones. This rules out a large contribution from ice-to-liquid transitions, as has been hypothesized in previous studies. Understanding and constraining these precipitation processes is crucial to constraining the response of midlatitude cyclones to warming and by extension climate sensitivity.

 

Predicted midlatitude cloud feedbacks based on convection-permitting model output (model output is shown in a). The moisture flux along the warm conveyor belt (WCB) of a cyclone plays a central role in determining cyclone cloud liquid water path (LWP) (b). Because WCB scales with water vapor path (WVP) and surface wind speed, WCB moisture flux increases following Clausius-Clapeyron and predicts a negative midlatitude cloud feedback.

 

How to cite: McCoy, D., Field, P., Bodas-Salcedo, A., Elsaesser, G., and Zelinka, M.: Midlatitude cyclone processes as a key to understanding climate sensitivity, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3946, https://doi.org/10.5194/egusphere-egu2020-3946, 2020.

EGU2020-5021 | Displays | AS1.23

Can Extratropical Cyclones Increase Baroclinicty? A Pathway to Cyclone Clustering

Chris Weijenborg and Thomas Spengler

The existence of cyclone clustering, the succession of multiple cyclones in a short amount of time, indicates that the baroclinicity feeding these storms undergoes episodic cycles. With the generally accepted paradigm of baroclinic instability for extratropical cyclones, one would anticipate that clustering coincides with increased baroclinicity, though simultaneously individual cyclones reduce baroclinicity to maintain their growth. This apparent contradiction motivates our hypothesis that some cyclones increase baroclinicity, which could be a pathway for cyclone clustering.

Using a new cyclone clustering diagnostic based on spatio-temporal distance between cyclone tracks, we analyse cyclone clustering for the period 1979 until 2016. We complement this analysis with a baroclinity diagnostic, the slope of isentropic surfaces. With the isentropic slope and its tendencies, the relative roles of diabatic and adiabatic effects associated with extra-tropical cyclones in maintaining baroclinicity are assessed. We first present a case study, for which a sequence of cyclones culminated in severe cyclones due to the fact that one of the storms significantly increased the background baroclinity along which the succeeding storms evolved. The life cycle of these storms is discussed in terms of how the storm changes and uses its environment to attain its intensity. We compare these findings to composites of clustered and non-clustered cyclones to quantify how consistent the proposed clustering-mechanism is.

How to cite: Weijenborg, C. and Spengler, T.: Can Extratropical Cyclones Increase Baroclinicty? A Pathway to Cyclone Clustering, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5021, https://doi.org/10.5194/egusphere-egu2020-5021, 2020.

The sea surface temperature (SST) distribution can modulate the development of extratropical cyclones through sensible and latent heat fluxes. However, the direct and indirect effects of these surface fluxes, and thus the SST, are still not well understood. This study tackles this problem using idealised channel simulations of moist baroclinic development under the influence of surface fluxes. The model is initialised with a zonal wind field resembling the midlatitude jet and a different SST distribution for each experiment, where both the strength and position of the SST gradient are varied.

The surface latent heat flux plays a key role in enhancing the moist baroclinic development, while the sensible heat fluxes play a minor and dampening role. The additional moisture provided by the latent heat fluxes originates from about 1000 km ahead of the cyclone a day prior to the time of the most rapid deepening. When the SST in this region is higher than 15 degrees Celsius, the additional latent heat is conducive to explosive cyclone development. A high absolute SST with a weak SST gradient, however, can lead to a delay of the deepening stage, because of unorganised convection at early stages. In addition, the cyclone can maintain its intensity for a longer period with an SST above 20 degrees Celsius, because there is a continuous and extensive moisture supply from the surface. The cyclone in this case has characteristics of a hybrid cyclone, where the latent heat release near the cyclone’s centre plays a major role in the development.

How to cite: Bui, H. and Spengler, T.: On the Influence of Sea Surface Temperatures on the Development of Extratropical Cyclones, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3502, https://doi.org/10.5194/egusphere-egu2020-3502, 2020.

EGU2020-17644 | Displays | AS1.23

Risk assessment of building damage related to extreme winter windstorms in the canton of Zurich, Switzerland

Thomas Röösli, Christoph Welker, and David Bresch

We compare the risk assessment for storm related building damage based on three different foundations: (1) insurance claims data, (2) modelled building damages based on a historic event set of wind gust data, and (3) modelled building damages based on a probabilistic extension of the historic event set. Windstorms cause large socio-economic damages in Europe. In the canton of Zurich (Switzerland) they are responsible for one third of the building damages caused by natural hazards.

The Wind Storm Information Service (WISC) of the Copernicus Climate Change Service provides open wind gust datasets for the insurance sector to understand and assess the risk of windstorms in Europe. This is the first open climatological data set covering a longer time range than the insurance claims data of most small insurance companies. Our science-practice collaboration is a case study to illustrate how climatological data can be used in risk assessments in the insurance sector and how this approach compares to risk assessments based on proprietary claims data. We describe and use a storm damage model that combines wind gust data with exposure and vulnerability information to compute an event set of modelled building damages. These modelled damages are used to calculate relevant risk metrics for the insurance industry like the annual expected damage (AED) as well as the damage of rare events, with a return period of up to 250 years.

The AED calculated based on the insurance claims data (i.e. the mean damage over the observation period of 35 years) is 2.34 million Swiss Francs (CHF). This is almost double the value of the AED computed based on the storm damage model and historic event set (CHF 1.36 million). The storm Lothar/Martin in December 1999 is the most damaging event in the insurance claims data (CHF 62.4 million) as well as the historic event set (modelled building damage of CHF 62.7 million).

Both the insurance claims data and the modelled building damages based on historic events are not well suited to derive information about rare events with return periods considerably exceeding the observation period. To provide some information about rare events, we propose a new probabilistic event set, by introducing various perturbations, resulting in 4’200 events. This probabilistic event set results in an AED of CHF 1.45 million and a damage amount of CHF 75 million for a return period of 250 years. The probabilistic event set allows for testing the sensitivity of the risk to e.g. portfolio changes and changes in the insurance condition for events of a higher intensity than the historic events.

Our analysis is implemented in the GVZ’s proprietary storm damage model as well as the open-source risk assessment platform CLIMADA (https://github.com/CLIMADA-project/climada_python). This guarantees scientific reproducibility and offers insurance companies the opportunity to apply this methodology to their own portfolio with a low entry threshold.

How to cite: Röösli, T., Welker, C., and Bresch, D.: Risk assessment of building damage related to extreme winter windstorms in the canton of Zurich, Switzerland, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17644, https://doi.org/10.5194/egusphere-egu2020-17644, 2020.

EGU2020-5885 | Displays | AS1.23

Cyclone activities as inferred from the Twentieth Century Reanalysis version 3 (20CRv3) for 1836-2015

Xiaolan Wang, Yang Feng, Rodney Chan, Gilbert P. Compo, Laura C. Slivinski, Bin Yu, Michael Wehner, and Xiao-Yi Yang

Preliminary results obtained from tracking cyclones in the ensemble-average and individual members of the NOAA-CIRES-DOE Twentieth Century Reanalysis version 3 (20CRv3) ensemble for the period 1836-2015 will be presented. Comparison with tracking in the 20CRv2c ensemble-average series will also be shown.

The results indicate that the 20CRv3 is an improvement in representing cyclone climate and variability compared to previous versions (20CRv2c or 20CRv2). However, as in previous versions, the 20CRv3 ensemble-average fields are too smooth to use for tracking cyclones and studying cyclone climate, especially for the period before 1960 for the NH and for the entire reanalysis period for the SH, and that there are still temporal inhomogeneity issues in the 20CRv3, especially in the SH and in the early period for the NH, due to the increases over time of observations available for assimilation. The improvements arise from the use of a higher model resolution and the assimilation of more observations. They include that the 20CRv3 ensemble shows cyclones of higher intensities and a higher number of deep cyclones (center pressure ≤ 960 hPa) in the Northern Hemisphere than the 20CRv2c counterpart. Historical trends of cyclone activity and their uncertainties will be discussed based on the results of tracking the individual members of the 20CRv3 ensemble, with the temporal inhomogeneity issues being taken into account.  

How to cite: Wang, X., Feng, Y., Chan, R., Compo, G. P., Slivinski, L. C., Yu, B., Wehner, M., and Yang, X.-Y.: Cyclone activities as inferred from the Twentieth Century Reanalysis version 3 (20CRv3) for 1836-2015, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5885, https://doi.org/10.5194/egusphere-egu2020-5885, 2020.

EGU2020-15778 | Displays | AS1.23

An Inter-Comparison of Arctic Synoptic Scale Storms between Four Global Reanalysis Datasets

Alexander Vessey, Kevin Hodges, Len Shaffrey, and Jonathan Day

Arctic sea ice has reduced significantly over recent decades and is projected to reduce further over this century. This has made the Arctic more accessible and increased opportunities for the expansion of business and industrial activities.  As a result, the exposure and risk of humans and infrastructure to extreme storms will increase in the Arctic.

Our understanding of the current risk from storms comes from analysing the past, for example, by using storm tracking algorithms to detect storms in reanalysis datasets.  However, there are multiple reanalysis datasets available from different institutions and there are multiple storm tracking methods.  Previous studies have found that there can be differences between reanalysis datasets and between storm tracking methods in the climatology of storms, particularly in mid-latitude regions rather than the Arctic.  In this study, we aimed to improve the understanding of Arctic storms by assessing their characteristics in multiple global reanalyses, the ECMWF-Interim Reanalysis (ERA-Interim), the 55-Year Japanese Reanalysis (JRA-55), the NASA-Modern Era Retrospective Analysis for Research and Applications Version 2 (MERRA-2), and the NCEP-Climate Forecast System Reanalysis (NCEP-CFSR), using the same storm tracking method based on 850 hPa relative vorticity and mean sea level pressure.

The results from this study show that there are no significant trends in Arctic storm characteristics between 1980-2017, even though the Arctic has undergone rapid change.  Although some similar Arctic storm characteristics are found between the reanalysis datasets, there are generally higher differences between the reanalyses in winter (DJF) than in summer (JJA).  In addition, substantial differences can arise between using the same storm tracking method based on 850 hPa relative vorticity or mean sea level pressure, which adds to the uncertainty associated with current Arctic storm characteristics.

How to cite: Vessey, A., Hodges, K., Shaffrey, L., and Day, J.: An Inter-Comparison of Arctic Synoptic Scale Storms between Four Global Reanalysis Datasets, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15778, https://doi.org/10.5194/egusphere-egu2020-15778, 2020.

EGU2020-1278 | Displays | AS1.23

Diverse Responses of Polar Mesocyclones Genesis Attributable to Orographic Forcing

Kenta Tamura and Tomonori Sato

Polar mesocyclones (PMCs) are mesoscale, maritime cyclones that occur around the high latitudes in the cold seasons. Over the northern Sea of Japan, PMC frequently occurs with cold air outbreaks from the east of the Eurasian Continent. In this study, effects of the mountains on the eastern end of the Eurasian Continent (Sikhote-Alin mountain range) on the PMCs genesis were examined by 36-years long-term numerical experiments. The sensitivity experiment, in which the Sikhote-Alin mountain range is removed, shows that the number of PMC genesis decreases and the duration between PMCs genesis and landfall becomes shorter compared with realistic experiment. These differences arise only in the southern part of the sea. This result suggests that the effect of the orographic forcing on PMC's behavior varies with the location of the PMCs genesis.

How to cite: Tamura, K. and Sato, T.: Diverse Responses of Polar Mesocyclones Genesis Attributable to Orographic Forcing, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1278, https://doi.org/10.5194/egusphere-egu2020-1278, 2020.

EGU2020-4431 | Displays | AS1.23

An evaluation of East Asian Extratropical cyclones in CMIP5 models and their response to greenhouse warming

Jaeyeon Lee, Jaeyoung Hwang, Seok-Woo Son, and John Gyakum

The extratropical cyclones (ETCs) over East Asia and their possible future changes are evaluated using the Coupled Model Intercomparison Project phase 5 (CMIP5) models. The East Asian ETCs are identified using an automated tracking algorithm applied to the 850-hPa relative vorticity field for both reference data (ERA-Interim reanalysis data) and model data. The CMIP5 models well capture the spatial distribution of East Asian ETC properties, although significant biases are present around the high-topography regions. Based on the individual model biases, Best 5 models are selected and used for examining the future changes of East Asian ETCs. In future climate, Best 5 shows declined cyclogenesis in the leeward side of the Tibetan Plateau, which is partly responsible for the decreased ETC frequency over the western North Pacific. The intensity of individual ETCs is also projected to decrease in a warm climate. These changes could be attributed to the combined effect of increased static stability and decreased vertical wind shear in East Asia, which means reduced local baroclinicity. It is also found that CMIP6 models have smaller bias than Best 5 CMIP5 models, indicating that the result documented in this study may change in quantity when newly-available CMIP6 models are utilized.

How to cite: Lee, J., Hwang, J., Son, S.-W., and Gyakum, J.: An evaluation of East Asian Extratropical cyclones in CMIP5 models and their response to greenhouse warming, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4431, https://doi.org/10.5194/egusphere-egu2020-4431, 2020.

Extratropical cyclones are a dominant feature of the mid-latitudes, as their passage is associated with strong winds, precipitation, and temperature changes. The statistics and characteristics of extratropical cyclones over the North Atlantic region exhibit some fundamental differences between Pre-Industrial (PI) and Last Glacial Maximum (LGM) climate conditions. Here, the statistics are analysed based on results of a tracking algorithm applied to global PI and LGM climate simulations. During the LGM, both the number and the intensity of detected cyclones was higher compared to PI. In particular, increased cyclone track activity is detected close to the Laurentide ice sheet and over central Europe. To determine changes in cyclone characteristics, the top 30 extreme storm events for PI and LGM have been simulated with a regional climate model and high resolution (12.5 km grid spacing) over the eastern North Atlantic and Western Europe. Results show that LGM extreme cyclones were characterised by weaker precipitation, enhanced frontal temperature gradients, and stronger wind speeds than PI analogues. These results are in line with the view of a colder and drier Europe, characterised by little vegetation and affected by frequent dust storms, leading to reallocation and build-up of thick loess deposits in Europe.

How to cite: Pinto, J. G. and Ludwig, P.: Extratropical cyclone characteristics over the North Atlantic and Western Europe during the Last Glacial Maximum, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6659, https://doi.org/10.5194/egusphere-egu2020-6659, 2020.

EGU2020-6829 | Displays | AS1.23

German Bight Storminess over the Last Century

Daniel Krieger, Oliver Krueger, Frauke Feser, Ralf Weisse, Birger Tinz, and Hans von Storch

Assessing past storm activity provides valuable knowledge for economic and ecological sectors, such as the renewable energy sector, insurances, or health and safety. However, long time series of wind speed measurements are often not available as they are usually hampered by inhomogeneities due to changes in the surroundings of a measurement site, station relocations, and changes in the instrumentation. On the contrary, air pressure measurements provide mostly homogeneous time series as the air pressure is usually unaffected by such factors.

Therefore, we perform statistical analyses on historical pressure data measured at several locations within the German Bight (southeastern North Sea) between 1897 and 2018. We calculate geostrophic wind speeds from triplets of mean sea level pressure observations that form triangles over the German Bight. We then investigate the evolution of German Bight storminess from 1897 to 2018 through analyzing upper quantiles of geostrophic wind speeds, which act as a proxy for past storm activity. The derivation of storm activity is achieved by enhancing the established triangle proxy method via combining and merging storminess time series from numerous partially overlapping triangles in an ensemble-like manner. The utilized approach allows for the construction of robust, long-term and subdaily German Bight storminess time series. Further, the method provides insights into the underlying uncertainty of the time series.

The results show that storm activity over the German Bight is subject to multidecadal variability. The latest decades are characterized by an increase in activity from the 1960s to the 1990s, followed by a decline lasting into the 2000s and below-average activity up until present. The results are backed through a comparison with reanalysis products from four datasets, which provide high-resolution wind and pressure data starting in 1979 and offshore wind speed measurements taken from the FINO-WIND project. This study also finds that German Bight storminess positively correlates with storminess in the North-East Atlantic in general. In certain years, however, notably different levels of storm activity in the two regions can be found, which likely result from shifted large-scale circulation patterns.

How to cite: Krieger, D., Krueger, O., Feser, F., Weisse, R., Tinz, B., and von Storch, H.: German Bight Storminess over the Last Century, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6829, https://doi.org/10.5194/egusphere-egu2020-6829, 2020.

EGU2020-7199 | Displays | AS1.23

Feature-based classification of European windstorms

Christian Passow, Uwe Ulbrich, and Henning Rust

Scientific work on European windstorms mainly focused on local damages, location (tracks), temporal evolution or the overall severity, often measured by severity indices of different definitions. Each of the aforementioned windstorm properties is directly related to important characteristics within the windstorm itself, such as wind speed, duration, spatial extent or internal variablity. Variation or changes within these characteritics are therefore defining aspects in the spatial and temproal evolution of windstorm or their overall severity in general. As a step towards a better understanding of such variations, we intend to classify windstorms based on their characteristics. For this purpose, we categorize individual storms based on their characteristics using a K-Means clustering procedure. As a result, we get a catalog of more than 400 storm tracks, each track having properties similar to the 20 most severe storm events in the European region. In an attempt to better understand driving mechanisms behind severe European windstorms, the catalog will be further examined to find key parameters that determine the cluster characteristics, such as large-scale situations or the sequencing of clusters.

How to cite: Passow, C., Ulbrich, U., and Rust, H.: Feature-based classification of European windstorms, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7199, https://doi.org/10.5194/egusphere-egu2020-7199, 2020.

EGU2020-8925 | Displays | AS1.23

Assessing the role of nudging, aerosols and run-up time in medicane simulations with WRF

Juan José Gómez-Navarro, Enrique Pravia-Sarabia, and Juan Pedro Montávez

Medicanes are small-scale cyclones with tropical characteristics that take place in the Mediterranean basin, showing hazardous features such as intense wind gusts and precipitation. Our ability to predict their consequences is of great importance for those cases of medicanes reaching coastal inhabited areas. Succeeding in a precise prediction of their characteristics is heavily subject to getting insight in the fundamental factors that are involved in their genesis, strengthening and maintenance. Given their small nature compared to the synoptic scale, RCMs are specially suitable for the simulation of these storms. However, when using RCMs, there are a number of configurations that must be controlled to specify the way the different physical and chemical mechanisms are solved during the simulation.


In this work, we evaluate the role of three different factors affecting the outcome of WRF, namely the run-up time, the inclusion or not of the on-line simulation of aerosols and the use of spectral nudging. To that end, six different medicanes have been simulated combining different possibilities for the aforementioned factors, resulting in a set of above 360 simulations. Although in principle the on-line simulation of aerosols is expected to have the strongest impact in the simulation of medicanes, it turns out that the run-up time -time delay from the simulation start to the medicane maximum intensity moment- is far more decisive in their successful development than the former. The results are also sensible to the use of spectral nudging, and the three considered factors end up having a considerable impact. Indeed, whereas the majority of their combinations lead to an erratic reproduction of the observed medicanes, there exist some combinations that allow reasonable results, showing that these configurations are in fact interdependent, i.e., the change in the simulation outcome due to a different configuration for one of the factors is dependent on the configuration of the others. This complicates the assessment on the influence of one factor alone, but facilitates gaining insight on the factors that control the genesis and maintenance of medicanes.

How to cite: Gómez-Navarro, J. J., Pravia-Sarabia, E., and Montávez, J. P.: Assessing the role of nudging, aerosols and run-up time in medicane simulations with WRF, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8925, https://doi.org/10.5194/egusphere-egu2020-8925, 2020.

EGU2020-10991 | Displays | AS1.23

Assessing reasons for skilful predictions of winter windstorms over the Atlantic/European region

Lisa Degenhardt, Gregor Leckebusch, and Adam Scaife

Severe Atlantic winter storms are affecting densely populated regions of Europe (e.g. UK, France, Germany, etc.). Consequently, different parts of the society, financial industry (e.g., insurance) and last but not least the general public are interested in skilful forecasts for the upcoming storm season (usually December to March). To allow for a best possible use of steadily improved seasonal forecasts, the understanding which factors contribute to realise forecast skill is essential and will allow for an assessment whether to expect a forecast to be skilful or not.

This study analyses the predictability of the seasonal forecast model of the UK MetOffice, the GloSea5. Windstorm events are identified and tracked following Leckebusch et al. (2008) via the exceedance of the 98th percentile of the near surface wind speed.

Seasonal predictability of windstorm frequency in comparison to observations (based e.g., on ERA5 reanalysis) are calculated and different statistical methods (skill scores) are compared.

Large scale patterns (e.g., NAO, AO, EAWR, etc.) and dynamical factors (e.g., Eady Growth Rate) are analysed and their predictability is assessed in comparison to storm frequency forecast skill. This will lead to an idea how the forecast skill of windstorms is depending on the forecast skill of forcing factors conditional to the phase of large-scale variability modes. Thus, we deduce information, which factors are most important to generate seasonal forecast skill for severe extra-tropical windstorms.

The results can be used to get a better understanding of the resulting skill for the upcoming windstorm season.

How to cite: Degenhardt, L., Leckebusch, G., and Scaife, A.: Assessing reasons for skilful predictions of winter windstorms over the Atlantic/European region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10991, https://doi.org/10.5194/egusphere-egu2020-10991, 2020.

The inter-annual variability of the European windstorm season is dependent on a number of large-scale climate drivers and conditions, for example the North Atlantic Oscillation. For seasonal forecasts to provide valuable information to decision makers about the potential severity of the winter windstorm season, they must capture this relationship between large-scale climate drivers and seasonal windstorm frequency in advance. Here, we examine the performance of the latest state of the art ECMWF seasonal forecast product (SEAS5) in capturing this climate response. We apply a statistical model previously shown to well reproduce the explained behaviour of European windstorms from large-scale climate drivers (Walz et al. 2018) to SEAS5, and examine the choice of statistically significant drivers. The model applied is a stepwise Poisson regression approach to account for serial clustering within inter-annual variability of windstorms, the resultant of which categorizes each windstorm season as either active, neutral or inactive. In particular, we focus on the European region where the explained variance of the statistical model in observations is highest (Walz et al. 2018), the British Isles. In addition to comparing the performance of the model in SEAS5 and in observations, we examine which relationships are not recreated in the seasonal forecast successfully from a dynamical perspective, to provide further insight into the current ability of seasonal forecasts to represent European windstorm inter-annual variability.
 
Reference:
Walz, M. A., Befort, D. J., Kirchner‐Bossi, N. O., Ulbrich, U., & Leckebusch, G. C. (2018). Modelling serial clustering and inter‐annual variability of European winter windstorms based on large‐scale drivers. International Journal of Climatology38(7), 3044-3057.

How to cite: Angus, M. and Leckebusch, G.: How well do seasonal forecasts reproduce European winter storm clustering and its relationship to large-scale climate drivers?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11149, https://doi.org/10.5194/egusphere-egu2020-11149, 2020.

EGU2020-13780 | Displays | AS1.23

The life cycle of cyclones, dry intrusions and cold fronts and their role in air-sea interaction

Vered Silverman, Shira Raveh-Rubin, and Jennifer Catto

Air-sea interaction in the midlatitudes is modulated by the passage of extratropical cyclones and their trailing fronts. Particularly strong ocean heat loss (both sensible and latent) is observed in the post-cold frontal region. In this region, airmasses within the dry intrusion (DI) airstream descend slantwise from the upper troposphere towards the cold trailing front. As the cyclone case-to-case variability is high, understanding the co-occurrence of DIs, cold trailing fronts and cyclones is important for understanding the variability of surface fluxes, especially in regions not usually associated with frequent frontal activity.

 

A climatological study quantifying the co-occurrence of fronts and DIs (Raveh-Rubin and Catto, 2019) found the presence of DIs to be associated with stronger surface heat fluxes. Here the climatological study is extended to account for the cyclone life-cycle by using feature-based identification and tracking in the ERA-Interim dataset, for the 1979-2018 winters. We focus on the relationship between extratropical cyclone characteristics, DIs and cold fronts, their co-evolution throughout the lifetime of a cyclone, and consequently their impact on air-sea interaction.

 

We show that 65-80% of the extratropical cyclones in the storm track region are matched with DIs, mainly during the early stages of the intensification period. Furthermore, cyclones associated with DIs are longer lived, induce up to 50% stronger precipitation in the frontal regions, and up to 60% stronger evaporation, especially in the DI region of influence, compared to non-DI cyclones. These transient events of strong evaporation induced by DIs account up to 40% of the observed climatology, demonstrating the significant role transient weather systems play in the air-sea interaction, at times through a fairly remote influence of the cyclones.

How to cite: Silverman, V., Raveh-Rubin, S., and Catto, J.: The life cycle of cyclones, dry intrusions and cold fronts and their role in air-sea interaction, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13780, https://doi.org/10.5194/egusphere-egu2020-13780, 2020.

EGU2020-11316 | Displays | AS1.23

Cyclones density and characteristics in different reanalyses dataset over South America

Natália Machado Crespo, Rosmeri Porfírio da Rocha, and Eduardo Marcos de Jesus

Cyclones developing over and at the eastern coast of South America impact extreme events over the region. Understanding the present climate is crucial to assess future extremes tendencies, which are important for engineering constructions over the southeast Brazil basin. To evaluate these systems in climate change scenarios it is important to study their preferred region of formation and trajectories in the present climate. Therefore, in this study we tracked cyclones in a period from 1979 to 2018 (present climate) using different reanalyses dataset (CFSR, ERA-Interim and ERA5), pointing out the main cyclogenetic regions affecting South America and discussing the main differences between the different dataset. As a preliminary result, the cyclone tracking shows a higher number of systems in CFSR than in ERA-Interim, which would be explained by the finer resolution of CFSR.  Annually, this difference is about 6%, and seasonally, the difference is smaller in summer (3.5%) and similar (~7%) for the other seasons. The reanalyses identify basically the same four cyclogenetic regions, however, there are differences in the density center position. Other features as lifetime, intensity, traveled distance, and wind extremes associated with the cyclones will be also discussed.

How to cite: Machado Crespo, N., Porfírio da Rocha, R., and Marcos de Jesus, E.: Cyclones density and characteristics in different reanalyses dataset over South America, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11316, https://doi.org/10.5194/egusphere-egu2020-11316, 2020.

EGU2020-16638 | Displays | AS1.23

Representation of the extratropical circulation in the MiKlip decadal prediction system - impacts of resolution and initialization

Jens Grieger, Mareike Schuster, Christopher Kadow, Andy Richling, and Uwe Ulbrich

This study analyzes the representation of the extratropical circulation over the North Atlantic (NA) region using the German decadal prediction system (MiKlip) of two different spatial resolutions. Four quantities are assessed, i.e. the storm track, blocking frequencies, cyclone frequencies, and windstorm frequencies. We investigate the effect of model initialization for the representation of the circulation in a lower resolution (LR, atm: T63L47, ocean: 1.5° L40) and higher resolution version (HR, atm: T127L95, ocean: 0.4° L40) of the decadal prediction system.

While LR shows common deficits in the climatological representation in both the initialized prediction system and the uninitialized historical projection, e.g. an overly zonal extratropical storm track and a deficit in blocking frequencies over the North Atlantic and Europe, the higher resolution version counteracts these biases. The initialized LR prediction system largely overestimates NA cyclone frequency, which is not the case for the uninitialized LR counterpart. This positive bias is mainly due to weak and short lived systems and is an effect of the initialization in the LR prediction system. Similar biases cannot be identified in the windstorm frequency which implies that the short lived cyclones are low of impact with respect to wind speed.

The initialization effect leading to an overestimation of weak and short lived cyclones cannot be found in the HR version. The overall better representation of the extratropical circulation in the HR version leads to an increased decadal prediction skill, which is measured in terms of anomaly correlation, with the increase in resolution for all four quantities. 

How to cite: Grieger, J., Schuster, M., Kadow, C., Richling, A., and Ulbrich, U.: Representation of the extratropical circulation in the MiKlip decadal prediction system - impacts of resolution and initialization, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16638, https://doi.org/10.5194/egusphere-egu2020-16638, 2020.

EGU2020-19358 | Displays | AS1.23

A Eulerian Explosive Cyclogenesis climatology from the ERA5 reanalysis, 1979-2018

Thomas Cropper and Stephanie Allen

Using the criterion of one Bergeron (24 hPa change over 24 h at 60°), we present the creation of a Eulerian explosive cyclogenesis climatology using hourly-temporal resolution data from the European Centre for Medium Range Weather Forecasting’s ERA5 reanalysis (1979-2018). This approach differs to the typically used Lagrangian methodologies adopted by many studies. The climatology created by this approach results in similar patterns to previous studies.

Assessments on the dataset are undertaken to analyse the influence of seasonality, teleconnections, climate change and individual events (the method picks up tropical cyclones as well as mid-latitude storms). The location experiencing the most consistent explosive cyclongenesis conditions (15% of the time during the Northern Hemisphere winter) is to the east of the Avalon Peninsula, Newfoundland. The preferred location of explosive cyclogenesis is shown to change in relation to patterns such as the El Niño Southern Oscillation and North Atlantic Oscillation. Potential applications of the dataset are suggested.

                                                

How to cite: Cropper, T. and Allen, S.: A Eulerian Explosive Cyclogenesis climatology from the ERA5 reanalysis, 1979-2018, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19358, https://doi.org/10.5194/egusphere-egu2020-19358, 2020.

EGU2020-21874 | Displays | AS1.23

High impact storms affecting the Iberian Peninsula during 2017-2019 extended winters

Ana Gonçalves, Margarida L. R. Liberato, Alexandre M. Ramos, and Raquel Nieto

The occurrence of an increasing number of high impact storms over southwestern Europe (e.g. Klaus, 23-24 January 2009 and Xynthia, 27-28 February 2010; Liberato et al. 2011; 2013) has led to the meteorological services of France (Météo-France), Portugal (IPMA) and Spain (AEMET) to assign names to storms, since 1st December 2017. This new list of named storms has the main objective to better inform the general public and media while contributing to increasing public awareness to high impact storms and associated warnings and timely safety recommendations. The Institute of Meteorology of the Freie Universität Berlin has named all pressure systems in Central Europe since 1954; since 1998, lows are given male names and highs are given female names in odd years, and vice versa in even years. This new list built by the southwestern Europe meteorological services has the main difference of naming only high impact storms.

In this study an analysis of the extreme storms affecting the Iberian Peninsula during the 2017-2019 extended winters is performed. From nine named high impact storms during the 2017-2018 season, seven of them affected the Iberian Peninsula region; and from the thirteen high impact storms during 2018-2019 winter, ten of them affected the region. Firstly an assessment of the strong winds, heavy precipitation and socio-economic impacts is presented. Secondly, a characterization of the synoptic conditions and associated extratropical cyclones is performed. Finally, the events are ranked and classified into the groups previously defined on Karremann et al. (2016) and a variability assessment is made in order to understand how their magnitude and frequency of occurrence fits the identified multi-decadal variability.

Acknowledgements

The authors would like to acknowledge the financial support by Fundação para a Ciência e a Tecnologia, Portugal (FCT), through projects PTDC/CTA-MET/29233/2017 and UIDB/50019/2020 – IDL. A.M. Ramos is supported by Scientific Employment Stimulus 2017 from FCT (CEECIND/00027/2017).

References

Karremann et al. (2016) Atmos. Sci. Let., 17: 354-361 DOI: 10.1002/asl.665

Liberato et al. (2011) Weather, 66: 330-334 DOI: 10.1002/wea.755

Liberato et al. (2013) Nat. Hazards Earth Syst. Sci., 13: 2239-2251 DOI: 10.5194/nhess-13-2239-2013

 

How to cite: Gonçalves, A., Liberato, M. L. R., Ramos, A. M., and Nieto, R.: High impact storms affecting the Iberian Peninsula during 2017-2019 extended winters, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21874, https://doi.org/10.5194/egusphere-egu2020-21874, 2020.

Using a recently developed methodology, namely, the multiscale window transform (MWT), and the MWT-based theory of canonical transfer and localized multiscale energetics analysis, we investigate in an eddy-following way the nonlinear eddy-background flow interaction in the North Pacific storm track, based on the ERA40 reanalysis data from ECWMF. It is found that more than 50% of the storms occur on the northern flank of the jet stream, about 40% are around the jet center, and very few (less than 5%) happen on the southern flank. For storms near or to the north of the jet center, their interaction with the background flow is asymmetric in latitude. In higher latitudes, strong downscale canonical available potential energy transfer happens, especially in the middle troposphere, which reduces the background baroclinicity and decelerates the jet; in lower latitudes, upscale canonical kinetic energy transfer intensifies at the jet center, accelerating the jet and enhancing the middle-level baroclinicity. The resultant effect is that the jet strengthens but narrows, leading to an anomalous dipolar pattern in the fields of background wind and baroclinicity. For the storms on the southern side of the jet, the baroclinic canonical transfer is rather weak. On average, the local interaction begins from about 3 days before a storm arrives at the site of observation, achieves its maximum as the storm arrives, and then weakens.

How to cite: Zhao, Y.-B.: The asymmetric eddy-background flow interaction in the North Pacific storm track, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12813, https://doi.org/10.5194/egusphere-egu2020-12813, 2020.

EGU2020-3458 | Displays | AS1.23

Seamless Detection of Cutoff Low and Preexisting Trough

Meiji Honda, Satoru Kasuga, Jinro Ukita, Shozo Yamane, Hiroaki Kawase, and Akira Yamazaki

Cutoff lows are cyclones existing in the upper troposphere developing from precursory preexisting troughs. We introduce a new method to seamlessly detect cutoff lows and even preexisting troughs aiming to improve lead time of meso scale disturbances like tornadoes. The method is based on a geometric character; in this method, a slope defined as the tangential line from a minimum point of each height depression is measured on an isobaric surface. This slope evaluates an intensity and horizontal extension (radius) of each depression. Adopting a mathematical assumption, we successfully achieved to make an algorithm to separate the depression and the local background flow. To remove the background flow enables us to detect both cutoff lows and preexisting troughs seamlessly in reanalysis height fields. So, our method would allow the life cycle to be illustrated continuously from the birth of the cutoff low, that is, from the precursory preexisting trough, and is expected to contribute to the improvement of the lead time for predicting severe weathers. Some further application examples, including tornado accompanying cases, and even for blocking highs, would be shown.

How to cite: Honda, M., Kasuga, S., Ukita, J., Yamane, S., Kawase, H., and Yamazaki, A.: Seamless Detection of Cutoff Low and Preexisting Trough, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3458, https://doi.org/10.5194/egusphere-egu2020-3458, 2020.

A method utilizing a prognostic potential vorticity (PV) inversion is designed and applied to quantify the processes that contribute to the explosive cyclone (EC) development over Northwestern Pacific and Atlantic in boreal winter. The ECs deepening in the two remarked regions are identified and tracked, by using the automated tracking method on ERA-Interim reanalysis data over the period of 1979–2017. The quantification process first involves time differentiation of linearized potential vorticity (PV), which results in a linear function of geopotential height tendency. It is then equated with the PV tendency equation that consists of mean and transient advection terms to represent dynamical processes that contribute to EC development. The quantification, finally, is performed through the inversion of PV tendency budgets, which yields corresponding geopotential height tendency. The results indicate that EC development is primarily caused by zonal advection of PV anomalies by mean flow (~65%) and diabatic production of PV (~40%), with some negative factors in both regions. The former contributes more for ECs deepening over Northwestern Atlantic (~71%) than Northwestern Pacific (~60%), whereas the latter contributes to a similar extent.

How to cite: Kang, J. and Son, S.-W.: The quantification of development processes of explosive cyclones over Northwestern Pacific and Atlantic in boreal winter, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4307, https://doi.org/10.5194/egusphere-egu2020-4307, 2020.

The explosive cyclone (EC), which is the most destructive subcategory of the extratropical cyclone, has been a research center for decades. Many key features of this type of cyclone have been shown, however, as a three-dimensional system, their vertical extents and associated important characteristics still remain vague. This study attempts to fill this vacancy by focusing on ECs’ vertical extents related features in the Northern Hemisphere on the basis of the ERA-I reanalysis data during a 40-yr period. Some new findings are reached: (i) overall, the EC is a type of deep weather system, as more than 63% of them reach an upmost level above 300 hPa, whereas only less than 12% of them maintain below 500 hPa during their whole life spans. (ii) ECs’ vertical extents show remarkable latitude dependent features (maximum vertical extents appear in the zone of 55oN-65oN), and they also show obvious seasonal changes, with the minimum vertical extents appeared in January. (iii) ECs’ maximum vertical extents show a significant positive correlation with their minimum central pressure, whereas, their maximum vertical extents show no obvious relationship to the ECs’ maximum deepening rates and maximum 10-m winds. (iv) in general, ECs over the northern Pacific Ocean have larger intensity, longer life spans, and thicker vertical extents than those of the ECs over the northern Atlantic Ocean.

How to cite: Fu, S., Jiang, L., and Sun, J.: Vertical extent related characteristics of the explosive cyclones in the Northern Hemisphere: A 40-yr climatology study based on the ERA-I reanalysis, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9235, https://doi.org/10.5194/egusphere-egu2020-9235, 2020.

AS1.24 – Clouds, Aerosols, Radiation and Precipitation (General Session)

EGU2020-2630 | Displays | AS1.24

Time evolution of activated aerosol particles in low clouds

Naděžda Zíková, Petra Pokorná, Petr Pešice, Pavel Sedlák, and Vladimír Ždímal

Atmospheric aerosol (AA) influences cloud formation, lifetime and other properties; the processes between AA and clouds are source of uncertainty in weather and climate changes estimations [1]. Apart from airborne measurements, the processes in clouds can be also studied on fogs, or low clouds present at a station with high frequency of fog occurrence, such as at Milešovka, Czech Republic, where fog is present for almost 55 % of the time [2]. At the observatory located on the top of the mountain, with a professional meteorological station and measurements of fog/cloud characterization and vertical cloud profile, an additional measurement of aerosol particle number size distributions (PNSD) was done. PNSD from 10 nm to 20 µm was conducted using SMPS and APS spectrometers, measuring activated and interstitial particles. From the activated PNSD (aPNSD), the activated fraction (AF) was estimated [3] i.e. size dependent share of activated particles from all available ones. The AF was fitted with Sigmoidal function and the inflection point, D50, a lower estimate for an activation diameter of fog [4], was calculated.

The changes in the aPNSD at the beginning of each fog episode have been studied. The largest changes in aPNSD and AF were found within the first two or three hours of the fog episode durations. During the episode, the D50 shifted to the smaller particles, and the AF became steeper. For most episodes, 120 minutes after their beginning the size-dependent AF reached a steady-state. The exceptions  were observed during fog episodes preceded by another hydrometeor-related episode. Under such circumstances, the shift in the AF was not observed, as the steady state had been already reached during the preceding episode.

If the time evolution during whole episodes is taken into account, two main groups of AF behavior in time were also found, based on the meteorological situation prior episode beginning. For one group, there is a strong decrease in the D50 in the first three hours, and later the D50 reaches almost a constant value. The steady value is of about 200 nm for all the episodes, independently of the time of the fog occurrence (time of day, season). In the second group, part of a long-term hydrometeor-related situations, the decrease at the beginning of the episode is not visible and the D50 only fluctuates around its original value. Depending on the air mass origin, it is either 90 or 200 nm.

This work was supported by the Czech Science Foundation under grant P209/18/15065Y.

[1]           IPCC, 2013. Cambridge Univ. Press, Cambridge, UK, and New York, 2013.

[2]           J. Fišák et al., Soil Water Res., vol. 196, pp. 273–285, 2009.

[3]           E. Asmi et al., Atmos. Chem. Phys., vol. 12, no. 23, pp. 11589–11607, 2012.

[4]           E. Hammer et al., Atmos. Chem. Phys., vol. 14, no. 19, pp. 10517–10533, 2014.

How to cite: Zíková, N., Pokorná, P., Pešice, P., Sedlák, P., and Ždímal, V.: Time evolution of activated aerosol particles in low clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2630, https://doi.org/10.5194/egusphere-egu2020-2630, 2020.

EGU2020-13194 | Displays | AS1.24

New particle formation events persistently reduce cloud droplets in boundary layer clouds

David Patoulias, Kalliopi Florou, Spyros N. Pandis, and Athanasios Nenes

Α considerable fraction of cloud condensation nuclei (CCN) originates from new particle formation (NPF). Because of this, NPF events themselves are thought to also increase CCN and cloud droplet number (CDN) and contribute to climate cooling. High resolution state-of-the-art simulations over Europe however portray a different view: radiatively important stratiform clouds influenced by NPF events experience a systematic and substantial decrease in droplet number during and after nucleation events. The drop in CDN occurs because particles present prior to the NPF experiences slower growth during and after each event (as the condensable material is consumed by the growth of the NPF particles that do not typically activate), leading to fewer CCN at the low supersaturation levels characteristic of stratiform clouds (~0.1%). Convective clouds, however, tend to experience a modest increase in cloud droplet number – consistent with established views on the NPF-cloud link. Our results are corroborated by published observational evidence and all together reshape our conceptual understanding of NPF events on clouds, where droplets in stratiform clouds tend to be reduced (leading to local warming from reductions in cloud albedo) but enhance in convection. Combined, these effects could bear important impacts on cloud structure following NPF events.

How to cite: Patoulias, D., Florou, K., N. Pandis, S., and Nenes, A.: New particle formation events persistently reduce cloud droplets in boundary layer clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13194, https://doi.org/10.5194/egusphere-egu2020-13194, 2020.

EGU2020-6244 | Displays | AS1.24

Regional modelling of aerosol interaction with deep convection and the effect on new particle formation over Amazonia

Xuemei Wang, Daniel Grosvenor, Hamish Gordon, Meinrat O. Andreae, and Ken Carslaw

It has been estimated that over 50% of the present-day global low-level cloud condensation nuclei (CCN) are formed from new particle formation (NPF), and that this process has a substantial effect on the radiative properties of shallow clouds (Gordon et al. 2017). In contrast, we have a very limited understanding of how NPF affects deep convective clouds. Deep clouds could interact strongly with NPF because they extend into the high free troposphere where most new particles are formed, and they are responsible for most of the vertical transport of the nucleating vapours. Andreae et al. (2018) hypothesised from ACRIDICON-CHUVA campaign that organic gas molecules are transported by deep convection to the upper troposphere where they are oxidised and produce new particles, which are then be entrained into the boundary layer and grow to CCN-relevent sizes.

Here we study the interaction of deep convection and NPF using the United Kingdom Chemistry and Aerosols (UKCA) model coupled with the Cloud-AeroSol Interacting Microphyics (CASIM) embedded in the regional configuration of UK Met Office Hadley Centre Global Environment Model (HadGEM3). We simulate several days over a 1000 km region of the Amazon at 4 km resolution. We then compare the regional model, which resolves cloud up- and downdrafts, with the global model with parameterised convection and low resolution.

Our simulations highlight three findings. Firstly, solely using a binary H2SO4-H2O nucleation mechanism strongly underestimates total aerosol concentrations compared to observations by a factor of 1.5-8 below 3 km over the Amazon. This points to the potential role of an additional nucleation mechanism, most likely involving biogenic compounds that occurs throughout more of the free troposphere. Secondly, deep convection transports insoluble gases such as DMS and monoterpenes vertically but not SO2 or H2SO4. The time scale for DMS oxidation (~ 1 day) is much longer than for monoterpene (1-2 hours), which points to the importance of simulating biogenic nucleation over the Amazon in a cloud-resolving model, while lower-resolution global models may adequately capture DMS effects on H2SO4 nucleation. Finally, we also examine the Andreae et al (2018) hypothesis of aerosol supply to the boundary layer by quantifying cloud-free and cloudy up- and downdraft transport. The transport of newly formed aerosols into the boundary layer is 8 times greater in cloud-free regions than in the clouds, but these transport processes are of similar magnitude for large aerosols.

How to cite: Wang, X., Grosvenor, D., Gordon, H., Andreae, M. O., and Carslaw, K.: Regional modelling of aerosol interaction with deep convection and the effect on new particle formation over Amazonia, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6244, https://doi.org/10.5194/egusphere-egu2020-6244, 2020.

EGU2020-20358 | Displays | AS1.24

Assimilating visible radiances to constrain aerosol properties in the ECMWF Integrated Forecast System.

Gareth Thomas, Angela Benedetti, Samuel Quesada Ruiz, Julie Letertre-Danczak, and Marco Matricardi

The Aerosol Radiance Assimilation Study (ARAS) has created a new approach for the assimilation of visible/near-IR radiances into the ECMWF’s Integrated Forecast System (IFS) for the constraining aerosol properties within the model. The capability is based on a new observation operator, based on the forward model used in the Optimal Retrieval of Aerosol and Cloud (ORAC) retrieval scheme, which predicts top-of-atmosphere radiances based on the model's aerosol field with sufficient accuracy while being computationally efficient enough to run in a operational analysis system such as that run at ECMWF. The system has been tested in the full IFS assimilation system, replacing the currently operational assimilation of MODIS AOD products, using MODIS radiances.
This presentation will give an overview of the new operator, show example results of its impact on the model output and discuss its merits and disadvantages compared to the AOD assimilation. 

How to cite: Thomas, G., Benedetti, A., Quesada Ruiz, S., Letertre-Danczak, J., and Matricardi, M.: Assimilating visible radiances to constrain aerosol properties in the ECMWF Integrated Forecast System., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20358, https://doi.org/10.5194/egusphere-egu2020-20358, 2020.

EGU2020-3534 | Displays | AS1.24

EarthCARE Mission Preparation Status: Performance and Science Processing

Tobias Wehr, Michael Eisinger, Rob Koopman, Alain Lefebvre, Damien Maeusli, Kotska Wallace, João Pereira Do Carmo, Jakob Livschitz, and Sebastian Maksym

The influence of clouds on the incoming solar and reflected thermal radiation remains one of the most important climate uncertainties. The global observation of vertical profiles of cloud ice and liquid water with simultaneous and collocated solar and thermal flux observation will provide crucial data to address this uncertainty. Furthermore, collocated global observation of vertical profiles of aerosol types are required to address the direct and indirect effects of aerosol.

In response to these needs, the European Space Agency (ESA), in cooperation with the Japan Aerospace Exploration Agency (JAXA), is implementing the Earth Cloud, Aerosol and Radiation Explorer Mission, EarthCARE.

Vertical profiles of cloud ice and liquid water, aerosol type, precipitation, heating rates, solar and thermal top-of-atmosphere radiances and flux profiles will be synergistically derived from the observations of the satellite’s four instruments.

Two active instruments are embarked, a cloud-aerosol lidar and a cloud Doppler radar. The Atmospheric Lidar (ATLID) operates at 355nm and is equipped with a high-spectral resolution receiver and depolarisation channel that separates molecular from particulate backscatter and distinguishes cloud and aerosol types. The Cloud Profiling Radar (CPR), provided by JAXA, is a highly sensitive W-band Doppler radar (94GHz) that measures cloud profiles, precipitation and vertical motion within clouds. The Doppler observation will measure vertical motion in clouds providing novel information on convection, precipitating ice particles and raindrop fall speed. Two passive instruments provide cloud and aerosol swath information and solar and thermal radiances and top-of-atmosphere fluxes. The Multi-Spectral Imager (MSI) has a 150km wide swath and seven channels in the visible, near-IR, short-wave IR, and thermal IR. The Broad-Band Radiometer (BBR) observes broad-band solar and thermal radiation reflected and emitted from the Earth, with three fixed fields of view: forward, nadir and backward.

In preparation for the science exploitation of the mission, complex data retrieval algorithms in the Ground Segment will exploit the synergy of the four instruments and deliver a range of cloud, aerosol and radiation related data products, including three-dimensional cloud-aerosol-precipitation scenes, with collocated broad-band heating rate and radiation data, over a mission lifetime of three years.

The presentation will provide an overview of the mission, main performances of the three ESA instruments and expected science data products.

 

How to cite: Wehr, T., Eisinger, M., Koopman, R., Lefebvre, A., Maeusli, D., Wallace, K., Pereira Do Carmo, J., Livschitz, J., and Maksym, S.: EarthCARE Mission Preparation Status: Performance and Science Processing, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3534, https://doi.org/10.5194/egusphere-egu2020-3534, 2020.

EGU2020-6819 | Displays | AS1.24

A space-based perspective on cloud phase partitioning over the Southern Ocean

Quentin Coopman, Corinna Hoose, and Martin Stengel

Liquid cloud droplets freeze homogeneously at -40°C. For temperature between -40 and 0°C, clouds can be either liquid, ice, or mixed-phase. Several variables determine the cloud phase: droplet size, ice nuclei concentration, meteorological parameters, etc. But, parameters which trigger, enhance or inhibit the phase transition are still poorly understood and disagreements remain between theory and observations. The phase transition is nonetheless important to determine cloud effects on climate.

In the present study, we analyse satellite observations from the geostationary passive instrument SEVIRI. We used the CLAAS-2 dataset to retrieve cloud top microphysical and optical properties from 2005 to 2015 over the Southern Ocean.

Cloud objects that contain liquid and ice pixels are identified for cloud top temperatures within specific temperature ranges: between -30 and -20°C, between -20 and -8°C, and between -8 to 0°C. The distributions of different cloud properties for mixed-phase, liquid or ice clouds are compared. For example, preliminary results show that cloud ice fraction increases with the cloud droplet size for cloud top temperature between -8 and 0°C. Indeed, ice fractions greater than 0.8 are associated with a median cloud droplet effective radius of 7 micrometers whereas ice fractions less than 0.2 are associated with a median cloud droplet effective radius of 12 micrometers. We hypothesize that this result can be associated to a secondary ice production process (e.g., the Hallet-Mossop process is the splinter production associated with riming process for temperature between -8 and -3°C and it can increase the ice particle concentration by several orders of magnitude). In line with our results, the Hallet-Mossop process is more efficient with larger cloud droplets. The spatial distribution of liquid and ice pixels within the cloud objects is also studied to better understand the phase partitioning of mixed-phase clouds.

How to cite: Coopman, Q., Hoose, C., and Stengel, M.: A space-based perspective on cloud phase partitioning over the Southern Ocean, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6819, https://doi.org/10.5194/egusphere-egu2020-6819, 2020.

The current generation of large-eddy models (e.g. the ICON-LEM) allows us to go beyond idealized simulations and to capture synoptic variability by including heterogeneous land surfaces as well as lateral boundary conditions. This would offer the possibility to compare simulations and observations of clouds on a detailed day-to-day basis. But while LEMs are able to reach resolutions that start to be comparable to state-of-the-art observations (e.g. Radar data), they are still facing the issue of different parameter spaces: either the model output has to be transfered to observable quantities, or the other way around. We will present examples from recent field campaigns (e.g. ACLOUD, EUREC4A), where we combined ICON-LEM simulations with remote sensing observations by applying the Passive and Active Microwave TRAnsfer simulator (PAMTRA). By the selection of examples, we will show the potential of this combination of high-resolution modeling, remote sensing observations and forward simulations at different places under different conditions (Arctic, European and Caribbean). While the general structure of clouds (e.g. timing, type, height) is often already captured quite well, the comparison to the remote sensing observations allows us to also get insights into the composition of clouds and to constrain microphysical parameterizations as well as the influence of the large-scale forcing on a more detailed level.

How to cite: Schemann, V. and Mech, M.: Confronting and combining high-resolution simulations (ICON-LEM) with remote sensing observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19201, https://doi.org/10.5194/egusphere-egu2020-19201, 2020.

EGU2020-9470 | Displays | AS1.24

Exploring the aerosol-cloud-radiation relationships in deep marine stratocumulus layers

Anna Possner, Ryan Eastman, Frida Bender, and Franziska Glassmeier

Marine stratocumuli cover around a fifth of the worlds oceans and are a key contributor to Earth’s radiative balance at the surface. Their sensitivity to changes in anthropogenic aerosol concentrations remain a key uncertainty in the climate system. Our current understanding of their sensitivity and the plausible range of the aerosol-cloud radiative forcing is largely based on the process understanding obtained from field campaigns, high-resolution modelling, and satellite records of aerosol-induced phenomena such as volcano or ship tracks.

Yet, a large fraction of these records is only applicable to relatively shallow planetary boundary layers (PBLs). Ship tracks are only found in boundary layers up to a depth of 800m. Field campaigns and high-resolution modelling studies of aerosol-cloud-radiation interactions in marine stratocumuli have been restricted to a similar range of PBL depths in the past. Meanwhile over 70% of marine boundary layers reside in deeper PBLs.

The liquid water path (LWP) adjustment due to aerosol-cloud interactions in marine stratocumuli remains a considerable source of uncertainty for climate sensitivity estimates. An unequivocal attribution of LWP adjustments to changes in aerosol concentration from climatology remains difficult due to the considerable covariance between meteorological conditions alongside changes in aerosol concentrations.

Here, we combine a range of space-born remote sensing retrievals to investigate the relationship of cloud-radiative properties for different boundary layer depths and aerosol concentrations. As done in previous studies we utilise the susceptibility framework, i.e. the relative change in LWP scaled by the relative change in cloud droplet number concentration, to quantify the change in LWP adjustment with PBL depth. We show that the susceptibility of LWP adjustments triples in magnitude from values of -0.1 in PBLs shallower than 0.5 km to -0.33 in PBLs deeper than 1 km.

We further argue that LWP susceptibility estimates inferred from deep PBL climatologies are poorly constrained due to a lack of process-oriented observations. Meanwhile, susceptibilities inferred from climatology in shallow PBL regimes are consistent with estimates obtained from process modelling studies, but are overestimated as compared to pollution track estimates.

How to cite: Possner, A., Eastman, R., Bender, F., and Glassmeier, F.: Exploring the aerosol-cloud-radiation relationships in deep marine stratocumulus layers, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9470, https://doi.org/10.5194/egusphere-egu2020-9470, 2020.

EGU2020-18231 | Displays | AS1.24

Aerosol effects on shallow cumulus cloud fields in idealised and realistic simulations

George Spill, Philip Stier, Paul Field, and Guy Dagan

Shallow cumulus clouds interact with their environment in myriad significant ways, and yet their behavour is still poorly understood, and is responsible for much uncertainty in climate models. Improving our understanding of these clouds is therefore an important part of improving our understanding of the climate system as a whole.

Modelling studies of shallow convection have traditionally made use of highly idealised simulations using large-eddy models, which allow for high resolution, detailed simulations. However, this idealised nature, with periodic boundaries and constant forcing, and the quasi-equilibrium cloud fields produced, means that they do not capture the effect of transient forcing and conditions found in the real atmosphere, which contains shallow cumulus cloud fields unlikely to be in equilibrium. 

Simulations with more realistic nested domains and forcings have previously been shown to have significant persistent responses differently to aerosol perturbations, in contrast to many large eddy simulations in which perturbed runs tend to reach a similar quasi-equilibrium. 

Here, we further this investigation by using a single model to present a comparison of familiar idealised simulations of trade wind cumuli in periodic domains, and simulations with a nested domain, whose boundary conditions are provided by a global driving model, able to simulate transient synoptic conditions. 

The simulations are carried out using the Met Office Unified Model (UM), and are based on a case study from the Rain In Cumulus over the Ocean (RICO) field campaign. Large domains of 500km are chosen in order to capture large scale cloud field behaviour. A double-moment interactive microphysics scheme is used, along with prescribed aerosol profiles based on RICO observations, which are then perturbed.

We find that the choice between realistic nested domains with transient forcing and idealised periodic domains with constant forcing does indeed affect the nature of the response to aerosol perturbations, with the realistic simulations displaying much larger persistent changes in domain mean fields such as liquid water path and precipitation rate. 

How to cite: Spill, G., Stier, P., Field, P., and Dagan, G.: Aerosol effects on shallow cumulus cloud fields in idealised and realistic simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18231, https://doi.org/10.5194/egusphere-egu2020-18231, 2020.

    Double-moment schemes with a constant shape parameter cannot describe the condensation process and the collision coalescence processes properly. Evolutions of cloud droplet spectra and raindrop spectra simulated with different current bulk microphysical schemes also showed big differences. The newly developed triple-moment scheme (IAP-LACS scheme) considered the variation of the shape parameters of water drop distributions by means of the radar reflectivities of cloud droplets and raindrops, respectively, during the condensation process and collision-coalescence processes. In order to evaluate the performance of our new scheme, we use large-eddy simulation in WRF to research the precipitation formation in Rain in Cumulus over the Ocean (RICO) observation study with new triple-moment warm cloud scheme. This paper will show the simulation results for the microphysical characteristic, specical for the evolution of warm raindrop size distribution in comparison with aircarft measurement. Our simulations show that our new triple-moment scheme can grasp the main characteristic of raindrop size distribution as observation and there must be difference exsiting in simulation results between new scheme and other microphysical bulk schemes.

How to cite: Deng, W.: Numerical Simulations for the Warm Rain Properties during RICO with a Newly Developed Triple-moment Warm Cloud Scheme, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4420, https://doi.org/10.5194/egusphere-egu2020-4420, 2020.

EGU2020-4636 | Displays | AS1.24

Machine Learning Rain Formation and the Impacts on Clouds, Precipitation and Radiation

Andrew Gettelman, Chih-chieh Chen, and David Gagne

Cloud, aerosols and precipitation processes are perhaps the most critical uncertainties for weather and climate prediction. The complex nature of sub grid scale clouds makes traceable simulation of clouds and precipitation across scales difficult (or impossible). However, many observations and detailed simulations of clouds are available as input to larger scale models. Machine learning provides another potential tool to improve our empirical parameterizations of clouds. Here we present a comprehensive investigation of replacing the warm rain formation process in an earth system model with emulators that use detailed treatments from small scale and idealized models: specifically a stochastic collection kernel and a superdroplet approach. The emulators consist of multiple neural networks that predict whether specific tendencies will be nonzero and the magnitude of the nonzero tendencies. We describe the opportunity (massive speed up of cloud process calculations) and the risks of overfitting, extrapolation and linearization of a non-linear problem by using perfect model experiments with and without the emulators. The impacts on short term time tendencies of clouds and precipitation, as well as long term climatological means and important emergent properties of the climate system (like radiative forcing through aerosol-cloud interactions and cloud feedbacks to climate change) are assessed. 

How to cite: Gettelman, A., Chen, C., and Gagne, D.: Machine Learning Rain Formation and the Impacts on Clouds, Precipitation and Radiation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4636, https://doi.org/10.5194/egusphere-egu2020-4636, 2020.

Southwestern France is an important wine region where hail-producing storms could cause considerable economic loss. To study the initiation and growth of hailstone, a new microphysical scheme based on the LIMA (Liquid, Ice, Multiple Aerosols, Vié et al., 2016) has been developed. The original LIMA only contains two-moment scheme for rain water, cloud water, and ice crystal. Whereas, the other ice hydrometeors are described by a single-moment scheme. The new scheme adds a full two-moment framework to snow, graupel, and hailstone, thus allowing a better representation of the microphysical processes than the original partial two-moment approach could offer. A large area of southwestern France is actually covered by hailpad network. Results from this network alongside other data thus have been used to evaluate the performance of the single-moment ICE3 scheme, the partial two-moment LIMA scheme, and the new full two-moment scheme in reproducing the evolution of observed hail-producing storm cases. The difference as well as similarity in modeled structures of the storms including hailstone development by different microphysics schemes are examined and will be presented.

How to cite: Taufour, M. and Wang, C.: A new 2-moment microphysical scheme for studying hail initiation and growth: model-observation comparison over Southweest of France, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3548, https://doi.org/10.5194/egusphere-egu2020-3548, 2020.

EGU2020-12065 | Displays | AS1.24

Model investigation into rain enhancement by hygroscopic seeding in mixed-phase convective clouds

Juha Tonttila, Harri Kokkola, Tomi Raatikainen, Jaakko Ahola, Hannele Korhonen, and Sami Romakkaniemi

Intentional release of large hygroscopic particles in a cloud, i.e. cloud seeding, is potentially capable of increasing rain formation. In this work, we focus on convective clouds of moderate intensity observed over the United Arab Emirates, where we use a large eddy simulator coupled with detailed bin aerosol-cloud microphysics module (UCLALES-SALSA) to study the processes controlling the seeding efficacy. Despite numerous field experiments, the conditions that favor efficient seeding induced rain enhancement are not well characterized. Models such as UCLALES-SALSA provide the means to study the microphysical effects in varying ambient conditions in a controlled setting. The clouds targeted by our simulations have a mixed-phase component and rain is primarily produced by the cold precipitation process. The results show that the fast growing droplets formed by the relatively large hygroscopic seeding aerosol affect the riming process in the mixed-phase region inside the clouds. The collision rate between the hydrometeors in the mixed-phase region is enhanced, producing larger frozen particles. Consequently, the ice tends to get more heavily rimed, as indicated by the fraction of rimed ice from the total ice mass, which promotes increased particle fall velocities.

 

However, the impact of seeding on the riming process depends on the state of the cloud and its environment. In conditions already favoring high rime fraction, often associated with relatively strong surface precipitation events, the effect of seeding is hindered, at least in terms of relative difference. Nevertheless, even if the effect of seeding on the total precipitation yield is small, it may still affect the timing of the precipitation onset, a topic currently under investigation. Work is also in progress to characterize the dependence between ambient conditions (in terms of aerosol and the thermodynamic properties of the atmospheric column) and the susceptibility of the mixed-phase clouds to seeding injection.

How to cite: Tonttila, J., Kokkola, H., Raatikainen, T., Ahola, J., Korhonen, H., and Romakkaniemi, S.: Model investigation into rain enhancement by hygroscopic seeding in mixed-phase convective clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12065, https://doi.org/10.5194/egusphere-egu2020-12065, 2020.

EGU2020-19517 | Displays | AS1.24

Quantifying snowfall from orographic cloud seeding

Katja Friedrich, Kyoko Ikeda, Sarah Tessendorf, Jeffrey French, Robert Rauber, Bart Geerts, Lulin Xue, Roy Rasmussen, Derek Blestrud, Melvin Kunkel, Nick Dawson, and Shaun Parkinson

Cloud seeding has been used as one water management strategy to overcome the increasing demand for water despite decades of inconclusive results on the efficacy of cloud seeding. In this study snowfall accumulation from glaciogenic cloud seeding is quantified based on snow gauge and radar observations from three days in January 2017, when orographic clouds in the absent of natural precipitation were seeded with silver iodide (AgI) in the Payette basin of Idaho during the Seeded and Natural Orographic Wintertime Clouds: The Idaho Experiment (SNOWIE). On each day, a seeding aircraft equipped with AgI flares flew back and forth on a straight-line flight track producing a zig-zag pattern representing two to eight lines of clouds visible through enhancements in radar reflectivity. As these seeding lines started to form precipitation, they passed over several snow gauges and through the radar observational domain. For the three cases presented here, precipitation gauges measured increases between 0.05-0.3 mm as precipitation generated by cloud seeding pass over the instruments. A variety of relationships between radar reflectivity factor and liquid equivalent snowfall rate were used to quantify snowfall within the radar observation domain. For the three cases, snowfall occurred within the radar observational domain between 25 -160 min producing a total amount of water generated by cloud seeding ranging from 123,220 to 339,540 m3 using the best-match Ze-S relationship. Uncertainties in radar reflectivity estimated snowfall are provided by considering not only the best-match Ze-S relationship but also an ensemble of Ze-S relationships based on the range of coefficients published from previous studies and then examining the percentile of snowfall estimates based on all of the Ze-S relationships within the ensemble. Considering the interquartile range and 5th/95th percentiles, uncertainties in total amount of water generated by cloud seeding can range between 20-45% compared to the best-math estimates. These results provide new insights towards understanding how cloud seeding impacts precipitation and its distribution across a region.

How to cite: Friedrich, K., Ikeda, K., Tessendorf, S., French, J., Rauber, R., Geerts, B., Xue, L., Rasmussen, R., Blestrud, D., Kunkel, M., Dawson, N., and Parkinson, S.: Quantifying snowfall from orographic cloud seeding , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19517, https://doi.org/10.5194/egusphere-egu2020-19517, 2020.

EGU2020-7745 | Displays | AS1.24

Bounding global aerosol radiative forcing of climate change

Nicolas Bellouin and the Ringberg 2018 review team

Aerosol radiative forcing plays an important role in the attribution of past climate changes, estimates of future allowable carbon emissions, and the assessment of potential geoengineering solutions. Substantial progress made over the past 40 years in observing, understanding, and modelling aerosol processes helped quantify aerosol radiative forcing, but uncertainties remain large.

In spring 2018, under the auspices of the World Climate Research Programme's Grand Science Challenge on Clouds, Circulation and Climate Sensitivity, thirty-six experts gathered to take a fresh and comprehensive look at present understanding of aerosol radiative forcing and identify prospects for progress on some of the most pressing open questions. The outcome of that meeting is a review paper, Bellouin et al. (2019), accepted for publication in Reviews of Geophysics. This review provides a new range of aerosol radiative forcing over the industrial era based on multiple, traceable and arguable lines of evidence, including modelling approaches, theoretical considerations, and observations. A substantial achievement is to focus on lines of evidence rather than a survey of past results or expert judgement, and to make the open questions much more specific.

This talk will present the key messages and arguments of the review and identify work that show promise for improving the quantification of aerosol radiative forcing.

How to cite: Bellouin, N. and the Ringberg 2018 review team: Bounding global aerosol radiative forcing of climate change, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7745, https://doi.org/10.5194/egusphere-egu2020-7745, 2020.

EGU2020-3635 | Displays | AS1.24

New evidence of soot particles affecting past and future cloud formation and climate

Ulrike Lohmann, Franz Friebel, Zamin A. Kanji, Fabian Mahrt, Amewu A. Mensah, and David Neubauer

Clouds play a critical role in the hydrological cycle and modulating the Earth’s climate via precipitation and radiative forcing. Aerosol particles acting as cloud condensation nuclei and ice nucleating particles aid in cloud formation, shaping their microphysical structure. Previously thought to be unimportant for cloud formation, soot particles that undergo oxidation by ozone and/or aging with aqueous sulfuric acid result in being both good centers for cloud droplets and ice crystals formation. However, the associated changes in cloud radiative properties and the consequences for Earth’s climate remain uncertain, because these processes have not been considered in global climate models. Here we present both past and future global climate simulations, which for the first time consider the effect of such aged soot particles as cloud condensation nuclei and ice nucleating particles. Our results constitute the first evidence that aging of soot particles produce a 0.2 to 0.25 Wm-2 less negative shortwave indirect aerosol forcing compared to previous estimates. We also conducted equilibrium climate sensitivity simulations representing a future warmer climate in which the carbon dioxide concentration is doubled compared to pre-industrial levels. Accounting for these soot aging processes significantly exacerbates the global mean surface temperature increase by 0.4 to 0.5 K. Thus, reducing emissions of soot particles will be beneficial for many aspects including air pollution and future climate.

 

How to cite: Lohmann, U., Friebel, F., Kanji, Z. A., Mahrt, F., Mensah, A. A., and Neubauer, D.: New evidence of soot particles affecting past and future cloud formation and climate, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3635, https://doi.org/10.5194/egusphere-egu2020-3635, 2020.

EGU2020-4920 | Displays | AS1.24

A CMIP6 multi-model study of fast responses on pre-industrial climate due to present-day aerosols

Prodromos Zanis, Dimitris Akritidis, Aristeidis K. Georgoulias, Robert J. Allen, Susanne E. Bauer, Olivier Boucher, Jason Cole, Ben Johnson, Makoto Deushi, Martine Michou, Jane Mulcahy, Pierre Nabat, Dirk Olivie, Naga Oshima, Adriana Sima, Michael Schulz, and Toshihiko Takemura

We present an analysis of the fast responses on pre-industrial climate due to present-day aerosols in a multi-model study based on Coupled Model Intercomparison Project Phase 6 (CMIP6) simulations from 10 Earth System Models (ESMs) and General Circulation Models (GCMs). The aforementioned simulations were implemented within the framework of the Aerosol Chemistry Model Intercomparison Project (AerChemMIP). All models carried out two sets of simulations; a control experiment with all forcings set to the year 1850 and a perturbation experiment with all forcings identical to the control, except for aerosols with precursor emissions set to the year 2014. The perturbation by the present-day aerosols indicates negative top of the atmosphere (TOA) effective radiative forcing (ERF) values around the globe, especially over continental regions of the Northern Hemisphere in summer, with the largest negative values appearing over East Asia. Simulations in 3 models (CNRM-ESM2-1, MRI-ESM2-0 and NorESM2-LM) with individual perturbation experiments using present day SO2, BC and OC emissions show the dominating role of sulfates in all-aerosols ERF. In response to the pattern of all aerosols ERF, the fast temperature responses are characterised by cooling over the continental areas, especially in the Northern Hemisphere, with the largest cooling over East Asia and India and sulfate being the dominant aerosol surface temperature driver for present-day emissions. The largest fast precipitation responses are seen in the tropical belt regions, generally characterized by  a reduction over continental regions and a southward shift of the tropical rain belt. This is a characteristic and robust feature among most models in this study, associated with a southward shift of the Intertropical convergence zone (ITCZ) and a weakening of the monsoon systems around the globe (Asia, Africa and America) in response to hemispherically asymmetric cooling from a Northern Hemisphere aerosol perturbation. An interesting feature in aerosol induced circulation changes is a characteristic dipole pattern with intensification of the Icelandic Low and an anticyclonic anomaly over Southeastern Europe, inducing warm air advection towards the northern polar latitudes in winter.

This research was funded by the project "PANhellenic infrastructure for Atmospheric Composition and climatE change" (MIS 5021516) which is implemented under the Action "Reinforcement of the Research and Innovation Infrastructure", funded by the Operational Programme "Competitiveness, Entrepreneurship and Innovation" (NSRF 2014-2020) and co-financed by Greece and the European Union (European Regional Development Fund).

How to cite: Zanis, P., Akritidis, D., Georgoulias, A. K., Allen, R. J., Bauer, S. E., Boucher, O., Cole, J., Johnson, B., Deushi, M., Michou, M., Mulcahy, J., Nabat, P., Olivie, D., Oshima, N., Sima, A., Schulz, M., and Takemura, T.: A CMIP6 multi-model study of fast responses on pre-industrial climate due to present-day aerosols , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4920, https://doi.org/10.5194/egusphere-egu2020-4920, 2020.

EGU2020-7537 | Displays | AS1.24

The impact of perturbations to tropical aerosols and their precursors on local and remote climates

Chris Wells, Apostolos Voulgarakis, and Matt Kasoar

Aerosols are a major climate forcer, but their historical effect has the largest uncertainty of any forcing, and so their mechanisms and impacts must be better understood. Due to their short lifetime, aerosols have large impacts near their emission region, but they also have effects on the climate in remote locations. In recent years, studies have investigated the influences of regional aerosols on global and regional climate, and the mechanisms that lead to remote responses to their inhomogeneous forcing. However, there has been little work on the influence of emissions from the tropics, as the aforementioned studies typically focused only on northern mid-latitude pollution effects. This work uses the new UK Earth System Model (UKESM1) to investigate the atmospheric composition and climate effects of tropical aerosols and aerosol precursor emissions. We performed three idealised perturbation experiments in which a) tropical SO2 emissions were multiplied by a factor of 10; b) tropical biomass burning carbonaceous aerosol emissions were multiplied by 10; and c) tropical biomass burning carbonaceous aerosol emissions were entirely removed. Impacts on radiation fluxes, temperature, circulation and precipitation are investigated, both over the emission regions, where microphysical effects dominate, and remotely, where dynamical influences become more relevant. Increasing tropical SO2 emissions causes a global cooling, and the asymmetric forcing (stronger negative forcing in the Northern Hemisphere Tropics) drives a southward shift of the intertropical convergence zone (ITCZ). The experiment with the large increase in tropical biomass burning organic carbon (OC) and black carbon (BC) features a net warming globally, and a local cooling in locations where the aerosol load increases the most, since OC and BC reduce radiation at the surface locally, causing cooling. However, whereas OC scatters radiation with a negative forcing, BC has a warming effect since it reduces the planetary albedo, and this warming wins out on the global scale. The forcing is asymmetric, but changes sign between seasons as biomass burning in Africa shifts across the Equator, driving a more complex response of the ITCZ. The removal of biomass burning OC and BC leads to opposite effects to the 10x increase, but with a smaller magnitude, and with dynamical changes playing a more important role than microphysical ones, relative to the larger perturbations. Using the Shared Socioeconomic Pathway scenarios (SSPs), transient future experiments have also been performed, testing the effect of Africa following a relatively more polluting route (SSP3-RCP7.0) to the rest of the world (SSP1-RCP1.9), relative to a global SSP1-RCP1.9 control. Preliminary results from this analysis will also be presented.

How to cite: Wells, C., Voulgarakis, A., and Kasoar, M.: The impact of perturbations to tropical aerosols and their precursors on local and remote climates, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7537, https://doi.org/10.5194/egusphere-egu2020-7537, 2020.

EGU2020-9457 | Displays | AS1.24

Accelerated increases in global and Asian summer monsoon precipitation from future aerosol reductions

Laura Wilcox, Zhen Liu, Bjørn Samset, Ed Hawkins, Marianne Lund, Kalle Nordling, Sabine Undorf, Massimo Bollasina, Annica Ekman, Srinath Kirshnan, Joonas Merikanto, and Andrew Turner

There is large uncertainty in future aerosol emissions scenarios explored in the Shared Socioeconomic Pathways (SSPs), with plausible pathways spanning a range of possibilities from large global reductions in emissions to 2050 to moderate global increases over the same period. Diversity in emissions across the pathways is particularly large over Asia. CMIP6 models indicate that rapid anthropogenic aerosol and precursor emission reductions between the present day and the 2050s lead to enhanced increases in global and Asian summer monsoon precipitation relative to scenarios with weak air quality policies. However, the effects of aerosol reductions don’t persist in precipitation to the end of the 21st century, when response to greenhouse gases dominates differences across the SSPs. The relative magnitude and spatial distribution of aerosol changes is particularly important for South Asian summer monsoon precipitation changes. Precipitation increases here are initially suppressed in SSPs 2-4.5 and 5-8.5 relative to SSP 1-1.9 and 3-7.0 when the impact of East Asian emission decreases is counteracted by that due to continued increases in South Asian emissions.

How to cite: Wilcox, L., Liu, Z., Samset, B., Hawkins, E., Lund, M., Nordling, K., Undorf, S., Bollasina, M., Ekman, A., Kirshnan, S., Merikanto, J., and Turner, A.: Accelerated increases in global and Asian summer monsoon precipitation from future aerosol reductions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9457, https://doi.org/10.5194/egusphere-egu2020-9457, 2020.

EGU2020-12998 | Displays | AS1.24

Cloud regimes and associated MJO variability over the Maritime Continent in austral summer

Zijie Zhao, Claire Vincent, and Todd Lane

In this study, a new technique to determine distinct cloud regimes and their variation in space and time is proposed, evaluated, and applied to two satellite products over the Maritime Continent (MC). Compared to previous methods, the method presented here allows different types of cloud to co-exist in the same grid at the same time, giving rise to physically explainable and spatially continuous patterns in cloud regimes. Similar results generated by ISCCP – H and Himawari 8 data suggests that the method is robust. The 4 cloud regimes determined using this method are associated with shallow, mid-level, deep convective and high level clouds respectively. The analysis shows that he MJO–induced variation in total cloud fraction is dominated by day-time high–level clouds, while the diurnal MJO variability is mostly demonstrated by low–level cumulus. Spatial and temporal rainfall variability over the MC during austral summer is dominated by high–level clouds, while most local signatures and land–sea differences are attributed to deep convective clouds. Using an artificial neural network, the cloud patterns over the MC can be classified into nine categories, largely dominated by the MJO-phase. Active MJO activity is shown by systematic propagation around the cloud categories, with one category associated with the inactive MJO phase. The inhomogenous propagation of the MJO can partially be revealed in the generated patterns, which can be physically explained by the enhanced/suppressed convection over the Indian Ocean. This work has implications for understanding the MJO-scale variation in precipitation and diabatic heating associated with different cloud regimes, and its representation in mesoscale and climate scale modelling systems.

How to cite: Zhao, Z., Vincent, C., and Lane, T.: Cloud regimes and associated MJO variability over the Maritime Continent in austral summer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12998, https://doi.org/10.5194/egusphere-egu2020-12998, 2020.

EGU2020-2417 | Displays | AS1.24 | Highlight

Solar Dimming and Brightening: Recent Developments in China

Martin Wild, Matthias Schwarz, Yawen Wang, Su Yang, Bart Sweerts, Doris Folini, and Jörg Trentmann

There is growing evidence that the amount of solar radiation at the Earth’s surface is not stable over time but undergoes substantial multidecadal variations. Particularly, a decrease in surface solar radiation has been noted from the 1950s to the 1980s at widespread observation sites, a phenomenon popularly known as “global (solar) dimming”, followed by a partial recovery known as “brightening”. An interesting hotspot in this context is China, where surface solar radiation (SSR) underwent particularly large changes over the past decades.

Here we discuss our latest studies, which shed new light on the magnitude, causes and implications of this phenomenon in China. The focus is on recent developments, which indicate, that after decades of decline in surface solar radiation, some recovery can be noted since the mid-2000s in the SSR records observed by the Chinese Meteorological Agency. This recovery is not seen in satellite derived records, which assume a constant aerosol climatology in their retrieval algorithm, suggesting the necessity for a decrease in aerosol to reconcile the diverging trends (Wang et al., 2019). This is independently supported by an analysis of SSR trends specifically in the cloud-free atmosphere, which show a turn into increase since around 2006, also suggesting a reduction of aerosol over China in recent years (Yang et al., 2019).

In a further study, the combination of the Chinese SSR observations with collocated space-based measurements  of the net solar exchanges at the Top of Atmosphere from CERES enabled the determination of changes in solar absorption within the atmospheric column as a residual over recent decades. The results suggest that the recent brightening in China is predominately caused by a weakening of the solar absorption within the atmosphere. This indicates that a reduction of particularly the absorbing aerosol must have taken place in recent years (Schwarz et al., 2020).

In summary, all these studies provide independent evidence that air pollution mitigation efforts in China have successfully induced a trend reversal in the amount of solar radiation reaching the Earth’s surface, with some recovery in recent years after decades of dimming.

We further estimated that, if such a recovery could persist and air pollution levels could eventually be reduced down to the pristine 1960s levels in China, this would have major benefits for Chinese photovoltaic (PV) solar power production, which could be enhanced by as much as 13 %. With the PV capacity currently installed in China, and as projected for the year 2030, this would correspond to a yearly economic benefit of 2 and 6 billion US dollars, respectively, assuming current electricity prices (Sweerts et al., 2019).

References

Yang, S., Wang, X.L., Wild, M. (2018) J. Climate 31, 4529-4541.

Yang, S., Wang, X.L., Wild, M. (2019) J. Climate 32, 5901-5913.

Sweerts, B., Pfenninger, S., Yang, S., Folini, D., vanderZwaan, B., Wild, M. (2019) Nature Energy 4, 657-663.

Wang, Y., Trentmann, Y., Pfeifroth, U., Yuan, W., Wild, M. (2019) Remote Sens. 11, 2910.

Schwarz, M., Folini, D., Yang, S., Allan, R.P., and Wild, M. (2020) Nature Geoscience (in press)

How to cite: Wild, M., Schwarz, M., Wang, Y., Yang, S., Sweerts, B., Folini, D., and Trentmann, J.: Solar Dimming and Brightening: Recent Developments in China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2417, https://doi.org/10.5194/egusphere-egu2020-2417, 2020.

    In situ measurements are performed to study the size-resolved hygroscopic behaviour of submicron aerosols during pollution and fireworks episodes in winter from late January to February 2019 in Chengdu, a megacity in Sichuan Basin, using a humidity tandem differential mobility analyser (H-TDMA). The H-TDMA is operated at a relative humidity of 90% with dry aerosol diameters between 40 and 200 nm. Three modes of aerosol particles, including nearly hydrophobic mode (NH), less hygroscopic mode (LH), and more hygroscopic mode (MH), are found in the probability distributions of the growth factor (GF-PDF) during the campaign. The GF-PDF shows that aerosol particles are usually externally mixed. The average ensemble mean hygroscopicity parameter values (κMean) over the entire sampling period are 0.16, 0.19, 0.21, 0.23, and 0.26 for aerosols with diameters of 40, 80, 110, 150, and 200 nm, respectively. These averages are lower than those in Shanghai and Nanjing. κMean for aerosols larger than 110 nm, however, are higher than those in Beijing and Guangzhou during winter. Distinct diurnal patterns for all measured sizes are observed for the number fractions of the NH (NFNH) and MH (NFMH) modes as well as κ-PDF and κMean. The NFNH values are lower, but κMean exhibits peak values during daytime. More aerosols are internally mixed because of photochemical ageing during daytime. The number fraction of LH (NFLH) for the 40-nm diameter aerosols in clean periods (CPs) is larger than that in the pollution episode (PEs) because of the increasing amount of SOA formation. More aerosols of diameters larger than 80 nm are internally mixed during CPs and stage of contaminant accumulation, resulting in higher κMean values compared to those in PEs. The aerosol emissions of fireworks that accumulate during the Chinese New Year's Eve contribute to the slow and continuous increasing trend in κMean with average values of 0.19, 0.19, 0.21,0.23, and 0.27 for the 40, 80, 110, 150, and 200-nm diameter aerosols, respectively. These values are higher than those during the pre- and post-fireworks days. The hygroscopic properties of submicron aerosols in Chengdu are essential for understanding the formation and evolution of severe haze events in Sichuan Basin.

How to cite: Yuan, L.: Size-resolved hygroscopic behaviour and mixing state of submicron aerosols in a megacity of Sichuan Basin during pollution and fireworks episodesn during pollution and fireworks episodes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2499, https://doi.org/10.5194/egusphere-egu2020-2499, 2020.

Precipitation over Southern China for the month of April, which is largely associated with mesoscale convective systems (MCSs), has declined significantly in recent decades. It is unclear how this decline in precipitation may be related to the concurrent increase in anthropogenic aerosols in the atmosphere over this region. Using observation analyses and model simulations, we showed that anthropogenic aerosols significantly reduced MCS occurrences by 21% to 32% over Southern China in April, leading to less and weaker rainfall. Half of this MCS occurrence reduction was due to the direct radiative scattering and the indirect enhancement of non-MCS liquid cloud reflectance by aerosols, which stabilized the regional atmosphere. The other half of the MCS occurrence reduction was due to the microphysical and dynamical responses of the MCS to aerosols. The model simulations showed that the higher levels of aerosols and the resulting increase in liquid cloud droplets both enhance the scattering of sunlight, cool the surface, and stabilize the lower atmosphere. As a result, the occurrence of strong convective systems is suppressed, leading to decreased rainfall in April over Southern China. Our results demonstrated the complex effects of aerosols on MCSs via impacts on both convective systems and non-convective cloud systems in the regional atmosphere.

How to cite: Zhang, L. and Fu, T.-M.: Impacts of Anthropogenic Aerosols on Springtime Mesoscale Convective Systems over Southern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4400, https://doi.org/10.5194/egusphere-egu2020-4400, 2020.

EGU2020-329 | Displays | AS1.24

Recent increase in winter hazy days over Central India

Vijay Kanawade, Abin Thomas, and Chandan Sarangi

The Indian subcontinent is greatly vulnerable to air pollution, especially during the dry winter season. Here, we use 15 years (2003-2017) of satellite and model reanalysis datasets over India and adjoining Seas to estimate the trends in the number of days with high aerosol loading (i.e. hazy days) from October to February. The number of days with high aerosol loading in recent years (2013-2017) is increasing at the rate of ~2.6 days/year over Central India, which is surprisingly higher than the more polluted Indo-Gangetic Plain (~1.7 days/year).  Similar increment in absorbing aerosols is also visible in recent years.  As a result, the estimated atmospheric warming over Central India is two-fold higher than that over Indo-Gangetic Plain. This anomalous increase in hazy days over Central India is attributed to a relatively higher increase in biomass burning over this region. The number of days with high aerosol loading in recent years are also higher over the Arabian Seas, which is located downwind to Central India, as compared to the Bay of Bengal. Thus, our findings not only draw attention to deteriorating air quality over Central India but also underlines the significance of enhanced biomass burning activities under recent climate change.

How to cite: Kanawade, V., Thomas, A., and Sarangi, C.: Recent increase in winter hazy days over Central India, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-329, https://doi.org/10.5194/egusphere-egu2020-329, 2020.

EGU2020-1542 | Displays | AS1.24

Aerosol properties obtained on cloudless days through direct broadband solar radiation measurements

Mohamed Zaiani, Abdanour Irbah, Djelloul Djafer, and Julien Delanoe

Anthropogenic and natural aerosols are important atmospheric constituents that can significantly reduce, by scattering and absorption, the solar radiation reaching the Earth’s surface. This impact depends on the aerosols properties, namely the optical thickness (τ), the exponent (α) and the coefficient (β) of Angström. These three parameters are first estimated by fitting the direct solar radiation measurements recorded on clear days with the Iqbal C model. The retrieval of τ and β using data collected in Tamanrasset, Southern Algeria, are in good agreement with those of retrieved by AERONET at the same time and location. However, α exponent comparison is not satisfactory, we have therefore developed an Artificial Neural Network method (ANN) to better estimate it. The ANN created was first learned from β and α obtained from AERONET. We then used β from the Iqbal C model with the ANN and obtain good estimate of α with R2 of 60% compared to the Angstrom exponent from AERONET. We will first give in this presentation an overview of the Iqbal C model, then present the data used and the processing method, and finally discuss the main results of this study.

How to cite: Zaiani, M., Irbah, A., Djafer, D., and Delanoe, J.: Aerosol properties obtained on cloudless days through direct broadband solar radiation measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1542, https://doi.org/10.5194/egusphere-egu2020-1542, 2020.

EGU2020-22087 | Displays | AS1.24

CCN properties of pollen from selected wind pollinated plants

Sebastian Sonnenberg, Julia Burkart, and Jürgen Gratzl

Aerosol particles that act as cloud condensation nuclei (CCN) inuence cloud albedo and lifetime and thereby affect the planetary radiative balance. The indirect aerosol effect on climate is still one of the largest uncertainties and especially the role of biological particles is not yet well described. Pollen grains are primary biological particles that become airborne during the blooming season of plants. Pollen from wind pollinated plants represent a seasonally signifficant portion of the organic aerosol in the atmosphere. Intact pollen grains are rather large (10-100 µm) but under conditions of high humidity pollen grains have been shown to rupture and release cytoplasmic material including a large number of particles much smaller in size (0.5-5 µm).

In this study we extract soluble and insoluble material from several pollen samples (Phleum, Betula, Artimesia, Poa, Corylus and Ambrosia) and investigate the CCN activity of the extracts in a laboratory study. The main component of the experiment is the continuous-flow streamwise thermal-gradient cloud condensation nuclei counter (CCNC) from Droplet Measurement Technologies (DMT). The CCNC was calibrated with (NH4)2SO4. The activation behavior of (NH4)2SO4 is theoretically well described by Kohler equation. For particles which consist of a multitude of organic components it is convenient to represent the chemical composition through the hygroscopicity parameter κ. In the first part of the experiment, we determine the activation diameter at 5 different supersaturations and calculate the kappa parameter for all pollen samples. We find that the values fall in the range from 0.1-0.2. which is typical for particles composed of organic substances. Extracts from Betula pollen show the highest hygroscopicity (κ = 0.18), while extracts from Artimesia exhibit the lowest hygroscopicity (κ = 0.13). In the second part of the experiment we will also investigate the CCN activity of the insoluble material.

How to cite: Sonnenberg, S., Burkart, J., and Gratzl, J.: CCN properties of pollen from selected wind pollinated plants, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22087, https://doi.org/10.5194/egusphere-egu2020-22087, 2020.

EGU2020-21180 | Displays | AS1.24

Variability of trends observed in Atmospheric Aerosol optical properties over Pune, India

Sudeep Das and Govindan Pandithurai

Long term trends of various aerosol optical properties are observed over the city of Pune, the ninth most populated city in India using ground and satellite based instruments such as AERONET, MODIS (Aqua and Terra), MISR, CALIOP and reanalysis tool MERRA. Annually, the Aerosol Optical Depth is observed to be increasing over all the types of instruments (2004-17) with values of 0.01 to 0.006 yr-1, whereas the Angstrom exponent has a negative slope (AERONET) which suggests that the fine aerosols are decreasing. Single scattering albedo (SSA) is also increasing (0.00657 yr-1), which means the emission of smaller darker particles like soot has decreased over the years. MISR shows that the Absorbing AOD trend is decreasing in the overall study period (-0.0001237 yr-1). All these annual trends are related to anthropogenic activities and show differing trends before and after 2008, the year when various pollution counter measures were introduced mainly in Pune and also in various nearby areas. After 2008, the AOD increasing slope reduces, and the AAOD reverses the trend from positive to a negative slope. The average height till various kinds of aerosols reach and their vertical profile is studied using CALIOP data. Monthly variations of AOD and their vertical distribution also observed and discussed. Aerosol characterization is done using the MERRA tool into dust, sea salt, sulfates, elementary carbon, and organic carbon. Their monthly variations are explained by source characterizations using the HySplit model. In summer, air from the Arabian sea brings in dust and sea salt into the city and in winter, aerosols come from central India dominantly as carbon and sulfates changing the air quality over there. This study lays its stress on the fact that even though aerosols cover over a city is mostly non-local, anthropogenic activities of that area do play a significant role and here the city of Pune is a role model to show how measures can be taken to improve air quality over any urban area.

How to cite: Das, S. and Pandithurai, G.: Variability of trends observed in Atmospheric Aerosol optical properties over Pune, India, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21180, https://doi.org/10.5194/egusphere-egu2020-21180, 2020.

EGU2020-19928 | Displays | AS1.24

Size distribution functions of submicron aerosol and approximation based on the direct Kolmogorov equation

Otto Chkhetiani, Evgeny Gledzer, and Natalia Vazaeva

The particle size distribution function is one of the characteristics reflecting the composition of aerosol during sand lifting and removal in desert regions. This characteristic, in addition to known practical applications, is important in describing radiation processes during the exchange of heat fluxes and in forming cloud systems in the models of atmospheric dynamics. Fine dust-aerosol fractions (less than 2 µm in diameter) are especially important for the atmospheric radiation budget, because such fractions (having a significant lifetime) most efficiently interact with short-wave solar radiation. One of the central regularities in considering the size distributions of simulated dust-aerosol particles is the following formula based on the so-called fragmentation process and verified using a large amount of empirical data N (d) ~ d -2. Similar dependence for particles with size d > 1 µm is associated with the consideration of the fragmentation process as a particle splitting according to the log-normal distribution.

Results of field measurements taken in the near–Caspian (2002, 2003, 2007, 2009, 2010, 2011, 2013, 2014, 2016 years) and near–Aral-sea (1998) deserts under the conditions of weak winds (almost in the absence of saltation processes) and strong heating of the land surface are given. These results show that the fine mineral dust aerosol (0.1-1 µm) considerably contributes to the total aerosol content of the atmospheric surface layer under such conditions. The scaling of daytime mean size d distribution at a height of 2 m is close to d -5 in contrast to the law d -2 for fraction d >1 µm.

Different compositions of aerosol particles at 0.1 < d < 1 µm, and d >1 µm, including multicomponent fractions (less than 1 µm) may result in different probabilities of their integration and disintegration, which, finally, determine equilibrium particle size distributions. The simplest distribution approximations based on the Kolmogorov direct differential equation are given. 

This study was supported by the RFBR (19-05-50110) and the Presidium of the Russian Academy of Sciences (programs 12 and 20).

How to cite: Chkhetiani, O., Gledzer, E., and Vazaeva, N.: Size distribution functions of submicron aerosol and approximation based on the direct Kolmogorov equation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19928, https://doi.org/10.5194/egusphere-egu2020-19928, 2020.

EGU2020-18728 | Displays | AS1.24

Spatio-temporal Patterns of the Precipitation Response to Aerosol Perturbations from an Energetic Perspective

Shipeng Zhang, Philip Stier, Duncan Watson-Parris, and Guy Dagan

Absorbing and non-absorbing aerosols have distinct effects on both global-mean and regional precipitation. Local changes of precipitation in response to aerosol perturbations are more complex than global-mean changes, which are strongly constrained by global energy budget. This work examines the changes of atmospheric energetic budget terms to study effects of large perturbations in black carbon (BC) and sulphate (SUL) on precipitation. Both cases show decrease of global-mean precipitation but with different geographical patterns. Decreased atmospheric radiative cooling contributes to the majority of decreased global-mean precipitation. It is caused by increased aerosols absorption in BC case but decreased cooling from clean-clear sky (without clouds and aerosols) in SUL case. Fast responses, which are independent of changes in sea surface temperature (SST), dominate the precipitation changes in the BC case, not only for global mean but also for regional patterns. Slow responses, which are mediated by changes in SST, dominate the precipitation responses in SUL case, both globally and regionally.

 

Relationships between temporal responses of local precipitation and diabatic cooling and precipitation are also examined for both BC and SUL perturbations. Both cases show remarkable similar pattern of correlations despite of essentially different patterns of changes in precipitation and diabatic cooling. Strong positive correlations are found over mid-latitude land and this is mainly due to the changes from surface sensible heat fluxes. Negative correlations are found over tropical oceans, mainly contributed by (longwave) radiative cooling from clouds and clean-clear sky. Further analysis shows this similarity is caused by the natural variability which is independent from external forcing. It indicates that the temporal relationship between changes in local precipitation and diabatic cooling is forcer-independent. This correlation is examined as a function of increasing spatial scales, which demonstrates the scale at which the dominating energetic term on regional precipitation shifts from energy transport to atmospheric diabatic cooling.

How to cite: Zhang, S., Stier, P., Watson-Parris, D., and Dagan, G.: Spatio-temporal Patterns of the Precipitation Response to Aerosol Perturbations from an Energetic Perspective, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18728, https://doi.org/10.5194/egusphere-egu2020-18728, 2020.

EGU2020-18123 | Displays | AS1.24

The observed impact of aerosols on cloud droplet formation during the RACLETS campaign

Paraskevi Georgakaki, Aikaterini Bougiatioti, and Athanasios Nenes

The influence of aerosols serving as cloud condensation nuclei (CCN) on the production of droplets in mixed-phase cloud systems is an ongoing research problem that influences their optical and microphysical properties. During February and March 2019, the Role of Aerosols and CLouds Enhanced by Topography on Snow (RACLETS) field campaign collected unique and detailed airborne and ground-based in-situ measurements of cloud and aerosol properties over the Swiss Alps. This study presents analysis of the observed CCN activity of the aerosol, which combined with observed aerosol size distributions, can be introduced into a cloud droplet activation parameterization to investigate the drivers of droplet variability in these clouds. The implications for secondary ice production are then discussed.

How to cite: Georgakaki, P., Bougiatioti, A., and Nenes, A.: The observed impact of aerosols on cloud droplet formation during the RACLETS campaign, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18123, https://doi.org/10.5194/egusphere-egu2020-18123, 2020.

EGU2020-2324 | Displays | AS1.24

Impact of ship emission controls recorded by cloud properties

Edward Gryspeerdt, Tristan Smith, Eoin O'Keefe, Matthew Christensen, and Fraser Goldsworth

The impact of aerosols on cloud properties is one of the largest uncertainties in the anthropogenic forcing of the climate system. As large, isolated sources of aerosol, ships provide the ideal opportunity to investigate aerosol-cloud interactions. However, their use for quantifying the aerosol impact on clouds has been limited by a lack on information on the aerosol perturbation generated by the ship.

In this work, satellite cloud observations are combined with ship emissions estimated from transponder data. Using over 17,000 shiptracks during the implementation of emission controls, the central role of sulphate aerosol in controlling shiptrack properties is demonstrated. Meteorological factors are shown to have a significant impact on shiptrack formation, particularly cloud-top relative humidity. Accounting for this meteorological variation, this work also demonstrates the potential for satellite retrievals of ship sulphate emissions, providing a pathway to the use of cloud observations for monitoring air pollution.

How to cite: Gryspeerdt, E., Smith, T., O'Keefe, E., Christensen, M., and Goldsworth, F.: Impact of ship emission controls recorded by cloud properties, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2324, https://doi.org/10.5194/egusphere-egu2020-2324, 2020.

We evaluate the impact of horizontal model resolution (~135, 60 and 25 km, respectively) and different levels of complexity of the aerosol-cloud interaction parameterization (interactive versus non-interactive) on springtime subtropical marine stratocumulus properties and stratocumulus-to-cumulus transition (SCT) using the atmosphere-only version of HadGEM-GC31. Higher resolution and non-interactive aerosols resulted in small, but significantly higher, liquid water contents and lower precipitation rates, in particular over the southern hemisphere. Higher resolution also resulted in a significantly stronger shortwave (SW) cloud radiative effect (CRE). Over the southern hemisphere, non-interactive aerosols also resulted in a stronger SW CRE, but over the northern hemisphere non-significant changes or a weaker SW CRE was obtained compared to the simulation using interactive aerosols. In general, no significant changes in the all-sky SW radiation was obtained. Only the model version with lowest resolution showed a weak tendency of a faster SCT than the other model versions. We conclude that a change in the complexity of the aerosol-cloud parameterization may significantly affect the SW CRE of marine stratocumuli, at least regionally, but the sign and magnitude of the impact will be dependent on the background level as well as the relative change in liquid water and the absolute change in cloud droplet number concentration of the specific model version.

How to cite: Ekman, A. M. L., Nygren, E., Svensson, G., and Bellouin, N.: Influence of horizontal resolution and complexity of aerosol-cloud interactions on marine stratocumulus and stratocumulus-to-cumulus transition in HadGEM-GC31, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4728, https://doi.org/10.5194/egusphere-egu2020-4728, 2020.

The maritime continent in Southeast Asia is characterized by the frequent convective activities on a wide range of scales, as well as by the seasonal emissions of biomass-burning particles. The emission of biomass-burning particles in this region typically peaks in September and October, whereas its intensity varies considerably from year to year. Since the atmospheric circulation over the region is heavily influenced by a range of meteorological and climatological variabilities, such as ENSO, it is important to quantitatively examine the impacts of biomass-burning particles on clouds while taking weather/climate regimes into account. We investigate the effects of biomass-burning particles on clouds, especially convective ones, with cloud-resolving simulations by the WRF-CHEM model. Instead of focusing on a particular case, our simulations cover an extended period of time in the month of September, allowing us to examine both individual convection and an ensemble of convective clouds developing under different weather/climate regimes and hence different aerosol abundance and distributions. Such long-term and high-resolution simulations over the region will give us an insight into the climate-regime dependent two-way interaction between aerosols and clouds.

How to cite: Takeishi, A. and Wang, C.: Interaction between biomass-burning aerosol and clouds under different climate/weather regimes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7433, https://doi.org/10.5194/egusphere-egu2020-7433, 2020.

EGU2020-7485 | Displays | AS1.24

Coupling aerosols to (cirrus) clouds in a global aerosol-climate model

Mattia Righi, Johannes Hendricks, Ulrike Lohmann, Christof Gerhard Beer, Valerian Hahn, Bernd Heinold, Romy Heller, Martina Krämer, Michael Ponater, Christian Rolf, Ina Tegen, and Christiane Voigt

The impact of aerosol on atmospheric composition and climate still represents one of the largest uncertainties in the quantification of anthropogenic climate change. This is particularly the case for modelling aerosol-cloud interactions, which requires a detailed knowledge of various processes acting on a wide range of spatial and temporal scales. While significant progress has been made in developing parameterizations for describing the aerosol activation process in liquid clouds in the framework of global models, the aerosol-induced formation of ice crystals in cirrus clouds is still poorly understood and only a few global models include explicit representations of aerosol-cloud interactions in the ice phase. This is due the high complexity of the freezing processes occurring in the ice phase, the uncertain properties of ice nucleating particles, and the competition between homogeneous and heterogeneous freezing at cirrus conditions. To tackle this issue, this study documents the implementation of a new cloud microphysical scheme, including a detailed parameterization for aerosol-driven ice formation in cirrus clouds, in the global chemistry climate model EMAC, coupled to the aerosol submodel MADE3. The new scheme is able to consistently simulate three regimes of stratiform clouds (liquid, mixed- and ice-phase/cirrus clouds), considering the activation of aerosol particles to form cloud droplets and the nucleation of ice crystals. In the cirrus regime, it allows for the competition between homogeneous and heterogeneous freezing for the available supersaturated water vapor, taking into account different types of ice-nucleating particles, whose specific ice-nucleating properties can be flexibly varied in the model setup. The new model configuration is tuned to find the optimal set of parameters that minimizes the model deviations with respect to observations. A detailed evaluation is performed comparing the model results for standard cloud and radiation variables with a comprehensive set of observations from satellite retrievals and in-situ measurements. The performance of EMAC-MADE3 in this new coupled configuration is in line with similar global coupled models and with other global aerosol models featuring ice cloud parameterizations. Some remaining discrepancies, namely a high positive bias in liquid water path in the northern hemisphere and overestimated (underestimated) cloud droplet number concentrations over the tropical oceans (in the extra-tropical regions), which are both a common problem of this kind of models, need to be taken into account in future applications of the model. To further demonstrate the readiness of the new model system for application studies, an estimate of the anthropogenic aerosol effective radiative forcing (ERF) is provided, showing that EMAC-MADE3 simulates a relatively strong aerosol-induced cooling, but within the range reported in the IPCC AR5 and in other, more recent, assessments.

How to cite: Righi, M., Hendricks, J., Lohmann, U., Beer, C. G., Hahn, V., Heinold, B., Heller, R., Krämer, M., Ponater, M., Rolf, C., Tegen, I., and Voigt, C.: Coupling aerosols to (cirrus) clouds in a global aerosol-climate model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7485, https://doi.org/10.5194/egusphere-egu2020-7485, 2020.

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Diurnal cycle in anthropogenic aerosol impacts on clouds

Jorma Rahu, Velle Toll, and Piia Post

The cooling effect of anthropogenic aerosols on Earth's climate offsets part of the greenhouse gas warming effect. To reduce the uncertainty in the aerosol cooling effect on climate, aerosol impact on clouds needs to be better understood. In this research, we extend satellite observations of polluted cloud tracks from Toll et al. (2019, Nature, https://doi.org/10.1038/s41586-019-1423-9) with analysis of temporal evolution of anthropogenic cloud perturbations using satellite data from SEVIRI instrument onboard geostationary Meteosat satellite. Study area is concentrated to European part of Russia as we have found strong contrast between properties of polluted and unpolluted clouds in this area. We analyze the properties of polluted clouds at pollution hot spots and compare these to the properties of the nearby unpolluted clouds. We compare the temporal evolution of the properties of the polluted and unpolluted clouds to study the importance of diurnal cycle in aerosol-cloud interactions.

How to cite: Rahu, J., Toll, V., and Post, P.: Diurnal cycle in anthropogenic aerosol impacts on clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8822, https://doi.org/10.5194/egusphere-egu2020-8822, 2020.

The influence of aerosol on lightning is very dependent on environmental factors, including thermal factors, humidity factors, and terrain factors. ADTD cloud-to-ground lightning data, ERA5 reanalysis data, and MERRA2 reanalysis data were applied to discuss the influence of aerosol on lightning activity in Sichuan basin. Thermodynamic factors were the main reasons for the difference in lightning density between the plateau and the basin. The results showed that the influence of aerosol on lightning activity in the basin and the plateau regions showed a significant difference, showing a positive correlation on the plateau and a negative correlation on the basin. In the plateau area, the aerosol concentration was relatively low, and the aerosol stimulated the lightning activity by influencing the microphysical processes. In the basin area, the aerosol load was very high, and the aerosol showed a more significant radiation effect. By reducing the solar radiation reaching the ground, the convective energy on the ground was reduced, and the intensity of lightning activity was finally suppressed.

How to cite: Zhao, P.: Effects of aerosol on lightning in Sichuan Basin, Southwest China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6056, https://doi.org/10.5194/egusphere-egu2020-6056, 2020.

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Constraining direct aerosol radiative forcing using remote sensing and in-situ constraints

Lucia Timea Deaconu, Duncan Watson-Parris, Philip Stier, and Lindsay Lee

Absorbing aerosols affect the climate system (radiative forcing, cloud formation, precipitation and more) by strongly absorbing solar radiation, particularly at ultraviolet and visible wavelengths. The environmental impacts of an absorbing aerosol layer are influenced by its single scattering albedo (SSA), the albedo of the underlying surface, and also by the atmospheric residence time and column concentration of the aerosols.

Black-carbon (BC), the collective term used for strongly absorbing, carbonaceous aerosols, emitted by incomplete combustion of fossil fuel, biofuel and biomass, is a significant contributor to atmospheric absorption and probably a main-driver in inter-model differences and large uncertainties in estimating the aerosol radiative forcing due to aerosol-radiation interaction (RFari). Estimates of BC direct radiative forcing suggest a positive effect of +0.71 Wm-2 (Bond and Bergstrom (2006)) with large uncertainties [+0.08, +1.27] Wm-2. These uncertainties result from poor estimates of BC atmospheric burden (emissions and removal rates) and its radiative properties. The uncertainty in the burden is due to the uncertainty in emissions (7.5 [2, 29] Tg yr-1) and lifetime (removal rates). In comparison with the available observations, global climate models (GCMs) tend to under-predict absorption near source (e.g. at AERONET stations), and over-predict concentrations in remote regions (e.g. as measured by aircraft campaigns). This may be due to GCM’s weak emissions at the source, but longer lifetime of aerosols in the atmosphere.

This study aims to address the parametric uncertainty of GCMs and constrain the direct radiative forcing using a perturbed parameter ensemble (PPE) and a collection of observations, from remote sensing to in-situ measurements. Total atmospheric aerosol extinction is quantified using satellite observations that provide aerosol optical depth (AOD), while the SSA is constrained by the use of high-temporal resolution aerosol absorption optical depth (AAOD) measured with AERONET sun-photometers (for near-source columnar information of aerosol absorption) and airborne black-carbon in-situ measurements collected and synthesised in the Global Aerosol Synthesis and Science Project (GASSP) (for properties of long-range transported aerosols). Measurements from the airborne campaigns ATOM and HIPPO are valuable for constraining aerosol absorption in remote areas, while CLARIFY and ORACLES, that were employed over Southeast Atlantic, are considered in our study for near source observations of biomass burning aerosols transported over the bright surface of stratocumulus clouds.

Using the PPE to explore the uncertainties in the aerosol absorption as well as the dominant emission and removal processes, and by comparing with a variety of observations we have confidence to better constrain the aerosol direct radiative forcing.

How to cite: Deaconu, L. T., Watson-Parris, D., Stier, P., and Lee, L.: Constraining direct aerosol radiative forcing using remote sensing and in-situ constraints, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17044, https://doi.org/10.5194/egusphere-egu2020-17044, 2020.

EGU2020-8998 | Displays | AS1.24

Distinct Impacts of Increased Aerosols on Cloud Droplet Number Concentration of Stratus/Stratocumulus and Cumulus

Hailing Jia, Xiaoyan Ma, Fangqun Yu, Yangang Liu, and Yan Yin

In situ aircraft measurements obtained during the RACORO field campaign are analyzed to study the aerosol effects on different cloud regimes. The results show that with increasing cloud condensation nuclei (CCN), cloud droplet number concentration (Nd) significantly increases in stratocumulus (Sc) while remains almost unchanged in cumulus (Cu). By using a new approach to strictly constrain the dynamics in Cu, we found that neither simultaneously changing cloud dynamics nor dilution of cloud water induced by entrainment-mixing can explain the observed insensitivity of Nd. The different degree of reduction in cloud supersaturation caused by increasing aerosols might be responsible for the observed different aerosol indirect effect between Sc and Cu.

How to cite: Jia, H., Ma, X., Yu, F., Liu, Y., and Yin, Y.: Distinct Impacts of Increased Aerosols on Cloud Droplet Number Concentration of Stratus/Stratocumulus and Cumulus, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8998, https://doi.org/10.5194/egusphere-egu2020-8998, 2020.

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Satellite Observations of Organizational Regimes in Low-Level Mixed-Phase Clouds over the Southern Ocean

Jessica Danker, Odran Sourdeval, Isabel L. McCoy, Robert Wood, and Anna Possner

On average stratocumulus clouds cover about 23% of the ocean surface and are important for Earth’s radiative balance. They typically self-organize into cellular patterns and thus are often referred to as mesoscale-cellular convective (MCC) cloud systems. In the Southern Ocean (SO), low-level clouds cover between 20% to 40% of the ocean surface in the mid-latitudes where they exert a substantial radiative cooling. In a previous study, McCoy et al (2017) demonstrated that different MCC regimes may be associated with different cloud albedos and thus different cloud radiative forcing.
Many of the MCC clouds in the SO are not pure liquid but contain a mixture of liquid and ice. Here we investigate whether the formation of ice within these mixed-phase clouds influences MCC organization and thus the cloud-radiative effect.
To investigate the cloud phase we use the raDAR-liDAR (DARDAR) data product (version 1) from Cloud-Aerosol-Water-Radiation Interactions (ICARE) Data and Services Center which provides collocated data from Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO), CloudSat and Moderate Resolution Imaging Spectroradiometer (MODIS). The “Simplified DARMASK Categorization Flag” of DARDAR is used to categorize the vertically resolved cloud phase into a single cloud phase per data point: clear, multi-layer, liquid, mixed or ice. In order to distinguish between open and
closed MCC regimes, we collocate the DARDAR product with an MCC classification data set from McCoy et al (2017) which is based on a neural network algorithm applied to MODIS Aqua data.
Our preliminary results confirm previous ground-based observations that most mixed-phase clouds are composed of a supercooled liquid top and ice underneath. Furthermore, our preliminary analysis suggests open MCCs occur more frequently as mixed-phase clouds (57% (DJF), 55% (JJA)) in the SO compared to liquid clouds (39% (DJF), 37% (JJA)) during both summer (DJF) and winter (JJA). In contrast, closed MCCs are more likely to appear as liquid clouds (58%) in comparison to mixed-phase clouds (40%) during winter, whereas during summer there seems to be no tendency for closed MCCs to be either liquid (51%) or mixed (49%).

How to cite: Danker, J., Sourdeval, O., McCoy, I. L., Wood, R., and Possner, A.: Satellite Observations of Organizational Regimes in Low-Level Mixed-Phase Clouds over the Southern Ocean, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13229, https://doi.org/10.5194/egusphere-egu2020-13229, 2020.

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Real-world laboratories for studying anthropogenic aerosol impacts on clouds and Earth’s climate

Velle Toll, Heido Trofimov, and Jorma Rahu

The cooling of the Earth’s climate through the effects of anthropogenic aerosols on clouds offsets an unknown fraction of greenhouse gas warming. We discuss how causal relationship between aerosols and clouds can be derived from contrast between clouds polluted by anthropogenic aerosols and nearby unpolluted clouds. Ship tracks have been long considered to be real-world laboratories of aerosol-cloud interactions. More recently, polluted cloud tracks induced by aerosols emitted from volcanoes and wildfires and various industrial sources - such as oil refineries, smelters, coal-fired power plants, and cities have been analysed (Toll et al. 2019; Nature, https://doi.org/10.1038/s41586-019-1423-9). In this research, we extend satellite observations of polluted cloud tracks from Toll et al. (2019) with analysis of smaller and larger scale polluted cloud areas detected in satellite images.

 

Polluted clouds are detected in MODIS and SEVIRI satellite images as areas with strongly increased cloud droplet number concentrations. Polluted cloud tracks can be utilized to study frequency and magnitude of anthropogenic cloud droplet number perturbations and subsequent cloud adjustments. Anthropogenic aerosol perturbations on liquid-water clouds are detected in various major global industrial areas. Both tens of kilometres wide ship-track-like polluted cloud tracks and hundreds by hundreds of kilometres wide polluted cloud areas show that cloud water can both increase and decrease in response to aerosols depending on meteorological conditions. On average, there is relatively weak decrease in cloud water. Polluted cloud tracks also show that cloud fraction can both increase and decrease compared to nearby less polluted clouds. Applicability of pollution tracks to study impact of absorbing aerosols situated above clouds on below-lying clouds is discussed. We expect that utilization of real-world laboratories of aerosol impacts on clouds will lead to improved physical parameterizations in global climate models and more reliable projections of the future climate.

How to cite: Toll, V., Trofimov, H., and Rahu, J.: Real-world laboratories for studying anthropogenic aerosol impacts on clouds and Earth’s climate, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4558, https://doi.org/10.5194/egusphere-egu2020-4558, 2020.

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An Observational Study of Macroscopic and Microphysical Characteristics of Clouds and Precipitation on Mount Lu, Jiangxi, China

Lijun Guo, Xueliang Guo, Xiaofeng Lou, Guangxian Lu, Kai Lyu, Hemin Sun, Jun Li, and Xiaopeng Zhang

The Mount Lu (Lushan) observational station of cloud and fog in Jiujiang, China was restarted in 2015. The observational experiment of clouds/fog and precipitation was conducted from 2015 to 2018 in Mount Lu station. The observation dataset of clouds/fog on the Mount Lu were collected and established. The observational characteristics of clouds and precipitation were investigated from November 2015 to February 2018, including microphysics properties of clouds/fog and precipitation of 15 months in cold and warm seasons. The statistical results suggested that the heavy precipitation on the Mount Lu was frequent in summer with the maximal daily precipitation exceeding 100 mm. The maximal number of clouds and fogs days reached 25 days per month, with the lowest visibility about 20m. Due to radiative effect of clouds and fog in the (early) morning, the lowest temperature in the diurnal variation of temperature happened at about 9 o’clock, right before the dissipation of clouds and fog. Based on the analysis of radar data, stratiform precipitation, stratocumulus and convective precipitation in the autumn and winter respectively accounted for 29%, 44% and 27% of the total precipitation, and convective and stratocumulus precipitation in the spring and summer respectively accounted for 83% and 17% of the total precipitation. Compared with precipitation in urban areas, the small and medium raindrops were predominant in the precipitation processes on Mount Lu. Compared with fog in urban areas, the clouds and fog were characterized by smaller number concentration, the more significant bimodal and wider spectra. With the increase of precipitation within cloud, the more raindrops in number and larger raindrops in size were easier to initiate the coagulation mechanism, resulting in reduction of cloud droplets smaller than 11μm and larger than 30 μm. As a result, the peak at 11μm became more obvious. During the snowfall periods, the small cloud droplets were abundant, and the solid precipitation growth consumed large freezing cloud droplets through the rimming process.

How to cite: Guo, L., Guo, X., Lou, X., Lu, G., Lyu, K., Sun, H., Li, J., and Zhang, X.: An Observational Study of Macroscopic and Microphysical Characteristics of Clouds and Precipitation on Mount Lu, Jiangxi, China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3111, https://doi.org/10.5194/egusphere-egu2020-3111, 2020.

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Aerosol-cloud interactions as observed over Western Ghats, India

Govindan Pandithurai

Atmospheric aerosols have an important role in global climate and weather by scattering and absorbing incoming shortwave radiation and absorbing outgoing longwave radiation that influences the Earth’s radiation budget. The aerosol indirect effect (AIE)  on the cloud microphysical properties has been studied over a high altitude site, Mahabaleshwar (17.92˚ N, 73.66˚ E; 1380m a.m.s.l.), Maharashtra, India, using ground-based in-situ measurements during monsoon season (June - August) of 2017. The AIE was estimated using cloud droplets number concentration (AIEn) and cloud droplet effective radius (AIEs) at different fixed liquid water contents (LWC). The AIE was varying in the range 0.01 – 0.13 when LWC was varying from 0.04 – 0.26 gm-3. The maximum values of AIEn and AIEs (0.125 and 0.119) were found at the lower LWC bin (0.06 - 0.07 gm-3). The calculated values of AIEn and AIEs showed that the values of AIEn were overestimated due to the dispersion effect. The maximum dispersion offset observed was 17.4% at LWC bin 0.16 – 0.17 gm-3. After dispersion correction, the offset was reduced and AIEn became close to AIEs. So dispersion correction is necessary for the correct estimation of AIE using cloud droplet number concentration (CDNC). For the first time in India, cloud droplets are classified into smaller and medium size droplets to study their relative dispersion and their contribution to the total dispersion of cloud droplet size distribution. The contribution of smaller and medium-size droplets on dispersion at a lower and higher LWC region was studied. In lower LWC (high AIE), the concentration of smaller size droplets are higher (71%) than medium size droplets, but medium size droplets are the major contributor (61%)  of dispersion compared to the contribution by smaller size droplets. When LWC is higher (low AIE), the number concentration of smaller size droplets was reduced and the concentration of medium size droplets increased, compared to the case of lower LWC. However, the dispersion contribution by smaller size droplets was increased and the dispersion contribution by medium size droplets was reduced. An inverse relation between CDNC at a particular size class (small/medium) and their contribution to dispersion in CDSD was observed. 

How to cite: Pandithurai, G.: Aerosol-cloud interactions as observed over Western Ghats, India, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21444, https://doi.org/10.5194/egusphere-egu2020-21444, 2020.

EGU2020-19108 | Displays | AS1.24

A numerical study of dust particle effects on cloud microphysical processes and hail/precipitation impacts

Ioannis Chaniotis, Platon Patlakas, and George Kallos

The effects of natural aerosols on microphysical processes in clouds are quite important for their development and evolution and still pose some unresolved questions on the impact they have in the atmosphere and climate. The processes where they interfere, can lead to an uncertainty in the intensity of precipitation and the hydrometeor species as well as the temporal and spatial extent of the affected areas. Apart from the scientific interest of such studies, the outcome highly affects applications and early warning systems associated to water management,  food security and agriculture.

For the needs of the study, the state of the art atmospheric modeling system RAMS-ICLAMS was used to investigate the effects of desert dust concentrations on microphysical processes in clouds. The model is able to run in very high resolutions in order to resolve cloud processes explicitly. Extreme case studies were selected, simulated and the model performance was evaluated showing satisfactory results. Sensitivity tests were performed in order to quantify the direct, indirect and semi-direct impact of CCN and IN concentrations. These tests showed notable effects on the cloud microphysical processes, as well as on hydrometeors. This further enhances the need for a more accurate description of aerosol feedbacks in regional and climate atmospheric models.

How to cite: Chaniotis, I., Patlakas, P., and Kallos, G.: A numerical study of dust particle effects on cloud microphysical processes and hail/precipitation impacts, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19108, https://doi.org/10.5194/egusphere-egu2020-19108, 2020.

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Detection of Fog Involving Heavy Pollutants by Using the New Geostationary satellite Himawari-8

Hongbin Wang, Zhiwei Zhang, and Duanyang Liu

Himawari-8 is the new geostationary satellite of the Japan Meteorological Agency (JMA) and carries the Advanced Himawari Imager (AHI), which is greatly improved over past imagers in terms of its number of bands and its temporal/spatial resolution. In this work, two different methods for the detection of the different levels of fog involving heavy pollutants by using the Himawari-8 were developed in China. The two different methods are the method of the difference between the 11.2 mm and 3.9 mm brightness temperatures (BTD3.9-11.2) and the method of 3.9 mm Pseudo-Emissivity (ems3.9).  The 3.9 mm Pseudo-Emissivity is the ratio of the observed 3.9 mm radiance and the 3.9 mm blackbody radiance calculated using the 11.2 mm brightness temperature. We identified the parameters optimal threshold at the 2400 stations and the grid points using the BTD3.9-11.2 and ems3.9 for different levels of fog involving heavy pollutants. Results on land and sea from the two methods were compared with surface observations from 2400 weather stations in China and CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation) VFM (Vertical Feature Mask) products. The results show that both the method of BTD3.9-11.2 and the method of ems3.9 can accurately identify the different levels of fog involving heavy pollutants and the accuracy of ems3.9 method is slightly better than the BTD3.9-11.2. The accuracy of two methods has increased significantly and the false alarm rate has significantly decreased with the decrease of the visibility. When the visibility is less than 50 m, the HR, FAR and KSS of the BTD3.9-11.2 method (the ems3.9 method) were 0.89 (0.90), 0.15 (0.15) and 0.74 (0.75), respectively. When mid- or high-level clouds were removed using surface temperature of the ground observations, the HR and KSS of two methods for the different levels of fog has increased significantly, and the FAR has significantly decreased. When the visibility is less than 1000 m, the HR of the BTD3.9-11.2 method (the ems3.9 method) is increased to 0.81(0.85) from 0.71 (0.74), the FAR is decreased to 0.12 (0.13) from 0.27 (0.28), and the KSS is increased to 0.69 (0.72) from 0.44 (0.46). The KSS of two method increase by 0.23 and 0.26, respectively. Three cases analysis show that the fog area can be clearly identified by using the BTD3.9-11.2, ems3.9 and RGB composite image. The results of the detection of sea fog by using Himawari-8 data and using CALIPSO VFM products have consistency.

How to cite: Wang, H., Zhang, Z., and Liu, D.: Detection of Fog Involving Heavy Pollutants by Using the New Geostationary satellite Himawari-8, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3929, https://doi.org/10.5194/egusphere-egu2020-3929, 2020.

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Algorithmic Differentiation for Cloud Schemes

Manuel Baumgartner, Max Sagebaum, Nicolas R. Gauger, Peter Spichtinger, and André Brinkmann

Numerical models in atmospheric sciences do not only need to approximate the flow equations on a suitable computational grid, they also need to include subgrid effects of many non-resolved physical processes. Among others, the formation and evolution of cloud particles is an example of such subgrid processes. Moreover, to date there is no universal mathematical description of a cloud, hence many cloud schemes were proposed and these schemes typically contain several uncertain parameters. In this study, we propose the use of algorithmic differentiation (AD) as a method to identify parameters within the cloud scheme, to which the output of the cloud scheme is most sensitive. We illustrate the methodology by analyzing a scheme for liquid clouds, incorporated into a parcel model framework. Since the occurrence of uncertain parameters is not limited to cloud schemes, the AD methodology may help to identify the most sensitive uncertain parameters in any subgrid scheme and therefore help limiting the application of Uncertainty Quantification to the most crucial parameters.

How to cite: Baumgartner, M., Sagebaum, M., Gauger, N. R., Spichtinger, P., and Brinkmann, A.: Algorithmic Differentiation for Cloud Schemes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1401, https://doi.org/10.5194/egusphere-egu2020-1401, 2020.

The warming effect of cirrus clouds is well-known. In recent years, in order to mitigate global warming, cirrus cloud thinning as a newly emerging method of geoengineering has been studied based on climate modeling. Adding a few (~10 L–1) INPs (ice nucleating particles including ice crystals) might hinder homogeneous ice nucleation, which can produce a large number of ice crystals (~1000 L–1), and then reduce cirrus clouds. On the other hand, the cirrus clouds might increase if too much INPs were added. Therefore, the effectiveness of cirrus seeding on cooling our earth is still in debate. In this study, we developed a method (optimal seeding scheme) to calculate the minimum concentration of seeding INPs, which is just enough to prevent homogeneous nucleation from happening. Simulation with the Community Atmosphere Model version 5(CAM5) using the optimal seeding scheme shows a significant cooling effect (–1.4 W/m2), which is equal to two-thirds of the cooling potential (–2.1 W/m2) derived from the pure heterogeneous simulation (i.e., homogeneous ice nucleation is artificially switched off). Seeding fixed 20 L-1 and 200 L-1 concentrations of INPs show the global average radiative effect at –0.5 W m-2 (cooling) and 0.1 W m-2 (warming), respectively. The cooling effect of seeding fixed number concentration of INPs is not obvious, which is consistent with previous studies. Furthermore, using the optimal seeding scheme, the sensitivities of cooling effects to seeding area, ice nucleation parameterizations and homogeneous ice nucleation occurrence frequency are also investigated.

How to cite: Liu, J. and Shi, X.: A comprehensive estimate of the global cooling effect from hindering homogeneous ice nucleation under cirrus conditions with CAM5, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4939, https://doi.org/10.5194/egusphere-egu2020-4939, 2020.

Qilian mountains, located in the arid and semi-arid region of Northwest China, has more amount of natural precipitation than that on both north and south sides, with unique geographical environment and abundant water vapor supply. It is a very important water resource for the surrounding areas. To deeper understand the features of cloud over the areas is significant for the utilization of cloud water resources and sustainable development in this region. In this article, based on MOD08-M3 data, grid ground precipitation data and FY-2 series satellite cloud parameter inversion products, the spatial and temporal features of cloud macro/micro physical parameters, such as Cloud Amount(CA), Cloud Water Path(CWP), Cloud Top Temperature(CTT), Cloud Top Pressure(CTP), Cloud Optical Depth(COD) and Cloud Particle Effective Radius (CPER) over Qilian Mountains area were analyzed, as well as the relationship between the precipitation and cloud parameters. The results are as follows:

  • (1) The regional average values of CA, CWP, CTP, COD and CPER in Qilian Mountains area are 55.50 %, 148.95 g/m², -21.13 ℃, 456.56 hPa, 12.64 and 21.04 μm, respectively. From 2006 to 2015, CA, CWP, COD and CPER decreased by 2.3 %, 21 g/m², 0.68 and 0.51 μm, respectively. CTT and CTP increased by 1.9 ℃ and 65.2 hPa, respectively. Cloud water resources over the area are abundant.
  • (2) There is the richest cloud water resource over the main area of Qilian Mountains, and the cloud parameter condition in Wushaoling area is the best for precipitation. The high value areas of CA in four seasons are distributed in Xining and surroundings, main and south part of mountain range, and Lenghu area, respectively. The high value areas of CWP in four seasons are located in the northeast, north-middle the main part of mountain area and the eastern side of Subei, respectively. The high value areas of COD are located in the east of Subei in winter and in the southeast of the study area in other seasons. The high value areas of CPER in spring are located in the region except Hexi Corridor. In other seasons they are located between Lenghu and Subei, Subei and Tuole, and in the northeast of range, respectively.
  • (3) The monthly precipitation is positively correlated with CA , CWP, COD, but negatively correlated with CTT and CTP. The relationship between CPERs and precipitation is positive in January, April, July, November and December, but negative in other months. CA and CPERs are most correlated with precipitation in May and September, respectively. while the correlation between other cloud parameters and precipitation are the highest in January.
  • (4) When the values of COD and CPER are too small or too large, the actual precipitation will be limited.

Key words: Cloud physical parameters; Precipitation; Water resource; Qilian Mountains

How to cite: Zhang, W., Wang, Y., Zhao, Q., Pu, C., and Chen, Y.: Analysis of the Temporal-Spatial Characteristics of Cloud Parameters and the Relationship with the Precipitation over Qilian Mountains Area in Northwest China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5226, https://doi.org/10.5194/egusphere-egu2020-5226, 2020.

EGU2020-1884 | Displays | AS1.24

The observed properties of summer convective clouds and precipitation over the central Tibetan Plateau

Yi Chang, Xueliang Guo, Jie Tang, Guangxian Lu, and Peng Qi

Macro- and micro-physical properties of summer convective clouds and precipitation over the central Tibetan Plateau (TP) were investigated using the in-situ observations during the Third Tibetan Plateau Atmospheric Sciences Experiment (TIPEX-Ⅲ) in 2014. The advanced aircraft and radar observational systems were employed during the experiment.
Results show that the convective events over the central TP were characterized as frequently weak precipitation with a significant daily variation. The convections were generally initiated in the late morning and peaked in the late afternoon, and the convective clouds were turned into stratiform clouds in the nighttime. The average heights of cloud top and cloud base were 11.62 ± 2.45 km and 6.89 ± 1.58 km, respectively. The average rain rate was ≈ 1.2 mm/h, and compared to M-P distribution, the Γ distribution was more suitable in describing the raindrop size distribution of precipitation over the central TP.
Aircraft observations show that the clouds over the central TP were normally in a mixed-phase state, and had lower concentrations of cloud particles and weaker updraft, but more larger particles than over plains. The particle size distributions (PSDs) of cloud droplets were mainly bimodal, and the large cloud particles (> 50 μm) had an exponential PSD type. The aircraft observed convective clouds were mainly singular newly born or developing convective cells, in which ice processes happened at early stage, quick and massive glaciation happened at higher altitude, coalescence and rimming contributed to the formation of precipitation.

How to cite: Chang, Y., Guo, X., Tang, J., Lu, G., and Qi, P.: The observed properties of summer convective clouds and precipitation over the central Tibetan Plateau, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1884, https://doi.org/10.5194/egusphere-egu2020-1884, 2020.

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A study on cloud cover in reanalysis datasets in tropical south India

Unnikrishnan Chirikandath Kalath

Clouds play a key role in Earth’s energy and water budgets. This study examines the cloud cover changes in two nearer and distinct locations in tropical south India, one location is a near-coastal region in Thiruvananthapuram (8.52oN, 76.90oE) and another one in Western Ghats mountain ranges (10.15oN, 77.01oE). The study validated the following reanalysis product with Lufft CHM 15k ceilometer observations in both locations during 2017: ERA5, ERA-Interim and MERRA-2 reanalysis. ERA5 daily cloud cover data has the lowest RMSE (20 %) than other reanalysis datasets in these tropical locations. Correlation between daily ceilometer cloud cover observation and reanalysis datasets shows that ERA5 data has better temporal cloud cover anomaly (0.8) in the mountain location. All reanalysis datasets show significant correlation (0.01 level) with observation. RMSE (correlation) is higher (lower) in coastal region. Further, a long period cloud cover trend (1985-2016) in both locations are calculated from multiple reanalysis and ISCCP datasets. All datasets show a consistent and significant (0.01 level) increasing cloud cover in both locations.  ISCCP Mean IR cloud amount (marginal) shows the highest increasing trend compared to reanalysis datasets (5.9 %). In the coastal location, the cloud cover increasing trend is much higher and all datasets agree well on it. A long period correlation analysis is performed between cloud cover variability in the study region and north Indian ocean SST to study their relation. Bay of Bengal SST is highly positively correlated with the cloud cover in the study region (significant at 0.01 level). This suggests that the observed increase in cloud cover has a strong relationship with the north Indian Ocean warming.

How to cite: Chirikandath Kalath, U.: A study on cloud cover in reanalysis datasets in tropical south India, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7911, https://doi.org/10.5194/egusphere-egu2020-7911, 2020.

There are conditions between cloudy and cloud-free air at which it is hard to define the suspended particles in the atmosphere either as a cloud or an atmospheric aerosol; it is called twilight or transition zone. This occurs when characteristics of the suspended particles are between those corresponding to a pure cloud and those corresponding to a pure atmospheric aerosol. However, in most meteorological and climate studies the condition of sky is assumed to be either cloudy (fully developed cloud) or cloud-free (dry aerosol), neglecting the transition zone. The present communication aims to show the uncertainties introduced by this simplified assumption in modeling longwave radiation. For this purpose, the parameterizations RRTMG, NewGoddard and FLG included in the Weather Research and Forecasting Model (WRF) version 4.0 were isolated from the whole model. These parameterizations were then used to perform a number of simulations under ideal “cloud” and “aerosol” modes, for different values of (i) cloud optical thicknesses resulting from different sizes of ice crystals or liquid droplets, cloud height, mixing ratios; and (ii) different aerosol optical thicknesses combined with various aerosol types. The differences in the resulting longwave radiative effects (RE) at the top of the atmosphere and at the Earth surface were analyzed. The primary results show: (1) the parameterization RRTMG is not capable of simulating the REs of the aerosols in the longwave region, (2) different assumptions of a situation corresponding to the transition zone lead to a mean relative uncertainty of about 170% in the estimated longwave irradiance at both top of the atmosphere and surface, (3) the absolute uncertainties observed in the surface downwelling irradiances are substantially greater than those relating to the upwelling irradiances at top of the atmosphere.

How to cite: Jahani, B., Calbó, J., and González, J.-A.: Longwave Radiation at the Cloud-Aerosol Transition Zone from Radiative Parameterizations in Weather Research and Forecasting Model (WRF) , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10344, https://doi.org/10.5194/egusphere-egu2020-10344, 2020.

The conditions between cloudy and cloud-free air, named “Transition (or twilight) Zone”, are a major source of uncertainty in the climate and meteorological studies. The transition zone involves microphysical and radiative characteristics which lay on the border between those corresponding to a pure cloud and those corresponding to pure atmospheric aerosols. Several studies show that a notable proportion of cloudless sky at any time may correspond to this phase. However, as the information available about radiative effects of this phase is still very limited in most meteorological and climate studies the condition of sky is assumed to be either cloudy (fully developed cloud) or cloud-free (dry aerosol), neglecting the transition zone. This implies that these models consider the area/layer corresponding to the transition zone as either cloud or aerosol. The authors of the current communication have shown in a previous work that there are substantial uncertainties associated with modeling the surface shortwave irradiances under this assumption [Jahani et al. (2019) JGR: Atmospheres, 124. https://doi.org/10.1029/2019JD031064]. The present communication aims to show the uncertainties in modeling the heating rate in the atmosphere (due to shortwave solar radiation) driven from different treatments of the transition zone. For this purpose, the relatively detailed shortwave radiation parameterizations included in the Weather Research and Forecasting model (WRF) version 4.0, which allow users to consider different treatments of aerosols and clouds (RRTMG, NewGoddard and FLG), were isolated from the whole model. These parameterizations were then utilized to perform a number of simulations under ideal “cloud” and “aerosol” modes, for different values of (i) cloud optical thicknesses resulting from different sizes of ice crystals or liquid droplets, cloud height, mixing ratios; and (ii) different aerosol optical thicknesses combined with various aerosol types. The optical thickness under both aerosol and cloud modes was considered to vary between 0.01 and 2.00. The differences in the resulting atmosphere column averaged heating rate were analyzed. The results showed (i) the simplified assumption about the state of the sky leads to a large difference among the atmospheric shortwave heating rate, (ii) magnitude of these uncertainties is higher when parameterizations which cope with the Radiative Transfer Equation in more detail (RRTMG and NewGoddard) are used.

How to cite: Calbó, J., Jahani, B., and González, J.-A.: Shortwave Heating Rate at the Cloud-Aerosol Transition Zone from Radiative Parameterizations in the Weather Research and Forecasting Model (WRF), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11326, https://doi.org/10.5194/egusphere-egu2020-11326, 2020.

Aerosol particles can serve as cloud condensation nuclei (CCN) to influence orographic clouds. Autoconversion, which describes the initial formation of raindrops from the collision of cloud droplets, is an important process for aerosol–cloud–precipitation systems. In this study, seven autoconversion schemes are used to investigate the impact of CCN on orographic warm-phase clouds. As the initial cloud droplet concentration is increased from 100 cm−3 to 1000 cm−3 (to represent an increase in CCN), the cloud water increases and then the rainwater is suppressed due to a decrease in the autoconversion rate, leading to a spatial shift in surface precipitation. Intercomparison of the results from the autoconversion schemes show that the sensitivity of cloud water, rainwater, and surface precipitation to a change in the concentration of CCN is different from scheme to scheme. In particular, the decrease in orographic precipitation due to increasing CCN is found to range from −87% to −10% depending on the autoconversion scheme. Moreover, the surface precipitation distribution also changes significantly by scheme or CCN concentration, and the increase in the spillover (ratio of precipitation on the leeward side to total precipitation) induced by increased CCN ranges from 10% to 55% under different autoconversion schemes. The simulations suggest that autoconversion parameterization schemes should not be ignored in the interaction of aerosol and orographic cloud.

How to cite: Xiao, H.: Effect of Aerosol Particles on Orographic Clouds: Sensitivity to Autoconversion Schemes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12070, https://doi.org/10.5194/egusphere-egu2020-12070, 2020.

EGU2020-12573 | Displays | AS1.24

Simulating mixed-phase cloud properties with ICON around the CAPRICORN field campaign at the kilometre scale

Veeramanikandan Ramadoss, Alain Protat, Yi Huang, Steven Siems, and Anna Possner

Stratocumulus clouds are low-level boundary layer clouds that cover 23% of the ocean surface on a global average, with a mean coverage of 25% to 40% in the mid-latitude oceans. These clouds affect Earth's radiative balance due to their strong radiative cooling effect. Many climate models underestimate the reflection of short wave radiation over the Southern Ocean (SO) which results in a positive mean bias of 2K in the annual mean SST in the mid-latitudes of the southern hemisphere. The organization, cloud field properties and the cloud radiative effects of these clouds occur at the lee of cold front in the SO are analyzed in this study. At this conference, we will present preliminary results.
Real case simulations are performed in this study by using ICON - LAM (Icosahedral Nonhydrostatic - Limited Area Model) with two-way nesting domains of resolutions 4.9 km to 2.4 km to 1.2 km. The initial and lateral boundary conditions for the model are derived from IFS meteorological data. CAPRICORN (Clouds, Aerosols, Precipitation, Radiation, and Atmospheric Composition over the Southern Ocean) field campaign that took place during March and April 2016 has continuously observed the open-cell and stratocumuli using shipborne radars and lidars on 26 and 27 March 2016 at the lee of a cold front between 47ºS 144ºE and 45ºS 146ºE (South of Tasmania). The results are evaluated quantitatively and qualitatively with the shipborne observations and HIMAWARI satellite retrievals respectively.

How to cite: Ramadoss, V., Protat, A., Huang, Y., Siems, S., and Possner, A.: Simulating mixed-phase cloud properties with ICON around the CAPRICORN field campaign at the kilometre scale, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12573, https://doi.org/10.5194/egusphere-egu2020-12573, 2020.

EGU2020-12591 | Displays | AS1.24

Linking marine fog variability in Atlantic Canada to changes in large-scale atmospheric and marine features

Patrick Duplessis, Minghong Zhang, William Perrie, George A Isaac, and Rachel Y W Chang

Marine and coastal fog forms mainly from the cooling of warm and moist air advected over a colder sea surface. Atlantic Canada is one of the foggiest regions of the world due to the strong temperature contrast between the two oceanic currents in the vicinity. Recurring periods of low visibility notably disrupt off-shore operations and marine traffic, but also land and air transportation. On longer time-scales, marine fog variability also has a significant impact on the global radiative budget. Clouds, including fog, are the greatest source of uncertainty in the current climate projections because of their complex feedback mechanisms. Meteorological records indicate a significant negative trend in the occurrence of foggy conditions over the past six decades at most airports in Atlantic Canada, with large internal variability, including interannual and interdecadal variations. Using the airport observations, reanalysis data and climate model outputs, we investigated the various variabilities on the trend, at interannual and interdecadal scales, and attempted to address what caused these changes in fog frequency. Our results show that the strength and position of the North Atlantic Subtropical High as well as the sea-surface temperature of the cold and warm waters near Atlantic Canada were highly correlated with fog occurrence. We applied the derived fog indices on climate model outputs and projected the fog trends and variability in the different future climate scenarios. The results from this study will be compared with those obtained from other methods and the implications will be discussed.

How to cite: Duplessis, P., Zhang, M., Perrie, W., Isaac, G. A., and Chang, R. Y. W.: Linking marine fog variability in Atlantic Canada to changes in large-scale atmospheric and marine features, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12591, https://doi.org/10.5194/egusphere-egu2020-12591, 2020.

EGU2020-12950 | Displays | AS1.24

Time dependence of climate sensitivity

Kai-Uwe Eiselt, Rune Graversen, and Hege-Beate Fredriksen

Climate sensitivity is a measure for the global mean temperature change of the earth in response to a given radiative forcing. In an experiment with an instantaneous forcing by e.g. a doubling of the atmospheric CO2 content the radiative imbalance at the top of the atmosphere can be regarded as a function of the global mean temperature change. In such an experiment the climate sensitivity can be approximated by linearly extrapolating to zero the TOA imbalance where equilibrium is obtained. The thus derived value is usually referred to as effective climate sensitivity. It has been established however, that the effective climate sensitivity changes over time. While the reason for this change is not clear, most recent investigations of the abrupt4xCO2 experiments of multiple members of the CMIP5 archive point to a delay in warming of the eastern tropical Pacific region relative to the global average in the multi model mean. Due to high stability in this region the heat is trapped there close to the surface which reduces the local lower tropospheric stability. The trapping of the warming close to the surface implies that the longwave cooling is less efficient in this region and its delayed warming relative to the global average increases global climate sensitivity over time. The decrease in lower tropospheric stability furthermore reduces low cloud cover leading to less negative low cloud feedback which causes additional warming.

We investigate the delayed warming in the eastern Pacific region in more detail in terms of its effects on stability as well as clouds for individual members and multi model means of both the CMIP5 and CMIP6 archives. We find that in the multi model mean, the CMIP6 members show an even larger delayed warming than the CMIP5 members. Furthermore, the individual members of both archives generally exhibit the same pattern of delayed eastern tropical Pacific warming and a corresponding decrease in lower tropospheric stability in the same region, which indicates robustness of the earlier results based on the CMIP5 multi model mean. Additionally, there is a decrease in liquid water content in the lower atmospheric layers, confirming the influence of reduced lower tropospheric stability on low clouds. However, there are several further regions such as the Southern Ocean with a consistent delayed warming and reduced stability, which might influence climate sensitivity as well.

How to cite: Eiselt, K.-U., Graversen, R., and Fredriksen, H.-B.: Time dependence of climate sensitivity, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12950, https://doi.org/10.5194/egusphere-egu2020-12950, 2020.

Clouds and their interaction with aerosols are considered one of the major factors that are connected with uncertainties in predictions of climate change and are highly associated with earth radiative balance. Semi long term in-situ measurements of Arctic low-level clouds have been conducted during last 10 year (2009 - 2019) autumns at Sammaltunturi station (67◦58´N, 24◦07´E, and 560 m a.s.l.), the part of Pallas Atmosphere - Ecosystem Supersite and Global Atmosphere Watch (GAW) programme. During these years a unique data set of continuous and detailed ground-based cloud observations over the sub-Arctic area was obtained. The in-situ cloud measurements were made using two cloud probes that were installed on the roof of the station: the Cloud, Aerosol and Precipitation Spectrometer probe (CAPS) and the Forward Scattering Spectrometer Probe (FSSP), both made by droplet measurement technologies (DMT, Longmont, CO, USA). CAPS in­cludes three instruments: the Cloud Imaging Probe (CIP, 12.5 μm-1.55 mm), the Cloud and Aerosol Spectrometer (CAS-DPOL, 0.51-50 μm) with depolarization feature and the Hotwire Liquid Water Content Sensor (Hotwire LWC, 0 - 3 g/m3). Vaisala FD12P weather sensor was used to measure all the meteorological data. The essential cloud microphysical parameters we investigated during this work were the size distributions, the total number concentrations, the effective radius of cloud droplets and the cloud liquid water content. The year to year comparison and correlations among semi long term in situ cloud measurements and meteorology are presented.

How to cite: Doulgeris, K. and Brus, D.: In situ ground based measurements of low level clouds during 10 years of Pallas cloud experiments., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13138, https://doi.org/10.5194/egusphere-egu2020-13138, 2020.

EGU2020-2930 | Displays | AS1.24

Dense Fog Burst Reinforcement over Eastern China

Duanyang Liu, Zihua Li, Wenlian Yan, Hongbin Wang, Chengying Zhu, Yuying Zhu, and Fan Zu

Fog can be hazardous weather. Dense and polluted fog is especially known to impact transportation, air quality, and public health. Low visibilities on fog days threaten the safety of air, sea and land traffic, especially in strong dense fog (SDF) and extremely dense fog (EDF), which is the most likely to cause accidents such as car rear-end collisions and ship collisions. Throughout more than ten years of observations, strong dense fog (SDF) (visibility less than 200m) and extremely dense fog (EDF) (visibility less than 50m) often occurred in the central and eastern regions of China. This could lead to serious traffic accidents.

This research summarizes the research results of dense fog in China, including the burst reinforcement features of strong dense fog (SDF) formation, universal feature of SDF, the microphysical process of the fog body enhancement, the causes of burst reinforcement and the characteristics of the boundary layer structure. There are also remarks about fog dissipations. The research results show that there are still many important scientific problems to be solved about dense fog. Future directions for understanding Dense Fog Burst Reinforcement including that: (1) How fog expands to the surrounding areas, and what factors influence the spread of fog? (2) The physical mechanism of dense fog burst reinforcement. (3) It needs to be further observed to study the role of low-level jets in the formation of dense fog. How the low-level jet stream forms? (4) impact of air pollution on the dense fog formation.

How to cite: Liu, D., Li, Z., Yan, W., Wang, H., Zhu, C., Zhu, Y., and Zu, F.: Dense Fog Burst Reinforcement over Eastern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2930, https://doi.org/10.5194/egusphere-egu2020-2930, 2020.

Atmospheric aerosols emitted from both natural and anthropogenic sources play a crucial role in the Earth’s radiation budget and regulating its climate. The mechanisms through which aerosols influence the radiation budget of the Earth is often classified as direct, semi-direct, and indirect effects of aerosols. It is important to understand the perturbation caused in the radiation budget of the Earth due to changing emissions of individual aerosol species and their precursors not only for estimating the responses of the climate system to such perturbations but also to be able to attribute these responses to changes in specific aerosol species and their sources for planning any mitigation or adaptation strategy to any undesirable consequences of climate change caused by aerosols. In the present study we use the Community Atmosphere Model version 5.3 (CAM5.3) to quantify the direct, semi-direct, and indirect aerosol radiative forcing due to changes in the emissions of individual aerosol species or their precursors from the pre-industrial (PI) to present day (PD) period following a new methodology proposed by Ghan et al. (2012) involving additional radiative diagnostics with neglected absorption and scattering of aerosols, whereas absorption and scattering of aerosols for the actual model setup remains unchanged. A series of systematically designed simulations with concentrations of individual aerosol species set to zero are conducted in order to estimate the direct, semi-direct, and indirect aerosol radiative forcing due to the corresponding aerosol species. Our preliminary results shows the global annual mean value of direct Short-Wave radiative forcing (DRF) at TOA due to all aerosols to be around -0.01W/m2, while the Cloud radiative forcing (CRF) to be around -1.5W/m2. The bias in the aerosol radiative forcing estimates as per the old conventional method are almost -0.55W/m2 for DRF which is nearly 60 times the DRF estimated using the new approach and 0.23W/m2 for CRF which is almost 15.43% of the total CRF at TOA respectively. Interestingly, for the South Asian region, the DRF based on the new approach is found to be positve in almost across south Asia (0.097 W/m2) thereby signifying a trapping of energy in the atmosphere due to aerosols, whereas according to the old conventional method the DRF is estimated to be around -0.59 W/m2 signifying a loss of energy in the atmosphere due to aerosols. Similarly a difference of about 1 W/m2 is noted in the estimates of CRF as per the new and the old methods of estimating radiative forcing. More results with greater details on the contribution of individual aerosols towards the total aerosol radiative forcing and other important meteorological parameters will be presented.

How to cite: Sharma, A. K. and Ganguly, D.: Investigating the sensitivity of direct, semi-direct and indirect effects of aerosols to changes in the emissions of individual aerosol species using a climate model., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18115, https://doi.org/10.5194/egusphere-egu2020-18115, 2020.

EGU2020-18691 | Displays | AS1.24

Potential of natural seeding by ice clouds over Switzerland

Ulrike Proske, Verena Bessenbacher, Zane Dedekind, Ulrike Lohmann, and David Neubauer

The ice phase in clouds determines many of their key properties and influences the water cycle, since most precipitation globally originates from the ice phase. Ice crystals falling as seeds from an ice cloud into a lower lying mixed-phase or liquid cloud can influence ice and precipitation formation. In the lower lying cloud, the ice crystals feed on the liquid, grow and enhance precipitation (seeder-feeder mechanism) or trigger glaciation (natural cloud seeding). The seeder-feeder mechanism has been associated with the intensification of extreme precipitation and flooding.

Even though there have been multiple case studies of the seeder-feeder mechanism and a few on natural cloud seeding, estimates of the occurrence frequency of these processes are lacking.

We derived the frequency of possible seeding situations (ice-layer above liquid or mixed-phase cloud layer) from radar/lidar satellite observations over Switzerland. We found an ice layer to be present above another cloud layer about 20% of the time. The distance between the cloud layers was uniformly distributed between 100m and 10km. In sublimation calculations we used the mean effective ice crystal radius from the satellite observations and calculated the crystals’ sublimation height, assuming a spherical shape. In a significant number of cases ice crystals would survive the fall between the two cloud layers. We investigated the effect of the falling ice crystals on the lower lying cloud layer and on precipitation formation in sensitivity studies of selected situations with the regional climate model COSMO.

The high occurrence frequency of seeding situations and the survival of the ice crystals indicate the seeder-feeder process and natural cloud seeding as widespread phenomena. To infer their importance, the magnitude of the seeding ice crystals’ effect on lower lying clouds and precipitation needs to be established.

How to cite: Proske, U., Bessenbacher, V., Dedekind, Z., Lohmann, U., and Neubauer, D.: Potential of natural seeding by ice clouds over Switzerland, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18691, https://doi.org/10.5194/egusphere-egu2020-18691, 2020.

EGU2020-21290 | Displays | AS1.24

Ground-based lidar processing and simulator framework for comparing models and observations

Peter Kuma, Adrian McDonald, Olaf Morgenstern, Richard Querel, Israel Silber, and Connor Flynn

Automatic lidars and ceilometers (ALCs) are well-established instruments for remote sensing of the atmosphere, with a large network of instruments deployed globally. Even though they provide a wealth of information about clouds and aerosol, they have not been used extensively to evaluate models. They complement active satellite observations, which are often unable to accurately detect low clouds due to obscuration by mid and high-level clouds. ALCs cannot be used directly for atmospheric model cloud scheme evaluation due to the wavelength-dependent attenuation of the lidar signal by clouds. Therefore, a forward lidar simulator has to be used to transform model fields to simulated backscatter comparable to backscatter measured by ALCs. Here we describe the Automatic Lidar and Ceilometer Framework (ALCF), an open source lidar processing tool and forward ground-based lidar simulator capable of transforming widely-used reanalysis and model output into a data structure which can be directly compared with observations. It implements steps such as conversion, absolute calibration, resampling, noise removal, cloud detection, model data extraction, and forward lidar simulation. The simulator is based on the Cloud Feedback Model Intercomparison Project (CFMIP) Observation Simulator Package (COSP), previously used with spaceborne lidars, with extensions for several ground-based ALCs. The forward simulator is essential to get from raw ALC and model data to a one-to-one backscatter profile. It also allows statistical comparison of cloud between models and observations. Four common commercial ALCs (Vaisala CL31, CL51, Lufft CHM 15k and Sigma Space MiniMPL), three reanalyses (ERA5, JRA-55, and MERRA-2), and two NWP models and GCMs (AMPS and the Unified Model) are supported. We present case studies evaluating cloud in the supported reanalyses and models using multi-instrument observations at three sites in New Zealand. We show that at these sites the reanalyses and models generally underestimate cloud fraction and overestimate cloud albedo. We demonstrate that the ALCF can be used as a generic cloud evaluation tool. It can assist in improving model cloud simulation, which has been identified as a critical deficiency in contemporary models limiting the accuracy of future climate projections.

How to cite: Kuma, P., McDonald, A., Morgenstern, O., Querel, R., Silber, I., and Flynn, C.: Ground-based lidar processing and simulator framework for comparing models and observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21290, https://doi.org/10.5194/egusphere-egu2020-21290, 2020.

EGU2020-21980 | Displays | AS1.24

Stratocumulus Clouds at the West Coast of South America: Observations of Diurnal and Seasonal Cycle

Jan H. Schween, Sarah Westbrook, and Ulrich Löhnert

Marine stratocumulus clouds of the eastern Pacific play an essential role in the Earth's energy and radiation budget. Parts of these clouds off the west coast of South America form the major source of water to the hyper-arid area at the northern coast of Chile. Within the DFG collaborative research center 'Earth evolution at the dry limit', for the first time, a long-term study of the vertical structure of clouds and their environment governing the moisture supply to the coastal part of the Atacama is available.

Three state of the art ground based remote sensing instruments were installed for one year at the airport of Iquique/Chile (20.5°S, 70.2°W, 56m a.s.l.) in close cooperation with Centro del Desierto de Atacama (Pontificia Universidad Católica de Chile). The instruments provide vertical profiles of wind, turbulence and temperature, as well as integrated values of water vapor and liquid water. Instrument synergy provides vertical cloud structure information.

We observe a land-sea circulation with a super-imposed southerly wind component. Highest wind speeds can be found during the afternoon. Clouds show a distinct seasonal pattern with a maximum of cloud occurrence during winter (JJA) and a minimum during summer (DJF). Clouds are higher and vertically less extended in winter than in summer. Liquid water path shows a diurnal cycle with highest values during night and morning hours and lowest values during noon. Furthermore, the clouds contain much more liquid water in summer. The turbulent structure of the boundary layer, together with the temperature profile, can be used to characterize the mechanism driving the cloud life cycle.

How to cite: Schween, J. H., Westbrook, S., and Löhnert, U.: Stratocumulus Clouds at the West Coast of South America: Observations of Diurnal and Seasonal Cycle , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21980, https://doi.org/10.5194/egusphere-egu2020-21980, 2020.

EGU2020-22027 | Displays | AS1.24

Empirical Formulation for number of ice crystal fragments by sublimational breakup

Akash Deshmukh and Vaughan Phillips

There is much uncertainty about high concentrations of ice observed in clouds and their origins. In the literature, there have been previous experimental studies reported about the sublimation process of an ice crystal causes emission of fragments by breakup.   Such sublimational breakup is a type of secondary ice production, which in natural clouds can cause ice multiplication. 

To represent this process of sublimation breakup in any cloud model, the present study proposes a numerical formulation of the number of ice fragments generated by sublimation of pristine ice crystal. This is done by amalgamating laboratory observations from previous published studies. The number of ice fragments determined by relative humidity (RH) and initial size of the ice particle were measured in the published experiments, and by simulating them we are able to infer parameters of a sublimation breakup scheme.   At small initial sizes, the dependency on size prevails, whereas at larger sizes both dependencies are comparable. This formulation is compared with observations to see the behaviour of it.

How to cite: Deshmukh, A. and Phillips, V.: Empirical Formulation for number of ice crystal fragments by sublimational breakup, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22027, https://doi.org/10.5194/egusphere-egu2020-22027, 2020.

AS1.25 – Atmospheric Convection

EGU2020-16505 | Displays | AS1.25

Forced Convective Aggregation

Beth Dingley, Guy Dagan, and Philip Stier

The phenomenon of convective aggregation in idealised radiative convective equilibrium simulations has the ability to change the mean state of its domain. When compared to non-aggregation conditions, these simulations usually have warmer drier mean atmospheres, with stronger precipitation in the convective areas. Many of these idealised experiments use a fixed sea surface temperature (SST), where higher temperatures generally increase the scale of aggregation. SST gradients have been shown to organise convection, yet there has been no work done to investigate the impact of heating perturbations in the air on the aggregation of convection. Here we investigate how strong diabatic heating of the atmospheric column affect the existence and properties of convective aggregation. These perturbations provide a link to studying the effect of large pollution plumes on convection, for example during the Indian monsoon season.

An aerosol model is used to insert plumes of strongly absorbing aerosols into aquaplanet, non-rotating, global RCE simulations. We study the sensitivity of the response to aerosol optical depth (AOD) and aerosol radiative properties under different SSTs.

Without any forcing, the simulations at low SST do not aggregate while at high SST they do. We also see that adding the forcing causes aggregation at both temperatures for a wide range of AODs. Detailed investigation shows that the diabatic heating source causes two circulations to develop, one with low-level convergence towards the plume and high-level divergence away from the plume. A secondary circulation works tangentially to the plume, again with low-level convergence and high-level divergence, driving the formation of several radial branches of aggregated convection. We argue that, as we see this aggregation for plumes with realistic AODs, this could be an analogue for real-world organisation during high pollution events. Future work will investigate the difference in mechanisms between forced and unforced convective aggregation as well as conducting similar experiments in smaller, cloud resolving domains.

How to cite: Dingley, B., Dagan, G., and Stier, P.: Forced Convective Aggregation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16505, https://doi.org/10.5194/egusphere-egu2020-16505, 2020.

EGU2020-14941 | Displays | AS1.25

Impact of an Interactive SST on the Convective Aggregation Process

Sara Shamekh, Caroline Muller, Jean-Philippe Duvel, and Fabio D'Andrea

The spontaneous aggregation of convective clouds over a moist portion of the domain is ubiquitous in cloud resolving model simulations. This phenomenon significantly reduces the domain mean total water vapor and enhances the outgoing long radiation. In this study we use the system of atmospheric modeling (SAM) in a radiative-convective equilibrium (RCE) setup in order to investigate the impact of an interactive sea surface temperature (SST) on the aggregation progress. We use a slab ocean (with depth of 5, 10 and 50 m) with constant target SST to which the domain mean SST is relaxed. Our results show that, consistent with previous studies, an interactive SST delays the aggregation with a larger impact for a shallower slab. This effect is enhanced for a smaller target SST.

The aggregation proceeds by the expansion of non-convective dry areas. Before aggregation, dry areas are associated with warmer surface due to enhanced short-wave radiation. During and after the aggregation, a single large dry patch develops and is associated with a colder surface. This cooling is due to a reduction in downwelling long-wave radiation and to enhanced latent heat flux due to drier boundary layer. The edge of the dry patch has warm SST anomaly forming a ring of warm water around it that favors divergence of low-level moist air from the dry patch and accelerates dry patch expansion. This is favored by a positive surface pressure anomaly (PSFC) in the dry patch.

Therefore, at first, the warm SST anomaly opposes the divergent flow from dry regions, opposing the aggregation. Then the cold SST anomaly that develops in dry regions increases the divergent flow and favors the dry patch expansion. For a small ocean slab, the warm SST anomaly that develops in the dry areas at early times inhibits the dry patch expansion and can significantly delay the beginning of aggregation.

How to cite: Shamekh, S., Muller, C., Duvel, J.-P., and D'Andrea, F.: Impact of an Interactive SST on the Convective Aggregation Process, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14941, https://doi.org/10.5194/egusphere-egu2020-14941, 2020.

EGU2020-11878 | Displays | AS1.25

Diurnal Self-Aggregation

Jan O. Haerter, Bettina Meyer, and Silas Boye Nissen

Convective self-aggregation is a modelling paradigm for thunderstorm organisation over a constant-temperature tropical sea surface. This setup can give rise to cloud clusters over timescales of weeks. In reality, sea surface temperatures do oscillate diurnally, affecting the atmospheric state. Over land, surface temperatures vary more strongly, and rain rate is significantly influenced. Here, we carry out a substantial suite of cloud-resolving numerical experiments, and find that even weak surface temperature oscillations enable qualitatively different dynamics to emerge: the spatial distribution of rainfall is only homogeneous during the first day. Already on the second day, the rain field is firmly structured. In later days, the clustering becomes stronger and alternates from day to day. We show that these features are robust to changes in resolution, domain size, and surface temperature, but can be removed by a reduction of the amplitude of oscillation, suggesting a transition to a clustered state. Maximal clustering occurs at a scale of lmax≈180 km, a scale we relate to the emergence of mesoscale convective systems. At lmax rainfall is strongly enhanced and far exceeds the rainfall expected at random. We explain the transition to clustering using simple conceptual modelling. Our results may help clarify how continental extremes build up and how cloud clustering over the tropical ocean could emerge much faster than through conventional self-aggregation alone.

How to cite: Haerter, J. O., Meyer, B., and Nissen, S. B.: Diurnal Self-Aggregation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11878, https://doi.org/10.5194/egusphere-egu2020-11878, 2020.

EGU2020-6219 | Displays | AS1.25

A Lagrangian perspective on cold pool collisions

Giuseppe Torri and Zhiming Kuang

Collisions represent one of the most important processes through which cold pools—essential boundary layer features of precipitating systems—help to organize convection. For example, by colliding with one another, expanding cold pools can trigger new convective cells, a process that has been argued to be important to explain the deepening of convection and the maintenance of mesoscale convective systems for many hours. In spite of their role, collisions are an understudied process, and many aspects remain to be fully clarified. In order to quantify the importance of collisions on the life cycle of cold pools, we will present some results based on a combination of numerical simulations in radiative-convective equilibrium and a Lagrangian cold pool tracking algorithm. First, we will discuss how the Lagrangian algorithm can be used to estimate that the median time of the first collision for the simulated cold pools is under 10 minutes. We will then show that cold pools are significantly deformed by collisions and lose their circular shape already at the very early stages of their life cycle. Finally, we will present results suggesting that cold pools appear to be clustered, and we will provide some estimates of the associated temporal and spatial scales.

How to cite: Torri, G. and Kuang, Z.: A Lagrangian perspective on cold pool collisions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6219, https://doi.org/10.5194/egusphere-egu2020-6219, 2020.

Cold pools are essential for organizing convection and play a particular role in convective initiation in the afternoon and evening. Both aspects are deficient in current convection-permitting models and a better representation of cold pools is likely necessary to overcome these deficiencies. In a recent investigation, we identified several sensitivities of cold pool driven convective initiation to model resolution within hectometer simulations. In particular, a causal graph analysis has revealed that the dominant impact of model resolution on convective initiation is due to too weak gust front vertical velocities. This implies that cold pool gust fronts in km-scale models are too weak to trigger sufficient new convection.

To address this deficiency, we develop a parameterization for the convection-permitting COSMO model to improve the representation of cold pool gust fronts. We use the potential temperature gradient to identify cold pool gust fronts and enhance vertical wind tendencies within these gust front regions.  Also, we perturb horizontal wind tendencies to yield 3d non-divergent perturbations.  This parameterization strengthens gust front circulations and thereby enhances cold pool driven convective initiation. Consequently, precipitation is amplified and becomes more organized in the afternoon and evening. This improves the diurnal cycle of precipitation and also has some positive impact on the spatial distribution as quantified by the fraction skill score. Furthermore, cold pools themselves are strengthened, which can further enhance the gust front circulations, giving rise to a feedback loop. 

How to cite: Hirt, M. and Craig, G.: Cold pool driven convective initiation: How can we improve its representation in km-scale models?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5260, https://doi.org/10.5194/egusphere-egu2020-5260, 2020.

EGU2020-9779 | Displays | AS1.25

Sub-mesoscale observations of cold pools during FESSTVaL

Bastian Kirsch, Felix Ament, Cathy Hohenegger, and Daniel Klocke

Cold pools are areas of cool downdraft air that form through evaporation underneath precipitating clouds and spread on the surface as density currents. Their importance for the development and maintenance of convection is long known. Modern Large-Eddy simulations with a grid spacing of 1 km or less are able to explicitly resolve cold pools, however, they lack reference data for an adequate validation. Available point measurements from operational networks are too coarse and, therefore, miss the horizontal structure and dynamics of cold pools.

The upcoming measurement campaign FESSTVaL (Field Experiment on Sub-mesocale Spatio-Temporal Variability in Lindenberg) aims to test novel measurement strategies for the observation of previously unresolved sub-mesoscale boundary layer structures and phenomena, such as cold pools. The key component of the experiment during this summer will be a dense network of ground-based measurements within 15 km around the Meteorological Observatory Lindenberg near Berlin. The network of 100 low-cost APOLLO (Autonomous cold POoL LOgger) stations allows to record air pressure and temperature with a spatial and temporal resolution of 100 m and 1 s, respectively. We present first results from a test campaign during last summer that successfully demonstrated the ability of the proposed network stations to observe cold pool dynamics on the sub-mesoscale.

How to cite: Kirsch, B., Ament, F., Hohenegger, C., and Klocke, D.: Sub-mesoscale observations of cold pools during FESSTVaL, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9779, https://doi.org/10.5194/egusphere-egu2020-9779, 2020.

Idealized simulations have shown decades ago that shallow clouds generate internal gravity waves, which under certain atmospheric background conditions become trapped inside the troposphere and influence the development of clouds. These feedbacks, which occur at horizontal scales of up to several tens of km are neither resolved, nor parameterized in traditional global climate models (GCMs), while the newest generation of GCMs is starting to resolve them. The interactions between the convective boundary layer and trapped waves have almost exclusively been studied in highly idealized frameworks and it remains unclear to what degree this coupling affects the organization of clouds and convection in the real atmosphere. Here, the coupling between clouds and trapped waves is examined in storm-resolving simulations that span the entirety of the tropical Atlantic and are initialized and forced by meteorological analyses. The coupling between clouds and trapped waves is sufficiently strong to be detected in these simulations of full complexity.  Stronger upper-tropospheric westerly winds are associated with a stronger cloud-wave coupling. In the simulations this results in a highly-organized scattered cloud field with cloud spacings of about 19 km, matching the dominant trapped wavelength. Based on the large-scale atmospheric state wave theory can reliably predict the regions and times where cloud-wave feedbacks become relevant to convective organization. Theory, the simulations and satellite imagery imply a seasonal cycle in the trapping of gravity waves. 

How to cite: Stephan, C.: Seasonal modulation of trapped gravity waves and their imprints on trade wind clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2612, https://doi.org/10.5194/egusphere-egu2020-2612, 2020.

EGU2020-1061 | Displays | AS1.25

Statistical Characteristics of Thermal Convection Structures based on Acoustic Sounding Data

Natalia Vazaeva, Otto Chkhetiani, Michael Kurgansky, Margarita Kallistratova, Vasily Lyulyukin, and Daria Zaytseva

The thermal convection structures (TCS) and their characteristics manifestations in the atmospheric boundary layer were investigated using the data from acoustic Doppler sodar LATAN-3M. A longwave LATAN-3M sodar with a vertical resolution of 20 m in 2007 and 10 m in 2016, 2018, 2019, a pulse emission interval of 5 s in 2007 and 3 s in 2016, 2018, 2019, an altitude range of 400–600 m in 2007 and 350 m in 2016, 2018, 2019, and a basic carrier frequency of 2 kHz in 2007 and 3 kHz in 2016, 2018, 2019 had measured the profiles of the wind velocity components which were used for calculating the scale of TCS. Experimental data were being obtained during the field campaigns organized by the A.M. Obukhov Institute of Atmospheric Physics RAS in Rostov region and over semi-arid zones of the Caspian lowland in the eastern part of Kalmykia Republic, Russia.

The wind was weak and the convection was well-developed in the case studies over July of years 2007, 2016, 2018, 2019. A moving rectangular filter was used for averaging the original data of the horizontal and vertical wind-velocity components. The averaging interval had been empirically chosen and, in this case, amounted to 10 min. At such values, the spatiotemporal velocity-field structure was adequately reproduced.

The original method of acoustic sounding data treatment for extracting TCS has been developed and put to an evaluation test. The episodes of the vertical velocities above limit values at which TCS aroused hypothetically were considered. As the threshold, a few alternatives were used: 0.3 m/s, 0.6 m/s and 1.2 m/s. The duration of vertical velocity excess over the threshold, the maximum velocity within this interval and the horizontal scale were calculated. It is assumed that TCS move forward with some averaged velocity during any relatively small time step. In this case, the spatial distribution of velocity field and its time variations have been reproduced suitably.

The statistical distribution was close to Rayleigh distribution:

p(U) = (2U/U02)*exp ((Um2-U 2)/U02),

where U02 = (<U 2>-Um2), <U 2> is the root-mean-square vertical velocity of TCS, and Um – the threshold for vertical velocity. This closeness can facilitate the understanding of the processes in the so-called “grey-zone” of numerical simulation and be implemented in the parameterization, forecast of TCS. Note that Rayleigh distribution is applied to the statistics of the intense moist convective vortices and also of the height of the ocean waves.

This work was supported by Russian Foundation for Basic Research (projects No.19-05-50110, No.19-05-01008, No.17-05-41121), and by fundamental research program of Russian Academy of Science (program No.1).

How to cite: Vazaeva, N., Chkhetiani, O., Kurgansky, M., Kallistratova, M., Lyulyukin, V., and Zaytseva, D.: Statistical Characteristics of Thermal Convection Structures based on Acoustic Sounding Data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1061, https://doi.org/10.5194/egusphere-egu2020-1061, 2020.

EGU2020-9511 | Displays | AS1.25

Experimental investigation on turbulent rotating thermal convection at large Rayleigh numbers

Marcel Wedi, Dennis van Gils, Guenter Ahlers, Eberhard Bodenschatz, and Stephan Weiss

Thermal convection is of major importance in various astro- and geophysical systems, exemplary are buoyancy driven flows in the atmosphere or in the stellar interior. It has been studied for decades in an idealized model system - the Rayleigh-Bénard convection (RBC) - which consists of a horizontal fluid layer heated at the bottom and cooled at the top. Within the Oberbeck-Boussinesq approximation this system is controlled by two parameters only. These are the Rayleigh number (Ra), which represents the thermal driving and the Prandtl number (Pr) that relates the momentum and thermal diffusivities of the fluid. Convection flows in geo- and astrophysics are often influenced by Coriolis forces due to the rotation of the planet or the star. In RBC-system, Coriolis forces are introduced by rotating the convection cell around its vertical axis. The rotation is expressed by an additional dimensionless control parameter, i.e., the inverse Rossby number 1/Ro. We study experimentally the influence of rotation on the heat transport and the temperature field at very large Ra in the High Pressure Convection Facility (HPCF) in Göttingen. The facility consists of a cylindrical cell of 1.10m diameter and 2.20m height that is filled with pressurized sulfur hexafluoride (SF6) at up to 19bar. The height of the cell and the large density of SF6 enable us to reach very large Ra (up to 8×1014) at 0.74<Pr<0.96. The cell is mounted on a rotating table and connected to the non-rotating world via water feed-throughs and slip rings. With these, the signals of more than 100 thermistors close to the sidewalls are collected.
We find a monotonic decrease of the heat transport with increasing rotation rate. Furthermore, we measure quantities of the flow close to the lateral side walls of the convection cylinder. For large rotation rates we analyze this as part of the recently proposed “Boundary Zonal Flow” (BZF), where the vertical heat transport is enhanced and warm (cold) up (down) flow self-organizes in a periodic manner. In the experiment we observe the BZF most notably in the probability density function of the temperature, which develops a bimodal Gaussian distribution. We also find that the periodic warm-cold structure drifts in anti-cyclonic direction and thus form traveling waves of the temperature field.

How to cite: Wedi, M., van Gils, D., Ahlers, G., Bodenschatz, E., and Weiss, S.: Experimental investigation on turbulent rotating thermal convection at large Rayleigh numbers, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9511, https://doi.org/10.5194/egusphere-egu2020-9511, 2020.

EGU2020-6465 | Displays | AS1.25

Thermodynamic constraints on the size distributions of tropical convective clouds.

Timothy Garrett, Steven Krueger, Ian Glenn, and Nicolas Ferlay
Parameterizations for sub-grid cloud dynamics are commonly developed by using fine scale modeling or measurements to explicitly resolve the mechanistic details of clouds to the best extent possible, and then to formulating these behaviors cloud state for use within a coarser grid. A second is to invoke physical intuition and some very general theoretical principles from equilibrium statistical thermodynamics. This second approach is quite widely used elsewhere in the atmospheric sciences: for example to explain the heat capacity of air, blackbody radiation, or even the density profile or air in the atmosphere. Here we describe how entrainment and detrainment across cloud perimeters is limited by the amount of available air and the range of moist static energy in the atmosphere, and that constrains cloud perimeter distributions to a power law with a -1 exponent along saturated isentropes and to a Boltzmann distribution across saturated isentropes. Further, the total cloud perimeter in a cloud domain is directly tied to the buoyancy frequency with respect to a moist adiabatic in the column. These simple results are shown to be reproduced within a complex dynamic simulation of a tropical convective cloud field, the Giga-LES, and in passive satellite observations of cloud 3D structures. The suggestion is that statistical properties of tropical cloud structures can be inferred from the bulk thermodynamic structure of the atmosphere rather than much more computationally expensive dynamic simulations.

How to cite: Garrett, T., Krueger, S., Glenn, I., and Ferlay, N.: Thermodynamic constraints on the size distributions of tropical convective clouds. , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6465, https://doi.org/10.5194/egusphere-egu2020-6465, 2020.

EGU2020-21644 | Displays | AS1.25

A semi-Lagrangian perspective of the lifecycle and interactions of deep convective clouds in geostationary satellite observations

William Jones, Max Heikenfeld, Matthew Christensen, and Philip Stier

The disparity in the increase in atmospheric water vapour and in the global energy budget with global warming is expected to lead to a greater contribution of precipitation from deep convective clouds (DCCs) to total precipitation. How this increase occurs is uncertain however; while many climate models predict that the intensity of precipitation in individual storms will increase while occurring at the same frequency, satellite observations of tropical cloud clusters have shown that the frequency of organised deep convective precipitation events is increasing. By studying the interactions between deep convective precipitation and the energy and water budgets, we aim to achieve a better understanding of how these budgets affect the intensity, frequency and organisation of deep convective clouds and the cloud feedbacks on subsequent convection.

 

The new generation of geostationary imaging satellites provides greatly improved observations of dynamic processes. Using optical-flow techniques, we show how a semi-Lagrangian perspective can be applied to GOES advanced baseline imager observations in the thermal IR spectrum, and how this perspective can improve our observations of the dynamics of DCCs. In this new perspective we are able to robustly track DCCs over their entire lifecycle. As a result, the interactions between energy budgets, organisation and growing convection can be linked to subsequent precipitation and radiative feedbacks over the entire lifetime of the DCC.

 

In a case study over the continental US, we observe a suppression of convective strength in the days following large, organised convective storms. Compared to similar DCCs prior to the large organised events, the subsequent DCCs develop more slowly and, despite having a similar maximum anvil cloud extent, have a shorter overall lifetime. Furthermore, the later anvil clouds and convective cores have warmer cloud top brightness temperatures by 10 K and up to 20 K respectively. We hope to gain a greater understanding of whether these changes are due to large scale dynamics associated with the large, organised convection or can instead be attributed to local cloud and thermodynamic feedbacks.

How to cite: Jones, W., Heikenfeld, M., Christensen, M., and Stier, P.: A semi-Lagrangian perspective of the lifecycle and interactions of deep convective clouds in geostationary satellite observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21644, https://doi.org/10.5194/egusphere-egu2020-21644, 2020.

EGU2020-21657 | Displays | AS1.25

The elements of the thermodynamic structure of the tropical atmosphere

Jiawei Bao and Bjorn Stevens

Deep convection plays an important role in driving the large-scale circulation and the complex interaction between moist convection and the large-scale circulation regulates the thermodynamic structure of the tropical atmosphere. 

The convectional thoughts of the thermodynamic structure of the tropical atmosphere are that the horizontal temperature in the free troposphere is homogeneous, which is referred to as weak temperature gradient (WTG), while the vertical structure follows a moist-adiabatic lapse rate. However, it is not known how accurate WTG holds and which moist- adiabatic process the tropical atmosphere indeed experiences. This study centers around the horizontal and vertical structure of the tropical atmosphere and uses the global storm resolving simulations (GSRMs) from ICON at 2.5 km to investigate them

The virtual effect or the vapor buoyancy effect arises from that the molecular weight of water vapor is much smaller than that of dry air. With the same pressure and temperature, this virtual effect makes moist air lighter than dry air. As the horizontal buoyancy differences are eliminated by convection gravity waves, virtual temperature, a temperature variable including the moisture conditions, is expected to be homogeneous. Then, to obtain a homogeneous virtual temperature horizontally, the absolute temperature has to change to accommodate the horizontal moisture difference. The model results show that virtual temperature is relatively homogeneous at mid- and lower troposphere. Therefore, the virtual effect plays a very important role in the horizontal temperature structure, making the absolute temperature colder in moist regions and warmer in dry regions. However, in the upper troposphere, both the absolute temperature and the virtual temperature are not homogeneous, and vary as a function of moisture, indicating a weakening influence of convection gravity waves there.

We use saturation equivalent potential temperature (theta-es) to explore the vertical structure of the tropical atmosphere. Theta-es is expected to be conserved above the lifting condensation level (LCL) if calculated following the exact moist-adiabatic process that tropical atmosphere undergoes. The pseudo-adiabat and the reversible-adiabat with the effect of condensate loading are compared. To minimize the horizontal differences in theta-es due to moisture, we also define theta-es to account for the virtual effect and the condensate loading effect. The model results suggest that the actual moist-adiabatic process that tropical atmosphere experiences is between the pseudo-adiabat and the reversible-adiabat with the effect of condensate loading assuming air parcels originating from 972 hPa. 

The above results are broadly consistent with the results from ERA5 reanalysis.

How to cite: Bao, J. and Stevens, B.: The elements of the thermodynamic structure of the tropical atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21657, https://doi.org/10.5194/egusphere-egu2020-21657, 2020.

EGU2020-7076 | Displays | AS1.25

The influence of convective momentum transport and vertical wind shear on the evolution of a cold air outbreak

Beatrice Saggiorato, Louise Nuijens, A. Pier Siebesma, Stephan de Roode, Irina Sandu, and Lukas Papritz

To study the influence of convective momentum transport (CMT) on wind, boundary layer and cloud evolution in a marine cold air outbreak (CAO) we use Large-Eddy Simulations subjected to different baroclinicity (wind shear) but similar surface forcing. The simulated domain is large enough ( ≈100 × 100 km2) to develop typical mesoscale cellular convective structures.  We find that a maximum friction induced by momentum transport (MT) locates in the cloud layer for an increase of geostrophic wind with height (forward shear, FW) and near the surface for a decrease of wind with height (backward shear, BW). Although the total MT always acts as a friction, the interaction of friction-induced cross-isobaric flow with the Coriolis force can develop super-geostrophic winds near the surface (FW) or in the cloud layer (BW). The contribution of convection to MT is evaluated by decomposing the momentum flux by column water vapor and eddy size, revealing that CMT acts to accelerate sub-cloud layer winds under FW shear and that mesoscale circulations contribute significantly to MT for this horizontal resolution (250 m), even if small scale eddies are non-negligible and likely more important as resolution increases. Under FW shear, a deeper boundary layer and faster cloud transition are simulated, because MT acts to increase surface fluxes and wind shear enhances turbulent mixing across cloud tops. Our results show that the coupling between winds and convection is crucial for a range of problems, from CAO lifetime and cloud transitions to ocean heat loss and near-surface wind variability.

How to cite: Saggiorato, B., Nuijens, L., Siebesma, A. P., de Roode, S., Sandu, I., and Papritz, L.: The influence of convective momentum transport and vertical wind shear on the evolution of a cold air outbreak, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7076, https://doi.org/10.5194/egusphere-egu2020-7076, 2020.

EGU2020-9736 | Displays | AS1.25

Validity of the hydrostatic approximation at convection-resolving scales: Diagnostic analysis and model intercomparison

Christian Zeman, Nikolina Ban, Nils Wedi, and Christoph Schär
The increasing availability of computing power allows the use of kilometer-scale convection-resolving weather and climate models for operational forecasts. One of the open questions at these scales concerns the validity of the hydrostatic approximation, which assumes that vertical accelerations are small compared to the balancing forces of gravity and the vertical pressure gradient. This assumption is valid as long as the ratio of vertical to horizontal length scales of motion is small. Results from previous studies suggest that the horizontal resolution at which the hydrostatic approximation becomes invalid is highly dependent on the particular model, model configuration, and case setup.
 
While most of the previous studies have been conducted with an idealized setup, this work will concentrate on a real-world case. To this end, a few summer days with strong convection over complex terrain in Europe are simulated with the nonhydrostatic regional Consortium for Small-scale Modelling (COSMO) model with horizontal resolutions ranging from 12 km to 275 m. To assess the validity of the hydrostatic approximation, we developed a hydrostatic reconstruction technique and diagnose the vertical wind using the hydrostatic set of equations. The diagnosed values are then compared to the actual nonhydrostatic up- and downdrafts with a statistical analysis of vertical wind speed frequencies for the different resolutions.
 
Results suggest that the diagnosed hydrostatic vertical velocities are very similar to the nonhydrostatic vertical velocities up to horizontal resolutions of 1 km and thus the use of the hydrostatic approximations at these scales still seems to be a valid option.
 
Furthermore, the study contains an intercomparison of precipitation and vertical winds produced by the nonhydrostatic COSMO model and the hydrostatic Integrated Forecast System (IFS) from ECMWF for the same case. The intercomparison supports the previous findings that at resolutions of ∼2 km and ∼4 km the effect of the hydrostatic approximation is negligible. The results also show that a small enough timestep size is essential in order to properly resolve the high vertical velocities associated with convection.

How to cite: Zeman, C., Ban, N., Wedi, N., and Schär, C.: Validity of the hydrostatic approximation at convection-resolving scales: Diagnostic analysis and model intercomparison, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9736, https://doi.org/10.5194/egusphere-egu2020-9736, 2020.

EGU2020-3758 | Displays | AS1.25

Evaluation of Organized Convection Parameterization in Global Climate Models

Chih-Chieh Chen, Changhai Liu, Mitch Moncrieff, and Yaga Richter

The importance of convective organization on the global circulation has been recognized for a long time, but parameterizations of the associated processes are missing in global climate models. Contemporary convective parameterizations commonly use a convective plume model (or a spectrum of plumes). This is perhaps appropriate for unorganized convection but the assumption of a gap between the small cumulus scale and the large-scale motion fails to recognize mesoscale dynamics manifested in mesoscale convective systems (MCSs) and multi-scale cloud systems associated with the MJO. Organized convection is abundant in environments featuring vertical wind shear, and significantly modulates the life cycle of moist convection, the transport of heat and momentum, and accounts for a large percentage of precipitation in the tropics. Mesoscale convective organization is typically associated with counter-gradient momentum transport, and distinct heating profiles between the convective and stratiform regions.

Moncrieff, Liu and Bogenschutz (2017) recently developed a dynamical based parameterization of organized moisture convection, referred to as multiscale coherent structure parameterization (MCSP), for global climate models. A prototype version of MCSP has been implemented in the NCAR Community Earth System Model (CESM) and the Energy Exascale Earth System Model (E3SM), positively affecting the distribution of tropical precipitation, convectively coupled tropical waves, and the Madden-Julian oscillation. We will show the further development of the MCSP and its impact on the simulation of mean precipitation and variability in the two global climate models.

How to cite: Chen, C.-C., Liu, C., Moncrieff, M., and Richter, Y.: Evaluation of Organized Convection Parameterization in Global Climate Models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3758, https://doi.org/10.5194/egusphere-egu2020-3758, 2020.

EGU2020-5075 | Displays | AS1.25

Role of dynamic and thermodynamic processes for the propagation of organized convection in a large-scale flow

Hyunju Jung, Ann Kristin Naumann, and Bjorn Stevens

Convective self-aggregation in radiative convective equilibrium has been studied due to its similarities to organized convection in the tropics. As tropical atmospheric phenomena are embedded in a large-scale flow, we impose a background wind to the model setup using convection-permitting simulation to analyze the interaction of convective self-aggregation with the background wind. The simulations show that when imposing a background wind, the convective cluster propagates in the direction of the imposed wind but slows down compared to what pure advection would suggest, and eventually becomes stationary. The dynamic process dominates slowing down the propagation speed of the cluster because the surface momentum flux acts as a drag on the near-surface wind, terminating the propagation. The thermodynamic process through the wind-induce surface feedback contributes to only 6% of the propagation speed of the convective cluster and is strongly modified by the dynamic process.

How to cite: Jung, H., Naumann, A. K., and Stevens, B.: Role of dynamic and thermodynamic processes for the propagation of organized convection in a large-scale flow, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5075, https://doi.org/10.5194/egusphere-egu2020-5075, 2020.

In this study we are trying to understand (limits of) predictability related to (organised) convection and its upscale error growth.

For that purpose we aim to analyse the impact of three convection driving and amplifying processes, namely latent heat release, redistribution of moist static energy and convective momentum transport on the development of the convective cells. Furthermore, we plan to investigate uncertainties in these processes on downward propagation of the flow and ensemble spread.

The first results to be presented regard an idealised and strongly organised case of splitting convective storms modeled at different resolutions and with some small adaptations in the model convective cloud resolving model CM1. Currently processed resolution experiments show that both the actual divergence field and the processes supected to underlie it exhibit some sensitivity to model resolution on the subkilometre scale (100-1000 m). We can also show that the upper tropospheric divergence can be directly related to the latent heat release, as it is located vertically above the major latent heat releases. Nevertheless, neither the vertical redistribution of moist static energy nor the convective momentum transport are negligible and all three impact the divergent outflow of the convective storm.

How to cite: Groot, E. and Tost, H.: Sensitivity analysis of divergence and underlying processes around organised convection with a cloud resolving model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5630, https://doi.org/10.5194/egusphere-egu2020-5630, 2020.

EGU2020-6313 | Displays | AS1.25

Sensitivity of convective cell dynamics and microphysics to model resolution for lake-effect shallow convection

Anders Jensen, Bart Geerts, and Philip Bergmaier

Shallow convection over an unfrozen lake (Lake Ontario) during a cold-air outbreak is simulated using the Weather Research and Forecasting model (WRF) with two horizontal grid spacings, 148 m and 1.33 km. The dynamics and microphysics of the simulated convective snow band are compared to radar and aircraft observations. The dynamical and microphysical changes that occur when going from 1.33-km to 148-m grid spacing are explored. Improved representation of the convective dynamics at higher resolution leads to a better representation of the microphysics of the snowband compared to radar and aircraft observations. Stronger updrafts in the high-resolution grid lead to larger ice nucleation rates and produce ice particles that are more heavily rimed and thus faster falling. These changes to the ice particle properties in the high resolution grid limit aggregation rates and result in more realistic radar reflectivity patterns. Graupel, observed at the surface, is produced in the strongest convective updrafts, but only at the higher resolution. Ultimately, the quantitative precipitation forecast is improved at a higher grid resolution. Additionally, the duration of heavy precipitation just onshore, where convection collapses, is better predicted.

How to cite: Jensen, A., Geerts, B., and Bergmaier, P.: Sensitivity of convective cell dynamics and microphysics to model resolution for lake-effect shallow convection, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6313, https://doi.org/10.5194/egusphere-egu2020-6313, 2020.

Mergers of cells in a severe convective weather on 22 July 2008 are simulated and analyzed by Mesoscale Model 5 (referred to as MM5)and radar network data. Observation results show that, the horizontal scale of the echo above 30 dBZ, which represent the small cells, is about 10 km, and the small cells that the echo centers are 20km apart merge into a larger cell at dozens of km of horizontal scale.. Mergers begin from the peripheral radar echo, and then strong central radar echo merges at the low level, at last, the acreage of strong radar echo increases after the merger. The contrast between the observations and the simulation results shows that they are consistent. Analysis on the simulation results of two kinds of cell mergers at different development stages based on the third network model output shows that, while the cell pairs are with almost the same intensity, cells would develop after merger; while one of the cell pairs is in stronger development however the other one weaker, the stronger cell would keep on development and the weaker cell would die out. During the merger, a new cloud water center appears in the low convergence region between the cell pairs, and would replace the two cloud water centers of the former cells, or the new cloud water center would merger with one of the old cloud water centers while the other old cloud water center disappears. The analysis of the simulation results also shows that, the cell merger would lead to the cloud top lifting and the increase in the radar echo, content of cloud water and ice, surface rainfall.

How to cite: Zhai, J. and Huang, Y.: Numerical Simulations of Convective Cloud Merging Processes at Different Development Stages, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6683, https://doi.org/10.5194/egusphere-egu2020-6683, 2020.

EGU2020-9467 | Displays | AS1.25

Lapse rate deviations from the moist adiabat in the tropical upper troposphere in climate models

Paul Keil, Hauke Schmidt, and Bjorn Stevens

The tropospheric lapse rate in the tropics follows a moist adiabat quite closely and is mainly set by surface temperature and humidity in the convecting regions. Therefore, warming or biases at the surface are transferred via the moist adiabat to the upper troposphere. However, climate models show large discrepancies in the upper troposphere and recent observed upper tropospheric warming is around 0.5K weaker than predicted by the moist adiabat theory. Here we use the control simulations of the CMIP5 ensemble to show that large differences in the upper troposphere exist in the mean state that are unrelated to inter-model differences in the lower troposphere. In fact, CMIP5 models diverge (positively and negatively) from the moist pseudoadiabat by up to 2K at 300hPa. Precipitation weighted SSTs have recently been used to resolve the discrepancy between models and observations in upper tropospheric warming, but we show that they are not able to explain the differences in the mean state. While it is difficult to exactly depict the reasons for the inter-model spread, we demonstrate how the upper tropospheric lapse rate can deviate from the moist adiabat for the same lower tropospheric state with AMIP experiments. For this we use the ICON-A model, in which we tune convective and microphysical parameters. An improved understanding of the effect of different parameterisations on the models' lapse rates may help to better understand differences in the response to global warming.

How to cite: Keil, P., Schmidt, H., and Stevens, B.: Lapse rate deviations from the moist adiabat in the tropical upper troposphere in climate models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9467, https://doi.org/10.5194/egusphere-egu2020-9467, 2020.

EGU2020-9711 | Displays | AS1.25

Detection and Characterization of Cold Pools over Germany in the DYAMOND Simulations

Jaemyeong Mango Seo and Cathy Hohenegger

Cold pool generated by convective clouds is an evaporatively cooled dry region which spreads out near the surface. Studying the cold pool characteristics enhances our understanding about convective clouds such as shallow-to-deep transition of convective clouds, long-lived squall line, and triggering secondary convection. In this study, cold pools over Germany are detected and characterized using phase 0 results of DYAMOND (stands for DYnamics of the Atmospheric general circulation Modeled On Non-hydrostatic Domains) intercomparison project. We aim to understand how the cold pool characteristics over Germany depend on topographic height, accompanying cloud size, and model.

Nine model results of the DYAMOND collection are remapped into 0.1˚ × 0.1˚ regular grid system. Cold pool cluster is defined as a cluster with an area larger than ~64 km2 (4 grids), with the perturbation virtual (density) potential temperature below 2 K and the maximum precipitation rate greater than 1 mm h–1. Detected cold pools are re-categorized by the topographic height to decompose cold pools related to orographic precipitation and by the accompanying cloud size to decompose cold pools related to large cloud system.

During simulated period (40 days from 1 August 2016), model averaged total detected cold pool number is 5.59 h–1. Although more number of cold pool clusters are detected over low topographic area (1.34 h–1 and 4.25 h–1 over high and low area, respectively), area weighted cold pool cluster number is 3.82 times larger over high topographic area (17.55 h–1 and 4.60 h–1 over high and low area, respectively). Most of cold pool clusters are accompanied by larger clouds than themselves (78 %) and 9 % of cold pools are detected outside of cloud cover. Except for the cold pools accompanied by clouds of synoptic low pressure system, most of cold pools are detected in the daytime. Cold pool clusters over high topographic area are larger, more non-circular shaped, colder, and with lower wind speed than those over low topographic area. Cold pool clusters accompanied by small clouds are colder, drier, with higher wind speed, and with stronger precipitation than those accompanied by large clouds. In this study, relationship between cold pool characteristic parameters in each category is also investigated. To understand how cold pool feature varies from model to model, the cold pool characteristic parameters in each DYAMOND model result are compared and analyzed.

How to cite: Seo, J. M. and Hohenegger, C.: Detection and Characterization of Cold Pools over Germany in the DYAMOND Simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9711, https://doi.org/10.5194/egusphere-egu2020-9711, 2020.

EGU2020-12367 | Displays | AS1.25

Cold pool collisions as a triggering mechanism of convection

Gustav Halvorsen, Bettina Meyer, and Jan Härter

Cold pools are produced by rain evaporation from
convective thunderstorms and play an important role 
in many atmospheric phenomena (e.g. transition to deep convection and convective self-aggregation). From observational
and numerical studies, it has been found that intersecting cold pools
increase the likelihood of triggering convection.
We test this hypothesis by combining observational
radar data from Darwin (Australia) with a simple conceptual model.

We identify precipitation objects in the radar data. It is assumed that each rain event produces a cold pool
that is initialized at the center of the precipitation cell. Cold pools are simulated with a stochastic surface growth model.
The spatial coordinate of each collision event is recorded. 
Collectively these points take the shape of a Voronoi diagram. 
According to our hypothesis, the probability of new rain events should decay with spatial distance to the Voronoi.

Our preliminary results suggest that rain events cluster in the
vicinity of the Voronoi with a higher frequency that one would expect if cold pool collisions did not stimulate convection. 
To conclude, our findings suggest that dynamic collisions between cold pools increase the likelihood of convection in the surrounding area.
This work allows us to study the effect of cold pools from radar data, despite cold pools being invisible to the radar images,
using a simple object-based model of convective cold pools. 

How to cite: Halvorsen, G., Meyer, B., and Härter, J.: Cold pool collisions as a triggering mechanism of convection, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12367, https://doi.org/10.5194/egusphere-egu2020-12367, 2020.

EGU2020-14171 | Displays | AS1.25

Impact of interactive sea surface temperature on convective clustering in radiative convective equilibrium

Addisu Gezahegn Semie and Adrian Mark Tompkins

We present results of radiative convective equilibrium runs using the WRF model coupled to an interactive slab ocean model, for which a relaxation term removes energy to constrain the domain mean sea surface temperature to a target value over a given timescale. By using a short adjustment timescale of one minute, drift in the mean temperature is constrained and the impact of the slab ocean is only through the spatial heterogeneity in sea  surface flux. We show how thin slabs slow the onset of organization, and conduct sensitivity experiments to determine the relative contributions of the radiative, sensible and latent surface fluxes, with surface fluxes key. Once clustering starts, the surface feedback acts to aid organization onset due to the drying atmosphere, although the speed of clustering onset is not significantly changed, indicating that it could be determined by a water vapour diffusive timescale as suggested by Windmiller and Craig.  An additional set of experiments that permit the mean surface temperature to undergo a diurnal adjustment show how diurnal variations in SST oppose the atmospheric radiative forcing and also act to prevent clustering onset. We show the mechanism for this acts through the reduction of the diurnal variation of convective mass flux and the distance between updraft towers.

How to cite: Semie, A. G. and Tompkins, A. M.: Impact of interactive sea surface temperature on convective clustering in radiative convective equilibrium, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14171, https://doi.org/10.5194/egusphere-egu2020-14171, 2020.

EGU2020-18167 | Displays | AS1.25

Model resolution dependence of convection initiation by orographically-induced thermal circulations

Matthias Göbel, Stefano Serafin, and Mathias Rotach

Thermally-driven circulations in mountainous terrain can play an essential role in the initiation of deep moist convection: They advect moisture at low levels and provide the necessary trigger mechanism to lift air parcels above the level of free convection.
Current limited-area numerical weather prediction models with a horizontal grid spacing of around 1 km may adequately resolve the larger-scale thermal circulations, namely, valley winds and plain-to-mountain winds, but not the small-scale slope winds. In addition, the planetary boundary-layer parametrizations typically employed in these models are based on the assumption of horizontally homogeneous and flat terrain and assume none of the turbulent boundary-layer eddies are explicitly resolved.
In this contribution, we investigate the problems that arise due to these deficiencies in the given context using idealized numerical simulations with the WRF model. We compare simulations at different horizontal resolutions in the turbulence gray zone with LES simulations. Previous idealized modeling studies have shown that simulations at kilometer-scale resolution may produce stronger moisture convergence due to thermally-driven circulations and thus earlier and more vigorous convection over the mountain ridges compared with an LES model.
We focus on strongly-inhibited initial conditions that lead to deep moist convection with a kilometer-scale but not with an LES model and investigate the reasons for the different convective behavior. The benefits of scale-adaptive boundary-layer schemes for the studied process are evaluated.

How to cite: Göbel, M., Serafin, S., and Rotach, M.: Model resolution dependence of convection initiation by orographically-induced thermal circulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18167, https://doi.org/10.5194/egusphere-egu2020-18167, 2020.

EGU2020-18494 | Displays | AS1.25

Characterizing cold pool interactions over land with observational data from the Netherlands

Irene Livia Kruse, Jan O. Haerter, and Bettina Meyer

When precipitation evaporates in a sub-saturated boundary layer, it cools the air and produces dense downdrafts, which flow towards the surface and can spread horizontally as a gust front. These spreading “cold pools” (CPs) can trigger convection and thus new precipitation events due to dynamical and thermodynamical lifting mechanisms. Due to their role in the local organization of convection, CP properties are currently being studied with the use of high-resolution numerical simulations. Measurement campaigns have been conducted over the ocean to validate the models. However, fewer studies have specifically targeted cold pools over land.

We use the observational network of the Netherlands (meteorological stations and radar) to study CPs developing from summer convection and their role in triggering new convective events over land. Detailed information about CP gust fronts in terms of temperature, wind speed, heat fluxes, moisture and pressure at high vertical resolution is obtained from time series, measured at the 213-meter Cabauw tower. We aim to create an algorithm that detects the passage of a CP from the tower time series to automatize the finding of CPs from a point measurement. To confirm the results, we have access to temperature time series from a spatially dense crowdsourcing weather station network (WOW-NL).

The properties of the detected CPs are further studied with imagery from the Herwijnen Doppler radar, situated in proximity to the Cabauw tower. We can see clear signatures of spreading CPs in reflectivity plots, probably caused by the upwelling of dust and insects in the gust front. We currently explore how this can serve as a direct way of visualizing the dynamics of CPs and their collisions.

With enough observations of CPs, we expect to learn more about the CP spreading velocity and lifetime in dependence of precipitation intensity of the generating precipitation cell and eventually triggered cell. This link will help gain more insight into the role of CPs in organizing convection over land.

How to cite: Kruse, I. L., Haerter, J. O., and Meyer, B.: Characterizing cold pool interactions over land with observational data from the Netherlands, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18494, https://doi.org/10.5194/egusphere-egu2020-18494, 2020.

Self-aggregation of convective cloud activity has attracted a lot of attention due to its role in the emergence of large scale weather phenomena such as the formation of hurricanes. Simulations with uniform boundary conditions show self-aggregation ocurring on the time-scale of a few weeks [1]. Recently, numerical experiments demonstrated that spatial clustering can form withing a few days, when the system is driven by diurnal temperature oscillations [2]. These simulations indicate that there may be a discontinuous phase transition between the clustered and the non-clustered state, i.e. that a threshold for the amplitudes of diurnal temperature oscillations exist, below which clustering does not emerge. A conceptual model has been proposed, suggesting that the phase transition might give rise to hysteresis in the sense that clustering emerging at high temperature amplitudes might persist if the amplitude is subsequently reduced to a level below the critical threshold.

Here we test the hysteresis–hypothesis explicitly by performing cloud-resolving simulations with a high-amplitude transient period followed by a period with a low diurnal temperature amplitude. In reality, diurnal temperature oscillations have significantly larger amplitudes over land than over the ocean. The existence of hysteresis effects in the convective cloud clustering could have profound implications: clusters formed over land, where diurnal temperature variations are large, could persist over the ocean when transported there by large-scale wind advection. Once present, the clusters could even intensify over the ocean—with possible implications for cyclogenesis.

[1] CJ Muller and IM Held, Journal of the Atmospheric Sciences, 69(8):2551–2565, 2012.
[2] arXiv:2001.04740 [physics.ao-ph]

How to cite: Jensen, G. G. and Haerter, J.: Hysteresis in self-organized mesoscale convective systems driven by diurnal temperature oscillations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20870, https://doi.org/10.5194/egusphere-egu2020-20870, 2020.

EGU2020-22156 | Displays | AS1.25

Criticality in Tropical Rainfall: A Simple Water Budget Model

Mikkel Svendsen

Deep convective rain events in the tropics represent an essential ingredient of Earth's climate system, acting as a driver of large-scale circulation which distributes energy and moisture. Understanding how they organize remains a challenge. Observational studies indicate that tropical convection may be understood as an instance of self-organized criticality (SOC) [1]:
(i) Rain rate vs. column water vapor follows a clear "pickup curve": Essentially no rain is observed in dry areas, while at column moistures above a critical value the rain rate increases sharply.
(ii) Rain events and clusters, defined as groups of contiguous rainy points in space and/or time, have size distributions well described by power laws.
The first result indicates that the atmosphere undergoes a phase transition, separating a non-raining "inactive" phase from a rainy "active" one. The second result suggests that the system is found close to the critical transition point, where "scale-free" power law distributions are expected. Indeed, observations find typical moisture values to be close to the critical moisture value. 

SOC theory would suggest that the observational results are an emergent phenomenon, caused by simple local interactions that carry over to larger scales. However, to our knowledge, no simple SOC model linking moisture and rainfall has been suggested that explains how criticality arises from convective processes while also predicting the observed rain cluster sizes. A more complete theory, especially on spatial aspects, is lacking.
We therefore present a simple spatiotemporal model of the atmospheric water budget, exploring whether a fuller picture including spatial information can be developed. Each site of the model represents an atmospheric column, where water can enter through surface evaporation, leave as surface rain, or get redistributed among neighboring sites due to convective in- and outflows. We analyse a cloud resolving model simulation in radiative-convective equilibrium, by grouping grid points into three categories: rainy points (convectively active), neighbors of rainy points and others (convectively passive). Tendencies, evolutions and transitions are examined to identify local "rules" to inform the interactions and parameters in our model.
Hence, in this project we use a simple model approach to find whether local convection mechanisms of water rearrangements can explain why tropical rainfall seems to show critical characteristics. In addition, this might aid development of convective parameterizations for climate models: Including a few key convective scale interactions, suggested by our model, might help to better capture important effects of subgrid correlations in a simple way.
 
[1] Peters, O., and J. D. Neelin (2006), Critical phenomena in atmospheric precipitation, Nat. Phys., 2(6), 393-396, doi:10.1038/nphys314.

How to cite: Svendsen, M.: Criticality in Tropical Rainfall: A Simple Water Budget Model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22156, https://doi.org/10.5194/egusphere-egu2020-22156, 2020.

EGU2020-15974 | Displays | AS1.25

Numerical Simulation of Squall line in idealized SINGV and WRF Models

Ragi Rajagopalan, Anurag Dipankar, and Xiang-Yu Huang

Squall lines are the prominent feature over Singapore region creating strongly localized rain events due to vigorous localized convective activity. These convective systems have relatively small spatial and temporal scales compared to other atmospheric features like monsoons, thus the prediction of these features lack accuracy. The SINGV numerical weather prediction model is able to provide improved weather forecasts over Singapore region, however, challenges still exist in predicting the thunderstorm/squall line events in onset, location, intensity and lead time. A few real-time case studies of squall lines indicate that SINGV could not capture these features appropriately, while WRF did a better forecasting. To understand the issues with SINGV model, idealized simulations replicating the Weismann & Klemp ‘82 case are conducted keeping similar physics in both the models. Preliminary results indicate that both models behave differently: WRF displays organized convection whereas in SINGV the storm splits at the early stages. Cross-sectional details along the propagating squall line suggest that the updrafts and downdrafts, at the storm development stages, are moderately higher in SINGV compared to WRF. It is speculated that these stronger updrafts in SINGV carry anomalously large amount of liquid water to the upper troposphere where these are converted into rain, which in turn result in stronger downdrafts facilitating the splitting of initial storm. Further analysis is required to conclude our speculation.

How to cite: Rajagopalan, R., Dipankar, A., and Huang, X.-Y.: Numerical Simulation of Squall line in idealized SINGV and WRF Models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15974, https://doi.org/10.5194/egusphere-egu2020-15974, 2020.

AS1.26 – Advancing understanding of the coupling between clouds, convection and circulation

EGU2020-6116 | Displays | AS1.26

EUREC4A: First Impressions

Bjorn Stevens, Sandrine Bony, David Farrell, Alan Blyth, Chris Fairall, Johannes Karstensen, Trish Quinn, Sabrina Speich, and Team Eurec4a

The EUREC4A field campaign took place during January and February 2020, in the lower trades of the northern tropical Atlantic, over and in the seas windward of Barbados.  The initial purpose of the campaign was to test hypothesized cloud responses underpinning large positive radiative feedbacks from the desiccation of marine shallow convection with warming. To do so EUREC4A built on a long-standing cooperation with the Caribbean Institute for Meteorology and Hydrology to collect long-term cloud observations. Its scope was subsequently expanded by the addition of many partners, with funding from a variety of additional EU and UK projects, and US participants through ATOMIC, to address many additional questions. These ranged from the role of fine-scale eddies and fronts on air-sea coupling, to the effects of meso-scale organization on cloud radiative effects, to the strength of aerosol cloud interactions, among others. Hundreds of scientists from nearly a dozen nations -- incorporating measurements from four large Research Vessels and five Research Aircraft, an advanced remote sensing ground station and a large number of autonomous vehicles in the air and sea -- combined their expertise  to develop an unusually comprehensive picture of the processes relevant to the lower atmosphere and the upper ocean in the lower trades. We share our first impressions from EUREC4A, its surprises, and its prospects for answering some of the riddles that motivated this tremendous and coordinated effort.

How to cite: Stevens, B., Bony, S., Farrell, D., Blyth, A., Fairall, C., Karstensen, J., Quinn, T., Speich, S., and Eurec4a, T.: EUREC4A: First Impressions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6116, https://doi.org/10.5194/egusphere-egu2020-6116, 2020.

EGU2020-4379 | Displays | AS1.26

Large-scale vertical motion and its influence on cloudiness

Geet George, Bjorn Stevens, Sandrine Bony, and Marcus Klingebiel

This study uses measurements from the Elucidating the Role of Clouds-Circulation Coupling in Climate, EUREC4A and the second Next-Generation Aircraft Remote Sensing for Validation, NARVAL2 campaigns to investigate the influence of large-scale environmental conditions on cloudiness. For the first time, these campaigns provide divergence measurements, making it possible to explore the impact of large-scale vertical motions on clouds. We attempt to explain the cloudiness through the varying thermodynamics and dynamics in the different environments.  For most of the NARVAL2 case-studies, cloudiness is poorly related to thermodynamical factors such as sea-surface temperature and lower tropospheric stability. Factors such as integrated water vapour and pressure velocity (ω) at 500 hPa and 700 hPa can be used to distinguish between actively convecting and suppressed regions, but they are not useful in determining the variation in cloudiness among suppressed cases. We find that ω in the boundary layer (up to ∼2 km) has a more direct control on the low-level cloudiness in these regions, than that in the upper layers. We use a simplistic method to show that ω at the lifting condensation level can be used to determine the cloud cover of shallow cumulus clouds. Thus, we argue that cloud schemes in models should not rely only on thermodynamical information, but also on dynamical predictors.

How to cite: George, G., Stevens, B., Bony, S., and Klingebiel, M.: Large-scale vertical motion and its influence on cloudiness, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4379, https://doi.org/10.5194/egusphere-egu2020-4379, 2020.

EGU2020-6420 | Displays | AS1.26

Transition of low clouds in the East China Sea and Kuroshio region in winter: A regional atmospheric model study

Jingchao Long, Yuqing Wang, Suping Zhang, and Jingwu Liu

EGU2020-21249 | Displays | AS1.26

Convectively driven wind variability in connection to wind biases in the ECMWF operational weather model

Louise Nuijens, Irina Sandu, Beatrice Saggiorato, Hauke Schulz, Mariska Koning, Kevin Helfer, and Vishal Dixit

Despite playing a key role in the atmospheric circulation, the representation of momentum transport by moist convection (cumulus clouds) has been largely overlooked by the model development community over the past decade, at least compared with diabatic and radiative effects of clouds. In particular, how shallow convection may influence surface and boundary layer winds is not thoroughly investigated. In this talk, we discuss the role of convective momentum transport (CMT) in setting low-level wind speed and its variability and evaluate its role in long-standing wind biases in the ECMWF IFS model.

We use high-frequency wind profiling measurements and high-resolution large-eddy simulations to inform our understanding of convectively driven wind variability. We do this at two locations: in the trades, using wind lidar and radiosonde measurements from the Barbados Cloud Observatory and the intensive EUREC4A field campaign, and over the Netherlands, using an observationally constrained reanalysis wind dataset and large-eddy simulation hindcasts.

At both locations we use the data and model output to investigate whether CMT can be responsible for a missing drag near the surface in the IFS model. Namely, at short leadtimes, the model produces stronger than observed easterly/westerly flow near the surface, while “a missing drag” produces weaker than observed wind turning. Consequently, the meridional overturning circulation in both the tropics and midlatitudes is weaker in the IFS and in ERA-Interim and ERA5 reanalysis products.

Comparing simulated and IFS wind tendencies at selected grid points at the above locations, and by turning off the process of CMT by shallow convection in the model, we gain insight in the role of CMT in explaining wind biases. We find that CMT alone does not explain a missing drag near the surface. CMT often acts to accelerate winds near the surface. But CMT plays a role in communicating biases in cloud base wind speeds towards the surface. In the trades, a strong jet near cloud base is determined by thermal wind and a strong flux of zonal momentum through cloud base, where “cumulus friction” minimizes. Near this jet, the presence of (counter-gradient) turbulent momentum fluxes produces most of the drag. Implications of these findings for CMT parameterization are discussed.

How to cite: Nuijens, L., Sandu, I., Saggiorato, B., Schulz, H., Koning, M., Helfer, K., and Dixit, V.: Convectively driven wind variability in connection to wind biases in the ECMWF operational weather model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21249, https://doi.org/10.5194/egusphere-egu2020-21249, 2020.

Understanding atmospheric processes, such as e.g. cloud and precipitation formation, requires high-resolution water vapor and temperature profile observations particularly in the cloudy boundary-layer. As current observation techniques are limited by low spatial or temporal resolution, the potential of combining microwave radiometer (MWR) with differential absorption radar is investigated by analysing the retrieval information content and retrieval uncertainty. Two radar frequency combinations are analyzed: Ka- and W-band (KaW), available at e.g. Barbados Cloud Observatory, as well as a synthetic combination of G-band frequencies (167 and 175 GHz, G2), simulated using the Passive and Active Microwave TRAnsfer model PAMTRA.

The novel synergistic retrieval approach is based on an optimal estimation retrieval scheme. The absolute humidity profile is retrieved from the MWR K-band brightness temperatures, as well as the Dual-Wavelength Ratio (DWR) signal of the two radars. Evaluating a suite of radiosonde profiles measured at Barbados from 2018, adding the active KaW combination to K-band MWR brightness temperatures increases the information content for the retrieved profile from 3.2 to 3.4 degrees of freedom for signal (DoF). The usage of the higher G2 radar frequencies leads to higher Dual-Wavelength Ratios (DWRs), and, in combination with the MWR, to increased DoF (4.5), decreased retrieval errors, and a more realistic retrieved profile within the cloud layer. Information partitioning among MWR and the radars makes the synergy particularly beneficial: the profile below and within the cloud is restricted by the radar observations, whereas the water vapor above cloud top and the LWP are constrained by the MWR.

Based on selected case studies with single- as well as multi-layered clouds from the EUREC4A campaign, different retrieval configurations will be evaluated based on the resulting retrieval error, as well as the Degrees of Freedom. Tools for customizing the retrieval to the trade wind driven atmosphere will be analyzed by e.g. constraining the humidity profile to saturation within the cloud layer, or making use of a direct inversion approach of the differential attenuation signals.

How to cite: Schnitt, S., Löhnert, U., and Preusker, R.: Combining Differential Absorption Radar and Microwave Radiometer for Water Vapor Profiling in the Cloudy Trade-Wind Environment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12107, https://doi.org/10.5194/egusphere-egu2020-12107, 2020.

In this work, the tropical wave precipitation-buoyancy relationship is revisited by analyzing 4-times daily wave-filtered brightness temperature, reanalysis, and radiosonde datasets over tropical South America during the wet season. Prior studies demonstrated that an integrated measure of buoyancy well-diagnoses precipitation over land and ocean. However, it is an open question whether the buoyancy-based approach can yield a robust relation to precipitation for equatorial wave disturbances. To advance our understanding of this relationship, a comprehensive analysis of their vertical thermodynamic structure and potential interactions with the basic state is also presented. An emphasis is placed on understanding the convection coupling mechanism in convectively coupled Kelvin and inertia-gravity waves. It will be shown that buoyancy is a better predictor of convection for these disturbances than the often-used moist static energy (MSE). Examination of this discrepancy reveals that a cooling of the lower troposphere by gravity wave motions, which reduces MSE, is key to the production of precipitation in these disturbances.

How to cite: Mayta, V. and Adames, A.: Tropical precipitation–buoyancy relationship in Convectively Coupled Waves over South America region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11137, https://doi.org/10.5194/egusphere-egu2020-11137, 2020.

Recent analyses of Coupled Model Intercomparison Project phase 6 (CMIP6) models have shown higher climate sensitivities than previously reported, and this increase has been preliminary attributed to the simulation of anomalous Shortwave Cloud Radiative Effect (SWCRE) over the southern midlatitude regions. In this work, we further explore how the seasonal and annual SWCRE over different regions of the globe influence the model climate sensitivities. Our study suggests a significant contribution of SWCRE on climate sensitivities in both northern and southern midlatitudes; and the relationship remains robust across the seasons. Additionally, we assess the underlying physics of the inter-model spread to diagnose model biases. The results will contribute to quantify the severity of the Equilibrium Climate Sensitivity, as simulated by the CMIP6 models.

How to cite: De, B. and Tselioudis, G.: Regional and Seasonal Influence of Cloud Radiative Effects on CMIP6 Model Climate Sensitivity, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12467, https://doi.org/10.5194/egusphere-egu2020-12467, 2020.

EGU2020-4622 | Displays | AS1.26

Dependence of mesoscale patterns of Trade-wind clouds on environmental conditions: an investigation using satellite and in-situ observations

Sandrine Bony, Hauke Schulz, Jessica Vial, and Bjorn Stevens and the EUREC4A team

Trade-wind clouds exhibit a large diversity of spatial organizations at the mesoscale. Over the tropical western Atlantic, a recent study has visually identified four prominent mesoscale patterns of shallow convection, referred to as Flowers, Fish, Gravel and Sugar. By using 19 years of satellite and meteorological data, we show that these four patterns can be identified objectively from satellite observations, and that on daily and interannual timescales, the near-surface wind speed and the strength of the lower-tropospheric stability discriminate the occurrence of the different organization patterns. Moreover, we point out a tight relationship between cloud patterns, low-level cloud amount and cloud-radiative effects. The EUREC4A field study taking place upwind of Barbados in Jan-Feb 2020 offers an opportunity to investigate these relationships from an in-situ and process-oriented perspective. Preliminary results will be discussed.

How to cite: Bony, S., Schulz, H., Vial, J., and Stevens, B. and the EUREC4A team: Dependence of mesoscale patterns of Trade-wind clouds on environmental conditions: an investigation using satellite and in-situ observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4622, https://doi.org/10.5194/egusphere-egu2020-4622, 2020.

Oceanic shallow convective clouds, which prevail in the trade-wind regions, have long been of great interest, because they strongly impact climate on a wide range of scales and they are critical in the estimation of the magnitude and pace of global warming. But surprisingly, the most fundamental mode of tropical variability, that is the daily cycle, has received very little attention for this cloud category, so that our knowledge of the diurnal processes in this oceanic shallow cumulus regime and their influence on climate at broader scales remains extremely limited. We recently relaunched the exploration of this topic. New investigating tools have been used, including large-eddy simulations run over large domains in realistic configurations and in-situ observations from the Barbados Cloud Observatory, which have helped study this daily cycle in the North Atlantic trade-wind region with a lot more details than was possible 40 years ago when it was first documented. Important features of this daily cycle have been found, which can have far reaching implications for climate change studies. Our hypothesis is that understanding the processes that control trade-wind cumuli on the diurnal timescale will benefit to our understanding of the mechanisms that are involved in the tropical marine low-level cloud feedbacks. In this regard, the wealth of observational data that will be collected during the EUREC4A campaign is unprecedented and offers a tremendous opportunity to enrich the characterisation and understanding of the mechanisms of the trade-wind daily cycle. Preliminary results will be discussed with a focus on the role of the shallow convective mixing and mesoscale organization in the daily cycle of trade-wind cumuli.

How to cite: Vial, J., Schulz, H., and Vogel, R.: On the understanding of the trade-wind cumuli daily cycle: the role of convective mixing and mesoscale organization of convection, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9807, https://doi.org/10.5194/egusphere-egu2020-9807, 2020.

EGU2020-9123 | Displays | AS1.26

Simulation of subtropical marine stratocumulus clouds in convection-resolving models

Christoph Heim, Laureline Hentgen, Nikolina Ban, and Christoph Schär

Even though the complexity and resolution of global climate models (GCMs) has increased over the last decades, the inter-model spread of equilibrium climate sensitivity has not narrowed. The representation of subtropical low-level clouds and their associated radiative feedbacks in climate models still poses a major challenge. A fundamental problem underlying the simulation of such clouds is their multiscale nature. On the one hand, current GCMs allow to capture the large-scale processes but are too coarse to represent the mesoscale and microscale dynamical processes governing their formation and dissipation. On the other hand, large eddy simulations (LES) resolving the micro scale are bound to small domains and thus lack a robust representation of the large-scale flow and the mesoscale organisation of the clouds. Convection-resolving models (CRMs) are an attractive compromise between the former two since they allow for simulations at much higher resolution than in conventional GCMs and on larger domains than in LES.

Here we analyse how CRMs simulate stratocumulus decks and investigate causes for inter-model differences. We consider a set of ten CRMs (nine GCMs that are run at convection-resolving resolution during a short time period as part of the pioneering DYAMOND initiative, and the limited area model COSMO run by ourselves) used to simulate stratocumulus clouds over the South-East Atlantic during a 40 day period. The simulations cover a range of horizontal grid spacings between 5 and 1 km.

We find pronounced differences in the mean cloud cover among the analysed CRMs. In comparison to observed radiation (CERES), most of them underestimate cloud cover, in particular the low-lying stratus decks close to the African coast. Nevertheless, the simulated mesoscale cloud organisation is realistic and similar in the set of CRMs, with few exceptions showing organisation on larger scales than in the other models. In general, the simulated cloud field appears to be more sensitive to the model choice than to the horizontal resolution.

Despite the differences in the cloud cover, most models capture the subtropical inversion and its spatial structure relatively well. Therefore, differences in the inversion strengths do not suffice to explain variability in the simulated cloud cover fraction between models. However, we find a relation between the mean height of the stratocumulus layer (or inversion layer) and its cloud cover fraction: Models with higher inversions tend to simulate a higher cloud cover fraction, bringing them closer to observations. Similarly, stronger vertical mixing within the boundary layer and enhanced surface latent heat fluxes appear to be related to higher cloud cover. Such relations may help to determine the physical processes responsible for the differences among CRMs in the simulated stratocumulus field.

How to cite: Heim, C., Hentgen, L., Ban, N., and Schär, C.: Simulation of subtropical marine stratocumulus clouds in convection-resolving models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9123, https://doi.org/10.5194/egusphere-egu2020-9123, 2020.

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Impact of Dry Intrusions on the Marine Boundary Layer

Eyal Ilotoviz, Shira Raveh-Rubin, and Virendra Ghate

Intrusions of dry air from the upper troposphere were recently suggested to reach the boundary layer and cause its significant deepening. Dry intrusions (DIs) are synoptic-scale slantwise descending airstreams from the midlatitude upper tropospheric jet towards the boundary layer at lower latitudes, thus acting as a circulation type potentially key for understanding boundary-layer cloud occurrence and regime transition. DIs occur mainly during winter over the mid-latitude oceanic storm track regions behind cold fronts trailing from cyclones. These regions are also home to marine boundary clouds that are an important component of the Earth’s radiation budget as they reflect much higher radiation back to the space compared to the ocean surface thereby cooling the Earth’s surface. Although subsidence is generally an inherent feature of the subtropical marine boundary layer, it is unclear how the marine boundary layer reacts to the transient, dynamically distinct DI, differently from the nominal subtropical subsidence resulting from the descending branch of Hadley circulation.

In this study we use the observations made at the Atmospheric Radiation Measurement (ARM) Eastern North Atlantic (ENA) site (39N, 28W) to characterize the impact of dry intrusions on Marine Boundary Layer (MBL) characteristics such as surface fluxes, thermodynamic stabilities and winds. Our analyses are based on measurements from the campaign: radiosondes, surface station data, polarimetric radar, lidar, radar wind profiler, ceilometer among others. Using all identified DI trajectories during the winters of 2016-2018 based on European Center for Medium-range Weather Forecasts (ECMWF) ERA Interim reanalysis data, we distinguish DI days from those before and following DIs, as well as periods with no DIs at all (with and without the occurrence of cold fronts for comparison). We find that during DI events the well-mixed MBL deepens and its vertical structure changes dramatically. Namely, the lower troposphere cools and dries substantially, inducing strong surface sensible and latent heat fluxes, while a strong inversion builds up at the MBL top, all affecting cloud occurrence. Finally, we used the numerical weather prediction (NWP) model COSMO at 2.2 km horizontal resolution to understand the detailed flows and structure in the MBL during DI events.

How to cite: Ilotoviz, E., Raveh-Rubin, S., and Ghate, V.: Impact of Dry Intrusions on the Marine Boundary Layer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13042, https://doi.org/10.5194/egusphere-egu2020-13042, 2020.

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Cloud Droplet Size Distributions from Observations of Glory and Cloudbow during the EUREC4A Campaign

Veronika Pörtge, Tobias Kölling, Tobias Zinner, Linda Forster, and Bernhard Mayer

The cloud droplet size distribution determines the evolution of clouds and their impact on weather and climate. First, droplet size determines
the cloud radiative effect. Second, evolution of clouds and formation of precipitation are determined by droplet size and the shape of the size distribution. Therefore, measurements of the size distribution are important to further our understanding of clouds and their role in the earth system. We present a remote sensing technique for droplet size and width of the size distribution based on polarized observations of the glory and the cloudbow.
Glory and cloudbow are caused by backscattering of sunlight by spherical droplets in liquid clouds. This backscattering results in colorful concentric rings surrounding the observer’s shadow; the formation is described quantitatively by Mie theory. The rings of the glory appear in an angular range of 170° – 180° scattering angle and the larger cloudbow rings in a range of about 130° – 160° . The angular radius of the rings is the most accurate and direct measure of the droplet size at cloud edge. In addition, the sharpness of the rings conveys information about the width of the droplet size distribution. The visibility of glory and cloudbow is significantly enhanced by the use of polarized observations which reduce the contribution of multiple scattering.
The specMACS sensor of LMU Munich has been upgraded recently by a polarization-sensitive wide-angle imager which was operated for the first time on the HALO aircraft during the EUREC4A campaign. The newly installed sensor offers a high spatial and temporal resolution, allowing to study small-scale variability of cloud microphysics at cloud top with a resolution of about 20 m. specMACS measurements and first retrieval results using the glory-cloudbow technique are presented.

How to cite: Pörtge, V., Kölling, T., Zinner, T., Forster, L., and Mayer, B.: Cloud Droplet Size Distributions from Observations of Glory and Cloudbow during the EUREC4A Campaign, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18813, https://doi.org/10.5194/egusphere-egu2020-18813, 2020.

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Clouds and Aerosols observed during EUREC4A by the UK Twin Otter aircraft.

Tom Lachlan-Cope, Alan Blyth, Steven Boeing, Philip Rosenberg, Paul Barrett, Keith Bower, Michael Flynn, James Dorsey, Gary Lloyd, and Leif Denby

The EUREC4A project took place during January and February of 2020 and involved aircraft and ships from Germany, France, the United States of America and the United Kingdom. The aim of the project is to advance the understanding of the interplay between clouds, convection and circulation and their role in climate change. The Twin Otter belonging to the British Antarctic Survey (BAS) has been used to take observations of clouds and aerosols to the East of Barbados in conjugation with the French ATR-42 and the German Halo aircraft. Here we report the preliminary results of the observations made by the British aircraft. These observations will include aerosols from 10nm to 10micron and numbers of cloud condensation nuclei as well as detailed in-situ measurements of clouds microphysical properties. The observations have been taken over a one month period and taken as a whole can be used to provide a statistical view of the aerosols and clouds observed during EUREC4A by the BAS Twin Otter Aircraft.

How to cite: Lachlan-Cope, T., Blyth, A., Boeing, S., Rosenberg, P., Barrett, P., Bower, K., Flynn, M., Dorsey, J., Lloyd, G., and Denby, L.: Clouds and Aerosols observed during EUREC4A by the UK Twin Otter aircraft., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3667, https://doi.org/10.5194/egusphere-egu2020-3667, 2020.

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Remote Sensing for Convective System Tracking and Associated Sea Surface Wind Pattern Detection

Tran Vu La, Christophe Messager, Rémi Sahl, and Marc Honnorat

Convective Systems (CS) are dangerous weather events since they are associated with intense precipitation (up to 50 mm/hr) and strong surface winds (exceeding 20 m/s), for instance over the sea surface. Furthermore, they happen suddenly and evolve quickly, and thereby their effects on the sea surface are difficult to track and predict. Thanks to the geostationary meteorological satellites of METEOSAT (Europe), GOES (USA), and Himawari (Japan), the CS detection and tracking can be performed in most of the world with a 5-15-minute observation time sampling and about 2.8-km spatial resolution (up to about 1-km for the new–generation satellites). Indeed, the instruments onboard these satellites perform the CS detection based on the identification of deep convective clouds. The deeper the convective clouds, the lower the brightness temperature is. The highest (coldest) clouds have the lowest brightness temperature (200 K–205 K).

While the CS detection has been significantly improved for recent years thanks to the infrared images, the investigation of strong winds (or wind gusts) produced by the CS downdrafts hitting the sea surface did not progress a lot. It is mainly due to the lack of in-situ data and (especially) high-resolution remote sensing images. Some studies proposed the use of ASCAT scatterometers for the detection of surface wind patterns associated with the CS. However, the ASCAT only identified the mesoscale patterns (100–300 km) and failed to detect the convective-scale gust fronts (5–20 km), due to their large spatial resolution (12.5–25 km wind grid). To be able to observe both small- and large-scale surface wind patterns, Synthetic Aperture Radar (SAR) images are used in this study thanks to their high spatial resolution, wide swath, and availability in most weather conditions. Indeed, the obtained results in (La et al., 2018, 2020) illustrate that Sentinel-1 (C-band SAR) may detect surface wind patterns in shapes of a mesoscale squall line and sub-mesoscale convection cells. The associated wind intensity with the patterns exceeds 10–25 m/s.

To strengthen the assumption that the detected wind patterns on SAR images are produced by the CS downdrafts hitting the sea surface, we use the corresponding METEOSAT images for the detection of deep convective clouds (200 K–205 K brightness temperature). The comparisons between Sentinel-1 and METEOSAT images illustrate that surface wind patterns and deep convective clouds have a matching in spatial location (and sometimes in shape). In particular, the coldest spots of deep convective clouds correspond to the one with high wind intensity (15–25 m/s) of the patterns. This result thus permits to highlight a strong relationship between the detected wind patterns on the sea surface and the CS aloft.

How to cite: La, T. V., Messager, C., Sahl, R., and Honnorat, M.: Remote Sensing for Convective System Tracking and Associated Sea Surface Wind Pattern Detection, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14102, https://doi.org/10.5194/egusphere-egu2020-14102, 2020.

Most uncertainty in the warming response of trade-wind cumuli in climate models occurs near cloud base and is associated with model diversity in the strength of shallow convective mixing. In contrast to climate models, cloud-base cloudiness in large-eddy simulations (LES) and in observations is relatively insensitive to changes in the environment. The cumulus-valve mechanism provides a conceptual framework for understanding changes in cloud-base cloudiness in response to changes in the shallow-convective mass flux (M)—an important measure for convective mixing. The mechanism assumes that M keeps the mixed-layer top close to the lifting condensation level, which could explain a larger cloud-base cloudiness with larger M if the increase in M was mostly due to an increasing area fraction of cumuli. Here we use real-case LES over the tropical Atlantic to understand if cloud-base cloudiness increases with increasing M.

We find that M explains a lot of the variations in cloud-base cloudiness (correlation coefficient R=0.86), but the maximum relative humidity at the mixed-layer top (RHmax) needs to be considered additionally to explain the nighttime behavior of cloud-base cloudiness (R=0.95). The coupling of M and RHmax through adjustments in the sub-cloud layer depth is crucial for regulating cloud-base cloudiness. Inability of GCMs to adjust the sub-cloud layer depth in response to a change in M may likely contribute to their overestimated trade-cumulus cloud feedback. The simulated relationships will be compared to measurements from the EUREC4A field campaign.

How to cite: Vogel, R. and Bony, S.: A detailed look at the cumulus-valve mechanism and its potential implications for cloud-base cloudiness, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5975, https://doi.org/10.5194/egusphere-egu2020-5975, 2020.

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Low-level cloud feedbacks in CMIP6 models and EUREC4A observations

Anna Lea Albright, Sandrine Bony, Jean-Louis Dufresne, and Jessica Vial

How will low-level clouds respond to global warming? We approach this question by first investigating the spread of climate sensitivity and cloud feedbacks in CMIP6 models. We stratify the cloud response by circulation regime and focus in greater detail on the cloud response in tropical regimes of subsidence and weak ascent  (i.e., their vertical structure in the present-day and future climate, how cloud profile changes relate to changes in cloud-controlling factors). This CMIP6 model analysis dovetails with an observational analysis of low cloud responses from the EUREC4A field campaign. We seek to employ a simple model of low cloud behavior, constrained with observations from EUREC4A and longer time series from the Barbados Cloud Observatory, to better constrain the range of low cloud behavior spanned by CMIP6 models. 

How to cite: Albright, A. L., Bony, S., Dufresne, J.-L., and Vial, J.: Low-level cloud feedbacks in CMIP6 models and EUREC4A observations , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4077, https://doi.org/10.5194/egusphere-egu2020-4077, 2020.

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Measuring the variability of the shallow convective mass flux profiles in the tropical trade wind region

Marcus Klingebiel, Heike Konow, and Bjorn Stevens

Mass flux is a key parameter to represent shallow convection in global circulation models. To estimate the shallow convective mass flux as accurately as possible, observations of this parameter are necessary. Prior studies from Ghate et al. (2011) and Lamer et al. (2015) used Doppler radar measurements over a few months to identify a typical shallow convective mass flux profile based on cloud fraction and vertical velocity. In this study, we extend their observations by using long term remote sensing measurements at the Barbados Cloud Observatory (13° 09’ N, 59° 25’ W) over a time period of 30 months and check a hypothesis by Grant (2001), who proposed that the cloud base mass flux is just proportional to the sub-cloud convective velocity scale. Therefore, we analyze Doppler radar and Doppler lidar measurements to identify the variation of the vertical velocity in the cloud and sub-cloud layer, respectively. Furthermore, we show that the in-cloud mass flux is mainly influenced by the cloud fraction and provide a linear equation, which can be used to roughly calculate the mass flux in the trade wind region based on the cloud fraction.

 

References:
Ghate,  V.  P.,  M.  A.  Miller,  and  L.  DiPretore,  2011:   Vertical  velocity structure of marine boundary layer trade wind cumulus clouds. Journal  of  Geophysical  Research: Atmospheres, 116  (D16), doi:10.1029/2010JD015344.

Grant,  A.  L.  M.,  2001:   Cloud-base  fluxes  in  the  cumulus-capped boundary layer. Quarterly Journal of the Royal Meteorological Society, 127 (572), 407–421, doi:10.1002/qj.49712757209.

Lamer, K., P. Kollias, and L. Nuijens, 2015:  Observations of the variability  of  shallow  trade  wind  cumulus  cloudiness  and  mass  flux. Journal of Geophysical Research: Atmospheres, 120  (12), 6161–6178, doi:10.1002/2014JD022950.

How to cite: Klingebiel, M., Konow, H., and Stevens, B.: Measuring the variability of the shallow convective mass flux profiles in the tropical trade wind region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4780, https://doi.org/10.5194/egusphere-egu2020-4780, 2020.

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The influence of the large-scale circulation on the thermodynamic profiles in the trades from a Lagrangian perspective

Leonie Villiger, Franziska Aemisegger, Maxi Boettcher, and Heini Wernli

In the tropical winter trades of the North Atlantic in the vicinity of Barbados four different mesoscale organisation patterns of clouds – sugar, gravel, flower, fish - are observed regularly. Each pattern is associated with a distinct cloud amount and radiative footprint. Therefore, the relative occurrence frequency of these patterns affects the global radiative budget. As shown by a recent study (Bony et al. 2019, Geophysical Research Letter), the occurrence of the four patterns is controlled by the near-surface wind speed and the strength of lower tropospheric instability. It is however not yet clear, whether these cloud patterns occur preferably in specific larger-scale flow configurations. These can be associated for example with upper-level wave breaking in the extratropics and different positions and strengths of low-level subtropical anticyclones.

Lower tropospheric air parcels at different altitudes in the trades are expected to have different transport histories associated with distinct diabatic processes such as radiative effects, phase changes within and below clouds and turbulent mixing. The diabatic processes encountered during transport modulate the thermodynamic properties of the air parcels and therefore influence the vertical thermodynamic structure of the atmosphere in the trades.

In this study, the impact of large-scale air mass advection on the thermodynamic profiles over Barbados is analysed for each of the four mesoscale organisation patterns observed during EUREC4A. The airmass transport history is characterised for different homogenous atmospheric layers. These layers are identified based on vertical pseudo-soundings above the Barbados Cloud Observatory (BCO) using ECMWF analysis data for cases where profiles agree well with independent observations from balloon soundings. The large-scale circulation within the 10 days prior to the sounding is considered for computing the trajectories of the air masses arriving in these layers. Backward trajectories are calculated with three-dimensional analysis wind fields. Thereby, the thermodynamic history and large-scale circulation configuration associated with the four cloud organisation patterns is described from a Lagrangian perspective. In addition, composites of the sea level pressure field provide information whether the four patterns co-occur with systematically differing positions and/or intensities of subtropical anticyclones. In future work, stable water isotopes will be used as observational tracers to find supportive evidence of the characterised transport history.

How to cite: Villiger, L., Aemisegger, F., Boettcher, M., and Wernli, H.: The influence of the large-scale circulation on the thermodynamic profiles in the trades from a Lagrangian perspective , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4859, https://doi.org/10.5194/egusphere-egu2020-4859, 2020.

The fair-weather cumulus clouds, that cover much of the low-latitude oceans, affect the radiation balance of the planet by reflecting incoming solar radiation and absorbing outgoing longwave radiation.  These clouds also drive atmospheric circulation by mixing the lower atmosphere in a process called shallow convection.  This mixing, in turn, affects sea surface temperature and salinity by moderating the air-sea exchange of energy and moisture.  Marine boundary layer (MBL) atmospheric aerosols play a role in the processes described above by scattering and absorbing solar radiation and by serving as cloud condensation nuclei (CCN) thereby influencing cloud droplet concentrations and size; the extent, lifetime, and albedo of clouds; and the frequency and intensity of precipitation. Quantifying the role of aerosols over the Northwest Tropical Atlantic is critical to advance understanding of shallow convection and air-sea interactions.

MBL aerosol properties were measured aboard the RV Ronald H. Brown during the EUREC4A and ATOMIC field studies in January/February 2020.  Aerosols encountered during the study include background sulfate/sea spray particles and African dust/biomass burning particles.  Aerosol physical, chemical, optical and cloud condensation nuclei properties will be presented and their interaction with local and regional circulation.

How to cite: Bates, T. and Quinn, P.: Shipboard Measurements of Aerosol Properties in the Coupled Ocean-Atmosphere System of the Northwest Tropical Atlantic, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5901, https://doi.org/10.5194/egusphere-egu2020-5901, 2020.

The representation of shallow tradewind cumulus clouds in climate models accounts for majority of inter-model spread in climate projections, highlighting an urgent need to understand these clouds better. In particular their spatial organisation appears to cause a strong impact of their radiative properties and dynamical evolution. The precise mechanisms driving different forms of convective organisation which arise both in nature and in simulations are however currently unknown.

The EUREC4A field campaign presents an unprecedented opportunity to study these clouds by measuring simultaneously the ambient conditions (e.g. windshear, horizontal convergence, subsidence) and the cloud properties. Using an unsupervised neural network able to autonomously discover different patterns of convective organisation this work quantifies the ambient and cloud-properties present in differently organised regimes and in the transitions between these regimes.

The model is trained on GOES-R imagery of the tropical Atlantic. Spatial maps of convective organisation and temporal evolution of these will be presented together with large-scale influences on their development, helping unpick the dynamics of convective clouds in this region.

How to cite: Denby, L.: Unsupervised Classification of Convective Organisation in EUREC4A with Deep Learning, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20551, https://doi.org/10.5194/egusphere-egu2020-20551, 2020.

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Precipitation within EUREC4A: a multi-sensor ship-based approach to tackle warm rain processes

Claudia Acquistapace and Tobias Boeck

Trade wind cumulus clouds play a vital role in the Earth's radiation budget and produce up to 20% of the total precipitation in the tropics. However, we still don't know how they will respond to global warming. Precipitation from trade wind cumuli can alter cloud macroscopic properties and the boundary layer structure and dynamics.

Precipitation development in models is very uncertain, being dependent on simulation setup and microphysics. In particular, the autoconversion scheme dramatically affects precipitation flux, cloud structure, and organization. Currently, no evaluations of the different autoconversion schemes with observations reduced the uncertainties in rain processes. Precipitation can impact convection organization and circulation intensity with massive effects on climate sensitivity and its evaporation determines the intensity of cold pools and influences the cloud field organization. It is hence key to quantify evaporation rates and their spatiotemporal variability. Parametrizations of evaporation below cloud base are available but strongly depend on the drop size distribution of raindrops. Also, in the observations, evaporation rates are hard to observe directly.

Here, we would like to present the potential given by the observations collected on the Maria S. Merian ship during the EUREC4A campaign to estimate evaporation rates and provide advanced multi-sensor observations of rain onset and development. The synergy of multiple in-situ and remote-sensing from the ship as well as aircraft observations available will allow to constrain the autoconversion scheme in LES models and reduce the uncertainties connected to rain processes. Moreover, quantification of evaporation rates will clarify the role of precipitation in moisturizing the boundary layer in trade wind regions.

 

How to cite: Acquistapace, C. and Boeck, T.: Precipitation within EUREC4A: a multi-sensor ship-based approach to tackle warm rain processes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6265, https://doi.org/10.5194/egusphere-egu2020-6265, 2020.

Cloud feedback in mid-latitude marine stratocumulus is not clearly understood due to few reliable observations. Stratocumulus cloud is the most frequent and extensive cloud type over mid-latitude marine areas and has strong short-wave radiative effect. In this study, large eddy simulation (LES) is used to resolve the vertical structure of mid-latitude marine stratocumulus. We find that, in the wintertime over North Pacific, stratocumulus cloud often forms in regions of high pressure and large-scale sinking motion, and can remain in steady-state for a couple of days. We then choose two typical cases to do LES simulation: One has a lower cloud top height and a stronger temperature inversion (case l), without mesoscale cellular structure; the other has a higher cloud top height and a weaker temperature inversion (case h), with closed-cell cellular structure. The liquid water content profiles are adiabatic, and the boundary layer is well-mixed for both cases. In case l, the main source of turbulent kinetic energy (TKE) is from cloud top long-wave radiative cooling for the entire boundary layer. In case h, TKE production due to cloud-top longwave cooling is only significant in the cloud layer, and the subcloud layer TKE is mainly from surface processes.

How to cite: Ren, Y. and Xue, H.: The vertical structure of mid-latitude marine stratocumulus simulated by large eddy simulation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6361, https://doi.org/10.5194/egusphere-egu2020-6361, 2020.

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Cloud macrophysical properties from airborne observations during EUREC4A

Heike Konow, Marcus Klingebiel, and Felix Ament

Trade wind cumulus clouds are the predominant cloud type over the tropical Atlantic east of the island of Barbados. Parameters describing their macroscopic shape can help characterizing and comparing general features of clouds. This characterizing will indirectly help to constrain estimates of climate sensitivity, because models with different structures of trade wind cumuli feature different response to increased CO2 contents.

Two aircraft campaigns with the HALO (High Altitude LOng range) aircraft took place in the recent past in this region: NARVAL-South (Next-generation Aircraft Remote-Sensing for VALidation studies) in December 2013, during the dry season, and NARVAL2 in August 2016, during the wet season. During these two campaigns, a wide range of cloud regimes from shallow to deep convection were sampled. This past observations are now extended with observations from this year’s measurement campaign EUREC4A, again during the dry season. EUREC4A is endorsed as WCRP capstone experiment and the synergy of four research aircraft, four research vessels and numerous additional observations will provide comprehensive characterizations of trade wind clouds and their environment.

Part of the NARVAL payload on HALO is a 35 GHz cloud radar, which has been deployed on HALO on several missions since 2013. These cloud radar measurements are used to segment individual clouds entities by applying connected component analysis to the radar cloud mask. From these segmented individual clouds, macrophysical parameters are derived to characterize each individual cloud.

This presentation will give an overview of the cloud macrophysics observed from HALO during EUREC4A. Typical macrophysical parameters, i.e. cloud depth, cloud length, cloud fraction, are analyzed. We will relate these to observations from past campaigns and assess the representativeness of EUREC4A. As special focus of the EUREC4A campaign, measurements will be performed during different times of the day to detect diurnal cycles. Macrophysical parameters can be used to characterize changes over the day and cloud scenes of similar clouds types can be identified.

How to cite: Konow, H., Klingebiel, M., and Ament, F.: Cloud macrophysical properties from airborne observations during EUREC4A, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11106, https://doi.org/10.5194/egusphere-egu2020-11106, 2020.

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Investigating the contribution of polarimetry in retrieving ice microphysical properties using Dual-Wavelength radar observations

Eleni Tetoni, Florian Ewald, Gregor Möller, Martin Hagen, Tobias Zinner, Christoph Knote, Bernhard Mayer, Qiang Li, and Silke Groß

Many studies have shown that multi-wavelength radar measurements can be valuable in inferring information about the size of observed hydrometeors in the atmosphere. Dual-wavelength radar method is widely known in such retrievals as it takes advantage of the different scattering behavior of hydrometeors in Rayleigh and MIE regime. Hydrometeors with sizes much smaller than the radar wavelength, act like Rayleigh scatterers and their radar reflectivity Z is proportional to the sixth power of their size. While these particles become larger due to riming or aggregation processes, with sizes comparable or larger than the radar wavelength, MIE effects can occur and thus, Z is proportional to the second power of their size. In the framework of IcePolCKa (Investigation of the initiation of Convection and the Evolution of Precipitation using simulatiOns and poLarimetric radar observations at C- and Ka-band) project, the evolution of ice in the precipitation formation will be studied exploiting these differences in both scattering regimes. Except for the logarithmic radar reflectivity difference, known as Dual-Wavelength Ratio (DWR) or Dual-Frequency Ratio (DFR), between C-band POLDIRAD weather radar from German Aerospace Center (DLR) in Oberpfaffenhofen and the Ka-band MIRA-35 cloud radar from Ludwig Maximilian University of Munich (LMU), other measured polarimetric variables from both radars, i.e. Differential Reflectivity (ZDR), Reflectivity Difference (ZDP), Linear Depolarization Ratio (LDR) will be also used. In addition to observations, scattering algorithms, i.e. T-matrix, will provide scattering simulations for a variety of ice particles shapes, sizes and mass-size relations. Combining DWR, polarimetric measurements and simulations the shape and/or the density of the observed ice particles will be retrieved. In this presentation, we will describe the instrumentation setup as well as the measuring methods in detail. Furthermore, we will present preliminary results of the retrieval approach using T-matrix calculations and measurements. Our first dataset consist of observations during snow events over Munich in January 2019 in order to avoid strong attenuation effects in the Ka-band.

How to cite: Tetoni, E., Ewald, F., Möller, G., Hagen, M., Zinner, T., Knote, C., Mayer, B., Li, Q., and Groß, S.: Investigating the contribution of polarimetry in retrieving ice microphysical properties using Dual-Wavelength radar observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13930, https://doi.org/10.5194/egusphere-egu2020-13930, 2020.

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Identifying the radiative ‘twilight zone’ surrounding shallow cumulus clouds from high-resolution ASTER observations

Theresa Mieslinger, Manfred Brath, Stefan A. Buehler, and Bjorn Stevens

The uncertain radiative effect of shallow cumulus clouds over tropical ocean significantly contributes to the high uncertainty in climate sensitivity estimates. Radiances corresponding to clear-sky and cloudy areas can be observed in moderate resolution satellite images. To observe the radiance originating from very small clouds and from the transition zone surrounding shallow cumulus clouds, the ‘twilight zone’, high-resolution data is required. Twilight zone radiances can be higher than clear-sky radiances due to unresolved cloud fragments and/or humidified aerosols. The area of the twilight zone depends on the resolution of the underlying data. If we think of the twilight zone in terms of partially cloudy pixels, such an area results in a high uncertainty in cloud and aerosol retrievals, as they are based on cloudy and clear-sky assumptions respectively. A precise knowledge of radiances from clouds and their twilight zone is decisive in terms of the total cloud reflectance and subsequently the shallow cumulus cloud radiative effect, which climate models struggle to properly simulate.

We therefore investigate the abundance and importance of such a twilight zone from high-resolution satellite images from ASTER recoded previously and during the EUREC4A field campaign. We use radiative transfer simulations to model the contribution of background clear-sky radiances including aerosols. Subtracting known clear-sky radiances from observed cloud field radiances leaves us with a precise knowledge of non-clear-sky radiances originating from shallow cumulus clouds and their surrounding twilight zone.

How to cite: Mieslinger, T., Brath, M., Buehler, S. A., and Stevens, B.: Identifying the radiative ‘twilight zone’ surrounding shallow cumulus clouds from high-resolution ASTER observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19086, https://doi.org/10.5194/egusphere-egu2020-19086, 2020.

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The hyperspectral and polarization resolving imager specMACS during EUREC4A

Tobias Kölling, Veronika Pörtge, Linda Forster, Tobias Zinner, Claudia Emde, and Bernhard Mayer

The EUREC4A field campaign, which takes place in January and February 2020 in the trade wind region east of Barbados, aims to Elucidate the Couplings Between Clouds, Convection and Circulation (Bony et al. 2017). For this field campaign, the hyperspectral imaging system specMACS (Ewald et al. 2016) has been equipped with additional color and polarization resolving cameras. The system is operated in downwards looking perspective on board the HALO research aircraft during this field campaign, aiming at the observation and characterization of clouds.

The combination of push-broom type spectral imaging sensors with two dimensional polarization resolving cameras offers new possibilities for cloud remote sensing. Using two dimensional images and stereographic techniques, the three dimensional structure of the cloud scene can be reconstructed (Kölling et al. 2019). The availability of a 3D model of the observed scene then allows to properly fuse passive observations from multiple sensors into a common data base. Additional information like cloud top height, cloud surface orientation, and an estimate of shadowed regions can aid previously available retrieval methods. Furthermore, the availability of polarization resolving images allows to strongly amplify the signal of single scattering processes. This and the large field of view of the two dimensional cameras largely improves the ability to derive cloud droplet size and width of the size distribution from the observation of cloudbows and glories (Mayer et. al. 2004, Pörtge 2019).

The poster will give an overview about the current instrument configuration and show data and first results from the EUREC4A field campaign.

References
Bony, S., Stevens, B., Ament, F. et al.: EUREC4A: A Field Campaign to Elucidate the Couplings Between Clouds, Convection and Circulation, Surv Geophys (2017) 38: 1529. https://doi.org/10.1007/s10712-017-9428-0

Ewald, F., Kölling, T., Baumgartner, A., Zinner, T., and Mayer, B.: Design and characterization of specMACS, a multipurpose hyperspectral cloud and sky imager, Atmos. Meas. Tech., 9, 2015–2042, https://doi.org/10.5194/amt-9-2015-2016, 2016.

Kölling, T., T. Zinner, B. Mayer, 2019, Aircraft-based stereographic reconstruction of 3-D cloud geometry, Atmos. Meas. Tech., 12, 1155-1166, https://doi.org/10.5194/amt-12-1155-2019, 2019.

Mayer, B., Schröder, M., Preusker, R., and Schüller, L.: Remote sensing of water cloud droplet size distributions using the backscatter glory: a case study, Atmos. Chem. Phys., 4, 1255–1263, https://doi.org/10.5194/acp-4-1255-2004, 2004.

Veronika Pörtge. Cloud Droplet Size Distributions from Observations of Glory and Cloudbow. Master’s thesis, Ludwig-Maximilians-Universität München, 11 2019.

How to cite: Kölling, T., Pörtge, V., Forster, L., Zinner, T., Emde, C., and Mayer, B.: The hyperspectral and polarization resolving imager specMACS during EUREC4A, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20300, https://doi.org/10.5194/egusphere-egu2020-20300, 2020.

EGU2020-13451 | Displays | AS1.26

Can we observe a correlation between vertical Doppler velocity and upwelling solar radiance for shallow marine boundary clouds?

Florian Ewald, Silke Groß, Martin Hagen, Tobias Kölling, and Bernhard Mayer

Clouds play an important role in the climate system since they have a profound influence on Earth’s radiation budget and the water cycle. Uncertainties in current climate models arise from a limited understanding of the coupling between cloud dynamics, cloud microphysics and, in turn, cloud radiative properties. Over decades, radiative properties of cloud tops were extensively studied using passive observations from multiple satellite missions. In recent years, our understanding of the inner workings of clouds has been greatly advanced by the deployment of cloud profiling microwave radars from low-earth orbit like CloudSat or the upcoming EarthCARE satellite mission. In order to exploit the future synergy between the cloud radar and the passive imager on EarthCARE, the scientific community is in dire need of collocated and spatially highly resolved measurements in advance of future spaceborne missions.  

In this context, the German research aircraft HALO is equipped with the high-power (30kW) cloud radar HAMP MIRA operating at 35 GHz and the hyperspectral imager specMACS (400 nm – 2500 nm). During the EUREC4A campaign, a number of flights were conducted over shallow marine boundary clouds in the vicinity of Barbados to collect simultaneous measurements with both instruments. For the first time, the spatial resolution of the Doppler velocity measurements from HALO now better match (<100 meter) the spatial resolution of the radiance imager, allowing for a more detailed separation of small up- und down-drafts.

In this presentation, we will give first impressions of these collocated, highly resolved radar-imager measurements of shallow marine boundary clouds during EUREC4A. On the basis of this data set we will try to answer the question if a correlation between the vertical Doppler velocity and the upwelling solar radiance for this kind of clouds can be observed. Such a relationship could prove valuable to assist synergistic retrievals (e.g. radar-lidar) in narrowing down the microphysical assumptions on which these retrievals rely upon. Furthermore, this data set could serve as a benchmark for cloud resolving modeling by constraining the relationship between cloud dynamics and radiation.

How to cite: Ewald, F., Groß, S., Hagen, M., Kölling, T., and Mayer, B.: Can we observe a correlation between vertical Doppler velocity and upwelling solar radiance for shallow marine boundary clouds?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13451, https://doi.org/10.5194/egusphere-egu2020-13451, 2020.

EGU2020-2082 | Displays | AS1.26

Higher climate sensitivity and cloud feedback in ECHAM6.3 with a prognostic cloud cover scheme due to changes in sub-grid scale dynamics

Steffen Muench and Ulrike Lohmann

EGU2020-4067 | Displays | AS1.26

Evaluation of Marine Boundary layer cloud in the NCEP Climate Forecast System (Version 2) via Stochastic Multicloud Model

Kumar Roy, Parthasarathi Mukhopadhyay, Ravuri Phani Murali Krishna, Bidyut Bikhash Goswami, and Boualem Khouider

Marine boundary layer (MBL) cloud is one of the major sources of uncertainty in the climate models and they have been identified in the Intergovernmental Panel on Climate Change’s (IPCC’s) fourth assessment as a primary source of uncertainty in determining the sensitivity of climate models. Further simulating it realistically is a huge challenge. To better represent organized convection in the Climate Forecast System version 2 (CFSv2), a stochastic multicloud model (SMCM) parameterization is adopted and it has showed promising improvement in different features of tropical convection. But the simulation of marine boundary cloud in CFSv2 SMCM (EXP1) is yet to be ascertained. We have calibrated the model by using radar observations and followed Markov-chain process to generate key parameters like transition probability, required for EXP1. This paper describes climate simulations of the EXP1 and 25 year run is made and last 20years are analysed. It replaces pre-existing convection scheme (CTL) and shows improvement in many aspects of climate compared to CTL. In addition, global distribution of MBL cloud is also improved and it is also with better agreement with observational analysis, which is inaccurate in CTL. Further, the transition from stratocumulus to trade cumulus is well simulated in EXP1. These results are also supported also by quantitative analyses like Root Mean Square Error (RMSE) etc. The improvement seen in EXP1 can be largely attributed to the general improved in the representation of shallow and cumulus clouds compared to CTL.

How to cite: Roy, K., Mukhopadhyay, P., Krishna, R. P. M., Goswami, B. B., and Khouider, B.: Evaluation of Marine Boundary layer cloud in the NCEP Climate Forecast System (Version 2) via Stochastic Multicloud Model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4067, https://doi.org/10.5194/egusphere-egu2020-4067, 2020.

EGU2020-4701 | Displays | AS1.26

The role of convection in the momentum budget of ICON-LEM hindcasts over the North Atlantic

Kevin Helfer, Louise Nuijens, Vishal Dixit, and Pier Siebesma

Motivated by the uncertain role of convective momentum transport from low clouds in setting patterns of wind in the trades, we discuss the impact of shallow convection on boundary-layer winds and its role in the overall momentum budget in the trades from large-domain large-eddy simulations. To this end, we analyse ICON-LEM hindcast simulations over the (sub)tropical North Atlantic during the NARVAL1 and NARVAL2 flight campaigns.

We describe that the character of the momentum flux profile differs significantly in regimes of shallow and deep convection and thus its influence on cloud-layer and near-surface winds. In particular, we establish that the momentum transport tendency is of similar importance as other terms in the momentum budget, and though the shape of the profile is remarkably insensitive to the horizontal resolution of the simulation, the relative role of subgrid and resolved fluxes changes with resolution. Furthermore, we find that counter-gradient transport occurs even in the absence of organisation, namely in the lower cloud layer, where cloudy updrafts carry slow momentum air upwards, which locally accelerates winds and may play a role at maintaining the cloud-base wind maximum.

How to cite: Helfer, K., Nuijens, L., Dixit, V., and Siebesma, P.: The role of convection in the momentum budget of ICON-LEM hindcasts over the North Atlantic, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4701, https://doi.org/10.5194/egusphere-egu2020-4701, 2020.

EGU2020-6326 | Displays | AS1.26

Evolution of Organized Shallow Convection

Hauke Schulz, Ryan Eastman, and Bjorn Stevens

Uncertainty in the response of clouds to warming is the leading source of uncertainty in projections of future warming. To a large fraction the frequently occurring shallow cumulus clouds in the trade wind region contribute to this uncertainty. In symbiosis with thin clouds of stratiform extent they often create various cloud patterns.

We introduce a neural network that is able to detect the mesoscale organization from GOES16 and MODIS satellite imagery in order to put eight years of ground-based measurements of the Barbados Cloud Observatory into the context of mesoscale organization. With this combination of long-term ground-based measurements from the trade-wind region and satellite image classifications, we overcome the common resolution limitations of satellite derived cloud products of shallow cumuli and are able to present the characteristics of shallow convection depending on the mesoscale organization with great detail.

By using back-trajectories and EUREC4A field campaign data, we show that differences in the atmospheric environment are not only present at the time of pronounced mesoscale organization, but are already distinguishable days ahead in LTS, wind speed and SST.

How to cite: Schulz, H., Eastman, R., and Stevens, B.: Evolution of Organized Shallow Convection, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6326, https://doi.org/10.5194/egusphere-egu2020-6326, 2020.

EGU2020-6982 | Displays | AS1.26

Which regional cloud-radiative changes are most important for the global warming response of the midlatitude jet streams?

Nicole Albern, Aiko Voigt, David W. J. Thompson, and Joaquim G. Pinto

Clouds and the midlatitude circulation are strongly coupled via radiation. Previous studies showed that global cloud-radiative changes contribute significantly to the global warming response of the midlatitude circulation. Here, we investigate the impact of regional cloud-radiative changes and identify which regional cloud-radiative changes are most important for the impact of global cloud-radiative changes. We show how tropical, midlatitude and polar cloud-radiative changes modify the annual-mean, wintertime and summertime jet stream response to global warming across ocean basins. To this end, we perform global simulations with the atmospheric component of the ICOsahedral Nonhydrostatic (ICON) model. We prescribe sea surface temperatures (SST) to isolate the impact of cloud-radiative changes via the atmospheric pathway, i.e. changes in atmospheric cloud-radiative heating, and mimic global warming by a uniform 4K SST increase. We apply the cloud-locking method to break the cloud-radiation-circulation coupling and to decompose the circulation response into contributions from cloud-radiative changes and from the SST increase.

In response to global warming, the North Atlantic, North Pacific, Northern Hemisphere and Southern Hemisphere jet streams shift poleward and the North Atlantic, Northern Hemisphere and Southern Hemisphere jets strengthen. Global cloud-radiative changes contribute to these jet responses in all ocean basins. In the annual-mean and DJF, tropical and midlatitude cloud-radiative changes contribute significantly to the poleward jet shift in all ocean basins. Polar cloud-radiative changes shift the jet streams poleward in the northern hemispheric ocean basins but equatorward in the Southern Hemisphere. In JJA, the poleward jet shift is small in all ocean basins. In contrast to the jet shift, the global cloud-radiative impacts on the 850hPa zonal wind and jet strength responses result predominantly from tropical cloud-radiative changes.

The cloud-radiative impact on the jet shift can be related to changes in upper-tropospheric baroclinicity via increases in upper-tropospheric meridional temperature gradients, enhanced wave activity and increased eddy momentum fluxes. However, the response of the atmospheric temperature to cloud-radiative heating is more difficult to understand because it is modulated by other small-scale processes such as convection and the circulation. Our results help to understand the jet stream response to global warming and highlight the importance of regional cloud-radiative changes for this response, in particular those in the tropics.

How to cite: Albern, N., Voigt, A., Thompson, D. W. J., and Pinto, J. G.: Which regional cloud-radiative changes are most important for the global warming response of the midlatitude jet streams?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6982, https://doi.org/10.5194/egusphere-egu2020-6982, 2020.

EGU2020-12434 | Displays | AS1.26

Characterizing precipitation in convective cloud regimes in the trades with the polarimetric C-band radar POLDIRAD

Martin Hagen, Florian Ewald, Silke Groß, Qiang Li, Lothar Oswald, and Eleni Tetoni

Low-level clouds in the trade regions play an important role in the Earth’s climate system since they have a considerable influence on the Earth’s radiation budget. However, the understanding of the coupling between cloud dynamics, cloud microphysics, and mesoscale organization is limited. This results in a large uncertainty in current climate predictions. Despite the importance, observations in these regions are limited. Geostationary satellites cannot provide high resolution three-dimensional details of clouds and precipitation. Polar orbiting satellites like the A-Train satellites Cloudsat and Calipso or the upcoming EarthCARE satellite do provide detailed profiles of cloud properties, but the temporal evolution cannot be observed. On the other hand, long range weather radar observations can provide both, high spatial and temporal observations, however not many weather radar do cover the trades.

During the Eurec4a campaign DLRs C-band polarimetric weather radar POLDIRAD was installed on the island of Barbados. The scope of the radar measurements is manifold:

- POLDIRAD will provide high resolution observations of the different mesoscale cloud patterns as observed from satellites: Flowers, Gravel, Fish, and Sugar. Will the mesoscale organization have an influence on observable microphysical properties?

- POLDIRAD will put the detailed measurements by aircraft (in situ and remote sensing) into a greater context. How are the aircraft measurements related to the spatial distribution of the precipitation pattern? How are the aircraft measurements related to the temporal evolution of the precipitation pattern?

- POLDIRAD will put the observed profiles of clouds and precipitation at the Barbados Cloud Observatory BCO at Deebles Point into a greater context. How are the profile measurements related to the spatial distribution of the precipitation pattern? How are the profile measurements related to the temporal evolution of the precipitation pattern?

How to cite: Hagen, M., Ewald, F., Groß, S., Li, Q., Oswald, L., and Tetoni, E.: Characterizing precipitation in convective cloud regimes in the trades with the polarimetric C-band radar POLDIRAD, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12434, https://doi.org/10.5194/egusphere-egu2020-12434, 2020.

EGU2020-13370 | Displays | AS1.26

On the persistence of tropical shallow convective squall lines - the role of cold pools

Ludovic Touzé-Peiffer, Nicolas Rochetin, and Raphaela Vogel

A considerable amount of literature has been devoted to the study of strong convective squall line. In particular, many studies have noted the role of cold pools on the persistence of these squall lines. Observations and simulations have shown that squall lines are often associated with pools of air cooled by partial rain evaporation. Such cold pools spread at the surface and may initiate new convective cells at their edges, thus contributing to the maintenance of a squall line. Under which environmental conditions the lifting at the edges of cold pools is most efficient has been subject to many debates. Yet, it is generally acknowledged that the environmental wind shear is a critical factor in this process. 

Recent observations and realistic simulations over the trade-wind region have revealed persistent structures of shallow cumuli associated with surface cold pools. We will call these structures shallow convective squall lines, due to their similarity with strong convective squall lines. Based on simulations from the German model ICON and on recent observations from the field campaign EUREC4A, we will study the characteristics of these shallow convective squall lines and their lifecycle. Similarly to strong convective squall lines, shallow convective squall lines organized around a leading edge composed by many updrafts and downdrafts feeding the surface cold pools. We will see that the environmental wind shear plays a key role in the persistence of these shallow convective squall line, and we will compare our findings with classical theories for strong convective squall lines.

How to cite: Touzé-Peiffer, L., Rochetin, N., and Vogel, R.: On the persistence of tropical shallow convective squall lines - the role of cold pools, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13370, https://doi.org/10.5194/egusphere-egu2020-13370, 2020.

EGU2020-22375 | Displays | AS1.26

Airborne Atmospheric Measurements with the mini Max Planck CloudKite

Marcel Schröder, Freja Nordsiek, Oliver Schlenczek, Antonio Ibanez Landeta, Eberhard Bodenschatz, and Gholamhossein Bagheri

Clouds play a key role in the energy balance of the Earth's atmosphere and its radiation budget. The lack of detailed understanding of clouds is one of the reasons for the uncertainties in weather forecasting and climate modelling. The dynamics of clouds extend over a wide range of spatial and temporal scales from micrometers to km and milliseconds to hours. Besides Plinian volcanic eruptions, clouds show the highest turbulence level on earth. The multiscale properties of the turbulent flow in combination with moisture and temperature transport, phase transitions, and inertial particle dynamics present a challenge for modelling and parameterization.  Here we use a specially developed airborne platform, the Mini-Max-Planck-CloudKite (Mini-MPCK), to measure meteorological and cloud microphysical properties with high spatial and temporal resolution. The mini-MPCK is a 75 qm helium-filled balloon kite carrying a tether-mounted instrument for measuring atmospheric state parameters, and the density and size distribution of cloud particles. We will report on measurements from the trade wind region obtained during the EUREC4A campaign in Jan-Feb 2020.

How to cite: Schröder, M., Nordsiek, F., Schlenczek, O., Ibanez Landeta, A., Bodenschatz, E., and Bagheri, G.: Airborne Atmospheric Measurements with the mini Max Planck CloudKite, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22375, https://doi.org/10.5194/egusphere-egu2020-22375, 2020.

AS1.30 – Convective and Volcanic Clouds monitoring and climate interaction

EGU2020-458 | Displays | AS1.30

Impact of November 2010 volcanic activity on the UTLS temperatures

Elżbieta Lasota, Riccardo Biondi, Florian Ladstädter, and Andrea K. Steiner

Recent studies have shown an increase of stratospheric aerosol optical depth in the last 20 years despite the absence of large volcanic eruptions in the same period, contributing to supporting the hypothesis that several minor eruptions could impact the atmospheric variability as a large one. November 2010 was a relatively active volcanic period in the tropical belt, three eruptions with Volcanic Explosivity Index higher than 3 occurred in a time span of about 3 weeks: Merapi, Tengger Caldera and Tungurahua. Merapi was the largest eruption of the three, directly overshooting the stratosphere and injecting a large amount of sulfur dioxide. In this study, we analyse the impact of this series of eruptions on the temperature derived from radio occultation observations in upper troposphere lower stratosphere at the local, regional and global scale. The impact of the Quasi‐Biennial Oscillation, El Niño–Southern Oscillation, and linear trend on temperature is estimated and removed from temperature time series using multiple linear regression. Signatures of volcanic eruptions in temperature are analysed using post fit residuals. The results show significant warming in the lower stratosphere between 10°S and 0° for a period of 7 months after the eruptions with a maximum anomaly amplitude of about 1.4 K at 18 km altitude. Whilst the maximum warming in Merapi’s vicinity occurred 4 months after the eruption and reached the magnitude of almost 4 K.

How to cite: Lasota, E., Biondi, R., Ladstädter, F., and Steiner, A. K.: Impact of November 2010 volcanic activity on the UTLS temperatures , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-458, https://doi.org/10.5194/egusphere-egu2020-458, 2020.

EGU2020-671 | Displays | AS1.30

SO2 volcanic clouds detected from space: a new database

Pierre-Yves Tournigand, Valeria Cigala, Mohammed Hammouti, Fred Prata, Hugues Brenot, Lieven Clarisse, Andrea K. Steiner, Gottfried Kirchengast, and Riccardo Biondi

Explosive volcanic eruptions can generate ash and SO2 clouds rising to the stratosphere and dispersing on a global scale. Such volcanic features are at the origin of many hazards including aircraft engine damages, ash fallouts, acid rains, short-term climate changes and health threats. It is thus crucial to monitor volcanic clouds altitude and dispersion over time in order to prevent these hazards. In the past decades, satellite monitoring techniques have proven to be efficient at detecting volcanic aerosols in the atmosphere. In particular the detection of SO2 (e.g. IASI, AIRS, GOME-2) spatial and temporal dispersion and altitude (e.g. CALIOP). However, satellite data are scattered amongst the different institutes and agencies acquiring and processing them, and their retrieval is time-consuming.

In this study, we are building a whole new database gathering SO2 volcanic cloud altitude and dispersion data of 12 VEI 4 volcanic eruptions from 2008 to 2019. The spatial and temporal dispersion is retrieved from AIRS, IASI and GOME-2 sensors, as well as from collocated backscatter data of CALIOP sensor. Cloud altitude estimations are retrieved based on IASI, CALIOP and Global Navigation Satellite System (GNSS) radio occultation (RO) data when available. Besides, GNSS RO atmospheric profiles collocated with the other sensors at 12h temporal window and 0.2° spatial window, will be included. For the first time a dataset gathering several of the primary sensors used to monitor volcanic clouds and new ones will be freely available. Such new tool provides direct access to volcanic clouds data, and enables to perform original analysis and comparisons between different techniques. Applications for this dataset will impact many fields of volcanology and atmospheric physics, including but not restricted to volcanic clouds dispersal numerical modelling and volcanic aerosol impact on the atmosphere and climate. In fact, the collocation with GNSS RO will allow the study of the atmospheric structure with high vertical resolution.

How to cite: Tournigand, P.-Y., Cigala, V., Hammouti, M., Prata, F., Brenot, H., Clarisse, L., Steiner, A. K., Kirchengast, G., and Biondi, R.: SO2 volcanic clouds detected from space: a new database, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-671, https://doi.org/10.5194/egusphere-egu2020-671, 2020.

EGU2020-2847 | Displays | AS1.30

Creating a 4D SO2 dataset with high vertical resolution by connecting volcanic cloud observations through trajectory modelling

Oscar S. Sandvik, Bengt G. Martinsson, Johan Friberg, and Moa Sporre

After major volcanic eruptions, sulphur dioxide (SO2) can be released in large quantities to the stratosphere. The sulphur dioxide is later oxidised into sulphate aerosol which reflect incoming sunlight and cools the surface temperatures around the globe. The duration length is highly dependent on the altitude of the SO2 cloud and its geographical location. Today, infrared sensors on-board satellites can give an estimate of the SO2 cloud top height and lidar instruments can give height profiles in their narrow field-of-view. Both these classes of instrument lack the capability to fully map the vertical distribution of the SO2 clouds. We propose a scheme to create a SO2 dataset with high vertical resolution. The scheme consists of distributing SO2 column densities from ultra-violet and infrared satellite instruments into SO2 profiles using scattering data from the CALIOP lidar on-board the CALIPSO satellite. The CALIOP lidar has a vertical resolution of up to 60 m in the region of interest. Since CALIOP only collect data along narrow fields-of-view, this initially gives us the SO2 dataset only where CALIOP has collected data. To make the most of this information we run the FLEXPART trajectory model. If air parcels that were initially in CALIOP’s field-of-view and later in another part of the SO2 cloud, then the output from FLEXPART gives us this information. Thus, from CALIOP we shift the vertical information in time to other parts of the SO2 cloud using the trajectory model.

How to cite: Sandvik, O. S., Martinsson, B. G., Friberg, J., and Sporre, M.: Creating a 4D SO2 dataset with high vertical resolution by connecting volcanic cloud observations through trajectory modelling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2847, https://doi.org/10.5194/egusphere-egu2020-2847, 2020.

EGU2020-4774 | Displays | AS1.30

Dispersion Modelling at the London VAAC 10 Years after the Eyjafjallajökull Ash Cloud

Frances Beckett, Claire Witham, Susan Leadbetter, Ric Crocker, Helen Webster, Matthew Hort, Andrew Jones, Benjamin Devenish, and David Thomson

It has been 10 years since the ash cloud from the eruption of Eyjafjallajökull caused chaos to air traffic across Europe. Although disruptive, the longevity of the event afforded the scientific community the opportunity to observe and extensively study the transport and dispersion of a volcanic ash cloud. Here we present the development of the NAME atmospheric dispersion model and modifications to its application in the London VAAC forecasting system since 2010, based on the lessons learned.

Our ability to represent both the vertical and horizontal transport of ash in the atmosphere and its removal have been improved through the introduction of new schemes to represent the sedimentation and wet deposition of volcanic ash, and updated schemes to represent deep atmospheric convection and parameterizations for plume spread due to unresolved mesoscale motions. A good simulation of the transport and dispersion of a volcanic ash cloud requires an accurate representation of the source and we have introduced more sophisticated approaches to representing the eruption source parameters, and their uncertainties, used to initialize NAME. Further, atmospheric dispersion models are driven by 3-dimensional meteorological data from Numerical Weather Prediction (NWP) models and the Met Office’s upper air wind field data is now more accurate than it was in 2010. These developments have resulted in a more robust modelling system at the London VAAC, ready to provide forecasts and guidance during the next volcanic ash event affecting their region.

How to cite: Beckett, F., Witham, C., Leadbetter, S., Crocker, R., Webster, H., Hort, M., Jones, A., Devenish, B., and Thomson, D.: Dispersion Modelling at the London VAAC 10 Years after the Eyjafjallajökull Ash Cloud, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4774, https://doi.org/10.5194/egusphere-egu2020-4774, 2020.

EGU2020-5653 | Displays | AS1.30

Lidar observations of volcanic aerosol over the UK since June 2019

Geraint Vaughan, David Wareing, and Hugo Ricketts

On 22 June 2019, the Raikoke volcano in the Kuril Islands erupted, sending a plume of ask and sulphur dioxide into the stratosphere. A Raman lidar system at Capel Dewi, UK (52.4°N, 4.1°W) has been used to measure the extent and optical depth of the stratospheric aerosol layer following the eruption. The lidar was modified to give it much enhanced sensitivity in the elastic channel, allowing measurements up to 25 km, but the Raman channel is only sensitive to the troposphere. Therefore, backscatter ratio profiles were derived by comparison with aerosol-free profiles derived from nearby radiosondes, corrected for aerosol extinction. Small amounts of stratospheric aerosol were measured prior to the arrival of the volcanic cloud, probably from pyroconvection over Canada. Volcanic ash began to arrive as a thin layer at 14 km late on 3 July, extending over the following month to fill the stratosphere below around 19 km. Aerosol optical depths reached around 0.03 by mid-August and continued at this level for the remainder of the year. The location of peak backscatter varied considerably but was generally around 15 km. However, on one notable occasion on August 25, a layer around 300 m thick with peak lidar backscatter ratio around 1.5 was observed as high as 21 km.

How to cite: Vaughan, G., Wareing, D., and Ricketts, H.: Lidar observations of volcanic aerosol over the UK since June 2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5653, https://doi.org/10.5194/egusphere-egu2020-5653, 2020.

EGU2020-10651 | Displays | AS1.30

Measurements of HCl in the volcanic plumes of Calbuco (2015) and Raikoke (2019)

Lieven Clarisse, Alexandre Deguine, Tim Hultberg, Nicolas Theys, Simon Carn, Karen Fontijn, Luna Decoster, Juliette Hadji-Lazaro, Daniel Hurtmans, Claude Camy-Peyret, Cathy Clerbaux, and Pierre-François Coheur

Hydrogen Chloride (HCl) is an important but still poorly understood magmatic volatile species. Degassed HCl and ratios with other volatiles can be used to monitor, understand and forecast volcanic activity. As the dominant chlorine reservoir species in the stratosphere, and a source of reactive halogens, HCl also plays an important role in the depletion of ozone. The contribution of volcanic HCl to the stratospheric budget is however somewhat debated, but it is generally accepted that scavenging by hydrometeors is a dominant process. Unlike the less soluble SO2, this prevents the majority of volcanically emitted HCl from reaching the stratosphere. Currently HCl measurements have only been reported from limb sounders (MLS and ACE-FTS in particular), but given their viewing geometry, their vertical sensitivity is limited to the upper troposphere/lower stratosphere. In the past ten years, MLS was able to measure traces of HCl in a number of large volcanic plumes such as those originating from Sarychev Peak, Nabro and Calbuco.

Here, we report the first measurements from IASI of HCl in volcanic plumes. We provide unambiguous spectroscopic identification of HCl in the 2670-2760 cm-1 spectral region in several IASI observed spectra. A survey of 12 years of IASI data was carried out, and revealed several large plumes of volcanic HCl. We show two notably large plumes of HCl identified in the eruptions of Calbuco (2015) and Raikoke (2019). For these two eruptions, we show that HCl is detected in the lower altitude plumes emitted towards the end of the eruptions (and not in the main, higher-altitude and SO2-rich plumes).  This finding could be a result of the greater scavenging of HCl relative to SO2 in rapidly rising plumes, but could also be related to particular degassing mechanics of different volatile components in the erupted melt. First quantitative estimates indicate that for the analysed plumes, the HCl/SO2 molar ratios exceed one, which is much higher than the typical ratios measured by MLS (typically below 0.05) and also higher than reported from petrological data or in situ measurements (typically in the range 0.1-0.3).

How to cite: Clarisse, L., Deguine, A., Hultberg, T., Theys, N., Carn, S., Fontijn, K., Decoster, L., Hadji-Lazaro, J., Hurtmans, D., Camy-Peyret, C., Clerbaux, C., and Coheur, P.-F.: Measurements of HCl in the volcanic plumes of Calbuco (2015) and Raikoke (2019), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10651, https://doi.org/10.5194/egusphere-egu2020-10651, 2020.

EGU2020-12220 | Displays | AS1.30

Exploiting the characteristics of volcanic lightning for volcano monitoring

Sonja Behnke, Harald Edens, Seda Senay, Diana Swanson, Alexa Van Eaton, David Schneider, Masato Iguchi, and Daisuke Miki

Volcanic lightning measurements are gaining momentum in the volcano monitoring community as a tool to identify when an ash producing eruption has occurred. As a volcanic plume develops from an ash-laden jet to a convective plume, the electrical discharges also evolve, ranging from small “vent discharges” (a few meters in length) and near-vent lightning (tens of meters to kilometers in length) to thunderstorm-like plume lightning (tens of kilometers in length). Currently, volcanic lightning monitoring capabilities for volcano observatories are mainly limited to using long-range lightning sensor networks, which do not detect the full gamut of volcanic lightning due to the networks’ detection efficiency and the radio frequency band that they use (very low frequency or low frequency). This biases the sensors towards detecting only the larger volcanic lightning discharges that occur at later stages in plume development, which can result in detection delays of minutes to tens of minutes from the onset of eruption. In addition to the latency, there is no way to know if the lightning picked up by long range networks is from a volcanic or meteorological source without some other additional source measurement. Both the latency and the source ambiguity could be reduced by using lightning sensors at close range that can detect the very small vent discharges associated with volcanic explosions. Vent discharges occur within the gas thrust region in a plume, starting simultaneously with the onset of an eruption and persisting continually for seconds or tens of seconds, depending on the duration of an eruption. They produce a distinctive ‘continual radio frequency’ signal, of which there is no analogous signature in meteorological lightning. Thus, the characteristics of the radio frequency signature of vent discharges could be exploited to innovate a new sensor design that is both low power and transmits information (i.e., a useful derived data product) at rates low enough to be used at remote volcanoes where volcano monitoring is often sparse. To meet this goal, a new experiment at Sakurajima Volcano in Japan is underway to learn more about the physical characteristics and signal characteristics of vent discharges. We use broadband very high frequency sensors to record time series measurements of the vent discharges and other volcanic lightning discharges that occur from explosions of the Minamidake crater of Sakurajima. These measurements reveal new information about vent discharges, such as their duration and spectral features, that can be used to help identify when explosive eruptions are occurring.

How to cite: Behnke, S., Edens, H., Senay, S., Swanson, D., Van Eaton, A., Schneider, D., Iguchi, M., and Miki, D.: Exploiting the characteristics of volcanic lightning for volcano monitoring, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12220, https://doi.org/10.5194/egusphere-egu2020-12220, 2020.

EGU2020-14040 | Displays | AS1.30

Control of ice and ash particles on electrical discharges in experimental volcanic jets

Corrado Cimarelli, Kimberly Genareau, Sönke Stern, Caron Vossen, and Donald B. Dingwell

EGU2020-15177 | Displays | AS1.30

The airport-sCAle seveRe weather nowcastinG prOject (CARGO)

Riccardo Biondi, Pierre-Yves Tournigand, Enrico Solazzo, Eugenio Realini, Corrado Cimarelli, and Sebastian Kauczok

Monitoring and predicting extreme atmospheric events, such as deep convective systems, is very challenging especially when they develop locally in a short time range. Despite the great improvement in model parametrization and the use of satellite measurements, there are still large uncertainties on the knowledge of the dynamical processes of deep convective systems at local scale.

We use an innovative approach integrating a dense network of in situ measurements and satellite-based observations/products for the improvement of meteorological nowcasting at airport spatial scale focusing on the Malpensa airport (Italy). We add to the standard atmospheric parameters analysis, the information of integrated water vapour and lightning spatio-temporal behaviour (potential heavy rain precursors) during heavy rain phenomena detected by meteorological radars. The study is based on the anomaly of each atmospheric parameter during a convective event in comparison to its climatology in non-pre-convective environment, so that we are able to detect the variation with respect to the “standard” conditions. The ground based GNSS receivers (allowing the determination of the integrated water vapour trend before and during the storm), together with the lightning detectors, the weather stations (providing the trend of temperature, humidity and wind fields), the radiosondes and the GNSS radio occultations (allowing the estimation of vertical profiles of temperature, pressure and humidity) provide information on the pre-convective and non-pre-convective environment as a 3D picture of the atmospheric conditions.

The final goal is the test of a severe weather events nowcasting algorithm with high spatial resolution, and based on neural networks, for improving aviation safety. This is followed by the development of a user-friendly tailored final product, easily understandable by the Air Traffic Management stakeholder.

We have collected more than 600 cases suitable to develop the neural network algorithm. We show here the algorithm implementation and the meteorological characterization of deep convection usually developing on the Malpensa airport area.

How to cite: Biondi, R., Tournigand, P.-Y., Solazzo, E., Realini, E., Cimarelli, C., and Kauczok, S.: The airport-sCAle seveRe weather nowcastinG prOject (CARGO), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15177, https://doi.org/10.5194/egusphere-egu2020-15177, 2020.

EGU2020-15249 | Displays | AS1.30

A yellow SWIM service dedicated to aviation and ATM by providing early warnings of volcanic SO2 layer height from TROPOMI and IASI sensors

Hugues Brenot, Nicolas Theys, Scott Wilson, Rory Clarkson, Lieven Clarisse, Adam Durant, Giuseppe Salerno, Stefano Corradini, Riccardo Biondi, Klaus Sievers, Christophe Lerot, Jeroen van Gent, Sheri Smith, and Michel Van Roozendael

Volcanic ash and gas is, like sulphur dioxide (SO2), a major risk for air traffic. To mitigate this risk and to improve situational awareness for air traffic management (ATM), we describe a new service using the SWIM (System Wide Information System Management) Yellow Profile – see https://www.eurocontrol.int/publication/eurocontrol-specifications-system-wide-information-management-swim – and aligned with the ATM Information Reference Model (AIRM) as required.

This new service provides early warnings of volcanic SO2 layer height (SO2LH) retrievals from 3 satellite instruments (TROPOMI on board S5P, and IASI-A&-B on board MetOp-A&B). The implementation of this service is enveloped in the framework of OPAS – Operational alert Products for ATM via SWIM – project, a KTN (Knowledge Transfer Network) Engage Catalyst funded project (Thematic Challenge 3; https://engagektn.com) of SESAR JU (Single European Sky ATM Research Joint Undertaking; https://www.sesarju.eu).

We present the TROPOMI SO2LH algorithm and the uses of inverse modelling and external observations from satellites and ground-based DOAS-FLAME instruments to validate TROPOMI SO2LH products for recent eruptions (i.e. Etna in Dec. 2018, Raikoke in June 2019, Ubinas in July 2019, Taal in January 2020). Cross-comparison with the satellite instruments CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization), IASI (Infrared Atmospheric Sounder Interferometer) and with GNSS (Global Navigation Satellite System) radio-occultations, is shown. 

This study will describe the specification of our SWIM service and highlight the point of view of an engine constructor (Rolls-Royce) directly in relation with airlines and ATM, with regard to the objectives of the APOS project. Note that due to engine susceptibility to aerosols, the avoidance of flights through volcanic plumes and SO2 clouds is critical.

The development of our new SO2LH products from TROPOMI contributes to an existing early warning system, so called SACS (Support to Aviation Control Service; http://sacs.aeronomie.be). This system is dedicated to support aviation and ATM, and was recently upgraded in the frame of EUNADICS-AV project (European Natural Airborne Disaster Information and Coordination System for Aviation; http://www.eunadics.eu), with many other alert products related to natural airborne hazard affecting air traffic (e.g. volcanic ash column and layer height, smoke from forest fires and desert dust).

How to cite: Brenot, H., Theys, N., Wilson, S., Clarkson, R., Clarisse, L., Durant, A., Salerno, G., Corradini, S., Biondi, R., Sievers, K., Lerot, C., van Gent, J., Smith, S., and Van Roozendael, M.: A yellow SWIM service dedicated to aviation and ATM by providing early warnings of volcanic SO2 layer height from TROPOMI and IASI sensors, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15249, https://doi.org/10.5194/egusphere-egu2020-15249, 2020.

EGU2020-18682 | Displays | AS1.30

Strength of TROPOMI observations on the retrieval of SO2 emissions at high temporal resolution from space

Abhinna Behera, Marie Boichu, and François Thieuleux

The adverse impact of volcanic gas and aerosol emission on global climate, air quality and ecosystem is well recognized. A better-refined knowledge of volcanic degassing mechanism and its interaction with the atmospheric environment can lead further to fill the persisting gaps in understanding well the impact of volcanic activities. The key is to monitor continuously the volcanoes at a global scale bearing also in mind the limitations of ground-based instruments during the ash-rich phase of emission. Thus, the space-borne sensors with a high spatial and temporal as well as spectral resolution are emerged but with complications in detecting low-altitude emissions, which are also limited to 12 h to 24 h of data acquisition frequency. Nonetheless, recently launched TROPOMI spectrometer onboard Sentinel 5P is shown to be a game-changer due to its high spatial and spectral resolution albeit the data acquisition frequency of only 24 h. To make further progress in retrieving high temporal SO2 emission, the contemporary inverse modelling method has already been shown to be promising. The obtained modelled parameters, viz., SO2 flux and altitude of injection, are reasonably compatible with the ground-based and space-borne observations [1] showing its importance in volcano monitoring [2] and towards forecasting large-scale plume dispersal [3]. The current work incorporates this advancing method and investigates a recent special volcanic event that occurred at Ambrym, Vanuatu during December 2018. The uniqueness of this eruption is the rapid shut down of decade long SO2 degassing and lava lake just after the eruption with the emplacement of a major dike [4]. Here, the hourly retrieved SO2 flux and altitude of injection are aimed to put to the fore the striking features of this unmonitored volcanic activity by assimilating the observations from several space-borne sensors.

To do so, the CHIMERE Eulerian chemistry-transport model (CTM) is used to simulate the Ambrym eruption at a large-scale during 13-19 December 2018. Weather Research and Forecast (WRF) model is used to force the meteorological fields in the CTM simulation, while ERA5 reanalysis data are used to force the initial and boundary conditions of the WRF simulation. The modelled SO2 column amount is then co-located with the TROPOMI, OMPS and GOME2 SO2 column amounts, respectively, to perform the inversion to estimate the modelled flux rates and altitude of injection. The high spatial and spectral resolution SO2 data from TROPOMI is shown to reshape significantly the results obtained from the inverse method in comparison to OMPS and GOME2 SO2 data. Furthermore, a proxy to the SO2 flux is then developed from the geostationary HIMAWARI data to validate the inversion results as the time resolution of HIMAWARI data acquisition is every 20 min. This work is further intended to explore more on the fate of sulphate aerosols formed during this eruption at a large-scale.

 

References:

1. Boichu et al., Atmospheric Chemistry and Physics, 15(14):8381–8400, July 2015.

2. Boichu et al., Atmospheric Chemistry and Physics, 13(17):8569–8584, September 2013.

3. Boichu et al., Geophysical Research Letters, 41(7):2637–2643, 2014.

4. Shreve et al., Scientific reports, 9(1):1–13, 2019.

How to cite: Behera, A., Boichu, M., and Thieuleux, F.: Strength of TROPOMI observations on the retrieval of SO2 emissions at high temporal resolution from space, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18682, https://doi.org/10.5194/egusphere-egu2020-18682, 2020.

AS1.32 – Atmospheric Ice clouds observations and modelling

Cirrus clouds in the tropopause region form via two major different pathways, i.e. freezing super-cooled cloud droplets (liquid origin) or nucleating ice crystals at humidities below water saturation (in situ formation). The latter case takes place in the low temperature regime (T<235K) and it is assumed that in this regime homogeneous freezing of supercooled solution droplets (short: homogeneous nucleation) is the dominant formation pathway. For homogeneous nucleation, a nucleation rate has been derived from laboratory experiments, based on water activity. The formulation of the nucleation rate is reassessed and simple but robust approximations are presented, which can be used in less complex models without a direct interaction with aerosols. The impact of nucleation rates and the formulation of diffusional growth for idealized nucleation rates is investigated. It can be found that the absolute value of the nucleation rate has almost no impact on the produced ice crystal number concentrations, whereas the steepness of the rate is much more important. Finally, it turns out that the formulation of diffusional growth affects nucleation events crucially in terms of produced ice crystal numbers.

How to cite: Spichtinger, P.: Impact of nucleation rates and diffusional growth on ice nucleation events, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19884, https://doi.org/10.5194/egusphere-egu2020-19884, 2020.

EGU2020-13448 | Displays | AS1.32

Modelling mixed-phase clouds with large-eddy model UCLALES-SALSA

Jaakko Ahola, Hannele Korhonen, Juha Tonttila, Sami Romakkaniemi, Harri Kokkola, and Tomi Raatikainen

We have extended the large-eddy model UCLALES-SALSA (Tonttila et al., 2017) to include formation of ice and mixed-phase clouds. The model has exceptionally detailed aerosol description for both aerosol number and chemical composition. We confirmed the accuracy of newly implemented ice microphysics with a comparison to a previous mixed-phase cloud model intercomparison study.

In a further simulation the model captured the typical layered structure of Arctic mixed-phase clouds: a liquid layer near cloud top and ice within and below the liquid layer. The simulation also demonstrated how larger droplets froze first. Moreover, the simulation showed realistic freezing rates of droplets within the vertical cloud structure. These characteristics were possible to capture with a heterogeneous ice nucleation scheme, where also ice nucleating particles (INP) are prognosed. Here, dust containing particles acted as INPs.

The prognostic simulation showed the importance of the self-adjustment of ice nucleation active particles. This is in good agreement with an observational study where resilient mixed-phase clouds are seen together with relatively high ice nuclei concentrations.

The implemented detailed sectional ice microphysics with prognostic aerosols is essentially important in reproducing the characteristics of mixed-phase clouds. The manuscript of this study is submitted for publication.

How to cite: Ahola, J., Korhonen, H., Tonttila, J., Romakkaniemi, S., Kokkola, H., and Raatikainen, T.: Modelling mixed-phase clouds with large-eddy model UCLALES-SALSA, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13448, https://doi.org/10.5194/egusphere-egu2020-13448, 2020.

We present a simulated simultaneous retrieval of mass mean cloud ice particle effective diameter, ice water content, water vapor, and temperature profiles using a combination of a 94-GHz cloud radar and multi-frequency (118, 183, 240, 310, 380, 664, and 850 GHz) millimeter- and submillimeter-wave radiometers from a space platform. The retrieval capabilities and uncertainties of the combined radar and microwave radiometers are quantified. We show that this combined active and passive remote sensing approach with SmallSat technologies addresses a gap in the current state-of-the-art remote sensing measurements of ice cloud properties, especially deriving vertical profiles of ice cloud particle sizes in the atmosphere together with the ambient thermodynamic conditions. Therefore, this new approach can serve as a plausible candidate for future missions that target cloud and precipitation processes to improve weather forecasts and climate predictions.  

How to cite: Jiang, J., Su, H., Yue, Q., and Kangaslahti, P.: Simulation of remote sensing of clouds and humidity from space using a combined platform of radar and multi-frequency microwave radiometers , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20864, https://doi.org/10.5194/egusphere-egu2020-20864, 2020.

EGU2020-12599 | Displays | AS1.32

Characterizing secondary ice production events in mixed-phase clouds using ground-based polarimetric radar

Nicholas Kedzuf, J. Christine Chiu, Venkatachalam Chandrasekar, and Christopher Westbrook

Secondary ice production processes are widely proposed as the pathway by which observed cloud ice number concentration can markedly exceed what is expected from primary ice nucleation alone. These processes play a critical, yet poorly constrained, role in the lifecycle of mixed-phase clouds. Presently, main constraints on secondary ice production come from airborne observations, but the transiency of such observations makes it difficult to paint a complete picture of these processes. Here, we develop a novel method for retrieving ice number concentration in a Lagrangian reference frame, allowing us to unearth information not accessible from existing aircraft observations. Our retrieval method employs an iterative ensemble approach, advanced ice crystal models, and the traditional suite of polarimetric radar observables. We will present examples from the Atmospheric Radiation Measurement (ARM) program Mobile Facility deployment in Finland and evaluations against in-situ observations from the UK Parameterizing Ice Clouds using Airborne obServationS and triple-frequency dOppler radar data (PICASSO) field campaign. We will also present a climatology of cloud ice number concentration from the Finland campaign, shedding light on the spatiotemporal evolution, process rates, and trigger requirements of secondary ice production events.

How to cite: Kedzuf, N., Chiu, J. C., Chandrasekar, V., and Westbrook, C.: Characterizing secondary ice production events in mixed-phase clouds using ground-based polarimetric radar, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12599, https://doi.org/10.5194/egusphere-egu2020-12599, 2020.

EGU2020-13353 | Displays | AS1.32

Lidar measurement of cirrus at Palau Island (7°N 134°E)

Francesco Cairo, Marcel Snels, Andrea Scoccione, Mauro De Muro, Luca Di Liberto, Stefano Ghisu, Ajil Kottayl, Bernard Legras, and Silvia Bucci

Lidar measurement of cirrus at Palau Island (7°N 134°E)

Francesco Cairo [1], Marcel Snels [1], Andrea Scoccione [1,2], Mauro De Muro [1,3], Luca Di Liberto [1], Stefano Ghisu [4], Ajil Kottayl [5], Bernard Legras [6], Silvia Bucci [6].

[1] Institute of Atmospheric Sciences and Climate, ISAC-CNR, Rome, Italy

[2] Now at: Centro Operativo per la Meteorologia, Aeronautica Militare, Pomezia, Italy

[3] Now at: AIT Thales Alenia Space, Roma, Italy

[4] Università degli Studi di Roma "Tor Vergata", Dipartimento di Fisica, Roma, Italy

[5] Cochin University of Science and Technology, CUSAT, Cochin, India

[6] Laboratoire de Météorologie Dynamique, LMD-CNRS, Paris, France

A polarization diversity elastic backscatter lidar has been deployed in the equatorial island of Palau in Feb- Mar 2016. The system operated unattended in the Atmospheric Observatory of Palau Island, from 15 February to 25 March 2016, working automatically 8 hrs per night, delivering 3650 atmospheric profiles (5 min average). Each profile extends from 1 to 30 km height. Here the dataset is presented and discussed in terms of the temperature structure of the UTLS, as derived from co-located PTU soundings. During the timeframe of the campaign it was found that the main convective outflows peaks roughly 3 km below the Cold Point Tropopause, its occurrence associated with cold anomalies in the upper troposphere (UT). When warm UT anomalies occur, presence of particles is restricted to a 5 km wide layer centered 5 km below the CPT. Particles have been detected also slightly above the CPT. These particles are depolarizing, with depolarization values generally lower than those encountered in the TTL. Results show a correlation between presence of optically detectable particles and cold anomalies above the Cold Point. A backtrajectory analysis coupled with satellite observation of convective activity was performed, in order to link the presence of cirrus with their convective origin and inferred lifetime, or possibly with in-situ formation processes. 

How to cite: Cairo, F., Snels, M., Scoccione, A., De Muro, M., Di Liberto, L., Ghisu, S., Kottayl, A., Legras, B., and Bucci, S.: Lidar measurement of cirrus at Palau Island (7°N 134°E), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13353, https://doi.org/10.5194/egusphere-egu2020-13353, 2020.

EGU2020-6733 | Displays | AS1.32

On the Dependence of Cirrus Parametrizations on the Cloud Origin

Thomas Kuhn, Veronika Wolf, and Martina Krämer

Particle size distributions (PSDs) for cirrus clouds are important for both climate models as well as many remote sensing retrieval methods. Therefore, PSD parametrizations are required. This study presents parametrizations of Arctic cirrus PSDs. The dataset used for this purpose originates from balloon-borne measurements carried out during winter above Kiruna (Sweden), i.e. north of the Arctic circle. The observations are sorted into two types of cirrus cloud origin, either in-situ or liquid. The cloud origin describes the formation pathway of the ice particles. At temperatures below −38 °C, ice particles form in-situ from solution or ice nucleating-aerosol particles. Liquid origin ice particles have formed at temperatures warmer than or equal to −38 °C, either via ice-nucleating particles embedded in liquid drops or via homogeneous drop freezing, and are then further uplifted to the cirrus temperature regime.

In order to derive parametrizations for each cloud origin, the observed PSDs are represented by gamma functions. The gamma coefficients exhibit large differences with regard to cloud origin. Functions describing the relationships in between the gamma coefficients and with temperature are fitted. These functions for Arctic cirrus confirm established parametrizations for continental cirrus sorted by two particle size modes but differ from others depending only on temperature. We suppose that the agreement between the parametrizations of the geographically different cirrus is because in-situ and liquid origin cirrus also distinguish by particle size modes. Since cloud sorting by their origin is based on physical processes that are independent of geographical region, we further hypothesize that these cloud-type-based parametrizations might be generally valid for use in global models and satellite retrievals, given the distribution of the cloud types is known.

How to cite: Kuhn, T., Wolf, V., and Krämer, M.: On the Dependence of Cirrus Parametrizations on the Cloud Origin, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6733, https://doi.org/10.5194/egusphere-egu2020-6733, 2020.

EGU2020-12982 | Displays | AS1.32

A Microphysics Guide to Cirrus -- Part II: Climatologies of Clouds and Humidity from Observations

Martina Krämer and Christian Rolf and the Cirrus Guide II Team

This study presents airborne in-situ and satellite remote sensing climatologies of cirrus clouds and humidity. The climatologies serve as a guide to the properties of cirrus clouds, with the new in-situ data base providing detailed insights into boreal mid-latitudes and the tropics, while the satellite-borne data set offers a global overview.

To this end, an extensive, quality checked data archive, the Cirrus Guide II in-situ data base, is created from airborne in-situ measurements during 150 flights in 24 campaigns. The archive contains meteorological parameters, IWC, Nice, Rice , RHice and H2O (IWC: ice water content, Nice: number concentration of ice crystals, Rice : ice crystal mean mass radius, RHice: relative humidity with respect to ice, H2O: water vapor mixing ratio) for each of the flights. Depending on the specific parameter, the data base has extended by about a factor of 5-10 compared to the previous studies of Schiller et al. (2008), JGR, and Krämer et al. (2009), ACP.

An important step in completing the Cirrus Guide II is the provision of the global cirrus Nice climatology, derived by means of the retrieval algorithm DARDAR-Nice from 10 years of cirrus remote sensing observations from satellite. The in-situ data base has been used to evaluate and adjust the satellite observations.

A specific highlight of the study is the in-situ observations of tropical tropopause layer (TTL) cirrus and humidity in the Asian monsoon anticyclone and the comparison to the surrounding tropics.

How to cite: Krämer, M. and Rolf, C. and the Cirrus Guide II Team: A Microphysics Guide to Cirrus -- Part II: Climatologies of Clouds and Humidity from Observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12982, https://doi.org/10.5194/egusphere-egu2020-12982, 2020.

EGU2020-17971 | Displays | AS1.32

Satellite-based estimate of the climate forcing due to aerosol - ice cloud interactions

Odran Sourdeval, Edward Gryspeerdt, Johannes Mülmenstädt, Martina Krämer, and Johannes Quaas

Substantial efforts have been led over the last decades to improve our understanding of the interactions between clouds and anthropogenic aerosols (aci). The effective radiative forcing associated with these interactions (ERFaci), which combines the radiative forcing (i.e. Twomey effect) and cloud adjustments, still constitutes a large part of our current uncertainties on climate predictions.

Important progress has been made in the assessment of ERFaci for liquid clouds, partly due to advances in the joint use of satellite and modelling data to tackle this problem. More particularly, the retrieval of the droplet number concentration from satellite remote sensing - a property closely related to droplet nucleation processes - has been extremely helpful to better quantify ERFaci. However, similar estimations for ice clouds have for long suffered from a lack of observational constraint on the ice crystal number concentration (Ni), a challenging task due to the high complexity of the physical processes associated with the nucleation and growth of ice crystals. However, a novel long-term global dataset of Ni from active satellite measurements has recently (DARDAR-Nice) opened the door to new observation-based estimates of RFaci for ice clouds.

This study investigates aerosol - ice clouds interactions using Ni profiles from the DARDAR-Nice product together with collocated aerosol information from the Copernicus Atmospheric Monitoring Service (CAMS) reanalyses. A multitude of cloud regimes, subdivided into seasonal and regional bins, are considered in order to disentangle meteorological effects from the aci signature. First results of joint-histograms between Ni and the aerosol mass show an overall positive sensitivity of Ni to the aerosols load. This response is particularly strong towards to cloud-top and flattens towards cloud-base, consistently with expectations for ice nucleation processes. In terms of adjustments, the relation between IWP and Ni is also investigated. Preliminary results suggest a slightly negative global ERFaci for ice clouds, with important regional variations, but a precise quantifications of these effects will require further statistics.

How to cite: Sourdeval, O., Gryspeerdt, E., Mülmenstädt, J., Krämer, M., and Quaas, J.: Satellite-based estimate of the climate forcing due to aerosol - ice cloud interactions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17971, https://doi.org/10.5194/egusphere-egu2020-17971, 2020.

EGU2020-8953 | Displays | AS1.32

Satellite observations of cirrus clouds in the lower stratosphere

Ling Zou, Sabine Griessbach, Lars Hoffmann, Bing Gong, and Lunche Wang

While cirrus cloud are frequently observed by ground-based lidars in the lowermost stratosphere, evidence from satellite observations is less conclusive. Following previous studies, we extracted information on stratospheric cirrus clouds from the latest version of Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) data (V4) and the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) data to investigate their global distribution and occurrence frequencies. The detection of stratospheric cirrus with MIPAS is particularly challenging because of the broad field-of-view of the instrument and presented here for the first time.

For the identification of stratospheric cirrus clouds, precise information on both, the cloud top height (CTH) and the tropopause height are crucial. The tropopause heights we derived from ERA-Interim using the WMO criterion for the first thermal tropopause. As tropopause from ERA-Interim show ~0.3km bias with GPS data and CALIPSO data are reported on a ~0.2 km vertical grid, we considered cirrus clouds with CTHs 0.5 km above the tropopause as being stratospheric. We focus on nighttime CALIPSO measurements because of their higher sensitivity. MIPAS measurements are known to overestimate CTHs of optically thick clouds and underestimate the CTHs of optically thin clouds. For the detection of stratospheric cirrus, we started 0.75 km above the tropopause, which is the average CTH overestimation by MIPAS found in previous studies. The comparison with the CALIPSO statistics showed that in the tropics the MIPAS stratospheric cirrus cloud occurrence frequency were slightly larger than for CALIPSO. Assuming that this is due to MIPAS overestimating the CTH, for MIPAS we increased the minimum distance of the CTH to the tropopause until the occurrence frequencies of both measurements agreed.

In the tropics, a four-year mean global analysis of stratospheric cirrus clouds from CALIPSO showed high occurrence frequencies (max. >32%) over the western Pacific Ocean, South Africa, and South America. Stratospheric cirrus clouds were more often detected in December-February than June-August in the tropics. At middle (40-60°) and higher latitudes (>60°), CALIPSO observed about 2% stratospheric cirrus clouds. MIPAS observed about twice as many stratospheric cirrus clouds at northern middle latitudes (>3%) and southern middle latitudes (4%). The maximum differences of nighttime stratospheric cirrus clouds between MIPAS and CALIPSO data were 4-6% over the northern Pacific and 6-8% over the Drake Passage.

Further sensitivity tests with higher average distance to the tropopause for MIPAS resulted in lower occurrence frequencies at middle latitudes. However, they were still larger than the occurrence frequencies derived from CALIPSO data. Hence, we consider the finding of higher stratospheric cirrus cloud occurrence frequencies at middle latitudes by MIPAS as robust. One possible explanation for MIPAS finding more stratospheric cirrus clouds at middle latitudes is that MIPAS is more sensitive towards thin cirrus clouds than CALIPSO (nighttime measurements), because of the satellite limb measurement geometry.

How to cite: Zou, L., Griessbach, S., Hoffmann, L., Gong, B., and Wang, L.: Satellite observations of cirrus clouds in the lower stratosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8953, https://doi.org/10.5194/egusphere-egu2020-8953, 2020.

Ice cloud particle size is important to determining ice cloud radiative effect and precipitating rate. However, there is a lack of accurate ice particle effective radius (Rei) observation on the global scale and the parameterization of Rei in climate models is poorly constrained. We conduct a modeling study to assess the sensitivity of climate simulations to Rei. Perturbations to Rei are represented in ice fall speed parameterization and radiation scheme, respectively, in NCAR CESM1 model with a slab ocean configuration. We show that an increase in ice fall speed due to a larger Rei results in a longwave cooling dominating over a shortwave warming, a global mean surface temperature decrease, and precipitation suppression. Similar longwave and shortwave cloud radiative effect changes occur when Rei is perturbed in the radiation scheme. Perturbing falling snow particle size (Res) results in much smaller changes in the climate responses. We further show that varying Rei and Res by 50% to 200% relative to the control experiment can cause climate sensitivity to differ by +12.3% to −6.2%. A future mission under design with combined multi-frequency microwave radiometers and cloud radar can reduce the uncertainty ranges of Rei and Res from a factor of 2 to ±25%, which would help reducing the climate sensitivity uncertainty pertaining to ice cloud particle size by approximately 60%.

 

How to cite: Su, H., Wang, Y., Jiang, J., Xu, F., and Yung, Y.: Impacts of Ice Cloud Particle Size Uncertainty on Radiation, and Precipitation and Climate Sensitivity and the Significance of Future Satellite-Based Constraints , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5864, https://doi.org/10.5194/egusphere-egu2020-5864, 2020.

Arctic mixed-phase clouds are still not properly represented in weather forecast and climate models. Recent field campaigns in the Arctic have successfully probed low level mixed-phase clouds, however it remains difficult to gain understanding of this complex system from observational datasets alone. Complementary high-resolution simulations, properly constrained by relevant measurements, can serve as a virtual laboratory that provides a deeper insight into a developing boundary layer in the Arctic.


Our study focus on the impact of variability in cloud condensation nuclei (CCN) concentrations on the turbulence in Arctic mixed-phase clouds. Large-Eddy Simulations of convective mixed-phase clouds over open water were performed as observed during the ACLOUD campaign, which took place in Fram Strait west of Svalbard in May and June 2017. The Dutch Atmospheric Large Eddy Simulation (DALES) is used including a well-established double-moment mixed-phase microphysics scheme of Seifert & Beheng.


The results highlight various impact mechanisms of CCN on the boundary layer thermodynamic state, turbulence, and clouds. Lower CCN concentrations generally lead to decreased turbulence near the cloud top. However, they can also enhance the turbulence in the lower part of the boundary layer due to increased amount of sublimation of ice hydrometeors. Further implications for the role of mixed-phase clouds in the Arctic Amplification will be discussed.

How to cite: Chylik, J., Mertes, S., and Neggers, R.: Impacts of Aerosol Concentration Variability on Turbulence in Convective Low Level Mixed-phase Clouds in the Arctic, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18426, https://doi.org/10.5194/egusphere-egu2020-18426, 2020.

EGU2020-11342 | Displays | AS1.32

Assessment of the impact of INP and CCN perturbations on mixed-phase cloud microphysics using a spectral-bin model and reference observations

Junghwa Lee, Patric Seifert, Tempei Hashino, Roland Schrödner, Michael Weger, Fabian Senf, and Oswald Knoth

Ice- and mixed-phase clouds largely contribute to global precipitation due to their high spatiotemporal coverage. It has been highlighted that aerosol-cloud interaction is a critical factor. However, our current understanding of the complexity of their microphysical properties is still rather limited.  

In this talk, we will discuss the impact of perturbations of the cloud condensation nuclei (CCN) and ice-nucleating particle (INP) on the structure and composition of mixed-phase clouds. The main methods are ground-based observations (i.e., Ka-band polarimetric cloud radar) as well as the spectral-bin microphysical methodology called AMPS (Advanced Microphysics Prediction System). Until now, significant efforts have been underway to improve microphysical processes in AMPS, such as the schemes for immersion freezing and habit prediction. Despite these endeavors, it is still challenging using modeling alone to resolve such complexity of microphysical processes due to many parameterizations and assumptions. In particular, the ice habit prediction system in AMPS is sensitive to the 3-D Eulerian advection scheme. Meanwhile, the Doppler-spectra derived from polarimetric cloud radar enables us to retrieve the hydrometeor habit of the significant signal peak in the Doppler spectrum of mixed-phase clouds. The synergy between the above mentioned advanced modeling approach and state-of-the-art observation techniques are in our study used to evaluate the effects of the CCN and INP perturbations on mixed-phase clouds. 

The steps are as follows. First of all, we will present the evaluation of a case study of a mixed-phase cloud by observation data. In the course of the work, AMPS is coupled with the German weather prediction system COSMO (Consortium for Small-scale Modeling) model. We choose an observation dataset from the ACCEPT (Analysis of the Composition of Clouds with Extended Polarization Techniques) field campaign in Cabauw, Netherlands, which was conducted during fall 2014. Also, we use the radar forward operator CR-SIM (Cloud Resolving Model Radar Simulator) that translates the dataset of simulation output into radar variables. Therefore, we will present direct comparisons between ground-based observation and modeling datasets. In the next step, AMPS is coupled with a simple 1-D dynamic core KiD (Kinematic Driver for microphysics intercomparison), so-called KiD-AMPS. In doing so, we will discuss the comparison with other schemes (i.e., Morrison 2-moment). Finally, in the frame of KiD-AMPS, we will debate the impact of the CCN and INP perturbations on mixed-phase clouds. 

How to cite: Lee, J., Seifert, P., Hashino, T., Schrödner, R., Weger, M., Senf, F., and Knoth, O.: Assessment of the impact of INP and CCN perturbations on mixed-phase cloud microphysics using a spectral-bin model and reference observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11342, https://doi.org/10.5194/egusphere-egu2020-11342, 2020.

EGU2020-12018 | Displays | AS1.32

Ice-nucleating Macromolecules from Alpine Forests as Possible Contributors to Cloud Glaciation Processes

Teresa M. Seifried, Paul Bieber, Laura Felgitsch, and Hinrich Grothe

Ice nucleation in the atmosphere leads to the formation of mixed-phase as well as cirrus clouds in the upper troposphere. Cloud glaciation can either occur homogeneously at temperatures below -38°C or heterogeneously in the presence of ice-nucleating particles (INPs) at temperatures higher than -38°C. Depending on the aggregate state of a cloud, it’s life time and radiative properties vary and thus affect regional and global climate. The influence of biogenic INPs on atmospheric processes as well as the transport of these particles from the land surface to the atmosphere remains elusive. Several plants from boreal and alpine forests are known to contain ice-nucleating macromolecules (INMs) to survive in extreme conditions. However, less is known about chemical characteristics and actual emission rates of such INMs.

We present here our investigation of surface extracts from different tree tissues (Betula pendula and Pinus sylvestris). We were able to extract INMs from nearly all samples. Furthermore, we analyzed the ability of these INMs to be released during rain fall events in-situ. To investigate possible transport mechanisms of INMs from the canopy of studied tree species to the atmosphere we sampled aerosols with two small scale drones, carrying our self-build sampling systems called DAPSI (Drone-based Aerosol Particles Sampling Impinger/Impactor). Results indicate that birches and pines outline an important source of airborne biogenic INPs.

How to cite: Seifried, T. M., Bieber, P., Felgitsch, L., and Grothe, H.: Ice-nucleating Macromolecules from Alpine Forests as Possible Contributors to Cloud Glaciation Processes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12018, https://doi.org/10.5194/egusphere-egu2020-12018, 2020.

EGU2020-15857 | Displays | AS1.32

Mineralogy sensitive ice nucleation parameterizations in Dust Regional Atmospheric Model (DREAM)

Luka Ilić, Aleksandar Jovanović, Maja Kuzmanoski, Fabio Madonna, Marco Rosoldi, Eleni Marinou, and Slobodan Ničković

The Sahara Desert is the major source of mineral dust, which is a significant portion of atmospheric aerosol. Mineral dust particles play a role in radiative balance, with a direct effect and by influencing cloud formation and lifetime. They have been recognized as highly efficient ice nuclei, fostering the development of parameterizations for immersion and deposition freezing involving dust particles. Feldspar minerals have shown to be a significantly more efficient ice nucleating agents than other dust minerals which led to the development of a ‘mineralogy sensitive’ immersion freezing parameterization. The investigation of the relative efficiency of quartz compared to feldspars for the immersion ice nucleation, based upon literature data and new experiments, led to the development of a new parameterization to be applied to mineral dust concentrations. Within numerical models, explicit simulation of mineral dust fractions enables the use of ‘mineralogy sensitive’ immersion parameterizations.

The operational DREAM model calculates the number of ice nuclei,but does not take into consideration the mineral composition of dust. In this study, instead, we use DREAM model to simulate the atmospheric cycle of feldspar and quartz fractions of dust. Dust mineral composition is used to calculate ice nucleating particle concentrations based on mineral-specific immersion freezing parameterizations. A case study related to the observations of geometrical and microphysical characteristics of the clouds formed in the Mediterranean, in April 2016 is considered. We compare the model results with ice nucleating particle concentrations retrieved using lidar and radar ground-based remote sensing observations at Cyprus and Potenza. The analysis explores how the mineral composition of dust and the parameterization of its effects on ice initiation could further improve ice nucleation representation in numerical models.

How to cite: Ilić, L., Jovanović, A., Kuzmanoski, M., Madonna, F., Rosoldi, M., Marinou, E., and Ničković, S.: Mineralogy sensitive ice nucleation parameterizations in Dust Regional Atmospheric Model (DREAM), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15857, https://doi.org/10.5194/egusphere-egu2020-15857, 2020.

EGU2020-7996 | Displays | AS1.32

Volcanic impact on cirrus clouds

Moa Sporre, Johan Friberg, Odran Sourdeval, Oscar Sandvik, and Bengt Martinsson

Cirrus clouds have a net warming effect on climate due to their high altitude and low optical thickness. Small changes in their properties may however shift this to a stronger warming or a cooling. Aerosol particles can strongly affect cirrus cloud properties since they can act as ice nuclei (IN) for the ice crystals. How downwelling sulfate aerosols from the stratosphere affect cirrus clouds is highly unknown but important both in terms of volcanic impact on climate and possible geoengineering through sulfate injections in the stratosphere. In this study we investigate how the microphysical properties of cirrus clouds change with aerosol loading in the lowermost stratosphere (LMS). The study is focused on the midlatitudes where the descending air motion in the stratosphere result in aerosol downwelling from the stratosphere to the troposphere. The study is conducted during 11 years (2006 - 2016) when the stratosphere had varying levels of aerosol load due to volcanic eruptions. 

The cirrus clouds are studied using the satellite dataset DARDAR (raDAR/liDAR) which combines data from the CloudSat radar and CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation) lidar. Also the aerosol loading in the LMS is retrieved using a satellite dataset, from CALIPSO (Friberg2018). The first results show that the ice water content of the cirrus clouds decrease when the aerosol loading in the LMS increase. This change occur mainly during spring and autumn for homogeneously frozen cirrus clouds. The results regarding the effective radius of the ice crystals are more uncertain but the effective radius also seem to decrease with increased aerosol loading in the LMS. However, this is mainly seen in the northern hemisphere which has experienced the largest changes in aerosol load due to volcanic eruptions during this period. Also data of ice crystal number concentration are being processed and will be studied to better understand the impact on the cirrus clouds from the downwelling stratospheric aerosol.

References

Friberg, J., Martinsson, B. G., Andersson, S. M., and Sandvik, O. S.: Volcanic impact on the climate - The stratospheric aerosol load in the period 2006-2015, Atmospheric Chemistry and Physics, 18, 11 149–11 169, https://doi.org/10.5194/acp-18-11149-2018, 2018.

How to cite: Sporre, M., Friberg, J., Sourdeval, O., Sandvik, O., and Martinsson, B.: Volcanic impact on cirrus clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7996, https://doi.org/10.5194/egusphere-egu2020-7996, 2020.

AS1.33 – Aerosols, radiation and clouds over the southeast Atlantic

EGU2020-2823 | Displays | AS1.33

The impact of an eastward traveling cut-off low on tropospheric composition and the formation of a river of smoke: a case from AEROCLO-sA

Cyrille Flamant, Marco Gaetani, Jean-Pierre Chaboureau, Patrick Chazette, and Paola Formenti

We investigate the impact of an eastward moving cut-off low (CoL) on the formation of a river of smoke as well as on the vertical distribution of biomass burning aerosols (BBAs) in the troposphere during the Aerosols, Radiation and Clouds in southern Africa (AEROCLO-sA) campaign in September 2017. The CoL developed in the westerlies over the Southeast Atlantic Ocean and advected over southern Africa between 1 and 6 September 2017. Northern Namibia, were most of the AEROCLO-sA related operations took place, was under the influence of a well formed, stationary, isolated CoL on 3 and 4 September. Subsequently, the fast evolving CoL travelled south-eastward over South Africa between 5 and 6 September before merging back with the main westerly flow. Based on the use of a tailored complementary suite of global and mesoscale numerical simulations as well as ground-based, airborne and space-borne observations of the atmospheric dynamics, thermodynamics and composition, the picture emerges that the characteristics of the river of smoke (timing, vertical extent of the BBA layer) are very much tied to the later (fast evolving) stage of the evolution of the CoL than the earlier (stationary) stage.  The mechanisms by which the CoL observed over southern Africa influences the vertical structure of the BBA layer is essentially through the ascending (descending) motion above the BBA layer to the northeast (southwest) of the CoL center. In the presence of the CoL, the top of the BBA layer over northern Namibia was found to reach attitudes in excess of 8 km AMSL. This is much higher that the height of the top of the BBA layer over the regions where the smoke originated from (Angola, Zambia, Zimbabwe, Mozambic) which was between 4 and 5 km AMSL. Also, the CoL favored the formation of mid-level clouds near the top of the BBA layer. Mid-level clouds were embedded in the river of smoke that were related to the circulation and ascending motions in the lee of the CoL.

How to cite: Flamant, C., Gaetani, M., Chaboureau, J.-P., Chazette, P., and Formenti, P.: The impact of an eastward traveling cut-off low on tropospheric composition and the formation of a river of smoke: a case from AEROCLO-sA, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2823, https://doi.org/10.5194/egusphere-egu2020-2823, 2020.

EGU2020-3723 | Displays | AS1.33

Dust and biomass burning aerosol transport in South Atlantic during AEROCLO-sA

Jean-Pierre Chaboureau, Laurent Labbouz, Cyrille Flamant, and Alma Hodzic

We investigate the transport of dust and biomass burning aerosols in South Atlantic during the Aerosols, Radiation and Clouds in southern Africa (AEROCLO-sA) campaign in September 2017. A regional Meso-NH simulation has been run using a 12-km horizontal grid-spacing without deep convection parameterization, an on-line dust emission scheme, a passive tracer of biomass burning aerosol (BBA) emitted using the daily Global Fire Emissions Database and online-computed backward trajectories. The simulation captures both the aerosol optical depth and the vertical distribution of aerosols as observed from airborne and spaceborne lidars. It also reproduces the occurrence of deep convection over Congo and stratocumulus over South Atlantic well. A Lagrangian analysis reveals the origin of aerosols in the South Atlantic. Dust aerosols found just above the stratocumulus were emitted from the coasts and the Ethosha Pan a few days earlier. The BBAs located between 1 and 5 km come mainly from Angola in about 3.5 days. The 8-12 km layer is fed by up to 12 % of the air masses that experienced convection over the Congo Basin in the last 5 days. This amount is much reduced in the sensitivity simulation with a deep convection parameterization.

How to cite: Chaboureau, J.-P., Labbouz, L., Flamant, C., and Hodzic, A.: Dust and biomass burning aerosol transport in South Atlantic during AEROCLO-sA, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3723, https://doi.org/10.5194/egusphere-egu2020-3723, 2020.

EGU2020-3844 | Displays | AS1.33

Chemical composition and characterization of aerosols off Namibia: results from the AEROCLO-sA project

Paola Formenti, Danitza Klopper, Servanne Chevaillier, Barbara D’Anna, Karine Desboeufs, Jean-François Doussin, Anaïs Feron, Chiara Giorio, Marc Daniel Mallet, Cécile Mirande-Brét, Anne Monod, Andreas Namwoonde, Sylvain Triquet, and Stuart Piketh

The western coast of southern Africa off Namibia is characterized by a semi-permanent and widespread stratocumulus (Sc) cloud deck, very frequent coastal fog, and the oceanic northern Benguela upwelling system (nBUS). It is also the crossroad of large quantities of natural and anthropogenic aerosols of distant and local origins (biogenic, anthropogenic, biomass burning, sea salt and mineral dust) from continental and marine sources, with significant differences in terms of physico-chemical and optical properties, water affinity, scale and height of transport, which are not well represented in climate models.

In this presentation we will illustrate the results of the first extensive chemical and microphysical characterisation of aerosol particles in the area that has been conducted since 2016 at  the coastal Henties Bay experimental site (22°6’ S, 14°17’ E) in the framework of the AErosol, RadiatiOn and CLOuds in southern Africa (AEROCLO-sA) and the Atmospheric Research in the Southern Africa and Indian Ocean (ARSAIO) projects.

Synergetic filter sampling and online measurements provide examples of the numerous new particle formation in link with marine biogenic emissions and the apportionment of maritime sulfate aerosols, including their biogenic component.

How to cite: Formenti, P., Klopper, D., Chevaillier, S., D’Anna, B., Desboeufs, K., Doussin, J.-F., Feron, A., Giorio, C., Mallet, M. D., Mirande-Brét, C., Monod, A., Namwoonde, A., Triquet, S., and Piketh, S.: Chemical composition and characterization of aerosols off Namibia: results from the AEROCLO-sA project, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3844, https://doi.org/10.5194/egusphere-egu2020-3844, 2020.

EGU2020-5508 | Displays | AS1.33

A weather regime characterisation of winter biomass aerosol transport in southern Africa

Marco Gaetani, Maria del Carmen Alvarez Castro, Cyrille Flamant, Benjamin Pohl, and Paola Formenti

Atmospheric dynamics over southern Africa and South Atlantic is dominated by complex aerosol-radiation-cloud interactions, and the characterisation of the tropospheric distribution of aerosols is essential for the full understanding of these interactions.

During austral winter, a compact low cloud deck over South Atlantic contrasts clear sky over southern Africa, where forest fires triggered by dry conditions emit large amount of biomass burning aerosols in the free troposphere. Most of the aerosol burden crosses the Tropical Atlantic embedded in the tropical easterly flow. However, mid-latitude synoptic disturbances can deflect part of the aerosols from the main transport path towards southern extra-tropics.

In this study, a characterisation of the synoptic variability controlling biomass burning aerosols in southern Africa and South Atlantic during austral winter is presented. By analysing ECMWF reanalysis data, a weather regime classification of the region is constructed and used to characterise the aerosol distribution in the period 2003-2017. Results show three southward transport paths, each associated with a specific circulation regime.

 

How to cite: Gaetani, M., Alvarez Castro, M. C., Flamant, C., Pohl, B., and Formenti, P.: A weather regime characterisation of winter biomass aerosol transport in southern Africa, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5508, https://doi.org/10.5194/egusphere-egu2020-5508, 2020.

EGU2020-5748 | Displays | AS1.33

Dependence of Cloud and Precipitation Properties over the South-East Atlantic on Aerosol Concentrations Above and Below Clouds

Siddhant Gupta, Greg McFarquhar, Joseph O'Brien, Michael Poellot, and Andrew Dzambo

Instances of contact and separation between biomass-burning aerosols and marine stratocumulus have been observed over the South-East Atlantic Ocean. In-situ measurements of aerosol and cloud properties were made onboard the NASA P-3 aircraft during the ObseRvations of Aerosols above Clouds and their intEractionS ORACLES field campaign in Sep. 2016, Aug. 2017 and Oct. 2018. Variations in vertical profiles of droplet concentration Nc, effective radius Re, and precipitation susceptibility So (change in rain rate R with Nc) as a function of cloud thickness H, were determined for varying above- and below-cloud aerosol concentration Na. The data were sorted into 4 regimes according to whether a prominent aerosol layer (Na > 500 cm-3) was in contact or separated from cloud tops, and whether the clouds occurred within a clean or dirty boundary layer (BL).

The Nc and Re were calculated using the number distribution function n(D) for 3 < D < 1280 μm from the Cloud and Aerosol Spectrometer and the 2D‐Stereo probe. Na was calculated using n(D) for 0.1 < D < 3 μm from the Passive Cavity Aerosol Spectrometer Probe, and rain rate R was derived using droplet mass m(D), fall speed u(D) and n(D) for 50 < D < 1280 μm. Across the 3 campaigns, a total of 359 vertical profiles were flown through clouds and for 181 contact, or C-cases (Na > 500 cm-3 within 100 m above cloud), the mean Nc was 77 cm-3 higher and mean Re 1.78 μm lower, compared to 178 separated, or S-cases (Na < 500 cm-3 within 100 m above cloud). Within clean BLs (Na < 400 cm-3 within 100 m below cloud), mean Nc for C-cases was 42% higher than S-cases. Within dirty BLs (Na > 400 cm-3 within 100 m below cloud), mean Nc for C-cases was 53% higher, and the Nc change increased from 20% near cloud base to 75% near cloud top. Although cloud-top entrainment increased Nc throughout the cloud layer, its effect was weaker (stronger) near cloud base (top) within dirty BLs.

For all data combined, the average So was positive (0.94) implying R decreased with an increase in Nc. For C- and S-cases, the average So was 0.60 and 1.01, respectively, with the difference arising from low So (-0.06) for thin (H < 131 m) C-case clouds. When the thin, C-case clouds were further classified into clean & dirty BL cases, So was 0.67 and -0.57, respectively. Condensational growth is limited by low H in thin clouds and increasing Nc in clean conditions decreased Re, hindering collision-coalescence. However, in dirty conditions with low Re, increasing Nc only increased the number and collision efficiency of small droplets. The mean Nc (average S­o) in the cleanest and dirtiest conditions (S-case & clean BL and C-case & dirty BL) was 84 cm-3 and 206 cm-3 (1.17 and 0.43), respectively. When condensational growth is no longer limited by H, Re decreases with Nc and clean clouds with the highest Re are the most susceptible to precipitation suppression.

How to cite: Gupta, S., McFarquhar, G., O'Brien, J., Poellot, M., and Dzambo, A.: Dependence of Cloud and Precipitation Properties over the South-East Atlantic on Aerosol Concentrations Above and Below Clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5748, https://doi.org/10.5194/egusphere-egu2020-5748, 2020.

EGU2020-7938 | Displays | AS1.33

NaFoLiCA: Synoptic-scale controls of fog and low cloud variability in the Namib Desert

Hendrik Andersen, Jan Cermak, Julia Fuchs, Peter Knippertz, Marco Gaetani, Julian Quinting, Sebastian Sippel, and Roland Vogt

This contribution presents new findings on synoptic-scale mechanisms that control the day-to-day variability of fog and low clouds (FLCs) in the Namib region.
FLCs are a defining element of the Namib-region climate and a crucial source of water for many species and ecosystems. Still, little is known on the processes driving Namib-region FLCs, in large part due to the very sparse observational records. Specifically, there is an ongoing debate in the scientific literature concerning the relevance of different mechanisms responsible for fog formation in the region. In this contribution, a new long-term satellite-based data set of FLC occurrence is used in conjunction with reanalysis data and backtrajectories to systematically analyze dynamical and thermodynamical differences between days with and without FLCs in the central Namib during two different seasons. The main findings are:

  1. Central-Namib FLCs are nearly always associated with the advection of marine-boundary-layer air masses.
  2. The variability of the overall FLC coverage in the central Namib is largely driven by dynamics at the synoptic scale.
  3. Seasonally different synoptic-scale mechanisms determine the probability of the occurrence of FLCs in the central Namib.

The findings lead to a better understanding of Namib-region FLCs and help broaden the understanding of low clouds along the southwestern African coastline and the southeast Atlantic. 

How to cite: Andersen, H., Cermak, J., Fuchs, J., Knippertz, P., Gaetani, M., Quinting, J., Sippel, S., and Vogt, R.: NaFoLiCA: Synoptic-scale controls of fog and low cloud variability in the Namib Desert, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7938, https://doi.org/10.5194/egusphere-egu2020-7938, 2020.

EGU2020-19860 | Displays | AS1.33

Evaluation of next day fog forecast over Namibia using the WRF model

Michael Weston, Stuart Piketh, Paola Formenti, Stephen Brocardo, Hendrik Andersen, and Roland Voogt

The Namibian coast line experiences fog when moist air from the southeast Atlantic is advected
over the desert landscape. We run the WRF model with the Thompson (2008) microphysics scheme,
with a default CCN number concentration of 100 cm-1, to forecast next day fog over the Namib
desert. Model output of liquid water content at the lowest level in the atmosphere is used to
represent fog and is evaluated against in situ observations of visibility and satellite products of
fog/low stratus. Preliminary results indicate that the model captures the spatial pattern of fog
excellently, however, the model over predicts fog occurrence. These results serve as the control run
for a future model sensitivity study.

How to cite: Weston, M., Piketh, S., Formenti, P., Brocardo, S., Andersen, H., and Voogt, R.: Evaluation of next day fog forecast over Namibia using the WRF model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19860, https://doi.org/10.5194/egusphere-egu2020-19860, 2020.

EGU2020-13086 | Displays | AS1.33

Radiative Properties of Aerosols and Clouds from Observations and Models over the Southeast Atlantic
not presented

Ian Chang and the NASA ORACLES Team

The southeast Atlantic serves as a natural laboratory for studying aerosol-cloud-radiation interactions due to the abundant presence of quasi-permanent stratocumulus and overlying biomass burning smoke aerosols during austral winters. Aerosol and cloud properties from the Spectrometers for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) and Solar Spectral Flux Radiometer (SSFR) on board NASA P-3 and High Spectral Resolution Lidar (HSRL) on board NASA ER-2 during the NASA ObseRvations of Aerosols above CLouds and their intEractionS (ORACLES) field campaign are used to compare with satellite retrievals. Aerosol and cloud properties from regional climate models such as WRF-Chem, WRF-Chem (with CAM5), ALADIN, GEOS-CHEM, EAM-E3SM, MERRA-2, and GEOS-5 with aerosol schemes are also compared against airborne measurements and satellite retrievals to evaluate and address the current model deficiencies in the southeast Atlantic. A preliminary estimate of the direct aerosol radiative effects over the southeast Atlantic will be presented.

How to cite: Chang, I. and the NASA ORACLES Team: Radiative Properties of Aerosols and Clouds from Observations and Models over the Southeast Atlantic, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13086, https://doi.org/10.5194/egusphere-egu2020-13086, 2020.

EGU2020-3001 | Displays | AS1.33

Development of convection in a mesoscale cloud system and its effect on the microphysics over the tropical Atlantic Ocean

Zhiqiang Cui, Alan Blyth, Steven Abel, Paul Barrett, and Hamish Gordon

Climate models have large uncertainty to represent the low clouds in the transitional zone from stratocumulus to cumulus clouds. This talk presents an observational study of a mesoscale cloud system near Ascension Island during the CLouds and Aerosol Radiative Impacts and Forcing (CLARIFY) field campaign. Extensive aircraft measurements were made to investigate the cloud microphysics when convection developed in a stratiform cloud system. The aircraft penetrated the clouds at levels below, within, and above the main layer. In-cloud penetrations show that the development of convections increased the drop number concentration, the effective radius of drops, the size of drizzle drops, and liquid water content. In the process of convection development, the morphology of the cloud changed from an overcast stratocumulus system to organised convective clouds. The wind shear and the compensating subsidence associated with the convections seemed to be responsible for the appearance of the system. The results indicate that the convective clouds significantly affected the stratocumulus cloud properties in the transition. Our study of the microphysical processes in the transitional zone helps to improve the representation and evolution of low clouds in models. 

 

How to cite: Cui, Z., Blyth, A., Abel, S., Barrett, P., and Gordon, H.: Development of convection in a mesoscale cloud system and its effect on the microphysics over the tropical Atlantic Ocean, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3001, https://doi.org/10.5194/egusphere-egu2020-3001, 2020.

Due to the wide spread nature of marine stratocumulus cloud they have a significant impact on the Earth’s radiation budget. Such clouds are sensitive to the presence of aerosol, which can promote the break-up of a cloud deck into pockets of open cell convection (POC). The transition from a cloud deck to pockets of open cells changes the overall cloud albedo thus affecting the Earth’s radiation budget. The representation of stratocumulus cloud and the transition to POCs is poorly represented in current climate and weather models. This study aims to improve understanding of this process using extensive in-situ measurements made during the CLARIFY campaign of stratocumulus cloud decks, transition areas between overcast and open cell cloud structures as well as areas of POCs, to inform and compare to large-eddy simulations.

A variety of different aerosol situations occurred during CLARIFY, combinations of polluted/clean boundary layer and polluted/clean conditions above the cloud layer. Large-eddy simulations are conducted to investigate the sensitivity of clouds to changes in the observed aerosol conditions with a particular focus on whether or not the change in aerosol initiates cloud breakup.

The MetOffice NERC Cloud model (MONC) is used to preform the large-eddy simulations and employs the CASIM cloud microphysics scheme which includes activation of aerosol particles to cloud drops. Such a model set-up allows direct interaction between aerosols and clouds. Observations from CLARIFY are used to initialise and evaluate model simulations.

How to cite: Simpson, E. and Choularton, T.: Modelling study on the formation of pockets of open cells in marine stratocumulus cloud during CLARIFY, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16043, https://doi.org/10.5194/egusphere-egu2020-16043, 2020.

AS1.34 – Joint Session of the MLT and the VarSITI-ROSMIC program

In the last decade, it was shown that volume emission rates (VMR) for transitions from the levels O2(b1Σ+g, v’ = 0 – 2) to the levels O2(X3Σ-g, v’’) can be used as proxies for retrieving the altitude profiles of [O(3P )], [O3] and [CO2] in the mesosphere and lower thermosphere (MLT) [1, 2]. Despite the fact that, in single experiments, radiation in the bands 762, 688, and 628 nm corresponding to the abovementioned transitions were observed (e. g., [3]), no systematic measurements of the intensities of these emissions have yet been performed. The main source of excitation of the levels O2(b1Σ+g, v’ = 0 – 2) is the energy transfer from the excited O(1D) atom, along with the resonant absorption of solar radiation in these bands in the mesosphere.

In the framework of the YM2011 model of electronical-vibrational kinetics of the excited products of O2 and O3 photolysis, using systematic SABER satellite experimental data on the [O (1D)] altitude profiles we calculated the altitudinal-latitudinal distributions of the O2(b1Σ+g, v’ = 0 – 2) concentrations  and VMR in the corresponding bands, using the 2010 data as an example. It was shown that there is a seasonal dependence of the altitude profiles of the concentrations of excited states O2(b1Σ+g, v’ = 0 – 2) obviously related to the seasonal changes of [O(3P)] and [O3] profiles.

This work was supported by the Russian Foundation for Basic Research  (grant RFBR No. 20-05-00450 A).

1. Yankovsky V. A., Martyshenko K. V., Manuilova R. O., Feofilov A. G. (2016), Oxygen dayglow emissions as proxies for atomic oxygen and ozone in the mesosphere and lower thermosphere, Journal of Molecular Spectroscopy, 327, 209-231, doi:10.1016/j.jms.2016.

2. Yankovsky V. A., Vorobeva E. V., Manuilova R. O. (2019), New techniques for retrieving the [O(3P)], [O3] and [CO2] altitude profiles from dayglow oxygen emissions: Uncertainty analysis by the Monte Carlo method, Advances in Space Research, 64, 1948–1967, https://doi.org/10.1016/j.asr.2019.07.020

3. Torr M. T., Torr D. G. (1985), A Preliminary Spectroscopic Assessment of the Spacelab 1/Shuttle Optical Environment, J. Geophys. Res. A 90, 1683–1690, https://doi.org/10.1029/JA090iA02p01683.

How to cite: Manuilova, R. and Yankovsky, V.: Seasonal-latitudinal distributions of the populations of the states O2(b1, v = 0 - 2) in the daytime mesosphere and lower thermosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-55, https://doi.org/10.5194/egusphere-egu2020-55, 2020.

EGU2020-2150 | Displays | AS1.34

The Unusual Intensity Pattern of OH(6,2) and O(1S) Airglow Observed Over the Andes Lidar Observatory
not presented

Tai-Yin Huang, Yolián Amaro-Rivera, Fabio Vargas, and Julio Urbina

Simultaneous observations of OH(6,2) and O(1S) nightglow at the Andes Lidar Observatory (ALO) from September 2011 to April 2018 have been analyzed to investigate an unusual intensity pattern showing an O(1S) nightglow intensity enhancement concurrent with an OH(6,2) nightglow intensity weakening. About 142 nights have been identified in the time period showing a remarkable biannual occurrence rate with maxima during the equinoxes. A semidiurnal (12-h) tide fitting applied to the 30-min bin size monthly averaged data shows that the largest amplitudes of the semidiurnal tide were observed for the months of April and August-October in the OH(6,2) data and April and September in the O(1S) data. It was also found that SABER’s atomic oxygen at the O(1S) peak height is 1.3-2.5 times higher during the nights that displayed the unusual intensity pattern. Simulations using the nonlinear, time-dependent, OH Chemistry Dynamics (OHCD) and Multiple Airglow Chemistry Dynamics (MACD) models have also been used to investigate the effect of a long-period wave on the OH(6,2) and O(1S) airglow intensities. The simulation results are in good agreement with the observations and replicate the unusual intensity pattern observed in the OH(6,2) and O(1S) airglow data.

How to cite: Huang, T.-Y., Amaro-Rivera, Y., Vargas, F., and Urbina, J.: The Unusual Intensity Pattern of OH(6,2) and O(1S) Airglow Observed Over the Andes Lidar Observatory, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2150, https://doi.org/10.5194/egusphere-egu2020-2150, 2020.

EGU2020-2485 | Displays | AS1.34

The atmospheric water vapor retrieved by OH(8-3) band airglow from astronomical observations

Weijun Liu, Jiyao Xu, Jianchun Bian, Xiao Liu, Wei Yuan, and Chi Wang

Water vapor in the atmosphere is an important trace gas, and seriously affects the ground-based astronomical observations due to water vapor attenuation and emission. It is significant to correct the effects of water vapor along the line-of-sight of astronomical target in real time. Here, we discuss a method to retrieve the precipitable water vapor (PWV) from the OH(8-3) band airglow spectrum. The pressure, temperature and water vapor profiles determine the effective absorption cross-section in PWV retrieval, so a simple and effective method of the effective absorption cross-sections using profiles from a standard atmosphere model is discussed. The Monte Carlo simulations are used to estimate the PWV retrieval. Besides, the PWV is calculated using the sky nightglows from UVES and is compared to that from the standard star spectra of UVES observed from 2000 to 2016. The results indicate that The PWV derived from OH(8-3) spectra is in good agreement with that retrieved from UVES standard star equivalent width and the averaged difference between the two is 0.66 mm. The regression result indicates that the slope α=1.06 +/-0.03 and the correlation coefficient is r=0.87. Because the sky emission spectra and the astronomical target are observed at the same time and along the same line-of-sight, the method of PWV retrieved by OH(8-3) band spectra provides a quick and economical means of correcting the effects if water vapor on ground-based astronomical observations locally, in real-time, and along the line-of-sight of astronomical observations.

How to cite: Liu, W., Xu, J., Bian, J., Liu, X., Yuan, W., and Wang, C.: The atmospheric water vapor retrieved by OH(8-3) band airglow from astronomical observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2485, https://doi.org/10.5194/egusphere-egu2020-2485, 2020.

EGU2020-3169 | Displays | AS1.34

Properties of OH roto-vibrational level populations in the Earth's mesopause region

Stefan Noll, Holger Winkler, Oleg Goussev, and Bastian Proxauf

Chemiluminescent OH airglow emission dominates the nighttime radiation of the Earth's atmosphere in the near-infrared wavelength regime. It is an important indicator of the state and variability of the mesopause region at about 90 km. However, the interpretation of the line intensities suffers from uncertainties in the knowledge of the complex roto-vibrational level population distribution, which is far from local thermodynamic equilibrium (LTE). For a better understanding, we investigated these populations in detail mainly based on a high-quality high-resolution mean spectrum from the UVES echelle spectrograph at Cerro Paranal in Chile, which allowed us to measure about 1,000 individual lines including numerous resolved Λ-doublet components between 560 and 1060 nm. As the quality of the currently available sets of OH Einstein-A coefficients is not sufficient for accurate population retrievals, we derived an improved set by a semi-empirical approach, which benefited from the measurement of multiple lines with the same upper level. The resulting populations indicate a clear bimodality for each vibrational level, which is characterised by a cold component indicating the ambient temperature at the OH layer heights and a hot non-LTE component dominating high rotational levels. Our promising two-population fits allowed us to constrain the non-LTE contributions to rotational temperatures based on lines with upper states with low rotational and fixed vibrational quantum number, which are widely used to estimate temperatures in the mesopause region. The bimodality is also clearly indicated by the different population changes depending on the effective altitude of the OH emission layer. Only the cold component significantly decreases with increasing altitude. Our results will be very useful for the challenging modelling of the OH thermalisation process.

How to cite: Noll, S., Winkler, H., Goussev, O., and Proxauf, B.: Properties of OH roto-vibrational level populations in the Earth's mesopause region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3169, https://doi.org/10.5194/egusphere-egu2020-3169, 2020.

EGU2020-2878 | Displays | AS1.34

Orographic gravity waves in OH-airglow imaging systems

Sabine Wüst, Jonas Till, René Sedlak, Patrick Hannawald, Carsten Schmidt, Samo Stanič, and Michael Bittner

Atmospheric dynamics is strongly influenced by waves on different scales. Airflow over mountains can lead to all kinds of atmospheric waves, planetary and gravity waves as well as infrasound. Under certain circumstances these waves can propagate through the atmosphere and lead to a re-distribution of energy.

In the case of gravity waves, a stably stratified atmosphere is a mandatory requirement for their generation and vertical propagation. Additionally, the vertical propagation depends on the horizontal wind field.

In the Alpine and pre-Alpine region, we currently operate five OH-airglow imaging systems, which allow the investigation of orographic gravity waves. Depending on tropo-, strato- and mesospheric wind and temperature, it is checked which wavelengths can propagate into the fields of view of our instruments. This is done for a whole year in order to take into account annual and semi-annual cycles in wind and temperature.

Concerning the generation of gravity waves, we put our focus on our OH-airglow imager (FAIM) deployed at Otlica (45.9°N, 13.9°E), Slovenia. Here, we also have additional measurements of an OH-airglow spectrometer (GRIPS). In case studies, we investigate whether strong wind events (Bora) lead to strong gravity waves activity or enhanced potential energy density.

This work received funding from the Bavarian State Ministry of the Environment and Consumer Protection.

How to cite: Wüst, S., Till, J., Sedlak, R., Hannawald, P., Schmidt, C., Stanič, S., and Bittner, M.: Orographic gravity waves in OH-airglow imaging systems, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2878, https://doi.org/10.5194/egusphere-egu2020-2878, 2020.

EGU2020-3609 | Displays | AS1.34

Influence of atmospheric winds and tides on the propagation direction of mesospheric gravity waves observed in OH airglow in the Alpine region

Patrick Hannawald, Sabine Wüst, Michael Bittner, Friederike Lilienthal, and Christoph Jacobi

Atmospheric gravity waves transport energy and momentum trough the different atmospheric layers from the troposphere up to the mesosphere and above. On the one hand this transport has influence on atmospheric circulation patterns and drives for example the meridional circulation in the mesosphere. On the other hand the prevailing wind field selectively influences the vertical propagation conditions of gravity waves of different phase speed and horizontal propagation direction.

The OH-airglow layer at ca. 86 km altitude (upper mesosphere / lower thermosphere, UMLT) is well-suited for the investigation of atmospheric dynamics, allowing continuous observations of the night-sky throughout the year. Especially, atmospheric gravity waves are prominent features in the data of airglow imaging systems. Furthermore, this altitude region is known to be a region where wave breaking occurs quite often making it particular interesting for quantifying the amount of energy and momentum released due to gravity waves.

Five years of airglow observations with three FAIM (Fast Airglow Imager) systems in and around the Alpine region are analysed regarding high-frequency gravity waves. Prevailing wind fields and tides from meteor radar wind data and ERA5 data are compared with the propagation direction of these waves and show patterns with high correlation. On seasonal timescales, the gravity waves clearly propagate predominantly to the East in summer and to the West in winter regarding the zonal direction. The meridional direction varies between the different years. On diurnal timescales, we find that atmospheric tides significantly impact the main propagation directions of the gravity waves.

We further present a case study of a stereoscopic reconstruction using two synchronized airglow-imagers with overlapping field-of-views. This allows deriving the wave amplitude and a 3D visualization of gravity wave patterns within the airglow layer.

This work received funding from the Bavarian State Ministry of the Environment and Consumer Protection.

How to cite: Hannawald, P., Wüst, S., Bittner, M., Lilienthal, F., and Jacobi, C.: Influence of atmospheric winds and tides on the propagation direction of mesospheric gravity waves observed in OH airglow in the Alpine region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3609, https://doi.org/10.5194/egusphere-egu2020-3609, 2020.

EGU2020-9916 | Displays | AS1.34

A comparison of OH nightglow volume emission rates as measured by SCIAMACHY and SABER

Martin Kaufmann, Yajun Zhu, Qiuyu Chen, Jiyao Xu, Qiucheng Gong, Jilin Liu, Daikang Wei, Manfred Ern, and Martin Riese

Hydroxyl (OH) short-wave infrared emissions arising from OH(4-2, 5-2, 8-5, 9-6) as measured by channel 6 of the SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY) are used to derive OH concentrations of OH(v=4, 5, 8, and 9) between 80 km and 96 km. Retrieved concentrations are used to simulate integrated radiances at 1.6 um and 2.0 um as measured by the Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) instrument, which are not fully covered by the spectral range of SCIAMACHY. On average, SABER 'unfiltered' data is on the order of 40% (at 1.6 um) and 20% (at 2.0 um) larger than the simulations using SCIAMACHY data. 'Unfiltered' SABER data is a product, which accounts for the shape, width, and transmission of the instrument’s broadband filters, which do not cover the full ro-vibrational bands of the corresponding OH transitions. It is found that the discrepancy between SCIAMACHY and SABER data can be reduced by more than 50%, if the unfiltering process is carried out manually using published SABER interference filter characteristics and latest Einstein coefficients from the HITRAN database. Remaining differences are discussed with regard to model parameter uncertainties and radiometric calibration.

How to cite: Kaufmann, M., Zhu, Y., Chen, Q., Xu, J., Gong, Q., Liu, J., Wei, D., Ern, M., and Riese, M.: A comparison of OH nightglow volume emission rates as measured by SCIAMACHY and SABER, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9916, https://doi.org/10.5194/egusphere-egu2020-9916, 2020.

EGU2020-15350 | Displays | AS1.34

Model studies on vibrationally-rotationally excited hydroxyl molecules in the mesopause region

Justus Notholt, Holger Winkler, and Stefan Noll

One of the standard methods to remotely sense the temperature of the mesopause region is based on spectroscopic measurements of near-infrared emissions of vibrationally-rotationally excited hydroxyl molecules, and to calculate  rotational temperatures. For the interpretation of the retrieved temperatures, the aspect of rotational thermalization is of great importance. We present results of a first-principle kinetic model of vibrationally-rotationally excited hydroxyl molecules which accounts for chemical production and loss processes as well as radiative and collision-induced vibrational-rotational transitions. The model allows one to assess deviations of the rotational populations from local thermodynamic equilibrium, and to identify the key parameters which control the rotational thermalization processes. The model simulations reproduce the observed bimodality in temperatures, i.e. a cold temperature component dominating the population of low rotational states, and a hot temperature component dominating higher states. The model results are compared to measurement data from the UVES echelle spectrograph at Cerro Paranal in Chile (Presentation EGU2020-3169) which allows us to confine free model parameters such as the rotational state changes in vibrational quenching process.

How to cite: Notholt, J., Winkler, H., and Noll, S.: Model studies on vibrationally-rotationally excited hydroxyl molecules in the mesopause region , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15350, https://doi.org/10.5194/egusphere-egu2020-15350, 2020.

In the nightglow of the atmosphere in the altitude range of 90-105 km, the Barth’ mechanism is the dominant mechanism of excitation of oxygen emissions [1].

The source of oxygen emissions in this altitude range is the three-body reaction of the association of oxygen atoms. The rate coefficient of this reaction, as well as the collision quenching rate coefficients of the excited oxygen components O(1S), O2(b1Σ+g), O2(a1Δg) depend on the kinetic temperature of the gas. The method of sensitivity analysis for complex photochemical systems developed in [2] allows one to comprehensively consider the temperature dependence of the processes of excitation and quenching for each excited component. Analytical expressions will be obtained for the sensitivity coefficients of the intensities of these emissions depending on temperature and altitude. The formulas obtained are also suitable for estimation of the effect of temperature on the contribution of the Barth’ mechanism to atmospheric dayglow. This work was supported by the Russian Foundation for Basic Research (grant RFBR No. 20-05-00450 A).

1. Krasnopolsky V. A. (2011), Excitation of the oxygen nightglow on the terrestrial planets, Planetary and Space Science, 59, 754-766, doi: 10.1016/j.pss.2011.02.015.

2. Yankovsky V. A., Martyshenko K. V., Manuilova R. O., Feofilov A. G. (2016), Oxygen dayglow emissions as proxies for atomic oxygen and ozone in the mesosphere and lower thermosphere, Journal of Molecular Spectroscopy, 327, 209-231, doi: 10.1016/j.jms.2016.

How to cite: Yankovsky, V.: The effect of atmospheric temperature on the calculations of the intensity of oxygen emissions in the framework of the Barth mechanism: sensitivity study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-57, https://doi.org/10.5194/egusphere-egu2020-57, 2020.

Abstract.The mesosphere and lower thermosphere are the least studied areas of the earth atmosphere. The reason for this is the lack of monitoring. We have the Fabry-Perot interferometer (FPI) installed in middle latitudes of East Siberia in the geophysical observatory of Institute of Solar-Terrestrial Physics SB RAS (51.8N, 103.1E).  The FPI is a unique instrument and has no analogues in Russia.The FPI with a temporal resolution of about 10–15 minutes observes the natural glow of the night atmosphere of 630.0, 557.7 nm and 843 nm, the characteristic heights of these lines are about 250, 100 and 90 km, respectively. In this study, we use data on the behavior of the zonal, meridional component of wind speed and temperature obtained with 557.7 nm line. We analyze the temperature regime and dynamics of the stratospheric polar vortex according to the data of climatic archive - ERA-interim to get the relationship of SSW and wind regime in MLT.  In this study, we consider winter atmosphere in 2017-2019 over East Siberia, namely the period of sudden stratospheric warming. We compared the evolution of stratospheric warming’s with temporary variations in background wind and temperature and tides in the mesosphere and lower thermosphere. It turned out that the sudden stratospheric warming's made a strong effect in upper layers of the atmosphere. During major stratospheric warming's, the zonal and meridional winds reversed and increase in the semidiurnal and thirdrdiurnal tides. Temperature in MLT dramatic drop followed by an increase during sudden stratospheric warming's. Minor sudden stratospheric warming's had a similar (but much lower in intensity) response in the upper atmosphere.

Acknowledgements. Analysis of stratosphere condition in this work was supported by the Russian Science Foundation, project No. 19-77-00009. Analysis of methosphere condition in ths work was supported by Rusian Foundation for Basic Research project No. 18-05-00594. The measurements were carried out on the instrument of Center for Common Use «Angara» [http://ckp-rf.ru/ckp/ 3056]. The authors gratefully acknowledge the access to the ECMWF ERA-Interim.

How to cite: Roman, V. and Olga, Z.: Study of temperature, wind speed and tides in the upper atmosphere from optical measurements during the 2017-2019 winter's, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-689, https://doi.org/10.5194/egusphere-egu2020-689, 2020.

Acoustic-gravity waves (AGWs) measuring at big heights may be generated in the troposphere and propagate upwards. A high-resolution three-dimensional numerical model was developed for simulating nonlinear AGWs propagating from the ground to the upper atmosphere. The model algorithms are based on the finite-difference analogues of the main conservation laws. This methodology let us obtaining the physically correct generalized wave solutions of the nonlinear equations. Horizontally moving sinusoidal structures of vertical velocity on the ground are used for the AGW excitation in the model. Numerical simulations were made in an atmospheric region having horizontal dimensions up to several thousand kilometers and the height extention up to 500 km. Vertical distributions of the mean temperature, density, molecular viscosity and thermal conductivity are specified using standard models of the atmosphere.

Simulations were made for different horizontal wavelengths, amplitudes and speeds of the wave sources at the ground. After “switch on” the tropospheric wave source, an initial AGW pulse very quickly (for several minutes) could propagate to heights up to 100 km and above. AGW amplitudes increase with height and waves may break down in the middle and upper atmosphere. Wave instability and dissipation may lead to formations of wave accelerations of the mean flow and to producing wave-induced jet flows in the middle and upper atmosphere. Nonlinear interactions may lead to instabilities of the initial wave and to the creation of smaller-scale perturbations. These perturbations may increase temperature and wind gradients and could enhance the wave energy dissipation.

In this study, the wave sources contain a superposition of two AGW modes with different periods, wavelengths and phase speeds. Longer-period AGW modes served as the background conditions for the shorter-period wave modes. Thus, the larger-scale AGWs can modulate amplitudes of small-scale waves. In particular, interactions of two wave modes could sharp vertical temperature gradients and make easier the wave breaking and generating  turbulence. On the other hand, small-wave wave modes might increase dissipation and modify the larger-scale modes.This study was partially supported by the Russian Basic Research Foundation (# 17-05-00458).

How to cite: Gavrilov, N. M. and Kshevetskii, S. P.: Numerical Modeling of Nonlinear Interactions of Spectral Components of Acoustic-Gravity Waves in the Middle and Upper Atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-76, https://doi.org/10.5194/egusphere-egu2020-76, 2020.

Energetic particle precipitation (EPP) is an important source of chemical changes in the polar middle atmosphere during winter. Recently, it has been suggested from modeling study that EPP-induced chemical changes can cause dynamic changes of the atmosphere. In this study we investigate the atmospheric responses to medium-to high energy electron (MEE) precipitations during 2005-2013 by using Specific Dynamics Whole Atmosphere Community Climate Model (SD-WACCM). Results show that MEE precipitations significantly increase the amount of NOx and HOx, resulting in mesospheric and stratospheric ozone depletions during polar winter. The ozone depletion due to MEE precipitation induces warming in the polar lower mesosphere. Large ozone loss in the polar middle atmosphere leads to clear dynamic impacts, which causes warming by 3-11 K temperature increase and weakening of the zonal wind in the lower mesosphere. Our study show that the MEE precipitation induces not only the chemical effects such as ozone depletion but also clear dynamic effects in the polar middle atmosphere.

How to cite: Lee, J.-H., Song, I.-S., and Jee, G.: Modeling study on the polar middle atmospheric responses to medium energy electron (MEE) precipitation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2520, https://doi.org/10.5194/egusphere-egu2020-2520, 2020.

EGU2020-2045 | Displays | AS1.34

Influence of thermospheric effects of solar activity on the middle atmosphere circulation and stationary planetary waves

Andrey Koval, Nikolai Gavrilov, Alexander Pogoreltsev, and Nikita Shevchuk

Atmospheric large-scale disturbances, for instance planetary waves, play a significant role in atmospheric general circulation, influencing its dynamical and thermal conditions. Solar activity may influence the mean temperature at altitudes above 100 km and alter conditions of wave propagation and reflection in the thermosphere. Using numerical simulations of the general atmospheric circulation during boreal winter, statistically confident evidences are obtained for the first time, demonstrating that changes in the solar activity (SA) in the thermosphere at heights above 100 km can influence propagation and reflection conditions for stationary planetary waves (SPWs) and can modify the middle atmosphere circulation below 100 km. A numerical mechanistic model simulating  atmospheric circulation and SPWs at heights 0 – 300 km is used. To achieve sufficient statistical confidence, 80 pairs of 15-day intervals were extracted from an ensemble of 16 pairs of model runs corresponding to low and high SA. Results averaged over these intervals show that impacts of SA above 100 km change the mean zonal wind and temperature up to 10% at altitudes below 100 km. The statistically confident changes in SPW amplitudes due to SA impacts above 100 km reach up to 50% in the thermosphere and 10 – 15% in the middle atmosphere depending on zonal wavenumber. Changes in wave amplitudes correspond to variations of the EP-flux and may alter dynamical and thermal SPW impacts on the mean wind and temperature. Thus, variable conditions of SPW propagation and reflection at thermospheric altitudes may influence the middle atmosphere circulation, thermal structure and planetary waves at different altitudes.

How to cite: Koval, A., Gavrilov, N., Pogoreltsev, A., and Shevchuk, N.: Influence of thermospheric effects of solar activity on the middle atmosphere circulation and stationary planetary waves, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2045, https://doi.org/10.5194/egusphere-egu2020-2045, 2020.

EGU2020-3283 | Displays | AS1.34

Intra-annual variations of spectrally resolved gravity wave activity and observations of turbulence in the UMLT region

René Sedlak, Alexandra Zuhr, Patrick Hannawald, Carsten Schmidt, Sabine Wüst, and Michael Bittner

Multi-year temperature time series from OH-airglow infrared (IR) spectrometers deployed at different sites in Europe as part of the Network for the Detection of Mesospheric Change (NDMC) are used to estimate the gravity wave activity in the upper mesosphere / lower thermosphere (UMLT) region.

The seasonal course of gravity wave activity is found to be strongly dependent on the wave period. While there is almost no clear variability of gravity wave activity for periods lower than about 60 minutes, we find strong evidence for an increasing variation throughout the year for periods longer than ca. 60 min. A dominant semi-annual structure with maxima at the solstices is found up to a periodicity of about 200 minutes, where a gradual transition to an annual cycle with maximum activity during winter and minimum activity during summer is observed.

The energy and momentum carried by gravity waves is dissipated in terms of turbulent wave breaking. Using observations of airglow imagers with high spatial and temporal resolution which were operated at the same time as the abovementioned IR-spectrometers we performed an investigation of turbulent gravity wave dynamics. The estimations of the turbulent eddy diffusion coefficient and the energy dissipation rate from the image series of a turbulent wave front agree quite well with the few available values in literature. A machine learning approach for the systematic extraction of turbulent episodes from the very large data set is presented.

This work received funding from the Bavarian State Ministry of the Environment and Consumer Protection.

How to cite: Sedlak, R., Zuhr, A., Hannawald, P., Schmidt, C., Wüst, S., and Bittner, M.: Intra-annual variations of spectrally resolved gravity wave activity and observations of turbulence in the UMLT region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3283, https://doi.org/10.5194/egusphere-egu2020-3283, 2020.

EGU2020-2733 | Displays | AS1.34

On the long term evolution of noctilucent clouds

Franz-Josef Lübken and Gerd Baumgarten

Some of the earliest observations in the transition region between the Earth's atmosphere and space (roughly at 80-120km) come from so called `noctilucent clouds' (NLC) which are located around 83km altitude and consist of water ice particles. They owe their existence to the very cold summer mesopause region (~130K) at mid and high latitudes. There is a long standing dispute whether NLC are indicators of climate change in the middle atmosphere. We use model simulations of the background atmosphere and of ice particle formation for a time period of 138 years to show that an increase of NLC appearance is expected for recent decades due to increased anthropogenic release of methane being oxidized to water vapor in the middle atmosphere. Since the beginning of industrialization the water vapor concentration at NLC heights has presumably increased by about 40 percent (1 ppmv). The water vapor increase leads to a large enhancement of NLC brightness. Increased cooling by enhanced carbon dioxide alone (assuming no water vapor increase) counter-intuitively would lead to a decrease(!) of NLC brightness. NLC existed presumably since centuries, but the chance to observe them by naked eye was very small before the 20th century, whereas it is likely to see an NLC in the modern era. The eruption of volcano Krakatoa in 1883 has seemingly triggered the first observation of an NLC in 1885. In this presentation we extend our analysis from middle to polar latitudes and expand comparison with observations.

How to cite: Lübken, F.-J. and Baumgarten, G.: On the long term evolution of noctilucent clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2733, https://doi.org/10.5194/egusphere-egu2020-2733, 2020.

EGU2020-10770 | Displays | AS1.34

Revealing small scale dynamics at the altitude of noctilucent clouds

Gerd Baumgarten, Jorge Chau, Jens Fiedler, Michael Gerding, Franz-Josef Lübken, and Britta Schäfer

Observing noctilucent clouds (NLC) by lidar and camera from ground reveals smallest scale structures of tens of meters and their evolution in the vertical and horizontal direction.
At the altitude of nocltilucent clouds (approx. 83 km) these structures are generated by microphysical processes affecting the ice particles, pure fluid dynamics, or a combination of both. On centennial time scales the NLC are linked to microphysical changes, mostly induced by changes of the available water vapor. On scales of hours to days the clouds are linked to temperature or the large scale flow. On scales of minutes the structures are often wave-like and associated with gravity waves and turbulence. 
For timescales below a few minutes only sparse observations were previously available. To systematically investigate the structure of NLC on such scales we make use of the ALOMAR RMR-lidar, located in Northern Norway at 69°N, that is detecting NLC with sub-second resolution since 2011. We have developed a classification scheme to identify the most important features on timescales of a few seconds. 
Furthermore we use a combination of lidar, radar and camera that allows studying simultaneously the horizontal and vertical scales. We will present new results from lidars and cameras that look at noctilucent clouds above ALOMAR and Kühlungsborn (54°N) with different scattering angles. The observations are used to investigate the mechanisms that generate the extraordinary appearance of NLC when observed by naked eye. 

How to cite: Baumgarten, G., Chau, J., Fiedler, J., Gerding, M., Lübken, F.-J., and Schäfer, B.: Revealing small scale dynamics at the altitude of noctilucent clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10770, https://doi.org/10.5194/egusphere-egu2020-10770, 2020.

Earth’s atmosphere supports a variety of internal wave motion which are responsible for spatio-temporal changes in temperature, winds, density, and chemical constituents. One of the most striking dynamical features of the upper atmosphere (i.e. mesosphere and lower thermosphere [MLT], 50-120 km) are atmospheric tides. In particular, the eastward-propagating nonmigrating diurnal tide with zonal wave number 3 (DE3), originating from tropical deep convection, introduces a large longitudinal and local time variability in temperature, wind and density in the MLT region. The DE3 is thus key to understanding how tropospheric weather influences space weather. However, DE3 short-term tidal variability is not well understood and part of the motivation for constellation missions. Single satellites such as TIMED nevertheless provide a pathway to identify multi-timescale tidal variability from days to years. We utilize 16 years of SABER (an instrument onboard the TIMED satellite) DE3 “tidal deconvolution” diagnostic that provides a unique opportunity to investigate interannual changes in short-term (days to weeks) tidal variability on various planetary wave time scales. The approach is based on information-theoretic techniques using Bayesian statistics, time dependent probability density functions and Kullback-Leibler divergence followed by multiple linear regression analysis. In this presentation, we focus on interannual changes in short-term DE3 variability on a 10-day planetary wave timescale and how it changes as a function of the quasi-biennial oscillation (QBO), El Niño-Southern Oscillation (ENSO) and the solar cycle.

How to cite: Kumari, K. and Oberheide, J.: QBO, ENSO and Solar Cycle Effects in Short-term Nonmigrating Tidal Variability on Planetary Wave Timescales from SABER - An Information-Theoretic Approach , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11856, https://doi.org/10.5194/egusphere-egu2020-11856, 2020.

EGU2020-11653 | Displays | AS1.34

Observations of migrating tides in the mid-latitude MLT using an array of SuperDARN HF-radars

Willem E. van Caspel, Patrick J. Espy, Robert E. Hibbins, and John P. McCormack

Solar thermal (migrating) atmospheric tides play an important role in shaping the day-to-day and seasonal variability of the Mesosphere-Lower-Thermosphere (MLT) region. Due the planetary scale of the migrating tides, observations have, however, remained sparse. This study uses meteor-echo wind measurements from a longitudinal array of SuperDARN HF-radars to isolate the amplitude and phase of the migrating diurnal, semidiurnal, and terdiurnal tide. The array of SuperDARN radars, covering nearly 180 degrees longitude at 60±5 degrees North, provide hourly horizontal wind measurements at approximately 95km altitude. The migrating components of the tides are isolated by fitting wave surfaces in space and time. The results are compared with global synoptic wind analyses from the high-altitude version of the Navy Global Environmental Model (NAVGEM-HA) to validate the method. The tides are also compared against those measured at a single station by the Trondheim (66N, 10E) meteor radar. We will present the method, a comparison between (migrating) tidal components in SuperDARN, NAVGEM-HA and the Trondheim meteor radar between 2014 and 2015, and migrating tide climatologies based on 21 years of SuperDARN data.

How to cite: van Caspel, W. E., Espy, P. J., Hibbins, R. E., and McCormack, J. P.: Observations of migrating tides in the mid-latitude MLT using an array of SuperDARN HF-radars, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11653, https://doi.org/10.5194/egusphere-egu2020-11653, 2020.

EGU2020-13462 | Displays | AS1.34

Limits of the WTQ method for calculating momentum flux

Peter Preusse, Markus Geldenhuys, and Manfred Ern

The acceleration of the large scale circulation by gravity wave is commonly described via the vertical gradient of the vertical flux of horizontal pseudomomentum, or in short of the momentum flux. The momentum flux vector is given by

 (Fpx,Fpy) = (1-f22) ( <u'w'>,<v'w'>)

where < > describes the spatial or temporal mean of at least one wavelength or period of the gravity wave. If one is going actually to calculate momentum flux from an observation or high-resolution model, several difficulties arise. First, one has to know the intrinsic frequency ω of the wave, second one tacitly assumes that only a single wave is causing the wind perturbations u', v' and w', and third one needs to find an appropriate averaging interval. One possibility to solve this is to perform spectral analysis. An alternative was introduced by Geller et al. (2013) which, based on the polarization relations, infers ω directly from the perturbation wind temperature quadratics and is hence referred to as WTQ. In a brief study we will investigate the implication of the single wave assumption for the momentum flux calculated from data sets calculating multiple waves.

How to cite: Preusse, P., Geldenhuys, M., and Ern, M.: Limits of the WTQ method for calculating momentum flux, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13462, https://doi.org/10.5194/egusphere-egu2020-13462, 2020.

EGU2020-21103 | Displays | AS1.34

Doppler spectral width studies from polar mesospheric summer echoes

Nikoloz Gudadze, Gunter Stober, Hubert Luce, and Jorge Luis Chau

Investigation of turbulence in the polar mesopause is essential for a better understanding of dynamical or mixing processes in the region. Polar Mesospheric Summer Echoes (PMSEs), occurring at mesopause altitudes during the summer season, are known to be a result of turbulence-induced fluctuations in the refractive index. The presence of ice particles controls and reduce the free-electron diffusivity in D region plasma, which in turn leads to complex, strong radar echoes at very high frequencies.

Often, Doppler spectral width of radar measurements are associated with the strength of turbulence in the target area and traditionally used to estimate turbulent kinetic energy dissipation rates, a fundamental parameter of the turbulence processes. Besides the cooling of summer mesopause region induced by GW drag, the turbulence produced by GW breaking contributes to the total energy budget due to release of turbulent kinetic energy to heat. We use PMSE spectral width measurements observed by Middle Atmosphere Alomar Radar System (MAARSY) during summer of 2016 to study their summer temporal mean profiles as well as temporal evolution and connection to the atmospheric turbulence at PMSE altitudes - 80 and 90 km. The current theoretical models suggest that the radar reflectivity should correlate to the strength of the turbulence; however, such a relation is mainly observed for the weaker PMSEs. The mean summer behaviour of estimated turbulent kinetic energy dissipation rates shows an increase from lower altitudes up to 90 km. It should be noticed that spectral width measurements contain additional broadening rather than turbulence, so derived energy dissipation rates are “upper values” than expected from pure turbulence. The results are still slightly lower than those known from climatology obtained from rocket soundings, mostly at altitudes close to the maximum occurrence of PMSE, 86-87 km.

We discuss a possible consequence of spectral width measurements under strong PMSEs. In such conditions, the strength of the echo does not correlate with the turbulence intensity, and the observed spectral width is weaker. However, the uniform distribution of spectral width values throughout the echo power is expected from the present theoretical understandings. Based on previous studies, strong PMSEs can also be observed during fossil turbulence. The interpretation of connection the spectral with measurements under fossil turbulence with the turbulence energy dissipation rates and the possibility of using PMSEs for the turbulence studies will be discussed.

How to cite: Gudadze, N., Stober, G., Luce, H., and Chau, J. L.: Doppler spectral width studies from polar mesospheric summer echoes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21103, https://doi.org/10.5194/egusphere-egu2020-21103, 2020.

Solar 11-year cycle variations of nighttime ozone near the secondary ozone maximum layer are analyzed with Aura Microwave Limb Sounder (MLS) observations since 2004 that covers complete solar cycle 24. Produced primarily from the recombination of molecular oxygen (O2) with single oxygen (O) transported from the lower thermosphere, the mesospheric nighttime ozone concentration is proportional to single oxygen density [O], of which the latter is modulated by UV solar cycle variations. MLS nighttime ozone and Solar Radiation and Climate Experiment (SORCE) Solar-Stellar Irradiance Comparison Experiment (SOLSTICE) measured UV show a positive correlation in-phase with the solar cycle. The nighttime ozone correlates strongly with temperature but not monotonously positive nor negative. The slope and sign of the correlation depend on location and season. They are positively correlated in general except for the boreal winter high latitudes.  Because the nighttime [O3] depends strongly on [O] in the upper mesosphere, it is expected the nighttime [O3] would follow the [O] distributions, producing similar diurnal, seasonal, and solar-cycle variations, as well as latitudinal distributions as observed in Carbon Monoxide (CO) in the upper mesosphere.

How to cite: Lee, J. N. and Wu, D. L.: Solar cycle modulation of nighttime ozone near the mesopause as observed by MLS, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11932, https://doi.org/10.5194/egusphere-egu2020-11932, 2020.

EGU2020-4946 | Displays | AS1.34

The role of EEP forcing and background dynamics on the seasonal NO variability in the MLT region

Christine Smith-Johnsen, Hilde Nesse Tyssøy, Daniel Marsh, and Anne Smith

Energetic electron precipitation (EEP) ionizes the Earth's atmosphere and leads to production of nitric oxide (NO) from 50 to 150 km altitude. In this study we investigate the direct and indirect NO response to EEP using the Whole Atmosphere Community Climate Model (WACCM). In comparison to observations from SOFIE / AIM (Solar Occultation For Ice Experiment / Aeronomy of Ice in the Mesosphere), we find that EEP production of NO in the D-region is well simulated when both medium energy electron precipitation and negative and cluster ion chemistry is included in the model. However, the main EEP production of NO occurs in the E-region, and there the observed and modeled production differ. This discrepancy impacts also the D-region, and is seasonally dependent with the highest underestimate of D-region NO occuring during winter. The modeled transport across the mesopause during winter is generally weak, but strengthens with increased gravity wave activity. Increased eddy diffusion, increases NO at all altitudes through the polar MLT region

How to cite: Smith-Johnsen, C., Tyssøy, H. N., Marsh, D., and Smith, A.: The role of EEP forcing and background dynamics on the seasonal NO variability in the MLT region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4946, https://doi.org/10.5194/egusphere-egu2020-4946, 2020.

EGU2020-4993 | Displays | AS1.34

Investigating a link between solar wind variability and atmospheric dynamics in polar regions

Jone Edvartsen, Ville Maliniemi, and Hilde Nesse Tyssøy

Evidence are pointing to two potential links between solar wind forcing and atmospheric dynamics in polar regions. The chemical link follows from energetic particle precipitation (EPP) ionizing the higher atmosphere, leading to a production of nitrogen and hydrogen oxides (NOx and HOx), which later on participate in ozone destruction. This can lead to changes in the radiative balance of the atmosphere, followed by related changes in winds. The physical link is related to the interplanetary magnetic field (IMF) and its ability to modulate the global electric circuit (GEC), with a hypothesized link between changes in the GEC and polar tropospheric dynamics through cloud generation processes. By use of ERA-5 reanalysis data and OMNI near Earth solar wind magnetic field and plasma parameter data, we investigate these links with a multiple correlation analysis. Internal atmospheric variability is excluded before the analysis. Time period of the data is 1979-2018. Results concerning the chemical link show a significant negative correlation between EPP (geomagnetic activity index Ap used as a proxy) and pressure anomalies in the local winter inside the polar vortex. The anomaly, starting in the stratosphere, extends downwards to the surface in a matter of days. The results indicate a greater response in the north compared to the south. For the physical link, a significant correlation is seen between the IMF horizontal (By) component and lower tropospheric pressure in the south for certain months in local summer. There seems to be no correlation between the two indices, Ap and By, indicating that these mechanisms operate individually without aliasing between the two. These results imply that solar wind variability can potentially impact polar atmospheric dynamics during specific seasons in different ways. This can enhance our understanding on solar related atmospheric effects.

How to cite: Edvartsen, J., Maliniemi, V., and Nesse Tyssøy, H.: Investigating a link between solar wind variability and atmospheric dynamics in polar regions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4993, https://doi.org/10.5194/egusphere-egu2020-4993, 2020.

EGU2020-5218 | Displays | AS1.34

Mesospheric fronts in airglow images and the variation of the bottomside sodium layer densities measured by a sodium lidar at Tromsø, Norway

Viswanathan Lakshmi Narayanan, Satonori Nozawa, Ingrid Mann, Shin-ichiro Oyama, Kazuo Shiokawa, Yuichi Otsuka, and Norihito Saito

Mesospheric frontal systems are waves extending to hundreds of kilometers along their phase fronts and appear like a boundary. They are observed in the upper mesospheric airglow imaging observations of OH, sodium and OI greenline nightglow emissions. It is believed that the fronts result from gravity wave dynamics associated with favorable background conditions like thermal ducting. Many of the frontal systems are identified as mesospheric bores when they are accompanied with sudden airglow intensity changes across the frontal boundary. Most of the frontal systems propagate with phase locked undulations following the leading front, while some induce turbulence behind the front. Though the existence of the frontal systems in the mesosphere is known for more than two decades, their role and importance is not understood properly. In this work, we use airglow data from an all-sky imager located at Tromsø to identify the frontal systems, particularly using OH images. Collocated five-beam sodium lidar measurements are used to identify the structuring in sodium densities around time of passage of the frontal systems. The sodium lidar at Tromsø is a versatile system capable of measuring sodium densities, temperatures and winds in the upper mesospshere region. Hence, we obtain the wind and temperature information to study the background conditions during passage of the intense frontal systems. Though, mostly we focus on OH airglow images as they are observed with broad pass band resulting in higher signal strength, we also utilize images from other emissions like OI greenline and sodium whenever they are available and free from auroral features. Interestingly, we find formation of some unusual structuring in the bottomside sodium layer around the passage of the frontal systems. We show different cases during winter months of the years 2013-14 and 2014-15 and investigate the relationship between unusual bottomside structuring in the sodium layer and passage of the frontal systems.

How to cite: Narayanan, V. L., Nozawa, S., Mann, I., Oyama, S., Shiokawa, K., Otsuka, Y., and Saito, N.: Mesospheric fronts in airglow images and the variation of the bottomside sodium layer densities measured by a sodium lidar at Tromsø, Norway , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5218, https://doi.org/10.5194/egusphere-egu2020-5218, 2020.

EGU2020-10731 | Displays | AS1.34

Mesospheric ionization rates due to Medium Energy Electron Precipitation – an overview

Hilde Nesse Tyssøy, Miriam Sinnhuber, Timo Asikainen, Max van de Kamp, Joshua Pettit, Cora Randall, Christine Smith-Johnsen, Pekka T. Verronen, Jan Maik Wissing, and Olesya Yakovchuk

Quantifying the ionization rates due to medium energy electron (MEE) precipitation into the mesosphere has long been an outstanding question. It is the key to understand the total effect of particle precipitation on the atmosphere. The first MEE ionization rate was provided by the Atmospheric Ionization Module Osnabrück (AIMOS) in 2009. It applies electron measurements by the 0o electron detector on the MEPED instrument on board the NOAA/POES satellites together with geomagnetic indices. Since then several other efforts to estimate the MEE precipitation and associated ionization rates has been made taking account e.g. of cross contamination by low-energy protons; Full Range Energy Electron Spectra (FRES) and ISSI-19. Recently, a parameterization based on the same electron data, scaled by the geomagnetic index Ap, has been included in the solar-driven particle forcing in the recommendation for Coupled Model Intercomparison Project 6 (CMIP6). Another parameterization aiming to resolve substorm activity applies the SML index, AISstorm. Further, three different methods to construct the total bounce loss cone fluxes based on both MEPED detectors has been suggested by the University of Colorado, University of Oulo, and the University of Bergen. In total, the space physics community offers a wide range of mesospheric ionization rates to be used in studies of the subsequent chemical-dynamical impact of the atmosphere, which are all based on the MEPED electron measurement.

Here we present a review of eight different estimates of energetic electron fluxes and the ionization rates during an event in April 2010. The objective of this comparison is to understand the potential uncertainty related to the MEE energy input in order to assess its subsequent impact on the atmosphere. We find that although the different parameterizations agree well in terms of the temporal variability, they differ by orders of magnitude in ionization strength both during geomagnetic quiet and disturbed periods and show some inconsistency in terms of latitudinal coverage.

How to cite: Nesse Tyssøy, H., Sinnhuber, M., Asikainen, T., van de Kamp, M., Pettit, J., Randall, C., Smith-Johnsen, C., Verronen, P. T., Wissing, J. M., and Yakovchuk, O.: Mesospheric ionization rates due to Medium Energy Electron Precipitation – an overview, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10731, https://doi.org/10.5194/egusphere-egu2020-10731, 2020.

EGU2020-15235 | Displays | AS1.34

First results of combined ground- and rocket-based measurements for investigation of polar mesospheric winter echoes (PMWE)

Tristan Staszak, Boris Strelnikov, Ralph Latteck, Toralf Renkwitz, Martin Friedrich, and Franz-Josef Lübken

Two experimental sounding rockets were launched from Andøya Space Center
(Norway) devoted to investigate the phenomenon of polar mesospheric winter
echoes (PMWE). PMWE are relatively strong radar returns during winter,
observed at various frequencies (e.g. ≈ 50 MHz Maarsy or ≈ 224 MHz with
EISCAT). Despite possible tracing capabilities for dynamics in the Meso-
sphere over a wide annual and altitudinal extend, the formation process is
still not understood. To clarify the formation mechanism and proof theories,
an experimental setup consisting of two rocket payloads were designed. Aim-
ing for measuring neutral air temperature, relative and absolute densities of
plasma constituents (electrons, ions, charged aerosols), neutral air and trace
gases as well as turbulence. In-situ measurements were complemented by
ground based measurements of multiple radars and lidars.
We show results from contemporaneous multi instrumental in-situ measure-
ments and ground based observations based on the first part of the PMWE-
Project and discuss them in the context of most relevant theories.

How to cite: Staszak, T., Strelnikov, B., Latteck, R., Renkwitz, T., Friedrich, M., and Lübken, F.-J.: First results of combined ground- and rocket-based measurements for investigation of polar mesospheric winter echoes (PMWE), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15235, https://doi.org/10.5194/egusphere-egu2020-15235, 2020.

Solar, auroral, and radiation belt electrons enter the atmosphere at polar regions leading to ionization and affecting its chemistry. Climate models usually parametrize this ionization and the related changes in chemistry based on satellite particle measurements. Precise measurements of the particle and energy influx into the upper atmosphere are difficult because they vary substantially in location and time. Widely used particle data are derived from the POES and GOES satellite measurements which provide electron and proton spectra.

We present electron energy and flux measurements from the Special Sensor Ultraviolet Spectrographic Imager (SSUSI) satellite instruments on board the Defense Meteorological Satellite Program (DMSP) satellites. This formation of now four satellites observes the auroral zone in the UV from which electron energies and fluxes are inferred in the range from 2 keV to 20 keV. We use these observed electron energies and fluxes to calculate ionization rates and electron densities in the upper mesosphere and lower thermosphere (≈ 70–200 km). We present an initial comparison of these rates to other models and compare the electron densities to those measured by the EISCAT radar. This comparison shows that with the current standard parametrizations, the SSUSI inferred auroral (90–120 km) electron densities are larger than the ground-based measured ones by a factor of 2–5. It is still under investigation if this difference is due to collocation (in space and time) and EISCAT mode characteristics or caused by incompletely modelling the ionization and recombination in that energy range.

How to cite: Bender, S., Espy, P., and Paxton, L.: Middle atmosphere ionization from auroral particle precipitation as observed by the SSUSI satellite instruments, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18489, https://doi.org/10.5194/egusphere-egu2020-18489, 2020.

AS1.35 – Aeolus data and its application

EGU2020-4091 | Displays | AS1.35

Aeolus: ESA’s wind mission. Status and future challenges

Tommaso Parrinello, Anne Grete Straume, Jonas Von Bismark, Sebastian Bley, Viet Duc Tran, Peggy Fischer, Thomas Kanitz, Denny Wernham, Thorsten Fehr, Emilio Alvarez, Oliver Reitebuch, and Isabell Krisch

The European Space Agency (ESA)’s wind mission, Aeolus, was launched on 22 August 2018. Aeolus is a member of the ESA Earth Explorer family and its main objective is to demonstrate the potential of Doppler wind Lidars in space for improving weather forecast and to understand the role of atmospheric dynamics in climate variability. Aeolus carries a single instrument called ALADIN: a high sophisticated spectral resolution Doppler wind Lidar which operates at 355 which is the first of its kind to be flown in space. It provides profiles of single horizontal line-of-sight winds (primary product) in near-real-time (NRT), and profiles of atmospheric backscatter and extinction. The instrument samples the atmosphere from about 30 km down to the Earth’s surface, or down to optically thick clouds. The required precision of the wind observations is 1-2.5 m/s in the troposphere and 3-5 m/s in the stratosphere while the systematic error requirement be less than 0.7 m/s. The mission spin-off product includes information about aerosol and cloud layers. The satellite flies in a polar dusk/dawn orbit (6 am/pm local time), providing ~16 orbits per 24 hours with an orbit repeat cycle of 7 days. Global scientific payload data acquisition is guaranteed with the combined usage of Svalbard and Troll X-band receiving stations.

The status of the Aeolus mission will be provided, including its performance assessment, planned operations and exploitation in the near future. This comprises the outcome of the instrument in its early operation phase, calibration and validation activities and a general review of the main scientific findings. Scope of the paper is also to inform about the programmatic highlights and future challenges.

How to cite: Parrinello, T., Straume, A. G., Von Bismark, J., Bley, S., Tran, V. D., Fischer, P., Kanitz, T., Wernham, D., Fehr, T., Alvarez, E., Reitebuch, O., and Krisch, I.: Aeolus: ESA’s wind mission. Status and future challenges , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4091, https://doi.org/10.5194/egusphere-egu2020-4091, 2020.

EGU2020-9471 | Displays | AS1.35

Data quality of Aeolus wind measurements

Isabell Krisch and the Aeolus DISC

The European Space Agency (ESA)’s Earth Explorer Aeolus was launched in August 2018 carrying the world’s first spaceborne wind lidar, the Atmospheric Laser Doppler Instrument (ALADIN). ALADIN uses a high spectral resolution Doppler wind lidar operating at 355nm to measure profiles of line-of-sight wind components in near-real-time (NRT). ALADIN samples the atmosphere from 30km altitude down to the Earth’s surface or to the level where the lidar signal is attenuated by optically thick clouds.

The global wind profiles provided by ALADIN help to improve weather forecasting and the understanding of atmospheric dynamics as they fill observational gaps in vertically resolved wind profiles mainly in the tropics,  southern hemisphere, and over the northern hemisphere oceans. In January 2020, the European Centre for Medium-Range Weather Forecasts (ECMWF) became the first numerical weather prediction (NWP) centre to assimilate Aeolus observations for operational forecasting.

A main prerequisite for beneficial impact is data of sufficient quality. Such high data quality has been achieved through close collaboration of all involved parties within the Aeolus Data Innovation and Science Cluster (DISC), which was established after launch to study and improve the data quality of Aeolus products. The tasks of the Aeolus DISC include the instrument and platform monitoring, calibration, characterization, retrieval algorithm refinement, processor evolution, quality monitoring, product validation, and impact assessment for NWP.

The achievements of the Aeolus DISC for the NRT data quality and the current status of Aeolus wind measurements will be described and summarized. Further, an outlook on future improvements and the availability of reprocessed datasets with enhanced data quality will be provided.

How to cite: Krisch, I. and the Aeolus DISC: Data quality of Aeolus wind measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9471, https://doi.org/10.5194/egusphere-egu2020-9471, 2020.

The European Space Agency’s Aeolus mission, which was launched in August 2018, provides profiles of horizontal line-of-sight (HLOS) wind observations from a polar orbiting satellite.  The European Centre For Medium-Range Weather Forecasts (ECMWF) began the operational assimilation of Aeolus Level-2B winds on 9 January 2020 in their global NWP (Numerical Weather Prediction) model, 1 year and 4 months after the first Level-2B wind products were produced in near real time via ESA’s ground processing segment.  This achievement was possible because of the production of good data quality, which was met through a close collaboration of all the parties involved within the Aeolus Data Innovation and Science Cluster (DISC) and via the great efforts of ESA, industry and ground processing algorithms pre- and post-launch.
Through the careful assessment of the statistics of differences of the Aeolus winds relative to the ECMWF model, the Level-2B Rayleigh winds were found to have large systematic errors.  The systematic errors were found to be highly correlated with ALADIN’s (Atmospheric Laser Doppler Instrument) primary mirror temperatures, which vary in a complex manner due to the variation in Earthshine and thermal control of the mirror.  The correction of this source of bias in the ground processing is underway, therefore in the meantime a bias correction scheme using the ECMWF model as a reference was developed for successful data assimilation; the scheme will be described.  
We will present the results of the Aeolus NWP impact assessment which led to the decision to go operational.  Aeolus’ second laser (FM-B, available since late June 2019) provides statistically significant positive impact of moderate to large amplitude, of similar magnitude to some other important and well-established observing systems (such as IR radiances, GNNS radio occultation and Atmospheric Motion Vectors).  Observing System Experiments demonstrate reduction of forecast errors in geopotential and vector wind of around 2% in the tropics and 2-3% in the southern hemisphere for short-range and medium range forecasts (up to day 10).  This positive impact is particularly impressive given that Aeolus provides less than 1% of the total number of observations assimilated, showing the value of direct wind observations for global NWP.

How to cite: Rennie, M. P. and Isaksen, L.: An Assessment of the Impact of Aeolus Doppler Wind Lidar Observations for Use in Numerical Weather Prediction at ECMWF, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5340, https://doi.org/10.5194/egusphere-egu2020-5340, 2020.

EGU2020-13805 | Displays | AS1.35

The application of ATLID techniques for aerosol/cloud retrievals to ALADIN

David Donovan, Gert-Jan van Zadelhoff, Thomas Flament, Dimitri Trapon, and Holgar Baars

After much anticipation and several years of delay the ALADIN lidar was launched on the Aeolus platform in August 2018. ALADIN is the world’s first space-based Doppler lidar. It operates at 355nm and its main products are line-of-sight winds. Wind-profiles are derived from the Doppler shift of the backscattered signals. Using a variation of the High Spectral Resolution Lidar technique (HSRL), two detection channels are used, a `Mie ‘-channel and a `Rayleigh’-channel. Cloud/aerosol information is also present in the signals, however, ALADIN’s design is optimized for wind observations and the retrieval of aerosol/cloud products is secondary (but important for various applications, e.g. the monitoring of atmospheric composition).

While cloud and aerosol products are secondary products for ALADIN, they are primary products for the EarthCARE lidar ATLID. EarthCARE stands for the Earth Clouds Aerosol and Radiation Explorer and is a joint ESA-JAXA multi-instrument cloud-aerosol-precipitation primarily process study oriented mission planned to be launched in 2022 EarthCARE will embark a lidar called ATLID. ATLID, like ALADIN is a 355 nm HSRL system, but is optimized for cloud/aerosol measurements. Compared to ALADIN, ATLID has a higher spatial resolution, measures the depolarization of the return signal and has a much cleaner Rayleigh- Mie backscatter signal separation. Like ALADIN though, the SNR makes accurate retrievals a challenge. Over the past several years, a suite of cloud/aerosol algorithms have been developed for ATLID that have focused on the challenge of making accurate retrievals of cloud and aerosol extinction and backscatter specifically addressing the low SNR nature of the lidar signals and the need for intelligent binning/averaging of the data. These ATLID approaches have reached a certain stage of maturity; however, they have been tested using mainly simulated data with the aid of the ECSIM multi-instrument end-to-end simulator.

The lessons learned by the application of ATLID-like algorithms on ALADIN data would lead to better ATLID products when it is launched. Further, preliminary work indicates that AT LID-inspired techniques can be successfully adapted to ALADIN measurements and have the potential to lead to improvements in the ALADIN extinction and backscatter products. In this presentation, ATLID-like approaches for ALADIN feature detection and extinction and lidar-ratio retrieval (based on an optimal-estimation approach) will be described. Examples will be presented and compared with observations made using ground-based lidars.

How to cite: Donovan, D., van Zadelhoff, G.-J., Flament, T., Trapon, D., and Baars, H.: The application of ATLID techniques for aerosol/cloud retrievals to ALADIN, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13805, https://doi.org/10.5194/egusphere-egu2020-13805, 2020.

EGU2020-19778 | Displays | AS1.35

Aeolus Calibration, Validation and Science Campaigns

Thorsten Fehr, Vassilis Amiridis, Sebastian Bley, Philippe Cocquerez, Christian Lemmerz, Griša Močnik, Gail Skofronick-Jackson, and Anne Grete Straume

Since 2007, a series of ESA supported airborne campaigns have been essential to the development of the Aeolus Doppler Wind Lidar satellite mission, which was successfully launched on 22 September 2018 and is providing a novel wind and aerosol profile data.

A core element of the Aeolus Cal/Val activities is DLR’s A2D wind lidar on-board the DLR Falcon aircraft, an airborne demonstrator for the Aeolus ALADIN satellite instrument flown in combination with the 2-µm Doppler Wind Lidar reference system. Following the pre-launch WindVal-I and –II campaigns in 2015 and 2016, a number of calibration and validation campaigns have been successfully implemented: WindVal-III providing early Cal/Val results in November 2018 only three months after the Aeolus launch, AVATAR-E in May 2019 focussing on the Cal/Val over Central Europe, and AVATAR-I in September 2019 providing Cal/Val information in the North Atlantic and Arctic flying from Iceland.

The airborne validation is also being supported through balloon flights in the tropical UTLS and lower stratosphere in the frame of the CNES Stratéole-2 stratospheric balloon activities. In the frame of the ESA supported pre-Stratéole-2 campaign, eight stratospheric balloons have been launched from the Seychelles in November/December 2019 providing unique upper level wind data for the Aeolus validation.

The largest impact of the Aeolus observations is expected in the Tropics, and in particular over the Tropical oceans, where only a limited number of wind profile information is provided by ground based observations. Aeolus provides key direct measurements which are of importance to correctly constrain the wind fields in models. In addition, Aeolus observations have the potential to further enhance our current knowledge on aerosols and clouds by globally providing optical properties products that include atmospheric backscatter and extinction coefficient profiles, lidar ratio profiles and scene classification. In the tropics, a particularly interesting case is the outflow of Saharan dust and its impact on micro-physics in tropical cloud systems. The region off the coast of West Africa allows the study of the Saharan Aerosol layer, African Easterly Waves and Jets, Tropical Easterly Jet, as well as the deep convection in ITCZ. 

Together with international partners, ESA is currently implementing a Tropical campaign in July 2020 with its base in Cape Verde that comprises both airborne and ground-based activities addressing the tropical winds and aerosol validation, as well as science objectives. The airborne component includes the DLR Falcon-20 carrying the A2D and 2-µm Doppler Wind lidars, the NASA P-3 Orion with the DAWN and HALO lidar systems, the APR Ku-, Ka- and W-band Doppler radar and drop sondes, and a Slovenian small aircraft providing in-situ information from aethalometers, nephelometers and optical particle counters. The ground-based component led by the National Observatory of Athens is a collaboration of European teams providing aerosol and cloud measurements with a range of lidar, radar and radiometer systems, as well as a drone providing in-situ aerosol observations. In addition, the participation airborne capabilities by NOAA and LATMOS/Meteo France are currently being investigated.

This paper will provide a summary of the Aeolus campaign focussing on the planned tropical

How to cite: Fehr, T., Amiridis, V., Bley, S., Cocquerez, P., Lemmerz, C., Močnik, G., Skofronick-Jackson, G., and Straume, A. G.: Aeolus Calibration, Validation and Science Campaigns , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19778, https://doi.org/10.5194/egusphere-egu2020-19778, 2020.

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Influence of Aeolus data assimilation on the representation of gravity waves in ECMWF analysis fields

Isabell Krisch, Michael Rennie, Bernd Kaifler, Sonja Gisinger, Oliver Reitebuch, and Markus Rapp

In January 2020, the European Centre for Medium-Range Weather Forecast (ECMWF) became the first numerical weather prediction (NWP) centre to assimilate wind observations from the new European Space Agency (ESA)’s Earth Explorer satellite Aeolus for operational forecasting. Aeolus was launched into space on August 22nd, 2018, carrying the world’s first spaceborne wind lidar, the Atmospheric Laser Doppler Instrument (ALADIN). ALADIN measures profiles of line-of-sight wind components from 30km altitude down to the Earth’s surface or to the level where the lidar signal is attenuated by optically thick clouds.

Impact assessment studies performed at ECMWF in 2019, show improved weather forecasting skills, by assimilating Aeolus wind measurements. As a side effect, these impact experiments also reveal an influence of Aeolus data assimilation on the representation of resolved gravity waves in the ECMWF model fields. Both, orographic and non-orographic gravity waves are impacted by the Aeolus data assimilation.

This impact of Aeolus data assimilation on the representation of gravity waves in ECMWF will be presented for selected case studies in the southern hemisphere. Ground-based and airborne measurement data from the SOUTHTRAC campaign will be used for validation where available.

How to cite: Krisch, I., Rennie, M., Kaifler, B., Gisinger, S., Reitebuch, O., and Rapp, M.: Influence of Aeolus data assimilation on the representation of gravity waves in ECMWF analysis fields, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9546, https://doi.org/10.5194/egusphere-egu2020-9546, 2020.

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Aeolus follow-on configurations

Gert-Jan Marseille and Ad Stoffelen

The ESA Earth Explorer mission Aeolus partly fulfills the well-expressed need for wind profile observations to initialize Numerical Weather Prediction (NWP) models. Aeolus has proven beneficial in particular over regions void of wind profile observations in the troposphere and lower stratosphere, particularly over the oceans, tropics and southern hemisphere. Although successful, Aeolus only partly fills the data gap following the requirements on data coverage, data quality and timeliness. These requirements are generally well captured by the World Meteorological Organization (WMO) Observing Systems Capability Analysis and Review (OSCAR) and Rolling Requirements Review (RRR).

 

With the success of Aeolus the moment has come to look forward to future vertical wind profiling capability to fulfil the rolling requirements in operational meteorology. Already in 2005 ESA initiated a study on potential Aeolus follow-on missions. Options studied included an Aeolus type instrument, but measuring profiles of the complete wind vector, rather than a single wind component like Aeolus. In addition, the benefits of a constellation of a number of Aeolus instruments was studied. It was shown that given a fixed number of observations doubling the coverage of single wind components, through the positioning of two Aeolus satellites in the same orbit, is more beneficial for NWP than a single satellite measuring the complete wind vector. A third Aeolus-type satellite in the same orbit further adds to NWP, although first indications of impact saturation emerged when distributing more satellites in the same sun-synchronous orbit.

 

This paper provides an overview of the methodology used to assess the potential impact of Aeolus follow-on missions and first conclusions on optimal wind profile sampling for NWP in the context of the WMO RRR.

How to cite: Marseille, G.-J. and Stoffelen, A.: Aeolus follow-on configurations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20758, https://doi.org/10.5194/egusphere-egu2020-20758, 2020.

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Aeolus: Payload Ground segment operations. Status, performances and evolution

Peggy Fischer, Luca Mellano, Marta De Laurentis, Stefano Aprile, and Antonio Biscuso

After about 1.5 years in operations, the Aeolus Ground Segment is performing very well for all core functions including X-band data acquisition, mission planning, systematic science data production in Near Real Time, data access, data archival and thus continues to secure successfully important operational mission objectives.

Aeolus Payload Ground Segment operations are implemented through a set of service contracts that are either based on a full service approach, e.g. for payload data acquisition, or on a delegated service approach as for systematic data production and mission planning, in which ground segment components specifically developed for Aeolus mission are operated. The Services performances are agreed and measured through service level agreements.

Global scientific payload data acquisition is guaranteed by KSAT with the combined usage of Svalbard and Troll X-band receiving stations. Level-2B and Level-2C products are systematically generated at ECMWF, European Centre for Medium-Range Weather Forecasts.

The current performances of the overall Aeolus ground segment will be provided, including its operations and planned evolution in the near future.

How to cite: Fischer, P., Mellano, L., De Laurentis, M., Aprile, S., and Biscuso, A.: Aeolus: Payload Ground segment operations. Status, performances and evolution , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9226, https://doi.org/10.5194/egusphere-egu2020-9226, 2020.

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AEOLUS weekly mission planning concept and strategy

Marta De Laurentis, Peggy Fischer, Loretta Mizzi, and Luca Mellano

Launched in August 2018, Aeolus is the first remote sensing mission using a Doppler Wind Lidar for the observation of Earth’s wind and air circulation on a global scale. The main instrument ALADIN – Atmospheric LAser Doppler INstrument –  is measuring the atmospheric dynamics in the near-UV at wavelength of 355 nm, receiving back the signal through two different channels for clear air molecules (Rayleigh) and aerosol and clouds particles (Mie).

ALADIN operations are commanded from ground and are a combination of wind acquisitions and in-flight calibrations, for monitoring the instrument health and improving data quality. The mission is based on a planning cycle of 111 orbits, covering exactly one calendar week, for ~16 orbits per day.

The analysis of the weekly mission planning is performed taking into account a number of requirements and constraints at different levels, including platform and instrument system requirements, calibrations measurement performance, NRT data optimisation, science and cal/val requests, and requirements in support to collocated measurement campaigns. Once the analysis is done, the planning is then built into a timeline of consecutive requests for changing measurement mode, using specific instrument parameters tables.

This poster will provide an overview of the Aeolus weekly mission planning concept, strategy and methodology, together with a description of the major operations events for Aladin FM-A and FM-B instruments during the operational phase.

How to cite: De Laurentis, M., Fischer, P., Mizzi, L., and Mellano, L.: AEOLUS weekly mission planning concept and strategy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13908, https://doi.org/10.5194/egusphere-egu2020-13908, 2020.

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VirES for Aeolus - Online visual analysis of Aeolus data

Daniel Santillan, Christian Schiller, Markus Meringer, Oliver Reitebuch, Fabian Weiler, and Dorit Huber

VirES (Virtual Workspace for Earth Observation Scientists) is a highly interactive data manipulation and retrieval interface for specific ESA Earth Explorer mission products. It is under evolutionary/operational maintenance by EOX since 2016 for the Swarm geomagnetic mission and starting 2018 it has been extended for ESA's Earth Explorer Aeolus wind profiling mission.

The goal of this service is to provide users with intuitive and easy access to the mission’s level 1B, 2A, 2B and several auxiliary data products.
In order to be able to understand, manage, visualize and analyze the new and complex data produced by the satellite a close collaboration between project partners DLR and DoRIT and EOX as industry partner has been established.

VirES for Aeolus provides means for multi-dimensional visualization, interactive plotting and analysis and stands for a modern concept of extended access to Earth Observation (EO) data. It supports novel ways of data discovery, visualization, filtering, selection, analysis, snapshotting and downloading.

The service was designed with a focus on the following areas of application:
Quality analysis, calibration and validation, scientific exploitation, modeling and prediction.

Specialized solutions have been developed to allow visualization of the complex and large datasets in an interactive and intuitive way. The tool has been further refined and improved since the Aeolus launch August 2018 in close collaboration with its users and project partners. VirES for Aeolus  offers easy access to the mission data through ordinary web browsers  via
without the need for installing any specialized software.

How to cite: Santillan, D., Schiller, C., Meringer, M., Reitebuch, O., Weiler, F., and Huber, D.: VirES for Aeolus - Online visual analysis of Aeolus data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22439, https://doi.org/10.5194/egusphere-egu2020-22439, 2020.

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Consolidation of Aeolus FMA and FMB datasets in the DSI X-PReSS Consortium: Methodology used to generate Master Datasets and the results that have been achieved

Nicola Comparetti, Gianluca Colamussi, Marta De Laurentis, Michel Douzal, Peggy Fischer, Alessandra Paciucci, Bart Schipperijn, Joost Smeets, and Marcella Veneziani

We present the methodology and results of the Aeolus VC01 and L0 FM-A and FM-B datasets consolidation performed by the X-PReSS team as part of the ESA (European Space Agency) Data Service Initiative (DSI) managed by ESA’s Ground Segment Operations Division. The goal of this activity is to generate master datasets and gap lists as well as assess data completeness for both future ESA reprocessing campaigns and data preservation activities. The consolidation was carried out first by removing fully overlapping products, products completely covered by other products (inside) and black-listed products. Secondly, remaining products HDR and DBL files were scanned to detect filename misalignments with specifications, intra-products and inter-products gaps and corrupted products. Ancillary data from several Aeolus facilities (KSAT, DISC, FOS, PDGS) were used for gaps justification and blacklisted products identification. For FM-A VC01, 4219 products were analysed. Out of these, 3927 were classified as Master, 142 as inside, 3 as Duplicates and 147 as Blacklisted. 57 gaps were found. No data corruption was found. No duplicated source packet data was found. Consolidation results are available at ESA and includes: list of gaps with metadata and known justification,  list of duplicated events with metadata, list of Instrument Function IDs with metadata, master dataset list and a list of discarded products including known justification.

How to cite: Comparetti, N., Colamussi, G., De Laurentis, M., Douzal, M., Fischer, P., Paciucci, A., Schipperijn, B., Smeets, J., and Veneziani, M.: Consolidation of Aeolus FMA and FMB datasets in the DSI X-PReSS Consortium: Methodology used to generate Master Datasets and the results that have been achieved, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6924, https://doi.org/10.5194/egusphere-egu2020-6924, 2020.

Title: One million feet view of Level-2 Processing Facility managed at European Centre for Medium-Range Weather Forecasts (ECMWF)

Authors: Rakesh Prithiviraj, Ioannis Mallas, Cristiano Zanna 

Affiliation of authors: European Centre for Medium-Range Weather Forecasts (ECMWF)

Abstract text
Launched in August 2018, European Space Agency’s Aeolus satellite mission measures Earth's wind profile from space. The Aeolus ground segment mainly comprises of:
• Flight Operations Segment (FOS) to monitor and control Aeolus satellite and the instrument onboard, 
• Payload Data Ground Segment (PDGS) for the acquisition and systematic generation of Level-1A and Level-1B products and 
• Level-2 Processing Facility (L2PF) at ECMWF for the generation and dissemination of Level-2B and Level-2C products. 

ECMWF is both a research institute and a 24/7 operational service, producing global numerical weather predictions and other data for our Member and Co-operating States and the broader community. ECMWF relies on its atmospheric model and data assimilation system which is called the Integrated Forecasting System (IFS) to make weather predictions. ECMWF has one of the largest supercomputer facilities and meteorological data archives in the world.

This talk focusses on the Aeolus L2PF facility at ECMWF providing an overview of the processing infrastructure, relevant dataflows, monitoring system and presents the technical/system perspective of Aeolus L2PF in the context of weather forecast. The L2PF facility receives L1B data from Aeolus PDGS and systematically generates and disseminates L2B products and L2C products. The centre is also responsible for the generation of meteorological auxiliary data which is one of the critical inputs for the L2B generation.  The talk also shows various components at ECMWF that work together to achieve more than 99% L2B completeness. The components include ECMWF Production Data Store (ECPDS), ECMWF's High Performance Computing Facility (HPCF) and L2PF cluster. 

The talk concludes with references to tests carried out at ECMWF that have demonstrated that new wind profile observations from Aeolus satellite significantly improve weather forecasts, particularly in the southern hemisphere and the tropics. Because the positive impact of Aeolus on the weather predictions, Aeolus data is expected to be part of the operational weather forecast system at ECMWF in January 2020.

How to cite: Prithiviraj, R.: One million feet view of Level-2 Processing Facility managed at European Centre for Medium-Range Weather Forecasts (ECMWF), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2391, https://doi.org/10.5194/egusphere-egu2020-2391, 2020.

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Validation of Aeolus winds using atmospheric radars in Arctic Sweden and in Antarctica and NWP modelling

Magnus Lindskog, Evgenia Belova, Peter Voelger, Sheila Kirkwood, Heiner Körnich, Susanna Hagelin, Sourav Chatterjee, and Karathazhiyath Satheesan

ESRAD and MARA, , respectivelyThe Aeolus HLOS wind component (L2B) is also compared to the corresponding component of winds derived from the HARMONIE model for the ESRAD collocations and from the ECMWF ERA5 re-analysis for the MARA collocations. We estimate bias, root-mean-squared error and correlation for the Aeolus winds the radar and model data.

 

 

How to cite: Lindskog, M., Belova, E., Voelger, P., Kirkwood, S., Körnich, H., Hagelin, S., Chatterjee, S., and Satheesan, K.: Validation of Aeolus winds using atmospheric radars in Arctic Sweden and in Antarctica and NWP modelling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4928, https://doi.org/10.5194/egusphere-egu2020-4928, 2020.

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Stratospheric Australian fire smoke layers over Punta Arenas, Chile, measured by ground-based lidar and AEOLUS

Kevin Ohneiser, Holger Baars, Cristofer Jimenez, Johannes Bühl, Patric Seifert, Athina Floutsi, Martin Radenz, Ulla Wandinger, and Albert Ansmann

Exceptionally strong wildfire activity in Australia in summer 2019-2020 triggered the evolution of pyrocumulonimbus clouds, releasing enormous amounts of fire smoke into the upper troposphere and lower stratosphere region of the usually very clean southern hemisphere. Measurements at the lidar site of Punta Arenas (53°S), Chile, show that the first stratospheric smoke layers arrived over Punta Arenas at 6 Jan 2020.

First results show striking similarities to a record-breaking event of stratospheric smoke layers from wildfires in Canada in 2017 (Baars et al., ACP 2019). At Punta Arenas, lidar ratios reach values of 45-50 sr at 355 nm, and 60-65 sr at 532 nm wavelength. Particle linear depolarization ratios reach values of 19% at 355 nm, and 15% at 532 nm wavelength.

Aeolus is able to detect these intense layers of stratospheric smoke in the southern hemisphere as well. In this contribution, we will discuss our findings of extensive and intensive smoke optical properties over Punta Arenas to the related Aeolus aerosol spin off products of nearby overpasses. Especially the particle linear depolarization ratio at 355 nm are of relevance as AEOLUS is only able to measure the co-polarized 355 nm signal.

How to cite: Ohneiser, K., Baars, H., Jimenez, C., Bühl, J., Seifert, P., Floutsi, A., Radenz, M., Wandinger, U., and Ansmann, A.: Stratospheric Australian fire smoke layers over Punta Arenas, Chile, measured by ground-based lidar and AEOLUS, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5140, https://doi.org/10.5194/egusphere-egu2020-5140, 2020.

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Statistically based calibration/validation control of space-borne lidars: application to ALADIN lidar onboard ADM/Aeolus

Artem Feofilov, Helene Chepfer, Vincent Noel, and Marjolaine Chiriaco

Clouds and aerosols play an important role in the Earth’s energy budget through a complex interaction with solar, atmospheric, and terrestrial radiation, and air humidity. Optically thick clouds efficiently reflect the incoming solar radiation and, globally, clouds are responsible for about two thirds of the planetary albedo. Thin cirrus trap the outgoing longwave radiation and keep the planet warm. Aerosols scatter or absorb sunlight depending on their size and shape and interact with clouds in various ways.

Due to the importance of clouds and aerosols for the Earth’s energy budget, global satellite observations of their properties are essential for climate studies, for constraining climate models, and for evaluating cloud parameterizations. Active sounding from space by lidars and radars is advantageous since it provides the vertically resolved information. This has been proven by CALIOP lidar which has been observing the Earth’s atmosphere since 2006. Another instrument of this kind, CATS lidar on-board ISS provided measurements for over 33 months starting from the beginning of 2015. The ALADIN lidar on-board ADM/Aeolus has been measuring horizontal winds and aerosols/clouds since August 2018. More lidars are planned – in 2021, the ATLID/EarthCare lidar will be launched and other space-borne lidars are currently in the development phase.

Needless to say that the quality of the retrieved data strongly depends on the quality of the calibration of the lidar system and its components. Besides “classical” calibration methods (laboratory calibration, calibration in space using on-board sources and/or known external sources and  calibration through collocation, which involves comparisons with ground-based station-, balloon-, and aircraft measurements), one can also make use of a vicarious calibration, where the sites with known properties are used. In this work, we use the whole atmosphere for quality control of the space-borne lidar system, which includes the laser, the sending optics, the receiver with its telescope, and the detection system.

We describe the quality control approach based on a set of several indicators, which characterize the behavior of the lidar system on a day-to-day basis using the L1 (and even L2) data as an input. With the help of this set one can trace:

(a) the stability of the detection chain for the lidar channels (Rayleigh, Mie);

(b) the drift of crosstalk coefficients;

(c) the stability of day- and nighttime stratospheric noise;

(d) the stability of the radiation detection for all atmospheric scenarios and over the whole globe using a clustering algorithm applied to the scattering ratio (SR) histograms.

We demonstrate the results using the L1B and L2A data flow of Aeolus obtained from the first days of its operation and up to now, compare them with the results obtained for CALIOP, and discuss the applications of the approach.

How to cite: Feofilov, A., Chepfer, H., Noel, V., and Chiriaco, M.: Statistically based calibration/validation control of space-borne lidars: application to ALADIN lidar onboard ADM/Aeolus, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10697, https://doi.org/10.5194/egusphere-egu2020-10697, 2020.

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Validation for ESA’s Aeolus Mission using the in-situ instruments at Canadian Arctic and reanalysis data

Chih-Chun Chou, Paul Kushner, Zen Mariani, Peter Rodriguez, and Christopher Fletcher

ESA’s Aeolus mission, launched in August 2018, is designed to capture tropospheric wind profiles on a global scale in near-real time. The Aeolus lidar system, Atmospheric LAser Doppler INstrument (ALADIN), uses two modes of lidar-driven active scattering, Mie and Rayleigh scattering channels, to retrieve horizontal line-of-sight (HLOS) winds under both clear and cloudy conditions. ESA Aeolus aims to improve numerical weather and climate prediction, and to advance understanding of atmospheric circulation and weather systems.

This presentation will describe the Canadian validation activities for ESA Aeolus level-2B product, coordinated by the University of Toronto’s Department of Physics and Environment and Climate Change Canada (ECCC). The main focus is the evaluation of Aeolus overpasses using the fifth major global reanalysis produced by the European Centre for Medium-Range Weather Forecasts (ECMWF ERA5), and in-situ measurements at Environment and Climate Change Canada’s (ECCC) Iqaluit and Whitehorse supersites where several wind sensing instruments are co-located. It will compare the Aeolus HLOS winds with the profiles of wind vector from regular radiosonde launches, line-of-sight winds from Doppler Lidar and Ka-Band Radar. The accuracy of the Aeolus measurements is analyzed based on the type of scattering and natural variability of the wind on different levels.

The radiosonde measures the profiles of temperature, relative humidity, pressure, and winds twice a day with a vertical resolution of 15 m up to 30 km. On the other hand, the Mie scattered 1.5 micron Doppler Lidar retrieves LOS winds at every 3 m as well as aerosol backscatter and depolarization ratio every 5 minutes up to 3 km. Lastly, for every 10 minutes, the dual-polarization Doppler Ka-Band Radar measures the LOS wind speed and direction, cloud and fog backscatter, and depolarization ratio up to a range of 25 km with a vertical resolution of 10 m.

The wind profiles were directly compared to the profiles derived from other instruments or reanalysis. The vertical structure of the Aeolus winds, for example the wind shear, will also be compared and discussed. The validation results showed that Aeolus is providing some promising initial products and that the ERA5 reanalysis is the most consistent dataset with the Aeolus wind measurements from level-2B product.

How to cite: Chou, C.-C., Kushner, P., Mariani, Z., Rodriguez, P., and Fletcher, C.: Validation for ESA’s Aeolus Mission using the in-situ instruments at Canadian Arctic and reanalysis data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13461, https://doi.org/10.5194/egusphere-egu2020-13461, 2020.

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The ERATOSTHENES Remote Sensing Supersite: Ground-truth observations over Cyprus

Rodanthi-Elisavet Mamouri, Argyro Nisantzi, Albert Ansmann, Johannes Bühl, Patric Seifert, Holger Baars, Vassilis Amiridis, Ulla Wandinger, and Diofantos Hadjimitsis

Cyprus is strategically located in the region of the Eastern Mediterranean, the Middle East and North Africa (EMMENA). As a crossroad between Europe, Asia and Africa, it is representative of meteorological conditions and coastal areas in the EMMENA region.

Incomplete coverage with ground monitoring stations is the main limitation to make fast and significant progress in understanding the complex climate-relevant atmospheric processes around the globe and thus to improve atmospheric models used for climate change projections and extreme weather predictions. Although satellites can continuously monitor the atmosphere on a regional to global scale, they must be ground-calibrated and validated in order to incorporate satellite data into atmospheric models.

Cyprus, and especially Limassol as a coastal city, can be considered an ideal natural laboratory for advanced and comprehensive field studies on climate change, aerosol-cloud-dynamics-precipitation interaction, and the weather-precipitation-dryness complex, providing additionally valuable ground truthing observations for satellite missions.

The vision of the ERATOSTHENES Research Centre (ERC) in Cyprus is to become a Centre of Excellence for Earth Surveillance and Space-Based Monitoring of the Environment, in the framework of the EU H2020 Teaming project EXCELSIOR. Within this vision, a modern observational super site in Cyprus is of fundamental importance and will be build up for long-term profiling of the atmosphere (wind, humidity, aerosol and cloud properties, precipitation fields), in one of the hot spots of climate change increasing extreme weather events.

The ERATOSTHENES station in Limassol, Cyprus with the current instrumentation (EARLINET Raman depolarization lidar) follows the CAL/VAL activities of the AEOLUS satellite launched August 2018 through the participation to the VADAM project. Selected cases that demonstrate the complex aerosol and meteorological conditions over Eastern Mediterranean will be presented as well as lidar observations during AEOLUS overpasses over Cyprus.

Acknowledgements

The authors acknowledge the EXCELSIOR H2020-WIDESPREAD-04-2017: Teaming Phase2 project under grant agreement No 857510, ACTRIS and the ESA AEOLUS CAL/VAL VADAM project (27409). CUT team acknowledge Research and Innovation Foundation for the financial support through the SIROCCO (EXCELLENCE/1216/0217) and AQ-SERVE (INTERGRATED/0916/0016) projects.

How to cite: Mamouri, R.-E., Nisantzi, A., Ansmann, A., Bühl, J., Seifert, P., Baars, H., Amiridis, V., Wandinger, U., and Hadjimitsis, D.: The ERATOSTHENES Remote Sensing Supersite: Ground-truth observations over Cyprus, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17658, https://doi.org/10.5194/egusphere-egu2020-17658, 2020.

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Experimental Validation and Assimilation of Aeolus Wind Observations

Anne Martin, Alexander Geiss, Alexander Cress, and Martin Weissmann

The earth explorer mission Aeolus from the European Space Agency for the first time worldwide opens up the possibility to directly observe Earths’ wind profiles from space. Aeolus carries a Doppler wind lidar operating at 335 nm which measures the Doppler frequency shift of backscattered laser light from air molecules and particles up to 30 km accumulated in 0.25 - 2 km vertical range bins. It’s expected that such global coverage of wind profiles helps to fill a gap in the global observing system.

As part of the German initiative EVAA (Experimental Validation and Assimilation of Aeolus observations) validation and monitoring activities for Aeolus are performed to determine and understand observation systematic and random errors. Independent ground-based measurements from radiosondes and tropospheric radar wind profilers are used as reference for the evaluation of Aeolus winds. In addition monitoring results from the global model ICON from the German Weather Service (DWD) are used to examine the results and investigate bias dependencies. An accurate understanding of the systematic errors of Aeolus wind observations is necessary for data assimilation processes. First impact experiments with an established bias correction for Aeolus wind data were run at DWD showing encouraging results for forecast improvements in upper tropospheric and lower stratospheric tropics and southern hemisphere.

How to cite: Martin, A., Geiss, A., Cress, A., and Weissmann, M.: Experimental Validation and Assimilation of Aeolus Wind Observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18186, https://doi.org/10.5194/egusphere-egu2020-18186, 2020.

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Aeolus / ALADIN data analysis in Korea

Hyemin Shin, Myoung-Hwan Ahn, Jisoo Kim, and Chu-Yong Chung

The assimilation of the Atmospheric Laser Doppler Instrument (ALADIN) wind profile data is expected to play a significant role in improving the skills of numerical weather prediction model. In this study, we analyze the Aeolus/ALADIN data over Korea region using data obtained by radiosonde, dropsonde and the ground based windprofiler. In addition, we analyze data by comparing with atmospheric movement vector (AMV) derived from the Geostationary Korea Multi Purpose Satellite -2A (GK-2A). The ALADIN wind data within the 150 km from the radiosonde/dropsonde/windprofiler station and within ±60 minutes to their observation time are collocated. The AMV data having the closest altitude to the ALADIN altitude are compared, within the 150 km from the ALADIN observation. With the limited number of collocated data obtained from August 29th to September 1th, 2019, the comparison results show a rather large discrepancy. In case of the radiosonde, RMSD is estimated to be 2.50 m/s and 2.67 m/s in the Rayleigh channel and the Mie channel, respectively. In case of the AMV, the error statistics varies significantly with the quality index of AMV data. When the quality index of 0.8 is applied to the AMV data, RMSD for the infrared AMV is about 3.36 m/s. In the conference, comparison results of all instruments along with the extended time period are going to be presented.

How to cite: Shin, H., Ahn, M.-H., Kim, J., and Chung, C.-Y.: Aeolus / ALADIN data analysis in Korea , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19595, https://doi.org/10.5194/egusphere-egu2020-19595, 2020.

EGU2020-19786 | Displays | AS1.35

Validation of ESA Aeolus wind observations using French ground-based Rayleigh Doppler lidars at midlatitude and tropical sites

Alain Hauchecorne, Sergey Khaykin, Robin Wing, Jean-François Mariscal, Jacques Porteneuve, Jean-Pierre Cammas, Nicolas Marquestaut, Guillaume Payen, and Valentin Duflot

French ground-based Rayleigh Doppler lidars deployed at Observatoire de Haute Provence (OHP) in southern France (44° N, 6° E) and Observatoire du Maido (La Reunion island, tropical Indian Ocean, 21° S, 55° E) are among the primary instruments within ESA Aeolus Cal/Val programme.  The ground-based lidars are designed to measure vertical profiles of wind velocity in the altitude range 5 - 70 km with an accuracy better than 1 m/s up to 30 km. The horizontal wind components are obtained by measuring Doppler shift between emitted and backscattered light by means of double-edge Fabry-Perot interferometer. This technique, pioneered by French Service d’Aeronomie in 1989, is implemented in Aeolus ALADIN instrument.

We present the results of validation of Aeolus L2B horizontal line-of-sight wind profiles using the French Doppler lidars and regular radiosoundings. The point-by-point validation exercise relies on the dedicated validation campaigns at OHP in January and Maido in September-October 2019 involving simultaneous lidar acquisitions and collocated radiosonde ascents coincident with the nearest Aeolus overpasses. For evaluation of the long-term variation of the bias in Aeolus wind product, we use twice-daily routine radiosoundings performed by MeteoFrance and regular wind lidar observations at both sites.

The orbital configuration of Aeolus satellite enables 2 overpasses per week above OHP within 100 km range and 2 overpasses in the vicinity of Maido observatory, of which one being within 10 km range. Evaluation of Aeolus wind profiles is done in consideration of the expected mesoscale variability of wind field inferred from numerous lidar-radiosonde intercomparisons at both stations. In addition to the quantitative validation of Aeolus wind profiles, we attempt to evaluate the capacity of Aeolus observations in resolving fluctuations of stratospheric wind field induced by atmospheric gravity waves.

How to cite: Hauchecorne, A., Khaykin, S., Wing, R., Mariscal, J.-F., Porteneuve, J., Cammas, J.-P., Marquestaut, N., Payen, G., and Duflot, V.: Validation of ESA Aeolus wind observations using French ground-based Rayleigh Doppler lidars at midlatitude and tropical sites, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19786, https://doi.org/10.5194/egusphere-egu2020-19786, 2020.

EGU2020-14242 | Displays | AS1.35

Validation of Aeolus aerosol and wind products with sophisticated ground-based instruments in the Northern and Southern Hemisphere

Holger Baars, Alina Herzog, Ronny Engelmann, Johannes Bühl, Martin Radenz, Patric Seifert, Albert Ansmann, Dietrich Althausen, Birgit Heese, Julian Hofer, Kevin Ohneiser, Karsten Hanbuch, Elizaveta Basharova, Tülin Gülbas, Alexandra Chudnovsky, Boris Barja, Maria Filioglou, Mika Komppula, and Ulla Wandiger

The European Space Agency (ESA) has launched the Earth Explorer Mission Aeolus on 22 August 2018. Within the German initiative EVAA (Experimental Validation and Assimilation of Aeolus observations), Cal/Val activities for Aeolus started immediately after the instrument was turned on in space. The aim is to validate the wind and aerosol products of Aeolus and to quantify the benefits of these new measurements for weather forecasting and aerosol and cloud research.
For this purpose, ground-based aerosol and wind lidar observations have been performed at the Leibniz Institute for Tropospheric Research (TROPOS) in Leipzig, Germany, and at Punta Arenas (53.13 S, 70.88 W), Chile, in the frame of the DACAPO-PESO campaign (dacapo.tropos.de). Radiosondes have been launched during the Aeolus overpasses each Friday at Leipzig in addition since mid of May 2019. In Punta Arenas, we also used Doppler cloud radar observations with respect to the validation of Mie and Rayleigh winds of Aeolus.  

Aerosol-only observations with multiwavelength-Raman polarization lidar were made at the PollyNET (Baars 2016) stations in Haifa (Israel), Dushanbe (Tajikistan), Tel Aviv (Israel), and in the United Arab Emirates (UAE) - the latter two are hosted by PollyNET partner institutions (Baars, 2016). These locations are close to the desert with frequent dense, lofted aerosol layers and are thus of particular interest for Aeolus Cal/Val. Considering the long averaging length of Aeolus (87 km) and the distance to the lidars (max. 100 km), a good agreement with respect to the co-polar backscatter coefficient is found between Aeolus and the ground-based lidars at these locations.

We will present results from the above-mentioned Cal/Val activities with respect to, both, wind and aerosol products of Aeolus. It will be shown, that one of the mission goals, namely the demonstration that wind observations from space by active remote sensing are possible, have been already achieved. Furthermore, it will be demonstrated that the spaceborne HSRL (high spectral resolution lidar) technique applied for Aeolus can provide independent backscatter and extinction measurements of aerosols – a spaceborne novelty as well. Since September 2019, also an aerosol-optimized range resolution, the so-called Mediterranean range-bin setting (MARS), is operational for Aeolus in the Eastern Mediterranean. First results show a significantly improved aerosol retrieval for this adapted instrumental setting and will be presented as well.

 

Reference:

Baars, H., et al. (2016), An overview of the first decade of PollyNET: An emerging network of automated Raman-polarization lidars for continuous aerosol profiling, Atmos. Chem. Phys., 16(8), 5111-5137, doi:10.5194/acp-16-5111-2016.

How to cite: Baars, H., Herzog, A., Engelmann, R., Bühl, J., Radenz, M., Seifert, P., Ansmann, A., Althausen, D., Heese, B., Hofer, J., Ohneiser, K., Hanbuch, K., Basharova, E., Gülbas, T., Chudnovsky, A., Barja, B., Filioglou, M., Komppula, M., and Wandiger, U.: Validation of Aeolus aerosol and wind products with sophisticated ground-based instruments in the Northern and Southern Hemisphere , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14242, https://doi.org/10.5194/egusphere-egu2020-14242, 2020.

EGU2020-5362 | Displays | AS1.35

Aeolus aerosol and cloud product

Alain Dabas, Thomas Flament, Dimitri Trapon, and Dorit Huber

Aeolus is a high-spectral resolution UV lidar. It implements two detection channels, a broadband (Rayleigh channel) and a narrowband (Mie channel). Carefully calibrated, the combination offers the possibility to derive independent estimates of the backscatter and extinction coefficients of the clouds and the aerosols, thus opening the possibility to acquire an information on their nature with the extinction-to-backscatter ratio. The presentation will show how the level-2A processor of the mission works for the retrieval of optical properties of cloud and aerosol particles, what products can be obtained with what limitations. The potential of L2A processor will be illustrated by results obtained on real data acquired since AEOLUS launch.

How to cite: Dabas, A., Flament, T., Trapon, D., and Huber, D.: Aeolus aerosol and cloud product, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5362, https://doi.org/10.5194/egusphere-egu2020-5362, 2020.

EGU2020-7146 | Displays | AS1.35

ESA’s Wind Lidar Mission Aeolus – Instrument Performance and Stability

Thomas Kanitz, Benjamin Witschas, Uwe Marksteiner, Thomas Flament, Michael Rennie, Marc Schillinger, Tommaso Parrinello, Denny Wernham, and Oliver Reitebuch

The European Space Agency, ESA deployed the first Doppler wind lidar in space within its Earth Explorer Mission Aeolus in August 2018. After the initial commissioning of the satellite and the single payload ALADIN, the mission has started to demonstrate the capability of Doppler lidar to measure wind from space. In order to provide the best Aeolus wind product possible, detailed monitoring of the instrument is crucial for analysis of system health, but also for the assessment of measurement performance and data product calibration. Within the last 1.2 years the different instrument modes to assess instrument and laser health, as well as the nominal wind processing indicated longterm instrument drifts. The laser beam profile has been monitored and showed an energy redistribution within the beam. The line of sight has slowly drifted, resulting in a change of incidence angle at spectrometer level. The impact of these observed drifts on the wind product are compensated on demand by updates of dedicated ground processing calibration files. This contribution will provide an overview about the Aeolus instrument modes and the observed stability that are needed to provide the Aeolus wind product. The current Aeolus performance has been assessed by various Numerical Weather Prediction centers. The positive outcome is represented by ECMWF’s decision to start using Aeolus data operationally on 9th January 2020.

How to cite: Kanitz, T., Witschas, B., Marksteiner, U., Flament, T., Rennie, M., Schillinger, M., Parrinello, T., Wernham, D., and Reitebuch, O.: ESA’s Wind Lidar Mission Aeolus – Instrument Performance and Stability, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7146, https://doi.org/10.5194/egusphere-egu2020-7146, 2020.

EGU2020-21436 | Displays | AS1.35

The ESA-funded Aeolus/EarthCARE Aerosol Assimilation Study (A3S)

Julie Letertre-Danczak, Angela Benedetti, Samuel Quesada-Ruiz, Alain Dabas, and Thomas Flament

How to cite: Letertre-Danczak, J., Benedetti, A., Quesada-Ruiz, S., Dabas, A., and Flament, T.: The ESA-funded Aeolus/EarthCARE Aerosol Assimilation Study (A3S), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21436, https://doi.org/10.5194/egusphere-egu2020-21436, 2020.

AS1.36 – Precipitation: Measurement, Climatology, Remote Sensing, and Modelling

EGU2020-7837 | Displays | AS1.36

Global observation-based climatology of precipitation occurrence and peak intensity

Hylke Beck, Seth Westra, and Eric Wood

We introduce a unique set of global observation-based climatologies of daily precipitation (P) occurrence (related to the lower tail of the P distribution) and peak intensity (related to the upper tail of the P distribution). The climatologies were produced using Random Forest (RF) regression models trained with an unprecedented collection of daily P observations from 93,138 stations worldwide. Five-fold cross-validation was used to evaluate the generalizability of the approach and to quantify uncertainty globally. The RF models were found to provide highly satisfactory performance, yielding cross-validation coefficient of determination (R2) values from 0.74 for the 15-year return-period daily P intensity to 0.86 for the >0.5 mm d-1 daily P occurrence. The performance of the RF models was consistently superior to that of state-of-the-art reanalysis (ERA5) and satellite (IMERG) products. The highest P intensities over land were found along the western equatorial coast of Africa, in India, and along coastal areas of Southeast Asia. Using a 0.5 mm d-1 threshold, P was estimated to occur 23.2 % of days on average over the global land surface (excluding Antarctica). The climatologies including uncertainty estimates will be released as the Precipitation DISTribution (PDIST) dataset via www.gloh2o.org/pdist. We expect the dataset to be useful for numerous purposes, such as the evaluation of climate models, the bias correction of gridded P datasets, and the design of hydraulic structures in poorly gauged regions.

How to cite: Beck, H., Westra, S., and Wood, E.: Global observation-based climatology of precipitation occurrence and peak intensity, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7837, https://doi.org/10.5194/egusphere-egu2020-7837, 2020.

EGU2020-1275 | Displays | AS1.36

Decadal trends in convection from satellite microwave observations of near-surface wind and deep precipitating clouds

Ziad Haddad, Svetla Hristova-Veleva, and Nobuyuki Utsumi

Since the past decade, evidence derived from model reanalysis (including outgoing longwave radiation, tropopause height, the latitude where zonal mean precipitation exceeds evaporation, and the latitude where the zonal mean 500-hPa meridional streamfunction crosses from positive to negative) indicate that the tropics have been expanding since at least 1979, by a very approximate one degree per decade. To the reanalysis evidence, we have added our direct analysis of near-surface wind estimated from satellite radar scatterometty. These show a widening of the Hadley circulation, with a distinct poleward migration of the zonally-averaged crossing latitudes (from easterly trade winds in the tropics to the mid-latitude westerly winds) by about 1 degree per decade. This begs the question: are the precipitation patterns changing accordingly? The brief answer, derived from analysis of the Tropical Rainfall Measuring Mission radar data, is that deep storm top heights in the tropics showed a monotone increase over the 16-year TRMM record, but their occurrences became steadily less frequent. This will be described in more detail, along with a method to increase the sample size from the rather poor temporal sampling by the TRMM radar to a 50-fold larger sample from the microwave radiometer constellation.

How to cite: Haddad, Z., Hristova-Veleva, S., and Utsumi, N.: Decadal trends in convection from satellite microwave observations of near-surface wind and deep precipitating clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1275, https://doi.org/10.5194/egusphere-egu2020-1275, 2020.

EGU2020-8413 | Displays | AS1.36

Uncertainty in decadal precipitation estimates over the Rur catchment

Manuel F. Rios Gaona, Prabhakar Shrestha, and Clemens Simmer

Precipitation is an important input for hydrological models. Uncertainty in its spatiotemporal variability is a major error source for forecasts generated with distributed hydrological models, because this uncertainty propagates non-linearly into simulated soil moisture patterns, groundwater table depths, discharge and surface energy flux partitioning. Thus, it is imperative to use accurate rainfall datasets that reproduce rainfall's intrinsic highly-spatiotemporal variability to obtain better forecasts from hydrological models.

In this study, we present the evaluation of the high-resolution precipitation product RADKLIM against precipitation from the COSMO-DE analysis over the Rur catchment, in western Germany, at a decadal time scale (2007-2015). RADKLIM is the climate version of the quantitative precipitation estimation product RADOLAN developed by the German national weather service (DWD, Deutscher Wetterdienst) by adjusting radar-derived estimates to gauge observations. Its spatiotemporal resolution is ~1x1 km and 5 minutes. The hourly COSMO-DE analysis precipitation data is obtained from the German weather forecast model (also available from DWD) with a spatial resolution of ~2.8x2.8 km. To make a scale-consistent comparison, the RADKLIM product was upscaled to the COSMO-DE resolution.

Overall, the COSMO-DE analysis yields over the studied area 50% more of the average precipitation of the RADKLIM product. The highest biases (COSMO-DE over RADKLIM) predominantly occur during afternoon (i.e., 15:00 - 21:00), and in the summer season; whereas the negative biases predominantly occur during autumn, with their highest in the early afternoon (i.e., 12:00 - 18:00).

How to cite: Rios Gaona, M. F., Shrestha, P., and Simmer, C.: Uncertainty in decadal precipitation estimates over the Rur catchment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8413, https://doi.org/10.5194/egusphere-egu2020-8413, 2020.

EGU2020-18366 | Displays | AS1.36

The role of free-stream turbulence on the collection performance of catching type precipitation gauges

Arianna Cauteruccio, Matteo Colli, and Luca G. Lanza

The numerical studies reported in the literature about the wind-induced bias of precipitation measurements assume that turbulence is only generated by the interaction of the airflow with the gauge body, and the associated CFD simulations are generally performed under the hypothesis of steady and uniform incoming airflow. However, wind is turbulent in nature due to the roughness of the site and the presence of obstacles so that, in operational conditions, precipitation gauges are immersed in a turbulent flow. In this work, further to the role of the local generation of turbulence due to the obstruction to the airflow caused by the bluff body nature of the precipitation gauge, the natural free-stream turbulence inherent to the wind, and its influence on precipitation measurements, are investigated. With the aim to obtain turbulence intensity values characterizing the wind near to the ground surface, 3-D sonic anemometer measurements at the gauge collector height were preliminarily analyzed. Data were kindly provided by Environmental Measurements Ltd. (EML) from the Nafferton (UK) experimental site and are composed of 38 minutes of high-frequency (20 Hz) wind measurements. The role of the free-stream turbulence on the collection performance of a chimney shaped gauge was investigated by performing Large Eddy Simulations (LES) both in uniform and turbulent free-stream conditions. The free-stream turbulence was generated by introducing geometrical obstacles upstream of the gauge and their distance from the gauge, along the longitudinal direction, was calibrated to obtain the desired level of turbulence intensity, as measured at the Nafferton site. The two free-stream turbulence conditions were compared in terms of catch ratios and collection efficiency. Catch ratios for dry snow particles were obtained by running a literature Lagrangian Particle Tracking model (Colli et al. 2015) applied to the LES airflow fields obtained for each free-stream turbulence condition. From the comparison, a stronger undercatch emerges for small size particles (less than 2mm) under turbulent free-stream conditions with respect to the uniform case, while the opposite occurs for larger particles (d > 2 mm). This is due to the higher attitude of the small size particles to follow the turbulent velocity fluctuations while larger particles are more inertial. The overall effect of the free stream turbulence on the collection performance of the gauge was quantified by computing the Collection Efficiency (CE) as the integral over the full range of particle diameters after assuming a suitable Particle Size Distribution (PSD) for the precipitation process. Results show that a higher CE is obtained under turbulent free-stream conditions, and demonstrated that the numerical derivation of correction curves for use in precipitation measurements as proposed in the literature based on the simplifying assumption of uniform free-stream conditions is affected by a systematic overestimation of the wind-induced error.

References:

Colli, M., Lanza, L.G., Rasmussen, R., Thériault, J.M., Baker, B.C. & Kochendorfer, J. An improved trajectory model to evaluate the collection performance of snow gauges.  Journal of Applied Meteorology and Climatology, 2015, 54, 1826–1836.

How to cite: Cauteruccio, A., Colli, M., and Lanza, L. G.: The role of free-stream turbulence on the collection performance of catching type precipitation gauges, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18366, https://doi.org/10.5194/egusphere-egu2020-18366, 2020.

EGU2020-17559 | Displays | AS1.36

A machine learning approach for faster and more accurate precipitation retrievals

Patrick Eriksson, Simon Pfreundschuh, Teo Norrestad, and Christian Kummerow

A novel method for the estimation of surface precipitation using passive observations from the GPM constellation is proposed. The method, which makes use of quantile regression neural networks (QRNNs), is shown to provide a more accurate representation of retrieval uncertainties, high processing speed and simplifies the integration of ancillary data into the retrieval. With that, it overcomes limitations of traditionally used methods, such as Monte Carlo integration as well as standard usage of machine learning.

The bulk of precipitation estimates provided by the Global Precipitation Measurement mission (GPM) is based on passive microwave observations. These data are produced by the GPROF algorithm, which applies a Bayesian approach denoted as Monte Carlo integration (MCI). In this work, we investigate the potential of using QRNNs as an alternative to MCI by assessing the performance of both methods using identical input databases.

The methods agree well regarding point estimates, but QRNN provides better estimates of the retrieval uncertainty at the same time as reducing processing times by an order of magnitude. As QRNN gives more precise uncertainty estimates than MCI, it gives an improved basis for further processing of the data, such as identification of extreme precipitation and areal integration.

Results so far indicate that a single network can handle all data from a sensor, which is in contrast to MCI where observations over oceans and different land types have to be treated separately. Moreover, the flexibility of the machine-learning approach opens up opportunities for further improvements of the retrieval: ancillary information can be easily incorporated and QRNN can be applied on multiple footprints, to make better use of spatial information. The effects of these improvements are investigated on independent validation data from ground-based precipitation radars.

QRNN is here shown to be a highly interesting alternative for GPROF, but being a general approach it should be of equally high interest for other precipitation and clouds retrievals.

How to cite: Eriksson, P., Pfreundschuh, S., Norrestad, T., and Kummerow, C.: A machine learning approach for faster and more accurate precipitation retrievals, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17559, https://doi.org/10.5194/egusphere-egu2020-17559, 2020.

EGU2020-7239 | Displays | AS1.36

Radar-based characterization of heavy precipitation in the eastern Mediterranean and its representation in a convection-permitting model

Efrat Morin, Moshe Armon, Francesco Marra, Yehouda Enzel, and Dorita Rostkier-Edelstein

Heavy precipitation events (HPEs) can lead to natural hazards (floods, debris flows) and contribute to water resources. Spatiotemporal rainfall patterns govern the hydrological, geomorphological and societal effects of HPEs. Thus, a correct characterization and prediction of rainfall patterns is crucial for coping with these events. However, information from rain gauges suitable for these goals is generally limited due to the sparseness of the networks, especially in the presence of sharp climatic gradients and small precipitating systems. Forecasting HPEs depends on the ability of weather models to generate credible rainfall patterns. In this study we characterize rainfall patterns during HPEs based on high-resolution weather radar data and evaluate the performance of a high-resolution (1 km2), convection-permitting Weather Research and Forecasting (WRF) model in simulating these patterns. We identified 41 HPEs in the eastern Mediterranean from a 24-year long radar record using local thresholds based on quantiles for different durations, classified these events into two synoptic systems, and ran model simulations for them. For most durations, HPEs near the coastline were characterized by the highest rain intensities; however, for short storm durations, the highest rain intensities were characterized for the inland desert. During the rainy season, center of mass of the rain field progresses from the sea inland. Rainfall during HPEs is highly localized in both space (<10 km decorrelation distance) and time (<5 min). WRF model simulations accurately generate the structure and location of the rain fields in 39 out of 41 HPEs. However, they showed a positive bias relative to the radar estimates and exhibited errors in the spatial location of the heaviest precipitation. Our results indicate that convection-permitting model outputs can provide reliable climatological analyses of heavy precipitation patterns; conversely, flood forecasting requires the use of ensemble simulations to overcome the spatial location errors.

How to cite: Morin, E., Armon, M., Marra, F., Enzel, Y., and Rostkier-Edelstein, D.: Radar-based characterization of heavy precipitation in the eastern Mediterranean and its representation in a convection-permitting model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7239, https://doi.org/10.5194/egusphere-egu2020-7239, 2020.

EGU2020-10407 | Displays | AS1.36

Rainfall estimate using Commercial Microwave Links (CML): first outcomes of the MOPRAM project

Roberto Nebuloni, Michele D'Amico, Greta Cazzaniga, Carlo De Michele, and Cristina Deidda

The measurement of space-time rainfall fields is of great importance for several purposes including weather forecast, water resource management, evaluation of hydrological risk and monitoring of hydrologic extremes. Conventional methods for rainfall measurement include rain gauges and weather radars, both types of sensor having their own advantages and limitations. A different and not fully tested methodology exploits the power loss (namely, the attenuation) experienced by microwave radio signals when travelling across rain along either terrestrial or ground-to-satellite links. Indeed, it is well known that microwave attenuation due to rain can be calculated from the rain rate along the propagation path. The inverse problem can be solved once the disturbances affecting the radio signal and not induced by rain have been identified and removed.

In this contribution, we present the first results of the experimental campaign carried out in the framework of MOPRAM (MOnitoring Precipitation through a Network of RAdio links at Microwaves). MOPRAM is a scientific project funded by Fondazione Cariplo, which aims at assessing the potential of Commercial Microwave Links (CML) for rainfall estimates and rainfall field retrieval in areas of hydrological interest located in Northern Italy. A network of CMLs, owned by a major mobile operator in Italy, has been exploited to estimate the average rain rate along each link. The available data are the minimum and maximum values of the transmitted and received signal power across each link (two-ways), measured during 15-min time slots.

We start by describing the procedure adopted for the estimation of the baseline, i.e. the received power level immediately before and after a precipitation event. Rain attenuation is subsequently calculated by subtracting the received power during the event from the baseline level. To this aim, every 15-min slot of each link is classified in advance as either wet or dry by taking advantage of the spatial correlation of rain. Path-averaged rainfall intensity can be retrieved from rain attenuation by formulas based on well-known electromagnetic models. Finally, CML-based rainfall is compared with the one obtained from co-located rain gauges and disdrometers.

Despite the CML setup is not optimized for rainfall measurements, preliminary results highlight a good correlation between the occurrence of wet periods detected by CMLs on one side and by rain gauges and disdrometers on the other, as well as a fair agreement between the corresponding time series of accumulated precipitation.

How to cite: Nebuloni, R., D'Amico, M., Cazzaniga, G., De Michele, C., and Deidda, C.: Rainfall estimate using Commercial Microwave Links (CML): first outcomes of the MOPRAM project, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10407, https://doi.org/10.5194/egusphere-egu2020-10407, 2020.

EGU2020-5282 | Displays | AS1.36 | Highlight

IMERG Multi-Satellite Products Across Two Decades

George J Huffman, David T. Bolvin, Dan Braithwaite, Kuolin Hsu, Robert J. Joyce, Christopher Kidd, Eric J. Nelkin, Soroosh Sorooshian, Jackson Tan, and Pingping Xie

The Version 06 Global Precipitation Measurement (GPM) mission products were completed over the last year, capping five years of development since the launch of the GPM Core Observatory, and covering the joint Tropical Rainfall Measuring Mission (TRMM) and GPM eras with consistently processed algorithms.  The U.S. GPM team’s Integrated Multi-satellitE Retrievals for GPM (IMERG) merged precipitation product enforces a consistent intercalibration for all precipitation products computed from individual satellites with the TRMM and GPM Core Observatory sensors as the TRMM- and GPM-era calibrators, respectively, and incorporates monthly surface gauge data in the Final (research) product.  Mid-latitude calibrations during the TRMM era necessarily are more approximate because TRMM only covered the latitude band 35°N-S, while GPM covers 65°N-S.  Starting in V06, IMERG employs precipitation motion vectors (used to drive the quasi-Lagrangian interpolation, or “morphing”) that are computed by tracking the vertically integrated vapor as analyzed in MERRA2 and GEOS FP.  This approach covers the entire globe, expanding coverage beyond the 60°N-S latitude band provided by IR-based vectors in previous versions, although we choose to mask out microwave-based precipitation over snowy/icy surfaces as unreliable.

We will provide examples of performance for the V06 IMERG products, including comparison with the long-term record of GPCP and TMPA, showing higher values by about 8% in the latitude band 50°N-S over oceans; diurnal cycle, demonstrating improvement over previous versions; and daily precipitation PDFs for the entire record, showing a shift at the TRMM/GPM boundary, as well as interannual variations.  These analyses have important implications for the utility of V06 IMERG data for long-record calculations.  Finally, we will review the retirement of the predecessor TMPA multi-satellite dataset.

How to cite: Huffman, G. J., Bolvin, D. T., Braithwaite, D., Hsu, K., Joyce, R. J., Kidd, C., Nelkin, E. J., Sorooshian, S., Tan, J., and Xie, P.: IMERG Multi-Satellite Products Across Two Decades, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5282, https://doi.org/10.5194/egusphere-egu2020-5282, 2020.

EGU2020-1277 | Displays | AS1.36

The GPM Operational Radiometer Algorithm - Changes for 2021

Christian Kummerow and Paula Brown

The Global Precipitation Measurement (GPM) mission was launched in February 2014 as a joint mission between JAXA from Japan and NASA from the United States.  GPM carries a state of the art dual-frequency precipitation radar and a multi-channel passive microwave radiometer that acts not only to enhance the radar’s retrieval capability, but also as a reference for a constellation of existing satellites carrying passive microwave sensors.  In May of 2017, GPM released Version 5 of its precipitation products starting with GMI and continuing with the constellation of radiometers.  The precipitation products from these sensors are consistent by design and show relatively minor differences in the mean global sense.  Since this release, the Combined Algorithm hydrometeor profiles have shown good consistency with surface observations and computed brightness temperatures agree reasonably well with GMI observations in precipitating regions.  The same is true for MIRS profiles in non-precipitating regions.  Version 7 of the GPROF code will therefore make use of these operational products to construct it's a-priori databases.  This will allow continuous improvements in the a-priori database as these operational products are reprocessed with newer versions, while allowing the user community to better focus on the algorithm’s error covariance matrix and its validation.  Results from early versions of this algorithm will be presented.  In addition to creating an a-priori database that can be more directly updated with improvement to the raining and non-raining scenes, GPROF is also undertaking steps to improve the orographic representation of snow and a Neural Network based Convective/Stratiform classification of precipitation that will both help improve instantaneous correlations with in-situ observations.

How to cite: Kummerow, C. and Brown, P.: The GPM Operational Radiometer Algorithm - Changes for 2021, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1277, https://doi.org/10.5194/egusphere-egu2020-1277, 2020.

EGU2020-4282 | Displays | AS1.36

Recent status of the Dual-frequency Precipitation Radar (DPR) and the Global Satellite Mapping of Precipitation (GSMaP) in the Global Precipitation Measurement (GPM) mission

Kinji Furukawa, Takuji Kubota, Moeka Yamaji, Tomoko Tashima, Yuki Kaneko, Kosuke Yamamoto, Riko Oki, Nobuhiro Takahashi, and Yukari Takayabu

The Global Precipitation Measurement (GPM) mission is an international collaboration to achieve highly accurate and highly frequent global precipitation observations. The GPM mission consists of the GPM Core Observatory jointly developed by U.S. and Japan and Constellation Satellites that carry microwave radiometers and provided by the GPM partner agencies. The GPM Core Observatory, launched on February 2014, carries the Dual-frequency Precipitation Radar (DPR) by the Japan Aerospace Exploration Agency (JAXA) and the National Institute of Information and Communications Technology (NICT).

JAXA is continuing DPR data monitoring to confirm that DPR function and performance are kept on orbit. A scan pattern of the DPR was changed in May 2018. The next product applying the new scan pattern will be released as an experimental product (V06X) in 2020. The DPR follow-on mission has been actively discussed in Japan.

JAXA also develops the Global Satellite Mapping of Precipitation (GSMaP), as national product to distribute hourly and 0.1-degree horizontal resolution rainfall map. GSMaP has been used for various research fields and JAXA keeps it developed and improved, in cooperation with domestic/international partner agencies.

The GSMaP near-real-time version (GSMaP_NRT) product provides global rainfall map in 4-hour after observation, and recently GSMaP near-real-time gauge-adjusted version (GSMaP_Gauge_NRT) product has been published. The higher priority to data latency time than accuracy leads to wider utilization by various users for various purposes, such as rainfall monitoring, flood alert and warning, drought monitoring, crop yield forecast, and agricultural insurance.

Improved GSMaP_Gauge_NRT product (v6) was open to the public in Dec. 2018. Correction coefficients are calculated using past 30 days based upon Mega et al. (2019)’s method. We completed reprocessing of past 19yr data record (since Mar. 2000). Validations with reference to the JMA radar around Japan show smaller RMSEs in this new product than the current NRT (no gauge-correction).

JAXA started to provide the GSMaP real-time product called GSMaP_NOW by using the geostationary satellite Himawari-8 operated by the Japan Meteorological Agency (JMA) since November 2015. Recently, the domain of GSMaP_NOW was extended to the global region in June 2019. Furthermore, we developed the gauge-adjusted real-time version, GSMaP_Gauge_NOW, which was also released in June 2019. In the method, estimates from the GSMaP_NOW are adjusted using an optimization model (Mega et al. 2019) with parameters calculated from the GSMaP_Gauge (gauge-adjusted standard version) during the past 30 days.

GSMaP products can be seen via website and easy to monitor the global rainfall with good latency. GSMaP since March 2000 up to 4-hour after observation is available from the “JAXA Global Rainfall Watch” website (https://sharaku.eorc.jaxa.jp/GSMaP/index.htm); while GSMaP_NOW product is from the "JAXA Realtime Rainfall Watch" web site (https://sharaku.eorc.jaxa.jp/GSMaP_NOW/index.htm).

How to cite: Furukawa, K., Kubota, T., Yamaji, M., Tashima, T., Kaneko, Y., Yamamoto, K., Oki, R., Takahashi, N., and Takayabu, Y.: Recent status of the Dual-frequency Precipitation Radar (DPR) and the Global Satellite Mapping of Precipitation (GSMaP) in the Global Precipitation Measurement (GPM) mission, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4282, https://doi.org/10.5194/egusphere-egu2020-4282, 2020.

EGU2020-9615 | Displays | AS1.36

Assessment of Ku- and Ka-band Dual-Frequency Radar for Snow Estimates

Liang Liao, Robert Meneghini, Ali Tokay, and Hyokyung Kim

Dual-frequency radars have been increasingly used for detecting and retrieving cloud and precipitation, such as the Ku- and Ka-band Dual-frequency Precipitation Radar (DPR) aboard the Global Precipitation Measurement (GPM) core satellite. The objective of this study is to evaluate performance of the standard dual-frequency technique, which uses the differential frequency ratio (DFR), defined as the difference of radar reflectivities between two wavelengths, for the estimation of snow microphysical properties and the associated bulk parameters from Ku- and Ka-band as well as Ka- and W-band dual-frequency radars. Although the DFR-based technique is effective in obtaining snow properties, its retrieval accuracy depends on the model assumptions, which include parameterization of particle size distribution (PSD), empirical mass-size relation that links the observed geometrical size of particle to its mass, and the radar scattering model. The complex nature of snowflakes regarding shape, structure, and the inability of the modeled PSD to represent actual snow spectra, lead to errors in the estimates of snow parameters. Additionally, uncertainties associated with scattering computations of snowflakes also affect the accuracy of the dual-wavelength radar retrieval of snow. Therefore, understanding the uncertainties in snow precipitation estimation that depend on PSD parameterizations and scattering models of individual particles is important in evaluating the overall performance of dual-frequency retrieval techniques. Furthermore, separation of the uncertainties associated with the PSD models and the scattering models and their respective contributions to overall uncertainties are useful for gaining insight into ways to improve the retrieval methods.

Snow PSD is usually modelled as a gamma distribution with 2 or 3 free parameters depending on whether its shape factor is fixed or taken as a function of Dm. In this study, our focus is on an assessment of the uncertainties in snow estimates arising from the PSD parameterization and the mass-size relation. To do this, measured PSD data are employed. The snow mass spectra, which can be converted from measured PSD using an empirical mass-size relation, are used to obtain PSD parameters, e.g., the liquid-equivalent mass-weighted diameter (Dm) and the normalized intercept of a gamma PSD (Nw), and the snow bulk parameters, such as snow water content (SWC) and liquid-equivalent snowfall rate (R) if a measured fall velocity-size relationship is utilized. Coupling measured PSD with particle scattering model, measured radar parameters can be computed, which are subsequently used as inputs to the standard dual-frequency algorithm. An evaluation of the retrieval accuracy is conducted by comparing the radar estimates of Dm, Nw, SWC and R with the same quantities directly computed from the PSD spectra (or truth). In this study, measurements of the snow PSD and fall velocity acquired from the Snow Video Imager/Particle Image Probe (SVI/PIP) at the NASA Wallops flight facility site in Virginia are employed. There are several scattering databases available that provide the scattering properties of snow aggregates in accordance with various snow and ice crystal growth models. Variability of the snow estimates caused by the differences of various scattering tables will be analyzed to explore the uncertainties associated with the scattering tables.

How to cite: Liao, L., Meneghini, R., Tokay, A., and Kim, H.: Assessment of Ku- and Ka-band Dual-Frequency Radar for Snow Estimates, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9615, https://doi.org/10.5194/egusphere-egu2020-9615, 2020.

EGU2020-21745 | Displays | AS1.36

Enhancing Precipitation Prediction Algorithm by Data Assimilation of GPM Observations

Takemasa Miyoshi, Shunji Kotsuki, Koji Terasaki, Shigenori Otsuka, Ying-Wen Chen, Kaya Kanemaru, Masaki Satoh, Hisashi Yashiro, Hirofumi Tomita, Keiichi Kondo, Kozo Okamoto, Eugenia Kalnay, and Takuji Kubota

In precipitation science, satellite data have been providing precious, fundamental information, while numerical models have been playing an equally important role. Data assimilation integrates the numerical models and real-world data and brings synergy. We have been working on assimilating the GPM data into the Nonhydrostatic ICosahedral Atmospheric Model (NICAM) using the Local Ensemble Transform Kalman Filter (LETKF). We continue our effort on “Enhancing Precipitation Prediction Algorithm by Data Assimilation of GPM Observations” funded by JAXA, following successful completion of the 3-year project titled “Enhancing Data Assimilation of GPM Observations” from April 2016 to March 2019. The project first started in April 2013 on “Ensemble-based Data Assimilation of TRMM/GPM Precipitation Measurements”, where we developed a global data assimilation system NICAM-LETKF from scratch. This presentation will provide a summary of the past 7-year effort with more emphasis on the recent achievements, including JAXA’s near-real-time analysis called NEXRA (NICAM-LETKF JAXA Research Analysis) and new theoretical developments of Local Particle Filter to treat highly non-Gaussian distributions of precipitation variables in data assimilation.

How to cite: Miyoshi, T., Kotsuki, S., Terasaki, K., Otsuka, S., Chen, Y.-W., Kanemaru, K., Satoh, M., Yashiro, H., Tomita, H., Kondo, K., Okamoto, K., Kalnay, E., and Kubota, T.: Enhancing Precipitation Prediction Algorithm by Data Assimilation of GPM Observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21745, https://doi.org/10.5194/egusphere-egu2020-21745, 2020.

EGU2020-2947 | Displays | AS1.36

Assessments of IMERG precipitation over Europe

Andrés Navarro, Eduardo García-Ortega, José Luis Sánchez, Andrés Merino, Christian Kummerow, and Francisco J. Tapiador

Accurate estimation of precipitation is essential in weather prediction, climate change research, and hydrologic applications. However, unlike temperature and pressure, precipitation fields can be spatially patchy and consequently extremely difficult to measure and predict. Many efforts have been made to measure precipitation since the 18th century, but building a global, consistent, and continuous database of rainfall is still challenging. The launch of the Global Precipitation Measurement Core Observatory (GPM-CO) in February 2019 emerged as a promising alternative to measure precipitation at global scale. After five years in orbit, the GPM Mission has produced enough quality-controlled data to allow a validation of their precipitation estimates over Europe.

This study evaluates Integrated Multi-Satellite Retrievals from GPM (IMERG) over Europe in order to evaluate application of the retrievals to hydrology. IMERG is compared with a pan-European precipitation dataset built on rain gauge stations, the ENSEMBLES OBServation (E-OBS) gridded dataset. Although there is overall agreement in the spatial distribution of mean precipitation (R2 =0.8), important discrepancies are revealed in mountainous regions, specifically the Pyrenees, the Alps, west coast of the British Isles, Scandinavia, the Italian and Iberian peninsulas, and the Adriatic coastline. The results show that the strongest contributors to poor performance are pixels where IMERG has no gauges available for adjustment. If rain gauges are available, IMERG yields results similar to those of the surface observations, although the performance varies by region. However, even accounting for gauge adjustment, IMERG systematically underestimates precipitation in the Alps and Scandinavian mountains. Conversely, IMERG overestimates precipitation in the British Isles, Adriatic coastline, Italian Peninsula, and eastern European plains. Additionally, the research shows that gauge adjustment worsens the spatial gradient of precipitation because of the coarse resolution of Global Precipitation Climatology Centre data (GPCC).

How to cite: Navarro, A., García-Ortega, E., Sánchez, J. L., Merino, A., Kummerow, C., and Tapiador, F. J.: Assessments of IMERG precipitation over Europe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2947, https://doi.org/10.5194/egusphere-egu2020-2947, 2020.

EGU2020-3096 | Displays | AS1.36

Latent Heating Retrieved from TRMM and GPM Satellite Measurements

Wei-Kuo Tao, Steve Lang, and Takamichi Iguchi

Latent heat release itself is a consequence of phase changes between the vapor, liquid, and frozen states of water.  This paper will highlight the retrieval of latent heat release from satellite measurements generated by the Tropical Rainfall Measuring Mission (TRMM) and Global Precipitation Mission (GPM) satellite observatory.  Both TRMM and GPM are providing four-dimensional account of rainfall and its associated precipitation properties over the global Tropics and mid-latitudes: information that can be used to estimate the space-time structure of latent heating.

 

Goddard Convective-Stratiform or CSH retrieved LH is one of two standard LH products (the other one is from Japan Spectral Latent Heating or SLH). This paper will present (1) the new improvements of the CSH LH algorithm by better CRM simulated LH for its look-up table, and (2) the performance of CSH retrieved LH by comparison with surface rainfall rate.  In addition, the similarities and differences of CSH retrieved LH obtained from TRMM and GPM measurements, respectively, will be presented.  At the end of presentation, the further research on latent heating retrieval from satellites will be discussed.

How to cite: Tao, W.-K., Lang, S., and Iguchi, T.: Latent Heating Retrieved from TRMM and GPM Satellite Measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3096, https://doi.org/10.5194/egusphere-egu2020-3096, 2020.

EGU2020-18421 | Displays | AS1.36

Airborne Phased-Array Radar (APAR): The Next Generation of Airborne Polarimetric Doppler Weather Radar

Vanda Grubišić, Wen-Chau Lee, and Louis L. Lussier

This paper presents a configuration of a novel, airborne phased array radar (APAR) motivated by major advances in cellular technology, component miniaturization, and radar antenna simulation software. This has paved the way for a next-generation radar being designed by NCAR/EOL to be installed on the NSF/NCAR C-130 aircraft. The APAR system will consist of four removable C-band active electronically scanned arrays (AESA) strategically placed on the fuselage of the aircraft. Each AESA measures approximately 1.5 x 1.5 m and is composed of 2368 active radiating elements arranged in a total of 37 line replaceable units (LRU). Each LRU is composed of 64 radiating elements that are the building block of the APAR system.

 

Polarimetric measurements are not available from current airborne tail Doppler radars. However, APAR, with dual-Doppler and dual polarization diversity at a lesser attenuating C-band wavelength, will further advance the understanding of the microphysical processes within a variety of precipitation systemsSuch unprecedented observations, in conjunction with the advanced radar data assimilation schema, will be able to address the key science questions to improve understanding and predictability of significant weather.

A Mid-scale Research Infrastructure proposal is submitted to the National Science Foundation to request the implementation cost. The development is expected to take ~5 years after the funding is in place. It adopts a phased approach as an active risk assessment and mitigation strategy. At the present time, both the National Science Foundation and the National Oceanic and Atmospheric Administration are funding the APAR project for risk reduction activities. The APAR Team is actively seeking partners in industry and in the university community. An APAR science and engineering advisory panel has been organized.

 

The authors will review the overall design and current progress of APAR and outline ambitious future development work needed to bring this exceptional tool into full operation.

How to cite: Grubišić, V., Lee, W.-C., and Lussier, L. L.: Airborne Phased-Array Radar (APAR): The Next Generation of Airborne Polarimetric Doppler Weather Radar, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18421, https://doi.org/10.5194/egusphere-egu2020-18421, 2020.

EGU2020-18910 | Displays | AS1.36

The Diurnal Cycle of Precipitation: A Comparison of State-of-the-Art Observations and Models

Daniel Watters, Alessandro Battaglia, and Richard Allan

Representation of the diurnal cycle is a key trial of the ability of models to capture precipitation timing, duration, and intra-daily variations.  The state-of-the-art model simulations from the Coupled Model Intercomparison Project (CMIP6), which are set to inform the upcoming IPCC sixth assessment report, are yet to be compared to the diurnal cycle of precipitation according to observations.  The recently released version 6 of the Integrated Multi-Satellite Retrievals for Global Precipitation Measurement (IMERG) product provides over 19 years of global-gridded observations (June 2000 - Present).  Such state-of-the-art observations, with inputs from space-borne dual-frequency radar, microwave radiometers, infrared sensors and ground-based gauges, have never been available at 0.1˚ gridding every half hour over such a long period.  This study aims to compare the amplitude and time of maximum precipitation accumulation between IMERG observations and CMIP6 models over an 8-year period (June 2000 – May 2008).  Preliminary results suggest that the CMIP6 models typically underestimate the amplitude of precipitation accumulation over land compared to observations, though there are overestimates in the Amazon and across central Africa.  Furthermore, the CMIP6 models typically lag behind observations in their time of maximum accumulation over land; observations suggest a late evening to night maximum whilst CMIP6 models show a late morning to early afternoon maximum.  The results will be beneficial to improving modelling of precipitation across the globe.

How to cite: Watters, D., Battaglia, A., and Allan, R.: The Diurnal Cycle of Precipitation: A Comparison of State-of-the-Art Observations and Models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18910, https://doi.org/10.5194/egusphere-egu2020-18910, 2020.

EGU2020-19460 | Displays | AS1.36

Verification study of passive microwave snowfall products using ground-based radar network observations

Mario Montopoli, Kamil Mroz, Giulia Panegrossi, Daniele Casella, Luca Baldini, Paolo Sanò, Andrea Camplani, Sante Laviola, Pierre Kirstetter, Mark Kulie, and Alessandro Battaglia

Snowfall remote sensing  is becoming an increasingly popular topic within both the scientific community and operational services. Studies focused on snow retrievals are important because snow represents a reservoir of fresh water and its quantification is a crucial task to thoroughly understanding the hydrological cycle. In addition, snow-cover plays a key role in the climate system, modifying the global energy budget because of its high albedo. In addition, snowfalls often represent a hazard to several public services (e.g. transportations, energy providers) as well as properties (e.g. roof loading) but also an opportunity (e.g. for hydropower).

Passive microwave observations provided by currently operating spaceborne radiometers (e.g. Advanced Technology Microwave Sounder (ATMS), the Global Precipitation Measurement (GPM) Microwave Imager (GMI)) are a unique source of global information on the occurrence and the quantity of snowfall. However, because of the weaker and more complex signatures of snow at microwave frequencies [1] compared to those from rainfall, the retrieval schemes used by such instruments are still not fully optimised for snowfall detection and estimation, and subject to large errors. The ESA-funded RAINCAST project aims, among other tasks, at the verification of passive microwave snowfall products with the goal of fostering and defining new retrieval algorithms and mission concepts specifically optimised for snowfall quantification.

In this study we show a comparative analysis between passive microwave snowfall rate estimates and high quality ground-based radar snowfall measurements to quantify the actual strengths and limitations in state-of-the-art passive microwave snowfall products. In particular, the performance of the Goddard profiling algorithm version 5A (GPROF V5A) and of a recently developed snowfall retrieval algorithm for GMI named SLALOM [2, 3] are investigated. The differences between GPROF and SLALOM are explored in relation to the environmental conditions (including the presence of supercooled droplets aloft that tend to mask the typical snowfall signature) where the snowfall retrievals are likely less accurate. In addition, ATMS snowfall products are analysed as well for selected case studies to evidence the potential and limitations of the different snowfall products in relation to the algorithm’s design (e.g., GPROF vs. SLALOM) and sensor characteristics (GMI and ATMS). Then quantitative assessments for all products are discussed by exploiting one year of ground reference radar network data over Northern U.S. and Canada provided by the Multi-Radar/Multi-sensor System (MRMS) product, available at 1x1 km horizontal regularresolution and 2 min time sampling, and providing gauge adjusted surface precipitation rate together with the indication of its phase.

Our analysis confirms results from recent work on the same topic [e.g., 4], although a long term large scale analysis that quantify passive microwave retrieval is not found in the past literature. 

This work is particularly relevant not only for the quantification of the limitations of the current snowfall retrieval algorithms, but also to give recommendations for algorithm development for upcoming satellite missions (e.g. EPS-SG MWS, MWI/ICI), and for future satellite mission concepts.

REFERENCES

[1] Liu, G. et al, 2008. doi:  10.1029/2007JD009766.

[2] Rysman, J.-F. et al., 2018. doi: 10.3390/rs10081278

[3] Rysman J.-F., et al., 2019. doi:10.1029/2019GL084576,

[4] Von Lerber, et al. doi: /10.1175/JAMC-D-17-0176.1

 

How to cite: Montopoli, M., Mroz, K., Panegrossi, G., Casella, D., Baldini, L., Sanò, P., Camplani, A., Laviola, S., Kirstetter, P., Kulie, M., and Battaglia, A.: Verification study of passive microwave snowfall products using ground-based radar network observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19460, https://doi.org/10.5194/egusphere-egu2020-19460, 2020.

EGU2020-19722 | Displays | AS1.36

Real-time rainfall maps from satellite telecommunication signals

Alberto Ortolani, Francesca Caparrini, Samantha Melani, Andrea Antonini, Alessandro Mazza, Luca Baldini, Filippo Giannetti, Luca Facheris, and Attilio Vaccaro

Modern ways to measure rainfall provide a variety of different solutions, direct and indirect, with respect to the standard approach that is the raingauge method. Retrieving the actual rain fallen on a target domain is not in fact as easy task due to its temporal and spatial variability, but its importance is paramount for meteorology and for the effects on human lives and the environment. Rainfall regimes are changing almost at every latitude with dramatic effects, with a complex connection to climate change in large part to be still understood.

Among the emerging new methods for rainfall estimation, a specific interest is in the so-called ‘opportunistic’ measurements, because they provide a chance to augment information without adding new infrastructures, also with clear cost advantages. These data are of course less precise than those from dedicated instruments. Therefore some smart efforts in devising proper processing are needed to extract all the geophysical information that they can provide. Use of microwave links in cellular phone networks is among these methods, bringing information on rainfall rates along their path through signal attenuation caused by raindrops. Following a similar principle also broadcast telecommunication satellite signals can be used, with additional problems related to the definition of the intercepted precipitation volumes and the effects of the melting layer, but additional advantages related to the worldwide availability of the signal and the easiness of data acquisition, that can be natively centralised when using two ways communication receivers. NEFOCAST, a research project funded by the regional administration of Tuscany (Italy), exploited this feature through new two-way (transmit-receive) devices named SmartLNB (Smart Low-Noise Block converter), that are going to constitute networks of sensors of opportunity, densely distributed especially in urbanised areas. Two-way receivers allow both to estimate and relying attenuation data that can be centralized to be processed for real-time rainfall estimation, every minute.

An experimental network of SmartLNBs has been deployed in Italy (namely Florence, Pisa and Rome), including co-located raingauges and radar measurements for cal/val objectives. SmartLNBs provide average measurements along quasi-parallel non-nadir paths, so that information on the structure of the intercepted rainfall system is needed in order to retrieve ground precipitation. The high rate of measurements provided by the SmartLNBs suggested to approach the rainfall retrieval problem similarly to a trajectory assessment in a phase space, using an ensemble Kalman filter to produce the rainfall field over a given domain. MSG satellite precipitation products can be used for the purpose and also as initial and boundary conditions, while atmospheric motion vectors from the same data source are used in the propagation model of the Kalman filter.

In this work, we present the measurement concept, the signal processing algorithm and the method to retrieve the rainfall fields, through some significant synthetic and real case studies, for events with different intensity, dynamics and morphology and for various sensor distributions.

How to cite: Ortolani, A., Caparrini, F., Melani, S., Antonini, A., Mazza, A., Baldini, L., Giannetti, F., Facheris, L., and Vaccaro, A.: Real-time rainfall maps from satellite telecommunication signals, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19722, https://doi.org/10.5194/egusphere-egu2020-19722, 2020.

EGU2020-5857 | Displays | AS1.36 | Highlight

Quantifying errors and uncertainties in satellite precipitation estimates

Chris Kidd and Viviana Maggioni

The utilization of satellite observations in the estimation of global precipitation is now well established. However, quantifying the errors and uncertainties associated with such estimates is very much in its infancy. While many validation studies have been undertaken, these tend to provide case-specific or longer-term/large area measures of the performance of the precipitation products: statistical performance has largely taken precedence over an assessment of errors and uncertainties within such products. As the requirements for finer spatial and temporal resolutions increase, the assumptions made on the bulk large area/long time-frame products are no longer appropriate: careful assessments of the apportionment of the errors and uncertainties within the precipitation products needs to be made.

The premise of this study is that to truly understand the errors and uncertainties in the final precipitation product it is essential to quantify these within the elements that make up each individual satellite sensor and precipitation retrieval scheme or algorithm. Thus, we start with two fundamental categories: the observation capability of the sensor and the ability of the retrieval scheme. Each sensor provides different observations resulting from the engineering aspects of the sensor itself through to the sampling regime once the sensor is taking measurements: the observation capability is fixed and will be the same for all the subsequent retrieval schemes. The retrieval schemes themselves have a number of assumptions, both in terms of what the sensor actually observes and in the observation-to-rainfall relationships. While many of the errors and uncertainties associated with these assumptions cannot be easily quantified, the relative magnitude of each can be assessed. Initial results are presented here that quantify the effects of the spatial and temporal sampling of sensors, together with the impact of channel selection upon the final products. These results provide an insight into ability of such techniques to retrieve precipitation from the local to global scales, and how such techniques may be improved in the future.

How to cite: Kidd, C. and Maggioni, V.: Quantifying errors and uncertainties in satellite precipitation estimates, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5857, https://doi.org/10.5194/egusphere-egu2020-5857, 2020.

EGU2020-20445 | Displays | AS1.36

Microphysical features indicated by GPM DPR product “flagHeavyIcePrecip” – Case studies on lightning activity

Kenji Suzuki, Rimpei Kamamoto, Tetsuya Kawano, Katsuhiro Nakagawa, and Yuki Kaneko

Two products from the Global Precipitation Measurement (GPM) Dual-frequency Precipitation Radar (DPR) algorithms, a flag of intense solid precipitation above the –10°C height (“flagHeavyIcePrecip”), and a classification of precipitation type (“typePrecip”) were validated quantitatively from the viewpoint of microphysics using ground-based in-situ hydrometeor measurements and X-band multi-parameter (X-MP) radar observations of snow clouds that occurred on 4 February 2018. The distribution of the “flagHeavyIcePrecip” footprints was in good agreement with that of the graupel-dominant pixels classified by the X-MP radar hydrometeor classification. In addition, the vertical profiles of X-MP radar reflectivity exhibited significant differences between footprints flagged and unflagged by “flagHeavyPrecip”. We confirmed the effectiveness of “flagHeavyIcePrecip”, which is built into “typePrecip” algorithm, for detecting intense ice precipitation and concluded that "flagHeavyIcePrecip" is appropriate to useful for determining convective clouds.

It is well known that the lightning activity is closely related to the convection. We examined the lightning activity using GPM DPR product flagHeavyIcePrecip that indicates the existence of graupel in the upper cloud. On 20 June 2016, we experienced heavy rain with active lightning during Baiu monsoon rainy season, while the GPM DPR passed over Kyushu region in Japan. The distribution of “flagHeavyIcePrecip” obtained from the GPM DPR well corresponded to the CG/IC lightning concentration. On 4 September 2019, isolated thunder clouds observed by the GPM DPR was also similar to the “flagHeavyIcePrecip” distribution. However, partially there was IC lightning without “flagHeavyIcePrecip”, which was positive lightning. It was suggested to have been produced in the upper clouds in which positive ice crystals were dominant.

How to cite: Suzuki, K., Kamamoto, R., Kawano, T., Nakagawa, K., and Kaneko, Y.: Microphysical features indicated by GPM DPR product “flagHeavyIcePrecip” – Case studies on lightning activity, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20445, https://doi.org/10.5194/egusphere-egu2020-20445, 2020.

EGU2020-15915 | Displays | AS1.36

Current and future CML-rainfall estimation in Germany: Improved data processing, real-time rainfall maps and fusion with weather radar data

Christian Chwala, Gerhard Smiatek, Maximilian Graf, Julius Polz, Tanja Winterrath, and Harald Kunstmann

Many cell phone base stations are connected by a network of commercial microwave links (CMLs). At the typically used frequencies between 15 GHz and 40 GHz, precipitation along the path of a CML leads to significant attenuation of the signal. The path-averaged rain rate along a CML can therefore be derived from measurements of the attenuation.

In cooperation with Ericsson, we record attenuation data of 4000 CMLs across Germany with our own open source data acquisition software. The data is acquired every minute and is available to us in real time. The dataset is continuously growing and now spans more than two and a half years. 

Here we present and discuss results from our current processing chain for hourly country-wide CML-derived rainfall fields. We show the effect of improved rain event detection in the raw attenuation time series and the necessity to correct for wet antenna attenuation (Graf et al., 2019). Validation is done via the gauge-adjusted radar product RADOLAN-RW of the German meteorological service. For summer months the pearson correlation between CML and radar data reaches up to 0.85, but is substantially worse during the winter months. The presented processing chain is fast enough to be applied in real-time, which will be illustrated in a live-demo. Furthermore, since Germany has both, a large network of CMLs and a modern weather radar network, we also work on the combination of these data sources. We will present first results of an approach where CMLs are used as an additional source for weather radar rain rate adjustment similarly to the existing gauge-adjustment done in RADOLAN.

Graf, M., Chwala, C., Polz, J., and Kunstmann, H.: Rainfall estimation from a German-wide commercial microwave link network: Optimized processing and validation for one year of data, Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2019-423, 2019

How to cite: Chwala, C., Smiatek, G., Graf, M., Polz, J., Winterrath, T., and Kunstmann, H.: Current and future CML-rainfall estimation in Germany: Improved data processing, real-time rainfall maps and fusion with weather radar data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15915, https://doi.org/10.5194/egusphere-egu2020-15915, 2020.

EGU2020-21836 | Displays | AS1.36

The "Excelsior" H2020 Widespread Teaming Phase 2 Project: ERATOSTHENES: EXcellence Research Centre for Earth SurveiLlance and Space-Based MonItoring Of the EnviRonment

Diofantos Hadjimitsis, Gunter Schreier, Haris Kontoes, Albert Ansman, Giorgos Komodromos, Kyriacos Themistocleous, Kyriacos Neocelous, Silas Michaelides, Rodanthi Mamouri, Ioannis Papoutsis, Johannes Bühl, Egbert Schwarz, Stelios Tziortzis, Argyro Nisantzi, Christodoulos Mettas, Christiana Papoutsa, Christos Danezis, and Marios Tzouvaras

The EXCELSIOR project aims to upgrade the existing ERATOSTHENES Research Centre established within the Cyprus University of Technology into a sustainable, viable and autonomous ERATOSTHENES Centre of Excellence (ECoE) for Earth Surveillance and Space-Based Monitoring of the Environment. The ECoE for Earth Surveillance and Space-Based Monitoring of the Environment will provide the highest quality of related services both on the National, European and International levels through the ‘EXCELSIOR’ Project under H2020 WIDESPREAD TEAMING. The vision of the ECoE is to become a world-class Digital Innovation Hub (DIH) for Earth observation and Geospatial Information becoming the reference Centre in the Eastern Mediterranean, Middle East and North Africa (EMMENA) within the next 7 years. The ECoE will lead multidisciplinary Earth observation research towards a better understanding, monitoring and sustainable exploitation and protection of the physical, built and human environment, in line with International policy frameworks. Indeed, the scientific potential of the new upgraded ECoE focusing on the integration of novel Earth observation, space and ground based integrated technologies for the efficient systematic monitoring of the environment. Furthermore, ECoE aims to excel in five domains:  i) Access to energy; ii) Disaster Risk Reduction; iii) Water Resource Management; iv) Climate Change Monitoring and v) Big Earth observation Data Analytics. This will be achieved through research and innovation excellence in the respective scientific and technological disciplines and working together with other Earth observation industries, whereby the ECoE will develop a pool of scientific expertise and engineering capability as well as technical facilities. The partners of the EXCELSIOR consortium include the Cyprus University of Technology as the Coordinator, the German Airspace Center (DLR), the Leibniz Institute for Tropospheric Research (TROPOS), the National Observatory of Athens (NOA) and the Department of Electronic Communications, of the Ministry of Transport, Communications and Works of Cyprus.

The EXCELSIOR project has received funding from the European Union’s Horizon 2020 research and innovation programme under Grant Agreement No 857510 and from the Government of the Republic of Cyprus through the Directorate General for the European Programmes, Coordination and Development.

How to cite: Hadjimitsis, D., Schreier, G., Kontoes, H., Ansman, A., Komodromos, G., Themistocleous, K., Neocelous, K., Michaelides, S., Mamouri, R., Papoutsis, I., Bühl, J., Schwarz, E., Tziortzis, S., Nisantzi, A., Mettas, C., Papoutsa, C., Danezis, C., and Tzouvaras, M.: The "Excelsior" H2020 Widespread Teaming Phase 2 Project: ERATOSTHENES: EXcellence Research Centre for Earth SurveiLlance and Space-Based MonItoring Of the EnviRonment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21836, https://doi.org/10.5194/egusphere-egu2020-21836, 2020.

EGU2020-9350 | Displays | AS1.36

A Case Study of Weather Radar Data Assimilation into the Harmonie Numerical Weather Prediction System

Silas Michaelides, Serguei Ivanov, Igor Ruban, Demetris Charalambous, and Filippos Tymvios

Quantitative Precipitation Forecasting (QPF) is among the most central challenges of atmospheric prediction systems. The primary aim of such a task is the generation of accurate estimates of heavy precipitation events associated with severe weather, atmospheric fronts and heavy convective rainfalls. QPF is still among the most intricate challenges of Numerical Weather Prediction. The efforts in this direction are mainly concentrated on improving model formulations for microphysics and convective process and remote sensing data assimilation.

This paper describes the first results with the regional radar signal processing chain that provides the radar data assimilation (RDA) in the Harmonie convection permitting numerical model. This task is performed for a case study focusing on a wintertime frontal cyclone over the island of Cyprus. Reflectivity measurements from two weather radars, at Larnaka and Paphos, are exploited for simulations of severe weather conditions associated with this synoptic-scale system. Through the variational assimilation procedure, the model takes into account the atmospheric processes occurring in the upstream flow which can be outside the area of radar measurements. The focus is on the precipitable water vapor content and its changes during the cyclone evolution, as well as on the impact of the radar data assimilation on precipitation estimates.

The results show that the numerical experiments exhibit, in general, a suitable simulation of precipitable water at different stages of the cyclone. In particular, the bulk of the rainfall volume exhibits three stages: intensive rain on the cyclone's frontal zone, weaker precipitation immediately behind the front, and the secondary enhancement of rainfall. The largest corrections due to RDA are of up to 5 mm and occur during the approach of the cyclone frontal zone in a form of enhanced rainfall over the whole area, but more prominently in weak precipitation locations.

How to cite: Michaelides, S., Ivanov, S., Ruban, I., Charalambous, D., and Tymvios, F.: A Case Study of Weather Radar Data Assimilation into the Harmonie Numerical Weather Prediction System, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9350, https://doi.org/10.5194/egusphere-egu2020-9350, 2020.

EGU2020-22356 | Displays | AS1.36

Disdrometer Gravitational Sorting Signature in a Mediterranean Environment

Takis Kasparis, Silas Michaelides, and John Lane

The motivation behind this research was initially the observation and the subsequent modelling of the gravitational sorting of precipitation in disdrometer-based spectra. The gravitational sorting signature (GSS) is expected to be observed when every drop impact measured by the disdrometer is time tagged and then displayed as a scatter plot diagram of drop diameter (D) versus time (t). The resulting D-t diagrams exhibit marked diagonal features and gravitational sorting signatures are characterized by a negative slope. However, because of the way that manufacturers and researchers process disdrometer data, this signature is typically wiped out. 

This research is based on the assumption that if a rain producing cloud that goes through a complete rain process from start to end, remains fixed (no advection) over a disdrometer site, then some GSS should occur; if advection dominates, then GSS may not be observable.  In this latter case, the precipitating cloud may move over the disdrometer. In this paper, two cases are presented one in which GSS was detected and another in which GSS was absent.

The disdrometer data used in this study were recorded by using a Joss-Waldvogel impact disdrometer located on the roof of a building of the meteorological station at Athalassa, Cyprus (35.15°N, 33.40°, 161.0 m above Mean Sea Level, MSL). The Joss-Waldvogel impact disdrometer used is able to record drop diameters from 0.3mm to 5.5mm in ten-second intervals, allowing for the establishment of the Drop Size Distribution (DSD) representing this range of drop sizes.

How to cite: Kasparis, T., Michaelides, S., and Lane, J.: Disdrometer Gravitational Sorting Signature in a Mediterranean Environment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22356, https://doi.org/10.5194/egusphere-egu2020-22356, 2020.

A recent review about diversities of epiphytes in tropical forests of the Neotropics revealed an unexpected high diversity at lower elevations in an area in French Guiana where the formation of nocturnal radiation fog, intensified by katabatic drainage flows from the surrounding terrain fosters epiphytic growth. Consequently, the new diversity hotspot has been termed ’Tropical Lowland Cloud Forest‘ (TLCF) in analogy to the well-known Tropical Montane Cloud Forests. In this new project funded by the German Research Foundation, we test the hypothesis that the new forest type is widespread in the Tropics if the local terrain allows the formation of nocturnal radiation fog. The presented study is based on satellite data because no operational fog measurements from natural rain forests are available. Since fog in TLCFs is a nocturnal / early morning phenomenon, we use all overflights by the MODIS Aqua platform with 1 km resolution. Fog / low stratus clouds are derived by using a machine learning approach which is trained by MODIS and CALIPSO data. Potential lowland forest areas will be derived from ASTER Global Digital Elevation Model  and Landsat Vegetation Continous Fields

 

 

How to cite: Pohl, M.: Spatial delineation of a new fog-driven ecosystem in the tropical lowlands , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7722, https://doi.org/10.5194/egusphere-egu2020-7722, 2020.

In this study, moisture sources for summer (June–July–August) precipitation over eastern China are investigated by performing a transient simulation for the period 1979–2009 using the Lagrangian particle dispersion model FLEXPART. The results show that the Indochinese Peninsula plus southern China, the South China Sea, the northwestern Pacific Ocean, the Asian continent, and the Bay of Bengal are major moisture source regions for summer precipitation over eastern China and that the moisture originated from eastern China, the Arabian Sea, and the Indian subcontinent has minor contributions. The contribution of the oceanic sources significantly surpasses that of the continental sources. The contributions of the various moisture source regions exhibited significant interannual variations during 1979–2009, especially the Indochinese Peninsula plus southern China, the South China Sea, the northwestern Pacific Ocean, the Asian continent, and the Bay of Bengal. Moreover, moisture sources have obvious monthly variations and seasonal cycle features, which are responsible for providing moisture for precipitation in the different stages of the monsoon over eastern China. In addition, it is revealed that a great amount of moisture for the slight precipitation over eastern China originates from the local and northwestern continental regions and eastern oceanic regions adjacent to eastern China, while more moisture comes from southwestern oceanic source regions and their adjacent continental regions for heavy precipitation.

How to cite: Hu, Q.: Moisture sources of summer precipitation over eastern China during 1979–2009: A Lagrangian transient simulation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8123, https://doi.org/10.5194/egusphere-egu2020-8123, 2020.

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Evaluation of wind-induced errors for the Hotplate precipitation gauge using computational fluid dynamic simulations.

Enrico Chinchella, Arianna Cauteruccio, Mattia Stagnaro, Andrea Freda, and Luca Giovanni Lanza

Wind is recognised as the major environmental source of error in precipitation measurements. For traditional catching type gauges, which are composed by a funnel to collect the precipitation and a container with a bluff body shape, the exposure effect produces the updraft and acceleration of the velocity field in front and above of the collector. These divert the trajectories of approaching hydrometeors producing  a relevant under-catch, which increases with increasing the wind velocity. This problem has been recently addressed in the literature using Computational Fluid Dynamics (CFD) simulations and a Lagrangian Particle Tracking (LPT) model to provide correction curves for various instruments, which closely match the under-catch observed in field measurements.

The present work concentrates on the Hotplate precipitation gauge developed at the Research Applications Laboratory, National Center for Atmospheric Research in Boulder, Colorado. The Hotplate differs from the traditional catching type gauges because it operates by means of an indirect thermodynamic principle. Therefore, it is not equipped with any funnel to collect the precipitation and is composed by a small disk with a diameter of 13 cm with two thin aluminium heated plates on the upper and lower faces. On the plates three concentric rings are installed to prevent the hydrometeors from sliding off during strong wind conditions.

In order to quantify the wind-induced error, the Unsteady Reynolds Averaged Navier Stokes (URANS) equations were numerically solved, with a k-ω SST turbulence closure model, to calculate the airflow velocity field around the instrument. Numerical results were validated by comparison with wind tunnel flow velocity measurements from pressure probes and a Particle Image Velocimetry (PIV) technique.

Then, with the objective to calculate the Collection Efficiency (CE) the hydrometeor trajectories were modelled using a literature LPT model (Colli et al. 2015) that solves the particle motion equation under the effects of gravity and wind. The path of each particle was analysed, considering the complex geometry of the gauge body, to establish whether it is captured by the instrument or not.

For various particle size/wind velocity combinations, the ratio between the number of particles captured by the instrument and the number of particles that would be captured if the instrument was transparent to the wind was calculated. Finally, the CE curve was derived assuming a suitable particle size distribution for solid precipitation.

The results show that the Hotplate gauge presents a very unique response to the wind if compared with more traditional instruments. The CE indeed decreases with increasing the wind speed up to 7.5 m/s, where the effect of geometry starts to overcome the aerodynamic effect, and slowly reverses the trend beyond that value. This effect is so prominent at high wind speed that slightly beyond 15 m/s the under-catch fully disappears and the instrument starts to exhibit a rapidly increasing over-catching bias.

References:

Colli, M., Lanza, L.G., Rasmussen, R., Thériault, J.M., Baker, B.C. & Kochendorfer, J. An improved trajectory model to evaluate the collection performance of snow gauges.  Journal of Applied Meteorology and Climatology, 2015, 54, 1826–1836.

How to cite: Chinchella, E., Cauteruccio, A., Stagnaro, M., Freda, A., and Lanza, L. G.: Evaluation of wind-induced errors for the Hotplate precipitation gauge using computational fluid dynamic simulations., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21543, https://doi.org/10.5194/egusphere-egu2020-21543, 2020.

   In East Asia, a significant subtropical front called the Baiu/Meiyu front appears just before midsummer and brings the huge rainfall there, greatly influenced by the Asian summer monsoon. However, large-scale atmospheric features and rainfall characteristics (such as convective or stratiform rain) as well as the total rainfall amount around the front show rather great differences between the western and eastern portions. For example, in the western part of the Japan Islands (especially around Kyushu District, the most western part) and the Changjiang River Basin in Central China, the more frequent appearance of the heavy rainfall events due to the organized deep convective clouds than in the eastern Japan results in the larger climatological precipitation amount there. This is greatly related to the larger moisture transport toward the western part of the Baiu front than toward the eastern part. On the other hand, the rainfall characteristics around the front in the eastern Japan tend to be largely influenced by the cool Okhotsk air mass with rather stable stratification. Furthermore, their year-to-year, intraseasonal and short-period variations including the diversity of the “heavy rainfall types” are also very large.

The extreme events in association with the Baiu/Meiyu activity are greatly reflected by the above variability of the frontal activity. Inversely, it would be also important viewpoint that detailed examination of some extreme events could lead to the better understanding of the “dynamic climatological features” of the Baiu/Meiyu system itself.

In such concept, the present study will examine the frontal-scale rainfall features and the atmospheric conditions for the extremely heavy rainfall event around the Baiu front in western to central Japan during 5-7 July 2018. Although it is the common feature for the Baiu frontal rainfall heavy in western Japan that the frequent appearance of the meso-scale intense rain bands results in the huge total rainfall amount there, it is noted that the extremely large total rainfall area was distributed much more widely up to the central Japan with also considerable contribution of the long-persistent “not-so-intense rain” there, as often found in the heavy rainfall in the eastern Japan. Our analyses of the atmospheric fields suggest that this extreme event seems to be characterized by the strong mixture both of the large-scale factors for activating the “western Japan Baiu” and the “eastern Japan Baiu”.

As for the precipitation analyses, the 10-minute precipitation data at many meteorological stations in the Japan Islands area were used to discuss on the frontal-scale “rainfall characteristics” as well as the total rainfall amounts.

How to cite: Kato, K., Matsumoto, K., Yamatogi, T., and Miyake, C.: On the Baiu frontal-scale rainfall characteristics and atmospheric conditions in the extremely heavy rainfall event around western Japan during 5-7 July 2018 with attention to the synoptic climatological viewpoint, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3083, https://doi.org/10.5194/egusphere-egu2020-3083, 2020.

EGU2020-5937 | Displays | AS1.36

Precipitation structure during the life cycle of cloud systems over Peru using satellite based observations

Shailenda Kumar, Yamina Silva, Carlos Del Castillo, Jose Luis Flores Rojas, Aldo Moya S. Alveraz, and Daniel Martinez Castro

In the present study, a unique approach is applied to investigate the life cycle properties of the precipitation combining the satellite-based information. Data from Global Precipitation Measurement Dual Precipitation Radar (GPM-DPR) and brightness temperature (BT) form the GOES satellite. First, we used the GPM-DPR data to identify the precipitating cloud systems (PCSs) and then 9 (± 4 hours) hours of GOES BT data to identify the life phases for a particular PCSs e.g., a developing stage, a mature stage, or a dissipating stage. The case study of PCS related to different phases of the PCSs shows that PCSs consist of different systematic properties including the area of convective-stratiform precipitation, the convective rain rate and the storm-top height. The developing stage PCSs have the highest convective precipitation fraction (~26%) with highest near surface rain rate (RR, 4.97 mm h-1), whereas the dissipating stage PCSs have the largest precipitation area (11489 km2) with least near surface convective RR (~4.11 mm h-1). The vertical structure of precipitation and raindrop size distribution (DSD parameters) show the different characteristics above and below the freezing level and related with the different microphysical processes during different stages and related with the convective to stratiform area fraction and water vapour. The developing stage PCSs have the largest but sparse, droplets in convective precipitation, whereas the mature stage has the largest droplets below in the freezing level for all the vertical rainy profiles. The developing stage PCSs have the highest concentration of least sized of hydrometeors. Also, north-eastern continent of SA has higher near surface RR with higher sized of hydrometeors and even higher in developing stage PCSs. Our analysis indicates that the different microphysical properties for the PCSs in different phases are related to cloud and ice water path upward motion and related to the orographic influence.

How to cite: Kumar, S., Silva, Y., Del Castillo, C., Flores Rojas, J. L., S. Alveraz, A. M., and Castro, D. M.: Precipitation structure during the life cycle of cloud systems over Peru using satellite based observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5937, https://doi.org/10.5194/egusphere-egu2020-5937, 2020.

EGU2020-1402 | Displays | AS1.36

Precipitation Retrieval over the Tibetan Plateau from the Geostationary Orbit

Christine Kolbe, Boris Thies, Nazli Turini, and Jörg Bendix

The distribution of precipitation on the Tibetan Plateau (TiP) is not yet understood due to various factors. Satellite-based precipitation retrieval can provide comprehensive information in a high spatial-temporal resolution. The aim of this feasibility study is to retrieve precipitation rates over High Asia using multi-spectral data from the two geostationary (GEO) satellites Elektro-L2 and Insat-3D in a 30 minutes and 4 km resolution. The variety of spectral bands from both satellites provides an insight into the cloud properties which are associated with precipitation. In the first step, the precipitation area is delineated, and in a second step, the rates are retrieved. To this end, we use a machine learning approach (Random Forest, RF) and a precipitation product of the Global Precipitation Measurement Mission (GPM IMERG) as a reference. From this product, we use the best quality gauge calibrated microwave (MW) precipitation estimates. We validate our results with independent gauge calibrated MW precipitation. To improve the RF models, we tested various optimization schemes. The results of this study will provide information about the precipitation processes in High Asia.

How to cite: Kolbe, C., Thies, B., Turini, N., and Bendix, J.: Precipitation Retrieval over the Tibetan Plateau from the Geostationary Orbit, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1402, https://doi.org/10.5194/egusphere-egu2020-1402, 2020.

EGU2020-1417 | Displays | AS1.36

The WegenerNet 3D weather and climate research facility: A unique open-air laboratory for high-resolution precipitation studies

Jürgen Fuchsberger, Gottfried Kirchengast, and Christoph Bichler

The WegenerNet Feldbach Region is a unique weather and climate observation facility
comprising 155 meteorological stations measuring temperature, humidity, precipitation,
and other parameters, in a tightly spaced grid within a core area of 22 km × 16 km
centered near the city of Feldbach (46.93°N, 15.90°E).
With its stations every about two square-km (area of about 300 square-km in total),
and each station with 5-min time sampling, the network provides regular measurements
since January 2007. In 2020, the station network will be expanded by three major
new components, converting it from a 2D ground station network into a 3D open-air
laboratory for weather and climate research at very high resolution.
The following new observing components will start operations by spring 2020:

  1. A polarimetric X-band Doppler weather radar for studying precipitation parame-
    ters in the troposphere above the ground network, such as rain rate, hydrometeor
    classification, Doppler velocity, and approximate drop size and number. It can
    provide 3D volume data (at about 1 km × 1 km horizontal and 500 m vertical res-
    olution, and 5-min time sampling) for moderate to strong precipitation. Together
    with the dense ground network this allows detailed studies of heavy precipitation
    events at high accuracy.
  2. An azimuth-steerable microwave/IR radiometer for vertical profiling of temperature,
    humidity, and cloud liquid water in the troposphere (with 200 m to 1 km vertical
    resolution, and 5-min time sampling), also capable of measuring integrated water
    vapor (IWV) along line-of-sight paths towards Global Navigation Satellite System
    (GNSS) satellites.
  3. A water vapor mapping high-resolution GNSS station network, named GNSS StarNet,
    comprising six ground stations, spatially forming two star-shaped subnets (one
    with ∼10 km interstation distance, and one embedded with ∼5 km distance), for
    providing slant IWV, vertical IWV, and precipitable water, among other parame-
    ters, at 5-min time sampling.

We will present a detailed overview of the new components, their location, specifica-
tion, and output data products.

How to cite: Fuchsberger, J., Kirchengast, G., and Bichler, C.: The WegenerNet 3D weather and climate research facility: A unique open-air laboratory for high-resolution precipitation studies, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1417, https://doi.org/10.5194/egusphere-egu2020-1417, 2020.

EGU2020-1674 | Displays | AS1.36

An Analysis and Example of Use of the GPM Gridded Text Products

Erich Franz Stocker, Owen Kelley, and Jason West

This poster provides the design, content and purpose of the
Global Precipitation Measurement (GPM) gridded text
products. Gridded text products at the same time and space resolution are
available from the start of the TRMM period in January 1998 through the
current GPM data collection period. The poster provides an example of the
use of this data product by examining the structure of the Indian monsoon as
well as examining the monsoon during El Nino and La Nina periods. It will
also look at diurnal precipitation during the Indian monsoon season. As
part of the examination of the Indian monsoon using the gridded text
product, the poster demonstrates the ease of integration with other data.
In this case, Sea Surface Temperature (SST) data that is relevant to the Indian monsoon is examined
side-by-side with the precipitation data. It further demonstrates the ease
of aggregating the daily gridded data across many years while still
retaining the hourly structure that enables diurnal studies. The GPM
gridded text product is currently the only level 3 GPM product which can
be aggregated in this way. The representation of data in ASCII format
allows potential users to concentrate on the scientific analysis rather
than the physical format of the data. In summary, the poster provides an
overview that uses examples to demonstrate the efficacy of this unique GPM
data product.

How to cite: Stocker, E. F., Kelley, O., and West, J.: An Analysis and Example of Use of the GPM Gridded Text Products, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1674, https://doi.org/10.5194/egusphere-egu2020-1674, 2020.

The operational use of observation products of rainfall for forecasting/nowcasting purposes is nowadays wide spread in several regions in the world. While the applications for such data are numerous (flood early warning systems, agriculture, urban flood, etc.) the dealing with the uncertainty of the data when they come from different sources is still an open question. In fact, due to the extreme spatial variability of the rainfall fields also when limited (but intense) rain events occur, even a quite dense ground raingauges network can be not sufficient to effectively describe the precipitation. Thus, there is the need to employ multi-sources observation systems by exploiting, when available, meteo-radar and satellite products that provide spatially continuous maps, without neglecting their limits. With specific reference to the satellite products, there are several issues about the accuracy of the reconstruction of the actual rainfall fields in terms of intensity, timing and even presence of rainfall. In this work the EUMETSAT operational rainfall product based on MSG (Meteosat Second Generation) is evaluated by comparison with the observed time series of the ground network of raingauges in the Italy territory. The focus of the comparison is to investigate on the properties of the MSG product error, in particular on how it varies  with the spatial and temporal scales of aggregation, in different regions and different seasonal periods. The analysis was conducted on the whole Italian territory, in the period 2009-2013.

How to cite: Campo, L.: Error structure of MSG rainfall operational product in Italy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1748, https://doi.org/10.5194/egusphere-egu2020-1748, 2020.

Abstract: This study investigates the character and complicated atmospheric influence factors of snow cover on a snowstorm event associated with Jianghuai cycle occurred from 21 to 22 February 2017 by automatic station, intensive and routine observation data. The results are as follows: (1) Special structure leads to different distribution  of snowfall and snow cover from south to north in Shandong province.(2) Snow depth rises to maximum when snow ends with timeliness. The maximum is not sure to continue at 8'clock next day.(3) Snow depth is influenced by precipitation type, snowfall, Snowfall intensity, air temperature, ground temperature and wind speed. Sleet can produce snow cover with 1cm before it converts to snow, or quantitative snow cover won't form. Snow-to-liquid ratio has great difference in various stations, and the average with 0.5cm·mm-1 in Shandong province is lower than in all country. Strong snowfall and snowfall intensive are favorable to form deep snow cover without melt snowfall, especially for air temperature and ground temperature higher than 0℃. More lower air temperature and ground temperature will benefit snow cover. The value of ground temperature threshold is about 0℃ when snow cover begin to form. The common character is that ground temperature drops quickly before visible snow cover and rises stably after 1 to 2 hours . Air temperature is usually below 0℃ when snow cover forms, or major snowfall will melt. Small wind speed is good for snow cover.
Key words: Jianghuai cycle, snowstorm, snow cover, influence factor

How to cite: Yang, C. F.: A Case Study of Snowstorm Associated with Jianghuai Cycle on Atmospheric Influence Factors and Character of Snow Cover, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1930, https://doi.org/10.5194/egusphere-egu2020-1930, 2020.

EGU2020-1931 | Displays | AS1.36

Investigation of tipping bucket rain gauges using digital photographic technology

Minhan Liao, Jiufu Liu, and Aimin Liao

When studying the tipping bucket rain gauge (TBR), it is rather difficult to make an objective and sophisticated measurement of the duration of bucket rotation. From the perspective of digital photographic technology, however, the problem can be easily solved. The primary interest of this research has been to use digital photographic technology to study the TBR under laboratory conditions. In this study, the interframe difference algorithm and a camera recording device were used. Based on three types of JDZ TBRs, the time variation characteristics of bucket rotation were obtained. The time from the beginning of a tip to the time that the bucket is horizontal (T1) and the time for a complete tip (T2) were analyzed in detail. The results showed that T1 and T2 were functions of rainfall intensity, and T1, T2 decrease as the rain intensity increases significantly (P<0.001). Moreover, excellent evidence shows that the averages of T1 and T2 were positively correlated with bucket mass. It took more time for the bucket to tip as the mass of the bucket increased. Furthermore, the error of each TBR was calculated by the new proposed error calculation formula, and the new method was compared with the traditional method. The results from the two methods were very close, which demonstrates the correctness and feasibility of the new formula. However, the traditional calibration cannot acquire the variation characteristics of the tipping time, but the proposed approach can achieve this.

How to cite: Liao, M., Liu, J., and Liao, A.: Investigation of tipping bucket rain gauges using digital photographic technology, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1931, https://doi.org/10.5194/egusphere-egu2020-1931, 2020.

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A sub-regional approach for the analysis of atmospheric teleconnection influence on precipitation in Calabria (southern Italy)

Giulio Nils Caroletti, Roberto Coscarelli, and Tommaso Caloiero

Due to the importance of precipitation as a climatic and meteorological variable, it is paramount to detect the relationships between teleconnections and precipitation at different temporal and spatial scale. In fact, large-scale systems can i) influence precipitation directly, ii) establish a favourable environment to deep moist convection, and thus extreme precipitation, but also iii) help triggering dry conditions and drought.

In this study, developed within the INDECIS EU project, the teleconnection influence on precipitation in the Calabria region has been evaluated over the 1981-2010 time period, by means of a database of 79 rain gauge stations and seven teleconnections indices. Calabria, the southernmost region of peninsular Italy, was chosen as a valuable test bed mainly because it is located in the centre of the Mediterranean region, which constitutes a hot spot for climate change. Moreover, Calabria has a high-density, long-time network of precipitation gauges, recently validated and homogenized.

Statistical relationships between teleconnection indices and precipitation are often developed through well-known correlation analyses techniques, e.g. Pearson, Spearman and Kendall, where a teleconnection index is compared to cumulated precipitation values. In this study, three types of correlation analysis were performed: i) seasonal indices vs seasonal cumulated precipitation; ii) three-month indices vs monthly cumulated precipitation; iii) monthly indices vs monthly cumulated precipitation. These analyses have been performed in five Rainfall Zones (RZs) of the study area, characterised by different climatic conditions: the North-Eastern Zone (I1), the Central-Eastern Zone (I2) and the South-Eastern Zone (I3) on the Ionian side of Calabria and the North-Western Zone (T1) and the South-Western Zone (T2) on the Tyrrhenian part.

Results showed that the Mediterranean Oscillation and the North Atlantic Oscillation are the most important large-scale contributors to the precipitation regime of Calabria. Moreover, seasonal Eastern Atlantic pattern influenced seasonal precipitation in the RZs I1 and T1; three-monthly East Atlantic/Western Russian pattern influenced monthly precipitation in the RZs I2 and T1; three-monthly Western Mediterranean Oscillation influenced monthly precipitation in the RZs I3 and T1; while three-monthly El Nino-Southern Oscillation influenced monthly precipitation in the RZ T2.

Investigating changes in the response of local precipitation and teleconnections throughout the 1951-2010 and 1951-1980 time periods, a change in precipitation response to teleconnection patterns emerged, i.e., in the impact that the Mediterranean Oscillation has on the East coast precipitation (RZs I1-I3), a possible result of natural variation or climate change. In addition, these results have been compared to those obtained with the classical correlation analyses between teleconnection indices and single-station precipitation.

The approach developed for this study is a general method that, in principle, can be reproduced for any variable for any region and for every teleconnection.

Acknowledgments:

The Project INDECIS is part of ERA4CS, an ERA-NET initiated by JPI Climate, and funded by FORMAS (SE), DLR (DE), BMWFW (AT), IFD (DK), MINECO (ES), ANR (FR) with co-funding by the European Union (Grant 690462).

How to cite: Caroletti, G. N., Coscarelli, R., and Caloiero, T.: A sub-regional approach for the analysis of atmospheric teleconnection influence on precipitation in Calabria (southern Italy), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3078, https://doi.org/10.5194/egusphere-egu2020-3078, 2020.

Polarimetric radar provides more choices and advantages for quantitative precipitation estimation (QPE). Utilizing the C-band polarimetric (CPOL) radar in Hangzhou, China, six radar QPE estimators based on the horizontal reflectivity (ZH), the specific attenuation (AH), the specific differential phase (KDP), and their corresponding double-parameters that further integrate the differential reflectivity (ZDR), namely R(ZH, ZDR), R(KDP, ZDR) and R(AH, ZDR), are investigated for an extreme precipitation event occurred in Eastern China on 1 June 2016. These radar QPE estimators are respectively evaluated and compared with a local rain gauge network and drop size distribution (DSD) data observed by two disdrometers. The results show that (i) Each radar QPE estimator has its own advantages and disadvantages depending on the specific rainfall patterns, and it can outperform other estimators at a certain period of time; (ii) although R(AH, ZDR) underestimates in the light rain pattern, it performs best of all radar QPE estimators according to statistical scores; (iii) Both the optimal radar rainfall relationship and the consistency between radar measurements aloft and surface observations are required to obtain accurate rainfall estimates close to the ground. The contamination of melting solid hydrometeors on AH and/or KDP may make them less effective than ZH. In addition, appropriate α coefficient can eliminate the melting impact on the AH-based rainfall estimator.

How to cite: Gou, Y., Chen, H., and Zhou, J.: Polarimetric Radar Signatures and Performance of Various Radar Rainfall Estimators during an Extreme Precipitation Event over the Thousand-Island Lake Area in Eastern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3252, https://doi.org/10.5194/egusphere-egu2020-3252, 2020.

EGU2020-3939 | Displays | AS1.36

The relationship between intraseasonal precipitation of Iran and combined effects of MJO and NAO

Farnaz Pourasghar, Iman Babaiean, and Hooshang Ghaemi

Because of low precipitation and its severe fluctuations in Iran, understanding the dynamics of large scale climate modes and probability of annual and intraseasonal precipitation variation is essential for water management. This study investigates the characteristics of the combined effects of Madden-Julian Oscillation (MJO) and North Atlantic Oscillation (NAO) on precipitation over Iran. Daily precipitation and atmospheric data (relative humidity and vertical velocity) were analysed over Iran during wet season (October to May) for the period 1961 to 2018. The results indicated that: 1) Distinct difference can be observed in spatial distribution of the probability of daily precipitation above upper tercile for MJO phases, phase 1 and 2 wetter while 4 and 5 are drier. The relative humidity is higher in phases (1-3 and 7-8) and lower in phases (4-6). The vertical velocity shows upward (downword) motion in phases 1-2 and 7-8 (3-6). 2) Response of rainy season precipitation over Iran to MJO is more affected by the large-scale atmospheric variation associated with negative NAO as compared to positive NAO. In the negative NAO, the MJO increase (decrease) the probability of upper tercile precipitation 1.2 (0.7) times in phases 2-3 (4-6) and significant tests show a significantly large response for west and North west of Iran. In contrast of positive NAO, the relative humidity and vertical velocity is more affected by negative NAO state. The more (less) humidity and upward (downward) motions increase (decrease) precipitation in phases 2-3 (4-6).

How to cite: Pourasghar, F., Babaiean, I., and Ghaemi, H.: The relationship between intraseasonal precipitation of Iran and combined effects of MJO and NAO, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3939, https://doi.org/10.5194/egusphere-egu2020-3939, 2020.

EGU2020-6148 | Displays | AS1.36

A new particle–by –particle hot plate technique for measurement of precipitation rate, snow density and visibility

Karlie Rees, Timothy Garrett, Dhiraj Singh, Eric Pardyjak, and Allan Reaburn

The diameter, mass and density of individual falling snowflakes is being measured automatically in Salt Lake City, Utah using a new device called the  Differential Emissivity Imaging Disdrometer (DEID). Hydrometeor properties are obtained from the DEID using a temperature-controlled hotplate to melt and evaporate hydrometeors and a thermal camera based upon the large difference in thermal emissivity between water and the aluminum hotplate. The density of each particle is calculated from the initial effective diameter imaged by the thermal camera and the individual particle mass, by assuming conservation of energy for heat transfer from the plate to the melted droplet and measuring the time taken for evaporation. Simultaneously recorded Multi-Angle Snowflake Camera (MASC) imagery provides hydrometeor types. These data are revealing detailed structures of snowfall density suited for avalanche studies, atmospheric precipitation rate, snow water equivalent and visibility, and size, and the mass and density distributions of individual particles. Results are generally consistent with past studies by e.g. Marshall and Palmer, Marshall and Gunn and Locatelli and Hobbs. However, order one million particles can be collected in a single storm cycle, so the range of particle collected and the statistical validity of the analyses is providing new insights into the nature of frozen precipitation.

How to cite: Rees, K., Garrett, T., Singh, D., Pardyjak, E., and Reaburn, A.: A new particle–by –particle hot plate technique for measurement of precipitation rate, snow density and visibility, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6148, https://doi.org/10.5194/egusphere-egu2020-6148, 2020.

EGU2020-5477 | Displays | AS1.36

The quasi-global geographical distribution of precipitation system scale

Yan Zhang and Kaicun Wang

The scale of precipitation systems can provide important information to acquire a better understanding of formation mechanism and environmental effects of precipitation as well as model promotion. However, the global geographical distribution of precipitation system scale remains poorly known from previous studies. This study uses the latest Integrated Multi-satellitE Retrievals for Global Precipitation Measurement (IMERG) data to get global patterns of precipitation system scale by grouping the contiguous rainy gridboxes during 2015-2018. Our results show that the large precipitation systems (>103 km) occur more frequently over ocean and the midlatitude land areas with low precipitation amount such as Siberia as well as the western and central parts of North America. The most apparent seasonal variation of precipitation system scale occurs over midlatitude ocean along with the northern and southern coast of South America. Most regions of the world have the highest peak in the late afternoon at around 17:00 local time (LT). In a statistical average, the relationships between scale and other precipitation properties including amount, frequency, intensity and duration all seem to be positive. The strongest associations of scale with amount, frequency, intensity and duration all occur over tropics and ocean with the highest correlation coefficient greater than 0.8.

How to cite: Zhang, Y. and Wang, K.: The quasi-global geographical distribution of precipitation system scale, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5477, https://doi.org/10.5194/egusphere-egu2020-5477, 2020.

EGU2020-6594 | Displays | AS1.36

Retrieving high resolution rainfall data for Ecuador using GOES-16 and IMERG data

Nazli Turini, Boris Thies, Rütger Rollenbeck, Andreas Fries, Franz Pucha-Cofrep, Johanna Orellana Alvear, Natalia Horna, Rolando Célleri, and Jörg Bendix

Accurate rainfall information in high spatio-temporal resolution is important for water resource management, particularly in water-scarce remote areas which are characterized by a coarse network of operational precipitation gauge stations. For such regions, satellite-based rainfall products potentially represent a source for reliable and area-wide data on rainfall. The poster presents a new satellite-based precipitation algorithm for semi-arid regions in Ecuador with the elevation range between 12 to 5700 a.s.l. The algorithm relies on the combination of  precipitation information from the Integrated Multi-SatEllite Retrieval for the Global Precipitation Measurement (GPM) (IMERG) and infrared (IR) data from the Geostationary Operational Environmental Satellite 16 (GOES-16). The algorithm is developed to (i) classify the rainfall area and then (ii) to assign the rainfall rate. For the period between 19.04.2017 to 19.04.2018 the brightness temperature derived from GOES-16 IR channels and ancillary geo-information are trained with microwave only rainfall information of the half-hourly IMERG-V06 product using the machine learning algorithm random forest. The validation is done against independent microwave-only IMERG-V06 rainfall data not used for model training and available gauge stations. The validation results show overall very good accuracy of the new rainfall retrieval technique in this case study, mostly in comparison with the GPM IMERG IR-only rainfall product. The product offers the potential for high spatio-temporal (2 km, 15 min) rainfall resolution in near real-time for Ecuador.

How to cite: Turini, N., Thies, B., Rollenbeck, R., Fries, A., Pucha-Cofrep, F., Orellana Alvear, J., Horna, N., Célleri, R., and Bendix, J.: Retrieving high resolution rainfall data for Ecuador using GOES-16 and IMERG data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6594, https://doi.org/10.5194/egusphere-egu2020-6594, 2020.

EGU2020-5025 | Displays | AS1.36

Hydrometeor classification in convective clouds using cloud profiler data

Jana Minářová and Zbyněk Sokol

In this contribution, we investigate hydrometeors and their distribution in thunderclouds. We classify 5 kinds of hydrometeors using data of a Ka-band cloud profiler (35 GHz) situated at the weather station Milešovka in Central Europe. The classification of hydrometeors is based on calculated vertical air velocity, terminal velocity of a target, minimum and maximum terminal velocity of hydrometeor classes, and Linear Depolarization Ratio within three temperature intervals. We performed the classification for convective events that were observed at the station in 2018 and 2019 and were related to lightning in the vicinity of the station.

Results suggest that there is a link between lightning flashes observed close to the weather station (based on EUCLID data) and the presence of graupel, ice, snow, and hail. These are the hydrometeors (graupel and ice in particular) that are considered to play major role in thundercloud electrification by the collision of hydrometeors.

How to cite: Minářová, J. and Sokol, Z.: Hydrometeor classification in convective clouds using cloud profiler data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5025, https://doi.org/10.5194/egusphere-egu2020-5025, 2020.

EGU2020-18819 | Displays | AS1.36

Decadal change in summer precipitation over the east of Northwest China and its associations with atmospheric circulations and sea surface temperatures

Shasha Shang, Gaofeng Zhu, Ruolin Li, Jie Xu, Juan Gu, Huiling Chen, Xiaowen Liu, and Tuo Han

As global warming has progressed, precipitation patterns over arid Northwest China have undergone significant change. In this study, changes in summer (JJA) precipitation over the eastern part of Northwest China (ENWC) from 1980 to 2014 were investigated using the China gridded monthly precipitation dataset (CN05.1). The results showed that summer precipitation over the ENWC experienced a decadal wet-to-dry shift in 1998. Westerlies played an important role in the upper atmospheric levels in terms of water vapor transport; the decadal variations in summer precipitation were principally controlled by the water vapor input from the ENWC's western boundary. In addition, the decadal variations in summer precipitation in the ENWC appear to be associated with a meridional teleconnection around 110°E and a zonal pattern over 45–60°N in the lower troposphere. These two teleconnections led to cyclonic anomalies in the ENWC and enhanced water vapor transport into the ENWC, resulting in above-normal precipitation during the 1989–1998 decadal period. Further, the warmer (colder) sea surface temperatures (SSTs) observed in the tropical Eastern Pacific correspond to the southward (northward) displacement of the Asian jet stream and a negative (positive) phase of the Silk Road pattern, resulting in a wet (dry) ENWC. Moreover, the SST anomalies in the North Atlantic and Northwest Pacific may affect summer precipitation over the ENWC via a zonal teleconnection in the middle troposphere. Details about the results will be presented in the conference.

How to cite: Shang, S., Zhu, G., Li, R., Xu, J., Gu, J., Chen, H., Liu, X., and Han, T.: Decadal change in summer precipitation over the east of Northwest China and its associations with atmospheric circulations and sea surface temperatures , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18819, https://doi.org/10.5194/egusphere-egu2020-18819, 2020.

EGU2020-7511 | Displays | AS1.36

Deepening our understanding of shallow precipitation measurements from space

Linda Bogerd, Hidde Leijnse, Aart Overeem, and Remko Uijlenhoet

Satellite-based remote sensing provides a unique opportunity for the estimation of global precipitation patterns. In order to use this approach, it is crucial that the uncertainty in the satellite estimations is precisely understood. The retrieval of high-latitude precipitation (especially shallow precipitation) remains challenging for satellite precipitation monitoring. This project will quantify the quality of the precipitation estimations obtained from the Global Precipitation Measurement (GPM) mission, where the focus will be on the level II and III products. Initially, the Netherlands is chosen as research area, since it has an excellent infrastructure with both in-situ and remotely sensed ground-based precipitation measurements, its flat topography, and the frequent occurrence of shallow precipitation events. The project will study the influence of precipitation type and the impact of the seasons on the accuracy of the GPM products. Hereafter, the project will focus on the physical causes behind the discrepancies between the GPM products and the ground validation, which can be used to improve the retrieval algorithms. The presentation will outline the project structure and will demonstrate the initial results.

How to cite: Bogerd, L., Leijnse, H., Overeem, A., and Uijlenhoet, R.: Deepening our understanding of shallow precipitation measurements from space, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7511, https://doi.org/10.5194/egusphere-egu2020-7511, 2020.

EGU2020-9718 | Displays | AS1.36

A method to fill-in discontinued daily precipitation series from nearby stations

Manolis G. Grillakis, Christos Polykretis, and Dimitrios D. Alexakis

Cornerstone of the meteorological and climatological science is the quality measurements of the precipitation. Large instrumentation gaps occur due to network destructions (fires, wars) or even technical limitations that dictate network reorganizations. This is a difficult to tackle issue as there are legacy networks that provide decades of valuable data, but for various reasons have been discontinued. A method to work out such problems is to include only part of the data to the analyses, or to use methods to fill the measuring gaps from nearby stations, such as interpolation techniques, regression techniques. In this work, we present and assess a method to estimate missing values in daily precipitation series based on a quantile mapping approach, originally used for bias correction of climate model output. The overall methodology is based on a three-step procedure. The first is to assess the missing values from nearby stations using inverse distance weighting interpolation method. Then, as a second step, the wet day fraction is adjusted to fit the respective fraction of the target point existing data. The third step is to adjust the biases in the probability density function of the filled values towards the target point existing data, using the Multi-segment Statistical Bias Correction methodology (MSBC- Grillakis et al., 2013). The methodology is applied to each calendar month separately. The presented methodology has the advantage of correcting the number of rainy days that is usually overestimated by conventional interpolation approaches, as well as, better reproduces large daily precipitation values. The methodology is assessed for its performance on completing the timeseries of a dense precipitation stations network, using data of a second, also dense station network for the island of Crete – Greece. Conceptual limitations of the method are discussed.

Acknowledgments: This research has received funding from the Hellenic Foundation for Research and Innovation (HFRI) and the General Secretariat for Research and Technology Hellas (GSRT), under Agreement No 651.

How to cite: Grillakis, M. G., Polykretis, C., and Alexakis, D. D.: A method to fill-in discontinued daily precipitation series from nearby stations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9718, https://doi.org/10.5194/egusphere-egu2020-9718, 2020.

EGU2020-10932 | Displays | AS1.36

Advances in knowledge 10 years after the torrential rains in Madeira Island (Portugal)

Rui Salgado, Flavio T. Couto, and Maria Joao Costa

On February 20, 2010, Madeira island was affected by a tragic event of extreme precipitation. The event was marked by huge economical damage estimated in millions of euros, and more than 40 deaths. Before the event, there were not many studies about severe precipitation in Madeira, which were highly motivated after 2010. This work intent is to show some advancements in knowledge of heavy precipitation events (HPE) in Madeira found in the last decade. The Meso-NH model was used with a rather complete parametrization package of several physical processes occurring in the atmosphere and configured into different dimensions. In order to explore the meridional water vapour transport, the total precipitable water field was extracted from the Atmospheric Infrared Sounder (AIRS) data products. In the first set of simulations, the experiments were performed with three horizontal nested domains (9 km, 3 km, and 1 km resolution). The results for the winter 2009-2010 raised two questions about the topic. First, associated with the large scale environment, and the second one linked to orographic effects. In the first case, apart from a cyclone affecting the island, it was identified the presence of atmospheric rivers (ARs) coupled to frontal systems transporting tropical moisture toward the island. For the orographic effects, the simulations at 1km resolution showed maximums of accumulated precipitation in the highlands. Subsequently, the analysis of the precipitation in Madeira highlands over a 10-year period showed dry summers and the highest rainfall amounts in the winters, although with some significant events occurring also in autumn and spring seasons. Furthermore, it was found that tropical moisture transported through the ARs may reach the island with different intensities and orientation during the winter seasons. However, for the 10 winter periods, the ARs were not the sole factor producing HPE in Madeira. In the second set of simulations, the model was configured with a larger domain of 2.5 km resolution and an inner domain of 0.5 km resolution. All the significant events in autumn 2012 were simulated confirming the orographic effect in the accumulated precipitation. The most interesting result found was the occurrence of maximums values in different regions over the island. For example, over the highlands in the central peaks and southern/northern slopes, or in the coastal plain at lowlands. From the simulations it was possible to explain the causes for the distinct rainfall patterns, and the atmospheric environments associated. The variations in the configuration of the ambient flow, jointly with the orographic forcing may produce convection in distinct regions of the island, resulting in different rainfall patterns. Ten years later, the advances in the understanding of significant precipitation in the Madeira is evident. The results show how different events may occur, since the formation or enhancement of the precipitation over the island is totally dependent on the geographic aspects and atmospheric conditions associated with each precipitating event.

How to cite: Salgado, R., Couto, F. T., and Costa, M. J.: Advances in knowledge 10 years after the torrential rains in Madeira Island (Portugal), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10932, https://doi.org/10.5194/egusphere-egu2020-10932, 2020.

Evaluations of satellite precipitation estimates have been routinely conducted, often in individual gridbox. However, real precipitation is organized as precipitation system in space with a certain extent and structure. Evaluation from the perspective of precipitation system to understand the relationship between satellite errors with the spatial extent of precipitation system and relative location in precipitation system may help to the better knowledge of satellite error sources but has rare been concerned. To address this issue, the Integrated Multi-satellitE Retrievals for GPM (IMERG) V05B final run half-hourly product is evaluated in this study with hourly rain gauge data collected at approximately 50,000 stations in China. We first identify the precipitation system in IMERG and make comparison in gridboxes with gauge observations as a function of gridboxes’ distance to the boundaries of system and the system sizes to investigate their relationships. Our results show that the false alarm proportions generally decrease as the increase of precipitation system sizes, while it is opposite for the miss proportions. Both the miss and false alarm proportion evidently decrease with the longer distance from the boundaries. Over 90% false alarms occur within the distance of 10% of the square root of precipitation system sizes from the boundaries, while 90% misses locate within the distance of 20% the square root of system sizes. The difference between the false alarm proportion inside the systems and miss proportion outside the systems in accordant distances from the boundaries indicate the generally overestimation of IMERG precipitation system sizes, but much severer for small systems than large systems. For the hit bias, IMERG generally underestimates in small precipitation systems but have regional-dependent sign of bias for larger systems. Accordantly, IMERG underestimates the hit precipitation rates for all distances from the boundaries, but the situation is more complex for larger precipitation systems, with an overestimation for about 0-50 km but underestimation for about 50-200km and again overestimation for over about 200km, indicating the evident location-dependent errors in precipitation system of IMERG.

How to cite: Li, R., Wang, K., and Qi, D.: Dependence of GPM precipitation product performance on the spatial extent of precipitation system and relative location in precipitation system, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11060, https://doi.org/10.5194/egusphere-egu2020-11060, 2020.

EGU2020-17684 | Displays | AS1.36

High-resolution gridded extreme precipitation indices for the wider Greek Region

Panagiotis T. Nastos, George E. Ntagkounakis, and Emmanuel Vassilakis

The goal of this study is to create a high-resolution grid of precipitation indices for the wider Greek region using real data from meteorological stations for the 1980-2010 period. Under the risk of increased extreme events caused by climate change, it is important to be able to have a high-resolution gridded extreme precipitation indices in order to overcome the lack of density of observations in both time and space. The development of such a grid can be used to validate model outputs and inform decision makers to better mitigate the damage from extreme precipitation.

The first step of the analysis is to calculate the extreme precipitation indices based on daily observations derived from more than 100 meteorological stations covering a wide range of altitudes and spatial climate patterns existing in Greece. Thereafter, the extreme indices will be multilinearly downscaled to a 12-meter resolution grid. The geophysical parameters used in the downscaling procedure consists of altitude, latitude, longitude, slope, aspect, solar irradiance and Euclidian distance from the water bodies. The altitude information came from the highly accurate 12-meter resolution TanDEM-X Elevation Model, which is a product generated from the TerraSAR-X satellite mission data. The resulting high-resolution patterns will give insight of the spatial and temporal variability of extreme precipitation, over the complex terrain of the wider Greek region.

How to cite: Nastos, P. T., Ntagkounakis, G. E., and Vassilakis, E.: High-resolution gridded extreme precipitation indices for the wider Greek Region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17684, https://doi.org/10.5194/egusphere-egu2020-17684, 2020.

EGU2020-22460 | Displays | AS1.36

Quantitative precipitation estimation in Antarctica using different ZE-SR relationships based on snowfall classification combining ground observations by radar and disdrometer

Alessandro Bracci, Nicoletta Roberto, Luca Baldini, Mario Montopoli, Elisa Adirosi, Eugenio Gorgucci, Claudio Scarchilli, Paolo Grigioni, Virginia Ciardini, Gianluca Di Natale, Luca Facheris, Vincenzo Levizzani, and Federico Porcù

The Antarctic Ice Sheet plays a major role in regional and global climate variability and represents, probably, the most critical factor of future sea-level rise. Snow and solid precipitation more broadly have been recognized as primary mass input for ice sheet. However, despite its fundamental role in the surface mass balance estimation, precipitation over Polar region and in the Antarctica particularly, remains largely unknown, being not well assessed by numerical weather/climate models, by ground observations and satellite measurements as well. More accurate estimations of precipitation in the Antarctic continent are desirable not only in understanding the behavior of the Antarctic Ice Sheet, but also in validating global climate and numerical weather prediction models and also in order to constrain measurements from space during validation/calibration satellite campaigns.

Recently, several observatories in Antarctica have been equipped with equipment for cloud and precipitation measurements, such as the two Italian stations “Mario Zucchelli”, Terra Nova Bay, and Concordia, in the Antarctic Plateau. At “Mario Zucchelli”, instrumentation includes 24-GHz vertical pointing radar Micro Rain Radar (MRR) and optical disdrometer. The synergetic use of such set of instruments allows for characterizing and quantifying precipitation, even if quantitative estimate of precipitation from radar is extremely demanding, especially in snowfall, because of variability microphysical features of hydrometeors.

Usually precipitation estimation methods with weather radar are based on relationships between radar equivalent reflectivity factor (Ze) and liquid equivalent snowfall rate (SR). Several relationships are reported in literature, derived from comparison between radar and ground sensors but very few are suitable for the Antarctic continent and none also considers the microphysical characterization of hydrometeors.

This work shows quantitative estimate of the Antarctic precipitation for several snow episodes at the Mario Zucchelli station using specific ZE-SR relationships also taking into account the snowfall classification according to dominating hydrometeor type (e.g. pristine, aggregate, dendrite, plate). Microphysical properties of precipitation are inferred by comparing radar measurements with simulations obtained from disdrometer measurements in terms of reflectivity factor. Specifically, the Ze directly derived by radar has been compared with the Ze calculated by disdrometer observations coupling particle size distributions and NASA database of hydrometeor backscattering values based on the Discrete Dipole Approximation. More challenging are estimations at Concordia, where ice particles have very small sizes and are hardly detectable by laser disdrometer, and where MRR lacks of adequate sensitivity.

How to cite: Bracci, A., Roberto, N., Baldini, L., Montopoli, M., Adirosi, E., Gorgucci, E., Scarchilli, C., Grigioni, P., Ciardini, V., Di Natale, G., Facheris, L., Levizzani, V., and Porcù, F.: Quantitative precipitation estimation in Antarctica using different ZE-SR relationships based on snowfall classification combining ground observations by radar and disdrometer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22460, https://doi.org/10.5194/egusphere-egu2020-22460, 2020.

Assessing the accuracy of precipitation sensors can prove very challenging due to the lack of a universal test standard, stemming from difficulties in creating a controlled test scenario. We propose a refined method of testing that is highly reproducible and can be applied to any precipitation sensor regardless of sensing technology.

It is widely understood that two identical disdrometers mounted close together in a real rain event are not likely to report the same precipitation measurements due to the small scale spatial variation of rain. This makes it difficult to draw comparisons between sensors of the same type and even more difficult to compare rain sensors that have different sensing areas and use different sensing technologies. It is therefore desirable to simulate rainfall in the laboratory that is representative of real world conditions but this presents its own set of challenges, primarily in creating rain drops that travel at terminal velocity. This test method significantly reduces the impact of this issue.

This is particularly important for sensors such as optical, acoustic, radar or impact, where the calculations used to obtain rainfall accumulation and drop size distribution assume that the droplets are at terminal velocity. Even for sensors such as capacitive rain gauges and tipping buckets, where the velocity of fall is not directly related to the measurements, more valid conclusions can be drawn about the sensor’s ability to measure precipitation when the droplets imitate real rainfall as closely as possible.

Here, the development of a drip rig capable of creating raindrops of a controlled size is documented. The drip rig can be mounted at a known height and used to test a variety of different precipitation sensors. However, due to height restrictions in the laboratory, it is not possible to get larger raindrops to terminal velocity. Mounted at a height of 7.4m, drops above 2 mm in diameter do not reach 99% terminal velocity, and drops above 3 mm do not reach 95%. For this reason, corrections must be applied to the calculations. It is therefore essential to have an understanding of the change in fall velocity of a water droplet with fall distance.

This work documents the equations used to calculate drop velocity with fall distance for different drop masses. Temperature, humidity and air pressure define air density, which has a significant impact on the velocity of a falling water droplet. The effect of each of these environmental factors has been investigated in order to allow for further corrections. Performing these corrections greatly improves the validity and repeatability of the tests carried out on precipitation sensors.

How to cite: Frame, G. and Spencer, E.: The development of a laboratory drip rig for performing reproducible comparisons on different precipitation sensors by correcting for environmental conditions and rig set up, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18046, https://doi.org/10.5194/egusphere-egu2020-18046, 2020.

EGU2020-18417 | Displays | AS1.36

Correcting position error in rainfall estimates using temporal and spatial warping

Camille Le Coz, Arnold Heemink, Martin Verlaan, Marie-claire ten Veldhuis, and Nick van de Giesen

An increasing number of satellite-based rainfall estimates, with ever finer resolution, are becoming available. They are particularly valuable in regions with sparse radar and gauge networks. For example, in most of sub-Saharan Africa, the gauge network is not dense enough to represent the high variability of the rainfall during the monsoon season. However, satellite-based estimates can be subject to errors in position and/or timing of the rainfall events, in addition to errors in the intensity.
Many satellite-based estimates use gauge measurements for bias correction. Bias correction methods focus on the intensity errors, and do not correct the position error explicitly. We propose to gauge-adjust the satellite-based estimates with respect to the position and time. We investigate two approaches: spatial and temporal warping. The first one is based on a spatial mapping and correct the spatial position while keeping the time constant. The second uses a temporal mapping and keeps the spatial domain unchanged. The mappings are derived through a fully automatic registration method. That is, only the gauge and satellite-based estimates are needed as inputs. There is no need to manually predefine the rain features.
The spatial and temporal approaches are both applied to a rainfall event during the monsoon season in southern Ghana. The Trans-African Hydro-Meteorological Observatory (TAHMO) gauge network is used to gauge-adjust the IMERG-Late (Integrated Multi-Satellite Retrievals for GPM) satellite-based estimates. The two approaches are evaluated with respect to the timing, the location and the intensity of the rainfall event.

How to cite: Le Coz, C., Heemink, A., Verlaan, M., ten Veldhuis, M., and van de Giesen, N.: Correcting position error in rainfall estimates using temporal and spatial warping, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18417, https://doi.org/10.5194/egusphere-egu2020-18417, 2020.

EGU2020-18636 | Displays | AS1.36

Development of a microwave-based precipitation climate data record for the Copernicus Climate Change Service

Giulia Panegrossi, Paolo Sanò, Leonardo Bagaglini, Daniele Casella, Elsa Cattani, Hannes Konrad, Anja Niedorf, Marc Schröder, Anna Christina Mikalsen, and Rainer Hollmann

Within the Copernicus Climate Change Service (C3S), the Climate Data Store (CDS) built by ECMWF will provide open and free access to global and regional products of Essential Climate Variables (ECV) based on satellite observations spanning several decades, amongst other things. Given its significance in the Earth system and particularly for human life, the ECV precipitation will be of major interest for users of the CDS.

C3S strives to include as many established, high-quality data sets as possible in the CDS. However, it also intends to offer new products dedicated for first-hand publication in the CDS. One of these products is a climate data record based on merging satellite observations of daily and monthly precipitation by both passive microwave (MW) sounders (AMSU-B/MHS) and imagers (SSMI/SSMIS) on a 1°x1° spatial grid in order to improve spatiotemporal satellite coverage of the globe.

The MW sounder observations will be obtained using, as input data, the FIDUCEO Fundamental Climate data Record (FCDR) for AMSU-B/MHS in a new global algorithm developed specifically for the project based on the Passive microwave Neural network Precipitation Retrieval approach (PNPR; Sanò et al., 2015), adapted for climate applications (PNPR-CLIM). The algorithm consists of two Artificial Neural Network-based modules, one for precipitation detection, and one for precipitation rate estimate, trained on a global observational database built from Global Precipitation Measurement-Core Observatory (GPM-CO) measurements. The MW imager observations by SSM/I and SSMIS will be adopted from the Hamburg Ocean Atmosphere Fluxes and Parameters from Satellite data (HOAPS; Andersson et al., 2017), based on the CM SAF SSM/I and SSMIS FCDR (Fennig et al., 2017). The Level 2 precipitation rate estimates from MW sounders and imagers are combined through a newly developed merging module to obtain Level 3 daily and monthly precipitation and generate the 18-year precipitation CDR (2000-2017).

Here, we present the status of the Level 2 product’s development. We carry out a Level-2 comparison and present first results of the merged Level-3 precipitation fields. Based on this, we assess the product’s expected plausibility, coverage, and the added value of merging the MW sounder and imager observations.

References

Anderssonet al., 2017, DOI:10.5676/EUM_SAF_CM/HOAPS/V002

Fennig, et al., 2017, DOI:10.5676/EUM_SAF_CM/FCDR_MWI/V003

Sanò, P., et al., 2015, DOI: 10.5194/amt-8-837-2015

How to cite: Panegrossi, G., Sanò, P., Bagaglini, L., Casella, D., Cattani, E., Konrad, H., Niedorf, A., Schröder, M., Mikalsen, A. C., and Hollmann, R.: Development of a microwave-based precipitation climate data record for the Copernicus Climate Change Service, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18636, https://doi.org/10.5194/egusphere-egu2020-18636, 2020.

EGU2020-18803 | Displays | AS1.36

Bluff body aerodynamics of the Thies Laser Precipitation Monitor investigated using CFD and wind tunnel measurements

Mattia Stagnaro, Enrico Chinchella, Arianna Cauteruccio, and Luca Giovanni Lanza

Optical disdrometers are among the non-catching type instruments used to measure liquid and solid precipitation. The increasing use of such instruments in operational observations is due to their capability to provide additional information than the precipitation rate alone, like e.g. the particle size distribution and the fall velocity of hydrometeors. Furthermore, they are well suited to operate in unattended, automatic weather stations. Having no collector to catch the approaching hydrometeors, their outer shape strongly depends on the measuring principle exploited. The impact of wind on the measurement is therefore different from the typical undercatch that is expected from more traditional catching type precipitation gauges. In general, they are not axisymmetric and base the identification and classification of hydrometeors on the coupling of particle size and fall velocity characteristics, which can be affected by the wind and by the airflow deformation and turbulence produced by their bluff-body aerodynamic response. The focus of this work is the Thies Laser Precipitation Monitor (LPM), which uses an optical sensor to detect the obstruction of an infrared laser beam caused by the crossing hydrometeors. The reduction in the sensor output voltage is proportional to the drop dimension, while the duration of the reduction is proportional to the drop falling speed. This instrument presents a very complex and not axisymmetric outer shape that makes it difficult to qualitatively predict the flow pattern and requires to consider multiple wind directions and wind speeds. The airflow field was obtained with a Computational Fluid Dynamics (CFD) approach, by numerically solving the Reynolds Averaged Navier-Stokes equations with the k-ω SST turbulence closure model. Results are validated through local flow velocity measurements obtained in the DICCA wind tunnel. The Thies LPM® was placed in the measuring chamber of the wind tunnel (1.7 x 1.35 x 8.8 m) on to a rotating plate and the airflow velocity was sampled at multiple positions around the instrument. The measurements were obtained using a traversing system equipped with a “Cobra” multi hole pressure probe, that provides the three velocity components of the local flow. Different orientation angles of the gauge with respect to the incoming flow direction were tested. Based on the simulations and wind tunnel tests performed, the less impacting configuration of the instrument relative to the main wind direction is obtained. The information can be useful to design effective solutions to minimise the impact of wind and turbulence on the measurements (e.g. windshields) and to derive suitable correction curves to improve the measurement accuracy. This work is funded as part of the activities of the EURAMET – Normative project “INCIPIT – Calibration and Accuracy of Non-Catching Instruments to measure liquid/solid atmospheric precipitation”.

How to cite: Stagnaro, M., Chinchella, E., Cauteruccio, A., and Lanza, L. G.: Bluff body aerodynamics of the Thies Laser Precipitation Monitor investigated using CFD and wind tunnel measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18803, https://doi.org/10.5194/egusphere-egu2020-18803, 2020.

EGU2020-22114 | Displays | AS1.36

Analisys of recent snow volumic mass and elevation of the threshold of natural skiability (lan) in the frioulan alps

Massimiliano Fazzini, Alessandro Cecili, Enrico Miccadei, Daniele Moro, and Carlo Bisci

The Friulian Alps show peculiar meteorologica and climatic features, deriving also from their geographic position between the northern Adriatic Sea to the South, the main Alpine watershed to the North (Tauern Alps) and the Carpathian belt to the East. Furthermore, there are many topoclimatic situations in relation to the geographic setting of the valleys carved between the main reliefs. This makes the Frioulian territory among the wettest in the entire Alpine region, with very abundant snowfall in relation to the moderate average altitude. Thanks to the availability of continuous and fairly homogeneously distributed historical series, a nivological characterization was carried out at the regional scale, with particular attention to the trend of the density of fresh snow, of the number of days with snow thickness higher than 30 cm and the consequent average elevation of the threshold of 100 skiable days (LAN). The ten snow fields under examination are located at elevations between 603 m. (Claut, Carnic Prealps) and 1843 m. (Rifugio Gilberti, Julian Alps); the analysed timespan goes from the winter season 1990-91 to the 2018-19. Surprising data resulted from this analysis. First of all, we noted that the volume mass (Kg /m3), which cannot be correlated with altitude, tends to a very light decrease (about 1.3 km/mc for year) in all the recording stations: this seems to be in contrast with the strong thermal increase that is occurring also on the Frioulian Alps (about 1.1°C in the same time span). Therefore, it’s very probable that in the last few years the thermal characteristics have changed, maybe together with the main origin of the air masses bringing snow in the study area. We also noted for all the stations an increase in the number of days with Hs> 30 cm: consequently, the average elevation of the limit of 100 days with natural ski possible is at about 1780 m a.s.l. and tends to decrease by about 7 meters per year (14 m in the nearby Slovenian Alps), even though it cannot be correlated with the aforementioned positive variation in temperatures and is in disagreement with the corresponding signals calculated for the northern side of the Alps.

How to cite: Fazzini, M., Cecili, A., Miccadei, E., Moro, D., and Bisci, C.: Analisys of recent snow volumic mass and elevation of the threshold of natural skiability (lan) in the frioulan alps, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22114, https://doi.org/10.5194/egusphere-egu2020-22114, 2020.

Warm clouds have a huge impact on radiative forcing and also precipitation properties. Knowledge about their raindrop size distribution (RSDs) is useful in realizing rain integral parameter and in the understanding of precipitation microphysics. Unfortunately, as a result of the discontinuity of spatiotemporal observation, obtaining a detailed process that occurs in warm clouds is still challenging. In this study, we try to identify the characteristics of cloud microphysical processes in warm rain formation over Northern Taiwan. The detailed analysis is conducted by using a combination of Joss-Waldvogel Disdrometer (JWD) and Himawari-8 in North Taiwan from December 2017 to January 2018.

The preliminary result shows that different rainfall intensity can build different kinds of RSDs.  In Taiwan winter season, warm rain has a lower concentration of midsize and large raindrops as compared to mixed and cold rain. However, small raindrops are more dominant than middle and large drops for warm rain. It is found that both microphysical properties (Cloud Optical Thickness/COT, Cloud Liquid Water Path/CLWP, and Cloud Effective Radius/CER) and Gamma parameter distribution are varied as the rain rate varied. A lower rain rate (e.g., drizzle) has resulted from a wider range of cloud microphysical properties while a higher rain rate (e.g., stronger rain rate) has resulted from certain ranges of cloud microphysical properties. The Gamma parameter distribution shows more homogenous distribution as the rain rate increase.

 

How to cite: Matondang, C. A. and Liu, C.-Y.: Warm Cloud Microphysical Properties and their Associated Raindrop Size Distributions over Northern Taiwan, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19938, https://doi.org/10.5194/egusphere-egu2020-19938, 2020.

Microphysical processes in cold precipitating clouds are not fully understood and their parametrization in atmospheric models remains challenging . In particular the lack of evaluation and validation of the microphysical parameterizations in polar regions questions the reliability of the ice sheet surface mass balance assessments. Recently, strong discrepancies have been found in the precipitation structure between simulations with different microphysical parameterizations over the Antarctic coast.

The dissimilarities between simulations seem to be due to different treatments of the riming, aggregation and sublimation processes.

 

Evaluating the representation of a particular microphysical process in a model is delicate, especially because it is difficult to obtain in situ estimations, even qualitative, of a given microphysical process. In this study, we developed a method to identify the regions in radar scans where either aggregation and riming, vapor deposition or sublimation are the dominant microphysical processes.

This method is based on the vertical (downward) gradients of reflectivity and differential reflectivity computed over columns extracted from range height indicator scans. Because of the expected increase in size and decrease in oblateness of the particles, aggregation and riming are identified as regions with positive gradients of reflectivity and negative gradients of differential reflectivity. Because of the expected increase in size and oblateness, vapor deposition is identified as regions with positive gradients of reflectivity and positive gradients of differential reflectivity. Because of the expected decrease in size and in concentration, snowflake sublimation, and possibly snowflake breakup, are defined as regions with negative gradients of reflectivity.

 

The method was employed on two frontal precipitation events, which took place during the austral summer APRES3 campaign (2015-2016) in Dumont d’Urville (DDU) station, Antarctic coast. Significant differences appear in the mean altitudinal distribution where each process takes place. Given that the radar signal extends up to 4500 m a.g.l., we could show that crystal growth dominates around 2800 m while aggregation and riming prevail around 1500 m. Sublimation mostly occurs below 900 m, concurring with previous studies stating that snowflakes preferentially sublimate in the relatively dry katabatic boundary layer.

Moreover the statistical distributions of different radar variables provides quantitative information to further characterize the microphysical processes of interest.

This method could be further used to assess the ability of atmospheric models to reproduce the correct microphysical processes at the correct locations.

How to cite: Planat, N., Gehring, J., Vignon, E., and Berne, A.: Automatic identification of the dominant microphysical processes in snowfall over the Antarctic coast using polarimetric radar observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21653, https://doi.org/10.5194/egusphere-egu2020-21653, 2020.

EGU2020-1907 | Displays | AS1.36

Assessment of IMERG precipitation over Taiwan at multiple timescales

Wan-Ru Huang, Ya-Hui Chang, and Pin-Yi Liu

Since March 2014, the Global Precipitation Measurement (GPM) Integrated Multi-satellitE Retrievals for GPM (IMERG) has provided satellite precipitation estimates across the globe. Using gridded surface precipitation data derived from local rain gauges as a reference, this study evaluated the performance of IMERG in depicting the spatial-temporal characteristics of precipitation variations over Taiwan at multiple (including annual, seasonal, intraseasonal, diurnal and semidiurnal) timescales. The analysis focused on the period of March 2014-February 2017. Our results show that, quantitatively, IMERG underestimated the magnitude of precipitation over most of Taiwan for all the examined timescales; spatially, the bias in variability was larger over the mountainous areas than over the plain areas; temporally, the bias in variability was larger in the warm seasons than in the cold seasons. Despite the magnitude differences, IMERG was capable of qualitatively depicting several distinct features of Taiwan precipitation changes, listed as follows: (1) a bimodal pattern, with a peak in May and another peak in September, in the annual evolution of precipitation area averaged over Taiwan; (2) a seasonal counterclockwise rotation feature, with the precipitation maximum located over northern Taiwan in the winter, over northwestern Taiwan in the spring, over southwest Taiwan in the summer and over eastern Taiwan in the autumn; (3) a 10-to-35-day intraseasonal oscillation feature, with a transition of variations from smaller amplitudes in the cold seasons to larger amplitudes in the warm seasons, occurring around mid-May (i.e., the so-called Meiyu onset in Taiwan); and (4) a roughly out-of-phase feature, with a morning precipitation maximum in the winter and an afternoon precipitation maximum in the other seasons, for the diurnal evolution of the area-averaged precipitation over Taiwan. In addition, IMERG was capable of qualitatively depicting the phase evolution of semidiurnal precipitation over Taiwan in most seasons, except for the winter season.

How to cite: Huang, W.-R., Chang, Y.-H., and Liu, P.-Y.: Assessment of IMERG precipitation over Taiwan at multiple timescales, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1907, https://doi.org/10.5194/egusphere-egu2020-1907, 2020.

AS1.37 – Aviation Meteorology And Nowcasting: Observations and Models (AMANOM)

EGU2020-12169 | Displays | AS1.37 | Highlight

Aviation meteorology in a changing climate

Paul Williams

The climate is changing, not just where we live at ground level, but also where we fly in the upper troposphere and lower stratosphere. Climate change has important consequences for aviation, because the atmosphere’s meteorological characteristics strongly influence flight routes, journey times, and turbulence. This presentation will review the possible impacts of climate change on aviation, which have only recently begun to emerge (as opposed to the impacts of aviation on climate change, which have long been recognised).

Turbulence currently injures hundreds of air passengers each year worldwide, costing airlines hundreds of millions of dollars and occasionally causing structural damage to planes. To investigate the influence of climate change on turbulence, we diagnose an ensemble of 21 clear-air turbulence measures from climate model simulations. We find that turbulence strengthens significantly under climate change, all around the world, in all seasons, and at a wide range of aircraft cruising altitudes. For example, within the transatlantic flight corridor in winter at around 39,000 feet, the occurrence of light turbulence increases by an ensemble-mean value of 59% (with an intra-ensemble range of 43–68%), light-to-moderate by 75% (39–96%), moderate by 94% (37–118%), moderate-to-severe by 127% (30–170%), and severe by 149% (36–188%). These findings underline the urgent need to improve the skill of operational clear-air turbulence forecasts, to avoid increases in on-board discomfort and injuries in the coming decades.

To investigate the influence of climate change on flight routes and journey times, we feed atmospheric wind fields generated from climate model simulations into a routing algorithm of the type used operationally by flight planners. We focus on transatlantic flights between London and New York, and how they change when the atmospheric carbon dioxide (CO2) concentration is doubled. We find that a strengthening of the prevailing jet-stream winds causes eastbound flights to significantly shorten and westbound flights to significantly lengthen in all seasons. For example, eastbound and westbound crossings in winter become approximately twice as likely to take under 5 hours 20 minutes and over 7 hours, respectively. Even assuming no future growth in aviation, the extrapolation of our results to all transatlantic traffic suggests that aircraft will collectively be airborne for an extra 2,000 hours each year, burning an extra 7.2 million gallons of jet fuel at a cost of US$ 22 million, and emitting an extra 70 million kg CO2.

The above findings provide further evidence of the two-way interaction between aviation and climate change, which is an emerging research area that deserves further study.

How to cite: Williams, P.: Aviation meteorology in a changing climate, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12169, https://doi.org/10.5194/egusphere-egu2020-12169, 2020.

Fog that limit visibility and low-level stratiform clouds represent a significant hazard to aviation especially during takeoff and landing, and also low-level flying of aircrafts, because accidents often occur in reduced visibility conditions and low clouds. Therefore, forecasting fog and low ceilings is one of the most important, but at the same time the most difficult issue, because both phenomena strongly depend on local conditions and unsteady in both time and space. So weather observations can be used for statistical dependencies of fog/ low-level stratiform cloud characteristics on numerical model outputs.

To study fog and low-level stratiform clouds event characteristics occurring at the airport of Odessa, Ukraine, half hourly observations in the period of 2010-2018 are used. Applying a statistical approach annual, seasonal and diurnal distribution of fog and low stratus and their frequency distribution associated with various meteorological parameters are obtained.

The monthly distributions of low-level stratiform clouds reveal maximum occurrence frequencies in November and January, and fog most frequently occurs in December. No significant diurnal cycle of stratiform cloud occurrence is discovered, as opposed to fog for which the highest frequency is observed in the hours before sunrise, while when the day sets in, frequencies are declining and increasing at night.

Fog and low-level stratiform clouds have the same distribution in duration and the mean event duration is 4.5 h while 55% of the events lasted 2 h or less. The most long-lived fog and stratiform clouds can last about 4 days during the December-January period.

Occurrence of fog and stratiform clouds as function of temperature and relative humidity reveals a close statistical relationship, especially for fog events. More than 33% of all fogs are observed at temperatures of 0°C to 6°C and 96-100% relative humidity, the most frequencies of low-level clouds (13%) occur in the same temperature interval, but at lower values of relative humidity (91-95%).

Regarding fog density 75% of the events have minimum visibility lower than 400 m, which indicates the severity of the problem, because, despite the season and type of fog, they are usually quite intense and dense.

In all seasons of the year, the highest frequency of low-level stratiform clouds is in interval of 3...4 m/s, excluding summer, when most often such cloud is registered at higher speeds. The wind directions associated with low-level stratiform clouds are, as a rule, northern and eastern ones, which meant that forming stratiform clouds is also related to cyclonic activity.

Fogs, on the contrary, most often in all seasons, except winter, are formed at calm, meaning that radiation fogs are the most common type in the Odessa airport. In winter fogs are most commonly associated with northern and easterly winds; in all other seasons the southern wind is the most frequent.

On this basis, a relationship between the weather conditions near the surface and occurrence of fog and low-level stratiform clouds can be found.

How to cite: Khomenko, I. and Hustenko, O.: Evaluation of local weather observations as predictors of fog and low-level stratiform clouds at the airport of Odessa, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-878, https://doi.org/10.5194/egusphere-egu2020-878, 2020.

EGU2020-4677 | Displays | AS1.37

Application of nighttime fog detection method using MSG8 SEVIRI in an arid environment

Michael Weston and Marouane Temimi

The detection of fog and low cloud (FLC) from satellite data remains challenging despite advances in methodologies and technology. Current methods make use of one or a combination of channel differencing from satellite instruments, surface observations, model data or artificial intelligence. An alternative to the brightness temperature difference method was developed for the GOES-R advanced baseline imager (ABI) which makes use of a channel ratio instead of a channel difference. We apply this method, the so called pseudo emissivity of the 3.9 µm channel, to SEVIRI MSG8 data over the United Arab Emirates, a desert region of the Arabian Peninsula. Low cloud is removed using temperature difference between ERA5 land surface temperature and 10.8 µm channel brightness temperature. Visual inspection of the final fog only mask shows that this method works well over this region. Verification at three sites where METAR data is available returned POD (FAR) of 0.77 (0.27), 0.50 (0.65) and 0.83 (0.26) respectively. Application of this method can be further developed to represent seasonal fog distribution and frequency across the United Arab Emirates.

How to cite: Weston, M. and Temimi, M.: Application of nighttime fog detection method using MSG8 SEVIRI in an arid environment , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4677, https://doi.org/10.5194/egusphere-egu2020-4677, 2020.

The outgoing longwave radiation (OLR) is a crucial parameter for studying many areas in the atmospheric science, including the investigations of the cloud/water vapor/radiative interaction processes, climate variability, and for climate change monitoring and numerical model evaluation and diagnostics, etc. The OLR has continued being observed or estimated from Fengyun meteorological satellites, including solar orbit satellites (such as FY3D/MERSI) and geostationary satellites (such as FY4A/AGRI).

The advantage of solar orbiting satellites is global coverage. Thus it is difficult to reflect the diurnal variation of OLR for twice observations a day. While geostationary satellites are observed 24 times a day, which can accurately describe the diurnal variation of OLR. But its coverage is limited. Therefore, the development of OLR fusion products combined with solar orbit satellite and geostationary satellite, can improve product accuracy without losing coverage advantage. In this study, we use OLR from FY4A and FY3D to build a fusion OLR product to correct the diurnal variation of OLR, and get good results.

How to cite: Zhang, W.: Outgoing Longwave Radiation and Its Diurnal Variation from Combined FY3D and FY4A, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2526, https://doi.org/10.5194/egusphere-egu2020-2526, 2020.

EGU2020-2899 | Displays | AS1.37

Investigating contrails within cirrus clouds

Peter Bräuer, Hanna Weikert, and Matthias Tesche

Effects of aviation on the Earth’s radiation budget and climate related to CO2 emissions and from the formation of linear contrails and contrail cirrus have been the focus of detailed studies. Aviation effects on existing cirrus clouds are much less investigated. Contrail formation in existing cirrus clouds has the potential to increase the cloud optical thickness (COT) of optically thin cirrus, which might result in a net cooling effect.

Spaceborne remote sensing generally provides the means for studying the impact of aviation on climate. However, only active instruments such as lidar or radar can be used to study the effect of contrails that form within existing cirrus clouds. For such an investigation, the location of an aircraft at a given time needs to be matched with information on cloud coverage, cloud type, cloud layer height, and COT as can be retrieved from spaceborne CALIPSO lidar data.

We have developed an algorithm to find intersections of aircraft flight tracks with satellite tracks. Besides the spatial coordinates, the time difference between the passing of the aircraft and the satellite at the intersection is monitored and relevant aircraft data and satellite recordings are retrieved at the intersection. The algorithm is highly adjustable so that it can be adapted for other applications such as investigation of ship tracks or cloud tracking. The new algorithm has been used to identify aircraft flying through cirrus clouds in remote regions of the Earth to study the effects of individual aircraft on existing cirrus.

How to cite: Bräuer, P., Weikert, H., and Tesche, M.: Investigating contrails within cirrus clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2899, https://doi.org/10.5194/egusphere-egu2020-2899, 2020.

Two tests of aircraft icing observations were conducted on March 2018 in Xin Jiang in northwest of China. The icing conditions are studied using observations of satellite, radar, soundings and simulations using the WRF mesoscale model coupled with CAMS cloud scheme. The large-scale weather systems of the two icing cases are the vortex and the shallow trough on 500hPa separately, accompanied by the cold front on the surface. The icing time is in the early stage of vortex system and the middle stage of shallow trough system. The icing clouds are both low and middle clouds. The cloud top height is 4km and the cloud top temperature is -15~-25℃. The cloud bottom height is 1.5km and the cloud thickness is 1-3km. The optical thickness is larger than 12 and the radar reflectivity is less than 10dBZ. There is an inversion layer of the shallow trough. The microphysical structures of CPEFS model simulations show that the icing cloud is composed of large number of supercooled water and few ice particles. The CIP initial icing potential results can basically reflect the icing height and time of the two cases.

How to cite: Sun, J.: Two Cases Studies of Cloud Structures of Aircraft Icing Tests in the Northwest of China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3193, https://doi.org/10.5194/egusphere-egu2020-3193, 2020.

EGU2020-4889 | Displays | AS1.37

Operational evaluation of volcanic source terms (volcanic ash and SO2) from inverse modelling for aviation

Mariëlle Mulder, Delia Arnold, Christian Maurer, and Marcus Hirtl

An operational framework is developed to provide timely and frequent source term updates for volcanic emissions (ash and SO2). The procedure includes running the Lagrangian particle dispersion model FLEXPART with an initial (a priori) source term, and combining the output with observations (from satellite, ground-based, etc. sources) to obtain an a posteriori source term. This work was part of the EUNADICS-AV (eunadics-av.eu), which is a continuation of the work developed in the VAST project (vast.nilu.no). The aim is to ensuring that at certain time intervals when new observational and meteorological data is available during an event, an updated source term is provided to analysis and forecasting groups. The system is tested with the Grimsvötn eruption of 2011. Based on a source term sensitivity test, one can find the optimum between a sufficiently detailed source term and computational resources. Because satellite and radar data from different sources is available at different times, the source term is generated with the data that is available the earliest after the eruption started and data that is available later is used for evaluation.

How to cite: Mulder, M., Arnold, D., Maurer, C., and Hirtl, M.: Operational evaluation of volcanic source terms (volcanic ash and SO2) from inverse modelling for aviation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4889, https://doi.org/10.5194/egusphere-egu2020-4889, 2020.

EGU2020-19130 | Displays | AS1.37

The impact of ensemble meteorology on volcano emission estimates and ash dispersion forecasts

Natalie Harvey, Helen Dacre, and Helen Webster

In the event of a volcanic eruption airlines need to make fast decisions about which routes are safe to operate and to ensure airborne aircraft land safely.  Currently these high-impact decisions are based on qualitative forecasts produced without any indication of uncertainty. Two of the largest sources of uncertainty in forecasting ash cloud location and concentration are the emissions of ash from the volcano and the meteorological situation. This study extends the UK Met Office Inversion Technique for Emission Modelling (InTEM) system to use an ensemble of meteorological conditions to investigate the dependence of emission estimates on wind field and wet deposition uncertainty. In the case of the 2011 Grimsvotn eruption, preliminary work shows that the impact of the variability of the ensemble wind fields is greater than that of the variability in the wet deposition. The next steps in this research are to quantify the improvement in the forecasts of ash location due to this ensemble approach and to develop an operational methodology that can be applied in a real-time emergency response situation.

How to cite: Harvey, N., Dacre, H., and Webster, H.: The impact of ensemble meteorology on volcano emission estimates and ash dispersion forecasts, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19130, https://doi.org/10.5194/egusphere-egu2020-19130, 2020.

EGU2020-5154 | Displays | AS1.37

A New Process for Producing First Guess TAFs

Andre Lanyon, Jessica Standen, and Piers Buchanan

Terminal Aerodrome Forecasts (TAFs) are a widely accepted international form of aviation forecast used for flight planning procedures at all major airports. TAF production in the UK is currently a time-consuming, manual process carried out by Operational Meteorologists. It has long been speculated that providing a numerical weather prediction (NWP) model-derived first guess solution could bring large improvements in the efficiency of TAF production. Research into first guess TAFs has a long history but making progress has been challenging. However, significant progress has been made at the Met Office in recent months. A practical approach has been adopted that draws on experience of manually producing TAFs. Although NWP model data is utilised as much as possible, steps have been taken to ensure the first guess TAFs are kept as simple and readable as possible whilst retaining information important to the customer. By taking this approach, it is hoped that the first guess TAFs will require minimal intervention from Operational Meteorologists in the majority of weather situations. Development of first guess TAFs is still in the preliminary stages and not all weather parameters are currently included. However, they are produced in such a way that they can be verified using standard Met Office methods, allowing objective comparison with operationally issued TAFs. Verification scores analysed over a 3 year period are encouraging and suggest that forecast performance of first guess TAFs is generally similar to that of operationally issued TAFs. Occasionally, some large differences become apparent when comparing forecasts of rare events such as mist, fog and very low cloud bases, and this is likely to be an area of future research. With further development, it is speculated that the use of first guess TAFs could significantly reduce TAF production time, allowing Operational Meteorologists to make better use of their expertise, perhaps by adding value to model output or by providing valuable consultation services to aviation customers.

How to cite: Lanyon, A., Standen, J., and Buchanan, P.: A New Process for Producing First Guess TAFs, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5154, https://doi.org/10.5194/egusphere-egu2020-5154, 2020.

In the framework of a single european sky and to improve Air Traffic Flow and Capacity
Management, involved actors need to share a common situational awareness of the airspace
conditions. These include the meteorological conditions with a focus on weather phenomena with a
strong impact on air traffic and network operations such as convection.
Within this framework, Météo-France is working to provide a new product of convection forecasts
based on ensemble prediction system (EPS) and global model, and is developing a similarity-based
method (Rottner et al., 2019) at Centre National de la Recherche Météorologique (CNRM).
The method aims to detect areas where meteorological conditions are homogeneous which are
called called objects. The latter are defined by a reference histogram representing the
meteorological phenomena to be detected and so are physically consistent. The similarity-based
method can be applied to each member of a EPS. The results can be summarized by a map that
contains the information predicted by all members of the ensemble. Thus, it provides spatialization
for local weather events. This method is currently tested to detect rainfall objects, however we can
apply this method to detect other event type, like convection. To discriminate the convection
characteristic within these rainfall objects, we use a diagnostic of cloud top pressure extracted from
global model outputs. Furthermore, to improve the convection forecast accuracy, the similarity-
based method can also be applied to several models to create a composite of convection forecast.
Météo-France will soon deliver a convection potential product to aeronautical users.

How to cite: Warnan, A.: Object-based aviaton convection forecasts from global ensemble model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6937, https://doi.org/10.5194/egusphere-egu2020-6937, 2020.

EGU2020-10962 | Displays | AS1.37

Evolving the Helicopter Emergency Medical Services (HEMS) Tool

Austin Cross, Stephanie Avey, and Dan Veitor

The Helicopter Emergency Medical Services (HEMS) tool is designed to be an intuitive web-based platform that presents weather conditions for short-distance and low-altitude flights to non-weather experts quickly and effectively.  Having timely and accurate weather information is crucial for the flight planning needs of the HEMS community.  

The Aviation Weather Center (AWC) has been working closely with FAA partners from the Aviation Weather Research Program (AWRP) and the Aviation Weather Demonstration and Evaluation (AWDE) Services group to enhance the ceiling and visibility capabilities within the tool, as well as the usability of the tool to meet user needs. An updated gridded ceiling and visibility analysis, as well as forecast ceiling and visibility, are two recent improvements based on user evaluation results that are set for operational implementation in early spring 2020. Evaluations have shown that users span well beyond helicopter pilots, and therefore the tool must evolve to accomodate all low level flight users, including unmanned aerial systems (UAS)/urban air mobility (UAM) users.

To meet this evolution, AWC will be incorporating the HEMS tool capabilities into the same framework as the one-stop-shop tool for general aviation users, the Graphical Forecasts for Aviation (GFA). The Low Altitude GFA (GFA-LA) will continue to meet the needs of the HEMS community, and will provide better consistency with other products across aviationweather.gov providing a common user experience for all aviation users. Research into automated quality control of surface observations is expected to allow addition of non-regulated station information to be added, and work on on-the-fly visualizations is expected to allow three dimensional data interrogation. Recent updates to the HEMS tool, as well as future plans to evolve HEMS into GFA-LA will be presented.

How to cite: Cross, A., Avey, S., and Veitor, D.: Evolving the Helicopter Emergency Medical Services (HEMS) Tool, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10962, https://doi.org/10.5194/egusphere-egu2020-10962, 2020.

EGU2020-18368 | Displays | AS1.37

EARLINET/ACTRIS Early Warning System for atmospheric aerosol aviation hazards

Nikolaos Papagiannopoulos, Vassilis Amiridis, Aldo Amodeo, Sara Barsotti, Giuseppe D'Amico, Anna Gialitaki, Anna Kampouri, Giuseppe Leto, Michelle Maree Parks, Simona Scollo, Stavros Solomos, and Lucia Mona

Volcanic eruptions have the capacity to significantly impact human life, consequently, tools for mitigating them are of high importance. The early detection of a potentially hazardous volcanic eruption and the issuance of early warnings concerning volcanic hazards (e.g. ash dispersal), are key elements in the initiation of operational response procedures. Historically, lidars have not typically played a key operational role during volcanic eruptions, with other remote sensing instruments such as radars, infrared and ultraviolet cameras being preferred. Recently, a tailored product of the European Aerosol Research Lidar Network (EARLINET) for the early warning of the presence of volcanic ash and desert dust plumes at cruising altitudes has been developed. Here, we extend the applicability of this methodology to lidars and ceilometers near active volcanoes in Iceland and Mt. Etna in Italy. The tailored methodology and selected case studies will be presented, demonstrating its potential for real-time application during volcanic eruptions.

Acknowledgements: This work has been conducted within the framework of the E-shape (Grant Agreement n. 820852) and EUNADICS-AV (Grant agreement no. 723986) H2020 projects. Furthermore, the authors acknowledge the ACTRIS-2 and ACTRIS Preparatory Phase projects that have received funding from the European Union’s Horizon 2020 research and innovation programme (grant agreement No. 654109) and from European Union’s Horizon 2020 Coordination and Support Action (grant agreement No. 739530), respectively.

How to cite: Papagiannopoulos, N., Amiridis, V., Amodeo, A., Barsotti, S., D'Amico, G., Gialitaki, A., Kampouri, A., Leto, G., Parks, M. M., Scollo, S., Solomos, S., and Mona, L.: EARLINET/ACTRIS Early Warning System for atmospheric aerosol aviation hazards, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18368, https://doi.org/10.5194/egusphere-egu2020-18368, 2020.

EGU2020-21913 | Displays | AS1.37

Scientific Enhancements to the World Area Forecast System (WAFS).

Piers Buchanan, Jacob Cheung, Katie Bennett, Graeme Anderson, Claire Bartholomew, Debi Turp, Mark Canning, Teil Howard, Andre Lanyon, Edward Steele, Brian Pettegrew, and Matt Strahan

Global aviation industry needs are evolving, with increased volumes of traffic, increased capacity demands and the need to limit the environmental impacts of travel. Therefore, the provision of accurate/detailed meteorological information is becoming even more essential for the safe and efficient management of airline and airport operations.  Underpinning much of this is the World Area Forecast System (WAFS), provided by the London and Washington centres, whose capabilities are currently undergoing significant upgrades that promises improved prediction of en-route hazards. These upgrades, focused on atmospheric turbulence, cumulonimbus cloud, and in-flight icing will see the transition of services to a fully probabilistic offering, as well as the provision of a new high-resolution (0.25 degree) deterministic severity-based forecasts of turbulence and icing (replacing the previously used ‘potential’ metric). With the delivery of the deterministic products due by 2020, and the probabilistic products due by 2024, we will report on these key developments – providing both an overview of the new operational diagnostics and their validation, presenting preliminary results from initial trials involving the ensemble data – enabling users to avoid en-route hazards more safely and efficiently in the future.

How to cite: Buchanan, P., Cheung, J., Bennett, K., Anderson, G., Bartholomew, C., Turp, D., Canning, M., Howard, T., Lanyon, A., Steele, E., Pettegrew, B., and Strahan, M.: Scientific Enhancements to the World Area Forecast System (WAFS)., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21913, https://doi.org/10.5194/egusphere-egu2020-21913, 2020.

EGU2020-22575 | Displays | AS1.37

A new look at assimilation and boundary-layer modeling effects to improve NOAA ceiling/visibility/convection HRRR forecasts

Stan Benjamin, Eric James, Joseph Olson, Curtis Alexander, and Terra Ladwig

An accurate short-range cloud and precipitation forecast is a fundamental component of rapidly updating data assimilation/short-range model forecast systems such as the NOAA 3-km High-Resolution Rapid Refresh or the 13-km Rapid Refresh (RAP). To reduce cloud and precipitation spin-up problems, a cloud/hydrometeor non-variational assimilation technique for stratiform clouds was developed within the Gridpoint Statistical Interpolation (GSI) data assimilation system. The goal of this technique was retention into the subsequent model forecast, as appropriate, of observed stratiform cloud and observed clear 3-d volumes.

New observation impact studies show that the ceiling forecasts are particularly improved by use of this cloud/hydrometeor assimilation in the HRRR/RAP model in both summer and winter season.   Daytime 2m temperature and dewpoint forecasts are also improved in the summer period, important for convective storms.

Improved design of the MYNN boundary-layer turbulence scheme is also shown to benefit HRRR/RAP ceiling prediction and is now also being tested in the FV3 3km stand-along regional model and in the NOAA FV3 Global Forecast System.   Improved boundary-layer prediction, also through other parameterization additions for gravity-wave drag and land/lake modeling, is demonstrated and isolated to these modifications.

How to cite: Benjamin, S., James, E., Olson, J., Alexander, C., and Ladwig, T.: A new look at assimilation and boundary-layer modeling effects to improve NOAA ceiling/visibility/convection HRRR forecasts, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22575, https://doi.org/10.5194/egusphere-egu2020-22575, 2020.

AS2.1 – Atmospheric Boundary Layer: From Basic Turbulence Studies to Integrated Applications

EGU2020-1547 | Displays | AS2.1 | Highlight

Observing the surface radiation and energy balance, carbon dioxide and methane fluxes over the city centre of Amsterdam

Gert-Jan Steeneveld, Sophie van der Horst, and Bert Heusinkveld

Cities largely affect boundary-layer climates due to complex surface structures, pollutant emissions, and anthropogenic heat release. As urban populations are expanding worldwide, insight is required into the urban surface radiation and energy balance and urban greenhouse gas fluxes. However, little long-term flux measurement records are available for dense city centres. We present one year (June 2018 - May 2019) of flux observations taken at a 40-meters tower in the city centre of Amsterdam. We analyse the diurnal and seasonal variation of the turbulent and greenhouse gas fluxes, and we estimate the flux footprint to gain insight in flux variation with wind direction. Also, anthropogenic heat flux and storage fluxes are estimated from emission inventories and the objective hysteresis model respectively. This analysis shows that, especially during the winter, the sum of the sensible and latent heat flux exceeds the net radiation. Thus, the storage flux and anthropogenic heat flux are significant energy providers. Also, we find a surprisingly good surface energy balance closure, especially during summer. To achieve annual energy closure, the sensible heat and latent heat flux require an increase of 13%. Moreover, we find that the measured carbon dioxide flux (45 kg CO2 m-2 y-1) is close to bottom-up source quantification (47 kg CO2 m-2 y-1). For some wind directions, the agreement is better than for others. In addition, we show that the annual methane emission is slightly higher than the emission found in Florence and London. Yet the methane source partitioning in Amsterdam remains open for more research.

How to cite: Steeneveld, G.-J., van der Horst, S., and Heusinkveld, B.: Observing the surface radiation and energy balance, carbon dioxide and methane fluxes over the city centre of Amsterdam, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1547, https://doi.org/10.5194/egusphere-egu2020-1547, 2020.

More than half of the world population lives in cities. It is imperative to improve our predictive understanding of the urban boundary layer. In particular, considerable knowledge gaps still exist in turbulent transport of scalars (temperature, moisture and air pollutants) over urban rough surfaces, especially in the urban roughness sublayers. Using obstacle-resolving large eddy simulations, we first compare and contrast momentum and passive scalar transport over large, three-dimensional roughness elements. Dispersive scalar fluxes are shown to be a significant fraction of the total fluxes within the roughness sublayers. Strong dissimilarity is also noted between the dispersive momentum and scalar fluxes. The results highlight the need for distinct parameterizations of the turbulent and dispersive fluxes, as well as the importance of considering the contrasts between momentum and scalar transport for flows over very rough surfaces. In addition, the links between momentum and scalar roughness lengths (z0m and z0s) are explored by developing a conceptual framework that considers z0m and z0s at two distinct scales, namely micro and macro scales. Using a surface renewal theory for macro-scale roughness lengths, a log(z0m/zos) scaling with Re*1/2 is predicted and is supported by LES results. Overall, these results underline the potential of using wall-modeled, large-obstacle resolving LES to improve our process-based understanding, as well as to identify and represent the missing first-order physical processes in the ABL.   

How to cite: Li, Q.: The impacts of large bluff roughness elements on turbulent transport of momentum and scalar in the urban boundary layer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1722, https://doi.org/10.5194/egusphere-egu2020-1722, 2020.

EGU2020-7156 | Displays | AS2.1

Statistical study of coherent turbulent structures properties observed by a Doppler lidar over Paris during two months

Ioannis Cheliotis, Elsa Dieudonné, Hervé Delbarre, Anton Sokolov, Egor Dmitriev, Patrick Augustin, Marc Fourmentin, François Ravetta, and Jacques Pelon

Pulsed Doppler wind lidars (PDWL) have been extensively used in order to study the atmospheric turbulence. Their ability to scan large areas in a short period of time is a substantial advantage over in-situ measurements. Furthermore, PDWL are capable to scan horizontally as well as vertically thus providing observations throughout the atmospheric boundary layer (ABL). By analysing PDWL observations it is possible to identify large turbulent structures in the ABL such as thermals, rolls and streaks. Even though several studies have been carried out to analyse such turbulent structures, these studies examine peculiar cases spanning over short periods of time.

For this study we analysed the turbulent structures (thermals, rolls, streaks) over Paris during a two-months period (4 September – 6 October 2014, VEGILOT campaign) observed with a PDWL installed on a 70 m tower in Paris city centre. The turbulent radial wind field was reconstructed from the radial wind field of the horizontal surface scans (1° elevation angle) by using the velocity azimuth display method. The VEGILOT campaign provided 4577 horizontal surface scans, hence for the classification of the turbulent structures we developed an automatic method based on texture analysis and machine learning of the turbulent radial wind fields. Thirty characteristic cases of each turbulent structure types were selected at the learning step after an extensive examination of the meteorological parameters. Rolls cases were selected at the same time that cloud streets were visible on satellite images, streaks cases were selected during high wind shear development near the surface and thermals case were selected when solar radiation measurements in the area were high. In addition, sixty cases of “others”, representing any other type of turbulence, were added to the training ensemble. The analysis of errors estimated by the cross-validation shows that the K-nearest neighbours’ algorithm was able to classify accurately 96.3% of these 150 cases. Subsequently the algorithm was applied to the whole dataset of 4577 scans. The results show 52% of the scans classified as containing turbulent structures with 33% being coherent turbulent structures (22% streaks, 11% rolls).

Based on this classification, the physical parameters associated with the different types of turbulent structures were determined, e.g. structure size, ABL height, synoptic wind speed, vertical wind speed. Range height indicator and line of sight scans provided vertical observations that illustrate the presence of vertical motions during the observation of turbulent structures. The structure sizes were retrieved from the spectral analysis in the transverse direction relative to the synoptic wind, and are in agreement with the commonly observed sizes (a few 100 m for streaks, a few km for rolls).

How to cite: Cheliotis, I., Dieudonné, E., Delbarre, H., Sokolov, A., Dmitriev, E., Augustin, P., Fourmentin, M., Ravetta, F., and Pelon, J.: Statistical study of coherent turbulent structures properties observed by a Doppler lidar over Paris during two months, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7156, https://doi.org/10.5194/egusphere-egu2020-7156, 2020.

EGU2020-21310 | Displays | AS2.1

The impact of Temperature inversions on Black Carbon and Particle Mass Concentrations from Wood-burning in a Mountainous Area

Kristina Glojek, Griša Močnik, Honey Dawn C. Alas, Andrea Cuesta-Mosquera, Luka Drinovec, Asta Gregorič, Matej Ogrin, Kay Weinhold, Irena Ježek, Thomas Müller, Martin Rigler, Maja Remškar, Dominik van Pinxteren, Hartmut Herrmann, Martina Ristorini, Maik Merkel, Miha Markelj, and Alfred Wiedensohler

Lately, researchers, policy makers and governments have focused their attention mainly on air quality in urban areas. The issue of quality of air in rural areas remains neglected, although studies (Largeron & Staquet, 2016 and the reference therein) show that especially in hilly/mountainous regions on the countryside, air pollution can be a serious problem.

Our aim is to quantify the influence of ground temperature inversions on spatiotemporal variability of equivalent black carbon (eBC) and Particulate Matter (PM) mass concentrations in mountainous regions, example of which is the model region Loški Potok, Slovenia.

Simultaneous mobile measurements with two instrumented backpacks (AE51, MA200, OPSS 3330, temperature sensor) (Alas et al., 2018) were performed along the woody karst hollow with the village Retje at the bottom. Mobile measurements were performed in winter 2017/18, three times a day (in the morning, at noon, and in the evening) with a 10- and 20-minute intercomparison with the reference instruments (AE-33, TROPOS and TSI MPSS) at the station on top of the hill and in the village. The regression slope between two AE51 microaethalometers was 1. Fixed instruments showed good agreement with the mobile instruments during inter-comparison periods (Alas et al., 2020).

The mean value of eBC and PM2.5 mass concentrations for the whole relief depression during temperature inversion episodes was 4 µg/m3 of eBC and 39.7 µg/m3 of PM2.5. During periods with mixed atmosphere mean eBC and PM2.5 mass concentrations were 0.9 and 11.4 µg/m3. The eBC and PM2.5 mass concentrations between 17:00 and 19:00 CET in the village reached 16–20 µg/m3 of eBC and 170–250 µg/m3 of PM2.5, yet on the top of the hill Tabor concentrations were 2–3.5 µg/m3 of eBC and 10–15 µg/m3 of PM2.5.

As a result of human activities (residential wood burning) and the shallow thickness of an inversion layer temporal and spatial variability of pollutant concentrations in the study area is significant. During stable atmospheric conditions (temperature inversion) concentration levels strongly increase yet rapidly decrease with the temperature inversion break up.

Key words: carbonaceous aerosols, atmospheric stability, residential wood combustion (RWC), mobile measurements, rural areas

 

The research was supported by the Slovenian Research Agency, the COST Action CA16109 and the Municipality of Loški Potok.

 

Alas, H. et al. (2018). Aerosol and Air Quality Research, 18, 2301–2317.

Alas, H. et al. (2020). Manuscript in preparation.

Largeron, Y., & Staquet, C. (2016). Atmospheric Environment, 135, 92–108.

How to cite: Glojek, K., Močnik, G., C. Alas, H. D., Cuesta-Mosquera, A., Drinovec, L., Gregorič, A., Ogrin, M., Weinhold, K., Ježek, I., Müller, T., Rigler, M., Remškar, M., van Pinxteren, D., Herrmann, H., Ristorini, M., Merkel, M., Markelj, M., and Wiedensohler, A.: The impact of Temperature inversions on Black Carbon and Particle Mass Concentrations from Wood-burning in a Mountainous Area, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21310, https://doi.org/10.5194/egusphere-egu2020-21310, 2020.

EGU2020-18022 | Displays | AS2.1

The estimate and scaling of mass and energy fluxes from three different ecosystems in the Trentino Alto Adige/South Tyrol (Italy) region: Preliminary results from the Wheat Project.

Marco Falocchi, Lorenzo Giovannini, Luca Belelli Marchesini, Damiano Gianelle, Leonardo Montagnani, and Dino Zardi

The estimate and parameterization of mass and energy fluxes exchanged in the atmospheric surface-layer, between the biosphere and the atmosphere, plays a key role in many disciplines, e.g. meteorology and atmospheric sciences, ecology and precision agriculture.

In mountain environments, crests lines tend to decouple the atmospheric processes close to the ground from those in the upper layers and deeply affect the penetration of solar radiation on the floors and the sidewalls of valleys. The consequent differential heating of the surface allows the onset of many local phenomena, such as thermally-driven flows and temperature inversions, with impacts on the regime of the exchanges. Indeed, the low-wind conditions, the wind interaction with landforms and the atmospheric stability control the turbulence and the development of sub-meso motions, i.e. those phenomena responsible for the diffusion and transport of substances, respectively.

The Wheat Project is a 2-year-long project, started on November 2018 and funded by the CARITRO Foundation (“Cassa di Risparmio di Trento e Rovereto”, Italy), which aims at investigating the basic mechanisms responsible for biosphere-atmosphere exchanges in mountain areas, in order to improve their estimate and scaling.

Three datasets collected by long-term research infrastructures and composed of both biochemical and atmospheric quantities measured over different ecosystems were selected in the Trentino Alto Adige/South Tirol region (Italy). Data were measured at the research facility managed by the Free University of Bolzano/Bozen at Caldaro, over an apple orchard (220 m ASL, available period 2010-2018), and at the research facilities managed by the Fondazione Edmund Mach at Monte Lavarone, over a forest (1349 m ASL, available period 2000-2018) and at Viote del Monte Bondone, over an Alpine grassland (1553 m ASL, available period 2002-2018).

This contribution focuses on the pre-processing procedure adopted to identify representative periods for the analyses and on the methods implemented to retrieve turbulence parameters. In particular, the identification of the characteristic time-scales of small-scale turbulence is carried out through an application of the anisotropic analysis of turbulence, whereas the separation of the turbulence signal from low-frequency fluctuations is performed by implementing a recursive digital filter. Finally, some preliminary results regarding the estimate and the scaling of the turbulent fluxes of momentum, sensible heat, moisture and carbon dioxide are presented.

How to cite: Falocchi, M., Giovannini, L., Belelli Marchesini, L., Gianelle, D., Montagnani, L., and Zardi, D.: The estimate and scaling of mass and energy fluxes from three different ecosystems in the Trentino Alto Adige/South Tyrol (Italy) region: Preliminary results from the Wheat Project., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18022, https://doi.org/10.5194/egusphere-egu2020-18022, 2020.

EGU2020-21259 | Displays | AS2.1 | Highlight

The Complex Terrain Measurement and Modeling Project of Land–Atmosphere Energy Exchanges (COMPLEX) Experiment

Laura Herrera, Carlos Hoyos, and Julián Urán

The heterogeneity of the urban features, in addition to the inherent challenges added by highly complex terrain, has not allowed the scientific community to reach a complete understanding of the Atmospheric Boundary Layer (ABL) dynamics regarding the land-atmosphere interactions. The intricacies are higher when trying to simulate the observed interactions and their implications for air quality in a numerical modeling framework.

 

Over the last two decades, the ABL research community has dedicated several research efforts to study turbulent exchanges and ABL processes over complex terrain, and the implications of the particular features of these sites have on turbulence characteristics. A better knowledge of the ABL structure and dynamics is fundamental to understand processes such as air pollutant dispersion and disposal in the atmosphere, development and evolution of deep convection, and urban effects on meteorology. One of the aspects hindering our understanding is the lack of pertinent information from urbanized mountainous regions representative of the entire globe, useful to assess the different hypotheses and conceptual models of the Mountain Boundary Layer (MBL) dynamics. Most of the short- and long-term ABL field experiments in mountainous terrains have taken place over the high-latitude regions such as the Alps and the Rockies, and few over in the tropical Andes, where the Cordillera plays an essential role in controlling orographic rainfall intensification and the ventilation in inter-Andean valleys, resulting in knowledge gap regarding momentum, and latent and sensible heat flux exchanges over low-latitude, urban, complex terrain regions. In addition to a top-down approach, it is essential to follow a bottom-up strategy to study in detail the turbulent heat, mass, and momentum transfer in the Andean region.

The COMPLEX Experiment (COmplex terrain Measurement and modeling Project of Land-atmosphere Energy eXchanges) is a new effort focused on the long-term energy balance measurement campaign settled in the Aburrá Valley, a narrow highly complex mountainous-urban terrain located in the Colombian Andes. The primary purpose of this campaign is to identify the more relevant phenomenological features and processes responsible for ABL spatio-temporal variability, and land-atmosphere interactions in inter-Andean valleys. The long-term observational set-up includes eight sites equipped with turbulent flux sensors and net radiometers, in a cross-section of the valley, a microwave radiometer, a boundary layer radar, a scintillometer, and radiosonde intense observation periods (IOPs). We present the status of the COMPLEX experiment equipment deployment and preliminary results on the relationship of the transition between the stable boundary layer and the convective boundary layer and air quality in the region, and an exploration of the diurnal cycle of the different turbulent terms of the energy budget as a function of time and hill location.

How to cite: Herrera, L., Hoyos, C., and Urán, J.: The Complex Terrain Measurement and Modeling Project of Land–Atmosphere Energy Exchanges (COMPLEX) Experiment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21259, https://doi.org/10.5194/egusphere-egu2020-21259, 2020.

Sloping terrain of any inclination favour the development, under daytime heating, of thermally-driven organised flows, displaying peculiar boundary layer structures, and eventually triggering the development of atmospheric convection.

The ubiquitous occurrence of variously tilted surfaces - from gently sloping plains top steep cliffs, or valley sidewalls – makes the understanding of such flows of utmost importance in view of the appropriate forecasting of the associated boundary layer transport processes. These may display quite a different structure from those, much better known, occurring over horizontal plain surfaces [1]. Also, they display a highly conceptual relevance, as the simplest, prototypal situations for many other thermally driven-flows over complex terrain [2]. Finally, with the increasing resolution of operational model runs, a more accurate parameterisation of these processes is required for a realistic simulation of their development in space and time.   

However, up-slope flows have received so far much less attention than downslope flows originating from cooling, which have been extensively investigated by means of theoretically analysis, field experiments and numerical simulations. Even the theoretical analysis on their onset and structure are rather limited (e.g. to gentle slopes: [3]). Analytical solutions, such as Prandtl’s [4], rely on severely restrictive assumptions (parallel flow, constant or slowly varying eddy viscosity and diffusivity, along-slope invariance of the ambient factors). Extensions of such solutions relaxing those restrictions are still limited [5]. Even extensive high-resolution numerical simulations are rare, and not much progress has been made after Schumann’s [6]. Further insight, especially on the conditions for flow separation, have been gained through laboratory-scale simulations [7], which however are limited to moderate flow situations.

The proposed presentation offers a comprehensive overview of our present understanding of these phenomena, ideas for scaling laws appropriate for these winds, and challenging open questions for future research.

References

  1. Rotach, M. W., and D. Zardi, 2007: On the boundary layer structure over complex terrain: Key findings from MAP. Quart. J. Roy. Meteor. Soc., 133, 937-948.
  2. Zardi, D. and C. D. Whiteman, 2013: Diurnal Mountain Wind Systems, Chapter 2 in “Mountain weather research and forecasting – Recent progress and current challenges” (Chow, F. K., S. F. J. De Wekker, and B. Snyder Editors), Springer Atmospheric Sciences, Springer, Berlin.
  3. Hunt, J. C. R., H. J. S. Fernando, and M. Princevac, 2003: Unsteady thermally driven flows on gentle slopes. J. Atmos. Sci., 60, 2169-2182.
  4. Prandtl L. 1942. Führer durch die strömungslehre, ch. V. Vieweg und Sohn [English translation: Prandtl, L., 1952: Mountain and Valley Winds in Stratified Air, in Essentials of Fluid Dynamics, Hafner Publishing Company, pp.422-425].
  5. Zammett, R. J., and A. C. Fowler, 2007: Katabatic winds on ice sheets: A refinement of the Prandtl model. J. Atmos. Sci., 64, 2707–2716.
  6. Schumann U. 1990. Large-eddy simulation of the up-slope boundary layer. Quart. J. Roy. Meteor. Soc. 116, 637–670.
  7. Hilel Goldshmid, R.; Bardoel, S.L.; Hocut, C.M.; Zhong, Q.; Liberzon, D.; Fernando, H.J.S. Separation of Upslope Flow over a Plateau. Atmosphere 2018, 9, 165.

How to cite: Zardi, D.: Surface-layer scaling for thermally-driven up-slope flows, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22284, https://doi.org/10.5194/egusphere-egu2020-22284, 2020.

EGU2020-15187 | Displays | AS2.1

Stable boundary layer height on a gentle slope

Ivana Stiperski, Albert A.M. Holtslag, Manuela Lehner, and C. David Whiteman

Height of the stable boundary layer (SBL) presents an important diagnostic used to describe the relevant processes governing the evolution and characteristics of SBL, and the extent to which the surface is communicating with the free atmosphere.  Here we investigate the SBL height over a gentle (1°) mesoscale slope on which relatively deep mid-latitude katabatic flows (with jet maxima between 20 and 50 m) develop during clear nights. We show that detecting the SBL top depends on the method used (Richardson number, flux- and anisotropy-profiles). The detected SBL depth, mostly deviates from the jet maximum height or the top of the near-surface inversion. The flat terrain formulations for the SBL height correlate well with the detected top of the SBL if instead of background stratification, near-surface stratification is used in their formulations, however, they mostly largely overestimate the SBL height. The difference to flat-terrain SBL is also shown through the dependence of size of the dominant eddy with height. In katabatic flows the eddy size is semi-constant with height throughout the SBL, whereas in flat terrain eddy size varies significantly with height.

How to cite: Stiperski, I., Holtslag, A. A. M., Lehner, M., and Whiteman, C. D.: Stable boundary layer height on a gentle slope, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15187, https://doi.org/10.5194/egusphere-egu2020-15187, 2020.

EGU2020-5227 | Displays | AS2.1

A Businger Mechanism for Intermittent Bursting in the Stable Boundary Layer

Steven van der Linden, Bas van de Wiel, Igor Petenko, Chiel van Heerwaarden, Peter Baas, and Harmen Jonker

High-resolution large-eddy simulations of the Antarctic very stable boundary layer reveal a mechanism for systematic and periodic intermittent bursting. A non-bursting state with a boundary-layer height of just 3 m is alternated by a bursting state with a height of ≈5 m. The bursts result from unstable wave growth triggered by a shear-generated Kelvin-Helmholtz instability, as confirmed by linear stability analysis. The shear at the top of the boundary layer is built up by two processes. The upper, quasi-laminar layer accelerates due to the combined effect of the pressure force and rotation by the Coriolis force, while the lower layer decelerates by turbulent friction. During the burst, this shear is eroded and the initial cause of the instability is removed. Subsequently, the interfacial shear builds up again, causing the entire sequence to repeat itself with a timescale of 10 min. Despite the clear intermittent bursting, the overall change of the mean wind profile is remarkably small during the cycle. This enables such a fast erosion and recovery of the shear. This mechanism for cyclic bursting is remarkably similar to the mechanism hypothesized by Businger in 1973. In his proposed mechanism, the momentum in the upper layer is increased by the downward turbulent transport of high-momentum flow. From the results, it appears that such transfer is not possible as the turbulent activity above the base flow is negligible. Finally, it would be interesting to construct a climatology of shear-generated intermittency in relation to large-scale conditions to assess the generality of this Businger mechanism.

How to cite: van der Linden, S., van de Wiel, B., Petenko, I., van Heerwaarden, C., Baas, P., and Jonker, H.: A Businger Mechanism for Intermittent Bursting in the Stable Boundary Layer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5227, https://doi.org/10.5194/egusphere-egu2020-5227, 2020.

Dust devils are convective vortices with a vertical axis of rotation mainly characterized by a local minimum in pressure and a local maximum in vertical vorticity within the vortex core. They are made visible by entrained dust particles. That's why they occur primarily in dry and hot areas. Currently, there is great uncertainty about the extent to which dust devils contribute to the atmospheric aerosol and heat transport and thereby influence earth's radiation budget as well as boundary layer properties. Past efforts to quantify the aerosol or heat transport and to study dust devils' formation, maintenance, and statistics using large-eddy simulation (LES) as well as direct numerical simulation (DNS) have been of limited success. Therefore, this study aims to provide better statistical information about dust devil-like structures and to extend, prove or disprove existing theories about the development and maintenance of dust devils. Especially, the vortex strength measured through the pressure drop in the vortex core is regarded, which is, in past LES simulations, almost one order of magnitude smaller compared to the observed range of several hundreds Pascals.
So far, we are able to reproduce observed core pressures with LES of the convective boundary layer by using a high spatial resolution of 2m while considering a domain of 4km x 4km x 2km, a model setup with moderate background wind and a spatially heterogeneous surface heat flux. It is found that vortices mainly appear at the vertices and branches of the cellular pattern and at lines of horizontal flow convergence above the centers of the strongly heated patches. The latter result is in contrast to some older observations in which vortices seemed to be created along the patch edges. Also further statistical properties, like lifetimes, diameters or frequency of occurrence, fit quite well in the observed range. Nevertheless, statistics of dust devils from LES face the general problem that they are highly influenced by the used grid spacing and thereby by the structures that can be explicitly resolved. For example, the near surface layer, which plays a major role for the vortex development, is poorly resolved and turbulent processes in this layer are highly parameterized. DNS would overcome this problem. Therefore, dust devil-like structures are also investigated with DNS by simulating laboratory-like Rayleigh-Bénard convection with Rayleigh numbers up to 1012. Such high Rayleigh numbers have never been used in DNS studies of dust devils. The focus is on the vortex formation dependence on the used Rayleigh number and aspect ratio. First results of the laboratory-like Rayleigh-Bénard convection simulated with DNS confirm the existence of dust devil-like structures also on small scales with much lower Rayleigh numbers than in the atmosphere.
In a next step, detailed statistics of dust devil-like structures in Rayleigh-Bénard convection will be derived focusing on Rayleigh number and aspect ratio dependencies. Afterwards, results will be compared to LES simulations of dust devils and experimental data.

How to cite: Giersch, S. and Raasch, S.: Genesis and Features of Dust Devil-Like Vortices in Convective Boundary Layers – A Numerical Study Using LES and DNS, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1579, https://doi.org/10.5194/egusphere-egu2020-1579, 2020.

EGU2020-11238 | Displays | AS2.1

Wind-turning over the atmospheric boundary layer in observations and models

Gunilla Svensson, Jenny Lindvall, and Joakim Pyykkö

As an attempt to find a way of evaluating the surface drag in global models, we have derived a climatology of the boundary-layer wind-turning angle over land (Lindvall and Svensson, 2019). It is based on radiosonde observations from 800 stations in the Integrated Global Radiosonde Archive (IGRA). The climatology and how the wind turning depend on a suite of parameters is analyzed. Results from previous studies indicating the importance of the planetary boundary layer (PBL) stratification for the angle of wind turning are confirmed. A clear increase in the wind-turning angle with wind speed, particularly for stratified conditions, is also evident. According to Rossby number similarity theory, the crossisobaric angle for a neutral and barotropic boundary layer decreases with the surface Rossby number, Ro. The IGRA observations indicate that this dependence on Ro might partly be linked to the dependence of the stratification on the wind speed, a dependence that seems to prevail even for the high wind speeds, a criterium that traditionally is used to approximate a neutral PBL. The vertical distribution of the turning of the wind is analyzed using the high resolution Stratospheric Processes And their Role in Climate (SPARC) data. For unstable cases, there is a maximum in the directional wind shear around the PBL top, whereas for the most stable class of cases there is a maximum near the surface. The midlatitude cross-isobaric mass transport is estimated using the IGRA data. The wind-turning angles from reanalysis fields and climate models are also presented, they generally underestimate the turning angle.

How to cite: Svensson, G., Lindvall, J., and Pyykkö, J.: Wind-turning over the atmospheric boundary layer in observations and models , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11238, https://doi.org/10.5194/egusphere-egu2020-11238, 2020.

EGU2020-17836 | Displays | AS2.1

The SOuth west FOGs 3D experiment for processes study (SOFOG3D) project

Frédéric Burnet, Christine Lac, Pauline Martinet, Nadia Fourrié, Martial Haeffelin, Julien Delanoë, Jeremy Price, Sébastien Barrau, Guylaine Canut, Grégoire Cayez, Alain Dabas, Cyrielle Denjean, Jean-Charles Dupont, Rachel Honnert, Jean-François Mahfouf, Thibault Montmerle, Greg Roberts, Yann Seity, and Benoit Vié

Fog strongly perturbs the aviation, marine and land transportation, leading to human losses and high financial costs. The primary objective of SOFOG3D is to advance our understanding of fog processes at the smallest scale to improve forecasts of fog events by numerical weather prediction (NWP) models.

Specifically, SOFOG3D conducts process studies on very well documented situations, using synergy between 3D high-resolution Large Eddy Simulation (LES) and unprecedented 3D detailed observations. SOFOG3D will particularly focus on the impact of surface heterogeneities (types of vegetation, rivers, orography) on the fog life cycle, on fog microphysics properties, on entrainment at fog top, on the surface energy budget, and on the impact of aerosols. SOFOG3D will also investigate how improving the initial conditions of NWP models can improve fog forecasts. To that end, data from a ground-based MWR network will be assimilated using an innovative ensemble-based variational data assimilation scheme.

A 6 months field experiment took place during wintertime 2019/2020 in the South-West of France to provide 3D mapping of the boundary layer during fog events. The observation strategy is to combine vertical profiles derived from new remote sensing instruments (microwave radiometer (MWR), Doppler cloud radar and Doppler lidars) and balloon-borne in-situ measurements, with local observations provided by a network of surface stations, and a fleet of Unmanned Aerial Vehicles (UAV) to explore fog spatial heterogeneities.

Three nested domains has been instrumented with increasing density to provide observations from regional scale (300x200 km) down to local scale on the super-site (10x10 km), thanks to Meteo France and U.K. Meteorological Office sensors. On the super site, meteorological conditions, visibility, aerosol optical, microphysical and hygroscopic properties, fog microphysics and liquid water content, water deposition, radiation budget, heat and momentum fluxes on flux-masts has been performed on different areas to investigate the impacts of surface heterogeneities on fog processes, as well as turbulence anisotropy. Combination of cloud radar and MWR measurements will allow optimal retrieval of temperature, humidity and liquid water content profiles.

We will present the instrumental set-up that has been deployed during this campaign and discuss the main objectives of the project. An overview of fog events that occurred during the 6 months experiment will be given, and preliminary analysis of data collected during IOPs with a tethered balloon and UAVs will be presented.

How to cite: Burnet, F., Lac, C., Martinet, P., Fourrié, N., Haeffelin, M., Delanoë, J., Price, J., Barrau, S., Canut, G., Cayez, G., Dabas, A., Denjean, C., Dupont, J.-C., Honnert, R., Mahfouf, J.-F., Montmerle, T., Roberts, G., Seity, Y., and Vié, B.: The SOuth west FOGs 3D experiment for processes study (SOFOG3D) project, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17836, https://doi.org/10.5194/egusphere-egu2020-17836, 2020.

EGU2020-18600 | Displays | AS2.1

Flow modeling within a Central European forest using large-eddy simulation

Max Plorin, Sandra Grunicke, Christian Bernhofer, and Ronald Queck

With the aim to simulate the exchange of energy and matter between air and vegetation, we applied the LES PALM to a typical Central European forest. The presentation shows how the level of detail within vegetation model and the orography alters the simulated flow.

The site of investigation is a managed mixed forest stand (mainly Picea abies, height 30 m; a long-term CarboEurope monitoring site) within the Tharandter Wald near Dresden, Germany. Terrestrial laser scans (TLS) provided the data basis for the high-resolution vegetation model of this forest stand and a nearby clearing (50x90 m) building the inner range of the model domain. To investigate orographic effects on the flow, we extended the domain for about 1.5 km to the west. This includes the S-Berg, which is about 40 m height and therefore the highest elevation on the windward side. We used information from airborne laser scanning (ALS) along with forest inventory data to build a vegetation model as well as a digital elevation model for the extended area (2 km in streamwise and 1.5 km in lateral direction) with a resolution of (2m)3

In a first step, we restricted all simulations to a neutral atmosphere to exclude effect of buoyancy.

Wind data from four measurement towers (from DFG SPP 1276 MetStröm) provided data for a validation of the simulations. They were located within the inner domain along a west-east transect over the clearing.

How to cite: Plorin, M., Grunicke, S., Bernhofer, C., and Queck, R.: Flow modeling within a Central European forest using large-eddy simulation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18600, https://doi.org/10.5194/egusphere-egu2020-18600, 2020.

EGU2020-7220 | Displays | AS2.1

Multifractal analysis of velocity and temperature fluctuations in the atmospheric surface layer

Ganapati Sahoo, Soumak Bhattacharjee, Timo Vesala, and Rahul Pandit

The characterization of the structure of non-stationary, noisy fluctuations in a time series, e.g., the time series of the velocity components or temperature in turbulent flows, is a problem of central importance in fluid dynamics, nonequilibrium statistical mechanics, atmospheric physics and climate science. Over the past few decades, a variety of statistical techniques, like detrended fluctuation analysis (DFA), have been used to reveal intricate, multiscaling properties of such time series. We present an analysis of velocity and temperature time series, which have been obtained by measurements over the canopy of Hyytiälä Forest in Finland.
In our study we use DFA, its generalization, namely, multifractal detrended fluctuation analysis (MFDFA), and the recently developed multiscale multifractal analysis (MMA), which is an extension of MFDFA. These methods allow us to characterize the rich hierarchy or multi- fractality of the dynamics of the time series of the velocity components and the temperature. In particular, we can clearly distinguish these time series from white noise and the signals that display simple, monofractal, scaling with a single exponent (also called the Hurst exponent). It is useful to recall that monofractal scaling is predicted for fluid turbulence at the level of the Kolmogorov’s phenomenological approach of 1941 (K41); experiments and direct numerical simulations suggest that three-dimensional (3D) fluid turbulence must be characterised by a hierarchy of exponents for it is truly multifractal.

We present an analysis of multifractality of velocity and temperature fields that have been measured, at different heights, over the canopy of Hyytiälä Forest in Finland. In particular, we carry out a detailed study of velocity and temperature time series by using MFDFA and MMA. Results from both these methods are consistent, as they must be; but, of course, the MMA results contain more information because they account for the dependence of the multifractality on the time intervals.

How to cite: Sahoo, G., Bhattacharjee, S., Vesala, T., and Pandit, R.: Multifractal analysis of velocity and temperature fluctuations in the atmospheric surface layer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7220, https://doi.org/10.5194/egusphere-egu2020-7220, 2020.

EGU2020-450 | Displays | AS2.1 | Highlight

A novel method for directly obtaining the water vapor isotope surface flux for evaluating snow-atmosphere exchange processes

Sonja Wahl, Hans Christian Steen-Larsen, Alexandra Zuhr, and Joachim Reuder

Water isotopologues offers a direct constraint on the physical processes controlling surface fluxes.  A novel method is presented which enables in-situ measurements of the water vapour isotope flux between the snow surface of the Greenland Ice Sheet and the atmosphere.

These observations have become possible by combining a cavity ring-down laser absorption spectroscopy analyzer with high frequency latent heat flux eddy-covariance measurements.

This new method reveals an isotope flux driven by the diurnal cycle.
Water isotopes can thus act as a natural tracer giving information of the physical processes such as the influence of turbulent fluxes in the water cycle. This allows the assessment of sublimation and deposition processes in the low accumulation zone of the interior Greenland Ice Sheet.
Therefore, we can provide a strategy to benchmark the parameterizations of surface mass balance and surface fluxes in regional climate models.

How to cite: Wahl, S., Steen-Larsen, H. C., Zuhr, A., and Reuder, J.: A novel method for directly obtaining the water vapor isotope surface flux for evaluating snow-atmosphere exchange processes , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-450, https://doi.org/10.5194/egusphere-egu2020-450, 2020.

The evolution of micrometeorological measurements has been recently manifested by developments in methodological and analytical techniques using spatial surface brightness temperature captured by infrared cameras (Schumacher et al. 2019, Katurji and Zawar-Reza 2016). The Thermal Image Velocimetry (TIV) method can now produce accurate 2D advection-velocities using high speed (>20Hz) infrared imagery (Inagaki 2013, Schumacher 2019). However, to further develop TIV methods and achieve a novel micrometeorological measurement technique, all scales of motion within the boundary layer need to be captured.

Spatial observations of multi-frequency and multi-scale temperature perturbations are a result from the turbulent interaction of the overlying atmosphere and the surface. However, these surface signatures are connected to the larger scales of the atmospheric boundary layer (McNaughton 2002, Träumner 2015). When longer periods (a few hours to a few days) of spatial surface brightness temperatures are observed, the larger scale information needs to be accounted for to build a comprehensive understanding of surface-atmospheric spatial turbulent interactions. Additionally, the time-frequency decomposition of brightness temperature perturbations shows longer periods of 4-15 minutes superimposed over shorter periods of ~ 4–30 seconds. This suggests that that boundary layer dynamic scales (of longer periods) can influence brightness temperature perturbations on the local turbulent scale. An accurate TIV algorithm needs to account for all scales of motion when analysing the time-space variability of locally observed spatial brightness temperature patterns.

To analyse these propositions temporally high resolved geostationary satellite infrared data from the Himawari 8 satellite was compared to near-surface and high speed (20 Hz) measured air and brightness temperature using thermocouple measurements and infrared cameras. The satellite provides a temporal resolution of 10-minutes and a horizontal resolution of 2 by 2 km per pixel and therefore captures the atmospheric meso γ and micro α scale which signals are usually active for ~10 minutes to < 12 hours. Moreover, the Himawari 8 brightness temperature was used to create the near-surface mean velocity field using TIV. Afterwards, the velocity field was compared to the in-situ measured wind velocity over several days during January 2019.

The results show that the atmospheric forcing from the micro α scale to lower atmospheric scales has a major impact on the near-surface temperature over several minutes. A significant (p-value: 0.02) positive covariance between the Himawari 8 measurement and the local measured temperature 1.5 cm above the ground on a 10 minute average, specifically concerning cooling and heating patterns, has been found.

Further analysis demonstrates that the retrieved near-surface 2-D velocity field calculated from the Himawari 8 brightness temperature perturbations is correctly representing the mean velocity. This finding allows the classification of meso-scale atmospheric forcing and its direct connection to local scale turbulent 2-D velocity measurements. This extends the TIV algorithm by a multi-scale component which allows to address inter-scale boundary layer analysis from a new point of view. In respect to the current findings a new experiment will focus on the repeated induced local velocity patterns from large scale forcing which will be measured through the surface brightness temperature.

How to cite: Schumacher, B., Katurji, M., and Zhang, J.: The infrared measurement cascade: Connecting large scale meteorologically induced surface temperature perturbations to local spatial velocity structures, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1106, https://doi.org/10.5194/egusphere-egu2020-1106, 2020.

EGU2020-12606 | Displays | AS2.1

The impact of the rotational direction of a wind turbine on its wake

Antonia Englberger, Andreas Dörnbrack, and Julie Lundquist

Wind turbines operating in a stably stratified atmospheric boundary layer often interact with a veering wind, which is characterized by a clockwise wind direction change with height in the Northern Hemisphere. The rotational direction of the wind turbine rotor has a significant impact on the flow field in the wake in case of a veering wind, whereas it is of minor importance if the wind direction is the same over the whole rotor.

The impact of the rotational direction in a stably stratified atmospheric boundary layer results in contrasting rotational directions of the near and far wake in case of a common clockwise rotating rotor, whereas in case of a counterclockwise rotating rotor the rotational direction of the wake persists in the whole wake. The change of the rotational direction of the wake at a downstream location, which is related to the transition from the near wake to the far wake region, results in a larger streamwise wake elongation and a narrower spanwise wake width. In the lower and upper part, the wake deflection angle is also influenced by the rotational direction of the blades, resulting in a smaller wake deflection angle in case of a common clockwise rotating rotor in the Northern Hemisphere. In the Southern Hemisphere, the situation is reversed, an effect related to the Coriolis force impact on the Ekman spiral.

As the rotational direction impacts the inflow velocity, it effects the produced power of a downwind turbine and likewise the loads acting on a downwind turbine. For a hypothetical downwind turbine with a staggered spacing of 7 D, the power output difference would be up to 23% in idealized simulations, whereas the power output difference for a counterclockwise rotating rotor instead of a clockwise one also depends on atmospheric conditions like the strength of stratification, the strength of the veering wind, the rotor fraction impacted by a veering wind, and wind speed.

How to cite: Englberger, A., Dörnbrack, A., and Lundquist, J.: The impact of the rotational direction of a wind turbine on its wake, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12606, https://doi.org/10.5194/egusphere-egu2020-12606, 2020.

EGU2020-1898 | Displays | AS2.1

The effect of row orientation on below-canopy turbulence characteristics in a wine-vineyard

Nurit Agam, Yasmin Levi, Joe Alfieri, and John Prueger

The momentum flux affects the energy exchange processes and thus may indirectly affect the water balance of agricultural fields. In wine vineyards, a high momentum flux between the vine rows may augment the evaporation and transpiration fluxes, and therefore decrease the water use efficiency. On the other hand, at night, high momentum fluxes may reduce (or even prevent) the formation of dew on the vine canopy, thus decrease the potential development of fungi and related diseases. We hypothesized that the wind direction relative to the row orientation in largely-spaced narrow hedge-rows characterizing wine vineyards greatly affects the turbulent structure and the momentum flux. This, in turn affects the vineyard microclimate, and ultimately, the grape quality. The objective of our research was to explore the effect of wine-vineyard row orientation on wind and temperature profiles below (and slightly above) the canopy and on the turbulence characteristics and eddy size.  The research was conducted in two adjacent vineyards in the Judean foothills in Israel (31°48'38.6"N 34°50'43.6"E and 31°48'37.1"N 34°50'24.0"E) having row orientations of NE-SW and SE-NW, respectively. With a NW prevailing wind direction, the wind is typically flowing perpendicularly to the former and in parallel to the latter. In each vineyard, 10 self-made type-T fine-wire thermocouples (0.08 mm diameter) were set on a pole places in the middle of the inter row, at heights above the ground of 5, 10, 20, 40, 80, 140, 220, 250, 300, and 400 cm. In addition, 4 fast-response 2D sonic anemometers were set at 10, 40, 140, and 250 cm above the ground. The measurements were conducted at 20 Hz.  Below canopy wind regime differed with orientation, mostly at heights lower than 2.5m. Higher wind speed below the canopy and smaller wind speed gradients were observed at the vineyard parallel to the prevailing wind direction.  Temperature gradients were mostly larger in the vineyard perpendicular to the prevailing wind direction.  Nevertheless, the power spectra were generally more uniform in height at the perpendicular vineyard.  

How to cite: Agam, N., Levi, Y., Alfieri, J., and Prueger, J.: The effect of row orientation on below-canopy turbulence characteristics in a wine-vineyard, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1898, https://doi.org/10.5194/egusphere-egu2020-1898, 2020.

EGU2020-21323 | Displays | AS2.1 | Highlight

Terrestrial and Martian Dust Devils: study of the translational motion and resolution of the size/distance degeneracy of the meteorological time series

Gabriele Franzese, Simone Silvestro, David Vaz, Ciprian Popa, and Francesca Esposito

Dust devils are convective vortices able to lift sand and dust grains from the surface. They are common not only in the terrestrial deserts, but also on Mars, where they give a substantial contribution to the planetary dust budget (∼50%). Dust devils are characterized by a central pressure drop that generates the rotation and translate advected by the wind background.
One of the problems related to their monitoring is due to the impossibility to directly separate the translational and rotational motion components from the study of the wind speed and direction time series. This means that it is not possible to directly retrieve information on their translational speed and direction and on the maximum rotational wind speed using only a meteorological station. 
In addition, there are other fundamental parameters that are not directly measurable, such as the distance of passage of the vortex from the station, its sense of rotation and its diameter.
These limitations lead in general to a size/distance degeneracy of the results, i.e. the acquired meteorological signatures of a smaller dust devils passing near the station could not be distinguished from the ones of a bigger and farther event. This, in turn, leads to several problems in the study of their physics.
To avoid these issues, the monitoring meteorological station can be equipped with an imaging camera system with a sufficient acquisition rate, resolution and field of view. However, this is not always possible, in particular for the planetary space missions.
Here, we want to present two simple methods for the characterization of the wind speed and direction time series of dust devils that allow an easy solution for the measure of the vortex translational wind speed and direction, distance of passage and sense of rotation.
The knowledge of these parameters allows to completely characterize the measured dust devils encounter just using the meteorological station acquisition.
In order to test the methods, we performed a field campaign in the Sahara desert, deploying a fully equipped meteorological station coupled with a camera system. We compared the results of the meteorological analysis with the ones obtained from the images, confirming the effectiveness of our methodology.
This methodology can give a substantial improvement in the interpretation of the past and next martian dust devils data. For example, the ESA/Roscosmos ExoMars 2020 mission will host on its lander a meteorological station (METEO package) and the Dust Complex, a suite of specific instruments devoted to the study of the primary airborne dust. These instruments can be used in tandem for the characterization of the local dust devils activity.

How to cite: Franzese, G., Silvestro, S., Vaz, D., Popa, C., and Esposito, F.: Terrestrial and Martian Dust Devils: study of the translational motion and resolution of the size/distance degeneracy of the meteorological time series , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21323, https://doi.org/10.5194/egusphere-egu2020-21323, 2020.

EGU2020-20503 | Displays | AS2.1

Statistical characterization of the sea-breeze physical mechanisms through in-situ and satellite observations

Antoni Grau Ferrer, Maria Antònia Jiménez Cortés, and Joan Cuxart Rodamilans
The physical mechanisms that take place under sea-breeze (SB) conditions in the Palma basin (Mallorca island, western Mediterranean sea) are analyzed through the inspection of data from automatic weather stations (AWS) during the period 2009-2017. Satellite-derived land-surface and sea-surface temperatures (LST and SST, respectively) are used to compute the surface thermal gradient (LST-SST) in the Palma basin. It presents a clear daily and seasonal cycles, and the daytime hourly averages for each month are always positive and maximal during summer time.
 
A method similar to the one proposed by Borne et al. (1998) is used to select the SB events from AWS data in Palma basin. Although the thresholds are valid for the SB features in the Palma basin, the method can be applied to other regions. SB conditions are mainly reported during the warm months of the year (from April to September) and specially during summer time. Results from the statistical analysis show that the SB follows diurnal cycle already described in previous works. Among the characteristics founded, the morning veering strongly depends on the speed and direction of the large-scale winds. Besides, weak wind conditions are reported during the morning veering and once the SB starts the cold advection from the sea counteracts the radiative heating and the 2 m-temperature levels off. The maximum surface thermal gradient under SB conditions is larger than 5ºC and it is often reported several hours after the morning veering. About two hours later the maximum wind speed is formed, strongly influenced by the amount of soil moisture. The thermal winds formed inside the basin also condition the propagation of the SB inland. The statistical analysis shows that the SB features in Mallorca depart from the idealized conditions due to the complex terrain of the island.

How to cite: Grau Ferrer, A., Jiménez Cortés, M. A., and Cuxart Rodamilans, J.: Statistical characterization of the sea-breeze physical mechanisms through in-situ and satellite observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20503, https://doi.org/10.5194/egusphere-egu2020-20503, 2020.

EGU2020-6797 | Displays | AS2.1

A Building Block Urban Meteorological Observation Experiment (BBMEX) over Seoul City, Korea

Moon-Soo Park, Jung-Hoon Chae, Jae-Sik Min, Minsoo Kang, Joon-Bum Jee, Sang-Heon Kim, and Chang-Rae Cho

For the purpose of understanding the detailed distribution of surface and air temperatures in a high-rise building block, a 3-dimensional Building-Block Meteorological observation EXperiment (BBMEX) campaign has been carried out over typical commercial area (Gwanghwamun) in Seoul Metropolitan Area, Korea during the heat-wave and tropical night periods (5-6 August) in 2019. Several types of fixed and mobile instruments were deployed in the experiment domain: A thermal infrared imager (TIR) monitored the surface temperature with 320×240 pixels including building wall, road, sidewalks at every 10 min; 6 automatic weather stations obtained air temperature and relative humidity, and wind speed and direction at every 1 min; a mobile weather vehicle (MOVE4) monitored road surface temperatures and 4-components of radiation at 1 s on roadway; a mobile cart for meteorological observation (MCMO) monitored surface, 0.5m, 1.5m, and 2.5m air temperatures at 1 s on the sidewalk and square. The TIR exhibited that east-face of a building was strongly heated during the morning time, while horizontal surface was strongly heated near noon. Air temperatures at 2 m high in 2×2 km2 exhibited 1.5 ℃ temperature range at 06 LST, while 4.0 ℃ temperature range at 15 LST on 6 August 2019, depending on the location of site in building blocks. Air temperatures in Gwanghwamun Square were 1.5-1.7 ℃ and 0.1-2.2 ℃ higher than those observed at the Seoul synoptic station (1 km apart) in night and day, respectively. Surface and 0.5, 1,5, and 2.5m temperatures was 49.1 ℃, 38.7 ℃, 38.1 ℃, and 37.9 ℃, respectively, at 1500 LST on 6 August 2019, when the hottest air temperature in the year 2019 (36.9 ℃) was recorded at the Seoul station. Surface and air temperatures were found to be affected by many factors in a building-block such as shades, trees, building height and density, aspect ratio of building canyon, sky-view, ground-fountain, waterway, etc.

How to cite: Park, M.-S., Chae, J.-H., Min, J.-S., Kang, M., Jee, J.-B., Kim, S.-H., and Cho, C.-R.: A Building Block Urban Meteorological Observation Experiment (BBMEX) over Seoul City, Korea, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6797, https://doi.org/10.5194/egusphere-egu2020-6797, 2020.

EGU2020-6668 | Displays | AS2.1

Horizontal distribution of temperature in a building-block using a Mobile Cart for Meteorological Observation (MCMO)

Minsoo Kang, Moon-Soo Park, Jung-Hoon Chae, and Jae-Sik Min

Horizontal distribution of building block scale meteorological information is important to understand the disastrous weather phenomena occurred at urban areas. Most meteorological models assume the same surface temperature, or an ideal surface temperature to simulate the high-resolution wind field in or above urban boundary-layer. This study aims to establish the basic foundation for producing the high-resolution and high-quality user-specific horizontal meteorological information at an urban building block in the Seoul Metropolitan Area. Therefore, the Mobile Cart for Meteorological Observation (MCMO) was developed and used in a meteorological experimental campaign during heat wave event days.
The MCMO includes 3 air temperature sensors, 1 weather transmitter, 1 infrared surface temperature sensor, 1 GPS (global positioning system), and video camera on the mobile cart. The MCMO measures the temperature at 4 altitudes (surface, 0.5m, 1.5m, and 2.5m), latitude, longitude, and surrounding environment condition of measurement site. The observation cycle is 1 second to produce pedestrian-friendly weather information. The meteorological experimental campaign was conducted in Gwanghwamun square in the Seoul, Korea. Gwanghwamun square is complex area which has high-rise building block, wide roads of heavy traffic, and green lung. Observation period was from 1200 LST 5 August 2019 to 2200 LST 6 August 2019 including the hottest day of the year. Through the meteorological experimental campaign, the MCMO shows the detail temperature change over time, location, and altitudes. The temperature was changed as the altitude of the sun changed. When the MCMO was move through the green lung or building block, also the temperature was changed. Temperature changes were the largest at surface temperature and tended to decrease as altitude increased. The MCMO can be used to understand high-resolution weather information and horizontal distribution of temperature in urban area. Additionally, another meteorological experimental campaign will be held in the summer of 2020.

How to cite: Kang, M., Park, M.-S., Chae, J.-H., and Min, J.-S.: Horizontal distribution of temperature in a building-block using a Mobile Cart for Meteorological Observation (MCMO), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6668, https://doi.org/10.5194/egusphere-egu2020-6668, 2020.

       Higher and denser building groups are the most concentrated reflection of urbanization on the underlying surface reconstruction. With the continuous city expanding, urban wind field structure was changed, also the aerodynamic parameters dependent on. Based on observational data (slow-response) collected at 15 levels on Beijing 325m meteorological tower from 1991-2018, time and vertical trends of atmospheric stability, wind direction, wind speed, aerodynamic parameters were analyzed. Through Sen's slope, Mann-Kendall trend test and mutation analysis, we believe that urbanization has made a significant influence on local meteorological condition, and all the above variables mutated around the year of 1999. Before 1999, the proportion of neutral and unstable conditions declined with a trend of -0.63% and -2.0% per year respectively, and increased with a trend of +0.08% and +0.06% per year after 1999. As for wind direction, the dominant wind direction below 47m turned from southwest/northwest before 1999 to southeast after 1999, while above 47m remain unchanged as southeast, reflecting that the action range of urban impact is clearly distinguished from that of atmospheric background field. In terms of wind speed, the annual mean value trended to decrease at -0.0019m/s per year, and vertical wind speed trended to increased with height (per meter) at m/s per year, which reflected the continuous enhancement of attenuation effect of complex underlying on the near-ground wind speed. Furthermore, we found that although there was indeed a weaken tendency for wind speed in Beijing urban areas, but near neutral wind speed maintained a growth trend under 140m during 1999-2018. It was possible the deal with urban wake effect, wind field structure mutation or turbulence effect. Aerodynamic parameters  and d have undergone significant changes during the peak stage of urbanization, and tended to develop steadily with a 7-years fluctuations trend after that. In the past 28 years, d has increased from 1.34m in 1991 to 26.19m in 2018, while  has decreased from 2.75m to 1.02m. This is due to the fact that the increase of buildings average height is the result of roughness superposition. If the 7-year fluctuations trend continues, d of Beijing urban area will soon enter the next uplift period, during which the wind speed may increase slightly under nearly neutral conditions, and the cleaning effect on the pollution may be gradually enhanced.

 

How to cite: Liu, X.: The Change of Aerodynamic Parameters over Beijing Urban Area during 1991-2018, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6228, https://doi.org/10.5194/egusphere-egu2020-6228, 2020.

Due to excessive anthropogenic emissions, heavy aerosol pollution episodes (HPEs) often occur during winter in the Beijing-Tianjin-Hebei (BTH) area of the North China Plain. Extensive observational studies have been carried out to understand the causes of HPEs; however, few measurements of vertical aerosol fluxes exist, despite them being the key to understanding vertical aerosol mixing, specifically during weak turbulence stages in HPEs. In the winter of 2016 and the spring of 2017 aerosol vertical mass fluxes were measured by combining large aperture scintillometer (LAS) observations, surface PM2.5 and PM10 mass concentrations, and meteorological observations, including temperature, relative humidity (RH), and visibility, at a rural site in Gucheng (GC), Hebei Province, and an urban site at the Chinese Academy of Meteorological Sciences (CAMS) in Beijing located 100 km to the northeast. These are based on the light propagation theory and surface-layer similarity theory. The near-ground aerosol mass flux was generally lower in winter than in spring and weaker in rural GC than in urban Beijing. This finding provides direct observational evidence for a weakened turbulence intensity and low vertical aerosol fluxes in winter and polluted areas such as GC. The HPEs included a transport stage (TS), an accumulative stage (AS), and a removal stage (RS). During the HPEs from 25 January 2017 to January 31, 2017, in Beijing, the mean mass flux decreased by 51% from 0.0049 mg m-2s-1 in RSs to 0.0024 mg m-2s-1 in the TSs. During the ASs, the mean mass flux decreased further to 0.00087 mg m-2s-1, accounting for approximately 1/3 of the flux in the TSs. A similar reduction from the TSs to ASs was observed in the HPE from 16 December 2016 to 22 December 2016 in GC. It can be seen that from the TS to the AS, the aerosol vertical turbulent flux decreased, but the aerosol particle concentration within surface layer increased, and it is inferred that in addition to the contribution of regional transport from upwind areas during the TS, suppression of vertical turbulence mixing confining aerosols to a shallow boundary layer increased accumulation.

How to cite: Yuan, R.: Understanding Aerosol Vertical Transport During Heavy Aerosol Pollution Episodes in the North China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4498, https://doi.org/10.5194/egusphere-egu2020-4498, 2020.

In this study, we investigated the effects of the anthropogenic heat caused by the energy usage on the air temperature distributions in an urban area using a CFD model. We calculated the anthropogenic heat fluxes using a top-down method with monthly and hourly allocation coefficients and the total amount of the yearly electrical energy usage of buildings. To construct the buildings and to estimate the anthropogenic heat fluxes in the CFD model for the target area, we used the land use and GIS data. We conducted the CFD simulations for the heatwave period (2018.08.02 ~ 2018.08.08) in a building-congested district around the Seoul ASOS (ASOS 108) to see how the anthropogenic heat fluxes affected the thermal environment in the target area. The target area is mostly composed of commercial and residential areas. The temperature increased near the roads and buildings. At the night time, the temperature increase near the buildings with high anthropogenic heat fluxes was more significant than the daytime. The comparison with the ASOS-observed temperatures showed that the inclusion of the anthropogenic heat fluxes improved the CFD simulations of temperatures.

How to cite: Mun, D.-S. and Kim, J.-J.: A Study on the Effects of the Anthropogenic Heat Fluxes on the Temperature Distribution in an Urban Area, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12118, https://doi.org/10.5194/egusphere-egu2020-12118, 2020.

EGU2020-21700 | Displays | AS2.1

Vertical distribution of Kolmogorov Constants of Atmospheric Turbulence over an Urban Surface

Weichen Ding, Yu Shi, Zhe Zhang, and Fei Hu

The Kolmogorov constant is fundamental in stochastic models of turbulence, and significant in boundary layer meteorology especially. Though lots of experiments have been conducted to study Kolmogorov Constant, constant at high elevation and over urban surface was rarely researched. Therefore, in this paper, ultrasonic data at seven levels over an urban underlying surface were used to calculate the Kolmogorov constants of velocity. The results of Kolmogorov constants at the different floors indicated that the constants below 47m were smaller because of the influence of the urban canopy layer. Besides, the time-varying result showed that constants were universally independent of stability. Furthermore, Kolmogorov constant in this paper was close to the result determined by former experiments.

How to cite: Ding, W., Shi, Y., Zhang, Z., and Hu, F.: Vertical distribution of Kolmogorov Constants of Atmospheric Turbulence over an Urban Surface, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21700, https://doi.org/10.5194/egusphere-egu2020-21700, 2020.

EGU2020-2632 | Displays | AS2.1

The distribution of positive and negative turbulent heat diffusivity under urban pollution conditions

Zhe Zhang, Yu Shi, Haijion Sun, Lei Liu, and Fei Hu

Turbulent diffusion efficiently transports momentum, heat, and matter and affects their transfers between the surface and the atmosphere. As an important parameter in describing turbulent diffusion, turbulent heat diffusivity KH has scarcely been studied in the context of frequent urban pollution in recent years. In this study, KH under urban pollution conditions was directly calculated based on the K-theory. We found an obvious diurnal variation in KH and its varying vertical distributions for each case and with time. Interestingly, the height of negative KH rises gradually after sunrise, peaks at noon, and falls near sunset. Negative KH is unusually significant at sunrise and sunset and approximately 140 m during most of the night. The magnitude and fluctuation in KH are smaller in the pollutant accumulation stage (CS) at all levels than in the pollutant transport stage (TS) and pollutant removal stage (RS). Turbulent diffusion may greatly affect PM2.5 concentration at the CS because of the negative correlation between PM2.5 concentration and the absolute value of KH at the CS accompanied by weak wind speed. The applicability of the K-theory is not very good during either day or at night. Note that these problems are inherent in K-theory when characterizing complex systems, such as turbulent diffusion, and require new frameworks or parameterization schemes. These findings may provide valuable insights for improving or establishing a new parameterization scheme for KH and promote the study of turbulent diffusion, air quality forecasting, and weather and climate modeling.

How to cite: Zhang, Z., Shi, Y., Sun, H., Liu, L., and Hu, F.: The distribution of positive and negative turbulent heat diffusivity under urban pollution conditions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2632, https://doi.org/10.5194/egusphere-egu2020-2632, 2020.

EGU2020-13388 | Displays | AS2.1

Surface thermal heterogeneities, dispersive fluxes and the conundrum of unaccounted statistical spatial inhomogeneities

Marc Calaf, Travis Morrison, Fabien Margairaz, Alexei Perelet, Chad W. Higgins, Stephen A. Drake, and Eric R. Pardyjak

The use of Numerical Weather Prediction (NWP) models is ubiquitous in our daily lives, whether to decide what to wear, to plan for the weekend, invest on wind turbines, decide strategies for food security or to forecast atmosphere-driven natural disasters, to name a few. Currently, intrinsic to most NWP models is the assumption of spatial homogeneity at kilometer to sub-kilometer scales when, for example, classic similarity scaling relationships are applied to account for unresolved near-surface momentum, heat and mass exchanges. While advances in computation (and computing) are enabling finer grid resolutions in NWP, representing land-atmosphere exchange processes at the lower boundary remains a challenge (regardless of the numerical resolution but not independent from it). This is partially a result of the fact that land-surface heterogeneity exists at all spatial scales and its variability does not ‘average’ out with decreasing scales. Such variability need not rapidly blend away from the boundary and thereby impacts the spatial distribution of fluxes throughout the near-surface region of the atmosphere.

     While, the effects of spatial surface heterogeneities have long been minimized under the assumption of an existing blending length-scale, in this work evidence is presented of the consequential effect of such surface heterogeneities. Specifically, canonical experiments based on in-situ measurements and high-resolution numerical simulations quantify the effect of surface thermal heterogeneities on an otherwise homogeneous planar surface. Therefore, such near-canonical case describes inhomogeneous scalar transport in an otherwise planar homogeneous flow when thermal stratification is weak or absent. In this work, the interaction between the characteristic length scales of the surface heterogeneities, and the scales of resolved fluid dynamics transport is further unraveled. Dispersive fluxes naturally appear as a means to account for unresolved, and time-lasting advection fluxes generated by a-priori unresolved spatial thermal heterogeneities. Results illustrate that dispersive fluxes can represent as much as 40% of the total resolved advection flux under weak wind conditions, and remain relevant under strong winds. Furthermore, results of this work appear not to only be relevant in the treatment of unresolved heterogeneities in NWP models, but also in understanding the unresolved problem of surface energy budget closure.

How to cite: Calaf, M., Morrison, T., Margairaz, F., Perelet, A., W. Higgins, C., A. Drake, S., and R. Pardyjak, E.: Surface thermal heterogeneities, dispersive fluxes and the conundrum of unaccounted statistical spatial inhomogeneities, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13388, https://doi.org/10.5194/egusphere-egu2020-13388, 2020.

EGU2020-13324 | Displays | AS2.1

High-resolution temperature and wind field observations in the atmospheric boundary layer

Matthias Zeeman, Marwan Katurji, and Tirtha Banerjee

Do we get a better picture of the world around us if we simultaneously observe many aspects instead of a few? Dense sensing networks are an elaborate way to validate our representation of land surface boundary layer processes commonly derived from single point monitoring stations or a three-dimensional model world. More samples promise unique insights into interactions that occur at different scales, separated in space and time.

We present a combination of techniques that purvey a) observations of the temperature and wind field in high detail and b) the extraction of information about dynamic interactions near the surface. A field experiment was conducted in complex terrain, in which landscape features dramatically modulate local flow patterns and the atmospheric stability during summer days rapidly transitions on a diurnal scale and between locations. Wind and temperature were simultaneously observed using a network of Doppler lidar, sonic anemometer, fiber-optic temperature sensing (DTS) and thermal imaging velocimetry (TIV) instrumentation, centered around the TERENO/ICOS preAlpine grassland observatory station Fendt, Germany, during the ScaleX Campaigns (https://scalex.imk-ifu.kit.edu). Data analyses relied on signal decomposition and statistical clustering, aimed at the characterization of (non-)turbulent motions and their feedback on turbulent mixing near the surface. The combination of methods offered multiple levels of detail about the development and impact of organized structures in the atmospheric boundary layer.

The study shows that the exploration of novel micrometeorological and data sciences techniques helps advance our knowledge of fundamental aspects of atmospheric turbulence, and provides new avenues for theoretical and numerical studies of the atmospheric boundary layer.

How to cite: Zeeman, M., Katurji, M., and Banerjee, T.: High-resolution temperature and wind field observations in the atmospheric boundary layer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13324, https://doi.org/10.5194/egusphere-egu2020-13324, 2020.

EGU2020-8674 | Displays | AS2.1

Experimental study of katabatic jets over steep slopes: buoyancy effect and turbulence properties

Claudine Charrondière, Christophe Brun, Martin Obligado, Jean-Emmanuel Sicart, Jean-Martial Cohard, Hélène Guyard, Romain Biron, and Catherine Coulaud

Katabatic winds are gravity flows that develop over sloping terrain due to radiative cooling at the surface. They have been extensively studied, but experimental works have generally been performed over gentle slopes. Some recent papers (eg. [3]) focused on the combined effect of surface angle and buoyancy on turbulence over steep slopes. In such configurations, the vertical component of the turbulent sensible heat flux may differ a lot from the slope-normal component, suggesting that buoyancy may act on turbulent quantities in an unusual way when katabatic jets develop over steep slopes. Such behavior seems to affect stability parameters used in Monin-Obukhov similarity theory applied in most meteorological models.

We study the buoyancy production term in the continuity of the work from [3], drawing on temperature and wind speed measurements acquired during 10 nights in November 2012 [1]. In situ measurements were performed under stable anticyclonic conditions, over an alpine slope of around 21° (French Alps) on a 4 level mast up to 6.5m, at a frequency sampling of 10 to 20Hz.

We conclude that turbulent kinetic energy and turbulent momentum flux are damped below the maximum wind speed height as expected from stably stratified atmospheric boundary layer. Conversely, turbulent kinetic energy can be locally reinforced by buoyancy in the external part of the katabatic jet, which confirms the results from [3]. Buoyancy may also produce turbulent momentum flux around the maximum wind speed due to the asymmetry of the jet. Results compare well with recent numerical modeling of a katabatic jet along a curved alpine slope under similar meteorological conditions [2].

Another field experiment took place during 16 nights in February 2019, over a snow-covered slope of around 34° in a similar location. The 11 wind speed levels and 17 temperature levels up to 12m, associated with a change of the surface level due to packing and melting of the snow, widen the range of analysis of the vertical profile. These data are associated with meteorological measurements and with a tethered balloon up to 50-100m above the ground surface.

Wind velocity measurements with a multi-hole pressure probe (cobra type) close to the ground provided more information than the previous dataset at a high frequency sampling of 1250 Hz. We show that the classical turbulent boundary layer wind speed profile applies well to the inner-layer region of katabatic jets, in spite of the presence of a maximum on the vertical streamwise velocity profiles. We find no significative changes caused by buoyancy on this profile. Roughness effect due to the snow on the surface will be discussed as well.

[1] Blein (2016), PhD

[2] Brun et al. (2017), JAS

[3] Oldroyd et al. (2016), BLM

How to cite: Charrondière, C., Brun, C., Obligado, M., Sicart, J.-E., Cohard, J.-M., Guyard, H., Biron, R., and Coulaud, C.: Experimental study of katabatic jets over steep slopes: buoyancy effect and turbulence properties, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8674, https://doi.org/10.5194/egusphere-egu2020-8674, 2020.

EGU2020-16184 | Displays | AS2.1

Exit jet in a narrow Pyrenean valley: the Aure Valley 2018 field experiment

Alexandre Paci, Maria Antonia Jiménez, Joan Cuxart, Marie Lothon, Olivier Clary, Yann Seity, Daniel Martinez-Villagrasa, Alain Dabas, Thomas Rieutord, and Carlos Román-Cascón

A field experiment took place from July to October 2018 in a narrow valley of the central Pyrenees in order to study local flows and their impacts.
This field experiment is a joint effort by CNRM, Laboratoire d'Aerologie and University of the Balearic Islands. It emerged from a recent numerical study done by the University of the Balearic Islands (Jiménez et al. 2019).
This study suggests that under clear-sky conditions a jet forms in the valley and can be observed several kilometers away from the valley exit.

Several instruments including a Doppler scanning lidar and three meteorological stations were deployed on the main site at the valley exit, where the jet maximum is expected, and on two other sites up valley. Data from the Atmospheric Research Center (part of the Pyrenean Platform for the Observation of the Atmosphere P2OA) in Lannemezan are also used. They include radio-soundings specifically planned for the field experiment. This instrumented platform of Laboratoire d'Aerologie, located about 10 km away from the valley exit, is an important asset for the project.

An overview of the field experiment as well as the valley exit jet main features will be presented. A comparison with outputs from the NWP model AROME will be also shown.

How to cite: Paci, A., Jiménez, M. A., Cuxart, J., Lothon, M., Clary, O., Seity, Y., Martinez-Villagrasa, D., Dabas, A., Rieutord, T., and Román-Cascón, C.: Exit jet in a narrow Pyrenean valley: the Aure Valley 2018 field experiment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16184, https://doi.org/10.5194/egusphere-egu2020-16184, 2020.

EGU2020-9919 | Displays | AS2.1

Surface thermal inversion evolution in the bottom of a Pyrenean valley studied by observations and mesoscale simulations

Maria A. Jiménez, Joan Cuxart, Alexandre Paci, Laura Conangla, Daniel Martínez-Villagrasa, and Belen Martí

Two experimental campaigns have been carried out in the Cerdanya valley at south side of the Pyrenees (E-W oriented, 35 km long and 9 km wide) during fall 2015 (Cerdanya Cold Pool experiment, CCP’15) and winter 2017 (CCP’17, as a part of the Cerdanya-2017 experiment) to study the cold pool that usually forms there at night. The main site (Das) is placed in the central bottom part of the basin. Conangla et al (2018, IJOC) showed that most cold pool events reported there have a daily cycle, being formed in the evening and destroyed by solar heating of the surface the morning after.

The availability of vertical soundings performed by a tethered balloon and a WindRASS, together with measured surface fluxes of latent and sensible heat and momentum at the surface layer allows to inspect the establishment and evolution of the surface thermal inversion in Das. This area collects also downslope and downvalley flows accumulating cold air in the valley along the night. The organization of the flow at low levels is studied through mesoscale simulations of some selected Intensive Operational Periods (IOPs) and the surface observations at different locations along and across the valley.

The selected IOPs comprise nights with only locally-generated winds and small cloud cover, and with variable surface state including grass, fresh snow and patches of old snow. The evolution of the strength and depth of the surface inversion as seen by the model are compared to the available data. Besides, the organization of the flow at low levels and the contribution of the air from the tributary valleys is analyzed in terms of temperature and wind speed budgets to properly characterize the differences in the strength of the cold pool for the selected studied IOPs.

How to cite: Jiménez, M. A., Cuxart, J., Paci, A., Conangla, L., Martínez-Villagrasa, D., and Martí, B.: Surface thermal inversion evolution in the bottom of a Pyrenean valley studied by observations and mesoscale simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9919, https://doi.org/10.5194/egusphere-egu2020-9919, 2020.

EGU2020-9145 | Displays | AS2.1

Turbulent flux estimation in the atmospheric surface layer through flux-gradient similarity during the ALEX17 field campaign

Belén Martí, Daniel Martínez-Villagrasa, and Joan Cuxart

Turbulent flux measurements require high frequency sampling in order to characterize appropriately all the variability scales of the atmosphere. A 3D sonic anemometer coupled with a gas detector allows for applying the eddy-covariance method which has become the standard. However, the high cost of this system often implies to look for alternative methods, specially when multiple stations are required. Turbulent fluxes can also be estimated through the flux-gradient similarity theory, requiring observations of mean quantities of (at least) air temperature and humidity at two levels and wind at one height. This approach is more sensitive to the disturbing influence of heterogeneous and complex surfaces and a comparison between methodologies is required under these conditions.

The data used in this study is part of the ALaiz EXperiment 2017-2018 (ALEX17). This campaign was the last within the New European Altas project. It had a duration of over a year with measurements in complex terrain. The location of the experiment is a valley bounded by two mountain ranges that rise 150 m north and over 600 m south. A central site in the centre of the valley was instrumented with a sodar-RASS, an 80-m tower, a surface energy balance (SEB) station with an eddy-covariance system and a surface-layer station (SLS) with the necessary measurements to estimate the turbulent fluxes. In addition, eight supplementary SLS were deployed along the longitudinal and transverse valley axes to characterize the surface layer variability within the valley.

This communication will present a comparison of the friction velocity and sensible heat flux obtained from both the eddy-covariance system and the flux-gradient method at the central site for a time series of 8 months. Friction velocity is highly comparable between methodologies with a correlation of 0.92 and a standard deviation of 0.05. The performance of the sensible heat flux estimation differs between stable and unstable cases, with a correlation of 0.70 and 0.89, respectively, after applying a quality control procedure. The poorer results obtained under stable conditions points out the need for alternative estimations of the sensible heat flux for these cases.

How to cite: Martí, B., Martínez-Villagrasa, D., and Cuxart, J.: Turbulent flux estimation in the atmospheric surface layer through flux-gradient similarity during the ALEX17 field campaign, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9145, https://doi.org/10.5194/egusphere-egu2020-9145, 2020.

EGU2020-4879 | Displays | AS2.1

Assessment of turbulent scales over complex terrain in central Spain

Félix García-Pereira and Gregorio Maqueda

In this work, a micrometeorological assessment of Atmospheric Boundary Layer paremeters is carried out in order to determine the characteristic turbulent scales over complex terrain in the Sierra de Guadarrama, a range in central Spain. Observational data series of temperature and wind velocity measured at high frecuency (10 Hz) are available. These data come from two different stations located in the Bosque de La Herrería and belonging to GuMNet (2020) (Guadarrama Monitoring Network).

Integral scales, both time and spatial, have been determined for different atmospheric conditions, defined by parameters such as wind direction or stability of stratification. Also, energy cascade phenomenon occurence is assessed. In order to carry this out, different time series analysis tools are used, such as autocorrelation functions in time, and normalised power spectra or wavelets. Results obtained are compared with previous works.

In general, results show that under no synoptic forcing there is a clear dependency on diurnal cycle, giving rise to the development of big integral scales at nighttime, while they are small during the day. When synoptic forcing prevails, the scales are also small, both at daytime and nighttime. Moreover, a correlation patterns method has been implemented for scales obtained at two different heights (4 and 8 meters) on the one hand and at two locations on the other. In the first case, integral scales are highly correlated, exceeding the threshold of 0.5. In the second case, temporal scales show high correlation values, but spatial ones do not.  In addition, the slopes of the spectra in the inertial subrange have  been obtained and compared to those over homogeneous terrain (Kaimal et al., 1972), getting similar results for velocity turbulent components but not in case of vertical kinematic momentum and heat fluxes.

 

References

GuMNet: Guadarrama Monitoring Network (UCM), https://www.ucm.es/gumnet/, 2020.

Kaimal, J. C., Wyngaard, J. C., Izumi, Y., and Coté, O. R.: Spectral characteristics of surface- layer turbulence, Quart. J. R. Met. Soc., 98, 563–589, 1972.

How to cite: García-Pereira, F. and Maqueda, G.: Assessment of turbulent scales over complex terrain in central Spain, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4879, https://doi.org/10.5194/egusphere-egu2020-4879, 2020.

EGU2020-5566 | Displays | AS2.1

Investigating the relationship between soil moisture and evapotranspiration at different surfaces. Do we improve fluxes just improving the land use in models?

Carlos Román-Cascón, Marie Lothon, Fabienne Lohou, Aurore Brut, Oscar Hartogensis, Olivier Merlin, Nitu Ojha, Carlos Yagüe, Ramón Soriguer, Ricardo Díaz-Delgado, Ana Andreu, and Maria P. González-Dugo

A correct spatial representation of the surface energy balance is still a challenge. In a first step, and assuming a correct knowledge of the incoming short-wave radiation, it is the land cover that mostly controls the albedo and the long-wave radiation emitted to the atmosphere, influencing significantly the net radiation available at the surface and the surface temperature. In a second step, the partitioning of this energy into evapotranspiration and sensible heat flux is, in part, controlled by the availability of soil moisture but also by the type, characteristics and physiological state of the vegetation covering the surface, since plants provide a pathway for soil moisture to the atmosphere through transpiration.

Hence, to correctly model the surface energy balance, we face three main challenges: an appropriate representation of the land use, soil moisture and a correct modelling of how plants regulate their stomatal behaviour under different soil-moisture limited conditions.

In this work, by using in situ data we explore the relations between soil moisture and evapotranspiration from several vegetation types at different soil-moisture limited regions: a wetter area in the south of France and a drier one in the south of Spain. For this, we try to distinguish different periods and vegetation states. Since significant differences are observed for the various plant types, we investigate whether using a more realistic and higher-resolution land-use database in the Weather Research and Forecasting (WRF) model improves the simulation of soil moisture and surface fluxes.

How to cite: Román-Cascón, C., Lothon, M., Lohou, F., Brut, A., Hartogensis, O., Merlin, O., Ojha, N., Yagüe, C., Soriguer, R., Díaz-Delgado, R., Andreu, A., and González-Dugo, M. P.: Investigating the relationship between soil moisture and evapotranspiration at different surfaces. Do we improve fluxes just improving the land use in models?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5566, https://doi.org/10.5194/egusphere-egu2020-5566, 2020.

EGU2020-19735 | Displays | AS2.1

Observational analysis of thermally-driven topographic flows and their turbulence-waves interaction

Carlos Yagüe, Carlos Román-Cascón, Marie Lothon, Fabienne Lohou, Jon Ander Arrillaga, and Gregorio Maqueda

Thermally-driven flows (TDFs) are mesoscale circulations driven by horizontal thermal contrasts in scales ranging from 1 and 100-200 km. The presence of mountains can generate a kind of these TDFs called thermally-driven topographic flows, with a typical daily cycle which is observed when weak synoptic conditions are present. These flows impact the turbulence features in the Atmospheric Boundary Layer (ABL), as well as different scalars (temperature, CO2, water vapor, pollutants, etc.). Moreover, these circulations, which can be of different scales (from small-scale shallow drainage flows to for example the larger Mountain – Plain flows) can generate gravity waves (GWs) along the transition to the stable boundary layer (SBL) and during the night. In this work, 88 days belonging to an extended period of the BLLAST field campaign[1] have been analysed. The corresponding nocturnal TDFs have been detected through a systematic and objective algorithm which considers both synoptic and local meteorological conditions. The main objectives of the study are: to characterize the TDFs at CRA (which is placed on a plateau near the Pyrenees in France); to evaluate the performance of the objective algorithm[2] in obtaining the events of interest; to establish different categories of TDFs and search for driving mechanisms (local, synoptic,..); and finally to explore the connections between TDFs and the generation of Gravity Waves (GWs), often observed in the nocturnal SBL[3]. Their interaction with turbulence is also analysed using different multiscale techniques, such as wavelets applied to pressure measurements obtained from high accurate microbarometers, and MultiResolution Flux Decomposition –MRFD- applied to sonic anemometer data. The contribution of different scales to turbulent parameters will be deeply evaluated and related to the arrival of TDFs and to the presence of GWs.

 

[1] Lothon, M., Lohou, F. et al (2014): The BLLAST field experiment: Boundary-Layer Late Afternoon and Sunset Turbulence. Atmos. Chem. Phys., 14, 10931-10960.

 [2] Román-Cascón, C., Yagüe, C., Arrillaga, J.A., Lothon, M., Pardyjak, E,R., Lohou, F., Inclán, R.M., Sastre, M., Maqueda, G., Derrien, S., Meyerfeld, Y., Hang, C., Campargue-Rodríguez, P. & Turki, I. (2019): Comparing mountain breezes and their impacts on CO2 mixing ratios at three contrasting areas. Atmos. Res., 221, 111-126.

[3] Sun, J., Nappo, C.J., Mahrt, L., Belusic, D., Grisogono, B., Stauffer, D.R., Pulido, M., Staquet, C., Jiang, Q., Pouquet, A., Yagüe, C. Galperin, B., Smith, R.B., Finnigan, J.J., Mayor, S.D., Svensson, G., Grachev, A.A. & Neff., W.D.: (2015): Review of wave-turbulence interactions in the stable atmospheric boundary layer, Rev. Geophys., 53, 956–993.

How to cite: Yagüe, C., Román-Cascón, C., Lothon, M., Lohou, F., Arrillaga, J. A., and Maqueda, G.: Observational analysis of thermally-driven topographic flows and their turbulence-waves interaction , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19735, https://doi.org/10.5194/egusphere-egu2020-19735, 2020.

EGU2020-3041 | Displays | AS2.1

Analyzing the atmospheric scales involved in sea-breeze formation and frontal characteristics

Jon Ander Arrillaga, Pedro Jiménez, Jordi Vilà-Guerau de Arellano, Maria Antonia Jiménez, Carlos Román-Cascón, Mariano Sastre, and Carlos Yagüe

We investigate sea-breeze (SB) frontal passages troughout a 10-year period. Spanning the whole period, numerical simulations from the Weather Research and Forecasting (WRF) model are compared with a comprehensive observational database from the Cabauw Experimental Site (Ruisdael Project). On the one hand, a fine horizontal resolution of 2 km is employed in the numerical simulations, and the observational vertical levels within the first 200 m above the surface are replicated. On the other hand, an algorithm based on objective and strict filters is applied to both observations and simulations to select the SB events. This methodology allows to investigate the atmospheric scales influencing the SB formation and their interaction with local turbulence in a robust and objective way.

By carrying out a filter-by-filter comparison, we find that the simulated large-scale conditions show a good rate of coincidence with the observations (69%). Small biases in the large scale wind direction, however, induce important deviations in the surface-wind evolution. Regarding the mesoscale forcings, the land-sea temperature gradient is overestimated in average up to 4 K, producing stronger SB fronts in WRF. The analysis of the SB frontal characteristics and impacts is carried out by classifying the events into three boundary-layer regimes (convective, transition and stable) based on the value of the sensible-heat flux at the moment of the SB onset. The stronger SB in the model leads to enhanced turbulence particularly in the convective and transition regimes: the friction velocity, for instance, is overstated by around 50% at the SB onset. In addition, the arrival of the SB front enhances the stable stratification and gives rise to faster afternoon and evening transitions compared with situations solely driven by local atmospheric turbulence.

The obtained results can be considered a benchmark of the aspects to be improved in order to produce finer SB forecasts and more adequate representations of the associated physical processes, particularly during the afternoon and evening transition of the ABL.

How to cite: Arrillaga, J. A., Jiménez, P., Vilà-Guerau de Arellano, J., Jiménez, M. A., Román-Cascón, C., Sastre, M., and Yagüe, C.: Analyzing the atmospheric scales involved in sea-breeze formation and frontal characteristics, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3041, https://doi.org/10.5194/egusphere-egu2020-3041, 2020.

EGU2020-12081 | Displays | AS2.1

An atmospheric surface layer study: The Idealized horizontal Planar Array experiment for Quantifying Surface Heterogeneity (IPAQS)

Travis Morrison, Marc Calaf, Eric Pardyjak, Marcus Hultmark, Chad Higgins, Giacomo Iungo, Stephan Drake, Sebastian Hoch, Dragan Zajic, Alexei Perelet, Alex Bingham, Claudia Brunner, Thomas DeBell, Nipun Gunawardena, Yi-Chun Huang, Gabe Mogollon, Behzad Najafi, Yajat Pandya, Matteo Puccioni, and Dhiraj Kumar Singh Sr

Numerical weather prediction models rely heavily on boundary-layer theories, which poorly capture the interactions between the Earth’s heterogeneous surface and the internal boundary layers aloft. Further, in relation to these theories, there remains outstanding questions that still require new understanding, such as the closure of the surface energy balance, advection quantification, and surface-flux interaction. We hypothesize that under certain conditions of unstable and neutral stratification, surface thermal heterogeneities can significantly influence the flow structure and alter momentum and scalar transport. To be able to access this hypothesis, we designed the Idealized horizontal Planar Array experiment for Quantifying Surface heterogeneity (IPAQS). IPAQS took place during the summers of 2018 and 2019 at the Great Salt Lake Desert playa in western Utah at the U.S. Army Dugway Proving Ground’s Surface Layer Turbulence and Environmental Test (SLTEST) facility. The site is characterized by a long uninterrupted fetch with uniform surface roughness and large thermal and moisture heterogeneities covering a wide range of scales. Observations were made with an array of 2-m high, temporally-synchronized, fast-response sonic anemometers, and finewire thermocouples, which were deployed on a coarse grid covering an area of 800 m x 800 m with 200-m spacing. Results provide valuable insight into the spatial and temporal evolution of the flow. Fine-scale turbulence was measured using Nano-Scale Thermal Anemometry Probes (NSTAP). Meanwhile, larger-scale turbulence was captured with Doppler wind LiDARs. Presented is an overview of the experiment and initial results.

How to cite: Morrison, T., Calaf, M., Pardyjak, E., Hultmark, M., Higgins, C., Iungo, G., Drake, S., Hoch, S., Zajic, D., Perelet, A., Bingham, A., Brunner, C., DeBell, T., Gunawardena, N., Huang, Y.-C., Mogollon, G., Najafi, B., Pandya, Y., Puccioni, M., and Kumar Singh Sr, D.: An atmospheric surface layer study: The Idealized horizontal Planar Array experiment for Quantifying Surface Heterogeneity (IPAQS) , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12081, https://doi.org/10.5194/egusphere-egu2020-12081, 2020.

EGU2020-16201 | Displays | AS2.1

Turbulent transport and deposition of fog droplets in the Central Namib

Robert Spirig, Christian Feigenwinter, and Roland Vogt

Regular, nocturnal fog is a defining and seasonally varying feature in the Namib desert. Historical observations were limited to the binary measure of fog occurrence and the concurrent fog water input is quantified only since 2014 via the FogNet using Juvik fog collectors. This installation opened new avenues of research such as the efficiency of the transport mechanism, sampling and spatial variation thereof. An eddy covariance setup of a cloud droplet probe and collocated sonic(s) was installed in turns at the two FogNet stations Vogelfederberg (23.10°S, 15.03°E, 515 m above sea level) and Gobabeb (23.56°S, 15.04°E, 406 m above sea level) for 2 years in the frame of the Namib Fog Life Cycle Analysis Field Measurements (NaFoLiCA-F) project. With this setup, we gathered duration, droplet size distribution, droplet concentration, liquid water content, turbulent liquid water flux and the fog water input via the Juvik fog collector with a total of over 150 fog events. We found that fog appears suddenly and front-like as seen by an increase of droplet numbers by several magnitudes and dissolves more gradually towards the morning. All droplet classes of the resolved range of 2 to 50 µm are present, but at the Vogelfederberg with around 2 to 3 times larger fog water input, the mean and median of the distribution are lower due to comparably fewer large droplets. Liquid water fluxes at both sites resulted in a net gain for the surface but the spatial discrepancy between fog water input recorded by fog collectors and the liquid water content indicates that drizzle, i.e. droplets outside the resolved range, may contribute to the larger total water deposition at Vogelfederberg.

How to cite: Spirig, R., Feigenwinter, C., and Vogt, R.: Turbulent transport and deposition of fog droplets in the Central Namib, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16201, https://doi.org/10.5194/egusphere-egu2020-16201, 2020.

EGU2020-12121 | Displays | AS2.1

CFD Simulations of Flows in Step-up Street Canyons

Soo-Jin Park, Jae-Jin Kim, Eric Pardyjak, and Ji-Yoon Hong

We analyzed the flow characteristics in strep-up street canyons using a computational fluid dynamics (CFD) model. Simulated results are validated against experimental wind-tunnel results, with the CFD simulations conducted under the same building configurations (Hu/Hd = 0.33, 0.6 and L/S = 1, 2, 3, and 4; Hu, Hd, L, and S respectively indicate the upwind, downwind building heights, the building length and street-canyon width) as those in the wind-tunnel experiments. The CFD model reproduced the in-canyon vortex, recirculation zones above the downwind buildings, and stagnation point position reasonably well. Furthermore, we analyze the flow characteristics in the step-up street canyons based on the numerical results. The in-canyon flows simulated in the shallow (Hu/Hd = 0.33) and deep (Hu/Hd = 0.6) street canyons underwent two stages (development and mature stages) as the building-length ratio increased. In the development stages, one clockwise-rotating vortex was formed in the step-up street canyons and its center was slightly tilted toward the wall of the upwind building. However, in the mature stages, two clockwise-rotating vortices were formed in the upper and lower layers. A clockwise vortex and a counterclockwise vortex were stabilized as the building width ratio increased.

How to cite: Park, S.-J., Kim, J.-J., Pardyjak, E., and Hong, J.-Y.: CFD Simulations of Flows in Step-up Street Canyons , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12121, https://doi.org/10.5194/egusphere-egu2020-12121, 2020.

  In this study, we analyzed the observation environments of the automated synoptic observing systems (ASOSs) using a computational fluid dynamics (CFD) model, focusing on the observational environments of air temperatures, wind speeds, and wind directions. The computational domain sizes are 2000 m × 2000 m × 750 m, and the grid sizes are 10 m × 10 m × 5 m in the x-, y-, and z- directions, respectively. We conducted the simulations for eight inflow directions (northerly, northeasterly, easterly, southeasterly, southerly, southwesterly, westerly, northwesterly) using the ASOS-observation wind speeds and air temperatures averaged in August from 2010 to 2019. We analyzed the effects of the surrounding buildings and terrains on the meteorological observations of the ASOSs, by comparing the wind speeds, wind directions, and air temperatures simulated at the ASOSs with those of inflows. The results showed that the meteorological observation environments were quite dependent on whether there existed the obstacles and surface heating on their surfaces at the observation altitude of the ASOSs.

How to cite: Kang, J.-E. and Kim, J.-J.: Assessment of Observational Environments of the Automated Synoptic Observing Systems in Korea Using a CFD Model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12244, https://doi.org/10.5194/egusphere-egu2020-12244, 2020.

Large-eddy simulations are performed to investigate the effects of background wind on the secondary circulations (SCs) in the convective boundary layer. Heterogeneities are produced by a prescribed two-dimensional surface sensible heat flux pattern of chessboard-type and have a size which is a bit larger than the boundary layer height.

When the wind blows along the diagonal of the chessboard-like pattern, the roll-like SCs are observed even when the background wind speed is as large as 10m/s, with whose axes are oriented along the diagonal of the pattern. Another case with wind direction along neither the diagonal nor the side of the chessboard-like pattern and weak wind speed shows the roll-like SCs still exist but lack symmetry. The SCs become much weaker and change their axes orientation when the wind speed increases.

Meanwhile, the results are different when the Coriolis force is considered. When the background wind is weak, the asymmetry of the SCs become more significant with the development of boundary layer when the Coriolis force is considered, while the SCs tend to be symmetrical without the Coriolis force. When the background wind strengthens, the SCs are more difficult to maintain in the case of Coriolis force.

Further analysis through rotational and divergent decomposition suggests which part contributes more to the maintenance of the SCs.

How to cite: Xiang, Z., Sun, J., and Zou, J.: Characteristics of the secondary circulations in the convective boundary layer over two-dimensional heterogeneous surfaces, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12391, https://doi.org/10.5194/egusphere-egu2020-12391, 2020.

EGU2020-18191 | Displays | AS2.1

Long-term Trend of Planetary Boundary Layer Height in Climate Models and Observations over East Asia

Man Yue and Minghuai Wang

WRF model provides a potentially powerful framework for coupled simulations of flow covering a wide range of
spatial and temporal scales via a successive grid nesting capability. Nesting can be repeated down to turbulence
solving large eddy simulation (LES) scales, providing a means for significant improvements of simulation of
turbulent atmospheric boundary layers. We will present the recent progress on our WRF-LES simulations of
the Perdigao Experiment performed over mountainous terrain. We performed multi-scale simulations using
WRF’s different Planetary Boundary Layer (PBL) parameterizations as well as Large Eddy Simulation (LES)
and compared the results with the detailed field measurements. WRF-LES model improved the mean flow field
as well as second-order flow statistics. Mean fluctuations and turbulent kinetic energy fields from WRF-LES
solution are investigated in several cross-sections around the hill which shows good agreement with measurements.

How to cite: Kirkil, G.: High-resolution atmospheric boundary layer simulations using WRF-LES, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21760, https://doi.org/10.5194/egusphere-egu2020-21760, 2020.

The lowest portion of the planetary boundary layer (PBL), where the turbulent fluxes are assumed to be constant, is known as the atmospheric surface layer (ASL). Within the surface layer, the surface exchange processes play an important role in land-atmosphere interaction. Thus, a precise formulation of the surface fluxes is crucial to ensure an adequate atmospheric evolution by numerical models. The Monin–Obukhov Similarity Theory (MOST) is a widely used framework to estimate the surface turbulent fluxes within the surface layer. MOST uses similarity functions of momentum (φm) and heat (φh) for non-dimensional wind and temperature profiles. Over the years, various formulations for these similarity functions have been proposed by the researchers ranging from linear to non-linear forms. These formulations have limitations in the weak wind, stable, and unstable atmospheric conditions. In the surface layer scheme currently available in the Community Atmosphere Model version 5 (CAM5.0), the stable and unstable regimes are divided into four parts, and the corresponding similarity functions are the functions proposed by Kader and Yaglom (1990) for strong unstable stratification, by Businger et al. (1971) for weak unstable stratification, functions by Dyer (1974) for weak stable stratification, and for moderate to strongly stable stratification, the functions from Holtslag et al. (1990) have been utilized. The criteria used for this classification are somewhat ad-hoc, and there is an abrupt transition between different regimes encountered.            

       In the present study, an effort has been made to implement the similarity functions proposed by Grachev et al. (2007) for stable conditions and Fairall et al. (1996) for unstable conditions in the surface layer scheme of Community Land Model (CLM) for CAM5.0. In the modified version, the similarity functions for unstable conditions are a combination of commonly used Paulson type expressions for near-neutral stratification and an expression proposed by Carl et al. (1973) that takes in to account highly convective conditions. Similarly, the formulation proposed by Grachev et al., for stable conditions, can cover a wider range of stable stratifications. The simulations with CAM5 model using the existing and modified version of surface layer scheme have been performed with 1° resolution for ten years, and the impact of modified functions on the simulation of various important near-surface variables over the tropical region is analyzed. It is found that the scheme with modified functions improving the simulation of surface variables as compared with the existing scheme over the tropical region. In addition, the limitations arbitrarily imposed on particular variables in the existing surface layer scheme can be eliminated or suppressed by using these modified functions.  

References:

Fairall CW, Bradley EF, Rogers DP, Edson JB, Young GS (1996) Bulk parameterization of air-sea fluxes for tropical ocean global atmosphere coupled-ocean atmosphere response experiment. J Geophys Res 101(C2):3747–3764

Grachev, A.A., Andreas, E.L., Fairall, C.W., Guest, P.S. and Persson, P.O.G. (2007a) SHEBA: flux–profile relationships in stable atmospheric boundary layer. Boundary-Layer Meteorology,124, 315–333.

Keywords:

Boundary layer, Turbulence, Climate Model, Surface Fluxes

How to cite: Namdev, P., Sharan, M., and Mishra, S. K.: Sensitivity studies with different formulations for similarity functions used in surface layer scheme, over the tropical region, in a climate model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16539, https://doi.org/10.5194/egusphere-egu2020-16539, 2020.

EGU2020-18036 | Displays | AS2.1

Camera Observation and Modelling of 4D Tracer Dispersion in the Atmosphere

Kerstin Stebel, Massimo Cassiani, Hamidreza Ardeshiri, Cirilo Bernardo, Anna Solvejg Dinger, Arve Kylling, Soon-Young Park, Ignacio Pisso, Norbert Schmidbauer, and Andreas Stohl

In the frame of the COMTESSA (Camera Observation and Modelling of 4D Tracer Dispersion in the Atmosphere) project, tracer dispersion release experiments were performed during three field campaigns in Norway in July 2017, 2018, and 2019.  The main goal of the project is to improve our understanding of turbulence and plume dispersion on local scale in the planetary boundary layer by bringing together full four-dimensional (space and time) observations of a (nearly) passive tracer (sulfur dioxide, SO2), with advanced data analysis and turbulence and dispersion modelling. By means of tomographic reconstruction of the 3D tracer concentration distribution, not only the mean but also higher moments of the probability density function of the tracer concentration field can be revealed. In 2017 first field tests were made, releasing SO2 in continuous plumes and puffs from a 10 m tower, while in the following years SO2 was released from a 60 m tower, located in the centre of a fenced-in 900 m x 400 m wide flat gravel field. The masts were equipped with eddy covariance measurement systems to continuously record turbulent fluxes of heat and momentum during the field campaigns. Up to six ultraviolet (UV) and in 2019 also three infrared (IR) SO2 cameras, were placed in a ring around the SO2 release tower at varying distances up to ~1.2 km to simultaneously image the movement and spread of the 2d integrated SO2 tracer column densities.

Here we present an overview of the field experiments and lessons learned, with focus on results from the 2019 summer campaign. It was a challenge to find a location where hazardous gas could be released and a main obstacle for the imaging-based experiment were the unfavourable weather conditions. Despite these challenges, progress was made throughout the years. During consecutive summers the release equipment was improved and optimized and in 2019 puff releases were made by filling balloons with SO2 and exploding them. The cameras were continuously developed, the setup of the cameras at the site was adjusted to allow observations for longer timescales.  During July 11-28, 2019 ~130 puffs were released from balloons holding between 250 g and 325 g SO2. Those are used to give an overview of the image/data processing and type of results that can be obtained from our observations, e.g. relative dispersion and meandering, Eulerian and Lagrangian integral time scales and their relation, tomographic reconstruction. The focus lies on the plume spread, i.e. relative dispersion processes we recorded under different stability conditions in July 2019.

How to cite: Stebel, K., Cassiani, M., Ardeshiri, H., Bernardo, C., Dinger, A. S., Kylling, A., Park, S.-Y., Pisso, I., Schmidbauer, N., and Stohl, A.: Camera Observation and Modelling of 4D Tracer Dispersion in the Atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18036, https://doi.org/10.5194/egusphere-egu2020-18036, 2020.

EGU2020-21055 | Displays | AS2.1

An approach to detect turbulence coherent structures based on quadrant analysis

Ye Wang, Baomin Wang, and Renzhi Fang

Turbulence coherent structures play an important role in the transport of momentum, sensible heat, water vapour and carbon dioxide fluxes over atmospheric surface layer (ASL) . Using eddy covariance system measurements on a 50m tower in Zengcheng, Guangdong province, we develop a novel method based on quadrant analysis to detect turbulent coherent structures. We presume that turbulent flux events’ durations smaller than threshold t are isotropic turbulence. Therefore, the durations of small-time-scale (duration< t) turbulent flux events of each quadrant are expect to be equal, which can be regarded as the criterion of threshold . A deviation of the similarity between four quadrant small-time-scale turbulent flux events’ durations is set to determine the  value. Contour map of momentum flux joint probability density function on quadrant domain proves our hypothesis. Coherent structures can be identified from large-time-scale (duration>t) turbulent flux events.

We apply this method to the momentum, sensible heat, water vapour and carbon dioxide fluxes and obtain individual turbulent coherent structures time-series of different fluxes. It is found that numbers and durations of turbulent coherent structures are similar. Secondly, threshold  is not sensitive to the change of ASL satiability. Compared with k method (NARASIMHA 2007), our  method stands for more physical background as it can be seen as the time-scale of isotropic turbulence, which makes our detecting method more efficient.

How to cite: Wang, Y., Wang, B., and Fang, R.: An approach to detect turbulence coherent structures based on quadrant analysis, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21055, https://doi.org/10.5194/egusphere-egu2020-21055, 2020.

Dust devils are atmospheric air vortices with a vertical axis, which are formed by strong sun radiation and the resulting vertical temperature gradient. The structure of a typical dust devil is dominated by a radial inflow near the surface and a vertical upward flow within the vortex. Since experimental investigations are limited to local in-situ measurements of the atmosphere, many mechanisms related to their formation and their characteristic properties are insufficiently understood. We will present an idea how dust devils can be generated in a laboratory experiment and how processes, which contribute to their formation, can be investigated.

We have chosen the so-called Rayleigh-Bénard set-up as an appropriate model experiment for our investigations. The "Barrel of Ilmenau" is a test facility, which consists mainly of an air-filled, cylindrical tank with a total diameter of 7 m and a total height of 8 m. At the bottom of the tank is a heating plate, whose temperature can be set precisely between 20°C and 80°C. A second plate, which can be positioned at any height between 0.2m and 6.3m above the heating plate, is used for cooling and can be set to temperatures as low as 10°C...30 °C. This results in a total temperature difference of up to 70K which is significantly beyond the temperature difference of the atmospheric boundary layer. The side wall of the tank is adiabatic. Due to the isothermal plates and a compensation heating system, a temperature that is constant over time is reached and controlled boundary conditions can be assumed.

For the characterization of Dust Devil-like vortices, an optical measurement method is used to obtain the trajectories of single particles. Since there are no commercial systems that are suitable for such a large measurement volume, we created our own system. The measurements in the RB cell are carried out with an aspect ratio Γ=3 and a Ra number of Ra=2x1010 and Ra=8x1010.  With the help of the measurements we want to show that Dust Devil-like vortices are created. The structure should be characterized and the results will be compared to DNS.

How to cite: Lösch, A. and du Puits, R.: Experimental investigation of Dust Devil like vortices with 3D particle tracking velocimetry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22451, https://doi.org/10.5194/egusphere-egu2020-22451, 2020.

EGU2020-25 | Displays | AS2.1

Diurnal and Seasonal Variations of Sensible and Latent Heat Fluxes at an Agricultural Site in Ile-Ife, Southwest Nigeria

Adewale Ajao, Omodara Obisesan, Muritala Ayoola, and Oluwagbemiga Jegede

Diurnal and seasonal variations of sensible heat (H) and latent heat (LE) fluxes observed at an agricultural site on the campus of Obafemi Awolowo University, Ile-Ife, southwest Nigeria have been reported in this paper. The deductions are made based on half-hourly flux data acquired from an open-path eddy covariance (OPEC) system measured continuously over a two-year observation period (2017-2018) at the study site. The study area is within tropical wet and dry climate of West Africa, thereby experiencing an alternating wet (that is, April – October) and dry (that is, December – February) seasons (monsoonal). Our results showed that peak hourly values of H and LE occurred at about 13:00 LT and 14:00 LT respectively, a lag of approximately one hour between them at the location. The diurnal range for H and LE during wet season was 75.3 W m-2 and 177.0 W m-2 respectively, while for dry season it was 182.0 W m-2 and 89.9 W m-2 respectively. The daily mean value of H for wet season was 19.7 ± 27.2 W m-2 and it was 52.1 ± 63.5 W m-2 for LE. For dry season, daily mean values for H and LE were 44.0 ± 66.4 W m-2 and 26.6 ± 33.7 W m-2 respectively. A transition of seasons from wet (Bowen ratio, Bo < 1) to dry (Bo > 1) was observed in November and reversal in March.

 

Keywords: Diurnal and Seasonal Variations, Sensible and Latent Heat Fluxes, Tropical Wet and Dry Climate

How to cite: Ajao, A., Obisesan, O., Ayoola, M., and Jegede, O.: Diurnal and Seasonal Variations of Sensible and Latent Heat Fluxes at an Agricultural Site in Ile-Ife, Southwest Nigeria, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-25, https://doi.org/10.5194/egusphere-egu2020-25, 2020.

AS2.2 – Boundary Layers in High Latitudes: Physics and Chemistry

We examine the representation of Föhn events across the Antarctic Peninsula Mountains during 2011 as they were observed in measurements by an Automatic Weather Station, and in simulations with the Weather Research and Forecasting Model (WRF) as run for the Antarctic Mesoscale Prediction System (AMPS). On the Larsen Ice Shelf (LIS) in the lee of this mountain range Föhn winds are thought to provide the atmospheric conditions for significant warming over the ice shelf thus leading to the initial firn densification and subsequently providing the melt water for hydrofracturing. This process has led to the dramatic collapse of huge parts of the LIS in 1995 and 2002 respectively.

We find that, while the model generally simulates meteorological parameters very well, and shows good skills in capturing the occurrence, frequency and duration of Föhn events realistically, it underestimates the temperature increase and the humidity decrease during the Föhn significantly, and may thus underestimate the contribution of Föhn to driving surface melt on the LIS. Our results indicate that the misrepresentation of cloud properties and particularly the absence of mixed phase clouds in AMPS, affects the quality of weather simulation under normal conditions to some extent, and to a larger extent the model’s capability to simulate the strength of Föhn conditions - and thus their contribution to driving surface melt on the LIS - adequately.

How to cite: Kirchgaessner, A., King, J., and Gadian, A.: The representation of Föhn events to the east of the Antarctic Peninsula in simulations by the Antarctic Mesoscale Prediction System (AMPS), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8728, https://doi.org/10.5194/egusphere-egu2020-8728, 2020.

EGU2020-3043 | Displays | AS2.2

Gravity wave excitation during the coastal transition of an extreme katabatic flow in Antarctica

Étienne Vignon, Ghislain Picard, Claudio Durán-Alarcón, Simon P. Alexander, Hubert Gallée, and Alexis Berne

The offshore extent of Antarctic katabatic winds exert a strong control on sea ice production and the formation of polynyas. In this study, we combine ground-based remotely-sensed and meteorological measurements at Dumont d’Urville (DDU) station, satellite images and simulations with the WRF model to analyze a major katabatic wind event in Adélie Land. Once developed over the slope of the ice sheet, the katabatic flow experiences an abrupt transition near the coastal edge. The transition consists in a sharp increase in the boundary layer depth, a sudden decrease in wind speed and a decrease in Froude number from 3.5 to 0.3. This so-called ‘katabatic jump’ visually manifests as a turbulent ‘wall’ of blowing snow in which updrafts exceed 5 m s −1 . The wall reaches heights of 1000 m and its horizontal extent along the coast is more than 400 km. By destabilizing the boundary-layer downstream, the jump favors the trapping of a gravity wave train  with an horizontal wavelength of 10.5 km. The trapped gravity waves exert a drag that significantly slows down the low-level outflow. Moreover, atmospheric rotors form below the first wave crests. The wind speed record measured at DDU in 2017 (58.5 m s −1 ) is due to the vertical advection of momentum by a rotor. A statistical analysis of observations at DDU reveals that katabatic jumps and low-level trapped gravity waves occur frequently over coastal Adélie Land. It emphasizes the important role of such phenomena in the coastal Antarctic dynamics.

How to cite: Vignon, É., Picard, G., Durán-Alarcón, C., Alexander, S. P., Gallée, H., and Berne, A.: Gravity wave excitation during the coastal transition of an extreme katabatic flow in Antarctica, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3043, https://doi.org/10.5194/egusphere-egu2020-3043, 2020.

EGU2020-3634 | Displays | AS2.2

Influence of sea-ice-derived halogens on atmospheric HOx as observed in springtime coastal Antarctica

Anna Jones, Neil Brough, and Paul Griffiths

We present first observations of OH and (HO2 + RO2) carried out in Antarctica outside the summer season. Measurements were made over 23 days in spring at the coastal Antarctic station Halley. Increases in concentrations were evident during the measurement period due to rapidly increasing solar irradiance, and clear diurnal cycles were present throughout. There were also notable differences in air mass composition depending on wind direction. Air masses that had traversed the sea-ice-zone had both higher concentrations of OH and a larger OH:(HO2 + RO2) ratio. We use steady-state kinetic arguments and a 0-D box model to probe the chemical drivers. We find that differences in bromine chemistry, previously measured at Halley, are sufficient to account for the observed differences in OH concentration as well as the ratio. There is some evidence also that chlorine chemistry is influencing concentrations of RO2.

Sea ice in the polar regions is undergoing considerable change. Our results suggest that changes in the characteristics and extent of the sea-ice-zone that lead to changes in abundance of atmospheric halogens, will also result in a change in OH. For example, a shift towards more new sea ice formation, with its higher salinity over multi-year ice, would be expected to increase the abundance of halogens; conversely, overall reduction in sea ice extent would ultimately reduce abundance of halogens. OH radicals play a key role in oxidation reactions that remove pollutants from the atmosphere. Especially given anticipated expansion of industrial activities in the Arctic, this is a further factor to take into account when considering the wider impacts of sea ice loss.

How to cite: Jones, A., Brough, N., and Griffiths, P.: Influence of sea-ice-derived halogens on atmospheric HOx as observed in springtime coastal Antarctica, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3634, https://doi.org/10.5194/egusphere-egu2020-3634, 2020.

The Biogenic Aerosol and Primary Production in the Ross Sea – BioAPRoS project, funded by funded by the Ministry for the Education, University and Scientific Research (MIUR) through the National Antarctic Research Programme (PNRA) aims to improve the understanding of the ocean-atmosphere interactions with particular attention to the interconnections between oceanic primary production and atmospheric gaseous and particulate compounds. These processes have a strong climatic relevance due to the aerosol interaction with solar radiation, its possible interaction with cloud formation and properties, in a region where other aerosol sources are very limited. To achieve the objectives of the project, measurements and sampling in the atmosphere (dimethylsulfide, in the gas phase, and methanesulfonic acid, sugars, amino acids and methoxyphenols in the aerosols) and in sea water (nutrients, chlorophyll, phytoplankton composition and physiological state, DMSP as a precursor of atmospheric DMS) were carried out simultaneously for the first time at the Italian "Mario Zucchelli" Station (MZS; 74.7°S, 164.1°E).

We report here the data obtained in two Antarctic field campaigns carried out in summers of 2018-19 and 2019-20. The DMS atmospheric concentration was measured directly in situ by Gas Chromatography.  It showed concentrations up to 921 pptv (the highest value obtained in both campaigns); the timing of maximum concentration was strongly related to the timing of sea ice melting in the surrounding oceanic areas. Within the project, the low-cost ACHAB (Antartic low-Cost Hydro Arduino Bio-optic profiler) probe has been developed for the acquisition of physical and bio-optical data along the water column, during the 2019-20 campaign. Furthermore, the Phyto-VFP (Phytoplankton Variable Fluorescence Production) bio-optical model was refined to be applied to the Southern Ocean for the estimation of primary production in Terranova Bay and Ross Sea at micro and mesoscale resolutions, respectively. Phyto-VFP was specifically set-up using as input chl a satellite data (merged products based on MODIS-A, MERIS, SeaWIFS, VIIRS-N for low resolution images and Sentinel-2 for high resolution ones) as well as the photosynthetic parameters obtained from a series of laboratory experiments conducted on polar species, enabling to take into account the effect of a nutrient limitation on their photosynthetic performance.

The evolution of concentration of the atmospheric compounds arising from phytoplankton activity was investigated with respect to oceanic parameters (chlorophyll and primary productivity, in turn related to the phytoplankton taxonomic composition and physiological state), to the variations of solar and photosynthetically active radiation, and to the dynamics of sea ice in the Ross Sea.

Understanding and quantifying the correlation between atmospheric compounds and oceanic primary productivity (affecting the oceanic and atmospheric CO2 budget) has a relevant importance in studies on global change because this interaction is influenced by, and in its turn influences, climatic variations.

How to cite: Becagli, S. and Traversi, R. and the BioAPRoS Team: Preliminary results on the correlation between biogenic aerosol and primary production in the Ross Sea – (PNRA-BioAPRoS Project), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9258, https://doi.org/10.5194/egusphere-egu2020-9258, 2020.

EGU2020-20267 | Displays | AS2.2

Role of dimethyl sulfide on the formation and growth of aerosols, and its impact on liquid clouds in the Arctic summer

Roya Ghahreman, Wanmin Gong, Ann-Lise Norman, Stephen R. Beagley, Ayodeji Akingunola, and Paul A. Makar

Atmospheric dimethyl sulfide, DMS, is the main biogenic source of sulfate particles in the Arctic atmosphere. Sulfate particles have a net cooling effect, which can partially offset Arctic warming from absorbing aerosols, such as black carbon. As efficient cloud condensation nuclei (CCN), sulfate particles are also able to influence the cloud’s microphysical properties. 

DMS production and emission to the atmosphere increase during the Arctic summer, due to a greater ice-free sea surface area and higher biological activity. In the model simulation of a field campaign conducted over the Canadian high Arctic during the summer of 2014 (NETCARE; Abbatt et al. 2019), the inclusion of DMS in the model, GEM-MACH, resulted in a significant increase, up to 100%, in the modelled atmospheric SO2 in some regions of the Canadian Arctic. Analysis of the modelled size-segregated aerosol sulfate indicated that DMS has the most significant impact on particles in the size range of 50 – 200 nm in this case. Simulations have shown that localized regions of high seawater DMS can have a significant impact on atmospheric concentrations.

Further investigation of DMS impact on the Arctic summer cloud microphysics was carried out by using a fully coupled version of GEM-MACH. Overall, the model simulations show that the inclusion of DMS in model leads to an increase in cloud droplet number concentrations (CDNC) and a decrease in droplet mean mass diameters (MMD), and has no significant effects on liquid water content (LWC). The impact of DMS on Canadian weather forecasts will be evaluated using operational forecast tools.

How to cite: Ghahreman, R., Gong, W., Norman, A.-L., Beagley, S. R., Akingunola, A., and Makar, P. A.: Role of dimethyl sulfide on the formation and growth of aerosols, and its impact on liquid clouds in the Arctic summer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20267, https://doi.org/10.5194/egusphere-egu2020-20267, 2020.

EGU2020-9643 | Displays | AS2.2

Evaluating Arctic meteorology modelled with the Unified Model and Integrated Forecasting System

Gillian Young, Jutta Vüllers, Peggy Achtert, Paul Field, Jonathan Day, Ewan O'Connor, Ian Brooks, Michael Tjernström, John Prytherch, and Ryan Neely III

State-of-the-art numerical models such as the UK Met Office Unified Model and European Centre for Medium-Range Weather Forecasting Integrated Forecasting System are crucial tools for forecasting future Arctic warming. However, their ability to reproduce clouds and boundary layer meteorology in the high Arctic has not been thoroughly evaluated following significant model developments over the last 10 years. Model evaluation is key to understanding where remaining process weaknesses lie, thus informing further parametrization developments to improve the simulated surface energy budget.

Here, we evaluate model performance with comparison to observations made during the Arctic Ocean 2018 expedition, where a suite of remote-sensing instrumentation was active aboard the Swedish icebreaker Oden measuring summertime Arctic cloud and boundary layer properties. We find that both models do not reproduce cloud fractions well at altitude (up to 8 km) and overestimate the occurrence of low (<1 km) clouds during the sea ice melt period of the expedition. Low cloud agreement with observations improves when the sea ice begins to refreeze; however, the underestimation of cloud aloft remains consistent regardless of sea ice conditions. In this presentation, we will indicate which model processes need to be improved to capture these summertime Arctic clouds more effectively.

How to cite: Young, G., Vüllers, J., Achtert, P., Field, P., Day, J., O'Connor, E., Brooks, I., Tjernström, M., Prytherch, J., and Neely III, R.: Evaluating Arctic meteorology modelled with the Unified Model and Integrated Forecasting System, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9643, https://doi.org/10.5194/egusphere-egu2020-9643, 2020.

EGU2020-15116 | Displays | AS2.2

The role of air-sea ice-ocean interaction processes for Arctic-midlatitude linkages

Sara Khosravi, Annette Rinke, Wolfgang Dorn, Christof Lüpkes, Vladimir Gryanik, Dmitry Chechin, Ralf Jaiser, and Dörthe Handorf

Climate models have deficits in reproducing Arctic circulation and sea ice development. The air-sea ice-ocean interaction parametrizations could be a potential reason of this shortcoming. In most climate models air-sea ice-ocean interaction are parametrized based on mid-latitude conditions which is not appropriate for polar region. The POLEX project, funded by Helmholtz Association and Russian Science Foundation, is studying the impact of improved representation of Arctic air-sea ice-ocean interaction on changes in Arctic atmospheric circulation and Arctic-midlatitude linkages. We have used a new suite of parametrizations, which are easily applicable for climate simulations and have been developed based on SHEBA expedition data by Gryanik and Lüpkes (2018). We implemented the new parametrizations in the global atmospheric model (ECHAM6) in the framework of POLEX to estimate its effect on regional Arctic and large-scale circulation changes. Several steps have been defined for implementing the new parameterization to be able to distinguish and understand better the impact of its parameters. Roughness length and stability functions for stable stratification have been modified. Here the initial results of ECHAM6 sensitivity runs for different steps of the parameterization will be presented. We will present first results from process-oriented evaluation over the Arctic sea ice, e.g. how is the impact on the simulation of the two states of the Arctic boundary layer in winter. Furthermore, we will show that the large-scale circulation reacts to the new parametrization in different months and years differently.
Reference:
Gryanik, V.M. and C. Lüpkes (2018) An efficient non-iterative bulk parametrization of surface fluxes for stable atmospheric conditions over polar sea-ice, Boundary-Layer Meteorol., 166, 301-325

How to cite: Khosravi, S., Rinke, A., Dorn, W., Lüpkes, C., Gryanik, V., Chechin, D., Jaiser, R., and Handorf, D.: The role of air-sea ice-ocean interaction processes for Arctic-midlatitude linkages, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15116, https://doi.org/10.5194/egusphere-egu2020-15116, 2020.

EGU2020-10670 | Displays | AS2.2

Analyzing Near Surface Temperature Inversions Across the Greenland Ice Sheet Using In-situ, Remote Sensing, and Reanalysis Data

Alden Adolph, Wesley Brown, Karina Zikan, and Robert Fausto

As Arctic temperatures have increased, the Greenland Ice Sheet has exhibited a negative mass balance, with a substantial and increasing fraction of mass loss due to surface melt. Understanding surface energy exchange processes in Greenland is critical for our ability to predict changes in mass balance. In-situ and remotely sensed surface temperatures are useful for monitoring trends, melt events, and surface energy balance processes, but these observations are complicated by the fact that surface temperatures and near surface air temperatures can significantly differ due to the presence of inversions that exist across the Arctic. Our previous work shows that even in the summer, very near surface inversions are present between the 2m air and surface temperatures a majority of the time at Summit, Greenland. In this study, we expand upon these results and combine a variety of data sources to quantify differences between surface snow/ice temperatures and 2m air temperatures across the Greenland Ice Sheet and investigate controls on the magnitude of these near surface temperature inversions. In-situ temperatures, wind speed, specific humidity, and albedo data are provided from automatic weather stations operated by the Programme for Monitoring of the Greenland Ice Sheet (PROMICE). We use the Clouds and the Earth's Radiant Energy System (CERES) cloud area fraction data to analyze effects of cloud presence on near surface temperature gradients. The in-situ temperatures are compared to Modern-Era Retrospective analysis for Research and Applications Version 2 (MERRA-2) and Moderate Resolution Imaging Spectrometer (MODIS) ice surface temperature data to extend findings across the ice sheet. Using PROMICE in-situ data from 2015, we find that these 2m temperature inversions are present 77% of the time, with a median strength of 1.7°C. The data confirm that the presence of clouds weakens inversions. Initial results indicate a RMSE of 3.9°C between MERRA-2 and PROMICE 2m air temperature, and a RMSE of 5.6°C between the two datasets for surface temperature. Improved understanding of controls on near surface inversions is important for use of remotely sensed snow surface temperatures and for modeling of surface mass and energy exchange processes.

How to cite: Adolph, A., Brown, W., Zikan, K., and Fausto, R.: Analyzing Near Surface Temperature Inversions Across the Greenland Ice Sheet Using In-situ, Remote Sensing, and Reanalysis Data , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10670, https://doi.org/10.5194/egusphere-egu2020-10670, 2020.

EGU2020-15227 | Displays | AS2.2

Contribution of turbulent heat fluxes to surface ablation on the Greenland ice sheet.

Maurice Van Tiggelen, Paul Smeets, Carleen Reijmer, Brice Noël, Jakob Steiner, Emile Nieuwstraten, Walter Immerzeel, and Michiel van den Broeke

Over ice sheets and glaciers, the turbulent heat fluxes are, next to the radiative fluxes, the second largest source of energy driving the ablation. In general, most (climate) models use a bulk turbulence parametrization for the estimation of these energy fluxes. Recent work suggest that the turbulent heat fluxes might be greatly underestimated by such models. Unfortunately, only a few direct and long-term observations of turbulent fluxes are available over ice sheets to evaluate their inclusion in models. 

In this study, we developed a vertical propeller eddy-covariance method to continuously monitor the sensible heat fluxes over the Greenland ice sheet (GrIS). We quantify its contribution to surface ablation using three years of data from the K-transect, located in the western ablation area of the GrIS. The direct flux measurements are also compared to those from several bulk turbulence models, and to a high-resolution regional climate model (RACMO2), in order to quantify modelling uncertainty.

The differences between observations and models highlight the need for upgrading the bulk turbulence parameterizations and especially the model parameters, such as the surface roughness lengths. We also find that during short but extreme warm events, the turbulent heat fluxes become the largest source for surface ablation. Typical for such intense events on the K-transect are fast changes in wind direction, which cause changes in the surface roughness parameters due to the anisotropic feature of the ice hummocks. These parameters are critical for modelling the turbulent fluxes in bulk parameterizations, but are often variable and unknown. We conclude with drone topography measurements to better constrain the surface roughness locally, and discuss methods to improve the modelling of turbulent surface fluxes on the whole GrIS.

How to cite: Van Tiggelen, M., Smeets, P., Reijmer, C., Noël, B., Steiner, J., Nieuwstraten, E., Immerzeel, W., and van den Broeke, M.: Contribution of turbulent heat fluxes to surface ablation on the Greenland ice sheet., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15227, https://doi.org/10.5194/egusphere-egu2020-15227, 2020.

EGU2020-2005 | Displays | AS2.2

The Boundary Layer and its Response to External Forcing at Summit Station Greenland

William Neff, Christopher Cox, and Mathew Shupe

The ICECAPS field program (Integrated Characterization of Energy, Clouds, Atmospheric State and Precipitation at Summit) has operated at Summit Station (over 3000 m ASL) since the spring of 2010 with a broad range of instruments to study the role of clouds and precipitation over the Greenland Ice Sheet (GIS).  In addition, a high-resolution minisodar has been operated nearby since 2008 (initially as part of an ice-atmosphere chemical exchange study).  The sodar provides detailed views of the thermodynamic structure of the boundary layer from 2 to 160 m above the surface. Several other collaborating programs support additional boundary-layer measurements such as broadband radiation and turbulent flux measurements. The sodar has proven useful in the interpretation of chemical interactions with the snow surface and underlying firn as well as comparisons of boundary layer depth estimators (Van Dam et al, 2013, 2015).  In addition it has documented the response of the boundary layer to changing cloud forcing (Shupe et al. 2013).  In addition, it has been used to study the wintertime boundary layer with super-cooled fog layers present (Cox et al, 2019).  Additional observations have added to an already rich data set, such as those of stable water vapor isotopes (e.g. Berkelhammer et al. 2016). 

As in the 2012 melt episode that encompassed nearly the entire ice sheet, atmospheric rivers (ARs) bring moisture from the south along the coasts of Greenland and have been increasing (Mattingly et al., 2018; Neff 2018).  We will present a climatology from 2000 to 2012 of ARs some of which are associated with increased transport of moisture from the subtropics at times in concert with hurricanes and tropical storms that follow the same path.  This climatology reveals a distinct low-high pressure pattern spanning from NE Canada to the central Atlantic: the boundary between these systems provides the pathway for moisture to flow from the subtropics.  In this presentation will describe the characteristic cloud/clear skies sequence and accompanying boundary layer structure at Summit Station during these events.  A typical sequence is one of ARs trapped along the west coast and then spreading moisture over the GIS in subsequent days.

To understand the origin of the moisture arriving at Summit Station we also carried out back trajectory analyses that show connections to both ARs and extratropical remnants of hurricanes that follow the same path to Greenland.  Of particular interest will be the boundary layer behavior during the dramatic melt episodes of June and then July 2019 that had their origins in heat waves off of Africa and over Europe. 

 

How to cite: Neff, W., Cox, C., and Shupe, M.: The Boundary Layer and its Response to External Forcing at Summit Station Greenland, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2005, https://doi.org/10.5194/egusphere-egu2020-2005, 2020.

EGU2020-18102 | Displays | AS2.2

Large Eddy Simulations of the Arctic atmospheric boundary layer around the MOSAiC drift track

Daniela Littmann, Wolfgang Dorn, Hélène Bresson, Marion Maturilli, and Markus Rex

The Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) is the largest one-year-long research expedition within the central Arctic and has started in September 2019 to gather comprehensive climate data from an almost unreachable region. The gathered observational data in combination with concurrent high-resolution modeling provide new insights that play a key role for the improvement of our understanding of the interaction processes between the atmosphere, ocean, and sea ice and eventually global climate change. The present study focuses on the influence of the surface conditions on the atmospheric boundary layer by applying the large eddy simulation model configuration of the icosahedral non-hydrostatic model (ICON-LES). ICON-LES is used here with a grid spacing between 50 m and 800 m and set up to a domain with radii of 10 km to 100 km around the MOSAiC drift track. The model is driven by output data from weather forecast simulations for selected stormy and rather calm days. Results of simulations with various spatial horizontal resolutions and with different surface conditions such as ice fraction, ice thickness, snow cover will be compared and evaluated against observational data from MOSAiC.

How to cite: Littmann, D., Dorn, W., Bresson, H., Maturilli, M., and Rex, M.: Large Eddy Simulations of the Arctic atmospheric boundary layer around the MOSAiC drift track, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18102, https://doi.org/10.5194/egusphere-egu2020-18102, 2020.

EGU2020-19187 | Displays | AS2.2

New modified and extended stability functions for the stable boundary layer based on SHEBA data

Vladimir M. Gryanik, Andrey Grachev, Christof Lüpkes, and Dmitry Sidorenko

The calculation of the near-surface turbulent fluxes of energy and momentum in climate and weather prediction models requires transfer coefficients. Currently used parametrizations of these coefficients are based on stability functions derived from measurements over land and not over sea ice. However, recently, a non-iterative parametrization has been proposed by Gryanik and Lüpkes (2018), which can be applied to climate and weather prediction models as well but uses stability functions of Grachev et al. (2007). These functions had been obtained from measurements during the Surface Heat Budget over the Arctic Ocean campaign (SHEBA) and thus from measurements over sea ice. A drawback of the scheme of Gryanik and Lüpkes (2018) is that there is still some complexity due to the complexity of the SHEBA based functions.

Thus new stability functions are proposed for the stable boundary layer, which are also based on the SHEBA measurements but avoid the complexity. It is shown that the new functions are superior to the former ones with respect to the representation of the measured relationship between the Obukhov length and the bulk Richardson number. Moreover, the resulting transfer coefficients agree slightly better with the SHEBA observations in the very stable range. Nevertheless, the functions fulfill the same criteria of applicability as the earlier functions and contain furthermore as an extension a dependence on the neutral Prandtl number. Applying the new functions, an efficient non-iterative parametrization of the near-surface turbulent fluxes of momentum and heat is developed where transfer coefficients result as a function of the bulk Richardson number (Rib) and roughness parameters. The new transfer coefficients, which are recommended for weather and climate models, agree well with the SHEBA data in a large range of stability (0< Rib<0.5) and with those based on the Dyer-Businger functions in the range Rib <0.08.

References

Grachev A.A., Andreas E.L, Fairall C.W., Guest P.S., Persson POG (2007) Boundary-Layer Meteorol., 124, 315–333.

Gryanik, V.M. and Lüpkes C. (2018) An Efficient Non-iterative Bulk Parametrization of Surface Fluxes for Stable Atmospheric Conditions Over Polar Sea-Ice,Boundary-Layer Meteorol 166:301-325

How to cite: Gryanik, V. M., Grachev, A., Lüpkes, C., and Sidorenko, D.: New modified and extended stability functions for the stable boundary layer based on SHEBA data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19187, https://doi.org/10.5194/egusphere-egu2020-19187, 2020.

EGU2020-22372 | Displays | AS2.2

Dependency of the turbulent heat exchange over polar leads on the lead width – an LES study

Micha Gryschka, Xu Zhou, and Matthias Sühring

Leads are Chanel-like openings in the sea-ice through which heat of several 100 Watt/m2 is transferred from the ocean into the atmosphere. Even though leads account only for a view percent to the total ice coverage in polar regions, they modify the polar boundary layer significantly. Therefore, leads need to be considered in numerical weather and climate models. Since, generally leads are not explicitly resolved in these models it is important to understand the overall effect of leads of different sizes onto the boundary layer for different meteorological conditions.

With numerous Large-Eddy Simulations we investigated the dependency of the lead averaged surface heat flux on the lead width in a range between 50 m and 25 000 m for different meteorological conditions. Generally, we found under same temperature differences between ice and water and same meteorological conditions an increase of the the lead averaged heat flux with increasing lead width by more then 200% for some situations. We like to give some brief explanations of the possible causes for this behavior as well as to oppose these results to other former studies in this field, which might disagree to them in some points.

How to cite: Gryschka, M., Zhou, X., and Sühring, M.: Dependency of the turbulent heat exchange over polar leads on the lead width – an LES study , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22372, https://doi.org/10.5194/egusphere-egu2020-22372, 2020.

EGU2020-7849 | Displays | AS2.2

Wintertime Arctic Air Pollution over Alaska

Eleftherios Ioannidis, Kathy Law, Jean-Christophe Raut, Tatsuo Onishi, William R. Simpson, Rachel M. Kirpes, and Karri A. Pratt

The Arctic is influenced by long-range transport of aerosols, for example, sulphate, black carbon, and dust from mid-latitude emissions, especially in winter and spring, leading to the formation of Arctic Haze with enhanced aerosol concentrations. However, more recently, local sources of aerosols, such as wood-burning or resource extraction, are highlighted as already being important, but many uncertainties about sources and aerosol processes still remain. For example, the formation of secondary aerosols, such as sulphate, in winter despite very low temperatures and the absence of sunlight.

In this study, which contributes to the international PACES-ALPACA initiative, the Weather Research Forecasting (WRF) and WRF-Chem models are used to investigate wintertime pollution over Alaska with a focus on regions influenced by local pollution, such as Fairbanks and by Arctic Haze, such as Utqiagvik (formerly known as Barrow). Fairbanks is the most polluted city in the United States during wintertime due to high emissions and the occurrence of strong surface temperature inversions.

As a first step, background aerosols originating from remote sources were evaluated in large- scale quasi-hemispheric WRF-Chem runs using ECLIPSE anthropogenic emissions. The model performs quite well over Alaska at background sites (e.g. Denali Park) compared to observations from the US Environmental Protection Agency (EPA). Discrepancies in modelled aerosols due to formation mechanisms and aerosol acidity are being investigated.

Secondly, in order to better simulate Arctic aerosols and local pollution episodes, different schemes in WRF were tested over Alaska with a particular focus on improving simulations of the Arctic boundary layer structure and, in particular, wintertime temperature inversions which trap pollution at the ground. In order to simulate these extreme/cold meteorological conditions, different schemes linked to boundary layer physics, surface layer dynamics and the land surface have been tested and evaluated against Integrated Global Radiosonde Archive (IGRA2) and Integrated Surface Database (ISD). The model captures the cold meteorological conditions over Alaska, for example, capturing strong temperature inversions over Utqiagvik and Fairbanks in winter 2012.

Thirdly, WRF-Chem is used to simulate background and local Arctic air pollution, using the improved WRF setup for meteorology over Alaska for winter 2013-2014. The model is being run with Hemispheric Transport of Air Pollution version 2 (HTAP v2) and other high-resolution emission inventories and evaluated against available aerosol data (PM2.5, black carbon, sulphate) over Alaska including data on aerosol chemical properties. The model is used to examine aerosol composition in locally produced and remote aerosols and to identify the origins contributing to aerosol distributions. The sensitivity of modelled aerosols to, for example, meteorological factors, such as humidity, is examined.

How to cite: Ioannidis, E., Law, K., Raut, J.-C., Onishi, T., Simpson, W. R., Kirpes, R. M., and Pratt, K. A.: Wintertime Arctic Air Pollution over Alaska, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7849, https://doi.org/10.5194/egusphere-egu2020-7849, 2020.

 Using 28-year satellite-borne Special Sensor Microwave Imager observations, features of high-wind frequency (HWF) over

the southern Indian Ocean are investigated. Climatology maps show that high winds occur frequently during austral winter,

located in the open ocean south of Polar Front in subpolar region, warm flank of the Subantarctic Front between 55oE-78oE, 

and south of Cape Agulhas, where westerly wind prevails. The strong instability of marine atmospheric boundary layer

accompanied by increased sensible and latent heat fluxes on the warmer flank acts to enhance the vertical momentum mixing,

thus accelerate the surface winds. Effects of sea surface temperature (SST) front can even reach the entire troposphere

by deep convection. HWF also shows distinct interannual variability, which is associated with the Southern Annual Mode

(SAM). During positive phase of the SAM, HWF has positive anomalies over the open ocean south of Polar Front, while

has negative anomalies north of the SST front. A phase shift of HWF happened around 2001, which is likely related to the

reduction of storm tracks and poleward shift of westerly winds in the Southern Hemisphere.

How to cite: Cheng, X.: The impact of SST front on the surface wind in the southern Indian Ocean, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7987, https://doi.org/10.5194/egusphere-egu2020-7987, 2020.

AS2.8 – Clouds, moisture, and precipitation in the Polar Regions: Sources, processes and impacts

EGU2020-2850 | Displays | AS2.8

Microphysics of Antarctic precipitation in climate models : recent advances and challenges

Étienne Vignon, Josué Gehring, Simon P. Alexander, Georgia Sotiropoulou, Nikola Besic, Nicolas Jullien, Noémie Planat, Jean-Baptiste Madeleine, and Franziska Gerber

The current assessment of the Antarctic surface mass balance mostly relies on reanalysis products or climate model simulations. The ability of models to reproduce the precipitation field at the regional and continental scales not only depends on the simulation of the atmospheric dynamics over the Southern Ocean and of the advection of moisture towards the ice sheet, but also on the representation of the microphysical processes that govern the formation and growth of ice crystals and snowflakes. This presentation reviews recent studies to stress the importance and challenges of evaluating the precipitation microphysics over Antarctica in climate models. It also discusses how recent observational campaigns including ground-based remote-sensing instruments can help pinpoint key processes that should be represented in models. We then present tangible examples of evaluation and improvement of microphysical schemes in the Polar WRF model thanks to radar and lidar observations acquired near Dumont d’Urville and Mawson stations on the Antarctic coast. Particular attention is devoted to three processes : i) the sublimation of snowfall within the katabatic layer that considerably reduces the amount of precipitation that actually reaches the surface ; ii) the snowflake aggregation responsible for rapid depletion of crystals within clouds ; iii) the generation of supercooled liquid water in frontal clouds that leads to crystal/snowflake riming. Such studies, albeit preliminary, could pave the way for further evaluations of clouds and precipitation in climate models in different Antarctic contexts, especially in the cold and pristine atmosphere of the Plateau.

How to cite: Vignon, É., Gehring, J., Alexander, S. P., Sotiropoulou, G., Besic, N., Jullien, N., Planat, N., Madeleine, J.-B., and Gerber, F.: Microphysics of Antarctic precipitation in climate models : recent advances and challenges, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2850, https://doi.org/10.5194/egusphere-egu2020-2850, 2020.

EGU2020-2603 | Displays | AS2.8

DACAPO-PESO: Remote Sensing and In-situ Observations in Sub-Antarctica (53°S,71°W) to Enhance the Understanding of Aerosol-Moisture-Cloud-Precipitation Interaction

Heike Kalesse, Patric Seifert, Martin Radenz, Johannes Bühl, Teresa Vogl, Willi Schimmel, Andreas Foth, Audrey Teisseire, Holger Baars, Ronny Engelmann, Boris Barja, Jonas Witthuhn, Frank Stratmann, Albert Ansmann, and Felix Zamorano

The southern midlatitudes and Sub-Antarctica are a key region for the Earth’s climate and a source for uncertainties in climate modelling. The low concentration of ice nucleating particles is considered to diminish the efficiency of heterogeneous ice formation. Climate models underestimate the supercooled liquid water content which causes shortwave radiation biases.

The project DACAPO-PESO (Dynamics, Aerosol, Cloud And Precipitation Observations in the Pristine Environment of the Southern Ocean) which is being conducted in Punta Arenas (53°S, 71°W), Chile from Nov 2018 – March 2020 is endorsed by YOPP (Year of Polar Prediction) and fills an observational gap in the Southern Oceans, for which to date hardly any combined observations of lidar, cloud radar and microwave radiometer are available.

During that field experiment, LACROS (Leipzig Aerosol and Cloud Remote Observations System) of Leibniz Institute for Tropospheric Research (TROPOS) which comprises numerous remote sensing instruments, including multi-wavelength polarization Raman lidar, cloud radars, microwave radiometer, radiation sensors among others is deployed. From March 2019 onwards, additionally in-situ observations of the INP and cloud condensation nuclei properties were collected by TROPOS on a 623m high mountain 10 km upwind of the LACROS site. Meso-scale numerical modeling will provide support for interpretation of the results.

The presentation will be dedicated to

How to cite: Kalesse, H., Seifert, P., Radenz, M., Bühl, J., Vogl, T., Schimmel, W., Foth, A., Teisseire, A., Baars, H., Engelmann, R., Barja, B., Witthuhn, J., Stratmann, F., Ansmann, A., and Zamorano, F.: DACAPO-PESO: Remote Sensing and In-situ Observations in Sub-Antarctica (53°S,71°W) to Enhance the Understanding of Aerosol-Moisture-Cloud-Precipitation Interaction, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2603, https://doi.org/10.5194/egusphere-egu2020-2603, 2020.

EGU2020-12003 | Displays | AS2.8 | Highlight

Understanding moisture transport associated with strong cyclones in the New Arctic

Linette Boisvert, Mircea Grecu, and Chung-Lin Shie

The Arctic climate system is undergoing rapid and drastic change in recent decades, with the thinning and loss of sea ice coverage and a warming and moistening atmosphere since the 2000’s; coining the term the ‘New Arctic’. This New Arctic ice pack is more vulnerable to external forcings, and with the increase in open water and warmer temperatures it is suggested that this could impact the moisture transport into the Arctic. In fact, all aspects of the hydrologic cycle are likely affected by and also feedback on these large and rapid changes in the New Arctic. However, the majority of the precipitation and moisture transported into the Arctic Ocean is that associated with cyclones, but one caveat is that the true magnitude of precipitation during these events remain uncertain, and a better understanding of the intensity, frequency, and phase of this precipitation is critically needed specifically for the freshwater and energy budget of the New Arctic.

 

Our work aims to track the moisture and precipitation associated with strong cyclones that terminate in the Arctic in order to improve our knowledge of the frequency, intensity and phase of the moisture, how and if it is changing in the New Arctic on an annual, seasonal and regional basis. In order to do this we will create a database of strong Arctic cyclone trajectories and Lagrangian track the moisture associated with them using ERA-Interim reanalysis. To balance the moisture budget we will constrain the net precipitation using NASA GPM precipitation and AIRS evaporation data at each time step. We propose a novel approach to achieve a more comprehensive, balanced moisture transport associated with Arctic cyclones in an Optimal Estimation and Lagrangian Framework (OELaF) allowing for the fundamental moisture processes associated with Arctic cyclones to be better observed and investigated. In this new work, we plan to apply this method with a few cyclones in the winter months of 2015-2017.

 

How to cite: Boisvert, L., Grecu, M., and Shie, C.-L.: Understanding moisture transport associated with strong cyclones in the New Arctic , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12003, https://doi.org/10.5194/egusphere-egu2020-12003, 2020.

EGU2020-209 | Displays | AS2.8

Cloud ice processes enhance spatial scales of organization in Arctic stratocumulus

Gesa Eirund, Ulrike Lohmann, and Anna Possner

Around the globe, clouds tend to organize into cellular patterns. This phenomenon has gained growing attention in recent years, mainly due to albedo changes associated with different cloud regimes. Transitions between cloud regimes can be impacted by environmental factors such as tropospheric moisture content, large-scale subsidence, surface temperature and the ambient aerosol concentration or, more locally, precipitation formation, turbulence and boundary layer characteristics. It has been suggested that cold pool formation caused by evaporative cooling of precipitation can induce small-scale overturning circulations that promote cloud cell growth in open-cell stratocumulus clouds.

Cloud organization has so far been primarily studied for the subtropical trade wind region or deep convective clouds. In the mid and high latitudes organized cloud structures have been attributed to frontal systems in low pressure systems or cold air outbreaks. However, cloud patterns are also observed away from these large-scale phenomena in the higher latitudes. As low-level clouds in the high latitudes are mostly mixed-phase, various processes can shape cloud formation, occurrence and breakup. Processes related to the ice phase remain poorly understood and especially with regard to cloud organization remain completely unexplored.

In cloud-resolving model simulations using COSMO-LES we investigate the processes driving organization in open-cell mixed-phase stratocumuli. Similar to warm-phase clouds, MPCs develop a sub-cloud circulation caused by evaporated/sublimated precipitation, cold pool formation, and consecutive updrafts driving new convective cells. For a larger ice to liquid water ratio, we find locally stronger precipitation and larger cloud cells. Hence, a higher concentration of ice nucleating particles can induce a breakup of the stratocumulus organization, with implications for the radiative balance at the surface. A decrease in cloud condensation nuclei concentration is also found to intensify precipitation and impact cloud organization.

How to cite: Eirund, G., Lohmann, U., and Possner, A.: Cloud ice processes enhance spatial scales of organization in Arctic stratocumulus, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-209, https://doi.org/10.5194/egusphere-egu2020-209, 2020.

EGU2020-6138 | Displays | AS2.8

Large Graupel Produced by Thin Clouds in the Arctic

Kyle Fitch, Tim Garrett, and Ahmad Talaei
Riming is a critical process for both numerical modeling and microwave remote sensing because of the significant changes to hydrometeor shape and density that occur. Basic continuous collection theory invokes a simple model that assumes a relatively large, massive graupel falls through a homogeneous field of much smaller, suspended supercooled droplets in still air. However, numerous studies have shown that turbulence enhances the rate of collisions between liquid droplets, and even more so for graupel-droplet collisions. Modeling and observational studies of turbulence-induced riming enhancement have all focused on convective clouds with relatively large dissipation rates. Here we combine theoretical work on the analytical solutions of precipitation size distributions with observations and simulations of Arctic graupel to show that this enhancement is common in “thin” Arctic boundary layer clouds with LWP<50gm-2. The median enhancement of rime mass over that expected from continuous collection ranges from 6.4 to 10.7 (for collection efficiencies ranging from 1 to 0.6) for 1,628 carefully selected graupel falling from thin clouds. Analytical solutions for precipitation size distributions imply that average updraft speed must be approximately one-third of particle settling speed to explain the enhancement quantitatively using bulk cloud and precipitation measurements. Analysis of an 8-day thin cloud case revealed that the two days of thin-cloud graupel occurred in conjunction with boundary layer capping inversions that were significantly weaker than on other days of the period. These graupel days were also preceded by boundary layer profiles indicating two days of very strong cloud top radiative cooling – implying that this generated a mixed layer that eroded the capping inversion. Finally, 1-D Lagrangian simulations of graupel settling in turbulent flow show that the particles spend more time in strong updrafts where riming time increases to a significant degree. These findings challenge the current understanding of riming growth and extent turbulence-induced collision enhancement to thin mixed-phase boundary layer clouds in the Arctic. Such enhanced riming leads to increased bulk density of precipitation particles and is therefore expected have strong implications for cloud lifecycles and corresponding radiative balance in the Arctic.

How to cite: Fitch, K., Garrett, T., and Talaei, A.: Large Graupel Produced by Thin Clouds in the Arctic, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6138, https://doi.org/10.5194/egusphere-egu2020-6138, 2020.

EGU2020-1735 | Displays | AS2.8

Seasonal Variations of Arctic Low‐Level Clouds and Its Linkage to Sea Ice Seasonal Variations

Yueyue Yu, Patrick Taylor, and Ming Cai

Using CALIPSO‐CloudSat‐Clouds and the Earth's Radiant Energy System (CERES)‐Moderate Resolution Imaging Spectrometer (MODIS) (C3M) dataset, this study documents the seasonal variation of sea ice, cloud, and atmospheric properties in the Arctic (70°N–82°N) for 2007–2010. A surface type stratification—consisting Permanent Ocean, Land, Permanent Ice, and Transient Sea Ice—is used to investigate the influence of surface type on low-level Arctic cloud liquid water path (LWP) seasonality. The results show significant variations in the Arctic low-level cloud LWP by surface type linked to differences in thermodynamic state. Subdividing the Transient Ice region (seasonal sea ice zone) by melt/freeze season onset dates reveals a complex influence of sea ice variations on low cloud LWP seasonality. We find that lower tropospheric stability (LTS) is the primary factor affecting the seasonality of cloud LWP. Our results suggest that variations in sea ice melt/freeze onset have a significant influence on the seasonality of low-level cloud LWP by modulating the lower tropospheric thermal structure and not by modifying the surface evaporation rate in late spring and mid-summer. We find no significant dependence of the May low-level cloud LWP peak on the melt/freeze onset dates, whereas and September/October low-level cloud LWP maximum shifts later in the season for earlier melt/later freeze onset regions. The Arctic low cloud LWP seasonality is controlled by several surface-atmosphere interaction processes; the importance of each varies seasonally due to the thermodynamic properties of sea ice. Our results demonstrate that when analyzing Arctic cloud-sea ice interactions, a seasonal perspective is critical.

How to cite: Yu, Y., Taylor, P., and Cai, M.: Seasonal Variations of Arctic Low‐Level Clouds and Its Linkage to Sea Ice Seasonal Variations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1735, https://doi.org/10.5194/egusphere-egu2020-1735, 2020.

EGU2020-20244 | Displays | AS2.8

Moisture sources for Greenland ice core sites: Seasonality and land/ocean contributions

Anne-Katrine Faber, Harald Sodemann, and Hans Christian Steen-Larsen
The interpretation of the climate ice core isotope signal relies on the knowledge on the underlying moisture transport and variability hereof. From ice core records from Greenland and Antarctica we have access to unique climate archives that provide knowledge of past climate changes and variability.  Availability of water vapor, formation of clouds and precipitation are all essential for shaping the radiative and hydrological conditions of the polar climate system. Understanding the mean state and the spatiotemporal variability of moisture transport towards the polar ice sheets is thus vital for exploring moisture and cloud processes affecting the energy and surface mass balance of the Greenland Ice sheet.   
 

This study identifies moisture sources for  both Greenland precipitation and near-surface vapor using a combination of backward trajectories and moisture source diagnostics. Using the Lagrangian moisture source diagnostic WaterSip, based on a global transport climatology calculated with the FLEXPART model, and spanning the entire ERA-Interim dataset, we identify Greenland moisture sources for present-day conditions (1980-2018). We focus on six deep ice core sites and identify the key moisture source areas and their patterns of variability. The role of land vs. ocean moisture sources are investigated, with a particular focus on land sources from North America and Greenland. Further, we evaluate moisture transport in relation to Greenland ice core isotopic composition observations of snow and ice, and explore how moisture sources of precipitation and near-source vapor can differ.

Results show that the deep ice core sites have different spatial patterns of moisture sources. Seasonality is important and large spatial variability with season exists due to precipitation seasonality.  Land-sources are found to be dominating the full moisture uptake budget during summer for some ice core sites.Differences are found between transport patterns for sources of near-surface vapor and sources of precipitation at the same site. This finding highlight that sources and transport of  respectively near-surface moisture and precipitation at the Greenland Ice Sheet are not necessarily comparable.  This suggest that the atmospheric drivers and variability of moisture sources over the Greenland Ice Sheet  can be different for near-surface vapor and precipating clouds at higher altitudes.  This is relevant for a better understanding of  isotope surface processes  related to how the climate signal gets imprinted in the snow. Furthermore these results elucidate the mean state and variability of Greenland moisture sources at different altitudes above the ice surface. This analysis of drivers of Greenland moisture transport therefore contribute to the understanding on how moisture variability influences the energy budget and  surface mass balance of the Greenland Ice sheet. 

 

How to cite: Faber, A.-K., Sodemann, H., and Steen-Larsen, H. C.: Moisture sources for Greenland ice core sites: Seasonality and land/ocean contributions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20244, https://doi.org/10.5194/egusphere-egu2020-20244, 2020.

EGU2020-506 | Displays | AS2.8

Atmospheric Rivers over the Arctic with the ICON model

Hélène Bresson, Annette Rinke, Vera Schemann, Susanne Crewell, Carolina Viceto, and Irina Gorodetskaya
The Arctic climate changes faster than the ones of other regions, but the relative role of the individual feedback mechanisms contributing to Arctic amplification is still unclear. Atmospheric Rivers (ARs) are narrow and transient river-style moisture flows arriving from the sub-polar regions. The
integrated water vapour transport associated with ARs can explain up to 70% of the precipitation variance north of 70°N. However, there are still un-
certainties regarding the specific role and the impact of ARs on the Arctic climate variability.
For the first time, the high-resolution ICON modelling framework is used over the Arctic region (from 13 km down to ca. 6 and 3 km) to investigate processes related with anomalous moisture transport into the Arctic. Based on a case study for Svalbard, the representation of the atmospheric circulation and the spatio-temporal structure of water vapour, temperature, and precipitation and snowfall within the limited-area mode (LAM) of the ICON model is assessed. Preliminary results show that the moisture intrusion is relatively well represented in the ICON-LAM simulations. The impact on the surface energy budget will also be calculated.

How to cite: Bresson, H., Rinke, A., Schemann, V., Crewell, S., Viceto, C., and Gorodetskaya, I.: Atmospheric Rivers over the Arctic with the ICON model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-506, https://doi.org/10.5194/egusphere-egu2020-506, 2020.

EGU2020-12989 | Displays | AS2.8

Poleward moisture transport and its influence on precipitation in the Arctic: From case studies to long-term statistics

Melanie Lauer, Annette Rinke, Irina Gorodetskaya, and Susanne Crewell

There are many factors which could contribute to the Arctic warming: feedback processes like the lapse rate and ice-albedo feedback, the increasing downward longwave radiation caused by clouds and water vapour, and the reduction of sea ice in summer that leads to absorption of solar radiation and increase in local evaporation and more clouds. But also the atmospheric moisture transport from the lower latitudes can contribute to the surface warming in high-latitudes. This poleward moisture transport is mostly accomplished by extra-tropical cyclones, with especially strong contribution by the Atmospheric Rivers (ARs). ARs are long, narrow bands of enhanced water vapour transport which are responsible for over 90% of the poleward water vapour transport in and across mid-latitudes. Furthermore, they are responsible for producing significant levels of rain and snow. In addition, the greenhouse effect of water vapour and the formation of clouds increase the downward longwave radiation which can cause a thinning and melting of Arctic sea ice and snow.

In this study, we investigate the contribution of ARs to Arctic precipitation. Firstly, we look into different case studies for which observational data from the campaigns within the Collaborative Research Center “Arctic Amplification: Climate Relevant Atmospheric and Surface Processes, and Feedback Mechanisms (AC)3” exist. The data include enhanced observations at/around Svalbard performed during the ACLOUD and the AFLUX campaigns.

Previous studies have shown that ARs reaching into the Arctic have different origins, including the Atlantic and the Pacific pathways and also Siberia. Here we examine which pathway is more common and which one transports more moisture into the Arctic for these case studies by using existing AR catalogues from global and polar-specific algorithms. Furthermore, the variability of precipitation influences the surface mass and energy balance of polar sea ice and ice sheets. Therefore, we will analyse the influence of ARs on precipitation in terms of frequency, intensity, and type of precipitation (rain or snow) for the different case studies. For this purpose, we will use reanalyses and observational data for the water vapour transport, total precipitation, rain and snow profiles.The occurrence of ARs and its influence on precipitation will be extended from case studies to the long-term statistics (for at least 10 years).

How to cite: Lauer, M., Rinke, A., Gorodetskaya, I., and Crewell, S.: Poleward moisture transport and its influence on precipitation in the Arctic: From case studies to long-term statistics, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12989, https://doi.org/10.5194/egusphere-egu2020-12989, 2020.

EGU2020-4428 | Displays | AS2.8

Horizontal moisture transport shapes the regional moistening patterns in the Arctic

Tiina Nygård, Tuomas Naakka, and Timo Vihma

The Arctic has experienced regionally and seasonally variable moistening of the atmosphere during the recent decades. Compared to the accompanying amplified warming and dramatic sea ice decline, the moistening has so far remained less studied.

We address the regional and seasonal trends in the horizontal moisture transport in the Arctic during the last four decades, in 1979–2018, based on data of ERA5 reanalysis of European Centre for Medium-Range Weather Forecasts. We show that regional trends in moisture transport are large and mainly driven by changes in atmospheric circulation. We demonstrate that the regional moistening patterns in the Arctic during the last four decades have dominantly been shaped by these strong trends in horizontal moisture transport. Changes in local evaporation in the Arctic have only had a minor role in shaping the moistening patterns. We show that increasing trends in evaporation have been restricted to the vicinity of sea-ice margin over a limited period during the local sea-ice decline, and this step-wise increase has been followed by negative trends in evaporation in open sea, due to suppressing effect of horizontal moisture transport.

Both evaporation and the horizontal moisture transport have been affected by the diminishing sea-ice cover during the cold seasons from autumn to spring, and their trends have been dependent on the flow direction. We summarize the current understanding and the new results of flow-dependency of the trends in moisture transport and evaporation near the sea-ice margin, and the cloud response to those.

For the first time, we provide a detailed picture of both the drastic regional changes in the moisture transport within the Arctic and changes in local evaporation, and demonstrate large impacts of these changes on the climate of the Arctic. We suggest that also in the future, moisture and cloud distributions in the Arctic are expected to respond to changes in atmospheric pressure patterns; circulation and moisture transport will also control where and when efficient surface evaporation can occur.

How to cite: Nygård, T., Naakka, T., and Vihma, T.: Horizontal moisture transport shapes the regional moistening patterns in the Arctic, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4428, https://doi.org/10.5194/egusphere-egu2020-4428, 2020.

EGU2020-12762 | Displays | AS2.8

Antarctic Cloud Property Retrievals from Infrared Radiances

Penny Rowe, Von Walden, Matthew Fergoda, Connor Krill, Jonathon Gero, and Steven Neshyba

Clouds exert a strong radiative impact on the surface and have complicated effects that are still not well understood, particularly in the Antarctic. The amount of supercooled liquid water in Antarctic clouds, for example, is still poorly constrained, due to the low number of observations on the continent. It is also not clear how the radiative properties of supercooled liquid in those clouds should be represented in climate models. In particular, the complex refractive index (CRI) of liquid water is known to depend on temperature, but this dependence is typically ignored in climate models.

Here, we present cloud properties retrieved from Antarctic downwelling infrared radiance measurements made by an Atmospheric Emitted Radiance Interferometer (AERI) and by the Polar AERI (PAERI), using the CLoud and Atmospheric Radiation Retrieval Algorithm (CLARRA). Preliminary retrievals were made of cloud height, optical depth, thermodynamic phase, and effective radius for field experiments at Amundsen-Scott South Pole Station (2001) and at McMurdo Station (2016).

At South Pole, we find that clouds are typically thin and near the surface, in keeping with prior work. For thin clouds, the mode of the effective radii of liquid droplets (~4 μm) and ice particles (~15 μm in summer, ~12 μm in winter) at South Pole are found to be smaller than typical Arctic values (~9 μm for liquid and 17 to 25 μm for ice). Although ice cloud was found to dominate year-round at South Pole, significant supercooled liquid water was present in the summer. Cloud properties retrieved at South Pole will be compared to retrievals from McMurdo.

We further find that ignoring the temperature dependence of the CRI of supercooled liquid cloud leads to negative biases in part of the atmospheric window region (700 – 1000 cm-1), indicating underestimation of the greenhouse effect. These biases are expected to be partially offset by positive biases below 600 cm-1. Based on these considerations, we recommend using temperature-dependent CRI for infrared radiance simulations of supercooled liquid water cloud.

How to cite: Rowe, P., Walden, V., Fergoda, M., Krill, C., Gero, J., and Neshyba, S.: Antarctic Cloud Property Retrievals from Infrared Radiances, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12762, https://doi.org/10.5194/egusphere-egu2020-12762, 2020.

EGU2020-1396 | Displays | AS2.8

Secondary Ice Production in Antarctic Clouds: a process neglected in large-scale models

Georgia Sotiropoulou, Etienne Vignon, Gillian Young, Thomas Lachlan-Cope, Alexis Berne, and Athanasios Nenes

In-situ measurements of Antarctic clouds frequently show that ice crystal number concentrations  are much higher than the available ice-nucleating particles, suggesting that Secondary Ice Production (SIP) may be active. Here we investigate the impact of two SIP mechanisms, Hallett-Mossop (H-M)and collisional break-up (BR), on a case from the Microphysics of Antarctic Clouds (MAC) campaign in Weddell Sea using the Weather and Research Forecasting (WRF) model. H-M is already included in the default version of the Morrison microphysics scheme in WRF; for BR we implement different parameterizations and compare their performance. H-M alone is not effective enough to reproduce the observed concentrations. In contrast, BR can result in realistic ice multiplication, independently of whether H-M is active or not. In particular, the Phillips parameterization results in very good agreement with observations, but its performance depends on the prescribed rimed fraction of the colliding ice particles. Finally, our results show low sensitivity to primary ice nucleation, as long as there are enough primary ice crystals to initiate ice-ice collisions. Our findings suggest that BR is a potentially important SIP mechanism in the pristine Antarctic atmosphere that is currently not represented in weather-prediction and climate models.

How to cite: Sotiropoulou, G., Vignon, E., Young, G., Lachlan-Cope, T., Berne, A., and Nenes, A.: Secondary Ice Production in Antarctic Clouds: a process neglected in large-scale models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1396, https://doi.org/10.5194/egusphere-egu2020-1396, 2020.

EGU2020-3019 | Displays | AS2.8

Synoptic conditions and atmospheric moisture pathways associated with virga and precipitation over coastal Adélie Land, Antarctica

Nicolas Jullien, Etienne Vignon, Michael Sprenger, Franziska Aemisegger, and Alexis Berne

Precipitation falling over the coastal regions of Antarctica often experiences low-level sublimation within the dry katabatic layer. The amount of water that reaches the ground surface is thereby considerably reduced. We investigate the synoptic conditions and the atmospheric transport pathways of moisture that lead to virga – when precipitation is completely sublimated – or actual surface precipitation at Dumont d’Urville (DDU) station, coastal Adélie Land, Antarctica. We combine ground-based radar measurements, Lagrangian back-trajectories, Eulerian diagnostics of extratropical cyclones and fronts as well as with moisture source estimations based on ERA5 reanalyses. Virga periods – corresponding to 36% of the precipitating events – often precede and sometimes follow surface precipitation periods. Pre-precipitation virga, surface precipitation and post-precipitation virga correspond to different phases of the same precipitating system. Precipitation and virga are always associated with the warm front of an extratropical cyclone that sets to the west of coastal Adélie Land but the exact locations of the cyclone and front differ between the three phases. On their way to DDU, the air parcels that ultimately precipitate above the station experience a large-scale lifting across the warm front. The lifting generally occurs earlier in time and farther from the station for virga than for precipitation. It is further shown that water contained in the precipitation falling above DDU during pre-precipitation virga has an oceanic origin farther away (30 degrees more to the west) from Adélie Land than the one that precipitates down to the ground surface.

How to cite: Jullien, N., Vignon, E., Sprenger, M., Aemisegger, F., and Berne, A.: Synoptic conditions and atmospheric moisture pathways associated with virga and precipitation over coastal Adélie Land, Antarctica, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3019, https://doi.org/10.5194/egusphere-egu2020-3019, 2020.

EGU2020-651 | Displays | AS2.8

Microphysical cloud parameters of optically thin clouds in the Arctic in summer 2017

Philipp Richter, Mathias Palm, Christine Weinzierl, Penny Rowe, and Justus Notholt

As a precursor of the current MOSAiC campaign, the PASCAL campaign took place in summer 2017 around Svalbard [1]. In the scope of the project (AC)3, infrared radiation emitted by clouds was measured using a calibrated Fourier Transform Infrared Spectrometer (EM-FTIR). EM-FTIR can be used for different purposes, like the observation of trace gases or microphysical cloud parameters (MCP) like cloud optical depths and cloud effective droplet radii. In the observation of MCP, EM-FTIR can be used to measure optically thin clouds with very low amounts of liquid water paths below 30 gm-2, where microwave radiometer face problems because of their larger measuring uncertainty. 

The retrieval of the MCP is performed using the newly introduced retrieval code CLARRA [2]. CLARRA shows a high accuracy in the retrieval of MCP from low-level clouds, which were often observed during the measurements. 

The measurements were performed between June 2017 and August 2017 around Svalbard and include measurements of clouds over sea ice and open water. The spatial distribution of the MCP around Svalbard and a comparison to model results will be shown. This dataset can later serve as a reference for the question, how representative the measurements in Ny-Alesund on Spitzbergen are for the nearby arctic region.

[1] Wendisch et al., 2019: The Arctic Cloud Puzzle: Using ACLOUD/PASCAL Multi-Platform Observations to Unravel the Role of Clouds and Aerosol Particles in Arctic Amplification, Bull. Amer. Meteor. Soc., 100 (5), 841–871, doi:10.1175/BAMS-D-18-0072.1
[2] Rowe et al., 2019: Toward autonomous surface-based infrared remote sensing of polar clouds: retrievals of cloud optical and microphysical properties, Atmos. Meas. Tech., 12, 5071–5086, https://doi.org/10.5194/amt-12-5071-2019

How to cite: Richter, P., Palm, M., Weinzierl, C., Rowe, P., and Notholt, J.: Microphysical cloud parameters of optically thin clouds in the Arctic in summer 2017, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-651, https://doi.org/10.5194/egusphere-egu2020-651, 2020.

EGU2020-2562 | Displays | AS2.8

Investigation of cloud radiative effects and closure in the Central Arctic based on ship-borne remote sensing observations

Carola Barrientos Velasco, Hartwig Deneke, Andre Ehrlich, Matthias Gottschalk, Hannes Griesche, Anja Hünerbein, Patric Seifert, Johannes Stapf, and Andreas Macke

The surface in the Arctic is warming at double the rate than the global average. This phenomenon, named Arctic amplification, makes the Arctic a sensitive and important location to investigate climate change. The principal mechanisms contributing to Arctic Amplification are still under debate due to lack of observations and comprehension of different mechanisms.
With the aim to collect additional observations for the investigation of several processes related to Arctic amplification, the project (AC)³ (Arctic Amplification: Climate Relevant Atmospheric and SurfaCe Processes and Feedback Mechanisms) established two major field campaigns in summer of 2017. Both performed in situ and remote sensing observations over the ocean with PASCAL and in the air with ACLOUD (Macke and
Flores, 2018, Wendisch et al., 2019).
The PASCAL expedition took place on board of the German research vessel Polarstern which was equipped with active and passive remote sensing instrumentation. The synergistic operation of this instrumentation was used to derive macro and microphysical properties of clouds by applying the Cloudnet algorithm. These retrievals together with vertical profiles of temperature and relative humidity are used as input to the Rapid
Radiative Transfer Model for GCM applications (RRTMG). We used the RRMG outputs of solar and terrestrial broadband irradiances and compare them to observations to assess the radiative closure.
In the scope of this study, the difference in radiative fluxes arriving at the surface by using model profiles instead of radiosonde data as thermodynamic driver is quantified, focusing on the representation of temperature and humidity inversions. Furthermore, a sensitivity study is given of the variation of cloud optical properties and their radiative effects at the surface. To test the radiative closure performance at different scales, an inter-comparison is made among airborne, tethered balloon-borne and ship-borne broadband solar and terrestrial radiation in different case studies.
The methodology described is also applicable to the current Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition which started in September 2019. First results will be presented for the first leg which will allow a direct comparison of the contrasting properties of cloud radiative effects during summer and winter.


Acknowledgements
We gratefully acknowledge the funding by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) – Project Number 268020496 – TRR 172, within the Transregional Collaborative Research Center “ArctiC Amplification: Climate Relevant Atmospheric and SurfaCe Processes, and Feedback Mechanisms (AC)³.


References
Macke, A. and Flores, H. (2018): The Expeditions PS106/1 and 2 of the Research Vessel POLARSTERN to the Arctic Ocean in 2017 , Berichte zur Polar- und Meeresforschung = Reports on polar and marine research, Bremerhaven, Alfred Wegener Institute for Polar and Marine Research, 719 , 171 p. http://hdl.handle.net/10013/epic.4ff2b0cd-1b2f-4444-a97f-0cd9f1d917ab
Wendisch, M., and coauthors. (2019): The Arctic Cloud Puzzle: Using ACLOUD/PASCAL Multiplatform Observations to Unravel the Role of Clouds and Aerosol Particles in Arctic Amplification. Bull. Amer. Meteor. Soc., 100, 841–871, https://doi.org/10.1175/BAMS-D-18-0072.1

How to cite: Barrientos Velasco, C., Deneke, H., Ehrlich, A., Gottschalk, M., Griesche, H., Hünerbein, A., Seifert, P., Stapf, J., and Macke, A.: Investigation of cloud radiative effects and closure in the Central Arctic based on ship-borne remote sensing observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2562, https://doi.org/10.5194/egusphere-egu2020-2562, 2020.

EGU2020-4541 | Displays | AS2.8

Mechanism of Phase Inversion in Arctic Stratiform Clouds

Pei-Hsin Liu, Jen-Ping Chen, Xiquan Dong, and Yi-Chiu Lin

Arctic stratiform clouds (ASC) often exhibit phase inversion structure (i.e., liquid top and mixed- or ice-phase below) and can persist for a very long time. According to past studies, the phase inversion structure is the result of persistent liquid cloud generation aloft and gravitational ice precipitation; however, observation reveals that the largest cloud reflectivity appears in the middle of the cloud, implying that the gravitational ice precipitation cannot fully explain the mechanism of phase inversion structure. Also, the role of ice nucleation in ASC is not fully addressed before. Ice nucleation processes are affected by temperature, ice nuclei (IN) species and number concentration. As the result, strong inversion or strong vertical gradient of IN number concentration may favor ice nucleation to occur in the lower levels and result in phase inversion.

This study aims to find out the mechanism of phase inversion and the dominant ice nucleation processes in ASC. Weather Research and Forecasting (WRF) model with detailed ice nucleation mechanisms is applied. The ice nucleation scheme used in the model takes different ice nucleation processes and IN species into account. Dust and soot, taken from MERRA-2, are the two main IN considered in this study and are fitted into lognormal distributions for providing the initial and boundary conditions. The 2008 Mar 04-05 case, chosen from the Atmospheric Radiation Measurement (ARM) program, is simulated. From observation, ASC and the phase inversion structure persisted for half a day. Temperature decreases with height in cloud, indicating that temperature inversion is not the mechanism of phase inversion in this case. More dust in the lower levels is seen from the model simulation results. In this case, strong vertical gradient of IN number concentration serves as the main mechanism of phase inversion, suggesting that ice nucleation process plays an important role in ASC. The role of soot particles will also be addressed.

How to cite: Liu, P.-H., Chen, J.-P., Dong, X., and Lin, Y.-C.: Mechanism of Phase Inversion in Arctic Stratiform Clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4541, https://doi.org/10.5194/egusphere-egu2020-4541, 2020.

EGU2020-5264 | Displays | AS2.8

Arctic Sea Ice: Observations and Global Climate Modelling

Juilin Li, Mark Richardson, Wei-Liang Lee, Jonathan Jiang, Kuan-Man Xu, Yi-Hui Wang, Eric Fetzer, Yinghui Liu, Jia-Yuh Yu, and Graeme Stephens

Recent Arctic sea ice retreat has been quicker than the projection in most general circulation model (GCM) simulations. Natural factors may have amplified this, but reliable attribution and projection requires accurate representation of relevant physical processes. In the meeting, we will present results indicating robust links between CloudSat-CALIPSO falling ice and Arctic sea ice melting from observations and global climate modelings.  Most current GCMs don’t fully represent falling ice radiative effects (FIREs).  We find that a small set of Coupled Model Intercomparison Project, phase 5 (CMIP5) models that include FIREs tend to show a faster Arctic sea ice retreat. We investigate this using controlled simulation with the CESM1-CAM5 model both in present-day and 1%CO2 scenarios. With FIREs, CESM1-CAM5 simulates more realistic present-day annual and seasonal variations of radiation and skin temperatures and Arctic sea ice coverage and thickness. Over 60—90 °N oceans, simulated radiative flux trends are similar but the current-day state differs substantially due to FIREs. Falling ice reduces downward shortwave and increase downward longwave, resulting in an improved agreement with the satellite-based CERES-EBAF surface dataset. Under 1pctCO2 simulations, including FIREs results in the first occurrence of an “ice free” Arctic (extent < 1×106 km2) in year 64, compared with year 91 otherwise. We propose that the equivalent greenhouse effects from falling ice results in fewer safe spaces in which sea ice can thicken during winter, resulting in a thinner pack whose retreat is more easily triggered by global warming. However, this explanation does not apply across the CMIP5 ensemble members. Our results therefore only apply to one model but we have shown that this can have substantial implications for Arctic sea ice projection. Given that falling ice interaction with radiation in reality, we propose that including FIREs in models is a high priority.

How to cite: Li, J., Richardson, M., Lee, W.-L., Jiang, J., Xu, K.-M., Wang, Y.-H., Fetzer, E., Liu, Y., Yu, J.-Y., and Stephens, G.: Arctic Sea Ice: Observations and Global Climate Modelling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5264, https://doi.org/10.5194/egusphere-egu2020-5264, 2020.

EGU2020-10331 | Displays | AS2.8

Impact of clouds on atmospheric heating rate profiles at Ny-Ålesund, Svalbard

Kerstin Ebell, Tatiana Nomokonova, Marion Maturilli, and Christoph Ritter

Clouds strongly impact the available energy at the surface and at the top of the atmosphere as well as its vertical distribution within the atmosphere by modifying the shortwave (SW) and longwave (LW) fluxes and heating rates. The so-called cloud radiative effect (CRE) and the cloud radiative forcing (CRF), i.e. the difference between the all-sky and clear-sky fluxes and heating rates, respectively, strongly depend on the cloud macrophysical (e.g. frequency of occurrence, cloud vertical distribution) and microphysical (e.g. phase, water content, hydrometeor size distribution) properties.

In the Arctic, the cloud–radiative interactions are even more complex due to low temperatures, frequently occurring temperature inversions, the dryness of the atmosphere, large solar zenith angles and a high surface albedo. In particular (supercooled) liquid containing clouds, which frequently occur in the Arctic and often have very low amounts of liquid water, exhibit a strong impact on the radiative fluxes.

Recently, Ebell et al. (2020) have analysed for the first time the radiative effect of clouds for the Arctic site Ny-Ålesund exploiting more than 2 years (06/2016 -10/2018) of continuous vertical cloud measurements at the French-German research station AWIPEV. They showed that at Ny-Ålesund, the monthly net surface CRE is positive from September to April/May and negative in summer. The annual surface warming effect by clouds is 11.1 W m-2.

Based on the same data set, we will now investigate in more detail how clouds modify the LW and SW heating rates in the atmospheric profile. First results show that the net CRF is dominated by the LW CRF with warming taking place in principal below the height of the maximum frequency of occurrence of liquid around 1 km, and cooling above. The strength of this cooling and warming is closely related to the amount of liquid. We will also analyze heating rates for different cloud types similar to the study by Turner et al. (2017) who found characteristic heating rate profiles for the Arctic site Barrow. In this way, we will gain insight into the representastiveness of these heating rate profiles throughout the Arctic.

We gratefully acknowledge the funding by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) – Project-ID 268020496 – TRR 172,  within the Transregional Collaborative Research Center “ArctiC Amplification: Climate Relevant Atmospheric and SurfaCe Processes,   and    Feedback Mechanisms (AC)³”.

References

Ebell, K., T. Nomokonova, M. Maturilli, and C. Ritter, 2020: Radiative Effect of Clouds at Ny-Ålesund, Svalbard, as Inferred from Ground-Based Remote Sensing Observations. J. Appl. Meteor. Climatol., 59, 3–22, https://doi.org/10.1175/JAMC-D-19-0080.1

Turner, D.D., M.D. Shupe, and A.B. Zwink, 2018: Characteristic Atmospheric Radiative Heating Rate Profiles in Arctic Clouds as Observed at Barrow, Alaska. J. Appl. Meteor. Climatol., 57, 953–968, https://doi.org/10.1175/JAMC-D-17-0252.1

How to cite: Ebell, K., Nomokonova, T., Maturilli, M., and Ritter, C.: Impact of clouds on atmospheric heating rate profiles at Ny-Ålesund, Svalbard, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10331, https://doi.org/10.5194/egusphere-egu2020-10331, 2020.

EGU2020-20196 | Displays | AS2.8

Humidity profiles and their interactions with moisture transport and surface fluxes in the Antarctic

Tuomas Naakka, Tiina Nygård, and Timo Vihma

Atmospheric humidity profiles control occurrence of clouds, which in turn has a large impact on radiative fluxes in the Antarctic. In addition, humidity profiles strongly interact with surface moisture fluxes, which are an important component in the water cycle. Despite their important role in the climate system, specific and relative humidity profiles in the Antarctic have not so far been comprehensively studied. Here, we address the vertical structure of tropospheric specific and relative humidity in the area south of 50°S and focus on interactions of this structure with horizontal and vertical moisture transport and surface fluxes of sensible and latent heat. The study is based on ERA5 reanalysis data from 15-years period, 2004 - 2018. 

We show that in the Antarctic, both moisture transport and surface fluxes shape the vertical structure of specific and relative humidity, but their relative contributions and effects vary considerably between regions. Therefore, we examined humidity profiles dividing the study area into five sub-regions: 1) open sea, 2) seasonal sea-ice area, 3) slopes of East Antarctica, 4) East Antarctica high plateau, and 5) West Antarctica. Expect west Antarctica, within each region the vertical structure of air moisture is relatively homogenous. Results indicate that each of these regions has own key processes (evaporation, condensation, vertical and horizontal moisture fluxes) controlling the vertical structure of relative and specific humidity.

The open ocean is a source area for atmospheric moisture. Over the open sea, a thin unsaturated well-mixed layer is seen near the surface, which is caused by year-around upward moisture flux (evaporation) and upward sensible heat flux. Above this layer, there is a layer of high relative humidity and frequently occurring cloud cover. Over sea ice, seasonal variability is large. During most of the year, moisture surface fluxes over sea ice are small, near-surface relative humidity is high, and specific humidity inversions are frequent. In summer, however, evaporation over sea ice increases, near-surface relative humidity is lower, and humidity inversions are uncommon.

The high plateau is the area where absolutely dry air masses are formed, as a consequence of near-surface condensation and downward moisture transport. There, the near-surface air is often saturated with respect to ice, and strong but thin surface-based specific humidity inversions are present during most of the year. On the slopes, adiabatic warming, due to katabatic winds, causes decrease of relative humidity when the air mass is advected downwards from the plateau. This leads to relatively high surface evaporation and makes surface-based specific humidity inversions rarer.

This study comprehensively describes the vertical structure of relative and specific humidity in the Antarctic, and increases understanding on how this vertical structure interacts with moisture transport and surface fluxes. The results can further contribute to understanding of processes related to cloud formation and water cycle in the high southern latitudes.

How to cite: Naakka, T., Nygård, T., and Vihma, T.: Humidity profiles and their interactions with moisture transport and surface fluxes in the Antarctic, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20196, https://doi.org/10.5194/egusphere-egu2020-20196, 2020.

EGU2020-14421 | Displays | AS2.8

Cloud, radiation, and surface heat flux simulations using Polar WRF with 3DVAR

dae hui Kim, Hyun Mee Kim, and Jinkyu Hong

In the Arctic region, cloud is an important factor affecting surface radiation and heat flux. Despite the development of cloud microphysics schemes in the Polar WRF, clouds in the Arctic region still have uncertainties. In this study, the possibility of improving cloud simulations by using data assimilation (DA) and its effects on the enhancement of the forecast accuracy for surface fluxes and meteorological variables are evaluated. The experimental period is from 1 to 19 September 2017.

Forecasts from both the cold start experiment without DA and the warm start experiment with DA underestimated summer arctic clouds. When satellite radiances (AMSU-A and MHS) were assimilated at the analysis time, the distribution and quantity of water vapor were simulated more realistically, which results in the improvement of cloud simulations at the forecast time. As a result, the 25–30 hour forecast error of the downward shortwave (longwave) radiation flux in the warm start experiment which assimilated both conventional observations and satellite radiance data was reduced by 8.1% (12.7%), compared to that in the cold start experiment. The 25–30 hour forecast error of the upward latent (sensible) heat flux in the warm start experiment was also reduced by 7.8% (3.3%), compared to that in the cold start experiment. For the 2 m temperature and 10 m wind, the forecast error with DA was less than that without DA at almost all observation stations. More detailed results will be presented in the conference.

Acknowledgments

This work was supported by the Korea Polar Research Institute (KOPRI, PN20081) and the Korea Meteorological Administration Research and Development Program under grant KMI2018-03712. The simulations are mostly carried out by utilising the supercomputer system supported by the National Center for Meteorological Supercomputer of Korea Meteorological Administration (KMA).

How to cite: Kim, D. H., Kim, H. M., and Hong, J.: Cloud, radiation, and surface heat flux simulations using Polar WRF with 3DVAR, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14421, https://doi.org/10.5194/egusphere-egu2020-14421, 2020.

EGU2020-21307 | Displays | AS2.8

Zooming in on Arctic clouds: A case study comparing A-Train and airborne remote sensing measurements.       

Birte Solveig Kulla, Elena Ruiz-Donoso, Leif-Leonard Kliesch, Vera Schemann, Christoph Ritter, Mario Mech, and Susanne Crewell
Despite their importance, our knowledge on arctic clouds and in particular their vertical structure is limited.
In the essentially remote regions of the Arctic, the only continuous measurements available usually are those of satellites, like the A-Train constellation. Climatologies have been derived from A-Train products, i.e. the combination of radar and lidar. However, due to the coarser resolution and bigger footprints of the sensors and the blind zone of CLOUDSAT in the boundary layer many features are missed. In the framework of the Collaborative Research Centre TR 172 “Arctic Amplification” four major aircraft campaigns with the AWI research aircraft POLAR5 took and will take place in the vicinity of Svalbard with emphasis on the Atlantic Arctic region close to the marginal sea ice zone. 
 
On board of the POLAR5 aircraft active measurements by radar (MiRAC) and lidar (AMALi) were performed and supported by microwave radiometer measurements in 9 frequency channels and a high spectral resolution solar imager (AISA Eagle/Hawk). We have calibrated and processed radar and lidar measurements and deduced highly resolved (7.5 m, 1.3 Hz) vertical profiles of backscatter, attenuation and reflectivity and retrieved a preliminary classification of cloud top. The potential of these measurements for a detailed characterization of Arctic clouds is assessed via the comparison with CALIPSO and CLOUDSAT as well as MODIS measurements for an A-Train underflight. Measurements cover a cold air outbreak in May 2017 with a complex situation with multiple layers of mixed phase clouds and several inversions evident in the thermodynamic structure given by dropsondes. A high resolution model simulation with ICON, which reproduces the general features of this situation, is used together with instrument simulators to investigate how much information on cloud processes can be gained from the measurements. 

How to cite: Kulla, B. S., Ruiz-Donoso, E., Kliesch, L.-L., Schemann, V., Ritter, C., Mech, M., and Crewell, S.: Zooming in on Arctic clouds: A case study comparing A-Train and airborne remote sensing measurements.       , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21307, https://doi.org/10.5194/egusphere-egu2020-21307, 2020.

AS2.9 – Polar meteorology and climatology and their link to changes in the cryosphere

EGU2020-1681 | Displays | AS2.9 | Highlight

Dynamic and thermodynamic drivers of Arctic lower tropospheric warm extremes

Lukas Papritz

Recent decades have revealed dramatic changes in the high Arctic (> 80°N) related to natural variability and anthropogenic climate change. In particular, episodes of extremely warm temperatures in the lower troposphere and their role for sea ice melting have gained considerable attention. While it has been recognized that injections of warm and humid air masses contribute to wintertime warm anomalies, summertime warm anomalies have also been linked to blocking anticyclones within the high Arctic. Yet, the relative importance of the various thermodynamic and atmospheric dynamical processes that can contribute to the formation of extreme warm anomalies in the high Arctic is poorly understood.

In this work, we present a systematic analysis of the processes leading to the formation of winter- and summertime lower tropospheric warm extremes in the high Arctic by means of kinematic backward trajectories based on the ERA-Interim reanalysis. The trajectories enable us to quantify the relative contributions of poleward transport from (potentially) warmer regions, adiabatic warming due to subsidence, and diabatic heating associated with surface sensible heat fluxes and latent heat release. Furthermore, we relate these processes to atmospheric dynamical flow features such as atmospheric blocking and extratropical cyclones.

Our analyses reveal that subsidence in blocking anticyclones over the Barents and Kara Seas and diabatic warming by surface sensible heat fluxes are the dominant mechanisms leading to wintertime warm extremes (contributing about 40% each), whereas the transport from southerly latitudes – predominantly accomplished by the injection of warm and humid air masses associated with an intensified and westward displaced storm track in the Nordic Seas - is of secondary importance (20%). Summertime warm anomalies, in contrast, are essentially the result of subsidence in blocking anticyclones (70%) that are located within the high Arctic. Thus, our findings point towards a rich, seasonally varying spectrum of dynamical and thermodynamic processes contributing to Arctic warm extremes that result from a complex interplay between transport induced by dynamical weather systems and diabatic processes. Furthermore, they emphasize the importance of processes within the Arctic for the formation of warm extremes.

Papritz, L., 2019: Arctic lower tropospheric warm and cold extremes: horizontal and vertical transport, diabatic processes, and linkage to synoptic circulation features, J. Climate, doi: 10.1175/JCLI-D-19-0638.1

How to cite: Papritz, L.: Dynamic and thermodynamic drivers of Arctic lower tropospheric warm extremes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1681, https://doi.org/10.5194/egusphere-egu2020-1681, 2020.

EGU2020-5127 | Displays | AS2.9

Structure and variability of the Antarctic coastal easterly winds

John King and Thomas Bracegirdle

The belt of climatological easterly (westward) winds that lies to the south of the circumpolar trough of low pressure surrounding Antarctica has received less attention than the westerlies to the north of the trough, yet it plays a crucial role in atmosphere-ocean-cryosphere interactions in the near-coastal region. The westward-directed wind stress associated with the easterly winds drives a coastal westward ocean current and a westward transport of sea ice around the continent. Easterly winds also inhibit the flow of warm water masses from intermediate depths onto the continental shelves, thus protecting coastal ice shelves from enhanced basal melt. We use the ECMWF ERA-Interim reanalysis to study the mean structure and variability of the coastal easterly winds. The surface component of the easterlies generally extends no more than 200 km to the north of the coast. The easterlies are quite shallow (~ 1-2 km) and are relatively weak (generally < 3 m s-1 at the surface in the annual mean) over the ocean but become both deeper (~ 2-3 km) and stronger (~ 7 m s-1) over the steep coastal slopes of the continent. While persistent katabatic flow down these slopes is a source of easterly momentum (through the action of the Coriolis force), the primary driver of the easterlies appears to be the large-scale baroclinicity of the flow, which is enhanced in the coastal region where isentropes are forced to follow the steep coastal orography. Variability of the easterlies on monthly and longer timescales is related to variations in the strength and latitude of the circumpolar trough. On shorter (synoptic) timescales, large variations in the strength of the easterlies at coastal locations are forced by cyclones that move south from the circumpolar trough and decay in the coastal region.

How to cite: King, J. and Bracegirdle, T.: Structure and variability of the Antarctic coastal easterly winds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5127, https://doi.org/10.5194/egusphere-egu2020-5127, 2020.

EGU2020-5211 | Displays | AS2.9

An evaluation of the surface climatology over the Totten region (Antarctica) using COSMO-CLM2

Samuel Helsen, Sam Vanden Broucke, Alexandra Gossart, Niels Souverijns, and Nicole van Lipzig

The Totten glacier is a highly dynamic outlet glacier, situated in E-Antarctica, that contains a potential sea level rise of about 3.5 meters. During recent years, this area has been influenced by sub-shelf intrusion of warm ocean currents, contributing to higher basal melt rates. Moreover, most of the ice over this area is grounded below sea level, which makes the ice shelf potentially vulnerable to the marine ice sheet instability mechanism. It is expected that, as a result of climate change, the latter mechanisms may contribute to significant ice losses in this region within the next decades, thereby contributing to future sea level rise. Up to now, most studies have been focusing on sub-shelf melt rates and the influence of the ocean, with much less attention for atmospheric processes (often ignored), which also play a key-role in determining the climatic conditions over this region. For example: surface melt is important because it contributes to hydrofracturing, a process that may lead to ice cliff instabilities. Also precipitation is an important atmospheric process, since it determines the input of mass to the ice sheet and contributes directly to the surface mass balance. In order to perform detailed studies on these processes, we need a well-evaluated climate model that represents all these processes well. Recently, the COSMO-CLM2 (CCLM2) model was adapted to the climatological conditions over Antarctica. The model was evaluated by comparing a 30 year Antarctic-wide hindcast run (1986-2016) at 25 km resolution with meteorological observational products (Souverijns et al., 2019). It was shown that the model performance is comparable to other state-of-the-art regional climate models over the Antarctic region. We now applied the CCLM2 model in a regional configuration over the Totten glacier area (E-Antarctica) at 5 km resolution and evaluated its performance over this region by comparing it to climatological observations from different stations. We show that the performance for temperature in the high resolution run is comparable to the performance of the Antarctic-wide run. Precipitation is, however, overestimated in the high-resolution run, especially over dome structures (Law-Dome). Therefore, we applied an orographic smoothening, which clearly improves the precipitation pattern with respect to observations. Wind speed is overestimated in some places, which is solved by increasing the surface roughness. This research frames in the context of the PARAMOUR project. Within PARAMOUR, CCLM2 is currently being coupled to an ocean model (NEMO) and an ice sheet model (f.ETISh/BISICLES) in order to understand decadal predictability over this region.

How to cite: Helsen, S., Vanden Broucke, S., Gossart, A., Souverijns, N., and van Lipzig, N.: An evaluation of the surface climatology over the Totten region (Antarctica) using COSMO-CLM2, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5211, https://doi.org/10.5194/egusphere-egu2020-5211, 2020.

EGU2020-5515 | Displays | AS2.9 | Highlight

Temperature increase is accelerating in the past five years in Greenland

Saiping Jiang and Aizhong Ye

Understanding the change of Greenlandic temperature is important for assessing and predicting Greenland ice sheet mass, which plays an important role in sea level rise. In this study, we analyze the annual and seasonal coastal Greenlandic temperature during period 1952 ~ 2017 based on the dataset obtained from Danish Meteorological Institute (DMI), focusing on the last five years. Overall, the annual coastal Greenlandic temperature increases during period 1952 ~ 2017 with a rate of 0.23 ℃ decade-1, especially in the south-eastern (0.70 ℃ decade-1) and northern (0.42 ℃ decade-1) region of the island. From seasonal coastal Greenlandic composite temperature (CT) change, winter has the largest change rate (0.28 ℃ decade-1), and summer increases 0.25 ℃ decade-1, while spring warms 0.17 ℃ decade-1 with a smaller variation. And temperature increase is accelerating during period 2013 ~ 2017 according to Mann-Kendall test, especially in the north-eastern and northern region of the island; And the order of seasonal temperature change of the whole island is as follows: annual > autumn > summer > winter > spring. And pearson correlation analysis was used to determine the teleconnection relationship between coastal temperature and large-scale atmospheric-ocean climate indexes, and we have found that Greenland Blocking Index (GBI), Atlantic Multi-decadal Oscillation (AMO), Tropical Northern Atlantic Index (TNA), North Tropical Atlantic Index (NTA), Caribbean Index (CAR), Atlantic Meridional Mode (AMM), East Atlantic (EA) and Western Hemisphere warm pool (WHWP) have a significant positive correlation relationship with coastal temperature in most months except February and May. But North Atlantic Oscillation (NAO), Arctic Oscillation (AO) and Eastern Asia/Western Russia (EAWR) show a significant negative correlation relationship with temperature. On the whole, there exists time lag effect between climate indexes and temperature except GBI, AO and NAO. And from Randomforest model result, we find that GBI, NAO, CO2, AMO, N2O, SF6, CH4, and Northern Oscillation Index (NOI) are most important variables that influence CT change during period 1979 ~ 2017. Finally, we calculated the contribution rate of important variables to temperature change during period 1979 ~ 2017, showing that contribution rate of GBI, CO2 and NOI to temperature change is 48.85%, 36.85%, and 17.58%, respectively. 

How to cite: Jiang, S. and Ye, A.: Temperature increase is accelerating in the past five years in Greenland, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5515, https://doi.org/10.5194/egusphere-egu2020-5515, 2020.

EGU2020-8064 | Displays | AS2.9 | Highlight

The Impact of Extratropical Cyclones on the Greenland Ice Sheet

Luca Maffezzoni, Laura Edwards, and Tom Matthews

The Greenland Ice Sheet (GrIS) stores enough freshwater to raise global sea level by more than 7 m, so its response to climate variability and change is of considerable societal significance. In this context, extratropical cyclones are known to impact the surface mass budget (SMB) via their influence on precipitation and the surface energy budget (SEB). However, there has so far been limited research on these pathways. We address this by expanding process-based knowledge of cyclones and their influence on the GrIS. Using a 58-year integration of the Model Atmospherique Regional (MAR) along with a cyclones`dataset covering the Northern Hemisphere for the same period, we show the mean standardized anomalies of SMB and SEB over the GrIS when cyclones are in close proximity. Overall, our results, show a positive contribution of extratropical cyclones to the SMB during warm and cold seasons alike, especially via snowfall. In both winter and summer, cyclones enhance the downwelling longwave radiative flux due to higher temperatures and increased humidity. In summer an increase (decrease) of long-wave downward and relative humidity (sensible heat flux and temperature) is observed. In winter the impact on these surface energy variables is similar, apart for temperature which have an opposite sign. Overall, cyclones suppress melt and run-off, especially in the ablation zone and peripherals areas of the Ice Sheet during the warm season. Results from this study will contribute to better understanding of how the GrIS may respond in terms of SMB and SEB to changes in the North Atlantic storm tracks under global warming scenarios.

How to cite: Maffezzoni, L., Edwards, L., and Matthews, T.: The Impact of Extratropical Cyclones on the Greenland Ice Sheet, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8064, https://doi.org/10.5194/egusphere-egu2020-8064, 2020.

EGU2020-8476 | Displays | AS2.9

Antarctic Atmospheric River Climatology and Impacts

Jonathan Wille, Vincent Favier, Irina V. Gorodetskaya, Cécile Agosta, Jai Chowdhry Beeman, Ambroise Dufour, Francis Codron, and John Turner

Atmospheric rivers, broadly defined as narrow yet long bands of strong horizontal vapor transport typically imbedded in a low level jet ahead of a cold front of an extratropical cyclone, provide a sub-tropical connection to the Antarctic continent and are observed to significantly impact the affected region’s surface mass balance over short, extreme events. When an atmospheric river makes landfall on the Antarctic continent, their signature is clearly observed in increased downward longwave radiation, cloud liquid water content, surface temperature, snowfall, surface melt, and moisture transport.

Using an atmospheric river detection algorithm designed for Antarctica and regional climate simulations from MAR, we created a climatology of atmospheric river occurrence and their associated impacts on surface melt and snowfall. Despite their rarity of occurrence over Antarctica (maximum frequency of ~1.5% over a given point), they have produced significant impacts on melting and snowfall processes. From 1979-2017, atmospheric rivers landfalls and their associated radiative flux anomalies and foehn winds accounted for around 40% of the total summer surface melt on the Ross Ice Shelf (approaching 100% at higher elevations in Marie Byrd Land) and 40-80% of total winter surface melt on the ice shelves along the Antarctic Peninsula. On the other side of the continent in East Antarctica, atmospheric rivers have a greater influence on annual snowfall variability. There atmospheric rivers are responsible for 20-40% of annual snowfall with localized higher percentages across Dronning Maud Land, Amery Ice Shelf, and Wilkes Land.

Atmospheric river landfalls occur within a highly amplified polar jet pattern and often are found in the entrance region of a blocking ridge. Therefore, atmospheric river variability is connected with atmospheric blocking variability over the Southern Ocean. There has been a significant increase in atmospheric river activity over the Amundsen-Bellingshausen sea and coastline and into Dronning Maud Land region from 1980-2018. Meanwhile, there is a significant decreasing trend in the region surrounding Law Dome. Our results suggest that atmospheric rivers play a significant role in the Antarctic surface mass balance, and that any future changes in atmospheric blocking or tropical-polar teleconnections may have significant impacts on future surface mass balance projections.

How to cite: Wille, J., Favier, V., Gorodetskaya, I. V., Agosta, C., Beeman, J. C., Dufour, A., Codron, F., and Turner, J.: Antarctic Atmospheric River Climatology and Impacts , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8476, https://doi.org/10.5194/egusphere-egu2020-8476, 2020.

EGU2020-11296 | Displays | AS2.9 | Highlight

Recent and near future climate change in the Antarctic Peninsula

Deniz Bozkurt, David H. Bromwich, and Roberto Rondanelli

This study assesses the recent (1990-2015) and near future (2020-2045) climate change in the Antarctic Peninsula. For the recent period, we make the use of available observations, ECMWF’s ERA5 and its predecessor ERA-Interim, as well as regional climate model simulations. Given the different climate characteristics at each side of the mountain barrier, we principally assess the results considering the windward and leeward sides. We use hindcast simulations performed with Polar-WRF over the Antarctic Peninsula on a nested domain configuration at 45 km (PWRF-45) and 15 km (PWRF-15) spatial resolutions for the period 1990-2015. In addition, we include hindcast simulations of KNMI-RACMO21P obtained from the CORDEX-Antarctica domain (~ 50 km) for further comparisons. For the near future climate change evaluation, we principally use historical simulations and climate change projections (until 2050s, RCP85) performed with PWRF (forced with NCAR-CESM1) on the same domain configuration of the hindcast simulations. Recent observed trends show contrasts between summer and autumn. Annual warming (cooling) trend is notable on the windward (leeward) coasts of the peninsula. Unlike the reanalysis, numerical simulations indicate a clear pattern of windward warming and leeward cooling at annual time-scale. These temperature changes are accompanied by a decreasing and increasing trend in sea ice on the windward and leeward coasts, respectively. An increasing trend of precipitation is notable on the central and northern peninsula. High resolution climate change projections (PWRF-15, RCP85) indicate that the recent warming trend on the windward coasts tends to continue in the near future (2020-2045) and the projections exhibit an increase in temperature by ~ 1.5°C and 0.5°C on the windward and leeward coasts, respectively. In the same period, the projections show an increase in precipitation over the peninsula (5% to 10%). The more notable warming projected on the windward side causes more increases in surface melting (~ +20% to +80%) and more sea ice loss (-4% to -20%) on this side. Results show that the windward coasts of central and northern Antarctic Peninsula can be considered as "hotspots" with notable increases in temperature, surface melting and sea ice loss.

How to cite: Bozkurt, D., Bromwich, D. H., and Rondanelli, R.: Recent and near future climate change in the Antarctic Peninsula, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11296, https://doi.org/10.5194/egusphere-egu2020-11296, 2020.

EGU2020-11468 | Displays | AS2.9

Impacts of strong surface winds on Antarctic Polynya

Adrian McDonald

This study investigates the impacts of strong wind events on the sea ice concentration within polynya regions, with a focus on the Ross Sea Polynya (RSP). In particular, this work quantifies the sensitivity of sea ice concentrations to surface winds and whether there are threshold wind speeds required for regions of the polynya  to open up with subsequent impacts on air-sea heat fluxes. To analyse these processes, we examine version 3.1 of the Bootstrap sea ice concentration (SIC) satellite data set derived from SSM/I brightness temperatures and how they are connected to the surface winds from the ERA5 reanalysis over the period 1979 to 2018. While we examine these relationships around the entire Antarctic continent, we focus on the RSP and low-level jets in the Ross Sea. In particular, we examine how strong wind events which impact SIC in the RSP are linked to Ross Ice Shelf Air Stream events (strong low-level jets in the region). The hypothesis that the increase in Ross Ice Shelf Air Stream events, associated with a strengthening of the Amundsen Sea Low, has contributed to trends in sea ice production in this region is examined.

How to cite: McDonald, A.: Impacts of strong surface winds on Antarctic Polynya, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11468, https://doi.org/10.5194/egusphere-egu2020-11468, 2020.

EGU2020-12285 | Displays | AS2.9

Atmospheric Dynamics Footprint on the January 2016 Ice Sheet Melting in West Antarctica

Xiaoming Hu, Sergio Sejas, Ming Cai, Zhenning Li, and Song Yang

In January of 2016, the Ross Sea sector of the West Antarctic Ice Sheet experienced a three-week long melting episode. Here we quantify the association of the large-extent and long-lasting melting event with the enhancement of the downward longwave (LW) radiative fluxes at the surface due to water vapor, cloud, and atmospheric dynamic feedbacks using the ERA-Interim dataset. The abnormally long-lasting temporal surges of atmospheric moisture, warm air, and low clouds increase the downward LW radiative energy flux at the surface during the massive ice-melting period. The concurrent timing and spatial overlap between poleward wind anomalies and positive downward LW radiative surface energy flux anomalies due to warmer air temperature provides direct evidence that warm air advection from lower latitudes to West Antarctica causes the rapid long-lasting warming and vast ice mass loss in January of 2016.

How to cite: Hu, X., Sejas, S., Cai, M., Li, Z., and Yang, S.: Atmospheric Dynamics Footprint on the January 2016 Ice Sheet Melting in West Antarctica, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12285, https://doi.org/10.5194/egusphere-egu2020-12285, 2020.

The present study investigated dominant characteristics of autumn Arctic sea ice concentration (SIC) interannual variations, and examined impacts of SIC anomalies in the East Siberian-Chukchi-Beaufort (EsCB) Seas on winter Eurasian climate variability and the associated possible physical mechanism. Results showed that the Arctic SIC variations in both September and October display a certain continuity to some extent, thus, we chose the September-October (SO) mean SIC as a factor to explore its delayed impacts on winter atmosphere. Dominant features of Arctic SIC variability in SO is characterized by sea ice loss in the EsCB Seas, with more evident interannual variability since the late 1990s. Such a change can be attributed to the central Arctic pattern of atmospheric variability. Along with the global warming, the interannual variation of sea ice in the EsCB Seas seemingly exerts an increasingly role in the Northern Hemispheric climate variability. When the EsCB sea ice decreases in the early autumn (SO), a barotropic response of wave number 2 structure with significant warming and positive geopotential height anomaly dominates the Arctic region a month later. Then, in the early winter (ND(0)J(1)), the Arctic anticyclonic anomaly extends southward into the central-western Eurasia and leads to evident surface cooling there. Two month later, it further develops toward downstream accompanied by a deepened trough, making the East Asia experience a colder late winter (JFM(1)), especially in the northeastern China. Meanwhile, enhanced North Pacific anticyclonic perturbation excites an eastward wave train and contributes to positive geopotential height anomaly around the Greenland. Combined with a cyclonic anomaly to its southeast, a dipole structure forms and favors negative surface temperature anomaly covering the western Europe. In addition, a weakened polar vortex in the lower stratosphere can be observed during the boreal winter. Similar atmospheric responses to EsCB sea ice loss are well reproduced in the simulation experiments, not only supporting the conclusions from observational analyses, but also illustrating the possible physical mechanism to some extent.

How to cite: Ding, S., Wu, B., and Chen, W.: Dominant Characteristics of early autumn Arctic sea ice variability and its impact on Winter Eurasian climate, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12370, https://doi.org/10.5194/egusphere-egu2020-12370, 2020.

EGU2020-13492 | Displays | AS2.9

Lagrangian Analysis of the Dynamical and Thermodynamic Drivers of Greenland Melt Events during 1979-2017

Mauro Hermann, Lukas Papritz, and Heini Wernli

Specific atmospheric circulation patterns can lead to strongly positive near-surface temperature anomalies over Greenland, fostering the occurrence of extensive surface melt events. In this study, we objectively identify 77 Greenland melt events in June-August 1979-2017, which also affect high-elevated regions of the Greenland ice sheet (GrIS), from ERA-Interim reanalysis data. Eight-day backward trajectories from the lowermost 500 m above the GrIS are used to investigate the air mass history and the synoptic, dynamical, and thermodynamic drivers of Greenland melt events. The key synoptic feature is a high-pressure system, in 65% of the events classified as atmospheric blocking, southeast of the GrIS. It is favorably located to induce rapid and long-range poleward transport of anomalously warm air masses (compared to climatology) from the lower troposphere to the GrIS. Due to orographic and dynamical lifting, latent heating from condensation of water vapor contributes additionally to the air mass’ warm anomaly - most important for melt events on top of the GrIS. Adiabatic warming by subsidence, however, is insignificant, in contrast to warm events in the central Arctic. Exemplarily, the warm anomaly of air masses arriving in the Summit area during the most extensive melt event in early July 2012 arose due to strong meridional transport, mainly from the western North Atlantic, and latent heat release during ascent to Greenland. The simultaneous occurrence of a North American record heat wave did not play any direct role for the Greenland melt event. Further, regionally varying short- and longwave radiative effects induced by the warm-moist air masses enhance melt all over the GrIS. The identified mechanisms that cause Greenland melt events imply that the understanding of the formation of high-pressure systems and their representation in climate models is crucial in determining future GrIS melt. More generally, we highlight the importance of atmospheric dynamics and air flow patterns for Greenland melt events as they eventually determine the temperature pattern and surface energy budget over the GrIS with consequences for global sea-level rise.

How to cite: Hermann, M., Papritz, L., and Wernli, H.: Lagrangian Analysis of the Dynamical and Thermodynamic Drivers of Greenland Melt Events during 1979-2017, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13492, https://doi.org/10.5194/egusphere-egu2020-13492, 2020.

EGU2020-15597 | Displays | AS2.9

Spatial and temporal variations of air temperature inversions over different surface types on Ammassalik Island (East Greenland)

Iris Hansche, Jakob Abermann, Sonika Shahi, and Wolfgang Schöner

Air temperature inversion, a situation in which atmospheric temperature increases with height, is a common feature in the Arctic planetary boundary layer. This stable layer has multiple consequences for the Arctic environment. While vertical gradients of flora and fauna are impacted by them, they also have a direct consequence on physical characteristics such as permafrost thaw depths and snow cover. Therefore, a comprehensive knowledge about the spatial and temporal variability of temperature inversion parameters such as thickness, intensity, magnitude and frequency is crucial for the surface impact of Arctic climate change.

Here, we investigate the spatial and temporal variations of temperature inversions over different surface types on Ammassalik Island in East Greenland. During a field campaign in summer 2019, high temporal resolution profiles of atmospheric variables such as air temperature, humidity and pressure were collected using UAVs. We acquired 147 profiles in a period of 13 days (06/07/2019-18/07-2019) over different surface types (rock, gravel, snow, ice) and with varying distance to the ocean (between 0 and 6 km). We found a distinct air temperature inversion present in most of the profiles whereby height and thickness differ considerably. Both ocean and ice surface act as near-surface cooling agents, which favours the development of surface inversions. The ice-free area between ocean and glacier tends to warm up strongly during Arctic summer and those different drivers manifest in an intricate pattern of air temperature stratification along a valley axis.

Our high-frequency and high-resolution profiles are compared with longer time series from the nearby Tassiilaq radiosonde and with ERA-5 reanalysis data in order to bring our campaign data into a larger spatio-temporal context. We conclude that the radiosonde is able to resolve the general pattern well but it fails in adequately representing the stratification relevant for glacio-meteorological processes.

How to cite: Hansche, I., Abermann, J., Shahi, S., and Schöner, W.: Spatial and temporal variations of air temperature inversions over different surface types on Ammassalik Island (East Greenland), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15597, https://doi.org/10.5194/egusphere-egu2020-15597, 2020.

EGU2020-15627 | Displays | AS2.9

Dynamical mechanism of the poleward intensification of the Southern Hemispheric Westerlies due to sea ice extent change

Hyeong-Gyu Kim, Joowan Kim, Sang-Yoon Jun, and Seong-Joong Kim

Paleoclimate data shows a good correlation between the concentration of CO2 and atmospheric temperature in the geological timescale. Many studies compare the Last Glacial Maximum (LGM) and the Pre-Industrial era (PI), to understand the coupling processes. A popular mechanism explaining this coupling process is a modulation of the ocean circulation and related CO2 emission over the Southern Ocean due to atmospheric westerly. The atmospheric westerly plays an important role in driving ocean circulation; however, the related processes are not fully understood for the LGM period.

In this study, we examine physical processes determining the characteristics of the atmospheric westerly focusing on the Southern Ocean. Atmospheric states for LGM and PI are reproduced using a coupled earth system model with different sea ice conditions. A poleward intensification of the Southern Hemispheric Westerlies is observed for the LGM experiment. A comparison to PI shows that the meridional temperature gradient largely determines this intensification, and the enhanced meridional gradient is observed due to decreased heat flux from the subantarctic ocean in the LGM experiment. This result suggests that the Antarctic sea ice is a crucial component for understanding the Southern Hemispheric Westerly.

How to cite: Kim, H.-G., Kim, J., Jun, S.-Y., and Kim, S.-J.: Dynamical mechanism of the poleward intensification of the Southern Hemispheric Westerlies due to sea ice extent change, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15627, https://doi.org/10.5194/egusphere-egu2020-15627, 2020.

EGU2020-18765 | Displays | AS2.9

Blowing snow in Antarctica and its contribution to the surface mass balance

Franziska Gerber, Varun Sharma, and Michael Lehning

On the windiest, coldest and driest continent of the world, blowing snow is frequently active, especially during the winter months. Coastal regions with strong katabatic winds are especially prone to blowing snow and its sublimation. However, the contribution of blowing snow to the surface mass balance from snow blown off the continent and blowing snow sublimation is not well constraint by direct measurements. Furthermore, model and satellite assessments disagree on the magnitude of the effect.

Current studies of the Antarctic surface mass balance are mainly based on regional climate models. However, most models rely on rather simple representations of the snow cover as well as blowing snow. With the aim of improving the surface mass balance representation and specifically snow transport and sublimation due to blowing snow, we coupled the well-established snow model SNOWPACK to the Weather Research and Forecasting Model (WRF). The new coupled model, called ‘CRYOWRF’, is aimed at an improved representation of snow and snow-atmosphere interaction in all cryospheric environments.

CRYOWRF simulations show good agreement with measurements at meteorological stations on the Antarctic continent. Moreover, the timing of modeled blowing snow events agrees well with few local blowing snow measurements. Monthly frequencies of simulated and satellite-derived spatial blowing snow distributions result in similar patterns. We will present estimates of the amount and importance of blowing snow on the surface mass balance in Antarctica based on 8 years of simulations (2010-2018), with a special focus on blowing snow sublimation. The introduced model will be useful for future predictions of surface mass balance estimates, which are important to assess the contribution of the Antarctic ice sheet to sea level rise in a warming world.

How to cite: Gerber, F., Sharma, V., and Lehning, M.: Blowing snow in Antarctica and its contribution to the surface mass balance, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18765, https://doi.org/10.5194/egusphere-egu2020-18765, 2020.

EGU2020-19488 | Displays | AS2.9

The response of Northern Hemisphere polar lows to2climate change in a 25 km high-resolution global climate model

Len Shaffrey, Helene Bresson, Kevin Hodges, and Giuseppe Zappa

Polar lows are small, intense cyclones that form at high latitudes during winter. Their high wind speeds and heavy precipitation can have substantial impacts on shipping, coastal communities and infrastructure. However, climate models typically have low resolutions and therefore poorly simulate Polar Lows. This reduces the confidence that can be placed in future projections of extreme high latitude weather and associated risks.

In this study, Polar Lows are assessed for the first time in a high-resolution (25 km) global climate atmosphere-only model, N512 HadGEM3-GA3, for both present-day and future RCP 8.5 climate scenarios. Using an objective tracking algorithm, the representation of Polar Lows in the N512 HadGEM3-GA3 present-day simulation is found to agree reasonably well the NCEP-CFS reanalysis. RCP8.5 scenario conditions are generated by adding SST changes between 1990-2010 and 2090-2110 from the RCP8.5 experiments with the HadGEM2-ES model to observed SSTs from the present-day climate. In the RCP8.5 N512 HadGEM-GA3 simulations, the number of Northern Hemisphere Polar Lows are projected to substantially decrease (by over 60%) by the end of the 21st century, which is largely due to an increase in atmospheric static stability. However, new regions of Polar Low activity along the northern Russian coastlines are found where the Arctic sea ice is projected to retreat.

How to cite: Shaffrey, L., Bresson, H., Hodges, K., and Zappa, G.: The response of Northern Hemisphere polar lows to2climate change in a 25 km high-resolution global climate model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19488, https://doi.org/10.5194/egusphere-egu2020-19488, 2020.

EGU2020-19718 | Displays | AS2.9 | Highlight

Air mass source regions associated with enhanced surface melting of the Greenland Ice Sheet

Thomas Mote, Jonathon Preece, Lori Wachowicz, Kyle Mattingly, and Thomas Ballinger

The Greenland ice sheet has experienced increased surface melt and mass loss since the mid-1990s. Surface melt and surface mass balance are partially driven by large-scale changes in atmospheric circulation, which can direct anomalously warm and humid air masses over the ice sheet and lead to pulses of extensive melt and high runoff rates. However, the connection between the air mass source regions and ice sheet surface melt is poorly understood. Here we examine extreme melt pulses (>95th percentile melt extent for 3 or more days) for topographically defined regions of the ice sheet during the months of June, July, and August. Daily melt extent is determined from a satellite passive microwave product. The NOAA Air Resources Laboratory HYSPLIT model is used to calculate 10-day back-trajectories leading up to melt pulses. We apply a clustering algorithm separately for each region and initialization altitude to visualize the predominant tracks of air masses that impact the ice sheet during extensive melt events. Potential temperature at 2 PVU is used to trace atmospheric motion prior to melt onset. Particular attention is given to extreme events that led to melt at the highest elevations of the ice sheet, Summit Station. Results show the difference in source region east and west of the ice divide, and the important role of air mass source regions from North America and Europe.

How to cite: Mote, T., Preece, J., Wachowicz, L., Mattingly, K., and Ballinger, T.: Air mass source regions associated with enhanced surface melting of the Greenland Ice Sheet, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19718, https://doi.org/10.5194/egusphere-egu2020-19718, 2020.

AS2.10 – Atmosphere – Cryosphere interaction with focus on transport, deposition and effects of dust, black carbon, and other aerosols

EGU2020-8256 | Displays | AS2.10 | Highlight

Possible albedo reduction due to light absorbing impurities in snowpack observed at various sites

Teruo Aoki, Masashi Niwano, Sumito Matoba, Tomonori Tanikawa, Yuji Kodama, and Yoichiro Hirozawa

Possible albedo reduction due to light absorbing impurities (LAI) in snowpack observed at various sites in the world are investigated. Reviewing previously measured black carbon (BC) concentrations, their values distribute in a range of 0.07-0.25 ppbw (ng of BC in g of snow) in Antarctica, 0.55-20 ppbw in Greenland Ice Sheet (GrIS), 4.4-87.6 ppbw for the other Arctic except GrIS, and 4-1221 ppbw for mid-latitudes. As albedo reduction rate by LAI depends on snow grain size, it is more enhanced by larger grain snow such as melt form (melting snow) than smaller grain snow such as precipitation particles (new snow). By assuming two typical snow grain radii rs = 1000 and 50 µm, respectively for those snow grain shapes, the albedo reduction as a function of BC concentration can be calculated with physically based snow albedo model. The result indicates that albedo in Antarctic snow is not affected by BC in any case of snow grain radius. In GrIS albedo reduction due to BC is small around 0.006 for rs = 50 µm (new snow) but it rises to 0.026 for rs = 1000 µm (melting snow), suggesting a few percent of albedo reduction could occur under warmer climate condition due to enhanced snow metamorphism. In the other Arctic except GrIS, the maximum albedo reductions for rs = 50 µm (1000 µm) are 0.015 (0.064) at the maximum BC concentration (87.6 ppbw). For. mid-latitudes, it is 0.070 (0.24) for rs = 50 µm (1000 µm) at the maximum BC concentration (1221 ppbw). These results mean albedo reduction in highly polluted area of mid-latitudes cannot be ignored even in case of new snow and is more serious for melting snow.

We have conducted energy budget and snow pit observations at Sapporo (43°N, 141°E, 15 m a.s.l), Japan since 2005. In addition, elemental carbon (EC~BC) and mineral dust concentrations in snowpack were also monitored for snow samples collected twice a week from 2007 by the thermal optical reflectance (TOT) method and gravimetric measurement of a filter. During 10 years from 2007 to 2017, the medians of EC and dust concentrations are 196 ppbw and 2700 ppbw, respectively. Using those data, contribution of LAI to albedo reduction and the radiative forcing (RF) were estimated. The 10-year-mean albedo reduction and RF due to BC+dust are 0.053 and +6.7 Wm-2, respectively, in which BC effect on albedo reduction is 5.6 times larger than dust. The albedo reduction by BC+dust for only melting period is 0.151, that is 4.8 times larger than that for accumulation period. The effect of LAI on albedo reduction is enhanced by snow grain growth as well as an increase of LAI in melting period compared to that for accumulation season.

How to cite: Aoki, T., Niwano, M., Matoba, S., Tanikawa, T., Kodama, Y., and Hirozawa, Y.: Possible albedo reduction due to light absorbing impurities in snowpack observed at various sites, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8256, https://doi.org/10.5194/egusphere-egu2020-8256, 2020.

EGU2020-8723 | Displays | AS2.10

Dust and Black Carbon size distributions in snow and some links to snow physics.

Didier Voisin, Julien Witwicky, François Tuzet, Dimitri Osmont, and Marie Dumont

Snow contain many insoluble particles, some of which can absorb light (such as mineral dust and black carbon) and are responsible for a large climate forcing, both directly through their influence on snow albedo and indirectly by inducing snow metamorphism – albedo feedbacks.

Light absorbing particles (LAPs) influence snow metamorphism and melting by changing the heat distribution in the snowpack. Conversely, some physical processes in snow influence the size distribution of LAPs in the snowpack: for example, melting partially redistributes the particles and dry metamorphism can induce vertical movement of particles. Yet, few studies investigate those couplings due to the scarcity of detailed physical and chemical characterization of snow.

During two consecutive winters, such detailed characterization of snow was conducted at a high altitude site in the Alps (col du Lautaret, 2058m a.s.l.). The physical properties used here include detailed profiles of snow types enabling to investigate links between LAPs size distribution and snow evolution.

Size distributions analysis shows that for both black carbon (BC) and mineral dust, concentrations are often underestimated due to a significant fraction of particles being too big to be detected by the instruments. The median value of this undetected fraction is at least 20% for dust and at least 5% for BC. In more than 10% of the samples, It even exceeds 60% for dust and 25% for BC.

We then used stratigraphic data to explore the impact of partial melt and refreeze on LAP size distributions through an hypothetic coagulation mechanism induced by freeze-thaw cycles. No visible effect was found for dust, due to the higher variability of deposited particles size distributions. Conversely, freeze-thaw cycles seem to lead to a slight shift of BC size distributions toward the big particles.

How to cite: Voisin, D., Witwicky, J., Tuzet, F., Osmont, D., and Dumont, M.: Dust and Black Carbon size distributions in snow and some links to snow physics., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8723, https://doi.org/10.5194/egusphere-egu2020-8723, 2020.

EGU2020-15209 | Displays | AS2.10 | Highlight

Role of Saharan dust and black carbon deposition on snow cover in the French mountain ranges over the last 39 years.

Marion Réveillet, Marie Dumont, Simon Gascoin, Pierre Nabat, Matthieu Lafaysse, Rafife Nheili, François Tuzet, Martin Menegoz, and Paul Ginoux

Light absorbing particles such as black carbon(BC) or mineral dust are known to darken the snow surface when deposited on the snow cover and amplify several snow-albedo feedbacks, drastically modifying the snowpack evolution and the snow cover duration. Mineral dust deposition on snow is generally more variablein time than black carbon deposition and can exhibit both a high inter and intra annual variability. In France, the Alps and the Pyrenees mountain ranges are affected by large dust deposition events originating from the Sahara . The aim of this study is to quantify the impact of these impurities on the snow cover variability over the last 39 years (1979-2018).

For that purpose, the detailed snowpack model Crocus with an explicit representation of impurities is forced by SAFRAN meteorological reanalysis and a downscaling of the simulated deposition fluxes from a regional climate model (ALADIN-Climate). Different simulations are performed: (i) considering dust and/or BC (i.e. explicit representation), (ii) without impurities and (iii) considering an implicit representation (i.e. empirical parameterization based on a decreasing law of the albebo with snow age).

Simulations are compared at point scale to the snow depth measured at more than 200 Meteo-France’s stations in each massif, and spatially evaluated over the 2000-2018 period in comparing thesnow cover area, snow cover duration and the Jacard index to MODIS snow products. Scores are generally better when considering the explicit representation of the impurities than when using the snow age as a proxy for light absorbing particles content.

Results indicate that dust and BC have a significant impact on the snow cover duration with strong variations in the magnitude of the impact from one year to another and from one location to another.We also investigate the contribution of light absorbing particles depositionto snow cover inter-annual variability based on statistical approaches.

How to cite: Réveillet, M., Dumont, M., Gascoin, S., Nabat, P., Lafaysse, M., Nheili, R., Tuzet, F., Menegoz, M., and Ginoux, P.: Role of Saharan dust and black carbon deposition on snow cover in the French mountain ranges over the last 39 years., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15209, https://doi.org/10.5194/egusphere-egu2020-15209, 2020.

EGU2020-12123 | Displays | AS2.10

Modeling dust sources, transport, and radiative effects at different altitudes over the Tibetan Plateau

Zhiyuan Hu, Jianping Huang, Chun Zhao, Qinjian Jin, Yuanyuan Ma, and Pen Yang

Mineral dust plays an important role in the climate of the Tibetan Plateau (TP) by modifying the radiation budget, cloud macro- and microphysics, precipitation, and snow albedo. Meanwhile, the TP with the highest topography in the word can affect intercontinental transport of dust plumes and induce typical distribution characteristics of dust at different altitudes. In this study, we conduct a quasi-global simulation to investigate the characteristics of dust source contribution and transport over the TP at different altitude by using a fully coupled meteorology-chemistry model (WRF-Chem) with a tracer-tagging technique. Generally, the simulation reasonably captures the spatial distribution of satellite retrieved dust aerosol optical depth (AOD) at different altitudes. Model results show that dust particles are emitted into atmosphere through updrafts over major desert regions, and then transported to the TP. The East Asian dust (mainly from Gobi and Taklamakan deserts) transports southward and is lifted up to the TP, contributing a mass loading of 50 mg/m2 at 3 km height and 5 mg/m2 at 12 km height over the northern slop of the TP. Dust from North Africa and Middle East are concentrated over both northern and southern slopes below 6 km, where mass loadings range from 10 to 100mg/m2 and 1 to 10 mg/m2 below 3 km and above 9 km, respectively. As the dust is transported to the north and over the TP, mass loadings are 5-10 mg/m2 above 6 km.

The imported dust mass flux from East Asia to the TP is 7.9 Tg/year mostly occuring at the heights of 3–6 km. The North African and Middle East dust particles are transported eastward following the westerly jet, and then imported into the TP at West side with the dust mass flux of 7.8 and 26.6 Tg/year, respectively. The maximum mass flux of the North African dust mainly occurs in 0–3 km (3.9 Tg/year), while the Middle East within 6–9 km (12.3 Tg/year). The dust outflow occurs at East side (–17.89 Tg/year) and South side (–11.22 Tg/year) of the TP with a peak value (8.7 Tg/year) in 6–9 km . Moreover, the dust mass is within the size range of 1.25~5.0

How to cite: Hu, Z., Huang, J., Zhao, C., Jin, Q., Ma, Y., and Yang, P.: Modeling dust sources, transport, and radiative effects at different altitudes over the Tibetan Plateau, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12123, https://doi.org/10.5194/egusphere-egu2020-12123, 2020.

EGU2020-11669 | Displays | AS2.10

Black Carbon deposition on snow from Antarctic Peninsula

Francisco Cereceda-Balic, Maria Florencia Ruggeri, Victor Vidal, and Humberto Gonzalez

Atmospheric Black carbon (BC) strongly affects direct radiative forcing and climate, not only while suspended in the atmosphere but also after deposition onto high albedo surfaces, which are especially sensitive, because the absorption of solar radiation by deposited BC accelerate the snowpack/ice melting. In the Southern Hemisphere, the BC generated in the continents can be transported through the atmosphere from low and mid-latitudes to Antarctica, or it can be emitted in Antarctica by the anthropogenic activities developed in situ.  To assess the potential origin of the BC deposited in the snow of the Antarctic, and establish a possible relationship with the human activities that are carried out there, snow samples were taken in different sites from the Antarctic peninsula during summer periods: Chilean Base O’Higgins (BO), 2014; La Paloma Glacier 2015 and 2016 (at a distance of 6 km separated from BO); close to Chilean Base Yelcho (BY), 2018 and away from Chilean Base Yelcho 2018 (at a distance of 5 km separated from BY). Shallow snow samples were collected in Whirl-Pak (Nasco) plastics bags from the top of the snowpack, in an area of 1 m2 and 5 cm thick layer, using a clean plastic shovel and disposable dust-free nitrile gloves. Sample weighed around 1500-2000 g, and they were kept always frozen (-20 °C), during transport and storage, until they could be processed in the laboratory. BC concentration in the snow samples was determined by using a novel methodology recently developed, published and patent by the authors (Cereceda et al 2019, https://doi.org/10.1016/j.scitotenv.2019.133934; US 16/690,013-Nov, 2019 ). The methodology consisted of a filter-based optical method where snow samples were microwave-assisted melted, then filtered through a special filtration system able to generate a uniform BC spot on Nuclepore 47 mm polycarbonate filters (Whatman, UK). BC deposited in filters was analyzed using a SootScan™, Model OT21 Optical Transmissometer (Magee Scientific, USA), where optical transmission was compared between the sample and a reference filter at a wavelength of 880 nm. The BC mass concentration was calculated using a 5-points calibration curve, previously prepared using real diesel BC soot as standard.  Results showed a BC concentration in snow of 1283.8 ± 1240 µg kg-1. Snow from O’Higgins Base presented the highest BC concentration (3395.7 µg kg-1), followed by snow from the site close to Yelcho Base (1309.2 µg kg-1), snow from La Paloma Glacier 2016 (745.9 µg kg-1), snow from the site away from Yelcho Base (734.5 µg kg-1) and snow from La Paloma Glacier 2015 (233.6 µg kg-1). BC values observed in Antarctic snow were higher than others previously reported in the literature (Cereceda et al 2019) and showed the influence that anthropic activities have in the study area, considering that the two highest values of BC concentration in snow were found at sites near the bases, which presented levels comparable to those found in snowy sites in the Andes, continental Chile (Cereceda et al 2019).

How to cite: Cereceda-Balic, F., Ruggeri, M. F., Vidal, V., and Gonzalez, H.: Black Carbon deposition on snow from Antarctic Peninsula , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11669, https://doi.org/10.5194/egusphere-egu2020-11669, 2020.

EGU2020-21231 | Displays | AS2.10

Black Carbon and Light-absorbing impurities in the Antarctic Peninsula

Raul Cordero, Alessandro Damiani, Sarah Feron, Alia Khan, Jose Jorquera, Edgardo Sepulveda, Juan Carrera, and Penny Rowe

Assessing the albedo response due to light-absorbing impurities (LAI) in coastal snowpacks has become of great interest in the light of the ‘Antarctic greening’. Reductions in the albedo (triggered by a change in air temperature or by the LAI deposition) can also enhance feedback mechanisms; as the albedo drops, the fraction of absorbed solar energy increases, which leads to additional albedo drops.

Here we assess the presence of Black Carbon (BC) and LAI in coastal snowpacks in the Antarctic Peninsula. The BC-equivalent contentwas assessed by applying the meltwater filtration (MF) technique to snow samples taken at 7 locations in theAntarctic Peninsula, from latitude 62oS to latitude 67oS. BC-equivalentconcentrations exhibited significant geographical differences,but were found to be generally lower than 5 ng/g (in the range of those reported for the Arctic Ocean and Greenland). Moreover, the Angstrom coefficients were found to be particularly high at the northern tip of the Antarctic Peninsula,likely due to the snow algae presence. After the onset of melt, red snow algae bloom, significantly affecting the surface albedo, as shown by our measurements.

How to cite: Cordero, R., Damiani, A., Feron, S., Khan, A., Jorquera, J., Sepulveda, E., Carrera, J., and Rowe, P.: Black Carbon and Light-absorbing impurities in the Antarctic Peninsula , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21231, https://doi.org/10.5194/egusphere-egu2020-21231, 2020.

Black carbon (BC) has been pointed as the second largest contributor to climate change after greenhouse gases due to its superior ability to absorb solar radiation. This characteristic is particularly relevant in cryospheric environments, where the presence of BC has been related to a decrease in the albedo of ice/snow surfaces and the acceleration of their melting. In this sense, determination and quantification of BC levels in remote areas can be useful when defining and differentiating emission sources from which they come, considering the importance that the resources of the cryosphere mean for the surrounding populations for drinking water supply, agriculture, hydropower, mining, etc.

In this work, measurements of atmospheric BC from August 2016 to November 2019, carried out in Portillo, Chilean Central Andes, in the "Nunatak" laboratory-refuge (32°50’43’’S, 70°07’47’’W, 3000 m.a.s.l) are presented. This site, located in the highest altitude sector of the Andes mountain range, is very close to “Los Libertadores”, the border between Chile and Argentina. The road connecting both countries has a very high traffic density, with many passenger cars and trucks traveling in both directions. Due to weather, this route has a seasonal operating schedule. During the austral summer (September 1 - May 31) vehicular traffic is allowed 24 hours a day, while in winter (June 1 - August 31) traffic is allowed only from 8 am to 8 pm. Additionally, during heavy snowfalls, the access for vehicles is banned. To establish the impact of vehicular traffic on the atmospheric BC levels in the area, BC concentrations were continuously monitored by a Multi-Angle Absorption Photometer (MAAP) (Model 5012, Thermo). BC was measured in PM2.5, sampled on a glass filter tape an inlet air flow of 1.0 m3 h−1. Measurements were based on the optical attenuation at a wavelength of 637 nm. Data were originally sampled in one-minute resolution, but hourly and monthly means were extracted for further analysis. Results showed a markedly seasonal profile. Summer months presented the highest levels of BC for all the studied years, when the max. values were observed during the night and early morning hours, reaching 2.1 µg m-3. In turn, during the day there were significant declines in BC concentrations, with min. BC values of 0.2 µg m-3. Conversely, for all the years studied, winter months had lower average BC values than the summer months, with a markedly different hourly profile, since the max. values (up to 1.7 µg m-3) were reached in noon and afternoon hours, while the min. values fell up to 0.1 µg m-3 during night and early morning hours. Furthermore, BC concentration levels in Portillo were measured at an altitude where the main glaciers of central Andes are, showing the impact that BC could cause in the nearby glaciers. This marked seasonal pattern is in line with the traffic operational schedule above-mentioned, suggesting that in the study area, vehicular traffic is the main emission source of atmospheric BC. These findings are key pieces to identifying and implementing successful strategies for mitigation and adaptation on climate change.

How to cite: Ruggeri, M. F., Vidal, V., and Cereceda-Balic, F.: Relationship between atmospheric BC concentration and vehicular traffic in high mountain locations, case of study: Portillo, Chilean Central Andes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11599, https://doi.org/10.5194/egusphere-egu2020-11599, 2020.

EGU2020-1645 | Displays | AS2.10 | Highlight

A 300-year high resolution Greenland ice record of large-scale atmospheric pollution by arsenic in the Northern Hemisphere

Khanghyun Lee, Changhee Han, Seong-Joon Jun, Jong Ik Lee, and Sungmin Hong

We report the first high-resolution record of arsenic (As) observed in Greenland snow and ice for the periods 1711 to 1970 and 2003 to 2009 AD. The results show well-defined large-scale atmospheric pollution by this toxic element in the Northern Hemisphere, beginning as early as the 18th century. The most striking feature is an abrupt, unprecedented enrichment factor (EF) peak in the late 1890s, with a ~30-fold increase in the mean value above the Holocene natural level. Highly enriched As was evident until the late 1910s; a sharp decline was observed after the First World War, reaching a minimum in the early 1930s during the Great Depression. A subsequent increase lasted until the mid-1950s, before decreasing again. Comparisons between the observed variations and Cu smelting data indicate that Cu smelting in Europe and North America was the likely source of early anthropogenic As in Greenland. Despite a significant reduction of ~80% in concentration and ~60% in EF from the 1950s to the 2000s, more than 80% of present-day As in Greenland is of anthropogenic origin, probably due to increasing As emissions from coal combustion in China. This highlights the demand for the implementation of national and international environmental regulations to further reduce As emissions.

How to cite: Lee, K., Han, C., Jun, S.-J., Lee, J. I., and Hong, S.: A 300-year high resolution Greenland ice record of large-scale atmospheric pollution by arsenic in the Northern Hemisphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1645, https://doi.org/10.5194/egusphere-egu2020-1645, 2020.

EGU2020-10260 | Displays | AS2.10

Deposition of Organic Compounds on Alpine Snow

Grant Francis, Dušan Materić, Elke Ludewig, Thomas Röckmann, and Rupert Holzinger

Currently, little is understood about the deposition and re-volatilisation of organic matter (OM) in snow. Understanding this balance for individual organic compounds has the potential to provide important information about present and past atmospheric conditions. This research investigates in detail the deposition and re-volatilisation rates for specific atmospheric OM that are present in alpine snow. Captured in the blank canvas of snow, any dissolved organic matter (DOM) in surface snow will reflect the relative abundances in the atmosphere once their deposition and revolatilisation rates are known. Likewise, DOM effectively preserved in glacial ice will also express relative atmospheric composition of past climates. A recent pilot study by D. Materić et al.[1] investigates the post-precipitation change of OM in snow near the Sonnblick Observatory in the Austrian Alps. Using proton transfer reaction mass spectrometry, surface snow samples taken over several days were analyzed, and any organics found were grouped by their similar dynamics. This research expands on this study by analyzing snow samples over a larger spatial domain around Sonnblick during the course of five days in conjunction with long-term snow sampling currently underway at the observatory. Together, analysis of these samples will reveal changes in OM in surface snow over the course of the entire melt season. This research also considers both filtered and unfiltered snow samples to differentiate and identify OM of different sizes that are present within each sample. Long-term measurements of post-precipitation OM in surface snow will provide more coherent trends for deposition and re-volatilisation rates of organics, which can be used to tie future measurements of DOM in surface snow to atmospheric OM.

How to cite: Francis, G., Materić, D., Ludewig, E., Röckmann, T., and Holzinger, R.: Deposition of Organic Compounds on Alpine Snow, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10260, https://doi.org/10.5194/egusphere-egu2020-10260, 2020.

EGU2020-9109 | Displays | AS2.10 | Highlight

Snow accumulation rate and atmospheric oxidation pathway proxies from nitrate isotopes in East Antarctica

Pete Akers, Joël Savarino, and Nicolas Caillon

Nitrate is naturally deposited in Antarctic snow and is detectable at low concentrations throughout our deepest ice cores. However, nitrate is photoreactive under ultraviolet light and experiences significant post-depositional loss. This nitrate loss favors 14NO3- over 15NO3-, and the resulting isotopic fractionation can be used as a proxy for duration of sunlight exposure. Here, we present nitrate isotope data (δ15N, δ18O, Δ17O) sampled from shallow snow cores and pits across East Antarctica. Our >30 sampling sites extend from coastal Adélie Land onto the high East Antarctic Plateau at Dome C and beyond, covering annual snow mass balances that range from 240 mm/yr to less than 30 mm/yr (water equivalent). The δ15N of nitrate at these sites show an inverse relationship with snow accumulation rate, with δ15N ≈ 20‰ at the coastal sites with the highest accumulations and δ15N ≈ 150-250‰ at the driest inland sites. This relationship develops because newly deposited nitrate is buried below the level of light penetration by new snow relatively quickly at high accumulation sites, but nitrate at drier sites can be exposed to sunlight for several years. After burial below the reach of sunlight, the δ15N signature of nitrate is preserved and thus offers a new proxy for snow accumulation rate in East Antarctic ice cores. In contrast, the oxygen isotopes of nitrate isotopically exchange with surrounding ice after burial, which complicates their interpretation. However, our large sample set allows an estimation of the rate of isotopic exchange at various sites, and the original isotopic values at the time of deposition may be approximated after correcting for this rate of exchange. These oxygen isotope values likely reflect in part the atmospheric oxidation history of the nitrate and its nitrogen oxide progenitor, but further study is needed to fully understand nitrate oxygen isotope dynamics.

How to cite: Akers, P., Savarino, J., and Caillon, N.: Snow accumulation rate and atmospheric oxidation pathway proxies from nitrate isotopes in East Antarctica, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9109, https://doi.org/10.5194/egusphere-egu2020-9109, 2020.

EGU2020-14064 | Displays | AS2.10

Ice-nucleating properties of Icelandic dust in mixed-phase cloud conditions

Nsikanabasi Umo, Caroline Schuapp, Pavla Dagsson Waldhauserová, Peter G. Weidler, Kristina Höhler, Olafur Arnalds, and Ottmar Möhler

The emission of natural dust particles into the atmosphere from the high-latitude/cold regions is fast-becoming more important than previously thought. Due to land use and climate changes, a vast expanse of land surface previously covered by ice is getting exposed; hence, leading to an increase in dust emissions from these regions. Currently, an estimated 500,000 km2 land surface area is contributing up to 100 Tg of dust annually1. Aside from the direct impact of this dust on the air quality and direct solar radiation budget, it can also influence the cloud glaciation processes. Many studies have clearly established that mineral dust aerosol particles are generally good ice-nucleating particles2. However, most of these ice nucleation studies have been conducted on dust from deserts and mid-latitude regions. At present, our understanding of the ice-nucleating abilities of dust from high-latitude regions is highly limited. Here, we report the first comprehensive quantification of ice-nucleating properties of dust obtained from a typical high-latitude region – Iceland. We engaged two laboratory set-ups for this investigation – the Aerosol Interactions and Dynamics in the Atmosphere (AIDA) cloud simulation chamber, and the Ice Nucleation Spectrum of Karlsruhe Institute of Technology (INSEKT). Based on the INAS density calculations which we adopted in quantifying the Icelandic dust ice-nucleating efficiencies, our current results show that dust from Iceland nucleates ice effectively in the range of ~ 103 – 1012 m-2 in the temperature range studied (266 K - 238 K). A preliminary assessment shows that from ~ 250 K its ice-nucleating abilities can compete with that of desert dust and agricultural soil dust. Currently, work is ongoing to understand the role that mineral composition plays in ice nucleation behaviour. Potentially, our new results suggest that the high-latitude dust source could contribute to the INP budget of clouds in the region and may influence precipitation and the climate conditions in high-latitude regions.

How to cite: Umo, N., Schuapp, C., Waldhauserová, P. D., Weidler, P. G., Höhler, K., Arnalds, O., and Möhler, O.: Ice-nucleating properties of Icelandic dust in mixed-phase cloud conditions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14064, https://doi.org/10.5194/egusphere-egu2020-14064, 2020.

EGU2020-2335 | Displays | AS2.10

Small scale spatial variability of spectral Albedo on Jamtalferner, Austria

Lea Hartl, Lucia Felbauer, Gabriele Schwaizer, and Andrea Fischer

Glacier albedo is one of the most important and most variable parameters affecting surface energy balance and directly impacts ice loss. We present preliminary results from a study aiming to quantify the range and variability of spectral reflectance on a glacier terminus and assess the effects of liquid water and impurities on ablation area reflectance. In a second step of the analysis, in-situ data is compared with Landsat 8 and Sentinel 2 surface reflectance products.

In-situ spectral reflectance data was collected for wavelengths from 350-1000nm, using a hand-held ASD spectroradiometer. 246 spectra were gathered along 16 profile lines.

The “brightest” profile has a maximum reflectance of 0.7 and consists of clean, dry ice. At several “dark” profiles, reflectance does not exceed 0.2. At these profiles, liquid water is present, often mixed with fine grained debris. Individual spectra can roughly be grouped into dry ice, wet ice, and dirt/rocks. However, transitions between groups are fluid and in practice these categories cannot always be clearly separated. The spread of reflectance values per profile is generally lower for darker profiles. The reflectance spectra for clean ice exhibit the typical shape found in literature, with highest reflectance values in the lower third of our wavelength range and declining values for wavelengths greater than approximately 580nm. For wet ice surfaces, the spectra follow roughly the same shape as for dry ice, but are strongly dampened in amplitude, with reflectance typically below 0.2.

For the comparison of in-situ and satellite data, we use a Sentinel 2A scene acquired the same day as the ground measurements and a Landsat 8 scene from the previous day. Both scenes are cloud free over the study area. The wavelength range of the in-situ data overlaps with Landsat 8 bands 1-5 and Sentinel 2 bands 1-9 and 8A, respectively.

Neither satellite captures the full range of in-situ reflectance values. In all bands in which both satellites overlap, Sentinel values are shifted up against Landsat, in the sense that the maximum values of the Sentinel data are closer to the maximum values measured on the ground, while the minimum Landsat data are closer to the minimum ground values. Comparing the mean of the spectral reflectances measured on the ground with the associated satellite band values yields Pearson correlation coefficients from 0.53 to 0.62 for Landsat and 0.3 to 0.65 for Sentinel. Correlation coefficients decrease significantly for lower resolution satellite bands.

When binning ground measurements by the associated satellite pixel, the difference between the median/mean ground value and the satellite value tends to decrease with increasing number of ground measurements mapped to unique satellite pixels. While this is expected, the relationship is not obviously linear for our data and differs between the satellites and different bands.

Further in-situ measurements and analysis of satellite data will be carried out to improve understanding of processes governing ablation area reflectance, satellite derived ablation area reflectance products, and the modelling of feedback mechanisms.

How to cite: Hartl, L., Felbauer, L., Schwaizer, G., and Fischer, A.: Small scale spatial variability of spectral Albedo on Jamtalferner, Austria, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2335, https://doi.org/10.5194/egusphere-egu2020-2335, 2020.

EGU2020-3299 | Displays | AS2.10

Water isotope and chemical records in a recent snow pit from Hercules Neve, northern Victoria Land, Antarctica

Songyi Kim, Yeongcheol Han, Soon Do Hur, HeeJin Hwang, Changhee Han, Sang-Bum Hong, Seong Joon Jun, Chaewon Chang, Seungmi Lee, Hyejin Jung, and Jeonghoon Lee

A snow pit samples contain information of atmospheric composition and weather condition for recent years. In this study, water isotope ratio and concentrations of major ions and rare earth elements (REE) were determined from a 2 m snow pit sampled at 5 cm intervals at Hercules Neve in northern Victoria Land, Antarctica (73° 03'S, 165° 25'E, 2900m). The water stable isotope ratios range from -45.10 to -29.51 ‰ for δ18O and from 355.8 to -229.2 ‰ for δD. From their clear seasonality, the snow pit is expected to cover the period of 2012–2015. The REE patterns reveal that there exist at least two distinct sources of terrestrial aerosols; One that makes superior contribution when sea salt input is high is likely located closer than another. 

How to cite: Kim, S., Han, Y., Hur, S. D., Hwang, H., Han, C., Hong, S.-B., Jun, S. J., Chang, C., Lee, S., Jung, H., and Lee, J.: Water isotope and chemical records in a recent snow pit from Hercules Neve, northern Victoria Land, Antarctica, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3299, https://doi.org/10.5194/egusphere-egu2020-3299, 2020.

EGU2020-15037 | Displays | AS2.10

Aerosol retrieval based on 10 years of passive remote sensing satellite measurements over the Arctic – validation and trend analysis

Soheila Jafariserajehlou, Marco Vountas, Larysa Istomina, and John P. Burrows

The Aerosol Optical Thickness (AOT) retrieval over the Arctic region is a challenging task due to uncertainties and difficulties in its prerequisites, mainly (i) cloud masking methods and (ii) modeling the underlying snow/ice surface. In the past this led to a large data gap over the Arctic which hampered our understanding of the direct/indirect aerosol effect on Arctic and global climate change. For the purpose of improving our knowledge, we present, for the first time, long-term AOT maps of snow and ice covered areas based on satellite remote sensing.

In this study, a previously developed aerosol retrieval algorithm over snow/ice, (Istomina et al., 2012; in IUP, University of Bremen) is used to retrieve AOT for a period of 10 years, 2002-2012, over the Arctic and to analyze its spatial and temporal changes. This algorithm is based on a multi-angle approach and uses pre-computed look-up tables to retrieve AOT.

The algorithm has been improved with respect to cloud masking (based on clear snow spectral shape) using the ASCIA cloud identification algorithm (Jafariserajehlou et al., 2019). The modified AOT retrieval algorithm is applied to observations from Advanced Along-Track Scanning Radiometer (AATSR) on European Space Agency’s (ESA) measurements. The retrieved dataset provides long-term AOT at a spatial resolution of 1 km2 over snow/ice covered surface in the extended Arctic region (60°- 90°) during polar day. The results show that Arctic haze events appearing every late-winter and early spring are very well captured in AATSR derived AOTs. To validate the retrieved AOTs, results are compared with ground-based AERONET data. The comparisons revealed partially excellent agreement but also limits of the retrieval algorithm are discussed. In addition, some preliminary results of a trend analysis of the long-term record will be presented. It is foreseen to use the results in the trans-regional research project (AC)³ investigating Arctic amplification.

References

[1] Istomina, L.: Retrieval of aerosol optical thickness over snow and ice surfaces in the Arctic using Advanced Along Track Scanning Radiometer, PhD thesis, University of Bremen, Bremen, Germany, 2012.

[2] Jafariserajehlou, S. and Mei, L. and Vountas, M. and Rozanov, V. and Burrows, J. P. and Hollmann, R., A cloud identification algorithm over the Arctic for use with AATSR/SLSTR measurements, Atmos. Meas. Tech., 12, 1059-1076, doi:10.5194/amt-12-1059-2019, 2019.

 

How to cite: Jafariserajehlou, S., Vountas, M., Istomina, L., and P. Burrows, J.: Aerosol retrieval based on 10 years of passive remote sensing satellite measurements over the Arctic – validation and trend analysis, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15037, https://doi.org/10.5194/egusphere-egu2020-15037, 2020.

EGU2020-3633 | Displays | AS2.10 | Highlight

Measurements and modelling of the impacts of light absorbing impurities during two contrasted snow seasons at Col du Lautaret

Marie Dumont, Francois Tuzet, Ghislain Picard, Maxim Lamare, Didier Voisin, Pierre Nabat, Matthieu Lafaysse, Fanny Larue, Jesus Revuelto, and Laurent Arnaud

Light absorbing impurities (LAP) in snow, such as dust or black carbon, trigger potent snow-climate feedbacks. However, detailed measurements of the evolution of LAPs in seasonal snow are scarce, especially in the Alps. Here, we conducted detailed measurements of LAP in snow, snow physical and optical properties in the French Alps at a high altitude site. The dataset includes chemical measurements of mineral dust and black carbon (precisely elemental carbon and refractory black carbon), as well as spectral albedo measurements. The analysis of this dataset reveals strong discrepancies between elemental carbon and refractory black carbon measured concentrations, making it challenging to link the content of LAP to their radiative impacts. Using the dataset, the ensemble version of the Crocus snow model is evaluated and used to estimate the impacts of light-absorbing particles on snow cover evolution. Their impact on snowmelt turns out to be extremely sensitive to both meteorological conditions and uncertainties of the snow model, with a median shortening of 10 days for both snow seasons.

How to cite: Dumont, M., Tuzet, F., Picard, G., Lamare, M., Voisin, D., Nabat, P., Lafaysse, M., Larue, F., Revuelto, J., and Arnaud, L.: Measurements and modelling of the impacts of light absorbing impurities during two contrasted snow seasons at Col du Lautaret, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3633, https://doi.org/10.5194/egusphere-egu2020-3633, 2020.

EGU2020-6556 | Displays | AS2.10

Impacts of Snow Darkening by Light-absorbing aerosols on the Water Cycle over the Western Eurasia and East Asia

Jeong Sang, Maeng-Ki Kim, William K. M. Lau, and Kyu-Myong Kim

In this paper, we have investigated the snow darkening effects by light-absorbing aerosols on the regional changes of the water cycle over the Eurasian continent using the NASA GEOS-5 Model with aerosol tracers and a state-of-the-art snow darkening module, the Goddard SnoW Impurity Module (GOSWIM) for the land surface. Two sets of ten-member ensemble experiments for 10-years were carried out forced by prescribed sea surface temperature (2002-2011) with different atmospheric initial conditions, with and without SDE, respectively. Results show that SDE can exert a significant regional influence in partitioning the contributions of evaporative and advective processes on the hydrological cycle, during spring and summer season. Over western Eurasia, SDE-induced rainfall increase during early spring can be largely explained by the increased evaporation from snowmelt. Rainfall, however, decreases in early summer due to the reduced evaporation as well as moisture divergence and atmospheric subsidence associated with the development of an anomalous mid- to upper tropospheric anticyclonic circulation. On the other hand, in the East Asian monsoon region, moisture advection from adjacent ocean is a main contributor to rainfall increase in the melting season. Warmer land-surface caused by earlier snowmelt and subsequent drying further increases moisture transport and convergence significantly enhancing rainfall over the region. This findings suggest that the SDE may play an important role in leading to hotter and drier summer over western Eurasia, through coupled land-atmosphere interaction, while enhancing East Asian summer monsoonal precipitation via enhanced land-ocean thermal contrast and moisture transport due to SDE-induced warmer Eurasian continent.

 

This work was supported by the Korea Meteorological Administration Research and Development Program under grant KMI2018-03410.

How to cite: Sang, J., Kim, M.-K., Lau, W. K. M., and Kim, K.-M.: Impacts of Snow Darkening by Light-absorbing aerosols on the Water Cycle over the Western Eurasia and East Asia , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6556, https://doi.org/10.5194/egusphere-egu2020-6556, 2020.

EGU2020-17565 | Displays | AS2.10 | Highlight

Deposition of brown carbon onto snow: changes of snow optical and radiative properties

Nicholas Beres, Deep Sengupta, Vera Samburova, Andrey Khlystov, and Hans Moosmüller

Light-absorbing organic carbon aerosol – colloquially known as brown carbon (BrC) – is emitted from combustion processes and has a brownish or yellowish visual appearance, caused by enhanced light absorption at shorter visible and ultraviolet wavelengths (0.3 µm ≤ λ ≤ 0.5 µm). Recently, optical properties of atmospheric BrC aerosols have become the topic of intense research, but little is known about how BrC deposition onto snow surfaces affects the spectral snow albedo, which can alter the resulting radiative forcing and in-snow photochemistry. Wildland fires in close proximity to the cryosphere, such as peatland fires that emit large quantities of BrC, are becoming more common at high latitudes, potentially affecting nearby snow and ice surfaces.

In this study, we describe the artificial deposition of BrC aerosol with known optical, chemical, and physical properties onto the snow surface and we monitor its spectral radiative impact and compare it directly to modeled values. First, using small-scale combustion of Alaskan peat, BrC aerosols were artificially deposited onto the snow surface. UV-vis absorbance and total organic carbon (TOC) concentration of snow samples were measured for samples with and without artificial BrC deposition. These measurements were used to estimate the imaginary part of the refractive index of deposited BrC aerosol with a volume mixing rule. Single particle optical properties were calculated using Mie theory, and these values were used to show that the measured spectral snow albedo of snow with deposited BrC was in general agreement with modeled spectral snow albedo using calculated BrC optical properties. The instantaneous radiative forcing per unit mass of BrC deposited to the ambient snowpack was found to be 1.23 (+0.14/-0.11) W m-2 per ppm.

How to cite: Beres, N., Sengupta, D., Samburova, V., Khlystov, A., and Moosmüller, H.: Deposition of brown carbon onto snow: changes of snow optical and radiative properties, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17565, https://doi.org/10.5194/egusphere-egu2020-17565, 2020.

EGU2020-18830 | Displays | AS2.10

Simulations of black carbon (BC) aerosol impact over Hindu-Kush Himalayan sites: validation, sources, and implications on glacier runoff

Sauvik Santra, Shubha Verma, Koji Fujita, Indrajit Chakraborty, Olivier Boucher, Toshihiko Takemura, John Faulkner Burkhart, Felix Matt, and Mukesh Sharma

Absorbing aerosols such as black carbon (BC) affects the cryospheric equilibrium by altering the ablation rate of snow. The influence of the albedo change on the glacial mass balance due to excess and earlier snow melting, and thereby an earlier glacier runoff, is expected to impact the downstream hydrology. This impact is specifically of concern for the Hindu Kush Himalayan (HKH) region as the Himalayan glaciers are the source of major rivers in South Asia, namely Ganges, Indus, Yamuna, and the Brahmaputra. While the measured data may serve as location and time-specific information, the ability of coarse-gridded models to adequately simulate the snow depth and thereby the BC concentration in snow and atmospheric BC radiative forcing is limited. In order to spatially map the estimates of atmospheric BC concentration and BC concentration in snow as adequately as possible, including the corresponding snow albedo reduction (SAR) over the HKH region, an integrated approach merging the relevant information from observations with a relatively consistent atmospheric chemical transport model estimates is applied in the present study. These estimates were based on free-running aerosol simulations (freesimu) and constrained aerosol simulations (constrsimu) from an atmospheric general circulation model, combined with numerical simulations of glacial mass balance model. BC concentration estimated from freesimu performed better over higher altitude (HA) HKH stations than that over lower altitude (LA) stations. The estimates from constrsimu mirrored well the measurements when implemented for LA stations. Estimates of the spatial distribution of BC concentration in the snowpack (BCC) over the HKH region led to identifying a hot-spot zone located around Manora peak. Among glaciers over this zone, BCC (> 60 μg kg−1) and BC-induced SAR (≈5%) were estimated explicitly being high during the pre-monsoon for Pindari, Poting, Chorabari, and Gangotri glaciers. The rate of increase of BCC in recent years (1961-2010) was, however, estimated being the highest for the Zemmu glacier. Sensitivity analysis with glacial mass balance model indicated the increase in annual runoff (ARI) from debris-free glacier area due to BC-induced SAR corresponding to BCC estimated for the HKH glaciers was 4%-18%, with the highest being for the Milam and Pindari glaciers. The rate of increase in annual glacier runoff per unit BC-induced SAR was specifically high for Milam, Pindari, and Shunkalpa glacier. Further analysis is carried out for other significant aerosol species, both anthropogenic and natural by origin (e.g. Sulfate, Organic carbon (OC) and Dust). Comparison of relative impact of aerosol constituents on the melting of snow from the glaciers, as well as the combined effects are estimated. The estimated ARI taking into account the effect of all the aerosols found to be significantly higher than in the case of only BC. The source-specific contribution to atmospheric BC aerosols by emission sources led to identifying the potential emission source being primarily from the biofuel combustion in the Indo-Gangetic plain south to 30° N, and open burning in a more remote region north to 30° N.

How to cite: Santra, S., Verma, S., Fujita, K., Chakraborty, I., Boucher, O., Takemura, T., Burkhart, J. F., Matt, F., and Sharma, M.: Simulations of black carbon (BC) aerosol impact over Hindu-Kush Himalayan sites: validation, sources, and implications on glacier runoff, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18830, https://doi.org/10.5194/egusphere-egu2020-18830, 2020.

EGU2020-20488 | Displays | AS2.10 | Highlight

Vertical distribution of aerosols in dust storms during the Arctic winter

Pavla Dagsson Waldhauserova, Jean-Baptiste Renard, Haraldur Olafsson, Damien Vignelles, Gwenaël Berthet, Nicolas Verdier, and Vincent Duverger

High Latitude Dust (HLD) contributes 5% to the global dust budget, but HLD measurements are sparse. Iceland has the largest area of volcaniclastic sandy desert on Earth where dust is originating from volcanic, but also glaciogenic sediments. Total Icelandic desert areas cover 44,000 km2 which makes Iceland the largest Arctic as well as European desert. Icelandic volcanic dust can be transported distances > 1700 km towards the Arctic and deposited on snow, ice and sea ice. It is estimated that about 7% of Icelandic dust can reach the high Arctic (N>80°). It is known that about 50% of Icelandic dust storms occurred during winter or subzero temperatures in the southern part of Iceland. The vertical distributions of dust aerosol in high atmospheric profiles during these winter storms and long-range transport of dust during polar vortex condition were unknown.

Dust observations from Iceland provide dust aerosol distributions during the Arctic winter for the first time, profiling dust storms as well as clean air conditions. Five winter dust storms were captured during harsh conditions.  Mean number concentrations during the non-dust flights were < 5 particles cm-3 for the particles 0.2-100 µm in diameter and > 40 particles cm-3 during dust storms. A moderate dust storm with > 250 particles cm-3 (2 km altitude) was captured on 10th January 2016 as a result of sediments suspended from glacial outburst flood Skaftahlaup in 2015. Similar particle number concentrations were reported previously in the Saharan air layer. Detected particle sizes were up to 20 µm close to the surface, up to 10 µm at 900 m altitude, up to 5 µm at 5 km altitude, and submicron at altitudes > 6 km.

Dust sources in the Arctic are active during the winter and produce large amounts of particulate matter dispersed over long distances and high altitudes. HLD contributes to Arctic air pollution and has the potential to influence ice nucleation in mixed-phase clouds and Arctic amplification.

 

Reference:

Dagsson-Waldhauserova, P., Renard, J.-B., Olafsson, H., Vignelles, D., Berthet, G., Verdier, N., Duverger, V., 2019. Vertical distribution of aerosols in dust storms during the Arctic winter. Scientific Reports 6, 1-11.

How to cite: Dagsson Waldhauserova, P., Renard, J.-B., Olafsson, H., Vignelles, D., Berthet, G., Verdier, N., and Duverger, V.: Vertical distribution of aerosols in dust storms during the Arctic winter, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20488, https://doi.org/10.5194/egusphere-egu2020-20488, 2020.

Seemingly small amounts of black carbon (BC) in snow, of the order of 10–100 parts per billion by mass (ppb), have been shown to decrease its albedo by 1–5 %. Due to the albedo-feedback mechanism, surface darkening accelerates snow and ice melt and contributes to Arctic warming.

Here we present the most recent procedures we use for sampling, filtering and analysis of Arctic snow, ice and water samples, to determine their black carbon (BC), organic carbon (OC) and total carbon (TC) contents. For the purpose, we apply the OCEC analyzer of the Finnish Meteorological Institute’s aerosol laboratory, Helsinki, Finland (60°12 N). Particles are collected on a quarz-fiber filter and subjected to different temperature ramps following the protocols (NIOSH-870, EUSAAR2, or IMPROVE). Pyrolysis correction is by laser transmittance. Light transmittance through the filter is monitored during the collection phase to quantify BC. The OCEC thermal-optical method is the current European standard method for determination of atmospheric BC.  

Our Arctic samples include surface snow and snow profile samples collected north of the Arctic Circle at the Finnish Meteorological Institute Arctic Space Center in Sodankylä, Finland (67◦37 N, 26◦63 E), which is also a World Meteorological Institute’s Global Atmospheric Watch station (WMO GAW). In addition, samples from H2020 EU-Interact stations of Faroes FINI, Iceland Sudurnes and UK Cairngorms, and elsewhere from Iceland and Finland, including Helsinki Kumpula SMEAR-III station (60°12 N, 24°57 E, Station for Measuring Ecosystem-Atmosphere Relations, https://www.atm.helsinki.fi/SMEAR/index.php/smear-iii) and the most northern research catchment area of Pallas (68°N, about 130 km north from the Arctic Circle, https://blogs.egu.eu/divisions/hs/2019/06/19/featured-catchment-series-pallas/), have been sampled and analyzed. The BC concentrations have been detected to vary according to the origin of the air masses and as a result of the seasonal snow melt process.

Acknowledgements. We gratefully acknowledge support from the EU-Interact-BLACK-project Black Carbon in snow and water (H2020 Grant Agreement No. 730938); the Academy of Finland NABCEA-project of Novel Assessment of Black Carbon in the Eurasian Arctic (No. 296302), Ministry for Foreign Affairs of Finland IBA-project Black Carbon in the Arctic and significance compared to dust sources (No. PC0TQ4BT-25); the Academy of Finland Center of Excellence program The Centre of Excellence in Atmospheric Science - From Molecular and Biological processes to The Global Climate (No. 272041), and The Nordic Center of Excellence CRAICC Cryosphere–Atmosphere Interactions in a Changing Arctic Climate.

 

 

How to cite: Meinander, O., Heikkinen, E., and Aurela, M.: Sampling, filtering and analyzing procedures for thermal-optical OCEC analysis to determine black carbon, organic carbon and total carbon concentrations in Arctic snow, ice and water samples, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7541, https://doi.org/10.5194/egusphere-egu2020-7541, 2020.

EGU2020-9607 | Displays | AS2.10

Visual and fluorescence characterisation of particulate aerosols in ice cores with imaging flow cytometry

Matthew Harris, Chris Fogwill, Ann Power, Chris Turney, John Love, Alix Cage, and Antonia Law

Current efforts to examine and quantify so-called ‘biomarkers’ present in polar ice samples offer exciting potential as biological and biochemical proxies for past climate and ocean dynamics. Here we present a new rapid and easily replicable method to provide measurements of the microscopic particulate content of ice samples from polar environments. Using an Amnis® Imagestream® Imaging Flow Cytometer, melted snow and ice samples from Patriot Hills in the Ellsworth Mountains, Antarctica were analysed for their particulate (biological and non-biological) content. Selective use of a nucleic acid stain pre-treatment allows for a straightforward gating strategy that resolves both autofluorescent and non-autofluorescent biological material in sample replicates. In the Patriot Hills samples this method clearly identifies marine picoplankton, along with non-biological particulates such as tephra and minerogenic material. Crucially, the 60x Brightfield images provided by the Imagestream offer a significant additional capability above standard flow cytometry systems; each object identified by the machine can be visually differentiated (automatically or manually) from particulates with similar fluorescence properties. Back-trajectory analysis with the NOAA Hybrid Single-Particle Lagrangian Integrated Trajectory (HySPLIT) model indicates that these ice-bound marine organisms originate from the Weddell and Amundsen-Bellingshausen Seas. This technique, when paired with established chemical and biochemical methods, shows considerable potential in providing valuable information about the nature and origin of aerosols and biomarker signals trapped in past ice layers.

How to cite: Harris, M., Fogwill, C., Power, A., Turney, C., Love, J., Cage, A., and Law, A.: Visual and fluorescence characterisation of particulate aerosols in ice cores with imaging flow cytometry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9607, https://doi.org/10.5194/egusphere-egu2020-9607, 2020.

EGU2020-3262 | Displays | AS2.10

A multiproxy approach to identify the Tambora volcanic fallout in 1810s from the Styx glacier in Victoria Land, Antarctica

Changhee Han, Songyi Kim, Yeongcheol Han, Jangil Moon, Sang-Bum Hong, Chaewon Chang, and Soon Do Hur

Ice cores provide records of past aerosol composition and have been used to reconstruct the relative contribution of different emission sources changing in time. A precise age scale is essential to achieve this goal, for which annual layer counting of seasonal cycles in water stable isotope ratios (δ18O and δD) and major ion concentrations have been basically utilized. Introducing additional time markers are helpful for reducing the uncertainty of the depth-age scale, and the fallout of volcanic products has offered useful time markers when they are well-dated. Here, we report lead isotope ratios (206Pb/207Pb and 208Pb/207Pb) and concentrations of thallium (Tl) and major ions in a shallow ice core from the Styx Glacier (73°51 S, 163°41 E) in the Victoria Land, Antarctica, analyzed for discriminating volcanic products of the 1815 AD Tambora eruption, Indonesia from local volcanic inputs. Mechanically decontaminated 19 inner core pieces between the depth interval 40.8 – 42.4 m were analyzed. The results show that the increases of volcanic SO42- input are accompanied by either (1) input of more-radiogenic lead (higher 206Pb/207Pb) and Tl or (2) relatively 208Pb enriched lead. These results suggest that the Tambora volcanic input is overprinted by local volcanic aerosol input and that the isotope-based assessment of the Pb sources can help to discriminate between remote and local components of the volcanic input signals recorded in Victoria Land glaciers.

How to cite: Han, C., Kim, S., Han, Y., Moon, J., Hong, S.-B., Chang, C., and Hur, S. D.: A multiproxy approach to identify the Tambora volcanic fallout in 1810s from the Styx glacier in Victoria Land, Antarctica, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3262, https://doi.org/10.5194/egusphere-egu2020-3262, 2020.

EGU2020-2997 | Displays | AS2.10

Effect from polynyas in the Laptev and the Beaufort seas to atmospheric transport of heat and moisture

Uliana Prokhorova, Alexandra Urazgildeeva, and Genrich Alexeev

Coastal and fast ice polynyas in the Arctic seas can have a noticeable effect on the Arctic climate, increasing the temperature of the cold air which coming from continental Siberia in winter to these seas and in the Arctic basin [1-2]. In this paper, were studied the effect of polynyas on surface air temperature and on the meridional heat and moisture transfers by the ERA-Interim reanalysis data. From reanalysis, meridional heat transfers were obtained through 70 ° N and 74 ° N, air temperature profiles, wind speed in the region of the Laptev (100 - 140 ° E.) and Beaufort (120 - 160 ° W.) Seas, and polynyas which located in the Laptev Sea (120 - 130 ° E) and Beaufort (160 - 140 ° W.). It was confirmed that winter transfers of cold air from the mainland do not have a cooling effect on the average winter air temperature north of 74 ° N due to the heating effect of polynyas.

How to cite: Prokhorova, U., Urazgildeeva, A., and Alexeev, G.: Effect from polynyas in the Laptev and the Beaufort seas to atmospheric transport of heat and moisture, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2997, https://doi.org/10.5194/egusphere-egu2020-2997, 2020.

Under most atmospheric conditions, the albedo and temperature of surface snow and ice are two of the main influences on the energy budget for glacier melting. Given that surface albedo and temperature are linked, knowing where and when negative albedo and positive surface temperature anomalies coincide is important for identifying locations and time periods in which anomalously high rates of surface melting are likely. We used measurements from the Moderate Resolution Imaging Spectroradiometer (MODIS) sensors on NASA's AQUA and TERRA satellites to map the albedo and surface temperature of snow and ice  on glaciers in the of Southern Rocky Mountain Trench ecoregion in the summer months (June-August) from 2000 to 2018. We use these data to identify specific regions and time periods in which low albedo and high surface temperature coincide since these conditions are likely to support anomalously high rates of surface melting. We also use these data to identify regions/periods in which albedo is particularly low while surface temperature is average or low, since such conditions suggest localized and/or short-term decoupling between the two parameters. We found anomalously low albedo and average/low temperature consistently at multiple glaciers during time periods when there were major forest fire events. We suggest the low albedo results from deposition of pyrogenic carbon from forest fires. We found that, on average, ~25% of the glaciers in the region experienced increasingly negative albedo anomalies and increasingly positive temperature anomalies in summer months from 2000 to 2018. However, we also found that for ~45% of the glaciers that are small, there was a poor correlation between the timing of albedo and temperature anomalies. Our results indicate that the correlation between albedo and temperature was weaker for the small glaciers, and identify specific glaciers that are likely the most vulnerable to climate warming.

How to cite: Naeimi, A. and Sharp, M.: Classification of glaciers during summer in Southern Rocky Mountain Trench using surface albedo and temperature anomalies, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3168, https://doi.org/10.5194/egusphere-egu2020-3168, 2020.

Using the latest daily MODIS satellite snow cover data, the present study reveals distinctly different sources of 10-30-day intraseasonal snow cover variations over the western and eastern Tibetan Plateau (TP) during September-December. The intraseasonal snow variation over the western TP is related to a mid-latitude wave train associated with the Arctic Oscillation and that over the eastern TP is related to a subtropical wave train triggered by the North Atlantic Oscillation. The Rossby wave train in both cases leads to anomalous water vapor convergence and ascending motion, which contributes to snow accumulation and positive snow cover anomalies. For the western TP snow events, the moisture comes from the Caspian Sea. During the eastern TP snow events, the moisture originates from the Bay of Bengal.

How to cite: Song, L.: Different Sources of 10-30-day Intraseasonal Variations of Autumn Snow over Western and Eastern Tibetan Plateau, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12158, https://doi.org/10.5194/egusphere-egu2020-12158, 2020.

AS2.12 – Physical processes of air-sea interaction and their representation in models

EGU2020-713 | Displays | AS2.12 | Highlight

Propagation of Freshwater Lenses as Buoyant Gravity Currents

Aurélie Moulin, James Moum, and Emily Shroyer

Freshwater lenses (FWL) deposited by rain create surface salinity and temperature anomalies that can persist for extended periods of time (> 1 day). The resulting patchiness in near-surface density and sea surface temperature influence upper ocean dynamics and air-sea fluxes of heat. For these reasons, understanding lens formation and evolution has been a focus of recent observational and modeling efforts. The work presented here integrates near-surface ocean and atmosphere time series with remote sensing of sea surface roughness (X-band radar) and precipitation (C-band radar) to describe the formation and temporal evolution of lenses within the equatorial Indian Ocean. Twenty-six FWLs are observed at different stages of their evolution from freshly deposited and actively spreading to older, passively advected features. Salinity anomalies reached -1.2 psu near the surface, while temperature anomalies were observed to be both cool (down to -0.8°C) and warm (up to +0.4°C). The largest density anomaly reached -0.5 kg/m3. Remotely-sensed, ship-based radar imagery allows for quantification of the observed propagation speeds of ten lenses, which follow internal gravity wave theory. These results offer a novel perspective on the evolution of FWLs whose dynamics need to be properly accounted for to assess lens longevity, including persistence of salinity and temperature anomalies, as well as influences to air-sea interactions.

How to cite: Moulin, A., Moum, J., and Shroyer, E.: Propagation of Freshwater Lenses as Buoyant Gravity Currents, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-713, https://doi.org/10.5194/egusphere-egu2020-713, 2020.

EGU2020-272 | Displays | AS2.12

Response of the North Atlantic circulation to the small-scale surface wind perturbations

Shenjie Zhou, Xiaoming Zhai, and Ian Renfrew

High-frequency and small-scale processes in the atmosphere have an important influence on the evolution of the underlying ocean. They can not only introduce variability to the coupled systems but also have long-term ramification effects on the sea surface temperature, thermocline structure and large-scale ocean general circulation via nonlinear interactions.

Comparisons between the newly-released ECMWF fifth-generation global climate reanalyses (ERA5) wind product and satellite/in-situ observations show that the latest reanalyses winds still considerably underestimate wind variability at high-frequencies and small-scales. A novel approach, Cellular Automata (CA), is used here to stochastically perturb the ERA5 wind field. CA, originally introduced into the weather forecast model to mimic the near-grid-scale variability associated with convective cloud clustering, generates spatially and temporally coherent perturbation patterns. Results show that the CA-perturbed ERA5 wind field enjoys an improved wavenumber spectrum, especially over high wavenumber bands (scales <400 km), when compared to the QuikSCAT measurements. In addition, including CA patterns also brings the level of wind variability at high-frequencies (>1 cpd) closer to in-situ mooring measurements. The local response of the upper ocean properties is investigated by a Multi-Column K-Profile Parameterization (MC_KPP) ocean mixed layer model over Atlantic section. It is found that overall the sea surface temperature (SST) decreases and oceanic boundary layer (OBL) deepens to respond to the enhanced surface turbulent heat loss and shear instability generated at the base of surface OBL caused by the small-scale wind perturbations. In particular, SST tends to decrease the most over the summer hemisphere by up to 1°C locally and 0.1°C averaging across the basin, in correlation with shallower background OBL and smaller OBL heat capacity. 

The ocean states under the forcing of stochastic wind perturbation as expressed by the local response are found rectified by a non-negilible magnitude. We argued that although the missed small-scale and high-frequency wind variability may be represented differently than our approach, our results highlighted the fact that these variabilities should take a singificant part in driving the current generation of coupled climate model. Furhtermore, the temproal and spatial variabilities of the local signals can pose significant influence on the large-scale ocean circulation in terms of their pathways, strengths and variabilities. The dynamical response of the ocean circulation is to be further understood with an eddy-resolving Massachusette Institute of Technology General Circulation Model (MITgcm).

How to cite: Zhou, S., Zhai, X., and Renfrew, I.: Response of the North Atlantic circulation to the small-scale surface wind perturbations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-272, https://doi.org/10.5194/egusphere-egu2020-272, 2020.

In consequence of sea ice fragmentation in winter a range of physical processes take place between the sea/sea ice and the atmospheric boundary layer (ABL). Most of them occur on the level of individual ice floes and cracks and thus cannot be directly resolved by numerical weather prediction (NWP) models.  Parametrizations of those processes aim to describe their overall effect on grid scale values, given the grid scale variables. However, as many of the processes taking place during winter sea ice fragmentation remain largely unrecognized they cannot be incorporated into the NWP models. 

The aim of the presented study is to determine whether the floe size distribution (FSD) has an effect on the ABL. Our previous research (Wenta, Herman 2018 and 2019) indicates that FSD might determine the intensity and spatial arrangement of convection and heat fluxes. A coefficient has been proposed for the correction of moisture heat flux, which can be incorporated into the NWP models. However, this research is based entirely on idealized model simulations and requires further modelling and observations based studies.

In order to address this shortcoming, a field campaign is going to take place in the Bay of Bothnia in March 2020. Our goal is to create a 3D view of the atmosphere above fragmented sea and verify whether the processes and effects we found in the modeling results take similar form in real situations. Measurements results will be useful in the validation of our numerical modelling studies and will provide a unique dataset about the sea-ice-atmosphere interactions in the Bay of Bothnia area. Considering a significant decreasing trend in winter sea ice extent in the Baltic Sea it might contribute to our understanding of the role of ice in the local weather patterns. The field campaign is going to be complemented by numerical modelling with full version of Weather Research and Forecasting (WRF) model adjusted to the conditions over the Bay of Bothnia. 

Combined together - the results of our previous modelling studies and the results from the Bay of Bothnia field campaign, may considerably increase our knowledge about the surface-atmosphere coupling in the event of winter sea ice fragmentation.

How to cite: Wenta, M. and Herman, A.: Submesoscale physical processes in the atmospheric boundary layer above fragmented sea ice. , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4980, https://doi.org/10.5194/egusphere-egu2020-4980, 2020.

EGU2020-14066 | Displays | AS2.12

Impact of SST on the development of the cold surges over East Asia

Hye-young Lee and Joowan Kim

This study investigates synoptic characteristics of the cold surges over South Korea during winter season (December-February). A total of 61 cold events are selected by quantile regression analysis using daily mean temperature observations from 11 surface stations for 38 years(1981–2018). Composite analyses reveal that a synoptic-scale cyclone developing over the northern Japan is a key feature that significantly contribute to the enhancement of cold advection by increasing pressure gradient over the Korean peninsula. Enhanced sensible and latent heat fluxes are observed over the southern ocean of Korea and Japan during the cold surges due to increased temperature and humidity differences between the lower atmosphere and ocean surface. These fluxes are transported toward the center of the surface cyclone and help the development of the surface cyclone by inducing positive PV in the lower atmosphere. These processes make a positive feedback loop that amplifies strength of the cold surge. To examine how sea surface temperature (SST) affects the strength of cold surge, we categorize the cold surges into warm, normal and cold SST cases. As a result, stronger and more pronounced cyclones are observed in cases of warm SST. Thus, the positive feedback process particularly enhanced when SST is warmer in the early winter.

How to cite: Lee, H. and Kim, J.: Impact of SST on the development of the cold surges over East Asia, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14066, https://doi.org/10.5194/egusphere-egu2020-14066, 2020.

EGU2020-20064 | Displays | AS2.12

Observing Sea Spray Aerosol Production in the Surf Zone of Hawaii

Katherine Ackerman, Chung Taing, Alison Nugent, and Jorgen Jensen

Sea spray aerosol (SSA) play a significant role in the local climatology of coastal areas through direct radiative forcing and the indirect aerosol effect. Quantifying the size and concentrations of SSA is essential to understanding their influence in these coastal regions. Current observations of SSA in the surf zone come from coastline station measurements. These stations are often limited to observing only the mass of SSA produced and are unable to differentiate SSA concentrations of varying sizes. NCAR has developed an instrument known as a giant nucleus impactor (GNI) that allows deliquesced salt particles to impact onto polycarbonate slides exposed to a free airstream. These slides are then analyzed in a humidified environment under a microscope providing information about the SSA sizes and concentrations present. By modifying the NCAR GNI, we created a smaller, low-cost method known as a mini-GNI from 3D printing and Arduino microcontrollers. Using this new instrumentation, we attached the mini-GNI to a drone that sampled four locations over the ocean perpendicular to the coastline: the outer reef crest, inner reef crest, lagoon area, and shoreline. While sampling occurred, atmospheric and oceanographic measurements were recorded. This methodology provided us a baseline concentration or “open-ocean” concentration at the outer reef crest. It allowed us to compare how sizes and concentrations changed as the air parcel interacted with the surf zone. As the sampling locations moved closer to the shore, we’ve observed an increase in larger and more concentrated SSA that were contributed by the surf zone. We’ve also found that SSA concentrations have a stronger relationship to wave activity than to wind speed in our coastal environment. The ultimate goal is to quantify how the ocean environment and atmospheric conditions contribute to SSA production in the surf zone.

How to cite: Ackerman, K., Taing, C., Nugent, A., and Jensen, J.: Observing Sea Spray Aerosol Production in the Surf Zone of Hawaii, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20064, https://doi.org/10.5194/egusphere-egu2020-20064, 2020.

Cold air outbreaks play a crucial role in the air-sea heat exchange in the higher latitudes. However, we still lack some basic understanding about the sensitivities of these phenomena to latent heating and the role of coupling to the ocean. Despite increasing model resolution, reliable forecasts of these events remain a challenge because of the vast range of scales and physical processes involved. To further explore these sensitivities and dependence on model representation, we couple a moist convective atmospheric boundary layer model with an ocean mixed layer model to investigate the response of moist convection as well as ocean mixing during cold air outbreaks. In addition, we perform sensitivity experiments based on the PolarWRF model in an idealised configuration to represent cold air outbreaks.

Varying sea ice concentration and resolution alters the distribution and intensity of the air-sea heat exchange with ramifications for mixed layer depths in both the atmosphere and ocean. Furthermore, integrated and local sensible and latent heat fluxes depend on the model resolution as well as the distribution of the sea-ice concentration in the marginal ice zone. While surface sensible heat fluxes appear to be rather consistent across different model resolutions, surface latent heat fluxes respond to the organisation of convection at higher resolutions, a feature that is absent for coarser model grids. Different geometries replacing a straight sea-ice edge with various simple geometrical shapes are also tested. Our results have implications for numerical weather prediction and climate models, in particular regarding model resolution and the degree of coupling for the representation of air-sea interaction during cold air outbreaks.

How to cite: Spengler, T. and Spensberger, C.: Sensitivity of Atmosphere-Ocean Interactions during Cold Air Outbreaks to Characteristics of the Sea-Ice Edge, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5489, https://doi.org/10.5194/egusphere-egu2020-5489, 2020.

EGU2020-10095 | Displays | AS2.12

Iterative Schwarz Method to Couple Ocean and Atmosphere in a Global Climate Model

Olivier Marti, Sébastien Nguyen, Pascale Braconnot, Florian Lemarié, and Eric Blayo

For historical and practical reasons, present-day coupling algorithms implemented in ocean-atmosphere models are primarily driven by the necessity to conserve energy and water at the air-sea interface. However the asynchronous coupling algorithms currently used in ocean-atmosphere do not allow for a correct phasing between the ocean and the atmosphere.

In an asynchronous coupling algorithm, the total simulation time is split into smaller time intervals (a.k.a. coupling periods) over which averaged-in-time
boundary data are exchanged. For a particular coupling period, the average atmospheric fluxes are computed in the atmospheric model using the oceanic surface properties computed and averaged by the oceanic model over the previous coupling period. Therefore, for a given coupling period, the fluxes used by the oceanic model are not coherent with the oceanic surface properties considered by the atmospheric model. The mathematical consistency of the solution at the interface is not guaranteed.

The use of an iterative coupling algorithm, such as Schwarz methods, is a way to correct this inconsistency and to properly reproduce the diurnal cycle when the coupling period is less than one day. In Lemarié et al. (2014), preliminary numerical experiments using the Schwarz coupling method for the simulation of a tropical cyclone with a regional coupled model were carried out. In ensemble simulations, the Schwarz iterative coupling method leads to a significantly reduced spread in the ensemble results (in terms of cyclone trajectory and intensity), thus suggesting that a source of error is removed with respect to the asynchronous coupling case.

In the present work, the Schwarz iterative method is implemented in IPSLCM6, a state-of-the-art global ocean-atmosphere coupled model used to study past, present and future climates. We analyse the convergence speed and the quality of the convergence. A partial iterative method is also tested: in a first phase, only the atmosphere physics and the vertical diffusion terms are computed, until the convergence. This provide a first guess for the full model which is then iterated until convergence of the whole system. The impact on the diurnal cycle will also be presented.

How to cite: Marti, O., Nguyen, S., Braconnot, P., Lemarié, F., and Blayo, E.: Iterative Schwarz Method to Couple Ocean and Atmosphere in a Global Climate Model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10095, https://doi.org/10.5194/egusphere-egu2020-10095, 2020.

EGU2020-14749 | Displays | AS2.12

Surface Meteorology and Air–Sea Fluxes in the Southwestern Tropical Atlantic Ocean

Marcelo Dourado and Carlos Lentini

Recent studies suggest that the Tropical Atlantic Warm Pool (PQAT) contributes to modulate the variability of the ZCIT in the Atlantic Ocean basin and, consequently, the precipitation regime in Brazilian northeastern. Hourly surface meteorology observations from the PIRATA buoy at 19°S, 34°W from August 2010 to November 2018 was used to characterize and estimate the exchanges of heat, freshwater, and momentum between the ocean and the atmosphere over the Tropical. We focus here on recent efforts to observe the surface meteorology and air-sea fluxes using those data to gain insights into how atmospheric variability may govern the structure and variability of the upper ocean there at diurnal and seasonal time scales. The surface fluxes are calculated using the COARE 3.0 algorithm, positive values are to the ocean. Using the observations collected from the mooring deployments, we developed a good understanding of the annual march of the surface forcing of the ocean by the atmosphere. During spring (March, April) mean SST and air temperature are the hottest of the year, 28oC and 26.7oC, respectively; SST is greater than air temperature all over the year, 1oC on average. Wind speed is minimum, the air is drier and there is a peak of precipitation in April. During the autumn (August, September), mean SST and air temperature are the coldest of the year, 24.5oC and 23.6oC. Wind speed increases form 4.4m/s in March to 5.9 m/s in December. The monthly averaged incoming shortwave radiation in July was the lowest of the whole year and maximum in December. Net longwave radiation shows an inverse variability, i.e., maximum in the winter, minimum in the summer. This occurs because the winter air is drier than in the summer. Sensible heat flux is maximum in August due to the increase of the wind speed and an increase of the air-sea temperature difference. Latent flux is higher between April and August due to an increase in wind speed and a drier atmosphere. In the summer the humidity increases and, consequently, the latent heat flux diminishes. Finally, the net heat flux, positive between January and March, is negative between April and August (maximum -36W/m2 in July ) and, again, positive between September and December, maximum +116 W/m2 in December.

How to cite: Dourado, M. and Lentini, C.: Surface Meteorology and Air–Sea Fluxes in the Southwestern Tropical Atlantic Ocean, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14749, https://doi.org/10.5194/egusphere-egu2020-14749, 2020.

EGU2020-14780 | Displays | AS2.12

Two-sided turbulent boundary layer parameterizations for assessing ocean – atmosphere fluxes

Florian Lemarie, Charles Pelletier, Pierre-Etienne Brilouet, Eric Blayo, Jean-Luc Redelsperger, and Marie-Noëlle Bouin

Standard methods for determining air – sea fluxes typically rely on bulk algorithms derived from the Monin-Obukhov stability theory (MOST), using ocean surface fields and atmosphere near-surface fields. In the context of coupled ocean – atmosphere simulations, the shallowest ocean vertical level is usually assimilated to the surface, and the turbulent closure is one-sided: it aims at extrapolating atmosphere near-surface solution profiles (for wind speed, temperature and humidity) to the prescribed ocean surface values. Assimilating near-surface ocean fields as surface ones is equivalent to considering that in the ocean surface layer, solution profiles are constant instead of also being determined by a turbulent closure. Here we introduce a method for extending existing turbulent parameterizations to a two-sided context, by including the ocean surface layer and the viscous sublayers, which are also generally neglected in standard air – sea fluxes computation. The formalism we use for this method is derived from that of classical turbulent closure, so that our novelties can easily be implemented within existing formulations. Special care is taken to ensure the smoothness of resulting solution profiles. We investigate the impact of such two-sided bulk formulations on air - sea fluxes and discuss further implications such as resulting bulk formulation retuning. We also present leads on incorporating other mechanisms impacting air – sea fluxes within our framework, such as waves and radiation penetration.

How to cite: Lemarie, F., Pelletier, C., Brilouet, P.-E., Blayo, E., Redelsperger, J.-L., and Bouin, M.-N.: Two-sided turbulent boundary layer parameterizations for assessing ocean – atmosphere fluxes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14780, https://doi.org/10.5194/egusphere-egu2020-14780, 2020.

EGU2020-18373 | Displays | AS2.12

Global ocean surface stratifications due to rain based on ERA5

Hugo Bellenger, Xavier Perrot, Lionel Guez, Jean-Philippe Duvel, Alexandre Supply, Jacqueline Boutin, and Gilles Reverdin

Temperature and Salinity at the ocean interface can be substantially different than their bulk values in the ocean mixed layer at 5-10 meters depth. The main phenomena that account for these differences are (i) the interfacial millimeter scale diffusive microlayer usually cooler and saltier than below due to surface fluxes and (ii) diurnal warm layers of few tens of centimeters to few meters that form under weak wind condition due to solar absorption. Although characterized by small vertical scales, these tightly wind-related phenomena corresponds to coherent structures up to the large-scale where they can impact air-sea exchanges of heat, water and chemical species. Another phenomenon that can impact global air-sea exchanges is the freshwater lenses produced by rain. Rain freshens and cools the ocean surface, as raindrops temperature is usually lower than surface temperature. The induced negative salinity anomaly enables surface cold anomalies to be sustained and further cooled down by surface fluxes after rain has ceased. This study presents a first global estimate of basic statistics rain-induced ocean surface freshening and temperature changes and of their variations with seasons.

How to cite: Bellenger, H., Perrot, X., Guez, L., Duvel, J.-P., Supply, A., Boutin, J., and Reverdin, G.: Global ocean surface stratifications due to rain based on ERA5, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18373, https://doi.org/10.5194/egusphere-egu2020-18373, 2020.

EGU2020-19820 | Displays | AS2.12

Surface flux errors in asynchronous coupling of GCM

Xavier Perrot, Jean-Philippe Duvel, and Lionel Guez

In coupled general circulation model, the accuracy of momentum and energy exchange at the air-sea interface is still a potential source of significant bias. In the framework of the COCOA project we investigate new methods (both mathematical and numerical) to have a more correct flux representation. One important source of error is the asynchronous coupling between oceanic and atmospheric model. Indeed, the time step of the coupling is generally longer than time steps used by either the atmospheric or the oceanic model. This introduces inconsistencies between the free evolution of the two models due to the exchange parameters that are held constant since the last coupling time step. In particular, non-synchronous exchange coefficients may lead to error in the diurnal evolution of the coupled system, or to bias in the ocean mixed layer temperature for period where surface fluxes increases or decrease linearly.

In order to evaluate the potential amplitude of this error, and its regional and sea- sonal distribution, we use the hourly fluxes that are available in the new ECMWF ERA5 re-analyses. The error due to asynchronous coupling is first evaluated by inspecting the flux difference between two successive time-steps. Results show more important differences over the western boundary currents and the circumpolar current for all the fluxes except for the solar flux. We also observe larger differences in summer compared to winter in the respective hemisphere. By taking in account the geometrical variation of the solar flux we show how we can reduce the error for the solar flux.

In a second time we are calculating the statistics for the linear increase and decrease of the flux for a fixed period (ig one day, two days...) over all the ocean for all the fluxes except the solar one. The results are showing coefficients that are decreasing as the period increase. We also use those coefficient in a simple mixed layer model to calculate the error made over the period of calcul. On the contrary we see the appearance of a plateau at two-three days on the impact of this linear bias. Finally, using the De Boyer de Montaigu climatology for the mixed layer height we show that the linear bias could lead to temperature change up to 0.1K.

How to cite: Perrot, X., Duvel, J.-P., and Guez, L.: Surface flux errors in asynchronous coupling of GCM, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19820, https://doi.org/10.5194/egusphere-egu2020-19820, 2020.

EGU2020-21028 | Displays | AS2.12 | Highlight

A first glimpse from the EUREC4A-OA/ATOMIC air-sea experiment

Sabrina Speich, Johannes Karstensen, Chris Fairall, Paquita Zuidema, Chelle Gentemann, Dongxiao Zhang, Hugo Bellenger, Gilles Reverdin, Elizabeth Thompson, Sebastien Bigorre, Wiebke Mohr, and Stefan Kinne and the EUREC4A team

Ocean mesoscale eddies create specific air-sea interaction patterns that can have an integral effect on the large scale atmosphere and ocean dynamics. Recent advances in the state of the art of these processes has been predominately obtained from modeling efforts, but only very few observational studies exist, and there are all located in the extra-tropics. Adding a dedicated ocean mesoscale eddy air-sea interaction experiment to the EUREC4A campaign will enhance the objectives and success of the whole program as it sets a local, oceanic constrain to the atmospheric evolution (as been outlined in the overall EUREC4A design: www.eurec4a.eu; Bony et al. 2017). Temporal variability over a fixed mesoscale (500 km x 500 km) study area allows for sampling varying atmospheric states, on the time-scales of the EUREC4A field study. The oceanographic component that add on EUREC4A consists of four ships and many autonomous platforms (gliders, Saildrones, specific surface drifters, Argo floats) sampling the mesoscale ocean and air-sea exchanges at different edges of the Northwest Atlantic tropical region. This will enable the extended spatial sampling required to characterize ocean variability and gather enough air-sea observations at different locations to assess with accuracy the involved processes and impacts.

The western tropical Atlantic is an ideal laboratory for the proposed study. It hosts rich ocean mesoscale variability under an atmosphere characterized by a rather steady trade wind regime. In this region, eddies have a diameter of 200 to 300 km and lifetimes of several months up to years. In particular south of Barbados, very energetic and long-lived anticyclonic North Brazil Current rings are commonly found. These eddies are key for the northward transport of properties from the South to the North Atlantic within the Atlantic Meridional Ocean Circulation. Moreover, preliminary studies based on satellite observations have suggested that they play a crucial role in air-sea interactions and on the atmosphere. This region and eddies are the focus of EUREC4A-OA, the French oceanographic component of the larger EUREC4A field experiments.

In this talk we will present the preliminary lessons learned and results obtained by this unprecedented observing effort.

How to cite: Speich, S., Karstensen, J., Fairall, C., Zuidema, P., Gentemann, C., Zhang, D., Bellenger, H., Reverdin, G., Thompson, E., Bigorre, S., Mohr, W., and Kinne, S. and the EUREC4A team: A first glimpse from the EUREC4A-OA/ATOMIC air-sea experiment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21028, https://doi.org/10.5194/egusphere-egu2020-21028, 2020.

EGU2020-22675 | Displays | AS2.12

The impact of atmosphere-ocean coupling on the tropospheric response to stratospheric temperature perturbations

Natasha Trencham, Joanna Haigh, and Arnaud Czaja

AS2.14 – Atmospheric Acidity, Air-sea Chemical Fluxes and their Impacts

EGU2020-21227 | Displays | AS2.14 | Highlight

Aerosol acidity as a driver of aerosol formation and nutrient deposition to ecosystems

Athanasios Nenes, Maria Kanakidou, Spyros Pandis, Armistead Russell, Shaojie Song, Petros Vasilakos, and Rodney Weber

Nitrogen oxides (NOx) and ammonia (NH3) from anthropogenic and biogenic emissions are central contributors to particulate matter (PM) concentrations worldwide. Ecosystem productivity can also be strongly modulated by the atmospheric deposition of this inorganic "reactive nitrogen" nutrient. The response of PM and nitrogen deposition to changes in the emissions of both compounds is typically studied on a case-by-case basis, owing in part to the complex thermodynamic interactions of these aerosol precursors with other PM constituents. In the absence of rain, much of the complexity of nitrogen deposition is driven by the large difference in dry deposition velocity when a nitrogen-containing molecule is in the gas or condensed phase.

Here we present a simple but thermodynamically consistent approach that expresses the chemical domains of sensitivity of aerosol particulate matter to NH3 and HNO3 availability in terms of aerosol pH and liquid water content. From our analysis, four policy-relevant regimes emerge in terms of sensitivity: i) NH3-sensitive, ii) HNO3-sensitive, iii) combined NH3 and HNO3 sensitive, and, iv) a domain where neither NH3 and HNO3 are important for PM levels (but only nonvolatile precursors such as NVCs and sulfate). When this framework is applied to ambient measurements or predictions of PM and gaseous precursors, the “chemical regime” of PM sensitivity to NH3 and HNO3 availability is directly determined. 

The same framework is then extended to consider the impact of gas-to-particle partitioning, on the deposition velocity of NH3 and HNO3 individually, and combined affects the dry deposition of inorganic reactive nitrogen. Four regimes of deposition velocity emerge: i) HNO3-fast, NH3-slow, ii) HNO3-slow, NH3-fast, iii) HNO3-fast, NH3-fast, and, iv) HNO3-slow, NH3-slow. Conditions that favor strong partitioning of species to the aerosol phase strongly delay the deposition of reactive nitrogen species and promotes their accumulation in the boundary layer and potential for long-range transport. 

The use of these regimes allows novel insights and is an important tool to evaluate chemical transport models. Most notably, we find that nitric acid displays considerable variability of dry deposition flux, with maximum deposition rates found in the Eastern US (close to gas-deposition rates) and minimum rates for North Europe and China. Strong reductions in deposition velocity lead to considerable accumulation of nitrate aerosol in the boundary layer –up to 10-fold increases in PM2.5 nitrate aerosol, eventually being an important contributor to high PM2.5 levels observed during haze episodes. With this new understanding, aerosol pH and associated liquid water content can be understood as control parameters that drive PM formation and dry deposition flux and arguably can catalyze the accumulation of aerosol precursors that cause intense haze events throughout the globe.

How to cite: Nenes, A., Kanakidou, M., Pandis, S., Russell, A., Song, S., Vasilakos, P., and Weber, R.: Aerosol acidity as a driver of aerosol formation and nutrient deposition to ecosystems, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21227, https://doi.org/10.5194/egusphere-egu2020-21227, 2020.

EGU2020-11366 | Displays | AS2.14

Global Survey of Aerosol Acidity from Polluted to Remote Locations: Measurements and Comparisons with Global Models

Benjamin A Nault, Pedro Campuzano-Jost, Duseong Jo, Doug Day, Roya Bahreini, Huisheng Bian, Mian Chin, Simon Clegg, Peter Colarco, Jack Kodros, Felipe Lopez-Hilfiker, Eloise Marais, Ann Middlebrook, Andrew Neuman, John Nowak, Jeffrey Pierce, Joel Thornton, Kostas Tsigaridis, and Jose Jimenez and the ATom Science Team

The inorganic composition of aerosol impacts numerous chemical and physical processes and properties. However, many chemical transport models show large variability in both the concentration of the inorganic aerosols and their precursors (up to 3 orders of magnitude differences) and the inorganic aerosol composition. Different models predict very different properties (e.g., aerosol liquid water concentration and aerosol acidity) and outcomes (e.g., heterogeneous uptake of gases or aerosols’ direct and indirect impacts on climate). Here, we use airborne observations from campaigns conducted around the world to investigate how the inorganic fine aerosol (PM1) composition, and one of its key parameters, aerosol acidity, changes from polluted regions (Mexico City, Los Angeles, Northeastern US, and Seoul) to remote ocean basins (the Atmospheric Tomography campaigns 1 and 2) in order to provide constraints for the chemical transport models. I find that the empirical ammonium balance with major ions (ammonium balance = mol NH4 / (2×mol SO4 + mol NO3)) rapidly decreases from ~1 at the highest inorganic PM1 concentration to 0 at the lowest inorganic PM1. The data indicate a robust trend for ammonium balance vs inorganic PM1 at all altitude levels in the troposphere, suggesting that NH3 emissions and subsequent neutralization of H2SO4 becomes negligible in the most remote (lowest inorganic PM1) regions. Further, a robust trend for PM1 pH (calculated with E-AIM) vs inorganic PM1 is observed at all levels for these campaigns, as well, decreasing from a pH of ~3 to a pH of ~ –1 from the highest to lowest inorganic PM1. The data overall implies very low NH3 (and NH4+) throughout most of the atmosphere, contrary to predictions of some models, implying different physical properties than predicted in models. We compare these trends of ammonium balance and pH vs inorganic PM1 against 9 chemical transport models (CTMs), and we find that the CTMs show large variability for both the ammonium balance and pH vs inorganic PM­1, compared to observations. Generally, we find a high bias in the ammonium balance and pH, likely due to too much NH­3 in model (possibly too high NH3 emissions over oceans or too long lifetime) and inclusion of externally mixed seasalt into the submicron pH calculation. These results overall would imply different aerosol properties in the models than observed, impacting the chemistry, optical properties, and cloud properties.

How to cite: Nault, B. A., Campuzano-Jost, P., Jo, D., Day, D., Bahreini, R., Bian, H., Chin, M., Clegg, S., Colarco, P., Kodros, J., Lopez-Hilfiker, F., Marais, E., Middlebrook, A., Neuman, A., Nowak, J., Pierce, J., Thornton, J., Tsigaridis, K., and Jimenez, J. and the ATom Science Team: Global Survey of Aerosol Acidity from Polluted to Remote Locations: Measurements and Comparisons with Global Models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11366, https://doi.org/10.5194/egusphere-egu2020-11366, 2020.

EGU2020-5739 | Displays | AS2.14

Size-resolved aerosol pH over Europe during summer

Spyros Pandis, Maria Zakoura, Stelios Kakavas, and Athanasios Nenes

The dependence of aerosol acidity on particle size, location and altitude over Europe during a summertime period is investigated using the hybrid version of aerosol dynamics in the chemical transport model PMCAMx. The pH changes more with particle size in northern and southern Europe owing to the enhanced presence of non-volatile cations (Na, Ca, K, Mg) in the larger particles. Differences of up to 1-4 pH units are predicted between sub- and super-micron particles, while the average pH of PM1-2.5 can be as much as 1 unit higher than that of PM1. Most aerosol water over continental Europe is associated with PM1, while PM2.5-5 and PM5-10 dominate the water content in the marine and coastal areas due to the relatively higher levels of hygroscopic sea salt. Particles of all sizes become increasingly acidic with altitude (0.5-2 units pH decrease over 2.5 km) primarily because of the decrease in aerosol liquid water content (driven by humidity changes) with height. Inorganic nitrate is strongly affected by aerosol pH with the highest average nitrate levels predicted for the PM2.5-5 range and over locations where the pH exceeds 3. Dust tends to increase aerosol water levels, aerosol pH and nitrate concentrations for all particle sizes. This effect of dust is quite sensitive to its calcium content. The size-dependent pH differences carry important implications for pH-sensitive processes in the aerosol.

How to cite: Pandis, S., Zakoura, M., Kakavas, S., and Nenes, A.: Size-resolved aerosol pH over Europe during summer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5739, https://doi.org/10.5194/egusphere-egu2020-5739, 2020.

EGU2020-2774 | Displays | AS2.14

Atmospheric Acidity over North America: GEM-MACH Simulations for AQMEII-4

Paul A. Makar, Ayodeji Akingunola, Junhua Zhang, Balbir Pabla, Qiong Zheng, Michael D. Moran, Philip Cheung, Julian Aherne, Olivia Clifton, Donna Schwede, Roberto Bianconi, Roberto Bellasio, Christian Hogrefe, and Stefano Galmarini

The fourth phase of the Air Quality Model Evaluation International Initiative (AQMEII-4) is a regional air-quality model intercomparison for North American and European domains, with a focus on acidifying deposition. The study protocol includes enhanced model outputs for acidic gas deposition resistances and conductances, and particle and aqueous phase deposition, and hence will provide an unprecedented estimation both of the variability in model predictions for the deposition of acidifying species, and indications of the reasons for model variability. All models make use of common lateral boundary conditions and emissions data. Model simulations are being conducted for the years 2009 and 2010 for the European domain, and 2010 and 2016 for the North American domain. Model outputs were reported on a common grid 0.125o grid cell size domain in each of these domains, as well as at the latitude and longitude locations of receptor observation stations in the ENSEMBLE database format, and are uploaded to a common database for comparison at the Joint Research Centre at Ispra.

The Global Environmental Multiscale – Modelling Air-quality and CHemistry (GEM-MACH) is Environment and Climate Change Canada’s air-quality modelling system, and is a participant in AQMEII-4, with simulations taking place on a 10km grid cell size domain covering North America. Several GEM-MACH simulations are underway for the AQMEII-4 campaign, including both the model’s research and operational configurations, based on the most recent version of the model code (GEM-MACHv3). The operational version of the model is optimized for rapid computation, making use of a 2-bin particle size distribution with occasional rebinning to/from 12-bin when necessary for improved particle microphysics accuracy. The research version of the model incorporates fully coupled chemistry (direct and indirect effects) with the P3 cloud parameterization, forest canopy shading and turbulence, revised anthropogenic plume rise, emitted and transported methane, modulation of particle crustal material by meteorology, the KPP/RODAS3 gas-phase solver, ammonia bi-directional fluxes, satellite-derived leaf area index data, a 12-bin particle size distribution, a revised parameterizations for some of the gas-phase resistances, and six additional particulate species (base cations, iron and manganese).

In addition to providing a status update on the AQMEII-4 ensemble simulations, we focus here on the simulations of the research version of GEM-MACH, for the years 2010 and 2016. The annual total values of acidifying sulphur and nitrogen’s deposition components will be compared for this time period, and the AQMEII-4 diagnostics will be used to show the relative contributions of GEM-MACH’s gas-phase resistances and conductances towards total gas-phase deposition. The gas-phase values will also be compared to the annual average lowest model layer molar concentrations of the depositing species, to determine the extent to which acidity in the atmosphere tracks atmospheric concentrations. In addition, we will also examine the relative impact of base cations on average atmospheric acidity and deposition and the extent to which the transportable versus non-transportable fractions of fugitive dust emissions may influence net acidic deposition. We will also exceedances of critical loads based on the simulation totals of sulphur and nitrogen deposition and critical load ecosystem data.

How to cite: Makar, P. A., Akingunola, A., Zhang, J., Pabla, B., Zheng, Q., Moran, M. D., Cheung, P., Aherne, J., Clifton, O., Schwede, D., Bianconi, R., Bellasio, R., Hogrefe, C., and Galmarini, S.: Atmospheric Acidity over North America: GEM-MACH Simulations for AQMEII-4, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2774, https://doi.org/10.5194/egusphere-egu2020-2774, 2020.

EGU2020-2009 | Displays | AS2.14

Effects of Water-soluble Organic Carbon on Aerosol pH

Christopher Hennigan, Michael Battaglia, Jr., Rodney Weber, and Athanasios Nenes

Water soluble organic carbon (WSOC) is a ubiquitous and significant fraction of fine particulate matter.  Despite advances in aerosol thermodynamic equilibrium models, there is limited understanding on the comprehensive impacts of WSOC on aerosol acidity (pH).  We address this limitation by studying submicron aerosol that represent the two extremes in acidity levels found in the atmosphere: strongly acidic aerosol from Baltimore, MD, and weakly acidic conditions characteristic of Beijing, China. These cases are then used to construct mixed inorganic/organic single-phase aqueous particles, and thermodynamically analyzed by the E-AIM and ISORROPIA models in combination with activity coefficient model AIOMFAC to evaluate the effects of WSOC on the H+ ion activity coefficients (γH+) and activity (pH).  We find that addition of organic acids and non-acid organic species concurrently increases γH+ and aerosol liquid water.  Under the highly acidic conditions typical of the eastern U.S. (inorganic-only pH ~1), these effects mostly offset each other, giving pH changes of < 0.5 pH units even at organic aerosol dry mass fractions in excess of 60%.  Under conditions with weaker acidity typical of Beijing (inorganic-only pH ~4.5), the non-acidic WSOC compounds had similarly minor effects on aerosol pH, but organic acids imparted the largest changes in pH compared to the inorganic-only simulations.  Organic acids affect pH in the order of their pKa values (oxalic acid > malonic acid > glutaric acid).  Although the inorganic-only pH was above the pKa value of all three organic acids investigated, pH changes in excess of 1 pH unit were only observed at unrealistic organic acid levels (aerosol organic acid concentrations > 35 µg m-3) in Beijing.  The model simulations were run at 70%, 80%, and 90% relative humidity (RH) levels and the effect of WSOC was inversely related to RH.  At 90% RH, WSOC altered aerosol pH by up to ~0.2 pH units, though the effect was up to ~0.6 pH units at 70% RH.  The somewhat offsetting nature of these effects suggests that aerosol pH is sufficiently constrained by the inorganic constituents alone under conditions where liquid-liquid phase separation is not anticipated to occur.

How to cite: Hennigan, C., Battaglia, Jr., M., Weber, R., and Nenes, A.: Effects of Water-soluble Organic Carbon on Aerosol pH, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2009, https://doi.org/10.5194/egusphere-egu2020-2009, 2020.

Aerosol acidity is an important parameter that affects gas-particle reaction rates, heterogeneous chemistry, human and ecosystem health, global biogeochemical cycles, and climate. Aerosol acidity is difficult to measure directly and remains poorly constrained in most of the troposphere. There is a further scarcity of measurements and/or proxy-estimates of aerosol acidity in the remote marine atmosphere, a region where aerosol acidity exerts strong control on the solubility, bioavailability, and toxicity of biogeochemically-relevant species that influence the productivity of the surface ocean. Here, we measure gas-phase ammonia, and aerosol phase (PM2.5) ammonium, sulfate, nitrate, sodium, and chloride in the summertime Southern Ocean marine boundary layer every two hours across a latitudinal gradient from Cape Town (-34.11 °S, 18.03 °E) to Antarctica (-58 °S, -0.06 °W). A thermodynamic equilibrium model, i.e., ISORROPIA-II, was run in “forward” mode to calculate aerosol pH using the measured gas + aerosol concentrations, atmospheric temperature, and relative humidity as inputs. The model was able to accurately predict the observed concentration of gas-phase ammonia across the entire dataset (R2 > 0.9). Aerosol pH ranged from 0.96 to 4.92 with pH generally increasing with distance away from Cape Town. Observed aerosol- and gas-phase concentrations were typical for the remote marine atmosphere and will be presented in full. Temperature varied significantly across the 8 day transect from 18.42 °C near Cape Town to a minimum of -2.13 °C. Factors that control aerosol pH across the time and space scales observed will be evaluated and discussed as well as implications for improving our understanding of atmospheric chemistry and biogeochemical cycling in remote marine atmospheres.

How to cite: Altieri, K., Spence, K., and Xokashe, S.: Thermodynamic predictions of aerosol pH in the summertime Southern Ocean marine boundary layer using high-resolution aerosol- and gas-phase observations from Cape Town to Antarctica , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22233, https://doi.org/10.5194/egusphere-egu2020-22233, 2020.

Atmospheric transport and the subsequent air-to-sea deposition of water-soluble iron (Fews), an essential micronutrient for the phytoplankton growth, have a profound influence on the biogeochemical cycles of carbon and nitrogen. Sources of Fews include contributions from poorly soluble natural mineral dust and highly soluble anthropogenic aerosols from biomass burning emissions and fossil-fuel combustion in the continental outflows. Apart from the source/emission contributions, atmospheric processing of aerosol iron (FeTot) by inorganic acidic species (e.g., non-sea-salt or nss-SO42- and NO3-) and/or organic acids also affect the supply of Fews to the surface waters that are downwind of pollution sources. Among these, the least understood process is the oxalic acid-mediated photochemical cycling of Fews. Laboratory studies have clearly demonstrated an enhancement in the fractional solubility of aerosol iron (i.e., Fews (%) = Fews/FeTot ×100) via the oxalic acid complexation with FeTot and subsequent photochemical reduction process. However, lacking support from the field measurements limits our ability to incorporate the proposed mechanism in the current biogeochemistry models. This study is designed with the overarching goal of investigating the role of oxalic acid on the Fews (%) over a coastal ocean (i.e., the Bay of Bengal: BoB) influenced by the atmospheric outflow from the Indo-Gangetic Plain (IGP) and South-east Asia (SEA) during the winter season. We analysed 31 PM2.5 samples for the mass concentrations of FeTot, Fews and other chemical composition including nss-SO42-, NO3-, oxalic acid and related polar compounds as well as stable carbon isotopic composition of oxalic acid (δ13Coxalic). Strong positive linear relationship of oxalic acid with FeTot and significant inverse linear relationship between δ13Coxalic and Fews over the BoB clearly emphasize the role of oxalic acid on the Fews (%).  These findings comply with the notion that oxalic acid formed from the precursor water-soluble organic acids in the deliquescent aerosols, is complexed with aerosol-Fe and undergoes through successive photochemical reactions, contributing to an overall increase in the Fews (%). 

How to cite: Bikkina, S., Kawamura, K., Sarin, M., and Tachibana, E.: Role of Oxalic acid on Fractional Solubility of Aerosol Iron over Coastal Ocean: Evidence from compound-specific stable carbon isotopic composition and diagnostic mass ratios , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-423, https://doi.org/10.5194/egusphere-egu2020-423, 2020.

EGU2020-9684 | Displays | AS2.14 | Highlight

Microplastics: All Up in the Air?

Peter S. Liss

It is often said that plastics, and particularly microplastics (<5mm), are all

around us, especially in the oceans where there is much concern about possible harmful

effects on marine life.  The route of entry for plastics to the marine environment is generally

seen to be via rivers acting as a conduit after their production on the land by a whole host of

processes and uses by our societies.   But in all the discussion on the

topic and rapidly growing research activity, the atmosphere barely gets a mention. 

 

But, recently published results show significant amounts of microplastics

in air at a remote terrestrial location in the Pyrenees (Allen et al., 2019, Nature Geoscience

12:339).  However, there appear to be no results from measurements over the oceans.   If

these results from the Pyrenees are representative of the marine atmosphere a simple

calculation indicates a significant atmospheric route for the distribution of microplastics and

their subsequent deposition to the oceans.  If correct such a pathway would lead to the

distribution of microplastics wider and faster than by ocean circulation alone.  It would also

more readily explain why microplastics have been reported recently in Arctic snow

(Bergmann et al., 2019, Sci. Adv. 5: eaax1157).  In addition, it would also lead to a reframing

of our understanding of the budget and distribution of microplastics globally.

How to cite: Liss, P. S.: Microplastics: All Up in the Air?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9684, https://doi.org/10.5194/egusphere-egu2020-9684, 2020.

EGU2020-19425 | Displays | AS2.14 | Highlight

Changing atmospheric acidity as a modulator of nutrient deposition and ocean biogeochemistry

Alex Baker, Maria Kanakidou, Athanasios Nenes, Peter Croot, Robert Duce, Yuan Gao, Cecile Guieu, Akinori Ito, Tim Jickells, Natalie Mahowald, Rob Middag, Stelios Myriokefalitakis, Morgane Perron, Manmohan Sarin, Rachel Shelley, and David Turner

Anthropogenic emissions of nitrogen and sulphur oxides and ammonia have altered the pH of aerosol, cloud water and precipitation, with significant decreases over much of the marine atmosphere. Some of these emissions have led to an increased atmospheric burden of reactive nitrogen and its deposition to ocean ecosystems. Changes in acidity in the atmosphere also have indirect effects on the supply of labile nutrients to the ocean. For nitrogen, these changes are caused by shifts in the chemical speciation of both oxidized (NO3- and HNO3) and reduced (NH3 and NH4+) forms that result in altered partitioning between the gas and particulate phases that affect transport. Other important nutrients, notably iron and phosphorus, are impacted because their soluble fractions increase due to exposure to low pH environments during atmospheric transport. These changes affect not only the magnitude and distribution of individual nutrient supply to the ocean but also the ratios of nitrogen, phosphorus, iron and other trace metals in atmospheric deposition.  Since marine microbial populations are sensitive to nutrient supply ratio, the consequences of atmospheric acidity change include shifts in ecosystem composition in addition to overall changes in marine productivity. Nitrogen and sulphur oxide emissions are decreasing in many regions, but ammonia emissions are much harder to control. The acidity of the atmosphere is therefore expected to decrease in the future, with further implications for nutrient supply to the ocean.

This presentation will explore the impact of increased atmospheric acidity since the Industrial Revolution, and the projected acidity decreases, on atmospheric nutrient supply and its consequences for the biogeochemistry of the ocean.

How to cite: Baker, A., Kanakidou, M., Nenes, A., Croot, P., Duce, R., Gao, Y., Guieu, C., Ito, A., Jickells, T., Mahowald, N., Middag, R., Myriokefalitakis, S., Perron, M., Sarin, M., Shelley, R., and Turner, D.: Changing atmospheric acidity as a modulator of nutrient deposition and ocean biogeochemistry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19425, https://doi.org/10.5194/egusphere-egu2020-19425, 2020.

EGU2020-20767 | Displays | AS2.14

Impact of desert and volcanic aerosol deposition on phytoplankton in the South Indian Ocean and Southern Ocean

Carla Geisen, Celine Ridame, Emilie Journet, Benoit Caron, Dominique Marie, and Damien Cardinal

The Southern Ocean is known to be the largest High Nutrient Low Chlorophyll (HNLC) area of the global ocean, where algal development is mainly limited by iron (Fe) deficiency, except in few naturally Fefertilized areas (e.g. around Kerguelen plateau). The availability of different nutrients is unevenly distributed in this area. Thus, northwards the polar front, nitrogen and phosphorus (N and P) concentrations are high, but the scarcity of silicon (Si) limits the growth of diatoms (HN-LSi-LC). Further North, the Southern Indian Ocean is characterized by macronutrient limitation and low primary production (LNLC).

In these areas, atmospheric input could play a major role in the nutrient supply of primary producers. The main aim of this study is to assess the biological response of local phytoplankton communities to a deposition of two types of natural aerosols: desert dust and volcanic ash. Preliminary trace-metal clean laboratory experiments enabled us to quantify the abiotic dissolution of main macro- and micronutrients in dry and wet deposition mode of different natural aerosols of these types that yield us to choose Patagonia dust and ash from the Icelandic volcano Eyjafjallajökull for our experiment at sea.


We set up a series of on-board trace-metal clean microcosm experiments in the contrasted biogeochemical conditions of the South Indian Ocean and Southern Ocean with addition of realistic amounts of dust and ash of respectively 2 and 25 mg.L-1. Experiments ran over 48 hours to evaluate the triggered primary production and cell abundances. Primary production was estimated by 13C spike and biogenic Si (bSi) uptake rates were assessed by 30Si spike. Parallel experiments with nutrient addition (dFe, DIP, DIN and dSi) along with flux cytometry for estimation of pico- and nanophytoplankton cells enabled us to determine which element(s) dissolved from the aerosols was responsible for the enhanced algal growth.


The highest CO2 fixation rate of 50 mg.m-3.day-1 was found at the natural Fe fertilized Kerguelen plateau station. Dust, ash and Fe addition triggered primary production, and CO2 fixation doubled in these treatments. We recorded an enrichment of b30Si, indicating an increase of Si uptake rate, mostly stimulated by Fe addition. At the different HNLC stations (high N - low Si and high N - high Si), Fe and aerosol addition induced as well increased CO2 fixation. In the northern LNLC stations, algal growth was stimulated by nitrogen addition as expected, but Fe, Si and aerosol addition also triggered a biological response from Synechococcus cyanobacteria and pico- and nanoeukaryotes.


Noteworthy, in most experiments the two contrasted aerosol types (desert dust and volcanic ash) at particle charges which varied over more than an order of magnitude triggered very similar biological responses in all of the sampled areas, even with distinct elementary and mineral compositions (e.g. the Icelandic volcano ash is 64 % amorphous and contains roughly twice the amount of Fe, P, Mn and
Zn compared to the Patagonian desert dust which is only 48 % amorphous).

How to cite: Geisen, C., Ridame, C., Journet, E., Caron, B., Marie, D., and Cardinal, D.: Impact of desert and volcanic aerosol deposition on phytoplankton in the South Indian Ocean and Southern Ocean, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20767, https://doi.org/10.5194/egusphere-egu2020-20767, 2020.

EGU2020-10721 | Displays | AS2.14

Quantifying the role of volcanic ash supply in the oceanic iron and manganese cycles

Jack Longman, Martin Palmer, and Thomas Gernon

Primary productivity in the upper ocean is a key driver of Earth’s carbon cycle. The supply of micronutrients such as iron (Fe) and manganese (Mn) to the ocean is now known to exert a controlling influence on net primary productivity. Fragmental volcanic material, or tephra, is enriched in such nutrients, highly reactive and regularly supplied to the upper ocean when eruptions occur. However, there are no existing estimates of the global magnitude of the volcanic supply of these (and associated) nutrients to the oceans. Here we present new data from ten volcanic provinces globally including the Aleutian Islands and Lesser Antilles to estimate depletion factors of both Fe and Mn in altered tephra. By comparing the concentration of altered tephra to unaltered protolithic compositions, we can estimate depletion factors, and thus the amount of each element supplied to the oceans via this method. Using a novel Monte Carlo approach, we estimate mean values of Fe and Mn to be on the order of 26.1 and 0.25 Gmol yr-1, respectively. These values are broadly comparable to riverine and atmospheric dust fluxes to the ocean, indicating that volcanism plays a major role in Fe and Mn ocean cycles.

How to cite: Longman, J., Palmer, M., and Gernon, T.: Quantifying the role of volcanic ash supply in the oceanic iron and manganese cycles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10721, https://doi.org/10.5194/egusphere-egu2020-10721, 2020.

EGU2020-7809 | Displays | AS2.14

Dust and pyrogenic iron boost phytoplankton blooms in sub-Antarctic waters of the Tasman Sea

Joan Llort, Richard J. Matear, Pete G. Strutton, Andrew R. Bowie, and Zanna Chase

Although it is commonly accepted that atmospheric deposition of Fe particles can fertilise phytoplankton, there is yet no clear evidence on how such a fertilisation effect takes place. Several studies have attempted to link individual dust events with surface chlorophyll responses but generally, they do not find a clear correspondence between dust deposition and its impact on chlorophyll. In this work, we use a biogeochemical model to show that the atmospheric deposition of Fe in high-latitude seas, rather than creating instantaneous phytoplankton responses, replenish the upper mixed layer of the ocean during the pre-bloom period, from winter to early summer. The Fe accumulated at the surface boosts the phytoplankton bloom of the following summer, resulting in surface chlorophyll accumulations of up to 3 times larger than the years without atmospheric deposition. We used this mechanism to explain the strong inter-annual variability of the phytoplankton bloom in sub-Antarctic iron-limited waters east of Australia. Putting together more than a 15-years-long record of ocean colour observations and atmospheric aerosols reanalysis we uncovered a strong correlation (r2>0.6) between the dust that crossed the region during the pre-bloom period and the magnitude of the surface chlorophyll bloom. Interestingly, the correlation increased when taking into account pyrogenic aerosols in addition to dust. Our study presents the first observational link between Climate Change-enhanced droughts and wildfires, atmospheric aerosols and primary production of iron-limited waters.

How to cite: Llort, J., Matear, R. J., Strutton, P. G., Bowie, A. R., and Chase, Z.: Dust and pyrogenic iron boost phytoplankton blooms in sub-Antarctic waters of the Tasman Sea, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7809, https://doi.org/10.5194/egusphere-egu2020-7809, 2020.

EGU2020-3359 | Displays | AS2.14

Marine organic matter in the remote environment of the Cape Verde Islands – An introduction and overview to the MarParCloud campaign

Manuela van Pinxteren, Khanneh Wadinga Fomba, Nadja Triesch, Heike Wex, Xianda Gong, Jens Vogtländer, Stefan Barthel, Christian Stolle, Enno Bahlmann, Tim Rixen, Detlef Schulz-Bull, Tiera-Brandy Robinson, Oliver Wurl, Frank Stratmann, and Hartmut Herrmann

The project MarParCloud (marine biological production, organic aerosol particles and marine clouds: a process chain) aims at achieving a better understanding of the biological production of organic matter (OM)in the oceans, its export into marine aerosol particles and finally its ability to act as ice and cloud condensation nuclei (INP and CCN). The core of MarParCloud comprised a field campaign at the Cape Verde Atmosphere Observatory (CVAO) in autumn 2017, where a variety of chemical, physical, biological and meteorological approaches were applied. The investigations included concerted measurements of the bulk water, the Sea Surface Microlayer (SML), ambient aerosol particles on the ground (30 m a.s.l.) and in mountain heights (744 m) as well as cloud water. Important aspects of the ocean atmosphere Interactions focusing on marine OM have been addressed through detailed observation and modeling approaches.

Key variables comprised the chemical characterization of the atmospherically relevant OM components (e.g. lipids, proteins, sugars) in the ocean and the atmosphere as well as measurements of INP and CCN. Moreover, bacterial cell counts, mercury species and trace gases were analysed. To interpret the results, the measurements were accompanied by various auxiliary parameters such as air mass back trajectory analysis, vertical atmospheric profile analysis, cloud observations and pigment measurements in seawater. Additional modelling studies supported the experimental analysis.

Here we show the proof of concept of the connection between organic matter emission from the ocean to the atmosphere and up to the cloud level. A link between the ocean and the atmosphere was clearly observed as (i) the particles measured at the surface are well mixed within the marine boundary layer up to cloud level and (ii) ocean-derived compounds can be found in the aerosol particles at mountain height and in the cloud water. The organic measurements will be implemented in a new source function for the oceanic emission of OM. However, from a perspective of particle number concentrations, the marine contributions to both CCN and INP are rather limited.

How to cite: van Pinxteren, M., Fomba, K. W., Triesch, N., Wex, H., Gong, X., Vogtländer, J., Barthel, S., Stolle, C., Bahlmann, E., Rixen, T., Schulz-Bull, D., Robinson, T.-B., Wurl, O., Stratmann, F., and Herrmann, H.: Marine organic matter in the remote environment of the Cape Verde Islands – An introduction and overview to the MarParCloud campaign, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3359, https://doi.org/10.5194/egusphere-egu2020-3359, 2020.

EGU2020-15108 | Displays | AS2.14

Biochemical responses of oligotrophic Adriatic Sea surface layers to atmospheric deposition inputs

Sanja Frka, Andrea Milinković, Abra Penezić, Saranda Bakija Alempijević, Blaženka Gašparović, Sanda Skejić, Danijela Šantić, Vedrana Džaja Grgičin, Stjepana Brzaj, Sonja Vidič, Iva Šimić, Silva Žužul, Ivan Bešlić, Ranka Godec, and Gordana Pehnec

Biochemical responses of oligotrophic Adriatic Sea surface layers to atmospheric deposition inputs

 

Frka1, A. Miliković1, A. Penezić1, S. Bakija Alempijević1, B. Gašparović1, S. Skejić2, D. Šantić2, S. Brzaj3, V. Džaja Grgičin3, S. Vidič3, I. Šimić4, I. Bešlić4, S. Žužul4, R. Godec4, G. Pehnec4

1Division for marine and environmental research, Ruđer Bošković Institute, Zagreb, Croatia

2Institute of Oceanography and Fisheries, Split, Croatia

3Croatian Meteorological and Hydrological Service, Zagreb, Croatia

4Institute for Medical Research and Occupational Health, Zagreb, Croatia

 

The atmosphere is a significant pathway by which both natural and anthropogenic material is transported from continents to both coastal and open seas. Once deposited through atmospheric deposition (AD) processing, atmospheric particulate matter (PM) provides the aqueous ecosystems with an external source of nutrients and pollutants. This, in turn, influences the organic matter (OM) production by the phytoplankton, changes CO2 uptake and indirectly affects the climate. The input of AD is especially important in oligotrophic environments and it is expected to increase in the future scenarios of a warmer atmosphere with increased PM emissions and deposition rates. While the majority of the data related to the AD impacts generated so far in the Mediterranean have been conducted on its western and eastern regions, the effects of the AD inputs to oligotrophic surface waters of the Adriatic Sea sub-basin are unknown. This work is designed to assess the impact of AD on complex biochemical responses of Adriatic oligotrophic systems, considering the sea surface microlayer (SML) at the air-water interface.

Field campaign was conducted during the period of retrieval of sea surface oligotrophic conditions (February-July 2019) at the Martinska, Central Adriatic, Croatia. On-line black carbon (BC) concentrations were measured while the PM10, wet and total deposition samples as well as the SML and underlying water (ULW; 0.5 m depth) samples were collected simultaneously. The temporal dynamics of the SML biology as well as concentrations of  inorganic and organic constituents enabled the assessment of their sources and the nature of the enrichments taking place within the SML. The first comprehensive insight into concentration levels of macro nutrients (N, P), trace metals (eg. Cu, Pb, Cd, Ni, Zn, Co) and OM (including aromatic pollutants) in atmospheric samples, their transport history, source apportionment and deposition fluxes to the oligotrophic Adriatic area will be presented. Daily and seasonal variations of PM10 composition were affected by local traffic and open-fire events as well as by local meteorological conditions and long-range transport. The BC contribution of biomass burning versus fossil fuel combustion changed seasonally. Source apportionment module of LOTOS-EUROS chemical transport model enabled identification and quantification of main source areas contributing to deposition of PM. The main PM contributor is a public power sector outside Croatia while other contributing sectors are energy production, traffic, residential combustion as well as shipping. First deposition fluxes estimates show reasonable agreement between model calculations and measured data, and could be used for more general assessments of atmospheric inputs.

 

Acknowledgment: This work has been supported by Croatian Science Foundation under the IP-2018-01-3105 project: Biochemical responses of oligotrophic Adriatic surface ecosystems to atmospheric deposition inputs.

How to cite: Frka, S., Milinković, A., Penezić, A., Bakija Alempijević, S., Gašparović, B., Skejić, S., Šantić, D., Džaja Grgičin, V., Brzaj, S., Vidič, S., Šimić, I., Žužul, S., Bešlić, I., Godec, R., and Pehnec, G.: Biochemical responses of oligotrophic Adriatic Sea surface layers to atmospheric deposition inputs, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15108, https://doi.org/10.5194/egusphere-egu2020-15108, 2020.

EGU2020-19558 | Displays | AS2.14

Aerosol pH 25-years trend predicted from fog composition in Po Valley, Italy

Marco Paglione, Stefano Decesari, Matteo Rinaldi, Francesco Manarini, Stefania Gilardoni, Michele Brunetti, Maria Cristina Facchini, Sandro Fuzzi, Dimitri Bacco, Arianna Trentini, Spyros N. Pandis, and Athanasios Nenes

pH is a fundamental aerosol property that affects ambient particle composition, concentration and toxicity, linking pH to all aerosol environmental impacts. Direct measurement of aerosol pH is highly challenging, and so indirect proxies are often used to represent particle acidity. Aerosol thermodynamic models, such as ISORROPIA-II, are able to calculate particle pH – based on concentrations of various aerosol species, temperature (T), and relative humidity (RH) – and offer a rigorous approach to obtain aerosol pH already tested in the past with ambient aerosol data. However not many long aerosol measurements datasets exist to understand the trend of particle acidity along the past decades in Europe as well as around the world. Long-term monitoring programs for cloud/fog composition and acidity are also lacking in the global scientific community, but there are a few locations around the world where such measurements have been made routinely or periodically over periods of a decade or more. One of these locations is the rural station of San Pietro Capofiume in the Po Valley (Italy), where a consistent long dataset of fog-water ionic composition exists spanning the last 25 years (1993-2018).

In this study, assuming that fog acts as an efficient natural scavenger of aerosol particles, we use the inorganic composition of fog-water collected at SPC as a proxy for the chemical composition of atmospheric aerosol in pre-fog conditions. So, we apply ISORROPIA-II to calculate the pH associated with particles having the same chemical composition of fog-water. In this way we extend the analysis to the long-time record of fog-water measurements obtaining the aerosol pH trend of the last 25 years. A comparison with existing aerosol samples and parallel ammonia gas measurements allow us to validate the approach.

Our thermodynamic analysis suggests a decreasing trend of aerosol pH in Po Valley. Over the twenty-five-year period the aerosol pH decreased approximately 1.1-1.6 pH units, progressing also with an increasing rate of reduction, which corresponds to 0.18 pH units between the first and the second decades (1993-2002 and 2003-2012 respectively) and 0.44 between the decade 2003-2012 and the last 6 years (2013-2018).

A multiple linear regression analysis applied on the simulated aerosol pH reveals that the aerosol pH reduction trend is driven by the contemporary decrease of the main pollutants atmospheric concentration (possibly due to the European environmental policies) and by the changing meteorogical parameters (T and RH), possibly linked with climate change.

Our analysis suggests for the first time the possibility of calculating pre-fog aerosol pH using fog compositional data in a thermodynamically consistent way, which can be useful to evaluate long-term trend of particles acidity also in other region of the world for which data are available (e.g., Californian Central Valley).

Projecting the trend in the future it is possible to speculate a potential change in deposition of nitrate/nitric acid from aerosol-dominant (slow) to gas-dominant (fast) with very important consequences in air quality.

How to cite: Paglione, M., Decesari, S., Rinaldi, M., Manarini, F., Gilardoni, S., Brunetti, M., Facchini, M. C., Fuzzi, S., Bacco, D., Trentini, A., Pandis, S. N., and Nenes, A.: Aerosol pH 25-years trend predicted from fog composition in Po Valley, Italy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19558, https://doi.org/10.5194/egusphere-egu2020-19558, 2020.

EGU2020-10045 | Displays | AS2.14

Impacts of acidity on multiphase chemistry in aqueous particles and clouds

Thomas Schaefer, Andreas Tilgner, Havala O. T. Pye, V. Faye McNeill, and Hartmut Herrmann

The acidity of aqueous atmospheric solutions is a key parameter driving both partitioning of semi-volatile acidic or basic trace gases and their linked aqueous-phase chemistry. On the other hand, acidity of atmospheric aqueous phases, e.g. deliquesced aerosol particles, cloud and fog droplets, is conversely affected by aqueous-phase chemistry processes. Those feedbacks in acidity and chemistry have crucial implications for the (i) tropospheric lifetime of air pollutants, hence air quality and atmospheric aerosol composition, (ii) deposition input into other terrestrial and oceanic ecosystems, (iii) the visibility, (iv) climate and (v) human health. Due to their fundamental role, atmospheric research has gained substantial progress in the understanding in feedbacks of acidity and multiphase chemistry. In the present study, the current state of knowledge on the acidity-multiphase chemistry feedbacks has been summarized. From a wide range of topics, two selected issues focusing on impacts of acidity (i) on the hydration of organic carbonyl compounds and (ii) multiphase chemistry of dissociating organic compounds in aqueous particles and clouds will be presented.

Hydration processes are typically known to be acid- or base-catalyzed. Thus, the acidity of an aqueous solution can affect the hydration and all other processes linked to it. This comprehensive literature study revealed that the hydration of simple aldehydes and ketones as well as dicarbonyls is less affected by acidity. However, for multifunctional carbonyl compounds such as pyruvic acid, the hydration equilibrium constant of the carbonyl group is strongly influenced by the electronic effects of the adjacent group. The hydration of carbonyl groups in compounds that also contain pH sensitive moieties, such as α-oxocarboxylic acids, is highly influenced by the acidity of the surrounding environment. However, this acidity effect is often not considered in multiphase models.

Furthermore, oxidation reactions of dissociating organic compounds can be affected by acidity. To examine the effect of acidity on the chemical processing of dissociating organic compounds, kinetic data for their oxidation by OH, NO3 and O3 have been newly compiled in the present study. Kinetic reactivity data of both protonated and deprotonated organic compounds together with their reactivity ratio  have been investigated to identify possible acidity effects. The present study showed that, for OH reactions, the impact of acidity on the chemical kinetics is often quite small and only important for some specific compounds. On the other hand, for NO3 reaction, particularly under cloud conditions, acidity can substantially affect the chemical NO3-initiated processing of organic compounds. Less acidic conditions will enhance the degradation of dissociating compounds via NO3 because of more rapid oxidation and possibility of additional ETR pathway. Furthermore, the present O3 kinetic data analyses have demonstrated the role of acidity for ozonolysis processes, especially for phenolic compounds. Overall, the present study summarizes atmospheric implications and needs for future investigations, particularly with respect to changing aerosol and cloud acidity conditions in the future.

How to cite: Schaefer, T., Tilgner, A., Pye, H. O. T., McNeill, V. F., and Herrmann, H.: Impacts of acidity on multiphase chemistry in aqueous particles and clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10045, https://doi.org/10.5194/egusphere-egu2020-10045, 2020.

EGU2020-9562 | Displays | AS2.14

Seasonal variability of submicron aerosol acidity at a coastal site in the Eastern Mediterranean

Anna Maria Neroladaki, Iasonas Stavroulas, Irini Tsiodra, Stelios Myriokefalitakis, Anthanasios Nenes, Nikos Mihalopoulos, and Maria Kanakidou

Aerosol acidity (pH) plays a significant role in the chemical behaviour of atmospheric particles, since it affects their composition and toxicity. This study investigates the seasonal variability of submicron particles acidity at the Finokalia atmospheric observatory in the eastern Mediterranean from February to December 2014. Direct measurements of aerosol pH are challenging and thus very rare. Therefore, aerosol pH is generally derived from thermodynamic model calculations. Submicron aerosol chemical composition data along with NH3 and HNO3 gas phase concentrations measured at Finokalia are here used in the thermodynamic model ISORROPIA-II in order to predict the aerosol pH. The predicted pH values show clear seasonality and the expected dependence on temperature and relative humidity. Submicron aerosols at Finokalia have been found to be acidic with an average pH values over the studied period of 1.77 ± 0.67, with the highest values occurring in winter and the lowest in summer and a winter to summer ratio of about 1.4.

We acknowledge support of this work by the project “PANhellenic infrastructure for Atmospheric Composition and climatE change” (MIS 5021516) which is implemented under the Action “Reinforcement of the Research and Innovation Infrastructure”, funded by the Operational Programme "Competitiveness, Entrepreneurship and Innovation" (NSRF 2014-2020) and co-financed by Greece and the European Union (European Regional Development Fund).

How to cite: Neroladaki, A. M., Stavroulas, I., Tsiodra, I., Myriokefalitakis, S., Nenes, A., Mihalopoulos, N., and Kanakidou, M.: Seasonal variability of submicron aerosol acidity at a coastal site in the Eastern Mediterranean, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9562, https://doi.org/10.5194/egusphere-egu2020-9562, 2020.

EGU2020-717 | Displays | AS2.14

Aerosol acidity and its neutralization in the eastern Indo-Gangetic Plain: implications for water-soluble organic carbon

Bijay Sharma, Anuraag J. Polana, Prashant Rawat, and Sayantan Sarkar

Aerosol acidity plays an important role in influencing precipitation pH, which has impacts on the environment as well as human health. It also has significance in shaping aerosol chemistry, including the catalytic formation of water-soluble organic carbon (WSOC), which in turn affects the hygroscopicity of aerosols. Past studies on aerosol acidity in the Indian subcontinent, mostly conducted in biomass burning (BB) source regions in the northwestern and central Indo-Gangetic Plain (IGP) and in western India, have identified Ca2+ and Mg2+ sourced from desert dust to be the predominant neutralizing agents. However, the prevalence of desert dust decreases progressively along the IGP corridor and is potentially rendered insignificant in the eastern IGP (eIGP). As such, there exists a critical weakness in our understanding of the processes governing aerosol acidity and its neutralization in the eIGP. To address this, the present study reports the seasonal variability of ionic species, WSOC and associated aerosol acidity in ambient PM2.5 from a rural receptor site in the eIGP. To this end, a total of 88 PM2.5 samples collected during the summer, post-monsoon and winter seasons of 2018 were analyzed for SO42-, NO3-, Cl-, Na+, NH4+, K+, Ca2+, Mg2+, F-, PO43- and WSOC, followed by estimation of strong acidity. Across all seasons, the aerosol phase was dominated by SO42-, NH4+ and NO3-, with values increasing by factors of 1.8-1.9, 1.4-2.9 and 1.8-11, respectively, for the regional BB-dominated post-monsoon and winter seasons as compared to summer. Significant positive Cl- depletion in summer pointed towards the influx of marine air while negative depletion in post-monsoon and winter suggested a BB source, which was further supported by concentration-weighted trajectory analysis. The averaged pH of the aerosol extract decreased progressively from summer (5.5±0.4) to winter (4.5±0.2). NH4+ was observed to be the major acid-neutralizing agent across all seasons, with dust-derived Ca2+ and Mg2+ playing only minor roles. In general, WSOC formation is known to be catalyzed by the presence of excess acidity; however, during winter, it appeared that the regional transport of organic acids in the BB plume contributed to aerosol acidity at this receptor site (r=0.92; p<0.01 for WSOC and H+). BB-derived K+ appeared to perform a dual function of neutralizing acidity as well as producing it via reactions with WSOC during atmospheric transport. The wintertime acidity was also strongly governed by aerosol NO3- sourced from BB emissions and possibly accentuated via nighttime atmospheric chemistry at lower ambient temperatures, resulting in the formation of haze. These observations of the NO3- and WSOC-driven wintertime acidity, the dual function of K+ and the dominant role of NH4+ in neutralization points to complex atmospheric processing of the IGP outflow during its transport to the eastern end of the corridor, which warrants further investigation.

How to cite: Sharma, B., J. Polana, A., Rawat, P., and Sarkar, S.: Aerosol acidity and its neutralization in the eastern Indo-Gangetic Plain: implications for water-soluble organic carbon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-717, https://doi.org/10.5194/egusphere-egu2020-717, 2020.

EGU2020-3611 | Displays | AS2.14

Iron in Soils and Road Dust is Modulated by Coal-Fired Power Plant Sulfur Making Toxic PM2.5

Rodney J. Weber, Jenny Wong, Yuan Wang, Ting Fang, James Mulholland, Armistead (Ted) Russell, Stefanie Sarnat, and Athanasios (Thanos) Nenes

Transition metal ions, such as water-soluble iron (WS-Fe), are toxic components of fine particulate matter (PM2.5). In Atlanta, GA, from 1998 to 2013, WS-Fe was the PM2.5 species most associated with adverse cardiovascular outcomes in a previous study. We examined this data set to investigate the sources of WS-Fe and effects of air quality regulations on ambient levels of WS-Fe. Insoluble forms of iron in mineral and traffic dust combined with sulfate from coal-fired electrical generating units (EGU) were converted to soluble forms by sulfate-driven acid-dissolution. Sulfate produced both the highly acidic aerosol (summer pH 1.5-2) and liquid water required for the aqueous phase acid-dissolution, but variability in WS-Fe was mainly driven by particle liquid water. These processes were more pronounced in summer when particles were most acidic, whereas in winter the relative importance of WS-Fe from combustion emissions increased. Although WS-Fe represents a minute mass fraction (0.15%) of PM2.5, the observed high correlation between WS-Fe and PM2.5 mass (r=0.67) may result from these formation routes and account for some association between mass and adverse health seen in past studies. Similar processes are expected in many regions, implying these unexpected benefits from coal-burning reduction may be widespread.

How to cite: Weber, R. J., Wong, J., Wang, Y., Fang, T., Mulholland, J., Russell, A. (., Sarnat, S., and Nenes, A. (.: Iron in Soils and Road Dust is Modulated by Coal-Fired Power Plant Sulfur Making Toxic PM2.5, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3611, https://doi.org/10.5194/egusphere-egu2020-3611, 2020.

We take moist air (and artificial air) at +0.35 ⁰C, variously doped with CO2, and pass it through a chamber chilled to -3⁰C.  We record any depletion of CO2 in the gas stream using differential NDIR spectrometers, and we then de-gas the melt-water to measure the captured CO2, again with NDIR.  Preliminary results are consistent with published curves for the CO2/hydrate equilibrium at partial pressures relevant to the petrochemical industry and to industrial carbon capture as determined by Raman microscopy (Chazallon and Pirim 2018).

Extension of the CO2/ice curve to atmospheric partial pressures allows a review of a range of related issues in atmospheric water, one of the more accessible being its acidity. The dissociation of CO2 in water at equilibrium with 400ppm CO2 at Earth surface is quoted as pH5.6, but fresh rainwater (and snow-melt) can be significantly more acidic, decaying exponentially to equilibrium with a half life of around four hours. This observation is consistent with published analyses of [CO2] in rainwater that are significantly higher than the Henry equilibrium (Warneck 2000).  Both would be explained if convection was resulting in CO2/ice-formation in clouds within the boundary layer, in turn leading to deposition of supersaturated levels of CO2 together with enhanced acidity.

This paper speculates on the local [H3O+] delivered by the melting of an ice particle that had grown in an atmosphere of 400ppm CO2 at an altitude of 1km, and its dissipation through dilution by neighbouring unfrozen water drops and by slow release from the residue of hydrate caging in liquid water. For Earth surface it has potential implications for acid rain, for the solution and redeposition of carbonate rocks, and for ocean acidification.  

How to cite: Durham, B. and Pfrang, C.: CO2 hydrate equilibria at atmospheric partial pressures, and implications for atmospheric acidity , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6107, https://doi.org/10.5194/egusphere-egu2020-6107, 2020.

EGU2020-17843 | Displays | AS2.14

The importance of atmospheric acidity for nutrient deposition on global scale

Maria Kanakidou, Stelios Myriokefalitakis, Athanasios Nenes, and Nikos Daskalakis

Atmospheric deposition can be an important source of nutrients and trace elements for land and ocean ecosystems. Atmospheric acidity is an important driver of the solubility of nutrients and trace elements present in atmospheric aerosols. Using a global 3-dimensional chemical transport model, we summarize here human driven past and future changes in the aerosol acidity and the resulting changes in the nitrogen, phosphorus and iron atmospheric deposition and solubility. We present and discuss the acidity driven changes in the chemical speciation and geographic patterns of nutrient deposition. Areas of uncertainties and implications for ecosystems functioning are discussed.

This work has been supported by the project “PANhellenic infrastructure for Atmospheric Composition and climatE change” (MIS 5021516) which is implemented under the Action “Reinforcement of the Research and Innovation Infrastructure”, funded by the Operational Programme "Competitiveness, Entrepreneurship and Innovation" (NSRF 2014-2020) and co-financed by Greece and the European Union (European Regional Development Fund) and by the University of Bremen Excellence Chair of MK.

How to cite: Kanakidou, M., Myriokefalitakis, S., Nenes, A., and Daskalakis, N.: The importance of atmospheric acidity for nutrient deposition on global scale, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17843, https://doi.org/10.5194/egusphere-egu2020-17843, 2020.

EGU2020-14697 | Displays | AS2.14

The role of Organophosphate Esters Flame Retardants (OPEs) and organophosphate pesticides in Phosphorus Cycle in the atmosphere of Mediterranean Sea.

Kalliopi Violaki, Maria Tsagaraki, Athanasios Nenes, Richard Sempere, Javier Castro Jimenez, and Christos Panagiotopoulos

The atmosphere is considered as an important external nutrient source for the marine environment, especially in remote ocean waters or the oligotrophic Mediterranean Sea. Phosphorus (P) is a critical nutrient affecting primary productivity in large areas of oceanic ecosystems. Much has been placed on inorganic P, while the importance of organic P as potential pool of bioavailable P is not widely recognized. In this study we quantify and speciate the anthropogenic organic P in the West and East Mediterranean atmosphere. Several anthropogenic organophosphorus compounds are analyzed, including pesticides (Phosmet, Malathion, Ethoprophos, Diazinon, Chloropyrifos-Me, Chloropyrifos-e), organophosphorus flame retardants and plasticizers (OPEs) (Tris- (1-chloro-2-propyl) phosphate (TCPP), tris[2-chloro-1-(chloromethyl)ethyl]phosphate (TDCP), Tris-(2-chloroethyl)phosphate (TCEP), tri-n-butyl phosphate (TnBP), triphenyl phosphate (TPhP), 2-ethylhexyl diphenyl phosphate (EHDPP)).

Our analysis applied to Total Suspended atmospheric Particles (TSP) collected in Eastern (Crete, n = 67) and Western (Marseille, n = 25) Mediterranean Sea by using high-volume air sampler. The analysis performed with the liquid chromatography coupled to mass spectrometry (Q–TOF–LC/MS) after optimization of the analytical protocol for the aerosol samples. Five pesticides were found during the sampling period in East Mediterranean in total of 27 samples. The most frequent were chlorpyrifos–e (n = 9) and phosmet (n = 10) with average concentration 0.24±0.38 pmol m–3 and 0.24±0.45 pmol m–3, respectively following by diazinon (n = 4) at 0.07±0.00 pmol m–3. Higher concentration was estimated in chlorpyrifos-me at 0.91±0.93 pmol m–3 (n = 3) while ethoprophos was detected only in one sample (0.002 pmol m m–3), malathion was below detection limit. In the West Mediterranean, the most abundant organophosphate pesticides were phosmet (n = 3) with an average concentration of 0.07±0.04 pmol m–3, followed by diazinon (0.05 pmol m–3, n = 1) and chloropyrifos-e (0.04 pmol m–3, n = 2). Malathion, chlorpyrifos-me and ethoprophos were not detected. The average contribution of organophosphate pesticides in atmospheric organic P detected during this study was 0.2% and 0.1% for East and West Mediterranean, respectively.

OPEs analyses in the same samples revealed higher concentrations in the West than in East Mediterranean atmosphere especially for TCPP, TCEP and TDCP, which are considered as the most potentially hazardous. In the West Med. the most abundant detected OPEs were the EHDPP (3.04±4.17 pmol m-3) and the TCPP (1.71±1.28 pmol m-3). In East Mediterranean, the most abundant detected OPEs were the TCPP (0.36±0.29 pmol m-3) and the TCEP (0.24±0.20 pmol m-3) whereas the TDCP and the EHDPP were not detected. The percentage contribution of OPEs in atmospheric organic–P over the West Mediterranean was 9%, while over East was 0.4%.

The total anthropogenic organic P deposited in East Mediterranean during stratification period (June-September) was calculated at 8 tons, which was 4 times lower comparing with West Mediterranean (29 tons of P) during the same period. Overall, the above anthropogenic compounds represented only 0.4% of the total anthropogenic P deposited during stratification period, however their toxicity and fate to the marine environment warrants further investigations.

How to cite: Violaki, K., Tsagaraki, M., Nenes, A., Sempere, R., Jimenez, J. C., and Panagiotopoulos, C.: The role of Organophosphate Esters Flame Retardants (OPEs) and organophosphate pesticides in Phosphorus Cycle in the atmosphere of Mediterranean Sea., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14697, https://doi.org/10.5194/egusphere-egu2020-14697, 2020.

EGU2020-13075 | Displays | AS2.14

A state-of-the-art parameterization of atmospheric nutrient deposition fluxes in the global ocean

Stelios Myriokefalitakis, Matthias Gröger, Jenny Hieronymus, and Ralf Döscher

Atmospheric deposition of trace constituents of natural and anthropogenic origin act as a nutrient source into the open ocean, affecting the marine ecosystem functioning and subsequently the exchange of CO2 between the atmosphere and the global ocean. Among other species that are deposited into the open ocean, nitrogen (N), iron (Fe), and phosphorus (P) are considered as highly significant nutrients that can limit marine phytoplankton growth and thus directly impact on ocean carbon fluxes in the ocean, particularly where the nutrient availability is the limiting factor for productivity. For this work, we take into account the up-to-date understanding of the effects of air quality on the atmospheric aerosol cycles to investigate the potential ocean biogeochemistry perturbations via the atmospheric input with the European Community Earth System Model EC-Earth (http://www.ec-earth.org/), which is jointly developed by several European institutes. In more detail, state-of-the-art N, Fe, and P atmospheric deposition fields are coupled to the embedded marine biogeochemistry model and the response of oceanic biogeochemistry to natural and anthropogenic atmospheric aerosols deposition changes is demonstrated and quantified. Model calculations show that compared to the present day, the preindustrial atmospheric deposition fluxes are calculated lower (~1.7, ~1.5, and ~1.4 times for N, Fe, and P, respectively) corresponding to a respective lower marine primary production. On the other hand, future changes in air pollutants under the RCP8.5 scenario result in a modest decrease of the bioaccessible nutrients input into the global ocean (~ -15%, ~ -16% and ~ -22% for N, Fe and P, respectively) and overall to a slightly lower projected export production compared to present day. Although the impact of atmospheric processing on atmospheric inputs to the ocean results in a relatively weak response in total global-scale simulated marine productivity estimates, strong regional changes up to 40-60% are calculated in the subtropical gyres. Overall, this study indicates that both the atmospheric processing and the speciation of the atmospheric nutrients deposited in the ocean should be considered in detail in carbon-cycling studies, since they may significantly affect the marine ecosystems and thus the current estimates of the carbon cycle feedbacks to climate.

This work has been financed by the National Observatory of Athens internal grant (number 5065), the “Atmospheric deposition impacts on the ocean system”, and the European Commission's Horizon 2020 Framework Programme, under Grant Agreement number 641816, the "Coordinated Research in Earth Systems and Climate: Experiments, kNowledge, Dissemination, and Outreach (CRESCENDO)".

How to cite: Myriokefalitakis, S., Gröger, M., Hieronymus, J., and Döscher, R.: A state-of-the-art parameterization of atmospheric nutrient deposition fluxes in the global ocean , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13075, https://doi.org/10.5194/egusphere-egu2020-13075, 2020.

EGU2020-12274 | Displays | AS2.14

Assessing the Contribution of Oceanic Fluxes to the Global Budget of Carbonyl Sulfide

Parvadha Suntharalingam, Zhaohui Chen, Sinikka Lennartz, and Erik Buitenhuis

Accurate quantification of the global budget of atmospheric carbonyl sulfide (COS) is needed given its role in atmospheric chemistry and the global carbon cycle. COS is the most abundant atmospheric sulfur gas. In the stratosphere, COS is photodissociated to provide a significant source of sulfate aerosol, a key agent of stratospheric ozone depletion.  In the troposphere, measurements of the COS variation have the potential to provide constraints on the rates of CO2 assimilation by terrestrial plants and hence on primary productivity. Accurate knowledge of the global budget of COS and of its respective source and sink fluxes is therefore needed to understand its impact on ozone depletion and on the carbon cycle. Recent estimates of the global COS budget, however, reveal discrepancies between known sources and sinks. In particular the magnitude of the oceanic flux (the largest known source to the atmosphere) remains uncertain. The ocean provides a source of COS to the troposphere through direct emission, and potentially through emission of COS precursors such as carbon disulfide (CS2). Here we assess the role of the ocean in the global COS budget using a global atmospheric transport model (GEOS-Chem) in combination with recent estimates of COS source and sink fluxes, and with available oceanic and atmospheric measurements of COS.  We compare different realizations of oceanic COS fluxes taken from ocean biogeochemistry models and from recent data syntheses, and assess their ability to reduce the uncertainty in the current global budget of COS.

How to cite: Suntharalingam, P., Chen, Z., Lennartz, S., and Buitenhuis, E.: Assessing the Contribution of Oceanic Fluxes to the Global Budget of Carbonyl Sulfide, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12274, https://doi.org/10.5194/egusphere-egu2020-12274, 2020.

In a recent study, it was suggested based on the apparent correlation between multi-annual measurements of summertime maxima and wintertime minima temperature and calculated pCO2 in the most eastern region of the Mediterranean Sea surface waters that they are a net source of atmospheric CO2. Furthermore, it was predicted that the magnitude of this source would increase substantially in this region and that adjacent regions in the Eastern Mediterranean as well would turn into net sources of atmospheric CO2 due to the fast warming of these waters. In order to confirm the underlying assumption that seasonal variations in pCO2 in Eastern Mediterranean surface waters are primarily a strong function of seasonal variations in temperature, water samples were collected for the analysis of total alkalinity and pH during 12 monthly cruises from February 2018 to January 2019 at the shallow (THEMO1) and the deep (THEMO2) open water stations that are ca.10 and 20 NM off the Mediterranean coast of Israel. The data from all the cruises show that surface (< 30m depth) seawater pCO2 has a strong positive linear relationship with temperature in both stations (n=56, r2=0.94, p<0.001). The calculated annual net flux of CO2 from the surface to the atmosphere based on these measurements is ca.1.13 Tg C y−1, which is ca.15% higher than the previously estimated flux, but within its range of uncertainty (± 30%). These results clearly demonstrate that surface water pCO2 levels are indeed a strong positive function of the seasonal variations in sea-surface temperature and that the open water of the most eastern Mediterranean Sea is a net source of atmospheric CO2. These results are also in agreement with the conclusions of observational and modelling studies of air-sea CO2 fluxes in the centers of subtropical gyres and therefore globally relevant.

How to cite: Yu, J.: Air-Sea seasonal CO2 fluxes in a fast warming oligotrophic region – the Eastern Mediterranean case study , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6143, https://doi.org/10.5194/egusphere-egu2020-6143, 2020.

One of the main goals in the regional biogeochemical research of East Asia is to evaluate the state of acid deposition and the related pollution within EANET region (EANET, 2019). In the south of the Russian Far East there are two networks developed to monitor the content of acidic substances in atmospheric fall-out. The first one is the Russian national precipitation chemistry stations operated for more than 30 years, and the second is the international atmospheric monitoring sites supervised by EANET and WMO-GAW (Yearbook, 2019). We calculate the total deposition of airborne sulfur and nitrogen in a large region to evaluate their atmospheric balances under the transboundary influence. The present study focuses on the development and application of the spatial interpolation method to estimate wet deposition fluxes based on the monitoring data for 2013-2018. On the first step of the algorithm, we analyze the correlation of pollution monitoring results between network stations and estimate the maximum radius of representativeness for each station. On the second step, we interpolate the precipitation chemistry data for the set of meteorological stations located in the region under the study and calculate the wet deposition fluxes of sulfur and nitrogen for these sites. The flux values obtained are further interpolated for the regular grid of 10-km by 10-km cells within the region under the study. Finally, the total wet sulfur and nitrogen deposition for the region is a sum of deposition fluxes calculated for each cell. Additionally, we compared the data obtained with the correspondent flux calculated on the basis of the national snow cover chemistry network for the same region and period.

References

  1. EANET. Fourth Report for Policy Makers (RPM4): Towards Clean Air for Sustainable Future in East Asia through Collaborative Activities. 2019. 50 p.
  2. Yearbook. State and pollution of the environment in the Russian Federation: 2018. Moscow: RosHydroMet, 2019. 227 p. [in Russian]

How to cite: Gromov, S. A., Galushin, D. A., and Zhadanovskaya, E. A.: Estimation of the total wet sulfur and nitrogen deposition as a part of pollution balance in the south of the Russian Far East based on the monitoring data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13871, https://doi.org/10.5194/egusphere-egu2020-13871, 2020.

Phytoplankton is closely related to the Arctic Amplification in a future caused by the biogeophysical feedback. In particular, the increase in nutrients, which is one of the limiting factors of phytoplankton, affected by the increased inflow of rivers due to the Arctic warming in the Arctic region. Since Arctic region is sensitive to the feedback, the biological feedback is still difficult to expect an accurate simulate in the modeling simulation. This study used the GFDL-TOPAZ model by prescribing a runoff nitrogen flux in the contemporary level to simulate the phytoplankton, then prescribing the nitrogen flux over the East Siberian-Chukchi Sea. The model results underestimate chlorophyll A concentration and nutrient compared to the ARAON ship observation. But, We showed that the experiment of prescribing a regional runoff nitrogen flux by the river is well simulatinges the chlorophyll A concentration and nutrients than the CTRL experiment. Also, a  model result showed that the sea ice concentration in the Chukchi-East Siberian Sea and Kara-Barents Sea decreased, and it suggests that the regional change of the nutrient could, directly and indirectly, affect that Arctic sea ice concentrations

How to cite: Park, J. H. and Kim, B.: Impact of the regional runoff Nitrogen Flux using the GFDL-TOPAZ simulation on the Arctic Ocean phytoplankton., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20893, https://doi.org/10.5194/egusphere-egu2020-20893, 2020.

EGU2020-19351 | Displays | AS2.14

Which Processes Sustain Biota in Open-Ocean Deep Chlorophyll Maxima?

Shaun Rigby, Richard Williams, Eric Achterberg, and Alessandro Tagliabue

Deep chlorophyll maxima (DCM) are productive layers widespread throughout the global ocean. In the DCM, marine phytoplankton are adapted to low light conditions at the cost of elevated cellular iron (Fe) requirements, leading to Fe deficient growth. To sustain productivity, nutrient demands must be met by sources such as the dissolution of sinking lithogenic particles, recycling of biogenic particles and physical transport from below. The GEOTRACES programme has expanded the global ocean datasets for a suite of trace metals and also noble gases. Here, we exploit helium measurements to derive a vertical flux estimate of nitrate (NO3), phosphate (PO4), silica (Si) and Fe into the DCM in the subtropical North Atlantic and equatorial Pacific. We apply the Si* relation to show differences in nutrient deficiency between waters in the DCM and the upward flux into the DCM. The offset in Si* between the DCM and upward flux may be enhanced or reduced by the dissolution of sinking particles or internal recycling. We show that the upward Fe flux to the DCM is of similar magnitude to Fe supplied through regeneration. In contrast, we show that the upward Fe flux outweighs estimates of Fe supplied to the DCM via recycling or lithogenic particles in the subtropical North Atlantic. The muted role of lithogenic particles in our estimates leads to the question: what assumptions must be made about aeolian deposition to increase the relevance of lithogenic particles at the DCM?

How to cite: Rigby, S., Williams, R., Achterberg, E., and Tagliabue, A.: Which Processes Sustain Biota in Open-Ocean Deep Chlorophyll Maxima?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19351, https://doi.org/10.5194/egusphere-egu2020-19351, 2020.

EGU2020-20613 | Displays | AS2.14

Determinants of calcite flux in planktonic foraminifera on seasonal and interannual time scales

Peter Kiss, Lukas Jonkers, Natália Hudáčková, Runa Turid Reuter, and Michal Kučera

Planktonic foraminifera precipitate calcareous shells, which after the death of the organisms are exported from the sea surface to the sea floor, where they are preserved on geologically relevant timescales. The export flux of planktonic foraminifera shells constitutes globally up to a half, and in the studied region off Cap Blanc (Atlantic Ocean) about one third, of the marine pelagic calcite flux. Given their importance for the marine calcite budget and for the pelagic carbonate counter pump, which counteracts the biological pump in terms of oceanic capacity for intake of CO2, it is crucial to gain an understanding of factors modulating the export flux of planktonic foraminifera calcite. In principle, variability in the export flux of planktonic foraminifera calcite could depend within one species on i) shell flux, ii) shell size and iii) calcification intensity, and where shell size and calcification intensity differ among species also on the species composition of the deposited assemblage. To assess the importance of these aspects in modulating the export flux of planktonic foraminifera calcite, we investigated two annual time series (from 1990-1991 and 2007-2008) from sediment traps moored in the Cap Blanc upwelling area. We assessed the predictability of foraminifera calcite flux variability on seasonal and interannual time scales, by determining the variability in species-specific shell fluxes, shell sizes and weights with bi-weekly resolution. We find a remarkable discrepancy in the contribution of the controlling factors between seasonal and interannual scales. On the seasonal time scale, 80% of the variability of the calcite flux is explained by shell flux. On the inter-annual time scale, on the other hand, variations in shell size and calcification intensity are key to explain the calcite flux, since the time series from 2007-2008 yielded 58% larger and 11% heavier specimens. These results imply that for the global estimate of planktonic foraminifera calcite flux, shell flux is likely the most relevant predictor. However, a prediction of the temporal evolution of the calcite flux will likely require estimates of changes in shell size and calcification intensity of the involved foraminifera species.

How to cite: Kiss, P., Jonkers, L., Hudáčková, N., Turid Reuter, R., and Kučera, M.: Determinants of calcite flux in planktonic foraminifera on seasonal and interannual time scales, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20613, https://doi.org/10.5194/egusphere-egu2020-20613, 2020.

EGU2020-3330 | Displays | AS2.14

Seasonal variation in inorganic carbon parameters in the southwestern Yellow Sea

Minwoo Seok, Ahra Mo, Seunghee Park, Young Ho Ko, Seongtae Yun, Dayoung Kim, and Tae-Wook Kim

To better understand carbon cycles in coastal and marginal seas, time-series monitoring is essential because of large temporal variabilities. In this regard, we conducted monthly field researches from April 2017 to May 2019 at the Socheongcho (SCC) Ocean Research Site (37°N‚124°E) in the Yellow Sea located between Korea and China. At each survey, we collected surface seawater samples during approximately 7 days with an sampling interval of two hours (except for spring 2017). Total alkalinity (TA) and dissolved inorganic carbon (DIC) were analyzed by using VINDTA 3C system, Apollo SciTech DIC analyzer and Apollo SciTech Alkalinity Titrator. In addition, a pH sensor (SeapHOx) was installed at the surface layer from September 2018 to June 2019 which is also capable of measuring salinity, temperature and oxygen. Based on the observations, we estimated a partial pressure of carbon dioxide (pCO2) and aragonite saturation state. As expected, seasonal variations in TA and DIC were strongly associated with those of salinity. We also detected a sudden increase DIC in October when vertical mixing was greatly enhanced. Despite a large outgassing during the fall season, annual mean air--sea influx of CO2 was ∼0.61mol·m−2·year−1, suggesting that the study area was a weak sink for atmospheric CO2. Aragonite was enerally reduced during winter (∼1.5). However, no undersaturation event was found during the whole investigation.

How to cite: Seok, M., Mo, A., Park, S., Ko, Y. H., Yun, S., Kim, D., and Kim, T.-W.: Seasonal variation in inorganic carbon parameters in the southwestern Yellow Sea, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3330, https://doi.org/10.5194/egusphere-egu2020-3330, 2020.

EGU2020-18860 | Displays | AS2.14

High-precision cavity ring-down measurements of ẟ13CO2 and 13CH4 along the Eastern North Atlantic onboard the sailing research vessel Fleur de Passion

Magdalena E. G. Hofmann, Daphne Donis, Jonathan D. Bent, Gregor Lucic, Ordonez Cesar, and Daniel F. McGinnis

Differentiating microbial, anthropogenic, and thermogenic sources of carbon dioxide (CO2) and methane (CH4) in background air is an important element of understanding upper ocean ecosystem processes. Concentrations of these gases alone are not dispositive indicators of processes, so additional diagnostic parameters including meteorological data, related gas species measurements, and isotopic values can allow researchers to better investigate processes. Here we present data from the Fleur de Passion sailing research vessel which traveled from Dakar, Senegal to the Azores, and to Northwest Spain between early April and October of 2019 as part of the larger Ocean Mapping Expedition by the Geneva-based NPO Fondation Pacifique. The 33-meter-long ketch research vessel carried as part of its instrument suite a Picarro G2201-i high precision gas analyzer, measuring concentrations and ẟ13C values of CO2 and CH4. The high precision data collected by the isotopic carbon analyzer (which are being sampled as part of the University of Geneva’s Winds of Change program) allow for subtle differentiation of modalities separated by a per mil or less, signals that could be lost by infrequent flask measurements or low-precision analyzers. We present findings from this expedition, as well as a brief description of future efforts to measure underway dissolved gases.

How to cite: Hofmann, M. E. G., Donis, D., Bent, J. D., Lucic, G., Cesar, O., and McGinnis, D. F.: High-precision cavity ring-down measurements of ẟ13CO2 and 13CH4 along the Eastern North Atlantic onboard the sailing research vessel Fleur de Passion, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18860, https://doi.org/10.5194/egusphere-egu2020-18860, 2020.

AS2.16 – Air-Land Interactions (General Session) and Land-Atmosphere Feedback

EGU2020-19004 | Displays | AS2.16

First Comprehensive Measurements of Emission Rates of Greenhouse Gases, Volatile Organic Compounds and Reduced Sulfur Compounds from a Tailings Pond in the Alberta Oil Sands

Ralf Staebler, Samar Moussa, Yuan You, Hayley Hung, Maryam Moradi, Amy Leithead, Peter Brickell, Katherine Hayden, Richard Mittermeier, and James Beck

Canada’s Oil Sands Region in northern Alberta contains the world’s largest deposits of commercially exploited bitumen. Extraction of synthetic crude oil from these deposits is a water intensive process, requiring large ponds for water recycling and/or final storage of tailings, already covering a total of over 100 km2 of liquid surface area in the Athabasca Oil sands. The primary extraction tailings ponds primarily contain sand, silt, clay and unrecovered bitumen, while a few secondary extraction ponds also receive solvents and inorganic and organic by-products of the extraction process. Fugitive emissions of pollutants from these ponds to the atmosphere may therefore be a concern, but until recently, data on emission rates for many pollutants, other than a few reported under regulatory compliance monitoring, were sparse. We present here the results from a comprehensive field campaign to quantify the emissions from a secondary extraction pond to the atmosphere of 68 volatile organic compounds (VOCs), 22 polycyclic aromatic compounds (PACs), 8 reduced sulfur compounds as well as methane, carbon dioxide and ammonia. Three micrometeorological flux methods (eddy covariance, vertical gradients and inverse dispersion modeling) were evaluated for methane fluxes to ensure their mutual comparability. Methane and carbon dioxide fluxes were similar to previous results based on flux chamber measurements. Emission rates for 12 PACs, alkanes and aromatic VOCs, several sulfur species, and ammonia were found to be significant. PACs were dominated by methyl naphthalenes and phenanthrenes, while diethylsulfide and  and n-heptane were the dominant reduced sulfur and VOC species, respectively. The role of these previously unavailable emission rates in regional pollutant budgets will be discussed.

How to cite: Staebler, R., Moussa, S., You, Y., Hung, H., Moradi, M., Leithead, A., Brickell, P., Hayden, K., Mittermeier, R., and Beck, J.: First Comprehensive Measurements of Emission Rates of Greenhouse Gases, Volatile Organic Compounds and Reduced Sulfur Compounds from a Tailings Pond in the Alberta Oil Sands, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19004, https://doi.org/10.5194/egusphere-egu2020-19004, 2020.

EGU2020-11796 | Displays | AS2.16

Deriving the sensible heat flux from the air temperature time-series through the flux-variance and the surface renewal methods

Milan Fischer, Gabriel Katul, Asko Noormets, Gabriela Pozníková, Jean-Christophe Domec, Matěj Orság, Miroslav Trnka, and John King

Eddy covariance (EC) has become the standard method for determining energy fluxes at the soil-plant-atmosphere interface. However, the cost and complexity of EC often limit its widespread deployment, and therefore, alternatives need to be considered. Here, two alternative methods, flux-variance (FV) and surface renewal (SR), are evaluated in quantifying sensible heat flux at three sites representing agricultural (wheat field, straw and bare soil), agroforestry (pine-switchgrass intercroping) and natural forested wetland (mixed conifer-deciduous wetland forest) systems that span a broad range of canopy height and structural complexity. By considering the position of the sensors with respect to canopy, the measurements at these three sites were carried out in the atmospheric surface layer, roughness layer, and roughness to surface transitional layer, respectively. Since the introduction of FV and SR, several versions of these methods have been proposed, with significantly differing perspectives and assumptions. Until now, the differences between the methods have not been fully standardized or clarified. In principle, both methods require the monitoring of high frequency (e.g. 10 Hz) air temperature variation while some approaches require additional wind velocity measurements. This presentation provides an overview of the FV and SR approaches, including new perspectives as well as identifies the common framework of the methods rather than carrying out their mere comparison. We show that the frequently reported need for the calibration (e.g. against EC) cannot be fully overcome. However, it can be put in a more universal framework where the parameters of both methods requiring calibration are represented by joint physically based parameters such as surface aerodynamic properties rather than similarity constants in the case of FV or the mean volume over the area of the air parcels in the case of SR. After the selection of the most reliable approaches, regression analyses against EC shows that both methods can estimate sensible heat flux with slopes within ±10 % from unity and R2 >0.9 across all the three sites. The best performance of both FV and SR was at the agricultural field, where the measurements are well in the surface layer while the worst in the case of the tall forest where the measurements are still in the roughness sublayer and the roughness layer depth (with its inherent uncertainty) needs to be taken into account in the calculations. We conclude there may be opportunities to fill gaps in knowledge of ecosystem energy balance at substantial cost-savings in specialized circumstances where EC may not be appropriate using both FV and SR methods.

Acknowledgement: This study was conducted with support of SustES - Adaptation strategies for sustainable ecosystem services and food security under adverse environmental conditions (CZ.02.1.01/0.0/0.0/16_019/0000797) and USDA NIFA-AFRI Sustainable Bioenergy Program, 2011-67009-20089, Loblolly pine-switch grass intercropping for sustainable timber and biofuels production in the Southeastern United States.  Funding for AmeriFlux core site US-NC4 (natural forested wetland) was provided by the U.S. Department of Energy’s Office of Science.

How to cite: Fischer, M., Katul, G., Noormets, A., Pozníková, G., Domec, J.-C., Orság, M., Trnka, M., and King, J.: Deriving the sensible heat flux from the air temperature time-series through the flux-variance and the surface renewal methods, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11796, https://doi.org/10.5194/egusphere-egu2020-11796, 2020.

Air flows above forest canopies are typically governed by large coherent eddies generated mechanically by inflected mean wind velocity profile or thermally by buoyancy in the convective regime. A significant body of research have been devoted to the role of these eddies on ecosystem scalar (gases and heat) exchange since they are likely related to the energy balance closure problem observed at the eddy covariance (EC) stations and turbulent flux divergence under stable stratification. Here we utilize fiber-optic distributed sensing on a tall mast to observe the turbulent fluctuations of air temperature with high spatial (25 cm) and temporal resolution (1 Hz) from the forest floor up to 120 m above the ground. These unique measurements resolved the continuous vertical profile of scalar turbulence and hence enabled us to study the topology (height – time space) of the turbulent eddies in different stability regimes. For example, the inclination angle of the eddies changed with stability and the scalar ramps often observed in canopy flows were evident only close to the canopy top, whereas higher up thermal eddies dominated the flow. Furthermore, the measurements permitted the identification of coupled air layers and hence analysis on the dynamics of below-canopy decoupling. During stable conditions with wind shear large eddies and the related inverted ramps in the temperature time series were observed at the top of the decoupling layer, however when the wind shear decreased the flow switched to submeso regime with canopy waves. These analyses were then combined with concurrent turbulence measurements with 3D sonic anemometers at several heights and EC gas flux measurements at one height to gain new insights on the role of these eddies on gas (e.g. carbon dioxide) transport. The measurements were conducted during summer 2019 at the Hyytiälä SMEAR II station located in central Finland and the permanent ICOS measurements at the site were utilized to the fullest.

How to cite: Peltola, O., Lapo, K., Thomas, C., and Vesala, T.: Spatial observations of large eddies and cross-canopy coupling with joint fiber-optic distributed sensing and eddy covariance flux measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15840, https://doi.org/10.5194/egusphere-egu2020-15840, 2020.

EGU2020-7820 | Displays | AS2.16

Floodplain forest carbon exchange – a micrometeorological point of view

Natalia Kowalska, Georg Jocher, Ladislav Šigut, and Marian Pavelka

Since the eddy covariance (EC) method became a key method for measurements of the energy and greenhouse gas exchange between ecosystems and the atmosphere, a large number of studies was conducted to understand the mechanisms driving the carbon exchange in forest ecosystems. In recent years, case studies further focused on testing and validating the applicability of the EC technique above forest ecosystems, also assessing the spatial and temporal variability of sub canopy fluxes. These studies led to the conclusion that there is a high probability of overestimating the forest carbon sink strength with EC measurements above the forest canopy only, as these measurements may miss respiration components from within and below the canopy due to insufficient mixing across the canopy. Additional below canopy EC measurements were suggested to tackle this problem and to get information about potential decoupling between below and above forest canopy air masses as well as potentially missing respiration components in the above canopy derived signal.

The overall goal of the study here is to derive an as detailed as possible understanding of the carbon exchange in Lanžhot floodplain forest with the help of concurrent EC measurements below and above the forest canopy. Lanžhot floodplain forest is situated 6.5 km north of the confluence of the Morava and Thaya rivers in Czech Republic (48.6815483 N, 16.9463317 E). The long-term average annual precipitation at this site is around 517 mm and the mean annual temperature is 9.5 °C. The average groundwater level is -2.7 m. Since a long time flooding occurs here very rarely, the last flooding event was in 2013. In addition, the site is hydrologically managed. Consequently, the water regime of the site changed over the years and represents nowadays relatively dry conditions for such type of ecosystem.

To reach our research goal we evaluate different single- and two-level filtering strategies of the above canopy derived carbon exchange values and the impact of these filterings on the annual ecosystem carbon exchange rates. Our hypothesis is that conventional single-level EC flux filtering strategies like the u*-filtering might not be sufficient to fully capture the carbon exchange of the studied floodplain forest ecosystem. We further hypothesize that additional below canopy EC measurements are mandatory to achieve unbiased forest carbon exchange values with the EC technique.

How to cite: Kowalska, N., Jocher, G., Šigut, L., and Pavelka, M.: Floodplain forest carbon exchange – a micrometeorological point of view, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7820, https://doi.org/10.5194/egusphere-egu2020-7820, 2020.

EGU2020-3140 | Displays | AS2.16

Highly accurate analytical footprint model for general stratification of the atmosphere

Jean-Claude Krapez, Gregoire Ky, and Claire Sarrat

The flux footprint (or so-called source area) is the zone of the surface that contributes to a measured vertical flux (e.g. of water vapor or carbon dioxide) between the ground and the atmosphere: Footprint models are then used to derive location and size of the source area and for interpretation of flux-tower measurements, in particular to estimate the contribution of passive scalar sources to these measured fluxes, and to combine measured fluxes with remotely sensed data.

Existing footprint models are of two types: either they derive from the solution of an advection-diffusion differential equation or they result from a parameterization based on numerical simulations performed with a Lagrangian stochastic particle dispersion model. Models of the first type are essentially based on the hypothesis of power-law profiles of the mean wind speed u(z) and eddy diffusivity K(z). Our objective was to suppress this constraint and to build a footprint model for any type of profile, in particular Monin-Obukhov surface-layer profiles.

The model was developed in the frame of the K-theory. Homogeneous conditions were assumed in the horizontal plane and the alongwind diffusion term was neglected with respect to the advection term. A semi-analytical tool has been developed to cope with any type of atmosphere stratification. Applying a dedicated quadrupole method, the boundary layer is divided into a series of sublayers and an extended power law model is applied in each of them (10 to 15 sublayers are enough to reach an error of less than 0.1%, whatever the atmosphere stability).

In the end, a highly accurate estimation of the footprint can be obtained very quickly for any profile of wind speed and eddy diffusivity.

How to cite: Krapez, J.-C., Ky, G., and Sarrat, C.: Highly accurate analytical footprint model for general stratification of the atmosphere , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3140, https://doi.org/10.5194/egusphere-egu2020-3140, 2020.

EGU2020-5506 | Displays | AS2.16

Disentangling turbulent and non-diffusive fluxes in the boundary layer

Andrew Kowalski, Gerardo Fratini, Gabriela Miranda, Penélope Serrano-Ortiz, and George Burba

Arithmetic averaging procedures are traditionally used in many applications in the field of micrometeorology, but these neglect Osborne Reynolds's specification of turbulence, and thus, strictly speaking, violate the momentum conservation law. Recently, it has been shown  that applying linear momentum conservation to surface exchanges defines an average motion in the surface-normal direction (i.e., a Stefan flow), and thereby describes a non-diffusive transport that is distinct from turbulent transport. Here we examine data from a nearly ideal micrometeorological field site (extensive, flat, and mono specific-reed wetland) to show that traditional flux-tower calculations, including but not limited to the Webb corrections,  generally provide an inadequate approximation of turbulent  fluxes and yet still adequately characterize the net fluxes in most traditional cases. The importance of such conflation of diffusive and non-diffusive transport is greatest for situations with relatively large non-diffusive fluxes, as occurs during particular times of day in general and particularly when considering fluxes in the stream-wise direction. An examination of fluxes calculated using the traditional arithmetic averaging procedure, versus the proposed, more theoretically appropriate calculations that fully obey conservation law, illustrates important implications for the characterization of gas-exchange processes and more generally the discipline of micrometeorology. These implications may become particularly critical in near future as gas flux measurements enter an era of automated operation on massive network scales, including automated gas flux calculations. At the same time, such measurements strive to adequately represent gas exchange of newer species with extremely low fluxes (vs traditionally measured larger fluxes of H2O and CO2). Multiple assumptions, and neglected terms and processes historically deployed for evaluating larger fluxes, may no longer work well when much smaller fluxes are considered, especially when measured by a non-expert using a fully automated flux station. These no-longer-negligible aspects include fundamentals of adequately handling the diffusive and non-diffusive transport mechanisms addressed in this presentation.

How to cite: Kowalski, A., Fratini, G., Miranda, G., Serrano-Ortiz, P., and Burba, G.: Disentangling turbulent and non-diffusive fluxes in the boundary layer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5506, https://doi.org/10.5194/egusphere-egu2020-5506, 2020.

EGU2020-17997 | Displays | AS2.16

Challenges and opportunities of quantifying local CO2 advection at a mountain forest in the Alps

Marta Galvagno, Georg Wohlfahrt, Peng Zhao, Edoardo Cremonese, and Gianluca Filippa

Mountain forests, which play an important role in the mitigation of anthropogenic CO2 emissions are supposed to be heavily affected by climatic changes and extremes. Efforts towards the understanding of the physiological processes regulating mountain forest carbon and water fluxes are crucial to correctly manage and protect these key ecosystems. However, among the challenges in micrometeorological flux measurements in complex terrain, the unaccounted presence of advective CO2 fluxes has the potential to bias the daily and longer-term CO2 exchange estimates towards unrealistic net uptake, a bias that urgently needs to be accounted for in order to reduce uncertainties related to role of mountain forests in the global carbon cycle. On the other hand, given the typical local bi-directional wind system in mountains, information on advective flows at these sites could be easier to detect compared to other terrains. We present the results of a CO2 advection experiment conducted at a European larch site in Northern Italy (2100 m asl). The setup consisted of: the main eddy covariance flux tower (20 m), a sub-canopy eddy covariance flux system (2 m), a home-assembled system for measuring CO2 concentrations at three heights on the four sides of a 40 x 40 m control volume, composed by a solenoid valve system, multiple sampling inlets and a gas analyzer, and three automatic chambers measuring bare soil respiration (two chambers) and the net ecosystem CO2 exchange from the vegetated forest floor (one chamber). Results show that: i) advection is a not-negligible fraction of the total net ecosystem CO2 exchange of this forest, ii) coupling measurements of above and below canopy eddy covariance in mountain forest sites could emerge essential for detecting/estimating the unaccounted CO2 flux

How to cite: Galvagno, M., Wohlfahrt, G., Zhao, P., Cremonese, E., and Filippa, G.: Challenges and opportunities of quantifying local CO2 advection at a mountain forest in the Alps, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17997, https://doi.org/10.5194/egusphere-egu2020-17997, 2020.

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Testing approaches to simulate drainage from the canopy in interception models

Sandra Grunicke, Max Plorin, Christian Bernhofer, and Ronald Queck

Drainage from the canopy is one of the sub-processes described in conceptual interception models. In theory, this refers to rainfall water that is temporally stored on the canopy and starts to drip down, when the canopy is saturated. In most Rutter-type models, storage in the canopy is described as a single linear storage (in multilayer models as a storage cascade) from which the drainage occurs after a saturation value is reached. For a precise simulation of the timing and amount of canopy drainage, this approach appears to be insufficient. E.g., with large time-steps and highly filled storage, drainage rates can become larger than the precipitation intensity, leading to a negative storage.

In our study, we present a review of different approaches to simulate drainage according to literature. We test those approaches using the interception model CanWat, which allows temporally and spatially resolved simulations of the relevant processes. CanWat relies on a vegetation model derived from terrestrial laser scans for a detailed description of the stand. CanWat is written in R language allowing to process multi-annual time series for a study area up to 1 km² with a spatial resolution of 1 m3 on a PC. For validation purposes, we use rain events that are available from long-term continuous measurements of interception in a spruce stand (mainly Picea abies; a continuous flux site since started within EUROFLUX in 1996) within the Tharandter Wald Southwest of Dresden.

We outline benefits and limitations of each approach and evaluate which one best fits the needs for a precise simulation of the timing and amount of canopy drainage. The implementation and refinement of the most suitable drainage simulation approach into CanWat is part of the overall attempt to improve the model description of the interception process being the focus of a German Science Foundation (DFG BE-1721/23-1) interception project.

How to cite: Grunicke, S., Plorin, M., Bernhofer, C., and Queck, R.: Testing approaches to simulate drainage from the canopy in interception models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13065, https://doi.org/10.5194/egusphere-egu2020-13065, 2020.

The Caatinga is a seasonally dry tropical forest, which is the dominant vegetation type in the northeastern region of Brazil. Its many plant species have adapted to the semiarid climate through different biophysical and physiological traits and drought survival strategies. In recent years, this region has endured a number of prolonged droughts that have adversely affected this already severely water-limited region. Despite the relatively small amounts of rainfall (with annual rainfall ranging approximately between 100–800 mm/year), there is an almost perpetual occurrence of clouds due to the regional atmospheric circulation; broadly speaking cumulus or cumulonimbus in the rainy season, and mostly stratocumulus during the transition from wet to dry, and dry seasons.  We studied the effect of cloud cover on the radiation balance, as well on the surface energy- and carbon balance of a pristine Caatinga area from 2011 to 2018.

This study used radiation and weather data obtained from a SONDA BSRN radiation station, as well from a flux tower installed in the study area; both were near the urban areaofPetrolina, Brazil. Furthermore, radio-sounding data collected nearby were employed to obtain column integrated atmospheric water vapour, to estimate atmospheric emissivity.

We derived cloudiness from a number of indirect methods (using shortwave- and longwave incoming radiation) at diurnal, seasonal and multi-year timescales. We also employed observed cloud cover data, including those from sky-cameras, for verification.

Estimates of clear-sky atmospheric emissivity were required to determine cloud cover.  These were obtained from well-known equations (e.g., Brunt, Brutsaert and Prata) using tower air temperature and/or vapour pressure; calibration of the constants in these equations was required and their performance varied considerably. Occasionally, there were large differences between column integrated atmospheric water vapour and near-surface humidity; this had implications for estimates of atmospheric emissivity and hence of cloud cover.

Seasonal variations in turbidity varied by a factor of 2. Clear-sky conditions occurred for between 8-18% of the time, with the lowest percentage occurring for the wettest year (2011).

Despite its considerable effect on the radiation balance, the variation in cloud cover had a relatively modest effect only on the energy- and carbon balance fluxes. This has implications for our understanding of the Caatinga vegetation functioning, as well as for the development and testing of land surface models for this ecosystem.

This work has been supported by The Natural Environment Research Council (NE/N012488/1) and Fundação de Amparo à Ciência e Tecnologia do Estado de Pernambuco (Caatinga-FLUX Phase 2 APQ 0062-1.07/15).

How to cite: Verhoef, A., Moura, M. S. B., and Nóbrega, R.: The effect of cloud cover on the radiation-, energy- and carbon balance of a seasonally dry tropical forest in Brazil (Caatinga), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9210, https://doi.org/10.5194/egusphere-egu2020-9210, 2020.

EGU2020-22480 | Displays | AS2.16

Using Spatial Eddy Covariance to Investigate Energy Balance Closure over a Heterogeneous Ecosystem

Brian Butterworth, Ankur Desai, Sreenath Paleri, Stefan Metzger, David Durden, Christopher Florian, Matthias Mauder, Luise Wanner, Matthias Sühring, and Ke Xu

Land surface heterogeneity influences patterns of sensible and latent heat flux, which in turn affect processes in the atmospheric boundary layer. However, gridded atmospheric models often fail to incorporate the influence of land surface heterogeneity due to differences between the temporal and spatial scales of models compared to the local, sub-grid processes. Improving models requires the scaling of surface flux measurements; a process made difficult by the fact that surface measurements usually find an imbalance in the energy budget.

The Chequamegon Heterogeneous Ecosystem Energy-balance Study Enabled by a High-density Extensive Array of Detectors (CHEESEHEAD19) was an observational experiment designed to investigate how the atmospheric boundary layer responds to scales of spatial heterogeneity in surface-atmosphere heat and water exchanges. The campaign was conducted from June – October 2019, measuring surface energy fluxes over a heterogeneous forest ecosystem as fluxes transitioned from latent heat-dominated summer through sensible heat-dominated fall. Observations were made by ground, airborne, and satellite platforms within the 10 x 10 km study region, which was chosen to match the scale of a typical model grid cell. The spatial distribution of energy fluxes was observed by an array of 20 eddy covariance towers and a low-flying aircraft. Mesoscale atmospheric properties were measured by a suite of LiDAR and sounding instruments, measuring winds, water vapor, temperature, and boundary layer development. Plant phenology was measured in-situ and mapped remotely using hyperspectral imaging.

The dense set of multi-scale observations of land-atmosphere exchange collected during the CHEESEHEAD field campaign permits combining the spatial and temporal distribution of energy fluxes with mesoscale surface and atmospheric properties. This provides an unprecedented data foundation to evaluate theoretical explanations of energy balance non-closure, as well as to evaluate methods for scaling surface energy fluxes for improved model-data comparison. Here we show how fluxes calculated using a spatial eddy covariance technique across the 20-tower network compare to those of standard temporal eddy covariance fluxes in order to characterize of the spatial representativeness of single tower eddy covariance measurements. Additionally, we show how spatial EC fluxes can be used to better understand the energy balance over heterogeneous ecosystems.

How to cite: Butterworth, B., Desai, A., Paleri, S., Metzger, S., Durden, D., Florian, C., Mauder, M., Wanner, L., Sühring, M., and Xu, K.: Using Spatial Eddy Covariance to Investigate Energy Balance Closure over a Heterogeneous Ecosystem, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22480, https://doi.org/10.5194/egusphere-egu2020-22480, 2020.

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An investigation into the influence of high-resolution land-surface heterogeneity on atmospheric dynamics

Jason Simon, Khaled Ghannam, Gabriel Katul, Paul Dirmeyer, Kirsten Findell, Joseph Santanello, and Nathaniel Chaney

Land-surface heterogeneity is known to play an important role in land surface hydrology and thus the boundary conditions for numerical weather prediction (NWP) and climate modeling. For this reason, there have been considerable efforts over the past two decades to improve its representation in large scale models. However, to date, the inclusion of sub-grid heterogeneity in modeling land-atmosphere interactions in regional and global models has been limited to sub-grid spatial means and thus have almost entirely disregarded its multi-scale impact on the simulated atmospheric dynamics. To begin to address this challenge, here we use large-eddy simulations (LES) coupled to a land-surface model to gain a more complete understanding of its role in the coupled land-atmosphere system. In this work, we illustrate its impact over the Southern Great Plains (SGP) site in the United States and present a path forward for using these modeling experiments to guide the development of a complementary coupling parameterization within climate models.

More specifically, over the SGP site, we use high-resolution LES to investigate the impact of SGS land heterogeneity under different atmospheric and surface conditions to inform the development of land-surface and planetary boundary layer (PBL) parameterizations for coarser, operational-scale weather and climate modeling efforts. The experiment methodology uses a high-resolution land-surface model (WRF-Hydro), spun-up over multiple years using reanalysis data, which is then coupled to the Weather Research and Forecasting (WRF) model for high-resolution LES. Cases are considered using both the fully heterogeneous land model as well as using a homogeneous surface with domain-averaged flux values at all grid points, allowing the dynamical effects of land-surface heterogeneity on the atmosphere to be isolated, and the land/atmospheric conditions under which land-surface heterogeneity plays a role to be studied. Results are evaluated primarily by the differences in the development of the planetary boundary layer and the extent, duration and intensity of developing rainfall events.

How to cite: Simon, J., Ghannam, K., Katul, G., Dirmeyer, P., Findell, K., Santanello, J., and Chaney, N.: An investigation into the influence of high-resolution land-surface heterogeneity on atmospheric dynamics, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20762, https://doi.org/10.5194/egusphere-egu2020-20762, 2020.

EGU2020-3371 | Displays | AS2.16

Imprints of evaporation and vegetation type in diurnal temperature variations

Annu Panwar, Axel Kleidon, and Maik Renner

Diurnal temperature variations are strongly shaped by the absorption of solar radiation, but evaporation, or the latent heat flux, also plays an important role. Generally, evaporation cools, but its relation to diurnal temperature variations is unclear. This study investigates the diurnal response of surface and air temperatures to solar radiation and how evaporation and vegetation modify their response. We used the warming rate of temperature to absorbed solar radiation in the morning under clear-sky conditions and evaluated how the warming rates change for different evaporative fractions. Results for 51 FLUXNET sites show that air temperature carries very weak imprints of evaporation across all vegetation types. However, surface temperature warming rates of short vegetation decrease significantly by ~23 x 10-3 K/W m-2 from dry to wet conditions. Contrarily, warming rates of surface and air temperatures are similar at forest sites and carry literally no imprints of evaporation. We explain these contrasting patterns with a surface energy balance model. The model reveals a strong sensitivity of the warming rates to evaporative fraction and aerodynamic conductance. However, for the large aerodynamic conductance, the sensitivity to the evaporative fraction is strongly reduced. We then show that in addition to the higher aerodynamic conductance of forests, imprints of evaporation in the warming rate of surface temperature are reduced by 50% through an enhanced aerodynamic conductance under dry conditions. This contribution is comparatively weak (28%) for short vegetation. These findings have implications for the interpretation of land-atmosphere interactions and the roles of moisture limitation and vegetation on diurnal maximum temperatures, which is of key importance for ecological functioning. We conclude that surface temperature warming rate is a promising predictor of evaporation for short vegetation. These findings are in agreement with our previous study (Panwar et al., 2019) where the weaker response of air temperature to the evaporative fraction is explained by the larger growth of the boundary layer on drier days. In forests, however, the diurnal variation in temperatures is governed by their aerodynamic properties resulting in no imprint of evaporation in diurnal temperature variations.

Reference: Panwar, A., Kleidon, A. and Renner, M.: Do Surface and Air Temperatures Contain Similar Imprints of Evaporative Conditions?, Geophysical Research Letters, 46(7), 3802–3809, doi:10.1029/2019GL082248, 2019.

How to cite: Panwar, A., Kleidon, A., and Renner, M.: Imprints of evaporation and vegetation type in diurnal temperature variations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3371, https://doi.org/10.5194/egusphere-egu2020-3371, 2020.

EGU2020-4943 | Displays | AS2.16

Influence of Mesoscale Soil Moisture Patterns on Convective Initiation over the Tibetan Plateau

Emma Barton, Christopher Taylor, Cornelia Klein, and Phil Harris

The Tibetan Plateau is the highest and most extensive plateau in the world, profoundly affecting climate and weather in the region. Due to its average elevation of more than 4000m, provides a strong thermal and dynamical forcing in the mid-troposphere during the summer months, fostering the frequent development of intense storms. Mesoscale convective systems (MCSs) are known to be associated with particularly extreme rainfall events and contribute up to ~60% of rainfall over the Tibetan Plateau (TP) and adjacent areas. In particular, MCSs that form on the TP may move off and bring heavy rain and flooding to downstream parts of China, affecting millions of people. A better understanding of the processes that impact MCS genesis over the TP could contribute to improved forecasting of these extreme events. Furthermore, there is strong evidence for accelerated climate warming on the TP, which may affect convection and makes the identification of factors for MCS development even more important.

Previous work in the Sahel has shown that mesoscale soil moisture patterns can influence the initiation of new MCSs, however the relationship has yet to be investigated for the more hydrologically and topographically complex TP. In this study we investigate the impact of mesoscale soil moisture features on convective initiation over the TP during the monsoon season (May – September) using satellite imagery. Convective clouds are identified using the Fengyun-2 cloud top temperature product. Fengyun-2 is a series of geostationary satellites that provide hourly data, allowing us to track systems as they evolve. Land surface temperature anomalies are used as a proxy to map pre-storm mesoscale soil moisture patterns.

Despite the presence of complex topography, we identify a tendency for MCS initiations to occur in the vicinity of mesoscale soil moisture gradients. Our results suggest that improved representation of land-atmosphere coupling on the TP within weather and climate models could impact the entire region.

How to cite: Barton, E., Taylor, C., Klein, C., and Harris, P.: Influence of Mesoscale Soil Moisture Patterns on Convective Initiation over the Tibetan Plateau, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4943, https://doi.org/10.5194/egusphere-egu2020-4943, 2020.

The intensity of latent heat fluxes strongly depends on the available amount of soil water for evapotranspiration, i.e. the water amount stored within the rooted soil depth. But the determination of the root depth itself, and consequently also of the water supply for evapotranspiration, is associated with large uncertainties. The latent heat fluxes are therefore in many cases spuriously simulated, leading to temperature biases especially in soil-moisture limited evapotranspiration regimes like Southern Europe.

To take these uncertainties into account, a new method is introduced, in which the root depths within the Regional Climate Model (RCM) COSMO-CLM are stochastically varied. For this, the root depths in each model grid box are perturbed by uniformly distributed random numbers. The results of this stochastic simulation are compared to the results of an unperturbed reference run. The study reveals that during the winter season, evapotranspiration is virtually not affected by the stochastic root depth perturbation. Changes in the simulated near-surface temperatures are caused by indirectly induced chaotic changes in the atmospheric circulation. But in summer, the latent heat fluxes are considerably increased all over Southern Europe, due to a stochastic increase of the available soil water amount for evapotranspiration. Soil warming is consequently reduced and lower near-surface temperatures are simulated for the whole Mediterranean region. These lower temperatures reduce the strong warm bias in South-Eastern Europe in the reference run, which is also consistently simulated in several other RCMs and General Circulation Models (GCMs). Therefore, stochastic root depth modelling constitutes a simple method that can be implemented in every modelling system, to mitigate systematically simulated warm biases and thus, potentially improving model performances in semi-arid regions.

How to cite: Breil, M.: The reduction of the systematic RCM summertime warm bias in South-Eastern Europe by stochastic root depth variation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5318, https://doi.org/10.5194/egusphere-egu2020-5318, 2020.

Open-path eddy covariance systems, based on broad-band non-dispersive infrared (NDIR) gas analyzers, are widely used for CO2 and H2O flux measurements in remote locations around the world, because of their low power consumption, fast response and reliable operation. Nevertheless, agreement between open- and closed-path CO2 fluxes has limited inter-site comparability, especially in cold or non-growing seasons and low-flux environments, where physiologically unreasonable CO2 uptake is often observed by the open-path systems. A possible explanation is sensor-surface heating from internal-electronics power dissipation and solar radiation, which causes unaccounted gas density changes in the optical path. Fast-response thermometers, co-located with the gas analyzer, have been used to correct these effects. However, the fragility of the thermometers has prevented the wide adoption of this approach.

A challenge for the open-path sensor design is that in-situ air temperature affects not only the gas density but also the broadened half-width and intensity of the spectral absorption lines. We hypothesize that fast air temperature fluctuations in the optical path of the gas analyzer can change the amount of absorbed light and cause errors in the CO2 concentration measurement. Because of the natural covariance of sensible and CO2 fluxes, such errors are well correlated with the vertical wind and can potentially propagate into flux calculations.

We used spectral-line parameters, obtained from the high-resolution transmission molecular spectroscopic database (HITRAN), to evaluate the temperature effects on the integrated absorption spectra of CO2-air-mixtures across the 4.2 to 4.3 μm infrared active region utilized by NDIR analyzers.  Results show that air temperature strongly influences absorption, and if not properly corrected, potentially introduces biases in the CO2 concentration measurements.  Strong lines exhibit Doppler broadening, where the line peak and width decline with increasing temperatures, causing underestimation of CO2 concentration. Weak lines exhibit the opposite behavior. Based on our simulations, optimizing the optical filter pass-band can balance these opposing effects and greatly reduce the temperature dependence. In practice, manufacturing tolerances, shifts in the center wavelength, and the temperature sensitivity of the optical filters prevent complete elimination of the temperature-line broadening. A 13 nanometer shift in the filter pass band can introduce a 0.008 mmol m-3 K-1 underestimation in the CO2 concentration, which is a 0.67 μmol m-2 s-1 systematic error in CO2 flux per 100 watts of sensible heat flux.

How to cite: Bogoev, I. and Holl, D.: Temperature Induced Spectroscopic Line-broadening Effects in Open-path Eddy Covariance CO2 Flux, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2779, https://doi.org/10.5194/egusphere-egu2020-2779, 2020.

EGU2020-10329 | Displays | AS2.16

First application of low-cost eddy covariance for CO2 fluxes over agroforestry

Justus van Ramshorst, Christian Markwitz, Timothy Hill, Robert Clement, Alexander Knohl, and Lukas Siebicke

Agroforestry is a combination of monoculture agriculture and trees. Studies of net ecosystem exchange of CO2 (NEE) of agroforestry systems are rare, in comparison to the extensive studies of NEE of agricultural systems (croplands and grasslands). Agroforestry has been shown to alter the microclimate, productivity, and nutrient and water usage – as compared to standard agricultural practise. The, potentially, higher carbon sequestration of agroforestry, relative to monoculture systems, provides an interesting option for mitigating climate change, highlighting the need for improved study of agroforestry systems. The current study, as part of the SIGNAL (sustainable intensification of agriculture through agroforestry) project, investigates NEE of agroforestry compared to that of monoculture agriculture. The study employs paired comparisons of flux measurements above agroforestry and monoculture agronomy, replicated at five locations across Germany. Fluxes are measured, using innovative low-cost CO2 eddy covariance sensors (slow response Vaisala GMP343 IRGA with custom made housing), which have been successfully used in a study over grassland. Continuous data series from mid-summer until winter 2019 show that both systems acted as a sink with comparable fluxes during summer. The diurnal CO2 cycle and the response to management activities are distinguishable and in autumn preliminary results suggest a small difference in fluxes between the two systems. The low-cost eddy covariance system is able to capture the turbulence and to measure the CO2 flux over the agroforestry and monoculture agricultural system. We aim to further improve the quality of the CO2 fluxes, by adapting post-processing software to better estimate the difference in carbon uptake between the agroforestry and monoculture systems.

How to cite: van Ramshorst, J., Markwitz, C., Hill, T., Clement, R., Knohl, A., and Siebicke, L.: First application of low-cost eddy covariance for CO2 fluxes over agroforestry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10329, https://doi.org/10.5194/egusphere-egu2020-10329, 2020.

EGU2020-17817 | Displays | AS2.16

Compressibility of air effects on eddy accumulation flux measurements

Anas Emad and Lukas Siebicke

Eddy accumulation is a direct flux measurement technique for trace gas exchange between the land surface and the atmosphere. Eddy accumulation complements the now common eddy covariance method in its ability to measure even small fluxes accurately with slow response gas analyzers and being power efficient. However, the physically most direct way of eddy accumulation, also known as true eddy accumulation (TEA), requires the sampling of air at a rate proportional to the vertical wind velocity at a fast rate of typically 10 Hz or more. Lack of suitable methods for high-speed air sampling has been a primary limitation for the practical application of eddy accumulation in the past. The compressibility of air causes a variation of pressure inside the sampling system, which affects the ability to control the sample flow rate accurately, potentially compromising the derived flux measurements. It is therefore essential to quantify the effect of compressibility on fluxes and understand the parameters which allow for mitigating the effect at the design stage.
In this study, we present successful true eddy accumulation measurements over the old-growth forest at the Fluxnet site Hainich (DE-Hai) and quantify the compressibility effects on fluxes. Performing simulations on high-frequency data of CO2 and vertical wind velocity for a range of system configurations, we are able to quantify the impact of compressibility on fluxes and explain why our measurements were successful. We find that different system configurations lead to flux changes over a representative range of 1 to 25 percent of the flux. Key controlling parameters are the size and arrangement of internal buffer volumes and the appropriate control of the inlet flow rate sampling device as a function of internal and external pressure states. This knowledge allows to mitigate compressibility effects and design accurate true eddy accumulation flux measurements for a range of atmospheric constituents.

How to cite: Emad, A. and Siebicke, L.: Compressibility of air effects on eddy accumulation flux measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17817, https://doi.org/10.5194/egusphere-egu2020-17817, 2020.

EGU2020-4352 | Displays | AS2.16

Aircraft observed diurnal variations of the planetary boundary layer under heatwaves

Yuanjie Zhang, Dan Li, and Zhiqiu Gao

This study investigates the diurnal variations of the planetary boundary layer (PBL) during heatwaves (HWs) based on a decade-long data record of hourly profiles from the Aircraft Meteorological Data Reports (AMDAR) at 54 major airports over the Contiguous United States. The results are also corroborated by the surface observations from weather station data. Temperature differences between HW and non-HW periods show strong diurnal and vertical variations in the PBL. Under HWs, the daytime convective PBL becomes higher while the nocturnal residual layer becomes excessively hotter, which creates a positive feedback on HW intensity and duration by providing heat for the next day through entrainment. Changes in wind speed in the PBL during HWs are dependent on the relative location between the observational site and the center of the high-pressure system and do not always show decreases. The specific humidity often increases in humid regions mainly due to the higher evaporation demand which causes more surface evaporation, but decreases in arid regions due to the dry air entrainment and subsidence. In addition, moisture advection could also play an important role in modulating the change of PBL humidity. This study improves our scientific understanding of HW-related changes in the PBL structure and highlights their possible connections with the synoptic-scale atmospheric circulation patterns and land-atmosphere feedbacks. However, future research examining the role of PBL in the onset and demise of HWs and examining whether meteorological models can capture the observed response of the PBL to HWs is strongly needed.

How to cite: Zhang, Y., Li, D., and Gao, Z.: Aircraft observed diurnal variations of the planetary boundary layer under heatwaves, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4352, https://doi.org/10.5194/egusphere-egu2020-4352, 2020.

EGU2020-15661 | Displays | AS2.16

What balloon soundings can tell about surface heat flux partitioning

Jasper Denissen, Hendrik Wouters, René Orth, Diego Miralles, and Ryan Teuling

The land surface can influence near-surface weather. This happens, amongst others, through the impact of soil moisture availability on surface heat fluxes: when soil moisture is unavailable in soil moisture-limited conditions, most of the available energy will be used for heating the air above the land surface (sensible heat flux). But as soil moisture increases, evapotranspiration (latent heat flux) increases, affecting the surface heat flux partitioning. At the point that ample soil moisture is available in energy-limited conditions, the surface heat flux partitioning remains unaffected by soil moisture. The atmospheric boundary layer (ABL) responds to changes in surface heat flux partitioning in particular in terms of its temperature and humidity. Based on these mechanisms, observations of boundary layer dynamics should allow to infer the large-scale land surface state.

The goal of this study is to use atmospheric measurements of temperature and humidity to estimate the surface heat flux partitioning. This is achieved by constraining an ABL model (CLASS4GL) with the vertical temperature and humidity profiles as observed by thousands of soundings of hot air balloons across the globe. In CLASS4GL, the initial soil moisture is adjusted to yield matching modelled versus observed vertical temperature and humidity profiles. By doing so, the resulting surface fluxes are inferred exclusively from atmospheric measurements.

We find that ABL’s tend to higher, warmer and drier in water-limited conditions. This largely results from changes in soil moisture availability, which mainly affects the sensible heat flux and consequently, the surface heat flux partitioning. We determine the critical soil moisture, which distinguishes between soil moisture- and energy- limited conditions, using the ratio between the sensible- and latent heat flux and independent satellite surface soil moisture.

This is the first time that balloon soundings are used globally to assess the critical soil moisture. This research will help to further improve our understanding of land-atmosphere feedbacks and foster a correct representation of land surface characteristics in Land Models and subsequently, Climate Models.

How to cite: Denissen, J., Wouters, H., Orth, R., Miralles, D., and Teuling, R.: What balloon soundings can tell about surface heat flux partitioning, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15661, https://doi.org/10.5194/egusphere-egu2020-15661, 2020.

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Water vapor transport in the turbulent planetary boundary layer (PBL) measured over heterogeneous terrain using multiple LiDAR systems.

Johannes Speidel, Hannes Vogelmann, Matthias Mauder, Matthias Perfahl, Timothy J. Wagner, and Luise Wanner

Water vapor plays a crucial role for several processes on almost every scale of Earth's atmosphere. However, its turbulent transport throughout the PBL is at the same time particularly important and not very well understood. With the increasing resolution of numerical models arises the need for improved representations of the small-scale and nonlinear turbulent processes inside the PBL. Recent papers have shown that these refinements, predominantly on water vapor transport, are urgently needed as they are a limiting factor in the process of lifting numerical weather prediction to the next level.
 The CHEESEHEAD campaign, carried out in summer 2019, especially addresses the complex, turbulent land-atmosphere interactions over heterogeneous terrain and aims to close the energy balance. Therefore, a dense network of sensors has been installed measuring throughout the scales of the PBL with a multiple set of different measurement techniques.
 Within this proposed contribution, first results from the CHEESEHEAD measurements with a water vapor DIAL in combination with several Doppler wind LiDARs will be presented. The synergy of a virtual tower scanning geometry of the Doppler LiDARs right next to the water vapor DIAL delivers highly resolved data throughout the entire PBL. Therefore, special focus of this work lies on turbulent fluctuations inside vertical water vapor columns during the measuring time, spanning the entire PBL. This gives the additional opportunity to observe important entrainment processes at the very top of the PBL. Furthermore, this work deals with the calculation of vertical fluxes of latent heat. Therefore, the essential question whether this data is suitable for these calculations, which are highly sensitive towards temporal resolution, will be addressed. As a further step, aerosol and temperature data that have been measured with the same LiDAR system shall be integrated as well - aiming towards a comprehensive insight on relevant processes throughout the entire PBL. 

How to cite: Speidel, J., Vogelmann, H., Mauder, M., Perfahl, M., Wagner, T. J., and Wanner, L.: Water vapor transport in the turbulent planetary boundary layer (PBL) measured over heterogeneous terrain using multiple LiDAR systems., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17200, https://doi.org/10.5194/egusphere-egu2020-17200, 2020.

EGU2020-20891 | Displays | AS2.16

Impact of the land surface forcing on land-atmosphere feedback in the convection permitting modeling

Josipa Milovac, Klaus Goergen, Jesus Fernandez, Kirsten Warrach-Sagi, Alvaro Lavin-Gullon, Joachim Ingwersen, and Volker Wulfmeyer

The evaluation of the first of its kind multi-model convection permitting - regional climate model (CP-RCM) ensemble, produced within the framework of the international CORDEX - Flagship Pilot Study on Convective phenomena over the Mediterranean (CORDEX-FPS-CEM), showed the improved spatial representation, frequency and extremes of precipitation compared to coarser resolution counterparts (Ban et al., submitted 2019). It is important, though, to keep in mind that the quality of each of such high resolution simulations strongly depend on the quality of the forcing used to drive the model.

In this work we investigate the impact of the land-surface forcing on the model representation of land-atmosphere (LA) feedback. For that we used the 2 Weather Research and Forecasting (WRF) settings from the CORDEX-FPS-CEM ensemble to run 4 simulations for 2 seasons (summer and fall), combining 2 sets of data for the land cover (MODIS and CORINE) and the top soil texture (FAO and HWSD). In such a way we generated two ensembles with 8 simulations for each season. Additionally we run 4 simulations with perturbed starting date for the summer season to obtain an additional 5-member ensemble to investigate the impact of the internal variability on the final results.

The objective of this study is to investigate the model sensitivity to (1) land-surface static forcing, (2) season, and (3) the model configuration. To quantify the strength of LA coupling for each grid, we use coupling metrics appropriate for seasonal time scales. We applied mixing diagram approach to investigate the impact of the land-surface changes on the boundary layer evolution. We also investigate the impact of these changes on the potential for convection triggering, and we calculate correlation matrices to quantify the impact on the strength of the land-atmosphere coupling.

Preliminary results show evident effects of the land surface changes on surface variables, boundary layer evolution, atmospheric stability and humidity in the lower atmosphere. Strength of the sensitivity to a specific change in the land-surface forcing depend on the model configuration: WRF with less sophisticated parameterization schemes is more sensitive to land use changes, while more sophisticated configuration shows higher sensitivity to the soil texture changes in representing boundary layer evolution. Furthermore, the WRF shows stronger coupling and therefore stronger sensitivity to the land surface changes in the summer season.

Acknowledgement: This work is partially funded by the Spanish Government R+D programme through grant INSIGNIA (CGL2016-79210-R) co-funded by the ERDF/FEDER.

References: Ban N., and coauthors: The first multi-model ensemble of regional climate simulations at kilometer-scale resolution, Part I: Evaluation of precipitation, (submitted to Climate Dynamics, 2019)

How to cite: Milovac, J., Goergen, K., Fernandez, J., Warrach-Sagi, K., Lavin-Gullon, A., Ingwersen, J., and Wulfmeyer, V.: Impact of the land surface forcing on land-atmosphere feedback in the convection permitting modeling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20891, https://doi.org/10.5194/egusphere-egu2020-20891, 2020.

EGU2020-21239 | Displays | AS2.16

Spatial Distribution of ABL height and Soil Temperature over Indian Subcontinent

Shikhar Upadhyay, Sarit Das, and Chandra Shekhar Ojha

The spatial variations of ABL depth has wide applications in aeronautical meteorology, urban meteorology, agricultural meteorology and hydrology. In the context of Indian subcontinent, it is more important where air pollution episodes, smog, fog etc. are getting worse over the years. The dispersal of smog and low-level pollutants depends strongly on meteorological conditions. Monitoring and management of air quality is closely associated with the transport and dispersal of atmospheric pollutants, including industrial plumes. Processes of pollutant transport include turbulent mixing in the ABL, particularly the role of convection, photochemistry and dry and wet deposition to the surface. The depth of the ABL determine the extent of thermal and mechanical mixing of pollutants. Further, mean ABL depth can be used to determine the average seasonal air pollution scenarios. Soil surface temperature is one of the major factors which derives the ABL depth. Thus, it is important to know - what is the spatial ABL depth and soil surface temperature variation, in which direction changes in ABL depth and soil surface temperature is more or less consistent, over Indian subcontinent.

To understand the spatial variability of ABL depth and soil surface temperature, a variogram analysis is performed taking 30 stations over Indian sub-continent. Data at 30 stations (Ahmadabad, Bhopal, Gwalior, Aurangabad, Nagpur, Raipur, New Delhi, Gorakhpur, Patna, Lucknow, Patiala, Siliguri, Karaikal, Vishakhapatnam, Machilipatnam, Lhasa, Minfeng, Jodhpur, Agartalla, Bengaluru, Bhubaneshwar, Chennai, Dibrugarh, Hotan, Hyderabad, Jagdalpur, Kolkata, Panjim, Port Blair, Srinagar) are collected for three years 1994, 1997 and 2000. ABL depths are computed using soundings obtained from the Integrated Global Radiosonde Archived (IGRA) by adopting the bulk Richardson method.

Both ABL depth and soil surface temperature are greater in central region, but low near shore and in hilly regions. By using both these parameters, omnidirectional variograms are drawn, which show the spatial distribution of ABL depths and surface soil temperature over India are determined for different years. The particular variogram demonstrates a well-suited spatial relationship for geostatistical analysis as pairs of points are more correlated the closer they are together and the greater the distance between points becomes less correlated. There are certain parameters of variogram (sill and range) that adjust iteratively to get the best fitted model. Then, models are fitted to the experimental variogram using least square approach between the experimental and modelled variogram values. The model with its corresponding parameters based on least square method is selected as the best variogram model. These parameters are finally used in the ordinary kriging analysis. Spherical variograms are fitted and found to have significant correlation for stations within a lags of 19, 18, 18 and 17, 17, 20 degrees latitude/longitude change for ABL depth and soil surface temperature and for the year 1994, 1997 and 2000 respectively. Utilizing variogram parameters, the spatial distributions are plotted using ordinary Kriging. A polynomial curve of order 3 fitted Cubic curve fitting on the scatter plots between soil surface temperature and ABL depth, yield R2 value as 0.44, 0.52 and 0.53 in 1994, 1997, 2000 respectively.

 

How to cite: Upadhyay, S., Das, S., and Ojha, C. S.: Spatial Distribution of ABL height and Soil Temperature over Indian Subcontinent, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21239, https://doi.org/10.5194/egusphere-egu2020-21239, 2020.

EGU2020-13833 | Displays | AS2.16

Modelling carbon sink of urban street trees and soil in Helsinki, Finland

Minttu Havu, Liisa Kulmala, Anu Riikonen, and Leena Järvi

A high proportion of anthropogenic carbon dioxide emissions originate from urban areas, which has led cities to become interested in reducing their own emissions and determining how much carbon could be sequestered by their own vegetation and soil. The challenge with the latter is that our current knowledge on carbon storage is based on data and models from natural and forest ecosystems, whereas the response of vegetation and soil to environmental factors most probably is altered in urban green space where the soil conditions, water availability and temperature are highly variable. Therefore, ecosystem models are required to correctly account for urban vegetation and soil to understand and quantify the biogenic carbon cycle in urban areas.

In this study, urban land surface model SUEWS (the Surface Urban Energy and Water Balance Scheme) and the soil carbon decomposition model Yasso15 are used to simulate urban carbon cycle on two streets in Helsinki, Finland for years 2003-2016. Curbside trees (Alnus glutinosa and Tilia x Vulgaris) were planted while the two test streets were constructed in 2002. Thereafter, carbon and water fluxes and pools with detailed street tree soil compositions were monitored in 2002-2014. SUEWS creates a local spatially variable temperature and specific humidity environment which is used in the model runs. The modelled evaporation is evaluated against sap flow measurements and modelled soil moisture against soil moisture observations. The Yasso15 model is evaluated against loss-on-ignition based soil carbon measurements as it has not been previously evaluated in urban soils. The modelled carbon dioxide flux combined with the changes in the soil carbon stock is used to estimate the carbon cycle of urban street trees and soils.

How to cite: Havu, M., Kulmala, L., Riikonen, A., and Järvi, L.: Modelling carbon sink of urban street trees and soil in Helsinki, Finland, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13833, https://doi.org/10.5194/egusphere-egu2020-13833, 2020.

EGU2020-21140 | Displays | AS2.16

Evaluation of land-atmosphere processes of the Polar WRF in the summertime Arctic tundra

Jeongwon Kim, Junhong Lee, Je-Woo Hong, Jinkyu Hong, Ja-Ho Koo, Joo-Hong Kim, Juyeol Yun, Sungjin Nam, Ji Young Jung, Taejin Choi, and Bang Yong Lee

Arctic tundra is changing rapidly under the influence of global warming and it is important to know its impact on local and regional climate. Polar Weather Research and Forecasting (PWRF) model is a regional climate model optimized for the polar region and it is a useful tool for studying the Arctic tundra in high resolution. In this study, we evaluate the performance of the PWRF model over the Arctic tundra on clear summer days, when the transition is taking place the most, based on the surface energy fluxes and PBL observations in Cambridge Bay, Nunavut, Canada.

The PWRF simulates a drier and warmer environment in PBL than the observations. Our analysis shows that it is due to the surface energy imbalance in the model caused by the uncertainties in prescribed initial input data and physical parameters rather than structural flaws in the model physics. The performance of the PWRF model over the Arctic tundra is improved when those values are modified based on the observation data.

How to cite: Kim, J., Lee, J., Hong, J.-W., Hong, J., Koo, J.-H., Kim, J.-H., Yun, J., Nam, S., Jung, J. Y., Choi, T., and Lee, B. Y.: Evaluation of land-atmosphere processes of the Polar WRF in the summertime Arctic tundra, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21140, https://doi.org/10.5194/egusphere-egu2020-21140, 2020.

Land surface processes have a significant impact on near-surface atmospheric phenomena. They determine, among others, near-surface sensible and latent heat fluxes and the radiation budget, and thus influence atmosphere and land characteristics, such as temperature and humidity, the structure of the planetary boundary layer, and even cloud formation processes. It is therefore important to simulate the land surface processes in atmospheric models as realistically as possible.

Verifications have shown that the amplitude of the diurnal cycle of the surface temperature simulated by the land surface scheme TERRA of the COSMO atmospheric model is systematically underestimated. In contrast, the diurnal cycles of the temperatures in the soil are overestimated, instead. This means that the other components of the surface energy balance are biased as well, for instance, the surface turbulent heat fluxes or the ground heat flux.

Data from the Meteorological Observatory Lindenberg of the German Meteorological Service (DWD) were used to analyse this model behaviour. In the standard model configuration of TERRA, there is no representation of the vegetation in the surface energy balance. This means, there is no energy budget including a temperature for the vegetation layer. Furthermore, the insulating effects by the vegetation at the sub-canopy level are missing as well. In this work, a scheme providing both of these missing model characteristics was implemented in TERRA. As a result, the simulated diurnal amplitude of the surface temperature is increased and the one of the soil temperature is reduced, both leading to better agreements with the measurements. These improvements are found in TERRA in offline mode, using Lindenberg observations, as well as in coupled mode in the atmospheric models of DWD, i.e. the limited-area COSMO model and the global ICON model.

How to cite: Schulz, J.-P. and Vogel, G.: An improved representation of the land surface temperature including the effects of vegetation in the COSMO model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22029, https://doi.org/10.5194/egusphere-egu2020-22029, 2020.

The eddy-covariance method generally underestimates sensible and latent heat fluxes, resulting in an energy-balance gap from 10 % to even 30 % across sites worldwide. In contrast to single-tower eddy-covariance measurements, large-eddy simulations (LES) provide information on a 3D array of grid points and can capture atmospheric processes such as secondary circulations on all relevant scales, which makes them a powerful tool to investigate this problem. In order to compare LES results to field measurements at 20 m height from the CHEESEHEAD (Chequamegon Heterogeneous Ecosystem Energy-balance Study Enabled by a High-density Extensive Array of Detectors) campaign, a LES-setup that provides comparability to the measurements at these low levels is necessary. However, former LES studies have shown that the energy balance is almost closed near the surface, which does not reflect the energy-balance gap in measurements. One possible reason might be the common use of prescribed surface fluxes that cannot adapt to changes in surface temperature and moisture, which would allow for the self-reinforcement of secondary circulations. Therefore, we set up an idealized study, in which we compare the performance of the land-surface and plant-canopy models implemented in PALM to the use of prescribed surface fluxes above homogeneous forest and grassland ecosystems under different atmospheric conditions with respect to realistic energy-balance closure behavior. Furthermore, we evaluate the performance of a dynamic subgrid-scale model, as well as an alternative to the Monin-Obukhov similarity theory (Banerjee et al. 2015, Q. J. R. Met. Soc.).

How to cite: Wanner, L., De Roo, F., and Mauder, M.: Optimizing large-eddy simulations for investigating the energy-balance closure problem at typical flux measurement heights, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19678, https://doi.org/10.5194/egusphere-egu2020-19678, 2020.

While land use and land cover change (LULCC) is often a temporal phenomenon (i.e., a patch transitions from one land cover type to another), many studies use a space-for-time approximation that quantifies the LULCC impact (say on surface temperature or fluxes) by comparing two adjacent patches of different land covers. An important consideration embedded in this space-for-time approximation is the scale, which determines what assumptions we can make when constructing models for studying land-atmosphere interactions over heterogeneous terrain. Most previous studies employ one-dimensional models without considering the appropriate scale associated with these models. In this presentation, the scale issue in studying LULCC-induced surface temperature anomalies will be discussed using a hierarchy of models. Typical one-dimensional models based on the surface energy balance and/or convective boundary layer dynamics will be compared to two-dimensional models where horizontal advection is explicitly considered. The results highlight the importance of scale in determining the sensitivity of land surface temperature to changes in albedo and moisture/vegetation characteristics. 

How to cite: Li, D. and Wang, L.: Land use and land cover change impact on surface temperature: the scale issue, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1634, https://doi.org/10.5194/egusphere-egu2020-1634, 2020.

EGU2020-5158 | Displays | AS2.16

Different aggregations of Corine land cover for WRF simulations of a pre-Alpine valley

Thierry Hedde and Michiel De Bode

The land cover defines what is on the earth’s surface. For atmospheric research, land cover is a leading influencer of surface exchange rates, roughness length and the surface heat flux. Nowadays, with finer resolution, the importance of land cover being correct increases. Especially over heterogeneous terrain, as gradients created by short-distance variability can influence local meteorology. For processing purposes, land covers maps group all land covers in classes based on certain conditions. Every land cover map has different classes and conditions to serve their purpose best.

The land cover map USGS is the default map for weather simulations with WRF. Since Pineda et al., 2004 developed a method to convert the Corine Land Cover (CLC) to a WRF readable format, is CLC available for simulations over Europe. CLC is a land cover map that focuses primarily on the EU and a few collaborating countries.

Our objective is to investigate the influence of land cover on valley winds. Our study focuses on the central part of the pre-Alpine Durance valley. Simulations exist out of a domain with three nested domains and verified with the KASCADE 2013 data. In previous simulations with USGS, land cover is in the domain near the Cadarache site almost homogeneous. Results and representation improved with the introduction of the CLC as land cover map.

This CLC study will act as an update and extension of a previous study of the area. In this study, we use an updated version of CLC, and we look at different methods of aggregation of the CLC data to quantify their effects on simulation results. CLC has 44 categories and 3 levels of detail. We compare direct aggregation to an aggregation, which takes into account the available detail levels.

First comparisons of aggregation methods show a mismatch ranging from 1.4 % in at 300 m resolution to values around 11 % for resolutions of 3 km and coarser.

How to cite: Hedde, T. and De Bode, M.: Different aggregations of Corine land cover for WRF simulations of a pre-Alpine valley, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5158, https://doi.org/10.5194/egusphere-egu2020-5158, 2020.

EGU2020-6521 | Displays | AS2.16

Impact of Soil Moisture on Winter 2-m Temperature Forecast in Northern China

Ji-Qin Zhong, Bing Lu, Wei Wang, Cheng-Cheng Huang, and Yang Yang

 The causes of the underestimated diurnal 2-m temperature range and the overestimated 2-m specific humidity in Northern China’s winter in the Rapid-refresh Multi-scale Analysis and Prediction System - Short Term (RMAPS-ST) system are investigated. Three simulations based on RMAPS-ST are conducted from Nov. 1st, 2016 to Feb. 28th, 2017. Further analyses show that the partitioning of surface upward sensible heat fluxes and downward ground heat fluxes might be the main contributing factor in 2-m temperature forecast biases. In this study, two simulations are conducted to examine the effect of soil moisture initialization and soil hydraulic property on the 2-m temperature and 2-m specific humidity forecast biases. Firstly, the High-Resolution Land Data Assimilation System (HRLDAS) is used to provide an alternative soil moisture initialization, and the result shows that the drier soil moisture leads to noticeable change in energy partition at the land surface, which in turn results in improved prediction of the diurnal 2-m temperature range, although it also enlarges the 2-m specific humidity bias in some parts of the domain. Secondly, a soil texture dataset developed by Beijing Normal University (BNU) and a revised hydraulic parameters are applied to provide a more detailed description of soil properties, which could further improve the 2-m specific humidity biases. In summary, the combination of using optimized soil moisture initialization, updated soil map and revised soil hydraulic parameters can help improve the 2-m temperature and 2-m specific humidity prediction in RMAPS-ST.

How to cite: Zhong, J.-Q., Lu, B., Wang, W., Huang, C.-C., and Yang, Y.: Impact of Soil Moisture on Winter 2-m Temperature Forecast in Northern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6521, https://doi.org/10.5194/egusphere-egu2020-6521, 2020.

EGU2020-21367 | Displays | AS2.16

Land Atmosphere Feedback Observatory (LAFO) and heterogeneous terrain in its footprint

Verena Rajtschan, Florian Späth, Thilo Streck, and Volker Wulfmeyer

Soil, land cover and the lower atmosphere form the land atmosphere system. The feedbacks in this system are nonlinear, because of two-way coupling between single variables such as soil moisture and precipitation. A detailed characterization of fluxes and feedbacks within and between the different compartments is essential to improve our understanding of the land atmosphere system. To investigate these fluxes and feedbacks the Land Atmosphere Feedback Observatory (LAFO) was established at the experimental station “Heidfeldhof” of the University of Hohenheim in 2018. LAFO applies a novel synergy of eddy covariance stations, vegetation measurements, and innovative scanning lidar systems. The measurements are comprehensive, highly resolved and very precise, so that new parameterizations of land-atmosphere exchange processes between soil/vegetation and the lower troposphere for model systems can be developed, implemented, and tested.

LAFO is situated in heterogeneous cropland with nearby urban areas and forests. The heterogeneous terrain forms a complex land atmosphere system. A footprint analysis of eddy covariance data from 2019 enables us to better characterize our site.  Here we present LAFO, its concept and first results on a footprint analysis of the eddy covariance data.

How to cite: Rajtschan, V., Späth, F., Streck, T., and Wulfmeyer, V.: Land Atmosphere Feedback Observatory (LAFO) and heterogeneous terrain in its footprint, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21367, https://doi.org/10.5194/egusphere-egu2020-21367, 2020.

EGU2020-2670 | Displays | AS2.16 | Highlight

Measuring and tracking nighttime inversions within a forest canopy

Bart Schilperoort, Miriam Coenders-Gerrits, and Hubert Savenije

One of the challenges of flux measurements above tall canopies, is that parts of the canopy can be decoupled from the atmosphere above. This decoupling can, for example, occur when the forest understory is colder than the air above, limiting exchange through convection. While concurrent above and below canopy eddy covariance (EC) measurements help with addressing the decoupling issue, these are still disconnected point measurements and do not show what is happening along the entire vertical profile. For this, Distributed Temperature Sensing (DTS) can give additional insights, as it can perform continuous temperature measurements along a vertically deployed fiber optic cable.

Measurements were performed at the ‘Speulderbos’ forest site in the Netherlands, where a 48 m tall measurement tower is located in a stand of 34 m tall Douglas Fir trees.  We measured a vertical temperature profile through the canopy using DTS (from the surface up to 32 m). The measurement frequency was ~0.5 Hz, with a vertical resolution 0.30 cm, and data was collected for two months. The fiber optic cable used had a diameter of 0.8 mm, allowing a sufficiently quick response to temperature changes. With this data we were able to detect the presence, height, and strength of inversions. The inversions appeared to occur mostly at night. The height of the inversion showed a bistable behavior, either staying around 1 m above the ground, or at approximately 16 m, which is just below the dense branches of the canopy.

By locating and tracking inversions within the canopy, decoupling events can be studied and explained in more detail. If vertical DTS profiles are available at a site, these can be used for filtering EC measurements as well. While more research will be needed before a wide application at flux sites is possible, this study can serve as a ‘proof-of-concept’ and demonstrates how vertical DTS profiles can help understand problematic flux sites.

How to cite: Schilperoort, B., Coenders-Gerrits, M., and Savenije, H.: Measuring and tracking nighttime inversions within a forest canopy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2670, https://doi.org/10.5194/egusphere-egu2020-2670, 2020.

EGU2020-7739 | Displays | AS2.16

Assessing decoupling of above and below canopy air masses at a Norway spruce stand in complex terrain

Georg Jocher, Milan Fischer, Ladislav Šigut, Marian Pavelka, Pavel Sedlák, and Gabriel Katul

Concurrent below (0.14 • canopy height) and above canopy sonic anemometer vertical velocity (w) measurements reveal frequent decoupling events between the air masses below and above the canopy at a dense spruce forest stand in mountainous terrain. Decoupling events occurred predominantly during nighttime but not exclusively. Several single-level approaches based on steady state and integral turbulence characteristic tests as well as u* filtering and two-level CO2 flux filtering methods are tested. These tests aimed at evaluating the filtering schemes to address decoupling and its effect on above canopy derived eddy covariance CO2 fluxes. In addition to the already existing two-level filtering approach based on the correlation of σw above and below canopy, two new filtering methods are introduced based on w raw data below and above the canopy. One is a telegraphic approximation agreement, which assumes coupling when w both above and below canopy are pointing in the same direction. Another one evaluates the cross correlation maximum between below and above canopy w data. This study suggests that none of the single-level approaches can detect decoupling when compared to two-level filtering approaches. It further suggests that the newly introduced two-level approaches based on w raw data may have advantages in comparison to the conventional σw approach regarding their flexibility on shorter time scales than one year. We tested the correlation of the newly introduced filtering approaches with the parameters u*, global radiation, buoyancy forcing across the canopy and wind shear across the canopy. In any case, this correlation was not existing or weakly positive, suggesting that concurrent below and above canopy measurements are mandatory for addressing decoupling sufficiently. Sonic anemometer measurements near the forest floor and above the canopy are sufficient to apply the new procedures and can be implemented in a routine manner at any forest site globally.

How to cite: Jocher, G., Fischer, M., Šigut, L., Pavelka, M., Sedlák, P., and Katul, G.: Assessing decoupling of above and below canopy air masses at a Norway spruce stand in complex terrain , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7739, https://doi.org/10.5194/egusphere-egu2020-7739, 2020.

EGU2020-7789 | Displays | AS2.16

Energy management in dry canopy starts with efficient leaf-scale heat exchange

Jonathan D. Müller, Eyal Rotenberg, Fedor Tatarinov, Itay Oz, Efrat Schwartz, and Dan Yakir

Dry forests are expected to heat up considerably more than adjacent shrubland areas due to lower albedo and reduced latent heat flux. Paradoxically, the forest surface at our research site was observed to be cooler than the non-forested neighbouring areas during drought. This reflected the control over canopy temperature through the sensible heat flux, i.e. a 'convector effect'. Our objective was to examine how the efficient non-evaporative energy management, critical to protect the biological functioning of dryland ecosystems, develops at the small, leaf scale. 

We developed a novel system to continuously measure the energy balance and heat dissipation mechanisms on a leaf scale under field conditions. It allows the measurement of emitted leaf and background longwave radiation, and estimating the incoming, absorbed and reflected shortwave radiation using PAR measurements and full spectrum models.  Latent heat exchange and photosynthetic activity were measured with branch chambers. The system was deployed during the long summer drought (>8 months) in drought-exposed and irrigated plots in our semi-arid research Aleppo Pine forest site in southern Israel (mean daytime temperature of >30°C).

Preliminary results showed that in spite of a x10 higher transpiration rate in the irrigated plot compared with the control plots, leaf temperature remains within 1-2°C of air temperature on average in both plots during direct exposure to sunlight at midday. These results suggest an effective leaf to air heat transfer which prevents overheating independent of the latent heat flux. Under the high radiation load, the midday summer value of incoming shortwave radiation was >800 W·m-2 (mostly absorbed by the low albedo leaves), and background longwave radiation was >500 W·m-2. In turn, the energy dissipation in the drought-exposed trees was dominated by sensible heat flux of >500 W·m-2, while the long-wave radiation balance was near neutral (~50 W m-2), and the residual latent heat flux was <50 W·m-2. We demonstrated a system that provided new insights to leaf and canopy energy management under drought, which is a basis for the evolution of the convector effect.

How to cite: Müller, J. D., Rotenberg, E., Tatarinov, F., Oz, I., Schwartz, E., and Yakir, D.: Energy management in dry canopy starts with efficient leaf-scale heat exchange, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7789, https://doi.org/10.5194/egusphere-egu2020-7789, 2020.

EGU2020-17618 | Displays | AS2.16

Eddy covariance measurements of the forest floor CO2 exchange in two contrasting forest stands in boreal Sweden

Jinshu Chi, Mats Nilsson, Natascha Kljun, and Matthias Peichl

Boreal forests cover a large portion of land surface area in the northern hemisphere and greatly affect the global carbon (C) cycle and climate. Since these forests exchange carbon dioxide (CO2) with the atmosphere in different vertical layers, many different CO2 sources and sinks exist within the complex forest stand. The forest floor (soil and understory vegetation) may act as an important component of the C budget in a forest stand, however its contribution may vary from negligible to determining the inter-annual variability of ecosystem C balance. To date, there are a limited number of studies that have directly quantified the CO2 fluxes over a forest floor using the eddy covariance (EC) method primarily due to challenges and potential violation of underlying assumptions when applying this method in the trunk space where turbulence characteristics are complicated, intermittent, and not in accordance with universal theories.

In this study, we installed two identical EC flux systems at two contrasting boreal forests (sparse pine stand vs. a dense mixed pine-spruce stand) in Sweden to measure the forest floor CO2 exchange. We developed site-specific ideal cospectral models for the below-canopy fluxes in the trunk space under the well-mixed condition as defined by the standard deviation of the vertical wind speed. Spectral correction to the half-hourly fluxes was performed based on the newly fitted cospectral models at each site. Chamber measurements of CO2 fluxes during the growing season were conducted to compare with the estimates from the below-canopy EC data.

Our below-canopy cospectral models show that more high-frequency signals (small eddies) occurred in the forest trunk space compared to the ideal above-canopy cospectral model. The high-frequency contribution was greater in the dense pine-spruce forest compared to the open pine stand. The spectral corrected CO2 fluxes measured by the EC method agreed well with the concurrent chamber measurements. The EC results revealed that the forest floor of the two contrasting stands acted as net CO2 sources during the 3-year period (2017-2019). This study highlights that by applying a data correction based on site-specific below-canopy cospectral models, the EC method can be used in the trunk space to accurately measure the net CO2 exchange between the forest floor and the atmosphere and thus to improve our understanding of the role of the forest floor in the ecosystem-scale C budget in the boreal forest region.

How to cite: Chi, J., Nilsson, M., Kljun, N., and Peichl, M.: Eddy covariance measurements of the forest floor CO2 exchange in two contrasting forest stands in boreal Sweden, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17618, https://doi.org/10.5194/egusphere-egu2020-17618, 2020.

Below-surface horizontal pore air velocity profiles in porous media in response to above-surface wind conditions were measured for 16 combinations of wind speed (1.4 – 5.7 ms-1) and main wind gust frequency (0 – 1 Hz) in four granular porous media (particle size: 0.6 – 10 mm) yielding 64 combinations of wind condition and porous medium. Measurements were carried out under controlled (wind tunnel) conditions using a recently developed experimental gas tracer tracking method. Gusty wind conditions were induced by a wind driven propeller capable of variable rotation frequencies.

A recent empirical model for predicting wind-induced horizontal pore velocity in porous media (using one empirical parameter, B together with surface wind speed as input) was validated against the experimental data and found to provide accurate approximations. Further investigations revealed that B could be accurately predicted from porous medium gas permeability. Overall the results indicate, that it is possible to accurately predict below-surface wind-induced pore velocity profiles based on the above-surface wind speed profile and the porous medium gas permeability.

 

How to cite: Poulsen, T. G.: Predicting below-surface pore velocity profiles in porous media from above-surface wind speed and porous medium gas permeability, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1747, https://doi.org/10.5194/egusphere-egu2020-1747, 2020.

EGU2020-5136 | Displays | AS2.16

The effect of soil type and crust cover on the absorption of atmospheric water vapor – laboratory and field trials.

Pedro Berliner, Anxia Jiang, Carmel Neuberger, and Agam Nurit

In arid and semiarid environments non-rainfall water inputs (NRWI) are an important source of water. In Israel's Negev desert direct absorption of atmospheric water vapor is the dominant NRWI and is strongly affected by soil properties, in particular clay content. The presence of a surface crust layer, whose physical and physico-chemical properties are substantially different from those of the underlying undisturbed substrate will likely affect the absorption patterns.  The objective of our study was to quantify the effect of soil type (loess vs. sand) and crust cover (crust vs. crust removed) on direct atmospheric water absorption.

The loess soil samples were obtained in an open field adjacent to the Jacob Bluestein Institutes for Desert Research (BIDR), Ben-Gurion University of the Negev (30˚51’ N, 034˚46’ E, 470 m a.s.l); and the sand samples from the Nizzana Sand Dune area (30˚58’N, 034˚24’E, 226 m a.s.l.).  The loess crusts were physically induced while those present on the sand samples were of biological origin.

A field experiment was carried out in the open field adjacent to the BIDR.  Four undisturbed 0.5 m depth soil samples (sand and loess with crust and with crust removed) were placed in micro-lysimeters and automatically weighed at 30 min. intervals.  This field experiment was carried during the dry season of May to October 2016.

The field study was supplemented with a laboratory experiment in which undisturbed samples (1,3, 7 and 10 cm) obtained from the above mentioned sites were used. Oven-dry samples were exposed during 6 days to constant temperature and relative humidity conditions (25±1 oC and  85±5 %, respectively)  in sealed chambers.  Mass changes were recorded at varying time intervals.   

The adsorption process in the field started in the late afternoon with the arrival of the sea breeze and ended with sun rise. On a daily basis the crusted loess sample adsorbed more water than the crusted sand sample, and the crust removed loess soil absorbed more water than the crust removed sand.  The crusted samples generally absorbed less water than the corresponding non-crusted ones.

The results of the laboratory tests showed that loess samples with crust and with crust removed absorbed similar water amounts for all sample depths throughout the study period. The crusted sand samples however absorbed systematically more water than the crust removed samples for all sample depths.

We conclude that the higher resistance of crusts to gaseous flux, a result of their higher bulk density and smaller pores, does not limit water vapor flux into the deeper soil layers and does not explain the field results.  

How to cite: Berliner, P., Jiang, A., Neuberger, C., and Nurit, A.: The effect of soil type and crust cover on the absorption of atmospheric water vapor – laboratory and field trials. , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5136, https://doi.org/10.5194/egusphere-egu2020-5136, 2020.

The study investigates impact of wind speeds on the turbulent transport of CO2 fluxes for a land-surface atmosphere interface in a low-wind tropical area between May 28th and June 14th, 2010; and May 24th and June 15th, 2015. Eddy covariance technique was used to acquire turbulent mass fluxes of CO2 and wind speed at the study site located inside the main campus of Obafemi Awolowo University, Ile – Ife, Nigeria. The results showed high levels of CO2 fluxes at nighttime attributed to stable boundary layer conditions and low wind speed. Large transport and distribution of CO2 fluxes were observed in the early mornings due to strong wind speeds recorded at the study location. In addition, negative CO2 fluxes were observed during the daytime attributed to prominent convective and photosynthetic activities. The study concludes there was an inverse relationship between turbulent transport of CO2 fluxes and wind speed for daytime period while nighttime CO2 fluxes showed no significant correlation.

Keywords: CO2 fluxes, Wind speed, Turbulent transport, Low-wind tropical area, Stable boundary layer

How to cite: Bello, T., Ajao, A., and Jegede, O.: Impact of wind speeds on turbulent transport of carbon dioxide (CO2) fluxes at a tropical location in Ile - Ife, southwest Nigeria, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1882, https://doi.org/10.5194/egusphere-egu2020-1882, 2020.

EGU2020-15930 | Displays | AS2.16

Carbon dioxide fluxes on agricultural grasslands – Uncertainty associated with gap-filling

Henriikka Vekuri, Juha-Pekka Tuovinen, Mika Korkiakoski, Laura Heimsch, Liisa Kulmala, Juuso Rainne, Timo Mäkelä, Juha Hatakka, Jari Liski, Tuomas Laurila, and Annalea Lohila

Mitigation of climate change requires – besides reductions in greenhouse gas emissions – actions to increase carbon sinks and storages in terrestrial ecosystems. Agricultural lands have a high potential for increased carbon sequestration through climate-smart land management and agricultural practices. However, in order to make climate-smart farming an accredited solution for climate policy, carbon markets and product footprints, reliable verification of carbon sequestration is needed. Direct measurement of the changes in soil carbon stock is slow, laborious and expensive and has significant uncertainties due to large background stocks and high spatial variability. An alternative is to infer the soil carbon stock change from measurements of the gaseous carbon fluxes between ecosystems and the atmosphere using the micrometeorological eddy covariance (EC) method.

Eddy covariance measures net ecosystem exchange (NEE), which is a small difference between two large components: carbon uptake by photosynthesis and losses due to plant and soil respiration. Therefore, small changes in either of them results in a large change in NEE. This sensitivity is also reflected in uncertainty estimates, which are critical for defining confidence intervals for annual carbon budget estimates and for making statistically valid comparisons of different management practices.  In addition, there are inevitable gaps in the data due to instrument failure, power shortages and non-ideal flow conditions. Therefore, in order to calculate daily and annual sums, the collected data must be temporally upscaled or gap-filled, which constitutes a major additional source of uncertainty. This study compares two different gap-filling methods for CO₂ fluxes: (1) an artificial neural network and (2) non-linear regression, which uses temperature and radiation as drivers. Uncertainties associated with both methods are estimated and discussed. The analysis is based on EC flux measurements conducted at two agricultural grassland sites in Finland.

How to cite: Vekuri, H., Tuovinen, J.-P., Korkiakoski, M., Heimsch, L., Kulmala, L., Rainne, J., Mäkelä, T., Hatakka, J., Liski, J., Laurila, T., and Lohila, A.: Carbon dioxide fluxes on agricultural grasslands – Uncertainty associated with gap-filling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15930, https://doi.org/10.5194/egusphere-egu2020-15930, 2020.

EGU2020-13970 | Displays | AS2.16

Cycling of carbon and water in mountain ecosystems under changing climate and land use (CYCLAMEN)

Florian Kitz, Georg Wohlfahrt, Mathias W Rotach, Erich Tasser, Simon Tscholl, Paulina Bartkowiak, Mariapina Castelli, Claudia Notarnicola, Hetal Dabhi, and Thorsten Simon

Land ecosystems presently sequester around 25% of the carbon dioxide (CO2) that is emitted into the atmosphere by human activity and thus, along with the oceans (absorbing a similar fraction), slow down the increase of atmospheric CO2. Whether land ecosystems will be able to continue to sequester atmospheric CO2 at similar rates in the future or whether carbon cycle-climate feedbacks will cause the land sink to saturate or even turn into a source, is a topic of controversial discussion. While taking up CO2 through the stomata, plants inevitably lose water through transpiration. Terrestrial evapotranspiration (ET) can have a feedback to (local) precipitation and therefore modulate near-surface climate. The terrestrial carbon and water cycles are highly connected and controlled by complex interactions between biological and abiotic drivers. Mountain ecosystems in the European Alps are a hot spot of climate and land-use changes. Over the last century, temperatures have increased in the region with a rate double that of the global average and are expected to rise rapidly. In addition, precipitation changes are highly complex with an increasing and a decreasing trend in the northern and southern Alps, respectively and different seasonal patterns. Socio-economic development in the Alps during the past centuries have caused large-scale changes in land-use and its intensity, which has contributed to the uncertainty about future land-atmosphere interactions. The objective of the CYCLAMEN project is to quantify and project the resilience and vulnerability of carbon and water cycling in North and South Tyrol. We aim at providing information for predicting likely future changes in climate and land-use over the region.

In the study we used a comprehensive and multidisciplinary approach to model biosphere-atmosphere interactions in the Alps. Data from eddy covariance stations spread across the region were chosen to test and calibrate the biosphere model SiB4. The meteorological data from the same stations was used to train a stochastic Weather Generator and simulate weather conditions under climate scenarios RCP8.5 and RCP2.6 until 2100. To account for future land- use/ land- cover (LULC) changes the SPA-LUCC model was used. Both the simulated weather conditions and the expected LULC were fed back to the SiB4 model to calculate ecosystem parameters, including carbon dioxide net ecosystem exchange and evapotranspiration. In parallel, an enhanced thermal remote sensing dataset was produced, specifically adapted for mountainous areas. This dataset will be the main driver for modelling ET with an energy balance model whose output will be cross compared with the one of the biosphere model SiB4.

How to cite: Kitz, F., Wohlfahrt, G., Rotach, M. W., Tasser, E., Tscholl, S., Bartkowiak, P., Castelli, M., Notarnicola, C., Dabhi, H., and Simon, T.: Cycling of carbon and water in mountain ecosystems under changing climate and land use (CYCLAMEN), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13970, https://doi.org/10.5194/egusphere-egu2020-13970, 2020.

EGU2020-6469 | Displays | AS2.16

How to differentiate nighttime transpiration and water recharge in nocturnal sap flow?

Zuosinan Chen, Zhiqiang Zhang, and Lixin Chen

Nocturnal sap flow (Qn) affect not only forest carbon and water budgets but also their responses to climate change as it consists of two ecohydrological and ecophysiological significant components: nighttime transpiration and water recharge. A vapor pressure deficit (VPD) based sap flow partitioning method has been developed to estimate nighttime transpiration, which is normally quantified through the discretely measured nighttime stomatal conductance, from the widely and continuously measured sap flow. However, given the increasing knowledge of Qn mechanisms, whether Qn could be partitioning simply by VPD and whether this method is valid in semi-arid regions remain unclear. We measured sap flow of Pinus tabuliformis and Acer truncatum in a middle-aged and a young monoculture forest stand, respectively, in a semi-arid mountainous area of northern China. We found the influence of VPD on Qn conditioned by soil moisture. Meanwhile, a considerable impact of wind speed on Qn was observed. In the stands with relatively dry soils, both increased and decreased soil moisture promoted Qn, which might be due to enhanced nighttime water recharge for two distinct purposes, i.e., capacitance refilling and avoiding hydraulic failures. For these three environmental factors (i.e., VPD, wind speed, and soil moisture) that have been considered most in previous studies, their total effect explained less than 55% of the Qn variations. This study highlights that physiological influences of VPD on nighttime stomatal water loss were uncertain. Furthermore, it suggests that there could exist considerable nighttime water loss induced by wind, possible region-specific patterns of nighttime water recharge, and limited concurrent environmental controls on Qn. Our findings are helpful to improve the VPD-based sap flow partitioning method to differentiate nighttime transpiration and water recharge.

How to cite: Chen, Z., Zhang, Z., and Chen, L.: How to differentiate nighttime transpiration and water recharge in nocturnal sap flow?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6469, https://doi.org/10.5194/egusphere-egu2020-6469, 2020.

EGU2020-9216 | Displays | AS2.16

Penman and Priestley-Taylor approaches in Atmospheric Boundary-Layer Dynamics

Jun Yin and Amilcare Porporato

By linearizing the saturation water vapor curve, Penman (1948) not only found the famous explicit approximation of wet-surface evaporation but also obtained a less well-known expression of surface temperature. Here the latter has been taken into the slab model of Atmospheric Boundary Layer (ABL) to derive multiple analytical approximations of ABL dynamics, which share the features of the Penman equation with evaporation driven by energy and drying power of the air. Noticing that these two parts of evaporation are proportional to each other within the Priestley-Taylor approximation at sub-daily timescale, a unified framework is obtained that links the Penman approach and Priestley-Taylor method to the diurnal behaviors of ABL. The resulting model is useful for diagnosing the land-atmosphere interactions.

How to cite: Yin, J. and Porporato, A.: Penman and Priestley-Taylor approaches in Atmospheric Boundary-Layer Dynamics, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9216, https://doi.org/10.5194/egusphere-egu2020-9216, 2020.

The coastal Chilean Atacama Desert comprise some of the driest areas of the world with anual mean precipitation partly less than 1 mm/year, like in the Tarapacá region. It is in these environments, where fog plays a relevant role for local ecosystems, like the so called Tillandsia Lomas. These fog ecosystems contain Tillandsia landbeckii as an endemic species, which covers a vertical range of about 800 to 1,250 m, related to fog availability. The study area “Oyarbide” (20°29’ S, 70°03’ W) is situated inland desert, over a range of 300 m elevation where the advective and orographic fog penetrate far enough to reach the east border of the site at around 1,200 m.

On local level, the understanding of the fog climate characteristics and variability is still poor as well as knowledge about the driving parameters, the temporal dynamics and spatial gradients. For this reason, various parameters of fog climate are analysed and characterised on the basis of a local station network in order to determine the local fog climatology.

From 2016, several high quality climatological stations (Thies Clima) were installed in “Oyarbide”, located in a transect from ca. 1,160 m to ca. 1,350 m in a distance between 10.3 km to 10.7 km from the coast. The local network of climate stations is generating a high temporal and spatial acquisition of climatological data of standard fog water (2 m), air temperature & humidity (2 m), surface temperature (5 cm), wind speed & direction (10 m & 2 m), air pressure, global radiation, leaf wetness and dew every 10 minutes until nowadays. Additionally, ten mini fog collectors (Mini FCs) were installed at the beginning 2019, covering a surface of ca. 3 km2, generating a monthly data of ground fog water collected (50 cm).

First spatio-temporal analyses of different parameters of the local fog climate will be presented. The results of the study show a seasonal, monthly and daily variability, with altitudinal and vertical differences and oscillation. The results will serve as input for the understanding of the fog variability into hyperarid zones.

How to cite: Pastene, J. C., Siegmund, A., del Río, C., and Osses, P.: Fog climatology analyses in coastal fog ecosystem at the Atacama Desert/Chile – spatio-temporal analysis of fog water characteristics and variability, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2608, https://doi.org/10.5194/egusphere-egu2020-2608, 2020.

EGU2020-13625 | Displays | AS2.16

Drivers of fog and low stratus - a satellite-based evaluation with machine learning

Eva Pauli, Hendrik Andersen, Jörg Bendix, Jan Cermak, and Sebastian Egli

In this study the distribution of fog and low stratus (FLS) relative to land cover and meteorological conditions in continental Europe is investigated using a state-of-the-art machine learning technique  and geostationary satellite data. While analyses of the spatial and temporal patterns of FLS exist, the relationships to land cover and meteorological conditions have not been studied explicitly, quantitatively and on a continental scale.
The machine learning model is built using daily means of a FLS dataset from Egli et al. (2017) as the predictand, and different land surface and meteorological parameters as predictors over continental Europe from 2006-2015. The application of a machine learning approach provides the ability to explicitly, synchronously and quantitatively link suspected determinants of FLS to its occurrence.
The model shows good performance with R² values ranging between 0.5 and 0.9, depending on model grid size, season and further settings such as the exclusion of low pressure values and subtraction of seasonality. It is thus able to adequately represent the dynamics that drive FLS development. Based on a systematic analysis of this model, the most important features for FLS prediction are mean surface pressure, wind speed, and FLS on the previous day. High mean surface pressure, high FLS cover on the previous day, low evapotranspiration, wind speed and land surface temperature lead to higher predicted FLS values.
Generally the results show that it is possible to predict FLS occurrence over continental Europe using meteorological as well as land surface parameters with good performance indicating the benefits of using machine learning in the analysis of non-linear, multivariate systems such as the land-atmosphere system. Further studies will integrate the machine learning model into a land surface based model grid and implement fog and low cloud properties as predictands.

How to cite: Pauli, E., Andersen, H., Bendix, J., Cermak, J., and Egli, S.: Drivers of fog and low stratus - a satellite-based evaluation with machine learning, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13625, https://doi.org/10.5194/egusphere-egu2020-13625, 2020.

EGU2020-14054 | Displays | AS2.16

Surface ozone and land-atmosphere coupling

Tamara Emmerichs, Huug Ouwersloot, Astrid Kerkweg, Silvano Fares, Ivan Mammarella, and Domenico Taraborrelli

Surface ozone is a harmful air pollutant, heavily influenced by chemical production and loss processes. Dry deposition to vegetation is a relevant loss process responsible for 20 % of the total tropospheric ozone loss. Its parametrization in atmospheric chemistry models represents a major source of uncertainty for the global tropospheric ozone budget and might account for the mismatch with observations. The model used in this study, the Modular Earth Submodel System (MESSy2) linked to ECHAM5 as atmospheric circulation model (EMAC) is no exception. Like many global models, EMAC employs a “resistances in series” scheme with the major surface deposition via plant stomata which is hardly sensitive to meteorology depending only on solar radiation. Unlike many global models, however, EMAC uses a simplified high resistance for non-stomatal deposition which makes this pathway negligible.                             

Hence, a revision of the dry deposition scheme of EMAC is desirable. The scheme has been extended with empirical adjustment factors to predict stomatal responses to temperature and vapour pressure deficit. Furthermore, an explicit formulation of humidity depending non-stomatal deposition at the leaf surface (cuticle) has been implemented based on established schemes. Next, the soil moisture availability function for plants has been critically reviewed and modified in order to avoid a stomatal closure where the model shows a strong soil dry bias, e.g. Amazon basin in dry season.

The last part of the presentation will show comparisons of dry deposition velocities and fluxes comparing simulations with data obtained from four experimental sites where ozone deposition is measured with micrometeorological techniques. The impacts of the changes on daily and seasonal patterns of ozone dry deposition will be discussed with a highlight on surface ozone, global distribution and budget.

How to cite: Emmerichs, T., Ouwersloot, H., Kerkweg, A., Fares, S., Mammarella, I., and Taraborrelli, D.: Surface ozone and land-atmosphere coupling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14054, https://doi.org/10.5194/egusphere-egu2020-14054, 2020.

EGU2020-12258 | Displays | AS2.16

Comparison of Seasonal Response of Isoprene Emission from Understory Type Bamboo and Canopy Type Bamboo Species

Ting-wei Chang, Motonori Okumura, Ken-hui Chang, Tomonori Kume, Lin-jie Jiao, Si-yu Chen, Ding-kang Xu, Zhi-ning Liu, and Yoshiko Kosugi

Bamboos are naturally distributed in Asia, Africa and America, and intentionally introduced in Europe. It has been reported with expansion of bamboos due to abandon of management in plantations and the niche shift under climate change. Furthermore, certain canopy type bamboo species are reported with high emission of isoprene, which can impact air quality and climate change. However, research about the isoprene emission from understory type species of bamboo, such as Sasa spp and Sasaella spp, are currently absent. This may cause uncertainties when estimating the isoprene emission from forest ecosystems. Thus, this study conducted measurement on isoprene emission flux (I) from leaves of 18 species of bamboo within five genera including understory type (Sasa and Sasaella) and canopy type (Pleioblastus, Semiarundinaria and Phyllostachys) species in a specimen garden in Kyoto, Japan, to compare the isoprene emission trait of the two types. The measurements were conducted monthly in 2nd-5th August, 12th-16th September and 15th-17th October 2019. Isoprene emitted from leaf is collected through an adsorbent tube while measuring factors such as photosynthesis rate and leaf temperature (TL) under a controlled intensity of photosynthetic active radiation (PAR) at 1000 μmol m-2 s-1 with a modified photosynthesis-measuring system equipped with a LED light-source leaf chamber. The isoprene in the adsorbents were then desorbed and quantified respectively with a preconcentrate system and a Gas chromatography - Mass spectrometer system; measured leaves were taken to laboratory for area and dry weight measurement. As the result, most of the species showed the largest I in August (18.8 nmol m-2 s-1), and then gradually decrease or ceased in the following two months (8.1 and 1.3 nmol m-2 s-1 in September and October, respectively), which was consistent with the tendency of monthly temperature; that is, positive correlations of I and TL were found in most of the species. Meanwhile, photosynthesis rate did not show significant variance to month in any species, which can be attributed to the weak or none correlation between photosynthesis rate and TL. On the other hand, the species within the same genus showed similar I and dependence to TL. The understory type genera showed significantly lower I than those from canopy type genera. The dependence of I to TL was also weaker in understory type genera than in canopy type genera. The low isoprene emission in understory type genera may attribute to the potentially lower heat stress for the understory vegetations, where the isoprene is produced in plants for enhancing heat tolerance. The significant difference in I and its seasonal variation between understory type species and canopy type species suggest that these two types of bamboo must be seemed as different groups when in the regional modelling of isoprene fluxes.

How to cite: Chang, T., Okumura, M., Chang, K., Kume, T., Jiao, L., Chen, S., Xu, D., Liu, Z., and Kosugi, Y.: Comparison of Seasonal Response of Isoprene Emission from Understory Type Bamboo and Canopy Type Bamboo Species, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12258, https://doi.org/10.5194/egusphere-egu2020-12258, 2020.

AS3.1 – Aerosol Chemistry and Physics (General Session)

EGU2020-106 | Displays | AS3.1

Surface Tension of Surfactant-Containing, Finite Volume Droplets

Bryan Bzdek, Rachael Miles, Jussi Malila, Hallie Boyer, Jim Walker, Jonathan Reid, Cari Dutcher, and Nonne Prisle

Surface tension influences the fraction of atmospheric particles that become cloud droplets. Recent field studies have indicated that surfactants, which lower the surface tension of macroscopic solutions, are an important component of aerosol mass. However, the surface tension of activating aerosol particles is still unresolved, with most climate models assuming activating particles have a surface tension equal to that of water. For surfactants to be relevant to particle activation into cloud droplets, multiple parameters must be considered. First, the concentration of surfactant in the initial particle must be sufficiently large that surface tension depression is maintained during activation, despite the dilution that occurs as water condenses onto the particle. Second, the high surface to volume ratio of micron and submicron particles necessitates partitioning a larger fraction of the surfactant molecules to the particle surface than in a typical solution, resulting in a depletion of the bulk concentration and an increase in the surface tension relative to a bulk sample. Third, the timescale for establishing equilibrium at the droplet surface must be known. The interplay of these parameters highlights the necessity of direct measurements of picolitre droplet surface tension.

This presentation will describe two cutting-edge approaches we have developed to directly measure the surface tension of microscopic droplets. In the first approach, ejection of ~20 µm radius surfactant-containing droplets from a dispenser excites oscillations in droplet shape that can be used to retrieve the droplet surface tension on microsecond timescales. These measurements allow investigation of surfactant partitioning timescales in aerosol and, crucially, test the assumption that droplet surfaces are generally in their equilibrium state. In the second approach, the coalescence of ~8 µm radius droplets is investigated. Coalescence excites droplet shape oscillations which again permit quantification of droplet surface tension. We demonstrate that surfactants can significantly reduce the surface tension of finite sized droplets below the value for water, consistent with recent field measurements. This surface tension reduction is droplet size dependent and does not correspond exactly to the macroscopic solution value. A new monolayer partitioning model confirms the observed size dependent surface tension arises from the high surface-to-volume ratio in finite-sized droplets and enables predictions of aerosol hygroscopic growth. This model, constrained by the laboratory measurements, is consistent with a reduction in critical supersaturation for activation and a 30% increase in cloud droplet number concentration, in line with a radiative cooling effect larger than current estimates assuming a water surface tension by 1 W·m-2. The results imply that one single value for surface tension cannot be used to predict the activated aerosol fraction.

How to cite: Bzdek, B., Miles, R., Malila, J., Boyer, H., Walker, J., Reid, J., Dutcher, C., and Prisle, N.: Surface Tension of Surfactant-Containing, Finite Volume Droplets, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-106, https://doi.org/10.5194/egusphere-egu2020-106, 2020.

The depolarisation ratio of heavily coated soot particles was previously found to be sensitive to the chemical composition of the coating material, which is reflected by the refractive index. Employing the Discrete Dipole Approximation code ADDA optical calculations were performed with a set of heavily coating soot aggregates with two different coating materials at 355 nm, 532 nm, and 1064 nm. As coating materials sulphate and a toluene-based material were assumed. The soot aggregates were modelled based on results reported from in-situ field measurements and using a coating model, which allows for a tunable transition between film coating and spherical shell coating. The aggregates’ size was varied by increasing the number of soot monomers inside each aggregate from 26 to 1508 in linearly equidistant steps.

Size-averaged lidar-measureable quantities for the coated aggregates, such as the linear depolarisation ratio, the extinction-to-backscatter ratio (lidar ratio), and the Ångström exponents of the extinction coefficient, the backscatter coefficient, and the extinction-to-backscatter ratio were calculated, and the error of the simulations was estimated. With the exception of the linear depolarisation ratio at 1064 nm these observables do not overlap within the estimated error bounds. As the coating materials result in clearly distinguishable lidar observables, information on the chemical composition of coated soot aerosol can potentially be inferred from lidar measurements.

 

 

How to cite: Kanngiesser, F. and Kahnert, M.: Coating material-dependent differences in modelled lidar-measurable quantities for heavily coated soot particles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-299, https://doi.org/10.5194/egusphere-egu2020-299, 2020.

EGU2020-2369 | Displays | AS3.1

Photo-Induced Heterogeneous Chemistry of Reactive Species on Aerosol Surfaces: Using Photo-Fragmentation Laser Induced Fluorescence for the Measurement of Nitrous Acid Production from Titanium Dioxide Aerosols

Joanna Dyson, Graham Boustead, Lauren Fleming, Mark Blitz, Daniel Stone, Stephen Arnold, Lisa Whalley, and Dwayne Heard

The hydroxyl radical (OH) is the main oxidant in the troposphere and is vitally important for its role in the removal of greenhouse gases such as methane from the atmosphere. Moreover, the OH radical also has a role in the formation of secondary pollutants such as tropospheric ozone and secondary organic aerosols (SOAs), formed via the oxidation of volatile organic compounds (VOCs). Understanding the sources and sinks of OH within the atmosphere is therefore crucial in order to fully understand the concentration and distribution of trace atmospheric species associated with climate change and poor air quality.

In polluted environments the dominant source of OH to initiate oxidation is the photolysis of nitrous acid (HONO). Current atmospheric chemistry models underestimate the concentration of HONO indicating a potential missing tropospheric source of HONO. There is a large uncertainty in the production of HONO from the contribution and role of aerosols and heterogeneous chemistry both under light and dark conditions.

In order to investigate the missing source of HONO from illuminated aerosols and determine its atmospheric relevance, a photo-fragmentation laser induced fluorescence (PF-LIF) instrument coupled to an aerosol flow tube system has been constructed. The PF-LIF instrument provides a highly sensitive measurement of HONO by fragmenting it into OH which is then detected in a low pressure cell by LIF. The aim of this system is to measure the rate of production of HONO from illuminated aerosol surfaces.

We will present an overview of the PF-LIF instrument and results from experiments investigating the reactive uptake of NO2 by TiO2 aerosols to produce HONO. The change in the reactive uptake coefficient as a function of NO2 concentration and the dependence of HONO production on relative humidity and light intensity will also be discussed.   

How to cite: Dyson, J., Boustead, G., Fleming, L., Blitz, M., Stone, D., Arnold, S., Whalley, L., and Heard, D.: Photo-Induced Heterogeneous Chemistry of Reactive Species on Aerosol Surfaces: Using Photo-Fragmentation Laser Induced Fluorescence for the Measurement of Nitrous Acid Production from Titanium Dioxide Aerosols, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2369, https://doi.org/10.5194/egusphere-egu2020-2369, 2020.

EGU2020-10982 | Displays | AS3.1

Thickness-Dependent Oxidation Kinetics of Coated Films of a Self-Assembled Unsaturated Fatty Acid Aerosol Proxy with Evidence for Inert “Crust” Formation

Adam Milsom, Adam M. Squires, Andrew D. Ward, Nicholas J. Terrill, and Christian Pfrang

This study focuses on the effect of surface film thickness on the ozone reaction kinetics of films of a self-assembled unsaturated fatty acid aerosol proxy coated inside quartz capillaries. It also reveals evidence for reaction stagnation and stopping for the thickest films, leaving a significant amount of unreacted material and suggesting that an inert product is formed during the course of the reaction. These findings have implications for the atmospheric lifetime of such a system.

The oleic acid-ozone reaction is used as the model system for heterogeneous oxidation reactions in organic aerosols. Major sources of oleic acid in the atmosphere include marine and cooking emissions. Oxidation of organic aerosols is known to affect Cloud Condensation Nuclei (CCN) generation and therefore cloud formation. It follows that factors affecting aerosol reactivity have an effect on cloud formation potential and therefore also on the climate.

In our experiments, oleic acid is mixed with its sodium salt (sodium oleate) to form a highly viscous self-assembled lamellar phase system observable using a synchrotron-based technique: Small Angle X-ray Scattering (SAXS). Here, we take advantage of intense synchrotron radiation to probe our coated capillary films. We use the observed decay of the self-assembled scattering peak as a function of time exposed to ozone. We have obtained ~50 kinetic decay parameters spanning a range of film thicknesses, showing a drastic increase in reaction kinetics with decreasing film thickness.

There is a linear relationship between increasing film thickness and amount of self-assembled material (reactant) remaining at the end of the reaction. This implies that a reaction product hinders further reactivity and that this product may take a while to form, explaining the occurrence only in thicker films.

Modelling studies will help us understand the mechanism behind these observations and to relate to a previously-postulated idea of an inert “crust” of products forming on the surface of this viscous aerosol proxy (Pfrang et al., Atmos. Chem. Phys., 2011, 11, 7343-7354).

In summary, we demonstrate thickness-dependent reaction kinetic parameters which vary significantly with film thickness, implying that the atmospheric lifetime for a film is sensitive to the film thickness. We present evidence for reaction stagnation by an as of yet unknown inert product. Kinetic modelling is ongoing in order to explain these findings.

How to cite: Milsom, A., Squires, A. M., Ward, A. D., Terrill, N. J., and Pfrang, C.: Thickness-Dependent Oxidation Kinetics of Coated Films of a Self-Assembled Unsaturated Fatty Acid Aerosol Proxy with Evidence for Inert “Crust” Formation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10982, https://doi.org/10.5194/egusphere-egu2020-10982, 2020.

The interactions among low and semi-volatile organic compounds, water and other inorganic components within fine-mode aerosols are complex. We show that understanding several features of this complexity can be important in the context of phase separation, a particle surface composition enriched by organics and for related cloud droplet activation modeling.  
Context: oxidized organic compounds contribute to the particle hygroscopicity, yet typically to a lesser extent than dissolved inorganic ions. The overall hygroscopicity of aerosols in turn greatly affects their water uptake in an air parcel experiencing increasing relative humidity. The mechanism acts directly in terms of adding water mass, as well as indirectly via a hygroscopicity-induced feedback leading to enhanced gas–to–particle partitioning of semi-volatile organic components alongside a re-equilibration of the aerosol with inorganic acids, ammonia and further water uptake. Furthermore, non-ideal mixing may induce liquid–liquid phase separation, often leading to an organic-rich phase of relatively low surface tension surrounding an inorganic-rich particle core. This phase separation effect and related surface enhancements of organic component concentrations affect not only the morphology but also the potential for near-surface chemical reactions, as well as the thermodynamics controlling an aerosol particle’s activation into a cloud droplet at realistic water vapour supersaturations.  New experimental techniques and field observations over the past few years have encouraged model development for an improved representation of these processes on a detailed level (see, e.g., discussion in Davies et al., 2019). This has led to a better understanding of the potential role of organic aerosol compounds spanning a range of polarities and an associated evolution of surface tension prior to the cloud condensation nucleus (CCN) activation point. While detailed process models still lack finer details to fully capture these composition and phase effects reliably and predictively, important challenges exist in translating these mechanisms into computationally efficient and feasible reduced-complexity models of use for air quality and chemistry-climate modelling.
In this presentation, we will outline the current state of a relatively complete process-level aerosol thermodynamics model based on AIOMFAC and introduce key features of a recently developed reduced-complexity organic aerosol model that accounts for water content and hygroscopicity-induced feedbacks on composition (Gorkowski et al., 2019). A key advantage of the reduced-complexity model is its ability to use only input typically known from field measurements or data available in large-scale air quality models. Our approach is compatible with a volatility basis set approach and allows for extending it by adding a realistic humidity dependence. In addition, we account for phase separation and related effects on surface tension in a simplified, computationally efficient manner. This approach and its results for aerosol hygroscopicity and cloud droplet activation will be discussed.

References:

Davies, J. F., Zuend, A., and Wilson, K. R.: Technical note: The role of evolving surface tension in the formation of cloud droplets, Atmos. Chem. Phys., 19, 2933–2946, doi:10.5194/acp-19-2933-2019, 2019.

Gorkowski, K., Preston, T. C., and Zuend, A.: Relative-humidity-dependent organic aerosol thermodynamics via an efficient reduced-complexity model, Atmos. Chem. Phys., 19, 13383–13407, 10.5194/acp-19-13383-2019, 2019.

How to cite: Zuend, A. and Gorkowski, K.: Modelling hygroscopicity-induced gas–aerosol partitioning, organic surface enrichment and cloud droplet formation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12463, https://doi.org/10.5194/egusphere-egu2020-12463, 2020.

EGU2020-10491 | Displays | AS3.1

Quantifying the effect of SVOC condensation on cloud droplet number in different airmass types

Liine Heikkinen, Samuel Lowe, Cheng Wu, Diego Aliaga, Wei Huang, Yvette Gramlich, Samara Carbone, Qiaozhi Zha, Fernando Velarde, Valeria Mardoñez, Isabel Moreno, Alkuin Koenig, Marcos Andrade, Paulo Artaxo, Federico Bianchi, Radovan Krejci, Mikael Ehn, Daniel Partridge, Ilona Riipinen, and Claudia Mohr

Clouds are made of droplets that arise from the activation of suitable aerosol particles (termed cloud condensation nuclei, CCN). In the activation process, water vapor saturation ratio exceeds a critial ratio enabling CCN runaway-growth to cloud droplet sizes. The number concentration of cloud droplets (CDNC) is highly dependent on the aerosol population properties (size distribution and composition), relative humidity, and the vertical wind component. While the activation of CCN consisting of non-volatile particulate matter is fairly well understood, the same process involving semi-volatile organic vapors (SVOCs) has received less attention despite their significant presence in ambient air. A recent cloud parcel modeling study shows substanial CDNC enhancement due to SVOC condensation (Topping et al., 2013). Surprisingly, the topic has not been widely investigated nor the results replicated with other cloud parcel models (CPM). Thus, in the current study we seek to quantify the CDNC enhancement by SVOC condensation using a recently developed CPM framework (Lowe et al., 2020, in prep.). Moreover, the CPM initialization is performed, for the first time, with state-of-the art measurement data including measured SVOC data for multiple airmass types.

Here, the CPM, which uses spectral microphysics for the simulation of CCN activation and hydrometeor growth, also includes a SVOC condensation equation analogous to those of water vapor. Equilibrium initialization of the SVOC volatility basis set (VBS) partitioning coefficients is performed iteratively, and constrained by the organic to inorganic ratio in the particle phase determined by ambient measurements performed at the Chacaltaya Global Atmospheric Watch (GAW) Station located at 5240 m a.s.l. in the Bolivian Andes, in spring 2018. The uniquely comprehensive data set recorded, which tracks all of the relevant aerosol population characteristics in near real-time, reveals a high degree of variability in aerosol composition, size distribution and loading depending on the air mass origin. Lagrangian backward simulations during the measurement period at Chacaltaya GAW reveal at least 18 significantly different airmass origins (Aliaga et al., 2020, in prep.). Such variability served multiple model initialization scenarios for individual case studies. We will show a suite of CDNC enhancements by SVOC condensation under different initialization scenarios actualized in data recorded at Chacaltaya GAW Station, including airmasses originating from the Amazon (biomass burning and biogenic VOCs), Andean plateau (volcanic activity), and La Paz/El Alto metropolitan areas (anthropogenic emissions).

References:

Topping, D., Connolly, P. and McFiggans, G., 2013. Cloud droplet number enhanced by co-condensation of organic vapours. Nature Geoscience, 6(6), p.443.

How to cite: Heikkinen, L., Lowe, S., Wu, C., Aliaga, D., Huang, W., Gramlich, Y., Carbone, S., Zha, Q., Velarde, F., Mardoñez, V., Moreno, I., Koenig, A., Andrade, M., Artaxo, P., Bianchi, F., Krejci, R., Ehn, M., Partridge, D., Riipinen, I., and Mohr, C.: Quantifying the effect of SVOC condensation on cloud droplet number in different airmass types, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10491, https://doi.org/10.5194/egusphere-egu2020-10491, 2020.

EGU2020-12744 | Displays | AS3.1

Impact of Long-Range Transport Biomass Burning (BB) Emissions on Cloud Condensation Nuclei (CCN) Activation in Continental Polluted Air of Delhi, India

Subha S. Raj, Mira L. Pӧhlker, Thomas Klimach, Jan-David Förster, David Walter, Ovid O. Krüger, Christopher Pӧhlker, Upasana Panda, Amit Sharma, Eoghan Derbyshire, James D. Allan, Ravi Krishna R., Vijay Kumar Soni, Siddhartha Singh, Gordon Mcfiggans, Hugh Coe, Ulrich Pӧschl, and Sachin S. Gunthe

Cloud Condensation Nuclei (CCN) and other aerosol properties were investigated in Delhi, India, from Feb. to Mar. 2018. The high anthropogenic influence on aerosol was studied with size-resolved CCN measurements (supersaturation (S) between 0.13 to 0.66% and selected diameters from 10 to 300 nm). Furthermore the chemical composition (Aerosol Chemical Speciation Monitor and Aethalometer AE33) of the particles was measured. The aerosol number size distribution was derived by size data inversion of Differential Mobility Particle Sizer (DMPS) from size-resolved CCN measurements. Based on multi-year back trajectory (BT) data, a spatial clustering analysis was done for the actual campaign period and two distinct clusters were identified: northwest- west northwest-long range transport (NW-LRT) and south-southeast-east southeast (SE).

There was preponderant organic mass fraction (forg) in the aerosols throughout the campaign, with prominent diurnal variation except during the SE period. Pronounced diurnal variation was observed also in black carbon (BC) with an average concentration of 16 µg/m3 during NW-LRT, in contrast to a weak diurnal cycle with lower average concentration of 8 µg/m3 during SE. During the NW-LRT cluster the air masses traversed over agriculture fields with biomass burning (BB) activities identified using the fire radiative power (FRP) observations of Copernicus Atmosphere Monitoring Service (CAMS) Global Fire Assimilation System (GFAS). So it can be speculated that the BB emissions from the fields have contributed to enhanced BC concentrations during this period over Delhi. The remaining period, showing a mixture of local and long-range transported emissions also had a BC concentration higher than SE period when only local/regional emissions were observed. This is an important insight into the air pollution apocalypse in Delhi.

The overall average values of critical dry diameter (Dc) for CCN activation varied from 54 ± 8 nm at S = 0.66% to 139 ± 12 nm at S = 0.13%.The hygroscopicity parameter derived from CCN data (кCCN) was in the range from 0.1 to 0.9 with an arithmetic mean of 0.27 ± 0.10, which is close to that of Beijing, another polluted continental region (0.31 ± 0.08, Gunthe et al., 2011). кCCN also shows good agreement with the hygroscopicity parameter derived from the chemical composition measurements. A linear fit (Gunthe et al., 2009) applied to the relationship between refractory/non-refractory organic mass fraction and кCCN at S = 0.13%, gives an effective hygroscopicity parameter кorg = 0.17 ± 0.09 and кinorg = 0.80 ± 0.09, when extrapolated to forg = 1 and forg = 0, respectively. The presence of externally mixed inactive CCN particles is indicated by an average maximum activated fraction (MAF) of 0.82 ± 0.17 at S = 0.13%. The overall average Dc, кCCN, and MAF did not vary much between NW-LRT and SE periods, although the particle number concentration was higher during NW-LRT. Moreover, high CCN efficiency was observed during NW-LRT, in spite of its enhanced BC concentration, indicating the presence of aged internally mixed aerosols. Further details will be presented.

How to cite: S. Raj, S., L. Pӧhlker, M., Klimach, T., Förster, J.-D., Walter, D., O. Krüger, O., Pӧhlker, C., Panda, U., Sharma, A., Derbyshire, E., D. Allan, J., Krishna R., R., Soni, V. K., Singh, S., Mcfiggans, G., Coe, H., Pӧschl, U., and S. Gunthe, S.: Impact of Long-Range Transport Biomass Burning (BB) Emissions on Cloud Condensation Nuclei (CCN) Activation in Continental Polluted Air of Delhi, India, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12744, https://doi.org/10.5194/egusphere-egu2020-12744, 2020.

EGU2020-9131 | Displays | AS3.1

Microbial metabolic activity measurements in clouds and precipitation at the puy de Dôme station (Central France)

Florent Rossi, Raphaëlle Péguilhan, Maxence Brissy, Laurent Deguillaume, Anne-Marie Delort, and Pierre Amato

Airborne bacteria are important components of biological aerosols. They have been shown to remain alive and metabolically active in the different compartment of the atmosphere (clouds, rain, aerosols), despite the harsh environmental conditions (U.V., free radicals, low temperatures, etc…). Current knowledge indicates that bacteria interfere with chemical reactivity in clouds, by utilizing carbon and nitrogen compounds, detoxifying free radicals and their precursors, etc. Nevertheless, due to the low biomass (≈ 102 to ≈106 cells/m3) and numerous sampling constraints, bacterial activity remains largely unexplored in atmospheric water; and regarding atmospheric chemistry, airborne bacteria are still essentially regarded as inert particles.

To fulfill this gap in knowledge, this study aims at quantifying microbial activity in the different compartments of the atmosphere. Sampling and analytical methods were developed and adapted to overcome the low biomass constraint and the required immediate analyses, to obtain in situ quantitative and qualitative measurements of biological activity. Samplings of cloud water were performed between September 2019 and April 2020 at the Puy de Dôme Mountain’s meteorological station (1465 m asl, France) using impactors and high-flow-rate impingers [1], whereas precipitations were collected below the summit (Opme station, 680 m asl) using an automated wet-deposition sampler. Bacterial metabolic activity was assessed by coupling two different approaches: the determination of the active fraction of bacteria using the ubiquitous esterase enzyme activity as proxy (fluorescein diacetate assay, flow cytometry), and the quantification of ribosomal DNA/RNA (qPCR). Relationship between these activities and meteorological, physical and chemical measurements were also examined.

Preliminary results showed traces of a recent metabolic activity in cloud’s bacterial communities, as highlighted by the observed rRNA/rDNA ratio of 1. In parallel, 8.5% of the bacteria in clouds exhibited an esterase activity, supporting that bacteria can remain active in clouds. The bacterial fraction displaying esterase activity in precipitation samples was much higher (30%), suggesting fast variations in bacterial metabolic activity, probably related with changes in environmental constraints and bacterial assemblage composition. Further investigations are on-going to specify microbial activity along the aerosol-cloud-precipitation continuum, its variability, and to quantify its contribution to atmospheric chemical processes.

 

[1]           T. Šantl-Temkiv et al., “High-Flow-Rate Impinger for the Study of Concentration, Viability, Metabolic Activity, and Ice-Nucleation Activity of Airborne Bacteria,” Environ. Sci. Technol., vol. 51, no. 19, pp. 11224–11234, 2017.

How to cite: Rossi, F., Péguilhan, R., Brissy, M., Deguillaume, L., Delort, A.-M., and Amato, P.: Microbial metabolic activity measurements in clouds and precipitation at the puy de Dôme station (Central France), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9131, https://doi.org/10.5194/egusphere-egu2020-9131, 2020.

EGU2020-2876 | Displays | AS3.1

Partitioning of microbial cells between clouds and precipitation

Raphaëlle Péguilhan, Ludovic Besaury, Florent Rossi, Jean-Luc Baray, Thibaud Mas, Laurent Deguillaume, Barbara Ervens, and Pierre Amato

It is known that microorganisms are present in the outdoor atmosphere, in clouds and precipitation. These microorganisms originate from various local and distant sources and consist of very diverse and ephemeral communities. The most abundant bacterial taxa typically include Alpha-, Beta- and Gamma-Proteobacteria, with notably Pseudomonas and Sphingomonas among the dominant genera observed. Still, very little is known about their sources, metabolic activity, distribution, and their dynamics during their atmospheric life cycle. It was proposed in the past that bacteria with high ice nucleation activity are likely more efficiently precipitated than others [1]. Here, we extend this hypothesis and suggest more generally that different bacteria taxa could exhibit different phase partitioning between aerosol particles, cloud and rainwater, which may affect their atmospheric residence times. This implies that microorganisms are not equally distributed among the different atmospheric compartments (clouds, aerosols and precipitation).

To investigate this hypothesis, cloud and rain samples were collected simultaneously from single precipitation events, from two meteorological stations located at different altitudes: the summit of puy de Dôme Mountain (1465 m above sea level; France), embedded in clouds, using cloud impactors and high-flow-rate impingers [2], and below the summit, at Opme Station (680 a.s.l.) where precipitation occurred, using automated precipitation collector. The bacterial biodiversity was examined by 16s rRNA gene amplicon MiSeq sequencing. Samples were also characterized for their chemical contents. We show that clouds and precipitation host distinct microbial communities. Clouds host communities from high altitude likely to be of distant origin, while precipitation also includes material originating from the air column underneath and from local origin. So, comparing the biodiversity hosted in clouds and precipitation within single air masses provides information on the relative contribution of local and distant sources to the microorganisms deposited at the surface with rainfalls, and provides very new information concerning the processing and fate of bacteria in the atmosphere.

 

[1]         M. Joly, P. Amato, L. Deguillaume, M. Monier, C. Hoose, and A. M. Delort, “Quantification of ice nuclei active at near 0 °c temperatures in low-altitude clouds at the Puy de Dôme atmospheric station,” Atmos. Chem. Phys., vol. 14, no. 15, pp. 8185–8195, 2014.

[2]         T. Šantl-Temkiv et al., “High-Flow-Rate Impinger for the Study of Concentration, Viability, Metabolic Activity, and Ice-Nucleation Activity of Airborne Bacteria,” Environ. Sci. Technol., vol. 51, no. 19, pp. 11224–11234, 2017.

How to cite: Péguilhan, R., Besaury, L., Rossi, F., Baray, J.-L., Mas, T., Deguillaume, L., Ervens, B., and Amato, P.: Partitioning of microbial cells between clouds and precipitation , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2876, https://doi.org/10.5194/egusphere-egu2020-2876, 2020.

EGU2020-223 | Displays | AS3.1

Air Pollution and its potential climate effect in Delhi, India

Ying Chen, Luke Conibear, Yu Wang, Liang Ran, Jianjun He, Lina Wang, and Oliver Wild

Delhi, the capital city of India with more than 10 million population, is suffering one of the worst particulate matter (or PM2.5) pollution over the world. Based on continuous observations during 2015-2018, we report that the PM2.5 pollution in Delhi is possibly one of the worst within Indian cities, and responsible for ~10,000 premature deaths of cities per year. Especially during the Diwali Fest, the hourly PM2.5 concentrations went above 1600 ug/m3, leading to ~20 extra premature deaths per day (Chen et al., 2019). We find a distinct seasonal variation of PM2.5 mass concentrations and a shift of morning rush hour from winter to summer, but a negligible weekend effect in Delhi. We also report a long-term result of hygroscopicity of PM2.5 in Delhi is about κ= 0.42 ± 0.07 for the first time, indicating much higher potential of cloud droplet activation from fine particles in Delhi compared with other Asian megacities, such as Beijing (κ=0.14–0.23) (Wang and Chen, 2019). It means, in addition to the great health burden, more significant cloud activation and greater influences on climate and hydrologic cycle are expected from fine particles in Delhi.

 

Method & Data

             We analysed the PM2.5 observations from US Embassy in Delhi, and used the Integrated Exposure Response Function to estimate the long-term and short-term health effect of PM2.5 exposure with a particular focus on the Diwali Fest period. Together with the temperature, RH and visibility data from the DEL airport in Delhi, we retrieved the 2016-2018 averaged hygroscopicity (κ) in Delhi according to the κ-kÓ§hler and Mie theories. In summary, we firstly retrieve the optical enhancement from visibility and RH, and then retrieve the optical-κ, and finally estimate the κ from the optical-κ. The detailed retrieving method is given in Wang and Chen (2019), this method has been validated in Beijing within an uncertainty of 30%.

 

Summary

                Our results show a strong seasonal variation of PM2.5 in Delhi, with severest pollution during the winter. The Diwali and New Year Fests also lead to extreme pollution events, i.e. worse than the ‘Severe’ Level, in the beginning of November and January. These lead to adverse health effect and make Delhi the top-1 health burden city in India. The long-term averaged hygroscopicity of PM2.5 in Delhi is much higher than Beijing and Asian average. This indicate much easier for fine particles serving as cloud condensation nuclei and contributing the climate change and hydrology cycle. Moreover, the high optical enhance factor, f(RH), implies strong direct radiative forcing enhancement and influences on the heterogeneous reactions in Delhi.

 

Acknowledgement: We thank NERC Fund supported project (NE/P01531X/1) and the joint scholarship of China Scholarship Council and University of Manchester. We thank the U.S. National Climatic Data Center and AirNow platform maintained by the EPA provide the observations.

 

References:

Chen, Y., Wild, O., Conibear, L., Ran, L., He, J., Wang, L., and Wang, Y.: Atmospheric Environment: X, 100052, 10.1016/j.aeaoa.2019.100052, 2019.

Wang, Y., and Chen, Y.: Geophysical Research Letters, 10.1029/2019GL082339, 2019.

How to cite: Chen, Y., Conibear, L., Wang, Y., Ran, L., He, J., Wang, L., and Wild, O.: Air Pollution and its potential climate effect in Delhi, India, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-223, https://doi.org/10.5194/egusphere-egu2020-223, 2020.

In recent years, China's industrialization and urbanization have accelerated, generating high emissions of pollutants every year, which has significantly deteriorated the air quality of Chinese cities and threatened public health and the happiness of urban residents. More and more studies have shown that several megacities in China and more and more cities have experienced more severe smog pollution. The occurrence of haze seriously affects the healthy development of human beings, so the research on haze should be vigorously promoted. Although many studies have made considerable progress in the research of smog in recent years, there is no systematic and comprehensive assessment method. But scholars have not stopped the pace of research.This study takes Weinan City, Shaanxi, China as the research object, The paper describes the formation mechanism of haze and the combined effects of emission sources, chemical aerosol material formation and transformation, meteorology and climatic conditions. The mechanism of haze formation is relatively complicated. Aerosols are widely used in the research of haze composition.Organic aerosols have a very important impact on the Earth's radiation, visibility and air quality on a global scale. However, the formation of secondary pollution makes this process more complicated. Secondary organic aerosols (SOA), free radicals that form volatile organic compounds and particles with ozone (O3), hydroxyl (OH) and nitrate (NO3) and artificial volatile organic compounds (VOCs) are considered organic gases One of the most important components of sol. In the past few decades, many studies have been conducted to study the formation of SOA. However, due to the complex formation mechanism of SOA, no further reason has been clarified.The reasons for the formation of haze are more complicated. For the true solution of the haze problem is still the key for our scholars to solve in the future, the government should also formulate corresponding measures to reduce the early discharge of pollutants, control the haze from the source, in short A long way to go requires joint efforts from everyone.

Keywords:Haze  Aerosol  Meteorological conditions  Weinan

How to cite: Meng, Y., Xi, J., and Wang, Y.: Discussion on the formation mechanism of severe haze in North China and its relationship with meteorological factors, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4343, https://doi.org/10.5194/egusphere-egu2020-4343, 2020.

EGU2020-7246 | Displays | AS3.1

Secondary Organic Aerosol Formation from Chinese Cooking Emission

Song Guo, Hui Wang, Wenfei Zhu, Zirui Zhang, Zheng Chen, Rongzhi Tang, Ruizhe Shen, Tiantian Wang, Ying Yu, Rui Tan, and Min Hu

Organic aerosol (OA) constitutes a significant fraction of the atmospheric fine particulate matter that influences both air quality and climate. Secondary organic aerosol (SOA), which is formed through photo-oxidation of organic vapors in the atmosphere, is a major component of OA. There are some studies indicating the major role of Chinese cooking emissions in SOA formation in China. However, SOA formation is complex and uncertain.

In this study, we investigate the primary emission and secondary formation from Chinese cooking. The cooking ways include stir-fry, fry, and deep fry. The dishes were stir-fired shredded cabbage, fried Tofu, Kung Pao Chicken, and fired Chicken. Besides, different kinds of oils were fried to investigate the effect of oil on emission. The cooking emission was diluted and exposed a range concentration of oxidants (O3 and OH) in the Go-PAM. Two SMPS were used to measure particle number concentrations before and after oxidation. A DMA-CPMA-CPC system was used to obtain the size resolved particle density, and together with particle number concentration, primary and secondary particle mass concentrations were calculated. One ptr-MS was used to measure primary VOCs concentration, and one Aerodyne VOCUS was deployed to measure the VOCs after PAM. An AMS was used to measure the secondary particles. Our results showed that the SOA/POA ratios varied significantly from 5-35, depending on cooking ways. The emission stir-fired shredded cabbage has largest SOA/POA ratio of 35, followed by fried Tofu (22), Kung Pao Chicken (16), and fried chicken (5). The O:C ratio increased from 0.12~0.26 of cooking POA to 0.40~0.52 of cooking SOA. Our results suggest Chinese cooking contributes significantly to ambient not only primary particles but secondary particles.

How to cite: Guo, S., Wang, H., Zhu, W., Zhang, Z., Chen, Z., Tang, R., Shen, R., Wang, T., Yu, Y., Tan, R., and Hu, M.: Secondary Organic Aerosol Formation from Chinese Cooking Emission, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7246, https://doi.org/10.5194/egusphere-egu2020-7246, 2020.

EGU2020-6390 | Displays | AS3.1

Estimation of ground PM2.5 based on GOCI TOA reflectance using Deep Neural Network

Chang Suk Lee, Sang-Min Kim, Kyung-Hwa Lee, Jongmin Yoon, Hyunkee Hong, Won Jun Choi, and Dong-Won Lee

Fine particulate matter (PM2.5), which consists of solid and liquid particles and mixture of both suspended in the near surface atmosphere, is known to be one of the most threatening elements to human health by penetrating skin, lungs and bronchi. There have been diverse studies with regard to monitoring near-surface PM2.5, particularly over East Asia, where recent rapid industrial development has produced serious air pollution. Some countries have already been operating ground-based monitoring networks and collecting relevant data. However, due to their poor spatial representativeness and inhomogeneous data quality, many of the previous studies were conducted based on space-borne observations. In this study, we tried to monitor concentrations of PM2.5, particles with aerodynamic diameters less than 2.5 µm, based on GOCI top of atmosphere reflectance using a deep neural network (DNN) method. DNN is a kind of machine learning developed from artificial neural networks. In order to enhance the model performance, near-surface atmospheric information from Unified Model was also used as input variables such as surface temperature, dew point temperature, surface pressure, height of planetary boundary layer, relative humidity and wind fields. Sensitivity examinations were conducted to find optimal structures of training models and several techniques (e.g., regularization, early stopping, and normalization of input variables) were applied to prevent over-fitting training datasets. The retrieved data were characterized by comparing with estimates from the operational MCAQ model, which is used in air quality forecasting, and conventional linear regression results.

How to cite: Lee, C. S., Kim, S.-M., Lee, K.-H., Yoon, J., Hong, H., Choi, W. J., and Lee, D.-W.: Estimation of ground PM2.5 based on GOCI TOA reflectance using Deep Neural Network, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6390, https://doi.org/10.5194/egusphere-egu2020-6390, 2020.

EGU2020-5313 | Displays | AS3.1

Organic functional group composition of particulate matter from fresh and aged wood burning and coal combustion

Amir Yazdani, Nikunj Dudani, Satoshi Takahama, Amelie Bertrand, André S. H. Prévôt, Imad El Haddad, and Ann M. Dillner

Particulate matter (PM) affects visibility and climate through light scattering, direct and indirect radiative forcing, and affecting cloud formation [1]. In addition, exposure to ambient fine PM is estimated to have caused 8.9 million deaths worldwide in 2015 [2]. Organic matter (OM), can make up more than half of total fine atmospheric PM, and yet its composition, formation mechanisms, and adverse health effects are not fully characterized due to its sheer compositional complexity. Biomass burning (e.g., residential wood burning, wildfires, and prescribed burning) and coal combustion (for heat and power generation) are two major OM sources, for which the impact of atmospheric aging - including secondary organic aerosol (SOA) formation - is not yet fully clear [3].

In this study, we investigated the effect of aging on composition and mass concentration of organic aerosols of wood burning (WB) and coal combustion (CC) emissions using two complementary methods, i.e., mid-infrared spectroscopy and aerosol mass spectrometry (AMS). For this purpose, primary aerosols were injected into the Paul Scherrer Institute (PSI) environmental chamber and aged using hydroxyl and nitrate radicals to simulate day-time and night-time oxidation processes in the atmosphere. In these experiments, aerosols reached an oxidative age comparable to that of atmospheric aerosols. A time-of-flight AMS instrument was used to measure the high-time-resolution composition of non-refractory fine PM, while we collected PM1 aerosols on PTFE filters before and after four hours of aging for off-line Fourier transform-infrared spectroscopy (FT-IR) measurements.

AMS and FT-IR estimates of organic aerosol mass concentration were highly correlated (r2=0.92); both indicating an approximately three-fold increase in organic aerosol concentration after aging. The OM/OC ratio, indicating the extent of oxidation also agreed closely between the two instruments and increased, on average, from 1.6 (before aging) to 2 (after aging). Mid-infrared spectroscopy, which is able to differentiate among oxygenated species, shows a distinct functional group composition for aged WB aerosols (high abundance of carboxylic acids) and CC aerosols (high abundance of non-acid carbonyls) and detects considerable amounts polycyclic aromatic hydrocarbons (PAHs) for both sources. Mid-infrared spectra of fresh WB and CC aerosols are reminiscent of their parent compounds with differences in specific functional groups suggesting the dominant oxidation pathways for each emission source. Finally, the comparison of mid-infrared spectra of aged WB aerosols in the environmental chamber with that of ambient samples affected by residential wood burning and wildfires reveals interesting similarities regarding the high abundance of alcohols and visible signatures of lignin. This finding is useful for interpreting sources of atmospheric aerosols and better interpretation of their complex mid-infrared spectra.

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REFERENCES

[1] M. Hallquist et al., “The formation, properties and impact of secondary organic aerosol: current and emerging issues,” Atmos Chem Phys, 2009.

[2] R. Burnett et al., “Global estimates of mortality associated with long-term exposure to outdoor fine particulate matter,” Proc. Natl. Acad. Sci., 2018.

[3] A. Bertrand et al., “Primary emissions and secondary aerosol production potential from woodstoves for residential heating: Influence of the stove technology and combustion efficiency,” Atmos. Environ., 2017.

How to cite: Yazdani, A., Dudani, N., Takahama, S., Bertrand, A., Prévôt, A. S. H., El Haddad, I., and Dillner, A. M.: Organic functional group composition of particulate matter from fresh and aged wood burning and coal combustion , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5313, https://doi.org/10.5194/egusphere-egu2020-5313, 2020.

EGU2020-7382 | Displays | AS3.1 | Highlight

The oxidizing power of the dark side: Rapid nocturnal aging of biomass burning as an overlooked source of oxidized organic aerosol

John Kodros, Dimitris Papanastasiou, Marco Paglione, Mauro Masiol, Stefania Squizzato, Kalliopi Florou, Agata Kołodziejczyk, Ksakousti Skyllakou, Athanasios Nenes, and Spyros Pandis

Oxidized organic aerosol (OOA) is a major component of ambient particulate matter, substantially affecting both climate and human health. A considerable body of evidence has established that OOA is readily produced in the presence of daylight, thus leading to the association of high concentrations of OOA in the summer or mid-afternoon. However, this current mechanistic understanding fails to explain elevated OOA concentrations during night or wintertime periods of low photochemical activity, thus leading atmospheric models to under predict OOA concentrations by a factor of 3-5. Here we show that fresh emissions from biomass burning rapidly forms OOA in the laboratory over a few hours and without any sunlight. The resulting OOA chemical composition is consistent with the observed OOA in field studies in major urban areas. To estimate the contribution of nocturnally aged OOA in the ambient atmosphere, we incorporate this nighttime-aging mechanism into a chemical-transport model and find that over much of the United States greater than 75% of the OOA formed from fresh biomass burning emissions underwent nighttime aging processes. Thus, the conceptual framework that OOA is predominantly formed in the presence of daylight fails to account for a substantial and rapid oxidation process occurring in the dark.

How to cite: Kodros, J., Papanastasiou, D., Paglione, M., Masiol, M., Squizzato, S., Florou, K., Kołodziejczyk, A., Skyllakou, K., Nenes, A., and Pandis, S.: The oxidizing power of the dark side: Rapid nocturnal aging of biomass burning as an overlooked source of oxidized organic aerosol, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7382, https://doi.org/10.5194/egusphere-egu2020-7382, 2020.

EGU2020-3669 | Displays | AS3.1

No Evidence for Brown Carbon Formation in Ambient Particles Undergoing Atmospherically Relevant Drying

Vikram Pratap, Michael Battaglia Jr., Annmarie Carlton, and Christopher Hennigan

Recent laboratory studies have reported the formation of light-absorbing organic carbon compounds (brown carbon, BrC) in aqueous particles undergoing drying.  Atmospheric particles undergo cycles of humidification and drying during vertical transport and through daily variations in temperature and humidity, which implies particle drying could potentially be an important source of BrC globally.  In this work, we investigated BrC formation in ambient particles undergoing drying at a site in the eastern United States during summer.  Aerosol BrC concentrations were linked to secondary organic aerosol (SOA) formation, consistent with seasonal expectations for this region.  Measurements of water-soluble organic aerosol concentrations and light absorption (365 nm) were alternated between an unperturbed channel and a channel that dried particles to 41% or 35% relative humidity (RH), depending on the system configuration. The RH maintained in the dry channels was below most ambient RH levels observed throughout the study.  We did not observe BrC formation in particles that were dried to either RH level. The results were consistent across two summers, spanning ~5 weeks of measurements that included a wide range of RH conditions and organic and inorganic aerosol loadings.  This work suggests that mechanisms aside from humidification-drying cycles are more important contributors to ambient particle BrC loadings.  The implications of this work on the atmospheric budget of BrC are discussed.

How to cite: Pratap, V., Battaglia Jr., M., Carlton, A., and Hennigan, C.: No Evidence for Brown Carbon Formation in Ambient Particles Undergoing Atmospherically Relevant Drying, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3669, https://doi.org/10.5194/egusphere-egu2020-3669, 2020.

EGU2020-13217 | Displays | AS3.1

Study of nitrogen compounds in different atmospheric compartments

Christelle Ghaffar, Maxence Brissy, Binta Dieme, Martin Lerembourg, Marcello Brigante, and Pierre Amato

Nitrogen molecules are present in the atmosphere also as inorganic ions (ammonium, nitrate…) and organic (peptides and proteins). Nowadays, there is still poor knowledge concerning the sources and fate of proteins and peptides in the atmosphere. In a larger context aiming at exploring microbial communities’ functioning in the atmosphere, the goal of this study is to examine the atmospheric proteome (peptide and protein contents, sequence, size distribution, biological functions) in the different atmospheric compartment (aerosols, cloud and rain waters).

Aerosols, cloud water and rain samples were collected at remote places nearby Clermont – Ferrand city (France) and from the Mountain “Puy de Dôme” (1465 m asl). Cloud droplet impactors and high volume impingers were used for allowing immediate fixation of the samples, by collecting within a protease inhibitor solution. Samples were filtered (0.22 µm porosity) and the proteins from water were digested using trypsin. The peptides were purified by solid phase extraction (SPE) method, concentrated by lyophilisation and analysed by LC – HRMS and MS². Preliminary results indicate the recurrence of certain small peptides in particular. Some of these most frequently observed peptides were selected as models for photochemical experiments. Briefly, these small peptides were irradiated under solar simulated conditions and products were identified by IC – MS, to assess the impact of such processes on the chemical composition of the atmosphere.

The next step will consist in analysing our observations along with chemical and biological parameters such as biodiversity, transcriptomic profiles, in order to better understand the interaction between microorganisms and atmosphere processes.

How to cite: Ghaffar, C., Brissy, M., Dieme, B., Lerembourg, M., Brigante, M., and Amato, P.: Study of nitrogen compounds in different atmospheric compartments, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13217, https://doi.org/10.5194/egusphere-egu2020-13217, 2020.

EGU2020-19552 | Displays | AS3.1

Molecular characterization and volatility of organonitrates: Latest observations from field and laboratory

Claudia Mohr, Cheng Wu, Wei Huang, Emelie Graham, Federico Bianchi, Marcos Andrade, and David Bell

Here we show recent results from different field and laboratory campaigns focusing on organonitrate (ON) formation, mass concentration, and physicochemical properties such as volatility. ONs are formed via volatile organic compounds (VOC) and NOx. They are therefore key species for our understanding of the interaction between the biosphere and anthropogenic activities, and the effects of altering both VOC and NOx emissions due to climate change and/or air quality mitigation measures. Recently, we were able to show that ONs from different precursor VOC can also contribute significantly to the growth of newly formed particles in the atmosphere to sizes where they can become active and cloud condensation nuclei (Huang et al., 2019).

We present direct, real-time observations of ONs in the gas and particle phase at the highest atmospheric research station in the world, Chacaltaya (5240 m a. s. l) in Bolivia. This southern hemisphere station is often located in the free troposphere during night time, and influenced by the emissions from the nearby El Alto-La Paz metropolitan area, and biogenic emissions from surrounding forests as well as from the Amazon through long-range transport. ONs were measured using a Chemical Ionization Mass Spectrometer with a Filter Inlet for Gases and Aerosols. We observed hundreds of highly functionalized ONs with different molecular composition during day- and nighttime, indicating different sources and formation processes. A large contribution of the highly functionalized ONs was found especially during new particle formation events regularly observed at this location (Rose et al., 2015). Observations from the field will be compared to results from the Nitrate Aerosol and Volatility Experiment (NArVE) at the EUROCHAMP 2020 PACS-C3 smog chamber (PSI, Switzerland), where we investigated the ON fraction, chemical composition, and volatility of secondary organic aerosol (SOA) formed via nitrate radical initiated oxidation reactions of biogenic and anthropogenic VOC.

How to cite: Mohr, C., Wu, C., Huang, W., Graham, E., Bianchi, F., Andrade, M., and Bell, D.: Molecular characterization and volatility of organonitrates: Latest observations from field and laboratory, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19552, https://doi.org/10.5194/egusphere-egu2020-19552, 2020.

EGU2020-3530 | Displays | AS3.1

Basicity and acidity promote hydrolysis of methyl nitrate in aqueous aerosols

Fatemeh Keshavarz, Theo Kurtén, and Hanna Vehkamäki

The chemistry of organic nitrates (ONs), also known as alkyl nitrates (RONO2), controls the lifetime of nitrogen oxides in continental areas, which in turn affects air quality and varies ozone concentration throughout the troposphere. ONs can be emitted to the troposphere from marine sources. Also, they can be produced in the atmosphere through addition of NO to peroxy radicals or through the reaction of NO3 radicals with volatile organic compounds. Atmospheric ONs may subsequently undergo oxidation or photolysis, in both gas and aerosol phases, or hydrolysis in aqueous aerosols. Though some recent studies have believed acid-catalysis promotes hydrolysis of ONs, earlier studies have claimed that acids have no effect on ON hydrolysis, and that it is the hydroxyl ion that can improve the hydrolysis process. The limited number of experimental studies performed so far have left this conflict with no appropriate answer, as mechanistic insight and full kinetics details have been partially or completely missing for the studied ONs. We report the detailed mechanism of methyl nitrate hydrolysis in acidic, neutral and basic conditions, in addition to analyzing the degradation of methyl nitrate into formaldehyde and nitrous acid in the presence of water and hydronium ions. According to the potential energy surfaces obtained at the CCSD(T)/cc-pVDZ//ωB97X-D/def2-TZVP level of theory (including the SMD solvent model) along with the rate coefficients estimated using asymmetric Eckart tunneling-corrected transition state theory (TST), mediation of water molecules and hydronium ions hinders degradation of methyl nitrate into formaldehyde and nitrous acid and, in general, this decomposition reaction is kinetically unfavorable. Furthermore, neutral hydrolysis of methyl nitrate is extremely slow with pseudo-first order rate coefficients (k; 298 K and 1 atm) falling below 10-27 s-1. Similarly, hydrolysis of methyl nitrate by hydronium ions is observed to be extremely slow (k < 10-27 s-1). However, under acidic conditions, protonation of methyl nitrate is quite feasible with the protonation Gibbs free energy of -429.1 kJ mol-1, at 298 K and 1 atm, and protonated methyl nitrate can hydrolyze into protonated methanol and nitric acid much faster relative to the hydronium ion-based and neutral hydrolysis (k = 3.83 s-1). On the other hand, the hydroxyl ions generated under basic conditions can hydrolyze methyl nitrate readily to give methanol and nitric acid (k = 6.63 × 103 s-1), or formaldehyde, nitrate and water (k = 9.40 × 106 s-1). In addition, regardless of the limitation on the rate of solvent-phase chemical reactions by the rate of diffusion, basic hydrolysis can produce methoxy ions and nitric acid quite fast (k = 8.95 × 109 s-1). In other words, methyl nitrate hydrolysis is faster in basic aerosols (i.e. some marine aerosols) and, to a less extent, in highly acidic aqueous aerosols (e.g. haze and urban aerosols).       

How to cite: Keshavarz, F., Kurtén, T., and Vehkamäki, H.: Basicity and acidity promote hydrolysis of methyl nitrate in aqueous aerosols, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3530, https://doi.org/10.5194/egusphere-egu2020-3530, 2020.

EGU2020-13355 | Displays | AS3.1

Formation of (nitrooxy)organosulfates from organic peroxides and S(IV) via daytime and nighttime chemistry

Martin Brüggemann, Matthieu Riva, Clement Dubois, Anke Mutzel, Christian George, and Hartmut Herrmann

Sulfur and nitrogen containing organic compounds, such as organosulfates (OSs) and nitrooxy organosulfates (NOSs), are recognized to be ubiquitously present in secondary organic aerosol (SOA). However, little is known about the chemical mechanisms or the required conditions for the formation of these compounds in the ambient atmosphere. Earlier studies have commonly suggested that OSs are predominantly formed through the reaction of organic gaseous epoxides with acidic sulfate particles. However, this epoxide pathway often fails to explain the formation of (N)OSs from monoterpenes. Moreover, recent studies highlight the potential role of gas-phase SO2 and organic peroxides for the formation of OSs, which might serve as predominant precursors for OSs and NOSs from atmospheric monoterpene oxidation.

Here, we conducted a series of chamber experiments to elucidate the formation mechanisms of (N)OSs from α-pinene oxidation during daytime and nighttime conditions. In particular, we focused on the role of organic peroxides and S(IV) (i.e., gas-phase SO2 and particulate SO32–) in contrast to organic epoxides and isotope-labelled particulate sulfate (i.e., S(VI)). SOA particles were analyzed online by extractive electrospray ionization coupled with high-resolution Orbitrap mass spectrometry (EESI-Orbitrap MS) allowing an unambiguous identification of OS and NOS species with a high time resolution. Additionally, filter samples were collected and analyzed by liquid chromatography (LC) coupled with Orbitrap MS to determine the presence of isomeric compounds.

Consistently, online and offline Orbitrap MS analysis showed that particulate sulfate played a minor role in the formation of OSs and NOSs. In contrast, (N)OSs were rapidly formed upon addition of either gaseous SO2 or particulate SO32–, suggesting S(IV) to react with organic peroxides that were formed through monoterpene oxidation. Based on these experiments, we identified specific NOS species that are formed only through either daytime or nighttime chemistry, and thus, might serve as marker molecules. Moreover, we present complete formation pathways for these species. Our study indicates that in contrast to previous work, the formation of OSs and NOSs does not require acidic sulfate particles, but rather involves the reaction of organic peroxides with S(IV) in the gas phase or the particle phase.

How to cite: Brüggemann, M., Riva, M., Dubois, C., Mutzel, A., George, C., and Herrmann, H.: Formation of (nitrooxy)organosulfates from organic peroxides and S(IV) via daytime and nighttime chemistry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13355, https://doi.org/10.5194/egusphere-egu2020-13355, 2020.

EGU2020-5370 | Displays | AS3.1

Investigating the Vapour Pressures of Nitroaromatic Compounds Using Knudsen Effusion Mass Spectrometry

Petroc Shelley, Thomas Bannan, Stephen Worrall, Ulrich Krieger, M. Rami Alfarra, and David Topping

Deeper understanding of the behaviour of aerosol particles in the atmosphere is essential for the continued improvement of aerosol representation within models. The saturation vapour pressure (Psat ) of secondary organic aerosols (SOA) can be used to predict partitioning between the gaseous and particulate phase. The extent of this partitioning affects the behaviour of SOA in the atmosphere1.

Typically Psat  of SOA are estimated using group contribution methods (GCMs) due to a lack of experimental data. The reliability of GCMs, when applied to a certain compound, depend on the how well represented the functionality present in the compound of interest is represented in the fitting data set of the GCM2.

Nitroaromatics are a class of compound that are useful atmospheric tracers for anthropogenic emissions3, and many nitroaromatic compounds are noted to be toxic4. There is a lack of atmospherically relevant experimental data available for nitroaromatic compounds. This leads to poor performance of GCMs when they try and predict Psat . Additional experimentally determined Psat data can be used to expand the fitting data sets of GCMs allowing for more accurate prediction in the future.

In this study we present results from recent experiments using Knudsen Effusion Mass Spectrometry (KEMS) and differential scanning calorimetry (DSC) and compare these results with predicted values from multiple GCMs. The KEMS measurements are supported by additional data from diffusion controlled evaporation rates of single particles in an electrodynamic balance (EDB). In many cases the differences between the experimental data and the predicted values was several orders of magnitude. The limited nitroaromatic data within the GCM fitting sets are then investigated so that the mostly likely causes of the multiple order of magnitude differences between the predicted values and experimental values can be identified.

1         M. Bilde, K. Barsanti, M. Booth, C. D. Cappa, N. M. Donahue, E. U. Emanuelsson, G. McFiggans, U. K. Krieger, C. Marcolli, D. Topping, P. Ziemann, M. Barley, S. Clegg, B. Dennis-Smither, M. Hallquist, Å. M. Hallquist, A. Khlystov, M. Kulmala, D. Mogensen, C. J. Percival, F. Pope, J. P. Reid, M. A. V Ribeiro da Silva, T. Rosenoern, K. Salo, V. Pia Soonsin, T. Yli-Juuti, N. L. Prisle, J. Pagels, J. Rarey, A. A. Zardini and I. Riipinen, Chem. Rev, 2015, 115, 4115–4156.

2         T. Kurtén, K. Tiusanen, P. Roldin, M. Rissanen, J.-N. Luy, M. Boy, M. Ehn and N. Donahue, J. Phys. Chem. A, 2016, 120, 2569–2582.

3         D. Grosjean, Atmos. Environ. Part A. Gen. Top., 1992, 26, 953–963.

4         P. Kovacic and R. Somanathan, J. Appl. Toxicol., 2014, 34, 810–824.

 

How to cite: Shelley, P., Bannan, T., Worrall, S., Krieger, U., Alfarra, M. R., and Topping, D.: Investigating the Vapour Pressures of Nitroaromatic Compounds Using Knudsen Effusion Mass Spectrometry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5370, https://doi.org/10.5194/egusphere-egu2020-5370, 2020.

EGU2020-16195 | Displays | AS3.1 | Highlight

How well do the latest Earth System Models capture the behaviour of biogenic secondary organic aerosol in the atmosphere?

Catherine Scott, Masaru Yoshioka, Chris Dearden, Ken Carslaw, Dominick Spracklen, Fiona O'Connor, Gerd Folberth, Mohit Dalvi, Jane Mulcahy, Yves Balkanski, Ramiro Checa-Garcia, Dirk Olivie, Michael Schulz, Twan van Noije, Philippe le Sager, Martine Michou, Pierre Nabat, Lars Nieradzik, Tommi Bergman, and Declan O'Donnell

Biogenic secondary organic aerosol (SOA) is formed as a result of the atmospheric oxidation of gas-phase biogenic volatile organic compounds (BVOCs). Here, we evaluate the ability of five European Earth System Models (CNRM-ESM2-1, EC-Earth3, IPSL-CM6, NorESM1.2, UKESM1) to capture the amount, and behaviour, of biogenic SOA in the atmosphere.

The ESMs cover a range of complexity in terms of their representation of the sources and processing of biogenic SOA (i.e., from a fixed climatology of SOA amount to an interactive BVOC emission scheme followed by atmospheric processing).

We combine station measurements of BVOC emission and atmospheric BVOC concentrations with remotely sensed isoprene emission estimates to evaluate the models’ representation of the sources of biogenic SOA. We use organic aerosol mass and particle number concentration measurements from a number of forested sites to evaluate the ability of the models to capture the seasonal cycle in the amount of biogenic SOA present, as well as its impact on the aerosol size distribution. Whilst the models appear to capture the seasonal cycle in organic aerosol well for a boreal forest site, the ESMs consistently over-predict the amount of organic aerosol present at a tropical forest location. 

Finally, we explore the ability of these models to capture the observed relationships between organic aerosol mass, or particle number, and temperature. We find that the ESMs equipped with vegetation models that generate BVOC emissions interactively are able to capture well the strength of the observed relationship between temperature and organic aerosol mass. This lends confidence to the ability of these ESMs to accurately represent changes in atmospheric composition driven by climate.

How to cite: Scott, C., Yoshioka, M., Dearden, C., Carslaw, K., Spracklen, D., O'Connor, F., Folberth, G., Dalvi, M., Mulcahy, J., Balkanski, Y., Checa-Garcia, R., Olivie, D., Schulz, M., van Noije, T., le Sager, P., Michou, M., Nabat, P., Nieradzik, L., Bergman, T., and O'Donnell, D.: How well do the latest Earth System Models capture the behaviour of biogenic secondary organic aerosol in the atmosphere?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16195, https://doi.org/10.5194/egusphere-egu2020-16195, 2020.

EGU2020-18027 | Displays | AS3.1

First global evaluation of the representation of water uptake within ten earth system models

Maria Ángeles Burgos Simón and the Aerosol hygroscopicity - model evaluation team

Aerosol optical properties, such as particle light scattering, depend on the particle size and chemical composition, which in turn are affected by the particle’s ability to take up water. Thus, particle hygroscopic growth will have an impact on the optical properties and in turn will affect the aerosol-radiation interaction and the calculations of the Earth’s radiative balance. The dependence of particle light scattering on relative humidity (RH) can be described by the scattering enhancement factor f(RH), defined as the ratio between the particle light scattering coefficient at a given RH divided by its dry value.

In our previous work (Burgos et al., 2019), we carried out a standardized analysis of scattering in-situ measurements at 26 sites around the globe, creating a benchmark dataset (open access via EBAS, http://ebas.nilu.no/). The project continues with the present work, which is part of the AeroCom phase III INSITU project: Evaluation of hygroscopicity of aerosol optical properties. Here, we present a comprehensive model-measurement evaluation of f(RH) for ten different earth system models. Modelled and measured scattering enhancement factors are compared for 22 sites, representative of Arctic, marine, rural, mountain, urban and desert aerosols.

Overall, a large variability and diversity in the magnitude of predicted f(RH) amongst the models is found and the modelled f(RH) tends to be overestimated relative to the measurement values. This difference cannot be explained by the aerosol type. Agreement between models and measurements was strongly influenced by the choice of RHref. Models show a significantly larger discrepancy with the observations if model dry conditions are set to RH=0% instead of RH=40%. Model parameterizations of aerosol hygroscopicity and mixing state may be driving the observed diversity among models as well as the discrepancy with measurements. Measurement conditions have to be considered in this type of evaluation, specifically the fact that “dry” measurements may not be “dry” in model terms.

This work has been submitted to ACPD.

Burgos, M., Andrews, E., Titos, G., Alados-Arboledas, L., Baltensperger, U., Day, D., Jefferson, A., Kalivitis, N., Mihalopoulos, N., Sherman, J., Sun, J., Weingartner, E., and Zieger, P.: A global view on the effect of water uptake on aerosol particle light scattering, Scientific Data, 6, https://doi.org/10.1038/s41597-019-0158-7, 2019.

How to cite: Burgos Simón, M. Á. and the Aerosol hygroscopicity - model evaluation team: First global evaluation of the representation of water uptake within ten earth system models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18027, https://doi.org/10.5194/egusphere-egu2020-18027, 2020.

EGU2020-6132 | Displays | AS3.1

How many particles do we need to measure aerosol mixing state?

Nicole Riemer, Jessica Gasparik, Qing Ye, Matthew West, Jeff Curtis, Ryan Sullivan, and Albert Presto

Atmospheric aerosols are evolving mixtures of different chemical species.  The term “aerosol mixing state” is commonly used to describe how different chemical species are distributed throughout a particle population.  A population is “fully internally mixed” if each individual particle consists of same species mixtures, whereas it is fully externally mixed if each particle only contains one species. Mixing state matters for aerosol health impacts and for climate-relevant aerosol properties, such as the particles’ propensity to form cloud droplets or the aerosol optical properties.

The mixing state metric χ quantifies the degree of internal or external mixing and can be calculated based on the particles’ species mass fractions. Several field studies have used this metric to quantify mixing states for different ambient environments using sophisticated single-particle measurement techniques. Inherent to these methods is a finite number of particles, ranging from a few hundred to several thousand particles, used to estimate the mixing state metric. 

This study evaluates the error that is introduced in calculating χ due to a limited particle sample size.  We used the particle-resolved model PartMC-MOSAIC to generate a scenario library that encompasses a large number of reference particle populations and that represents a wide range of mixing states. We stochastically sub-sampled these particle populations using sample sizes of 10 to 10,000 particles and recalculated χ based on the sub-samples. This procedure mimics the impact of only having a limited sample size as it is common in real-world applications. The finite sample size leads to a consistent overestimation of χ, meaning that the populations appear more internally mixed than they are in reality. These findings are experimentally confirmed using single-particle SP-AMS measurement data from the Pittsburgh area. We also determined confidence intervals of χ for our sub-sampled populations. To determine χ within a range of  +/- 10 percentage points requires a sample size of at least 1000 particles.

 

How to cite: Riemer, N., Gasparik, J., Ye, Q., West, M., Curtis, J., Sullivan, R., and Presto, A.: How many particles do we need to measure aerosol mixing state?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6132, https://doi.org/10.5194/egusphere-egu2020-6132, 2020.

EGU2020-18016 | Displays | AS3.1

Characterization of an improved PTR3 mass spectrometer for the detection of highly oxidized aerosol precursors

Markus Sebastian Leiminger, Tobias Reinecke, Markus Müller, Stefan Feil, Philipp Sulzer, and Alfons Jordan

The recently introduced PTR3-TOF mass spectrometer (Proton Transfer Reaction Time-Of-Flight) allows for a direct and quantitative detection of volatile organic compounds (VOC) and their oxidation products. With a design of the inlet system and the ionization chamber that allows analyte transfer with virtually no wall interactions, organics ranging from volatile to extremely low volatility (ELVOC) can be measured, even at ambient temperature. In addition, PTR3 has recently shown to detect and quantify RO2 radicals. Unlike the traditional PTR-MS ionization technique, the PTR3 is operated at an elevated reaction pressure of 50 to 80 mbar while reaction kinetics are precisely defined via radial electric fields emitted from a tripole ion guide. With this setup, outstanding sensitivities of more than 30,000 cps/ppbV are achieved.

Herein, we present an improved version of a PTR3-TOF instrument. The inlet comprises three cylindrically arranged ion sources allowing for fast electrical switching between a set of reagent ions including H3O+, NO+, O2+ and NH4+. The tripole geometry is aerodynamically improved to further reduce surface interactions. Extraction of analyte ions from the PTR3 ionization chamber and subsequent transfer to the TOF mass analyzer is now enhanced by an ion booster in series to a hexapole ion guide. This setup enables a precise control of extraction energies to reduce unwanted collision induced fragmentation and at the same time efficiently transmits ions of a broad m/z range. Analyte ions are analyzed with a high-resolution Time-Of-Flight mass spectrometer achieving mass resolving powers of typically 13,000 to 15,000.

We have characterized the performance of this optimized PTR3-TOF instrument using pure chemical compounds of intermediate to low volatility, including carboxylic acids and peroxides. Hereby, the effects of PTR3 reaction conditions and ion extraction settings are studied. Monoterpene ozonolysis experiments demonstrate the performance in detecting aerosol precursors from intermediate to extremely low volatility. These new insights in gas phase chemistry are further combined with particle phase measurements conducted with a CHARON PTR-MS to emphasize the analytical capabilities of the PTR3.

How to cite: Leiminger, M. S., Reinecke, T., Müller, M., Feil, S., Sulzer, P., and Jordan, A.: Characterization of an improved PTR3 mass spectrometer for the detection of highly oxidized aerosol precursors, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18016, https://doi.org/10.5194/egusphere-egu2020-18016, 2020.

EGU2020-19635 | Displays | AS3.1

Chemical Characterization of Particulate and Volatile Organic Compounds in the Rural Wintertime Atmosphere by CHARON PTR-ToF-MS

Armin Wisthaler, Markus Müller, Laurent Poulain, Felix Piel, Ricarda Gräfe, Gerald Spindler, Alfred Wiedensohler, and Hartmut Herrmann

We have shown in previous work that Proton-Transfer-Reaction Time-of-Flight Mass Spectrometry (PTR-ToF-MS) in combination with the “Chemical Analysis of Aerosol Online" (CHARON) inlet is a powerful tool for direct and online analysis of sub-µm particulate organic matter in the urban atmosphere. Herein, we report on the first CHARON PTR-ToF-MS measurements in the continental background environment, at the TROPOS Research Station in Melpitz near Leipzig (Germany) during a three week period in February 2019.

A state-of-the-art CHARON PTR-TOF 6000X2 instrument (IONICON Analytik GmbH, Austria) was used for measuring particulate organic compounds online (i.e., without filter pre-collection) and in real-time (< 1-min time resolution), at sub-ng m-3 mass concentrations, and on an elementary composition level. Periodic switching between the standard PTR-MS gas-phase inlet and the CHARON particle inlet made it possible to comprehensively measure atmospheric organic matter in both the gaseous and particulate state at a time resolution of 10 minutes. In addition, an aerosol mass spectrometer (HR-TOF-AMS) and an aerosol chemical speciation monitor (ACSM; both Aerodyne Inc., USA) were deployed for monitoring the composition of non-refractory particulate matter. A Dual Mobility Particle Size Spectrometer (TROPOS-type T-MPSS) was used for determining the total particle size distribution. In addition, particles were collected on filters once per day and analysed offline in the laboratory.

The CHARON PTR-TOF 6000X2 instrument operated stably and reliably over the three week measurement period. Our data show that a single instrument can be used for characterizing both gaseous and particle-bound organic matter in the atmosphere at 10 minute time resolution. The obtained data agree well with ACSM, HR-TOF-AMS and T-MPSS results. A comparison with the offline results obtained from the filter samples confirmed that the CHARON PTR-ToF-MS technique accurately measures the atmospheric concentrations of selected anhydrosugars and polycyclic aromatic hydrocarbons (PAHs). We also show that CHARON PTR-ToF-MS data are useful for improving the source apportionment of particles via positive matrix factorization (PMF).

This work is part of a project that has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 654109 (ACTRIS-2). F. P. has received funding through the EU's Horizon 2020 programme under grant agreement Nº674911 (IMPACT). 

How to cite: Wisthaler, A., Müller, M., Poulain, L., Piel, F., Gräfe, R., Spindler, G., Wiedensohler, A., and Herrmann, H.: Chemical Characterization of Particulate and Volatile Organic Compounds in the Rural Wintertime Atmosphere by CHARON PTR-ToF-MS, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19635, https://doi.org/10.5194/egusphere-egu2020-19635, 2020.

Oxidized and highly oxidized organic molecules are important target analytes in atmospheric air samples. In recent years, several chemical ionization mass spectrometry (CIMS) methods have been developed for detecting these target analytes in real time and at ultra-trace levels. One of these CIMS techniques is proton-transfer-reaction mass spectrometry (PTR-MS), which, in combination with the so-called CHARON inlet, measures oxidized and highly oxidized organic molecules in the atmosphere in the gaseous and particulate state. PTR-MS typically uses hydronium ions (H3O+) as reagent ions for detecting organic analytes in their protonated form, [A+H+]. H3O+ ions react with all oxidized organics at unit efficiency, meaning that PTR-MS universally detects these target analytes, with little dependency of the signal response on their oxidation state. A drawback of PTR-MS operation in the H3O+ mode is that oxidized functional groups are often ejected upon protonation.

Herein, we present the results obtained when a CHARON PTR-MS analyzer was operated with ammonium (NH4+) ions as CI reagent ions. We studied the instrumental response to a set of oxidized and highly oxidized compounds including hydroxy, carboxy and peroxy functional groups. We found that fragmentation was greatly suppressed, with ammonium adducts, [A+NH4]+, being the main analyte ions formed. The ionization efficiency ranged from 10 to 80% of the collisional limit, meaning that the NH4+ mode is less quantitative than the H3O+ mode. The performance and advantages of ammonium adduct ionization are demonstrated on two application examples: i) secondary organic aerosol generated in the laboratory from the ozonolysis of limonene, with a particular focus on the detection of peroxides and dimers, and (ii) ambient organic aerosol in Innsbruck, Austria, which was characterized at the molecular level at single digit ng m-³ mass concentrations.

How to cite: Müller, M., Piel, F., and Wisthaler, A.: On the detection of oxidized and highly oxidized organic molecules by CHARON PTR-MS via ammonium adduct ionization, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4471, https://doi.org/10.5194/egusphere-egu2020-4471, 2020.

EGU2020-16571 | Displays | AS3.1

The connection of atmospheric new particle formation to fair-weather Earth-atmosphere electric field

Xuemeng Chen, Susana Barbosa, Antti Mäkelä, Jussi Paatero, Catarina Monteiro, Diana Guimarães, Heikki Junninen, Tuukka Petäjä, and Markku Kulmala

Atmospheric new particle formation (NPF) generates secondary aerosol particles into the lower atmosphere via gas-to-particle phase transition. Secondary aerosol particles dominate the total particle number concentration and are an important source for cloud condensation nuclei [1]. NPF typically begins with clustering among gaseous molecules. Once the newly formed clusters attain a size larger than the critical cluster size (~1.5 nm), their growth to larger sizes is energetically favoured and eventually they become nanoparticles [2]. NPF is often observed with the participation of air ions [3] and sometimes is induced by ions [4]. Air ions are a constituent of atmospheric electricity. The presence of the Earth-atmosphere electric field poses an electrical force on air ions. The earth-atmosphere electric field exhibits variability at different time scales under fair-weather conditions [5]. It is therefore interesting to understand whether the Earth-atmosphere electric field influences atmospheric new particle formation.

We analysed the Earth-atmosphere electric field together with the number size distribution data of air ions and aerosol particles under fair-weather conditions measured at Hyytiälä SMEAR II station in Southern Finland [6]. The electric field were measured by two Campbell CS 110 field mills in parallel. Air ion data were obtained with a Balance Scanning Mobility Analyser (BSMA) and a Neutral and Air Ion Spectrometer (NAIS), and aerosol particle data with a Differential Mobility Particle Sizer (DMPS). We used condensation Sinks (CS) derived from the DMPS measurement, air temperature, relative humidity, wind speed, global radiation as well as brightness derived from the global radiation measurement to assist the analysis. The measured earth-atmosphere electric field on NPF days was higher than on non-NPF days. We found that under low CS conditions, the electric field can enhance the formation of 1.7-3 nm air ions, but the concentration of 1.7-3 nm ions decreased with an increasing electric field under high CS conditions.

References:

[1]       Kerminen V.-M. et al., Environ. Res. Lett. 2018, 13, 103003.

[2]       Kulmala M. et al., Science 2013, 339, 943-946.

[3]       Manninen H. E. et al., Atmos. Chem. Phys. 2010, 10, 7907-7927.

[4]       Jokinen T. et al., Science Advances 2018, 4, eaat9744.

[5]       Bennett A. J., Harrison R. G., Journal of Physics: Conference Series 2008, 142, 012046.

[6]       Hari P., Kulmala M., Boreal Environ. Res. 2005, 10, 315-322.

How to cite: Chen, X., Barbosa, S., Mäkelä, A., Paatero, J., Monteiro, C., Guimarães, D., Junninen, H., Petäjä, T., and Kulmala, M.: The connection of atmospheric new particle formation to fair-weather Earth-atmosphere electric field, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16571, https://doi.org/10.5194/egusphere-egu2020-16571, 2020.

Organic carbon (OC) and elemental carbon (EC) in PM2.5 were measured with Sunset Laboratory Model-5 Semi-Continuous OC/EC Field Analyzer at Anmyeondo Global Atmosphere Watch (GAW) Regional Station (37°32´N, 127°19´E) in July and August, 2017. It employs TOT (Thermal-Optical-Transmittance) method. The mean values of OC and EC were 3.7 μg m-3 and 0.7 μg m-3, respectively. During the study period, the concentrations of reactive gases and aerosol species were evidently lower than those of other seasons. It is mostly due to meteorological setting of the northeast Asia, where the influence of continental outflow is at its minimum during this season under southwesterly wind. While the diurnal variation of OC and EC were not clear, the concentrations of O3, CO, NOx, SO2, and CO2 were evidently enhanced under easterly wind at night from 20:00 to 8:00. However, the high concentration of EC was observed concurrently with CO and NOx under northerly wind during 20:00 ~ 24:00. It indicates the influence of thermal power plant and industrial facilities, which was recognized as a major emission source during KORUS-AQ campaign. The diurnal variation of O3 clearly showed the influence of land-sea breeze, in which O3 concentration was enhanced with OC in sea-breeze. OC concentration was relatively high, compared to those Seoul. This study suggests that in general, Anmyeondo station serves well as a background monitoring station. However, the variation in meteorological condition is so dynamic that it is primary factor to determine the concentrations of secondary species as well as primary pollutants at Anmyeondo station.

 

How to cite: Ham, J.: PM2.5 organic carbon (OC) and elemental carbon (EC) of summer monsoon season observed at the Anmyeondo Global Atmosphere Watch (GAW) Regional Station, South Korea , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-946, https://doi.org/10.5194/egusphere-egu2020-946, 2020.

EGU2020-1700 | Displays | AS3.1

Cluster dynamics in different environments: from the boreal forest to megacities

Dominik Stolzenburg, Runlong Cai, Lauri Ahonen, Tiia Laurila, Sebastian Holm, Jenni Kontkanen, and Juha Kangasluoma

New particle formation (NPF) by gas-to-particle conversion occurs frequently in many different environments around the globe (Nieminen et al., 2018). NPF is the major contributor to the global cloud condensation nuclei budget (Gordon et al., 2017) and also impacts urban air quality (Guo et al., 2014). It is therefore crucial to understand how the newly formed particles can survive and grow to larger particles under different environmental conditions. Depending on the environment different condensable vapours and also different aerosol dynamics govern the NPF process.

In order to investigate the dynamics of aerosol growth in the sub-10 nm regime, where the newly formed particles are most vulnerable for losses to pre-existing aerosol, we tested several combining instrument inversion approaches. This allows to combine the measurements of several different particle sizing instruments in the sub-10 nm range, where each instrument offers different benefits and weaknesses. If the instruments are combined during the inversion, this could significantly reduce the error of the inferred particle size-distributions. Model results show that the regularization approach proposed by Wolfenbarger and Seinfeld (1990) yield the most stable inversion for data heavily influenced by measurement errors.

We than apply the tested inversion techniques to measurements in three different environments where an array of different state-of-the-art sub-10 nm sizing instruments was deployed: The SMEAR-II station in Hyytiälä, Finland, representative for a rural boreal forest background site, the SMEAR-III station in Helsinki, Finland, representative for a medium-polluted middle-scale European city, and at the Beijing University of Chemical Technology, China, an urban site in a global megacity.

We demonstrate that the combining instrument approach can enable a more detailed analysis of the cluster dynamics, e.g. by the application of size- and time resolving growth rate analysis tools (Pichelstorfer et al., 2018). This will lead to a better understanding of the role of coagulation and condensation in the particle growth process and will help to explain the different dynamics which lead to NPF in fundamentally different environments.

References:

Gordon, H. et al.: Causes and importance of new particle formation in the present-day and preindustrial atmospheres, J. Geophys. Res.-Atmos., 122, doi:10.1002/2017JD026844, 2017.

Guo, S. et al.: Elucidating severe urban haze formation in China, P. Nat. Acad. Sci. USA, 111(49), 17373 LP – 17378, doi:10.1073/pnas.1419604111, 2014.

Nieminen, T. et al.: Global analysis of continental boundary layer new particle formation based on long-term measurements, Atmos. Chem. Phys., (April), 1–34, doi:10.5194/acp-2018-304, 2018.

Pichelstorfer, L et al.: Resolving nanoparticle growth mechanisms from size- and time-dependent growth rate analysis, Atmos. Chem. Phys., 18(2), 1307–1323, doi:10.5194/acp-18-1307-2018, 2018.

Wolfenbarger, J. K. and Seinfeld, J. H.: Inversion of aerosol size distribution data, J. Aerosol Sci., 21(2), 227–247, doi:https://doi.org/10.1016/0021-8502(90)90007-K, 1990.

How to cite: Stolzenburg, D., Cai, R., Ahonen, L., Laurila, T., Holm, S., Kontkanen, J., and Kangasluoma, J.: Cluster dynamics in different environments: from the boreal forest to megacities, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1700, https://doi.org/10.5194/egusphere-egu2020-1700, 2020.

EGU2020-3349 | Displays | AS3.1

Bias in CMIP6 models compared to observed regional dimming and brightening trends (1961-2014)

Kine Onsum Moseid, Michael Schulz, Trude Storelvmo, Ingeborg Rian Julsrud, Dirk Olivié, Pierre Nabat, Martin Wild, Jason N. S. Cole, and Toshihiko Takemura

Anthropogenic aerosol emissions have increased considerably over the last century, but climate effects and quantification of the emissions are highly uncertain as one goes back in time. This uncertainty is partly due to a lack of observations in the pre-satellite era, and previous studies show that Earth system models (ESMs) do not adequately represent surface energy fluxes over the historical era. We investigated global and regional aerosol effects over the time period 1961-2014 by looking at surface downwelling shortwave radiation (SDSR).
We used observations from ground stations as well as multiple experiments from five ESMs participating in the Coupled Model Intercomparison Project Version 6 (CMIP6). Our results show that this subset of models reproduces the observed transient SDSR well in Europe, but poorly in China. 
The models do not reproduce the observed trend reversal in SDSR in China in the late 1980s, which is attributed to a change in the emission of SO2 in this region. The emissions of SO2 show no sign of a trend reversal that could explain the observed SDSR evolution over China, and neither do other aerosols relevant to SDSR. The results from various aerosol emission perturbation experiments from DAMIP, RFMIP and AerChemMIP suggest that its likely, that aerosol effects are responsible for the dimming signal, although not its full amplitude. Simulated cloud cover changes in the different models are not correlated with observed changes over China.  Therefore we suggest that the discrepancy between modeled and observed SDSR evolution is partly caused by erroneous aerosol and aerosol precursor emission inventories. This is an important finding as it may help interpreting whether ESMs reproduce the historical climate evolution for the right or wrong reason.

How to cite: Moseid, K. O., Schulz, M., Storelvmo, T., Julsrud, I. R., Olivié, D., Nabat, P., Wild, M., Cole, J. N. S., and Takemura, T.: Bias in CMIP6 models compared to observed regional dimming and brightening trends (1961-2014), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3349, https://doi.org/10.5194/egusphere-egu2020-3349, 2020.

EGU2020-3469 | Displays | AS3.1

Seasonal changes in stable nitrogen isotopic composition in fine aerosols at a rural background station Košetice (Central Europe).

Petr Vodička, Kimitaka Kawamura, Jaroslav Schwarz, Bhagawati Kunwar, and Vladimír Ždímal

The stable nitrogen isotope ratios (δ15N) of total nitrogen (TN) were studied for fine aerosol particles (PM1) collected with a 24-h time resolution every two days at a Central European rural background site from September 27, 2013, to August 9, 2014 (n=146).
We observed a seasonal cycle of enrichment and depletion of 15N in aerosol particles with lower values in winter and higher values in summer. The majority of the yearly data showed a strong correlation between δ15N and ambient temperature, supporting an enrichment of 15N via isotopic equilibrium exchange between the gas and particulate phases. This process seemed to be one of the main mechanisms for 15N enrichment at the Košetice site, especially during spring. The most 15N-enriched summer and most 15N-depleted winter samples were limited by the partitioning of nitrate in aerosols and suppressed equilibrium exchange between gaseous NH3 and aerosol NH4+. During winter, we observed an event with the lowest δ15N values which deviate from temperature dependence. The winter event was connected with prevailing southeast winds and the lowest δ15N values were probably associated with agriculture emissions of NH3 under low-temperature conditions (<0°C).

Acknowledgement:
This conference contribution was supported by the Ministry of Education, Youth and Sports of the Czech Republic under the project No. LM2018122, by the ERDF project "ACTRIS-CZ RI" (No. CZ.02.1.01/0.0/0.0/16_013/0001315) and by the Japan Society for the Promotion of Science (JSPS) through Grant-in-Aid No. 24221001. We appreciate the financial support of JSPS fellowship to P. Vodička (P16760) in Japan.

Reference:
Vodička, P., Kawamura, K., Schwarz, J., Kunwar, B. and Ždímal, V.: Seasonal study of stable carbon and nitrogen isotopic composition in fine aerosols at a Central European rural background station, Atmos. Chem. Phys., 19, 3463–3479, 2019.

How to cite: Vodička, P., Kawamura, K., Schwarz, J., Kunwar, B., and Ždímal, V.: Seasonal changes in stable nitrogen isotopic composition in fine aerosols at a rural background station Košetice (Central Europe)., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3469, https://doi.org/10.5194/egusphere-egu2020-3469, 2020.

EGU2020-3431 | Displays | AS3.1

Primary Organic Aerosol Source Identification and Aging Observed by Hourly Measurements of Organic Molecular Markers in Urban Shanghai, China

Qiongqiong Wang, Xiao He, Min Zhou, Dandan Huang, Liping Qiao, Shuhui Zhu, Ying-ge Ma, Hong-li Wang, Li Li, Cheng Huang, Wen Xu, Douglas Worsnop, Allen H. Goldstein, Hai Guo, and Jian Zhen Yu

Molecular markers in ambient organic aerosol (OA) are valuable in providing source information and insights to formation process of OA. Their traditional quantification is based on offline analysis of filter samples, hugely hindering the utility of the tracer data due to the coarse time resolution and labor-intensive nature. In this study, hourly organic molecular markers in fine particulate matter were measured using a recently commercialized Thermal desorption Aerosol Gas chromatography-mass spectrometry (TAG) at an urban location in Shanghai, China during a three-week campaign from 9 November-3 December 2018. Anhydro sugars, fatty acids, aromatic acids, and polycyclic aromatic hydrocarbons (PAHs) were examined in detail. Their diurnal variations showed characteristic features representing the corresponding emission source activities. For example, stearic acid showed a clear peak around 7 pm, in accordance with the enhanced cooking activities during mealtime. Diagnostic ratios of related maker species of different reactivity provided unique information in uncovering the source information and tracking evolution of OA in the atmosphere. For example, Levo/Manno and Levo/K+ ratio analysis identified crop residue burning as the major form of biomass burning. Ratios of unsaturated and saturated fatty acids gave unambiguous indication of atmospheric degradation of unsaturated fatty acids after emissions. Furthermore, oleic acid to stearic acid ratio was highly correlated with O/C ratios, suggesting the possible utility of oleic acid as a model compound to examine the heterogeneous reaction of cooking-related OA. PAH ratio-ratio plots helped tag varying influences of major combustion sources associated with air masses of different origins, with coal combustion and biomass burning dominant under the influence of long range transport air mass and vehicle emissions dominant under local/median range air mass influence. This study demonstrated the utility of the hourly organic markers in capturing the dynamic change of the source emissions and atmospheric ageing, providing observational evidence to support their use in rapid source apportionment.

How to cite: Wang, Q., He, X., Zhou, M., Huang, D., Qiao, L., Zhu, S., Ma, Y., Wang, H., Li, L., Huang, C., Xu, W., Worsnop, D., Goldstein, A. H., Guo, H., and Yu, J. Z.: Primary Organic Aerosol Source Identification and Aging Observed by Hourly Measurements of Organic Molecular Markers in Urban Shanghai, China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3431, https://doi.org/10.5194/egusphere-egu2020-3431, 2020.

EGU2020-3722 | Displays | AS3.1

Laboratory Measurements of the Size Distribution and Activation Ratio of Synthetic Ice Nuclei

David Delene, Eli Peske, Mascha Rauscher, and Werner Lubitz

Laboratory measurement of the particle size distribution and cloud condensation nucleation activation ratio are conducted using two types of synthetic ice nuclei (IN). New Engineered Organic Nuclei (NEON) are fabricated by fermentation and so-called E-lysis of Gram-negative bacteria, which are havested via centrifugation and resuspended in a NaHCO3 buffer (pH of ~7.8) for final inactivation of lysis escape muntants. NEON is inactivated using 1.25 % (final concentration) glutaraldehyde (GA) and stored in a deep freezer. The NEON with GA solution is atomized using a Sparging Liquid Aerosol Generator (SLAG), which does not sheer or impact the aerosols. The measured size distribution is compared to aerosols produced by the TSI Atmomizer (Model 3076), which impacts generated droplets. The size distribution is measured using a TSI Scanning Mobility Particle Sizer Spectrometer (SMPS) and a TSI Aerodynamic Particle Sizer. A DMT Cloud Condensation Nuclei Counter (CCNC) operated at 0.6 % supersaturation and a TSI Condensation Particle Counter (CPC) is used to measure the activation ratio, which is important to determine effectiveness of the NEON as an immersion ice nuclei. The NEON results are compared to IN produced by burning silver iodine cloud seeding flares.

How to cite: Delene, D., Peske, E., Rauscher, M., and Lubitz, W.: Laboratory Measurements of the Size Distribution and Activation Ratio of Synthetic Ice Nuclei, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3722, https://doi.org/10.5194/egusphere-egu2020-3722, 2020.

Benefited from the tightening emissions of air pollutants, a large annual decrease in mixing ratio of SO2 and a moderate decrease in PM2.5 can be identified in northern China since 2014. However, a few extreme PM2.5 pollution events still occur for sometimes during heating seasons, e.g., the 99th percentile value of PM2.5 concentrations during the heating season in 2018 had exceeded 200 µg m-3 therein. One unit of percentile value corresponds to approximately 30 hours. To reveal real causes of these extreme PM2.5 pollution events, we define two technical terms in this study, i.e., 1) secondary particulate species formed in ambient air (conventionally-defined FSPM); 2) formation of secondary particulate matter in the fresh plumes during the initial several minutes (plume-processed FSPM). We also introduce a metric, i.e., PM2.5/CO in unit of µg m-3 / ppm. With these technical terms in mind, we then struggle to dissect real mechanisms causing the severe PM2.5 pollution event in 11-14 January 2019 across norther China. A staircase function of ratios of PM2.5/CO against PM2.5 rather than a linear increase or decrease with PM2.5 generally occurred through the event. However, in general, larger ratios of PM2.5/CO were indeed observed with larger concentration of PM2.5. Regarding frequently observed invariant ratios accompanying with large variations in PM2.5, larger ratios are, however, probably not caused by conventionally-defined FSPM in PM2.5. Alternatively, our further multiple-technical analysis results confirm plume-processed FSPM, followed by accumulation under poor meteorological conditions, dominatingly resulting in the severe event. 

How to cite: Yao, X., Zhu, Y., and Meng, H.: Small contribution of conventionally-defined formation of secondary particulate matter to severe PM2.5 pollution in today’s northern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4556, https://doi.org/10.5194/egusphere-egu2020-4556, 2020.

EGU2020-5064 | Displays | AS3.1

Real neutralization reactions of amines against ammonia by acids in ambient air

Dihui Chen, Yujiao Zhu, Yanjie Shen, and Xiaohong Yao

Amines reportedly overwhelm ammonia in generating new particles through neutralizing sulfuric acid vapor even with several orders smaller concentrations of amines against ammonia in ambient air, demonstrating an attractive prospect in adjusting concentrations of amines to adjust aerosol number loadings, alleviate air pollution and manipulate aerosol cooling effects. Due to lack of in-situ observations, real competition of amines against ammonia in ambient air to be neutralized by acids remains poorly understood. Here, successful semi-continuous measurements of gaseous amines and ammonia and their particulate partners in marine atmospheres reveal that atmospheric trimethylamine (TMAgas) unable to compete with NH3gas and to form particulate trimethylaminium (TMAH+), but the particulate TMA (TMAparticulate) is detectable and comparable to TMAgas under NH3gas <1.0 µg m-3. Contradictory to the common knowledge, the preexisting TMAparticulate is largely depleted in strong SO2 plumes with abundant acids and even depleted NH3gas. A two-aerosol-phase transfer concept model is proposed to interpret the new findings, but no single-phase acid-base neutralization reactions can. In contrast, observational evidences confirm that gaseous dimethylamine (DMAgas) plus particulate dimethylaminium (DMAH+) overwhelmingly exist as DMAH+ under atmospheric NH3 (NH3gas) <0.3 µg m-3 versus DMAgas under NH3gas >1.8 µg m-3, respectively. The neutralization of DMAgas to form DMAH+ is always enhanced in strong SO2 plumes, almost independent on NH3gas. Thermodynamically, DMAgas may act as a competitor in generating secondary particles only under low NH3gas or in SO2 plumes.

How to cite: Chen, D., Zhu, Y., Shen, Y., and Yao, X.: Real neutralization reactions of amines against ammonia by acids in ambient air, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5064, https://doi.org/10.5194/egusphere-egu2020-5064, 2020.

EGU2020-5152 | Displays | AS3.1

New Particle Formation Involving Charged Sulfuric Acid – Ammonia Clusters

Vitus Besel, Jakub Kubečka, Theo Kurtén, and Hanna Vehkamäki

The bulk of aerosol particles in the atmosphere are formed by gas-to-particle nucleation (Merikanto et al., 2009). However, the exact process of single molecules forming cluster, which subsequently can grow into particles, remains largely unknown. Recently, sulfuric acid has been identified to play a key role in this new particle formation enhanced by other compounds such as organic acids (Zhang, 2010) or ammonia (Anttila et al., 2005). To identify the characteristics of cluster formation and nucleation involving sulfuric acid and ammonia in neutral, positive and negative modes, we conducted a computational study. We used a layered approach for configurational sampling of the molecular clusters starting from utilizing a genetic algorithm in order to explore the whole potential energy surface (PES) with all plausible geometrical minima, however, with very unreliable energies. The structures were further optimized with a semi-empirical method and, then, at the ωB97X-D DFT level of theory. After each step, the optimized geometries were filtered to obtain the global minimum configuration. Further, a high level of theory (DLPNO-CCSD(T)) was used for obtaining the electronic energies, in addition to performing DFT frequency analysis, to calculate the Gibbs free energies of formation. These were passed to the Atmospheric Cluster Dynamics Code (ACDC) (McGrath et al., 2012) for studying the evolution of cluster populations. We determined the global minima for the following sulfuric acid - ammonia clusters: (H2SO4)m(NH3)n with m=n, m=n+1 and n=m+1 for neutral clusters, (H2SO4)m(HSO4)(NH3)n with m=n and n=m+1 for positively charged clusters, and (H2SO4)m(NH4)+(NH3)n with m=n and m=n+1 for negatively charged clusters. Further, we present the formation rates, steady state concentrations and fluxes of these clusters calculated using ACDC and discuss how a new configurational sampling procedure, more precise quantum chemistry methods and parameters, such as symmetry and a quasiharmonic approach, impact these ACDC results in comparison to previous studies.

References:
J. Merikanto, D. V. Spracklen, G. W. Mann, S. J. Pickering, and K. S. Carslaw (2009). Atmos. Chem.  Phys., 9, 8601-8616.
R. Zhang (2010). Science, 328, 1366-1367.
T. Anttila, H. Vehkamäki, I. Napari, M. Kulmala (2005). Boreal Env. Res., 10, 523.
M.J. McGrath, T. Olenius, I.K. Ortega, V. Loukonen, P.  Paasonen, T. Kurten, M. Kulmala (2012). Atmos. Chem. Phys., 12, 2355.

How to cite: Besel, V., Kubečka, J., Kurtén, T., and Vehkamäki, H.: New Particle Formation Involving Charged Sulfuric Acid – Ammonia Clusters , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5152, https://doi.org/10.5194/egusphere-egu2020-5152, 2020.

EGU2020-5727 | Displays | AS3.1

Oxidative Potential of PM2.5 in Dammam, Saudi Arabia, and the effect of dust storms.

Manna Alwadei, Steven Thomson, Louisa Kramer, Zongbo Shi, and William Bloss

The ability of particulate matter (PM) to generate reactive oxygen species and induce oxidative stress in human body is known as oxidative potential (OP). OP is considered an important indicator of the toxicity of PM, which is associated with adverse health impacts. Linking the predicted health impacts of aerosols to OP may be more relevant than considering PM mass only. In this study, we determined the OP of PM2.5 (PM with aerodynamic diameter less than 2.5 µm) in Dammam, Saudi Arabia, in order to understand the relationship of OP to PM mass and composition in the present and absent of dust storm.
PM2.5 was collected from two locations in Dammam city in the winter and summer of 2018. The first location was the city centre as an urban area while the second one was in the campus of Imam Abdulrahman Bin Faisal University as an urban background area. OP was quantified using dithiothreitol (DTT) assay. The mean PM2.5 mass in the summer (120.5 µg/m3) was nearly  twice that in the winter (62.6 µg/m3). The average OP activity per air volume (DDTv) in the winter was 1.14 nmol min-1 m-3 while in the summer it was 1.77 nmol min-1 m-3. Conversely, the mean OP activity per PM mass (DDTm) in the winter was 24.56 pmol min-1 µg-3 while it was lower in the summer at 17.3 pmol min-1 µg-3. Results showed an inverse correlation between PM mass and DDTm, while there was a positive correlation between PM mass and DDTv. Even though the average mass of PM2.5 in the summer was almost twice that in the winter, the average DDTm was lower in the summer compared to winter. This is due to the much lower oxidative potential in dust storm particles, which contribute significantly to the summertime PM2.5. Our results suggest that OP is driven by PM composition rather than mass. 

 

How to cite: Alwadei, M., Thomson, S., Kramer, L., Shi, Z., and Bloss, W.: Oxidative Potential of PM2.5 in Dammam, Saudi Arabia, and the effect of dust storms., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5727, https://doi.org/10.5194/egusphere-egu2020-5727, 2020.

EGU2020-6259 | Displays | AS3.1

Chemical composition and light absorption of brown carbon emitted from residential coal combustion in China

Jianzhong Song, Meiju Li, Xingjun Fan, and Peng'an Peng

Brown carbon (BrC) is a type of light-absorbing organic compounds with a high capacity to absorb light in the low-wavelength visible and near-ultraviolet regions, which is ubiquitous in atmospheric aerosols, rainwater, and cloudwater samples. BrC can not only alter the light absorption and radiative forcing of aerosols but can also influence the formation of cloud condensation nuclei; therefore, it has a potential impact on atmospheric chemistry and climate change. Numerous studies have demonstrated that combustion processes are significant sources of atmospheric BrC, however most of these studies were focused on the emissions of biomass burning. Knowledge of primary BrC from coal combustion is still limited. In the study, smoke particles emitted from the combustion of residential coals with different geological maturity were collected in a combustion system. Then BrC fractions, including water soluble organic carbon (WSOC), water soluble humic-like substances (HULISw), alkaline soluble organic carbon (ASOC) and methanol soluble organic carbon (MSOC) were extracted and characterized for their abundances, chemical, and light absorption properties.

 

Our results showed that the abundance and light absorption of the coal combustion-derived BrC fractions were strongly dependent on the extraction methods used and the coal maturity. The abundances of MSOC fraction was significantly higher than WSOC and ASOC fractions and even higher than the sum of WSOC and ASOC, indicating that most organic compounds in smoke particles were soluble in pure methanol. The WSOC and MSOC fractions from the combustion of low maturity coal had relatively low SUVA254 and MAE365 values, indicated that they had relatively low levels of aromatic structures and light absorption.

 

The WSOC and MSOC fractions were characterized by ultrahigh-resolution mass spectrometry. The results showed that S-containing compounds (CHOS and CHONS) are found to be the dominant components of the WSOC, whereas CHO and CHON compounds make a great contribution to the MSOC samples. Noted that a greater abundance of S-containing compounds was found in the smoke produced from coal combustion compared to biomass burning and atmospheric samples, indicated that coal combustion could be an important source of atmospheric S-containing compounds in certain areas. The findings also suggest that organic molecules with a high aromaticity index and low polarity showed stronger light absorption. In summary, our study indicated that coal combustion is a potential source of atmospheric BrC and their abundance, chemical, and light absorption were strongly dependent on the extraction methods used and the coal maturity.

How to cite: Song, J., Li, M., Fan, X., and Peng, P.: Chemical composition and light absorption of brown carbon emitted from residential coal combustion in China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6259, https://doi.org/10.5194/egusphere-egu2020-6259, 2020.

EGU2020-6530 | Displays | AS3.1

New particle formation characteristics in the Arctic (Zeppelin, Svalbard)

Haebum Lee, KwangYul Lee, Radovan Krejci, Wenche Aas, Jiyeon Park, Ki-tae Park, Bang Yong Lee, Young-Jun Yoon, and Kihong Park

Continuous measurement of atmospheric nanoparticles down to 3 nm was conducted in the Arctic (Zeppelin) from Oct 2016 to Dec 2018. The measured size distributions of particles from 3 nm to 60 nm were classified into distinct clusters with mode diameters of 10 nm (cluster 1), 20 nm (cluster 2), 30 nm (cluster 3), and 50 nm (cluster 4). Cluster 1 includes newly formed particles with high population which was often observed in summer season. A significant amount of nanoparticles down to 3 nm often appeared during new particle formation (NPF), suggesting that the NPF happened near the site rather than being transported from other regions after growth. The average NPF occurrence frequency per year was found to be 28%. The particle formation rate (J3-7) for particles in 3 nm to 7 nm was 0.044 cm-3 s-1 on average, ranging from 0.001 to 0.714 cm-3 s-1. The average growth rate (GR3-25) was around 2.62 nm h-1. Even though the NPF occurrence frequency in the Arctic was comparable to other areas (highly or moderately polluted areas), the intensity of NPF events (e.g. J3-7 and GR3-25) was much smaller than other continental areas. The increase of nanoparticles occurred more frequently when the air mass passed over the south and southwest ocean region, and concentration of NH3 increased in the NPF event days compared to non-event days, suggesting that that the marine biogenic and animal sources played important roles in the NPF. The NPF occurrence criteria previously developed was also applicable for the NPF in the Arctic.

How to cite: Lee, H., Lee, K., Krejci, R., Aas, W., Park, J., Park, K., Lee, B. Y., Yoon, Y.-J., and Park, K.: New particle formation characteristics in the Arctic (Zeppelin, Svalbard) , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6530, https://doi.org/10.5194/egusphere-egu2020-6530, 2020.

EGU2020-6702 | Displays | AS3.1

Light absorption properties, chromophore composition and sources of brown carbon aerosol in Xi’an, Northwest China

Ru-Jin Huang, Wei Yuan, Lu Yang, Jie Guo, Jing Duan, and Haiyan Ni

The impact of brown carbon aerosol (BrC) on the Earth’s radiative forcing balance has been widely recognized but remains uncertain, mainly because the relationships among BrC sources, chromophores, and optical properties of aerosol are poorly understood (Feng et al., 2013; Laskin et al., 2015). In this work, the light absorption properties and chromophore composition of BrC were investigated for samples collected in Xi’an, Northwest China from 2015 to 2016. Both absorption Ångström exponent and mass absorption efficiency show distinct seasonal differences, which could be attributed to the differences in sources and chromophore composition of BrC. Three groups of light-absorbing organics were found to be important BrC chromophores, including those show multiple absorption peaks at wavelength > 350 nm (12 polycyclic aromatic hydrocarbons and their derivatives) and those show single absorption peak at wavelength < 350 nm (10 nitrophenols and nitrosalicylic acids and 3 methoxyphenols). These measured BrC chromophores show distinct seasonal differences and contribute on average about 1.1% and 3.3% of light absorption of methanol-soluble BrC at 365 nm in summer and winter, respectively, about 7 and 5 times higher than the corresponding mass fractions in total organic carbon. The sources of BrC were resolved by positive matrix factorization (PMF) using these chromophores instead of commonly used non-light absorbing organic markers as model inputs. Our results show that in spring vehicular emissions and secondary formation are major sources of BrC (~70%), in fall coal combustion and vehicular emissions are major sources (~70%), in winter biomass burning and coal combustion become major sources (~80%), while in summer secondary BrC dominates (~60%).

 

References:

Feng, Y., V. Ramanathan, and V. R. Kotamarthi: Brown carbon: A significant atmospheric absorber of solar radiation?, Atmos. Chem. Phys., 13, 8607-8621, doi:10.5194/acp-13-8607-2013, 2013.

Laskin, A., J. Laskin, and S. A. Nizkorodov: Chemistry of atmospheric brown carbon, Chem. Rev., 115, 4335-4382, doi:10.1021/cr5006167, 2015.

How to cite: Huang, R.-J., Yuan, W., Yang, L., Guo, J., Duan, J., and Ni, H.: Light absorption properties, chromophore composition and sources of brown carbon aerosol in Xi’an, Northwest China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6702, https://doi.org/10.5194/egusphere-egu2020-6702, 2020.

EGU2020-7020 | Displays | AS3.1

Concurrent increases of PM2.5 and Ozone observed in Seoul, May 2019

Jeewon Son, Sunggu Kang, Joo-ae Kim, Junsu Gil, Meehye Lee, Taehyung Lee, Moon-soo Park, and Gookyoung Heo

 In Seoul, PM2.5 concentrations were frequently elevated with O3 in May 2019. The most abundant constituent of PM2.5 was nitrate, which was the best correlated with OC (organic carbon) as well as NH4+. An intensive experiment was conducted in the eastern part of Seoul from March 29 to June 19, 2019. Measurement was made for PM2.5 and its chemical composition including NO3-, SO42-, NH4+ , OC, EC (elemental carbon), and reactive gases including O3, NO, NO2, CO, HONO, HNO3, NH3, and SO2, and meteorological variables including vertical winds and mixed layer height (MLH). The particle number concentration was measured using SMPS (Scanning Mobility Particle Sizer). All measurements were averaged for 1 hour according to the resolution of PM2.5 chemical composition. For the entire experiment, the mean mass concentrations of PM2.5, NO3-, SO42-, NH4+, OC, and EC were 20.40 μg/m3, 4.07 μg/m3, 2.62 μg/m3, 2.01 μg/m3, 4.01 μg/m3, and 1.04 μg/m3, respectively. For reactive gases, the mean concentration was 1.03 ppbv for HONO, 0.70 ppbv for HNO3, 14.87 ppbv for NH3, 2.77 ppbv for SO2, and 48.79 ppbv for O3

 The maximum PM2.5 concentration of 72.81 μg/m3 was observed under the influence of weak Asian dust event in the end of April. In May, there were three distinct episodes with highly enhanced PM2.5. In the early May, the maximum nitrate concentration (36.11 μg/m3) was observed with high HONO (2.41 ppbv) on 4 May. In the middle of May, PM2.5 was raised with SO42- under stagnant condition. On 25 May, PM2.5 was raised up to 92 μg/m3 with high nitrate concentration (18.56 μg/m3) , when O3 reached 205 ppbv. In this episode, O3 concentration remained around 90 ppbv at night and OC and EC were well correlated with highly enhanced K+. Thus, the concurrent enhancement of PM2.5 and O3 was likely due to the influence of aged biomass combustion plume laden air transported from southeast China. At the same time, HNO3 and HONO concentration was highly elevated, indicating that heterogeneous reactions played a role.

How to cite: Son, J., Kang, S., Kim, J., Gil, J., Lee, M., Lee, T., Park, M., and Heo, G.: Concurrent increases of PM2.5 and Ozone observed in Seoul, May 2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7020, https://doi.org/10.5194/egusphere-egu2020-7020, 2020.

EGU2020-7050 | Displays | AS3.1

Nitrate-driven high PM2.5 episodes in Seoul during pre-monsoon season

Joonhyoung Park, Saehee Lim, Meehye Lee, Taehyung Lee, Moon-soo Park, Gookyoung Heo, and Cheol-hee Kim

Ammonium nitrate (NH4NO3) is the main driver of high PM2.5 episodes in Seoul, but its formation processes are not fully understood yet. Intensive experiments were conducted at the Korea University campus in Seoul during June ~ August 2018 and April ~ June 2019, when the chemical composition of PM2.5 including Na+, SO42-, NH3, NO3-, Cl-, Ca2+, K+, Mg2+, OC and EC, and its gaseous precursors including NOX, HNO3 and SO2 were continuously measured. The concentrations of PM2.5 and its major constituents were noticeably higher in pre-monsoon (June) than summer monsoon (July~August) period. In particular, nitrate concentration was much higher (6.9 μg/m3) during the high PM2.5 episode (24-hr average PM2.5 > 35 μg/m3) in June compared to those of non-episode (3.1 μg/m3) and the other two months (0.74 μg/m3). Aerosol liquid water content (ALWC) was calculated using ISORROPIA II model, ALWC was higher during the episode than non-episode and the highest ALWC was found concurrently with the highest NO3- concentration (18.2 μg/m3) at night. Concurrent increases of nitrate and ALWC cause aqueous-phase formation and hygroscopic growth of aerosol, which lead to high PM2.5 concentration. In addition, ALWC was more rapidly increased with the number of accumulation mode particles larger than 100 nm in diameter at higher RH and nitrate concentration. In this study, PM2.5 mass and nitrate were elevated after the NOX peak in the morning as well as at dawn. The surface of pre-existing particles was found to be prerequisite for nitrate driven PM2.5 episode.

How to cite: Park, J., Lim, S., Lee, M., Lee, T., Park, M., Heo, G., and Kim, C.: Nitrate-driven high PM2.5 episodes in Seoul during pre-monsoon season, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7050, https://doi.org/10.5194/egusphere-egu2020-7050, 2020.

EGU2020-7071 | Displays | AS3.1

Characterization of volatile organic compounds (VOCs) in megacity Seoul from multiyear observation

Sunggu Kang, Jeewon Son, Joo-ae Kim, Meehye Lee, and Junbok Lee

Volatile organic compounds (VOCs) are the key precursors of O­3 and secondary organic aerosols in urban atmosphere. This study investigates the variations and emission sources of 55 VOCs observed in central Seoul between 2013 and 2019. VOCs were continuously measured every hour using an online gas chromatography system by the Seoul Metropolitan Government Research Institute of Public Health and Environment (SIHE). The lower limit of detection was 0.1 ppbC and outliers were removed by applying Chauvenet’s criterion.

Of the 55 VOCs, the most abundant species was ethane, followed by propane and toluene and their average concentrations were 6.6 ppbv, 5.9 ppbv and 4.6 ppbv, respectively. In terms of TVOCs, toluene was the most abundant with the average concentration of 32.1 ppbC and comprises about the half of the aromatic VOCs. Alkane and aromatics showed different seasonal, diurnal and weekly variations, and dependence on meteorological variables. In addition, the toluene to benzene ratio was greater in summer than in winter with the average of 11.0. These results indicate the additional sources for VOCs to traffic related emissions in megacity Seoul. The PSCF (Potential Source Contribution Function) and cluster analysis of backward trajectories of air masses indicate that while alkanes are chiefly emitted from vehicles, aromatic concentrations are greatly influenced by fugitive emission from neighboring cities of Seoul. There is also chance for some VOCs with relatively long lifetime to be transported from nearby countries.

How to cite: Kang, S., Son, J., Kim, J., Lee, M., and Lee, J.: Characterization of volatile organic compounds (VOCs) in megacity Seoul from multiyear observation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7071, https://doi.org/10.5194/egusphere-egu2020-7071, 2020.

EGU2020-7118 | Displays | AS3.1

Effects of physical and chemical nonlinearities on evolution of optical properties of biomass burning aerosol

Nikolai Golovushkin, Igor Konovalov, and Matthias Beekmann

Aerosol from open biomass burning (BB) is known to strongly impact the Earth radiation budget. Therefore, a good knowledge of its optical properties and their evolution is an important prerequisite for accurate assessments of contributions of various factors to climate change by means of chemistry-transport and climate models. As a major component of typical BB aerosol is organic matter, the atmospheric evolution of BB aerosol can be strongly affected by the physical and chemical processes governing the gas-particle partitioning of organic compounds. Recently, it has been shown [1] that these processes can give rise to strongly nonlinear behavior of mass concentration of organic fraction of BB aerosol during its atmospheric lifetime. It has been also argued that chemical and physical nonlinearities can explain part of the observed diversity of the effects of BB aerosol atmospheric aging. The present study has extended the previous analysis of the nonlinear behavior of BB aerosol, focusing on the evolution of BB aerosol optical properties, such as, specifically, mass absorption and scattering efficiencies (MAE and MSE) in the near-UV and optical wavelength ranges. The evolution of aerosol in BB plumes was simulated with the MDMOA [1] microphysical box model that involves a schematic parameterization of the dilution process and represents the oxidation and gas-particle partitioning processes within the volatility basis set (VBS) framework. The Mie-theory-based simulations of the optical properties of aging BB aerosol were performed with the OPTSIM module [2] coupled with MDMOA. The simulations show that both MAE and MSE can exhibit strong and diverse changes during BB aerosol evolution mostly due to significant changes in the aerosol particle size distribution. Furthermore, similar to the mass concentration, both MAE and MSC of the aged BB aerosol depend in a nonlinear manner on the initial BB aerosol concentration and the initial size of a smoke plume and are sensitive to the choice of a concrete VBS scheme. The results of this study may have important implications for modeling of radiative effects of BB aerosol with chemistry-transport and climate models and for interpretation of remote observations of BB aerosol.

The study was supported by the Russian Foundation for Basic Research (grant No. 18-05-00911).

References

  1. Konovalov, I. B., Beekmann, M., Golovushkin, N. A., and Andreae, M. O.: Nonlinear behavior of organic aerosol in biomass burning plumes: a microphysical model analysis, Atmos. Chem. Phys., 19, 12091–12119, https://doi.org/10.5194/acp-19-12091-2019, 2019.
  2. Stromatas, S., Turquety, S., Menut, L., Chepfer, H., Péré, J. C., Cesana, G., and Bessagnet, B.: Lidar signal simulation for the evaluation of aerosols in chemistry transport models, Geosci. Model Dev., 5, 1543–1564, https://doi.org/10.5194/gmd-5-1543-2012, 2012.

How to cite: Golovushkin, N., Konovalov, I., and Beekmann, M.: Effects of physical and chemical nonlinearities on evolution of optical properties of biomass burning aerosol, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7118, https://doi.org/10.5194/egusphere-egu2020-7118, 2020.

EGU2020-7202 | Displays | AS3.1

Mixing States of Aerosol Particles in Urban Haze

Shuo Yang, Peter Alpert, Yunzhi Xu, Fengkui Duan, Kebin He, and Markus Ammann

Secondary organic aerosols (SOA) are a large fraction of PM2.5 mass and contribute to extreme haze events, reducing visibility and impairing human health, especially in the Northern China Plain. It has been observed that laboratory generated and field collected SOA material can undergo liquid-liquid phase separation (LLPS), however this has never been directly observed in single ambient aerosol particles. Oligomers are a significant component of atmospheric SOA typically having a molecular mass of >200 g mol-1. These large molecules can be produced via multiphase chemical processes and, when soluble in the aerosol phase, may lead to interesting phase separation behavior.

We conducted a campaign in Beijing during which PM2.5 was analyzed using matrix-assisted laser desorption ionization time of flight mass spectrometry (MALDI-TOF-MS) to observe oligomers at significant quantities. Aerosol particle samples collected before, during and at the peak of a pollution event were targeted. We have evidence that oligomers were the result of multiphase chemistry at high relative humidity. Single particles were probed for chemical morphology and mixing states using X-ray spectro-microscopy to characterize the numbers of particles mixed with inorganic matter, organic matter or soot. Using an environmental microchamber, we subjected single ambient particles to humidity cycles and observed any LLPS to occur. We also quantify the humidity required for LLPS to occur. Our data links oligomeric material having different solubility than e.g. inorganic hygroscopic components with LLPS, giving rise to a clear constraint for urban haze. The results will give statistically significant information about particle mixing state for aerosol population having different oligomer content, humidity history, LLPS behavior and pollution levels.

How to cite: Yang, S., Alpert, P., Xu, Y., Duan, F., He, K., and Ammann, M.: Mixing States of Aerosol Particles in Urban Haze, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7202, https://doi.org/10.5194/egusphere-egu2020-7202, 2020.

In this study, simplified analytic type of expression for size dependent MEs (Mass efficiencies) are developed. The entire size was considered assuming lognormal size distribution for sulfate, nitrate and NaCl aerosol species and the MEE of each aerosol chemical composition was estimated by fitting Mie’s calculation. The obtained results are compared with the results from the Mie-theory-based calculations and showed comparable results.

The mass efficiencies of all aerosol components for each size range are compared with Mie’s results and approximated as a function of geometric mean diameter in the form of a power law formula. Finally, harmonic mean type approximation was used to cover entire particle size range.

Also, analytic expression of approximated scattering enhancement factor which stands for the effect of hygroscopic growth factor for polydispersed aerosol on aerosol optical properties are obtained.

Based on aerosol thermodynamic models, mass growth factor can be obtained and their optical properties can be obtained by using Mie theory with different aerosol properties and size distribution. Finally, scattering enhancement factor was approximated fRH for polydispersed aerosol as a function of RH.

Finally, we also compared the simple forcing efficiency (SFE, W/g) of polydisperse aerosols between the developed simple approach and by the method using the Mie theory. The results show that current obtained approximated methods are comparable with existing numercal calculation based results for polydipersed particle size.

How to cite: Jung, C. H., Lee, J., Um, J., and Kim, Y. P.: Reconstructed expression for aerosol extinction coefficient by considering mass extinction efficiency and hygroscopic growth for polydipersed aerosol, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7475, https://doi.org/10.5194/egusphere-egu2020-7475, 2020.

EGU2020-8743 | Displays | AS3.1

The aging process of ambient black carbon and brown carbon from biomass burning emission during MOYA-2017 aircraft campaign

HuiHui Wu, Jonathan Taylor, Justin Langridge, Chenjie Yu, Paul Williams, Michael Flynn, and Hugh Coe

The biomass burning over West Africa during the dry season (December – February) is a globally significant source of trace gases and carbonaceous aerosol particles in the atmosphere. The MOYA-2017 (Methane Observations Yearly Assessments 2017) campaign were conducted using the UK FAAM Bae-146 airborne research aircraft, to investigate biomass burning emissions in this region. Research sorties were flown out of Senegal, with some flights directly over terrestrial fires and others sampling transported smokes over the Atlantic ocean.

The aircraft was equipped with a variety of aerosol-related instruments to measure submicron aerosol chemical properties (aerosol mass spectrometer, AMS and single-particle soot photometer, SP2) and absorption at different wavelengths (Photoacoustic spectrometer, PAS, measure at 405, 514 and 658 nm). In this study, we focus on the aging process of ambient black carbon (BC) and brown carbon (BrC) from biomass burning, in time scale from (<0.5) h to (9 – 15) h. The transport age of smokes was estimated using Met Office's Numerical Atmospheric-dispersion Modelling Environment (NAME).

The sampled smokes during MOYA-2017 were controlled by flaming-phase combustion. The enhancement ratios of BC with respect to CO ranged from 14 to 26 (ng m–3 / ppbv) at sources. Our measurements show that count and mass median diameters of BC core size were relatively stable, which were around 106 and 190 nm respectively. Average BC coating thickness increased from (1.16 ± 0.03) to (1.71 ± 0.06) after approximately half-day transport. Average absorption angstrom exponents (AAE405-658) increased from (1.1 ± 0.1) to (1.8 ± 0.3), suggesting that BrC contributed little in the very freshly emitted aerosols (<0.5 h) and were formed during aging process. In order to investigate the importance of BrC in this area, we also attributed the measured aerosol absorption into BC and BrC separately. By linking AAE405-658 with organic (OA) composition measured by the AMS, we found that the increasing AAE405-658 is positively correlated with O/C ratio (oxygenation) of the OA. These data indicate that BrC in smokes controlled by flaming combustion is likely to be from the condensation of semi-volatile OA during cooling stage of smokes, and from the aged primary OA or secondary OA formation.

How to cite: Wu, H., Taylor, J., Langridge, J., Yu, C., Williams, P., Flynn, M., and Coe, H.: The aging process of ambient black carbon and brown carbon from biomass burning emission during MOYA-2017 aircraft campaign, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8743, https://doi.org/10.5194/egusphere-egu2020-8743, 2020.

EGU2020-9468 | Displays | AS3.1

Can Particle Size Magnifiers detect HOMs with carbon numbers between C10 and C30?

Wiebke Scholz, Birte Rörup, Markus Leiminger, Gerhard Steiner, Katrianne Lehtipalo, Juha Kangasluoma, and Armin Hansel

The Particle Size Magnifier (PSM, Airmodus) [1] is able to size sub 3 nm particles in mobility diameter. A PSM‘s sensitivity and cutoff size (50% detection efficiency) is usually calibrated only with particles out of metal oxides, e.g. tungsten oxide [2], or with different salt particles [1]. The PSM used in this experiment has a cutoff size for ammonium sulfate particles of 1.3 nm in mobility diameter. Ternary nucleation in the atmospheric boundary layer, however, involves organic molecules. It is therefore questionable, if the inorganic calibration curves of the PSM can be applied to these particles.

In this study we aim to understand the PSM‘s response to purely biogenic particles as well as to highly oxidized molecules (HOMs) with carbon backbones of different sizes (C10-, C15-, C20- and C30-HOMs). We used a flow reactor with a short reaction time of about 9s that allows for undisturbed radical – radical reactions due to negligible wall contacts to quantitatively generate HOMs by ozonolysis of different precursors. Reactants were ozone and either alpha-Pinene (C10H16) or beta-Caryophyllene (C15H24) with and without an OH-scavenger.

A recent study [3] demonstrated, that the ozonolysis of alpha-Pinene produces covalently bound C20-HOMs from self- and cross-reactions of two C10-peroxy radicals. The C30-HOMs are formed equivalently from C15-radicals of beta-Caryophyllene oxidation. This mechanism shows, why the C20- and C30-HOMs increase quadratically, in contrast to the C10- and C15-HOMs, that increase linearly with respective reacted precursor concentrations. Making use of this principle, we are able to show, that already C20-HOMs are detected by the PSM, but with a much smaller detection efficiency than the C30-HOMs, that have an ion mobility diameter of approximately 1.6 nm. Our size-dependent calibration gave a steep sensitivity increase around the particle size of about 1.8 nm mobility diameter for organic particles, showing, that organics are far more difficult to detect than ammonium sulfate particles.

 

[1] J. Vanhanen, J. Mikkilä, K. Lehtipalo, M. Sipilä, H. E. Manninen, E. Siivola, T. Petäjä & M. Kulmala (2011) Particle Size Magnifier for Nano-CN Detection, Aerosol Science and Technology, 45:4, 533-542, DOI: 10.1080702786826.2010.547889

[2] J. Kangasluoma, M. Attoui, H. Junninen, K. Lehtipalo, A. Samodurov, F. Korhonen, N. Sarnela, A. Schmidt-Ott, D. Worsnop, M. Kulmala, T. Petäjä (2015) Sizing of neutral sub 3nm tungsten oxide clusters using Airmodus Particle Size Magnifier, Journal of Aerosol Science, 87, 53-62, DOI: https://doi.org/10.1016/j.jaerosci.2015.05.007

[3] T. Berndt, B. Mentler, W. Scholz, L. Fischer, H. Herrmann, M. Kulmala, A. Hansel (2018) Accretion Product Formation from Ozonolysis and OH Radical Reaction of α-Pinene: Mechanistic Insight and the Influence of Isoprene and Ethylene, Environ. Sci. Technol. 2018, 52, 19, 11069-11077, DOI: https://doi.org/10.1021/acs.est.8b02210

How to cite: Scholz, W., Rörup, B., Leiminger, M., Steiner, G., Lehtipalo, K., Kangasluoma, J., and Hansel, A.: Can Particle Size Magnifiers detect HOMs with carbon numbers between C10 and C30?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9468, https://doi.org/10.5194/egusphere-egu2020-9468, 2020.

EGU2020-9740 | Displays | AS3.1

Combination of aerosol sectional scheme and modal scheme in NorESM: Sensitivities to emissions

Sara Marie Blichner, Moa K. Sporre, Risto Makkonen, and Terje K. Berntsen

Cloud-aerosol interactions give rise to much of the uncertainty in estimates of climate forcing, climate sensitivity and thus also future climate predictions. Furthermore, the modelled concentration of cloud condensation nuclei (CCN) in the past, present and future are highly dependent on the how the models represent new particle formation (NPF) – a process which is both poorly understood theoretically and difficult to model due to its complex nature. Global modellers in particular have to prioritize between theoretical accuracy and keeping computational costs low. A common approach in these models is to use a modal scheme to parameterize the sizedistribution of the aerosols, while sectional schemes are in general considered closer to first principals.

To better capture the dynamics of early growth in the Norwegian Earth System Model (NorESM), we have implemented a sectional scheme for the smallest particles (currently 5 - 39 nm), which proceeds to feed particles into the original modal scheme (Kirkevåg et al, 2018) after growth. The sectional scheme includes two species, H2SO4 and low volatile organics and has 5 bins. The motivation is: (1) In the original scheme in NorESM, newly formed particles are added to the smallest mode which has a number median diameter of 23.6 nm. The survival of particles from NPF (formed at ~4 nm diameter) to this mode is calculated based on Lehtinen et al (2007). Thus it does not take into account dynamics within this size range, i.e. competition for condensing vapours and growth of particles over more than one time step. (2) Including a sectional scheme in this range adds precision for this crucial stage of growth while keeping the computational cost low due to the limited number of species involved (currently 2 in the model). (3) A sectional scheme within this size range is an interesting alternative to a nucleation mode, which is known to have problems with moving particles to larger sizes at the same time as adding newly formed particles.

We present several sensitivity tests which investigate the response of the model to changes in emissions of SO2 and biogenic volatile organic compounds and nucleation parameterizations, with and without the sectional scheme. Our results in particular show that in the globally averaged boundary layer, the sectional scheme drastically reduces the number of particles that survive to the modal scheme compared the original model, while more particles survive in remote regions. On the other hand, the sectional scheme is less sensitive to the choice in NPF/nucleation parameterization. 

References: 

Lehtinen, Kari E. J., Miikka Dal Maso, Markku Kulmala, and Veli-Matti Kerminen. "Estimating Nucleation Rates from Apparent Particle Formation Rates and Vice Versa: Revised Formulation of the Kerminen–Kulmala Equation." Journal of Aerosol Science 38, no. 9 (September 1, 2007): 988–94. https://doi.org/10.1016/j.jaerosci.2007.06.009.

Kirkevåg, A., A. Grini, D. Olivié, Ø. Seland, K. Alterskjær, M. Hummel, I.H.H Karset, A. Lewinschal, X. Liu, R. Makkonen, I. Bethke, J. Griesfeller, M. Schulz and T. Iversen. "A production-tagged aerosol module for Earth system models, OsloAero5.3 – extensions and updates for CAM5.3-Oslo." Geoscientific Model Development 11. no. 10 (October, 2018): 3945--3982. https://doi.org/10.5194/gmd-11-3945-2018

How to cite: Blichner, S. M., Sporre, M. K., Makkonen, R., and Berntsen, T. K.: Combination of aerosol sectional scheme and modal scheme in NorESM: Sensitivities to emissions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9740, https://doi.org/10.5194/egusphere-egu2020-9740, 2020.

EGU2020-10470 | Displays | AS3.1

Interactive Aerosol Feedbacks on Photolysis Rates in the GEM-MACH Air Quality Model for an Athabasca Oil-Sands Modelling Study

Mahtab Majdzadeh, Craig Stroud, Ayodeji Akingunola, Paul Makar, Christopher Sioris, Chris McLinden, Xiaoyi Zhao, Michael Moran, and Ihab Abboud

The radiative transfer module of an on-line chemical transport models requires input data from aerosol extinction efficiency, single scatter albedo and asymmetry factor, in order to predict the radiative state of the atmosphere. These aerosol optical properties (aerosol optical depth, AOD), may be integrated vertically for comparison to satellite observations. These optical effects may also influence the shorter wavelengths associated with atmospheric gas photolysis, influencing atmospheric reactivity. These processes may be harmonized in an on-line reaction transport model, such as Environment and Climate Change Canada’s GEM-MACH (GEM: Global Environmental Multi-scale – MACH: Modelling Air quality and Chemistry). Previous photolysis routine in the radiative transfer module, MESSY-JVAL (Modular Earth Sub-Model System), in GEM-MACH, made use of a climatology of aerosol optical properties, and the previous on-line version made use of a homogeneous mixture Mie code for meteorological radiative transfer calculations.

We calculated a new lookup table for the extinction efficiency, absorption and scattering cross sections of each aerosol type. The new version of MESSY-JVAL uses GEM-MACH predicted aerosol size distributions, chemical composition and relative humidity in each vertical column at each time step as input, reads aerosol absorption and scattering cross section data from the new lookup table and calculates aerosol optical properties, that are then used to modify both photolysis and meteorological radiative transfer calculations.

In order to evaluate these modifications to the model, we performed a series of simulations with GEM-MACH with wildfire emissions inputs from the Canadian Forest Fire Emissions Prediction System (CFFEPS) and compared the model AOD output with satellite and AERONET (Aerosol Robotic Network) measurement data. Comparison of the hourly AERONET and monthly-averaged satellite AOD demonstrates major improvements in the revised model AOD predictions. The impact of the updated photolysis rates and meteorological radiative transfer calculations on predictions of oxidant mixing ratios and rates of pollutant oxidation (nitrogen dioxide conversion to nitric acid) will be assessed both within and below the forest fire plume.

How to cite: Majdzadeh, M., Stroud, C., Akingunola, A., Makar, P., Sioris, C., McLinden, C., Zhao, X., Moran, M., and Abboud, I.: Interactive Aerosol Feedbacks on Photolysis Rates in the GEM-MACH Air Quality Model for an Athabasca Oil-Sands Modelling Study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10470, https://doi.org/10.5194/egusphere-egu2020-10470, 2020.

EGU2020-10700 | Displays | AS3.1

A Study on modification of Aircraft Platform for Air Quality Measurement in Korea

Beom-Keun Seo, Jongho Kim, Soo bog Park, Jeonghun Yu, and Misun Lee

The aircraft measurement for air quality is able to fly in three dimensions within the planetary boundary layer of inland and sea. In this study, the Beechcraft B1900D was modified to build a unique aircraft measurement platform for the measurement of particulate matter and gas. This aircraft has a maximum takeoff weight of 7,765kg and this aircraft is loaded with various air quality measurement equipment. The contents of aircraft modification are as follows. The installed contents for air quality measurement are aircraft aerosol inlets, trace gas inlets, discharge tubes, AIMMS-30, and pylon adapter. The power supply of the measurement equipment replaced the generating capacity of starter generators from 300A to 400A (at DC 28V). In addition, this aircraft was installed on the time synchronization and network system of measurement equipment (HR-ToF-AMS, PTR-ToF-MS, CIMS, etc). Currently, the air quality scientists in Korea have been investigating on long-range transport or local large point sources.

How to cite: Seo, B.-K., Kim, J., Park, S. B., Yu, J., and Lee, M.: A Study on modification of Aircraft Platform for Air Quality Measurement in Korea, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10700, https://doi.org/10.5194/egusphere-egu2020-10700, 2020.

EGU2020-11460 | Displays | AS3.1

HO2 reactive uptake on organic aerosols: a molecular level study

Antoine Roose, Celine Toubin, Sebastien Dusanter, Veronique Riffault, and Denis Duflot

Significant uncertainties are still associated to chemical reaction mechanisms used in atmospheric models, in particular for ROx radicals (OH, HO2, RO2). Recent measurements of radicals in forested areas characterized by low NOx (NO2, NO) concentrations indicate that models can significantly overestimate peroxy radical concentrations.1,2 These results question the ability of models to correctly simulate the oxidative capacity of the troposphere since peroxy radicals are a main source of the hydroxyl radical (OH), one of the most important oxidative species in the atmosphere.3  One possible explanation is the occurrence of heterogeneous processes (uptake of radicals) on the surface of aerosols that are either misrepresented or not included in models. While recent studies have reported uptake coefficients of HO2 on different types of aerosols, the process is not completely understood yet.

Molecular dynamics combined with ab-initio calculations have been used to study HO2 reactive uptake on organic aerosols. The sticking process of HO2 and its reactivity have been modelled on a nanometer size aerosol particle.4 Those theoretical calculations provide insight into the uptake process at the molecular scale and are planned to be compared to experimental measurements carried out with an aerosol flow tube.

This work is supported by the CaPPA project (Chemical and Physical Properties of the Atmosphere), funded by the French National Research Agency (ANR) through the PIA (Programme d’investissement d’avenir) and by the regional council “Hauts-de-France”. The authors also thank CPER Climibio and FEDER for their financial support. Calculations were performed using HPC resources from GENCI-TGCC (Grant 2020- A0070801859).

References

  • [1] T. Griffith et al., Atmos. Chem. Phys. 13, 5403 (2013)
  • [2] Mao et al., Atmos. Chem. Phys. 12, 8009 (2012)
  • [3] Stone et al., Chem. Soc. Rev. 41, 6348 (2012)
  • [4] Roose et al., ACS Earth Space Chem. 3, 380 (2019)

 

How to cite: Roose, A., Toubin, C., Dusanter, S., Riffault, V., and Duflot, D.: HO2 reactive uptake on organic aerosols: a molecular level study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11460, https://doi.org/10.5194/egusphere-egu2020-11460, 2020.

This work presents an overview of more than 3-year measurements of ultrafine particle size distributions (PSD, 6-800 nm) at a sub-urban site, the Station for Observing Regional Processes of the Earth System (SORPES) located in Nanjing, Yangtze River Delta of China. For the purpose of understanding the temporal variations as well as the source of ultrafine particles, k-means cluster analysis was applied and seven clusters were finally separated from the PSD data set. PSD spectra, hourly and seasonal frequencies of occurrence, the data of pollutant gases, PM2.5 and chemical composition, as well as metrological parameters were used to define and interpret each cluster. In general, four clusters (i.e. C1, C2, C3, and C4) were related with new particle formation (NPF) and growth, but they were at different stages or with different intensity, accounting for 20.4% of total PSD data; One (i.e. C5) was attributed to clean regional background, with high level of relative humidity, accounting for 37.9% of total data; Two clusters (i.e. C6 and C7) were polluted clusters, accounting for 41.6% of total data. Two extremely polluted episodes in C6 and C7, respectively, one was caused by fossil fuel combustion and another was caused by biomass burning, were selected as case study. The PSD of two polluted episodes was totally different, even though the mass concentration was similar. The associations between each clusters were analyzed, showing that the contribution of NPF to pollution and the conversion between clean and pollution because of accumulation and wet deposition.

How to cite: Chen, L.: Cluster analysis of ultrafine particle size distribution based on long-term measurement at SORPES in Yangtze River Delta of China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12671, https://doi.org/10.5194/egusphere-egu2020-12671, 2020.

EGU2020-12747 | Displays | AS3.1

Chemical Characteristics and Source Apportionment of Non-refractory PM1 from a Marine Urban Location

Snehitha M. Kommula, Upasana panda, Amit Sharma, Subha S. Raj, Ernesto Reyes villegas, James D. Allan, Mira Pöhlker, Ravi Krishna R., Pengfei Liu, Ulrich Pöschl, Gordan MCfiggans, Hugh Coe, and Sachin S. Gunthe

Atmospheric aerosol particles, known for their direct interaction with incoming solar radiations (direct effect) and for perturbation of the cloud properties (indirect effect) by acting as cloud condensation nuclei (CCN), represents largest uncertainty in the current and future understanding of the climate change. In part, this uncertainty is attributed to the lack of accurate measurements of aerosol physical and chemical properties for the improvement of various schemes in prognostic modelling useful for the effective prediction of cloud and precipitation formation. The Indian tropical region, constitutes ~18% of the world’s total population spread heterogeneously over diverse land cover, experiences a distinctive meteorological phenomenon by means of Indian Summer Monsoon (ISM). Thus, the sources, chemical properties and characteristics of aerosols are also expected to have significant variations over the Indian subcontinent depending upon the location and seasons. Online continuous measurements of NR-PM1 (Non refractory particulate matter ≤1 µm) have been carried out in near real-time using ACSM (Aerosol Chemical Speciation Monitor) at a marine urban location of Chennai, from 4th January to 2nd February, 2019, complimented by simultaneous measurements of meteorological parameters. Average NR-PM1 mass concentration for the duration of the measurements was 30.37±28.31 µg/m3 with organics constituting major fraction of ~47.43% followed by sulphate (~33.34%), ammonium (~11.89%), nitrate (~4.57%) and chloride (~2.74%). Back trajectory analysis using HYSPLIT model enabled the classification of air samples measured in to three periods: “Continental polluted”, “Marine polluted” and “Clean marine”. The polluted periods were distinguished by the potential biomass burning event, which occurs during the regional festival Bhogi, celebrated on 14th of January in this part of the country. During this period the organics had a peak concentration of 211 µg/m3 followed by chloride ~ 42 µg/m3. During the clean marine period, low mass concentration of PM1 is attributed to change in meteorological conditions accompanied by airmass originating from the Bay of Bengal. The average mass concentration of NR-PM1 during this period was observed to be 7.14±2.78 µg/m3, which is ~5 times lesser than the polluted period.

            A comprehensive source apportionment study was carried out using Positive Matrix Factorization (PMF) model implemented through the multilinear engine tool (ME-2) in Source Finder (SoFi) graphical user interface, to understand the contribution of primary and secondary sources to the organic aerosols. Primary anthropogenic emissions contributed on average ~45% (~19% from traffic, ~16.7% from cooking, ~10% from biomass burning) to the total organic mass for entire measurement period, while the major contribution was associated with secondary formation ~55%. On the other hand, for clean marine period, the fractional contribution of secondary formation to PM1 increased to ~75% to 85%, while that of primary emissions decreased to less than ~15%.

In brief, these findings indicate the influence of oceanic air masses on aerosol mass concentration and composition. Further details will be presented.

How to cite: M. Kommula, S., panda, U., Sharma, A., S. Raj, S., Reyes villegas, E., D. Allan, J., Pöhlker, M., Krishna R., R., Liu, P., Pöschl, U., MCfiggans, G., Coe, H., and S. Gunthe, S.: Chemical Characteristics and Source Apportionment of Non-refractory PM1 from a Marine Urban Location, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12747, https://doi.org/10.5194/egusphere-egu2020-12747, 2020.

EGU2020-13059 | Displays | AS3.1

Concentration uncertainties in atmospheric aerosol measurement with Condensation Particle Counters

Sebastian H. Schmitt, Francois Gendarmes, Torsten Tritscher, Axel Zerrath, Thomas Krinke, and Oliver F. Bischof

Condensation Particle Counters (CPCs) are the best-known and most frequently used tools for determining airborne particle number concentrations in the laboratory and a variety of real-life situations. While being a very established technique, current generations of CPCs have enhanced capabilities in terms of lower cut-off diameters, upper concentration limit as well as measurement quality features (e.g. pulse height monitoring). Knowledge of instrument accuracy is a primary matter in order to retrieve high quality data. In recent years, there has been an effort from measurement networks and within the EU’s standardization committee (CEN-TS 16976) to make ambient ultrafine particle number concentration data comparable. Long-term ambient monitoring requires frequent validation of instrument performance.

Inter-comparisons of multiple instruments against a reference instrument are important measures in order to secure long-term data quality. During inter-comparisons in the laboratory typically an aerosol of a certain type is generated and eventually classified in order to retrieve a monodisperse aerosol population. The aerosol needs to be equally distributed between the different instruments without being biased by sampling line losses.

This presentation will focus on inter-comparisons of CPCs being challenged with different types of aerosol. This includes lab-generated, highly monodisperse aerosol as well as ambient polydisperse aerosol. The accuracy of 10 units of a recently-introduced CPC (Model 3750, TSI Inc.) will be shown for ambient aerosol at data rates up to 50 Hz. All CPCs characterized agreed within 10% during the test, with concentrations of the ambient aerosol ranging from a few thousands up to 100,000 Particles/cm³.

In addition, results from inter-comparison studies using different butanol- and water-based CPC models that have been used for multiple years in different laboratories will be shown. Despite the different schedules for all instrument services and calibrations related to owners metrology requirement, these different CPC models demonstrated similar responses for the tested aerosols taking into account 10% uncertainties and are suitable candidates for reliable long-term operation in ambient ultrafine particle monitoring.

How to cite: Schmitt, S. H., Gendarmes, F., Tritscher, T., Zerrath, A., Krinke, T., and Bischof, O. F.: Concentration uncertainties in atmospheric aerosol measurement with Condensation Particle Counters, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13059, https://doi.org/10.5194/egusphere-egu2020-13059, 2020.

EGU2020-15121 | Displays | AS3.1

Light absorption properties of brown carbon over the western Pacific region

Shantanu Kumar Pani, Neng-Huei Lin, Chung-Te Lee, and Sheng-Hsiang Wang

Brown carbon (BrC) is generally emitted during coal combustion, biomass burning, and the formation of secondary organic aerosols. BrC is an exceptional type of organic compound that absorbs the incoming solar radiation efficiently at near-ultraviolet wavelengths and can influence the direct radiative forcing estimates. Lulin Atmospheric Background Station (LABS, 23.47°N, 120.87°E; 2862 m above sea level) on the summit of Lulin Mountain in central Taiwan is the only high-altitude background station in the western Pacific region to study the impact of various long-range transported air pollutants. LABS usually receives the westerly winds coupled with biomass-burning emissions from peninsular Southeast Asia during the springtime. Aerosol measurements are carried out at LABS as a part of the Seven South East Asian Studies/Biomass-burning Aerosols & Stratocumulus Environment: Lifecycles & Interactions Experiment (7-SEAS/BASELInE) 2013 spring campaign. Light absorption coefficients are measured by the Aethalometer (AE 31, Magee Scientific, USA). Assuming a negligible contribution from dust, absorption solely due to BrC is estimated by subtracting the absorption of black carbon (BC) from total absorption. The relationships between BrC light absorption and carbonaceous fractions are investigated during the sampling period. The atmospheric radiative forcing due to BrC over the western Pacific region accounts for approximately 30% of that from BC. The detailed results will be presented.

How to cite: Pani, S. K., Lin, N.-H., Lee, C.-T., and Wang, S.-H.: Light absorption properties of brown carbon over the western Pacific region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15121, https://doi.org/10.5194/egusphere-egu2020-15121, 2020.

EGU2020-15354 | Displays | AS3.1

Atmospheric aerosol analysis close to the mining area of Aljustrel (SW of Portugal)

Ana Barroso, Sandra Mogo, Manuela Silva, Victoria Cachorro, and Ángel de Frutos

Mining activities are associated with dust emissions and increased contaminant levels in the environment, due to excavation, crushing and transportation of ore and the generation of a high amount of polluting wastes. Therefore, it is crucial to study the particulate matter in these areas to understand their impacts on nearby urban areas and populations (Csavina et al., 2012). Analysis PM10 samples collected near the active mining area of Aljustrel (SW Portugal) allowed to do an individual characterization and to investigate the contaminants levels and aerosols sources. In Aljustrel, the exploitation of volcanogenic massive sulphides (VMS) deposits has been done since pre-Roman times, releasing great quantities of mine wastes, which have contaminated the soils (Candeias, et al. 2011). Now the exploitation is done underground, but even so, the ore processing plant releases dust, which is transported by wind to the village.

The PM10 samples were collected in two points at the southeast of the ore processing plant. The sampling was done in two periods July 10-17 and November 1-10 of 2018. Two different techniques were used: SEM-EDX for the individual characterization and ICP-MS for the elemental concentration of 11 elements (Ca, Na, Fe, Mn, As, Cd, Cu, Sb, Pb, and Zn). PM10 mass concentration observed was 20 to 47 µg m-3 (July) and 4 to 23 µg m-3 (November) which is lower than the limit of 50 μg m-3 established in the European Directive (Directive 2008/50/CE of May 21). The individual characterization of 2006 particles by SEM-EDX shows the presence of oxides (17%) and sulphides (10%) in the aerosols, and the elements Na, Si, Fe, S, Al and Cu are those with the most representativeness in all the analyzed particles. The Principal Component Analysis (PCA) allowed to distinguish the main sources of aerosols. Five factors were extracted (72% of the total variance of the data): CP1 is defined by O, Al, Si and Fe, the geogenic elements; CP2 is defined by As and Pb, CP3 is defined by S, CP4 defined by Cu and Zn; and finally, the CP5 defined by Mn. These factors are related to the ore minerals. The ICP-MS results indicate that daily elemental concentration in the samples collected in July is higher than in those collected in November, for each element. The elements Fe, Cu, Zn, As, Cd, Sb, Pb have strong correlations (α = 0.05, r > 0.93) and are the main constituents of the ore minerals. Therefore, these elements will have an anthropogenic source. Comparing the concentration of some pollutes (As, Cd, and Pb) with their limits in the European legislation only As exceeds its limit in all samples.

This work was the first study about atmospheric aerosols developed in this area and shows a strong relationship between PM10 analyzed and the ore exploited in Aljustrel, indicating implications in the quality of the air for the resident population. Even if some limits are not exceeded, the continuous exposition over many years is a potential hazard.

How to cite: Barroso, A., Mogo, S., Silva, M., Cachorro, V., and de Frutos, Á.: Atmospheric aerosol analysis close to the mining area of Aljustrel (SW of Portugal), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15354, https://doi.org/10.5194/egusphere-egu2020-15354, 2020.

EGU2020-17298 | Displays | AS3.1

Miniaturized, Lightweight, Cost-effective and Fast Response Particle Classifier

Nikoleta Lekaki, Marinos Costi, George Biskos, and Anne Maisser

Aerosol particles properties depend strongly on their particle size and they have significant effects on both, human health and environment. Nanometer sized particles possess special electrical, optical, and/or magnetic properties. This is one of the reasons which started the interest towards studying aerosol particles in the nanometer size range (Chen and Pui, 1995). The most efficient tool for determining the size of aerosol particle in the sub-micrometer and nanometer range is the differential mobility analyzer (DMA). This popular tool has two coaxial cylindrical electrodes between of them a potential difference is applied and forces the charged polydisperse aerosol to migrate from one electrode to another. Only those particles which have an electrical mobility in a narrow range, the will pass through the classifier (Stolzenburg, 1988).   Classifying aerosols according to their electrical mobility dates back to the first half of the 20th century and from that time plethora different DMAs have been build and their performances have been tested according to their transfer function and size resolution. One major limitation of classical DMAs is the time it takes to scan over the entire size range to get the size distribution of the aerosol. This is especially leading to the loss of information if the aerosol is changing its size and/or concentration rapidly. This happens for instance during new particle formation events, or also when the measurement takes place on fast moving platforms, such as cars, or airplanes.

The present work evaluates the performance of two different, newly developed DMA types, that aim towards overcoming this limitation. This is done by replacing the classic design of a single monodisperse outlet DMA to a multiple monodisperse outlet DMA. In our case the DMAs have three monodisperse outlets and are 3D-printed (namely, the 3MO-DMA) (Chen et al., 2007; Giamarelou et al., 2012; Barmpounis et al., 2016; Bezantakos et al., 2016). The 3MO-DMA is not only a fast response instrument able to sizing three different sizes ranges at the same time but also is a cost-effective and lightweight instrument suitable to get measurements not only ground based but also on Unmanned Aerial Vehicles or balloons.

How to cite: Lekaki, N., Costi, M., Biskos, G., and Maisser, A.: Miniaturized, Lightweight, Cost-effective and Fast Response Particle Classifier, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17298, https://doi.org/10.5194/egusphere-egu2020-17298, 2020.

Black carbon (BC) aerosols over the Indian subcontinent have been represented inadequately so-far in chemical transport models restricting the accurate assessment of BC-induced climate impacts. The divergence between simulated and measured BC concentration has specifically been reported to be large over the Indo-Gangetic Plain (IGP) during winter when a large BC burden is observed. In this study, we evaluate the BC transport simulations over the IGP in a high resolution (0.1º × 0.1º ) chemical transport model, CHIMERE. We examine the model efficiency to simulate the observed BC distribution executing five sets of simulation experiments: Constrained and bottomup (Smog, Pku, Edgar, Cmip) implementing respectively, the recently estimated India-based constrained BC emission and the latest bottom-up BC emissions (India-based: Smog-India, and global: Coupled Model Intercomparison Project phase 6 (CMIP6), Emission Database for Global Atmospheric Research-V4 (EDGAR-V4) and Peking University BC Inventory (PKU)). The mean BC emission flux over most of the IGP from the five emission datasets is considerably high (450–1000 kg km-2 y-1) with a relatively low divergence obtained for the eastern and upper-mideastern IGP. Evaluation of BC transport simulations shows that the spatial and temporal gradient in the simulated BC concentration from the Constrained was equivalent to that from the bottomup and also to that from observations. This indicates that the spatial and temporal patterns of BC concentration are consistently simulated by the model processes. However, the efficacy to simulate BC distribution is commendable for the estimates from Constrained for which the lowest normalised mean bias (NMB, < 20%) is obtained in comparison to that from the bottomup (37–52%). 75–100% of the observed all-day (daytime) mean BC concentration is simulated most of the times (>80% of the number of stations data) for Constrained, whereas, this being less frequent (<50%) for the Pku, Smog, Edgar and poor for Cmip. The BC-AOD (0.04–0.08) estimated from the Constrained is 20–50% higher than the Pku and Smog. Three main hotspot locations comprising of a large value of BC load are identified over the eastern, mideastern, and northern IGP. Assessment of the effect of BC burden on the wintertime radiative perturbation over the IGP shows that the presence of BC aerosols in the atmosphere enhances atmospheric heating by 2–3 times more compared to that considering atmosphere without BC. Also, a net warming at the top of the atmosphere (TOA) by 10–17 W m-2 is noticed from the Constrained, with the largest value estimated in and around megacities (Kolkata and Delhi) that extends to the eastern coast. This value is higher by 10–20% than that from Cmip over the IGP and by 2–10% than that from Smog over Delhi and eastern part of the IGP.

How to cite: Ghosh, S., Verma, S., and Kuttippurath, J.: Evaluation of emission strength efficacy in simulating black carbon burden with CHIMERE: estimating wintertime radiative effect over Indo-Gangetic Plain, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17436, https://doi.org/10.5194/egusphere-egu2020-17436, 2020.

EGU2020-17585 | Displays | AS3.1

Investigation of structural changes of 21 atmospheric aerosol samples during a thermal-optical measurement procedure (EUSAAR2)

Theresa Haller, Eva Sommer, Thomas Steinkogler, Anna Wonaschuetz, Anne Kasper-Giebl, Hinrich Grothe, and Regina Hitzenberger

Elemental Carbon (EC), Black Carbon (BC) and Organic Carbon (OC) contribute a large amount to atmospheric aerosols. Due to their significant influence on climate and health, a reliable measurement of these components is essential. Nevertheless, their correct determination is not trivial and results of different measurement techniques show differences by factors up to nine especially in the presence of Brown Carbon (BrC) (e.g. Reisinger et al., 2008; Hitzenberger et al., 2006; Wonaschuetz et al., 2009). EC and OC are usually measured with thermal-optical techniques: The sample is heated stepwise, first in an inert (He) atmosphere, then in an oxidizing (He+O2) atmosphere. The darkening of the sample during the heating procedure is traced with a laser transmission/reflection signal. Based on the progress of this signal, the amount of pyrolyzed carbon is calculated and attributed to OC in the subsequent evaluation. Despite this optical correction, the pyrolyzation of OC can lead to uncertainties in the OC/EC split (Cheng et al., 2012). Especially Brown Carbon (BrC) and water soluble organic carbons (WSOC) have a high tendency to pyrolyze and therefore bias the OC/EC split. Moreover several metal salts in the atmospheric aerosol can influence the measurement process and enhance or suppress pyrolysis of OC (Wang et al., 2010). These highly complex chemical and physical reactions are not fully investigated yet but are essential for a profound understanding of the biases in thermal-optical measurement techniques. 

The aim of the present study was to investigate the structural reorganizations of the carbonaceous materials in atmospheric aerosol samples occurring during a thermal-optical heating procedure (EUSAAR2, Cavalli et al., 2010) and to set them in relation with several properties of the samples such as ionic composition, EC, OC, BC and BrC, as well as the air mass origins during sampling of the atmospheric aerosol samples.
The changes of the internal structure of the material during the heating procedure of an EC/OC analyzer (Sunset instruments) were analyzed with Raman spectroscopy, which is sensitive to C-C bonding types and to the degree of structural ordering within the sample (Ferrari and Robertson, 2000). Different types of restructuration behavior were defined depending on the temperature levels of the EUSAAR2 protocol where measurable structural changes occur. For all samples ion chromatography was performed with a Dionex Aquion system (Thermo Fisher), BrC and BC were analyzed with the Integrating Sphere method (Wonaschütz et al., 2009) and air mass back trajectories for the respective sampling days were calculated with HYSPLIT.

How to cite: Haller, T., Sommer, E., Steinkogler, T., Wonaschuetz, A., Kasper-Giebl, A., Grothe, H., and Hitzenberger, R.: Investigation of structural changes of 21 atmospheric aerosol samples during a thermal-optical measurement procedure (EUSAAR2) , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17585, https://doi.org/10.5194/egusphere-egu2020-17585, 2020.

EGU2020-17815 | Displays | AS3.1

Numerical simulation of chemical reactions occurring in fog droplets

Gabriella Schmeller and István Geresdi

Introduction

Fog provides a significant medium for chemical reactions occurring in liquid phase. Fog droplets are relatively small (5 < r < 50 µm) hence the surface-to-volume ratio is large. Through the larger overall surface the absorption of inorganic and organic gases from different sources may be enhanced. Depending on the stability of fog, the chemical processes may have more time to take place in fog droplets. Also, ground based sources of solid aerosol particles and gases may be in direct connection with fog.

Inorganic and organic components may change the pH of fog droplets and significant amount of sulphate ion can be formed due to the oxidation (e.g. by hydrogen-peroxide and ozone) of dissolved sulphur-dioxide. At the same time there are some organic components, e.g. formaldehyde, which also react with the dissolved sulphur-dioxide but produces hydroxymethanesulfonic acid (HMSA), thus decreases the possibility of producing sulphate ion through oxidation. These competitive processes are important in understanding the formation of sulphate ion in solution. In addition, the liquid phase concentration of compounds and also the sulphate ion formation strongly depends on the size of the droplets. Physical and chemical processes in fog may have an impact on both the size distribution and solubility of solid aerosol particles.

 

Numerical model

A box model with detailed microphysics and chemistry scheme with moving bin boundaries was used to simulate the following processes in fog:

  • (i) Formation of drops on hygroscopic aerosol particles (ammonium-sulphate). Fog is formed due to cooling rate -0.0001 K/s.
  • (ii) Condensational growth of drops.
  • (iii) Scavenging of aerosol particles by water drops due to Brownian motion and phoretic forces.
  • (iv) Absorption and desorption of inorganic (CO2, H2O2, O3, NH3, SO2) and organic (HCHO, HCOOH, CH3COOH) gases, dissociation, change of pH, sulphate formation (oxidation of S(IV) by hydrogen-peroxide and by ozone and reaction of formaldehyde with S(IV)).

 

Results

Significant amount of HMSA formed in drops due to the reaction of S(IV) with formaldehyde. Taking into account this reaction, the amount of S(VI) formed is decreased compared to the case when no formaldehyde was present. Formation of HMSA modifies the solubility of the solid aerosol residue after evaporation of drops.

How to cite: Schmeller, G. and Geresdi, I.: Numerical simulation of chemical reactions occurring in fog droplets, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17815, https://doi.org/10.5194/egusphere-egu2020-17815, 2020.

Aliphatic dicarboxylic acids (DCA) are significant constituents of oxygenated organic aerosol. Laboratory studies indicated that the major heterogeneous oxidation product of aerosol-phase aliphatic DCAs was the corresponding hydroxy DCAs (hDCAs). In this work, we focused our field investigation on hydroxyl DCAs and report their ambient abundance in an urban environment, and their correlations with other measured aerosol species. Good correlations (R~0.5-0.9) were observed between DCAs and hDCAs, supporting the precursor-product relationships between the two as suggested by laboratory studies. Moderate to good correlations were also observed for DCAs/hDCAs with oxidant potential (Ox=O3+NO2) (R~0.5-0.9) and sulfate (R~0.2-0.8) in summer. Ox might act as a gas phase oxidant indicator, hinting hat gas phase oxidation might play a role in formation of hDCAs. The effect of estimated LWC and sulfate was examined and illustrated through the contour plots. It was found that the episodic formation of DCAs and hDCAs was more associated with high concentration of sulfate, suggesting commonality in their formation pathways. However, high hDCA was not always associated with high estimated LWC. Long range transport contribution might explain such an observation. More efforts are needed to understand the formation conditions and mechanisms for hydroxyl dicarboxylic acids.

How to cite: Cheng, Y. Y. and Yu, J. Z.: Field observation of hydroxy diacids in PM2.5 and insights into their formation from aliphatic diacids through heterogeneous oxidation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18131, https://doi.org/10.5194/egusphere-egu2020-18131, 2020.

EGU2020-18136 | Displays | AS3.1

Evaluation of combined radiocarbon and carbon stable isotope data of PM2.5 carbonaceous aerosol in Debrecen, Hungary

István Major, Enikő Furu, Tamás Varga, Anikó Horváth, István Futó, Brigitta Gyökös, Zsófia Kertész, AJ Timothy Jull, and Mihály Molnár

Comprehensive atmospheric studies have demonstrated that carbonaceous aerosol is one of the main components of atmospheric particulate matter over Europe. Despite its significant role in atmospheric processes, the characteristic of carbonaceous particle sources and the contributions from modern and fossil sources in the Pannonian Basin are still less known. Using radiocarbon as a tracer, the ratio of modern (biological aerosol, wood burning etc.) and fossil (coal or oil burning, transportation) sources for an aerosol sample can unambiguously be determined but identification of exact sources is not possible. Considering other isotopic techniques, carbon stable isotope results can provide us such supplementary information that can be used in separating different large source clusters (e.g. burning of C3 type wood, coal burning or transportation). Different aerosol sources have well defined carbon stable isotope ranges, which can be used in source apportionment models. Nevertheless, these ranges often overlap each other, making the accurate source identification rather difficult. Combined radiocarbon and carbon stable isotope measurements can however help us to differentiate more precisely numerous modern or fossil sources.

In our study, the isotopic composition of carbon in the PM2.5 atmospheric aerosol collected on weekly basis in Debrecen, Hungary was investigated. In doing so, the organic and elemental carbon content, the specific 14C content and the δ13C values of total carbon were measured using a Sunset OC/EC analyser, an accelerator mass spectrometer (AMS) and an EA/IRMS instrument, respectively. Based on our three-year long carbon stable isotope data of carbonaceous aerosol, relatively enriched δ13C results can be observed in each wintertime period, which are supposed by other authors to be related to the effect of coal combustion (mainly in heavily industrialised areas). Contrarily, radiocarbon measurements imply the dominance of modern sources for the same wintertime periods when the biological activity of vegetation is moderate. Consequently, according to our assumption, these values are caused by modern sources having more positive δ13C value such as biomass burning of residences. In contrast to single stable isotope or radiocarbon measurements our study sheds light on the importance of combined carbon isotopic investigations. The research was supported by the European Union and the State of Hungary, co-financed by the European Regional Development Fund in the project of GINOP-2.3.2-15-2016-00009 ‘ICER’

How to cite: Major, I., Furu, E., Varga, T., Horváth, A., Futó, I., Gyökös, B., Kertész, Z., Jull, A. T., and Molnár, M.: Evaluation of combined radiocarbon and carbon stable isotope data of PM2.5 carbonaceous aerosol in Debrecen, Hungary, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18136, https://doi.org/10.5194/egusphere-egu2020-18136, 2020.

EGU2020-18319 | Displays | AS3.1

Direct and catalytic contribution of formaldehyde to particulate matter?

Frank Keutsch, Eleni Dovrou, and Kelvin Bates

Formaldehyde (HCHO) is produced mainly via photochemical oxidation of volatile organic compounds as well as direct emissions mainly from combustion processes. HCHO has a high vapor pressure but as a result of the hydration of the aldehyde group, it has a Henry’s law constant that allows it to partition into cloud droplets. We present results of two different pathways through which HCHO may contribute to the mass of particulate matter: Formation of hydroxymethanesulfonate (HMS) from reaction of HCHO with dissolved sulfur dioxide (SO2aq) and formation of sulfate by reaction of HCHO with hydrogen peroxide (H2O2) to form hydroxyl methyl hydroperoxide (HMHP), which in turn can oxidize SO2aq to sulfate and reform HCHO. The former pathway contributes to both the carbon and sulfur component of particulate matter whereas the latter contributes to the sulfur particulate budget and suggests a catalytic role of formaldehyde.

We combine laboratory kinetics studies of these reactions with model simulations using GEOS-Chem. The model simulations are analyzed at regional and global scales under present day and simplified preindustrial conditions, in which all anthropogenic emissions are set to zero. The analysis suggests that, depending on conditions, these processes may have significant impact on the sulfur particulate matter budget, specifically the rate of particulate sulfur formation. The results also suggest that under conditions that favor HMS formation, HMS may be the most abundant single organic molecule contributing particulate matter carbon.

How to cite: Keutsch, F., Dovrou, E., and Bates, K.: Direct and catalytic contribution of formaldehyde to particulate matter?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18319, https://doi.org/10.5194/egusphere-egu2020-18319, 2020.

EGU2020-18338 | Displays | AS3.1 | Highlight

Evaluation of Air Pollutant Emission Inventories in East Asia

Younha Kim, Jung-hun Woo, Youjung Jang, Minwoo Park, Bomi Kim, Markus Amann, Zbigniew Klimont, Fabian Wagner, Wolfgang Schöpp, and Robert Sander

Concentration of air pollutants such as tropospheric ozone and aerosols are mainly affected by meteorological variables and emissions. East Asia has large amount of anthropogenic and natural air pollutant emissions and has been putting lots of efforts to improve air quality. In order to seek effective ways to mitigate future air pollution, it is essential to understand the current emissions and their impacts on air quality. Emission inventory is one of the key datasets required to understand air quality and find ways to improve it. Amounts and spatial-temporal distributions of emissions are, however, not easy to estimate due to their complicate nature, therefore introduce significant uncertainties.

In this study, we had developed an updated version of our Asian emissions inventory, named NIER/KU-CREATE (Comprehensive Regional Emissions inventory for Atmospheric Transport Experiment) in support of climate-air quality study. We first inter-compare multiple bottom-up inventories to understand discrepancies among the dataset(sectoral, spatial). We then inter-compare those bottom-up emissions to the satellite-based top-down emission estimates to understand uncertainties of the databases. The bottom-up emission inventories used for this study are: CREATE, MEIC(Multiresolution Emission Inventory for China), REAS (Regional Emission inventory in ASia), and ECLIPSE(Evaluating the Climate and Air Quality Impacts of Short-Lived Pollutants). The satellite-derived top-down emission inventory had been acquired from the DECSO (Daily Emission derived Constrained by Satellite Observations) algorithm data from the GlobEmissions website.

The analysis showed that some discrepancies, in terms of emission amounts, sectoral shares and spatial distribution patterns, exist among the datasets. We analyzed further to find out which parameters could affect more on those discrepancies. Co-analysis of top-down and bottom-up emissions inventory help us to evaluate emissions amount and spatial distribution. These analysis are helpful for the development of more consistent and reliable inventories with the aim of reducing the uncertainties in air quality study. More results of evaluation of emissions will be presented on site.     

Acknowledgements : This work was supported by National Institute of Environment Research (NIER-2019-03-02-005), Korea Environment Industry & Technology Institute(KEITI) through Public Technology Program based on Environmental Policy Program, funded by Korea Ministry of Environment(MOE)(2019000160007). This research was supported by the National Strategic Project-Fine particle of the National Research Foundation of Korea(NRF) funded by the Ministry of Science and ICT(MSIT), the Ministry of Environment(ME), and the Ministry of Health and Welfare(MOHW) (NRF-2017M3D8A1092022).

How to cite: Kim, Y., Woo, J., Jang, Y., Park, M., Kim, B., Amann, M., Klimont, Z., Wagner, F., Schöpp, W., and Sander, R.: Evaluation of Air Pollutant Emission Inventories in East Asia, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18338, https://doi.org/10.5194/egusphere-egu2020-18338, 2020.

EGU2020-18555 | Displays | AS3.1

Modelling the non-ideal multiphase chemical processing in aqueous aerosol particles with SPACCIM-SpactMod

Ralf Wolke, Andreas Tilgner, Ahmad Jhony Rusumdar, and Hartmut Herrmann

Tropospheric deliquesced particles including haze particles are a complex multiphase and multi-component environment with simultaneously occurring multiphase chemical transformations. Such chemical processes are able to alter the chemical composition and the deduced physical aerosol properties. Deliquesced particles are characterized by concentrated non-ideal solutions (‘aerosol liquid water’ or ALW) that can affect the occurring multiphase chemical processing. The effects of such non-ideal solutions have generally not been adequately investigated by present complex multiphase chemistry models. Thus, the present study is aimed at investigating the impact of non-ideality on multiphase chemical processing. Therefore, simulations with a multiphase chemistry model (SPACCIM-SpactMod) including the CAPRAM chemical mechanism are performed for polluted and less polluted environmental conditions and different ALW conditions.

The present study shows that activity coefficients of inorganic ions are often below unity under deliquesced aerosol conditions, and that most uncharged organic compounds exhibit activity coefficient values around or even above unity. The model studies demonstrated that the inclusion of non-ideality considerably affects the multiphase chemical processing of transition metal ions (TMIs), key oxidants, and related chemical subsystems, e.g. organic chemistry. In detail, both the chemical formation and oxidation fluxes of Fe(II) are substantially lowered by a factor of 2.8 under polluted haze conditions compared to a case study without non-ideality treatment. The reduced Fe(II) processing in the polluted base case, including lowered chemical fluxes of the Fenton reaction (-70 %), results in a reduced processing of HOx/HOy. under deliquesced aerosol conditions. Therefore, higher multiphase H2O2 concentrations (by a factor of 3.1 larger) and lower aqueous-phase OH concentrations (by a factor of ≈ 4 lower) were modelled during aerosol conditions. For H2O2, the consideration of non-ideality increases S(VI) oxidation fluxes under aqueous aerosol conditions by 40 %. Moreover, the chemical fluxes of the OH radical are about 50 % lower in the non-ideal haze case. Accordingly, the consideration of non-ideality affects the chemical processing and the concentrations of organic compounds under deliquesced particle conditions in a compound-specific manner. For important organic carboxylic acids, e.g. glyoxylic acid and oxalic acid, the reduced radical oxidation budget under aqueous particle conditions leads to increased concentration levels. For oxalic acid, the present study demonstrates that the non-ideality treatment enables more realistic predictions of high oxalate concentrations observed under ambient highly polluted conditions. Furthermore, the simulations show that lower humidity conditions, i.e. more concentrated solutions, might promote higher oxalic acid concentration levels in aqueous aerosols due to differently affected formation and degradation processes. Overall, the performed studies demonstrate the crucial role of a detailed non-ideality treatment in multiphase models dealing with aqueous aerosol chemistry and the needs to further improve current model implementations.

How to cite: Wolke, R., Tilgner, A., Rusumdar, A. J., and Herrmann, H.: Modelling the non-ideal multiphase chemical processing in aqueous aerosol particles with SPACCIM-SpactMod , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18555, https://doi.org/10.5194/egusphere-egu2020-18555, 2020.

EGU2020-18959 | Displays | AS3.1

Rate enhancement in collisions of sulfuric acid molecules due to long-range intermolecular forces

Roope Halonen, Evgeni Zapadinsky, Theo Kurtén, Hanna Vehkamäki, and Bernhard Reischl

Collisions of molecules and clusters play a key role in determining the rate of atmospheric new particle formation and growth. Traditionally the statistics of these collisions are taken from kinetic gas theory assuming spherical noninteracting particles, which may significantly underestimate the collision coefficients for most atmospherically relevant molecules. Such systematic errors in predicted new particle formation rates will also affect large-scale climate models. We studied the statistics of collisions of sulfuric acid molecules in a vacuum using atomistic molecular dynamics simulations. We found that the effective collision cross section of the H2SO4 molecule, as described by an optimized potentials for liquid simulation (OPLS) all-atom force field, is significantly larger than the hard-sphere diameter assigned to the molecule based on the liquid density of sulfuric acid. As a consequence, the actual collision coefficient is enhanced by a factor of 2.2 at 300 K compared with kinetic gas theory. This enhancement factor obtained from atomistic simulation is consistent with the discrepancy observed between experimental formation rates of clusters containing sulfuric acid and calculated formation rates using hard-sphere kinetics. We find reasonable agreement with an enhancement factor calculated from the Langevin model of capture, based on the attractive part of the atomistic intermolecular potential of mean force.

How to cite: Halonen, R., Zapadinsky, E., Kurtén, T., Vehkamäki, H., and Reischl, B.: Rate enhancement in collisions of sulfuric acid molecules due to long-range intermolecular forces, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18959, https://doi.org/10.5194/egusphere-egu2020-18959, 2020.

Fine particles can reach deeply into various tracts in the human body, causing adverse health effects. In addition, particulate matter affects earth energy balance directly, scattering solar radiation, and indirectly, forming clouds and changing cloud properties. In these respects, understanding the variations of aerosol concentrations in each mode of aerosol size distributions and the factors affecting those variations, is important.

In this study, we attempted to separate each mode from the aerosol size distributions obtained from long-term observations with scanning mobility particle sizer (SMPS) (December 2007 to October 2018) in Jeju Island (Gosan, national background concentration network, 33.17˚N, 126.12˚E).

The particle number size distributions (54 channels, from 10.4 nm to 469.8 nm) were separated into three modes using a fitting method based on the multiple lognormal distribution function. We then attempted to examine how these modes of particles have changed in time, and what factors (air trajectories, meteorology, other pollutants, and others) were related to the variations in each mode. We also calculated the deposition fractions of inhaled aerosols in each human respiratory tract from the observed size distributions using the International Commission on Radiological Protection (ICRP) deposition model, and we examined how these deposition fractions vary in different air quality conditions.

More details in the discussion concerning temporal variations in aerosol size distributions, the factors affecting those variations, and variations in deposition fractions in the human body are presented.

Keywords: aerosol, size distribution, deposition fraction, lognormal distribution mode.

 

How to cite: An, C., Kim, S., and Choi, W.: Variations in aerosol size distributions and deposition fractions in human body based on long-term observations (2007 to 2018), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19389, https://doi.org/10.5194/egusphere-egu2020-19389, 2020.

East Asia has suffered from severe air pollution, particularly concerning particulate matter less than 2.5 µm in diameter (PM2.5). Although air quality in Korea has been gradually improved with respect to annual mean PM2.5 and PM10 concentrations, high PM pollution events have been worse in their peak concentrations and durations.

In this study, we attempted to find statistically how the characteristics of PM2.5 pollution over Korea have changed with a focus on temporal and spatial variations. Hourly PM2.5 concentration data were obtained from 374 air quality monitoring stations (AQMS) throughout the country from January 2015 to June 2019. With obtained air quality data, we selected high PM pollution periods based on the national air pollution standard, and examined how the magnitudes and durations of high PM pollution events, as well as the background concentrations, have changed since 2015 over Korea. Additionally, we applied the time-lag correlation method to see how the onsets of PM2.5 pollution events differ in space and how high PM2.5 spread out in time. We also applied the coefficient of divergence (COD) to countrywide datasets of PM2.5 as a measure of spatial heterogeneity of PM2.5 distributions.

Although annual mean concentrations of PM2.5 tend to decline from 2015 to 2018, the peak concentrations and durations for severe PM2.5 pollution events tend to increase in most regions of Korea for the periods of January to April. We also categorized the characteristic distribution patterns in severe PM events combining the time-lag correlation and COD results. In most pollution events, the time-lag distributions showed clear delay patterns of pollution events from the reference area (Seoul). Additionally, COD results showed a clear heterogeneity of PM2.5 distributions as the distance from the reference area increases along the time-lag. Although spatial correlations and COD results of PM2.5 concentrations between the reference area and other regions indicated heterogeneous distributions, time-lag corrected COD values imply that PM2.5 over much wider regions of Korea are homogeneously distributed in both magnitudes and temporal variations. The R2 values were significantly improved after time-lag correction. These results imply that high PM2.5 events are significantly affected by synoptic weather conditions over most regions of Korea; thus, potential modification of synoptic weather patterns in East Asia caused by climate change can be an important factor for variations in high PM2.5 pollution events.

Keywords: coefficient of divergence (COD), PM2.5 pollution events, spatial heterogeneity of PM distributions, pattern analysis.

How to cite: Han, S., Park, Y., and Choi, W.: Spatiotemporal variability patterns of PM2.5 in severe pollution events based on a large dataset from air quality monitoring stations over South Korea, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19493, https://doi.org/10.5194/egusphere-egu2020-19493, 2020.

EGU2020-20589 | Displays | AS3.1

A process model to predict the faith of clusters in CI-APi-TOF mass spectrometers

Ivo Neefjes, Tommaso Zanca, Jakub Kubecka, Evgeni Zapadinsky, Monica Passananti, Theo Kurtén, and Hanna Vehkamäki
Recent technological developments have made it possible to detect the elemental composition of even the smallest airborne clusters at low ambient concentrations through chemical ionization atmospheric pressure interface time-of-flight mass spectrometry (CI-APi-TOF-MS). The charging process and collisions inside the instrument will however affect the molecular composition of the original sample clusters. A process model is therefore needed to connect the mass spectra to the original molecular clusters in the measured sample.
 
Our research has been focused on developing this process model for clusters involving highly oxygenated organic molecules (HOM) with molecular formula C10H16O8. This elemental composition corresponds to one of the most common mass peaks observed in experiments on ozone-initiated autoxidation of α-pinene.
 
For the model, two situations inside the mass spectrometer have to be taken into account: the chemical ionization and collisions with carrier gas inside the atmospheric pressure interface. Recently, a model predicting the fragmentation of clusters as a result of collisions in APi has been developed by Zapadinsky et al. (2018). We used this model to perform numerical simulations of fragmentation in the APi on our selected clusters. The results show that fragmentation is highly unlikely for the considered clusters, provided their bonding energy is large enough to allow formation in the atmosphere in the first place.
 
Current research is focused on developing a model for the charging process inside CI-APi-TOF MS. Configurational sampling is combined with high quality quantum chemistry calculations to derive the binding energies and evaporation rates of the studied clusters. This model should eventually connect the ionized clusters after charging to the original distribution of neutral clusters in the measured sample.

How to cite: Neefjes, I., Zanca, T., Kubecka, J., Zapadinsky, E., Passananti, M., Kurtén, T., and Vehkamäki, H.: A process model to predict the faith of clusters in CI-APi-TOF mass spectrometers, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20589, https://doi.org/10.5194/egusphere-egu2020-20589, 2020.

EGU2020-21035 | Displays | AS3.1 | Highlight

Blooming trees as a source of fine (< 5μm) aerosol particles

Jürgen Gratzl, Teresa M Seifried, Paul Bieber, Hinrich Grothe, and Julia Burkart

During the blooming season of trees, pollen is an important component of the atmospheric aerosol, even in urban areas. Wind pollinated plants such as early flowering trees (e.g. birch, alder) release pollen grains in extremely large quantities. Once in the atmosphere pollen can impact human health and cloud formation (Schäppi et al. 1999, Pummer et al. 2012, Steiner et al. 2015). Intact pollen grains are rather large with geometrical diameters from 10-100 μm and therefore have short residence times in the atmosphere. However, it is known that under certain conditions (high humidity and after germination) pollen grains release cytoplasmic material including starch granules from their interior, commonly referred to as subpollen particles (SPP). Studies have shown that the cytoplasmic material contains cloud active substances and allergens (Steiner et al. 2015, Pummer et al. 2012, Basci et al. 2006). How and if this material becomes airborne and whether it distributes in the atmosphere is still an open question. Motivated by this question we took a detailed look at the particles shed from blooming catkins.

In this study freshly harvested branches with flowering catkins of different trees were put in an aerosol chamber. An Aerodynamic Particle Sizer (TSI Spectrometer 3321; 0.5 – 20 μm) and a Cascade Impactor (Sioutas; 2.5 μm, 1.0 μm, 0.50 μm, 0.25 μm) were attached to the chamber to sample the released aerosol. The catkins were agitated with puffs of clean air to simulate wind. The aerodynamic diameters of the released particles were recorded and the filters of the impactor were analyzed with a Scanning Electron Microscope and a light microscope. We find that not only large pollen grains are released but also smaller particles. Up to 50% of all released particles were in the size range from (0.5 – 5 μm). Additionally, we find that the aerodynamic diameter of pollen grains is in general smaller than their geometrical diameter. For instance, the aerodynamic diameter of pollen grains from birch is 30-70% smaller than the geometrical diameter.

 

References:
Schäppi, G. F.; Taylor, P. E.; Pain, M. C.; Cameron, P. A.; Dent, A. W.; Staff, I. A. & Suphioglu, C.; Concentrations of major grass group 5 allergens in pollen grains and atmospheric particles: implications for hay fever and allergic asthma sufferers sensitized to grass pollen allergens.; Clinical and experimental allergy: journal of the British Society for Allergy and Clinical Immunology, 1999, 29, 633-641
Pummer, B. G.; Bauer, H.; Bernardi, J.; Bleicher, S. & Grothe, H.; Suspendable macromolecules are responsible for ice nucleation activity of birch and conifer pollen; Atmospheric Chemistry and Physics, Copernicus GmbH, 2012, 12, 2541-2550
Steiner, A. L.; Brooks, S. D.; Deng, C.; Thornton, D. C. O.; Pendleton, M. W. & Bryant, V.; Pollen as atmospheric cloud condensation nuclei; Geophysical research letters, Wiley Online Library, 2015, 42, 3596-3602
Bacsi, A.; Choudhury, B. K.; Dharajiya, N.; Sur, S. & Boldogh, I.; Subpollen particles: carriers of allergenic proteins and oxidases; Journal of Allergy and Clinical Immunology, Elsevier, 2006 , 118 , 844-850

How to cite: Gratzl, J., Seifried, T. M., Bieber, P., Grothe, H., and Burkart, J.: Blooming trees as a source of fine (< 5μm) aerosol particles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21035, https://doi.org/10.5194/egusphere-egu2020-21035, 2020.

The earth observing satellites including the low earth orbit (LEO) and geostationary orbit (GEO) platforms have been provided the geophysical data. Spectral radiances measured by a satellite-borne sensor are sensitive to both atmospheric transmission and surface reflection. These volumetric data were used to retrieve atmospheric transmission and surface reflection which can be useful to derive surface reflectance (SR) and aerosol optical thickness (AOT). Based on the extensive radiative transfer simulations with the LEO satellite’s operational atmospheric products, it is demonstrated that the use of the combined LEO and GEO satellite measurements allows for timely retrieval of SR and AOT at a reasonable accuracy. The method for both the Geostationary Ocean Color Imager (GOCI) and the Landsat-8 Operational Land Imager (OLI) data. After the spatial and temporal collocations between two different orbit data, the atmospheric correction of both satellite’s spectral reflectances showed that the averaged changes of reflectance in 10% to 30%. Moreover, comparisons with the other operational products of SR and AOT such as the ground-based Aerosol Robotic Network (AERONET) showed retrieval error of within ±5.6% SR and ±9.8% AOT. Combining the LEO and GEO satellite data are effective method for the atmospheric correction and geophysical parameter retrieval. Further work will be applied to the next generation geostationary satellites, namely the Geostationary Earth Orbit Korea Multi-Purpose Satellite (GEO-KOMPSAT-2A and -2B) platforms.

Acknowledgement
This subject is supported by the Korea Aerospace Research Institute (KARI) (FR19920W05) and Korea Ministry of Environment (MOE) as "Public Technology Program based on Environmental Policy (2017000160003).

 

How to cite: Lee, K.-H. and Yum, J.-M.: Aerosol remote sensing from the integrated LEO and GEO satellite observation data by determination of atmospheric transmission and surface reflection, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21280, https://doi.org/10.5194/egusphere-egu2020-21280, 2020.

EGU2020-21531 | Displays | AS3.1

Reconciling multiphase reactivity of oleic acid with ozone using a kinetic flux model

Coraline Mattei, Manabu Shiraiwa, Ulrich Pöschl, and Thomas Berkemeier

The ozonolysis of oleic acid on aerosol particles has been extensively studied in the past and is often used as a benchmark reaction for the study of organic particle oxidation. However, to date, no single kinetic model has reconciled the vastly differing reactive uptake coefficients reported in the literature that were obtained at different oxidant concentrations, particle sizes and with various commonly used laboratory setups (single-particle trap, aerosol flow tube, and environmental chamber). We combine the kinetic multi-layer model of aerosol surface and bulk chemistry (KM-SUB, Shiraiwa et al. 2012) with the Monte Carlo Genetic Algorithm (MCGA, Berkemeier et al. 2017) to simultaneously describe nine experimental data sets with a single set of kinetic parameters. The KM-SUB model treats chemistry and mass transport of reactants and products in the gas and particle phases explicitly, based on molecular-level chemical and physical properties. The MCGA algorithm is a global optimization routine that aids in unbiased determination of these model parameters and can be used to assess parameter uncertainty. This methodology enables us to derive information from laboratory experiments using a “big data approach” by accounting for a large amount of data at the same time.

We show that a simple reaction mechanism including the surface and bulk ozonolysis of oleic acid only allows for the reconciliation of some of the data sets. An accurate description of the entire reaction system can only be accomplished if secondary chemistry is considered and present an extended reaction mechanism including reactive oxygen intermediates. The presence of reactive oxygen species on surfaces of particulate matter might play an important role in understanding aerosol surface phenomena, organic aerosol evolution, and their health effects.

 

References

Berkemeier, T. et al.: Technical note: Monte Carlo genetic algorithm (MCGA) for model analysis of multiphase chemical kinetics to determine transport and reaction rate coefficients using multiple experimental data sets, Atmos. Chem. Phys., 17, 8021-8029, 2017.

Shiraiwa, M., Pfrang, C., and Pöschl, U.: Kinetic multi-layer model of aerosol surface and bulk chemistry (KM-SUB): the influence of interfacial transport and bulk diffusion on the oxidation of oleic acid by ozone, Atmos. Chem. Phys., 10, 3673-3691, 2010.

How to cite: Mattei, C., Shiraiwa, M., Pöschl, U., and Berkemeier, T.: Reconciling multiphase reactivity of oleic acid with ozone using a kinetic flux model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21531, https://doi.org/10.5194/egusphere-egu2020-21531, 2020.

EGU2020-21614 | Displays | AS3.1

Improved identification of evaporation rates and thermodynamic data by Monte-Carlo method

Anna Shcherbacheva, Tapio Helin, Heikki Haario, and Hanna Vehkamäki

Atmospheric new particle formation and successive cluster growth to aerosol particles is an important field of research, in particular due to climate change phenomena and air quality monitoring. Recent developments in the instrumentation have enabled quantification of ionic clusters formed in the gas phase at the first steps of particle formation under atmospherically relevant mixing ratios. However, electrically neutral clusters are prevalent in atmospheric conditions, and thus must be charged prior to detection by mass spectrometer. The charging process can lead to cluster fragmentation and thus alter the measured cluster composition.

Even when the cluster composition can be measured directly, this does not quantify individual cluster-level properties, such as cluster collision and evaporation rates. Collision rates contain relatively small uncertainties in comparison to evaporation rates, which are computed using detailed balance assumption together with the free energies of cluster formation, which can in turn be obtained from Quantum chemistry (QC) methods. As evaporation rates depend exponentially on the free energies, even difference by several kcal/mol between different QC methods results in orders of magnitude differences in evaporation rates.

On the other hand, in spite of the error margins associated with the evaporation rates, simulations of cluster populations, which incorporate collision and evaporation rates as free parameters (such as Becker-Döring models), have demonstrated good qualitative agreement with experimental data. The Becker-Döring equations are a system of Ordinary Differential equations (ODE) which account for cluster birth and death processes, as well as external sinks and sources. In mathematical terms, prediction of cluster concentrations using kinetic simulations with given cluster collision and evaporation rates is called a forward problem.

In the present study, we focus on the so-called inverse problem of how to derive the evaporation rates and thermodynamic data (enthalpy change and entropy change due to addition or removal of molecule) from available measurements, rather than on the forward problem. We do this by Delayed Rejection Adaptive Monte Carlo (DRAM) method for the system containing sulfuric acid and ammonia with the maximal size of the pentamer. Initially, we tested the method on the synthetic data created from Atmospheric Cluster Dynamic Code (ACDC) simulations. By so doing, we identify the combination of fitted parameters and concentration measurements, which leads to the best identification of the evaporation rates. Additionally, we demonstrated that the temperature-dependent data yield better estimates of the evaporation rates as compared to the time-dependent data measured before the system has reached the steady state.

Next, we apply the technique to improve the identification of the evaporation rates from CLOUD chamber data, which contain cluster concentrations and new particle formation rates measured at different temperatures and a wide range of atmospherically relevant sulfuric acid and ammonia concentrations. As a result, we were able to obtain the probability density functions (PDFs) that show small standard variations for thermodynamic data. By using the values from the PDFs as parameters in the ACDC model, we achieve a fair agreement with the measured NPFs and cluster concentrations for a wide range of temperatures.

How to cite: Shcherbacheva, A., Helin, T., Haario, H., and Vehkamäki, H.: Improved identification of evaporation rates and thermodynamic data by Monte-Carlo method, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21614, https://doi.org/10.5194/egusphere-egu2020-21614, 2020.

EGU2020-21640 | Displays | AS3.1

Source apportionment of time- and size-resolved particulate matter over two sites in New Delhi & NCR

Suneeti Mishra, Sachchida Tripathi, Navaneeth Thamban, Vipul Lalchandani, Varun Kumar, Pragati Rai, Shashi Tiwari, Dilip Ganguly, Deepika Bhattu, Jay Slowik, and Andre Prevot

Size resolved data of chemical species carries a lot of latent information about the sources and atmospheric processes which lead to their formation and growth. Source apportionment techniques on organic or inorganic aerosols provide a fair amount of information about the sources but this analysis only provides a partial picture owing to the complicated nature of the ambient aerosols which may contain both, organic as well as inorganic particulate matter. Traditionally, potential emission sources are distinguished by either the organic or inorganic tracers present in ambient aerosol, but recently several studies have performed PMF on both the species (Sun et al, 2012). However, it tells more about the final transformed products which could be formed from different pathways but not much about the transformation pathways. Insights about the source and the atmospheric processes involved can be derived from the analysis of size-resolved data of the ambient aerosol. PMF on Size-resolved information helps us to narrow down the possible pathways of the transformed products.

However, there is very limited literature available to help us understand more about size-resolved bulk particulate matter. In this manuscript, a novel approach to perform Positive Matrix Factorization (PMF) on real-time size-resolved Unit Mass Resolution (UMR) data from Aerosol Mass Spectrometer (AMS) is presented. Both size- and time-resolved PMF is performed on non-refractory particle composition (organic & inorganic) on the UMR PTOF data of two sites in one of the most polluted cities in the world. The sampling through Long Time of flight mass spectrometer (LToF-AMS) was carried out at Indian Institute of Technology, Delhi which is located in Hauz Khaz area, at the heart of Delhi NCR, whereas parallel sampling through High-resolution Time of flight aerosol mass spectrometer (HR-ToF-AMS) was carried out at Manav Rachna University which is located in Faridabad within Delhi NCR at a downwind location. PMF was performed on the data by using Multi-linear Engine (ME-2) on PMF model by SoFi (Source Finder) tool. A seven-factor solution was chosen based on the factor profiles, time series, diurnals and correlation with the external factors obtained by supplementary instruments. The size-resolved spectra of the species at an individual site was studied and the difference between the sites was compared.

How to cite: Mishra, S., Tripathi, S., Thamban, N., Lalchandani, V., Kumar, V., Rai, P., Tiwari, S., Ganguly, D., Bhattu, D., Slowik, J., and Prevot, A.: Source apportionment of time- and size-resolved particulate matter over two sites in New Delhi & NCR, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21640, https://doi.org/10.5194/egusphere-egu2020-21640, 2020.

EGU2020-21813 | Displays | AS3.1

Chemical characterization of fine particulate matter, and source apportionment of organic aerosol at three sites in New Delhi, India

Sachchida Tripathi, Vipul Lalchandani, Varun Kumar, Anna Tobler, Navaneeth Thamban, Suneeti Mishra, Jay Slowik, Deepika Bhattu, Dilip Ganguly, Shashi Tiwari, and Andre Prevot

Atmospheric particulate matter has adverse effects on human health, and causes over 4 million deaths per year globally. New Delhi was ranked as world’s most polluted megacity with annual average PM2.5 concentration of ~140 ug.m-3. Thus, real time chemical characterization of fine particulate matter and identification of its sources is important for developing cost effective mitigation policies.

Highly time resolved real-time chemical composition of PM2.5 was measured using Long-Time of Flight-Aerosol Mass Spectrometer (L-ToF-AMS) at Indian Institute of Technology Delhi and Time of Flight-Aerosol Chemical Speciation Monitor (ToF-ACSM) at Indian Institute of Tropical Meteorology, Delhi, and PM1 using High Resolution-Time of Flight-Aerosol Mass Spectrometer (HR-ToF-AMS) at Manav Rachna International University, Faridabad, Haryana located ~40 km downwind of Delhi during Jan-March, 2018. Black carbon concentration was measured using Aethalometer at all three sites. Unit mass resolution (UMR) and high resolution (HR) data analysis were performed on AMS and ACSM mass spectra to calculate organics, nitrate, sulfate and chloride concentrations. Positive Matrix Factorization (PMF) (Paatero and Tapper, 1994) of organic mass spectra was performed by applying multilinear engine (ME-2) algorithm using Sofi (Source finder) for identifying sources of OA.

How to cite: Tripathi, S., Lalchandani, V., Kumar, V., Tobler, A., Thamban, N., Mishra, S., Slowik, J., Bhattu, D., Ganguly, D., Tiwari, S., and Prevot, A.: Chemical characterization of fine particulate matter, and source apportionment of organic aerosol at three sites in New Delhi, India, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21813, https://doi.org/10.5194/egusphere-egu2020-21813, 2020.

AS3.2 – Atmospheric composition variability and trends

EGU2020-3115 | Displays | AS3.2

Multidecadal trend analysis of aerosol radiative properties at a global scale

Martine Collaud Coen, Elisabeth Andrews, Cathrine Lund Myhre, Jenny Hand, Marco Pandolfi, and Paolo Laj and the SARGAN: trend analysis of aerosol radiative properties

In order to assess the global evolution of aerosol parameters affecting climate change, a long-term trend analyses of aerosol optical properties were performed on time series from 52 stations situated across five continents. The time series of measured scattering, backscattering and absorption coefficients as well as the derived single scattering albedo, backscattering fraction, scattering and absorption Ångström exponents covered at least 10 years and up to 40 years for some stations. The non-parametric seasonal Mann-Kendall (MK) statistical test associated with several prewhitening methods and with the Sen’s slope were used as main trend analysis methods. Comparisons with General Least Mean Square associated with Autoregressive Bootstrap (GLS/ARB) and with standard Least Mean Square analysis (LMS) enabled confirmation of the detected MK statistically significant trends and the assessment of advantages and limitations of each method. Currently, scattering and backscattering coefficients trends are mostly decreasing in Europe and North America and are not statistically significant in Asia, while polar stations exhibit a mix of increasing and decreasing trends. A few increasing trends are also found at some stations in North America and Australia. Absorption coefficients time series also exhibit primarily decreasing trends. For single scattering albedo, 52% of the sites exhibit statistically significant positive trends, mostly in Asia, Eastern/Northern Europe and Arctic, 18% of sites exhibit statistically significant negative trends, mostly in central Europe and central North America, while the remaining 30% of sites have trends, which are not statistically significant. In addition to evaluating trends for the overall time series, the evolution of the trends in sequential 10 year segments was also analyzed. For scattering and backscattering, statistically significant increasing 10 year trends are primarily found for earlier periods (10 year trends ending in 2010-2015) for polar stations and Mauna Loa. For most of the stations, the present-day statistically significant decreasing 10 year trends of the single scattering albedo were preceded by not statistically significant and statistically significant increasing 10 year trends. The effect of air pollution abatement policies in continental North America is very obvious in the 10 year trends of the scattering coefficient – there is a shift to statistically significant negative trends in 2010-2011 for all stations in the eastern and central US. This long-term trend analysis of aerosol radiative properties with a broad spatial coverage enables a better global view of potential aerosol effects on climate changes.

How to cite: Collaud Coen, M., Andrews, E., Lund Myhre, C., Hand, J., Pandolfi, M., and Laj, P. and the SARGAN: trend analysis of aerosol radiative properties: Multidecadal trend analysis of aerosol radiative properties at a global scale , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3115, https://doi.org/10.5194/egusphere-egu2020-3115, 2020.

EGU2020-3568 | Displays | AS3.2

Global variability of aerosol optical properties retrieved from the network of GAW near-surface observatories

Alessandro Bigi, Martine Collaud Coen, Elisabeth J. Andrews, Clémence Rose, Cathrine Lund Myhre, Markus Fiebig, Michael Schulz, John A. Ogren, Jonas Gliss, Augustin Mortier, Alfred Wiedensohler, Marco Pandolfi, Tuukka Petäja, Sang-Woo Kim, Wenche Aas, Jean-Philippe Putaud, Olga Mayol-Bracero, Melita Keywood, Lorenzo Labrador, and Paolo Laj

Atmospheric aerosols are known to play a key role in Earth’s radiative budget, although the quantification of their climate forcing is still highly uncertain. In order to improve the scientific understanding of their climatic effect, in-situ ground-based aerosol properties observations are needed by the research community. Such data would also allow the global assessment of the effect of environmental policies over both the short and the long term.

To develop a robust and consistent view over time of the worldwide variability of aerosol properties, data resulting from a fully-characterized value chain, including uncertainty estimation, is needed.

The present work is part of a wider project, having among its goals the investigation of the variability of climate-relevant aerosol properties observed at all sites connected to the Global Atmospheric Watch network, whose data are publicly available from the World Data Centre for Aerosols and follow the aforementioned specifications.

This work focuses on aerosol optical proprieties, i.e. the aerosol light scattering coefficient (σsp), the aerosol light absorption coefficient (σap), single scattering albedo (ωo) and both scattering and absorption Ångström exponents (åsp and åap).

The analysis includes 108 yearly datasets collected either during 2016 or 2017 at different sites: 53 for absorption and 55 for scattering coefficient datasets, respectively. For 29 of these sites it was also possible to compute single scattering albedo.

The spatial variability in extensive and intensive optical properties was analysed in terms of each site’s geographical location (either polar, continental, coastal or mountain) and its footprint (from pristine to urban, representing increasing levels of anthropogenic influence).

The results highlight the impact of anthropogenic emissions and biomass burning on absolute levels and annual variability. The effect of sea spray or long range transport of dust is also evident for several sites, along with the influence of regional emissions. The largest seasonality in aerosol loading was observed at mountain sites under mixed footprint conditions, while the lowest seasonality occurred at urban sites. Urban sites also exhibited the highest σsp and σap values. The lowest levels in σsp and σap were observed at some polar sites, along with few coastal and mountain sites, despite their typically mixed footprint.

Acknowledgements

The authors acknowledge WMO-GAW World Data Centre on Aerosol for providing data available at http://ebas.nilu.no

How to cite: Bigi, A., Collaud Coen, M., Andrews, E. J., Rose, C., Lund Myhre, C., Fiebig, M., Schulz, M., Ogren, J. A., Gliss, J., Mortier, A., Wiedensohler, A., Pandolfi, M., Petäja, T., Kim, S.-W., Aas, W., Putaud, J.-P., Mayol-Bracero, O., Keywood, M., Labrador, L., and Laj, P.: Global variability of aerosol optical properties retrieved from the network of GAW near-surface observatories, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3568, https://doi.org/10.5194/egusphere-egu2020-3568, 2020.

EGU2020-6161 | Displays | AS3.2

Aerosol Optical Depth Measurements at high altitude and polar WMO Global Atmospheric Watch - PFR Network Stations

Stelios Kazadzis, Natalia Kouremeti, and Julian Groebner

Multiwavelength aerosol optical depth (AOD) has been defined as an essential climate variable for the Global Climate Observing System (GCOS) and the Global Atmosphere Watch (GAW) Program of the World Meteorological Organization. It is the most important parameter related to aerosol radiative forcing studies. PMOD/WRC have developed the Precision Filter Radiometer (PFR) that has been used for long term AOD measurements under a GAW-PFR Network of sun-photometers started in 1995 at Davos Switzerland and from 1999 at other locations, worldwide.

Here we present:

An overview of the results of the long term GAW-PFR AOD series for four high altitude stations (Izana/Spain, Mauna Loa/USA, Mt. Walliguan/China and Jungfraujoch/Switzerland). Mean AODs at 500nm were from 0.015 up to 0.096 with small negative changes per year for all stations.

An overview of the results for polar stations (Ny Ålesund/Norway, Summit/Denmark, Marambio/Finland). Ny Ålesund mean AODs at 500nm were almost double compared with the other stations.

How to cite: Kazadzis, S., Kouremeti, N., and Groebner, J.: Aerosol Optical Depth Measurements at high altitude and polar WMO Global Atmospheric Watch - PFR Network Stations , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6161, https://doi.org/10.5194/egusphere-egu2020-6161, 2020.

EGU2020-2147 | Displays | AS3.2 | Highlight

A global analysis of climate-relevant aerosol properties retrieved from the network of GAW near-surface observatories

Paolo Laj, Clémence Rose, Alessandro Bigi, Martine Collaud Coen, Elisabeth Andrews, Cathrine Lund Myhre, Markus Fiebig, Wenche Aas, Alfred Wiedensohler, Michael Schulz, Augustin Mortier, Jonas Gliss, Jean-Philippe Putaud, Sang-Woo Kim, Olga Mayol, Melita Keywood, Tuukka Petäjä, Marco Pandolfi, Lorenzo Labrador, and John Ogren and the SARGAN team

Aerosol particles are essential constituents of the Earth’s atmosphere, impacting the earth radiation balance directly by scattering and absorbing solar radiation, and indirectly by acting as cloud condensation nuclei. In contrast to most greenhouse gases, aerosol particles have short atmospheric residence time resulting in a highly heterogeneous distribution in space and time. There is a clear need to document this variability at regional scale through observations involving, in particular, the in-situ near-surface segment of the atmospheric observations system. This paper will provide the widest effort so far to document variability of climate-relevant in-situ aerosol properties (namely wavelength dependent particle light scattering and absorption coefficients, particle number concentration and particle number size distribution) from all sites connected to the Global Atmosphere Watch network. High quality data from more than 90 stations worldwide have been collected and controlled for quality and are reported for a reference year in 2017, providing a very extended and robust view of the variability of these variables worldwide. The range of variability observed worldwide for light scattering and absorption coefficients, single scattering albedo and particle number concentration are presented together with preliminary information on their long-term trends and comparison with model simulation for the different stations. The scope of the present paper is also to provide the necessary suite of information including data provision procedures, quality control and analysis, data policy and usage of the ground-based aerosol measurements network. It delivers to users of the World Data Centre on Aerosol, the required confidence in data products in the form of a fully-characterized value chain, including uncertainty estimation and requirements for contributing to the global climate monitoring system.

How to cite: Laj, P., Rose, C., Bigi, A., Collaud Coen, M., Andrews, E., Lund Myhre, C., Fiebig, M., Aas, W., Wiedensohler, A., Schulz, M., Mortier, A., Gliss, J., Putaud, J.-P., Kim, S.-W., Mayol, O., Keywood, M., Petäjä, T., Pandolfi, M., Labrador, L., and Ogren, J. and the SARGAN team: A global analysis of climate-relevant aerosol properties retrieved from the network of GAW near-surface observatories, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2147, https://doi.org/10.5194/egusphere-egu2020-2147, 2020.

EGU2020-17221 | Displays | AS3.2

Evaluation of climate model aerosol trends with ground-based observations over the last two decades – an AeroCom and CMIP6 analysis

Augustin Mortier, Jonas Gliss, and Michael Schulz and the climate models and aerosol measurements group

This study presents a multi-parameter analysis of aerosol trends over the last two decades at regional and global scales. Regional time series have been computed for a set of nine optical, chemical composition and mass aerosol properties by using the observations of several ground-based networks. From these regional time series the aerosol trends have been derived for different regions of the world. Most of the properties related to aerosol loading exhibit negative trends, both at the surface and in the total atmospheric column. Significant decreases of aerosol optical depth (AOD) are found in Europe, North America, South America and North Africa, ranging from −1.3 %/yr to −3.1 %/yr. An error and representativity analysis of the incomplete observational data has been performed using model data subsets in order to investigate how likely the observed trends represent the actual trends happening in the regions over the full study period from 2000 to 2014. This analysis reveals that significant uncertainty is associated with some of the regional trends due to time and space sampling deficiencies. The set of observed regional trends has then been used for the evaluation of the climate models and their skills in reproducing the aerosol trends. Model performance is found to vary depending on the parameters and the regions of the world. The models tend to capture trends in AOD, column Angstrom exponent, sulfate and particulate matter well (except in North Africa), but show larger discrepancies for coarse mode AOD. The rather good agreement of the trends, across different aerosol parameters between models and observations, when co-locating them in time and space, implies that global model trends, including those in poorly monitored regions, are likely correct. The models can help to provide a global picture of the aerosol trends by filling the gaps in regions not covered by observations. The calculation of aerosol trends at a global scale reveals a different picture from the one depicted by solely relying on ground based observations. Using a model with complete diagnostics (NorESM2) we find a global increase of AOD of about 0.2 %/yr between 2000 and 2014, primarily caused by an increase of the loads of organic aerosol, sulfate and black carbon.

How to cite: Mortier, A., Gliss, J., and Schulz, M. and the climate models and aerosol measurements group: Evaluation of climate model aerosol trends with ground-based observations over the last two decades – an AeroCom and CMIP6 analysis, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17221, https://doi.org/10.5194/egusphere-egu2020-17221, 2020.

Within the framework of the AeroCom (Aerosol Comparisons between Observations and Models) initiative, the present day modelling of aerosol optical properties has been assessed using simulated data representative for the year 2010, from 14 global aerosol models participating in the Phase III Control experiment. The model versions are close or equal to those used for CMIP6 and AerChemMIP and inform also on bias in state of the art Earth-System-Models (ESMs).
Modelled column optical depths (total, fine and coarse mode AOD) and Angstrom Exponents (AE) were compared both with ground based observations from the Aerosol Robotic Network (AERONET, version 3) and space based observations from the AATSR instrument. In addition, the modelled AODs were compared with MODIS (Aqua and Terra) data and a satellite AOD data-set (MERGED-FMI) merged from 12 different individual AOD products. Furthermore, for the first time, the modelled near surface scattering (under dry conditions) and absorption coefficients were evaluated against measurements made at low relative humidity at surface in-situ GAW sites. 
The AeroCom MEDIAN and most of the participating models underestimate the optical properties investigated, relative to remote sensing observations. AERONET AOD is underestimated by 21%+/-17%. Against satellite data, the model AOD biases range from -38% (MODIS-terra) to -17% (MERGED-FMI). Correlation coefficients of model AODs with AERONET, MERGED-FMI and AATSR-SU are high (0.8-0.9) and slightly lower against the two MODIS data-sets (0.6-0.8). Investigation of fine and coarse AODs from the MEDIAN model reveals biases of -10%+/-20% and -41%+/-29% against AERONET and -13% and -24% against AATSR-SU, respectively. The differences in model bias against AERONET and AATSR-SU are in agreement with the established bias of AATSR against AERONET. These results indicate that most of the AOD bias is due to missing coarse AOD in the regions covered by these observations. Underestimates are also found when comparing the models against the surface GAW observations, showing AeroCom MEDIAN mean bias and inter-model variation of -44%+/-22% and -32%+/-34% for scattering and absorption coefficients, respectively. Dry scattering shows higher underestimation than AOD at ambient relative humidity and is in agreement with recent findings that suggest that models tend to overestimate scattering enhancement due to hygroscopic growth. 
Considerable diversity is found among the models in the simulated near surface absorption coefficients, particularly in regions associated with dust (e.g. Sahara, Tibet), biomass burning (e.g. Amazonia, Central Australia) and biogenic emissions (e.g. Amazonia). Regions associated with high anthropogenic BC emissions such as China and India exhibit comparatively good agreement for all models. Evaluation of modelled column AEs shows an underestimation of 9%+/-24% against AERONET and -21% against AATSR-SU. This suggests that models tend to overestimate particle size, with implications for lifetime and radiative transfer calculations. An investigation of modelled emissions, burdens and lifetimes, mass-specific-extinction coefficients (MECs) and optical depths (ODs) for each species and model reveals considerable diversity in most of these parameters. Inter-model spread of aerosol species lifetime appears to be similar to that of mass extinction coefficients, suggesting that AOD uncertainties are still associated to a broad spectrum of parameterised aerosol processes.

How to cite: Gliß, J., Mortier, A., and Schulz, M. and the AeroCom modellers and aerosol measurements team: Multi-model evaluation of aerosol optical properties in the AeroCom phase III Control experiment, using ground and space based observations from AERONET, MODIS, AATSR and a merged satellite product as well as surface in-situ observations from GAW sites, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18390, https://doi.org/10.5194/egusphere-egu2020-18390, 2020.

EGU2020-1831 | Displays | AS3.2

Long-term AOD trend analysis and Classification of major aerosol types over Iran from 1980 to 2018

Robabeh Yousefi, Fang Wang, Quansheng Ge, Abdallah Shaheen, and Juerg Luterbacher

Based on the importance of the effects of aerosols on climate pattern change, our study contributes towards a better understanding of the Aerosol Optical Depth (AOD) trends from different datasets and the contribution of each dominant aerosol over Iran. A long-term AOD dataset (1980–2018) from the reanalysis-based Modern Era Retrospective Analysis for Research and Applications (MERRA-2) and the satellite-based Moderate Resolution Imaging Spectroradiometer (MODIS) /Terra Collection 6.1(C6.1) and Level 2 (L2) in the years 2001-2018. The result of AOD trend showed some differences between MERRA-2 and MODIS in autumn and winter.  But, generally, the increasing and slightly decreasing trends appeared over the southwest and north of the country, respectively. The upward trend was mainly observed in the southwest of Iran because of the proximity to the major source areas of natural mineral dust in spring and summer of both AOD datasets which was also obtained in the regional trend analysis and the city of Ahvaz experienced a strong positive trend compared with other selected cities. Also, an unforeseen downward trend was observed in the last decade. Finally, the classification of major aerosol types during 1980-2018 indicated that the mixed aerosols (43.28%) and clean marine (37.38%) were the dominate aerosols followed by the clean continental (9.78%) and desert dust (5.56%) with minor contributions of biomass burning/urban industrial (3.98%) aerosols. Later, the increase of desert dust around 2010 was another obvious result in spring and summer. Our study results indicate that the variation in dust aerosols has a key role in determining the AOD changes in Iran which are contributed in regional climate change and environmental evolutions.

How to cite: Yousefi, R., Wang, F., Ge, Q., Shaheen, A., and Luterbacher, J.: Long-term AOD trend analysis and Classification of major aerosol types over Iran from 1980 to 2018, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1831, https://doi.org/10.5194/egusphere-egu2020-1831, 2020.

Abstract: Ecological region in southern China has been perennially affected by monsoon climate and anthropogenic emissions, resulting in complex aerosol components and frequent long-range transport. In this study, a Santa Barbara DISORT Atmospheric Radiative Transfer (SBDART) model is applied to estimate aerosol radiative forcing (ARF) and multiple aerosol observation datasets is used to estimate the aerosol chemical components and optical properties. The aerosol loading and the radiative effects in the ecological region exhibited strong seasonal changes. The average major components (NH4+, NO3, SO42−) in Total water soluble ionic (TWSI) ,organic carbon (OC) concentration, the ratio of organic carbon to element carbon (OC/EC) and biogenic secondary organic aerosol (BSOA) tracers were 3.20±1.22 μg·m-3, 2.19±1.39 μg·m-3, 3.17 and 74.00±35.23 ng·m-3 in the dry season and 2.22±0.91 μg·m-3, 3.14±1.62 μg·m-3, 7.13 and 186.34±113.82 ng·m-3 in the wet season, respectively. The average radiative forcing at the top of atmosphere (TOA) is -11.73±11.36 W/m2 and -0.41±10.08 W/m2 in dry and wet season. When the aerosol single scattering albedo (SSA) less than 0.9, the retrieve frequency in wet season reached account for 75%. The increase of OC and BSOA transformed by forests in the wet season weaken the cooling effects. However, the dry season is mainly composed of anthropogenic inorganic aerosols, which enhances the scattering effect. The aerosol observation baseline also verified the seasonal variation of ARF in the ecological region. Driven by multiple factors such as meteorological conditions, emission sources, and the mixed state of particulate matter, the transport patterns of air masses in ecological area exhibits completely opposite affects to ARF.

How to cite: Yining, M. and Jinyuan, X.: Spatial and temporal heterogeneity in aerosol radiative effects over ecological area in south China: Composition and transmission implications, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4351, https://doi.org/10.5194/egusphere-egu2020-4351, 2020.

Due to their multiple effects on climate and human health, aerosol particles are a key component of the Earth’s atmosphere. The understanding of these effects however remains incomplete, which in turn affects their quantification at the present time as well as future predictions. These limitations highlight the need for continuing the efforts to organize long term monitoring of the climate-relevant aerosol properties in as broad a network as possible.

The value of such measurements, which are performed in compliance with homogenous protocols and meet high quality standards, is clearly demonstrated in the present analysis. This work, which is focused on the particle number concentration and particle number size distribution (PNSD), is part of a wider project, one of the objectives of which is to document the variability of climate-relevant aerosol properties based on available in-situ near-surface measurements. To investigate the spatial variability of the abovementioned aerosol physical properties, observations collected at 57 sites connected to the Global Atmosphere Watch (GAW) network were analysed for a reference year (2017). Measurements performed with condensation particle counters (CPC, 21 sites) and mobility particle size spectrometers (MPSS, 36 sites) were both included in the analysis; in the latter case, the total particle number concentration, Ntot, was calculated over the diameter range 10 – 500 nm.

As a result of enhanced sources, Ntot is generally higher during warmer seasons at all sites (in connection with atmospheric boundary layer dynamics for mountain sites). In addition, based on available MPSS data, the major contribution of Aitken mode particles (30-100 nm) to the total particle number concentration also appears as a common feature of all environments. In contrast, the observed levels of Ntot, between 101 and 104 cm-3, and the magnitude of its seasonal cycle, exhibit, together with the variations of the PNSD, some distinctive behaviour for the different geographical categories and environmental footprint classes, with additional site-dependent characteristics. Among other factors (including the nature and proximity of the particles sources), the level of anthropogenic influence appears to strongly affect the observations.

This work will be completed in the near future with a trend analysis to document the temporal variability of the particle number concentration and PNSD.

How to cite: Rose, C. and the co-workers: Global variability of aerosol physical properties retrieved from the network of GAW near-surface observatories, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9653, https://doi.org/10.5194/egusphere-egu2020-9653, 2020.

EGU2020-3248 | Displays | AS3.2

Characterization of aerosol composition and sources in a polluted city in Central China
not presented

Qingqing Wang, Yele Sun, Jie Li, Yong Chen, and Yanyu Li

Air pollution problem in megacities in China has been significantly improved as annual average PM2.5 in 2019 in Beijing was 42 µg/m3. But is still a serious problem in many smaller cities. Sanmenxia is located in the Fen-Wei Plain, close to China's largest coal base. The annual average PM2.5 of Sanmenxia decreased from 72 µg/m3 in 2015 to 59 µg/m3 in 2019. The highly concentrated industries, especially coal industries, heavy traffic, and the typical terrain that it locates nearby the gorge of the Yellow river, make Sanmenxia a highly polluted city. The highest average PM2.5 was ~100 µg/m3 in winter. Non-refractory PM1 (NR-PM1) species including organic aerosol (Org), sulfate (SO4), nitrate (NO3), ammonium (NH4) and chloride (Chl) were measured at Sanmenxia Environmental Protection Bureau (34.794°N,111.171°E) by the ACSM at a time resolution of ~5 min from December 21, 2018 to January 21, 2019. High time resolution of online meteorological variables, as well as precursor gases, OC/EC, and trace elements were also collected at the site, aiming to characterize the pollution sources and evolution mechanisms of aerosol chemical composition. A long haze episode lasted for 16 days was observed with NR-PM1 = 76±33 µg/m3, PM2.5 = 180±89 µg/m3. During this episode, the primary species, nitrate accounted for 32% of NR-PM1 due to high emission of NOx. Positive matrix factorization (PMF) analysis indicates that industrial emission, coal combustion, traffic emission, and secondary species (sulfate + nitrate + ammonium + secondary organic aerosol) were the major sources of pollution. The diurnal variations of pollutants in Sanmenxia were affected significantly by the vertical movement of air flows, but were not sensitive to the regional transport.

How to cite: Wang, Q., Sun, Y., Li, J., Chen, Y., and Li, Y.: Characterization of aerosol composition and sources in a polluted city in Central China , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3248, https://doi.org/10.5194/egusphere-egu2020-3248, 2020.

EGU2020-655 | Displays | AS3.2

Optical and chemical properties of wintertime light-absorbing aerosols in the eastern Indo-Gangetic Plain, India

Supriya Dey, Archita Rana, Prashant Rawat, and Sayantan Sarkar

Light-absorbing carbonaceous aerosols such as black and brown carbon (BC and BrC) and humic-like substances (HULIS) have pronounced effects on the earth’s radiative balance and tropospheric photochemistry. In India, large heterogeneities exist for BC and organic carbon (OC) emission inventories, which necessitates regionally-representative ground-based measurements. Such measurements are spatially scattered for BC, rare for BrC and non-existent for HULIS. This severely limits a robust understanding of the optical and chemical properties of these aerosols, and consequently, their climate effects. To address this issue, the present study reports optical and chemical properties of wintertime (December 2018-February 2019) BC, BrC and HULIS at a rural receptor site in the highly polluted eastern Indo-Gangetic Plain (IGP), India. A 7 wavelength aethalometer was deployed to measure time-resolved BC mass concentration, and absorption coefficients (babs) and Angstrom exponent (AE) of BrC. Separation of aqueous and organic BrC (BrCaq and BrCorg) and HULIS fractions via a multi-step chemical extraction procedure followed by optical measurements (UV-Vis, fluorescence and FT-IR), and supplementary measurements of OC, water-soluble organic carbon (WSOC) and ionic species led to better insights into the potential chromophore composition and their relative importance in constraining aerosol optical properties.

The daily averaged BC mass concentration was 15.4±9.5 μg m-3 during winter, where the biomass burning (BB) contribution was 25±5%. The diurnal profile of BCBB and BrC light absorption coefficient (babs_BrC) showed a prominent morning peak (0700-0800 H) characterized by mixed fossil fuel and biofuel emission and a gradual increase towards night due to enhanced primary BB emission from cooking activities and lowering of the mixing depth. The regionally transported BB plume from northwestern IGP contributed substantial BC and BrC to this receptor location in the eastern end of the corridor, which was supported by concentration-weighted air mass trajectories (CWTs).

The BrCorg light absorption at 365 nm (babs_BrC_org) was almost 2 times compared to that of BrCaq (babs_BrC_aq) (36±7.1 vs 18.3±4.3 Mm-1), which suggested a dominance of non-polar polyconjugated BrC chromophores. This was also supported by the increasing trend of water-insoluble BrC from 49±10% at 365 nm to 64±21% at 550 nm, with averaged contributions of 49±8% at 300-400 nm and 67±9% at 400-550 nm, respectively. A strong correlation between WSOC and NO3- (r=0.78, p<0.01) and WSOC and NH4+ (r=0.63, p<0.01) indicated the possibility of nighttime secondary organic aerosol formation. A prominent fluorescence peak at ~409 nm for BrCaq confirmed the presence of HULIS, and babs_BrC_aq was dominated by the low-polarity HULIS-n fraction. AE of individual HULIS fractions increased by 7-36% towards the more polar HULIS-a and highly-polar water-soluble organic matter (HPWSOM) compared to the less polar HULIS-n for the 300-700 nm range. Distinct FTIR peaks at 3400 cm-1, 1710 cm-1 and 1643 cm-1 suggested abundance of C-H, C=O and C=C functional groups, respectively, in the BrC chromophores. Overall, it appeared that the regionally transported BB plume significantly enriches BrC and HULIS in the eastern part of the IGP corridor.   

How to cite: Dey, S., Rana, A., Rawat, P., and Sarkar, S.: Optical and chemical properties of wintertime light-absorbing aerosols in the eastern Indo-Gangetic Plain, India, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-655, https://doi.org/10.5194/egusphere-egu2020-655, 2020.

To better understand the abundance and sources of water-soluble inorganic ions (WSIIs), semi-continuous measurements of WSIIs were performed during autumn 2015 and spring 2016 at a high-altitude background station (2,862 m above sea level) on the summit of Mt. Lulin in central Taiwan. During autumn, the mass concentration of PM2.5, major WSIIs, and CO increased significantly from 12:00 to 18:00 hrs local standard time (LST), whereas the visibility and concentration of O3 decreased at the same time. The backward trajectories analyses showed that the sampling site was under the influence of lifted air masses by the upslope wind from 12:00 to 18:00 hrs. Thus the mountain-valley (M-V) circulation could be the major driving force for the observed aerosol diurnal patterns over the study region during autumn. In sharp contrast to autumn, five high aerosol loading events were observed during spring with each event lasting for a few days. These events were synchronized with the long-range transport of biomass burning (BB) smoke emissions from the Indochina region, as revealed from the fire count map and backward trajectories. The plumes appear to mask their characteristic diurnal features that are driven by the local M-V circulation. These plumes also affected the acidity of ambient aerosol. During BB events, aerosol was found to be relatively more alkaline in nature as revealed by higher molar ratio of [NH4+]calc/[NH4+]meas during BB events (0.88 ± 0.25) than that of the whole spring season (0.81 ± 0.33). The third BB event (BB3), March 29 to April 04, 2016, was the most prominent one among all BB events. During BB3, the mass concentration of PM2.5, NH4+, K+, NO3- and SO42- increased from 8.3 to 29, 0.01 to 2.0, 0.02 to 0.4, 0.01 to 1.6, and 0.4 to 4.1 μg m-3, respectively as compared to before the event. A fog event (March 31; 0:00 to 10:00 LST) was also observed during the BB3 event that decreased the mass concentration of all the species significantly. It suggested that aerosol scavenging and cloud-active processing may occur in this fog event.

How to cite: Singh, A., Chen, W.-R., and Lee, C.-T.: Semi-continuous measurements of water-soluble inorganic ions over a high-altitude background site in central Taiwan, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12251, https://doi.org/10.5194/egusphere-egu2020-12251, 2020.

Atmospheric traffic-related elements (TRE) generated from traffic-related emissions have been linked to a wide range of human diseases and also affect the ecosystem. This study focuses on data from the Nigerian air quality network along the segment of the National Highway Roads (NHR), inner-city Major Roads (MR) and Rural Roads (RR) in Ibadan. The aim of this near-road monitoring was to assess the levels of TRE, determine the particulate matter (PM10) concentrations and mineralogical composition of the PM10 particles.

Sixty particulate matter (PM10) samples were collected from 5 traffic-related stations (2-NHR; 2-MR; 1-RR) (six samples from each station) in the study area using traffic-related high-volume air sampler with PM10 cut-off on cellulose filter. PM10 concentration was calculated from the difference in weight of the filter and flow rate of the sampler while the mineralogical composition of the PM10 was determined by single-particle analysis using scanning electron microscopy and energy-dispersive x-ray spectroscopy (SEM/EDXS) techniques, and the TRE were determined by inductively coupled plasma-optical emission spectrometry (ICP-OES).

The results of the PM10 concentration showed that NHR had the highest concentration of 1194.30 µg/m3, while the lowest concentration was observed in RR (36.33 µg/m3), these correspond to the level of traffic density in both stations, the former having 60,000 vehicle/day while the later had <2000 vehicle/day. More than 80% of the PM10 concentrations in the NHR and the MR were classified as being unhealthy-hazardous to humans living very close to this environment on the basis of the air quality index (AQI). The most abundant mineral particles were clay (53%), quartz (9%) and rock-forming minerals (<3%) sourced from roadside soil and fly ash from construction rock dust. Other particles such as clay+sulphate (17%), sulphur-rich particle (8%), soot (7%) and tarballs (8%) were generated from anthropogenic input from traffic-related activities. The highest average concentration of TRE such as Ba, Cd, La, Pb, V and Zn (2.81, 1.61, 1.21, 6.92, 8.92 and 10.73 respectively all in µg/m3) was observed in NHR, while those of Cu, Mo and Mn (5.45 µg/m3, 6.67 µg/m3 and 11.78 µg/m3 respectively) was observed in MR. Principal component analysis (PCA) revealed four factors (PC1 to PC4). In PC1 26.57% of the variability was observed and loaded with Ba (0.76), Pb (0.82), V (0.85) while PC 2 could explain 17.94% variability and had La (0.67), Mn (0.83) and Mo (0.68), PC 3 explained 15.91% variance loaded with Cd (0.84) and Zn (0.77), and PC 4 gave account of 13.83% of the variance and was loaded with Cu (0.86). PC1 and PC2 were products of both gasoline and diesel engine while PC3 and PC4 were generated from engine oil, brake and tyre wares. The calculated enrichment factor classified the TRE as being moderate to highly contaminated in both NHR and MR while RR was considered relatively uncontaminated.

 

Keywords: Traffic-related elements; Air quality index; National highway roads; Major roads; Rural roads

How to cite: Kolawole, O. T., Olatunji, A. S., and Fomba, K. W.: Particulate matter (PM10) concentration, mineralogical characteristics and traffic-related element (TRE) composition of urban traffic particles in Ibadan, Nigeria, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15274, https://doi.org/10.5194/egusphere-egu2020-15274, 2020.

EGU2020-19729 | Displays | AS3.2

Chinese emissions reductions deliver reduced PM2.5-caused mortality across China during 2015-2017

Ben Silver, Luke Conibear, Carly Reddington, Christophe Knote, Steve Arnold, and Dominick Spracklen

Air pollution is a serious environmental issue and leading contributor to the disease burden in China. Following severe air pollution episodes during the 2012-2013 winter, the Chinese government has prioritised efforts to reduce PM2.5 emissions, and established a national monitoring network to record air quality trends. Rapid reductions in fine particulate matter (PM2.5) concentrations and increased ozone concentrations have occurred across China, during 2015 to 2017. We used measurements of particulate matter with a diameter < 2.5 µm (PM2.5) and Ozone (O3) from >1000 stations across China combined with similar datasets from Hong Kong and Taiwan to calculate trends in PM2.5, Nitrogen Dioxide, Sulphur Dioxide and O3 across the greater China region during 2015-2019. We then use the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) regional air quality simulations, to explore the drivers and impacts of observed trends. Using annually varying emissions from the Multi-resolution Emission Inventory for China, we simulate air quality across China during 2015-2017, and calculate a median PM2.5 trends of -3.9 µg m-3 year-1. The measured nationwide median PM2.5 trend of -3.4 µg m-3 year-. With anthropogenic emissions fixed at 2015-levels, the simulated trend was much weaker (-0.6 µg m-3 year-1), demonstrating interannual variability in meteorology played a minor role in the observed PM2.5 trend. The model simulated increased ozone concentrations in line with the measurements, but underestimated the magnitude of the observed absolute trend by a factor of 2. We combined simulated trends in PM2.5 concentrations with an exposure-response function to estimate that reductions in PM2.5 concentrations over this period have reduced PM2.5-attribrutable premature morality across China by 150 000 deaths year-1.

How to cite: Silver, B., Conibear, L., Reddington, C., Knote, C., Arnold, S., and Spracklen, D.: Chinese emissions reductions deliver reduced PM2.5-caused mortality across China during 2015-2017, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19729, https://doi.org/10.5194/egusphere-egu2020-19729, 2020.

To meet public concerns of health caused by the high concentration of PM highly raised, this research has been done to find out unique physical, chemical, and optical characteristics of aerosols in the case of recent four years high PM concentration events over the East Asian region, especially in Korea and China. Severe air pollution over the East Asian region has occurred by the rapid development of urban areas and industrialization. Also, the meteorological conditions in East Asia are strongly correlated with a high concentration of air pollution and seasonal variation of aerosols. There are three types of aerosol properties (physical, chemical, and optical property), and each property is essential to understand the characteristics of regional and seasonal high PM concentrations. This research has been done to find out unique physical, chemical, and optical characteristics of aerosols in the case of high PM concentration events, especially in two super-mega cities (Seoul and Beijing) of Korea and China, by using various observations measured during recent four years. To analyze those characteristics of aerosols at high concentration events occur, various measurement data are used, like ambient surface air monitoring data (for physical properties) from national network in both Korea and China, Intensive Monitoring Data (for chemical properties), AERONET, GOCI satellite (for optical properties), and meteorological data during recent years (2015 – 2018). This study can provide observational evidence to confirm that each different region has different physical, chemical and optical characteristics of aerosol with the different time periods. The comprehensive results analyzed from this study and integrated methodologies suggested in this study might be useful to make a better in-depth understanding of the relations between various aerosol properties in certain regions and periods.

 

 

Key words : Aerosol, High concentration events, Physical/Chemical/Optical Properties of aerosols

How to cite: Cha, Y. and Song, C.-K.: Analysis of aerosol properties at recent (2015-2018) high PM concentration events in two super-mega cities, Seoul and Beijing, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20979, https://doi.org/10.5194/egusphere-egu2020-20979, 2020.

EGU2020-21639 | Displays | AS3.2

High-resolution size distributions of organic aerosol sources at two sites in Delhi National capital region (NCR) in Indo-Gangetic Plain

Navaneeth M. Thamban, Vipul Lalchandani, Varun Kumar, Suneeti Mishra, Deepika Bhattu, Jay Slowik Gates, Andre Prevot, and Sachchida Nand Tripathi

Delhi National Capital Region (NCR) is a well-known aerosol hotspot in the world, located in the western Indo-Gangetic Plain (IGP). Understanding the size and evolution of organic aerosol (OA) sources at NCR in winter period is very important due to their complexity in origin and processing.  High-Resolution Particle Time of Flight (HR-PToF) size distribution analysis is performed on the HR-ToF aerosol mass spectrometer (AMS) derived data at two sites, i.e., Indian Institute of Technology, Delhi (IITD) and Manav Rachna University, Faridabad (MRU) in NCR region to understand the size distribution and evolution of OA. Proxies of UMR sources of Hydrocarbon OA (m/z 57), Biomass burning OA (m/z 60), Semi volatile OA (m/z 43) and Low-volatile oxygenated OA (m/z 44) are selected to understand the size distribution of the isobaric high-resolution fragments at these proxies. The HR size distribution of primary and secondary fragments at these organic proxies shows relatively distinct mass distributions at lower and higher size bins. The diurnal variation of the mean modal diameters (MMD) of the HR fragments indicates that the C4H9+ (Hydrocarbon OA proxy) shows much diurnal variation in both the sites than the other proxies, where CO2+ shows the least variation.

How to cite: M. Thamban, N., Lalchandani, V., Kumar, V., Mishra, S., Bhattu, D., Gates, J. S., Prevot, A., and Tripathi, S. N.: High-resolution size distributions of organic aerosol sources at two sites in Delhi National capital region (NCR) in Indo-Gangetic Plain, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21639, https://doi.org/10.5194/egusphere-egu2020-21639, 2020.

EGU2020-12358 | Displays | AS3.2

Variability of PM pollution in the light of emission changes and meteorological variability: a case study for Styria, Austria

Christian A. Schmidt, Peter Huszár, Monika Mayer, Johannes Fritzer, and Harald E. Rieder

Despite ambitious efforts to abate surface air pollution, the air quality thresholds for PM10 and PM2.5 are regularly exceeded in the state of Styria. PM target levels are most frequently exceeded in industrial regions and urban cores of the forelands preceeding the alps. Besides local emissions, ambient meteorology and particularly stagnation are of special importance for PM pollution. Here we assess local and regional changes in PM pollution following emission reduction measures, while simultaneously considering effects of meteorological variability. We further supplement our observational study with a set of high-resolution chemistry-transport-model (CTM) simulations to assess future changes in the PM burden in Styria.

How to cite: Schmidt, C. A., Huszár, P., Mayer, M., Fritzer, J., and Rieder, H. E.: Variability of PM pollution in the light of emission changes and meteorological variability: a case study for Styria, Austria, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12358, https://doi.org/10.5194/egusphere-egu2020-12358, 2020.

Recently, the climatological and environmental communities have paid significant attention to the long-term trends and variations in haze-related weather conditions in North China (NC). This study investigates the issue based on a quantified air stagnation index (ASIE) that combines the stagnation intensity with the background emissions, considering that haze occurrence strongly depends on the rate of emission. ASIE shows a close spatial and temporal relationship with the observed PM2.5 concentrations, and a strong sensitivity to haze occurrence in NC. The change in ASIE revealed an approximate 19% increase in the annual stagnation intensity over the period of 1980-2018, due to significant decreases in PBLH and ventilation potency. The interannual variations in stagnation intensity were very significant. The percentage change of ASIE was as high as 50-70% in some years. However, there was an apparent drop in stagnation intensity during 2013-2018, which possibly contributed to the recently reported improvement in aerosol concentration in NC. It also shows that such low-frequency oscillation occurred twice during 1980-2018. Hence, once the current trend of decreasing stagnation intensity changes, haze events may become more common in the future. Finally, we present a quick estimate for the emission reduction ratio that can balance the variations and trend of stagnation intensity using a simple linear model, which can be used to evaluate the difficulty of the “clean air challenge” in NC. The results suggest that the enforcement of the emission reduction plan should be tailored according to the stagnation conditions in the case study year and region.

How to cite: Feng, J.: Long-term trends and variations in haze-related stagnation intensity in North China during 1980-2018, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3780, https://doi.org/10.5194/egusphere-egu2020-3780, 2020.

EGU2020-3129 | Displays | AS3.2

Linking the variability of PM10 in Europe to the position of the extratropical jet

Carlos Ordóñez, Jose M. Garrido-Perez, Ricardo García-Herrera, and David Barriopedro

We have investigated the impact of the polar jet on the winter PM10 (particulate matter with aerodynamic diameter ≤ 10 μm) concentrations in Europe during a 10-year period. For this purpose, we have computed the daily latitude and strength of the jet by using reanalysis wind fields in the lower troposphere over the eastern North Atlantic (0°–15° W). Then we have extracted daily average surface PM10 observations at ~440 sites from the European air quality database (AirBase).

Four preferred jet positions have been identified over the 0°–15° W sector in winter: southern (south of 41° N), central-southern (between 41° N and 51° N), central-northern (between 51° N and 63° N) and northern (north of 63° N). They exert a stronger influence than the jet strength on the mean PM10 levels. Consequently, we have examined whether the full distribution of PM10 and the occurrence of PM10 extremes (exceedances of the local winter 95th percentiles) are also linked to the jet position.

The northern position is associated with enhanced PM10 concentrations (on average ~9 μg m−3 above the mean values) and threefold increases in the odds of PM10 extremes over northwestern / central Europe. Comparable increases have been found in southern Europe when the jet is in its central-northern position. In both cases, the rise in the PM10 concentrations is associated with blocking of the zonal flow over those regions and the impact on PM10 extremes is maximised for time lags of around 1–2 days. On the other hand, the mean sea level pressure (SLP) patterns of the central-southern jet position resemble a positive phase of the winter North Atlantic Oscillation (NAO), yielding large PM10 decreases (on average around −9 μg m−3) in northwestern / central Europe. Similarly, the southern jet position results in low PM10 concentrations in southern Europe.

These results demonstrate that winter near-surface PM10 concentrations in Europe are strongly sensitive to the jet latitude, with implications for future projections of air pollution. As there is no consensus on the future evolution of the North Atlantic jet in a warming climate, different responses among model simulations could be relevant to understand discrepancies in their climate change projections of PM10 and other pollutants.

How to cite: Ordóñez, C., Garrido-Perez, J. M., García-Herrera, R., and Barriopedro, D.: Linking the variability of PM10 in Europe to the position of the extratropical jet, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3129, https://doi.org/10.5194/egusphere-egu2020-3129, 2020.

EGU2020-13585 | Displays | AS3.2

To what extent can the synoptic weather explain high PM2.5 pollution in Seoul?
not presented

limseok chang, hyunkee hong, and cheolhee kim

The change in PM level is the combined result of meteorological change and emission control. Meteorological change can strengthen or weaken the effectiveness of emission control. We applied an empirical and a statistical method to understand the effect of the meteorological variables on high PM2.5 event. A major meteorological mode associated with synoptic weather pattern that governs the high PM2.5 concentration in Seoul was identified through the empirical synoptic weather pattern classification and principal component analysis and regression. We used 2016-2018 PM2.5 observations from ~110 sites and 1 surface meteorological observation and 1 radiosonde observation within Seoul Metropolitan Area (SMA). Fifty cases with high PM2.5 concentration in SMA were selected in 2016 for the empirical weather pattern classification, and observed PM2.5 and meteorological data during 2017 ~ 2018 for the principal component analysis and regression.

As a result, a total of six synoptic weather patterns were derived, which was in agreement with the dominant meteorological mode of principal component analysis and regression. The dominant meteorological consists of high temperature at 850hPa, high geopotential height at 500hPa, high surface temperature, low wind speed at both surface and 850 hPa. The meteorological modes associated with the six patterns account for more than 90% of all high PM2.5 pollution days. Our results suggest that major synoptic weather modes can be used to easily predict high dust concentration potentials compared to WRF-SMOKE-CMAQ based air quality forecasting models.

How to cite: chang, L., hong, H., and kim, C.: To what extent can the synoptic weather explain high PM2.5 pollution in Seoul?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13585, https://doi.org/10.5194/egusphere-egu2020-13585, 2020.

Despite frequent haze pollution in China in recent years, our knowledge of regional pollution episodes associated with air transport and synoptic weather systems is limited. In this study, we conducted two intensive campaigns simultaneously to measure the highly time-resolved chemical composition of fine particles (PM2.5) in suburban Shanghai and Nanjing during the winter of 2017 and the summer of 2018. The average PM2.5 mass concentrations were 53.9 (65.7) µg m-3 and 32.8 (37.3) µg m-3 in Shanghai (Nanjing) in winter and summer, respectively. In winter, extreme haze episodes were observed synchronously with enhanced contributions of nitrate at both sites and of low-volatile oxidized organic aerosol (LV-OOA) in Shanghai. Long-range transport from Northern China was demonstrated to play an important role in the episodes, which occurred simultaneously at both sites. Influenced by the cold fronts, Nanjing had a relatively longer pollution duration, whereas Shanghai exhibited faster PM increases. In summer, air masses passing though the city-clusters of the YRD were responsible for the pollution episodes. Low wind speeds, which favored the accumulation of primary aerosols, and strong photochemical activity indicated by high ozone level, which promoted the formation of secondary aerosols, resulted in elevated contributions of nitrate, Hydrocarbon-like organic aerosol (HOA) and semi-volatile oxidized organic aerosol (SV-OOA) to PM in Shanghai. In addition, a pollution episode dominated by increases of nitrate and organic aerosols was observed in Nanjing two days later despite the clean situation in Shanghai. Our results highlight the importance of regional or sub-regional emission control to mitigate haze pollution in city clusters, such as the YRD in Eastern China.

How to cite: Sun, P.: Impact of air transport and secondary formation on haze pollution in the Yangtze River Delta: In situ online observations in Shanghai and Nanjing, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1971, https://doi.org/10.5194/egusphere-egu2020-1971, 2020.

EGU2020-2972 | Displays | AS3.2

Particulate Monitoring and Evaluation of the Low-cost Sensors Performance at the Middle East

Yasser Alshehri, Mansour Alghamdi, Mamdouh Khoder, Fahd Almehmadi, Amer Bamuneef, Rayan Moathen, and Georgiy Stenchikov

Key Words:
Air Quality; Air Pollution Monitoring; Low-Cost Sensors; Reference Methods, Microsensors, Experimental Campaign
 
Abstract:

Air quality in the Middle East (ME) is strongly affected by desert dust besides anthropogenic pollutants. The health hazards associated with particulate matter (PM) are the most severe in this desert region. The enhancement of Air quality monitoring is needed to implement abatement strategies and stimulate environmental awareness among citizens. Several techniques are used to monitor PM concentration. The air quality monitoring stations (AQMS) equipped with certified instrumentation is the most reliable option. However, AQMSs are quite expensive and require regular maintenance. Another option is low-cost sensors (LCS) that seen as innovative tools for future smart cities. They are cost-effective and allow to increase the spatial coverage of air-quality measurements as the number of conventional AQMS is generally quite small, so the current density of the monitoring stations in the Middle East is low.


In this work, we evaluated the PM air-quality climatology in the major cities in Saudi Arabia (Jeddah, Riyadh, and Dammam) for four years between 2016 and continued until 2020. We used the measurement data that were conducted by the Saudi Authority for Industrial Cities and Technology Zones (MODON) using certified reference AQMS installed inside the suburban areas of the three major cities in Saudi Arabia. Also, we tested the performance of the five LCS systems for eight months, starting in May 2019 and continued until January 2020. For this purpose, we set AQMS with the PM reference instrumentation (based on beta-ray absorption) side-by-side with five different LCS systems (based on light scattering) in the industrial part of Jeddah city. We collected, filtered, validated PM data, and applied standard measurement and calibration procedures.

The AQMS measurements show that in Summer, the daily mean PM concentrations exceed the World Health Organization (WHO) limits for PM2.5 and PM10 almost every day in Jeddah, Riyadh, and Dammam. The WHO limits are also frequently violated in the winter months. The AQMS measurements reliably show dust storm spikes when PM pollution is extremely high while all the LCSs fail to capture these severe events. We found that LCS and AQMS PM measurements are poorly correlated in Summer, but show slightly better results in fair-weather Winter days when humidity and temperature are low. But they still cannot capture severe dust events.

How to cite: Alshehri, Y., Alghamdi, M., Khoder, M., Almehmadi, F., Bamuneef, A., Moathen, R., and Stenchikov, G.: Particulate Monitoring and Evaluation of the Low-cost Sensors Performance at the Middle East, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2972, https://doi.org/10.5194/egusphere-egu2020-2972, 2020.

EGU2020-2722 | Displays | AS3.2

Link between precipitations and air quality in Bucharest Greater Area, Romania
not presented

Tiberiu Hriscan, Sorin Burcea, and Gabriela Iorga

Air pollution and climate change represent today key environmental issues. They are highly linked each other through various ways. Pollutant emission reductions can improve both air quality and mitigate the climate changes. On the other hand, heavy precipitations and/or an increased frequency of their occurrence (climate change) might help to clean the air from pollutants. Despite of the scientific progress, the understanding of atmospheric pollutant wet removal in urban and peri-urban areas is still subject to a large uncertainty. Among factors of uncertainties are aerosol large variability, different sources, aerosol-cloud processing.

This study examines how the concentrations of particulate matter with an aerodynamic diameter below 10 μm (PM10) and below 2.5 μm (PM2.5) might be linked with precipitation characteristics using an observational data set for three years (2015-2017) in Bucharest metropolitan area. Particulate matter data and meteorological parameters at each site (atmospheric pressure, relative humidity, temperature, global solar radiation, wind speed and direction) were extracted from the public available Romanian National Air Quality Database. Meteorology was complemented with radar products (images, reflectivity, echotops) from the C-band meteorological radar from National Meteorological Administration in Bucharest. Change of aerosol mass concentration during the evolution of the precipitation events was investigated. The aerosol scavenging coefficients were estimated and compared with those in scientific literature. Correlations between meteorological parameters and ambient PM10 and PM2.5 levels were analyzed. Connection of meteorological phenomena occurrence and air mass origin was investigated by computing air mass backward trajectories using the HYSPLIT (Hybrid Single-Particle Lagrangian Integrated Trajectory) model for 72 hours back.

It was found that heavy precipitations have a strong influence on the atmospheric aerosol concentrations, determining an increased value of scavenging coefficient with up to one order of magnitude higher than in case of a moderate precipitation. Higher values of scavenging coefficient than in literature reveals a good capability of the convective precipitating systems to clear the atmosphere from aerosol and pollutant species.

The obtained results are important for modeling of air quality and for investigations of aerosol wet deposition processes.

Acknowledgement:

The authors thank the financial support from UB198/Int project and to National Meteorological Administration for access to the RADAR database. The data regarding ground-based air pollution and meteorology by site was extracted from the public available Romanian National Air Quality Database, www.calitateaer.ro, last accessed in December 2019.

How to cite: Hriscan, T., Burcea, S., and Iorga, G.: Link between precipitations and air quality in Bucharest Greater Area, Romania, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2722, https://doi.org/10.5194/egusphere-egu2020-2722, 2020.

EGU2020-6862 | Displays | AS3.2

Variation of the surface ozone concentration during precipitation

Igor V. Ptashnik, Boris D. Belan, Denis E. Savkin, Gennadii N. Tolmachev, Tatayana K. Sklyadneva, Tatayana M. Rasskazchikova, Victoria Arshinova, and Alexandr V. Fofonov

In the review compiled by Monks et al. (2015), it is noted that the main variations in the tropospheric ozone are determined by the exchange between the troposphere and the stratosphere, in-situ photochemical production from gaseous precursors depending on their composition and concentration, solar radiation income, and meteorological conditions. The impact of precipitation on the surface ozone concentration is a less well-studied factor.

The process of ozone interaction with precipitation was studied theoretically (Heicklen, 1982). Two ways of the above process were analyzed: adsorption of gas molecules on the surface of a particle and a chemical reaction with its surface. There are no direct data on the verification of these findings in the literature. At the same time, there is some evidence of a possible link between precipitation and ozone.

This study is aimed to analyze the presence or absence of changes in the ozone concentration during precipitation. Variations of the surface ozone concentration (SOC) in the presence of precipitation were analyzed using the long-term data obtained at the TOR-station established in 1992 for ozone monitoring in Tomsk. It was revealed that these changes can be both positive (increase in concentration) and negative. The sharp changes in the SOC are observed when frontal precipitation takes place. In the presence of air-mass precipitation, the sign and magnitude of the change is determined by the diurnal variation of ozone concentration.

The analysis showed a coincidence of the SOC growth during precipitation with its increase in diurnal variation in 59% of cases. The coincidence in the wave of the concentration decline in the diurnal variation with decreasing precipitation rate is even higher and amounts to 85%.

Airborne sounding carried out in the vicinity of the TOR-station shown that in a number of cases the ozone deposition from the boundary layer is observed upon the transition of thermal stratification during the precipitation to neutral.

 

Monks P. S, Archibald A. T., Colette A., Cooper O., Coyle M., Derwent R., Fowler D., Granier C., Law K. S., Mills G. E., Stevenson D. S., Tarasova O., Thouret V., von Schneidemesser E., Sommariva R., Wild O., Williams M. L. Tropospheric ozone and its precursors from the urban to the global scale from air quality to short-lived climate forcer. Atmos. Chem. Phys., 2015, v.15, N15, p.8889–8973.

Heicklen J. The Removal of Atmospheric Gases by Particulate Matter. In Heterogeneous Atmospheric Chemistry, ed. D. R. Schryer, Geophysical Monograph 26. American Geophysical Union, Washington, DC, USA, 1982, p. 93-98.

How to cite: Ptashnik, I. V., Belan, B. D., Savkin, D. E., Tolmachev, G. N., Sklyadneva, T. K., Rasskazchikova, T. M., Arshinova, V., and Fofonov, A. V.: Variation of the surface ozone concentration during precipitation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6862, https://doi.org/10.5194/egusphere-egu2020-6862, 2020.

EGU2020-10337 | Displays | AS3.2

Changes in the temperature sensitivity of surface ozone production: a case-study based on long-term observations in Austria

Monika Mayer, Christoph Staehle, Christian Schmidt, and Harald E. Rieder

As the production of ozone in surface air is determined by ambient temperature and by the prevalent chemical regime, a very different temperature dependence of ozone production emerges for NOx and VOC limited regions. In this study we evaluated the temperature sensitivity of ozone production for rural, suburban as well as urban sites in Austria on seasonal basis. The analysis is based on observational data from Austrian monitoring networks for the time period spanning 1990 – 2018. Surface ozone, nitrogen oxides (NOx), daily sums of global radiation and minimum daily temperature are used as covariates in our study. The observed NOx to VOC ratio at individual sites is variable over time due to changes in precursor emissions and/or the variability of meteorological parameters such as mixing layer height. At the site level we relate the temperature sensitivity of ozone production to the daily mean NOx mixing ratio and the daily minimum temperature. This information allows us to determine the impact of past/future temperature changes on surface ozone  abundance in the context of reductions of NOx emissions and changing methane backgrounds.

How to cite: Mayer, M., Staehle, C., Schmidt, C., and Rieder, H. E.: Changes in the temperature sensitivity of surface ozone production: a case-study based on long-term observations in Austria, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10337, https://doi.org/10.5194/egusphere-egu2020-10337, 2020.

EGU2020-9213 | Displays | AS3.2 | Highlight

The differing impact of air stagnation on near-surface ozone across Europe

José M. Garrido-Pérez, Carlos Ordóñez, Ricardo García-Herrera, and Jordan L. Schnell

Daily maximum temperature is known to be the meteorological variable that mostly controls the afternoon near-surface ozone concentrations during summer. Air stagnation situations, characterised by stable weather conditions and poor ventilation, also lead to the accumulation of pollutants and regional ozone production close to the surface. This work evaluates the joint effect of daily maximum temperature and a simplified air stagnation index on surface ozone observations in eight regions of Europe during summer 1998-2015.

As expected, the correlations of MDA8 O3 (maximum daily 8-h running average ozone) with temperature are higher than with stagnation for most regions. Nevertheless, stagnation can also be considered as a good predictor of ozone, especially in the regions of central/southern Europe, where the correlation coefficients between MDA8 O3 and the percentage of stagnant area are within the range 0.50–0.70. MDA8 O3 consistently increases over central/southern Europe under stagnant conditions, but this is not always the case in the north. Under non-stagnant conditions and daily maximum temperatures within 20-25 ºC (typical temperatures of fair weather conditions that allow photochemical production), northern Europe is affected by southerly advection that often brings aged air masses from more polluted areas, increasing the MDA8 O3 mixing ratios.

We have also found that the ozone diurnal cycles in the central/southern regions exhibit large amplitudes, with above-average daytime and below-average night-time concentrations, when stagnation occurs. Stagnant nights are often associated with stable shallow planetary boundary layer and, presumably, enhanced dry deposition and chemical destruction of ozone. After sunrise, mixing with air from air from the residual layer, accumulation of ozone and precursors, and photochemical production seem to be the main mechanisms involved in the build-up of daytime ozone.

According to previous studies, some of the central/southern European regions where stagnation has a clear impact on ozone have undergone significant upward trends in air stagnation in the past and are also likely to experience increases in the future. However, our study has identified other regions with unclear responses of summer ozone to the occurrence of stagnation. This indicates that climate model projections of increases in stagnation should not directly be translated into enhanced summer ozone pollution if the sensitivity of this pollutant to stagnation has not been proved for a particular region.

How to cite: Garrido-Pérez, J. M., Ordóñez, C., García-Herrera, R., and Schnell, J. L.: The differing impact of air stagnation on near-surface ozone across Europe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9213, https://doi.org/10.5194/egusphere-egu2020-9213, 2020.

Ambient ozone (O3) remains a serious air pollution problem (O3) of Northern Hemisphere, and still represents a considerable threat both for human health and ecosystems. In Europe, the critical levels of O3 are permanently exceeded over vast areas (EEA, 2019). In the Czech Republic (CR), monitoring of O3 has been operated since 1993, currently at 50 sites, including both rural and urban stations covering the country (CHMU, 2019). O3 exposures in the CR are relatively high (Hůnová, Schreiberová, 2012; Hůnová et al., 2016), and may result in negative endpoints, both regarding human health (Hůnová et al. 2013) and vegetation (Hůnová et al., 2011). O3 is highly meteorology dependent and shows considerable year-to-year variations (Hůnová et al., 2019 a, b). Two to three-decade time series allows for a sound trend analysis, hence O3 concentrations for trends at Czech long-term monitoring sites were already analysed using Mann-Kendall non-parametric test (Hůnová, Bäumelt, 2018).

This time, however, our approach for time analysis was different. We applied a generalized additive model, GAM (Wood, 2017; Hastie & Tibshirani, 1990) framework as a flexible, semiparametric regression approach to address nonlinear trend shapes in a formalized and unified way. In particular, we employed penalized spline approach with cross-validated penalty coefficient estimation.  We have examined daily mean O3 concentrations measured at twelve Czech sites representing different environments, geographical areas, and altitudes across the country; four urban, for rural and four mountain sites. We used long-term data series from the time period of 1994–2018.

Our results show inconsistent behaviour of sites before 1998 when the strict emission limits were introduced with an immediate consequence of substantial decrease in O3 precursor emissions. The highest concentrations and the most dynamic O3 decrease in this time period was recorded at the Praha 4-Libus urban background site, the lowest concentrations and the steepest increase in O3 were recorded at the Rudolice mountain site in the former Black Triangle Area. Two local maxima – around 2003 for some sites and 2006 for other sites – and a local minimum around 2013 are indicated. Steady increase in O3 concentrations for all sites is evident after 2014 up to now, most likely due to recent five hot and dry summer seasons. Seasonal O3 course averaged for the entire measuring period is similar for all sites, with clear maximum in May-June. The highest O3 in summer and lowest in winter were observed at the Usti nad Labem-Kockov site, relatively most flat curve, with the least differences between summer and winter was recorded at the Churanov site, in the Sumava Mts. More interesting is to compare the seasonal O3 curves for individual years.

In contrast with Mann-Kendall test standardly used for this kind of analysis, the GAM approach offers a detailed view on both time trend and seasonality curve and facilitates the analysis and interpretation of the results.

 

 

How to cite: Hunova, I., Brabec, M., and Malý, M.: Trends in ambient ozone concentrations at twelve sites of the Czech Republic over the past three decades, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6973, https://doi.org/10.5194/egusphere-egu2020-6973, 2020.

EGU2020-3839 | Displays | AS3.2

Long-term Variations in Ozone Levels over Beijing: Observations and Model Simulations

Yuli Zhang, Mengchu Tao, JinQiang Zhang, Yi Liu, Hongbin Chen, Zhaonan Cai, and Paul Konopka

Tropospheric ozone is a major pollutant and a short-lived greenhouse gas and has therefore attracted much concern in recent years. The ozone concentration in the troposphere and lower stratosphere over Beijing has been observed since 2002 by ozonesondes developed by the Institute of Atmospheric Physics. We used these balloon-based observations to analyze the long-term variability of ozone over Beijing during the whole period from 2002 to 2018. The ozonesondes measured increasing concentrations of ozone from 2002 to 2012 in both the troposphere and lower stratosphere. There was a sudden decrease in observed ozone between 2011 and 2012. After this decrease, the increasing trend in ozone concentrations slowed down, especially in the mid-troposphere, where the positive trend became neutral. We used the Chemical Lagrangian Model of the Stratosphere (CLaMS) to determine the influence of the transport of ozone from the stratosphere to the troposphere on the observed ozone profiles. Because there is no tropospheric chemistry in CLaMS, the sudden decrease simulated by CLaMS indicates that a smaller downward transport of ozone from the stratosphere after 2012 may explain a significant part of the observed decrease in ozone in the mid-troposphere and lower stratosphere. However, the influence of stratospheric ozone in the lower troposphere is negligible in CLaMS and the hiatus in the positive trend after 2012 can be attributed to a reduction in ozone precursors as a result of stronger pollution control measures in Beijing.

How to cite: Zhang, Y., Tao, M., Zhang, J., Liu, Y., Chen, H., Cai, Z., and Konopka, P.: Long-term Variations in Ozone Levels over Beijing: Observations and Model Simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3839, https://doi.org/10.5194/egusphere-egu2020-3839, 2020.

EGU2020-12605 | Displays | AS3.2

Vegetation feedbacks during drought exacerbate ozone air pollution extremes in Europe

Meiyun Lin, Larry Horowitz, Yuanyu Xie, Fabien Paulot, Sergey Malyshev, Elena Shevliakova, Angelo Finco, Giacomo Gerosa, Dagmar Kubistin, and Kim Pilegaard

This study highlights a previously under-appreciated “climate penalty” feedback mechanism - namely, substantial reductions of ozone uptake by water stressed vegetation – as a missing piece to the puzzle of why European ozone pollution episodes have not decreased as expected in recent decades, despite marked reductions in regional emissions of ozone precursors due to regulatory changes. The most extreme ozone pollution episodes are linked to heatwaves and droughts, which are increasing in frequency and intensity over Europe, with severe impacts on natural and human systems. Under drought stress, plants close their stomata to reduce water loss, consequently limiting the ozone uptake by vegetation (a component of dry deposition), leading to increased surface ozone concentrations. Such land-biosphere feedbacks are often overlooked in prior air quality projections, owing to a lack of process-based model formulations. Here, we use six decades of observations and Earth system model simulations (1960-2018) with an interactive dry deposition scheme to show that declining ozone removal by water-stressed vegetation in the warming climate exacerbate ozone air pollution over Europe. Incorporated into a dynamic vegetation land – atmospheric chemistry – climate model, the dry deposition scheme mechanistically describes the response of ozone deposition to atmospheric COconcentration, canopy air vapor pressure deficit, and soil water availability. Our observational and modeling analyses reveal drought stress causing as much as 70% reductions in ozone removal by forests. Reduced ozone removal by water-stressed vegetation worsens peak ozone episodes during European mega-droughts, such as the 2003 event, offsetting much of the air quality improvements gained from regional emission controls. Accounting for vegetation feedbacks leads to a three-fold increase in high surface ozone events above 80 ppbv (8-hour average) and a 20% increase in the sensitivity of ozone pollution extremes (95th percentile) to increasing temperature. As the frequency of hot and dry summers is expected to increase in the coming decades, this ozone climate penalty could be severe and therefore needs to be considered when designing clean air policy in the European Union. 

Notes: This study is currently under review for possible publication in Nature Climate Change. 

How to cite: Lin, M., Horowitz, L., Xie, Y., Paulot, F., Malyshev, S., Shevliakova, E., Finco, A., Gerosa, G., Kubistin, D., and Pilegaard, K.: Vegetation feedbacks during drought exacerbate ozone air pollution extremes in Europe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12605, https://doi.org/10.5194/egusphere-egu2020-12605, 2020.

EGU2020-13357 | Displays | AS3.2

A Statistical Model for Automated Quality Assessment of the TOAR-II

Najmeh Kaffashzadeh, Kai-Lan Chang, Sabine Schröder, and Martin G. Schultz

The Tropospheric Ozone Assessment Report, phase 2, (TOAR-II) database is a collection of global ground-level ozone in-situ measurements from various locations. It also holds data of selected ozone precursors and meteorological variables. TOAR-II assembles air quality data from many different sources and thus requires a common data quality assessment (QA) to ensure the data meet the quality required for globally consistent analyses. The large volume of this database (more than 100,000 data series) enforces the use of automated, data-driven QA procedures.

Accordingly, we have developed a statistical model for automated QA. This model consists of several statistical tests that are classified into several sub-groups. In this model, a QA-score (an indicator ranging from 0 to 1) was assigned to each individual data point to estimates the value‘s plausibility. The foundation of this concept is statistical hypothesis testing and the probability theory. This model was implemented in a Python package and is called AutoQA4Env.

One application of AutoQA4Env is the data ingestion workflow of TOAR-II. The tool generates a data quality report which is then sent back to the data provider for inspection. Since AutoQA4Env is easily configurable, it allows the users to set quality thresholds and thus filter data according to their use case. While we primarily develop AutoQA4Env for air quality data, the same concept and model might be applicable to other databases and the software framework is flexible enough to allow for other use cases.

How to cite: Kaffashzadeh, N., Chang, K.-L., Schröder, S., and Schultz, M. G.: A Statistical Model for Automated Quality Assessment of the TOAR-II, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13357, https://doi.org/10.5194/egusphere-egu2020-13357, 2020.

EGU2020-14701 | Displays | AS3.2

Long-range air transport in Northern Eurasia: Seasonal ozone variations and implications for regional ozone budget

Yury Shtabkin, Konstantin Moiseenko, Andrey Skorokhod, and Elena Berezina

Effect of photochemically active species emissions on near-surface air composition in industrial regions is non-local and in many cases can be traced in transcontinental scale. Largescaled plumes of polluted air defined by observations of tracer species on background stations and calculations with chemical-transport models are examples of this effect. In this work we use GEOS-Chem chemical transport model to make an assessment of influence have anthropogenic and biogenic emissions in Europe, European territory of Russia (ETR) and Siberia on total ozone generation taking into account common non-linear properties of O3–NOx–СО–VOC system. It is shown that increasing of ozone production rate due to regional anthropogenic emissions of NOx leads to substantial (up to 20 ppbv) increase of near-surface ozone concentrations in mid-latitudes traced up to 120E. The predominant role of long-range air transport against regional sources of photochemical ozone production was determined for the most part of European Russia and Siberia.
We also make a numerical assessment of ozone balance in Europe, ETR and Siberia. Annual ozone total mass in lower troposphere (from surface to 800 hPa) for Europe, ETR and Siberia depending on region is 1.5–2.4 Tg in warm period (1 April – 30 September) and 1.3–2.2 Tg in cold period (1 October - 31 March). Ozone production in chemical processes with a high degree of accuracy (about 99%) is balanced by total atmospheric transport, while absolute variations in O3 total mass do not exceed 0.5 Tg/year in Europe and 0.4 Tg/year in Siberia.
This work was supported by the Russian Foundation for Basic Research under grant 18-35-20031.

How to cite: Shtabkin, Y., Moiseenko, K., Skorokhod, A., and Berezina, E.: Long-range air transport in Northern Eurasia: Seasonal ozone variations and implications for regional ozone budget, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14701, https://doi.org/10.5194/egusphere-egu2020-14701, 2020.

EGU2020-20033 | Displays | AS3.2

Long-term observations of reactive gases at the puy de Dôme (PUY Global GAW) station (France, 1465 m a.s.l.)

Aurélie Colomb, Manon Rocco, Agnès Borbon, Yang Yu, Miao Wang, Laetitia Bouvier, Jean-Marc Pichon, Mickael Ribeiro, Laurent Deguillaume, and Jean-Luc Baray

The puy de Dôme (pdD) altitude research station is located in the centre of France (45° 46' N, 2° 57' E, 1465 m altitude a.s.l), 16 km from the town of Clermont-Ferrand. This station is a global GAW station (PUY), and is part of the ACTRIS-2 integrating activities (H2020). Long series of meteorological parameters such as wind speed and direction, temperature, pressure, relative humidity and radiation, atmospheric trace gases (O3, NOx, SO2, CO2, CO), and physical, optical and chemical properties of aerosols (particle size, black carbon, mass,..) are available.

Cartridge sampling measurements are performed to link the observations of volatile organic compounds (VOCs) within ACTRIS and GAW. A selection of VOCs, including a large set of non-methane hydrocarbons and some terpenes (isoprene, α-pinene), was measured during summer 2010, spring and summer 2011, winter 2012, summer and winter 2013, summer 2015, and twice a week in 2017, 2018 and 2019. The analysis of VOCs collected off-line on Tenax/Carbosieve III or Tenax TA cartridges was carried out using gas chromatography coupled with thermo-desorption with mass spectrometry (GC-MS).

In August 2018, a new gas chromatography (GC-FID) system was installed at the station. It allows the acquisition of non-methane hydrocarbons (C5-C10) with a temporal resolution of two hours.

The reactive gas measurement series are analysed in terms of observed levels (i), diurnal and seasonal variability (ii), air mass origins (iii) and sources of these gaseous pollutants (iv).

(i) The level observed at the PUY station is discussed and compared with two other stations: Monte Cimone (mainly in the free troposphere) and Hohenpeissenberg (mainly in the planetary boundary layer PBL).

(ii) As the height of the PBL changes with a diurnal cycle and with the seasons, the PUY station is in the different layers of the troposphere during the year impacting the measured concentrations.

(iii) In order to determine the transport pathways of the air masses before their arrival at the pdD site, the HYSPLIT (Hybrid Single Particle Lagrangian Trajectory) model was used. Trajectories were classified according to their predominant transport direction prior to measurement, either continental (C), marine (M), modified marine (Mod), Mediterranean (Med), or mixed according to their trajectories. In order to determine the influence of wind direction, the pollution wind rose was determined for the main pollutants.

(iv) Comparison with temperature, air mass origins, boundary layer height are used to identify the main parameters influencing the variability of VOCs. The Principal Component Analysis (PCA) has been performed to deduce correlations between the main atmospheric species and their main determinants.

How to cite: Colomb, A., Rocco, M., Borbon, A., Yu, Y., Wang, M., Bouvier, L., Pichon, J.-M., Ribeiro, M., Deguillaume, L., and Baray, J.-L.: Long-term observations of reactive gases at the puy de Dôme (PUY Global GAW) station (France, 1465 m a.s.l.), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20033, https://doi.org/10.5194/egusphere-egu2020-20033, 2020.

EGU2020-21123 | Displays | AS3.2

Quantifying and attributing changes in tropospheric ozone from a combination of satellite measurements and models

Jessica Neu, Kazuyuki Miyazaki, Kevin Bowman, and Gregory Osterman

Given the importance of tropospheric ozone as a greenhouse gas and a hazardous pollutant that impacts human health and ecosystems, it is critical to quantify and understand long-term changes in its abundance.  Satellite records are beginning to approach the length needed to assess variability and trends in tropospheric ozone, yet an intercomparison of time series from different instruments shows substantial differences in the net change in ozone over the past decade.  We discuss our efforts to produce Earth Science Data Records of tropospheric ozone and quantify uncertainties and biases in these records.  We also discuss the role of changes in the magnitude and distribution of precursor emissions and in downward transport of ozone from the stratosphere in determining tropospheric ozone abundances over the past 15 years.

How to cite: Neu, J., Miyazaki, K., Bowman, K., and Osterman, G.: Quantifying and attributing changes in tropospheric ozone from a combination of satellite measurements and models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21123, https://doi.org/10.5194/egusphere-egu2020-21123, 2020.

Trace gases and aerosols in the troposphere exhibit significant variability, particularly so over regions where biomass burning occurs, and downwind of both biomass burning and large urban areas. Knowledge and quantification of the mean, trends, and most importantly variance over these source regions and their downwind plumes over climatological scales can therefore be used to retrieve information about both the source amounts as well as the amounts transported.

In this work, we pinpoint a way to separate these regions from one another by simultaneously employing a variance maximization approach to global weekly column measurements of OMI NO2 (which has a very short atmospheric lifetime) and MOPITT CO (which has a relatively long atmospheric lifetime) from the past decade and a half. The variance maximization is done using the EOF/PCA approach, and yields important results in northern Australia, Indonesia, northern Southeast Asia, Siberia, central and southern Africa, Amazonia and California. We then compare and contrast the spatial and temporal results in terms of the difference in the atmospheric lifetime of the co-emitted species. We specifically look for an overlap between the two over the source regions, and a strong signal in CO exclusively over both the source and downwind transport regions.

This technique improves upon the current generation of bottom-up techniques detecting land-use change and hotspots, in terms of offering higher temporal resolution and better representations under cloud cover. However, to further improve the work, we hope to employ AOD measurements to refine our results, as co-emitted aerosols like BC are sensitive to precipitation, and thus able to pick up the source and transport under different precipitation conditions.

How to cite: Deng, W. and Cohen, J.: Using Variance Maximization with Multi-species Measurements to Pinpoint the Sources and Long Range Transport of Biomass Burning over the Past 15 Years, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13533, https://doi.org/10.5194/egusphere-egu2020-13533, 2020.

EGU2020-5114 | Displays | AS3.2

Impacts of monocyclic aromatics on regional and global tropospheric gas-phase chemistry

Rolf Sander, David Cabrera-Perez, Sara Bacer, Sergey Gromov, Jos Lelieveld, Domenico Taraborrelli, and Andrea Pozzer

Aromatic compounds in the troposphere are reactive towards ozone
(O3), hydroxyl (OH) and other radicals. Here we present an
assessment of their impacts on the gas-phase chemistry, using the
general circulation model EMAC (ECHAM5/MESSy Atmospheric Chemistry). The
monocyclic aromatics considered in this study comprise benzene, toluene,
xylenes, phenol, styrene, ethylbenzene, trimethylbenzenes, benzaldehyde
and lumped higher aromatics bearing more than 9 C atoms. On a global
scale, the estimated net changes are minor when aromatic compounds are
included in the chemical mechanism of our model. For instance, the
tropospheric burden of CO increases by about 6 %, and those of OH,
O3, and NOx (NO + NO2) decrease between
2 % and 14 %. The global mean changes are small partially because of
compensating effects between high- and low-NOx regions. The
largest change is predicted for glyoxal, which increases globally by 36
%. Significant regional changes are identified for several species. For
instance, glyoxal increases by 130 % in Europe and 260 % in East Asia,
respectively. Large increases in HCHO are also predicted in these
regions. In general, the influence of aromatics is particularly evident
in areas with high concentrations of NOx, with increases up
to 12 % in O3 and 17 % in OH. Although the global impact of
aromatics is limited, our results indicate that aromatics can strongly
influence tropospheric chemistry on a regional scale, most significantly
in East Asia.

How to cite: Sander, R., Cabrera-Perez, D., Bacer, S., Gromov, S., Lelieveld, J., Taraborrelli, D., and Pozzer, A.: Impacts of monocyclic aromatics on regional and global tropospheric gas-phase chemistry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5114, https://doi.org/10.5194/egusphere-egu2020-5114, 2020.

EGU2020-9238 | Displays | AS3.2

Analysis of the diurnal evolution of atmospheric ammonia over the Paris megacity from ground-based and satellite remote sensing

Rebecca D. Kutzner, Juan Cuesta, Pascale Chelin, Jean-Eudes Petit, Frank Hase, Johannes Orphal, Thomas Blumenstock, Matthias Schneider, Camille Viatte, and Cathy Clerbaux

Ecosystems and human health are directly affected by atmospheric ammonia, by unbalancing the vegetation nutrient cycle and causing respiratory troubles both directly and through the formation of fine particles. In Europe, agricultural practices are the dominant source of atmospheric ammonia. It is released to the atmosphere by volatilization of fertilizer applied to soils and decay of organic matter. Then, it reacts with acids (such as sulphuric, nitric and chlorine acids) or nitrogen oxides (all produced in high concentrations from anthropogenic activities) to produce ammonium aerosols, whose concentrations over Europe and Paris megacity are particularly high during springtime pollution events, as occurred in 2014 and 2015.

Difficulties for measuring ammonia by in situ techniques are induced by its polarity, which causes accumulation in inlets and sampling tubes. Remote sensing is therefore a valuable alternative method to measure ammonia, without direct interaction with the sample. Measurements of ammonia total atmospheric columns using the OASIS observatory are routinely made in the Paris suburbs since 2009 using a medium spectral resolution BRUKER Fourier transform infrared spectrometer. Spectra of radiation emitted by the sun and absorbed by the atmosphere were recorded every 10 minutes, under clear sky conditions, enabling the observation of the diurnal evolution of ammonia concentrations.

Our work provides a new analyse of the diurnal evolution of ammonia over the Paris megacity during springtime pollution events. For this, we use measurements of total atmospheric columns of ammonia derived from the ground-based OASIS observatory for the first time and from satellite approaches, such as that from IASI and other available satellites. Furthermore, this study takes into account the influence of meteorological conditions and atmospheric chemical composition, of gaseous and particulate phases, from surface measurements simultaneously performed at Palaiseau, in the Paris region.

How to cite: Kutzner, R. D., Cuesta, J., Chelin, P., Petit, J.-E., Hase, F., Orphal, J., Blumenstock, T., Schneider, M., Viatte, C., and Clerbaux, C.: Analysis of the diurnal evolution of atmospheric ammonia over the Paris megacity from ground-based and satellite remote sensing , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9238, https://doi.org/10.5194/egusphere-egu2020-9238, 2020.

Nitrous acid (HONO), an important precursor of the hydroxyl radical (OH), has long been recognized as of significance to atmospheric chemistry, but its sources are still debated. In this study, we conducted continuous measurement of HONO from November 2017 to November 2018 at the SORPES station in Nanjing of eastern China. The yearly average mixing ratio of observed HONO was 0.69±0.58 ppb, showing a larger contribution to OH relative to ozone with a mean OH production rate of 1.16 ppb h−1. To estimate the effect of combustion emissions of HONO, the emitted ratios of HONO to NOx were derived from 55 fresh plumes (NO∕NOx > 0.85), with a mean value of 0.79 %. During the nighttime, the chemistry of HONO was found to depend on RH, and the heterogeneous reaction of NO2 on an aerosol surface was presumably responsible for HONO production. The average nighttime NO2-to-HONO conversion frequency (CHONO) was determined to be 0.0055±0.0032 h−1 from 137 HONO formation cases. The missing source of HONO around noontime seemed to be photo-induced, with an average Punknown of 1.04 ppb h−1, based on a semi-quantitative HONO budget analysis. An over-determined system of equations was applied to obtain the monthly variations in nocturnal HONO sources. Besides the burning-emitted HONO (accounting for about 23 % of the total concentration), the contribution of HONO formed heterogeneously on ground surfaces to measured HONO was an approximately constant proportion of 36 % throughout the year. The soil emission revealed clear seasonal variation and contributed up to 40 % of observed HONO in July and August. A higher propensity for generating HONO on aerosol surfaces occurred in severe hazes (accounting for 40 % of the total concentration in January). Our results highlight ever-changing contributions of HONO sources and encourage more long-term observations to evaluate the contributions from varied sources.

How to cite: Liu, Y.: Semi-quantitative understanding of source contribution to nitrous acid (HONO) based on 1 year of continuous observation at the SORPES station in eastern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8791, https://doi.org/10.5194/egusphere-egu2020-8791, 2020.

EGU2020-1822 | Displays | AS3.2

Observations of aerosol and NO2 vertical profiles derived from MAX-DOAS in four metropolises of China during 2019

Chengzhi Xing, Cheng Liu, Haoran Liu, Qihua Li, Wei Tan, Hua Lin, Xiangguang Ji, Pengcheng Zhu, Heng Xu, and Jianguo Liu

Air pollution has become one of the major environmental problems around the world. It is particularly serious in China due to the rapid development of the economy and industrialization. Four ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS) were performed in four metropolises of China during 2019. Beijing, Nanjing, Guangzhou and Chongqing are central cities of Beijing-Tianjin-Hebei region, Yangtze River Delta, Pearl River Delta and Sichuan basin, four major polluted areas of China, respectively. In this study, vertical profiles of aerosol extinction coefficient, nitrogen dioxide (NO2) in these four cities were retrieved from MAX-DOAS. In order to understand the pollution characteristics in four major polluted areas during 2019, the averaged diurnal variation and seasonal variation of aerosol and NO2 in above four cities were performed. On the other hand, the differences of vertical structure of aerosol and NO2 in four cities were analyzed. In addition, the variation of PM2.5, PM10 and PM2.5/PM10 in above four cities during 2019 were analyzed, and it is helpful to understand the formation and source of haze occurred in the four major polluted areas. PM2.5/PM10 increasing when PM2.5 pollution became worse indicates that regional transport is the major pathway for haze. PM2.5/PM10 decreasing when PM2.5 pollution became worse indicates that primary emission and secondary chemistry are the major pathways for haze.

How to cite: Xing, C., Liu, C., Liu, H., Li, Q., Tan, W., Lin, H., Ji, X., Zhu, P., Xu, H., and Liu, J.: Observations of aerosol and NO2 vertical profiles derived from MAX-DOAS in four metropolises of China during 2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1822, https://doi.org/10.5194/egusphere-egu2020-1822, 2020.

EGU2020-1823 | Displays | AS3.2

Long distance mobile MAX-DOAS observation of NO2 and SO2 over the North China Plain, and identification of regional transport and emission of power plant

Wei Tan, Cheng Liu, Shanshan Wang, Haoran Liu, Yizhi Zhu, Wenjing Su, Qihou Hu, and Jianguo Liu

In this study, the spatial-temporal distribution of the NO2 and SO2 Vertical Columns Densities (VCDs) in the North China Plain (NCP) region was achieved by the long-distance mobile measurements using the mobile Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) instrument. The mobile observations were taken in both summer (July 2017) and winter (January and February 2018) and the total driving mileage exceeded 3000 km. The concentrations of NO2 and SO2 pollution in different seasons and places were significantly different. During winter observations, the serious NO2 and SO2 pollution were both observed in northern Anhui province, central Shandong province, and the Beijing-Tianjin-Hebei Region. The evolution and transportation process of the three typical heavy pollution cases were discussed in detail. Combined with the WRF-chem simulated wind field information, the NO2 transportation flux from the northern Jiangsu province to the northern Anhui province was quantified to be 7.12 kg s-1. Finally, we estimated the NO2 and SO2 emissions from the Dezhou and Hengshui power plants by the plume cross section scanning observation and encircled observation methods, respectively. The NO2 and SO2 emission fluxes of the Dezhou power plant are 0.79 and 1.11 kg s-1, while the NO2 and SO2 emission fluxes of the Hengshui power plant are 0.12 and 0.36 kg s-1. This study has quantitatively analyzed the transportations of atmospheric pollutants and emissions of power plants, which is helpful to understand the occurrence and evolution of pollution and also useful for the government to put forward some policies to protect and control the atmospheric environment.

How to cite: Tan, W., Liu, C., Wang, S., Liu, H., Zhu, Y., Su, W., Hu, Q., and Liu, J.: Long distance mobile MAX-DOAS observation of NO2 and SO2 over the North China Plain, and identification of regional transport and emission of power plant, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1823, https://doi.org/10.5194/egusphere-egu2020-1823, 2020.

EGU2020-10924 | Displays | AS3.2

Tropopause folds in North America studied from partial columns of trace gases measured at two ground-based sites

Ruben Pavia-Hernandez, Michel Grutter, Wolfgang Stremme, Kimberly Strong, and Shoma Yamanouchi

Tropopause folds can change the composition of the Upper Troposphere (UT) by bringing down stratospheric parcels with different gas abundances. In this work, partial columns of gases with strong vertical gradients near the tropopause are studied during such events. Partial columns were retrieved from high-resolution infrared spectra measured at subtropical and mid-latitude locations. These stations, contributing to the Network for the Detection of Atmospheric Composition Change (NDACC), are the Altzomoni High-altitude Observatory (19.11°N, 98.66°W) in central Mexico, and the University of Toronto Atmospheric Observatory (43.66°N, 79.40°W) in southern Canada. These datasets constitute a valuable tool for studying the effects of folding on UT composition because of their time resolution (~ 1-hourly, during daylight) and the time periods they span (2012–2019 and 2002–2019, respectively). Our study shows that when tropopause folds occur, partial columns below the tropopause are correlated (anti-correlated) for species whose vertical gradients have the same (different) signs. It is also shown that tropospheric carbon monoxide (CO) in layers closest to the tropopause contributes less to the CO tropospheric partial column during folds because the UT receives low-CO air from the stratosphere.

How to cite: Pavia-Hernandez, R., Grutter, M., Stremme, W., Strong, K., and Yamanouchi, S.: Tropopause folds in North America studied from partial columns of trace gases measured at two ground-based sites, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10924, https://doi.org/10.5194/egusphere-egu2020-10924, 2020.

EGU2020-1774 | Displays | AS3.2

Satellite UV-Vis spectroscopy: implications for air quality trends and their driving forces in China during 2005–2017

Chengxin Zhang, Cheng Liu, Qihou Hu, Zhaonan Cai, Wenjing Su, Congzi Xia, Yizhi Zhu, Siwen Wang, and Jianguo Liu

Abundances of a range of air pollutants can be inferred from satellite UV-Vis spectroscopy measurements by using the unique absorption signatures of gas species. Here, we implemented several spectral fitting methods to retrieve tropospheric NO2, SO2, and HCHO from the ozone monitoring instrument (OMI), with radiative simulations providing necessary information on the interactions of scattered solar light within the atmosphere. We analyzed the spatial distribution and temporal trends of satellite-observed air pollutants over eastern China during 2005–2017, especially in heavily polluted regions. We found significant decreasing trends in NO2 and SO2 since 2011 over most regions, despite varying temporal features and turning points. In contrast, an overall increasing trend was identified for tropospheric HCHO over these regions in recent years. Furthermore, generalized additive models were implemented to understand the driving forces of air quality trends in China and assess the effectiveness of emission controls. Our results indicated that although meteorological parameters, such as wind, water vapor, solar radiation and temperature, mainly dominated the day-to-day and seasonal fluctuations in air pollutants, anthropogenic emissions played a unique role in the long-term variation in the ambient concentrations of NO2, SO2, and HCHO in the past 13 years. Generally, recent declines in NO2 and SO2 could be attributed to emission reductions due to effective air quality policies, and the opposite trends in HCHO may urge the need to control anthropogenic volatile organic compound (VOC) emissions.

How to cite: Zhang, C., Liu, C., Hu, Q., Cai, Z., Su, W., Xia, C., Zhu, Y., Wang, S., and Liu, J.: Satellite UV-Vis spectroscopy: implications for air quality trends and their driving forces in China during 2005–2017, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1774, https://doi.org/10.5194/egusphere-egu2020-1774, 2020.

EGU2020-5186 | Displays | AS3.2

Total columns of freons retrieved from ground-based IR solar spectra measurements near Saint Petersburg, Russia

Alexander Polyakov, Maria Makarova, Yana Virolainen, Anatoly Poberovsky, and Yury Timofeyev

Measurements of the atmospheric total columns (TCs) of trichlorofluoromethane CCl3F (CFC-11), dichlorodifluoromethane CCl2F2 (CFC-12), and chlorodifluoromethane CHClF2 (HCFC-22)  at the NDACC station St. Petersburg are considered. These gases are the most common representatives of a group of aliphatic organic compounds often called by the DuPont brandname "Freons". Since the 30-ies of the last century, they have been used in industrial applications as refrigerants and propellants. Due to their destructive effect on the ozone layer the production of CFC-11 and CFC-12 has been phased out under the Montreal Protocol entered into force in 1989, which led to the beginning of a decrease in their content. Nevertheless, they are still one of the major anthropogenic sources of active chlorine that destroys ozone in the stratosphere. HCFC-22 became a replacement for the most dangerous for ozone layer freons, but later it was also recognized as a dangerous compound for stratospheric ozone. Nowadays, the production and consumption of HCFC-22 are reduced and it is planned to be completely phased out. Therefore, the monitoring the content of freons in the atmosphere is very important.

Although the content of freons is measured by satellite methods and the sampling method, only the ground-based IR method based on the measurement of IR solar radiation allows obtaining TCs of freons.

A technique for ground-based measurements of the TCs of CFC-11, CFC-12, and HCFH-22 has been developed. The technique is based on the ground-based measurements of solar IR spectra by IFS125HR instrument. For the processing of spectra, the SFIT4 software is used. The analyzed spectral windows are: 1160 – 1162 cm-1 for CFC-12, 828.75 – 829.4cm-1 for HCFC-22, and  830 – 860 cm-1 for CFC-11. Due to the wide spectral interval for CFC-11 retrieval, the preliminary measured spectral transmission function of the instrument filter, the water vapor continuum, and the absorption of radiation by an ice on the MCT detector are taken into account as well. Systematic and random errors of TCs retrieval are estimated as 7.4% and 2.9% for the CFC-11 TCs, 5.0% and 3.7% for the CFC-12 TCs, and 2.0% and 2.7% for the HCFH -22 TCs.

Estimates of TCs above Saint Petersburg have been obtained using the developed technique for the period of 2009 – 2019. The variability during  a day is of 0.8, 0.9, and 3.7 %, the total variabilitiey for 2009 – 2019 is of 3.7, 2.4 and 5.6%, for CFC-11, CFC-12 and HCFC-22, respectively. Trend estimates of CFC-11, CFC-12 and HCFC-22 for 2009 –2019 are –0.31±0.07%, –0.45 ± 0.06% and +2.2 ± 0.14%, respectively, which  are consistent with data from other authors.

In recent years, a tendency toward a decrease of HCFC-22 TCs in the atmosphere above St. Petersburg has been observed, that can be associated with the restriction of HCFC-22 production and use.

Acknowledgements

Measurements of solar radiation were performed with the equipment of the resource center "Geomodel". The investigation was supported by grant 18-05-00426 of the Russian Foundation for Basic Research.

How to cite: Polyakov, A., Makarova, M., Virolainen, Y., Poberovsky, A., and Timofeyev, Y.: Total columns of freons retrieved from ground-based IR solar spectra measurements near Saint Petersburg, Russia, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5186, https://doi.org/10.5194/egusphere-egu2020-5186, 2020.

Reactions with hydroxyl radicals and photolysis are the main processes dictating a compound’s residence time in the atmosphere for a majority of trace gases.  In case of very short-lived halocarbons their reaction with OH dictates both the atmospheric lifetime and active halogen release.  Therefore, the accuracy of OH kinetic data is of primary importance for the comprehensive modeling of a compound’s impact on the atmosphere, such as in ozone depletion (i.e., the Ozone Depletion Potential, ODP) and climate change (i.e., the Global Warming Potential, GWP), each of which are dependent on the atmospheric lifetime of the compound.

 

Atmospheric modeling provides total lifetimes for a number of compounds as well as their partial lifetimes due to specific photochemical removal process (reactions with OH in the troposphere, reactions with OH in the stratosphere, reactions with O(1D), and UV photolysis), and partial lifetimes associated with the atmospheric removal regions (troposphere and stratosphere).  We have analyzed these results in an effort to find a correlation useful for estimating the lifetimes of other atmospheric trace gases based only on laboratory data of their photochemical properties.  Based on this analysis, we suggest an improved semi-empirical approach for deriving a “best” value of the total atmospheric lifetime due to photochemical removal processes based on laboratory derived photochemical properties of a compound, which is consistent with both empirically derived tropospheric lifetime of Methyl Chloroform and results of rigorous atmospheric modeling.  These aspects will be illustrated in this presentation for a variety of atmospheric trace gases.

 

The ability to conduct high accuracy laboratory determinations of OH reaction rate constants over the temperature range of atmospheric interest, thereby decreasing the uncertainty of input kinetic data to 2-3% will be demonstrated as well.

How to cite: Orkin, V., Kurylo, M., and Fleming, E.: Atmospheric Lifetimes of Halogenated Hydrocarbons: Laboratory Measurements and Improved Estimations from an Analysis of Modeling Results., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12842, https://doi.org/10.5194/egusphere-egu2020-12842, 2020.

EGU2020-12955 | Displays | AS3.2

The impact of iodine on ozone trends in the lower stratosphere

Martyn Chipperfield, Wuhu Feng, Sandip Dhomse, Yajuan Li, Ryan Hossaini, and Klaus Pfeilsticker

Depletion of the stratospheric ozone layer by chlorine and bromine species has been a major environmental issue since the early 1970s. Following controls on the production of the long-lived halocarbons which transport chlorine and bromine to the stratosphere, the ozone layer is expected to recover over the course of this century. Decreases in the stratospheric loading of chlorine and bromine have been observed and there are signs of this resulting in an increase in ozone in the upper stratosphere and the Antarctic lower stratosphere. However, in contrast to this expectation of increasing stratospheric ozone, Ball et al. (ACP doi:10.5194/acp-18-1379-2018, 2018, ACP doi:10.5194/acp-19-12731-2019, 2019) have reported evidence for an ongoing decline in lower stratospheric ozone at extrapolar latitudes between 60°S and 60°N. Chipperfield et al. (GRL, doi:10.1029/2018GL078071, 2018) analysed these results using the TOMCAT 3-D chemical transport model (CTM). They reported that much of the observed ozone decrease could be explained by dynamical variability. Furthermore, they investigated the potential role for bromine and chlorine from very short-lived species (VSLS) but found only a small contribution.

Very recently, Koenig et al. (PNAS, doi:10.1073/pnas.1916828117, 2020) have reported quantitative observations of almost 1 pptv iodine in the lower stratosphere. They show that this iodine is an important contribution to the local iodine loss budget and speculate that a trend in iodine could therefore explain the observed downward trend in ozone.

Here we use an updated version of the TOMCAT CTM to investigate the impact of iodine on lower stratospheric ozone trends. We repeat the simulations of Chipperfield et al. (2018), using both ERA-Interim and ERA5 reanalyses (to compare the quantification of the dynamical contribution). We use assume trends in the stratospheric injection of iodine to quantify the possible impact of this on global ozone trends through both gas-phase chemistry and novel heterogeneous processes.

 

How to cite: Chipperfield, M., Feng, W., Dhomse, S., Li, Y., Hossaini, R., and Pfeilsticker, K.: The impact of iodine on ozone trends in the lower stratosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12955, https://doi.org/10.5194/egusphere-egu2020-12955, 2020.

Polychlorinated biphenyls (PCBs) are persistent and hazardous chemicals that are still detected in the atmosphere and other environmental compartments although their production was banned several decades ago. At the Great Lakes region PCBs have been monitored via the IADN network since 1993. In this study, we report results from seven different PCB congeners measured at six different sites around the Great Lakes. The PCBs exhibit a strong seasonal cycle with highest concentrations in summer and lowest concentrations in winter. The concentrations measured in Chicago and Cleveland are higher compared to the concentrations reported from more remote stations. We evaluated the correlations for the seven PCB congeners at each station. PCB-53,-101,-118 and -138 are highly correlated at each of the six stations. PCB-180 is the least correlated with all the other PCBs. This is explicitly true for Eagle Harbor, where PCB-180 and -153 are not correlated with the other 6 PCBs. This may be explained by the less pronounced seasonal cycle of these heavier PCBs at Eagle Harbor. We observed significant correlations between PCB-28 concentrations at the remote stations, but PCB concentrations at the stations of Chicago and Cleveland are only poorly correlated with PCB concentrations at the other stations. The weak correlation of the PCB concentrations measured at the different stations and the relatively high concentrations of the PCB congeners at each station indicate that local conditions and small scale processes (sources, temperature, wind direction, wind speed) dictate the spatial distribution of the  PCBs. We will feed available data on temperature, wind speed, wind direction, emissions, precipitation, ice cover of the Great Lakes and large scale atmospheric teleconnection patterns into a General Additive Model (GAM) to further investigate the relationships between the measured PCB concentrations and selected environmental conditions and atmospheric parameters. 

How to cite: Ubl, S. and Scheringer, M.: Dependencies of Polychlorinated Biphenyl Concentrations Measured at the Great Lakes on Climate Variables, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16640, https://doi.org/10.5194/egusphere-egu2020-16640, 2020.

EGU2020-15059 | Displays | AS3.2

The FDR4ATMOS Project

Günter Lichtenberg, Sander Slijkhuis, Mourad Hamidouche, Melanie Coldewey-Egbers, Bernd Aberle, Stefan Noël, Klaus Bramstedt, Tina Hilbig, Tim Bösch, Jean-Christopher Lambert, Jeroen van Gent, Daan Hubert, Paul Green, Sam Hunt, Matthijs Krijger, Angelika Dehn, and Gabriele Brizzi

The Fundamental Data Record for ATMOSpheric Composition (FDR4ATMOS) project is part of the ESA Long Term Data Preservation (LTDP) programme aimed at the preservation and valorization of data assets from ESA’s Earth Observation (EO) Heritage Missions. It has two objectives. The first one is to update the SCIAMACHY processing chain for better Ozone total column data. After the full re-processing of the SCIAMACHY mission with the updated processor versions 9 (Level 1) and version 7 (Level 2), ground-based validation showed that the total Ozone column drifted downward by nearly 2% over the mission lifetime. This drift is likely caused by changes in the degradation correction in the Level 1 processor, that led to subtle changes in the spectral structures. These are misinterpreted as an atmospheric signature. FDR4ATMOS will update the Level 0-1 processor accordingly with the final aim of a mission re-processing.

The main objective of the FDR4ATMOS project is to develop a cross-instrument Level 1 product for GOME-1 and SCIAMACHY for the UV, VIS and NIR spectral range, with focus on the spectral windows used for O3, SO2, NO2 total column retrieval and the determination of cloud properties. Contrary to other projects, FDR4ATMOS does not aim to build harmonised time series based on Level 2 products (geophysical parameters) but to build a Fundamental Data Record (FDR) of Level 1 products, i.e. radiances and reflectances. The GOME-1 and SCIAMACHY instruments together span 17 years of spectrally highly resolved data essential for air quality, climate, ozone trend and UV radiation applications. The goal of the FDR4ATMOS project is to generate harmonised data sets that allow the user to use it directly in long-term trend analysis, independently of the instrument. Since this was never done for highly resolved spectrometers, new methods have to be developed that e.g. take into account the different observation geometries and observation times of the instrument without impacting the spectral structures that are used for the retrieval of the atmospheric species. The resulting algorithms and the processor should also be as generic as possible to be able to easily transfer the methodology to other instruments (e.g. GOME-2 and Sentinel-5p) for a future extension of the time series. The project will support new applications and services and will enhance traceability of satellite-derived data with improved uncertainty estimates based on rigorous metrological principles.

FDR4ATMOS started in October 2019 and is currently in phase 1. We will present the motivation, goals and first results of the project.



How to cite: Lichtenberg, G., Slijkhuis, S., Hamidouche, M., Coldewey-Egbers, M., Aberle, B., Noël, S., Bramstedt, K., Hilbig, T., Bösch, T., Lambert, J.-C., van Gent, J., Hubert, D., Green, P., Hunt, S., Krijger, M., Dehn, A., and Brizzi, G.: The FDR4ATMOS Project, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15059, https://doi.org/10.5194/egusphere-egu2020-15059, 2020.

EGU2020-12154 | Displays | AS3.2

Atmospheric composition changes in CMIP6 experiments over the North Atlantic region

Paul Griffiths, James Keeble, Fiona O'Connor, Alexander Archibald, and John Pyle and the UKESM1 AerChemMIP team

A grand challenge in the field of chemistry-climate modelling is understanding the connection between anthropogenic emissions, atmospheric composition and the radiative forcing of trace gases and aerosols.

The 6th phase of the Coupled Model Intercomparison Project (CMIP6) includes a number of climate model experiments that can be used for this purpose.  AerChemMIP [Collins et al.2017] focuses on calculating the radiative forcing of gases and aerosol particles over the period 1850 to 2100, and comprises several tiers of experiments designed to attribute the effect of changes in emissions. 

The UK Earth System Model, UKESM-1, is a novel climate model developed for CMIP6  [Sellar et al., 2019] and is a community research tool for studying past and future climate.  It includes a detailed treatment of tropospheric chemistry, interactive BVOC emissions and extensive stratospheric chemistry.

The North Atlantic Climate System is an area of current interest [Robson et al., 2020] and is the focus of the UKRI 'ACSIS' project.  ACSIS brings together scientists from a range of different specialisms to understand complex changes in the North Atlantic climate system.    By understanding how these changes relate to external drivers of climate, such as human activity, or natural variability, ACSIS aims to improve our capability to detect, explain and predict changes in the North Atlantic climate system.

We present an analysis of the evolution of atmospheric composition over the period 1950-2015. The work is based on a recent global multi-model evaluation of tropospheric ozone for CMIP6 [Griffiths et al., 2020] , but focuses on changes over the North Atlantic region in UKESM-1.  We draw on CMIP and AerChemMIP simulations to provide an initial survey of the response of this region to changing emissions , focusing on atmospheric composition and attempting attribution from a series of targeted experiments involving perturbed emissions .

How to cite: Griffiths, P., Keeble, J., O'Connor, F., Archibald, A., and Pyle, J. and the UKESM1 AerChemMIP team: Atmospheric composition changes in CMIP6 experiments over the North Atlantic region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12154, https://doi.org/10.5194/egusphere-egu2020-12154, 2020.

EGU2020-18458 | Displays | AS3.2

Constraints on OH in a global 3D inversion of methyl chloroform

Stijn Naus, Stephen Montzka, Prabir Patra, and Maarten Krol

The hydroxyl radical (OH) is the primary atmospheric oxidant. In this role, OH is involved in the removal of a wide variety of atmospheric pollutants and greenhouse gases. Despite the central role of OH in atmospheric chemistry, important metrics such as interannual variability and trends in OH on large spatial scales remain poorly constrained. This is mainly due to its low abundance and short lifetime of seconds.

Over the past decades, the anthropogenically emitted methyl chloroform (MCF) has been uniquely qualified as a tracer to indirectly constrain OH on large spatio-temporal scales. However, recent box model studies have shown that OH, as estimated from MCF observations, is still very uncertain 1,2,3. This translates for example to large uncertainties in global methane (CH4) emissions, even if changes in the global CH4 burden are well-defined. Box model studies however, do not fully capitalize on the MCF measurement network and the gradients therein. Moreover, they may introduce biases due to incorrect or incomplete representation of atmospheric transport.

Here, we present results from a 4DVAR inversion of MCF over the 1998-2018 period, performed in the 3D chemistry-transport model TM5. Starting from typical OH priors, we find adjustments in the OH spatio-temporal distribution that bring the simulated MCF mole fractions closer to observations. Large uncertainties in this improved estimate remain, but we find that no large interannual variability (>2%) and no significant trend in global mean OH are needed to match MCF observations. We do find significant adjustments in the latitudinal gradients of OH (e.g. an increase in tropical OH).

Rigby, M., et al. PNAS (2017), 114.21: 5373-5377

2 Turner, A.J., et al. PNAS (2017), 114.21: 5367-5372

3 Naus, S et al. ACP (2019), 19.1: 407-424

How to cite: Naus, S., Montzka, S., Patra, P., and Krol, M.: Constraints on OH in a global 3D inversion of methyl chloroform, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18458, https://doi.org/10.5194/egusphere-egu2020-18458, 2020.

EGU2020-7651 | Displays | AS3.2

The state of greenhouse gases in the atmosphere using global observations through 2018

Oksana Tarasova, Alex Vermeulen, Jocelyn Turnbull, Yousuke Sawa, and Ed Dlugokencky

We present results from the fifteenth annual Greenhouse Gas Bulletin (https://library.wmo.int/doc_num.php?explnum_id=10100) of the World Meteorological Organization (WMO). The results are based on research and observations performed by laboratories contributing to the WMO Global Atmosphere Watch (GAW) Programme (https://community.wmo.int/activity-areas/gaw).

The Bulletin presents results of global analyses of observational data collected according to GAW recommended practices and submitted to the World Data Center for Greenhouse Gases (WDCGG). Bulletins are prepared by the WMO/GAW Scientific Advisory Group for Greenhouse Gases in collaboration with WDCGG.

Observations used for the global analysis are collected at more than 100 marine and terrestrial sites worldwide for CO2 and CH4 and at a smaller number of sites for other greenhouse gases. The globally averaged surface mole fractions calculated from this in situ network reached new highs in 2018, with CO2 at 407.8 ± 0.1 ppm, CH4 at 1869 ± 2 ppb and N2O at 331.1 ± 0.1 ppb. These values constitute, respectively, 147%, 259% and 123% of pre-industrial (before 1750) levels. The increase in CO2 from 2017 to 2018 is very close to that observed from 2016 to 2017 and practically equal to the average growth rate over the last decade. The increase of CH4 from 2017 to 2018 was higher than both that observed from 2016 to 2017 and the average growth rate over the last decade. The increase of N2O from 2017 to 2018 was also higher than that observed from 2016 to 2017 and the average growth rate over the past 10 years. The National Oceanic and Atmospheric Administration (NOAA) Annual Greenhouse Gas Index (AGGI) shows that from 1990 to 2018, radiative forcing by long-lived greenhouse gases (GHGs) increased by 43%, with CO2 accounting for about 81% of this increase.

The Bulletin highlights the value of the long-term measurement of the GHGs isotopic composition. In particular, it presents the use of the radiocarbon and 13C measurements in atmospheric CO2 in discriminating between fossil fuel combustion and natural sources of CO2. The simultaneous decline in both 13C and 14C content alongside CO2 increases can only be explained by the ongoing release of CO2 from fossil fuel burning. The Bulletin also articulates how the measurements of the stable isotopes can be used to provide the insights into the renewed growth of methane that started in 2007. Though there are several hypotheses articulated in the peer-reviewed literature, the most plausible is that an increase has occurred in some or all sources of biogenic (wetlands, ruminants or waste) emissions, which contain relatively little 13C. An increase in the proportion of global emissions from microbial sources may have driven both the increase in the methane burden and the shift in δ13C-CH4.

How to cite: Tarasova, O., Vermeulen, A., Turnbull, J., Sawa, Y., and Dlugokencky, E.: The state of greenhouse gases in the atmosphere using global observations through 2018, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7651, https://doi.org/10.5194/egusphere-egu2020-7651, 2020.

EGU2020-20807 | Displays | AS3.2

Carbon dioxide variability at Research Station "Ice Base Cape Baranova" during 2015 - 2019

Marina Loskutova, Alexander Makshtas, Tuomas Laurila, and Eija Asmi

The Arctic region is one of the main areas of greenhouse gases sources due to large amount of biomass, carbon stocks in the soil and extensive wetlands. Large resources of previously inactive organic carbon may take part in atmospheric chemical reactions under melting permafrost conditions. In this case, carbon dioxide concentrations will increase in the atmosphere. Since 2015 Arctic and Antarctic Research Institute in cooperation with Finnish Meteorological Institute have been measuring the continuous concentrations of water vapor, methane, carbon dioxide and carbon monoxide at Research Station "Ice Base Cape Baranova" (79° 18´ N, 101° 48´ E, 30 m asl.) using cavity ringdown spectroscopy (CRDS) analyzer Picarro G2401. The sampling inlet is located at 10 m height.

Data preprocessing consists of deleting values obtained during power failures and 2 minutes after calibration. The values for wind directions corresponding to the transfer from diesel power station (90 - 145 °) and for wind speeds less than 3 m/s were also discarded because in this case polluted air may be distributed over the station homogeneously. After that data were adjusted taking into account the nearest calibration values by linear interpolation. The archive of carbon dioxide concentrations data averaged over each hour from October 2015 to December 2019 was used for further analysis.

CO2 time series are characterized by a pronounced annual variation with concentration decreasing in summer months. The absorption by sea phytoplankton in the absence of sea ice cover causes the annual variability of carbon dioxide. Besides, the predominant presence of stable stratification of the atmospheric surface layer throughout the polar night contributes to accumulation of the gas in the surface layer in winter. The annual amplitude is 18–20 ppm approximately, which is consistent with the data of Alert and Barrow polar stations.

The analysis of the dependence of registered concentration distribution on the wind direction shows that the highest values are observed during the air-mass transfer from the south-western and northern directions. If the first case can be explained by the anthropogenic impact and presence of extensive wetlands in the summer, the reason for the second one requires a more detailed analysis. Applying the HYSPLIT trajectory model for cases of elevated values of greenhouse gas concentrations did not allow us to obtain an unambiguous answer. Although elevated values were observed, as a rule, when air masses transferred from the regions of Norilsk, Yamal, the Kola Peninsula, and Lena estuary, however, there were cases of elevated concentrations during the transfer of air masses from the Arctic Ocean. This may be due to the action of any local sources, but their detection requires additional data analysis. The work had been executed in frame of CNTP Roshydromet 1.5.3.3.

How to cite: Loskutova, M., Makshtas, A., Laurila, T., and Asmi, E.: Carbon dioxide variability at Research Station "Ice Base Cape Baranova" during 2015 - 2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20807, https://doi.org/10.5194/egusphere-egu2020-20807, 2020.

EGU2020-9432 | Displays | AS3.2

Italian network of four permanent observatories: implementation of background data selection (BaDSfit) and 5-year analysis of the atmospheric CO2 mixing ratio.

Pamela Trisolino, Alcide di Sarra, Damiano Sferlazzo, Salvatore Piacentino, Francesco Monteleone, Tatiana Di Iorio, Francesco Apadula, Daniela Heltai, Andrea Lanza, Antonio Vocino, Luigi Caracciolo di Torchiarolo, Paolo Bonasoni, Francescopiero Calzolari, Maurizio Busetto, and Paolo Cristofanelli

The Mediterranean basin is considered a global hot-spot region for climate change and air-quality. CO2 is the single most-important anthropogenic greenhouse gas (GHG) in the atmosphere, accounting approximatively for ∼63% of the anthropogenic radiative forcing by long-lived GHG. According to Le Quérée et al. (2018), the increasing of the atmospheric CO2 mixing ratios in the global atmosphere is driven by fossil fuel and cement production.
In order to reduce GHG emissions and taking into account the needs for economy and society development, schemes of regulation and emission trading have been adopted at international, national, and city levels. The implementation of these regulation, to achieve the goal successfully, needs scientific evidence and information provided on consistent datasets. In the last year, efforts are dedicated to set up harmonized reference networks at difference scales (WMO/GAW, AGAGE, ICOS).
In this work, we analysed a set of continuous long-term measurements of CO2 carried out at 4 atmospheric observatories in Italy belonging to the WMO/GAW network and spanning from the Alpine region to central Mediterranean Sea: Plateau Rosa (western Italian Alps, 3480 m a.s.l.), Mt. Cimone (northern Apennines, 2165 m a.s.l.), Capo Granitola (southern Sicily coastline) and Lampedusa Island. Mt. Cimone is also a “class-2” ICOS station, while Plateau Rosa and Lampedusa are in the labelling process. Starting time of GHG observations range from 1979 for Mt. Cimone to 2015 for Capo Granitola. Due to their different locations and ecosystems, they provide useful hints to investigate CO2 variability on different latitudinal and altitudinal ranges in the Mediterranean basin and to study of natural and anthropogenic-related processes able to affect the observed variability.
The study addresses primarily differences in daily and seasonal cycles at the different sites, and implemented a procedure to identify background conditions called BaDSfit (Background Data Selection for Italian stations; Trisolino et al., submitted). This methodology was originally used at Plateau Rosa station (Apadula, 2019) and it is based on the Mauna Loa data selection method (Tans and Thoning, 2008). BaDSfit consist of three steps and an optimization of the procedure was carried out with a sensitivity study.  Marked differences among the daily cycles at the various sites exist. The effect of the data selection on the seasonal and diurnal cycle and long-term evolution is investigated. The BaDSfit lead to a more coherent diurnal and seasonal evolution of the different datasets, is able to identify background condition and allows the separation of local/regional scale from large scale phenomena in the CO2 time series.

How to cite: Trisolino, P., di Sarra, A., Sferlazzo, D., Piacentino, S., Monteleone, F., Di Iorio, T., Apadula, F., Heltai, D., Lanza, A., Vocino, A., Caracciolo di Torchiarolo, L., Bonasoni, P., Calzolari, F., Busetto, M., and Cristofanelli, P.: Italian network of four permanent observatories: implementation of background data selection (BaDSfit) and 5-year analysis of the atmospheric CO2 mixing ratio., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9432, https://doi.org/10.5194/egusphere-egu2020-9432, 2020.

EGU2020-16371 | Displays | AS3.2

Update on IAGOS greenhouse gas observations from commercial airliners

Christoph Gerbig, Harald Franke, Ralf Stosius, Florian Obersteiner, Torsten Gehrlein, and Andreas Zahn

Within the framework of the research infrastructure IAGOS (In-service Aircraft for a Global Observing System), a cavity ring-down spectroscopy (CRDS)-based measurement system for the autonomous measurement of the greenhouse gases (GHGs) CO2 and CH2, as well as CO and water vapour is deployed on a Lufthansa Airbus A330 since September 2018. This IAGOS-CORE system is equipped with a two-standard in-flight calibration system, allowing for trace gas measurements to be fully traceable to WMO calibration scales. Various lessons have been learned during the first deployment periods related to the autonomous operation of the system over periods of several months, enabling the future extension of the GHG measurements to aircraft from further airlines. Apart from the presentation of the observations, the presentation will discuss the data quality and uncertainty estimation.

A further CRDS system for autonomous measurement CO2 and CH4 is integrated within the instrumented IAGOS-CARIBIC container deployed on board an Airbus A340 on a bi-monthly schedule since July 2018. By now this system has provided data from more than 30 flights. Data will be presented, and the potential of the observations for research applications will be introduced. Also the availability of IAGOS GHG data to the research community will be discussed.

How to cite: Gerbig, C., Franke, H., Stosius, R., Obersteiner, F., Gehrlein, T., and Zahn, A.: Update on IAGOS greenhouse gas observations from commercial airliners, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16371, https://doi.org/10.5194/egusphere-egu2020-16371, 2020.

EGU2020-18864 | Displays | AS3.2

Using robust baseline extraction to examine synoptic-scale variability in European CO2

Alex Resovsky, Michel Ramonet, Leonard Rivier, Sebastien Conil, and Gerard Spain

Continuous measurements of long-lived greenhouse gases at ground-based monitoring stations are frequently influenced by regional surface fluxes and atmospheric transport processes, which induce variability at a range of timescales.  Dissecting this variability is critical to identifying long-term trends and understanding regional source-sink patterns, but it requires a robust characterization of the underlying signal comprising the background air composition at a given site.  Methods of background signal extraction that make use of chemical markers or meteorological filters yield reliable estimates, but often must be adapted for site-specific measurement conditions and data availability.  Statistical baseline extraction tools provide a more generally transferable alternative to such methods.  Here, we apply one such technique (REBS) to a continuous time series of atmospheric CO2 readings at Mace Head, Ireland and compare the results to a modeled baseline signal obtained from local wind observations. We then assess REBS’ performance at two continental sites within the Integrated Carbon Observation System (ICOS) network at which baseline signals are derived using back-trajectory analyses.  Overall, we find that REBS effectively reduces the bias in wintertime baseline estimation relative to other statistical techniques, and thus represents a computationally inexpensive and transferable approach to baseline extraction in atmospheric time series. To investigate one potential application of such an approach, we examine wintertime synoptic-scale CO2 excursions from the REBS baseline during the period 2015-2019.  Our goal is to identify relationships between the timing and strength of such events and to better understand sub-seasonal variability in CO2 transport over Europe.

How to cite: Resovsky, A., Ramonet, M., Rivier, L., Conil, S., and Spain, G.: Using robust baseline extraction to examine synoptic-scale variability in European CO2, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18864, https://doi.org/10.5194/egusphere-egu2020-18864, 2020.

EGU2020-18289 | Displays | AS3.2

Investigation of global atmospheric carbonyl sulphide between 2004 and 2018: an observational and modelling study

Michael P. Cartwright, Jeremy J. Harrison, David P. Moore, John J. Remedios, Martyn P. Chipperfield, and Richard J. Pope

The challenge in quantifying the sources and sinks of atmospheric carbon dioxide (CO2) is that the CO2 taken up by plants during photosynthesis cannot be distinguished from the CO2 released by plants and micro-organisms during respiration. It has been shown that carbonyl sulfide (OCS), the sulphur-containing analogue of CO2, can be used as a proxy for photosynthesis. The relationship between the vegetative flux of OCS and CO2 has been quantified for various species of plants and ecosystems, the results of which have been used in observing the relationship on a continental scale. The aim of this project is to both quantify the location and magnitude of the sources and sinks of atmospheric OCS, and to use these data to infer photosynthetic uptake of CO2 by vegetation on a global scale.

A tracer version of the 3-dimensional chemical transport model TOMCAT has been adapted to include eleven different sources and sinks of OCS, including direct and indirect oceanic emissions, vegetative uptake and stratospheric photolysis. The modelled OCS (TOMCAT-OCS) distribution between 2004 and 2018 has been co-located spatially and temporally to OCS profiles measured by the Atmospheric Chemistry Experiment (ACE-FTS) over the 5 – 30 km altitude, showing generally good agreement. Furthermore, surface TOMCAT-OCS has been compared to OCS measurements made at twelve NOAA-ESRL sites, across both hemispheres, showing that the model captures the seasonal cycle at the surface.

There have been several calls in recent years for a new satellite product of atmospheric OCS, which this project aims to satisfy. Work is ongoing to retrieve OCS total columns from measurements taken by the Infrared Atmospheric Sounding Interferometer (IASI) instruments on-board the MetOp satellites. The University of Leicester IASI Retrieval Scheme (ULIRS) has been adapted to retrieve OCS columns globally. Various case studies for different geographic regions and time periods will be presented and compared to other satellite observations.

How to cite: Cartwright, M. P., Harrison, J. J., Moore, D. P., Remedios, J. J., Chipperfield, M. P., and Pope, R. J.: Investigation of global atmospheric carbonyl sulphide between 2004 and 2018: an observational and modelling study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18289, https://doi.org/10.5194/egusphere-egu2020-18289, 2020.

EGU2020-12808 | Displays | AS3.2 | Highlight

Methane Past, Present and Future -- 250-year Methane Trend from a Fully Interactive Earth System Model Simulation

Gerd A. Folberth, Nicola Gedney, Chris D. Jones, Fiona M. O'Connor, Alistair A. Sellar, and Andy Wiltshire

Methane (CH4) is the second most important anthropogenic greenhouse gas. Its Global Warming Potential over 100 years (GWP100) exceeds 28 times that of CO2. Methane surface concentrations have steadily increased since the pre-industrial due to industrialisation combined with fossil fuel use. In 1850, around the onset of heavy industrialisation in Europe and North America, the CH4 mole fraction was approximately 700 ppbv, and since then it has increased 2.5-fold to slightly more than 1830 ppbv in 2015. Fossil fuel use, raising of livestock, and cultivation of rice are the dominant contributions to the atmospheric methane burden at present with significant emissions from natural wetlands also playing a central role.


Here we present first results from the UK Earth System Model (UKESM1.0). The default release version of UKESM1.0 has been extended to represent the methane cycle fully interactively, including dynamic wetlands with global CH4, full stratospheric-tropospheric CH4 chemistry, and CH4 surface deposition. The extended configuration is capable of simulating the climate feedbacks on methane wetland emissions which are typically neglected in current Earth system models. Our simulation is driven with anthropogenic CH4 emissions from CMIP6. We conducted fully-coupled transient simulations of the atmospheric CH4 burden from 1850 to 2100 based on the historic and two future scenarios (SSP3-7.0 and SSP1-2.6) scenarios.


We compare the time series of global CH4 surface concentrations between the default CH4 concentration-driven configuration of UKESM1.0 with the fully-interactive emissions-driven configuration. Surface concentrations for the emissions-driven simulation show reasonable agreement with the concentration-driven simulation, but a low bias in the fully interactive simulation gradually emerges after about 1920 which reaches approximately -250 ppbv in the 2000s. We then present a full-cycle CH4 budget analysis based on decadal means for every 50 years between 1850 and 2100. We demonstrate that methane burden and surface mole fractions are expected to return to their 1930s values under SSP1-2.6, albeit with the natural methane sources still heavily disturbed from their original state. We also produce a detailed analysis of the contribution of wetland CH4 emissions for the 250 years of simulation.

 

How to cite: Folberth, G. A., Gedney, N., Jones, C. D., O'Connor, F. M., Sellar, A. A., and Wiltshire, A.: Methane Past, Present and Future -- 250-year Methane Trend from a Fully Interactive Earth System Model Simulation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12808, https://doi.org/10.5194/egusphere-egu2020-12808, 2020.

Measurements of stable isotope ratios of atmospheric CH4 (δ13C-CH4, δD-CH4) have been utilized to evaluate contributions of individual CH4 sources and sinks to global atmospheric CH4 budget. However, given the uncertainty of both the source isotope signatures and kinetic isotope effects, recent estimates of the global atmospheric CH4 budget using stable isotope observations are still inconclusiveRadiocarbon measurements (Δ14C-CH4) could provide stronger additional constraint on the fossil-fuel CH4 sources (i.e.,14C-free), but the uncertainty of 14CH4 emissions from nuclear power facilities and a lack of data have limited such utilization. Here we describe new approach to estimate plausible global CHemissions and sinks scenarios over 1850–2015 using observations and one-box model simulations of atmospheric CH4, δ13C-CH4, δD-CH4, and Δ14C-CH4. As inputs to the model, we prepare a priori bottom-up CH4 emission inventories, total atmospheric CH4 lifetime, source and sink isotope signatures, nuclear power facility database, and atmospheric δ13C-CO2 and Δ14C-CO2 observations and their uncertainties. We then run a Monte Carlo simulation of atmospheric CH4, δ13C-CH4, δD-CH4, and Δ14C-CH4 over the period using the inputs with the uncertainties. By using the observational CH4 and three isotope constraints, we derive the best combinations of biogenic, anthropogenic fossil-fuel, natural geologic, biomass-burning, and nuclear power facility emissions and total CHlifetime. We find that reconciling CH4, δ13C-CH4, δD-CH4, and Δ14C-CH4 observations indicates that (1) natural geologic emissions are likely smaller than the recent bottom-up estimate 43–50 Tg CH4 yr-1 reported by Etiope et al. (2019), (2) biomass burning and anthropogenic fossil emissions are larger than current bottom-up estimates, and (3) biogenic emissions are somewhat smaller than current bottom-up estimates. Our finding suggests multiple isotope measurements, including Δ14C-CH4, have a strong potential to evaluate the current and future bottom-up global CH4 emission inventories.

How to cite: Fujita, R. and Graven, H.: Impact of atmospheric radiocarbon and stable isotope measurements on understanding the global CH4 budget over 1850–2015, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9635, https://doi.org/10.5194/egusphere-egu2020-9635, 2020.

EGU2020-3139 | Displays | AS3.2

A gridded inventory for global CFC-11 emissions from 2008 to 2019

Jianxiong Sheng and Ronald Prinn

CFC-11 is a potent ozone depleting gas and is regulated under the Montreal Protocol. The rate of decline in global CFC-11 concentrations has slowed since 2013 largely due to the renewed, increasing emissions from eastern China (Montzka et al, Nature, 2018; Rigby et al, Nature, 2019). However, regional inversions suggest that this increase only accounts for 40-60% of the global rise. Therefore, there is an urgent need for emission estimates in other regions or countries. A global 3D inversion of atmospheric measurements is essential to improve our understanding of CFC-11 emission trends and sources, but it requires a reliable emission inventory as a prior estimate. In this study, we develop a gridded bottom-up inventory of global CFC-11 emissions from 2008 to 2019. Our inventory is driven by various, gridded proxy datasets including population, energy consumption, GDP per capita, and industrial clusters. A machine learning model is built between the proxy data and the previous emission estimates for eastern China, Korea, and Japan derived from inversions of AGAGE and NOAA surface measurements (Rigby et al, Nature, 2019). Our model is cross-validated in the East Asia and then applied to the other regions and countries to construct the gridded inventory with error characterization. Use of our inventory as prior information in future inverse analyses can help better quantify spatial distributions and sources of CFC-11 emissions as well as better guide the regulation of CFC-11.

How to cite: Sheng, J. and Prinn, R.: A gridded inventory for global CFC-11 emissions from 2008 to 2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3139, https://doi.org/10.5194/egusphere-egu2020-3139, 2020.

EGU2020-11308 | Displays | AS3.2

A recent slowdown in the decline of CFC-11 concentrations in the upper troposphere

Patrick Sheese, Kaley Walker, Chris Boone, Laura Saunders, Sandip Dhomse, Wuhu Feng, and Martyn Chipperfield

Since 2004, the Atmospheric Chemistry Experiment – Fourier Transform Spectrometer (ACE-FTS) instrument has been measuring concentrations of chlorofluorocarbons (CFCs) in the stratosphere and upper troposphere and is currently the only satellite instrument that measures vertically resolved profiles of CFC‑11. Since CFCs are major ozone depleting substances, monitoring their atmospheric abundances is critical for understanding ozone layer recovery. Recent studies based solely on surface-level measurements have shown strong evidence for new CFC‑11 production, leading to an increase in CFC‑11 emissions over the past decade. In this study, the TOMCAT/SLIMCAT 3-D chemical transport model is used in order to bridge the altitude/geolocation gap between ACE-FTS measurements in the UTLS and surface level measurements. Trends in two different time periods over the ACE-FTS mission, 2004-2012 and 2013-2018, are examined to determine if the recent change in surface level CFC-11 trends is influencing UTLS concentrations. The ACE-FTS measurements show that, below ~10 km, the rate of decrease of global CFC-11 concentrations was slower during 2013-2018 (-1.2 pptv/year) than during 2004-2012 (‑2.0 pptv/year). Similar trends are observed in the model data for the same spatial/temporal regions.

How to cite: Sheese, P., Walker, K., Boone, C., Saunders, L., Dhomse, S., Feng, W., and Chipperfield, M.: A recent slowdown in the decline of CFC-11 concentrations in the upper troposphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11308, https://doi.org/10.5194/egusphere-egu2020-11308, 2020.

EGU2020-18925 | Displays | AS3.2

Water vapour in the Upper Troposphere and Lower Stratosphere (UTLS): A new vertically resolved dataset from limb and nadir satellite observations

Hao Ye, Michaela Hegglin, Martina Krämer, Christian Rolf, Alexandra Laeng, Dale Hurst, and Holger Vömel

Water vapour in the upper troposphere and lower stratosphere (UTLS) has a significant impact both on the radiative and chemical properties of the atmosphere. Reliable water vapour observations are essential for the evaluation of the accuracy of UTLS water vapour from model simulations, and thereafter of the contribution to the global radiative forcing and climate change. Limb-viewing and nadir satellites provide high quality water vapour observations above the lower stratosphere and below the upper troposphere, respectively, but show large uncertainties in the tropopause region.  Within the ESA Water Vapour Climate Change Initiative, we have developed a new scheme to optimally estimate water vapour profiles in the UTLS and in particular across the tropopause, by merging observations from a set of limb and nadir satellites from 2010 to 2014. The new data record of vertically resolved water vapour is validated against the aircraft in-situ water vapour observations from the JULIA database and frostpoint hydrometer records from WAVAS. Furthermore, the new data record is used to evaluate the UTLS water vapour distribution and interannual variations from chemistry-climate model (CCM) simulations and the ERA-5 reanalysis.

How to cite: Ye, H., Hegglin, M., Krämer, M., Rolf, C., Laeng, A., Hurst, D., and Vömel, H.: Water vapour in the Upper Troposphere and Lower Stratosphere (UTLS): A new vertically resolved dataset from limb and nadir satellite observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18925, https://doi.org/10.5194/egusphere-egu2020-18925, 2020.

AS3.3 – Middle atmosphere composition and feedbacks in a changing climate

Water vapour is the most important natural greenhouse gas in the atmosphere and provides a positive feedback to the climate forcing from carbon dioxide. Water vapour is also the source of hydroxyl (OH) which controls the lifetime of shorter-lived pollutants and long-lived greenhouse gases. Despite the importance of water vapour to chemistry and the radiative balance of the atmosphere, its observed long-term changes in the stratosphere are not well understood, and may even conflict with the theoretical understanding of its drivers. 

I here present a new climate data record of stratospheric water vapour developed within the ESA Water Vapour Climate Change Initiative and discuss recent changes in stratospheric water vapour concentrations in the light of earlier observational studies, modelling results from the SPARC Chemistry-Climate Model Initiative, and our theoretical understanding of its drivers. In addition, the radiative forcing of surface climate and inferred changes in the Brewer-Dobson Circulation will be highlighted. 

How to cite: Hegglin, M. I.: Long-term changes in stratospheric water vapour and its implications for climate, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8874, https://doi.org/10.5194/egusphere-egu2020-8874, 2020.

EGU2020-2420 | Displays | AS3.3

On the magnitude of the stratospheric radiative feedback in global warming

Yi Huang and Yuwei Wang

Global warming is amplified by radiative feedbacks. Compared to the feedback in the troposphere, the feedback in the stratosphere is less understood. The stratospheric water vapor (SWV), one of the primary feedbacks in the stratosphere, is argued to be an important contributor to global warming. This, however, is at odds with the finding that the overall stratospheric feedback does not amount to a significant value in global climate models (GCMs). The key to reconciling these seemingly contradictory arguments is to understand the stratospheric temperature (ST) change since the impact of SWV on the top-of-atmosphere (TOA) radiation budget results more from its cooling of the stratosphere than its direct radiative impact on the TOA radiation. Here, we develop a method to decompose the ST change and to quantify the effects of different climate responses associated with SWV on the TOA radiation budget. We find that although the SWV feedback by itself would lead to strong stratospheric cooling, this cooling is strongly offset by the radiative coupling between the stratosphere and troposphere. Such compensation results in an insignificant overall stratospheric feedback. SWV-locking experiments verify that the SWV feedback does not significantly modify the overall climate sensitivity in the GCM global warming simulations.

How to cite: Huang, Y. and Wang, Y.: On the magnitude of the stratospheric radiative feedback in global warming, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2420, https://doi.org/10.5194/egusphere-egu2020-2420, 2020.

EGU2020-2436 | Displays | AS3.3

Towards fast machine learning parameterizations of stratospheric ozone feedbacks in climate change simulations

Peer Nowack, Nathan Luke Abraham, and Peter Braesicke

There is a plethora of ways in which the representation of upper tropospheric and stratospheric ozone (‘ozone feedbacks’) can affect the outcome of climate change simulations. Prominent examples include modulations of the tropospheric and stratospheric circulation, climate sensitivity, cloud formation, and stratospheric water vapour (e.g. [1-8]). Here I first revisit some recent work providing evidence for such effects. I then provide an update on a recently developed machine learning parameterization for ozone using the UK Earth System Model (UKESM1, [9]). Such a parameterization could adequately represent ozone feedbacks without adding the high computational expense of a fully interactive atmospheric chemistry scheme. The parameterization could also provide several notable scientific advantages, for example concerning the treatment of important chemistry-climate model biases. Finally, I put my results into the context of several other methods suggested as potential means for addressing ozone-related effects in idealized climate sensitivity simulations, also considering the still substantial uncertainties related to modelling ozone [10,11] and associated climate feedbacks [5,12].

References:

[1] Son et al. (2008), The impact of stratospheric ozone recovery on the Southern Hemisphere westerly jet. Science 320, 1486, doi:10.1126/science.1155939.

[2] Dietmüller et al. (2014), Interactive ozone induces a negative feedback in CO2-driven climate change simulations, Journal of Geophysical Research: Atmospheres 119, 1796-1805, doi:10.1002/2013JD020575.

[3] Chiodo & Polvani (2016), Reduction of climate sensitivity to solar forcing due to stratospheric ozone feedback, Journal of Climate 29, 4651-4663, doi:10.1175/JCLI-D-15-0721.1.

[4] Chiodo & Polvani (2017), Reduced Southern Hemispheric circulation response to quadrupled CO2 due to stratospheric ozone feedback, Geophysical Research Letters 43, 465-474, doi:10.1002/2016GL071011.

[5] Nowack et al. (2015), A large ozone-circulation feedback and its implications for global warming assessments. Nature Climate Change 5, 41-45, doi:10.1038/nclimate2451.

[6] Nowack et al. (2017), On the role of ozone feedback in the ENSO amplitude response under global warming, Geophysical Research Letters 44, doi:10.1002/2016GL072418.

[7] Nowack et al. (2018), The impact of stratospheric ozone feedbacks on climate sensitivity estimates. Journal of Geophysical Research: Atmospheres 123, 4630-4641, doi:10.1002/2017JD027943.

[8] Rieder et al. (2019), Is interactive ozone chemistry important to represent polar cap stratospheric temperature variability in Earth-System Models?, Environmental Research Letters 14, 044026, doi: 10.1088/1748-9326/ab07ff.

[9] Nowack et al. (2018), Using machine learning to build temperature-based ozone parameterizations for climate sensitivity simulations, Environmental Research Letters 13, 104016, doi:10.1088/1748-9326/aae2be.

[10] Chiodo & Polvani (2019), The response of the ozone layer to quadrupled CO2 concentrations: implications for climate, Journal of Climate 31, 3893-3907, doi:10.1175/JCLI-D-17-0492.1.

[11] Keeble et al. (2020), Evaluating stratospheric ozone and water vapour changes in CMIP6 models from 1850-2100, Atmospheric Chemistry and Physics Discussions.

[12] Dacie et al. (2019), A 1D RCE study of factors affecting the tropical tropopause layer and surface climate. Journal of Climate 32, 6769-6782, doi:10.1175/JCLI-D-18-0778.1.

How to cite: Nowack, P., Abraham, N. L., and Braesicke, P.: Towards fast machine learning parameterizations of stratospheric ozone feedbacks in climate change simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2436, https://doi.org/10.5194/egusphere-egu2020-2436, 2020.

EGU2020-9282 | Displays | AS3.3

Impacts of stratospheric ozone extremes on Arctic high cloud

Karen Smith, Sarah Maleska, and John Virgin

Stratospheric ozone depletion in the Antarctic is well known to cause changes in Southern Hemisphere tropospheric climate; however, due to its smaller magnitude in the Arctic, the effects of stratospheric ozone depletion on Northern Hemisphere tropospheric climate are not as obvious or well understood. Recent research using both global climate models and observational data has determined that the impact of ozone depletion on ozone extremes can affect interannual variability in tropospheric circulation in the Northern Hemisphere in spring. To further this work, we use a coupled chemistry-climate model to examine the difference in high cloud between years with anomalously low and high Arctic stratospheric ozone concentrations. We find that low ozone extremes during the late twentieth century, when ODS emissions are higher, are related to a decrease in upper tropospheric stability and an increase in high cloud fraction, which may have contributed to Arctic surface warming via a positive longwave cloud radiative effect in the past few decades compared to other regions. A better understanding of how Arctic climate is affected by ODS emissions, ozone depletion and ozone extremes will lead to improved predictions of Arctic climate and its associated feedbacks with atmospheric fields as ozone levels recover.

How to cite: Smith, K., Maleska, S., and Virgin, J.: Impacts of stratospheric ozone extremes on Arctic high cloud, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9282, https://doi.org/10.5194/egusphere-egu2020-9282, 2020.

Southern hemisphere lower stratospheric ozone depletion has been shown to lead to a poleward shift of the tropospheric jet stream during austral summer, influencing surface atmosphere and ocean conditions, such as surface temperatures and sea ice extend. The characteristics of stratospheric and tropospheric responses to ozone depletion, however, differ among climate models largely depending on the representation of ozone in the model.

The most accurate way to represent ozone in a model is to calculate it interactively. However, due to computational costs, in particular for long-term coupled ocean-atmosphere model integrations, the more common way is to prescribe ozone from observations or calculated model fields.

Here, we investigate the difference between an interactive chemistry and a specified chemistry version of the same atmospheric model in a fully-coupled setup using a large 9-member model ensemble. In contrast to most earlier studies, we use daily-resolved ozone fields in the specified chemistry simulations to achieve a better comparability between the ozone forcing with and without interactive chemistry. We find that although the short-wave heating rate trend in response to ozone depletion is the same in the different chemistry settings, the interactive chemistry ensemble shows a stronger trend in polar cap stratospheric temperatures and circumpolar stratospheric and tropospheric zonal mean zonal winds as compared to the specified chemistry ensemble. We attribute part of these differences to the missing representation of feedbacks between chemistry and dynamics in the specified chemistry ensemble and part of it to the lack of zonal asymmetries in the prescribed ozone fields.

This study emphasizes the value of interactive chemistry for the representation of the southern hemisphere tropospheric jet response to ozone depletion.

How to cite: Haase, S., Fricke, J., and Matthes, K.: Sensitivity of the southern hemisphere tropospheric jet response to ozone depletion: specified versus interactive chemistry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2831, https://doi.org/10.5194/egusphere-egu2020-2831, 2020.

EGU2020-283 | Displays | AS3.3

The Response of the QBO to Increases in CO2 Using Three Atmospheric Chemistry Configurations

Kevin DallaSanta, Clara Orbe, and Lorenzo Polvani

Long-term projections of the Quasi-Biennial Oscillation (QBO) remain highly uncertain. This is partly due to the paucity of models which are able to properly simulate that phenomenon. Only 5 of the 47 CMIP5 models are capable of spontaneously generating a realistic QBO (Butchart et al., 2018), and even those models exhibit large biases in key QBO characteristics (e.g. amplitude, period, vertical extent) when compared with observations. Furthermore, only 1 of these 5 employed interactive atmospheric chemistry, which is known to modulate QBO dynamics.

We here investigate the QBO response to increased greenhouse gases using the NASA Goddard Institute for Space Studies Middle Atmosphere Model E2.2. Compared to lower vertical resolution versions of Model E, version 2.2 has a higher model top (0.002 hPa), and additional interactive non-orographic gravity wave drag sources from convection and shear, which produce a sufficiently realistic QBO, thus rendering it suitable for use in climate change studies. Steady-state responses to doubled and quadrupled CO2 from a pre-industrial control are analyzed, as well as the transient response to a 1% per year CO2 increase. In addition, we systematically explore the impact of interactive chemistry in modulating the QBO response to increased CO2 by contrasting interactive, prescribed, and linearized ozone chemistry configurations of the model. Overall, in response to increase CO2 concentrations the QBO is seen to increase in frequency and weaken in amplitude, consistent with previous results, but the memory of the tropical stratosphere may complicate assessments of trends in chemistry and surface impacts. We also discuss implications for the trade-off between ensemble size and the complexity of the chemistry scheme in the model.

How to cite: DallaSanta, K., Orbe, C., and Polvani, L.: The Response of the QBO to Increases in CO2 Using Three Atmospheric Chemistry Configurations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-283, https://doi.org/10.5194/egusphere-egu2020-283, 2020.

EGU2020-9852 | Displays | AS3.3

Investigation of strongly enhanced methane Part II: Slow climate feedbacks.

Laura Stecher, Franziska Winterstein, Martin Dameris, Patrick Jöckel, and Michael Ponater

Methane (CH4) is the second most important anthropogenic greenhouse gas and its atmospheric abundance is rising rapidly at the moment (e.g. Nisbet et al., 2019). 

We assess the effects of doubled and fivefold present-day (2010) CH4 lower boundary mixing ratios on the basis of sensitivity simulations with the
chemistry-climate model EMAC. As a follow-up on Winterstein et al. (2019) we investigate slow adjustments by applying a mixed layer ocean (MLO) model
instead of prescribed oceanic conditions. In the simulations with prescribed oceanic conditions, tropospheric temperature changes are largely suppressed,
while with MLO tropospheric temperatures adjust to the forcing. In the present study we compare the changes in the MLO sensitivity simulations to the
sensitivity simulations with prescribed oceanic conditions (Winterstein et al., 2019). Comparing the responses of these two sets of sensitivity simulations separates rapid adjustments and the effects of slow climate feedbacks associated with tropospheric warming.

The chemical interactions in the stratosphere in the MLO set-up (slow adjustments) compare in general well with the results of Winterstein et al. (2019) (rapid adjustments). The increase of stratospheric water vapor is albeit 5 % (15 %) points weaker in the MLO doubling (fivefolding) experiment compared to the doubling (fivefolding) experiment with prescribed oceanic conditions in line with a weaker increase of stratospheric OH. Stronger O3 decrease and CH4
increase in the lowermost tropical stratosphere in the MLO sensitivity simulations compared to the sensitivity simulations with prescribed oceanic conditions indicate a more distinct strengthening of tropical up-welling due to tropospheric warming in the MLO set-up. The MLO simulations also show evidence of a strengthening of the Brewer-Dobson Circulation. When separating the quasi-instantaneous chemically induced O3 response from the O3 response pattern in the MLO set-up, the O3 response to slow climate feedbacks remains. This pattern is consistent with the O3 response to slow climate feedbacks induced by increases of CO2.

This first of its kind study shows the climatic impact of strongly enhanced CH4 mixing ratios and how the slow climate response of tropospheric warming potentially damp instantaneous chemical feedbacks.

How to cite: Stecher, L., Winterstein, F., Dameris, M., Jöckel, P., and Ponater, M.: Investigation of strongly enhanced methane Part II: Slow climate feedbacks., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9852, https://doi.org/10.5194/egusphere-egu2020-9852, 2020.

EGU2020-22211 | Displays | AS3.3

Emergence of Southern Hemisphere circulation changes in response to ozone recovery

Brian Zambri, Susan Solomon, David Thompson, and Qiang Fu

Ozone depletion in the Southern Hemisphere (SH) stratosphere in the late 20th century cooled the air there, strengthening the SH stratospheric westerly winds near 60ºS and altering SH surface climate. Since ~1999, trends in Antarctic ozone have begun to recover, exhibiting a flattening followed by a sign reversal in response to decreases in stratospheric chlorine concentration due to the Montreal Protocol, an international treaty banning the production and consumption of ozone-depleting substances. Here we show that the post–1999 increase in ozone has resulted in thermal and circulation changes of opposite sign to those that resulted from stratospheric ozone losses, including a warming of the SH polar lower stratosphere and a weakening of the SH stratospheric polar vortex.  Further, these altered trends extend to the upper troposphere, albeit of smaller magnitudes.  Observed post–1999 trends of temperature and circulation in the stratosphere are about 20–25% the magnitude of those of the ozone depletion era, and are broadly consistent with expectations based on modeled depletion-era trends and variability of both ozone and reactive chlorine, thereby indicating the emergence of healing of dynamical impacts of the Antarctic ozone hole.

How to cite: Zambri, B., Solomon, S., Thompson, D., and Fu, Q.: Emergence of Southern Hemisphere circulation changes in response to ozone recovery, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22211, https://doi.org/10.5194/egusphere-egu2020-22211, 2020.

 The impacts of stratospheric ozone and greenhouse gas changes on the Southern Hemisphere (SH) climate are re-visited by examining the single forcing experiments from the Chemistry-Climate Model Initiative (CCMI) project. In particular, the fixed ozone-depleting substance (ODS) runs and the fixed greenhouse gas (GHG) concentration runs are directly compared with the reference runs for both the past and future. Consistent with the previous studies, the SH-summer general circulation changes, such as changes in the jet location, Hadley cell edge, and Southern Annular Mode (SAM), show the opposite trends from the past to the future in response to the Antarctic ozone depletion and recovery. The GHG-induced circulation changes largely enhance the ozone-induced circulation changes in the past, but partly cancel them in the future. The ozone recovery-related tropospheric circulation return dates are also estimated in this study. We will further discuss the inter-model diversity among the CCMI models.

How to cite: Han, B.-R., Choi, J., and Son, S.-W.: Impacts of stratospheric ozone and greenhouse gas changes on the Southern Hemisphere circulation in the CCMI models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6570, https://doi.org/10.5194/egusphere-egu2020-6570, 2020.

EGU2020-13468 | Displays | AS3.3

Influence of the stratospheric shrinkage on the detected CCMI simulation trends

Petr Pisoft and Petr Šácha

There is a well-established observational evidence that the tropopause is shifting upward. More generally, warming of the troposphere is directly connected with a positive trend of geopotential of pressure levels in the troposphere, which reaches its maximum around the tropopause. In the stratosphere, the geopotential height trends are affected by the stratospheric cooling resulting in a gradual reduction of the upward shift and even its reversal in the upper stratosphere. That leads to a decreasing trend of the stratospheric thickness - a so-called stratospheric shrinkage. In GCMs, shrinkage is one of the strongest and most robust fingerprints of the changing climate. In this study, we investigate the question whether the shrinkage presents additional dynamical feedback influencing other detected trends in the middle atmosphere (besides the influence of vertical shift). Analyzing set of CCMI models, we compute inter-model correlations of shrinkage with trends of various variables to separate the possible shrinkage effect, which is otherwise a non-local function of the temperature.

How to cite: Pisoft, P. and Šácha, P.: Influence of the stratospheric shrinkage on the detected CCMI simulation trends , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13468, https://doi.org/10.5194/egusphere-egu2020-13468, 2020.

EGU2020-20440 | Displays | AS3.3

Numerical modeling of the natural and anthropogenic factors influence on the past and future changes in polar, mid-latitude and tropical ozone

Sergei Smyshlyaev, Polina Blakitnaya, Maxim Motsakov, and Vener Galin

The INM RAS – RSHU chemistry-climate model of the lower and middle atmosphere is used to compare the role of natural and anthropogenic factors in the observed and expected variability of stratospheric ozone. Numerical experiments have been carried out on several scenarios of separate and combined effects of solar activity, stratospheric aerosol, sea surface temperature, greenhouse gases, and ozone-depleting substances emissions on ozone for the period from 1979 to 2050. Simulations for the past and present periods are compared to the results of ground-based and satellite observations, as well as MERRA and ERA-Interim re-analysis. Estimation of future ozone changes are based on different scenarios of changes in solar activity and emissions of ozone-depleting substances and greenhouse gases, as well as the possibility of large volcanic aerosol emissions at different periods of time.

How to cite: Smyshlyaev, S., Blakitnaya, P., Motsakov, M., and Galin, V.: Numerical modeling of the natural and anthropogenic factors influence on the past and future changes in polar, mid-latitude and tropical ozone, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20440, https://doi.org/10.5194/egusphere-egu2020-20440, 2020.

EGU2020-9786 | Displays | AS3.3

Investigation of strongly enhanced methane Part I: Chemical feedbacks and rapid adjustments.

Franziska Winterstein, Patrick Jöckel, Martin Dameris, Michael Ponater, Fabian Tanalski, and Laura Stecher

Methane (CH4) is the second most important greenhouse gas, which atmospheric concentration is influenced by human activities and currently on a sharp rise. We present a study with numerical simulations using a Chemistry-Climate-Model (CCM), which are performed to assess possible consequences of strongly enhanced CH4 concentrations in the Earth's atmosphere for the climate.

Our analysis includes experiments with 2xCH4 and 5xCH4 present day (2010) lower boundary mixing ratios using the CCM EMAC. The simulations are conducted with prescribed oceanic conditions, mimicking present day tropospheric temperatures as its changes are largely suppressed. By doing so we are able to investigate the quasi-instantaneous chemical impact on the atmosphere. We find that the massive increase in CH4 strongly influences the tropospheric chemistry by reducing the OH abundance and thereby extending the tropospheric CH4 lifetime as well as the residence time of other chemical pollutants. The region above the tropopause is impacted by a substantial rise in stratospheric water vapor (SWV). The stratospheric ozone (O3) column increases overall, but SWV induced stratospheric cooling also leads to enhanced ozone depletion in the Antarctic lower stratosphere. Regional  patterns of ozone change are affected by modification of stratospheric dynamics, i.e. increased tropical up-welling and stronger meridional transport  towards the polar regions. We calculate the net radiative impact (RI) of the 2xCH4 experiment to be 0.69 W m-2 and for the 5xCH4 experiment to be 1.79 W m-2. A substantial part of the RI is contributed by chemically induced O3 and SWV changes, in line with previous radiative forcing estimates and is for the first time splitted and spatially asigned to its chemical contributors.

This numerical study using a CCM with prescibed oceanic conditions shows the rapid responses to significantly enhanced CH4 mixing ratios, which is the first step towards investigating the impact of possible strong future CH4 emissions on atmospheric chemistry and its feedback on climate.

How to cite: Winterstein, F., Jöckel, P., Dameris, M., Ponater, M., Tanalski, F., and Stecher, L.: Investigation of strongly enhanced methane Part I: Chemical feedbacks and rapid adjustments., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9786, https://doi.org/10.5194/egusphere-egu2020-9786, 2020.

EGU2020-10611 | Displays | AS3.3

Improved characterisation of the impact of chlorinated VSLSs on atmospheric chemistry and climate: past, present and future

Ewa Bednarz, Ryan Hossaini, Luke Abraham, and Martyn Chipperfield

The emissions of most long-lived halogenated ozone-depleting substances (ODSs) are now decreasing, owing to controls on their production introduced by Montreal Protocol and its amendments. However, short-lived halogenated compounds can also have substantial impact on atmospheric chemistry, including stratospheric ozone, particularly if emitted near climatological uplift regions. It has recently become evident that emissions of some chlorinated very short-lived species (VSLSs), such as chloroform (CHCl3) and dichloromethane (CH2Cl2), could be larger than previously believed and increasing, particularly in Asia. While these may exert a significant influence on atmospheric chemistry and climate, their impacts remain poorly characterised.

 

We address this issue using the UM-UKCA chemistry-climate model. We use a newly developed Double-Extended Stratospheric-Tropospheric (DEST) chemistry scheme, which includes emissions of all major chlorinated and brominated VSLSs alongside an extended treatment of long-lived ODSs. Employing novel estimates of Cl-VSLS emissions we show model results regarding the atmospheric impacts of chlorinated VSLSs over the recent past (2000-present), with a focus on stratospheric ozone and HCl trends. Finally, we introduce our plans regarding examining the impacts of chlorinated VSLSs under a range of potential future emissions scenarios; the results of which will be directly relevant for the next WMO/UNEP assessment.

How to cite: Bednarz, E., Hossaini, R., Abraham, L., and Chipperfield, M.: Improved characterisation of the impact of chlorinated VSLSs on atmospheric chemistry and climate: past, present and future, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10611, https://doi.org/10.5194/egusphere-egu2020-10611, 2020.

EGU2020-3375 | Displays | AS3.3

Reconciling modelled and observed age of air through SF6 sinks

Sheena Loeffel, Roland Eichinger, Hella Garny, Thomas Reddmann, Stefan Versick, Frauke Fritsch, Gabriele Stiller, and Florian Haenel

Mean age of air (AoA) is a common diagnostic for the stratospheric overturning circulation in both climate models and observations. Observations of AoA mostly base on measurements of SF6, which is an almost ideal AoA tracer because its emssions across the recent decades increased nearly linearly and it is fairly stable in the troposphere and stratosphere. Over the last ten years, however, researchers were puzzled as to why AoA climatologies and trends of model simulations and observational data do not coincide. AoA in climate models is generally much lower than in observations and models show a clear decrease of AoA over time while measurements show a non-significant increase.

What is commonly not considered in the models is that SF6 has chemical sinks in the mesosphere, and these lead to apparently older air in the stratosphere. In our experiment, we explicitely calculate SF6 sinks based on physical processes in simulations with the global chemistry-climate model EMAC (ECHAM MESSy Atmospheric Chemistry). We show that considering the SF6 removal reactions strongly increases stratospheric AoA and leads to much better agreement between the climatologies of EMAC and MIPAS (Michelson Interferometer for Passive Atmospheric Sounding) satellite observations. Moreover, the stratospheric AoA trend over the recent decades reverses sign when we derive it from SF6 with sinks. This means that the trend can such be reconciled with the trend that has been derived from long-term balloon-borne measurements. Our specifically designed sensitivity studies moreover reveal that this positive trend results neither from circulation changes, nor from variations of the reactive species involved in mesospheric SF6 depletion. Instead, it is generated through the temporally growing influence of the SF6 sinks themselves, an effect that overcompensates the negative trend resulting from the accelerating stratospheric overturning circulation.

How to cite: Loeffel, S., Eichinger, R., Garny, H., Reddmann, T., Versick, S., Fritsch, F., Stiller, G., and Haenel, F.: Reconciling modelled and observed age of air through SF6 sinks, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3375, https://doi.org/10.5194/egusphere-egu2020-3375, 2020.

EGU2020-17593 | Displays | AS3.3

Why we believe there is still a model ozone deficit in the upper stratosphere

Jonas Debosscher, Quentin Errera, Simon Chabrillat, Daniele Minganti, Yves Christophe, and Didier Fussen

Historically, many photochemical models suffered from an underestimation of the ozone abundance in the upper stratosphere – lower mesosphere, known as the “Ozone deficit problem” (Prather, 1981; Eluszkiewicz et al., 1993, Siskind at al., 2013). Despite improvements in models and increased accuracy of observations, it seems this problem is still present, as evidenced by comparing models participating in the Chemistry-Climate Model Initiative (CCMI) with observations.

The Belgian Assimilation System for Chemical ObsErvations (BASCOE), developed at BIRA-IASB, is used to study and monitor the chemical composition of the stratosphere. It consists of a 3D chemical transport model (CTM) in combination with two data-assimilation methods (4D-Var and EnKF). BASCOE shows an ozone deficit of ~20 % against MLS observations around 1hPa. Since BASCOE will provide operational analysis of ozone based on the assimilation of the future ALTIUS satellite data, and is part of the Integrated Forecasting System of the ECMWF (C-IFS-CB05-BASCOE, Huijnen et al., 2016), the CTM needs to better model the ozone observations in this region of the stratosphere.

We present the results of a sensitivity study using the BASCOE CTM to identify factors that have the largest influence on the ozone budget in the upper stratosphere and can provide clues to solve the ozone deficit. We investigated the effects of solar spectral irradiance, surface albedo, photo-dissociation computation, reaction rate uncertainties and temperature.

Ozone concentrations in the upper stratosphere turned out to be very sensitive to temperatures and to a lesser degree to the solar spectral irradiances used to drive the model. The sensitivity to temperature is compatible with predictions made using a photochemical equilibrium approximation based on pure oxygen chemistry. Given the relatively large temperature uncertainties in the upper stratosphere, we believe temperature biases could substantially contribute to the ozone deficit.

How to cite: Debosscher, J., Errera, Q., Chabrillat, S., Minganti, D., Christophe, Y., and Fussen, D.: Why we believe there is still a model ozone deficit in the upper stratosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17593, https://doi.org/10.5194/egusphere-egu2020-17593, 2020.

EGU2020-21692 | Displays | AS3.3

UV-Indien Network- a network dedicated to the long-term monitoring of UV radiation in the Indian Ocean.

Thierry Portafaix, Kevin Lamy, Jean-Baptiste Forestier, Solofo Rakotoniaina, and Vincent Amélie

Radiation (UV) is one of the main components of solar radiation transmitted by the Earth's atmosphere. Exposure to UV radiation can have both positive and negative effects on the biosphere and humans in particular. Overexposure significantly increases the risk of skin cancer and eye problems.

Ozone, cloud cover and zenithal solar angle are the main parameters affecting UV radiation levels at the surface. Stratospheric ozone in particular strongly absorbs UV radiation. A dense cloud cover absorbs UV radiation, while a split cloud cover may tend to amplify it.

Although the stratospheric ozone layer is showing signs of recovery from reduced ozone-depleting substances. The impact of greenhouse gases on the climate is still in increase and global climate models anticipate an acceleration in Brewer-Dobson Circulation, which would lead to lower ozone levels in the tropics. Butler et al. (2016) estimate a decrease in stratospheric ozone in the tropics of 5 to 10 DU for all climate scenarios. Some recent projections (Lamy et al., 2019) predict a 2-3% increase in UVR in the southern tropical band, a region where UV levels are already extreme.

The purpose of the UV-Indien network is to :

- Monitor UV levels at different sites in the Western Indian Ocean (WIO)

- Describe the annual and inter-annual variability of UV radiation in the WIO

- Perform regional climate projections of UV radiations, validated by quality ground measurements.

UV-Indien is split into three phases. The first phase began in 2016, with the deployment of the first measurement sites (Reunion Island, Madagascar, Seychelles, Rodrigues). These sites are equipped with a broadband radiometer measuring the UVI and a camera estimating the coverage and sometimes a spectrometer for the measurement of total ozone. The second phase from 2019, sees the extension of this network to 4 other sites (Juan de Nova, Diego Suarez, Fort Dauphin and Grande Comoros). The data validation phase began in 2019 (comparative study with satellite data) and will also propose the study of the variability of UV radiation on different sites. Finally, climate projections will be made from 2020 onwards and will use data from the network to validate the results.

The aim of this communication is to describe the entire network and its objectives. The first results, as well as the first climatologies will also be discussed.

How to cite: Portafaix, T., Lamy, K., Forestier, J.-B., Rakotoniaina, S., and Amélie, V.: UV-Indien Network- a network dedicated to the long-term monitoring of UV radiation in the Indian Ocean., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21692, https://doi.org/10.5194/egusphere-egu2020-21692, 2020.

EGU2020-21369 | Displays | AS3.3

Effects of the 11-year Solar Cycle including Medium-Energy Electron Precipitation in WACCM decadal climate predictions

Sigmund Guttu, Yvan Orsolini, Frode Stordal, Odd Helge Otterå, Thomas Toniazzo, and Pekka Verronen

There is an ongoing discussion whether the lagged surface impact of the 11-year solar cycle, which peaks 2-4 years after solar maximum, may be contributed by the North Atlantic Oscillation (NAO) coupling to the ocean. Several studies have suggested that this atmosphere-ocean feedback is involving annual re-emergence of anomalous ocean temperatures stored below the mixed layer. Energetic Electron precipitation effects also lag the solar maximum by a few years, peaking in the declining phase of the solar cycle. While recent studies have incorporated the stratospheric UV radiation component of the solar forcing, the importance of the effect from precipitating medium-to-high energy electrons (MEE), which are able to significantly disturb the stratospheric chemical composition, is not fully addressed, partly due to lack of realistic forcing in current Earth System Models. In this study, we use the high-top atmospheric model WACCM coupled to the MICOM ocean model and adopt a state-of-the-art MEE forcing data set. Results will be presented from two decadal ensemble experiments with solar cycle induced forcings, one with UV and one with UV and MEE. The anomalous forcing from MEE precipitation is studied in relation to patterns of Northern Hemispheric atmospheric variability modes.

How to cite: Guttu, S., Orsolini, Y., Stordal, F., Otterå, O. H., Toniazzo, T., and Verronen, P.: Effects of the 11-year Solar Cycle including Medium-Energy Electron Precipitation in WACCM decadal climate predictions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21369, https://doi.org/10.5194/egusphere-egu2020-21369, 2020.

EGU2020-5120 | Displays | AS3.3

Will climate change impact polar NOx produced by energetic particle precipitation?

Ville Maliniemi, Daniel R. Marsh, Hilde Nesse Tyssøy, and Christine Smith-Johnsen

Energetic electron precipitation (EEP) is an important source of polar nitrogen oxides (NOx) in the upper atmosphere. During winter, mesospheric NOx has a long chemical lifetime and is transported to the stratosphere by the mean meridional circulation. Climate change is expected to accelerate this circulation and therefore increase polar mesospheric descent rates. We investigate the southern hemispheric polar NOx distribution during the 21st century under a variety of future scenarios using simulations of the Whole Atmosphere Community Climate Model (WACCM). Each future scenario has the same moderate variable solar activity scenario, where EEP activity is lower than during the 20th century. We simulate stronger polar mesospheric descent in all future scenarios that increase the atmospheric radiative forcing. By the end of 21st century polar NOx in the upper stratosphere is significantly enhanced in two future scenarios with the largest increase in radiative forcing. This indicates that the ozone depleting NOx cycle will become more important in the future, especially if stratospheric chlorine species decline. Thus, EEP-related atmospheric effects may become more prominent in the future.

How to cite: Maliniemi, V., Marsh, D. R., Nesse Tyssøy, H., and Smith-Johnsen, C.: Will climate change impact polar NOx produced by energetic particle precipitation?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5120, https://doi.org/10.5194/egusphere-egu2020-5120, 2020.

AS3.4 – Atmospheric Chemistry and Transport: Observing and Modeling the not-so-well-mixed Troposphere and the well-stratified Lower Stratosphere

     The last seventy years have witnessed a marked acceleration of the impact of human activity impacting the planet due to the combination of rapid population growth, increased consumption of resources, and technological development. Nearly the entire human population occupies an astonishingly small percentage of the Earth’s surface, yet the imprint of human activity is being recorded in global climate and is perturbing the chemistry and composition of the most remote stretches of the atmosphere. These remote regions are exceptionally important for global air quality and climate (accounting on average for 75% of global CH4 removal, 59% of chemical production of O3, and 68% of chemical destruction of O3), yet the paucity of observations over the remote oceans have limited our understanding of these fundamental processes and their sensitivity to increased human perturbation.

     The NASA Atmospheric Tomography Mission (ATom) was designed to address these gaps in our understanding of chemical composition, reactivity, and transport through a combination of extensive measurements and photochemical modeling, and to provide much needed observational data from the remote regions of the atmosphere to provide rigorous tests that will lead to improvements in our global chemistry-climate models and to validate remote sensing retrievals. From 2016-2018, ATom utilized the fully instrumented NASA DC-8 research aircraft to collect an unprecedented suite of measurements of trace gases, aerosols, and key radical species from the remote troposphere and lower stratosphere.  Four complete pole-to-pole global circuits (one in each season) were conducted by performing near-continuous vertical profiles between 0.2 – 14 km altitude along meridional transects of the Pacific and Atlantic Ocean Basins. The data provided by this project have already led to several significant new findings, with many more on the horizon as research teams continue to uncover the full value of this dataset. In this talk, we will provide an overview of the ATom mission and discuss some of the major outcomes and new findings that have resulted from this project to date.

How to cite: Thompson, C. and the The ATom Science Team: The NASA Atmospheric Tomography Mission: A Global-Scale Survey of Composition, Reactivity, and Transport in the Remote Atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12202, https://doi.org/10.5194/egusphere-egu2020-12202, 2020.

EGU2020-12042 | Displays | AS3.4

Mapping the Oxidizing Capacity of the Global Remote Troposphere

Julie Nicely, Glenn Wolfe, Jason St. Clair, Thomas Hanisco, Jin Liao, Luke Oman, and Gonzalo González Abad and the ATom Science Team

Observations from the NASA Atmospheric Tomography Mission (ATom) have elucidated a strong relationship between the production of hydroxyl radical (OH), the primary oxidant of the troposphere, and formaldehyde (HCHO), a major product of the oxidation of methane and other hydrocarbons.  We present a proxy for global over-ocean OH based on this principle, using remote observations of HCHO from the Ozone Monitoring Instrument (OMI).  Analysis of summer and wintertime remote OH from this proxy suggest a near-constant mean concentration of 1.03 ± 0.25 × 106 cm−3 and a Northern Hemisphere to Southern Hemisphere over-ocean OH ratio of 0.89 ± 0.06 averaged over both seasons (1s uncertainties).  We also share ongoing efforts to expand on this approach by refining the scaling factors that relate OH production to HCHO as a function of CO, NOx, and VOCs, with the goal of extending the proxy over land as well as across the OMI record.

How to cite: Nicely, J., Wolfe, G., St. Clair, J., Hanisco, T., Liao, J., Oman, L., and González Abad, G. and the ATom Science Team: Mapping the Oxidizing Capacity of the Global Remote Troposphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12042, https://doi.org/10.5194/egusphere-egu2020-12042, 2020.

Reactive halogens have wide-ranging consequences on tropospheric chemistry including ozone destruction, HOx and NOx partitioning, oxidization of volatile organic compounds (VOCs) and initiation of new particle formation. Of particular note and importance, the tropospheric Ox loss due to halogens is estimated to be between 10-20% globally, and up to 50% in some local marine environments. In this work, we include a state-of-the-art coupled halogen and VOCs chemical mechanism into the CAM-Chem global model. Complementing the model development and providing the opportunity to test the model are recent results from the NASA Atmospheric Tomography (ATom) experiment.  ATom was conducted with a heavily instrumented NASA DC-8 aircraft over the course of two and a half years, transecting the lengths of the Pacific and Atlantic Oceans during four seasons, constantly profiling from the surface (200 m) to the upper troposphere/lower stratosphere (12000 m). The ATom payload included instruments that measured both inorganic halogens and organic halogen-containing very short-lived substances (VSLS), as well as those that measured additional volatile organic compounds (VOCs), including hydrocarbons and oxygenated VOCs (OVOCs), both of which react with halogens. Modeled BrO is sensitive to the inclusion of reactions between Br and OVOCs, particularly the aldehydes, which rapidly convert Br to HBr, a far less reactive form of Bry. These reactions can have large implications in the remote troposphere where the ATom measurements have revealed significant emissions and chemical production of low molecular weight aldehydes over the remote marine environment. A version of CAM-chem, updated to include aldehyde emissions from the ocean to close the gap between models and measurements, is used in these analyses. Comparisons between measured and modeled halogen containing species, both organic and inorganic, is presented along with a summary of the implications of our findings on the overall budgets of tropospheric halogens and ozone.

How to cite: Apel, E. C.: Interactions and implications of halogens and VOCs on tropospheric oxidant cycles in the remote atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5877, https://doi.org/10.5194/egusphere-egu2020-5877, 2020.

EGU2020-8233 | Displays | AS3.4

Measurement of NOx and Ozone over the North Atlantic Ocean.

James Lee, Freya Squires, Simone Andersen, Jim Hopkins, Dominika Pasternak, and Alex Archibald

Tropospheric ozone (O3) can adversely affect human health and environmental ecosystems and it is therefore vitally important to understand its formation pathways from both natural and anthropogenic precursors. Background O3 levels in the Northern Hemisphere have increased by more than a factor of two over the last century and it is believed that this increase is strongly tied to the increase in and distribution of anthropogenic nitrogen oxide (N0x) emissions. This is important as the changing level of O3 in the background troposphere impacts the ability of countries downwind to achieve their air quality standards.

As part of the NERC funded North Atlantic Climate System Integrated Study (ACSiS) and Methane Observations and Yearly Assessments (MOYA) projects, multiple research flights have taken place over the North Atlantic Ocean, spanning an area from 55oN to 12oN and 8oW to 25oW using the UK’s large research aircraft (The Facility for Airborne Atmospheric Measurements – FAAM). Flights took place in all seasons from 2017 – 2020. A variety of gas and aerosol measurements were made, including NOx, O3, CO and a range of VOCs and an overview of the data is presented here. Measurements were taken in a range of air masses, including biomass burning outflow from West Africa, urban outflow from Europe and emissions from the busy shipping lanes to the West of Portugal.

Data was analysed to assess O3 formation from the different emission sources, in particular examining the difference between anthropogenic and natural emissions. In addition, the output of regional chemistry models is compared to the data in order to assess the performance of the models in predicting O3 and its precursors.

How to cite: Lee, J., Squires, F., Andersen, S., Hopkins, J., Pasternak, D., and Archibald, A.: Measurement of NOx and Ozone over the North Atlantic Ocean., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8233, https://doi.org/10.5194/egusphere-egu2020-8233, 2020.

EGU2020-5628 | Displays | AS3.4

Analysis of the impact of biomass burning emissions on global ozone production in the upper troposphere with MOCAGE CTM and IAGOS airborne data.

Martin Cussac, Virginie Marécal, Valérie Thouret, and Béatrice Josse

The UTLS (Upper Troposphere/Lower Stratosphere) is a key layer of the atmosphere as its chemical composition impacts both the troposphere and the stratosphere, and therefore plays a significant role in the climate system. Ozone at this altitude for instance plays a great role on surface temperature. Unlike in the stratosphere; it can be produced from the photolysis of precursors originating in the troposphere; mainly nitrous oxides (NOx) and carbon monoxide (CO) at this pressure range. Biomass burning emissions in particular are likely to play a significant role in the quantities of these species in the upper troposphere and thus impacting ozone balance. This effect is investigated thanks to the global chemistry transport model MOCAGE. Because of the strong vertical gradients in this layer of the atmosphere, well resolved in-situ observation dataset are valuable for model evaluation. As of measurements used to validate MOCAGE results, IAGOS in-situ measurements from equipped commercial aircraft were chosen for their fine vertical resolution as well as their wide geographical coverage. Using both of these tools, upper tropospheric air composition is studied, with a focus on ozone precursors and production linked to biomass burning emissions.

Firstly is investigated the direct impact of biomass burning emissions on CO concentration in the upper troposphere, as it is both a good tracer of wildfire plumes in the atmosphere and it plays a role in the upper troposphere chemical balance. For this purpose MOCAGE simulations spaning over the year of 2013 where biomass burning emissions were turned on and off are compared to estimate a contribution to upper tropospheric CO. These simulations were validated using all the available data from the IAGOS database. It was found that biomass burning impacted CO levels globally, with the strongest enhancement happening above the most emitting areas (equatorial Africa and the Boreal forests). The importance of a fast vertical transport pathway above the fires was also highlighted with the possible occurrence of pyroconvection in addition to deep convection. Secondly, other chemical species related to ozone production were looked upon. Peroxyacetyl Nitrates (PAN) for instance were found to be impacted by biomass burning as it is a product of NOx oxidation as well as the main "reservoir" specie for NOx in the upper troposphere. Ultimately, ozone production resulting from biomass burning emissions is investigated, both in biomass burning plumes encountered by IAGOS aircraft, and on a more global scale using the MOCAGE simulations.

How to cite: Cussac, M., Marécal, V., Thouret, V., and Josse, B.: Analysis of the impact of biomass burning emissions on global ozone production in the upper troposphere with MOCAGE CTM and IAGOS airborne data., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5628, https://doi.org/10.5194/egusphere-egu2020-5628, 2020.

EGU2020-1919 | Displays | AS3.4

From ERA-Interim to ERA5: considerable impact of ECMWF's next-generation reanalysis on Lagrangian transport simulations

Lars Hoffmann, Gebhard Günther, Dan Li, Olaf Stein, Xue Wu, Sabine Griessbach, Yi Heng, Paul Konopka, Rolf Müller, Bärbel Vogel, and Jonathon S. Wright

The European Centre for Medium-Range Weather Forecasts’ (ECMWF’s) next-generation reanalysis ERA5 provides many improvements, but it also confronts the community with a "big data" challenge. Data storage requirements for ERA5 increase by a factor of ∼80 compared with the ERA-Interim reanalysis, introduced a decade ago. Considering the significant increase in resources required for working with the new ERA5 data set, it is important to assess its impact on Lagrangian transport simulations. To quantify the differences between transport simulations using ERA5 and ERA-Interim data, we analyzed comprehensive global sets of 10-day forward trajectories for the free troposphere and the stratosphere for the year 2017. The new ERA5 data have a considerable impact on the simulations. Spatial transport deviations between ERA5 and ERA-Interim trajectories are up to an order of magnitude larger than those caused by parameterized diffusion and subgrid-scale wind fluctuations after 1 day and still up to a factor of 2–3 larger after 10 days. Depending on the height range, the spatial differences between the trajectories map into deviations as large as 3 K in temperature, 30 % in specific humidity, 1.8 % in potential temperature, and 50 % in potential vorticity after 1 day. Part of the differences between ERA5 and ERA-Interim is attributed to the better spatial and temporal resolution of the ERA5 reanalysis, which allows for a better representation of convective updrafts, gravity waves, tropical cyclones, and other meso- to synoptic-scale features of the atmosphere. Another important finding is that ERA5 trajectories exhibit significantly improved conservation of potential temperature in the stratosphere, pointing to an improved consistency of ECMWF’s forecast model and observations that leads to smaller data assimilation increments. We conducted a number of downsampling experiments with the ERA5 data, in which we reduced the numbers of meteorological time steps, vertical levels, and horizontal grid points. Significant differences remain present in the transport simulations, if we downsample the ERA5 data to a resolution similar to ERA-Interim. This points to substantial changes of the forecast model, observations, and assimilation system of ERA5 in addition to improved resolution. A comparison of two Lagrangian trajectory models allowed us to assess the readiness of the codes and workflows to handle the comprehensive ERA5 data and to demonstrate the consistency of the simulation results. Our results will help to guide future Lagrangian transport studies attempting to navigate the increased computational complexity and leverage the considerable benefits and improvements of ECMWF’s new ERA5 data set.

Reference: Hoffmann, L., Günther, G., Li, D., Stein, O., Wu, X., Griessbach, S., Heng, Y., Konopka, P., Müller, R., Vogel, B., and Wright, J. S.: From ERA-Interim to ERA5: the considerable impact of ECMWF's next-generation reanalysis on Lagrangian transport simulations, Atmos. Chem. Phys., 19, 3097–3124, https://doi.org/10.5194/acp-19-3097-2019, 2019.

 

How to cite: Hoffmann, L., Günther, G., Li, D., Stein, O., Wu, X., Griessbach, S., Heng, Y., Konopka, P., Müller, R., Vogel, B., and Wright, J. S.: From ERA-Interim to ERA5: considerable impact of ECMWF's next-generation reanalysis on Lagrangian transport simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1919, https://doi.org/10.5194/egusphere-egu2020-1919, 2020.

EGU2020-5159 | Displays | AS3.4

The influence of transport model resolution on the inverse modelling of synthetic greenhouse gas emissions in Switzerland

Ioannis Katharopoulos, Dominique Rust, Martin Vollmer, Dominik Brunner, Stefan Reimann, Lukas Emmenegger, and Stephan Henne

Climate change is one of the biggest challenges of the modern era. Halocarbons contribute already about 14% to current anthropogenic radiative forcing, and their future impact may become significantly larger due to their long atmospheric lifetimes and continued and increasing usage. In addition to their influence on climate change, chlorine and bromine-containing halocarbons are the main drivers of the destruction of the stratospheric ozone layer. Therefore, observing their atmospheric abundance and quantifying their sources is critical for predicting the related future impact on climate change and on the recovery of the stratospheric ozone layer.

Regional scale atmospheric inverse modelling can provide observation-based estimates of greenhouse gas emissions at a country scale and, hence, makes valuable information available to policy makers when reviewing emission mitigation strategies and confirming the countries' pledges for emission reduction. Considering that inverse modelling relies on accurate atmospheric transport modelling any advances to the latter are of key importance. The main objective of this work is to characterize and improve the Lagrangian particle dispersion model (LPDM) FLEXPART-COSMO at kilometer-scale resolution and to provide estimates of Swiss halocarbon emissions by integrating newly available halocarbon observations from the Swiss Plateau at the Beromünster tall tower. The transport model is offline coupled with the regional numerical weather prediction model (NWP) COSMO. Previous inverse modelling results for Swiss greenhouse gases are based on a model resolution of 7 km x 7 km. Here, we utilize higher resolution (1 km x 1 km) operational COSMO analysis fields to drive FLEXPART and compare these to the previous results.

The higher resolution simulations exhibit increased three-dimensional dispersion, leading to a general underestimation of observed tracer concentration at the receptor location and when compared to the coarse model results. The concentration discrepancies due to dispersion between the two model versions cannot be explained by the parameters utilized in FLEPXART’s turbulence parameterization, (Obhukov length, surface momentum and heat fluxes, atmospheric boundary layer heights, and horizontal and vertical wind speeds), since a direct comparison of these parameters between the different model versions showed no significant differences. The latter suggests that the dispersion differences may originate from a duplication of turbulent transport, on the one hand, covered by the high resolution grid of the Eulerian model and, on the other hand, diagnosed by FLEXPART's turbulence scheme. In an attempt to reconcile FLEXPART-COSMO’s turbulence scheme at high resolution, we introduced additional scaling parameters based on analysis of simulated mole fraction deviations depending on stability regime. In addition, we used FLEXPART-COSMO source sensitivities in a Bayesian inversion to obtain optimized emission estimates. Inversions for both the high and low resolution models were carried out in order to quantify the impact of model resolution on posterior emissions and estimate about the uncertainties of these emissions.  

How to cite: Katharopoulos, I., Rust, D., Vollmer, M., Brunner, D., Reimann, S., Emmenegger, L., and Henne, S.: The influence of transport model resolution on the inverse modelling of synthetic greenhouse gas emissions in Switzerland, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5159, https://doi.org/10.5194/egusphere-egu2020-5159, 2020.

EGU2020-16472 | Displays | AS3.4

Comparison of cirrus clouds in naturally and anthropogenically influenced regions of the atmosphere

Maximilian Dollner, Josef Gasteiger, Charles A. Brock, Manuel Schöberl, Christina Williamson, Agnieszka Kupc, Anne Philipp, Petra Seibert, Karl Froyd, Gregory P. Schill, Daniel M. Murphy, Glenn Diskin, T. Paul Bui, and Bernadett Weinzierl

Cirrus clouds are an important contributor to the uncertainty of future climate prediction, especially due to the weak understanding of anthropogenic impacts on cirrus clouds.

We investigate aerosol and cloud microphysical properties of the remote atmosphere over the Pacific and Atlantic Oceans from about 80°N to 86°S and the region in the Mediterranean using airborne aerosol and cloud measurements of the entire atmospheric column up to approx. 13 km from the ATom (Atmospheric Tomography; 2016-2018) and the A-LIFE (Absorbing aerosol layers in a changing climate: aging, lifetime and dynamics; 2017) field experiments, respectively. Aerosol microphysical properties are retrieved from in-situ measurements of aerosol particle size distributions between 0.003 and 50 µm, single particle mass spectrometry as well as simulations with the Lagrangian transport and dispersion model FLEXPART. The microphysical properties of cirrus clouds are obtained from size distribution measurements covering the range between 3 and 930 µm.

In this study we show microphysical properties of aerosols and cirrus clouds in regions with high mineral dust concentrations as well as pristine and anthropogenic influenced regions in order to advance the knowledge of the natural and anthropogenic impact on cirrus clouds.  We present comparisons of ice crystal number concentrations, aerosol and cloud particle size distributions, and meteorological conditions of cirrus clouds in the above-mentioned regions of the atmosphere.

How to cite: Dollner, M., Gasteiger, J., Brock, C. A., Schöberl, M., Williamson, C., Kupc, A., Philipp, A., Seibert, P., Froyd, K., Schill, G. P., Murphy, D. M., Diskin, G., Bui, T. P., and Weinzierl, B.: Comparison of cirrus clouds in naturally and anthropogenically influenced regions of the atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16472, https://doi.org/10.5194/egusphere-egu2020-16472, 2020.

EGU2020-21948 | Displays | AS3.4

Constraining the model representation of the aerosol life cycle in relation to sources and sinks.

Paul Kim, Daniel Partridge, and James Haywood

Global climate model (GCM) ensembles still produce a significant spread of estimates for the future of climate change which hinders our ability to influence policymakers. The range of these estimates can only partly be explained by structural differences and varying choice of parameterisation schemes between GCMs. GCM representation of cloud and aerosol processes, more specifically aerosol microphysical properties, remain a key source of uncertainty contributing to the wide spread of climate change estimates. The radiative effect of aerosol is directly linked to the microphysical properties and these are in turn controlled by aerosol source and sink processes during transport as well as meteorological conditions.

A Lagrangian, trajectory-based GCM evaluation framework, using spatially and temporally collocated aerosol diagnostics, has been applied to over a dozen GCMs via the AeroCom initiative. This framework is designed to isolate the source and sink processes that occur during the aerosol life cycle in order to improve the understanding of the impact of these processes on the simulated aerosol burden. Measurement station observations linked to reanalysis trajectories are then used to evaluate each GCM with respect to a quasi-observational standard to assess GCM skill. The AeroCom trajectory experiment specifies strict guidelines for modelling groups; all simulations have wind fields nudged to ERA-Interim reanalysis and all simulations use emissions from the same inventories. This ensures that the discrepancies between GCM parameterisations are emphasised and differences due to large scale transport patterns, emissions and other external factors are minimised.

Preliminary results from the AeroCom trajectory experiment will be presented and discussed, some of which are summarised now. A comparison of GCM aerosol particle number size distributions against observations made by measurement stations in different environments will be shown, highlighting the difficulties that GCMs have at reproducing observed aerosol concentrations across all size ranges in pristine environments. The impact of precipitation during transport on aerosol microphysical properties in each GCM will be shown and the implications this has on resulting aerosol forcing estimates will be discussed. Results demonstrating the trajectory collocation framework will highlight its ability to give more accurate estimates of the key aerosol sources in GCMs and the importance of these sources in influencing modelled aerosol-cloud effects. In summary, it will be shown that this analysis approach enables us to better understand the drivers behind inter-model and model-observation discrepancies.

How to cite: Kim, P., Partridge, D., and Haywood, J.: Constraining the model representation of the aerosol life cycle in relation to sources and sinks., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21948, https://doi.org/10.5194/egusphere-egu2020-21948, 2020.

EGU2020-7132 | Displays | AS3.4

Take one dispersing plume and add some precipitation: using ensembles to simulate deposition uncertainty

Susan Leadbetter, Peter Bedwell, Gertie Geertsema, Irene Korsakissok, Jasper Tomas, Hans de Vries, and Joseph Wellings

In the event of an accidental airborne release of radioactive material, dispersion models would be used to simulate the spread of the pollutant in the atmosphere and its subsequent deposition. Typically, meteorological information is provided to dispersion models from numerical weather prediction (NWP) models. As these NWP models have increased in resolution their ability to resolve short-lived, heavy precipitation events covering smaller areas has improved. This has led to more realistic looking precipitation forecasts. However, when traditional statistics comparing precipitation predictions to measurements at a point (e.g. an observation site) are used, these high-resolution models appear to have a lower skill in predicting precipitation due to small differences in the location and timing of the precipitation with respect to the observations. This positional error is carried through to the dispersion model resulting in predictions of high deposits where none are observed and vice versa; a problem known as the double penalty problem in meteorology.

Since observations are not available at the onset of an event, it is crucial to gain insight into the possible location and timing errors. One method to address this issue is to use ensemble meteorological data as input to the dispersion model. Meteorological ensembles are typically generated by running multiple model integrations where each model integration starts from a perturbed initial state and uses slightly different model parametrisations to represent uncertainty in the atmospheric state and its evolution. Ensemble meteorological data provide several possible predictions of the precipitation that are all considered to be equally likely and this allows the dispersion model to produce several possible predictions of the deposits of radioactive material.

As part of the Euratom funded project, CONFIDENCE, a case study involving the passage of a warm front, where the timing of the front is uncertain in relation to a hypothetical nuclear accident in Europe was examined. In this study a ten-member meteorological ensemble was generated using time lagged forecasts to simulate perturbations in the initial state and two different model parameterisations. This meteorological ensemble was used as input to a single dispersion model to generate a dispersion model ensemble. The resulting ensemble dispersion output and methods to communicate the uncertainty in the deposition and the resulting uncertainty in the air concentration predictions are presented. The results demonstrate how high-resolution meteorological ensembles can be combined with dispersion models to simulate the maximum impact of precipitation and the uncertainty in its position and timing.

How to cite: Leadbetter, S., Bedwell, P., Geertsema, G., Korsakissok, I., Tomas, J., de Vries, H., and Wellings, J.: Take one dispersing plume and add some precipitation: using ensembles to simulate deposition uncertainty, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7132, https://doi.org/10.5194/egusphere-egu2020-7132, 2020.

EGU2020-22479 | Displays | AS3.4 | Vilhelm Bjerknes Medal Lecture

The Nonlinear Nature of Atmospheric Chemistry

Michael Prather

When scientific or policy-relevant questions involve atmospheric chemistry, one often hears "nonlinear" being invoked to describe the problem in a vague unspecific way.  The precise nature of the nonlinearity is never delineated, and we are left with the fuzzy impression that nonlinear problems are difficult to solve or have no simple answer.  For differentiable systems, nonlinear behavior can be expressed through a Taylor expansion whereby any of the 2nd order terms (x2, y2 or xy) are the first nonlinear parts.  In this lecture we shall explore a range of scientific discoveries or developments in atmospheric chemistry where the nonlinear nature was critical to understanding the problem.  I select a set of problems worked on by many colleagues and myself over the last four decades.  These include:  multiple solutions in stratospheric chemistry; depletion of ozone; numerical methods for tracer transport; our developing understanding of methane; chemical feedbacks and indirect greenhouse gases; and finally the rich heterogeneity of gases that drives tropospheric chemistry. I hope to convince you that by embracing the nonlinear nature of atmospheric chemistry and understanding when it is important and when it is not, we can advance the field.   

How to cite: Prather, M.: The Nonlinear Nature of Atmospheric Chemistry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22479, https://doi.org/10.5194/egusphere-egu2020-22479, 2020.

EGU2020-11517 | Displays | AS3.4

Stable isotopic composition of CO, H2 and CH4 in the troposphere and lower stratosphere: results from the ATom-WAS samples

Maria Elena Popa, Carina van der Veen, Simone Meinardi, Donald R. Blake, and Thomas Roeckmann

The NASA Atmospheric Tomography Mission (ATom) aimed to improve the understanding of atmospheric composition through global scale aircraft sampling campaigns in different seasons. The flights included continuous profiling between 0.2 and 12 km over the Atlantic and Pacific Oceans.

A large number of samples were taken using the Whole Air sampler (WAS, UC Irvine, CA). In a selection of these samples, we measured the stable isotopic composition of CO, H2 and CH4. The samples cover remote clean air from different latitudes, from troposphere and lower stratosphere, and air influenced by specific (pollution) sources or processes.

We will give an overview of the data available and the main characteristics. We observe large variations in the isotopic composition, showing the large scale influence of tropospheric sources and sinks, but also stratospheric processing. The three gas species are mainly affected by the same sources and processes but in different ways, thus giving complementary information on the atmospheric processes.

How to cite: Popa, M. E., van der Veen, C., Meinardi, S., Blake, D. R., and Roeckmann, T.: Stable isotopic composition of CO, H2 and CH4 in the troposphere and lower stratosphere: results from the ATom-WAS samples, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11517, https://doi.org/10.5194/egusphere-egu2020-11517, 2020.

EGU2020-13313 | Displays | AS3.4

Using ATom observations and models to understand what precursors drive NPF in the remote free troposphere

Agnieszka Kupc, Christina Williamson, Anna L. Hodshire, Jeffrey R. Pierce, Jan Kazil, Eric Ray, Karl Froyd, Andrew Rollins, Mathews Richardson, Bernadett Weinzierl, Maximilian Dollner, Frank Erdesz, T. Paul Bui, and Charles A. Brock

Current estimates suggest that globally, about one third of low-level cloud condensation nuclei (CCN) originate from new particle formation (NPF) in the free troposphere. However, the exact mechanisms of how these new particles form and grow to CCN sizes are not yet well quantified. We investigate the formation of new particles and their initial growth in the remote marine atmosphere over the Pacific and Atlantic basins (~80 °N to ~86 °S using (1) gas-phase and size distribution measurements (0.003-4.8 µm) from the airborne-based NASA Atmospheric Tomography global survey (ATom; 2016-2018), (2) back trajectory data, and (3) two aerosol microphysics box models.

In the ATom observations, newly formed particles were ubiquitous at high altitudes throughout broad regions of the tropics and subtropics under low condensation sink conditions and were associated with upwelling in convective clouds. This pattern was observed over four seasons and both ocean basins.

In this study, we explore processes that govern NPF and growth in the tropical and subtropical free troposphere, discuss similarities and differences in NPF over both ocean basins, use box models to examine which nucleation schemes (e.g. binary, ternary, or charged) best explain the observations, and evaluate whether sulfuric acid precursors alone can explain the NPF and the initial particle growth. Comparing aerosol size distribution measurements with box model simulations shows that none of the NPF schemes commonly used in global models are consistent with observations, regardless of precursor concentrations. Newer schemes that incorporate organic compounds as nucleating or growth agents can plausibly replicate the observed size distributions. We conclude that organic precursor species may be particularly important in NPF in the tropical upper troposphere, even above marine regions.

How to cite: Kupc, A., Williamson, C., Hodshire, A. L., Pierce, J. R., Kazil, J., Ray, E., Froyd, K., Rollins, A., Richardson, M., Weinzierl, B., Dollner, M., Erdesz, F., Bui, T. P., and Brock, C. A.: Using ATom observations and models to understand what precursors drive NPF in the remote free troposphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13313, https://doi.org/10.5194/egusphere-egu2020-13313, 2020.

EGU2020-15855 | Displays | AS3.4

Simulation of mineral dust transport to the East China Sea with FLEXPART 10.4

Andreas Hilboll, Anna Beata Kalisz Hedegaard, Lia Adam, Katharina Kaiser, Johannes Schneider, and Mihalis Vrekoussis

Particulate matter is of special interest in atmospheric studies because it has important effects on both the Earth's climate and on human health.  Currently, aerosols contribute largest to the overall uncertainty of the net radiative effects in studies of climate change.  At the same time, aerosols are responsible for a large fraction of the overall impact of air quality on human health.  Mineral dust is an important aerosol constituent and makes up a significant part of the total aerosol load.  After its emission, mineral dust can be transported over very large distances in the atmosphere, and in extreme cases influence air quality far away from its source region.

The project Effect of Megacities on the Transport and Transformation of Pollutants on the Regional to Global Scales (EMeRGe) consisted of two measurement campaigns with the research aircraft HALO.  HALO operated for two four-week periods in Europe (based close to Munich) and East Asia (based in Taiwan) in July 2017 and March 2018, respectively.  The aircraft was fully equipped with extensive measurement instrumentation to sample atmospheric composition with a focus on the air pollution outflow from major population centers.

Here, we present simulations of coarse-mode aerosol transport to the East China Sea, where EMeRGe-Asia flight E_AS_F#11 was flying from Taiwan to Japan and back on 30 Mar 2018.  During the flight, enhanced concentrations of aerosol in the 0.5-3µm diameter range were measured using an optical particle counter (OPC) in several different locations.  We used version 10.4 of the FLEXPART Lagrangian dispersion model to simulate sensitivity fields to emissions of dust, sea-sealt, and biomass burning aerosol.  Combined with emission data for the three aerosol species, we can estimate the contribution of the different species and source regions to the measured aerosol enhancements.

Among others, our simulations show that mineral dust from as far as the Sahara desert in North Africa can contribute significantly to the total aerosol concentration over the East China Sea.

How to cite: Hilboll, A., Kalisz Hedegaard, A. B., Adam, L., Kaiser, K., Schneider, J., and Vrekoussis, M.: Simulation of mineral dust transport to the East China Sea with FLEXPART 10.4, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15855, https://doi.org/10.5194/egusphere-egu2020-15855, 2020.

EGU2020-22672 | Displays | AS3.4

The Lagrangian particle dispersion model FLEXPART version 10.4

Ignacio Pisso and the The FLEXPART developers

Following its release and corresponding publication in GMD, we present the Lagrangian model FLEXPART 10.4, which simulates the transport, diffusion, dry and wet deposition, radioactive decay and first order chemical reactions of atmospheric tracers. The model has been recently updated, both technical and in the representation of physico-chemical processes. 

FLEXPART was in its original version in the mid-1990s designed for calculating the long-range and mesoscale dispersion of hazardous substances from point sources, such as released after an accident in a nuclear power plant. Given suitable meteorological input data, it can be used for scales from dozens of meters to the global scale. In particular, inverse modelling based on source-receptor relationships from FLEXPART has become widely used. In this paper, we present FLEXPART version 10.4, which works with meteorological input data from the European Centre for Medium-Range Weather Forecasts’ (ECMWF) Integrated Forecast System (IFS), and data from the United States’ National Centers of Environmental Prediction (NCEP) Global Forecast System (GFS). Since the last publication of a detailed FLEXPART description (version 6.2), the model has been improved in different aspects such as performance, physico-chemical parametrizations, input/output formats and available pre- and post-processing software. The model code has also been parallelized using the Message Passing Interface (MPI). We demonstrate that the model scales well up to using 256 processors, with a parallel efficiency greater than 75% for up to 64 processes on multiple nodes in runs with very large numbers of particles. The deviation from 100% efficiency is almost entirely due to remaining non-parallelized parts of the code, suggesting large potential for further speed-up. A new turbulence scheme for the convective boundary layer has been developed that considers the skewness in the vertical velocity distribution (updrafts and downdrafts) and vertical gradients in air density. FLEXPART is the only model available considering both effects, making it highly accurate for small-scale applications, e.g. to quantify dispersion in the vicinity of a point source. The wet deposition scheme for aerosols has been completely rewritten and a new, more detailed gravitational settling parameterization for aerosols has also been implemented. FLEXPART has had the option for running backward in time from atmospheric concentrations at receptor locations for many years, but this has now been extended to work also for deposition values . To our knowledge, to date FLEXPART is the only model with that capability. Furthermore, temporal variation and temperature dependence of chemical reactions with the OH radical have been included, allowing more accurate simulations for species with intermediate lifetimes against the reaction with OH, such as ethane. Finally, user settings can now be specified in a more flexible namelist format, and output files can be produced in NetCDF format instead of FLEXPART’s customary binary format. In this paper, we describe these new developments. Moreover, we present some  tools for the preparation of the meteorological input data and for processing of FLEXPART output data and briefly report on alternative FLEXPART versions. 

How to cite: Pisso, I. and the The FLEXPART developers: The Lagrangian particle dispersion model FLEXPART version 10.4, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22672, https://doi.org/10.5194/egusphere-egu2020-22672, 2020.

EGU2020-18222 | Displays | AS3.4

Detection of aerosols in Antarctica from long-range transport of the 2009 Australian wildfires

Julien Jumelet, Florent Tencé, Philippe Keckhut, and Slimane Bekki

We analyze the long-range transport to high latitudes of a smoke particle filament originating from the southern tropics main plume after the Australian wildfires now colloquially known as ‘Black Saturday’ on February 7th 2009. Using a high-resolution transport/microphysical model, we show that the monitoring cloud/aerosol lidar instrument operating at the French Antarctic station Dumont d’Urville (DDU - 66°S - 140°E) recorded a signature of those aerosols. The 532 nm scattering ratio of this thin aerosol structure is comparable to typical moderate stratospheric volcanic plume, with values between 1.4 and 1.6 on the 1st and 3rd days of March above DDU station at around the 14 and 16 km altitude respectively.

In this study, a dedicated model is described and its ability to track down such fine optical signatures at the global scale is assessed and validated against the Antarctic lidar measurements. Using one month of tropical CALIOP/CALIPSO data as a minimal support to a relatively simple microphysical scheme, we report modeled presence of the aerosols above DDU station after advection of the aerosol size distribution. The space-borne lidar data provide constraints to the microphysical evolution during the simulation and ensure reliable long-range transport of the particles as well as accurate rendering of the plume small-scale features below the 1°x1° resolution threshold.

This case study of smoke particle signature identification above Antarctica provides strong evidence that biomass burning events, alongside volcanic eruptions, have to be considered as processes able to inject significant amounts of material up to stratospheric altitudes. Among the questions arising out of this study, we highlight the occurrence and imprint of such smoke particles on the Antarctic atmosphere over larger time scales. Any degree of underestimation of the global impact of such deep particle transport will lead to uncertainties in modeling the associated chemical or radiative effects, especially in polar regions where many specific microphysical processes take place. Mainly through sedimentation, particle trapping above Antarctica may also impact the ground albedo (which is some of the largest in the world). Correlated to the smoke presence, we also report an associated ozone increase observed with the DDU ozone lidar. This feature only rarely been observed for events where pyroconvection is originally involved.

How to cite: Jumelet, J., Tencé, F., Keckhut, P., and Bekki, S.: Detection of aerosols in Antarctica from long-range transport of the 2009 Australian wildfires, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18222, https://doi.org/10.5194/egusphere-egu2020-18222, 2020.

Haze pollution caused by atmospheric aerosols has become one of the most severe environmental problems in China, especially in the Beijing-Tianjin-Hebei (BTH) region. Air pollution is not caused by local emission and secondary formation of air pollutants, but also affected by transport from its surrounding areas. A number of studies with respect to the regional transport of air pollutants in the BTH region have been conducted based on surface observation. However, owing to the inhomogeneous vertical distribution of air pollutants and meteorological conditions, the vertical profiles of transport fluxes should be considered for a comprehensive understanding of regional transport. In this study, the vertical profiles of aerosol and its precursor indicators HCHO, NO2 and SO2 were observed by ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS) at the Nancheng (NC) site in suburban Beijing on the southwest transport pathway. The profiles of the pollutants varied with seasons with more aerosols concentrated at the surface in the winter. Through potential source contribution function (PSCF) analysis, southwest transport pathway was determined as the main transport source region, particularly for air pollutants in the middle and upper boundary layer. The transport fluxes of air pollutants at each vertical layer on the southwest-northeast direction were estimated combining with wind field simulated by WRF-Chem modeling. The average fluxes of the measured pollutants from June 2018 to May 2019 during the southwest transport (from southwest to northeast) were all higher than those during the northeast transport (from northeast to southwest), indicating net input of pollutants to urban Beijing from southwest transport pathway. Except for northwest transport of aerosols, the other maximum transport fluxes occurred at high altitudes instead of at the surface. The proportions of surface flux in the column flux for all the species during southwest transport were higher than those during northeast transport. Surface observation would overestimate the relative contribution from urban Beijing to southwest pathway and underestimate the contribution from southwest pathway to urban Beijing. Southwest transport played an important role on the developing stage of aerosol pollution in urban Beijing in the autumn and winter, and this transport mainly occurred in the middle boundary layer.

How to cite: Hu, Q., Liu, C., Ji, X., Liu, T., and Zhu, Y.: Vertical structure of the transport fluxes of aerosol and its precursors on the southwest transport pathway in the Beijing-Tianjin-Hebei region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4967, https://doi.org/10.5194/egusphere-egu2020-4967, 2020.

EGU2020-9065 | Displays | AS3.4

Effect of sea breeze regime on aerosol optical properties over the city of Rome, Italy.

Annalisa Di Bernardino, Anna Maria Iannarelli, Stefano Casadio, Gabriele Mevi, Monica Campanelli, Giampietro Casasanta, Alexander Cede, Martin Tiefengraber, and Marco Cacciani

Mesoscale meteorological phenomena, such as sea-land breeze regime, strongly impact meteorological conditions of coastal areas, affecting wind intensity, moisture, heat and momentum fluxes and polluted air masses dispersion. This effect must be considered in order to correct design urban spaces, predict the possible influence of land use change on air pollution and climate change and, consequently, improve the quality of life and urban comfort.

In recent years, it has been shown that the breeze regime does not only affect microclimatic conditions but also air quality in coastal areas, because of the mixing of different types of aerosols and condensable gases. Moreover, the advection of marine, colder and more humid air leads to the decrease of the boundary layer height and, consequently, to the increase of the surface concentration of locally emitted pollutants, that are trapped within the boundary layer itself.

The effect of breeze regime is particularly interesting in coastal cities, where the sea breeze entails large modification of physical, optical, chemical, and hygroscopic properties of the urban aerosol.

In this work, we developed an approach to determine the breeze effect on aerosol in correspondence of the BAQUNIN [1] Super-site urban location, in the centre of Rome, Italy. The city is about 28 km far from the Tyrrhenian coast and is often exposed to sea-breeze circulation and to extreme aerosol events [2] [3].

In-situ measurements obtained from different remote sensing instruments are used: (i) vertical profile of horizontal wind velocity and direction by means of SODAR wind profiler; (ii) moisture, air temperature and wind speed from ground-based meteorological station; (iii) aerosol optical depth (AOD), height and evolution of the Boundary Layer from Raman and elastic LIDAR; (iv) precipitable water, AOD, Ångström exponent (AE) and single-scattering albedo (SSA) from sun-photometer CIMEL [4], (v) AOD, AE and SSA from POM 01 L Prede sun-sky radiometer [5][6], (vi) superficial NO2 and formaldehyde amounts from PANDORA spectrometer [7], (vii) particulate matter (PM2.5 and PM10) concentrations from ground-based air quality station.

The investigation is focused on several days, during summer of 2019, characterized by anemological breeze regime conditions.

In this study, we present preliminary results aimed to the in-depth analysis of the effects of the breeze regime on the optical properties of aerosols in coastal, urban environment and the impact of the aerosol vertical stratification on ground-level PM concentrations.

 

References:

[1] BAQUNIN Boundary-layer Air Quality-analysis Using Network of Instruments, www.baqunin.eu

[2] Petenko I. et al. (2011) “Local circulation diurnal patterns and their relationship with large-scale flows in a coastal area of the Tyrrhenian sea”, Boundary-Layer Meteorology, 139:353-366.

[3] Ciardini V. et al. (2012) “Seasonal variability of tropospheric aerosols in Rome”, Atmospheric Research, 118:205-214.

[4] AERONET, https://aeronet.gsfc.nasa.gov/new_web/index.html

[5] EUROSKYRAD http://www.euroskyrad.net/

[6] Campanelli M. et al. (2019) “Aerosol optical characteristics in the urban area of Rome, Italy, and their impact on the UV index”, Atmospheric Measurement Techniques Discussion.

[7] PGN, https://www.pandonia-global-network.org/

How to cite: Di Bernardino, A., Iannarelli, A. M., Casadio, S., Mevi, G., Campanelli, M., Casasanta, G., Cede, A., Tiefengraber, M., and Cacciani, M.: Effect of sea breeze regime on aerosol optical properties over the city of Rome, Italy., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9065, https://doi.org/10.5194/egusphere-egu2020-9065, 2020.

EGU2020-13449 | Displays | AS3.4

Development of a novel method for Nitrogen Dioxide vertical profile retrieval

Hyunkee Hong, Junsung Park, and Hanlim Lee

Abstract Text
Start Text
We developed an algorithm, for the first time, to retrieve nitrogen dioxide (NO2) vertical profile (surface NO2 volume mixing ratio) using multi NO2 slant column densities (SCDs) at ultra-violet (UV) and visible (VIS) channels since the sensitivity of nadir measurements decreases due to absorption of the gas near the surface and with decreasing wavelength. Firstly, to create a look-up table, synthetic radiances were calculated from the vector discrete ordinate radiative transfer (VLIDORT) model in the UV and VIS range using various parameters such as aerosol properties (e.g., aerosol optical depth, single scattering albedo, and aerosol loading height), geometry information (e.g., solar zenith angle, viewing zenith angle, and relative azimuth angle), NO2 vertical profile, and surface reflectance. Secondly, spectral fitting was performed at an interval of 1 nm from the center wavelength of 350 nm to 380 nm with a fitting window of about 30 nm to calculate the ratio of average NO2 SCDs in the VIS range to those in UV range. To validate the NO2 vertical profile retrieval algorithm, synthetic radiances were calculated based on NO2 vertical profiles with random values. NO2 vertical profiles are assumed to have exponential distribution and are generated with random NO2 upper limits with a range of 0 to 3 km, random total NO2 VCDs with a range of 1 to 5 × 1016 molecules cm-2, and a random relaxation parameter of exponential distribution with a range of 0.5 to 1.5. The results showed that the NO2 upper limit was 0.3 km or lower and the surface NO2 volume mixing ratio was estimated within 15% error. In addition, we also retrieved tropospheric NO2 vertical profiles using OMI LV1B radiance data.

End Text

How to cite: Hong, H., Park, J., and Lee, H.: Development of a novel method for Nitrogen Dioxide vertical profile retrieval , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13449, https://doi.org/10.5194/egusphere-egu2020-13449, 2020.

EGU2020-21844 | Displays | AS3.4

An automatic algorithm for the detection and the characterization of cloud boundaries from BAQUNIN LIDAR signals

AnnaMaria Iannarelli, Marco Cacciani, Gabriele Mevi, Stefano Casadio, and Annalisa Di Bernardino

The lidar LIDAR system is widely used in atmospheric aerosol and boundary layer (BL) studies, and for the detection of cloud boundaries. However automatic and accurate identification of cloud top and bottom heights and BL height is not trivial, especially for low signal to noise ratio values, and for cloud layers below the top of BL, because of the disentanglement of cloud and aerosol contribution to LIDAR signal.

In this work, a signal threshold approach is presented, starting from the Range Corrected Signal (RCS) and using its spatial and temporal variations. The approach has been tested using one year of acquisitions of the elastic LIDAR hosted in the BAQUNIN (Boundary-layer Air QUality analysis using Network of INstruments) Supersite(https://www.baqunin.eu) with a spatial and temporal resolution of 7.5 m and 10 s, respectively.

A minimum threshold value Tc applied to the RCS values allows detecting the presence of a cloud layer. This approach could be applied to each type of acquired LIDAR elastic signal, but depends on the specific LIDAR channel characteristics, in particular the signal to noise ratio.

RCS values obtained for each acquired profile and altitude could be considered as a two-dimensional matrix M. As first step the elements Mij>Tc of this matrix are labeled as possible cloud elements.

Subsequently, the algorithm excludes from the calculation the elements Mij corresponding to spike values or affected by high noise considering the spatial and temporal variations of the RCS. A labeled element is confirmed to be a cloud element if the number of its labeled neighbors is above a selected percentage threshold Tperc. The grid of elements considered as neighbors can be defined according to spatial and temporal resolution of the LIDAR acquisition.

Finally, bottom and top of cloud layers are retrieved as the altitude of first and last labeled elements of each cloud layer and profile.

The accuracy of the results depends on the spatial and temporal resolution of the acquired signal, considering the BAQUNIN LIDAR characteristics the best accuracy is 15 m and 20 s.

The same approach could be used to distinguish aerosol from cloud layers, using a different threshold value for the aerosol.

This method was tested for different atmospheric conditions and results are discussed in this work.

How to cite: Iannarelli, A., Cacciani, M., Mevi, G., Casadio, S., and Di Bernardino, A.: An automatic algorithm for the detection and the characterization of cloud boundaries from BAQUNIN LIDAR signals, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21844, https://doi.org/10.5194/egusphere-egu2020-21844, 2020.

EGU2020-18983 | Displays | AS3.4

Source region cluster analysis in the high-altitude measuring site of Chacaltaya with WRF and FLEXPART

Diego Aliaga, Victoria Sinclair, Zha Qiaozhi, Marcos Andrade, Claudia Mohr, and Radovan Krejci

Measuring aerosol at high altitude sites is useful as it enables sampling of the free troposphere over long time frames. However, in order to draw conclusions from station measurement data, we need to determine which air mass sources are present at any given sampling time. This task is challenging at mountain sites, due to complex topography which in turn drives complex meteorology. Between December 2017 and May 2018, the Southern hemisphere high ALTitude Experiment on particle Nucleation And growth (SALTENA) campaign was conducted at Chacaltaya in Bolivia at 5240 m a.s.l. The data set obtained in this campaign contains records of nearly all relevant aerosol characteristics and aerosol precursors. To identify the source regions of the observed air masses we performed high resolution (down to 1 km) simulations with the Weather Research and Forecasting Model (WRF). The WRF model output is then used to as input to the Lagrangian particle dispersion model (FLEXPART). FLEXPART simulations are initialised every hour and 20 thousand particles are released per hour and track backwards in time for 96 hours. The FLEXPART footprint output is regridded onto a log-polar cylindrical grid where we perform a ‘K-means’ cluster analysis on the 3D cells defined by the grid. The cells are clustered based on the time series of their source receptor relationship (i.e. emission sensitivities), producing regions (clusters) resolved not only in the horizontal but also the vertical domain. Our results show that regions located close to the station (<100km) have a low but persistent influence with diurnal variations and close contact to the surface. Mid-range regions (100-800km) have the highest influence with a higher percentage of air masses from the free troposphere. Long-range regions (>800km) have a higher influence than the short-range regions but lower than the middle-range regions. Most of the air masses from these long-range regions come from the free troposphere. With this method we have successfully resolved the various air mass influences at the measurement site. The high meteorological resolution and the stochastic nature of FLEXPART are seminal for capturing the transport pathways.

How to cite: Aliaga, D., Sinclair, V., Qiaozhi, Z., Andrade, M., Mohr, C., and Krejci, R.: Source region cluster analysis in the high-altitude measuring site of Chacaltaya with WRF and FLEXPART, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18983, https://doi.org/10.5194/egusphere-egu2020-18983, 2020.

EGU2020-12507 | Displays | AS3.4

Relative effects of open biomass and crop straw burning on haze formation over central and eastern China: modelling study driven by constrained emissions

Pengfei Li, Shaocai Yu, Yujie Wu, khalid Mehmood, Liqiang Wang, Xue Chen, Zhen Li, Yibo Zhang, Mengying Li, Weiping Liu, Yannian Zhu, Daniel Rosenfeld, and John H. Seinfeld

Open biomass burning (OBB) has large potential in triggering local and regional severe haze with elevated fine particulate matter (PM2.5) concentrations and could thus deteriorate ambient air quality and threaten human health. Open crop straw burning (OCSB), as a critical part of OBB, emits abundant gaseous and particulate pollutants, especially in fields with intensive agriculture, such as central and eastern China (CEC).  However, uncertainties in current OCSB and other types of OBB emissions in chemical transport models (CTMs) lead to inaccuracies in evaluating their impacts on haze formations. Satellite retrievals provide an alternative that can be used to simultaneously quantify emissions of OCSB and other types of OBB, such as the Fire INventory from NCAR version 1.5 (FINNv1.5), which, nevertheless, generally underestimate their magnitudes due to unresolved small fires. In this study, we selected June in 2014 as our study period, which exhibited a complete evolution process of OBB (from June 1 to 19) over CEC. During this period, OBB was dominated by OCSB in terms of the number of fire hotspot and associated emissions, most of which were located at Henan and Anhui with intensive enhancements from June 5 to 14. OCSB generally exhibits spatiotemporal correlation with regional haze over the central part of CEC (Henan, Anhui, Hubei, and Hunan), while other types of OBB emissions had influences on Jiangxi, Zhejiang, and Fujian. Based on these analyses, we establish a constraining method that integrates ground-level PM2.5 measurements with a state-of-art fully coupled regional meteorological and chemical transport model (the two-way coupled WRF-CMAQ) in order to derive optimal OBB emissions based on FINNv1.5. It is demonstrated that these emissions allow the model to reproduce meteorological and chemical fields over CEC during the study period, whereas the original FINNv1.5 underestimated OBB emissions by 2 ~ 7 times, depending on specific spatiotemporal scales. The results show that OBB had substantial impacts on surface PM2.5 concentrations over CEC. Most of the OBB contributions were dominated by OCSB, especially in Henan, Anhui, Hubei, and Hunan, while other types of OBB emissions also exerted influence in Jiangxi, Zhejiang, and Fujian. With the concentration-weighted trajectory (CWT) method, potential OCSB sources leading to severe haze in Henan, Anhui, Hubei, and Hunan were pinpointed. The results show that the OCSB emissions in Henan and Anhui can cause haze not only locally but also regionally through regional transport. Combining with meteorological analyses, we can find that surface weather patterns played a cardinal role in reshaping spatial and temporal characteristics of PM2.5 concentrations. Stationary high-pressure systems over CEC enhanced local PM2.5 concentrations in Henan and Anhui. Then, with the evolution of meteorological patterns, Hubei and Hunan in the low-pressure system were impacted by areas enveloped in the high-pressure system. These results suggest that policymakers should strictly undertake interprovincial joint enforcement actions to prohibit irregular OBB, especially OCSB over CEC. Constrained OBB emissions can, to a large extent, supplement estimations derived from satellite retrievals as well as reduce overestimates of bottom-up methods.

How to cite: Li, P., Yu, S., Wu, Y., Mehmood, K., Wang, L., Chen, X., Li, Z., Zhang, Y., Li, M., Liu, W., Zhu, Y., Rosenfeld, D., and Seinfeld, J. H.: Relative effects of open biomass and crop straw burning on haze formation over central and eastern China: modelling study driven by constrained emissions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12507, https://doi.org/10.5194/egusphere-egu2020-12507, 2020.

EGU2020-9447 | Displays | AS3.4

Unmanned Stratospheric Glider for Satellite Calibration

Nick Craine

Stratodynamics Aviation Inc. is an Earth Observation platform and service provider that’s pioneered a new cost-effective method of remote access the stratosphere. The platform called the HiDRON has successfully deployed scientific instruments over 100,000 feet above the earth and back again using balloon launched, autonomous technology.

Most satellites are able to self-calibrate however, optical and spectral units that are required to interpret data through the boundary layer face difficult challenges. We’ve identified opportunities to calibrate instruments by flying proxy beam/pulse emitters at stratospheric altitudes. As well, we see meaningful advantages to an Aircore integrated system that can capture high altitude air samples as a validation exercise. This method serves to extend the mission life of satellites beyond their intended length. Specifically, the RADARSAT constellation, the COPERNICUS program, AEOLUS as well as future Greenhouse Gas sensing satellites.

We would like to propose this technology to the EGU General Assembly 2020 for consideration as a calibration solution.

How to cite: Craine, N.: Unmanned Stratospheric Glider for Satellite Calibration, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9447, https://doi.org/10.5194/egusphere-egu2020-9447, 2020.

Southeast Asia has a far-reaching influence on the atmospheric distribution of aerosols and co-emitted trace gasses due to the high amount of emissions, the large contribution from co-emitted heat (i.e. biomass burning and urbanization), the highly variable topography, and intense and variable meteorology. We aim to quantify the pathways and constrain the impact of long-range transport on the measured increase in aerosol loading and variability. When the dry season comes in January through April, a large number of aerosols are discharged into the atmosphere from Myanmar, Thailand, Cambodia and Vietnam, which in theory, should transport them to the East under the influence of the Indian monsoon. What we observe is that first, this eastward transport is much larger in area than expected, with measurements clearly showing aerosols and long-lived trace gasses passing Taiwan and winding up in the Central Pacific, or passing around Taiwan and winding up in Northeastern China, Korea, and Japan. Secondly, we observe a significant although smaller transport of aerosols far to the south, breaching the equator, even though the climatology at this time of year indicates a Monsoon belt from 7oN southward.

We first employ a new emissions spatial-temporal distribution, forced by remotely sensed measurements of trace gasses, and second we consider meteorology associated with both fire plumes and mountain slopes. The combination of these forcings we argue is essential to reconstruct the observations. We second use observations from dozens of AERONET sites located in Southeast Asia from 2010 to 2018, to obtain the distribution of extreme events of AOD and AAOD. In addition, we combine precipitation from TRMM. These are used in tandem to establish the structural observational relationship between emissions, rainfall, transport, and diffusion.

We run these new emissions in the WRF-CHEM framework and observe a strong improvement in comparison with the measured means and variability of aerosols from MODIS and MISR, gasses from MOPITT. Furthermore, we observe a change in the vertical distribution and location of the large-scale meteorology itself, indicating that there is a possible important two-way feedback at work. We specifically note that there are significant changes induced in the high rainfall days, and in the loadings of aerosols and wind in the region from 800 to 950 hPa, with different sized particles segregated into different height levels.

How to cite: Wang, S. and Cohen, J. B.: A New Approach to Quantify the Transport of Extreme Aerosol Events in Southeast Asia by Combining WRF-CHEM with Various Models and Remotely Sensed Measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9465, https://doi.org/10.5194/egusphere-egu2020-9465, 2020.

EGU2020-2998 | Displays | AS3.4

Airborne Measurements of Formaldehyde In Biomass Burning and Urban Plumes In Central Africa Using Laser Induced Fluorescence

Grace Ronnie, Lisa Whalley, Dwayne Heard, Trevor Ingham, James Lee, Dominka Pasternak, Stéphane Bauguitte, Rebecca Carling, Thomas Bannan, Huihui Wu, and Alexander Archibald

Formaldehyde is a key intermediate in photochemical oxidation of volatile organic compounds in the troposphere and is also directly emitted by a range of sources, including biomass burning and fuel combustion. Airborne measurements of formaldehyde have therefore been used to investigate oxidation in biomass burning (BB) plumes intercepted during the Methane Observations and Yearly Assessments (MOYA) campaign. The MOYA campaign took place January/February 2019 in Uganda and Zambia and mixing ratios of formaldehyde were obtained using the University of Leeds formaldehyde Laser Induced Fluorescence (LIF) instrument. A range of air masses were intercepted including multiple near-field biomass burning (BB) plumes, with up to 140 ppb of formaldehyde observed, and urban emission plumes from the capital city of Kampala in Uganda, where up to 7 ppb of formaldehyde was measured. Formaldehyde emission factors have been calculated for Ugandan BB (1.20 ± 0.23 g kg-1) which agree well with literature (1.23 ± 0.65 g kg-1) for Savannah combustion. Production of formaldehyde as a function of plume age has also been investigated in order to discriminate direct emission from photochemical formation in BB plumes. BB plumes were also intercepted during other aircraft campaigns several days downwind of emission such as a plume transported from Canadian wildfires observed in the North Atlantic during ACSIS-5/ARNA-1 where levels of up to 18.30 ppb were detected, indicative of sustained photochemical oxidation within the plume. Comparison of urban, near-field BB and far-field BB plumes provides a variety of environments and photochemical ages to test our understanding of combustion oxidation processes.

How to cite: Ronnie, G., Whalley, L., Heard, D., Ingham, T., Lee, J., Pasternak, D., Bauguitte, S., Carling, R., Bannan, T., Wu, H., and Archibald, A.: Airborne Measurements of Formaldehyde In Biomass Burning and Urban Plumes In Central Africa Using Laser Induced Fluorescence , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2998, https://doi.org/10.5194/egusphere-egu2020-2998, 2020.

EGU2020-18077 | Displays | AS3.4

Aircraft observations of a new DMS oxidation product over the North Atlantic using a HR-ToF-CIMS

Emily Matthews, Thomas Bannan, Archit Mehra, Alexander Archibald, Huihui Wu, Paul Williams, James Lee, Patrick Veres, Carl Percival, Hugh Coe, and Martin Gallagher

Marine ecosystems are an important component of the climate feedback system. One of the main pathways for ocean-climate interaction is through the oxidation of DMS (dimethyl sulphide), a gas released from phytoplankton in the sea surface. DMS derived products are known to be important in marine cloud formation and the Earth’s radiation budget. Aerosol-Cloud interactions currently represent the largest uncertainty in climate modelling (Boucher et al., 2013). Our research focuses on airborne measurements using real-time high resolution instruments to identify and quantify trace oceanic biogenic gases on board the FAAM research aircraft. Here we present aircraft measurements made over the North Atlantic ocean using a HR-ToF-CIMS, across three seasons during the most recent ACSIS/ARNA campaigns. Here we report some of the first observations of an alternative DMS oxidation product, hydperoxymethyl thioformate (HPMFT) using chemical ionisation mass spectrometry with iodide reagent ion. Observations of this novel species have never been reported in the atmosphere but laboratory studies suggest that the main oxidation route of DMS occurs through this species, in certain environments (Berndt et al., 2019). This has potentially significant climate implications, none of which are currently represented in global climate models. The fate of this newly measured species once in the atmosphere is uncertain but is likely to alter our understanding of the marine sulphur cycle. These observations along with laboratory and modelling studies will aid in being able to understand the role of HPMFT in the ocean-climate feedback system.

References

T. Berndt, W. Scholz, B. Mentler, L. Fischer, E. H. Hoffmann, A. Tilgner, N. Hyttinen, N. L. Prisle, A. Hansel, and H. Herrmann, The Journal of Physical Chemistry Letters 2019 10 (21), 6478-6483,DOI: 10.1021/acs.jpclett.9b02567

Boucher O, Randall D, Artaxo P, Bretherton C, Feingold G, Forster P, Kerminen VM, Kondo Y, Liao H, Lohmann U, Rasch P, Satheesh S, Sherwood S, Stevens B, Zhang X. In: Clouds and aerosols. Cambridge: Cambridge University Press; 2013. United Kingdom and new york, NY, USA, book section Chapter 7, pp 571–658. https://doi.org/10.1017/CBO9781107415324.016.

 

 

 

How to cite: Matthews, E., Bannan, T., Mehra, A., Archibald, A., Wu, H., Williams, P., Lee, J., Veres, P., Percival, C., Coe, H., and Gallagher, M.: Aircraft observations of a new DMS oxidation product over the North Atlantic using a HR-ToF-CIMS, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18077, https://doi.org/10.5194/egusphere-egu2020-18077, 2020.

EGU2020-6155 | Displays | AS3.4

Quantifying organic aerosol removal in the remote troposphere: Constraints on physical and chemical removal of OA provided by the ATom mission

Pedro Campuzano-Jost, Benjamin Nault, Jason Schroder, Duseong Jo, Douglas Day, Alma Hodzic, Simone Tilmes, Luisa Emmons, Eric Ray, Pengfei Yu, Huisheng Bian, Mian Chin, Peter Colarco, Paul Newman, Jack Kodros, Jeffrey Pierce, Jakob Schacht, Bernd Heinold, Ina Tegen, and Jose Luis Jimenez and the ATom Science Team

Organic aerosol (OA) is one of the major contributors to the PM2.5 burden both in the continental Northern Hemisphere and globally. Understanding its sources and aging is central to current air quality control strategies. For the remote troposphere, sparse in-situ data to date results in highly under constrained OA prediction models, with model diversity of up to three orders of magnitude in the recent AEROCOM-II comparison.  

In the course of the recent NASA Atmospheric Tomography (ATom) set of aircraft missions, we have acquired four unique global datasets of submicron aerosol concentration and composition over the remote Atlantic and Pacific Oceans. In the remote FT OA and sulfate are the main components (about 0.3 µg sm-3 in total, fairly constant outside of continental outflow. However, OA in the remote FT exhibits a much higher average carbon oxidation state than in continental airmasses (OSc up to +1 compared to -1 over the continents), much higher than assumed in most models. This also suggests a fairly hygroscopic OA. Nevertheless, in the cleanest/most remote parts of the global free troposphere (FT), sulfate predominates. This is not captured by current global models and suggests an additional chemical removal of OA (and possibly continuing formation of sulfate).

Using several different hydrocarbon-ratio based photochemical clocks in combination with back trajectories to infer the age of the airmasses sampled during ATom, we estimate that the lifetime of OA in the remote UT (after most of the convective removal has happened) is of the order of 4 days. In contrast, for chemically inert black carbon, the estimated removal timescale using the same method is significantly longer (about a week), in general agreement with previous estimates of physical removal that are used in models. The significantly shorter OA lifetime suggests an additional, chemical removal mechanism. This provides a key constraint for modeling of OA in the FT, based solely on measurements.  Both heterogeneous oxidation by OH and aerosol photolysis are possible pathways for OA removal that have been suggested previously. Sensitivity studies in CESM2 AND GEOS-Chem with updated chemistry and aerosol sources are used to constrain the relative importance of each pathway for OA removal during ATom.

How to cite: Campuzano-Jost, P., Nault, B., Schroder, J., Jo, D., Day, D., Hodzic, A., Tilmes, S., Emmons, L., Ray, E., Yu, P., Bian, H., Chin, M., Colarco, P., Newman, P., Kodros, J., Pierce, J., Schacht, J., Heinold, B., Tegen, I., and Jimenez, J. L. and the ATom Science Team: Quantifying organic aerosol removal in the remote troposphere: Constraints on physical and chemical removal of OA provided by the ATom mission, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6155, https://doi.org/10.5194/egusphere-egu2020-6155, 2020.

EGU2020-11119 | Displays | AS3.4

Pyrocumulonimbus Events over British Columbia, 2017: The Long-term Transport and Radiative Impacts of Smoke Aerosols in the Stratosphere

Sampa Das, Peter Colarco, Luke Oman, Ghassan Taha, and Omar Torres

Interactions of meteorology with wildfires in British Columbia, Canada during August 2017 led to several extreme pyrocumulonimbus (PyroCb) events that resulted in the injection of smoke aerosols and other combustion products into the lower stratosphere. These plumes of stratospheric smoke were observed by many satellite instruments to have elevated values of aerosol extinction and backscatter compared to the background state and were readily tracked as they spread across the Northern Hemisphere and resided in the lower stratosphere for about ten months following the fires. To investigate the radiative impacts of these events on the Earth system, we performed a number of simulations with the Goddard Earth Observing System (GEOS) global Earth system model, which includes detailed aerosol and chemistry packages coupled to the underlying model physical and dynamical cores. Retrievals of smoke aerosol properties from space-based OMPS/NPP, SAGE-III/ISS, and CALIOP/CALIPSO instruments were used to calibrate the injection location, timing, amount, and optical properties of the smoke aerosols. The resulting simulations of three-dimensional smoke transport were evaluated over a year following the injections using observations from OMPS-Limb Profiler (LP), which provides aerosol retrievals at a high temporal and vertical resolution for altitudes greater than 10 km. We found that diabatic heating due to aerosol absorption, combined with the large-scale atmospheric motions, play important roles in lifting the smoke plumes from near the tropopause altitudes to about 22 km into the atmosphere. The model was able to simulate the rate of plume ascent from lower to the middle stratosphere, hemispherical spread and residence time of the smoke aerosols in the stratosphere in close agreement with OMPS-LP. Finally, we also investigated the impact of these PyroCb emitted smoke aerosols on the stratospheric radiative forcing and the subsequent impact on temperature tendencies.

How to cite: Das, S., Colarco, P., Oman, L., Taha, G., and Torres, O.: Pyrocumulonimbus Events over British Columbia, 2017: The Long-term Transport and Radiative Impacts of Smoke Aerosols in the Stratosphere , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11119, https://doi.org/10.5194/egusphere-egu2020-11119, 2020.

AS3.5 – Dynamics and chemistry of the upper troposphere and stratosphere

EGU2020-12704 | Displays | AS3.5

Age of Air in the Stratosphere from Observations

Marianna Linz, Benjamin Birner, Alan Plumb, Edwin Gerber, Florian Haenel, Gabriele Stiller, Douglas Kinnison, and Jessica Neu

Age of air is an idealized tracer often used as a measure of the stratospheric circulation. We will show how to quantitatively relate age to the diabatic circulation and the adiabatic mixing. As it is an idealized tracer, age cannot be measured itself and must be inferred from other tracers. Typically, the two primary trace gases used are sulfur hexafluoride and carbon dioxide. Other tracers have a compact relationship with age, however, and can also be used to calculate age. We will discuss a range of tracer measurements from both satellites and in situ, including sulfur hexafluoride, carbon dioxide, nitrous oxide, methane, and the ratio of argon to nitrogen. We will compare the age derived from these different species, including different calculation methods and caveats, and compare with modeled ideal age and trace gas concentrations. We conclude by showing the strength of the diabatic circulation and the adiabatic mixing calculated from these trace gas calculations.

How to cite: Linz, M., Birner, B., Plumb, A., Gerber, E., Haenel, F., Stiller, G., Kinnison, D., and Neu, J.: Age of Air in the Stratosphere from Observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12704, https://doi.org/10.5194/egusphere-egu2020-12704, 2020.

EGU2020-2660 | Displays | AS3.5

Improved global distributions of SF6 and mean age of stratospheric air by use of new spectroscopic data

Gabriele P. Stiller, Jeremy J. Harrison, Florian J. Haenel, Norbert Glatthor, Sylvia Kellmann, and Thomas von Clarmann

The first and only global data set of mean age of stratospheric air (AoA) with dense day and night coverage has been derived from MIPAS observations by analysis of the spectral signature of SF6 (Stiller et al., 2008, 2012; Haenel et al., 2015). Since SF6 is a tracer with no sinks in the troposphere and stratosphere and an almost linearly increasing atmospheric abundance, it is often used to derive information on stratospheric transport and mixing due to the Brewer Dobson Circulation, quantified usually as mean age of stratospheric air (AoA). The global data sets of AoA derived so far from MIPAS observations, on basis of spectroscopically measured absorption cross sections by Varanasi et al. (1994), had a high bias in the middle to upper stratosphere compared to balloon-borne in situ observations from the 1990s. By applying a new spectroscopic data set measured in the laboratory recently (J.J. Harrison, to be published), we show that part of the high bias in AoA can be removed, and the residuals between measured and modelled atmospheric spectra can be decreased significantly. In this presentation we discuss the new SF6 and AoA distributions, variablilities and trends, and compare to previous versions and independent in situ observations. 

References:

Haenel, F. J., Stiller, G. P., von Clarmann, T., Funke, B., Eckert, E., Glatthor, N., Grabowski, U., Kellmann, S., Kiefer, M., Linden, A., and Reddmann, T.: Reassessment of MIPAS age of air trends and variability, Atmos. Chem. Phys., 15, 13161-13176, https://doi.org/10.5194/acp-15-13161-2015, 2015.
Stiller, G. P., von Clarmann, T., Höpfner, M., Glatthor, N., Grabowski, U., Kellmann, S., Kleinert, A., Linden, A., Milz, M., Reddmann, T., Steck, T., Fischer, H., Funke, B., López-Puertas, M., and Engel, A.: Global distribution of mean age of stratospheric air from MIPAS SF6 measurements, Atmos. Chem. Phys., 8, 677-695, https://doi.org/10.5194/acp-8-677-2008, 2008.
Stiller, G. P., von Clarmann, T., Haenel, F., Funke, B., Glatthor, N., Grabowski, U., Kellmann, S., Kiefer, M., Linden, A., Lossow, S., and López-Puertas, M.: Observed temporal evolution of global mean age of stratospheric air for the 2002 to 2010 period, Atmos. Chem. Phys., 12, 3311-3331, https://doi.org/10.5194/acp-12-3311-2012, 2012.
Varanasi, P., Li, Z., Nemtchinov, V., and Cherukuri, A.: Spectral Absorption–Coefficient Data on HCFC-22 and SF6 for Remote– Sensing Applications, J. Quant. Spectrosc. Radiat. Transfer, 52, 323–332, 1994.

 

How to cite: Stiller, G. P., Harrison, J. J., Haenel, F. J., Glatthor, N., Kellmann, S., and von Clarmann, T.: Improved global distributions of SF6 and mean age of stratospheric air by use of new spectroscopic data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2660, https://doi.org/10.5194/egusphere-egu2020-2660, 2020.

EGU2020-21998 | Displays | AS3.5

Quantitative Detection of Iodine in the Stratosphere

Rainer Volkamer, Theodore Koenig, Pedro Campuzano-Jost, Alfonso Saiz-Lopez, Jose Jimenez, Rafael Fernandez, Doug Kinnison, and Carlos Cuevas

Ozone in the extrapolar lower stratosphere is currently declining for reasons that are not well understood. Iodine is emitted mostly from marine sources, and changing iodine emissions provide a possible chemical reason for why ozone in the lower stratosphere continues to decline (Koenig et al., 2020). Previous stratospheric measurements had detected iodine qualitatively in particles. More recently, IO observations in the daytime tropical tropopause layer (TTL) have suggested that between 0.25 to 0.70 pptv Iy are injected into the stratosphere, which is 1.6 to 3.5 times the WMO2014 upper limit. These indirect observations have led to revised estimates of 0 - 0.8 pptv Iy stratospheric injection in the WMO2018 report. This presentation discusses first quantitative measurements of IO radicals and of submicron particulate iodine from aircraft in the stratosphere that support 0.77 pptv Iy stratospheric injection. Our observations support the WMO2018 upper limit estimate, and clearly are incompatible with zero iodine injection. The implications of the obseved iodine concentrations for ozone loss in the lower stratosphere are discussed, also in light of climate records that find increasing iodine in recent decades, observed ozone trends, and ongoing and future research needs to better quantify iodine's contribution to explain these trends. 

How to cite: Volkamer, R., Koenig, T., Campuzano-Jost, P., Saiz-Lopez, A., Jimenez, J., Fernandez, R., Kinnison, D., and Cuevas, C.: Quantitative Detection of Iodine in the Stratosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21998, https://doi.org/10.5194/egusphere-egu2020-21998, 2020.

EGU2020-12585 | Displays | AS3.5

Empirical ozone production in the subtropical UTLS from South American biomass burning during SOUTHTRAC

Peter Hoor, Daniel Kunkel, Hans-Christoph Lachnitt, Heiko Bozem, Vera Bense, Jens-Uwe Grooß, Jörn Ungermann, Andreas Engel, Andreas Zahn, Helmut Ziereis, Felix Friedl-Vallon, Sören Johansson, Björn-Martin Sinnhuber, Martin Riese, and Markus Rapp

The biomass burning season in America was exceptionally intense during summer 2019. Particularly in the subtropics biomass burning potentially contributes significantly to the trace gas budget of the upper troposphere and can affect chemistry and composition far from the source.

During the SOUTHTRAC mission, which took place in September and November 2019, several cross sections from the equator to the southern tip of south America were flown at typical altitudes of 13-14 km. During the northbound flight on October, 7th 2019 massive enhancements of pollutants were observed at these altitudes. Notably, in-situ observations show continuously elevated CO values exceeding 200 ppbv over a flight distance of more than 1000 km. These massive enhancements were accompanied by largely elevated NO and NOy as well as CO2 and could be attributed to the large fires in South America during this time. Observations of C2H2 and PAN from GLORIA show, that pollution covered a layer extending from 8-9 km to the flight level at 13 km.

Comparing the tracer observations to previous flights in exactly the same region three weeks earlier, we could estimate the ozone production due to the biomass burning. Based on first results we estimate ozone production in the polluted air masses up to 30-40 ppbv in the UT which is almost 40% of the observed ozone mixing ratio. Given the large extent of the polluted area over 15 degrees of latitude this may have an impact on the local energy budget of the tropopause region.   

 

How to cite: Hoor, P., Kunkel, D., Lachnitt, H.-C., Bozem, H., Bense, V., Grooß, J.-U., Ungermann, J., Engel, A., Zahn, A., Ziereis, H., Friedl-Vallon, F., Johansson, S., Sinnhuber, B.-M., Riese, M., and Rapp, M.: Empirical ozone production in the subtropical UTLS from South American biomass burning during SOUTHTRAC, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12585, https://doi.org/10.5194/egusphere-egu2020-12585, 2020.

EGU2020-7507 | Displays | AS3.5

Inorganic and organic bromine measurements around the extra-tropical tropopause: Insights into total stratospheric bromine

Meike Rotermund, Ben Schreiner, Flora Kluge, Tilman Hüneke, Andreas Engel, Tanja Schuck, Timo Kerber, Jens-Uwe Grooß, Andreas Zahn, and Klaus Pfeilsticker

Bromine greatly influences the UT/LS ozone concentrations, however the transport of bromine across the tropical tropopause layer and in particular across the extratropical tropopause is not well quantified. Air-borne measurements of atmospheric trace gases such as organic and inorganic bromine along the tropopause are studied during the WISE (Wave-driven ISentropic Exchange) research campaign over the northern Atlantic and western Europe from September 13 - October 21, 2017. The remote sensing instrument mini-DOAS (Differential Optical Absorption Spectroscopy) is mounted on the HALO (High Altitude and LOng range) aircraft and measures BrO (O3, NO2 among other trace gases). The novel scaling method is applied to infer the target gas BrO mixing ratios from slant column densities using in-situ O3 measurements from the FAIRO instrument (operated by KIT) as the scaling gas. For each flight, the inferred mixing ratios are directly compared with CLaMS (Chemical Lagrangian Model of the Stratosphere) simulated curtains of the trace gases along the flight path. The partitioning coefficient of inorganic bromine from CLaMS and all relevant organic halogen species and air mass ages (SF6, CO2) from the GhOST-MS instrument (operated by UFra) are used to determine the total bromine budget along the UT/LS. A climatology of organic, inorganic and total bromine is constructed with respect to the extratropical tropopause as well as the air mass ages. This indicates the interplay of bromine transport across the extratropical tropopause and of the transport of air via the lower branch from the tropics as well as potential losses of inorganic bromine by uptake onto and sedimentation of ice particles.

How to cite: Rotermund, M., Schreiner, B., Kluge, F., Hüneke, T., Engel, A., Schuck, T., Kerber, T., Grooß, J.-U., Zahn, A., and Pfeilsticker, K.: Inorganic and organic bromine measurements around the extra-tropical tropopause: Insights into total stratospheric bromine, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7507, https://doi.org/10.5194/egusphere-egu2020-7507, 2020.

EGU2020-8992 | Displays | AS3.5

Vertical distribution, seasonality and troposphericity of ice-supersaturated air masses in the northern mid-latitudes from regular in-situ observations by passenger aircraft

Andreas Petzold, Susanne Rohs, Mihal Rütimann, Patrick Neis, Berkes Florian, Smit Herman, Krämer Martina, Spelten Nicole, Spichtinger Peter, Nedelec Philippe, and Wahner Andreas

The vertical distribution and seasonal variation of water vapour volume mixing ratio (H2O VMR), relative humidity with respect to ice (RHice) and particularly of regions with ice-supersaturated air masses (ISSR) in the extratropical upper troposphere and lowermost stratosphere are investigated at northern mid-latitudes over the regions Eastern North America, the North Atlantic and Europe for the period 1995 to 2010.

Observation data originate from regular and continuous long-term measurements of H2O VMR, temperature and RHice by instrumented passenger aircraft in the framework of the European research program MOZAIC which is continued as European research infrastructure IAGOS (from 2011; see www.iagos.org). The observation data are analysed with respect to the thermal and dynamical tropopauses, as provided by ERA-Interim. Additionally, collocated O3 observations from MOZAIC are used as tracer for stratospheric air masses.

Our key results provide in-depth insight into seasonal and regional variability and tropospheric nature of ice-supersaturated air masses at various distances from the tropopause layer. For the vertical distribution and seasonal variation of ISSR occurrence we show a comparison of our results to radio soundings and to satellite observations of cirrus cloud occurrence from AIRS and TOVs Path B instruments. Finally, for all three regions, we investigate the trends and the dependencies of ISSR occurrence on the North Atlantic Oscillation (NAO) index.

How to cite: Petzold, A., Rohs, S., Rütimann, M., Neis, P., Florian, B., Herman, S., Martina, K., Nicole, S., Peter, S., Philippe, N., and Andreas, W.: Vertical distribution, seasonality and troposphericity of ice-supersaturated air masses in the northern mid-latitudes from regular in-situ observations by passenger aircraft, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8992, https://doi.org/10.5194/egusphere-egu2020-8992, 2020.

Ozone pollution is currently a serious environmental issue in China. Most of studies have attributed the surface ozone pollution over China to the strong photochemical production from anthropogenic sources. As another important source of tropospheric ozone, the stratospheric intrusion (SI), however, has been less concerned. This study investigates the SI events over the Yangtze River Delta in eastern China using the newest ERA5 (the fifth generation of ECMWF atmospheric reanalysis) meteorological and ozone data, the In-service Aircraft for a Global Observing System (IAGOS) ozone profiles and the station-based ground-level ozone measurements. Results indicate that SI plays important roles in spring and summer ozone pollution episodes over the Yangtze River Delta, eastern China. Based on CAM-Chem (the Community Atmosphere Model with Chemistry) and LPDM (Lagrangian Particle Dispersion Modeling) model simulations, we found that deep SIs contribute ~15 ppbv in spring and ~10 ppbv in summer to surface ozone variations in eastern China. A deep SI event occurred in 2018 spring associated with a strong horizontal-trough, which brought ozone-rich air from the stratosphere to the troposphere and resulted in severe surface ozone pollution over the Yangtze River Delta. From 7-year statistics, we found that strong SI events during summer are associated with a cyclonic valley between the South Asian High and the Subtropical High, accompanied by downward fast transport of ozone from the stratosphere to the troposphere. Our results provide important information for surface ozone prediction and control in eastern China.

How to cite: Wang, W.: Impacts of Stratospheric Intrusion on Surface Ozone over Eastern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6898, https://doi.org/10.5194/egusphere-egu2020-6898, 2020.

EGU2020-7432 | Displays | AS3.5

N2O-based climatology of the Brewer-Dobson Circulation in WACCM, a chemical reanalysis and a CTM driven by four dynamical reanalyses

Daniele Minganti, Simon Chabrillat, Yves Christophe, Quentin Errrera, Marta Abalos, Maxime Prignon, Douglas Kinnison, and Emmanuel Mahieu

The Brewer-Dobson Circulation (BDC) plays a major role in the stratospheric dynamics in terms of tracer transport through the mean residual meridional advection and the isentropic 2-way mixing.
The climatological BDC in the Whole Atmosphere Community Climate Model (WACCM) is separated in its components and evaluated through a comparison with a chemical reanalysis of the Aura Microwave Limb Sounder version 2 (BRAM2) and with a chemistry-transport model driven by four modern reanalyses (ERA-Interim, JRA-55, MERRA and MERRA2). The BDC seasonal means and climatological annual cycle are addressed using the Transformed Eulerian Mean (TEM) analysis of the long-lived tracer N2O. The N2O TEM budget terms considered in this study are the vertical residual advection and the horizontal two-way mixing terms.
WACCM presents a general underestimation of the horizontal mixing term in the wintertime Northern Hemisphere with respect to the reanalyses throughout the stratosphere.In the wintertime antarctic region the mid-low stratospheric horizontal mixing term in WACCM does not agree with the reanalyses: it shows near-zero positive values, while all the reanalyses show a consistent negative contribution. This disagreement between WACCM and the reanalyses is located in the region and period of the polar vortex development, and can be related to a different representation of the polar jet. In this region the reanalyses are nevertheless affected by large uncertanties of the TEM analysis: the residual term of the budget has the same magnitude as the horizontal mixing term.Even though the residual term can be interpreted as the effect of sub-grid mixing processes, caution must be exerted when considering these regions because the N2O TEM budget is not completetely closed.
The mid-stratospheric arctic region are characterized by smaller uncertanties of the TEM budget together with large differences among the datasets during winter: the WACCM realizations, characterized by a large internal variability, show a smaller horizontal mixing contribution with respect to the reanalyses.
The agreement among datasets is generally improved when considering the middle and low latitudes, especially in the Northern Hemisphere: those regions are characterized by smaller differences among datasets and a well-closed TEM budget.
The inter-annual variability of the horizontal mixing term and the vertical advection term is highly latitude-dependent: the horizontal mixing term presents a large variability, together with a large dataset spread, in the antarctic region in the austral fall and during boreal winter in the Arctic; the vertical advection shows large variability in the arctic region and large model spread in the Tropical regions.

How to cite: Minganti, D., Chabrillat, S., Christophe, Y., Errrera, Q., Abalos, M., Prignon, M., Kinnison, D., and Mahieu, E.: N2O-based climatology of the Brewer-Dobson Circulation in WACCM, a chemical reanalysis and a CTM driven by four dynamical reanalyses, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7432, https://doi.org/10.5194/egusphere-egu2020-7432, 2020.

The intraseasonal (20-90 day) variability of the tropical upper troposphere/lower stratosphere (UTLS)  is dominated by the Madden-Julian Oscillation (MJO). Previous studies showed a strong connection between the MJO and variability in the UTLS circulation and trace gases. However, seasonality of UTLS circulation and trace gas response to the MJO has received very little attention in the literature. In this study, we use observations of trace gases (ozone, carbon monoxide and water vapor) and temperature from the Microwave Limb Sounder (MLS, version 4) and meteorological fields from the Modern-Era Retrospective analysis for Research and Applications, version 2 (MERRA-2) reanalyses to examine and explain the seasonal and zonal differences in the UTLS temperature, circulation, and trace gas anomalies associated with the MJO propagation. We find that the response of the UTLS during boreal summer months (June -September, JJAS) is different from the response during boreal winter months (November -February, NDJF). Ozone, temperature and circulation anomalies during JJAS are more zonally symmetric with a stronger Kelvin wave response than during NDJF. These differences are explained in terms of seasonal variations in vertically propagating Kelvin waves that strongly depend on the zonal structure of the climatological zonal winds. The trace gas response to the MJO is in agreement with circulation anomalies, showing strong seasonal differences. The analysis of MLS observations presented in this study may be useful for evaluation and validation of the MJO-related physical and dynamical processes in a hierarchy of models.

How to cite: Tweedy, O., Oman, L., and Waugh, D.: The seasonal and zonal differences in the temperature, circulation and composition of the tropical upper troposphere and lower stratosphere due to the MJO, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10418, https://doi.org/10.5194/egusphere-egu2020-10418, 2020.

EGU2020-3545 | Displays | AS3.5

The impact of sudden stratospheric warmings (SSWs) on UTLS composition, local radiative effects and air quality

Ryan Williams, Michaela Hegglin, Patrick Jöckel, Hella Garny, Keith Shine, and Michael Sprenger

Midwinter sudden stratospheric warmings (SSWs), characterised by the reversal of the temperature gradient poleward of 60°N and the 10 hPa climatological zonal mean wind from westerly to easterly at 60°N, are known to have pronounced impacts on tropospheric circulation which lead to regional changes in temperature, precipitation and other meteorological variables. Such abrupt events are furthermore known to be associated with large-scale changes in the distribution of stratospheric chemistry constituents, such as ozone (O3) and water vapour (H2O), although the implications for stratosphere-troposphere exchange (STE) have not been previously investigated. The evolution of O3 and H2O anomalies during an SSW life cycle are first examined from the surface up to 1 hPa using specified-dynamics simulations from the European Centre for Medium-Range Weather Forecasts – Hamburg (ECHAM)/Modular Earth Submodel System (MESSy) Atmospheric Chemistry (EMAC) model over the period 1979-2013. We show that significant positive anomalies in O3 occur around the onset of an SSW in the middle to lower stratosphere, with persistence timescales of around 50 days in the upper troposphere-lower stratosphere (UTLS). Similarly, we find significant H2O anomalies in the lowermost stratosphere (± 25 %) for up to 75 days. The extent and magnitude of the anomalies are largely confirmed in both Copernicus Atmospheric Monitoring Service (CAMS) reanalysis and ozonesonde measurements at five different Arctic stations. These chemical perturbations result in local temperature changes of up to 2 K, which may impact numerical weather prediction (NWP) of the tropospheric response to SSWs. Evaluation of the vertical residual velocity (w*) support the notion of transport changes being the driver of the temporal evolution of the anomalies. Using a stratospheric-tagged O3 tracer, a signal for enhanced STE of ozone is subsequently inferred (~ 5-10 %), which is maximised around 50 days after the SSW onset date. We furthermore attempt to elucidate STE transport pathways using a tropopause fold identification algorithm applied to ERA-Interim during this period, and assess such changes in folding frequency and distribution during such events. Our results highlight that SSWs can induce significantly disturbed O3 and H2O distributions in the UTLS, leading to enhanced STE of O3, with potentially significant implications for radiative fluxes, atmospheric heating rates and air quality.

How to cite: Williams, R., Hegglin, M., Jöckel, P., Garny, H., Shine, K., and Sprenger, M.: The impact of sudden stratospheric warmings (SSWs) on UTLS composition, local radiative effects and air quality, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3545, https://doi.org/10.5194/egusphere-egu2020-3545, 2020.

EGU2020-5899 | Displays | AS3.5

Enhanced transport and mixing of Arctic ozone during SSWs

Alvaro de la Camara, Marta Abalos, Peter Hitchcock, Natalia Calvo, and Rolando Garcia

The extreme disruptions of the wintertime stratospheric circulation during sudden stratospheric warmings (SSW) have important effects on tracer concentrations through alterations in transport and mixing properties. In this presentation we will examine the dynamics that control changes of Arctic ozone during the life cycle of SSWs, providing a quantitative analysis of both advective transport and mixing of Arctic ozone. We use output from four ensemble members (60 years each) of the Whole Atmospheric Community Climate Model, and also use reanalysis and satellite data for validation purposes. The composite evolution of ozone displays positive mixing ratio anomalies up to 0.5 – 0.6 ppmv above 550 K (∼50 hPa) around the central warming date and negative anomalies below (-0.2 to -0.3 ppmv), consistently in observations, reanalysis and model.

Our analysis shows a clear temporal offset between ozone eddy transport and diffusive ozone fluxes. The initial changes in ozone are mainly driven by isentropic eddy fluxes linked to enhanced wave drag responsible for the SSW. The recovery of climatological values in the aftermath of SSWs is slower in the lower than in the upper stratosphere, and is driven by the competing effects of cross-isentropic motions (which work towards the recovery) and isentropic mixing (which delays the recovery). These features are enhanced in strength and duration during sufficiently deep SSWs, particularly those also labeled as Polar-night Jet Oscillation (PJO) events. It is found that SSW-induced ozone concentration anomalies below 600 K (∼40 hPa), as well as total column estimates, persist around one month longer in PJO than in non-PJO warmings.

How to cite: de la Camara, A., Abalos, M., Hitchcock, P., Calvo, N., and Garcia, R.: Enhanced transport and mixing of Arctic ozone during SSWs, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5899, https://doi.org/10.5194/egusphere-egu2020-5899, 2020.

EGU2020-609 | Displays | AS3.5

Transport into the upper troposphere-lower stratosphere over North America

Xinyue Wang, William Randel, and Yutian Wu

We study fast transport of air from the surface into the North American upper troposphere-lower stratosphere (UTLS) during northern summer with a large ensemble of Boundary Impulse Response (BIR) idealized tracers. Specifically, we implement 90 pulse tracers at the Northern Hemisphere surface and release them during July and August months in the fully coupled Whole Atmosphere Community Climate Model (WACCM) version 5. We focus on the most efficient transport cases above southern U.S. (10°-40°N, 60°-140°W) at 100 hPa with modal ages fall below 10th percentile. We examine transport-related terms, including resolved dynamics computed inside model transport scheme and parameterized processes (vertical diffusion and convective parameterization), to pin down the dominant dynamical mechanism. Our results show during the fastest transport, air parcels enter ULTS directly above the Gulf of Mexico. The budget analysis indicates that strong deep convection over the Gulf of Mexico fast uplift the tracer into 200 hPa, and then is vertically advected into 100 hPa and circulated by the enhanced large-scale anticyclone. 

How to cite: Wang, X., Randel, W., and Wu, Y.: Transport into the upper troposphere-lower stratosphere over North America , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-609, https://doi.org/10.5194/egusphere-egu2020-609, 2020.

EGU2020-18936 | Displays | AS3.5

Transport processes in the lowermost stratosphere - interhemispheric differences from trace gas observations during WISE and SouthTRAC

Vera Bense, Peter Hoor, Björn Kluschat, Heiko Bozem, Daniel Kunkel, Hans-Christoph Lachnitt, Thorsten Kaluza, Philipp Joppe, Maximilian Büttner, Jens Krause, Andreas Engel, Andreas Zahn, Jens-Uwe Grooß, Martin Riese, Markus Rapp, and Björn-Martin Sinnhuber

The lowermost stratosphere (LMS) plays an important role in determining the Earth's energy budget. The chemical species that absorb and re-emit radiation in the LMS have a large spatial and temporal variability, which is controlled by mixing and transport processes. The troposphere and middle stratosphere affect the LMS through large scale isentropic transport across the tropopause or downwelling from higher altitudes.

The data presented in this study originates from two HALO measurement campaigns that allow an interhemispheric comparison of the composition of the lower stratosphere: First the WISE campaign which took place in September and October 2017 over Europe and the North Atlantic, and second the mission SouthTRAC (September and November 2019) where measurements focused on South America and the region around the Antarctic Peninsula.

We use high resolution in-situ measurements of different trace gases (N2O, O3, CO2, CO, SF6) in order to quantify transport time scales, to estimate tracer fluxes and to examine the prevalent transport pathways. Particularly correlations of trace gases of different lifetime can provide insight in the origin of air masses in the lower stratosphere and their transport histories.

During WISE a remarkable change of the N2O-O3 correlation at the 380 K potential temperature isentrope indicates a surprisingly strong distinction between the lowermost stratosphere and the stratosphere, suggesting two mixing regimes. Above 380 K, isentropic mixing occurs between stratospheric air masses from the tropics towards high latitudes leading to a slope flattening effect. In the lowermost stratosphere isentropic mixing connects the stratosphere with the tropical tropopause layer (TTL). Based on CO observations we quantify the contribution of air from the TTL to reach 60 % - 80 % in the LMS. Using CO2 measurements we estimate a typical time scale of less than 30 days for transport from the TTL into the LMS.

These methods are applied to the observations during SouthTRAC as well. Preliminary CO budget calculations suggest a smaller contribution of TTL air to the LMS in the order of 50 %. This analysis along with correlation slope studies allow for an interhemispheric and interseasonal comparison of the transport processes that were observed during the two measurement periods.

How to cite: Bense, V., Hoor, P., Kluschat, B., Bozem, H., Kunkel, D., Lachnitt, H.-C., Kaluza, T., Joppe, P., Büttner, M., Krause, J., Engel, A., Zahn, A., Grooß, J.-U., Riese, M., Rapp, M., and Sinnhuber, B.-M.: Transport processes in the lowermost stratosphere - interhemispheric differences from trace gas observations during WISE and SouthTRAC, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18936, https://doi.org/10.5194/egusphere-egu2020-18936, 2020.

EGU2020-13251 | Displays | AS3.5

Isentropic transport of water vapor into the extra-tropical lower stratosphere

Christian Rolf, Felix Plöger, Martina Krämer, and Martin Riese

Water vapor is one of the most important greenhouse gases in the Earth’s atmosphere. Due to the high sensitivity of atmospheric radiative forcing to changes in greenhouse gases in the cold upper troposphere and lower stratosphere (UTLS) region, even small variations in water vapor in the lower LS are an important source of the decadal variability of the surface temperature. This implies the need for a detailed understanding of the observed water vapor variability in the UTLS and their underlying processes.

Isentropic transport of water vapor due to planetary waves and their breaking provides a mechanism for bringing moist tropical tropospheric air into the dry lower extra-tropical stratosphere (exLS, see e.g. McIntyre and Palmer, 1983). Uplifted moist air masses by the Asian and American monsoons at the sub-tropical jet generate maximum water vapor concentrations in the summer/fall season. This water vapor maximum coincides with a maximum in planetary wave breaking in the northern hemisphere lower stratosphere and thus subsequent horizontal poleward transport. This transport serves as the dominant pathway to moisten the exLS in boreal summer (e.g. Ploeger et al., 2013 , Rolf et al. 2018).

We investigate this transport pathway with measurements to better understand the water vapor distribution and their annual cycle in the exLS. Here, we use in-situ measurements of water vapor obtained with the FISH instrument (Fast In-situ Stratospheric Hygrometer) during the aircraft field campaigns TACTS in August/ September 2012 and WISE in September/October 2017. Water vapor observations with the AURA MLS satellite instrument encompassing the entire exLS are used to put the temporal and spatial limited in-situ observations into a larger perspective. A very good agreement between the median of the in-situ water vapor distribution and the satellite observation is found, which shows that the in-situ observations are representative for the water vapor distribution of the exLS. Isentropic transport is shown to be dependent on the planetary wave activity by using the divergence of the Eliassen-Palm flux. Together with an extensive backward trajectory analysis we show that the isentropic transport is the dominant pathway of moistening the exLS up to 420 K potential temperature.

References

  • McIntyre, M. E., and T. N. Palmer (1983), Breaking planetary waves in the stratosphere, Nature, 305, 593-600.

  • Ploeger, F., Günther, G., Konopka, P., Fueglistaler, S., Müller, R., Hoppe, C., Kunz, A., Spang, R., Grooß, J.‐U., and Riese, M. ( 2013), Horizontal water vapor transport in the lower stratosphere from subtropics to high latitudes during boreal summer, J. Geophys. Res. Atmos., 118, 8111– 8127, doi:.

  • Rolf, C., Vogel, B., Hoor, P., Afchine, A., Günther, G., Krämer, M., Müller, R., Müller, S., Spelten, N., and Riese, M.: Water vapor increase in the lower stratosphere of the Northern Hemisphere due to the Asian monsoon anticyclone observed during the TACTS/ESMVal campaigns, Atmos. Chem. Phys., 18, 2973–2983, https://doi.org/10.5194/acp-18-2973-2018, 2018.

How to cite: Rolf, C., Plöger, F., Krämer, M., and Riese, M.: Isentropic transport of water vapor into the extra-tropical lower stratosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13251, https://doi.org/10.5194/egusphere-egu2020-13251, 2020.

EGU2020-20658 | Displays | AS3.5

The response of the Brewer Dobson circulation to a quadruple CO2 increase in WACCM

Natalia Calvo, Daniel R. Marsh, Rolando R. Garcia, Gabriel Chiodo, and Lorenzo Polvani

The Brewer-Dobson circulation is the mean meridional circulation in the stratosphere. It is important for the chemical distribution of trace gases in the stratosphere and its thermal structure. Chemistry climate models consistently project an acceleration of its shallow branch in response to increasing greenhouse gas concentrations, while changes in the deep branch have been much less explored. Most models agree that enhanced resolved wave forcing is the main driver of the trend in tropical upwelling in the lower stratosphere although the ultimate mechanism is not well understood. Both changes in wave generation and wave dissipation related to climate change can lead to increased wave driving and modeling results are not conclusive.

Here, we revisit this issue based on the timescales of the BDC response to an abrupt quadrupling of CO2 concentrations. We analyze CMIP5 and CMIP6 preindustrial, 4xCO2 and AMIP simulations of the Whole Atmosphere Community Climate Model (WACCM) to compare the fast and slow responses of the BDC to the increase in CO2. While the fast response is associated with the direct radiative forcing of increasing CO2, the slow response of the BDC is related to warmer sea surface temperatures. Our results show that the shallow branch is tightly coupled to the evolution of tropical surface temperature. About half of the response to an abrupt 4xCO2 increase occurs in the first 10 years in WACCM. In the deep branch, about half of the response of the tropical upwelling in the deep branch is due to warmer SSTs, the other half is radiatively-driven. The waves involved in driving these changes are also investigated together with possible mechanisms.

How to cite: Calvo, N., Marsh, D. R., Garcia, R. R., Chiodo, G., and Polvani, L.: The response of the Brewer Dobson circulation to a quadruple CO2 increase in WACCM, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20658, https://doi.org/10.5194/egusphere-egu2020-20658, 2020.

Accurate representation of tracer transport --- the movement of trace constituents by the atmospheric flow --- continues to be a challenge for climate models. Differences in the resolved circulation, biases due to physical parameterizations, and differences in the numerical representation of trace gases result in large variations in transport, even among state-of-the-art climate models. These differences result in disagreement among model projections of the evolution of stratospheric ozone throughout the 21st century particularly in the recovery of the Antarctic ozone hole. In addition to transport, the delicate momentum balance in the upper-troposphere and lower-stratosphere (UTLS) also presents a stiff challenge for model numerics, exposing the impacts of numerical dissipation, the resolution of waves, and the consequences of imperfect momentum conservation. Biases in this region impact the global circulation, e.g., influencing the extratropics jets and stratospheric polar vortices, and alter the transport and exchange of trace gases between and through the troposphere and stratosphere.

 

In this study, we compare 2 modern dynamical cores (dycores) that employ very different numerics: the cubed sphere finite volume (CSFV) core from GFDL and the spectral element (SE) core from NCAR-CAM5. We force these dycores using identical Held-Suarez diabatic forcing in the troposphere and Polvani-Kushner diabatic forcing in the stratosphere, varying the horizontal and vertical resolution. We observe significant differences in circulation, between the two models at high vertical resolution in the lower and middle tropical stratosphere. While the finite volume core is relatively insensitive to any changes in vertical resolution, the PS and SE dycores resolve considerably different tropical stratospheric dynamics at high vertical resolution (80 levels). These models develop QBO-like westerly winds in the tropics and induce a secondary meridional circulation in the tropical stratosphere, which sets of transport between the models. Using the theoretical leaky pipe transport model we analyze and separate out the transport differences due to differences is diabatic circulation and isentropic mixing and infer that this secondary circulation strikingly modulates stratospheric tracer transport (age of air) by altering the tropical-extratropical mixing, and impacts the extratropical circulation through the subtropical jets. Implications for comprehensive atmospheric modeling are discussed.

How to cite: Gupta, A., Gerber, E., and Lauritzen, P.: Assessing numerical impacts on stratospheric dynamics and transport using the age of air and the leaky pipe theoretical model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4281, https://doi.org/10.5194/egusphere-egu2020-4281, 2020.

The tropical tropopause layer (TTL) provides a major pathway for troposphere-to-stratosphere transport of radiatively active gases, thus it is an important region for understanding stratospheric composition and related climate variability. This work examines the thermal characteristics of the TTL in climate models using the results from state-of-the-art models participated in phase 1 of the Chemistry-Climate Model Initiative (CCMI).
 The CCMI models reproduce reasonable thermal structures in the TTL on climatological and seasonal timescales. However, a near-tropopause temperature bias and corresponding stratospheric moisture bias appear in many models. The temperature bias presents a strong relationship with the ozone bias in the TTL, which causes the temperature bias through local radiative processes. The CCMI models show large inter-model differences in ozone, and it is likely due to different ozone transport mechanisms in the models. These uncertainties could pose a significant limitation on understanding the Earth’s radiation budget and corresponding climate projection. 

 

How to cite: Kim, J.: Thermal characteristics of the tropical tropopause layer and their implication on stratospheric moisture in CCMI models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4410, https://doi.org/10.5194/egusphere-egu2020-4410, 2020.

EGU2020-12615 | Displays | AS3.5

New Connections Between Tropical Dynamics and Lower Stratospheric Chemistry

Catherine Wilka, Susan Solomon, Timothy Cronin, Douglas Kinnison, and Rolando Garcia

Matsuno-Gill circulations arising from tropospheric heating have been widely studied in tropical meteorology, but their impact on stratospheric chemistry and composition has seldom been explicitly evaluated. We show how anticyclonic Rossby wave gyres that form near the tropopause due to equatorially-symmetric Matsuno-Gill heating in near-equinox months provide a mechanism to influence chemistry in the tropical and subtropical upper-troposphere/lower-stratosphere (UTLS). This heating both generates anticyclonic flow in the lower stratosphere, which entrains extratropical air from higher latitudes deeper into the tropics of both hemispheres, and induces cooling in this already cold region. These two aspects of the circulation combine to allow heterogeneous chlorine activation on the surface of sulfuric acid aerosols to proceed rapidly. We use reanalysis to show that these Matsuno-Gill heating and wind response patterns are present in the months of interest, and then demonstrate that, in the WACCM model, they can substantially influence the distributions of species related to chlorine activation such as ClO and NO2. This provides a potential target for future tropical UTLS observation campaigns, and demonstrates a previously unrecognized mechanism in near-equinox months for dynamical influences on the spatial structures of atmospheric composition changes in this region. 

How to cite: Wilka, C., Solomon, S., Cronin, T., Kinnison, D., and Garcia, R.: New Connections Between Tropical Dynamics and Lower Stratospheric Chemistry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12615, https://doi.org/10.5194/egusphere-egu2020-12615, 2020.

EGU2020-4687 | Displays | AS3.5

Shedding new light on the radiative impacts of ozone-depleting substances

Gabriel Chiodo and Lorenzo M. Polvani

It is well established that ozone-depleting substances (ODS) have been the primary cause of stratospheric ozone depletion. It is also widely accepted that stratospheric ozone depletion has been the primary driver of summertime circulation trends in the Austral Hemisphere in the second half of the twentieth century. However, the climate impacts of ODS that are independent of ozone depletion have received little attention. It has long been known that, while much less abundant than carbon dioxide, ODS have a much higher global warming potential (GWP) ecent studies have indicated that ODS may have played a key-role in the observed weakening trends of the Walker circulation (Polvani and Bellomo, 2019), and in the warming of the Arctic and the associated sea ice loss (Polvani et al., 2020). that the climate efficacy of ODS may be much larger than previously thought, but .

Here, we seek to better understand the radiative effect of ODS in the global atmosphere. Instead of confining our attention on a single metric, e.g. globally averaged radiative forcing (RF) or GWP which are typically reported in the IPCC Assessment Reports, we seek to understand how ODS alter the temperature structure of the entire atmosphere. Focusing on the half-century 1950-2000, which saw the largest growth of ODS concentrations in the atmosphere, we start by performing careful computations of the RF of individual ODS, including the effects of rapid temperature adjustments. We then explore how the vertical and latitudinal distribution of ODS (which are not well mixed in the stratosphere) affects their RF, and what temperature responses are associated with those changes. These calculations are repeated individually for each of the other well-mixed GHG, as well as for other composition changes arising from ODS (ozone depletion). It is shown that ODS, in contrast to other GHG, warm the lower stratosphere, implying a different fingerprint from CO2. Furthermore, the RF of ODS exhibits the largest meridional gradient of any other well-mixed GHG. Implications for the climate efficacy of ODS, and more generally for climate sensitivity, will be discussed.

References

Polvani, L.M and K. Bellomo: The key role of ozone depleting substances in weakening the Walker circulation in the second half of the 20th century, J. Climate, 32, 1411-1418 (2019).

Polvani et al.,: Substantial twentieth-century Arctic warmng caused by ozone depleting substances, Nature Climate Change, in press (2019)

How to cite: Chiodo, G. and Polvani, L. M.: Shedding new light on the radiative impacts of ozone-depleting substances, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4687, https://doi.org/10.5194/egusphere-egu2020-4687, 2020.

Ozone in the upper troposphere is a dominant radiative constituent.  In this study, we investigate ozone variability due to stratospheric intrusions in the upper troposphere over India, and its associated radiative impacts during monsoon breaks co-occurring with El Niño. For this purpose, we use the ECHAM5-HAMMOZ, Global-Chemistry-climate model simulations, and ERA-Interim reanalysis data. Our analysis shows that during El Niño deep stratospheric intrusions, occurring at the North India - Tibetan Plateau (NI-TP) region and the western edge of the monsoon anticyclone, lead to an enormous increase in ozone amounts (~160 ppb) in the upper troposphere over India. These intrusions elevate the surface ozone levels by ~20 ppb and ozone radiative forcing by ~0.33 W m-2 at the top of the atmosphere (TOA). 

Interestingly, the stratospheric intrusions are associated with a wave train composed of cyclonic and anticyclonic circulation in the upper troposphere, emanating from El-Niño region in the east Pacific, traversing towards NI-TP locale. The wave train transports extra-tropical cold air mass, producing an anomalous cooling of ~2 - 3 K in the upper troposphere over NI-TP. The cold wave train induces Rossby wave breaking (RWB), which facilitates stratospheric intrusions, thereby enhancing subsidence over NI-TP region. Additionally, this severe cold subsidence over North India during break days may further intensify the deficit rainfall condition during break days.

How to cite: Roy, C., Fadnavis, S., and Thazhe Purayil, S.: The stratospheric ozone rich cold intrusion during El-Nino over the Indian region: implication during the Indian summer monsoon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-937, https://doi.org/10.5194/egusphere-egu2020-937, 2020.

EGU2020-8666 | Displays | AS3.5

The processes driving the water budget in the tropical stratosphere

Thibaut Dauhut, Keun-Ok Lee, Jean-Pierre Chaboureau, Vincent Noël, and Peter Haynes

The water vapour in the stratosphere is a strong green-house gas. The usual picture makes its abundance depend first on the temperature of the tropical tropopause via saturation, and second on the activity of the scarce but intense troposphere-stratosphere transport by the very deep convection. This study, designed to identify the various processes at play at the regional scale, benefits from the insitu observations during the StratoClim campaign (August 2017) and the 100-m vertical resolution of a cloud-resolving simulation over the whole south Asia (key region for the stratospheric water budget during the boreal summer). With a combination of Eulerian budget and Lagrangian track of the air masses, we show how the three main driving processes compete: the convective injections via overshoots, the turbulent diffusion, and the freeze-drying episodes driven by large-scale gravity waves, and how much they contribute to the stratospheric humidity at different altitudes.

How to cite: Dauhut, T., Lee, K.-O., Chaboureau, J.-P., Noël, V., and Haynes, P.: The processes driving the water budget in the tropical stratosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8666, https://doi.org/10.5194/egusphere-egu2020-8666, 2020.

We've  built a numerical model of the propagation and scattering of laser radiation in a turbulent medium, taking into account molecular and aerosol scattering . The model will be based on the method of random phase screens. In the framework of this method, the direct propagation of laser radiation is modeled by the method of stepwise splitting. For this purpose, a random medium is divided into layers, and each layer is presented as a composition of an infinitely thin phase screen and vacuum propagation. To simulate a random medium, random phase screens whose phase thickness is associated with the spectrum of random medium inhomogeneities will be used.

Modeling incoherent (molecular and aerosol) scattering is based on the principle of reciprocity. Since the Green function for the propagation problem in a random medium is symmetric with respect to the permutation of the source and receiver, the backscattering problem can be reduced to solving the direct radiation propagation problem. In this case, the summation of the contributions of elementary random scatterers are performed in an incoherent manner. 

         In 2009–2015, with the support of the Commission of the European Communities, as part of the 7th framework program, the DELICAT project  (DEmonstration of LIdar based Clear Air Turbulence detection) was carried out . In the course of this project , a lidar was designed , manufactured and tested for installation on an airplane with the aim of early detection of clear sky turbulence . The emitted signal was polarized vertically. The scattered radiation was measured in two polarizations: vertical and horizontal. The experiment showed that the effects of aerosol scattering at given altitudes can almost never be neglected.

    To build an aerosol scattering model, the experimental data from the DELICAT project was analyzed . Spectral and cross-spectral analysis of measurements in two polarizations is already  performed. Cross-spectral analysis will evaluate the effects of radiation depolarization. A model of the aerosol scattering matrix describing the observed effects of depolarization was constructed. In particular, multicomponent models will be considered. The spatio-temporal properties of aerosol clouds are closely investigated and also  contribution of variations in the measurement geometry during the flight to measurement errors.

       The constructed numerical model shall make it possible to plan similar experiments in the future and better understand the role of aerosol and molecular scattering in the interpretation of experimental data in order to detect clear sky turbulence.

This work was supported by the RFBR grant No. 18-35-00368

How to cite: Mamontov, A., Koval, O., and Kulikov, V.: Development of numerical model of laser sensing of clear air turbulence (CAT) taking into account effects of the propagation of laser radiation in a random medium, molecular and aerosol scattering, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-365, https://doi.org/10.5194/egusphere-egu2020-365, 2020.

EGU2020-4171 | Displays | AS3.5

A different perspective on how parameterized orographic gravity waves influence atmospheric transport and dynamics in current generation global climate models

Harald Rieder, Petr Šácha, Roland Eichinger, Aleš Kuchař, Nadja Samtleben, Petr Pišoft, and Christoph Jacobi

In the atmosphere, internal gravity waves (GWs) are a naturally occurring and ubiquitous, though intermittent phenomenon. In addition, GWs (especially orographic; OGWs) are asymmetrically distributed around the globe. In current generation global climate models (GCMs), GWs are usually smaller than the model grid resolution and the majority of their spectrum therefore must be parameterized. To some extent, the intermittency and asymmetry of a spatial distribution of the resulting OGW drag (OGWD) is present also in GCMs. As the GW parameterization schemes in GCMs are usually tuned to get the zonal mean climatology of particular features right, an important question emerges: what kind of influence do GW parameterizations have on the individual models atmosphere locally? Here we focus on answering this question regarding the impact of spatiotemporally intermittent OGW forcing in the extra-tropical lower stratosphere region (LS). The LS region is characterized by a strong interplay of chemical, physical and dynamical processes. To date, the representation of this dynamically active region in models frequently mismatches observations. Although we can find a climatological maximum of oGWD in the LS, the role of OGW forcing for the transport and composition in this region is poorly understood. We combine observational evidence, idealized modeling and statistical analysis of GCM outputs to study both the short-term and long-term model response to the OGW forcing. The results presented will question the relationship between the advective part of the Brewer- Dobson circulation and the zonally asymmetric GW forcing, and a so-far neglected link between oGWD and large-scale quasi-isentropic stirring will be discussed.

How to cite: Rieder, H., Šácha, P., Eichinger, R., Kuchař, A., Samtleben, N., Pišoft, P., and Jacobi, C.: A different perspective on how parameterized orographic gravity waves influence atmospheric transport and dynamics in current generation global climate models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4171, https://doi.org/10.5194/egusphere-egu2020-4171, 2020.

EGU2020-7289 | Displays | AS3.5

Climate impact of clear air turbulence induced mixing in the UTLS

Holger Tost and Peter Hoor

The upper troposphere / lower stratosphere (UTLS) region has been identified as a region with a high climate sensitivity of the Earth's atmosphere. Past studies have shown that mixing processes can have a substantial impact on the radiative budget of the atmosphere with implications for the climate of the planet. However, in most large-scale models some of these mixing processes are hardly resolved or considered explicitely.
In this study, we focus on clear air turbulence (CAT) as a dynamically driven mixing process, which can induce vertical mixing of radiative active trace gases. For this purpose, we have equipped a chemistry-climate model with a diagnostics for dynamical CAT including vertical stability conditions and a mixing parameterisation for CAT-induced vertical exchange of trace gases.  
With the help of this tool we analyse the occurrence of CAT, the mixing of chemical compounds and the resulting radiative impact of this mixing.
The model simulations indicate a more efficient mixing of trace species in the UTLS, weakening some of the strong gradients of compounds, such that an occasional deeper penetration into the lower stratosphere becomes possible.
A suitable choice of simulation configuration also allows us to disentangle the radiative forcing of climate active gases (e.g., N2O, O3, CH4) from
feedback processes occurring in the holistic system. 

How to cite: Tost, H. and Hoor, P.: Climate impact of clear air turbulence induced mixing in the UTLS, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7289, https://doi.org/10.5194/egusphere-egu2020-7289, 2020.

EGU2020-9544 | Displays | AS3.5

Cross-isentropic mixing: A DEEPWAVE case study

Hans-Christoph Lachnitt, Peter Hoor, Daniel Kunkel, Stafan Hofmann, Martina Bramberger, Markus Rapp, Andreas Dörnbrack, and Hans Schlager

The tropopause acts as a transport barrier between the upper troposphere and the lower stratosphere. Non-conservative (i.e. PV changing) processes are required to overcome this barrier. Orographically generated gravity waves (i.e. mountain waves) can potentially lead to cross-isentropic fluxes of trace gases via the generation of turbulence. Thus they may alter the isentropic gradient of these trace species across the tropopause.
The specific goal of this study is to identify cross-isentropic mixing processes at the tropopause based on the distribution of trace gases (i.e. tracer-tracer correlations). Based on airborne in-situ trace gas measurements of CO and N2O during the DEEPWAVE (Deep Propagating Gravity Wave Experiment) campaign in July 2014 we identified mixing regions above the Southern Alps during periods of gravity wave activity. These in-situ data show that the composition of the air above the Southern Alps change from the upstream to the leeward side of the mountains indicating cross isentropic mixing of trace gases in the region of gravity wave activity.
We complement our analysis of the measurement data with high resolution operational analysis data from the ECMWF (European Centre for Medium-Range Weather Forecasts). Furthermore, using potential vorticity and stability parameters.
Using 3D wind fields, data form Graphical Turbulence Guidance (GTG) system and in-situ measurements of the vertical wind we identify occurrence of turbulence in the region of mixing events. Using wavelet analysis, we could identify the spatial and temporal scales of local trace gas fluxes. We also give estimates of cross-isentropic flux, i.e. we want to quantify the mixing in terms of exchange.

How to cite: Lachnitt, H.-C., Hoor, P., Kunkel, D., Hofmann, S., Bramberger, M., Rapp, M., Dörnbrack, A., and Schlager, H.: Cross-isentropic mixing: A DEEPWAVE case study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9544, https://doi.org/10.5194/egusphere-egu2020-9544, 2020.

The extratropical transition or mixing layer indicates the chemical transition from well mixed troposphere to the stably stratified stratosphere . It is located around the classical defitinition of the tropopause and is defined by a set of unique tracer-tracer correlations. Physically, it is the result of cross-tropopause transport, however, many processes associated with the formation and maintenance of the extratropical transition layer with its very distinct features as well as the importance of its overlap with the tropopause inversion layer (TIL) are still a subject of research. In particular, turbulent motions in the UTLS and their relative importance for the ExTL are still unknown.

 

We analyse the top end of the spectrum of vertical shear of the horizontal wind, S2, in the troposphere and stratosphere as a proxy for turbulent motions. For this we use 10 years of ECMWF (European Centre for Medium-Range Weather Forecasts) ERA5 reanalysis data. We focus our analysis on the Northern Hemisphere extratropical UTLS, and more specifically on the Northern Pacific and Atlantic sectors. We find strong signatures of high S² just above the tropopause in both region. However, differences between the two regions are evident due to difference in the jet stream characteristics in these two regions . The areas of strong vertical wind gradients appear as regions of reduced Richardson numbers in the elsewhere highly dynamically stable lowermost stratosphere. We compare features of these regions in the model output with known characteristics of the extratropical transition layer to see if they are linked.

 

This work was supported by DFG grant no. KU 3524/1-1.

How to cite: Kaluza, T., Kunkel, D., and Hoor, P.: On the accumulation of enhanced vertical shear of the horizontal wind in the upper troposphere / lower stratosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10891, https://doi.org/10.5194/egusphere-egu2020-10891, 2020.

EGU2020-21312 | Displays | AS3.5

Investigation of transport in the northern lowermost stratosphere between spring and fall using airborne in situ tracer measurements

Andrea Rau, Valentin Lauther, Johannes Wintel, Emil Gehardt, Peter Hoor, Jens Krause, Björn Kluschat, Felix Plöger, Bärbel Vogel, and Michael Volk

Over the course of the summer, when the subtropical jet is weakest, quasi-isentropic transport of young air from the troposphere and the tropical tropopause layer into the northern hemisphere (NH) lowermost stratosphere (LMS) is increased resulting in a drastic change of LMS chemical composition between spring and fall. The focus of this work is on the role of different transport paths into the NH LMS, including outflow from the Asian Monsoon, and their associated time scales of transport and mixing.

We present and analyse in situ measurements of CO2 and various long-lived tracers obtained during three recent aircraft campaigns encompassing over 40 research flights in the NH UTLS during winter/spring, summer, and fall. The POLSTRACC/GW-LCYCLE/SALSA campaign probed the northern high latitude LMS in winter/spring 2016, deploying the German research aircraft HALO from Kiruna (Sweden) and from Germany. The second campaign deployed the M55 Geophysica research aircraft in July/August 2017 from Kathmandu, Nepal, in the frame of the EU-funded project StratoClim (Stratospheric and upper tropospheric processes for better Climate predications) in order to probe in situ for the first time the inside of the Asian Monsoon anticyclone. Roughly two months later the WISE (Wave-driven ISentropic Exchange) campaign deployed again HALO from Shannon (Ireland) in September and October 2017 to investigate isentropic transport and mixing in the NH LMS.

The University of Wuppertal measured CO2 and a suite of long-lived tracers on each aircraft. On the Geophysica, the measurements were made with the HAGAR (High Altitude Gas AnalyzeR) instrument. On HALO, a recently developed extended 5-channel version, HAGAR-V, was flown, which in addition measured a suite of short-lived tracers by GC coupled with a mass spectrometer. The University of Mainz measured N2O and CO on HALO using laser absorption techniques. For our analysis we use mixing ratios of CO2, SF6, CFC-11, CFC-12, and N2O.

Owing to their different lifetimes, tropospheric growth (for SF6) and a seasonal cycle (for CO2), the LMS distributions of these long-lived trace gases and their development between spring and fall contain key information about the origin and mean stratospheric age of LMS air as well as time scales of rapid isentropic transport and mixing. The analysis of tracer measurements is complemented by simulations with the Chemical Lagrangian Model of the Stratosphere (CLaMS) providing information on age of air spectra and fractions of origin from specific surface regions, allowing in particular to assess the role of the Asian Monsoon in determining the composition of the NH LMS in fall.

How to cite: Rau, A., Lauther, V., Wintel, J., Gehardt, E., Hoor, P., Krause, J., Kluschat, B., Plöger, F., Vogel, B., and Volk, M.: Investigation of transport in the northern lowermost stratosphere between spring and fall using airborne in situ tracer measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21312, https://doi.org/10.5194/egusphere-egu2020-21312, 2020.

EGU2020-6931 | Displays | AS3.5

GLORIA observations of pollution tracers C2H6, C2H2, HCOOH, and PAN in the North Atlantic UTLS region

Gerald Wetzel, Felix Friedl-Vallon, Norbert Glatthor, Jens-Uwe Grooß, Thomas Gulde, Michael Höpfner, Sören Johansson, Farahnaz Khosrawi, Oliver Kirner, Anne Kleinert, Erik Kretschmer, Guido Maucher, Hans Nordmeyer, Hermann Oelhaf, Johannes Orphal, Christof Piesch, Björn-Martin Sinnhuber, Jörn Ungermann, and Bärbel Vogel

The Gimballed Limb Observer for Radiance Imaging of the Atmosphere (GLORIA) is an imaging Fourier transform spectrometer (iFTS) using a 2-dimensional detector array to record emission spectra in the mid-infrared region with high spatial resolution. GLORIA is operated on high altitude research aircraft, mainly in the limb observational geometry to measure vertical profiles of temperature and atmospheric trace species with high vertical resolution.

In autumn 2017, the Wave-driven ISentropic Exchange (WISE) aircraft campaign took place from Shannon (Ireland). Sixteen flights with the High Altitude and Long Range Research Aircraft (HALO) were performed between 31 August and 21 October 2017 over the eastern North Atlantic region.

GLORIA observations were analysed with regard to pollutant species like C2H6, C2H2, HCOOH, and PAN, which are produced at distinct source regions near the ground and transported to remote regions due to their atmospheric lifetime of several weeks. Enhanced volume mixing ratios of these molecules were detected along some parts of the flight track in the upper troposphere and lowermost stratosphere (UTLS).

Measured profiles of these species are compared to simulations from the ECHAM/MESSy Atmospheric Chemistry (EMAC) model and reanalysis data from the Copernicus Atmosphere Monitoring Service (CAMS). Furthermore, emission tracers and back-trajectories from the Chemical Lagrangian Model of the Stratosphere (CLaMS) are used to analyse the source regions of these pollution events.

How to cite: Wetzel, G., Friedl-Vallon, F., Glatthor, N., Grooß, J.-U., Gulde, T., Höpfner, M., Johansson, S., Khosrawi, F., Kirner, O., Kleinert, A., Kretschmer, E., Maucher, G., Nordmeyer, H., Oelhaf, H., Orphal, J., Piesch, C., Sinnhuber, B.-M., Ungermann, J., and Vogel, B.: GLORIA observations of pollution tracers C2H6, C2H2, HCOOH, and PAN in the North Atlantic UTLS region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6931, https://doi.org/10.5194/egusphere-egu2020-6931, 2020.

EGU2020-21478 | Displays | AS3.5

Simulation of current and future tropospheric chemistry with the Earth System Model EMAC

Oliver Kirner, Jöckel Patrick, Sören Johansson, Gerald Wetzel, and Franziska Winterstein

The increasing future methane (CH4) leads to changes in the lifetime of CH4 and in the Hydroxyl radical (OH) and (O3) mixing ratios and distribution in the lower atmosphere. With increasing CH4 the lifetime of CH4 and the O3 mixing ratios in the troposphere will increase, the tropospheric OH mixing ratios will decrease (Winterstein et al., 2019; Zhao et al., 2019). The CH4 changes, together with the future Nitrous oxide (N2O) and temperature increase, will lead to a different tropospheric chemistry. For example, substances as acetone (CH3COCH3), ethane (C2H6), formic acid (HCOOH) or peroxy acetyl nitrate (PAN) will change their distribution and mixing ratios.

In different studies we could show that EMAC (ECHAM/MESSy Atmospheric Chemistry, Jöckel et al., 2010) has the ability to simulate some of the mentioned tropospheric substances in comparison to results of the GLORIA (Gimballed Limb Observer for Radiance Imaging of the Atmosphere) instrument, used on board of the research aircrafts Geophysica and HALO during the STRATOCLIM (July/August 2017) and WISE (August to October 2017) campaigns (Johansson et al., 2020; Wetzel et al., 2020).   

In this study, we will additional show the first results of the simulated future changes of tropospheric chemistry (especially with focus on CH3COCH3, C2H6, HCOOH and PAN and the upper troposphere) related to the future increase of CH4, N2O and temperature change as a result of climate change. For these we use different EMAC simulations from the project ESCiMo (Earth System Chemistry Integrated Modelling, Jöckel et al., 2016).

We will present some results of the comparison of EMAC to GLORIA and results with regard to the future development of the (upper) tropospheric chemistry in EMAC.    

How to cite: Kirner, O., Patrick, J., Johansson, S., Wetzel, G., and Winterstein, F.: Simulation of current and future tropospheric chemistry with the Earth System Model EMAC, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21478, https://doi.org/10.5194/egusphere-egu2020-21478, 2020.

EGU2020-2688 | Displays | AS3.5

Observed distribution of halocarbons in the Southern Hemispheric UTLS and implications for the bromine and chlorine budget of the lowermost stratosphere

Markus Jesswein, Sarah Soria Galvarro, Timo Keber, Tanja Schuck, Thomas Wagenhäuser, and Andreas Engel

Since the end of the 1980's, the Montreal Protocol regulates production and use of chlorine and bromine containing substances because they thin out the ozone layer. This has led to a phase out of the long-lived halocarbons like the chlorofluorocarbons (CFCs). Next to the long-lived halocarbons, bromine and chlorine containing substances with atmospheric lifetimes of less than 6 months can reach the lower stratosphere. These substances, also known as "very short-lived" substances (VSLS), have their origin both from natural and anthropogenic sources. An increase of the relative contribution of the VSLS to the stratospheric halogen loading is assumed. Due to their short lifetime, chlorine and bromine of these gases are released quickly into the stratosphere, making them particularly effective catalysts for destruction of ozone in the lower stratosphere.

Here we present airborne measurements of halocarbons including chlorine and bromine VSL source gases. Measurements were taken on the HALO aircraft during the measurement campaign SOUTHTRAC in the Southern Hemisphere UTLS. Using an airborne GC/MS system in electron impact ionization mode, samples were taken in a time resolution of around 6 minutes. One of the focuses are the exchange processes between the Northern and Southern Hemisphere. We further compare results of this campaign with these of previous ones of the Northern Hemisphere.

How to cite: Jesswein, M., Soria Galvarro, S., Keber, T., Schuck, T., Wagenhäuser, T., and Engel, A.: Observed distribution of halocarbons in the Southern Hemispheric UTLS and implications for the bromine and chlorine budget of the lowermost stratosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2688, https://doi.org/10.5194/egusphere-egu2020-2688, 2020.

EGU2020-10351 | Displays | AS3.5

Biomass burning pollution products C2H6, C2H2, HCOOH, and PAN in the Southern hemisphere UTLS region observed by the GLORIA instrument during the SouthTRAC HALO aircraft campaign Sep-Nov 2019

Felix Friedl-Vallon, Jörn Ungermann, Sören Johansson, Gerald Wetzel, Markus Geldenhuys, Andreas Engel, Jens-Uwe Grooß, Thomas Gulde, Michael Höpfner, Peter Hoor, Anne Kleinert, Erik Kretschmer, Guido Maucher, Johannes Orphal, Christof Piesch, Peter Preusse, Markus Rapp, Martin Riese, Michelle L. Santee, and Björn-Martin Sinnhuber

The Gimballed Limb Observer for Radiance Imaging of the Atmosphere (GLORIA) is an imaging Fourier transform spectrometer (iFTS) using a 2-dimensional detector array to record emission spectra in the mid-infrared region with high spatial resolution. GLORIA has been operated on the High Altitude and Long Range Research Aircraft (HALO) during the SouthTRAC campaign in September-November 2019. The campaign with base in Rio Grande (Tierra del Fuego) consisted of two observational periods, mainly in September and November 2019. Apart from many local flights, between the two phases HALO returned to Germany which allowed us to acquire long-range hemispheric cross-sections.

Two dimensional distributions of pollution species like C2H6, C2H2, HCOOH, and PAN, which are produced as primary and secondary products from biomass burning sources have been derived from the GLORIA observations. We will show that during the hemispheric cross sections as well as during some of the local flights, GLORIA observed pollution plumes with extensions of many kilometres in altitude and hundreds of kilometres horizontally with strongly enhanced concentrations of these species.

Trajectory analysis as well as comparisons to Microwave Limb Sounder (MLS) satellite observations show that the origin of plumes are mainly fires in South America and Africa, but also first signs of the Australian bush fires have been detected in the UTLS as early as November 2019.

How to cite: Friedl-Vallon, F., Ungermann, J., Johansson, S., Wetzel, G., Geldenhuys, M., Engel, A., Grooß, J.-U., Gulde, T., Höpfner, M., Hoor, P., Kleinert, A., Kretschmer, E., Maucher, G., Orphal, J., Piesch, C., Preusse, P., Rapp, M., Riese, M., Santee, M. L., and Sinnhuber, B.-M.: Biomass burning pollution products C2H6, C2H2, HCOOH, and PAN in the Southern hemisphere UTLS region observed by the GLORIA instrument during the SouthTRAC HALO aircraft campaign Sep-Nov 2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10351, https://doi.org/10.5194/egusphere-egu2020-10351, 2020.

Water vapor is one of the strongest greenhouse gases of the atmosphere. Its driving role in the upper troposphere / lower stratosphere region (UTLS) for the radiation budget was shown by e.g. Riese et al., (2012). Despite its low abundance of 4 - 6 ppmv in the stratosphere, even small changes in its mixing ratio can leed to a positive feedback to global warming. To better understand changes and variability of water vapor in the lower stratosphere, we focus here on exchange processes from the moist troposphere to the dry stratosphere in the mid latitudes. These processes are caused by extreme vertical convection, which is expected to increase in intensity and frequency with progressive global climate change.

Within the MOSES (Modular Observation Solutions for Earth Systems) campaign in the summer of 2019, two extreme vertical convection events could be captured with balloon borne humidity sensors over the eastern part of Germany. The comparison of measurements before and after both events reveal distinct water vapor enhancements in the lower stratosphere and show that even in mid-latitudes over shooting convection can impact the water vapor mixing ratio in the UTLS. The measurements are compared with the Microwave Limb Sounder (MLS) data as well as ECMWF reanalysis data.

We will show a deeper analysis of both events by using visible and infrared weather satellite images in combination with meteorological fields of ECMWF. Backward trajectories of the air masses with the enriched water vapor mixing ratios calculated with the CLAMS model and combined with the satellite images can confirm the convective origin. Additionally, we show the further development of this distinct water vapor filaments within the lower stratosphere in order to trace the transport and mixing process, based on an analysis of forward trajectories.

How to cite: Khordakova, D., Rolf, C., Krämer, M., and Riese, M.: Direct injection of water vapor into the lower stratosphere through extreme convection: A case study for the summer 2019 in the mid latitudes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14224, https://doi.org/10.5194/egusphere-egu2020-14224, 2020.

EGU2020-9301 | Displays | AS3.5

Ice supersaturated regions: properties and validation of ERA-Interim reanalysis with IAGOS in situ water vapor measurements

Philipp Reutter, Patrick Neis, Susanne Rohs, Bastien Sauvage, Peter Spichtinger, and Andreas Petzold

Cirrus clouds and their potential formation regions, so-called ice-supersaturated regions (ISSRs) occur frequently in the tropopause region. It is assumed that ISSRs and cirrus clouds can change the tropopause structure by diabatic processes, driven by latent heating due to phase transitions and interaction with radiation. These effects may also alter the distribution of potential vorticity (PV) in the upper troposphere, thus leading to changes in large scale dynamics and stratosphere-to-troposphere exchange.  

The measurement of water vapour at the tropopause level is not trivial. Beside radiosonde data the most important in-situ dataset is provided by in-service passenger airplanes. The European Research Infrastructure ’In-service Aircraft for a Global Observing System’ (IAGOS) (Petzold et al., 2015) provides long-term in-situ measurements on board commercial passenger aircraft. Along its flight track every aircraft is monitoring the chemical composition of the surrounding air and atmospheric state parameters by compact instruments. Especially in the upper troposphere/lowermost stratosphere (UTLS) these measurements are very valuable as most flight tracks are situated in heights between 9 to 13 km, depending on the actual weather conditions, seasons and geographic region. 

However, for many research questions a three-dimensional picture including a sufficient temporal resolution of the water vapour fields in the UTLS region is required. Hence, in our study we use the in-situ data from IAGOS to quantify the quality of the established and often used ERA-Interim data set. The underlying IFS-model of this reanalysis data allows explicitly ice-supersaturation in cloud free conditions and is therefore suitable for comparison. For instance, we compare properties such as the seasonal cycle of the vertical distribution of water vapour mixing ratio, relative humidity and the fraction of ice-supersaturated regions. 

How to cite: Reutter, P., Neis, P., Rohs, S., Sauvage, B., Spichtinger, P., and Petzold, A.: Ice supersaturated regions: properties and validation of ERA-Interim reanalysis with IAGOS in situ water vapor measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9301, https://doi.org/10.5194/egusphere-egu2020-9301, 2020.

EGU2020-2073 | Displays | AS3.5

Has the stratospheric HCl in the Northern Hemisphere been increasing since 2005

Yuanyuan Han, Wenshou Tian, and Fei Xie

During the Asian summer monsoon (ASM) season, the stratosphere-troposphere exchange (STE) process has a significant effect on the stratospheric chemical constituent concentration and spatial distribution. In order to further explain the STE process during the ASM season, the impact of ASMA intensity on chemical species within the anticyclone escaping process during the ASM season is studied. Using the MERRA 2, NCEP reanalysis data and MLS satellite data in June, July and August (JJA) of 2004-2017, the relationship between the day-to-day intensity variation of the ASMA and the horizontal distribution of ozone (O3) and carbon monoxide (CO) during the intra-seasonal east-west oscillation is discussed based on an ASMA intensity index we defined. The results show that the intensity of the ASMA varied during the intra-seasonal east-west oscillation. The ASMA intensity index increased continuously from early June and peaked during mid-July to early August. ASMA has a constraints effect on the air inside. Its intra-seasonal oscillation and its intensity influenced the chemical distribution in the upper troposphere and lower stratosphere (UTLS). The distribution of chemical substances during its strong periods (SP) were relatively concentrated than that in weaker periods (WP). The air inside of the ASMA was easier to mix into stratosphere when the intensity was weak, and vice verse. The intensity variation of the ASMA caused by its intra-seasonal oscillation may affect the STE process during the Asian summer monsoon season.

How to cite: Luo, J. and Peng, K.: The Iimpact of the Iintraseasonal Intensity Variation of Asian Summer Monsoon Anticyclone on Chemical Constituents Distribution in the Upper Troposphere and Lower Stratosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3223, https://doi.org/10.5194/egusphere-egu2020-3223, 2020.

A robust but thin aerosol layer in summer extending geographically from Eastern Mediterranean to Western China, the Asian Tropopause Aerosol Layer (ATAL) was observed and verified by the CALIPSO lidar measurements. However, its source and forming mechanism is still under debate. In August 2018 and 2019, two experimental campaigns over the Tibetan Plateau were carried out at Golmud (GLM, 36.48°N, 94.93°E) and Qaidam (QDM, 37.74°N, 95.34°E), during which a balloon-borne Portable Optical Particle Counter (POPS) was used to measure the features of aerosol particulates. The in-situ measurements show a robust ATAL around the tropopause, ranging from 14 to 18 km a.s.l., with a maximum aerosol number density of 35–40 cm-3 and a maximum aerosol mass concentration of 0.13 μg m-3 for particles with diameters between 0.12 and 3 μm, and majority of the particulates (98%) are smaller than 0.4 μm in diameter.

Backward-trajectory simulations are conducted with the Massive-Parallel Trajectory Calculations (MPTRAC) model to investigate the possible sources and transport pathways of the observed particulates. The backward-trajectory analysis revealed that the air parcels arrived at the altitude of the ATAL through two separate pathways: 1) the uplift below the 360 K isentropic surface, where air parcels were first elevated to the upper troposphere and then joined the ASM anticyclonic circulation, which will take about 5–10 days; and 2) the quasi-horizontal transport along the anticyclonic circulation, located approximately between the 360 and 440 K isentropic surfaces. The dispersion of the volcanic aerosol from the volcanic eruption of Raikoke in June 2019 has enhanced the aerosol layer in the Tibetan Plateau upper troposphere and lower stratosphere (UTLS), but the ATAL was not concealed by the volcanic plume because the boundary of the Asian summer monsoon (ASM) anticyclone acted as a transport barrier which stopped most of the volcanic aerosol entering the ASM region. Only at most 20% of the aerosol particulates observed in the Tibetan Plateau UTLS was contributed by the Raikoke volcanic eruption. Comparing with the Nabro eruption in 2011, the influence of volcanic eruption on the ATAL significantly depends on the relative geographical location of the volcanic eruption and the ASM anticyclone, as well as the volcanic plume height.

How to cite: Wu, X., Zhang, J., and Lyu, D.: In-situ Measurements of the Tropopause Aerosol Layer at the Tibetan Plateau and the Influence of the Volcanic Eruptions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1346, https://doi.org/10.5194/egusphere-egu2020-1346, 2020.

EGU2020-9907 | Displays | AS3.5

Global age of air spectrum from the earth surface to the upper troposphere and tropopause: a model study

Aurelien Podglajen, Edward Charlesworth, and Felix Ploeger

Transport of air masses from the surface into the atmosphere occurs via a variety of processes (including clear-air turbulence, atmospheric convection and large-scale circulations), which entails a multitude of transport time scales. This complexity can be characterized in an atmospheric transport model by calculating the age of air spectrum (transit time distribution from the surface). Up to now, mainly the slow time scales of stratospheric and interhemispheric transport (>10 days) have thus been studied. Vertical transport through the troposphere, for which convection is the major player, has only been evaluated using a handful of measured compounds (Radon, CO2 and SF6). However, a wealth of chemically relevant species are affected by the detailed structure of the age spectrum. Recent work (Luo et al., 2018) have used this sensitivity in order to gain observational insights into the tropospheric age spectrum, calling for a comparison with models.

To that end, we derive upper tropospheric and tropopause age spectra in the EMAC (ECHAM/MESSy Atmospheric Chemistry) model using the Boundary Impulse Response (BIR) method. Because of the large range of time scales involved in tropospheric transport, which extend from tens of minutes (convective transport) to years (stratospheric intrusions), we rely on a suite of pulses with variable durations providing hourly resolution for short time scales (< 12 hours) and monthly for long ones (> 1 month). We first describe the age spectra obtained and their diurnal and seasonal variability. Then, we examine the transport properties from a few specific surface regions to the upper troposphere and stratosphere, with an emphasis on fast pathways from the tropical Western Pacific and on interhemispheric transport. Finally, we investigate the sensitivity of different transport pathways to changes in some of the available model parameterizations (convection) and to different set-ups (using nudging or not).

How to cite: Podglajen, A., Charlesworth, E., and Ploeger, F.: Global age of air spectrum from the earth surface to the upper troposphere and tropopause: a model study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9907, https://doi.org/10.5194/egusphere-egu2020-9907, 2020.

EGU2020-2768 | Displays | AS3.5

21st century trends in stratosphere-to-troposphere transport

Marta Abalos, Clara Orbe, Douglas Kinnison, David Plummer, Luke Oman, Patrick Jöckel, Olaf Morgenstern, Rolando Garcia, Guang Zeng, Kane Stone, and Martin Dameris

One of the key questions in the air quality and climate sciences is how will tropospheric ozone concentrations change in the future. This will depend on two factors: changes in stratosphere-to-troposphere transport (STT) and changes in tropospheric chemistry. Here we aim to identify robust changes in STT using simulations from the Chemistry Climate Model Initiative (CCMI) under a common climate change scenario (RCP6.0). We use two idealized stratospheric tracers implemented in the models to examine changes in transport. We find that the strengthening of the shallow branch of the Brewer-Dobson circulation (BDC) in the lower stratosphere and of the upper part of the Hadley cell in the upper troposphere lead to enhanced STT in the subtropics. The acceleration of the deep branch of the BDC in the NH and changes in eddy transport contribute to increase STT at high latitudes. In the SH, the deep branch does not accelerate due to the dynamical effects of the ozone hole recovery.

How to cite: Abalos, M., Orbe, C., Kinnison, D., Plummer, D., Oman, L., Jöckel, P., Morgenstern, O., Garcia, R., Zeng, G., Stone, K., and Dameris, M.: 21st century trends in stratosphere-to-troposphere transport , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2768, https://doi.org/10.5194/egusphere-egu2020-2768, 2020.

EGU2020-5497 | Displays | AS3.5

Temporal changes in the structure of the UTLS and their potential impact on lower stratospheric ozone

Daniel Kunkel, Franziska Weyland, William Ball, and Peter Hoor

Although a general recovery of stratospheric ozone is expected after the successful implementation of the Montreal Protocol, strong indications for a decline in lower stratospheric ozone in the extratropics are still evident. Related studies attribute this decline to internal dynamic variability affecting the UTLS, in particular associated to the QBO and the exchange of air masses between tropical and extratropical regions. The dynamics affect the transport of ozone from the source region in the tropics into the extratropical lower stratosphere. More so, dynamics affect the structure of the lower stratosphere. In particular, the locations of the tropopause and of isentropic surfaces in the lower stratosphere, i.e., the region up to ~25 km altitude, affect the vertical profile of ozone and as such the integrated column ozone in the lower stratosphere.
This study aims to address the relation between the changing altitude of the tropopause and isentropic surfaces in the lower stratosphere and the declining ozone in the extratropical UTLS. For this we use reanalysis data from ECMWF and dynamic linear modeling to study trends of the dynamic tropopause and of the thermodynamical structure and the potential consequences of these trends for lower stratospheric ozone. In particular, we ask the question: do ozone trends still show a decline if we use a dynamic instead of a fixed coordinate system to calculate these trends?

How to cite: Kunkel, D., Weyland, F., Ball, W., and Hoor, P.: Temporal changes in the structure of the UTLS and their potential impact on lower stratospheric ozone, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5497, https://doi.org/10.5194/egusphere-egu2020-5497, 2020.

EGU2020-7734 | Displays | AS3.5

Ozone variability and trends in the UTLS derived from the IAGOS- CARIBIC observatory using JETPAC

Harald Boenisch, Andreas Zahn, and Luis Millan

The CARIBIC (Civil  Aircraft  for  the  Regular  Investigation  of the atmosphere Based on an 
Instrumented Container) project is part of the a European research infrastructure IAGOS (In-
Service Aircraft for a Global Observing System) making regular in-situ measurements of more 
than 100 atmospheric constituents, include ozone and water vapour, on-board of an in-service 
passenger  aircraft  operated  by  Lufthansa.  The  dataset  of  the  IAGOS-CARIBIC  is  therefore 
ideally suited as a testbed for the SPARC (Stratosphere-troposphere Processes And their Role 
in Climate) activity OCTAV-UTLS (Observed Composition Trends And Variability in the Upper 
Troposphere and Lower Stratosphere). One key aspect, shown here as work in progress, is to 
develop, define and apply common metrics for the comparison of different UTLS datasets 
using a variety of meteorological coordinate systems derived from reanalysis datasets. The 
focus here is on the variability of ozone in the upper troposphere and lower stratosphere 
(UTLS) on interannual and seasonal timescales and the observed trends. The in-situ ozone 
measurements by IAGOS-CARIBIC are analysed relative to different tropopause definitions 
and coordinate systems. All these meteorological information applied here are produced with 
the JETPAC tool ‒ Jet and Tropopause Products for Analysis and Characterization (Manney et 
al., 2011).

How to cite: Boenisch, H., Zahn, A., and Millan, L.: Ozone variability and trends in the UTLS derived from the IAGOS- CARIBIC observatory using JETPAC, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7734, https://doi.org/10.5194/egusphere-egu2020-7734, 2020.

EGU2020-16138 | Displays | AS3.5

Comparison of observed lower stratospheric ozone changes with free-running chemistry climate models
not presented

William Ball, Gabriel Chiodo, Marta Abalos, and Justin Alsing

The ozone layer was damaged last century due to the emissions of long-lived ozone depleting substances (ODSs). Following the Montreal Protocol that banned ODSs, a reduction in total column ozone (TCO) ceased in the late 1990s. Today, ozone above 32 km displays a clear recovery. Nevertheless, a clear detection of TCO recovery in observations remains elusive, and there is mounting evidence of decreasing ozone in the lower stratosphere (below 24 km) in the tropics out to the mid-latitudes (30-60°). Chemistry climate models (CCMs) predict that lower stratospheric ozone will decrease in the tropics by 2100, but not at mid-latitudes.
 
Here, we compare the CCMVal-2 models, which informed the WMO 2014 ozone assessment and show similar tendencies to more recent CCMI data, with observations over 1998-2016. We find that over this period, modelled ozone declines in the tropics are similar to those seen in observations and are likely driven by increased tropical upwelling. Conversely, CCMs generally show ozone increases in the mid-latitude lower stratosphere where observations show a negative tendency. We provide evidence from JRA-55 and ERA-Interim reanalyses indicating that mid-latitude trends are due to enhanced mixing between the tropics and extratropics, in agreement with other studies. 

Additional analysis of temperature and water vapour further supports our findings. Overall, our results suggest that expected changes in large scale circulation from increasing greenhouse gases may now already be underway. While model projections suggest extra-tropical ozone should recover by 2100, our study raises questions about their ability to simulate lower stratospheric changes in this region.

How to cite: Ball, W., Chiodo, G., Abalos, M., and Alsing, J.: Comparison of observed lower stratospheric ozone changes with free-running chemistry climate models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16138, https://doi.org/10.5194/egusphere-egu2020-16138, 2020.

EGU2020-16682 | Displays | AS3.5

The QBO as driver of lower stratospheric ozone variability as quantified in the CCM SOCOLv3

Andrea Stenke, William T. Ball, and Daniela Domeisen

The quasi-biennial oscillation (QBO) is the dominating mode of variability in the tropical stratosphere. The oscillation of zonal winds between downward propagating easterlies and westerlies induces a secondary meridional circulation. This, in turn, modulates tropical upwelling, which also affects transport between tropical and extratropical regions and can induce large swings in tracer anomalies. Chemistry-climate models (CCMs) need a sufficiently high vertical resolution to spontaneously generate a QBO, while models with lower resolution often nudge zonal winds to observed equatorial wind profiles. Here, we evaluate the QBO impact on lower stratospheric ozone variability in the CCM SOCOLv3 using various model set-ups. Composites of stratospheric ozone observations demonstrate large interannual variations in mid-latitudes driven by QBO phase-dependent variability. From a large ensemble of free-running model simulations with nudged QBO, we find simulated ozone anomalies in the tropical stratosphere consistently reproduce those observed. However, extratropical anomalies show significant deviations from observations. In the southern hemisphere, about 65% of all cases from our ensemble agree in the sign of the observed anomalies, but the amplitude is underestimated. In contrast to the free-running model, simulations in specified dynamics mode show an overall good agreement with observations, including extratropical regions. This suggests a strong impact of the state of the large-scale stratospheric circulation on the QBO effect upon mid-latitudes. This is supported by model simulations where specified dynamics are applied to the troposphere only. Here we present a detailed analysis of the interaction between simulated stratospheric circulation and the QBO-induced secondary circulation. The realistic representation of such QBO-driven events in terms of frequency and strength in CCMs may be crucial for reproducing the observed large interannual variability in lower stratospheric tracer concentrations and, hence, for correctly retrieving lower stratospheric ozone trends.

How to cite: Stenke, A., Ball, W. T., and Domeisen, D.: The QBO as driver of lower stratospheric ozone variability as quantified in the CCM SOCOLv3, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16682, https://doi.org/10.5194/egusphere-egu2020-16682, 2020.

EGU2020-19734 | Displays | AS3.5

Beyond model spread: a process-based attribution of uncertainties in stratospheric ozone modelling

Simon Chabrillat, Vincent Huijnen, Quentin Errera, Jonas Debosscher, Idir Bouarar, Guy Brasseur, Sophie Belamari, Virginie Marécal, Béatrice Josse, and Johannes Flemming

Intercomparisons between Chemistry-Climate Models (CCMs) have highlighted shortcomings in our understanding and/or modeling of long-term ozone trends, and there is a growing interest in the impact of stratospheric ozone changes on tropospheric chemistry via both ozone fluxes (e.g. from the projected strengthening of the Brewer-Dobson circulation) and actinic fluxes. Advances in this area require a good understanding of the modelling uncertainties in the present-day distribution of stratospheric ozone, and a correct attribution of these uncertainties to the processes governing this distribution: photolysis, chemistry and transport. These processes depend primarily on solar irradiance, temperature and dynamics.

Here we estimate model uncertainties arising from different input datasets, and compare them with typical uncertainties arising from the transport and chemistry schemes. This study is based on four sets of tightly controlled sensititivity experiments which all use temperature and dynamics specified from reanalyses of meteorological observations. The first set of experiments uses one Chemistry-Transport Model (CTM) and evaluates the impact of using 3 different spectra of solar irradiance. In the second set, the CTM is run with 4 different input reanalyses: ERA-5, MERRA-2, ERA-I and JRA-55. The third set of experiments still relies on the same CTM, exploring the impact of the transport algorithm and its configuration. The fourth set is the most sophisticated as it is enabled by model developments for the Copernicus Atmopshere Monitoring Service, where the ECMWF model IFS is run with three different photochemistry modules named according to their parent CTM: IFS(CB05-BASCOE), IFS(MOCAGE) and IFS(MOZART).

All modelling experiments start from the same initial conditions and last 2.5 years (2013-2015). The uncertainties arising from different input datasets or different model components are estimated from the spreads in each set of sensitivity experiments and also from the gross error between the corresponding model means and the BASCOE Reanalysis of Aura-MLS (BRAM2). The results are compared across the four sets of experiments, as a function of latitude and pressure, with a focus on two regions of the stratosphere: the polar lower stratosphere in winter and spring - in order to assess and understand the quality of our ozone hole forecasts - and the tropical middle and upper stratosphere - where noticeably large disagreements are found between the experiments.

How to cite: Chabrillat, S., Huijnen, V., Errera, Q., Debosscher, J., Bouarar, I., Brasseur, G., Belamari, S., Marécal, V., Josse, B., and Flemming, J.: Beyond model spread: a process-based attribution of uncertainties in stratospheric ozone modelling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19734, https://doi.org/10.5194/egusphere-egu2020-19734, 2020.

EGU2020-5231 | Displays | AS3.5

Revisiting the factors that drive interannual variability in stratospheric entry water vapour

Shlomi Ziskin Ziv and Chaim I. Garfinkel

Understanding the sinks, sources and transport processes of stratospheric trace gases can improve our prediction of mid to long term climate change. In this study we consider the processes that lead to variability in stratospheric water vapor. We perform a Multiple Linear Regression(MLR) on the SWOOSH combined anomaly filled water vapor product with ENSO, QBO, BDC, mid-tropospheric temperature, and CH4 as predictors, in an attempt to find the factors that most succinctly explain observed water vapor variability. We also consider the fraction of entry water vapor variability that can be accounted for by variations of the cold point temperature as an upper bound on how much water vapor variability is predictable from large scale processes. Several periods in which the MLR fails to account for interannual variability are treated as case studies in order to better understand variability in entry water not governed by these large scale processes.

How to cite: Ziskin Ziv, S. and I. Garfinkel, C.: Revisiting the factors that drive interannual variability in stratospheric entry water vapour, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5231, https://doi.org/10.5194/egusphere-egu2020-5231, 2020.

EGU2020-12643 | Displays | AS3.5

Hydration of the tropical tropopause layer (TTL) by convective updraft during tropical cyclone ENAWO(2017) and generalization to tropical storms in the southwestern Indian Ocean in summer 2016-2017.

Damien Héron, Stephanie Evan, Jerome Brioude, Joris Pianezze, Thibault Dauhut, Vincent Noel, Soline Bielli, Christelle Barthe, and Jean-Pierre Cammas

Stratospheric water vapor variations play an important role on the climate. Predictions of changes in stratospheric humidity are uncertain because of gaps in our understanding of physical processes occurring in the TTL, between 14 and 20 km altitude. In particular, climate models have great difficulties in modelling water vapor variations in the TTL due to a poor representation of tropical convection, which largely controls the vertical transport of water vapor to UTLS, among other things.

One of the scientific objectives of the CONCIRTO5 program is to better understand the role of marine deep convective systems, and tropical cyclones in particular, on the hydration of TTL in the Southwestern Indian Ocean.  In March 2017, a rapid deepening of the tropical cyclone Enawo occured north-west of Reunion island before to strike and cross Madagascar from north to south. The progressive intensification of the cyclone to the intense tropical cyclone stage makes it an ideal case study to analyze the transport of water vapor and hydrometeors in the TTL according to the intensity phase of the cyclone. 

We will present modelling results on water vapor transport into the TTL in March 4 during ENAWO’s intensification. On March 4, the mesoscale model Meso-NH simulated a large water vapour transport through the TTL, associated with the injection of ice through the tropopause and the observation of cirrus clouds. The model validation is done by comparison with satellite data (CALIPSO, Meteosat-8). We generalize the intrusion modelling during ENAWO intensification by comparing the brightness temperature observed above the tropical cyclones and the tropical tropopause temperature extracted from ECMWF-Analysis during the 2016-2017 cyclonic season. From these studies, we can estimate the number of intrusions during a cyclonic season and the cyclonic intensity associated with the intrusions.

 

5Effects of convection and cirrus clouds on the Tropical Tropopause Layer over the Indian Ocean

How to cite: Héron, D., Evan, S., Brioude, J., Pianezze, J., Dauhut, T., Noel, V., Bielli, S., Barthe, C., and Cammas, J.-P.: Hydration of the tropical tropopause layer (TTL) by convective updraft during tropical cyclone ENAWO(2017) and generalization to tropical storms in the southwestern Indian Ocean in summer 2016-2017., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12643, https://doi.org/10.5194/egusphere-egu2020-12643, 2020.

EGU2020-13903 | Displays | AS3.5

Investigating stratospheric changes between 2009 and 2018 with aircraft, AirCores, a global model and a focus on CFC-11

Johannes Laube and Felix Ploeger and the Stratospheric CFC-11 team

We present new observations of trace gases in the stratosphere based on a cost-effective sampling technique that can access much higher altitudes than aircraft. The further development of this method now provides detection of species with abundances in the parts per trillion (ppt) range and less. We focus on mixing ratios for CFC-11 and CFC-12 which are important for understanding stratospheric ozone depletion and circulation. After demonstrating the quality of the data through comparisons with ground-based records and aircraft-based observations we combine them with the latter to demonstrate their potential. We first compare them with results from a global model driven by three widely used meteorological reanalyses (ERA-Interim, JRA-55, MERRA-2). Secondly, we focus on CFC-11 as recent evidence has indicated renewed atmospheric emissions of that species relevant on a global scale. Because the stratosphere represents the main sink region for CFC-11, potential changes in stratospheric circulation and troposphere-stratosphere exchange fluxes have been identified as the largest source of uncertainty for the accurate quantification of such emissions. Our observations span over a decade (up until 2018) and therefore cover the period of the slowdown of CFC-11 global mixing ratio decreases measured at the Earth’s surface. The spatial and temporal coverage of the observations is insufficient for a global quantitative analysis, but we do find some trends that are in contrast with expectations; indicating that the stratosphere may have contributed to tropospheric changes. Further investigating the model data we find that the required dynamical changes in the stratosphere required to explain the apparent change in tropospheric CFC-11 emissions after 2013 are possible, but with a very high uncertainty range in the change of stratosphere-to-troposphere flux of CFC-11. This is partly caused by the high variability of mass flux from the stratosphere to the troposphere, especially at time scales of a few years, and partly by large differences between runs driven by different reanalysis products, none of which agree with our observations well enough for such a quantitative analysis.

How to cite: Laube, J. and Ploeger, F. and the Stratospheric CFC-11 team: Investigating stratospheric changes between 2009 and 2018 with aircraft, AirCores, a global model and a focus on CFC-11, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13903, https://doi.org/10.5194/egusphere-egu2020-13903, 2020.

EGU2020-16999 | Displays | AS3.5

Impacts of stratospheric dynamical variability on total inorganic fluorine from observations and models constrained by state-of-the-art reanalyses

Maxime Prignon, Peter F. Bernath, Simon Chabrillat, Martyn P. Chipperfield, Sandip S. Dhomse, Wuhu Feng, Daniele Minganti, Christian Servais, Dan Smale, and Emmanuel Mahieu

Man-made halogenated compounds emitted from the Earth’s surface ultimately reach the stratosphere where they undergo photolysis, leading to three main fluorine reservoirs: hydrogen fluoride (HF), carbonyl fluoride (COF2) and carbonyl chloride fluoride (COClF). This process is directly influenced by the strength of the mean meridional circulation of the stratosphere, the Brewer-Dobson Circulation (BDC). The BDC is projected to speed-up with the greenhouse gases induced global warming. However, studies have highlighted a multiyear variability in the strength of the BDC resulting in hemispheric asymmetries in observed and modelled trends of age of air and long-lived tracers.

Total inorganic fluorine (Fy, the fluorine weighted sum of HF, COF2 and COClF) is used here as a tracer of the stratospheric circulation changes. We perform an analysis and interpretation of Fourier transform infrared (FTIR) multidecadal time-series of HF and COF2 from the Jungfraujoch (Switzerland, 46.55°N) and Lauder (New-Zealand, 45.03°S) stations and from the space-borne Atmospheric Chemistry Experiment - Fourier Transform Spectrometer (ACE-FTS). Indeed, the summation of HF and COF2 is a very good proxy of Fy as we determine, from ACE-FTS and the chemical-transport model (CTM) TOMCAT, that COClF is only accounting for less than 5% of the total Fy budget.

The kinematic CTM BASCOE (Belgian assimilation system for chemical observations) is used here to assess the representation of the investigated circulation changes in four state-of-the-art meteorological reanalyses, i.e., ERA-Interim, JRA-55, MERRA and MERRA-2. We also investigate if WACCM4 (Whole Atmosphere Community Climate Model version 4) is able to reproduce these changes through a free-running simulation.

The ground-based and satellite FTIR time-series of COF2 show contrasting results over their common time period (2004-2019), with a positive total column trend above the Jungfraujoch, and a non-significant (ground-based) or decreasing trend (ACE-FTS) above Lauder. We find large discrepancies between the BASCOE-CTM simulations, with MERRA-2 inducing overly large simulated Fy total columns which could confirm the weaker tropical upwelling highlighted in previous age of air studies.

How to cite: Prignon, M., Bernath, P. F., Chabrillat, S., Chipperfield, M. P., Dhomse, S. S., Feng, W., Minganti, D., Servais, C., Smale, D., and Mahieu, E.: Impacts of stratospheric dynamical variability on total inorganic fluorine from observations and models constrained by state-of-the-art reanalyses, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16999, https://doi.org/10.5194/egusphere-egu2020-16999, 2020.

EGU2020-19192 | Displays | AS3.5

Mean Age from in situ observations with AirCore: Accuracy of altitude attribution investigated with the CO-spiking experiment

Thomas Wagenhäuser, Andreas Engel, Robert Sitals, and Irina Kistner

In order to monitor possible changes of the mean age of air in the stratosphere, in situ high altitude observations of suitable tracers are required. The AirCore is a simple sampling technique, which can be deployed to weather balloons in order to capture a continuous vertical profile of atmospheric trace gases up to 30 km. During ascent it empties due to the decreasing ambient pressure with height. During descent the AirCore fills with ambient air due to the positive change in ambient pressure. The analysis results from a continuous gas analyzer are merged with the recorded in-flight information to obtain the vertical distribution of the target trace gases mole fractions.

In context of the Goethe-University data processing procedure, an instantaneous pressure equilibrium is assumed across the whole AirCore. Since the amount of collected air sample is especially low at high altitudes, the assumptions made for data processing affect the accuracy of the altitude attribution primarily in the stratosphere. In order to evaluate the sample-to-altitude attribution procedure, the setup for an altitude dependent CO-spiking experiment was developed, tested and deployed to an AirCore that was flown and analyzed in Traînou, France, in June 2019. This setup allows for releasing small spikes of high CO signal gas in the inlet of the AirCore during descent at predefined GPS altitudes. By assigning the associated mole fraction measurements to the sampling altitude, the spiking signals are assigned to a modelled altitude as well. The quality of the altitude retrieval can be evaluated by comparing the assigned signal altitudes to the GPS release altitudes. In principle, every laboratory can deploy this experiment to its respective AirCores in order to evaluate its altitude attribution quality. Here we present the experimental details and the results of the evaluation to show the accuracy of the altitude registration of Goethe-University AirCore profiles. In addition, the long-term time series of mid-latitude stratospheric mean age observations from Engel et al 2017 is extended with mean age calculated from CO2-profiles obtained from recent AirCore observations.

How to cite: Wagenhäuser, T., Engel, A., Sitals, R., and Kistner, I.: Mean Age from in situ observations with AirCore: Accuracy of altitude attribution investigated with the CO-spiking experiment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19192, https://doi.org/10.5194/egusphere-egu2020-19192, 2020.

EGU2020-9596 | Displays | AS3.5

Development of a Fast Solar Tracker Enabling Atmospheric Direct Sun Remote Sensing Applications on Different Moving Platforms

Ralph Kleinschek, Julian Kostinek, Philip Holzbeck, Marvin Knapp, Andreas Luther, Frank Hase, and André Butz

Spectroscopic direct sun remote sensing of the atmosphere offers an essential tool for the validation of models and satellite observations as well as for the monitoring of emissions. Validation missions for greenhouse gas monitoring satellites are essential to improve the performances of the satellite products, thereby gaining a better understanding of the dynamics between sources and sinks. Furthermore, the monitoring of ozone-depleting substances is a vital contribution to observe the progress in restoring the ozone layer. A high tracking precision is in particular for measuring CO2 and CH4 columns required. We aim for an accuracy better than 0.05°.

This work presents the development of a compact and reliable stand-alone sun tracker for mobile applications. The tracking is camera-based and has two modes. In the first mode, image processing using the image of a fish-eye lens with a field of view of 185° monitoring the entire hemisphere above the instrument calculates the coarse position of the sun. On reaching this coarse position, the other camera-based tracking system takes over and centers the projection of the sun with high precision and fast response times (100 Hz control loop). The tracker is compatible with different kinds of spectrometers like grating spectrometers and Fourier transform infrared spectrometers (FTIR). The tracking is also suitable for different mobile platforms like cars, ships, or stratospheric balloons. 

During the CoMet (Carbon Dioxide and Methane Misson 2018) campaign, the tracking has performed well in a stop and go manner on a car-mounted setup. On every stop, the tracker was able to autonomously find the sun regardless of the relative position of the vehicle. For the MORE-2 (Measuring Ocean REferences 2) campaign onboard a research vessel over the Pacific ocean, the tracking allowed for using over 99 % of the measuring time for high-precision retrievals of CO2 and CH4 using an EM27/SUN FTIR. Based on the lessons learned during the performed campaigns, a further improved version of the tracker for flying on a stratospheric balloon in August 2020 is in development. 

How to cite: Kleinschek, R., Kostinek, J., Holzbeck, P., Knapp, M., Luther, A., Hase, F., and Butz, A.: Development of a Fast Solar Tracker Enabling Atmospheric Direct Sun Remote Sensing Applications on Different Moving Platforms, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9596, https://doi.org/10.5194/egusphere-egu2020-9596, 2020.

EGU2020-22092 | Displays | AS3.5

NDACC Lidar Validation Activities in Europe

Robin Wing, Wolfgang Steinbrecht, Sophie Godin-Beekmann, Thomas J. McGee, John Sullivan, Grant Sumnicht, Gérard Ancellet, Alain Hauchecorne, Sergey Khaykin, and Philippe Keckhut

Recent intercomparison exercises have been conducted at two European NDACC lidar sites.  The mobile NASA Stratospheric Ozone Lidar (NASA STROZ) was present for a two part validation campaign at the Observatoire de Haute-Provence (43.93 N, 5.71 E) in July 2017 and March 2018 and at the Hohenpeißenberg Meteorological Observatory (47.80 N, 11.00 E) in March 2019.  Lidar profiles of ozone and temperature were compared with local radiosondes and ozonesondes; satellite profiles from local overpasses of Sounding of the Atmosphere by Broadband Emission Radiometry instrument (SABER) and Microwave Limb Sounder (MLS); and NCEP reanalysis. There is overall good agreement between all the lidar instruments and the balloon measurements, particularly in the reproduction of small scale features, during all three phases of the European campaign.  

We have conducted a detailed correlational study of all instruments involved in the campaign and have rigorously evaluated the uncertainty budget of each instrument.  We will discuss the strengths and drawbacks of different statistical techniques for evaluating coincident ozone and temperature measurements and compare how our estimates of instrument uncertainty compare to the observed variance in the data.

How to cite: Wing, R., Steinbrecht, W., Godin-Beekmann, S., McGee, T. J., Sullivan, J., Sumnicht, G., Ancellet, G., Hauchecorne, A., Khaykin, S., and Keckhut, P.: NDACC Lidar Validation Activities in Europe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22092, https://doi.org/10.5194/egusphere-egu2020-22092, 2020.

AS3.7 – Natural Aerosols in Climate Change

EGU2020-1893 | Displays | AS3.7

Test of Dust Emission Over the Middle East

Mokhammad Suleiman Mostamandi, Georgiy Stenchikov, Alexander Ukhov, Illia Shevchenko, Johann Engelbrecht, Yasser Alshehri, and Anatolii Anisimov

Abstract

The dust emission simulated within the up-to-date global and regional models differs by almost an order of magnitude. The models are tuned to reproduce the observed aerosol optical depth (AOD) that, with some caveats, reflects the dust mass retained in the atmosphere. However, the amount of dust suspended in the atmosphere is controlled independently by the dust emission and deposition; therefore, only AOD observations are insufficient to constrain both these processes. To calculate the dust emission over the Middle East (ME), in this study, we employ dust deposition observations, AERONET AOD, micro-pulse lidar, and satellite observations to constrain the WRF-Chem simulations. The dust deposition is measured on a monthly bases for 2015-2019 using passive samplers over six sites over land and the sea. We compare the WRF-Chem simulations, conducted with 10-km grid spacing, with the recent MERRA-2 and CAMS reanalysis. WRF-Chem is configured with the GOCART dust scheme. We calculate the meteorological and aerosol initial and boundary conditions using the MERRA-2 reanalysis. 

We evaluated the dust regional mass balance controlled by emission, deposition, and cross-boundary transport. The smallest dust particles are transported at vast distances while the heaviest ones deposit inside of the domain. Since the model accounts for dust particles with radii<10 um, we process the deposition samples to extract the weight of particles smaller than 10 um. WRF-Chem was tuned to reproduce the observed AOD and monthly deposition of dust particles with radii < 10 um. We found that the ME dust emission comprises about 30% of the global annual dust emission. MERRA-2 underestimates the ME dust emission by about 15%.

How to cite: Mostamandi, M. S., Stenchikov, G., Ukhov, A., Shevchenko, I., Engelbrecht, J., Alshehri, Y., and Anisimov, A.: Test of Dust Emission Over the Middle East, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1893, https://doi.org/10.5194/egusphere-egu2020-1893, 2020.

EGU2020-4763 | Displays | AS3.7

The influence of volcano activity on aerosol formation over the Andes

Federico Bianchi, Diego Aliaga, Qiaozhi Zha, Liine Heikkinen, Marcos Andrade, Markku Kulmala, and Claudia Mohr

A significant fraction (>50%) of cloud condensation nuclei (CCN) in the atmosphere arises from new particle formation (Dunne et al., 2016). While particle nucleation has been observed almost everywhere in the atmosphere, the mechanisms governing this process are still poorly understood and subject of on-going research. For example, it is still largely unknown which components participate in new-particle formation. Laboratory experiments and quantum chemical calculations have identified potential candidates that may play a role, including sulphuric acid, ions, ammonia, amines and highly oxygenated organic molecules (Kirkby et al., 2011; Almeida et al., 2013; Bianchi et al., 2016; Bianchi et al., 2019).

Here we present observations of the formation and growth of newly formed particles measured during intense volcano activities.

The measurements were conducted at Chacaltaya mountain station (5240 m a.s.l.) in Bolivia. The station is located on top of the Cordillera Real. It has air masses coming from the Amazon forest, La Paz and the Bolivian altiplano.

With the Chemical Ionization Atmospheric Pressure interface Time-Of-Light mass spectrometers (CI-APi-TOF) we measured H2SO4, the APi-TOF retrieved the chemical composition of positive and negative ions. Ion and particle size distributions were measured with the NAIS (Neutral cluster and Air Ion Spectrometer) and the SMPS (Scanning Mobility Particle Sizer), respectively. The PSM (Particle Sizer Magnifier) measured particles with a cut off that varied from 1-4 nm. Finally, with the ACSM (Aerosol Chemical Speciation Monitor) and the FIGAERO (Filter Inlet for Gases and AEROsols) we retrieved the aerosol chemical composition. Besides this set of instruments, other parameters were measured at the Chacaltaya GAW station.

During the intensive measurement campaign, air masses coming directly from volcano eruptions were detected by all our instruments. We were therefore able to determine the gas and particle chemical composition of the air mass. In addition to that, we observed several NPF events triggered by air masses coming from volcanic emissions. With this set of instruments, we were able to retrieve the chemical composition of the vapours leading to the formation of new particles. It was found that all the nucleation event observed during the volcano activity were triggered by sulphuric acid and ammonia. In the presentation we will show more details on the chemical and physical mechanism behind this process.

 

Almeida, J., et al., (2013) Nature 502, 359-363.

Bianchi, F., et al., (2016) Science 6289, 1109-1112.

Bianchi, F., et al., (2019) Chemical Review 119, 3472−3509

Dunne et al., (2016) Science 354, 1119-1124.

Kirkby, J., et al., (2011) Nature 476, (7361), 429-433.

How to cite: Bianchi, F., Aliaga, D., Zha, Q., Heikkinen, L., Andrade, M., Kulmala, M., and Mohr, C.: The influence of volcano activity on aerosol formation over the Andes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4763, https://doi.org/10.5194/egusphere-egu2020-4763, 2020.

EGU2020-5722 | Displays | AS3.7

Coarse and giant particles are ubiquitous in Saharan dust export regions and are radiatively significant over the Sahara

Claire Ryder, Eleanor Highwood, Adrian Walser, Petra Walser, Anne Philipp, and Bernadett Weinzierl

Mineral dust is an important component of the climate system, interacting with radiation, clouds, and biogeochemical systems and impacting atmospheric circulation, air quality, aviation, and solar energy generation. These impacts are sensitive to dust particle size distribution (PSD), yet models struggle or even fail to represent coarse (diameter (d>2.5µm) and giant (d>20µm) dust particles and the evolution of the PSD with transport. Here we examine three state-of-the-art airborne observational datasets, all of which measured the full size range of dust (d=0.1 to >100µm) at different stages during transport with consistent instrumentation. We quantify the presence and evolution of coarse and giant particles and their contribution to optical properties using airborne observations over the Sahara (from the Fennec field campaign) and in the Saharan Air Layer (SAL) over the tropical eastern Atlantic (from the AER-D field campaign).

Observations show significantly more abundant coarse and giant dust particles over the Sahara compared to the SAL: effective diameters of up to 20 µm were observed over the Sahara compared to 4 µm in the SAL. Excluding giant particles over the Sahara results in significant underestimation of mass concentration (40 %), as well as underestimates of both shortwave and longwave extinction (18 % and 26 %, respectively, from scattering calculations), while the effects in the SAL are smaller but non-negligible. The larger impact on longwave extinction compared to shortwave implies a bias towards a radiative cooling effect in dust models, which typically exclude giant particles and underestimate coarse-mode concentrations.

A compilation of the new and published effective diameters against dust age since uplift time suggests that two regimes of dust transport exist. During the initial 1.5 d, both coarse and giant particles are rapidly deposited. During the subsequent 1.5 to 10 d, PSD barely changes with transport, and the coarse mode is retained to a much greater degree than expected from estimates of gravitational sedimentation alone. The reasons for this are unclear and warrant further investigation in order to improve dust transport schemes and the associated radiative effects of coarse and giant particles in models.

This work has been recently published in ACP (Ryder, C. L., Highwood, E. J., Walser, A., Seibert, P., Philipp, A., and Weinzierl, B.: Coarse and giant particles are ubiquitous in Saharan dust export regions and are radiatively significant over the Sahara, Atmos. Chem. Phys., 19, 15353–15376, https://doi.org/10.5194/acp-19-15353-2019, 2019).

How to cite: Ryder, C., Highwood, E., Walser, A., Walser, P., Philipp, A., and Weinzierl, B.: Coarse and giant particles are ubiquitous in Saharan dust export regions and are radiatively significant over the Sahara, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5722, https://doi.org/10.5194/egusphere-egu2020-5722, 2020.

EGU2020-5796 | Displays | AS3.7

Finding linkages between ocean ecosystems and natural marine aerosols in the minimally polluted North Atlantic atmosphere

Patricia Quinn, Tim Bates, Eric Saltzman, Tom Bell, and Mike Behrenfeld

The emission of sea spray aerosol (SSA) and dimethylsulfide (DMS) from the ocean results in marine boundary layer aerosol particles that can impact Earth’s radiation balance by directly scattering solar radiation and by acting as cloud condensation nuclei (CCN), thereby altering cloud properties. The surface ocean is projected to warm by 1.3 to 2.8°C globally over the 21st century. Impacts of this warming on plankton blooms, ocean ecosystems, and ocean-to-atmosphere fluxes of aerosols and their precursor gases are highly uncertain. A fundamental understanding of linkages between surface ocean ecosystems and ocean-derived aerosols is required to address this uncertainty. One approach for improved understandings of these linkages is simultaneous measurements of relevant surface ocean and aerosol properties in an ocean region with seasonally varying plankton blooms and a minimally polluted overlying atmosphere. The western North Atlantic hosts the largest annual phytoplankton bloom in the global ocean with a large spatial and seasonal variability in plankton biomass and composition. Periods of low aerosol number concentrations associated with unpolluted air masses allow for the detection of linkages between ocean ecosystems and ocean-derived aerosol.

 

Five experiments were conducted in the western North Atlantic between 2014 and 2018 with the objective of finding links between the bloom and marine aerosols. These experiments include the second Western Atlantic Climate Study (WACS-2) and four North Atlantic Aerosol and Marine Ecosystem Study (NAAMES) cruises. This series of cruises was the first time the western North Atlantic bloom was systematically sampled during every season with extensive ocean and atmosphere measurements able to assess how changes in the state of the bloom might impact ocean-derived aerosol properties. Measurements of unheated and heated number size distributions, cloud condensation nuclei (CCN) concentrations, and aerosol composition were used to identify primary and secondary aerosol components that could be related to the state of the bloom. Only periods of clean marine air, as defined by radon, particle number concentration, aerosol light absorption coefficient, and back trajectories, were included in the analysis.

 

CCN concentrations at 0.1% supersaturation were best correlated (r2 = 0.73) with accumulation mode nss SO4=. Sea spray aerosol (SSA) was only correlated with CCN during November when bloom accumulation had not yet occurred and dimethylsulfide (DMS) concentrations were at a minimum. The fraction of CCN attributable to SSA was less than 20% during March, May/June, and September, indicating the limited contribution of SSA to the CCN population of the western North Atlantic atmosphere. The strongest link between the plankton bloom and aerosol and cloud properties appears to be due to biogenic non-seasalt SO4=.

 

How to cite: Quinn, P., Bates, T., Saltzman, E., Bell, T., and Behrenfeld, M.: Finding linkages between ocean ecosystems and natural marine aerosols in the minimally polluted North Atlantic atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5796, https://doi.org/10.5194/egusphere-egu2020-5796, 2020.

EGU2020-5976 | Displays | AS3.7

The sensitivity of Southern Ocean aerosol concentrations to sea spray and DMS emissions in the HadGEM3-GA7.1 chemistry–climate model

Laura Revell, Stefanie Kremser, Sean Hartery, Mike Harvey, Jane Mulcahy, Jonny Williams, Olaf Morgenstern, Adrian McDonald, Vidya Varma, Leroy Bird, and Alex Schuddeboom

With low concentrations of tropospheric aerosol, the Southern Ocean offers a "natural laboratory" for studies of aerosol–cloud interactions. Aerosols over the Southern Ocean are produced from biogenic activity in the ocean, which generates sulfate aerosol via dimethylsulfide (DMS) oxidation, and from strong winds and waves that lead to bubble bursting and sea spray emission. Here, we evaluate the representation of Southern Ocean aerosols in the Hadley Centre Global Environmental Model version 3, Global Atmosphere 7.1 (HadGEM3-GA7.1) chemistry–climate model. Compared with aerosol optical depth (AOD) observations from two satellite instruments (the Moderate Resolution Imaging Spectroradiometer, MODIS-Aqua c6.1, and the Multi-angle Imaging Spectroradiometer, MISR), the model simulates too-high AOD during winter and too-low AOD during summer. By switching off DMS emission in the model, we show that sea spray aerosol is the dominant contributor to AOD during winter. In turn, the simulated sea spray aerosol flux depends on near-surface wind speed. By examining MODIS AOD as a function of wind speed from the ERA-Interim reanalysis and comparing it with the model, we show that the sea spray aerosol source function in HadGEM3-GA7.1 overestimates the wind speed dependency. We test a recently developed sea spray aerosol source function derived from measurements made on a Southern Ocean research voyage in 2018. In this source function, the wind speed dependency of the sea spray aerosol flux is less than in the formulation currently implemented in HadGEM3-GA7.1. The new source function leads to good agreement between simulated and observed wintertime AODs over the Southern Ocean; however, it reveals partially compensating errors in DMS-derived AOD. While previous work has tested assumptions regarding the seawater climatology or sea–air flux of DMS, we test the sensitivity of simulated AOD, cloud condensation nuclei and cloud droplet number concentration to three atmospheric sulfate chemistry schemes. The first scheme adds DMS oxidation by halogens and the other two test a recently developed sulfate chemistry scheme for the marine troposphere; one tests gas-phase chemistry only, while the second adds extra aqueous-phase sulfate reactions. We show how simulated sulfur dioxide and sulfuric acid profiles over the Southern Ocean change as a result and how the number concentration and particle size of the soluble Aitken, accumulation and coarse aerosol modes are affected. The new DMS chemistry scheme leads to a 20% increase in the number concentration of cloud condensation nuclei and cloud droplets, which improves agreement with observations. Our results highlight the importance of atmospheric chemistry for simulating aerosols and clouds accurately over the Southern Ocean.

How to cite: Revell, L., Kremser, S., Hartery, S., Harvey, M., Mulcahy, J., Williams, J., Morgenstern, O., McDonald, A., Varma, V., Bird, L., and Schuddeboom, A.: The sensitivity of Southern Ocean aerosol concentrations to sea spray and DMS emissions in the HadGEM3-GA7.1 chemistry–climate model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5976, https://doi.org/10.5194/egusphere-egu2020-5976, 2020.

EGU2020-9236 | Displays | AS3.7

Properties and challenges of mineral dust aerosol modelling in the latest Earth System Models

Ramiro Checa-Garcia, Yves Balkanski, Tommi Bergman, Ken Carslaw, Mohit Dalvi, Beatrice Marticorena, Martine Michou, Pierre Nabat, Lars Nieradzik, Twan van Noije, Declan O’Donnell, Dirk Olivie, Fiona O'Connor, Michael Schulz, and Catherine Scott

Mineral dust aerosols participate in the climate system and biogeochemistry processes due to its interactions with key components of Earth Systems: radiation, clouds, soil and chemical components. A central element to improve our understanding of mineral dust is through its modeling with Earth Systems Models where all these interactions are included. However, current simulations of dust variability exhibit important uncertainties and biases, which are model-dependent, whose cause is our imperfect knowledge about how to best represent the dust life cycle. For these reasons a continuous evaluation of the performance and properties of the different models compared against measurements is a crucial step to improve our knowledge of the dust cycle and its role in the climate system and biogeochemical cycles. Here we present an exhaustive evaluation of mineral dust aerosols in CRESCEND-ESMs over global, regional and local scales. We compare models against three networks of instruments for total dust deposition flux, yearly surface concentrations, and optical depths. Global and regional dust optical depths are compared with MODIS and MISR derived products. Specific analyses are done over the Sahel region where improved and compressive dust observational datasets are available. The results indicate that all the models capture the general properties of the global dust cycle, although the role of larger particles remains challenging. Differences are partially due to surface winds as nudged simulations improve the inter-model comparison and the performance in optical depth compared to MODIS. At the regional scale, there is an optical depth reasonable agreement over main source areas, but a joint inter-comparison including fluxes and concentration indicates larger differences. At the local scale, the uncertainties increase and current models are not able to reproduce together several observables at the same time.

How to cite: Checa-Garcia, R., Balkanski, Y., Bergman, T., Carslaw, K., Dalvi, M., Marticorena, B., Michou, M., Nabat, P., Nieradzik, L., Noije, T. V., O’Donnell, D., Olivie, D., O'Connor, F., Schulz, M., and Scott, C.: Properties and challenges of mineral dust aerosol modelling in the latest Earth System Models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9236, https://doi.org/10.5194/egusphere-egu2020-9236, 2020.

EGU2020-11662 | Displays | AS3.7

Composition and Properties of the Natural Aerosol over the Boreal and Tropical Forests

Hans-Christen Hansson, Paulo Artaxo, Meinrat Andreae, and Markku Kulmala

We, together with 50 of our colleagues present a review on the interaction between tropical and boreal forests and the atmosphere, especially addressing their influence in the climate system. With its emissions of VOCs, aerosols and trace gases, with strong atmosphere interactions, forests are a key component of the climate system. These emissions and atmospheric processing regulates atmospheric chemistry and are the major source of cloud condensation nuclei (CCN) affecting cloud formation and development, and thus temperature and precipitation. Emissions from forests are thus closely connected to the hydrological and the carbon cycles, being  an essential integrated part of the climate system.

In terms of meteorology, tropical and boreal forests are very different. Temperature, solar radiation, precipitation, evapotranspiration, albedo, cloud structure and cover, convection etc., are all very different. However, the aerosols in the two systems show similarities as Primary Biological Aerosol Particles are the major component (70%) of coarse mode particles in Amazonia while Secondary Organic Aerosol in the tropics are mainly isoprene driven giving a slightly more hygroscopic SOA than the boreal monoterpene driven SOA. The organics constitutes 70 to 85% of PM1 mass for both boreal and tropical forests. In Amazonia, sulfates, nitrates and BC shows very low concentrations, while the boreal sites shows 2-3 times higher concentrations. The Siberian continental site and Amazonian site show remarkable similarities in the lack of new particle formation (NPF) which will be  discussed.

In the tropics dry season and boreal spring and early summer, increasing biomass burning emissions in both forest types dominates the aerosol composition, with high OC and BC concentrations while anthropogenic pollution influences boreal forest atmospheric composition during wintertime. The changes in diffuse to direct radiation due to scattering aerosols has important effects in tropical forests but minor in boreal, enhancing the net ecosystem exchange by 30% and 10% respectively. Thus the natural forest emissions affects the direct as well as the indirect forcing.

An Amazonia high altitude NPF process chain was recently observed at the top of the troposphere, and is an interesting interaction between forest emissions, cloud transport and processing and particle formation and aging at high altitudes that are brought back to the boundary layer, populating the CCN. For boreal forests, the complex relationship between GPP, BVOC, SOA, CCN, clouds, radiation, temperature and CO2 show multiple pathways and feedbacks, and some of them can be quantified. All showing the complexity of the interaction between forests, atmosphere and climate.

How to cite: Hansson, H.-C., Artaxo, P., Andreae, M., and Kulmala, M.: Composition and Properties of the Natural Aerosol over the Boreal and Tropical Forests, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11662, https://doi.org/10.5194/egusphere-egu2020-11662, 2020.

EGU2020-13495 | Displays | AS3.7 | Highlight

The effect of dust absorption on Sahel precipitation

Yves Balkanski

Absorption of shortwave radiation by dust depends on its iron oxide content. Iron oxides amount to just a few percents of dust mineralogy. In the Sahel, the amount of iron oxide in soils is significantly greater than over the rest of North Africa. Recent measurements from the AER-D campaign have evidenced the presence of large dust particles over Northern African sources, which measurements showed absorb higher shortwave radiation than smaller ones.

I present two 100-years simulations of the earth system model IPSLCM6, one with a detailed description of dust and one without dust. Over the summer months (JJAS), dust absorption amounts to 25 W.m-2 over the region. The changes caused by this absorption to the water budget are analyzed. Dust absorption causes an increase of 16% of summer Western Sahel precipitation, whereas in the Eastern Sahel, summer precipitation is increased by 7%. The analysis is extended to evaporation, surface relative humidity, low-level clouds and total cloud liquid water path, all of which show a significant increase caused by absorbing dust.

The water budget over the Sahel is computed over an airshed that covers the region, 16W:36E and 10N:20N from the surface to 200mb, contrasting the water flux with and without aerosol absorption. Dust absorption causes a change in the mean circulation between 1000 and 800mb that induces an increased inflow of moist air at these levels at the western and southern Sahel boundaries during the summer monsoon.  Hence, it is important to understand the influence of aerosol absorption when studying the causes of variations in Sahel precipitation.

How to cite: Balkanski, Y.: The effect of dust absorption on Sahel precipitation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13495, https://doi.org/10.5194/egusphere-egu2020-13495, 2020.

EGU2020-17620 | Displays | AS3.7

Cluster analysis of organic molecules in an alpine ice core: the transition from the pre-industrial to the industrial era

Franziska Bachmeier, Alexander L. Vogel, Anja Lauer, Ling Fang, Katarzyna Arturi, Urs Baltensperger, Saša Bjelić, Imad El Haddad, and Margit Schwikowski

The effects of atmospheric aerosol particles on the Earth’s radiative balance are a major source of uncertainty in global climate models. A distinction and quantification between natural and anthropogenic atmospheric aerosol concentration and their sources has to be made to reduce this uncertainty. Therefore, the natural pre-industrial aerosol concentration of the atmosphere must be determined. Ice cores are climate archives that enable the reconstruction of past atmospheric composition changes.

For such a reconstruction, an ice core from the Swiss Alps, which covers the years from 1682-1985, was examined for secondary organic aerosol (SOA) compounds. A non-target analysis (NTA) was used to determine the chemical composition of small organic molecules in the ice. The analytical method of the melted ice samples is based on solid-phase extraction, liquid chromatography and high-resolution mass spectrometry. The result of the NTA showed more than 630 features statistically different from the blank. A hierarchical cluster analysis was performed, in which compounds with a similar trend over time were grouped (clustered) together. The cluster analysis separated the considered features into two main groups. The first cluster showed a good correlation with the dissolved organic carbon concentration (DOC) of non-fossil origin (R = 0.75) while the second main group correlated excellently with the fossil DOC (R = 0.95), attributed based on the radiocarbon content. This leads to the presumption that compounds represented in the first cluster originated from biogenic sources while compounds in the second cluster are anthropogenic emissions or SOA formed by anthropogenically emitted precursors. This hypothesis is supported by the temporal trend of the two groups. The potential biogenic compounds show a relative stable behavior throughout time.  At the beginning of the 20th century a decrease of biogenic SOA is recorded. No compounds from the anthropogenic cluster were detected in pre-industrial times, they increase slowly from 1800 and more and more from 1900. Based on the division into the two main clusters, a detailed graphical evaluation of their chemical composition was performed. We show that the suspected biogenic cluster consists mainly of oxidation products of volatile organic compounds (VOC). The presumed anthropogenic cluster consists mainly of organosulfates, nitrooxy-organosulfate, aromatic compounds and mono- and dinitroaromatics.

How to cite: Bachmeier, F., Vogel, A. L., Lauer, A., Fang, L., Arturi, K., Baltensperger, U., Bjelić, S., El Haddad, I., and Schwikowski, M.: Cluster analysis of organic molecules in an alpine ice core: the transition from the pre-industrial to the industrial era, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17620, https://doi.org/10.5194/egusphere-egu2020-17620, 2020.

EGU2020-19556 | Displays | AS3.7

Lagrangian evaluation of marine aerosols sources in an Earth System Model.

Emanuele Tovazzi, Daniel Partridge, Jim Haywood, Alistair Sellar, Dalvi Mohit, and Paul Kim

Increasing the current understanding of how the Earth will respond to a warming climate requires a more accurate representation of aerosols by Earth system models (ESMs). Reducing current uncertainties associated with model estimates of climate change sensitivity to greenhouse gas emissions is hampered by our understanding of the impact aerosol particles have on the radiative budget via their interactions with clouds. The complexity of such interactions leads to their imperfect representation in models.

Emissions of marine organic aerosols play a relevant role on cloud formation in regions where there is a high concentration of phytoplankton, for example in the Southern Ocean (SO). Comparisons between GCMs and satellite observations over the SO show that the models simulate too little reflection of shortwave radiation and this is strongly linked with modelled cloud properties. A potential cause of this issue is a source of missing aerosols in the ESM.

In this study we evaluate the ability of a state-of-the-art ESM, UKESM1, in reproducing aerosol particles originating from organic marine sources that reach a measurement station in pristine air through long-range transport. UKESM1 is developed by the Met. Office and our simulation is nudged by reanalysis datasets for a fair comparison with observations. This ESM is unique in using its ocean biogeochemistry module to interactively simulate the emission of marine organic aerosols. To this end, a novel Lagrangian trajectory framework for evaluating GCMs has been developed. This method makes use of satellite measurements of chlorophyll concentration (a proxy of phytoplankton abundance in the sea surface) at the sea surface, together with the cloud condensation nuclei (CCN) concentration at 0.5% of supersaturation measured at Cape Grim (Southern Ocean, Tasmania) station. Chlorophyll and wind speed data are collocated along air mass trajectories, which are calculated through the HYSPLIT model. A source-receptor analysis is then performed to look for potential spatial correlation between the collocated chlorophyll concentration experienced by air parcel paths coming from a defined clean air sector of the boundary layer (to avoid anthropogenic influences) and CCN measurements. Additionally, a temporal correlation analysis is performed in this framework. This method is applied to both UKESM1 output data and observations to evaluate aerosol processes in climate models.

Preliminary results show a positive correlation in model data between marine organic activity and CCN production that is found also in the observations. Despite the model well representing the seasonal variability of CCN at the station, the model struggles to reproduce the positive relationship obtained from the observations between wind speed and CCN concentration during the winter season. This can be attributed to a potential missing source in the model.

How to cite: Tovazzi, E., Partridge, D., Haywood, J., Sellar, A., Mohit, D., and Kim, P.: Lagrangian evaluation of marine aerosols sources in an Earth System Model., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19556, https://doi.org/10.5194/egusphere-egu2020-19556, 2020.

EGU2020-20321 | Displays | AS3.7

Provenance of the Saharan winter dust plume and its response to climatic variability over the last 200 kyr

Amy Jewell, Will Burton, Tereza Kunkelova, Anya Crocker, Ursula Röhl, Matthew Cooper, Rachael James, Chuang Xuan, Alistair Pike, Natalie Bakker, Charlie Bristow, Nick Drake, and Paul Wilson

North Africa is very likely to warm over the coming century, but there is fundamental disagreement among climate model projections over the predicted response of rainfall to that warming. Geological records of wind-blown dust accumulating in marine sediment cores in the North Atlantic Ocean provide a way to assess the response of rainfall climate in the region to past intervals of global warmth.

 

Dust is transported to the North Atlantic Ocean from North Africa via two routes, a summer (northern) route and a winter (southern) route. Virtually everything we have learnt so far from marine sediment cores about North African hydroclimate has come from drill sites located beneath the summer (northern) dust plume. Here we report (i) geochemical records (radiogenic isotope (87Sr/86Sr and eNd) and XRF core scanning) from Ocean Drilling Project (ODP) Site 662 in the eastern equatorial Atlantic spanning the last 200,000 years and (ii) new 87Sr/86Sr and eNd data from North African dust sources. We redefine existing dust Preferential Source Areas (PSAs) into three geochemically distinct (Western, Central and Eastern) source regions. We show that ODP Site 662 is well-situated to study the palaeo-history of the previously under-studied African winter (southern) dust plume. We find that the primary source of terrigenous material to Site 662 throughout the past 200,000 years is palaeolake Megachad in the Central source region. This palaeolake basin is often described as the largest single dust source on Earth but comparatively little is known on geological timescales about its history. We show that its dust contribution to ODP Site 662 varies on orbital timescales, and that it reaches a minimum during insolation maxima, such as the last African Humid Period, coincident with lake high-stands. Large excursions in radiogenic isotope data reveal extreme variability in the relative strength of aeolian dust and distal riverine sources of terrigenous material, associated with hydroclimate change over the last 200 thousand years.

How to cite: Jewell, A., Burton, W., Kunkelova, T., Crocker, A., Röhl, U., Cooper, M., James, R., Xuan, C., Pike, A., Bakker, N., Bristow, C., Drake, N., and Wilson, P.: Provenance of the Saharan winter dust plume and its response to climatic variability over the last 200 kyr, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20321, https://doi.org/10.5194/egusphere-egu2020-20321, 2020.

EGU2020-21012 | Displays | AS3.7

Chemical composition of summertime High Arctic aerosols using chemical ionization mass spectrometry

Karolina Siegel, Paul Zieger, Matthew Salter, Ilona Riipinen, Annica M.L. Ekman, and Claudia Mohr

Low-level clouds and fogs play a key role in the radiative balance over the Arctic pack ice by regulating surface energy fluxes. The radiative features of clouds are dependent on the amount of airborne aerosol particles and their properties, since the particles can act as CCN (cloud condensation nuclei) and INP (ice nucleating particles). As the Arctic climate is currently warming, the local emissions and formation mechanisms of aerosols are expected to change, possibly leading to altered cloud properties.

We measured aerosol chemical composition using FIGAERO-CIMS (Chemical Ionization Mass Spectrometer coupled to a Filter Inlet for Gases and AEROsols) analysis of samples collected during the MOCCHA campaign (Microbiology-Ocean-Cloud-Coupling in the High Arctic) close to the North Pole in 2018. The goal of the campaign was to investigate natural aerosol emissions from the ocean to the atmosphere during summertime in terms of local sources and potential contribution to cloud formation. The sampling period was therefore around the seasonal sea ice minimum in September. With our CIMS setup, the sample molecules are ionised by iodide ions (I-). The negatively charged adducts are then separated by mass, allowing for characterisation on a molecular level. This is the first time aerosol chemical composition of High Arctic aerosols has been measured using this technique. As the current knowledge about the atmospheric composition in this region is low, our results suggest a potential for using this method for further aerosol chemical characterisation in the pristine Arctic environment.

Our analysis shows that sulphur-containing compounds were most abundant in the aerosol samples, including sulphuric acid, sulphur trioxide, methanesulphonic acid (MSA) and dimethyl sulphoxide (DMSO). MSA and DMSO are oxidation products of dimethyl sulphide (DMS), which is released by marine phytoplankton to the atmosphere under ice-free conditions. Non-sea-salt sulphate (nss-SO42-) aerosols are known to be efficient CCN. The results will be compared to aerosol samples from the NASCENT campaign (Ny-Ålesund Aerosol and Cloud Experiment), analysed using the same CIMS technique. The campaign runs for a year during 2019-2020 at the Zeppelin station in Svalbard. Our findings are expected to contribute to better understanding of the connection between aerosols and cloud formation in the polar regions and the effects on the ocean and pack ice.

How to cite: Siegel, K., Zieger, P., Salter, M., Riipinen, I., Ekman, A. M. L., and Mohr, C.: Chemical composition of summertime High Arctic aerosols using chemical ionization mass spectrometry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21012, https://doi.org/10.5194/egusphere-egu2020-21012, 2020.

EGU2020-22415 | Displays | AS3.7

Is aerosol optical depth a good metric to map dust properties? Lessons learned from AER-D

Franco Marenco, Claire Ryder, Victor Estelles, and Debbie O'Sullivan

The main observable quantity used on a global scale to map aerosols is aerosol optical depth (AOD), from ground-based and satellite remote sensing. It is at the same time an optical property and a vertically integrated quantity, and it is commonly used as the main metric towards which to pull aerosol models, through data assimilation, verification, and tuning. Here we introduce a few reflections on how to better constrain our knowledge of the Saharan Air Layer and its associated mineral dust, following results from the AER-D campaign.

AER-D was a small field experiment in the Eastern Atlantic during August 2015, based on the opportunity given by the simultaneous ICE-D experiment. The purpose of AER-D was to investigate the physical properties of the Saharan Air Layer, and to assess and validate remote sensing and modelling products. The FAAM atmospheric research aircraft was used as a flying laboratory, and it carried a full set of instruments aimed at both in-situ sampling and remote sensing.

A broad distribution of particle sizes was consistently observed, with a significant giant mode up to 80 µm, generally larger than what was observed in previous experiments: we ascribe this to the set of instruments used, able to capture the full spectrum. We will discuss the representation of the particle size in operational models, and we will show that despite predicting an extinction coefficient of the correct order of magnitude, the particle size is generally underestimated. We will also discuss the implication of the giant particles for the ground-based remote sensing of columnar size-distributions from the SKYNET and AERONET networks (Sunphotometer Airborne Validation Experiment, which was a component of AER-D).

We will present the vertical structure of the Saharan Air Layer, and in particular one episode when the structure was very different than the one generally accepted in the conceptual model. Moreover, the comparison with the operational models showed that they can predict a correct aerosol optical depth (AOD, a vertically integrated quantity) despite missing the vertical distribution.

These findings lead to a series of reflections on how to better constrain our knowledge of the Saharan Air Layer and its representation in operational models. Size-resolved properties and the vertical distribution are essential companions of the global AOD observations commonly used operationally. We will also discuss objectives and ideas for future field experiments.

How to cite: Marenco, F., Ryder, C., Estelles, V., and O'Sullivan, D.: Is aerosol optical depth a good metric to map dust properties? Lessons learned from AER-D, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22415, https://doi.org/10.5194/egusphere-egu2020-22415, 2020.

AS3.8 – Aeolian dust: initiator, player, and recorder of environmental change

Mineral dust accumulation is often causally associated with aridity, with higher dust deposition rates are assumed to reflect increasing magnitude of aridity. However, the relation between dust deposition and aridity is not straightforward; grain sizes play a crucial role in processes associated with mineral dust generation, transportation and deposition in sedimentary settings.

In this study, we apply grain-size analyses in six well-studied cores (spanning the late Holocene) previously collected from alpine lake sites distributed across the arid and semi-arid regions of west, southwest, and the Great Plains of North America. Previous work with these cores has demonstrated that the lake sediments are predominantly detrital, windblown particles and little to no impact of fluvial proceeses . We find that the most commonly occurring grain sizes are a fine fraction (typically <4 microns, which is easily lofted and transported long distances) and a coarse fraction (typically >25 microns and in some cases with a distinct peak at 100 microns, both of which are are too large to be carried long distances and suggest short distance transportation). We used grain size separation techniques to separate the two size fractions and geochemically fingerprinted those from three sites.

We find that more rapid accumulation of the coarser coarser-grain size fractions occurred during wetter intervals in the Holocene. Furthermore, the geochemistry of the coarse fractions indicates regional rather than local sourcing of the material from bedrock weathering. We do not find any clear relationships between the fine fraction and aridity patterns, nor a clear source region for this material.

We hypothesize that the increase in coarser dust deposition during wetter intervals is related to either intensification of land-use patterns associated with agriculture and/or to episodically strong winds. Warmer and wetter intervals in the areas under consideration have been associated with intensified cyclogenesis. Our study demonstrates the critical need to incorporate grain-size analysis as well as geochemical fingerprinting of the different size fractions in interpreting mineral dust record.

 

Acknowledgement: James Sickman, Jason Neff (for sharing samples), Jacob Ashford, Tyler Vollmer, Audriana Pollen, Alejandra Pedrazza, (for assistance with analyses and archival visits), John Morton, Wendy Freeman (for assisting students in the laboratory), Aradhna Tripati and Juan Lora (for assisting with data interpretation).

 

How to cite: Bhattacharya, A., Bennett, A., Marchitto, T., and Leithold, E.: Coarse-grained mineral dust deposition in alpine lakes provide evidence of increased windspeeds associated with more intense cyclogenesis during warmer intervals of the late Holocene period in arid and semi-arid tracts of North America., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-190, https://doi.org/10.5194/egusphere-egu2020-190, 2020.

A three-month experiment (June-August 2019) had been carried out on the undulating terrain of the Taklimakan Desert. The mass concentration characteristics of PM2.5 and PM10 at different locations of the sand ridge were obtained, studying the correlation between dust aerosol mass concentration and meteorological factors under different weather conditions. The results show that: (1) There are differences about the concentration of PM2.5 and PM10 in different locations of sand ridges under different typical weather conditions. The average mass concentration of PM2.5 on sunny days meets: West Low Site > East Low Site > High Site, According to the dynamic  characteristic of PM10, peak-valley value of the three stations fluctuated sharply, and the daily average value of mass concentration shows: High Site > East Low Site > West Low Site. When the sand blowing and floating weather occurred, the variation of PM2.5 mass concentration meet the following rule: East Low Site > High Site, PM10 shows the opposite law. When the first sandstorm occurs, the PM2.5 mass concentration satisfies the following Law: West Low Site 10 mass concentration change is generally expressed as: West Low Site 2.5 and PM10 meets: West Low Site> High Site> East Low Site (2) Sunny Temperature、 Atmospheric Pressure, Relative Humidity of east low site, high site have a close correlation with PM2.5, PM10 Mass Concentrations, the wind speed of the west low site and the high site was significantly correlated with the PM2.5 and PM10 mass concentrations. When the dusty weather occurs, the wind speed has a significant effect on the mass concentration of dust aerosol in the high site, and there is a significant positive correlation between the atmospheric pressure and the aerosol mass concentration in the east low site or high site. During the sand-dust weather , the PM2.5 and PM10 mass concentrations were significantly negatively correlated with the atmospheric pressure in the high sand dunes, the correlation between wind speed and the PM2.5 and PM10 mass concentrations was greater than the East low Site. During the sandstorm, atmospheric pressure and temperature have a significant effect on the mass concentration of PM2.5 and PM10.

How to cite: He, Q. and Zhao, Q.: Analysis on mass concentration of dust aerosols in rough terrains of the Taklimakan Desert Hinterland, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1512, https://doi.org/10.5194/egusphere-egu2020-1512, 2020.

EGU2020-9181 | Displays | AS3.8

Relative importance of three climate factors on dust emissions over North Africa

Lamei Shi, Jiahua Zhang, Fengmei Yao, and Da Zhang

The breakdown of nocturnal low-level jets (NLLJs), West African heat low (WAHL), and Harmattan Surges (HS) have been proved to be important meteorological drivers of the seasonal variation of dust emissions over North Africa. This study further investigated their relative contributions to the interannual variation of dust emissions from 1980 to 2018. Dust emissions from the Modern-Era Retrospective Analysis for Research and Applications, version 2 (MERRA-2), precipitation data from TerraClimate, and wind speed, temperature, and geopotential from the European Centre for Medium-Range Weather Forecasts (ECMWF) were used to examine the roles of precipitation and wind speed in the dust emission trend as well as the spatiotemporal characteristics of the contributions of those three meteorological factors to the interannual variation of dust emissions. Results indicated that the dust emissions over Sahel and the southern coast of Mediterranean were more sensitive to precipitation rather than wind speed, while areas that were not influenced by rainfall were highly correlated with the cube of the wind speed at 10 m above surface with p < 0.001. The regional difference in the contribution of the three meteorological factors was significant. HS was the main contributor for dust emissions over the northern North Africa primarily in winter and spring. NLLJs primarily controlled the southern part (south of 20°N) in almost all seasons especially in winter and spring, while they contributed more to dust emissions north of 20° N from June to August. The contribution of WAHL started from the south of the Hoggar-Tibesti channel and the lee of Ethiopian Highlands in winter, then it moved northwestward in spring and reached their strongest states in summer.

How to cite: Shi, L., Zhang, J., Yao, F., and Zhang, D.: Relative importance of three climate factors on dust emissions over North Africa, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9181, https://doi.org/10.5194/egusphere-egu2020-9181, 2020.

EGU2020-18441 | Displays | AS3.8

The role of Southern Africa as a dust precursor to East Antarctica

Stefania Gili, Aubry Vanderstraeten, Mathieu Cazaunau, Amelie Chaput, Jean-Francois Doussin, Claudia Di Biagio, Paola Formenti, James Stephen King, Alexander Magnold, Nadine Mattielli, Edouard Pangui, Preben Van Overmeiren, and Christophe Walgraeve

Identifying the provenance of mineral dust depositions in Antarctica is crucial to reconstruct Southern Hemisphere (SH) atmospheric circulation, validate numerical models, evaluate their contribution as micronutrients in the Southern Ocean and assess their control on the climate changes. For the last few decades, it has been demonstrated Southern South America (SSA) is the main precursor of dust reaching Antarctica during both ice ages and interglacial periods (e.g. Gili et al., 2017, 2016). However, the origin of modern dust depositions on the Antarctic continent is still poorly constrained. Back in the nineties, together with SSA, Australia, New Zealand, and Southern Africa were firstly identified as dust contributors to East Antarctica (EA) (e.g. Delmonte et al., 2004a). Since then, only SSA and Australian dust sources benefited from detailed studies. While some works identified the Makgadikgadi and Etosha Pans as southern Africa's major mineral dust sources in the SH, it was not until recently the Namib Desert coastal areas were described as another important regional dust sources. Within the Namib Desert and along the coast, the Kuiseb (K), Omaruru (O) and Huab (H) dry riverbeds are the three main areas identified as the dustiest ones with the higher frequency of dust emission events (Von Holdt et al., 2017). Here we use Sr, Nd and Pb isotopes (measured on HR-MC-ICP-MS) to characterize and evaluate the influence of this region in Southern Africa as a dust source to EA. Samples collected in K, O and H desertic areas were analyzed together with snow samples collected along a ~250 km N-S transect (defined from the coast to inland) at seven different sampling sites in the surroundings of Dronning Maud Land, EA. In addition, using the bulk of the Huab region, dust aerosols were generated into an atmospheric simulation chamber (CESAM) to reproduce, mechanically the saltation and sandblasting processes responsible for the release of mineral dust in natural conditions. Our isotopic results show Namibia’s coast emerged as another possible source end-member, together with some regions in SSA, that supply dust to EA during warmer periods.

References:

Delmonte, B., Basile-Doelsch, I., Petit, J.R., Maggi, V., Revel-Rolland, M., Michard, A., Jagoutz, E., Grousset, F., 2004. Comparing the EPICA and Vostok dust records during the last 220,000 years: stratigraphical correlation and provenance in glacial periods. Earth-Sci. Rev. 66, 63–87.

Gili, S., Gaiero, D.M., Goldstein, S.L., Chemale, F. Jr., Koester, E., Jweda, J., Vallelonga, P., Kaplan, M.R., 2016. Provenance of dust to Antarctica: a lead isotopic perspective. Geophys. Res. Lett. 43. http://dx.doi.org/10.1002/2016GL068244.

Gili, S., D.M. Gaiero, S.L. Goldstein, F. Chemale, J. Jweda, M.R. Kaplan, R.A. Becchio, and E. Koester (2017). Glacial/interglacial changes of Southern Hemisphere wind circulation from the geochemistry of South American dust. Earth Planet. Sci. Lett., 469, 98-109, doi: 10.1016/j.epsl.2017.04.007.

Von Holdt, JR., Eckardt FD., and Wiggs GFS., 2017. Landsat identifies aeolian dust emission dynamics at the landform scale. Remote Sensing of Environment 198., 229–243.

How to cite: Gili, S., Vanderstraeten, A., Cazaunau, M., Chaput, A., Doussin, J.-F., Di Biagio, C., Formenti, P., King, J. S., Magnold, A., Mattielli, N., Pangui, E., Van Overmeiren, P., and Walgraeve, C.: The role of Southern Africa as a dust precursor to East Antarctica, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18441, https://doi.org/10.5194/egusphere-egu2020-18441, 2020.

EGU2020-19212 | Displays | AS3.8

Saharan dust deposited in Lake Bastani, Corsica: The northernmost dust record of the termination of the Holocene African Humid Period?

Maxime Leblanc, Charlotte Skonieczny, Pierre Sabatier, Christophe Colin, Serge Miska, Aline Govin, Viviane Bout-Roumazeilles, Aloys Bory, Maxime Debret, Isabelle Jouffroy-Bapicot, and Boris Vannière

Throughout the Quaternary, variations of the insolation received over Africa have governed the monsoon dynamics in this region, generating a recurrence of intense rainfall periods. These African Humid Periods (AHP) are characterized by a major transformation of the Saharan hydrological cycle, favouring the development of vast fluvial systems and tropical humid ecosystems in the currently hyper-arid Sahara Desert. In the current context of global warming, the mechanisms as well as the environmental responses associated with these periods of rapid changes between two extreme climatic contexts remain crucial to understand. Many studies have investigated the mechanisms associated with the last AHP that occurred in the early Holocene (9 to 5ka), and more particularly its initiation and termination. Despite all these efforts, these climatic transitions remain highly debated (e.g. influence of high latitudes versus regional forcing, vegetation feedback). Here, we propose to improve our understanding of the Holocene AHP by studying Saharan dust deposited in Lake Bastani (Corsica, western Mediterranean) during the last 12ka. Indeed, as dust emissions are function of the aridity of their sources, among other parameters such as wind intensity, Saharan dust fluxes recorded over and out of Africa may represent an indirect way to reconstruct Sahara past hydrological changes. Bastani Lake is a high elevation system with a very restricted watershed and has been described as a natural Saharan dust trap during the last 3ka (Sabatier et al., accepted). In this study, we present a Holocene multi-proxy characterization of the fine-grained sediments recorded in Bastani lake. We develop a multiproxies approach based on mineralogy and major elements composition of the clay fraction as well as microscopic observations and quantification of the biogenic silica, which complicates Saharan dust supply estimation in this system. This effort to decipher the Bastani lake sediments composition will allow us to qualify and quantify the Saharan dust signal from the bulk sediment record (watershed erosion/alteration, biogenic silica productivity) in order to discuss, to our knowledge, the northernmost aeolian response of the Sahara desert hydrological changes of the termination of this key climatic transition.

 

Reference: Sabatier et al., Past African dust inputs in Western Mediterranean area controlled by the complex interaction between ITCZ, NAO and TSI, Climate of the Past, accepted.

Keywords: Saharan dust, Saharan hydrological cycle, Paleoclimatology, Holocene, clay mineralogy, geochemistry, biogenic silica.

How to cite: Leblanc, M., Skonieczny, C., Sabatier, P., Colin, C., Miska, S., Govin, A., Bout-Roumazeilles, V., Bory, A., Debret, M., Jouffroy-Bapicot, I., and Vannière, B.: Saharan dust deposited in Lake Bastani, Corsica: The northernmost dust record of the termination of the Holocene African Humid Period?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19212, https://doi.org/10.5194/egusphere-egu2020-19212, 2020.

EGU2020-19416 | Displays | AS3.8

Present-day Saharan dust fluxes across the Atlantic Ocean

Jan-Berend Stuut, Catarina Guerreiro, Geert-Jan Brummer, Laura Korte, and Michèlle Van der Does

Mineral dust plays an important role in the ocean’s carbon cycle through the input of nutrients and metals which potentially fertilise phytoplankton, and by ballasting organic matter from the surface ocean to the deep sea floor. In addition, mineral dust feeds back on climate through many different pathways like changing the radiative balance of the atmosphere, by stimulating cloud formation, dampening hurricane formation and by changing the earth’s albedo. Because open-ocean dust-flux measurements are either based on shipboard- or sediment-trap data, they are biased by interpolation and extrapolation of point observations in space and time. Alternatively, dust-flux estimations can be made using satellite observations, but these are often hampered by the presence of clouds. For these reasons we have been studying Saharan dust along a Transatlantic transect between northwest Africa and the Caribbean, focussing on temporal and spatial variability of dust-deposition fluxes and how these are reflected in terms of dust particle size and composition. One important finding deals with the deposition of Saharan dust by rain, which seems to be an important way to make nutrients available to phytoplankton living in the surface ocean. Nutrient-release bottle experiments in ambient sea water carried out along the same transect demonstrate how wet deposition of Saharan dust increases the release of both macro- (P, Si) and micronutrients (Fe) up to an order-of-magnitude as opposed to dry deposition. Rain-amplified bioavailability of these nutrients may well be the key to increased surface-ocean productivity in the remote and oligotrophic parts of the oceans and, potentially, also continental ecosystems. See: www.nioz.nl/dust

How to cite: Stuut, J.-B., Guerreiro, C., Brummer, G.-J., Korte, L., and Van der Does, M.: Present-day Saharan dust fluxes across the Atlantic Ocean, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19416, https://doi.org/10.5194/egusphere-egu2020-19416, 2020.

EGU2020-17657 | Displays | AS3.8

Investigating the consequences of the desiccation of lakes in the Middle East and Central Asia for regional dust activity

Jamie Banks, Bernd Heinold, and Kerstin Schepanski

EGU2020-20517 | Displays | AS3.8

40-years of Saharan dust events in the Carpathian Basin: background, frequency, intensity, changing patterns

György Varga, Nadia Gammoudi, and János Kovács

Saharan dust events were investigated in the Carpathian Basin (Central Europe) for the period between 1979 and 2018 by using various satellite (TOMS and OMI Aerosol Index; MODIS AOD) and numerical forecast (Barcelona Supercomputing Centre’s DREAM, NMMB/BSC-Dust-model and SKIRON) products and modelled deposition of NASA’s Modern-Era Retrospective analysis for Research and Applications, Version 2. The identified 218 episodes were classified into three characteristic clusters based on synoptic background. 700 hPa geopotential height, wind vectors and meridional flow patterns, as well as backward trajectories of the episodes determined the classification.

Interannual variability of dust activity was remarkable, while seasonal frequencies of the episodes revealed clear spatiotemporal patterns with spring (40.2%) and summer (31.6%) maxima of the events. Mean values of dust deposition showed springtime maxima (44.1%) and dominance of wet deposition (77-93%), while amount of deposited dust material in the other seasons were quite similar, indicating the governing role of local weather conditions (e.g., precipitation patterns). Average warm advection of the episodes was 3.5°C (with spring minima, due to the more rain), but the decadal surface air temperature anomalies showed a general increasing trend.

Recently, a few more intense wintertime dust deposition events indicated changes in the deterministic atmospheric flow system. Seasonal and decadal zonal mean surface air temperature anomalies of dusty days showed clearly the increased warming of high latitudes during the last few winter episodes. The enhanced meridionality of (dust transporting) winds was also observable in the number of days with 15< m/s meridional wind component (at 700 hPa). Warmer Arctic region and more meandering air flow patterns could be responsible for these unusual dust episodes in the recent years.

Support of the National Research, Development and Innovation Office NKFIH KH130337 and NKFIH K120213 are gratefully acknowledged.

How to cite: Varga, G., Gammoudi, N., and Kovács, J.: 40-years of Saharan dust events in the Carpathian Basin: background, frequency, intensity, changing patterns, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20517, https://doi.org/10.5194/egusphere-egu2020-20517, 2020.

EGU2020-20288 | Displays | AS3.8

A climatology of dust episodes in the broader Mediterranean Basin using satellite MODIS C6.1 and OMI OMAERUV data

Nikos Hatzianastassiou, Maria Gavrouzou, Antonis Gkikas, and Nikos Mihalopoulos

Aerosols, due to their interaction primary with the shortwave, but also with the longwave radiation, constitute a significant climate component, and at the same time an important, but still uncertain, factor of the contemporary climatic change. Apart from radiation, aerosols also interact with clouds, acting as Cloud Condensation Nuclei (CCN) and/or Ice Nuclei (IN), modifying the cloud optical and physical properties like cloud albedo, extent, lifetime or precipitation producing ability. Hence, it is also expected that high loads of specific aerosol types, such as desert dust, can induce even stronger effects on the above mentioned cloud properties.

More specifically, dust aerosols, which are inserted in the atmosphere mainly from the great world deserts, represent the major global aerosol component. These aerosols can remain suspended in the air and travel for several days, reaching areas far away from their sources. The Mediterranean Basin (MB), which is one of the most responsive regions to climate change, due to its location (nearby the Sahara desert in North Africa and the deserts of Middle East), is frequently affected from massive and extended dust transport. Because of the potentially significant role of these dust episodes, and their seasonal and inter-annual variability, they are worth to be studied and monitored through time.

In the present study, a modified version of a satellite algorithm, which is fully described by Gavrouzou et al. in another study of this conference, is used for the determination of strong and extreme dust episodes in the Mediterranean Basin over the period 2005-2018. The algorithm, using MODIS C6.1 spectral Aerosol Optical Depth (AOD) and OMI OMAERUV Aerosol Index (AI) as input data, ran on a daily and an 1°x1° pixel level basis and determined the occurrence and intensity of dust episodes whenever the AI is greater than 1 and the Angstrom Exponent (AE), which is calculated from spectral AOD data, is lower than 0.4. Any day is characterized as an episodic one when the dust optical depth (DOD) exceeds a computed threshold value (mean value plus two or four standard deviations for strong and extreme episodes, respectively) on at least 30 pixels of the study area. According to the algorithm results, 148 dust episode days (104 strong and 44 extreme) are found during the 2005-2018 period in the Mediterranean Basin. Most of the episodes occur in July (27 strong- and 3 extreme-episode days) and April (25 strong- and 6 extreme-episode days) while dust episodes are not detected at all in November and December. It is also found that in April, March and May take place the highest number of extreme MB episodes (23 out of the total 44 ones).

How to cite: Hatzianastassiou, N., Gavrouzou, M., Gkikas, A., and Mihalopoulos, N.: A climatology of dust episodes in the broader Mediterranean Basin using satellite MODIS C6.1 and OMI OMAERUV data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20288, https://doi.org/10.5194/egusphere-egu2020-20288, 2020.

EGU2020-706 | Displays | AS3.8

Global dust climatology based on MODIS C6.1 and OMI-OMAERUV satellite data for the period 2005 to 2019

Maria Gavrouzou, Nikos Hatzianastassiou, Antonis Gkikas, and Nikos Mihalopoulos

Aerosol particles influence the Earth’s radiation budget, and thus weather and climate, through their interaction primarily with solar, but also with terrestrial radiation. Moreover, aerosol-cloud interactions are essential, since aerosols act as Cloud Condensation Nuclei (CCN) and/or Ice Nuclei (IN), and thus crucially affect cloud properties. Dust is a major aerosol type, accounting for a great fraction of the global aerosol mass, mostly originating from the global deserts). Dust aerosols exert a strong radiative forcing, while acting as CCN and/or IN, thus modifying the cloud physical optical and radiative properties as well as also cloud lifetime and precipitation. However, the direct and indirect effects of dust are strongly dependent on their spatial and temporal distribution, which still has a considerable degree of uncertainty. This uncertainty is due to limitations of our knowledge about the dust spatiotemporal variability, which is due to the strong variability both of the dust sources and emissions as well as their transport and removal processes. However, in the last two decades, significant steps have been made towards improving the ability to observe dust from satellites. Advanced retrieval algorithms enable to effectively derive key aerosol optical properties which are characteristic of their physical properties such as size and absorptivity. The availability of such aerosol data since the early 2000s offers nowadays the possibility to build satellite-based dust climatologies.

In the present study a global dust climatology is constructed using a satellite based algorithm. The algorithm is initialized with the latest editions of Collection 6.1 MODIS-Aqua and OMAER-UV OMI-Aura data spanning the 14-year period from 2005 to 2018. The raw data of the algorithm are: (1) spectrally resolved MODIS Aerosol Optical Depth-AOD and (2) OMI Aerosol Index-AI), both available on a daily basis and at 1°x1° latitude-longitude spatial resolution. The algorithm computes, using the spectral AOD values, the aerosol Angstrom Exponent (AE), which is finally used along with AI as the main algorithm input data that are characteristic of aerosol size (AE) and absorptivity (AI). By applying appropriate thresholds that ensure the coarse size and significant absorptivity of dust, the algorithm identifies presence of dust in the atmospheric column on a daily and 1°x1° basis over the entire globe and the period 2005-2018. The algorithm estimates the frequency of presence and the associated loading (in terms of dust optical depth, DOD) of dust on a monthly and annual basis. The 14-year study period enables the computation of climatological mean values, as well as the intra-annual and inter-annual variability and trends of dust. Specific emphasis is given to the world’s great deserts, as well as to regions undergoing important transport of dust.

How to cite: Gavrouzou, M., Hatzianastassiou, N., Gkikas, A., and Mihalopoulos, N.: Global dust climatology based on MODIS C6.1 and OMI-OMAERUV satellite data for the period 2005 to 2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-706, https://doi.org/10.5194/egusphere-egu2020-706, 2020.

EGU2020-21863 | Displays | AS3.8

Evaluation of NMMB-MONARCH dust reanalysis within the DustClim ERA4CS project

Michail Mytilinaios, Lucia Mona, Francesca Barnaba, Sergio Ciamprone, Serena Trippetta, Nikolaos Papagiannopoulos, Sara Basart, Enza Di Tomaso, Oriol Jorba, Carlos Pérez García-Pando, Emmanouil Proestakis, Eleni Marinou, Vassilis Amiridis, Paola Formenti, Juan Cuesta, Claudia Di Biagio, Benoit Laurent, and Beatrice Marticorena

An advanced dust reanalysis with high spatial (at 10km x 10km) and temporal resolution is produced in the framework of DustClim project (Dust Storms Assessment for the development of user-oriented Climate Services in Northern Africa, Middle East and Europe) [1], aiming to provide reliable information on dust storms current conditions and predictions, focusing on the dust impacts on various socio-economic sectors.

This regional reanalysis is based on the assimilation of dust-related satellite observations from MODIS instrument [2], in the Multiscale Online Nonhydrostatic Atmosphere Chemistry model (NMMB-MONARCH) [3], over the region of Northern Africa, Middle East and Europe. The reanalysis is now available for a seven-year period (2011-2016) providing the following dust products: Columnar and surface concentration, distributed in 8 dust particle size bins, with effective radius ranging from 0,15μm to 7,1μm, dust load, dry and wet dust deposition, dust optical depth (DOD) and coarse dust optical depth (radius>1μm) at 550nm and profiles of dust extinction coefficient at 550nm.

A thorough evaluation of the reanalysis is in progress to assess the quality and uncertainty of the dust simulations, using dust-filtered products, retrieved from different measurement techniques, both from in-situ and remote sensing observations. The datasets considered for the DustClim reanalysis evaluation, provide observations of variables that are included in the model simulations. The DOD is provided by AERONET network [4] and by IASI [5], POLDER [6], MISR [7] and MODIS space-borne sensors; Dust extinction profiles are provided by ACTRIS/EARLINET network [8] and CALIPSO/LIVAS dataset [9]; Dust PM10 surface concentrations derived from INDAAF/SDT [10] network and estimated from PM10 measurements [11] performed within EEA/EIONET [12] network; Dust deposition measurements collected by the INDAAF/SDT and the CARAGA/DEMO [13] networks; Dust size distribution from in situ observations (ground-based and airborne); And column-averaged dust size distribution at selected stations from the AERONET network.

In this work, we present the results of the model evaluation for the year 2012. The first evaluation results will focus on dust extinction coefficient profiles from EARLINET and LIVAS, on DOD using AERONET, MISR and MODIS datasets, and on dust PM10 concentration from INDAAF/SDT network. Moreover, a DOD climatology covering the whole reanalysis period (2011-2016) will be compared with the results obtained from AERONET network.

 

References

[1] https://sds-was.aemet.es/projects-research/dustclim

[2] https://modis.gsfc.nasa.gov/

[3] Di Tomaso et al., Geosci. Model Dev., 10, 1107-1129, doi:10.5194/gmd-10-1107-2017., 2017.

[4] https://aeronet.gsfc.nasa.gov/

[5] Cuesta et al., J. Geophys. Res., 120, 7099-7127, 2015.

[6] http://www.icare.univ-lille1.fr/parasol/overview/

[7] https://misr.jpl.nasa.gov/

[8] https://www.earlinet.org/

[9] Marinou et al., Atmos. Chem. Phys., 17, 5893–5919, https://doi.org/10.5194/acp-17-5893-2017, 2017.

[10] https://indaaf.obs-mip.fr/

[11] Barnaba et al., Atmospheric environment, 161, 288-305, 2017.

[12] https://www.eionet.europa.eu/

[13] Laurent et al., Atmos. Meas. Tech., 8, 2801–2811, 2015.

 

 

Acknowledgement

DustClim project is part of ERA4CS, an ERA-NET initiated by JPI Climate, and funded by FORMAS (SE), DLR (DE), BMWFW (AT), IFD (DK), MINECO (ES), ANR (FR) with co-funding by the European Union (Grant 690462).

How to cite: Mytilinaios, M., Mona, L., Barnaba, F., Ciamprone, S., Trippetta, S., Papagiannopoulos, N., Basart, S., Di Tomaso, E., Jorba, O., García-Pando, C. P., Proestakis, E., Marinou, E., Amiridis, V., Formenti, P., Cuesta, J., Di Biagio, C., Laurent, B., and Marticorena, B.: Evaluation of NMMB-MONARCH dust reanalysis within the DustClim ERA4CS project, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21863, https://doi.org/10.5194/egusphere-egu2020-21863, 2020.

EGU2020-17599 | Displays | AS3.8

Towards high-towards high-resolution dust reanalysis for Northern Africa, the Middle East and Europe

Enza Di Tomaso, Sara Basart, Jeronimo Escribano, Paul Ginoux, Oriol Jorba, Francesca Macchia, Gilbert Montane, Miguel Castrillo, and Carlos Pérez García-Pando

DustClim (Dust Storms Assessment for the development of user-oriented Climate Services in Northern Africa, Middle East and Europe) is a project of the European Research Area For Climate Services (ERA4CS). DustClim is aiming to provide reliable information on sand and dust storms for developing dust-related services for selected socio-economic sectors: air quality, aviation and solar energy.

This contribution will describe the work done within the DustClim project towards the production of a dust reanalysis over the domain of Northern Africa, the Middle East and Europe at an unprecedented high spatial resolution (at 10km x 10km) using the state-of-art Multiscale Online Nonhydrostatic Atmosphere Chemistry model (MONARCH) and its data assimilation capability (Di Tomaso et al., 2017). An ensemble-based Kalman filter (namely the local ensemble transform Kalman filter – LETKF) has been utilized to optimally combine model simulations and satellite retrievals.

Dust ensemble forecasts are used to estimate flow-dependent forecast uncertainty, which is used by the data assimilation scheme to optimally combine model prior information with satellite retrievals. Satellite observations from MODIS Deep Blue with specific observational constraint for dust (Ginoux et al., 2012; Pu and Ginoux, 2016; Sayer et al., 2014) are considered for assimilation over land surfaces, including source regions. MONARCH ensemble has been generated by applying multi-parameters, multi-physics, multi-meteorological initial and boundary conditions perturbations. Sensitive parameters of the assimilation configuration like the balance between observational and background uncertainty, or the spatial location of errors have been carefully calibrated.

The dust reanalysis for the period 2011-2016 is being compared against independent dust-filtered observations from AERONET (AErosol RObotic NETwork) show the benefit of the assimilation of dust-related MODIS Deep Blue products over areas not easily covered by other observational datasets. Particularly relevant is the improvement of the model skills over the Sahara.

References:
Di Tomaso, E., Schutgens, N. A. J., Jorba, O., and Pérez García-Pando, C. (2017): Assimilation of MODIS Dark Target and Deep Blue observations in the dust aerosol component of NMMB-MONARCH version 1.0, Geosci. Model Dev., 10, 1107-1129, doi:10.5194/gmd-10-1107-2017.
Ginoux, P., Prospero, J. M., Gill, T. E., Hsu, N. C. and Zhao, M. Global-Scale Attribution of Anthropogenic and Natural Dust Sources and Their Emission Rates Based on Modis Deep Blue Aerosol Products. Rev Geophys 50, doi:10.1029/2012rg000388 (2012).
Pu, B., and Ginoux, P. (2016). The impact of the Pacific Decadal Oscillation on springtime dust activity in Syria. Atmospheric Chemistry and Physics, 16(21), 13431-13448.
Sayer, A. M., Munchak, L. A., Hsu, N. C., Levy, R. C., Bettenhausen, C., and Jeong, M.-J.: MODIS Collection 6 aerosol products: Comparison between Aqua’s e-Deep Blue, Dark Target, and “merged” data sets, and usage recommendations, J. Geophys. Res.-Atmos., 119, 13965–13989, doi:10.1002/2014JD022453, 2014.

Acknowledgement
DustClim project is part of ERA4CS, an ERA-NET initiated by JPI Climate, and funded by FORMAS (SE), DLR (DE), BMWFW (AT), IFD (DK), MINECO (ES), ANR (FR) with co-funding by the European Union (Grant 690462). We acknowledge PRACE for awarding access to HPC resources through the eDUST and eFRAGMENT1 projects.

 

How to cite: Di Tomaso, E., Basart, S., Escribano, J., Ginoux, P., Jorba, O., Macchia, F., Montane, G., Castrillo, M., and Pérez García-Pando, C.: Towards high-towards high-resolution dust reanalysis for Northern Africa, the Middle East and Europe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17599, https://doi.org/10.5194/egusphere-egu2020-17599, 2020.

Dust aerosols play key roles in affecting the regional and global climate through their direct, indirect, and semi-direct effects. Dust events have decreased rapidly since the 1980s in East Asia, particularly over northern China, primarily because of changes in meteorological parameters (e.g. surface wind speed and precipitation). In this study, we found that winter (December– January–February) Arctic amplification associated with weakened temperature gradients along with decreased zonal winds is primarily responsible for the large decline in following spring (March–April–May) dust event occurrences over northern China since the mid-1980s. A dust index was developed for northern China by combining the daily frequency of three types of dust events (dust storm, blowing dust, and floating dust). Using the empirical orthogonal function (EOF) analysis, the first pattern of dust events was obtained for spring dust index anomalies, which accounts for 56.2% of the variability from 1961–2014. Moreover, the enhanced Arctic amplification and stronger Northern Hemisphere annular mode (NAM) in winter can result in the anticyclonic anomalies over Siberia and Mongolia, while cyclonic anomalies over East Europe in spring. These results are significantly correlated with the weakened temperature gradients, increased precipitation, and soil moisture, and decreased snow cover extent in the mid-latitude over Northern Hemisphere. Based on the future predictions obtained from the Fifth Climate Models Intercomparison Project (CMIP5), we found that the dust event occurrences may continually decrease over northern China due to the enhanced Arctic amplification in future climate.

How to cite: Wang, X. and Liu, J.: Impact of Arctic amplification on declining spring dust events in East Asia, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8175, https://doi.org/10.5194/egusphere-egu2020-8175, 2020.

EGU2020-5463 | Displays | AS3.8

DustIron: Global mineral dust simulations with ECHAM-HAMMOZ for modern and last glacial maximum climate conditions

Stephan Krätschmer, Martin Werner, Frank Lamy, Christoph Völker, and Michèlle van der Does

In this study, we present results of new mineral dust simulations performed with the model setup ECHAM-HAMMOZ. The simulations are part of the AWI project DustIron, a coupled data-model approach to investigate past changes of the Southern Hemisphere dust cycle and potential Southern Ocean iron fertilization as a result of atmospheric mineral dust / iron input.

The model setup consists of the latest atmospheric general circulation model release ECHAM6, coupled to the aerosol model HAM2.3 and the atmospheric chemistry model MOZ1.0. Our focus is on dust emission and deposition rates as well as the identification of key source and deposition areas in the Southern Hemisphere by sensitivity experiments for modern (1850 AD) and last glacial maximum (21 ka BP) climate conditions. The spatial patterns of the decadal mean of the simulated annual dust deposition agree well with recent CESM simulation results (Albani et al., 2016) for modern climate conditions. A comparison of the decadal mean of the total global annual dust emissions simulated with ECHAM-HAMMOZ (1361 Tg a-1) to CESM (2785 Tg a-1, Albani et al., 2019) shows that the model performs rather at the lower end concerning global dust emissions. The tendency to a slight underestimation of global annual mineral dust emissions, however, is in agreement with the model’s aerosol evaluation by Tegen et al. (2019).

How to cite: Krätschmer, S., Werner, M., Lamy, F., Völker, C., and van der Does, M.: DustIron: Global mineral dust simulations with ECHAM-HAMMOZ for modern and last glacial maximum climate conditions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5463, https://doi.org/10.5194/egusphere-egu2020-5463, 2020.

Since the late 20th century East Asia has frequently experienced unprecedented transboundary extreme ultrafine dust events (TEUDEs) due to a fast economic development based on significant amount of fossil fuel consumption. In this study, spatio-temporal patterns of the TEUDEs in East Asia and the roles of synoptic climate patterns and changing large-scale atmospheric circulation systems in exacerbating the anthropogenic atmospheric pollution events causing considerable human deaths are examined. Analyses of the Moderate Resolution Imaging Spectroradiometer (MODIS) Aqua and Terra aerosol optical depth (AOD) data (2000-2019) clearly show that the pollutants are produced mainly in northern China and move toward central Korea and southern Japanese islands during cold seasons when coals consumption soars for heating. Synoptic climatic maps drawn from the NCEP-NCAR I reanalysis data for multiple TEUDEs demonstrate that a north clockwise- south anticlockwise wind vector anomaly pattern in cold seasons formed by less southward meandering of Siberian High pressure (SH) helps the stagnation of significant amount of ultrafine dusts over East Asia. It is also notable that the long-term poleward retreating trend of cold season circumpolar vortex, which is associated with less frequent gusty wind flow from the SH, may provide a favorable condition for intense, long-lasting TEUDEs across East Asia under a warmer monsoon climate.

How to cite: Choi, G.: Transboundary Extreme Ultrafine Dust Events in East Asia under a Warmer Monsoon Climate, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18811, https://doi.org/10.5194/egusphere-egu2020-18811, 2020.

EGU2020-21883 | Displays | AS3.8

The impact of ecosystem change on dust emission in North America

Mark Hennen, Nicholas Webb, and Adrian Chappell

An estimated 50 Mt yr-1 of dust is emitted from North American landscapes, with profound regional impacts (Shao et al., 2011). Dust emission flux in North America is controlled by wind speed and land surface (aerodynamic) roughness that are variable in both space and time. Vegetation growth, form and spatial distribution characterise different ecosystem regimes and protect the soil surface from the shearing stress of the wind. In the dry western US, diverse land use and management drivers create disturbance regimes that produce diverse ecosystem responses that could be drastically impacting rates of wind erosion and dust emission (Ravi et al., 2010). Resolving the impacts of ecosystem change on aeolian processes is needed to quantify anthropogenic-induced dust loads and identify management options as environmental solutions (Webb and Pierre, 2018).

Currently, erosion surfaces in North America are derived from satellite imagery, either by spatial analysis of mean aerosol optical depth concentrations (e.g. Ginoux et al., 2012) or point source identification through subjective analysis of individual daily multispectral images (e.g. Lee et al., 2012; Kandakji et al., 2020). In either approach, the results are subjected to spatial and temporal bias caused by a lag in emission-to-observation period and loss of data during cloudy (dust and meteorological) periods. To complement these approaches we produced the first moderate (500 m) resolution daily maps of dust emission across the dry western United States. These maps were based on estimates of soil surface wind friction velocity (us*) derived from MODIS albedo data (Chappell and Webb 2016) using a commonly applied model (Marticorena and Bergammetti, 1995).

The North American dust emission climatology from 2001-2018 was compared with the us* data volume to identify the spatio-temporal occurrence of three key disturbance regimes: i) land clearing for energy infrastructure, ii) invasion of shrublands by exotic annual grasses that alter fire regimes, and iii) replacement of grasslands by invasive shrub species. Against this background we examine the state and transition of ecosystem change across these landscapes to understand the impact on current dust emission. We use these findings to comment on the implications for future dust emission and to encourage the development of this modelling approach in Earth System Models.    

How to cite: Hennen, M., Webb, N., and Chappell, A.: The impact of ecosystem change on dust emission in North America, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21883, https://doi.org/10.5194/egusphere-egu2020-21883, 2020.

With the advances in modeling approaches, and the application of satellite and ground-based data in dust-related research, our understanding of the dust cycle is significantly improved in recent decades. However, two aspects of the dust cycle, the vertical profiles and diurnal cycles of dust aerosols have not been understood adequately, mainly due to the sparsity of observations. A micro-pulse LIDAR has been operating at the King Abdullah University of Science and Technology (KAUST) campus located on the east coast of the Red Sea (22.3N, 39.1E), measuring the backscattering from atmospheric aerosols at a high temporal resolution for several years since 2015. It is the only operating LIDAR system over the Arabian Peninsula. We use this LIDAR data together with other collocated observations and high-resolution WRF-Chem model simulations to study the 3-d structure of aerosols, with a focus on dust over the Red Sea Arabian coastal plains. 

Firstly, we investigate the vertical profiles of aerosol extinction and concentration in terms of their seasonal and diurnal variability. Secondly, using the hourly model output and observations, we study the diurnal cycle of aerosols over the site. Thirdly, we explore the interactions between dust aerosols and land/sea breezes, which are the critical components of the local diurnal circulation in the region. 

We found a substantial variation in the vertical profile of aerosols in different seasons. There is also a marked difference in the daytime and nighttime vertical distribution of aerosols in the study site, as shown by LIDAR data. A prominent dust layer is observed at ~5-7km at night in the LIDAR data, corresponding to the long-range transported dust of non-local origin. The vertical profiles of aerosol extinction are consistently reproduced in LIDAR, MERRA-2 reanalysis, and CALIOP data, as well as in WRF-Chem simulations in all seasons. Our results show that the sea breezes are much deeper (~1km) than the land breezes (~200m), and both of them prominently affect the distribution of dust aerosols over the study site. Sea breezes mainly trap the dust aerosols near the coast, brought by the northeasterly trade winds from inland deserts, causing elevated dust maxima at the height of ~1.5km. Also, sea and land breezes intensify dust emissions from the coastal region in daytime and nighttime, respectively. Such dust emissions caused by sea breezes and land breezes are most active in spring and winter. Finally, WRF-Chem successfully captures the onset, demise, and the height of some large-scale dust events as compared to LIDAR data qualitatively. 

How to cite: Parajuli, S., Stenchikov, G., Ukhov, A., and Shevchenko, I.: Interaction of the Vertical Profile of Dust Aerosols with Land/sea Breezes over the Eastern Coast of the Red Sea from LIDAR and High-resolution WRF-Chem Simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2077, https://doi.org/10.5194/egusphere-egu2020-2077, 2020.

EGU2020-15180 | Displays | AS3.8

Contribution of IASI to the observation of the dust aerosol diurnal cycle over Sahara

virginie capelle, alain chedin, Noelle Scott, and Martin Todd

The Infrared Atmospheric Sounder Interferometer (IASI) is well suited for monitoring of dust aerosols because of its capability to determine both AOD and altitude of the dust layer, and because of the good match between the IASI times of observation (9.30 am and pm, local time) and the time of occurrence of the main Saharan dust uplift mechanisms. Here, starting from IASI-derived dust characteristics for an 11-year period, we assess the capability of IASI to bring realistic information on the dust diurnal cycle. We first show the morning and nighttime climatology of IASI-derived dust AOD for two major dust source regions of the Sahara: The Bodele Depression and the Adrar region. Compared with simulations from a high resolution model, permitting deep convection to be explicitly resolved, IASI performs well. In a second step, a Dust Emission Index specific to IASI is constructed, combining simultaneous information on dust AOD and mean altitude, with the aim of observing the main dust emission areas, daytime and nighttime. Comparisons are then made with other equivalent existing results derived from ground based or other satellite observations. Results demonstrate the capability of IASI to improve the documentation of dust distribution over Sahara over a long period of time. Associating observations of dust aerosols in the visible, on which a majority of aerosol studies are so far based, and in the infrared thus appears as a way to complement the results from other satellite instruments in view of improving our knowledge of their impact on climate.

How to cite: capelle, V., chedin, A., Scott, N., and Todd, M.: Contribution of IASI to the observation of the dust aerosol diurnal cycle over Sahara, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15180, https://doi.org/10.5194/egusphere-egu2020-15180, 2020.

EGU2020-11443 | Displays | AS3.8

Modelling an exceptional desert dust transport toward Portugal on February 2017

Maria João Costa, Flavio Couto, Eduardo Cardoso, Rui Salgado, and Juan Luis Guerrero-Rascado

The terrain surrounding the Sahara desert is formed by some mountains ranges, as the Atlas mountain system in the northern edge of the desert and the Hoggar Mountains in Southern Algeria. Such orography, jointly with atmospheric circulation, plays an important role in the mobilization and transport of desert dust over medium and large distances. This study explores the interaction between complex terrain and atmospheric circulation in order to better understand an exceptional desert dust outbreak affecting Portugal in February 2017. The Meso-NH model is able to represent the atmospheric motions in different scales, and has been implemented with a rather complete parametrization package of physical processes in the atmosphere. The capability of the model to simulate dust emission is also explored. The on-line dust emission parametrization type is taken from the distribution of emitted dust of SURFEX with no need to use chemistry to activate dusts. A set of two simulations was performed for the period between 16 February at 0000 UTC to 24 February 1200 UTC, with the Meso-NH model configured in a single domain at 10 km horizontal resolution and 300x360 grid points. The experiments were defined as a) control experiment (CTRL), and b) dust experiment (DUST). From the large domain simulations, it was possible to assess the source of dust and its mobilization over Western Sahara desert, namely over the Northern part of Mauritania and Mali and Eastern part of Algeria. The formation of a cyclonic circulation at the surface favoured the dust uplifting. Such a surface low merged with a cut-off low that moved southward over the Iberian Peninsula and remained centred in the north of Morocco. Such pattern intensified the northward flow found at 700 hPa toward the Atlas Mountains range, inducing the dust transport above 3 km altitude. As expected, the simulations showed the ability to assess important details about the atmospheric circulation not resolved by low density of observations over the domain considered. Furthermore, the simulations were able to show the way that the atmospheric ingredients were brought together to produce the exceptional transport of desert dust toward Portugal. The orographic effects playing an important role in dust mobilization (convergence and cyclogenesis at the surface) and atmospheric circulation to the maintenance of the dust transport have been highlighted. Such event were responsible for the transport of high amount of dust toward the Iberian Peninsula.

How to cite: Costa, M. J., Couto, F., Cardoso, E., Salgado, R., and Guerrero-Rascado, J. L.: Modelling an exceptional desert dust transport toward Portugal on February 2017, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11443, https://doi.org/10.5194/egusphere-egu2020-11443, 2020.

EGU2020-7330 | Displays | AS3.8

Saharan Dust and Solar Energy Generation in Europe: Case Study of June 2019

Gholam Ali Hoshyaripour, Vanessa Bachmann, Florian Filipitsch, Jonas Straub, Jochen Foerstner, Ina Mattis, Frank Wagner, Heike Vogel, and Bernhard Vogel

Aeolian dust, the most dominant atmospheric aerosol by mass, decreases the solar energy reaching the Earth surface by absorbing and scattering the solar radiation. This energy loss increases mainly with the dust concentration in the atmosphere, which is controlled by the emission, transport and removal of the dust particles. All these processes can vary significantly depending on the convection treatment in the model simulations, thereby affect the solar energy forecast.

This study investigates the dust impacts on solar energy generation within convection-resolving simulations using the next-generation atmospheric modeling system ICON-ART (ICOsahedral Nonhydrostatic with Aerosols and Reactive Trace gases). The simulation set-up includes a global domain with 40 km horizontal resolution with three nests down to 5 km horizontal resolution over North Africa and Europe. The innermost nest resolves convection while other domains are based on parameterized convection. This set-up is used to simulate the period 22-27 June 2019, which is associated with a Saharan dust outbreak in clear sky conditions over North Africa and large parts of Europe. 

Compared to the global simulation, the convection-resolving simulation leads to significantly higher dust optical depth in North Africa. This is related to the elevated coarse mode concentrations due to higher vertical velocities in the convection-resolving simulation. However, dust optical depth over Europe only slightly changes as a large portion of coarse mode particles do not reached Europe due to their large sedimentation velocities. The results are compared with AERONET, ceilometer and radiation measurements.

How to cite: Hoshyaripour, G. A., Bachmann, V., Filipitsch, F., Straub, J., Foerstner, J., Mattis, I., Wagner, F., Vogel, H., and Vogel, B.: Saharan Dust and Solar Energy Generation in Europe: Case Study of June 2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7330, https://doi.org/10.5194/egusphere-egu2020-7330, 2020.

EGU2020-1515 | Displays | AS3.8

Influence of Sand-Dust on Solar Radiation in the Hinterland of Taklimakan Desert

Lili Jin, Qing He, Zhenjie Li, Ali Mamtimin, and Qilong Miao

In order to reveal the essential feature of radiation in extreme arid region of Northwest China,using the global radiation,direct radiation,diffuse radiation and meteorological data in the Tazhong station( in Takli-makan desert hinterland,83°39'E,38°58'N),the characteristics of atmospheric transparency coefficient,influence of sand-dust on solar radiation were analyzed by the statistical methods.The results show that: The coefficient of atmosphere transparency is better from October to December than other months,but it's worse in spring and summer.The index of the atmosphere transparency P2 is the most ( least) in clear day ( sand storm day ) .The global radiation is more than 1000 W·m-2 in clear day,dust day and sand blowing day,while,it is up to 700 W·m-2 in sand storm day at most.The diffuse radiation is partly less than 400 W·m-2,mainly between 100 and 200 W·m-2in clear day.It is less than 600 W·m-2 in dusty day mostly. The direct radiation is reduced by dust aerosol.The probability are 41.2%,72.5%,78.1% and 100% when direct radiation is less than 200 W·m-2 during clear day,dust day,sand blowing day and sand storm day.The diffuse radiation is gradually concentration high value with the sand of the atmosphere is increased.The variation of every radiation is big in dusty day.The daily curve (value) of diffuse radiation is similar to the global radiation,which is reduced by dust aerosol is the same as the direct radiation.That suggests the atmosphere transparency is closely related to the global radiation,diffuse radiation and direct radiation.

How to cite: Jin, L., He, Q., Li, Z., Mamtimin, A., and Miao, Q.: Influence of Sand-Dust on Solar Radiation in the Hinterland of Taklimakan Desert, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1515, https://doi.org/10.5194/egusphere-egu2020-1515, 2020.

EGU2020-8381 | Displays | AS3.8

Weaker cooling by aerosols due to dust-pollution interactions

Klaus Klingmueller, Vlassis Karydis, Sara Bacer, Georgiy Stenchikov, and Jos Lelieveld

The interactions between aeolian dust and anthropogenic air pollution, notably chemical ageing of mineral dust and coagulation of dust and pollution particles, modify the atmospheric aerosol burden. Since the aerosol particles can act as cloud condensation nuclei, this not only affects the radiative transfer directly via aerosol radiation interactions, but also indirectly through cloud adjustments. We study both radiative effects using the global ECHAM/MESSy atmospheric chemistry-climate model (EMAC) which combines the Modular Earth Submodel System (MESSy) with the European Centre/Hamburg (ECHAM) climate model. Our simulations show that the dust-pollution interactions reduce the cloud water and hence the reflection of solar radiation. The associated climate warming outweighs the cooling which the dust-pollution interactions exert through the direct radiative effect. In total, this results in a net warming by dust-pollution interactions which we estimate to moderate the negative global anthropogenic aerosol forcing at the top of the atmosphere by more than 0.1 W / m².

How to cite: Klingmueller, K., Karydis, V., Bacer, S., Stenchikov, G., and Lelieveld, J.: Weaker cooling by aerosols due to dust-pollution interactions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8381, https://doi.org/10.5194/egusphere-egu2020-8381, 2020.

EGU2020-18006 | Displays | AS3.8

Model study on effect of hematite and goethite on optical properties of inhomogeneous desert dust aerosols

Josef Gasteiger, Andreas Gattringer, and Bernadett Weinzierl

Desert dust aerosols occur as complex ensembles of particles with irregular shapes. Furthermore, these particles consist of a variety of different minerals which often coexist next to each other within individual particles. While in recent years the nonsphericity of particles is considered more and more in optical models of desert dust, the mineralogical inhomogeneity is still rarely considered though it can have a significant effect on light scattering and absorption.

Is this study, we discuss optical properties of irregularly-shaped inhomogeneous dust particles which were modelled with a Discrete Dipole Approximation code. We show how absorbing inclusions embedded in a non-absorbing material affect absorption and scattering by a particle as compared to the case when all the absorbing material is homogeneously distributed inside the particle. Hematite and goethite were selected as the material of the absorbing inclusions since these minerals are known to be responsible for most of the light absorption in desert dust aerosols.

How to cite: Gasteiger, J., Gattringer, A., and Weinzierl, B.: Model study on effect of hematite and goethite on optical properties of inhomogeneous desert dust aerosols, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18006, https://doi.org/10.5194/egusphere-egu2020-18006, 2020.

Natural mineral dust and intensive anthropogenic emissions and its complex mixing processes during transport result in great impacts on regional environmental quality and climate in East Asia. However, the morphology change and hygroscopicity of East Asian dust particles owing to coating anthropogenic pollutants are still statistically poorly understood. In this study, the statistically significant morphology change and hygroscopic growth of East Asian dust particles in a real atmosphere were firstly evaluated by combining CALIOP lidar measurements and relative humidity (RH) derived from the MERRA-2 during the past ten years (2007-2016). Our statistical results indicate that the optical properties of East Asian dust aerosol have significant region inhomogeneity and trend to be smaller in particle size and regular in shape during transport away from the source area. The dust particle irregularities and extinction coefficient were significantly decreasing and increasing with increasing ambient RH, respectively.The irregularity declining rate of mineral dust tended to slow down from source region (-0.89) to transport region with intensive anthropogenic emissions (-0.14). The strong positive linear correlation between dust extinction coefficient and relative humidity demonstrate the dust aerosol’s hygroscopic growth. It is attributed as a result of possible saline component and coating anthropogenic pollutants. The stronger hygroscopic growth of dust aerosol in the lower atmosphere has also been found. These results improve our understanding on the hygroscopicity of East Asian dust aerosol. Dust particles coating with anthropogenic pollution have a great ability of acting cloud condensation nucleus (CCN) in the lower atmosphere, which will affect the cloud microphysical processes and even climate effect.

How to cite: Wang, T. and Han, Y.: CALIPSO-based morphology change and hygroscopic growth of East Asian dust , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9312, https://doi.org/10.5194/egusphere-egu2020-9312, 2020.

EGU2020-857 | Displays | AS3.8

A 3D Time-Dependent Model for the Study of the Electrification of Non Spherical Dust Particles due to Ion Attachment

Sotirios Mallios, Vasiliki Daskalopoulou, Evangelos Skoubris, George Hloupis, Athanasios Papaioannou, and Vassilis Amiridis

Electrical processes can be a potential key player in the lifecycle of desert dust. The dust particles can be charged during their transport, either by the attachment of atmospheric ions or by particle to particle collisions (triboelectric effect). Measurements indicate that, on average, larger particles become positively charged while the smaller ones become negatively charged [Zhao, H. L., J. Electrostat, 55, 2002; Lacks, D.J., et al., Phys. Rev. Lett., 100, 188305, 2008; Merrison, J.P., Aeolian Res., 4, 2012; Shinbrot, T. and Herrmann, H.J., Nature, 451, 2008]. During dust transportation, the larger and mainly positively charged particles separate from the smaller negatively charged particles due to the gravitational sedimentation, which sorts the dust particles by size. This process develops vertical electric fields within the dust cloud, enhancing the pre-existing field due to the depletion of atmospheric conductivity by the presence of the dust layer [Gringel W. and Mulheisen. R., Beitr. Phys. Atmos., 51, 121–8, 1978]. Depending on its strength, the total electric field within the dust cloud can: (a) counteract the gravitational settling of large particles and (b) cause a preferential orientation of the non-spherical particles along the vertical direction affecting particle aerodynamics [Ulanowski, Z., et al., Atmos. Chem. Phys., 7, 2007]. Therefore, electrical processes may alter dust removal processes, and thus the evolution of particle size during transport, affecting dust-radiation-cloud interactions and the associated air quality [Sajani S.Z., et al., Occup. Environ. Med., 68(6), 2011], weather, and climate modeling [Mahowald, N., et al., Aeolian Res., 15, 2014].

In the present work, we have developed a novel 3D Cartesian time-dependent model that takes into account several atmospheric processes, such as: (i) the ionization due to the galactic cosmic rays radiation, (ii) the ion-ion recombination, and (iii) the ion attachment to non spherical dust particles.  The model is able to self-consistently calculate the time dynamics of the atmospheric conductivity, and the atmospheric electric field, under the presence of a distribution of stationary non spherical dust particles. Additionally, the total charge density, dust particle charge and dust particle orientation are also quantified. The new 3D electrification formalism allows the study of dust layers without imposing any symmetry and  is valid for layers with any horizontal and vertical extend, as opposed to 1D models which are valid when the horizontal extend is much larger than the vertical, or to 2D models which assume a symmetry in the shape of the dust layer. The results are compared, in the limiting case that the horizontal extend is much larger than the vertical one, with those obtained from 1D models found in the past literature [e.g. Zhou, L., Tinsley, B.A., Adv. Space Res. 50, 2012]. Moreover, the effect of the studied electrification process is assessed through a comparison with recent and unique electric field measurements within lofted dust layers, as performed with the use of novel low cost atmospheric electricity sensors in an experimental campaign of the D-TECT ERC project, in Cyprus the past November.

How to cite: Mallios, S., Daskalopoulou, V., Skoubris, E., Hloupis, G., Papaioannou, A., and Amiridis, V.: A 3D Time-Dependent Model for the Study of the Electrification of Non Spherical Dust Particles due to Ion Attachment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-857, https://doi.org/10.5194/egusphere-egu2020-857, 2020.

EGU2020-10111 | Displays | AS3.8

Saharan dust events in the Carpathian Basin (Central Europe) in 2018: provenance analyses by granulometry, XRD and SEM methods

János Kovács, Nadia Gammoudi, Alex Kovács, and György Varga

Sediment samples were collected from Morocco, Algeria and Tunisia (as possible source sediments) and from Hungary (2018 dust events), and analyzed with the following measurements: laser diffraction, X-ray powder diffraction, automated static image analysis, and scanning electron microscopy (SEM). Similarities were expected in the results of desert-originated samples and samples collected in Hungary. In order to identify the typical dust transportation routes and possible source areas, the backward trajectories were plotted using the NOAA HYSPLIT model [1].

According to particle size distribution results, active dust emission is taking place at the location of investigated desert samples, and the samples collected in Hungary can be the particles out-blown from the source areas. The evaluated mineralogical results show that every sample contains quartz and phyllosilicates. SEM micrographs and image analyses results assume that the samples collected in Hungary are from the same source area. Using HYSPLIT application, trajectories of two analyzed dust events reveal that one desert sample, as a possible source is excluded and that the two trajectories cross each other at a junction point above North Africa (depression area between the Hoggar Mts. and Tademaït). This point can be the sought possible source location. The results in this study are convenient with those founded by Blott et al. [2] and Ahmed et al. [3]

Acknowledgment

Support of the National Research, Development and Innovation Office NKFIH KH130337 and K120213 is gratefully acknowledged.

References

  1. Draxler, RR, Rolph, GD. 2012. HYSPLIT (HYbrid Single‐Particle Lagrangian Integrated Trajectory) Model access via NOAA ARL READY Website. NOAA Air Resources Laboratory: Silver Spring, MD. http://ready.arl.noaa.gov/HYSPLIT.php, last accessed 2019/03/20.
  2. Blott, S. J., Al-Dousari, A. M., Pye, K., Saye, S. E.: Three-dimensional characterization of sand grain shape and surface texture using a nitrogen gas adsorption technique. Journal of Sedimentary Research 74, 156–159‏ (2004).
  3. Ahmed, M., Al-Dousari, N., Al-Dousari, A.: The role of dominant perennial native plant species in controlling the mobile sand encroachment and fallen dust problem in Kuwait. Arabian Journal of Geosciences 9, 134 (2016)

How to cite: Kovács, J., Gammoudi, N., Kovács, A., and Varga, G.: Saharan dust events in the Carpathian Basin (Central Europe) in 2018: provenance analyses by granulometry, XRD and SEM methods, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10111, https://doi.org/10.5194/egusphere-egu2020-10111, 2020.

The contemporary aeolian system is poorly understood due in part to a scarcity of direct measurements of modern dust deposition. The Uinta Mountains of Northeastern Utah, USA are well-suited to the study of contemporary dust owing to their gently sloping, soil-mantled alpine zones and relatively inert, quartzite-dominated bedrock. Capitalizing on this unique setting, eight marble dust traps, as well as one active dust collector, have been installed throughout the mountain range. Previous study of samples from these collectors has supported the quantification of mineral dust inputs to alpine pedogenesis and identified isotopic fingerprints that link dust to potential source regions. This project focuses on dust emptied from these samplers in Fall 2019, representing two years of continuous dust accumulation. The mean dust flux for these years is 4.1 g/m2/y, which corresponds to historic flux measurements ranging from 2.7 g/m2/y to 4.4 g/m2/y. The relatively large dust mass of these multi-year samples allows for samples from each collector to be split into a coarse and fine fraction prior to further analysis. Before separation, the median grain size of 2019 dust samples is approximately 10 µm. After sample separation, carried out through timed settling following Stoke’s Law, the approximate median particle diameter is 6 µm for the fine fraction, and 20 µm for the coarse fraction. Coarse Uinta dust is more enriched in quartz and feldspar relative to fine dust, which is dominated by clay minerals. The coarse material is therefore more mineralogically similar to local bedrock, supporting the theory that larger particles are endogenous in origin. Clay minerals are less abundant in local bedrock, suggesting that fine mineral dust may have an exogenous source. Analysis of trace and major elemental abundances, as well as Sr and Nd isotopic fingerprinting will support additional interpretations about the nature and origin of modern dust in the Uintas. These results will contribute to ongoing efforts to better understand how specific dust source regions influence the properties of mineral aerosols arriving in remote alpine environments.

How to cite: Olson, P. and Munroe, J.: Geochemical characterization of discrete grain size fractions within contemporary alpine dust, Uinta Mountains, Utah, USA, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11041, https://doi.org/10.5194/egusphere-egu2020-11041, 2020.

Atmospheric aerosols over polar regions have attracted considerable attention for their pivotal effects on climate change. In this study, temporospatial variations in single-particle-based depolarization ratios (δ: s-polarized component divided by the total backward scattering intensity) were studied over the Northwest Pacific and the Arctic Ocean using an optical particle counter with a depolarization module. The δ value of aerosols was 0.06 ± 0.01 for the entire observation period, 61 ± 10% lower than the observations for coastal Japan (0.12 ± 0.02) (Pan et al. Atmos. Chem. Phys. 2016, 16, 9863−9873) and inland China (0.19 ± 0.02) (Tian et al. Atmos. Chem. Phys. 2018, 18, 18203−18217) in summer. The volume concentration showed two dominant size modes at 0.9 and 2 μm. The super-micrometer particles were mostly related to sea-salt aerosols with a δ value of 0.09 over marine polar areas, ∼22% larger than in the low-latitude region because of differences in chemical composition and dry air conditions. The δ values for fine particles (<1 μm) were 0.05 ± 0.1, 50% lower than inland anthropogenic pollutants, mainly because of the complex mixtures of sub-micrometer sea salts. High particle concentrations in the Arctic Ocean could mostly be attributed to the strong marine emission of sea salt associated with deep oceanic cyclones, whereas long-range transport pollutants from the continent were among the primary causes of high particle concentrations in the Northwest Pacific region.

How to cite: Pan, X., Tian, Y., Yan, J., Lin, Q., Sun, Y., Fu, P., and Wang, Z.: Size Distribution and Depolarization Properties of Aerosol Particles over the Northwest Pacific and Arctic Ocean from Shipborne Measurements during an R/V Xuelong Cruise, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13205, https://doi.org/10.5194/egusphere-egu2020-13205, 2020.

EGU2020-530 | Displays | AS3.8

Uptake and surface chemistry of SO2 on natural Icelandic volcanic dusts under simulated atmospheric conditions

Darya Urupina, Manolis Romanias, Frederic Thevenet, and Jerome Lasne

Volcanic dust (v-dust) is a highly variable source of natural particles in the atmosphere, and during the period of high volcanic activity it can provide a large surface for heterogeneous interactions with other atmospheric compounds. With an area of 103,000 km2, Iceland is the biggest volcanic desert on earth. It was chosen as a case study due to frequency of volcanic eruptions and high aeolian activity in the area. This is a comprehensive study of the heterogeneous reactivity of Icelandic volcanic dust with sulfur dioxide (SO2) gas. First, we focused on the kinetics of the reaction of SO2 with natural v-dust samples under atmospheric conditions using coated wall flow tube reactor. Steady-state uptake coefficients were measured to represent the long-term phenomena of the processing of aerosols in the atmosphere and the values obtained can be directly incorporated in chemical transport modeling. Second, the mechanism of the reaction of SO2 with natural v-dust samples was studied using infrared Fourier transform spectroscopy (DRIFTS). Both sulfites and sulfates were observed on the surface of v-dust, with sulfates being the final oxidation product, attesting to SO2 heterogeneous reactivity. Surface hydroxyl groups were found to play a crucial role in the conversion of SO2 to sulfates as evidenced from both flow tube and DRIFTS experiments. Based on these experimental results, a mechanism for SO2 interaction with different surface sites of v-dust was proposed and discussed. Third, in order to monitor the amount of sulfites and sulfates formed on the surface of mineral dusts of different origins a simple, accurate and precise reversed-phase liquid chromatography method was developed and validated to stabilize and analyze sulfites and sulfates in the extract of dusts exposed to SO2. Besides SO2 gas, v-dust reacts with other atmospheric pollutants, such as NO2 and O3, proving that heterogeneous processes play an important role in the atmospheric chemistry. One must keep in mind that as a result of such transformations, such properties as ice nucleation and optical properties might change as well soliciting further investigation of heterogeneous reactivity of Icelandic v-dusts.

How to cite: Urupina, D., Romanias, M., Thevenet, F., and Lasne, J.: Uptake and surface chemistry of SO2 on natural Icelandic volcanic dusts under simulated atmospheric conditions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-530, https://doi.org/10.5194/egusphere-egu2020-530, 2020.

Samples from the Horqin sandy land were exposed to a series of wind velocities and the sink particles were collected at the end of the diffusion section of a wind tunnel. The resulting grain size was coarser than the original one, and the original samples showed lower average content of the SiO2 and higher average content of Al2O3, Fe2O3, MgO, CaO, Na2O, and K2O than the collected samples did. Comparing with other dust source area in China, the Horqin sandy land had higher content of the Zr, Ba, SiO2, Al2O3 and K2O. Compared with the average upper continental crust (UCC) composition, surface samples were rich in the content of the Y, Zr, Nb, Ba, La, Nd. Geochemistry characteristics of the fine grain components of the Horqin sandy land differ from those from other dust source regions, because the fine-grained particles in the Horqin sandy land were mostly derived from various local deposits formed in its unique depositional environments controlled by several tectonic activities.

How to cite: Zhang, C. and Wang, X.: A wind-tunnel study on the sorting effects of wind erosion towards the geochemistry and the particle size of the surface samples from the Horqin sandy land, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3894, https://doi.org/10.5194/egusphere-egu2020-3894, 2020.

AS3.9 – Atmospheric Surface Science and Ice Particles

We present our laboratory and field test results of a newly developed commercial ice nucleation chamber, the so-called PINE, for its semi-autonomous measurements of atmospheric ice-nucleating particles (INPs). The PINE instrument is developed based on the design of the AIDA cloud chamber (Möhler et al., 2003) to promote long-term ambient INP measurements even at a remote location. Unique features of the PINE instrument include its plug-and-play feature (so it runs on a standard power outlet), susceptivity to the INP detection for 0.2 – 50K L-1 STP in the ~0.7 – 220 mm size range (256 channels) with ~8 min time resolution, cryo-cooler-based automatic ramping-temperature operation, capability of quantifying INPs in different IN modes (e.g., immersion freezing and deposition mode at >-60 °C), and small particle loss through the system (~5% for <3 mm diameter particles). Our laboratory test results show that ammonium sulfate homogeneously freezes at -33 °C in PINE, which is comparable to the previous homogeneous freezing AIDA result (Hiranuma et al., 2016). Further, we observe immersion freezing of Snomax and illite NX at approx. -7 °C and -20 °C in PINE as seen by other online INP instruments (Wex et al., 2015; Hiranuma et al., 2015). These results validate the PINE’s capability to detect INPs in a wide temperature range, where “clear and significant research issues remain” (DeMott et al., 2011). Next, as for the first field test, we have performed a ground-based INP measurement with PINE at the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) observatory, where long-term measurements provide statistical context (Marinescu et al., 2019). Briefly, we have successfully operated PINE via network for INP concentration measurements on a 24/7 basis for 45 consecutive days. Other findings from our lab characterization of PINE and first field deployment in the Southern Great Plains (e.g., comparison to other INP techniques) will be presented.

Acknowledgement: This material is based upon work supported by the U.S. Department of Energy, Office of Science, Office of Biological and Environmental Research (DE-SC0018979) – work packages 1-2 of Implications of Aerosol Physicochemical Properties Including Ice Nucleation at ARM Mega Sites for Improved Understanding of Microphysical Atmospheric Cloud Processes.

References:

  • DeMott, P. J. et al.: Bull. Amer. Meteorol. Soc. 92, 1623, 2011.
  • Hiranuma, N. et al.: Atmos. Chem. Phys., 15, 2489–2518, 2015.
  • Hiranuma, N. et al.: Atmos. Meas. Tech., 9, 3817–3836, 2016.
  • Marinescu, P. J., et al.: Atmos. Chem. Phys., 19, 11985–12006, 2019.
  • Möhler, O. et al.: Atmos. Chem. Phys. 3, 211–223, 2003.
  • Wex, H. et al.: Atmos. Chem. Phys., 15, 1463–1485, 2015.

How to cite: Hiranuma, N., Vepuri, H. S., Lacher, L., Nadolny, J., and Möhler, O.: The Portable Ice Nucleation Experiment chamber (PINE): laboratory characterization and field test for its semi-automated ice-nucleating particle measurements in the Southern Great Plains, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12385, https://doi.org/10.5194/egusphere-egu2020-12385, 2020.

EGU2020-11259 | Displays | AS3.9 | Highlight

Thermodynamic and Kinetic controls to the ice nucleation rate

Donifan Barahona

EGU2020-7609 | Displays | AS3.9

Laboratory Experiments on the Droplet Shattering Secondary Ice Production Mechanism

Alice Keinert, Judith Kleinheins, Dominik Spannagel, Alexei Kiselev, and Thomas Leisner

Supercooled drizzle droplets may produce multiple ice particles upon freezing. This mechanism could potentially explain the high ice number concentrations outside of temperature range where the well-known Hallett-Mossop mechanism of ice multiplication would take place. Limited experimental methods in the past prevented direct observations of the shattering droplets, resulting in a wide range of experimental results, unsuitable for the development of a sophisticated cloud model parameterization. Recently, we have revived experiments on secondary ice production by levitating individual drizzle droplets in electrodynamic balance (EDB) and observing the freeze-shattering with high-speed video microscopy and high-resolution infrared thermal measuring system. In this way we have been able to identify three additional SIP mechanisms (cracking, jetting and bubble bursts) associated with the freezing of drizzle droplets (Lauber et al., 2018).
Additionally, we have extended the range of experimental conditions to mimick the freezing of continental (pure water) and maritime (aqueous solution of analogue sea salt) drizzle droplets suspended in the updraft of cold moist air. We report a strong enhancement of shattering probability as compared to the previous studies conducted under stagnant air conditions. The high-definition video records of shattering events reveal the coupling between various microphysical processes caused by ice propagation inside the freezing drop and reveal striking difference between freezing of pure water and SSA solution droplets. Application of high-resolution infrared microscopy allowed us to record the evolution of the droplet temperature under realistic flow conditions and thus constrain the thermodynamic parameters controlling the pressure build-up inside the droplet. Based on these new observation data and theoretical model of freezing droplet, we discuss the physical mechanism behind the shattering of drizzle droplets and its implication for mixed-phase cloud modeling.

Lauber, A., A. Kiselev, T. Pander, P. Handmann, and T Leisner (2018). “Secondary Ice Formation during Freezing of Levitated Droplets”, Journal of the Atmospheric Sciences 75, pp. 2815–2826.

How to cite: Keinert, A., Kleinheins, J., Spannagel, D., Kiselev, A., and Leisner, T.: Laboratory Experiments on the Droplet Shattering Secondary Ice Production Mechanism, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7609, https://doi.org/10.5194/egusphere-egu2020-7609, 2020.

EGU2020-20623 | Displays | AS3.9

Chemical insights into the ice nucleating ability of macromolecules in immersion freezing

Nadine Borduas-Dedekind, Anna Miller, Sophie Bogler, and Jon Went

Cloud glaciation is an atmospheric process with important implications for climate and weather. Indeed, clouds made of liquid water and of ice crystals impact the global radiative balance of the atmosphere by reflecting incoming solar radiation and by absorbing outgoing terrestrial radiation. The relevance of ice nucleating particles (INPs) to the atmosphere depends on three main factors, namely on (1) their atmospheric concentration, (2) their freezing temperature and relative humidity, and (3) their freezing mechanism (Cziczo et al., 2013). Research on characterizing ice nucleating organic matter often takes a “top-down” approach where a whole sample of a complex mixture of organic, often biological, macromolecules is subjected to separation techniques and heat treatments to identify IN active sub-components. Studies have used this approach for characterizing bulk soil organic matter, volcanic ash and biological macromolecules from pollen, fungi, and bacteria.

 

We and others have recently found that dissolved organic matter collected from rivers and swamps surprisingly contain active INP (Borduas-Dedekind et al., 2019; Knackstedt et al., 2018; Moffett et al., 2018). Yet, all three studies state that it is unclear which sub-component of the dissolved organic matter is responsible for the ice nucleating ability. There are clear challenges in attributing the ice nucleating ability when starting with a complex mixture of organic and/or biological material, including matrix effects, impurities accumulated through the separation and/or heating process and lack of molecule identity.

 

We present here a “bottom-up” approach to compliment the top-down approach for atmospheric ice nucleation research of macromolecules. Using our home-built drop Freezing Ice Nuclei Counter (FINC) with automated imaging, a range of macromolecules were investigated. Indeed, we have analysed a wide range of dissolved organic matter subcomponents including proteins and fulvic acids. We find a range of ice nucleating ability. We find that lignin, the second most abundant biopolymer in plants, is ice active with 50% frozen fraction temperatures (T50) at –18 °C at a concentration of 100 mg C/L. Furthermore, we have investigated the ice nucleation ability of common diatom exudates and found that at atmospherically relevant concentration they are likely not ice active in immersion freezing within the detection of our FINC instrument. We are currently investigating the effect of atmospheric processing on these macromolecules with the goal of understanding how macromolecules’ ice activity evolves over their one-week lifetime in the atmosphere.

How to cite: Borduas-Dedekind, N., Miller, A., Bogler, S., and Went, J.: Chemical insights into the ice nucleating ability of macromolecules in immersion freezing, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20623, https://doi.org/10.5194/egusphere-egu2020-20623, 2020.

Anthropogenic aerosols impact cirrus clouds through ice nucleation, thereby changing the Earth’s radiation budget. However, the magnitude and sign of anthropogenic forcing on cirrus clouds are still very uncertain depending on the treatments for ice nucleating particles (INPs) and the ice nucleation scheme. In this study, a new ice nucleation scheme (hereafter the HYBRID scheme) is developed to combine the best features of two previous ice nucleation schemes, so that the global model is able to calculate the ice number concentration in both the updrafts and downdrafts associated with gravity waves and has a robust sensitivity to the change of aerosol number. The ice number concentrations calculated using the HYBRID scheme are overestimated somewhat but are in reasonable agreement with an adiabatic parcel model and observations. The forcing and cloud changes associated with changes in aircraft soot, sulfur emission and all anthropogenic emissions between the preindustrial period (PI) and the present day (PD) are examined using a global model with the HYBRID scheme. Aircraft soot emissions decrease the global average ice number concentration (Ni) by -1.0±2.4×107 m-2 due to the inhibition of homogeneous nucleation and lead to a radiative forcing of -0.14±0.07 W m-2, while the increase in the sulfur emissions increases the global average Ni by 7.3±2.9×107 m-2 due to the increase in homogeneous nucleation and leads to a radiative forcing of -0.02±0.06 W m-2. The possible effects of aerosol and cloud feedbacks to the meteorological state in remote regions partly contribute to reduce the forcing and the change in Ni due to anthropogenic emissions. The radiative forcing due to all increased anthropogenic emissions from PI to PD is estimated to be -0.20±0.05 W m-2. If newly formed secondary organic aerosols (SOA) acts an INP and inhibit homogeneous nucleation, the Ni formed from heterogeneous nucleation is increased. As a result, the inclusion of INPs from SOA increases the change in Ni to 12.0±2.3×107 m-2 and increases (makes less negative) the anthropogenic forcing on cirrus clouds to -0.04±0.08 W m-2 from PI to PD.

How to cite: Zhu, J. and Penner, J. E.: Radiative forcing of anthropogenic aerosols on cirrus clouds using a hybrid ice nucleation scheme, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4158, https://doi.org/10.5194/egusphere-egu2020-4158, 2020.

EGU2020-16445 | Displays | AS3.9

The seasonal cycle of biogenic ice-nucleating particles in a boreal forest environment

Julia Schneider, Kristina Höhler, Paavo Heikkilä, Jorma Keskinen, Barbara Bertozzi, Tobias Schorr, Nsikanabasi Umo, Franziska Vogel, Zoé Brasseur, Yusheng Wu, Simo Hakala, Jonathan Duplissy, Tuukka Petäjä, Michael P. Adams, Benjamin J. Murray, Kimmo Korhonen, Erik S. Thomson, Dimitri Castarède, Thomas Leisner, and Ottmar Möhler

By triggering the formation of cloud ice crystals in the atmosphere, ice-nucleating particles (INP) strongly influence cloud properties, cloud life cycle and precipitation. Describing the abundance of atmospheric INPs in weather forecasts and climate projections remains challenging, as the global distribution and variability of INPs depend on a variety of different aerosol types and sources. Although widespread field measurements have been conducted, neither short-term variability nor long-term seasonal cycles have yet been well characterized by continuous measurements. In 2018, the University of Helsinki and the Karlsruhe Institute of Technology (KIT) initiated a field campaign HyICE to perform comprehensive long-term INP measurements in the Finnish boreal forest. The campaign took place in Hyytiälä, Southern Finland at the University of Helsinki SMEARII research station (Hari and Kulmala, 2005). KIT provided the INSEKT (Ice Nucleation Spectrometer of the Karlsruhe Institute of Technology) to analyse the INP content of ambient aerosols sampled on filters. INSEKT is able to measure INP concentrations in the immersion-freezing mode at temperatures between 273 K and 248 K. The measurements started in March 2018 and ended in May 2019, which provides a unique continuous long-term time series of INP concentrations for over more than one year with a time resolution of about one to three days. This long-term observation record is used to examine systematic seasonal trends in the INP concentrations and to find meteorological and aerosol related parameters to describe the observed trends and variabilities. These findings will enable to find new parameterizations of atmospheric INP concentrations, as current parameterizations do not reproduce the observed seasonal cycle yet. In addition to INP concentration measurements, heat treatment tests of the aerosol samples have been conducted providing additional indications about the INP types dominating the INP population in the boreal forest, also in dependence on the season. Finally, this contribution will summarize and discuss major findings and implications from the HyICE long-term INP observation.

 

Hari and Kulmala (2005), Boreal Environ Res. 14, 315-322.

How to cite: Schneider, J., Höhler, K., Heikkilä, P., Keskinen, J., Bertozzi, B., Schorr, T., Umo, N., Vogel, F., Brasseur, Z., Wu, Y., Hakala, S., Duplissy, J., Petäjä, T., Adams, M. P., Murray, B. J., Korhonen, K., Thomson, E. S., Castarède, D., Leisner, T., and Möhler, O.: The seasonal cycle of biogenic ice-nucleating particles in a boreal forest environment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16445, https://doi.org/10.5194/egusphere-egu2020-16445, 2020.

EGU2020-13167 | Displays | AS3.9

The hydrogen bonding structure of adsorbed water on silver iodide and Feldspar minerals

Markus Ammann, Huanyu Yang, Luca Artiglia, and Anthony Boucly

The hydrogen bonding structure of adsorbed water on a solid substrate may control deposition nucleation, which is a pathway of heterogeneous ice nucleation. Hydrogen bonding of water molecules is also controlling the interface between the solid and liquid water relevant for other heterogeneous freezing modes. The hydrogen bonding structure may be affected by short and long-range interactions between the substrate and the water molecules nearby. Electron yield near edge X-ray absorption fine structure (NEXAFS) spectroscopy at the oxygen K-edge is used to experimentally explore the difference between the hydrogen bonding structure of interfacial H2O molecules under different conditions of temperature and water vapor pressure. Experiments reported in this work were performed at the in-situ electron spectroscopy endstation at the ISS beamline at the Swiss Light Source (PSI, SLS). We report electron yield oxygen K-edge NEXAFS spectra and X-ray photoelectron spectra from silver iodide (AgI) particles and milled feldspar samples exposed to water vapor at high relative humidity, but subsaturated with respect to ice. AgI serves as a well-studied reference case; and it contains no oxygen in its lattice, which simplifies the analysis of NEXAFS spectra at the O K-edge. The feldspar samples include a potassium containing microcline and a sodium-rich albite. The analysis of the NEXAFS spectra indicate rather tetrahedrally coordinated adsorbed water molecules on AgI particles. On the feldspars, the mobility of ions, as directly observed by the XPS spectra appears to have a strong impact on the hydrogen bonding structure, as apparent from substantial differences between samples previously immersed in pure water or as prepared. To sum up, we attempt to understand the behavior of the hydrogen bonding structure, which provides rich information about the arrangement of water molecules in the vicinity of a solid surface, that is linked to the ability of the solid to induce ice formation.

How to cite: Ammann, M., Yang, H., Artiglia, L., and Boucly, A.: The hydrogen bonding structure of adsorbed water on silver iodide and Feldspar minerals, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13167, https://doi.org/10.5194/egusphere-egu2020-13167, 2020.

EGU2020-255 | Displays | AS3.9

Lignin's ability to nucleate ice via immersion freezing

Sophie Bogler and Nadine Borduas-Dedekind

Uncertainties in current predictions for the atmosphere’s radiative balance are dominated by the impact of clouds. Ice nucleating particles (INPs) play a dominant role in the formation of mixed-phase clouds, however there is still a lack of understanding of how INPs interact with water in the freezing process. Detailed elucidations of the organic aerosol chemical composition from IN active atmospheric samples are scarce which is due to the analytical challenge of resolving their high complexity. We chose to reduce sample complexity by investigating the IN activity of a specific sub-component of organic aerosols, the biopolymer lignin. This approach facilitates connecting ice nucleating abilities to molecular properties. Ice nucleation experiments were conducted in our home-built Freezing Ice Nuclei Counter (FINC) to measure freezing temperatures in the immersion freezing mode which is the dominant IN mechanism in mixed-phase clouds. We find that lignin acts as an INP at temperatures relevant for mixed-phase cloud processes (e.g. 50% activated fraction at – 20 °C concentrated 20 mg C/L). Photochemistry and ozonation experiments were subsequently conducted to test the effect of atmospheric processing on lignin’s IN activity. We discovered that this activity was not susceptible to change under environmentally relevant conditions even though structural changes were introduced by monitoring UV/Vis absorbance. Additionally to atmospheric processing, laboratory treatments including heating, sonication and oxidation with hydrogen peroxide were done, where only the heating experiments had a decreasing effect on lignin’s IN activity.  Based on these results, we present a thorough INP characterization of lignin, a specific organic matter subcomponent, and contribute to the understanding of how organic material present in the atmosphere can nucleate ice.

How to cite: Bogler, S. and Borduas-Dedekind, N.: Lignin's ability to nucleate ice via immersion freezing, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-255, https://doi.org/10.5194/egusphere-egu2020-255, 2020.

EGU2020-630 | Displays | AS3.9

Development of drop freezing ice nucleation chamber (FINC), validation using lignin, and application to organic matter samples

Anna Miller, Killian Brennan, Jörg Wieder, Claudia Mignani, Assaf Zipori, and Nadine Borduas-Dedekind

Aerosol-cloud interactions are a source of high uncertainties in predicting future climate. One important aerosol-cloud interaction is ice nucleation of supercooled liquid water droplets caused by ice nucleating particles (INPs). Predicting the distribution and concentration of INPs is a challenge because of their spatial and temporal heterogeneity in source, number, and composition. Organic aerosols are particularly diverse and complex in chemical and physical composition and can be highly ice active to varying degrees. Here we present the development of our drop Freezing Ice Nucleation Chamber (FINC) for the quantification of INP concentration of aerosol in the immersion freezing mode. As part of the development and validation of FINC, we show results from an intercomparison using lignin as a comparison standard with three other drop-freezing instruments (ETH’s Drop Freezing Ice Nucleation counter Zurich (DRINCZ), University of Basel’s LED-based Ice Nucleation Detection Apparatus (LINDA), and Weizmann Institute’s Supercooled Droplet Observation of Microarray (WISDOM)). In addition, we present here preliminary findings of FINC’s application for determining predictors of the ice nucleating ability of organic matter, using several standards and field-collected samples of dissolved organic matter as a proxy for organic aerosol emitted from natural waters. These methods and results can aid in the community’s search for predictors and parameterizations of organic aerosol induced ice nucleation.

How to cite: Miller, A., Brennan, K., Wieder, J., Mignani, C., Zipori, A., and Borduas-Dedekind, N.: Development of drop freezing ice nucleation chamber (FINC), validation using lignin, and application to organic matter samples, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-630, https://doi.org/10.5194/egusphere-egu2020-630, 2020.

EGU2020-1518 | Displays | AS3.9

Surface modification of bioaerosol by physical, chemical, and biological ageing processes

Minghui Zhang, Amina Khaled, Pierre Amato, Anne-Marie Delort, and Barbara Ervens

Primary biological aerosol particles (PBAP) are a significant fraction of total atmospheric aerosol burden and can exhibit unique properties in terms of ice nucleation. In current atmospheric models, it is usually assumed that the physicochemical properties of PBAP are constant during their atmospheric residence time. However, several experimental studies have shown that PBAP undergo microphysical, chemical, and biological ageing processes in the atmosphere. These processes include bacterial agglomeration, modification of protein surfaces by chemical reactions (e.g., nitration) and cellular responses to changing ambient conditions. In addition, possible biological ageing processes such as cell growth and multiplication may change cell size and number. Here, we explore by means of process models the modification of the ice nucleating, hygroscopic and optical (scattering/absorption) properties of PBAP by such ageing processes with an emphasis on biological ageing. We show that cell growth/multiplication of ice-nucleating bacteria could enhance IN activity. Besides, cell modficaiton by ageing processes might change bacteria scattering properties due to size and surface composition modfication. Modification of protein surfaces  decreases IN activity for certain types of PBAP over atmospeherically relevant time scales. We perform model sensitivity tests over wide ranges of chemcial and biological parameters to identify conditions, under which these and other ageing processes have a significant effect on physicochemical properties of aged PBAP. Based on this analysis, we develop parameterizations for PBAP ageing processes to be included in aerosol and cloud models of different scales.

How to cite: Zhang, M., Khaled, A., Amato, P., Delort, A.-M., and Ervens, B.: Surface modification of bioaerosol by physical, chemical, and biological ageing processes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1518, https://doi.org/10.5194/egusphere-egu2020-1518, 2020.

EGU2020-2889 | Displays | AS3.9

Thermal imaging of a shattering freezing water droplet

Judith Kleinheins, Alexei Kiselev, Alice Keinert, and Thomas Leisner

The freezing of a supercooled water drop freely falling through a mixed-phase cloud is an ubiquitous natural process fundamental for the formation of precipitation in clouds. The freezing is known to proceed in two stages: first, a network of ice dendrites spreads across the volume of a supercooled droplet resulting in ultrafast release of latent heat and warming of the droplet up to the melting point of ice; during the second stage a solid ice shell grows from the outside into the droplet, leading to a pressure increase inside the liquid core. Once the pressure gets too high, either the shell cracks open or the droplet explodes. The resulting secondary ice fragments start growing in the water-saturated environment or cause the freezing of neighbouring droplets. This secondary ice production mechanism is important for the rapid glaciation of mixed-phase clouds, however, the details of the underlying mechanisms are poorly understood. To quantify this process of ice multiplication, the evolution of the droplet’s surface temperature during the second freezing stage was investigated with a high-resolution infrared thermography system (INFRATEC). Drops of about 300 µm diameter were levitated in an electrodynamic trap under controlled conditions with respect to temperature, humidity and ventilation. The surface temperature of the droplet was measured with the IR system while the freezing process and shattering of the freezing droplet was recorded by a high-speed video camera. Combining experimental results and comprehensive process modelling, we explore the thermodynamic conditions beneficial for secondary ice production upon freezing of freely falling drizzle droplets.

How to cite: Kleinheins, J., Kiselev, A., Keinert, A., and Leisner, T.: Thermal imaging of a shattering freezing water droplet , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2889, https://doi.org/10.5194/egusphere-egu2020-2889, 2020.

EGU2020-5820 | Displays | AS3.9

Solid-gas interactions in the eruption plume can both depress and enhance volcanic ash ice-nucleating activity

Elena Maters, Ana Casas, Corrado Cimarelli, Donald Dingwell, and Benjamin Murray

Volcanic ash generated by explosive eruptions can act as ice-nucleating particles, promoting freezing of supercooled water droplets in the eruption plume and the ambient atmosphere, and so impacting processes such as plume electrification, ash aggregation, and cloud glaciation. Our initial study of a compositional range of milled ash and glass materials demonstrated that mineralogy is likely a key property influencing ice nucleation by ash.1 However, the surface properties of ash are modified by interaction with magmatic gases in the hot core of the eruption plume, and it is not known how such in-plume interactions might affect the ice-nucleating activity (INA) of ash.

Here we investigated the influence of high temperature solid-gas interactions on the INA of three milled ash (Tungurahua, Astroni, Etna) and two milled mineral (K-feldspar, quartz) materials. Sub-samples of these materials were exposed to pure water vapour (H2O) or mixtures of water vapour with HCl(g) (H2O-HCl) or SO2(g) (H2O-SO2) under an 800 °C/400 °C heating sequence in the Advanced Gas-Ash Reactor.2 The INA of the non-treated and treated samples was then assessed using a microlitre Nucleation by Immersed Particle Instrument.3 The H2O treatment decreased the INA relative to that of the non-treated sample for all materials, and the H2O-HCl treatment decreased the INA to the same extent or more. Conversely, the H2O-SO2 treatment increased the INA (Tungurahua ash, Etna ash), or decreased the INA 1) to a lesser extent than the other treatments (Astroni ash), 2) to the same extent as the other treatments (quartz), or 3) to a greater extent than the other treatments (K-feldspar).

The depression in INA induced in all cases by the H2O treatment may relate to dehydroxylation of the silicate materials’ surfaces at high temperatures. On the other hand, differing effects on INA of the H2O-HCl and H2O-SO2 treatments is inferred to relate to contrasting reactivities of these materials towards HCl(g) and SO2(g). Water leachates of the samples suggest that chloride and sulphate salts (e.g., NaCl, CaSO4) formed on the H2O-HCl- and H2O-SO2-treated ash surfaces, respectively, but not on the H2O-HCl- and H2O-SO2-treated mineral surfaces. Additional tests suggest that the changes in INA observed for these treated ash samples do not reflect a ‘solute effect’4 imparted by the chloride or sulphate salts in water, implying that the ice-nucleating properties of the ash surfaces themselves are somehow changed by reaction with HCl(g) and SO2(g).

Surface-sensitive analyses could be useful to elucidate how sample surfaces have been modified by the different solid-gas interactions at the scale relevant for ice nucleation, and so potentially shed light on the cause of the depression and enhancement in INA observed here. The possibility that in-plume reaction with SO2(g) can increase the INA of volcanic ash in particular merits further investigation, as a previous line of thought has been that exposure of silicate particles to this acidic gas decreases INA.

 

1Maters et al. (2019) Atmos. Chem. Phys., 19, 5451–5465. doi:10.5194/acp-19-5451-2019

2Ayris et al. (2015) Bull. Volcanol., 77, 104. doi:10.1007/s00445-015-0990-3

3Whale et al. (2015) Atmos. Meas. Tech., 8, 2437-2447. doi:10.5194/amt-8-2437-2015

4Whale et al. (2018) Chem. Sci., 9, 4142-4151. doi:10.1039/C7SC05421A

How to cite: Maters, E., Casas, A., Cimarelli, C., Dingwell, D., and Murray, B.: Solid-gas interactions in the eruption plume can both depress and enhance volcanic ash ice-nucleating activity, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5820, https://doi.org/10.5194/egusphere-egu2020-5820, 2020.

EGU2020-7064 | Displays | AS3.9

Biological ice nucleation particles in the urban atmosphere of two megacities Beijing and Tianjin in North China

Wei Hu, Shu Huang, Jie Chen, Jingchuan Chen, Xiangyu Pei, Zhijun Wu, and Pingqing Fu

Biological materials are the most active ice nucleating particles (INPs), which can nucleate ice at relatively warm temperatures, affecting cloud properties and regional or even global climate. However, the understanding on the impact of biological INPs in urban areas is quite limited. Beijing is the biggest megacity in North China suffered from severe air pollution. Tianjin is the biggest coastal megacity in North China and influenced by both continental/anthropogenic pollution and marine air masses, especially in summer. In this study, we collected aerosol samples on the urban campuses of Tianjin University (39.11°N, 117.17°E) from 01 to 08 July 2019 and PeKing University (39.99°N, 116.31°E) from 11 to 18 August 2019 with SKC Biosamplers. The concentration of INPs in aerosols has been investigated using the PeKing University Ice Nucleation Array (PKU-INA). The abundance of total bacteria in aerosols was enumerated using the LIVE/DEAD bacterial viability assay and an epifluorescence microscope (DM2500, Leica, Germany). The average concentration of INPs in Beijing (18 ± 23 L-1) is higher than in Tianjin (8 ± 18 L-1) at -19 °C. Heat-sensitive INPs inactivated by heat treatment (inactivating ice nucleation protein, 95°C, 15 min) and lysozyme-sensitive INPs (digested by lysozyme) were inferred to biological INPs and bacterial INPs, respectively. The contribution of biological INPs in Beijing (86 ± 14%) was higher than in Tianjin (72 ± 26%), but the proportion of bacterial INPs in Beijing (57 ± 20%) was lower than in Tianjin (64 ± 22%). In addition, we measured the ice nucleation activity of ice nucleating macromolecules (INMs) in filtrate (0.22 µm) and after heat treatment. INMs can be found both in Tianjin and Beijing and the majority of them can be inactivated by heat treatment, indicating most of them were likely proteinaceous materials. Also, we found a significant increase in the concentration of INPs during a rain period with strong wind in Tianjin, which implies rainfall and wind speed may significantly influence the abundance of INPs in this region. Backward air masses trajectories indicated that continental air masses can bring high bacterial INPs in Tianjin and Beijing. Interestingly, the air masses in Tianjin with low bacterial INP concentration were mainly from marine areas. These results imply that biological sources including bacteria may contribute a large fraction of INPs above -19 °C in Tianjin and Beijing in the summer of 2019, and biological INPs potentially play an important role in cloud formation and precipitation in Chinese urban areas.

How to cite: Hu, W., Huang, S., Chen, J., Chen, J., Pei, X., Wu, Z., and Fu, P.: Biological ice nucleation particles in the urban atmosphere of two megacities Beijing and Tianjin in North China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7064, https://doi.org/10.5194/egusphere-egu2020-7064, 2020.

EGU2020-7758 | Displays | AS3.9

Towards understanding heterogeneous ice nucleation on realistic silver iodide surfaces from atomistic simulation

Bernhard Reischl, Golnaz Roudsari, Siiri Turtola, Olli Pakarinen, and Hanna Vehkamäki

Small particles of silver iodide (AgI) are known to have excellent ice nucleating capabilities and have been used in rain seeding applications. It is widely believed that the silver terminated (0001) surface of β-AgI acts as a template for the basal plane of hexagonal ice. However, the (0001) surface of ionic crystals with the wurtzite structure is polar and will therefore exhibit reconstructions and defects. Here, we use atomistic molecular dynamics simulations to study how the presence of defects on AgI(0001) affects the rates and mechanism of heterogeneous ice nucleation at moderate supercooling at -10 ºC. We first consider AgI(0001) surfaces exhibiting vacancies, step edges, terraces, and pits, and compare them to simulations of the corresponding ideal surface. We find that, while point defects have no significant effect on ice nucleation rates, step edges, terraces, and pits reduce both the nucleation and growth rates by up to an order of magnitude, which can be understood from the atomistic details extracted from the simulations. The reduction of the ice nucleation rate correlates well with the fraction of the surface area around the defects where perturbations of the hydration layer hinder the formation of a critical ice nucleus. Finally, we consider more realistic AgI(0001) surfaces with 5x5 surface reconstructions that cancel the surface dipole, and report on their ice nucleating abilities.

How to cite: Reischl, B., Roudsari, G., Turtola, S., Pakarinen, O., and Vehkamäki, H.: Towards understanding heterogeneous ice nucleation on realistic silver iodide surfaces from atomistic simulation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7758, https://doi.org/10.5194/egusphere-egu2020-7758, 2020.

EGU2020-8279 | Displays | AS3.9

A spectroscopic view of mineral aerosol surface aging under atmospheric conditions

Ahmed Abdelmonem, Johannes Lützenkirchen, Sanduni Ratnayake, and Naruki Hiranuma

Atmospheric mineral aerosols have direct and indirect influence on the climate system. So far, atmospheric interactions studies have mainly focused on pristine samples, despite the fact that aerosol particles may age under natural atmospheric conditions. For example, multiple freeze-melt or evaporation-condensation cycles of an aerosol-containing cloud droplet can change the surface chemistry of the aerosol particle, the droplet ionic strength and pH. These changes have a large impact on the ice nucleation ability of the aerosol particles. We probe the water structure and surface chemistry at water-mineral interface using surface spectroscopic techniques, particularly supercooled nonlinear spectroscopy [1-4]. We found that successive freeze-melt cycles disrupt the dissolution equilibrium, substantially changing the surface chemistry, giving rise to variations ice nucleation ability of the surface [4]. Along the aging process, the restructuring of the water molecules at the surface upon cooling changes. This was found to be correlated to the ice nucleation ability of the surface. We present here a spectroscopic overview on aging of selected mineral surfaces (Al2O3, Silica, Mica and PbO). We found that the pH, ionic strength, time in contact with water and number of freezing-melting events influence the aging dynamics and hence the ice nucleation ability.

 

  1. Abdelmonem, A., Direct Molecular-Level Characterization of Different Heterogeneous Freezing Modes on Mica – Part 1. Atmos. Chem. Phys., 2017. 17(17): p. 10733-10741.
  2. Abdelmonem, A., et al., Surface-Charge-Induced Orientation of Interfacial Water Suppresses Heterogeneous Ice Nucleation on α-Alumina (0001). Atmos. Chem. Phys., 2017. 17(12): p. 7827-7837.
  3. Lützenkirchen, J., et al., A set-up for simultaneous measurement of second harmonic generation and streaming potential and some test applications. Journal of Colloid and Interface Science, 2018. 529: p. 294-305.
  4. Abdelmonem, A., et al., Cloud history changes water-ice-surface interactions of oxide mineral aerosols (e.g. Silica). Atmos. Chem. Phys. Discuss., 2019. 2019: p. 1-17.

 

How to cite: Abdelmonem, A., Lützenkirchen, J., Ratnayake, S., and Hiranuma, N.: A spectroscopic view of mineral aerosol surface aging under atmospheric conditions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8279, https://doi.org/10.5194/egusphere-egu2020-8279, 2020.

EGU2020-11569 | Displays | AS3.9

The Surface of Tree Tissues as Source of Extractable Ice Nucleating Macromolecules during Rainfall Events

Hinrich Grothe, Teresa M. Seifried, Paul Bieber, and Laura Felgitsch

Several biological particles are able to trigger heterogeneous ice nucleation at subzero temperatures above -38°C. Many plants species such as winter rye [1], certain berries [2], pines and birches [3, 4] are known to contain biological ice-nucleating particles (BINPs) or rather ice-nucleating macromolecules (INMs). However, the influence of these BINPs on atmospheric processes including cloud glaciation and precipitation formation, as well as transport mechanisms of BINPs from the land surface into the atmosphere remain uncertain. If those INMs are easily available on the surfaces of a plant, they could be washed down by heavy rain events and could add an important new source for BINPs in the atmosphere, which has not received enough attention in the past.

In this study, we have focused on alpine trees, which form INMs extractable from their surfaces. We examined ice nucleation activity of samples from different birches (Betula pendula) and pines (Pinus sylvestris) growing in the Alps in Austria, Europe. Filtered aqueous extracts of leaves, needles, bark and wood were analyzed in the laboratory in terms of heterogeneous ice nucleation using VODCA (Vienna Optical Droplet Crystallization Analyzer), a cryo-microscope  for  emulsion  samples.  All plant tissues contained INMs in the submicron size range. Furthermore, we conducted a field experiment, in which we investigated the possibility of INMs to be released from the surface of the trees into the atmosphere during rain showers.

[1] Brush, R.A., M. Griffith, and A. Mlynarz, Characterization and Quantification of Intrinsic Ice Nucleators in Winter Rye (Secale cereale) Leaves. Plant Physiol, 1994. 104(2): p. 725-735.

[2] Felgitsch, L., et al., Heterogeneous Freezing of Liquid Suspensions Including Juices and Extracts from Berries and Leaves from Perennial Plants. Atmosphere, 2019. 10(1): p. 1-22.

 [3] Pomeroy, M.K., D. Siminovitch, and F. Wightman, Seasonal biochemical changes in the living bark and needles of red pine (Pinus resinosa) in relation to adaptation to freezing. Canadian Journal of Botany, 1970. 48(5): p. 953-967.

[4] Felgitsch, L., et al., Birch leaves and branches as a source of ice-nucleating macromolecules. Atmospheric Chemistry and Physics, 2018. 18(21): p. 16063-16079.

[5] Pummer, B.G., et al., Ice nucleation by water-soluble macromolecules. Atmospheric Chemistry and Physics, 2015. 15(8): p. 4077-4091.

How to cite: Grothe, H., Seifried, T. M., Bieber, P., and Felgitsch, L.: The Surface of Tree Tissues as Source of Extractable Ice Nucleating Macromolecules during Rainfall Events, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11569, https://doi.org/10.5194/egusphere-egu2020-11569, 2020.

EGU2020-12099 | Displays | AS3.9

Development, Characterization and Testing of a Drone-based Sampling Method for Investigations of Ice-Nucleating Particles

Paul Bieber, Teresa M. Seifried, Jürgen Gratzl, Julia Burkart, Anne Kasper-Giebl, David G. Schmale III, and Hinrich Grothe

Terrestrial ecosystems can contribute various particles to the troposphere, some of which are known for their ice nucleation activity. Most of the land-surface in Europe is covered with forests and fields, representing potential sources of ice nucleation active bioaerosols in form of pollen grains, fungal spores and bacterial cells. The presence of biogenic ice-nucleating particles (INPs) in clouds leads to heterogeneous freezing events and therefore influences the hydrological cycle and the Earth’s climate. Many studies focus on measurements and characterizations of INPs in clouds using aircrafts or sample on ground with stationary devices. Less is known about the actual emission and transport to high tropospheric layers. We focused on the development of an efficient sampling device that can be attached to small scale drones, such as the DJI Phantom 4 model. The Drone-based Aerosol Particles Sampling Impinger/Impactor (DAPSI) system was developed to sample airborne INPs above emission sources. It includes a cascade impactor that collects particles with size resolution and a self-build impinging system that accumulates INPs in a sterile solution. Additionally, the system contains an electric sensor for environmental data records (temperature, relative humidity and air pressure) as well as an optical particle counter to monitor particular matter concentrations during flight times. This study leads through the building, characterization and test-campaign of DAPSI. We present a validation test, regarding the sampling effectivity to sample aerosols (polystyrene latex spheres and INPs) as well as results from the first field campaign which took place in a rural sampling site in the Austrian Alps. Fluorescence- and cryo-microscopic assays show auto-fluorescent particles and heterogeneous ice nucleation activity of DAPSI samples. We highlight the opportunity to use DAPSI with small un(wo)manned aerial vehicles during field campaigns to sample and identify biogenic INPs in vertical and spatial resolution above emission sources.

How to cite: Bieber, P., Seifried, T. M., Gratzl, J., Burkart, J., Kasper-Giebl, A., Schmale III, D. G., and Grothe, H.: Development, Characterization and Testing of a Drone-based Sampling Method for Investigations of Ice-Nucleating Particles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12099, https://doi.org/10.5194/egusphere-egu2020-12099, 2020.

EGU2020-12357 | Displays | AS3.9

Ice nucleation by black carbon particles in the cirrus regime: dominated by pore condensation and freezing or deposition ice nucleation?

Cuiqi Zhang, Yue Zhang, Martin Wolf, Longfei Chen, and Daniel Cziczo

Deposition ice nucleation (IN) is a heterogeneous pathway by which water vapor deposits directly onto a solid surface and forms ice. Deposition IN happens below water saturation. However, the pore condensation and freezing (PCF) mechanism offers another explanation to ice formation on porous particles at low ice supersaturation. A single black carbon (BC) aggregate consists of several primary particles, forming crevices between primary particles. Whether BC IN happens via deposition or PCF remains uncertain due to the fractal nature of BC particles.

We estimated aggregate surface area, morphology, and primary particle size distribution directly from scanning electron microscopy (SEM) images of size-selected (200 nm, 300 nm, and 400 nm) commercial BC particles. Correlations between surface area data obtained from SEM image estimation and traditional BET tests were explored. Several shape parameters were chosen to characterize particle morphology. The IN ability of aerosolized BC particles was determined with the Spectrometer for Ice Nuclei (SPIN) in the cirrus regime (-46 to -38°C). Particle number concentration and chemical composition were monitored online by a Condensation Particle Counter (CPC) and the Particle Analysis by Laser Mass Spectrometry (PALMS) instrument, respectively.

Preliminary experimental results suggest that larger (400 nm) BC particles are more fractal and branching compared with smaller (200-300 nm) particles. Larger, more fractal BC particles are superior ice nucleating particles (INP) when compared with smaller, more spherical ones. The primary particle size distribution of all samples peaks around 30-45 nm. To understand the relevance of the PCF mechanism with our experimental IN results, we established Young-Laplace equations for the potential liquid-vapor interfaces within inter-primary particle crevices and pores and inter-aggregate pores. Solutions of the Young-Laplace equation on a saddle surface was deducted. Whether ice nucleation happens via PCF mechanism or deposition still requires further investigation, since particle surface chemistry can also affect both ice formation pathways.

How to cite: Zhang, C., Zhang, Y., Wolf, M., Chen, L., and Cziczo, D.: Ice nucleation by black carbon particles in the cirrus regime: dominated by pore condensation and freezing or deposition ice nucleation?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12357, https://doi.org/10.5194/egusphere-egu2020-12357, 2020.

EGU2020-13437 | Displays | AS3.9

Comparison of INP Parameterizations for Dust Minerals in Climatological Simulations With a Global Model

Jan Perlwitz, Daniel Knopf, and Ron Miller

The effect of aerosol particles on ice nucleation and, in turn, the formation of ice and mixed phase clouds is recognized as one of the largest sources of uncertainty in weather and climate prediction.  We utilize an improved sectional dust module in NASA GISS Earth System ModelE2.1, which distinguishes eight different mineral species and accretions between iron oxides and the other minerals.  Simulations over a period of 20 years have been carried out with this model, and the mineral fields and other model variables (temperature, relative humidity) are used to calculate the ice nucleating particle (INP) number concentration, applying time-independent and time-dependent INP parameterizations, such as active site parameterization and water activity based immersion freezing model (ABIFM).  We study how the dependence of the parameterizations on different model variables affects the mean INP number concentration.  The sensitivity of the INP number concentration to fundamental dust properties such as emitted mineral size distributions and mixing state between minerals is also investigated.  Results show that the sensitivity of the total INP number concentration to the emitted dust size distribution is rather small, but the sensitivity over the whole size range obscures offsetting differences in the magnitude and the sign of the sensitivity between smaller and larger particles.

How to cite: Perlwitz, J., Knopf, D., and Miller, R.: Comparison of INP Parameterizations for Dust Minerals in Climatological Simulations With a Global Model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13437, https://doi.org/10.5194/egusphere-egu2020-13437, 2020.

EGU2020-16462 | Displays | AS3.9

Do the rain microphysics provide information on the overlying ice cloud?

Kamil Mroz, Alessandro Battaglia, Stefan Kneifel, and Jose Dias Neto

This study investigates to what degree the information about the Drop Size Distribution (DSD) of rain can be used to narrow down uncertainty associated with complex ice microphysics. For this purpose, measurements from vertically pointing multi-frequency Doppler radar are thoroughly analysed. Linear Depolarization Ratio information is used to unambiguously separate hydrometeor phases. Within radar volumes where pure rain is identified multi-frequency Doppler spectra are utilised to retrieve a binned DSD with a high degree of confidence (Tridon et al. 2017). By assuming no breakup and negligible interaction between melting particles (Szyrmer and Zawadzki 1999, Olson et al. 2001, Matrosov 2008) the rain drop size distribution closest to the melting region is used to predict the particle size distribution (PSD) in the overlying snow. With these assumptions the resulting shape of the ice PSD depends solely on the hydrodynamical properties of snow that are dictated by its microphysics.  Several ice models are considered in the analysis, ranging from aggregates of columns, dendrites, needles and plates to different stages of rimed snow. Their scattering properties are simulated with Self-Similar-Rayleigh-Gans approximation (Leinonen et al. 2018) whereas falling velocities are modelled after Khvorostyanov and Curry (2005). Doppler spectra are simulated for the predicted ice PSD and compared to the measurements above the melting region. Results suggest that, if appropriate snow model used, the predicted reflectivity differs by less than 3 dB from the measured values as has been tentatively suggested by Fabry and Zawadzki (1995).

Tridon, F., A. Battaglia, E. Luke, P. Kollias, 2017. Rain retrieval from dual-frequency radar Doppler spectra: validation and potential for a midlatitude precipitating case study. Q. J. Roy. Meteorol. Soc. 143, 1364-1380. DOI: 10.1002/qj.3010

Szyrmer, W. and I. Zawadzki, 1999: Modeling of the Melting Layer. Part I: Dynamics and Microphysics. J. Atmos. Sci., 56, 3573–3592, https://doi.org/10.1175/1520-0469(1999)056<3573:MOTMLP>2.0.CO;2

S. Olson, P. Bauer, N. F. Viltard, D. E. Johnson, W-K. Tao, R. Meneghini, and L. Liao, “A melting layer model for passive/active microwave remote sensing applications—Part I: Model formulation and comparisons with observations,” J. Appl. Meteorol., vol. 40, no. 7, pp. 1145–1163, Jul. 2001

Y. Matrosov, "Assessment of Radar Signal Attenuation Caused by the Melting Hydrometeor Layer," in IEEE Transactions on Geoscience and Remote Sensing, vol. 46, no. 4, pp. 1039-1047, April 2008. doi: 10.1109/TGRS.2008.915757

Fabry, F., and I. Zawadzki, 1995: Long-term radar observations of the melting layer of precipitation and their interpretation. J. Atmos. Sci., 52, 838–851.

Jussi, Leinonen, Kneifel, Stefan, Hogan, Robin J.. Evaluation of the Rayleigh–Gans approximation for microwave scattering by rimed snowflakes. Q J R Meteorol Soc 2018; 144 ( Suppl. 1): 77– 88. https://doi.org/10.1002/qj.3093

How to cite: Mroz, K., Battaglia, A., Kneifel, S., and Neto, J. D.: Do the rain microphysics provide information on the overlying ice cloud?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16462, https://doi.org/10.5194/egusphere-egu2020-16462, 2020.

EGU2020-19008 | Displays | AS3.9

Effect of water confinement on heterogeneous ice nucleation

Olli Pakarinen, Golnaz Roudsari, Bernhard Reischl, and Hanna Vehkamäki

Understanding the formation of ice is of great importance to many fields of science. Sufficiently pure water droplets can remain in the supercooled liquid phase to nearly -40 ºC. Crystallization of ice in the atmosphere therefore typically occurs in the presence of ice nucleating particles (INPs), such as mineral dust or organic particles. These can trigger heterogeneous ice nucleation at clearly higher temperatures. Therefore, a better understanding of how the various types of aerosol particles present in the atmosphere affect ice nucleation (IN) in clouds would be an important advance in the field of atmospheric science.

Experiments have shown in great detail what is the IN activity of different types of compounds, and recently also clarified the importance of small surface features such as surface defects, which function as active sites for ice nucleation. On most mineral dust particles, there may be only a few active sites for ice nucleation, typically around defects or pits (Holden et al., 2019). Simulations also showed enhanced ice nucleation efficiency in confined geometry such as wedges or pits (Bi, Cao and Li, 2017).

We systematically study the effect of water confining defects with different surface geometries; pyramidal pits, wedge-shaped cracks and slits with water confined between two parallel walls, using molecular dynamics simulations with both all-atom and monatomic water models, and show that that these defects enhance ice nucleation both at large supercooling and at very low supercooling.

Results of simulations on pyramidal pits on Si (100) surfaces, realizable experimentally, show a clear (∆T > 10 ºC) enhancement of ice nucleation compared to the very weakly IN active flat Si (100) or Si (111) surfaces. To show that water confinement can enhance IN also at very low supercooling, at temperatures above −10 ºC, we constructed wedge shaped structures with β-AgI (0001) surface as one of the two side walls, and slit systems by positioning two β-AgI (0001) slabs to mirror each other to cancel the dipole field from the polar surfaces. Depending on the wedge angle or the relation of the width of the gap between two slabs in the slit systems with the thickness of ice bilayers, ice nucleation can be clearly enhanced or hindered. We also clarify the different mechanisms behind IN enhancement at different geometries.

Understanding the enhanced activity at surface features may enable characterization of ice nucleation active sites on some atmospheric particles, creation of IN active sites at otherwise poorly active materials such as silicon, and also enable enhancing very active IN materials such as AgI, to nucleate ice at nearly zero supercooling.

This work was supported by the Academy of Finland Center of Excellence programme (grant no. 307331) and ARKTIKO project 285067 ICINA, by University of Helsinki, Faculty of Science ATMATH project, by the National Center for Meteorology (NCM), Abu Dhabi, UAE, under the UAE Research Program for Rain Enhancement Science, as well as ERC Grant 692891-DAMOCLES. Supercomputing resources were provided by CSC–IT Center for Science, Ltd, Finland.

How to cite: Pakarinen, O., Roudsari, G., Reischl, B., and Vehkamäki, H.: Effect of water confinement on heterogeneous ice nucleation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19008, https://doi.org/10.5194/egusphere-egu2020-19008, 2020.

EGU2020-19183 | Displays | AS3.9

Influence of organic and biogenic substances on the ice nucleation properties of mineral dust particles

Kristian Klumpp, Claudia Marcolli, and Thomas Peter

The formation of ice in mixed phase clouds occurs in the presence of aerosol particles with the ability to nucleate ice on their surface. These ice-nucleating particles (INPs) represent usually a small fraction of particles in an atmospheric aerosol. One of the main particle types which act as INPs are mineral dust particles. Among other factors, the accumulation of semivolatile substances on the particle surface can alter the ice nucleation properties of such particles.

In recent immersion freezing experiments, we investigated the influence of organic acids, amino acids and polyols on the highly ice nucleation active K-feldspar microcline. Microcline dust was suspended in solutions of the above-mentioned substances and frozen in a differential scanning calorimeter (DSC). These experiments give us insight into the ice nucleation characteristics of the particles in the presence of the tested organic and biogenic substances. Our measurements show an overall decrease in ice nucleation activity of microcline in the presence of organic acids and amino acids.

How to cite: Klumpp, K., Marcolli, C., and Peter, T.: Influence of organic and biogenic substances on the ice nucleation properties of mineral dust particles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19183, https://doi.org/10.5194/egusphere-egu2020-19183, 2020.

EGU2020-20274 | Displays | AS3.9

The genesis of an ice sample matters!

Dominik Heger

We performed laboratory experiments to examine the relationship between the technique of preparing a frozen sample; its morphology; and chemical speciation. The luminescence of aromatic compounds (naphthalene, methylnaphthalene, anthracene) was utilized to learn about the extent of the compounds’ aggregation.

In aqueous solutions, the cooling rate determines the morphology of the resulting ice samples (analyzed with an environmental scanning microscope), (Vetráková, Neděla et al. 2019) the extent of the solute crystallization, and the plasticity of the freeze-concentrated solution (FCS) glass formed in the veins in between the ice crystals. Faster cooling allows higher degree of hydration of the aromatic compounds in the FCS. Conversely, vapor deposition of naphthalene on ice at 253 K results in microscopic naphthalene crystals, suggesting molecular mobility on the surface layer of ice at atmospherically relevant temperatures. (Ondrušková, Krausko et al. 2018) Surface acidity was proved via sulfonephthalein dyes, finding strong dependence on the salts present.(Imrichova, Vesely et al. 2019)

Our results connect the freezing methods and sample history with the compounds’ chemical identity in ice.

 

 

Imrichova, K., L. Vesely, T. M. Gasser, T. Loerting, V. Nedela and D. Heger (2019). "Vitrification and increase of basicity in between ice Ih crystals in rapidly frozen dilute NaCl aqueous solutions." J Chem Phys 151(1): 014503.

Ondrušková, G., J. Krausko, J. N. Stern, A. Hauptmann, T. Loerting and D. Heger (2018). "Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer." The Journal of Physical Chemistry C 122(22): 11945-11953.

Vetráková, Ľ., V. Neděla, J. Runštuk and D. Heger (2019). "The morphology of ice and liquid brine in an environmental scanning electron microscope: a study of the freezing methods." The Cryosphere 13(9): 2385-2405.

How to cite: Heger, D.: The genesis of an ice sample matters!, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20274, https://doi.org/10.5194/egusphere-egu2020-20274, 2020.

EGU2020-21557 | Displays | AS3.9

The ice-nucleating efficacy of glacial dust from the Copper River, Alaska

Sarah Barr, Bethany Wyld, Natalie Ratcliffe, Jim McQuaid, and Benjamin Murray

Ice nucleating particles (INPs) play an important role in the climate system by influencing cloud radiative properties, cloud lifetime and precipitation. An understanding of the interaction between INPs and clouds is needed in order to improve the accuracy of both climate projections and short term weather forecasts. In the high latitudes the influence of mid and low latitude sources of INPs (such as potassium feldspar from desert dust) is reduced and local sources could be important for ice nucleation. However, there is a scarcity of field observations and many dust sources which could be important sources of INPs have not been quantified. The south coast of Alaska, in particular the Copper River valley in the Valdez-Cordova region, is one such area where there are regular dust storms. These can clearly be seen from satellite imagery, which provides information on the frequency and extent of these outbreaks. In order to investigate the potential importance of the Copper River valley as a source of INPs we undertook a field campaign to collect samples in October 2019. During this campaign size segregated aerosol samples from the near surface (1.5  metre) were collected on to polycarbonate filter substrates using a multistage cascade impactor with 5 size categories in the range <0.25 μm to >2.5 μm. We collected samples during 7 dust emission events over a 10 day period. In addition, samples of dry sediment were collected from the surface. We used the University of Leeds Microlitre Nucleation by Immersed Particle Instrument (μL-NIPI) to quantify the ice nucleating ability of these samples. We also used laser diffraction particle size analysis to determine the surface area of particles to allow the subsequent calculation of ice active surface site density (ns). In addition, surface samples were separated in order to isolate the atmospherically relevant fraction (<10 μm) and used to determine the chemical composition of the dust using x-ray diffraction. This, combined with further work such as heat testing, will be used to identify what controls the ice nucleating efficacy in this dust and if there is an active biological contribution.  We will present the results from the field campaign and subsequent analysis. These results show high ice nucleating activity of the samples, comparable to glacial dust from other regions, and highlight the importance of glacial dust as a source of INPs in the high latitudes.

How to cite: Barr, S., Wyld, B., Ratcliffe, N., McQuaid, J., and Murray, B.: The ice-nucleating efficacy of glacial dust from the Copper River, Alaska, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21557, https://doi.org/10.5194/egusphere-egu2020-21557, 2020.

EGU2020-22458 | Displays | AS3.9

The sensitivity of ice-nucleating minerals to heat and implications for the detection of biogenic ice-nucleating particles

Martin Ian Daily, Thomas Francis Whale, and Benjamin John Murray

Ice nucleating particles (INP) are a subset of atmospheric aerosols which strongly influence the radiative properties and precipitation onset in mixed phase clouds. Mineral dust and biogenic particles such as bacteria, pollen and fungal spores can act as INP and are present in the atmosphere as internal or external mixtures. However, the sources, abundance and distribution of INP are poorly understood. The current widely accepted method of determining the relative contributions of mineral and biogenic INP is to treat INP samples with heat. This is based on the hypothesis that proteinaceous biogenic INP will be deactivated and mineral INP will be unaffected. However the hypothesis that mineral INP are never deactivated by heating not been tested to date. Mineral surfaces may undergo a range of geochemical reactions when heated in air or water and the potential effects of this on their ice nucleating activity is not known. We therefore subjected a range of atmospherically relevant minerals and atmospheric dust analogues to heat treatments equivalent to those used in the past studies. The samples were heated both as aqueous suspensions (100°C for 30 minutes) and in air as dry powders (250°C for 4 hours) and their ice nucleating activity was tested before and after treatment with a microlitre droplet freezing assay. We found that silica based samples showed a significant response to aqueous heating (reduction of median freezing temperature of a 1% suspension of up to 5.4°C) but little response to dry heating. Similar responses were seen in Arizona Test Dust and calcite. In contrast, K-feldspar samples were largely unaffected by aqueous heating but some showed mild deactivations when dry heated. Notably, K-feldspar was sensitive to longer heat treatments. Overall this survey shows that the assumption that mineral INP are completely inert to heat should be reconsidered in the context of using heat to ‘detect’ biogenic INP. We conclude that while INP heat tests are an effective method for positive detection of biogenic INP in ambient air samples they have the potential to produce false positives. For example, in a silica-rich mineral dust a deactivation may be related to the mineral component. Nevertheless, in samples where the mineral ice nucleating activity is determined by K-feldspar the aqueous heat test provides a valid qualitative test for proteinaceous biological INP.

How to cite: Daily, M. I., Whale, T. F., and Murray, B. J.: The sensitivity of ice-nucleating minerals to heat and implications for the detection of biogenic ice-nucleating particles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22458, https://doi.org/10.5194/egusphere-egu2020-22458, 2020.

AS3.10 – Photochemistry of aqueous phase organic matter in atmospheric and aquatic environments

Organic aerosol (OA) is an important component of the atmospheric submicron particulate mass, consisting of a complex mixture of organic compounds from natural and anthropogenic sources. During its lifetime of approximately one week in the atmosphere, OA is exposed to sunlight and thus undergoes atmospheric processing through photochemistry. This photochemical aging mechanism is thought to have a substantial effect on the propensity of OA to participate in cloud-forming processes by increasing its cloud condensation nuclei (CCN) activity. However, this effect is not well-constrained, and the influence of photochemistry on the ice nucleation (IN) activity of OA is uncertain. In this study, we aim to better understand how the photomineralization mechanism changes the cloud-forming properties of OA by measuring the CCN and IN abilities of photochemically aged OA of different sources: (1) Laboratory-generated ammonium sulfate-methylglyoxal (a proxy for secondary OA), and ambient OA bulk solutions collected from (2) wood smoke and (3) urban particulate matter in Padua (Italy). The solutions are exposed to UV-B radiation in a photoreactor for up to 25 hour and subsequently analyzed for their IN ability and, following aerosolization, for their CCN ability. To correlate changes in cloud-forming properties with changes in chemical composition due to photomineralization, we measure total organic carbon, UV-Vis absorbance, and CO, CO2, acetic acid, formic acid, pyruvic acid and oxalic acid production. Indeed, preliminary data of wood smoke OA highlights photomineralization as an important atmospheric aging process that modifies the CCN ability of OA. By characterizing both the CCN and IN abilities of photochemically aged OA, our study may thus provide important insights into the atmospheric evolution and cloud-forming properties of OA, potentially establishing photomineralization of OA as an important mechanism to consider in regional and global climate model predictions.

How to cite: Müller, S. and Borduas-Dedekind, N.: The effect of the photomineralization mechanism on ambient organic aerosols' cloud condensation nuclei and ice nucleation abilities, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-346, https://doi.org/10.5194/egusphere-egu2020-346, 2020.

EGU2020-348 | Displays | AS3.10

Photochemical production of sulfate from dissolved organic matter and atmospheric aqueous phases: Is there something in common?

Rachele Ossola, Baptiste Clerc, Julie Tolu, Lenny H. E. Winkel, and Kristopher McNeill

In a recent study, we showed that photodegradation of dissolved organic sulfur (DOS) from a wide range of natural terrestrial environments releases sulfate (SO42–) and other small and highly oxidized S-containing compounds as degradation products, similar to what had already been reported for dissolved organic carbon, nitrogen and phosphorous. However, the underlying chemical mechanism of photoproduction of sulfate is still unknown.

To fill this knowledge gap, we selected cysteine as a DOS model compound and we investigated its photodegradation to sulfate using model sensitizers as the source of singlet oxygen (1O2) and triplet excited states (3Sens*), two photochemically produced reactive species ubiquitous in sunlit surface waters. Using a combination of steady-state photochemistry experiments, kinetic modeling and mechanistic knowledge from the biochemistry literature, we reconstructed the molecular events that likely lead to the release of sulfate. We found that the release of SO2 via triplet-sensitized fragmentation of cysteine sulfinic acid, a 1O2 degradation product of cysteine, is a key step in the reaction mechanism. In the presence of oxygen and a photosensitizer, SO2 is then rapidly oxidized to SO42–.

Interestingly, nowadays there is great interest in the atmospheric chemistry community on the same transformation (i.e., aqueous phase oxidation of SO2 to SO42–) in the context of extreme haze events. Triplet-induced SO2 oxidation has already been proposed as a potential aqueous phase reaction that might explain the mismatch between measured and modelled sulfate concentrations, but the mechanism of this process is still not established. Our work provides an example of how mechanistic knowledge gained on the (photo)chemical behaviour of dissolved organic matter in aquatic systems can offer insights on processes occurring in atmospheric aqueous phases.

How to cite: Ossola, R., Clerc, B., Tolu, J., Winkel, L. H. E., and McNeill, K.: Photochemical production of sulfate from dissolved organic matter and atmospheric aqueous phases: Is there something in common?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-348, https://doi.org/10.5194/egusphere-egu2020-348, 2020.

EGU2020-1517 | Displays | AS3.10

Photochemistry versus biological activity towards organics in cloud water

Amina Khaled, Minghui Zhang, Pierre Amato, Anne-Marie Delort, and Barbara Ervens

The aqueous phase of clouds is a complex atmospheric medium containing a multitude of organic and inorganic species with different reactivities. The main oxidant towards organics in the aqueous phase is the OH radical. Many studies have identified biological material as a major fraction of ambient aerosol loading with bacteria being a small fraction. Laboratory experiments in our and other research groups have shown that microbial degradation of small organics (e.g., formic and acetic acids) can efficiently occur in artificial and real cloud water in competition to chemical radical reactions. However, in current models, it is usually assumed that bacteria are not metabolically active in the atmosphere. The aim of our study is to identify conditions, under which biological activity is significant in the multiphase system for specific organic compounds. Using a cloud multiphase process model, we compare the predicted fractions of organics consumed by radicals in the gas and aqueous phases to that by microbial processes of bacteria in the aqueous phase over large ranges of microphysical (e.g., cloud liquid water content, drop number), biological (cell concentration and activity) and chemical parameters (reaction rate constants and Henry’s law constants). We identify the organic properties and cloud parameters under which metabolic processes represent major atmospheric sinks for organics. In our cloud model, we consider the fact that only a small number fraction of droplets contain active bacteria cells. As many other models might not be able to describe such microphysical details, we also suggest simplified model approaches to represent microbial activity in clouds.

How to cite: Khaled, A., Zhang, M., Amato, P., Delort, A.-M., and Ervens, B.: Photochemistry versus biological activity towards organics in cloud water, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1517, https://doi.org/10.5194/egusphere-egu2020-1517, 2020.

EGU2020-2776 | Displays | AS3.10

Chemistry of Atmospheric Brown Carbon

Alexander Laskin

Fundamental understanding of the complex chemistry of light absorbing atmospheric aerosols (aka Brown Carbon - BrC), their physico-chemical properties and environmental impacts is a challenging task because no single method of analytical chemistry is capable of providing the full range of analytical chemistry information. Micro-spectroscopy approaches can visualize individual particles and their internal structures; however, they largely exclude molecular-level information, and are limited to elemental and chemical bonding characterization. Contemporary methods of high-resolution mass spectrometry can provide detailed information on the molecular content of BrC, but these methods use bulk particle samples and provide no knowledge of the individual particle composition. Therefore, application of complementary analytical methods of chemical analysis is necessary for comprehensive characterization of aerosol properties ranging from bulk molecular composition of BrC constituents to microscopy level details of individual particles. Combined assessment of the results provided by complementary analytical chemistry techniques offers unique insights to understand the composition and physico-chemical properties of BrC aerosols determining their effects on air quality and climate. This presentation will give an overview of recent field and laboratory studies of BrC with an overall goal to understand fundamental relationship between chemical transformations of airborne particles and their environmental and climate impacts.

How to cite: Laskin, A.: Chemistry of Atmospheric Brown Carbon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2776, https://doi.org/10.5194/egusphere-egu2020-2776, 2020.

EGU2020-3967 | Displays | AS3.10

The changing nature of particulate organic carbon and the relation to aerosol liquid water

Annmarie Carlton, Amy Christiansen, William Porter, and Madison Flesch

Particulate organic carbon (OC) mass concentrations demonstrate decreasing trends in many regions across the contiguous US (CONUS). We investigate decadal trends in specific total organic carbon (TOC) volatility fractions OC1, OC2, OC3, and OC4 as defined and reported at 121 locations in the Interagency Monitoring of PROtected Visual Environments (IMPROVE) monitoring network from 2005-2016 for 23 chemical climatology regions across the CONUS. Volatility fraction OC2 drives ubiquitous decadal decreases in TOC, and OC3 mass concentrations increase. The largest changes in OC2 and OC3 occur in the eastern US. In four focus regions (Northeast, Appalachia, West Texas, and Northwest), OC fraction mass concentrations are converted to organic mass (OM) using region-specific OM:OC ratios. GEOS-Chem simulations reproduce and correlate strongly (R2>0.7) with OM fraction decadal trends. Decreases in aerosol liquid water (ALW) concentrations are tightly linked to observed change in individual TOC thermal fractions, and aerosol products derived from aqueous-phase isoprene oxidation predicted by GEOS-Chem. These results lend insight to changing chemical regimes with implications for particle phase state, viscosity, and oxidation state.

How to cite: Carlton, A., Christiansen, A., Porter, W., and Flesch, M.: The changing nature of particulate organic carbon and the relation to aerosol liquid water, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3967, https://doi.org/10.5194/egusphere-egu2020-3967, 2020.

EGU2020-4909 | Displays | AS3.10

Tropospheric Aqueous-phase Oxidation of Green Leaf Volatiles with Hydroxyl, Sulfate and Nitrate Radicals

Kumar Sarang, Tobias Otto, Krzysztof Rudzinski, Irena Grgic, Klara Nestorowicz, Hartmut Herrmann, and Rafal Szmigielski

Introduction
 Numerous green leaf volatiles (GLVs) are released into the atmosphere due to the stress, cell damage or wounding. Fog forming over vegetation takes up these compounds, promoting their aqueous-phase oxidation to less volatile compounds. The droplets eventually dry out, leaving behind the secondary organic aerosol (SOA). These pathways are still poorly recognized as potentially novel routes for the formation of atmospheric SOA. Kinetic investigations of GLVs in the gas phase have already been reported by Shalamzari et. al. 2014, Davis et. al. 2011 and many others, while there is no kinetic data on the aqueous phase reactions of selected C6 and C5 GLVs. In the present study, we focussed on the kinetic studies of GLVs with the hydroxyl, sulfate and nitrate radicals as a possible source of aqueous SOA.

Experimental method
 The rate constants of reactions of GLVs with atmospherically relevant radicals were studied using a laser flash photolysis-laser long path absorption (LFP-LLPA). Kinetic investigations of GLVs with hydroxyl radicals were performed using competition kinetics, where H2O2 (2 x 10-4 mol L-1) was used as a radical precursor and KSCN (2 x 10-5 mol L-1) as a reference compound. The method is similar to that introduced by Behar, et al. 1972. Kinetic measurements of sulfate and nitrate radicals with GLVs, were done using a direct flash photolysis method, where sodium persulfate (5 x 10-4 mol L-1) was the precursor in the generation of SO4•ꟷ and sodium nitrate (1 x 10-1 mol L-1) and sodium sulfate (3 x 10-2 mol L-1) were the precursor for the generation of nitrate radicals.

Conclusions
 In the present study, we explored the kinetics of aqueous-phase reactions of three GLVs- 1-penten-3-ol, cis-2-hexen-1-ol and 2-E-hexenal - with atmospheric radicals SO4•ꟷ, OH and NO3. The second-order rate constants were determined for a temperature range of 278 K to 318 K. A weak temperature dependence was observed for the aqueous-phase kinetics of all three GLVs with selected atmospherically relevant radicals. To explain the weak temperature dependence of aqueous-phase reaction of GLVs with atmospheric radicals, rate constants were investigated for the diffusion limitation. The atmospheric significance of the aqueous-phase reaction was evaluated, by calculating aqueous-phase lifetime and their relative rate to the gas phase reactions with respective radicals, which clearly demonstrated their importance above the gas-phase reactions in tropospheric aqueous-phase. The present work is a part of the bigger research project on the aqueous-phase reactions of a series of atmospherically relevant GLVs whereas a next step oxidation products in the aqueous-phase are being investigated at a present stage. 

This project is supported by the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No. 711859 and by financial resources for science in the years 2017-2021 awarded by the Polish Ministry of Science and Higher Education for the implementation of an international co-financed project. The research project was also partially supported by funding under Project CREATE of European Union’s H2020 and ERASMUS PLUS staff mobility programme.

How to cite: Sarang, K., Otto, T., Rudzinski, K., Grgic, I., Nestorowicz, K., Herrmann, H., and Szmigielski, R.: Tropospheric Aqueous-phase Oxidation of Green Leaf Volatiles with Hydroxyl, Sulfate and Nitrate Radicals, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4909, https://doi.org/10.5194/egusphere-egu2020-4909, 2020.

EGU2020-5433 | Displays | AS3.10

Photochemical aging of organic aerosols at temperatures between 213 K and 293 K

Magdalena Vallon, Linyu Gao, Junwei Song, Feng Jiang, and Harald Saathoff

The chemical composition of aerosols, in both gas and particle phase, is an important factor regarding their properties influencing weather, climate and human health. Organic compounds are a major fraction of atmospheric aerosols and their composition depends on chemical processing by atmospheric oxidants and photochemical reactions. These processes are complex due to the abundance of possible reactions and reaction partners and rarely studied over a wider range of atmospheric temperatures. To get a better understanding of photochemical processes in the atmosphere we studied different organic test aerosols from simple to more complex systems between 213 K and 293 K in the AIDA simulation chamber at the Karlsruhe Institute of Technology.  Photochemical reactions were studied using a new LED light-source simulating solar radiation in the UV and visible. The organic aerosols were either generated in situ by oxidation of VOC with ozone, OH radicals and NO3 radicals or by nebulizing aqueous solutions containing the aerosol components.  The aerosols were analysed by a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and a high–resolution time-of-flight chemical ionization mass spectrometer (FIGAERO-HR-ToF-CIMS).  The latter one offers the possibility to study the composition of gas phase and particle phase separately. First results suggest that secondary organic aerosols from single precursors like toluene or α-pinene show no or only very small changes related to photochemistry even when formed in presence of high NOx concentrations. In contrast, aerosol particles containing molecules with larger mesomeric systems or atmospherically relevant photosensitizers show significant changes upon irradiation.

In this presentation, we will discuss the changes that organic aerosols undergo in gas and particle phase, during photochemical aging at temperatures between 213 and 293 K.

How to cite: Vallon, M., Gao, L., Song, J., Jiang, F., and Saathoff, H.: Photochemical aging of organic aerosols at temperatures between 213 K and 293 K, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5433, https://doi.org/10.5194/egusphere-egu2020-5433, 2020.

EGU2020-15572 | Displays | AS3.10

Effect of ammonium salts on the photochemical degradation of iron containing organic aerosol

Ulrich Krieger, Nir Bluvshtein, and Jing Dou

Formation of organic aerosol by oxidation of gas phase compounds has been intensely studied, and is much better understood than the aerosol ageing transformations during the lifetime of organic aerosol. Aerosol ageing influences how those aerosol particles affect climate and human health and is still not well constrained in current models.

Photochemistry in the condensed phase is an important mechanism responsible for ageing of organic aerosol. In the lower troposphere, where UV light intensity with sufficiently low wavelength to directly photolyze aerosol components is low, indirect photochemistry (catalyzing redox processes of non-absorbing molecules) is especially relevant. Recently we studied transition metal complex photochemistry in single particles levitated in an electrodynamic balance. In particular, we investigated the aqueous iron(III)-citrate/citric acid system and found that irradiation at 473 nm led to rapid and significant degradation of the citric acid. Up to 80% of the initial particle mass was partitioned to the gas phase with the degradation rate depending on kinetic transport limitations of oxygen. These kinetic limitations arise are influenced strongly by the relative humidity dependence of particle viscosity where water acts as a plasticizer.

Here we will report on photochemical degradation experiments adding various salts in different (ammonium sulfate, ammonium bisulfate, etc.) to the reference system iron(III)-citrate/citric acid. Preliminary experiments suggest that pH of the aerosol particle influences the degradation rate in this system significantly.

How to cite: Krieger, U., Bluvshtein, N., and Dou, J.: Effect of ammonium salts on the photochemical degradation of iron containing organic aerosol, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15572, https://doi.org/10.5194/egusphere-egu2020-15572, 2020.

AS3.11 – Multiphase chemistry of secondary aerosol formation under severe haze

EGU2020-10308 | Displays | AS3.11 | Highlight

Reducing urban new particle formation as a plausible solution to mitigate particulate air pollution in Beijing and other Chinese megacities

Markku Kulmala, Lubna Dada, Federico Bianchi, and Chao Yan and the Aerosol and Haze Laboratory Team

With multi- and interdisciplinary approaches we show that atmospheric secondary particles are the dominating contributor to haze formation in terms of aerosol number, surface area and mass. Supported by our comprehensive observations in Beijing during 15 January 2018– 15 January 2020, we show that 80–90% of the aerosol mass (PM2.5) was formed via atmospheric reactions during the haze days and over 65% of the number concentration of haze particles resulted from urban new particle formation (NPF). Furthermore, the haze formation was much faster when the subsequent growth of newly formed particles was enhanced (rapid growth). We found that since the direct emissions of primary particles in Beijing has gone down significantly within recent years, all present-day haze episodes we preceded by a urban NPF event. We are also able to show that reducing the subsequent growth of freshly formed particles by a factor of 3-5 would delay the buildup of haze episodes by 1–3 days. Actually, this delay will decrease the length of each haze episode and the number of annual haze days could be approximately halved. The improvement can be achieved with targeted reduction of NPF precursors, mainly dimethyl amine, ammonia and further reductions of SO2 emissions. Furthermore, reduction of anthropogenic VOC and nitrate emissions will slow down the growth rate of newly-formed particles and consequently reduce the haze formation. Our results show that the presence of haze decreases both boundary layer height and urban heat island intensity, which will further enhance haze particle number and mass concentrations over large spatial scales.

 

How to cite: Kulmala, M., Dada, L., Bianchi, F., and Yan, C. and the Aerosol and Haze Laboratory Team: Reducing urban new particle formation as a plausible solution to mitigate particulate air pollution in Beijing and other Chinese megacities , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10308, https://doi.org/10.5194/egusphere-egu2020-10308, 2020.

EGU2020-8262 | Displays | AS3.11

Kinetics of sulfuric acid-amine nucleation in the urban atmospheric environment

Runlong Cai, Chao Yan, Jun Zheng, Lin Wang, Markku Kulmala, and Jingkun Jiang

The formation of new secondary aerosols form gaseous precursors is a frequent phenomenon in various atmospheric environments and it impacts aerosol number concentration, cloud formation, and hence climate. There has been a considerable number of new particle formation (NPF) studies in various atmospheric environments, but current knowledge on NPF in the polluted atmospheric boundary layer (e.g., the urban environment in megacities) is still limited. The clustering of H2SO4 and amines is a possible mechanism driving the fast nucleation and initial growth of new particles in the polluted urban environment. Laboratory studies using typical ambient H2SO4 concentrations and theoretical calculations based on quantum chemistry have provided insights into H2SO4-amine nucleation. However, the molecular-level mechanism and governing factors for H2SO4-amine nucleation have not been quantitatively investigated in the real atmosphere. Some previous studies indicate that differently from clean environments, the coagulation scavenging is a governing factor for NPF in polluted environments. In the presence of a high aerosol concentration in the polluted environment, a considerable fraction of the newly formed particles are scavenged by coagulation within minutes and hence, NPF is significantly suppressed. Similarly, the coagulation scavenging may also impact the steady-state cluster concentrations and the new particle formation rate. Due to the differences in the coagulation scavenging and perhaps some gaseous precursor concentrations between laboratory and atmospheric conditions, the reaction kinetics determined in previous laboratory studies may not directly applicable to the real atmosphere. Herein, based on long-term atmospheric measurements from January 2018 to March 2019 in urban Beijing, we show the different reaction kinetics under laboratory and atmospheric conditions and how to unify them using proper normalization approaches. The influences of governing factors on particle formation rate are then quantitatively elucidated. Based on the synergistic effects of these factors, an indicator for the occurrence of NPF in the urban environment is proposed and verified.

How to cite: Cai, R., Yan, C., Zheng, J., Wang, L., Kulmala, M., and Jiang, J.: Kinetics of sulfuric acid-amine nucleation in the urban atmospheric environment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8262, https://doi.org/10.5194/egusphere-egu2020-8262, 2020.

EGU2020-7948 | Displays | AS3.11

Chemical Mixing State of Urban Haze Particles

Zhijun Wu, Yishu Zhu, Peter Alpert, Jing Dou, Taomou Zong, Song Guo, Ulrich K. Krieger, Markus Ammann, and Min Hu

EGU2020-18043 | Displays | AS3.11

Influence of size and mixing state on the wet scavenging of black carbon aerosol in the North China Plain

Xihao Pan, Nan Ma, Yaqing Zhou, Shaowen Zhu, Long Peng, Guo Li, Yuxuan Zhang, Jiangchuan Tao, Xinhui Bi, Qiang Zhang, Hang Su, and Yafang Cheng

Black carbon (BC) is the most important light-absorbing species in the atmosphere and has a strong positive direct radiative forcing. In-cloud scavenging is the major way to wash out BC from the atmosphere. Understanding the connection between its physico-chemical properties and scavenging efficiency is therefore a key to evaluate its lifetime, atmospheric burden and spatial distribution. During an intensive field campaign conducted in the North China Plain in 2019, a ground-based counterflow virtual impactor was utilized to separate fog droplets in radiation fog events. BC mass and mixing state of fog droplet residues were online measured with a single particle soot photometer (SP2). In a strong radiation fog event with visibility of about 50 m, more than 20% fog droplets are found to contain a BC core. BC scavenging efficiency is found to be strongly determined by its diameter and mixing state. Driven by different mechanisms, higher scavenging efficiencies up to 10% are observed for larger and smaller BC particles, and the minimum efficiency is found at BC diameter of 120 nm. For large core (>120 nm) BC-containing particles, the scavenging efficiency increases significantly with coating thickness (CT), from about 10% for CT<100 nm to 80% for CT>300 nm. Chemical composition may also be a key parameter influencing the scavenging of BC. Based on the observation of 3 fog events, parameterizations of BC scavenging efficiency are also given in this study.

How to cite: Pan, X., Ma, N., Zhou, Y., Zhu, S., Peng, L., Li, G., Zhang, Y., Tao, J., Bi, X., Zhang, Q., Su, H., and Cheng, Y.: Influence of size and mixing state on the wet scavenging of black carbon aerosol in the North China Plain, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18043, https://doi.org/10.5194/egusphere-egu2020-18043, 2020.

EGU2020-7 | Displays | AS3.11

Hygroscopic properties of saline mineral dust from different regions in China

Mingjin Tang, Huanhuan Zhang, and Wenjun Gu

Saline mineral dust particles, emitted from saline topsoil in arid and semi-arid regions, contribute significantly to tropospheric aerosol particles. However, hygroscopic properties of saline mineral dust particles, especially for those found in regions other than North America, are poorly understood. In this work we investigated hygroscopic properties of thirteen saline mineral dust samples collected from different locations via measuring sample mass change as different relative humidity (RH, up to 90%), and measured their chemical and mineralogical compositions using ion chromatography and X-ray diffraction. The mass growth factors at 90% RH, defined as the sample mass at 90% RH relative to that at <1% RH, were found to display large geographical variations, spanning from ~1.02 to 6.7, and the corresponding single hygroscopicity parameters (κ) were derived to be in the range of <0.01 to >1.0. The saline components (mainly Na+, Cl- and SO42-) contained by saline mineral dust particles largely determined their hygroscopicity, and the predicted mass growth factors at 90% RH using an aerosol thermodynamic model (ISORROPIA-II), agreed with measured values within 20% for most of samples examined, though larger discrepancies also occurred for three samples. Our results improve our understanding in hygroscopicity of saline mineral dust particles and thus their heterogeneous chemistry and ability to serve as cloud condensation nuclei to form cloud droplets.

How to cite: Tang, M., Zhang, H., and Gu, W.: Hygroscopic properties of saline mineral dust from different regions in China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7, https://doi.org/10.5194/egusphere-egu2020-7, 2020.

EGU2020-12687 | Displays | AS3.11

Comparison of volatility, hygroscopicity and oxidation state of submicron aerosols over the Pearl River Delta region in China

Shuang Han, Juan Hong, Hanbing Xu, Haobo Tan, Fei Li, Lin Wang, and Nan Ma

Volatility and hygroscopicity properties of atmospheric particles with dry sizes of 60 and 145 nm were measured by using a Volatility-Hygroscopicity Tandem Differential Mobility Analyzer (VH-TDMA) at a suburban site over the Pearl River Delta region in China during the late summer of 2016. Specifically, volatility properties of the aerosols were studied by heating the ambient samples step-wise to seven temperatures ranging from 30 to 300℃. In general, particles started to evaporate at the heating temperature of 100℃. After heating the aerosols above 200℃, the probability density function of the volatility growth factor showed an apparent bimodal distribution with a distinct non-volatile mode and a volatile mode, indicating that the particle population was mainly externally mixed. Even at 300℃, around 20% of the aerosol volume still remained in the particle phase (non-volatile material). Black carbon (BC) mass fraction of aerosol mass correlated well (R2≈ 0.5) with the volume fraction remaining (VFR) at 300℃, but could not explain the non-volatile residual alone. On the basis of the comparison analysis between the VFR at different temperatures and the hygroscopic growth factor (HGF) at 90% RH, we observed the non-volatile residual material were hygroscopic (HGF=1.45). These results indicate that the observed non-volatile residual material at 300℃ did not consist solely of black carbon, but some other compounds such as sea salt, low-volatile ammonium or organic polymer.

How to cite: Han, S., Hong, J., Xu, H., Tan, H., Li, F., Wang, L., and Ma, N.: Comparison of volatility, hygroscopicity and oxidation state of submicron aerosols over the Pearl River Delta region in China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12687, https://doi.org/10.5194/egusphere-egu2020-12687, 2020.

Secondary organic aerosol (SOA) is an important component of fine particular matter (PM2.5) in China. Most air quality models use an equilibrium partitioning method along with estimated saturation vapor pressure of semi-volatile organic compounds (SVOCs) to predict SOA formation. However, this method ignores partitioning of water vapor to the organic aerosols and the organic phase non-ideality, both of which affect the partitioning of SVOCs. In this study, the Community Multi-scale Air Quality model (CMAQv5.0.1) was used to investigate the above impacts on SOA formation during winter (January) and summer (July) of 2013 over eastern China. The organic aerosol module was updated by incorporating water partitioning into the organic particulate matter (OPM) and considering non-ideality of organic-water mixture. The modified model can generally capture the observed organic carbon (OC), the total organic aerosol (OA) and diurnal variation of PM2.5 at ground sites. SOA concentration shows significant seasonal and spatial variations, with high concentration levels in North China Plain (NCP), Central China and Sichuan basin (SCB) areas during winter (up to 25 μg m-3) and in Yangtze River Delta (YRD) during summer (up to 12 μg m-3). When water partitioning is included in winter, SOA concentrations increase slightly, with the monthly-averaged daily maximum relative difference of 10-20% at the surface and 10-30% for the whole column, mostly due to the increase in anthropogenic SOA. The increase in SOA is more significant in summer, by 20-90% at the surface and 30-70% for the whole column. The increase of SOA over the land is mostly due to biogenic SOA while the increase of SOA over the coastal regions is related with that of anthropogenic origin. Further analysis of two representative cities, Jinan and Nanjing, shows that changes of SOA are favored under hot and humid conditions. The increases in SOA cause a 12% elevation in the aerosol optical depth (AOD) and 15% enhancement in the cooling effects of aerosol radiative forcing (ARF) over YRD in summer. The aerosol liquid water content associated with OPM (ALWorg) at the surface is relatively high over the land in winter and over the ocean in summer, with the monthly-averaged daily maximum of 2-9 and 5-12 μg m-3, respectively. By using the -Köhler theory, we calculated the hygroscopicity of OA with modeled ALWorg, finding that the correlation with O:C ratio varies significantly across different cities and seasons. Water partitioning into OPM only promotes SOA formation, while non-ideality of organic-water mixture only leads to decreases in SOA in most regions of eastern China. Water partitioning into OPM should be considered in air quality models in simulating SOA, especially in hot and humid environments.

How to cite: Li, J., Ying, Q., and Hu, J.: Impacts of water partitioning and polarity of organic compounds on secondary organic aerosol over Eastern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2803, https://doi.org/10.5194/egusphere-egu2020-2803, 2020.

EGU2020-1319 | Displays | AS3.11 | Highlight | AS Division Outstanding ECS Lecture

Aerosol Pollution in Asia and Its Interactions with Climate

Meng Gao

With rapidly expanding economic and industrial developments and tremendous increases in energy consumption, China and India are facing serious aerosol pollution, posing great threat to human health. Aerosols also modulate the climate and ecosystems via aerosol-cloud-radiation interactions. Yet, the poor understanding of aerosol pollution in Asia and its interactions with climate impedes the design and implementation of effective pollution control measures. Combining atmospheric modeling and observations, we demonstrated that the aerosol interactions with radiation and clouds contributed in important ways to intensification of the aerosol enhancements in North China. We manifested also how assimilation of PM2.5 in winter haze periods can improve model predictions and that these improved predictions can reduce significantly the uncertainties in health impacts and estimates of aerosol radiative forcing. It was also demonstrated that the conditions of the ocean temperature in fall can be effectively used to predict the severity of Indian winter haze, which provides useful implications for pollution control at least a season in advance.

How to cite: Gao, M.: Aerosol Pollution in Asia and Its Interactions with Climate, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1319, https://doi.org/10.5194/egusphere-egu2020-1319, 2020.

EGU2020-19687 | Displays | AS3.11 | Highlight

Aerosol Chemistry and Effects in the Anthropocene

Gregory Carmichael

Atmospheric aerosols impact air quality and human health. They also play a key role in the Earth’s weather and climate systems.  Aerosol amounts and physical and chemical properties determine their toxicity, radiative and microphysical impacts. Recent advances in observations and models are significantly enhancing our ability to quantify the distribution and properties of aerosols, understand their impacts on atmospheric radiation and cloud distributions and properties, and their presence near the Earth’s surface and the resulting impacts to human health. There is a need for closer integration of aerosols into numerical prediction systems. The World Meteorological Organization has set a strategic goal to advance earth systems modeling to enhance seamless prediction of environmental, weather and climate services across spatial and temporal scales. In this talk the need for this approach and the opportunities and advances will be discussed.

How to cite: Carmichael, G.: Aerosol Chemistry and Effects in the Anthropocene, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19687, https://doi.org/10.5194/egusphere-egu2020-19687, 2020.

EGU2020-9793 | Displays | AS3.11

Modelling the photochemical formation of high H2O2 concentrations and secondary sulfate observed during winter haze periods in the NCP

Andreas Tilgner, Erik Hans Hoffmann, Lin He, Bernd Heinold, Can Ye, Yujing Mu, Hui Chen, Jianmin Chen, and Hartmut Herrmann

During winter, the North China Plain (NCP) is frequently characterized by severe haze conditions connected with extremely high PM2.5 and NOx concentrations, i.e. strong air pollution. The NCP is one of the most populated regions worldwide where haze periods have direct health effects. Tropospheric haze particles are a complex multiphase and multi-component environment, in which multiphase chemical processes are able to alter the chemical aerosol composition and deduced physical aerosol properties and can strongly contribute to air pollution. Despite many past investigations, the chemical haze processing is still uncertain and represents a challenge to atmospheric chemistry research. Recent NCP studies during autumn/winter 2017 haze periods have revealed unexpected high H2O2 concentrations of about 1 ppb suggesting H2O2 as a potential contributor to secondary PM2.5 mass, e.g., due to sulfur(IV) oxidation. However, the multiphase H2O2 formation under such NOx concentrations is still unclear. Therefore, the present study aimed at the examination of potential multiphase H2O2 formation pathways, and the feedback on sulfur oxidation.

Multiphase chemistry simulations of a measurement campaign in the NCP are performed with the box model SPACCIM. The multiphase chemistry model within SPACCIM contains the gas-phase mechanism MCMv3.2 and the aqueous-phase mechanism CAPRAM4.0 together with both its aromatics module CAPRAM-AM1.0 and its halogen module CAPRAM-HM2.1. Furthermore, based on available literature data, the multiphase chemistry mechanism is extended considering further multiphase formation pathways of HONO and an advanced HOx mechanism scheme enabling higher in-situ H2O2 formations in haze particles. The simulations have been performed for three periods characterized by high H2O2 concentrations, high RH and PM2.5 conditions and high measurement data availability. Several sensitivity runs have been performed examining the impact of the soluble transition metal ion (TMI) content on the predicted H2O2 formation.

Simulations with the improved multiphase chemistry mechanism shows a good agreement of the modelled H2O2 concentrations with field data. The modelled H2O2 concentration shows a substantial dependency on the soluble TMI content. Higher soluble TMI contents result in higher H2O2 concentrations demonstrating the strong influence of TMI chemistry in haze particles on H2O2 formation. The analysis of the chemical production and sink fluxes reveals that a huge fraction of the multiphase HO2 radicals and nearly all of the subsequently formed reaction product H2O2 is produced in-situ within the haze particles and does not origin from the gas phase. Further chemical analyses show that, during the morning hours, the aqueous-phase reaction of H2O2 with S(IV) contributes considerably to S(VI) formation beside the HONO related formation of sulfuric acid by OH in the gas-phase.

Finally, a parameterization was developed to study the particle-phase H2O2 formations as potential source with the global model ECHAM-HAMMOZ. The performed global modelling identifies an increase of gas-phase H2O2 by a factor of 2.8 through the newly identified particle chemistry. Overall, the study demonstrated that photochemical reactions of HULIS and TMIs in particles are an important H2O2 source leading to increased particle sulfate formation.

How to cite: Tilgner, A., Hoffmann, E. H., He, L., Heinold, B., Ye, C., Mu, Y., Chen, H., Chen, J., and Herrmann, H.: Modelling the photochemical formation of high H2O2 concentrations and secondary sulfate observed during winter haze periods in the NCP, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9793, https://doi.org/10.5194/egusphere-egu2020-9793, 2020.

A suite of instruments were deployed to simultaneously measure nitrous acid (HONO), nitrogen oxides (NOx= NO + NO2), carbon monoxide (CO), ozone (O3), volatile organic compounds (VOCs, including formaldehyde (HCHO)) and meteorological parameters near a typical industrial zone in Nanjing of the Yangtze River Delta region, China. High levels of HONO were detected using a wet chemistry-based method. HONO ranged from 0.03-7.04 ppbv with an average of 1.32 ±0.92 ppbv. Elevated daytime HONO was frequently observed with a minimum of several hundreds of pptv on average, which cannot be explained by the homogeneous OH + NO reaction (POH+NO) alone, especially during periods with high loadings of particulate matters (PM2.5). The HONO chemistry and its impact on atmospheric oxidation capacity in the study area were further investigated using a MCM-box model. The results show that the average hydroxyl radical (OH) production rate was dominated by the photolysis of HONO (7.13×106molecules cm-3 s-1), followed by ozonolysis of alkenes (3.94×106molecules cm-3 s-1), photolysis of O3(2.46×106molecules cm-3 s-1) and photolysis of HCHO (1.60×106molecules cm-3 s-1), especially within the plumes originated from the industrial zone. The observed similarity between HONO/NO2and HONO in diurnal profiles strongly suggests that HONO in the study area was likely originated from NO2heterogeneous reactions. The averagenighttimeNO2to HONO conversion ratewas determined to be ~0.9% hr-1. Good correlation between nocturnal HONO/NO2and the products of particle surface area density (S/V) and relative humidity (RH), S/V×RH,supports the heterogeneous NO2/H2O reaction mechanism. The other HONO source, designated as Punknonwn, was about twice as much as POH+NO on average and displayed a diurnal profile with an evidently photo-enhanced feature, i.e., photosensitized reactions of NO2may be an important daytime HONO source. Nevertheless, our results suggest that daytime HONO formation was mostly due to the light-induced conversion of NO2on aerosol surfaces but heterogeneous NO2reactions on ground surface dominated nocturnal HONO production. Concurred elevated HONO and PM2.5levels strongly indicate that high HONO may increase the atmospheric oxidation capacity and further promote the formation of secondary aerosols, which may in turn synergistically boost NO2/HONO conversion by providing more heterogeneous reaction sites.

How to cite: Zheng, J., Shi, X., and Ma, Y.: Heterogeneous formation of HONO and its impacts on haze formation in the YRD region of China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3202, https://doi.org/10.5194/egusphere-egu2020-3202, 2020.

High–concentration particulate matter (PM) at East Asia threatens human health and potentially alters climate. High levels of SO2, NOx and NH3 emissions attribute the formation of inorganics including sulfates, nitrates and ammoniums in PM. Consequently, PM contains a large fraction of these inorganics, and aerosol liquid water (ALW) is considered to promote inorganic PM formation. A thermodynamic model has been used to estimate inorganic concentrations and a pH of PM because PM can be viewed as an ammonium-sulfate-nitrate-water system, which maintains thermodynamic equilibriums between the gas and particle phase and in the aqueous phase within particles. However, gas–particle partitioning of semivolatile inorganic species (i.e., NH3–NH4 + and HNO3–NO3-) particularly influenced by organics and aqueous-phase secondary organic aerosol (aqSOA) formation in PM through multiphase chemistry are not well understood.

We conducted smog chamber experiments for OH-radical initiated reactions of toluene in the presence of ammonium sulfate seed particles under high NOx, NH3 and humid conditions, which were similar to high-concentration haze conditions at Seoul, Korea. Measurements of inorganic concentrations in particles agree well with outputs of thermodynamic model simulations. The nitrate increase in seed particles is most prominent because ALW enhances the uptake of total HNO3 photochemically formed from NOx. We identified methylglyoxal as a precursor for aqSOA formation. It appears that organics attribute ALW formation under deliquescence relative humidity for inorganic salts. We further investigated the response of particle mass concentrations to various NOx concentrations, which can be useful for NOx controls for PM reduction.

How to cite: Lim, Y., Do, D., Jin, H., Lee, J., and Kim, J. Y.: Photochemistry of toluene under high NOx, NH3 and humid conditions in the presence of inorganic seed particles: a smog chamber study for urban haze formation at East Asia, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13236, https://doi.org/10.5194/egusphere-egu2020-13236, 2020.

EGU2020-12014 | Displays | AS3.11

Multifactor colorimetric analysis on pH-indicator papers: an optimized approach for direct determination of ambient aerosol pH

Guo Li, Hang Su, Nan Ma, Guangjie Zheng, Uwe Kuhn, Meng Li, Thomas Klimach, Ulrich Pöschl, and Yafang Cheng

Direct measurement of the acidity (pH) of ambient aerosol particles/droplets has long been a challenge for atmospheric scientists.  A novel and facile method was introduced recently by Craig et al. (2018), where the pH of size-resolved aerosol droplets was directly measured by two types of pH-indicator papers (pH ranges: 0 – 2.5 and 2.5 – 4.5) combined with RGB-based colorimetric analyses using a model of G-B (G minus B) versus pH2.  Given the wide pH range of ambient aerosols, we optimize the RGB-based colorimetric analysis on pH papers with a wider detection range (pH ~ 0 to 6).  Here, we propose a new model to establish the linear relationship between RGB values and pH: pHpredict = a×Rnormal + b×Gnormal + c×Bnormal.  This model shows a wider applicability and higher accuracy than those in previous studies, and is thus recommended in future RGB-based colorimetric analyses on pH papers.  Moreover, we identify one type of pH paper (Hydrion® Brilliant pH dip stiks, Lot Nr. 3110, Sigma-Aldrich) that is more applicable for ambient aerosols in terms of its wide pH detection range (0 to 6) and strong anti-interference capacity.  The determined minimum sample mass (~ 180 µg) highlights its potential to predict aerosol pH with a high time resolution (e.g., ≤ 1 hour).  We further show that the routinely adopted way of using pH color charts to predict aerosol pH may be biased by the mismatch between the standard colors on the color charts and the real colors of investigated samples.  Thus, instead of using the producer-provided color chart, we suggest an in-situ calibration of pH papers with standard pH buffers.

Reference:

Craig, et al., Direct determination of aerosol pH: Size-resolved measurements of submicrometer and supermicrometer aqueous particles. Analytical Chemistry, 90 (19), 11232-11239, 2018.

Cheng, et al., Reactive nitrogen chemistry in aerosol water as a source of sulfate during haze events in China. Science Advances, 2 (12), e1601530, 10.1126/sciadv.1601530, 2016.

Zheng, et al., Exploring the severe winter haze in Beijing: The impact of synoptic weather, regional transport and heterogeneous reactions. Atmospheric Chemistry and Physics, 15, 2969-2983, 2015.

Li, et al., Multifactor colorimetric analysis on pH-indicator papers: an optimized approach for direct determination of ambient aerosol pH, Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2019-394, in review, 2019.

How to cite: Li, G., Su, H., Ma, N., Zheng, G., Kuhn, U., Li, M., Klimach, T., Pöschl, U., and Cheng, Y.: Multifactor colorimetric analysis on pH-indicator papers: an optimized approach for direct determination of ambient aerosol pH, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12014, https://doi.org/10.5194/egusphere-egu2020-12014, 2020.

EGU2020-2340 | Displays | AS3.11

How Are Strong Acids or Strong Bases Substituted by Weak Acids or Weak Bases in Aerosols?

Zhe Chen, Na Wang, Shu-Feng Pang, and Yun-Hong Zhang

Due to significant influence on global climate and human health, atmospheric aerosols have attracted numerous interests from the atmospheric science community. To provide insight into the aerosol effect, it is indispensable to investigate the aerosol properties comprehensively.

Since atmospheric aerosols are surrounded by substantial gas phase and have high specific surface area, the composition partitioning between particle phase and gas phase must be considered as a key aerosol property, which is termed as volatility for volatile organic/inorganic components. Recent studies show that the aerosol volatility can also be induced by the reaction of components in addition to the volatile compositions. Herein, we summarize four types of volatility induced by reaction, namely chloride depletion, nitrate depletion, ammonia depletion and volatility induced by salt hydrolysis. For chloride depletion and nitrate depletion, these processes can be regarded as reactions that strong acids are substituted by weak acids. The high volatility of the formed HCl or HNO3 drives the reaction continuously moving forward.

For ammonium depletion, we observed the reaction occurs between (NH4)2SO4 and organic acid salts during dehydration process by ATR-FTIR. For example, when molar ratio is 1:1, significant depletion of ammonium was observed in the disodium succinate/(NH4)2SO4 particles, indicating the evaporation of NH3. Besides, the hygroscopicity of the aerosol particles decreased after the dehydration, which should be attributed to the formation of less hygroscopic succinic acid and ammonium depletion. By regarding organic acid salts as weak bases, the ammonium depletion is a reaction that strong base substituted by weak base, driving by the continuous release of NH3. In addition to volatility induced by reactions within multi-component aerosols, we also found that the salt hydrolysis can also cause the formation of volatile product. For magnesium acetate (MgAc2) aerosols, we found significant water loss of the aerosol particles under constant relative humidity condition, while the amount of acetate was also decreased. We infer that the acetic acid (HAc) evaporation is caused by the hydrolysis of MgAc2, leading to the volatility and declined hygroscopicity. Two factors contribute to the volatility of MgAc2 aerosols. One is the volatile acid donner (Ac2-), which can lead to the formation of volatile HAc. The other is the residual ion accepter (Mg2+), which can combine residual OH- after the proton is depleted by the evaporation of HAc. The formation of insoluble Mg(OH)2 effectively maintains the aqueous pH in a suitable range, keeping the reaction moving forward. It should be noted that the co-exist of volatile acid donner and residual ion accepter is indispensable for the volatility induced by hydrolysis.

Generally, for the volatile species present in atmosphere, the aerosol volatility induced by the reaction of components can be an important pathway for their recycling processes. Due to the substantial composition modification, the hygroscopicity is also affected by such reaction. Therefore, this partitioning behavior of aerosols needs to be considered in the future atmospheric aerosol study, which may prevent the underestimate of particle volatilization or overestimate of hygroscopicity.

How to cite: Chen, Z., Wang, N., Pang, S.-F., and Zhang, Y.-H.: How Are Strong Acids or Strong Bases Substituted by Weak Acids or Weak Bases in Aerosols?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2340, https://doi.org/10.5194/egusphere-egu2020-2340, 2020.

EGU2020-8194 | Displays | AS3.11

Exploring the trends and potential drivers of surface ozone in eastern China in 2015-2018

Ning Yang, Yanru Bai, Yong Zhu, Nan Ma, and Qiaoqiao Wang

In the last six years, China has experienced significant improvement in air quality due to great emission reduction efforts. However, ozone concentrations are still slowly increasing in three major regions of eastern China, respectively Jing-Jin-Ji(JJJ), Yangtze River Delta region(YRD) and Pearl River Delta region(PRD). It is shown from the 2015-2018 national urban air quality real-time release platform that the surface ozone in JJJ, YRD and PRD has increased each year and reached the highest in 2018. The monthly ozone concentration peaked in June in almost all cities of JJJ, while it had multiple peaks in other two regions (summer and autumn in YRD - and February, May and September in PRD). Simulation with a chemical transport model(GEOS-Chem) indicates that the formation of ozone is affected by the optical properties of PM2.5 and also the heterogeneous uptake of N2O5 on sea salt aerosol.

How to cite: Yang, N., Bai, Y., Zhu, Y., Ma, N., and Wang, Q.: Exploring the trends and potential drivers of surface ozone in eastern China in 2015-2018, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8194, https://doi.org/10.5194/egusphere-egu2020-8194, 2020.

EGU2020-19363 | Displays | AS3.11

Particle production in the upper troposphere over the Amazon Basin

Lixia Liu, Hang Su, Ulrich Pöschl, and Yafang Cheng

Particle production in the upper troposphere has been reported as an important source of aerosol particles and cloud condensation nuclei in pristine environment and tropical regions and exerts significant climate effects. In this work, we develop a new organic nucleation scheme to the WRF-Chem model with extended particle size bins from 1nm to 10μm. We improve on previous coarse-resolution global simulations that approximate the highly oxygenated multifunctional organic compounds (HOMs) in a thermodynamic state by implementing kinetic calculation of HOMs and using fine-grid regional simulations. Sensitivity studies are conducted over the Amazon Basin during the dry season in 2014 to characterize the HOMs-induced new particle formation and identify its key controlling factors in Amazon. The model simulations are evaluated using aircraft observations of profiles of aerosol particles during the 2014 ACRIDICON-CHUVA campaign. We show that the new particle formation occurs mostly at the upper troposphere and modestly in the planetary boundary layer, driven by low temperature and high concentration of biogenic precursors, respectively. Including the HOMs-induced biogenic new particle formation mechanism decreases the model prediction bias of the particle number concentration in the upper troposphere by over 50%, suggesting an important role of the HOMs-induced biogenic new particle formation in the dry season over the Amazon region.

How to cite: Liu, L., Su, H., Pöschl, U., and Cheng, Y.: Particle production in the upper troposphere over the Amazon Basin, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19363, https://doi.org/10.5194/egusphere-egu2020-19363, 2020.

EGU2020-16757 | Displays | AS3.11

McFAN experiment: An integrated analysis of the multiphase chemistry experiment in Fogs and Aerosols in the North China Plain

Hang Su, Nan Ma, Yele Sun, Jiangchuan Tao, Pingqing Fu, and Yafang Cheng

Fine-particle pollution associated with winter haze threatens the health of more than 400 million people in the North China Plain. The Multiphase chemistry experiment in Fogs and Aerosols in the North China Plain (McFAN) investigated the physical-chemical mechanisms leading to the haze formation with a focus on the contributions of multiphase processes in aerosol and fogs. We integrated multiple platform observations with regional and box models to identify the key oxidation process producing sulfate, nitrate and secondary organic aerosols, and their impact. A new environmental chamber was deployed to conduct kinetic experiments with real atmospheric compositions in comparison to literature kinetic data from laboratory studies. The experiments were carried out for multiple years since 2017 at the Gucheng site in the center of polluted areas and have performed experiments in the winter season. The location of the site minimizes fast transition between clean and polluted air masses (e.g., in Beijing), and helps to maintain a pollution regime representative for the North China Plain. The multi-year consecutive experiments documented the trend of PM2.5 pollution and corresponding change of aerosol physical and chemical properties, and allowed to investigate newly proposed mechanisms. The preliminary results show new proofs of the key role of aqueous phase reactions in regulating the aerosol compositions during haze events.

Reference:

Zheng et al., Exploring the severe winter haze in Beijing: the impact of synoptic weather, regional transport and heterogeneous reactions. Atmospheric Chemistry and Physics 15, 2969-2983 (2015).

Cheng et al., Reactive nitrogen chemistry in aerosol water as a source of sulfate during haze events in China. Science Advances 2,  (2016).

Li et al., Multifactor colorimetric analysis on pH-indicator papers: an optimized approach for direct determination of ambient aerosol pH. Atmos. Meas. Tech. Discuss. 2019, 1-19 (2019).

Kuang et al., Distinct diurnal variation of organic aerosol hygroscopicity and its relationship with oxygenated organic aerosol. Atmos. Chem. Phys. Discuss. 2019, 1-33 (2019).

 

How to cite: Su, H., Ma, N., Sun, Y., Tao, J., Fu, P., and Cheng, Y.: McFAN experiment: An integrated analysis of the multiphase chemistry experiment in Fogs and Aerosols in the North China Plain, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16757, https://doi.org/10.5194/egusphere-egu2020-16757, 2020.

EGU2020-8156 | Displays | AS3.11

Particle number size distribution measurements of PM1 and PM10 in fogs and implications on fog droplet evolutions

Jiangchuan Tao, Nan Ma, Yanyan Zhang, Ye Kuang, Juan Hong, Hang Su, and Yafang Cheng

Recent wintertime observations in north China found high concentrations of nitrous acid (HONO), secondary organic aerosols (SOA) and peroxyacetyl nitrate (PAN), especially during heavy haze periods, indicating stronger atmospheric oxidation capacity in winter haze days. Researchers speculated that HONO formation was enhanced in haze days through NO2 heterogeneous reaction on aerosol surfaces, and high concentrations of HONO during daytime further improved SOA and PAN formation.

In this study, the WRF-Chem model updated with six potential HONO sources was used to quantify the impacts of potential HONO sources on the production and loss rates of ROx ( OH+HO2+RO2) radicals, and on the concentrations of SOA and PAN in the Beijing-Tianjin-Hebei (BTH) region of China during wintertime of 2017. HONO simulations were greatly improved after considering the six potential sources, NO2 heterogeneous reactions were the main sources of HONO. HONO photolysis was the key precursors of primary OH while the contribution of O3 photolysis to OH could be neglected, the potential HONO sources remarkably accelerated ROx cycles, significantly improved SOA and PAN simulations, especially in heavy polluted periods. The above results suggest that the potential HONO sources should be considered in regional and global chemical transport models when conducting relevant studies.

How to cite: Zhang, J. and An, J.: Effect of potential HONO sources on ROx budgets and SOA and PAN formation in North China in winter, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1438, https://doi.org/10.5194/egusphere-egu2020-1438, 2020.

We coupled the heterogeneous hydrolysis of N2O5 into the newly updated Weather Research and Forecasting model with Chemistry (WRF-Chem) to reveal the relative importance of the hydrolysis of N2O5 and additional nitrous acid (HONO) sources for the formation of nitrate during high PM2.5 events in the North China Plain (NCP) in four seasons. The results showed that additional HONO sources produced the largest nitrate concentrations in winter and negligible nitrates in summer, leading to a 10% enhancement of a PM2.5 peak in southern Beijing and a 15% enhancement in southeastern Hebei in winter. In contrast, the hydrolysis of N2O5 produced high nitrate in summer and low nitrate in winter, with the largest contribution of nearly 20% for a PM2.5 peak in southeastern Hebei in summer. During PM2.5 explosive growth events, the additional HONO sources played a key role in nitrate increases in southern Beijing and southwestern Hebei in winter, whereas the hydrolysis of N2O5 contributed the most to a rapid increase in nitrate in other seasons. HONO photolysis produced more hydroxyl radicals, which were greater than 1.5 μg m-3 h-1 in the early explosive stage and led to a rapid nitrate increase at the southwestern Hebei sites in winter, while the heterogeneous reaction of N2O5 contributed greatly to a significant increase in nitrate in summer. The above results suggest that the additional HONO sources and the heterogeneous hydrolysis of N2O5 contributed the most to nitrate formation in NCP in winter and summer, respectively.

How to cite: Qu, Y. and An, J.: Seasonal effects of additional HONO sources and the heterogeneous reactions of N2O5 on nitrate in the North China Plain, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1476, https://doi.org/10.5194/egusphere-egu2020-1476, 2020.

As a characteristic pollutant of urban compound pollution, submicron particulate matter (PM1) has significantly impacted on human health and climate change. In this study, four intensive campaigns using a high-resolution time-of-flight AMS (HR-ToF-AMS) and other online instruments from 2016 to 2017 were conducted to investigate the seasonal characteristics of submicron particles in Shanghai. The average mass concentrations of submicron particulate matter during spring, summer, autumn and winter observations in Shanghai are 23.9 ± 20.7 μg/m3, 28.5 ± 17.6 μg/m3, 22.0 ± 17.2 μg/m3 and 31.9 ± 22.7 μg/m3, respectively. The major chemical components in submicron particulate matter showed obvious seasonal and daily variations. The increase of submicron particulate matter is mainly due to the contribution of nitrate in spring, autumn and winter, while the photochemical reaction promotes the rapid growth of sulfate in summer. Detailed source apportionment of organic aerosol showed that the fraction of more oxidized oxygenated organic aerosol in organic aerosol in spring was much lower than primary organic aerosol. Oxygenated organic aerosol dominated organic aerosol in summer (69%). More oxidized oxygenated organic aerosol account for 28% in autumn, suggesting that organic aerosol was aging. The liquid phase oxidation and the strong photochemical reaction concentration have a significant contribution to the formation of more oxidized oxygenated organic aerosol and less oxidized oxygenated organic aerosol in the spring, summer and winter observations, respectively. However, the photochemical reaction process dominated the formation of more oxidized oxygenated organic aerosol in autumn.

How to cite: Zhu, W., Lou, S., and Guo, S.: Seasonal variations in chemical characterization of submicron aerosol particles in Shanghai, China: Insights from a high-resolution aerosol mass spectrometry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6458, https://doi.org/10.5194/egusphere-egu2020-6458, 2020.

EGU2020-21501 | Displays | AS3.11

Aerosol chemical composition and formation of secondary aerosol during haze events at the SORPES station in China

Jiaping Wang, Jinbo Wang, Wei Nie, Xuguang Chi, Jiandong Wang, and Aijun Ding

Haze pollution is a serious air quality concern in China up to now, which occurs frequently in mega city clusters, e.g. Beijing-Tianjin-Hebei and Yangtze River Delta region, especially in the cold season. Understanding the dominating secondary aerosol formation processes is vital for improving the prediction and emission control strategy of haze pollution. In this study, we reported measurements of aerosol chemical composition using the soot particle aerosol mass spectrometer (SP-AMS) at a regional background station, the Station for Observing Regional Processes of the Earth System (SORPES), in Nanjing, eastern China. Characteristics of aerosol chemical composition and dominating secondary aerosol formation processes were analyzed during typical haze events and compared with that in clean episodes. Sources and transportation of organic aerosol were performed using positive matrix factorization (PMF) together with backward Lagrangian particle dispersion modeling (LPDM).

How to cite: Wang, J., Wang, J., Nie, W., Chi, X., Wang, J., and Ding, A.: Aerosol chemical composition and formation of secondary aerosol during haze events at the SORPES station in China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21501, https://doi.org/10.5194/egusphere-egu2020-21501, 2020.

BIO-MAÏDO is a French collaborative program founded by the ANR (Agence Nationale de La Recherche). BIO-MAÏDO aims at better understanding the chemical and biological multiphasic mechanisms that control the Secondary Organic Aerosol (SOA) formation. The tropical environment of the Reunion Island represents an ideal site to study SOA formation: (1) numerous biogenic volatile organic compounds, precursors of SOA are emitted in huge amount and the high solar intensity flux and the temperature favors their chemical transformations; (2) due to the high occurrence of orographic clouds over this region, this site allows evaluating the influence of aqueous processes on SOA formation. The strategy adopted is based on an intensive field campaign over several sites with the objective to characterize sources of gases and aerosols and to evaluate multiphasic pathways controlling the formation and oxidation of SOA. This work is done in synergy with modeling investigations using a lagrangian particle dispersion model (FLEXPART), a 0D process cloud model (CLEPS) together with a 3D chemistry/transport model (Meso-NH).

The campaign took place from 13th of March to 4th of April 2019 at La Réunion Island. The main objectives were to document the cloud cycle on the slope of the Maïdo, the boundary layer development and the chemical evolution of atmospheric composition (primary and secondary aerosols as well as gaseous precursors) along the slope up to the receptor site, the Maïdo observatory. For this reason, the campaign took place on five sites distributed on the slope from the Maïdo to the observatory. A innovative instrumentation was deployed: three PTR-MS, a tethered balloon, an instrumented mast measuring biogenic volatile organic compounds fluxes, a mobile mast with a cloud impactor, etc. Preliminary results from the campaign will be presented.

How to cite: Leriche, M. and Colomb, A. and the BIO-MAÏDO: The BIO-MAÏDO (Bio-physicochemistry of tropical clouds at Maïdo (La Réunion Island): processes and impacts on secondary organic aerosols formation) campaign, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19029, https://doi.org/10.5194/egusphere-egu2020-19029, 2020.

Firework (FW) emissions have strong impacts on air quality and public health. However, little is known about the molecular composition of FW-related aerosols especially the organic fraction. Here we describe the detailed molecular composition of Beijing aerosols collected before, during, and after a FW event in New Year's Eve evening. Subgroups of CHO, CHNO, CHOS, and CHNOS were characterized using ultrahigh resolution Fourier transform-ion cyclotron resonance (FT-ICR) mass spectrometry. We found that high molecular weight compounds with relatively low H/C and O/C ratios and high degree of unsaturation were greatly enhanced during the New Year’s Eve, which are likely to be aromatic-like compounds. They plausibly contributed to the formation of brown carbon and affect the light absorption properties of atmospheric aerosols. Moreover, the number concentration of sulfur-containing compounds especially the nitrooxy-organosulfate was increased dramatically by the FW event, suggesting the important effect of nighttime chemistry on their formation. But, the number concentration of CHO and CHON doubled after the event with photooxidation. The co-variation of these subgroups was suggested to be associated with multiple atmospheric aging processes of aerosols including the multiphase redox chemistry driven by NOx, O3, and ·OH. Our study provides new insights into the anthropogenic emissions for urban SOA formation.

How to cite: Xie, Q. and Fu, P.: Molecular Characterization of Firework-Related Urban Aerosols using FT-ICR Mass Spectrometry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12532, https://doi.org/10.5194/egusphere-egu2020-12532, 2020.

EGU2020-8008 | Displays | AS3.11

Evaluation of multi-component ensemble simulation of PM2.5 in the Pearl River Delta region

Qian Wu, Xiao Tang, Lei Kong, Miaomiao Lu, and Zifa Wang

Sulfate, nitrate, ammonium, organic carbon and black carbon are the key components of PM2.5, but their simulations are still facing high uncertainty. Exploring the sources of such uncertainty is important for the modeling of PM2.5 and the understanding of atmospheric chemical processes. This study aims to evaluate and investigate the modeling uncertainty of these aerosols over Pearl River Delta (PRD) region based on Monte Carlo simulations of a Nested Air Quality Prediction Modeling System (NAQPMS) during 2015. Emission inventory as one of the most important uncertainty sources are perturbed according to their uncertainties to derive 50 ensemble simulations of NAQPMS with 15km horizontal resolution. The surface observations of sulfate, nitrate, ammonium, OC and BC from 10 sites in PRD region for one year are used to evaluation the performance of the ensemble mean estimation of the simulations. The results suggested that the ensemble mean could well reproduce the spatial and temporal variations of nitrate, ammonium, OC and BC with the correlation coefficients above 0.74 and their mean bias less than 2μg·m-3 . However, the model has poor skills in the sulfate modeling with the correlation coefficients 0.26 and remarkable underestimation in winter. Further analysis for such modeling uncertainties suggested that the uncertainties in emissions can explain most of modeling uncertainties for BC and OC. However, the biases in sulfate and ammonium modeling especially during the wintertime are probably caused by the uncertainty in heterogeneous reaction modeling. The above results provide an overall assessment of the uncertainty in inorganic aerosol modeling over PRD region and can serve a basis for its simulation improvement.

How to cite: Wu, Q., Tang, X., Kong, L., Lu, M., and Wang, Z.: Evaluation of multi-component ensemble simulation of PM2.5 in the Pearl River Delta region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8008, https://doi.org/10.5194/egusphere-egu2020-8008, 2020.

EGU2020-12155 | Displays | AS3.11

Size-resolved effective density of submicron particles during autumn in the North China Plain

Yaqing Zhou, Nan Ma, Zhibin Wang, Linhong Xie, Baofang Xie, Shaowen Zhu, Xihao Pan, Sen Wu, Hang Su, and Yanfang Cheng

Effective density is one of the most important physical property of atmospheric aerosols, which is link to particle formation and aging process. Combined characterization of density, chemical composition and source evolution of aerosol is crucial for understanding their interactions and effects on environment and climate. The effective density of sub-micrometer aerosol particles was investigate at a heavily polluted rural site in the North China Plain from 16 October to 1 November 2019. A tandem technique coupling a Centrifugal Particle Mass Analyzer (CPMA) with a differential mobility analyzer (DMA) and a Condensation Particle Counter (CPC) were used to determine the effective density of ambient aerosol particles with selected diameters of 50, 100, 150, 220 and 300 nm. The measured effective density is higher during clean period than pollution period, with average values ranged from 1.13 to 1.36 g/cm3, which is lower than the reported values in Shanghai and Beijing. Similar diurnal cycles of effective density are observed for the five diameters, that is, started to increase in the morning and reached a peak in the afternoon around 13:00-16:00, then decreased and remained at a relative low value during the night. Two valleys are found during morning and evening rush hours for particle diameter smaller than 150 nm, which is likely to stem from the higher fresh emissions such as BC, BBOA and HOA. In most cases, measured particle effective density shows a single-modal distribution. But during clean days, bimodal distribution was observed with an extra low-density mode peaking at around 0.5 -1.0 g/cm3, which may be attributed to freshly emitted soot particles.

How to cite: Zhou, Y., Ma, N., Wang, Z., Xie, L., Xie, B., Zhu, S., Pan, X., Wu, S., Su, H., and Cheng, Y.: Size-resolved effective density of submicron particles during autumn in the North China Plain, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12155, https://doi.org/10.5194/egusphere-egu2020-12155, 2020.

EGU2020-20887 | Displays | AS3.11

Formation of low molecular weight mono- and di-carboxylic acids and related compounds from photochemical oxidation of stearic and linoleic acids in aqueous-phase

Chandra Mouli Pavuluri, Subba Rao Devineni, Zhanjie Xu, Kimitaka Kawamura, Pingqing Fu, Yan-Lin Zhang, and Cong-Qiang Liu

Secondary organic aerosols (SOA) that account for a substantial and often a dominant fraction of total OA mass are formed by photooxidation of various precursors derived from anthropogenic and biogenic sources in the atmosphere. They have serious impacts on the Earth’s climate system directly by scattering and absorbing solar radiation and indirectly by acting as cloud condensation nuclei, and adverse effects on human health. In recent times, considerable attention has been paid on laboratory studies, preferably in gas-phase, in order to understand the chemistry of SOA formation. However, the studies on SOA formation in aqueous phase are limited, which are mainly focused on high abundant volatile organic compounds (e.g., isoprene) and/or their oxidation products, but not on fatty acids (except oleic acid). To better understand the air-water interface photochemistry of fatty acids and their transformations to lower homologous monoacids and more oxygenated species such as diacids and related compounds in atmospheric waters (fog, cloud and aqueous aerosol), we conducted batch UV irradiation experiments on a saturated (stearic acid, C18H36O2) and an unsaturated (linoleic acid, C18H32O2) fatty acids for different time periods (age, 0-120 h) in aqueous-phase. All the irradiated samples were analyzed for measurements of mono- and di-acids, oxoacids and α-dicarbonyls. We found high abundances of monoacids followed by diacids, pyruvic acid and α-dicarbonyls in less aged samples, whereas C3 and C4 diacids were abundant in the more aged samples. Our results imply that the photochemical oxidation of fatty acids and subsequent transformations of the product species in atmospheric waters are significant and their contribution to more oxygenated SOA is increased with aging in the atmosphere.

How to cite: Pavuluri, C. M., Devineni, S. R., Xu, Z., Kawamura, K., Fu, P., Zhang, Y.-L., and Liu, C.-Q.: Formation of low molecular weight mono- and di-carboxylic acids and related compounds from photochemical oxidation of stearic and linoleic acids in aqueous-phase, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20887, https://doi.org/10.5194/egusphere-egu2020-20887, 2020.

EGU2020-12389 | Displays | AS3.11

Oxidative Potential and Chemical Characteristics of Ambient PM2.5 in Guangzhou, China

Peng Cheng, Manman Zhang, and Yongjie Li

The dithiothreitol (DTT) assay is widely used to characterize the Oxidation Potential (OP) of atmospheric particulate matter (PM), which can cause adverse effects on human health. However, it’s under debate which chemical species determines the consumption rate of DTT. During January and April 2018, we measured the improved DTT assay of daily PM2.5 samples collected in Guangzhou, China with complimentary measurements of water-soluble ions, organic/elemental carbon (OC/EC) and metal elements. The average sampled air volume normalized consumption rate of DTT (DTTv) was 4.67 ±1.06 and 4.45 ± 1.02 nmol min-1 m-3, in January and April, respectively while the average PM2.5 mass normalized consumption rate of DTT (DTTm) was 13.47 ± 3.86 and 14.66 ± 4.49 pmol min-1 μg-1. Good correlations were found between DTTv and concentration of PM2.5, OC, and EC while no correlation was found between DTTm and concentrations of water-soluble ions, OC, EC or metal element, which is consistent with most early observations. We also evaluated the contribution of soluble metals to DTT assay by addition of EDTA, a strong metal chelator. We found that nearly 90% of DTTv and DTTm were reduced by EDTA, suggesting a dominant role of soluble metals in determining the response of DTT to ambient PM2.5. Based on responses of DTT to soluble metals in literature, we found that Cu(II) and Mn(II) are the major contributors to OP of PM2.5 in Guangzhou. The correlation coefficient between DTTm and OC shows a clear increase after addition of EDTA, implying that the response of DTT to quinones is not strongly suppressed by EDTA.

How to cite: Cheng, P., Zhang, M., and Li, Y.: Oxidative Potential and Chemical Characteristics of Ambient PM2.5 in Guangzhou, China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12389, https://doi.org/10.5194/egusphere-egu2020-12389, 2020.

EGU2020-14982 | Displays | AS3.11

Aerosol pH and regime transition of sulfate formation in aerosol water during winter haze events in northern China

Wei Tao, Hang Su, Guangjie Zheng, Jiandong Wang, Lixia Liu, Chao Wei, Meng Li, Qiang Zhang, Ulrich Poschl, and Yafang Cheng

Understanding the formation mechanism of severe haze is crucial for the development of efficient pollution control strategy. Recently, multiphase reactions in aerosol water has been suggested as an important source of sulfate aerosol during severe haze (Zheng et al., 2015;Cheng et al., 2016). Though several oxidation mechanisms have been recognized, the dominant oxidation pathway is still under debate reflecting a missing consensus. Based on a model survey with Weather Research and Forecasting model coupled with Chemistry (WRF-Chem), we have investigated the variability of aerosol pH and regimes of sulfate formation through multiphase oxidation during the haze episodes in January of 2013. Our results show a large spatial and temporal variability in the aerosol pH and sulfate formation regimes. Surface aerosol pH shows a clear diurnal variation with low pH during daytime and high pH during night-time for most cases. Aerosol pH tends to decrease with increasing altitude in the lower atmosphere. For the scenario best reproduces the observations in Beijing, NO2, TMI+O2, O3 and H2O2 pathways can all dominate the production of sulfate in specific areas of the Beijing-Tianjin-Hebei (BTH) region. With the increasing height, O3 pathway and gas phase oxidation by OH radicals become more important. Moreover, sensitivity tests also suggest that, emissions of crustal particles, NH3 and soluble iron/manganese have great impacts on aqueous phase chemistry, and should be better constrained in future studies.

References:

Zheng, G. J., Duan, F. K., Su, H., Ma, Y. L., Cheng, Y., Zheng, B., Zhang, Q., Huang, T., Kimoto, T., Chang, D., Poschl, U., Cheng, Y. F., and He, K. B.: Exploring the severe winter haze in Beijing: the impact of synoptic weather, regional transport and heterogeneous reactions, Atmos. Chem. Phys., 15, 2969-2983, 10.5194/acp-15-2969-2015, 2015.

Cheng, Y. F., Zheng, G. J., Wei, C., Mu, Q., Zheng, B., Wang, Z. B., Gao, M., Zhang, Q., He, K. B., Carmichael, G., Poschl, U., and Su, H.: Reactive nitrogen chemistry in aerosol water as a source of sulfate during haze events in China, Sci Adv, 2, e1601530, UNSP e1601530,10.1126/sciadv.1601530, 2016.

How to cite: Tao, W., Su, H., Zheng, G., Wang, J., Liu, L., Wei, C., Li, M., Zhang, Q., Poschl, U., and Cheng, Y.: Aerosol pH and regime transition of sulfate formation in aerosol water during winter haze events in northern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14982, https://doi.org/10.5194/egusphere-egu2020-14982, 2020.

             After years of development, Mie lidar has become an important technical means to explore aerosol particles in the atmosphere, and has been widely used to explore the optical and physical properties of aerosols in atmosphere. By Using backscatter signal collecting by lidar, optical characteristics of aerosols can be qualitatively analyzed. However, in order to get the actual value of optical parameters, the accurate lidar ratio (LR) (the ratio of extinction coefficient to back-scattering coefficient) is needed in inversion.

            Using the Mie scattering theory, the key parameter of inversion: LR, can be measured out. The value of LR has been discussed in detail by changing complex refractive index, size parameter  and field angle of a single particle. It is found that when the scale parameter is greater than 0.6, the value of LR increases first and then decreases with the increasing scale parameter, and there are several extremums; the value of LR decreases with the increasing imaginary part of the complex refractive index; the value of LR increases with the increasing filed angle.

            To study the influence of different mixing states on optical parameters of aerosol clusters, a three-component optical equilibrium spherical aerosol model is assumed. The results shows that when the mixing states of aerosol are complete external mixture, complete uniform internal mixture and complete coated mixture, the value of LR appears to be: complete uniform internal mixture > complete external mixture > complete coated mixture.

            Assuming that the hygroscopic growth factor of aerosol is a constant which does not increase with the particle size and its value is GF = 1.5[p2] , the value of LR after hygroscopic growing is discussed. It is found that the value of LR will increase after hygroscopic growing, but it still follows the law that: complete uniform internal mixture > complete external mixture > complete coated mixture.

            By correcting the value of LR, accurate extinction coefficient and back-scattering coefficient can be measured out with inversion. The production of lidar will be quantified instead of qualitative after doing this.

How to cite: zhang, Z.: Study on the influence of different aerosol mixing states on lidar ratio, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21217, https://doi.org/10.5194/egusphere-egu2020-21217, 2020.

EGU2020-18014 | Displays | AS3.11

Mass-based mixing state of black carbon measured by a tandem CPMA-SP2 system in wintertime in the North China Plain

Shaowen Zhu, Nan Ma, Xihao Pan, Wenlin Dong, Jiangchuan Tao, Juan Hong, Yuxuan Zhang, Guo Li, Jeannine Ditas, Hang Su, and Yafang Cheng

Black carbon (BC) is the most important light absorbing component in the atmosphere and has significant impacts on the climate, environment and public health. Its effects depend not only on its spatial-temporal distribution, but also on its physico-chemical characteristics. Mixing state is one of the most important properties of BC and strongly determines its hygroscopicity and radiative properties. During an intensive field campaign conducted in the North China Plain in winter 2018, mass-based mixing state of BC-containing particles were online measured with a Centrifugal Particle Mass Analyzer and Single Particle Soot Photometer (CPMA-SP2) tandem system. This technique directly provides the mass ratio of non-refractory coating matter to BC core (MR) in individual particles and does not require to assume the density, morphology and refractive index of BC core and coating in data retrieval, therefore has lower uncertainly compared with leading-edge fit technique. In our measurement, the mean number fraction of uncoated (MR=0), thin coated (0<MR<3) and thick coated (MR≥3) BC-containing particle during the campaign were respectively ~10%, ~35% and ~55%, indicating the strong aging process of BC-containing particle in the North China Plain. The median value of MR was much higher in polluted days than clean days, for example, the median value of MR with a particle mass of 8.56 fg (~220 nm in diameter) for polluted and clean days were ~3.2 and ~1.6, respectively. The mixing state of BC-containing particles obtained by different methods were also compared and evaluated.

How to cite: Zhu, S., Ma, N., Pan, X., Dong, W., Tao, J., Hong, J., Zhang, Y., Li, G., Ditas, J., Su, H., and Cheng, Y.: Mass-based mixing state of black carbon measured by a tandem CPMA-SP2 system in wintertime in the North China Plain, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18014, https://doi.org/10.5194/egusphere-egu2020-18014, 2020.

AS3.12 – Connecting the oxidation of organic compounds with the role of peroxy radicals, RO2, and aerosol properties

EGU2020-10345 | Displays | AS3.12

New pathways of the reaction of OH radicals with dimethyl sulfide based on CH3SCH2O2 isomerization

Torsten Berndt, Wiebke Scholz, Bernhard Mentler, Lukas Fischer, Erik Hans Hoffmann, Andreas Tilgner, Noora Hyttinen, Nonne Prisle, Armin Hansel, and Hartmut Herrmann

Dimethyl sulfide (DMS), produced by marine organisms, represents the most abundant, biogenic sulfur emission into the Earth´s atmosphere. The gas-phase degradation of DMS is mainly initiated by the reaction with the OH radical forming first CH3SCH2O2 radicals from the dominant H-abstraction channel. A fast CH3SCH2O2 isomerization process was proposed as a result of quantum chemical calculations. In the present study, experimental investigations on the product formation from OH + DMS have been conducted in a free-jet flow system at 295 ± 2 K and 1 bar air. Very efficient detection of CH3SCH2O2 isomerization products has been achieved by iodide-CI-APi-TOF measurements allowing to run the reaction for close to atmospheric conditions. It is experimentally shown that the CH3SCH2O2 radicals undergo a two-step isomerization process finally forming a product consistent with the formula HOOCH2SCHO. The isomerization process is accompanied by OH recycling. The rate-limiting first isomerization step, CH3SCH2O2 → CH2SCH2OOH proceeds with k = (0.23 ± 0.12) s-1 at 295 ± 2 K. Competing bimolecular CH3SCH2O2 reactions with NO, HO2 or RO2 radicals are less important for trace-gas conditions over the oceans.  Results of atmospheric chemistry simulations demonstrate the predominance (≥95%) of CH3SCH2O2 isomerization. The rapid peroxy radical isomerization, not yet considered in models, substantially changes the understanding of DMS´s degradation processes in the atmosphere.

How to cite: Berndt, T., Scholz, W., Mentler, B., Fischer, L., Hoffmann, E. H., Tilgner, A., Hyttinen, N., Prisle, N., Hansel, A., and Herrmann, H.: New pathways of the reaction of OH radicals with dimethyl sulfide based on CH3SCH2O2 isomerization, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10345, https://doi.org/10.5194/egusphere-egu2020-10345, 2020.

EGU2020-20144 | Displays | AS3.12 | Highlight

Alkane autoxidation and aerosol formation: new insights from combustion engines to the atmosphere

Mikael Ehn, Zhandong Wang, Matti Rissanen, Olga Garmash, Lauriane Quéléver, Manuel Monge-Palacios, Pekka Rantala, Neil Donahue, Torsten Berndt, and Mani Sarathy

Autoxidation is a process whereby organic compounds become oxidized by molecular oxygen (O2). It is ubiquitous in various reaction systems, contributing to the spoilage of food and wine, ignition in internal combustion engines, and formation of atmospheric secondary organic aerosol (SOA) from volatile emissions. Autoxidation thus greatly influences both engine operation and efficiency, and, via SOA, climate and air quality. Recent progress in atmospheric chemistry has identified double bonds and oxygen-containing moieties as structural facilitators for efficient autoxidation, and subsequent OA formation. Lacking either of these functionalities, alkanes, the primary molecular class in fuels for combustion engines and an important class of urban trace gases, have been expected to have low susceptibility to undergo autoxidation. In this work, we show that alkanes can indeed undergo efficient autoxidation both under combustion-relevant and atmospheric temperatures, consequently producing more highly oxygenated species than previously expected. By bridging methodologies and knowledge from both combustion and atmospheric chemistry, we mapped the autoxidation potential of a range of alkane structures under various conditions, from the combustion domain to the atmospheric domain. We identified the importance of isomerization steps driven by both peroxy and alkoxy radicals, and show that isomerization and production of low-volatile condensable vapors is efficient even under highly polluted ([NO]>10ppb) conditions. Our findings, currently under review, provide insights into the underlying chemical mechanisms causing highly variable SOA yields from alkanes, which were observed in previous atmospheric studies. The results of this inter-disciplinary effort provide crucial new information on oxidation processes in both combustion engines and the atmosphere, with direct implications for engine efficiency and urban air quality.

How to cite: Ehn, M., Wang, Z., Rissanen, M., Garmash, O., Quéléver, L., Monge-Palacios, M., Rantala, P., Donahue, N., Berndt, T., and Sarathy, M.: Alkane autoxidation and aerosol formation: new insights from combustion engines to the atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20144, https://doi.org/10.5194/egusphere-egu2020-20144, 2020.

EGU2020-6360 | Displays | AS3.12

Secondary Organic Aerosol Formation of Ambient Intermediate Volatility Organic Compounds: Implication from Gasoline Vehicles

Rongzhi Tang, Quanyang Lu, Wenfei Zhu, Kai Song, Hanyun Fan, Rui Tan, Kefan Liu, Ying Yu, Ruizhe Shen, Hui Wang, Shiyi Chen, Allen L. Robinson, and Song Guo

Intermediate volatility organic compounds (IVOCs) have been proposed to be great contributors to SOA formation. In this study, we performed comprehensive measurement of ambient IVOCs and calculated their SOA production at an urban site Peking University Urban Atmospheric Environment Monitoring Stations (PKUERS). Results showed that the campaign-average concentration IVOCs was 62.5 ± 45.2 μg·m-3 (average ± standard deviation), which is comparable to the emission of VOCs. Only ~10% of the IVOCs could be speciated, with most of the IVOCs existing as unresolved complex mixture (UCM). Back trajectory analysis showed that clusters from near south has the highest IVOC concentration, suggesting the importance to control the IVOC emissions from the polluted regions of China. Using the OH exposure estimated by o-xylene to benzene and m/p-xylene to benzene, the estimated daily average SOA concentration was 5.8 ±3.4 μg·m-3, in which IVOCs contributed 15 times that of single-ring aromatics. The estimated vehicular-SOA could be 1.04 ± 0.7 μg·m-3. Considering its high SOA formation potential, this study highlights the importance to study the IVOC emissions in China.

How to cite: Tang, R., Lu, Q., Zhu, W., Song, K., Fan, H., Tan, R., Liu, K., Yu, Y., Shen, R., Wang, H., Chen, S., Robinson, A. L., and Guo, S.: Secondary Organic Aerosol Formation of Ambient Intermediate Volatility Organic Compounds: Implication from Gasoline Vehicles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6360, https://doi.org/10.5194/egusphere-egu2020-6360, 2020.

EGU2020-3415 | Displays | AS3.12

Using explicit mechanisms of Secondary Organic Aerosol (SOA) formation and evolution to extrapolate chamber studies to the atmosphere

Joel A Thornton, John Shilling, Havala Pye, Emma D'Ambro, Maria Zawadowicz, and Jiumeng Liu

 

The applicability of chamber-derived Secondary Organic Aerosol (SOA) yields to the atmosphere remains a key uncertainty in modeling SOA. The chemical and environmental conditions achieved in chambers are narrower than and often significantly biased from those experienced in the atmosphere. We present results from applying explicit chemical mechanisms in a dynamic gas-particle partitioning model (FOAM-WAM) to simulate SOA formation and evolution from a range of chamber experiments involving isoprene and monoterpenes. We focus on how such comparisons can highlight the applicability, or the lack thereof, of derived SOA yields, extrapolate measured SOA yields to more complex chemical or environmental conditions, and identify key gaps in chemical or physical mechanisms and thus feedback on chamber experiment design and earth system model parameterizations. In particular, we show that current mechanisms of low-NOx isoprene and a-pinene oxidation that incorporate RO2 H-shift reactions can adequately explain corresponding fresh SOA without the need for substantial vapor-pressure lowering accretion chemistry, while substantial particle-phase photo-chemistry is required to explain the dynamic evolution of SOA characteristics (volatility, O/C ratios, etc)observed in chambers at longer aging times. We find that chemical conditions, such as absolute concentrations, are as important as vapor wall loss, or even more so, at perturbing SOA yields from realistic values. Consistent with recent field studies but in contrast to previous chamber studies, our modeling predicts that low-NOx isoprene oxidation is unlikely to produce significant SOA in warm boundary layers, except through isoprene epoxy-diol multi-phase chemistry. Current mechanisms are unable to reproduce the non-linear response of isoprene-derived photochemical SOA with NOx observed in multiple chambers, suggesting a potentially important missing mechanism of volatility reduction at intermediate NOx concentrations in that system. 

How to cite: Thornton, J. A., Shilling, J., Pye, H., D'Ambro, E., Zawadowicz, M., and Liu, J.: Using explicit mechanisms of Secondary Organic Aerosol (SOA) formation and evolution to extrapolate chamber studies to the atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3415, https://doi.org/10.5194/egusphere-egu2020-3415, 2020.

Biomass burning emissions, domestic- and wild-fires, agricultural burning, and fuel use, emit a blend of gases and particles with adverse effects on humans-health, climate and air quality. Furans are heterocyclic organic compounds (OVOC) that have been recently identified as important biomass burning emission-products. It is estimated that furan (C4H4O), 2-methylfuran (C5H6O), 2-furaldehyde (C5H4O2) and benzofuran (C8H6O) emission levels are 70 to 120 times higher compared to CO. Once furans are emitted in the atmosphere, they will undergo gas phase chemistry and, to an extent, they will be photolyzed at actinic wavelengths. OH and NO3 radicals, Cl atoms and O3 chemistry might result in tropospheric O3 and in secondary organic aerosols (SOA) formation, which might be enhanced due to their potent low volatility. Therefore, it is essential to investigate the kinetics and the mechanism of all the photochemically induced degradation pathways and identify and quantify SOA precursors, so as to evaluate their impact on Air-Quality and Climate.

 

Within this framework, a thorough laboratory study, using two complementary techniques has been carried out. First, major atmospheric oxidants reaction rate coefficients with furans were determined. Secondly, the degradation mechanisms were investigated from both kinetic and conversion-yields perspectives. A Teflon atmospheric simulation chamber, named THALAMOS (THermALly regulated AtMOSpheric simulation chamber), was used to study the reactions at atmospheric pressure. State-of-the-art in-line instrumentation, e.g., FTIR spectroscopy and Chemical ionization mass spectrometry, were used for the real-time monitoring of reactants and products. To further our understanding, the reactions rate coefficients were also measured at 2 mTorr, between 253 and 363 K, with the continuous flow technique of the Very Low Pressure Reactor, in which an effusive molecular beam is analyzed with Quadrupole Mass Spectrometry (VLPR/QMS). Intercomparing the results from the two techniques reactions mechanistic-scheme was mapped-out and their impact was evaluated.

 

OH and NO3 radicals and Cl atoms reactions with all the furans were measured to be in the order of 10-11, 10-10 and 10-12 cm3 molecule-1 s-1, respectively, leading to atmospheric-lifetimes between 2 and 10 hours. Temperature and pressure dependent kinetic measurements revealed association as the dominant reaction channel. However, experiments at very-low-pressure regime showed that HCl elimination cannot be excluded, especially when the furan-ring aromaticity is not breaking.

 

Finally, it is evident that furans degradation will occur at low altitudes and SOA precursors, i.e., end-oxidation products will be formed nearby their emission locations. Further, kinetics studies were used to study the structure-reactivity trend of furans and to estimate their Photochemical Ozone Creation Potential (POCP). Results from this study are expected to significantly improve our insight on furans tropospheric photochemistry and via identifying and quantifying end-products and SOA formation, to assess their indirect and direct impact, on Climate, Air-Quality and humans-health.

How to cite: Angelaki, M., Papadimitriou, V., and Romanias, M.: Atmospheric Degradation and Climate and Air-Quality Impact of Furan-based Biomass Burning Emission Products: A Kinetic and Mechanistic study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1074, https://doi.org/10.5194/egusphere-egu2020-1074, 2020.

EGU2020-8607 | Displays | AS3.12

Secondary Organic Aerosol Reduced by Mixture of Atmospheric Vapours

Thomas Mentel, Gordon McFiggans, Jürgen Wildt, and Astrid Kiendler-Scharr and the JPAC-Team 2015

Biogenic volatile organic compounds (VOC) are important secondary organic aerosol (SOA) precursors. Whilst isoprene dominates VOC plant emissions globally, its yield of SOA mass is found to be modest in comparison to that of monoterpenes (MT). Tracers from isoprene oxidation have been observed in particles showing that they condense from the gas phase and yet new particle formation is suppressed by the presence of isoprene in mixtures of plant emissions containing MT.

Experiments were performed in the JPAC chamber in Jülich. We showed that isoprene can suppress both the instantaneous mass formation and overall yield of monoterpenes in mixtures by two effects: oxidant and product scavenging. Isoprene scavenged OH radicals from reacting with MT (oxidant scavenging). Subsequently, the resulting isoprene peroxy radicals reacted with highly oxygenated peroxy radicals from MT oxidation (product scavenging). These effects from isoprene, also demonstrated using CO or CH4, reduced the yield of low-volatility, highly oxygenated molecules (HOM) from MT that would otherwise form SOA.

Our results show that in mixtures changes in particle mass and number are not additive, and yields from single precursor experiments cannot simply be linearly combined. Reactive, modest SOA yield compounds are not necessarily net SOA producers and isoprene oxidation can suppress both SOA number and mass. Global model calculations support that OH scavenging and product scavenging can also operate in the real atmosphere. Our results highlight a need for more realistic consideration of SOA formation in the atmosphere analogous to the treatment of ozone formation, where interactions between the mechanistic pathways involving peroxy radicals are recognised to be essential.

How to cite: Mentel, T., McFiggans, G., Wildt, J., and Kiendler-Scharr, A. and the JPAC-Team 2015: Secondary Organic Aerosol Reduced by Mixture of Atmospheric Vapours, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8607, https://doi.org/10.5194/egusphere-egu2020-8607, 2020.

EGU2020-961 | Displays | AS3.12

Nighttime to daytime transition of the oxidation products of isoprene by NO3 radicals

Epameinondas Tsiligiannis, Rongrong Wu, Sungah Kang, Luisa Hantschke, Joel Thornton, Hendrik Fuchs, Thomas Mentel, and Mattias Hallquist

Biogenic volatile organic compounds (BVOC) dominate the overall VOC emissions. Isoprene is the most common BVOC emitted from vegetation, accounting up to 50% of the total BVOC emissions. Despite being emitted in daytime it can accumulate in the stratified nocturnal layer. Thus, the oxidation of isoprene by nitrate radicals (NO3) may be of high importance. A series of experiments were conducted in the atmospheric simulation chamber SAPHIR in Jülich, Germany, in order to investigate the gas and particle phase products of the oxidation of isoprene by NO3, under a variety of conditions (e.g. high RO2, high HO2, nighttime to daytime transition, with and without seed aerosol) using a wide range of instrumentation. However, herein the focus is on the results of gas-phase product characterisation using high resolution time of flight chemical ionization mass spectrometers (HR-ToF-CIMS) using iodide or bromide as the primary reagent ion. The use of two HR-ToF-CIMS with different primary reagents provides possibilities to scrutinise the time profiles of isomers of selected products.

We will discuss qualitatively and quantitatively how the distribution of oxidation products change under different conditions, with a focus on the nighttime daytime transition of the major products and the role of subsequent OH oxidation on the products initially formed by NO3 oxidation. Generally, the dominant gas phase products include compounds like nitrooxy hydroperoxide (INP) & dihydroxy nitrate (IDHN) (C5H9NO5), carbonyl nitrate (ICN) (C5H7NO5), hydroxy nitrate (IHN) (C5H9NO4), hydroxy hydroperoxy nitrate (IHPN) (C5H9NO6), as well as a C4 compound (C4H7NO5) among others.

How to cite: Tsiligiannis, E., Wu, R., Kang, S., Hantschke, L., Thornton, J., Fuchs, H., Mentel, T., and Hallquist, M.: Nighttime to daytime transition of the oxidation products of isoprene by NO3 radicals, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-961, https://doi.org/10.5194/egusphere-egu2020-961, 2020.

EGU2020-2614 | Displays | AS3.12

Computational studies of gas-phase accretion product formation involving RO2

Theo Kurtén, Siddharth Iyer, Vili-Taneli Salo, Galib Hasan, Matti Rissanen, and Rashid Valiev

Field and laboratory studies have indirectly but conclusively established that reactions involving peroxy radicals (RO2) play a key role in the gas-phase formation of accretion products, also commonly referred to as “dimers”, as they typically contain roughly twice the number of carbon atoms compared to their hydrocarbon precursors. Using computational tools, we have recently presented two different potential mechanisms for this process.

First, direct and rapid recombination of peroxy and alkoxy (RO) radicals, analogous to the recently characterized RO2 + OH reaction, leads to the formation of metastable RO3R’ trioxides, which may have lifetimes on the order of a hundred seconds. [1] However, due to both the limited lifetime of the trioxides, and the low concentration of alkoxy radicals, the RO2 + R’O pathway is likely to be a minor, though not necessarily negligible, pathway for atmospheric dimer formation.

Second, we have shown that recombination of two peroxy radicals – phenomenologically known to be responsible for the formation of ROOR’ – type dimers – very likely occurs through a multi-step mechanism involving an intersystem crossing (ISC). [2]  In contrast to earlier predictions, we find that the rate-limiting step for the overall RO2  + R’O2 reaction is the initial formation of a short-lived RO4R’ tetroxide intermediate. For tertiary RO2, the barrier for the tetroxide formation can be substantial. However, for all studied species the tetroxide decomposition is rapid, forming ground-state triplet O2, and a weakly bound triplet complex of two alkoxy radicals. The branching ratios of the different RO2 + R’O2 reaction channels are then determined by a three-way competition of this complex. For simple systems, the possible channels are dissociation (leading to RO + R’O), H-abstraction on the triplet surface (leading to RC=O + R’OH), and ISC and subsequent recombination on the singlet surface (leading to ROOR’). All of these can potentially be competive with each other, with rates very roughly on the order of 109 s-1. For more complex RO2 parents, rapid unimolecular reactions of the daughter RO (such as alkoxy scissions) open up even more potential reaction channels, for example direct alkoxy – alkyl recombination to form (either singlet or triplet) ether-type (ROR’) dimers.

[1] Iyer, S., Rissanen, M. P. and Kurtén, T. Reaction Between Peroxy and Alkoxy Radicals can Form Stable Adducts. Journal of Physical Chemistry Letters, Vol. 10, 2051-2057, 2019.

[2] Valiev, R., Hasan, G., Salo, V.-T., Kubečka, J. and Kurtén, T. Intersystem Crossings Drive Atmospheric Gas-Phase Dimer Formation. Journal of Physical Chemistry A, Vol. 123, 6596-6604, 2019.

 

How to cite: Kurtén, T., Iyer, S., Salo, V.-T., Hasan, G., Rissanen, M., and Valiev, R.: Computational studies of gas-phase accretion product formation involving RO2, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2614, https://doi.org/10.5194/egusphere-egu2020-2614, 2020.

EGU2020-6719 | Displays | AS3.12

Stereoselectivity in Atmospheric Autoxidation

Kristian H. Møller, Eric Praske, Lu Xu, John D. Crounse, Kelvin H. Bates, Paul O. Wennberg, and Henrik G. Kjaergaard

The importance of peroxy radical hydrogen shift reactions in the atmosphere has gained acceptance in recent years. Recent theoretical calculations have suggested that these can be stereoselective i.e. that different stereoisomers react with significantly different rate coefficients. Combining experiments (GC-CIMS) with high-level calculations (MC-TST), we show that two hydroxy peroxy radical diastereomers formed in the oxidation of crotonaldehyde have rate coefficients for their peroxy radical hydrogen shift reactions that differ by more than a factor of 10. The difference is large enough that under urban atmospheric conditions, one diastereomer would react primarily by the unimolecular H-shift, while the other would react mainly by bimolecular reactions leading to diastreomeric enhancement of the products.

For a large set of peroxy radical hydrogen shift reactions in the oxidation of isoprene, the stereospecific rate coefficients are calculated to assess the global importance of this phenomenon in the atmosphere.  These calculated rate coefficients are implemented into the global chemistry-transport model GEOS-Chem to model the effect. Results show that more than 30 % of all isoprene molecules emitted undergo a minimum of one peroxy radical hydrogen shift reaction during its oxidation. Furthermore, the results show that the different diastereomers may react with rate coefficients differing by up to almost a factor of 1000, highlighting how important it is to account for this phenomenon.

How to cite: Møller, K. H., Praske, E., Xu, L., Crounse, J. D., Bates, K. H., Wennberg, P. O., and Kjaergaard, H. G.: Stereoselectivity in Atmospheric Autoxidation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6719, https://doi.org/10.5194/egusphere-egu2020-6719, 2020.

EGU2020-18456 | Displays | AS3.12

Linking Peroxy Radical Chemistry to Global Climate: The Common Representatives Intermediates Chemical Mechanism in the UK Earth System Model

Scott Archer-Nicholls, James M. Weber, N. Luke Abraham, Maria R. Russo, Christoph Knote, Paul T. Griffiths, Douglas Lowe, Steven Utembe, Fiona O'Connor, Oliver Wild, Torsten Berndt, Michael E. Jenkin, and Alexander T. Archibald

Production of ozone and secondary organic aerosols (SOA) in the troposphere is driven by the photo-oxidation of volatile organic compounds (VOCs). Crucial intermediates in these oxidation steps are peroxy radicals, which enable ozone generation when reacting with NO. Recent pioneering studies have shown peroxy radical chemistry to have much broader impacts on the atmosphere, with many of these species undergoing autoxidation and forming highly oxidised organic molecules (HOMs), including accretion products, which can form new particles, contribute to SOA growth and influence global climate. However, explicitly simulating the full complexity of this chemistry is impractical due to the many thousands of VOC species in the atmosphere; techniques for reducing complexity are therefore necessary. The Master Chemical Mechanism (MCM) is a near-explicit scheme, with ~6,000 species and ~19,000 reactions, but is almost exclusively used in box-model applications due to its high cost. The Common Representative Intermediates (CRIv2-R5) mechanism is an effective compromise, preserving the ozone forming potential of the MCM from the emission and atmospheric degradation of isoprene, α/β-pinene, and 19 other primary VOC species whilst reducing the number of species and reactions to be feasible in a 3D model (approximately 240 species and 650 reactions, including 47 non-transported peroxy radical species and their associated reactions).

We have implemented CRIv2R5 into a global chemistry-climate model, the UK Earth System Model (UKESM1). We present results from a present-day emissions scenario for the Coupled Model Intercomparison Project (CMIP6) to enable a broad scope of model simulations with more basic chemistry and observations to evaluate the model changes against. We find significant differences to tropospheric ozone production and oxidative capacity of the atmosphere, with a strong sensitivity to magnitude and speciation of VOC emissions, highlighting the importance of accurately simulating VOC chemistry to understand trends in tropospheric ozone under changing emissions and climate.

Moving forward, having the comprehensive CRIv2R5 mechanism within UKESM1 provides the framework for investigating the impacts of recently discovered peroxy radical chemical processes on global climate. We present further work that has focused on expanding the CRI mechanism in box-model studies with a semi-explicit treatment key peroxy radical processes including (i) the autoxidation of peroxy radicals from the hydroxyl radical and ozone initiated reactions of α-pinene, (ii) the formation of multiple generations of peroxy radicals, (iii) formation of accretion products (dimers) and (iv) isoprene-driven suppression of accretion product formation as observed in experiments. This new CRI-HOM mechanism is now being implemented into the global UKESM1 model and coupled with its aerosol mechanism. This work will enable pioneering investigations linking best process-level understanding of gas-phase peroxy radical chemistry to SOA formation and thus improving our understanding of the relationship between biogenic VOC emissions and global climate.

How to cite: Archer-Nicholls, S., Weber, J. M., Abraham, N. L., Russo, M. R., Knote, C., Griffiths, P. T., Lowe, D., Utembe, S., O'Connor, F., Wild, O., Berndt, T., Jenkin, M. E., and Archibald, A. T.: Linking Peroxy Radical Chemistry to Global Climate: The Common Representatives Intermediates Chemical Mechanism in the UK Earth System Model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18456, https://doi.org/10.5194/egusphere-egu2020-18456, 2020.

EGU2020-2661 | Displays | AS3.12

Double Bonds are Key to Fast Unimolecular Reactivity in First Generation Monoterpene Hydroxy Peroxy Radicals

Jing Chen, Kristian H. Møller, Rasmus V. Otkjær, and Henrik G. Kjaergaard

Monoterpenes are a group of volatile organic compounds that are emitted to the atmosphere in large amounts by natural sources. Some monoterpenes such as limonene and Δ3-carene are also widely used as additives in detergents and perfumes, and thus have a potential impact on indoor air quality and human health.

The volatile organic compounds like monoterpenes may undergo a series of autoxidation processes in the atmosphere to form highly oxygenated compounds, which have been linked to the formation of secondary organic aerosols. For this process to occur, the unimolecular reactions of the peroxy radicals formed during oxidation must have rate coefficients comparable to or greater than those of the competing bimolecular reactions with HO2, NO or other RO2 radicals.

We studied the hydrogen shift (H-shift) and the cyclization reactions of all 45 hydroxy peroxy radicals formed by hydroxyl radical (OH) and O2 addition to six monoterpenes (α-pinene, β-pinene, Δ3-carene, camphene, limonene and terpinolene). The reaction rate coefficients of the possible unimolecular reaction were initially studied at a lower level of theory. Those deemed likely to be atmospherically competitive were then calculated using the multi-conformer transition states theory approach developed by Møller et al. (J. Phys. Chem. A, 120, 51, 10072-10087, 2016). This approach has been shown to agree with the experimental values to within a factor of 4 for other systems.

It was found that double bonds are key to fast unimolecular reactions in the first-generation monoterpene hydroxy peroxy radicals. The H-shift reactions abstracting a hydrogen from a carbon adjacent to a double bond are found to typically be fast enough to compete with the bimolecular reactions, likely due to the resonance stability of the nascent allylic radical. The reactivity of the cyclization reaction between the carbon-carbon double bonds and the peroxy group, which forms an endoperoxide ring, is high as well. The H-shifts abstracting the hydrogen from the hydroxy group may be competitive in some cases but the reaction rate coefficients for these reactions are more uncertain. Generally, the cyclization reaction and the allylic H-shift reactions are the dominant reaction paths for the studied peroxyl radicals. Since the OH radical addition consumes one double bond, we suggest that the monoterpenes with more than one double bond in their structure are likely to have unimolecular reactions that can be important for the first-generation monoterpene peroxy radicals. On the other hand, the ones with only one double bond initially are not likely to have fast unimolecular reactions that can compete with the bimolecular reactions under the atmospheric condition, unless a double bond can be formed during their oxidation process as found for α-pinene and β-pinene. This result greatly limits the amount of potentially important unimolecular reaction paths in atmospheric monoterpene oxidation.

How to cite: Chen, J., Møller, K. H., Otkjær, R. V., and Kjaergaard, H. G.: Double Bonds are Key to Fast Unimolecular Reactivity in First Generation Monoterpene Hydroxy Peroxy Radicals, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2661, https://doi.org/10.5194/egusphere-egu2020-2661, 2020.

EGU2020-6865 | Displays | AS3.12

Rapid formation of HOMs from gas-phase alpha-pinene ozonolysis

Siddharth Iyer, Matti Rissanen, Rashid Valiev, Joel Thornton, and Theo Kurtén

Alpha-pinene is the largest globally emitted monoterpene. Its oxidation reaction with ozone leads to peroxy radicals (RO2) that can subsequently form highly oxygenated organic molecules (HOMs) through the process of autoxidation. HOMs are considered to play a critical role in the growth of early particles as they can have sufficiently low saturation vapor pressures.

Pseudo-unimolecular autoxidation reaction is generally thought to compete with bimolecular reactions of RO2in the atmosphere. While these bimolecular reactions could potentially lead to radical recycling, [1] they are generally thought to lead to the formation of non-reactive products. In order to compete with these bimolecular reactions, the unimolecular autoxidation reaction must be rapid, especially in high RO2/NO conditions.

The initial ozonolysis reaction of a-pinene leads to the first-generation RO2with the 6-member ring broken. Current knowledge dictates the perpetuation of the inner 4-member cylobutyl ring in the first-generation RO2. This ring has proven to be a hurdle for rapid unimolecular autoxidation reactions as the steric hindrance the ring affords leads to high barriers (and therefore slow reaction rates) for hydrogen-shift (H-shift) reactions central to autoxidation. [2]

In this work, we show that the ozonolysis of a-pinene could directly lead to the formation of a hitherto unexplored completely ring-opened RO2 product. This pathway is made feasible by considering the large amount of excess energy channeled into the rovibrational modes of the vinoxy product after ozonolysis. This leads to the opening of the cyclobutyl ring of a significant fraction of the “hot” vinoxy radicals under atmospheric conditions, as opposed to all of them adding an O2molecule as was previously thought. The breaking of the ring potentially leads to the formation of products with up to 8 oxygen atoms after a single hydrogen shift reaction following the formation of the vinoxy.

 

[1] Iyer, S.; Reiman, H.; Møller, K. H.; Rissanen, M. P.; Kjaergaard, H. G.; Kurtén, T. Computational Investigation of RO2+ HO2and RO2+ RO2Reactions of Monoterpene Derived First-Generation Peroxy Radicals Leading to Radical Recycling. J. Phys. Chem. A2018, 49, 9542-9552.

[2] Kurtén, T.; Rissanen, M. P. Rissanen, Mackeprang, K.; Thornton, J. A.; Jørgensen, S.; Ehn, M.; Kjaergaard, H. G. Computational Study of Hydrogen Shifts and Ring-Opening Mechanisms in a-Pinene Ozonolysis Products. J. Phys. Chem. A2015, 119, 11366-11375.

 

How to cite: Iyer, S., Rissanen, M., Valiev, R., Thornton, J., and Kurtén, T.: Rapid formation of HOMs from gas-phase alpha-pinene ozonolysis, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6865, https://doi.org/10.5194/egusphere-egu2020-6865, 2020.

EGU2020-8525 | Displays | AS3.12

Oxidation products of alpha-pinene and their electrical mobilities

Aurora Skyttä, Lauri Ahonen, Runlong Cai, and Juha Kangasluoma

OXIDATION PRODUCTS OF ALPHA-PINENE AND THEIR ELECTRICAL MOBILITIES
A. SKYTTÄ 1 , L. AHONEN 1 , R. CAI 1 and J. KANGASLUOMA 1
1 Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of
Helsinki, Helsinki, 00140, Finland

α-pinene C10H16 is a monoterpene emitted by vegetation and its low volatile oxidation products are important source for secondary organic aerosols (SOA) in the atmosphere (Ehn et al., 2014). Because of the significant amount of α-pinene in the atmosphere, we investigated the oxidation
products of α-pinene.

In our setup we used parallel plate DMA (SEADM; (de la Mora et al., 2006)) at mobility resolution of about 80 coupled with APITOF-MS (Tofwerk AG; (Junninen et al., 2010)) and a flow tube system. A DMA can be used to measure the electrical mobility of the molecule or cluster and mass
spectrometer to measure the mass of those clusters. Based on the mass the chemical composition of the cluster can be determined.


The electrospray solution is sprayed through a thin capillary into the chamber through which neutral
sample is passed through. As a solute we used NaNO3 , NaI, LiCl and CH3CO2K dissolved in
methanol all charged in positive and negative mode. Particles that are charged by reagent ions are
led into the DMA via narrow inlet slit.


α-pinene was evaporated into a carrier gas flow and then oxidized using ozone produced from synthetic air with UV-light. The oxidation products are detected by charging them with ions sprayed from the electrospray solution and then directed into the DMA chamber. α-pinene oxidation products of oxidation state C10H16O2−7 were detected with almost all charger ions. Also, other products with different amounts of carbon and hydrogen were detected. Measurements made in negative mode were much more clear and because of this concentrated to examine them.


Mobility provides information on the structure of the compound. One cluster can have multiple peaks in the mobility spectrum if it has multiple different structures. In the mobility spectrum of C10H16O3 charged with NO3− we observe two peaks clearly separate mobility peaks that likely
correspond to two different structural isomers of the compound. We will present analysis of the mobility-mass measurements of α-pinene oxidation products, from where structural information will be obtained when combined to chemical reaction pathways and modeling of the electrical mobilities from the calculated structures.


REFERENCES
Ehn, M. et al, (2014). A large source of low-volatility secondary organic aerosol. (Nature, 506(7489), 476-+.
doi:10.1038/nature13032).


Fernández de la Mora et al, (2006). The potential of differen-
tial mobility analysis coupled to MS for the study of very large singly and multiply chargedproteins and protein complexes in the gas phase.
doi:10.1002/biot.200600070). (Biotechnology Journal, 1(9), 988-997.


Junninen, H. et al, (2010). A high-resolution mass spectrometer
to measure atmospheric ion composition. (Atmospheric Measurement Techniques, 3(4), 1039-
1053. doi:10.5194/amt-3-1039-2010).

How to cite: Skyttä, A., Ahonen, L., Cai, R., and Kangasluoma, J.: Oxidation products of alpha-pinene and their electrical mobilities, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8525, https://doi.org/10.5194/egusphere-egu2020-8525, 2020.

EGU2020-8308 | Displays | AS3.12

The effect of NOx on formation of Highly Oxidized Multifunctional Molecules and SOA formation in photochemical system of α-pinene and β-pinene

Sungah Kang, Thomas Mentel, Iida Pullinen, Monika Springer, Einhard Kleist, Sebastian Schmitt, Cheng Wu, Silvia Proff, Luc Vereecken, Jürgen Wildt, and Astrid Kiendler-Scharr

Highly oxygenated organic molecules (HOM) are formed in the atmosphere by autoxidation, i.e. peroxy radicals can undergo H-shift followed by O2 addition. A sequence of these very fast steps leads to highly oxygenated peroxy radicals (HOM-RO2) and finally to stable termination products with O/C>1.
As other RO2, HOM-RO2 are terminated by reactions with RO2, HO2 and NOx and in addition form efficiently stable accretion products. In this study, three noticeable effects on HOM formation were found by introducing NOx in the photochemical system of monoterpenes. One effect is formation of highly oxygenated organic nitrates (HOM-ON) with sufficiently low vapor pressures allowing significant contributios to SOA formation. The second one is dimer suppression, because of competing dimer pathway (HOM-RO2·+ RO2·) and organic nitrate pathway (HOM-RO2·+ NOx). Thirdly, the reaction between peroxy radicals and NO increases alkoxy radicals in the system. The fragmentation of alkoxy radicals produces volatile compounds that should result in decrease of SOA yield. However, the effect of fragmentation is offset: alkoxy radicals also undergo H-shifts that produce alkyl radicals and after O2 addition peroxy radicals, that eventually are higher oxygenated.

Because of their low volatility, HOM play a crucial role in new particle formation and secondary organic aerosol (SOA) formation. Suppression of dimers and increased degree of oxidation of the HOM monomer play together with the result of only a small reduction of the SOA yields.

How to cite: Kang, S., Mentel, T., Pullinen, I., Springer, M., Kleist, E., Schmitt, S., Wu, C., Proff, S., Vereecken, L., Wildt, J., and Kiendler-Scharr, A.: The effect of NOx on formation of Highly Oxidized Multifunctional Molecules and SOA formation in photochemical system of α-pinene and β-pinene, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8308, https://doi.org/10.5194/egusphere-egu2020-8308, 2020.

EGU2020-5733 | Displays | AS3.12

The Absorption Spectrum and Absolute Absorption Cross Sections of Acetylperoxy Radicals, CH3C(O)O2 in the near IR

Michael Rolletter, Emmanuel Assaf, Mohamed Assali, Hendrik Fuchs, and Christa Fittschen

Acetylperoxy radicals (CH3C(O)O2) play an important role in the tropospheric chemistry. They are produced by the photooxidation of most emitted biogenic non-methane hydrocarbons. Recent studies show that the CH3C(O)O2 + HO2 reaction, which is the most important tropospheric loss reaction of acetylperoxy radicals in regions that are dominated by biogenic emissions (low NO emissions), does not only lead to radical chain terminating products but can also regenerate OH. The competing secondary chemistry, e. g., the CH3C(O)O2 self-reaction, complicate kinetic measurements. The detection of acetylperoxy radicals in previous kinetic laboratory studies was mainly done in the UV region. However, the spectral overlap of different peroxy species in this region is prone to systematic errors in the quantitative detection. These complications can be avoided, if acetylperoxy radicals are detected by absorption in the near IR.

In our work, the near infrared CH3C(O)O2 spectrum was measured in the spectral ranges from 6094 cm-1 to 6180 cm-1 and 6420 cm-1 to 6600 cm-1. CH3C(O)O2 radicals were generated by pulsed photolysis of a acetaldehyde/Cl2/O2 mixture at 351 nm and were subsequently detected by time-resolved continuous-wave cavity ring-down spectroscopy (cw-CRDS). Experiments were done at 67 hPa in synthetic air and helium. The absorption cross sections of eight discrete absorption lines were determined relative to the absorption cross section of HO2, which has previously been reported.

How to cite: Rolletter, M., Assaf, E., Assali, M., Fuchs, H., and Fittschen, C.: The Absorption Spectrum and Absolute Absorption Cross Sections of Acetylperoxy Radicals, CH3C(O)O2 in the near IR, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5733, https://doi.org/10.5194/egusphere-egu2020-5733, 2020.

EGU2020-4415 | Displays | AS3.12

Chemical composition and volatility distribution of SOA formed by ozonolysis of β-caryophyllene between 213-313 K

Linyu Gao, Magdalena Vallon, Junwei Song, Wei Huang, Thomas Leisner, and Harald Saathoof

β-Caryophyllene is the most common and abundant of the sesquiterpenes emitted into the atmosphere (Duhl et al., 2008). Although sesquiterpene emission rates were estimated to be only 9–16% of the total terpene emissions (Duhl et al., 2008), they are more reactive and larger in size than monoterpenes. Consequently, their aerosol mass yields are large and result in a significant contribution to the SOA budget in the atmosphere (Tasoglou and Pandis, 2015). Therefore, we studied the composition of both gas and particle phases as well as phase partitioning of SOA from ozonolysis of β-caryophyllene in presence and absence of NOx at five temperatures (213 K, 243 K, 273 K, 298 and 313 K) in the AIDA aerosol simulation chamber. This work focusses on the characterization of the SOA by mass spectrometry employing a FIGAERO-HR-TOF-CIMS operated with iodide ions and a HR-TOF-AMS (both Aerodyne Inc.). Particle phase analysis shows three groups of compound masses with m/z 240-400, (C5-16),  (m/z 400-560, (C20-34), and m/z 560-680, (C35-40) classified as monomers, dimers, and trimers, respectively.  Trimeric compounds were observed preferentially in SOA formed at higher temperatures (273 K, 298 K, 313 K), while only monomeric and dimeric compounds were detected at lower temperatures (243 K and 213 K). Interestingly, dimeric compounds, including CxHyOz and CxHyOzN1, contribute more to SOA mass for the lower temperatures. Comparing volatility distributions for the five different temperatures using the Volatility Basis Set (VBS) and thermal desorption information from FIGAERO-CIMS (298-473 K) we find more compounds with lower volatility for lower SOA formation temperatures. This contribution will discuss the volatility distributions obtained with and without NOx as well as the abundance of specific reaction products.

How to cite: Gao, L., Vallon, M., Song, J., Huang, W., Leisner, T., and Saathoof, H.: Chemical composition and volatility distribution of SOA formed by ozonolysis of β-caryophyllene between 213-313 K, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4415, https://doi.org/10.5194/egusphere-egu2020-4415, 2020.

Nitrate radical (NO3) oxidation of biogenic volatile organic compounds (BVOCs) represents one of the most important interactions between anthropogenic emissions related to combustion and natural emissions from the biosphere. The functionalization process during this oxidation process leads to the formation of multifunctional compounds such as organic nitrates (ON). ON account for a significant fraction of total organic aerosols (OA) in ambient air, which influence atmospheric chemistry process, air quality, and climate through regional and global budgets for reactive nitrogen (particularly ON), ozone, and OA formation. Despite the significance of this process in atmospheric chemistry, the climatic effect of SOA from this process is undefined, largely due to a lack of knowledge about their optical properties with respect to their chemical composition. In this study, we generated SOA from NO3 radical oxidation of a series BVOCs including isoprene, monoterpenes, and sesquiterpenes followed by photo-chemically aging in oxidation flow reactor (OFR/PAM). The chemical composition of the SOA was characterized online by high-resolution time-of-flight mass spectrometer (HR-Tof-AMS) and off-line by ultra-high-performance liquid chromatography (HPLC) coupled with photodiode array (PDA) detector coupled to a high-resolution Orbitrap mass spectrometer with a standard electrospray ionization (ESI) source (HPLC-PDA-HRMS). The UV-visible wavelength-resolved refractive index of the SOA, which is essential to understand their radiative forcing, was retrieved by measuring the light extinction using a novel broadband cavity-enhanced spectrometer (BBCES, 315-700 nm). We found that the SOA contain a large fraction of highly oxygenated ON, consisting of monomers and oligomers with single and multiple nitrate groups, which formed through bimolecular and unimolecular reactions. Strong absorption was detected in the UVA range which was attributed to the ON. The influence of the initial BVOCs/NO3 ratio and the transition from nighttime oxidation to daytime aging on the SOA optical properties will be discussed. We will highlight the link between the SOA optical properties evolution and the chemical composition transformation with respect to the highly oxygenated ON formation and its atmospheric fate upon daytime photochemical aging.

How to cite: Rudich, Y., He, Q., Laskin, A., and Brown, S.: Optical Properties of Secondary Organic Aerosol from Nitrate Radical Oxidation of Biogenic Volatile Organic Compounds: The Role of Highly Oxygenated Organic Nitrates  , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4136, https://doi.org/10.5194/egusphere-egu2020-4136, 2020.

EGU2020-11986 | Displays | AS3.12

New insights into secondary organic aerosol from nitrate oxidation of isoprene in the atmospheric simulation chamber SAPHIR

Juliane L. Fry, Bellamy Brownwood, Thorsten Hohaus, Avtandil Turdziladze, Philip Carlsson, Epameinondas Tsiligiannis, Matthias Hallquist, Anna Novelli, and Hendrik Fuchs and the NO3Isop Campaign at SAPHIR chamber, August 2018

Experiments at a set of atmospherically relevant conditions were performed in the atmospheric simulation chamber SAPHIR, investigating the oxidation of isoprene by the nitrate radical (NO3). A comprehensive set of instruments detected trace gases, radicals, aerosol properties and hydroxyl (OH) and NO3 radical reactivity. The chemical conditions in the chamber were varied to change the fate of the peroxy radicals (RO2) formed after the reaction between NO3 and isoprene, and seed aerosol of varying composition was added to initiate gas/aerosol partitioning. This presentation discusses observed gas/aerosol partitioning of the major organic nitrate products and summarizes the observations of secondary organic aerosol yield.

How to cite: Fry, J. L., Brownwood, B., Hohaus, T., Turdziladze, A., Carlsson, P., Tsiligiannis, E., Hallquist, M., Novelli, A., and Fuchs, H. and the NO3Isop Campaign at SAPHIR chamber, August 2018: New insights into secondary organic aerosol from nitrate oxidation of isoprene in the atmospheric simulation chamber SAPHIR, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11986, https://doi.org/10.5194/egusphere-egu2020-11986, 2020.

EGU2020-11196 | Displays | AS3.12

New insights into the gas-phase oxidation of isoprene by the nitrate radical from experiments in the atmospheric simulation chamber SAPHIR

Philip Carlsson, Patrick Dewald, Justin Shenolikar, Nils Friedrich, John Crowley, Steven Brown, François Bernard, Li Zhou, Juliane Fry, Bellamy Brownwood, Mattias Hallquist, Epameinondas Tsiligiannis, Xu Kangmin, Rupert Holzinger, Hendrik Fuchs, Luc Vereecken, Anna Novelli, Birger Bohn, Franz Rohrer, and Thomas Mentel and the NO3-Isoprene Campaign at Saphir

Experiments at a set of atmospherically relevant conditions were performed in the simulation chamber SAPHIR, investigating the oxidation of isoprene by the nitrate radical (NO3). An extremely comprehensive set of instruments detected trace gases, radicals, aerosol properties and hydroxyl (OH) and NO3 radical reactivity. The chemical conditions in the chamber were varied to change the fate of the peroxy radicals (RO2) formed after the reaction between NO3 and isoprene from either mainly recombining with other RO2 or mainly reacting with hydroperoxyl radicals (HO2). These major atmospheric pathways for RO2 radicals lead to the formation of organic nitrate compounds which then have different atmospheric fates. The experimental concentration profiles are compared to box model calculations using both the current Master Chemical Mechanism (MCM) as well as recently available literature data alongside new quantum chemical calculations. The discussion here focusses on the resulting RO2 distribution and deviations in the predictions of early products and total alkyl nitrate yields for the different chemical conditions. Preliminary results for instance show too high night time losses of alkyl nitrates due to ozonolysis in the current MCM. 

How to cite: Carlsson, P., Dewald, P., Shenolikar, J., Friedrich, N., Crowley, J., Brown, S., Bernard, F., Zhou, L., Fry, J., Brownwood, B., Hallquist, M., Tsiligiannis, E., Kangmin, X., Holzinger, R., Fuchs, H., Vereecken, L., Novelli, A., Bohn, B., Rohrer, F., and Mentel, T. and the NO3-Isoprene Campaign at Saphir: New insights into the gas-phase oxidation of isoprene by the nitrate radical from experiments in the atmospheric simulation chamber SAPHIR, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11196, https://doi.org/10.5194/egusphere-egu2020-11196, 2020.

EGU2020-4597 | Displays | AS3.12

Chamber Studies of NO3 reactivity during the oxidation of isoprene

Patrick Dewald, Justin Shenolikar, Nils Friedrich, Franz Rohrer, Ralf Tillmann, David Reimer, Kangming Xu, Rupert Holzinger, François Bernard, Li Zhou, Steven Brown, Hendrik Fuchs, and John Crowley

Isoprene is the major volatile organic compound that is released into the environment via biogenic emissions and its oxidation can result in formation of secondary organic aerosol (SOA). Although isoprene emission occurs mainly at daytime, it can accumulate at nighttime and be oxidized by the nitrate radical (NO3) to form organic nitrates that can partition to the particle phase. A detailed understanding of the reaction between isoprene and NO3 is thus required to predict its role in e.g. NOX lifetimes and SOA formation.

The reaction between NO3 and isoprene was investigated under varying experimental conditions (high or low RO2/HO2, temperature, humidity, seed aerosols) during the NO3ISOP campaign at the atmospheric simulation chamber SAPHIR of the research centre in Jülich (Germany). Direct measurement of the NO3 reactivity was carried out with means of a flowtube coupled to a cavity-ring-down spectroscopy (FT-CRDS) setup which enabled the evolution of the NO3 lifetime during the isoprene oxidation process to be monitored.

By comparing direct NO3 reactivity measurements with those calculated from VOC mixing ratios and those calculated from a stationary-state analysis we identify the contributions of isoprene, secondary oxidation products and peroxy radicals to NO3 losses.

How to cite: Dewald, P., Shenolikar, J., Friedrich, N., Rohrer, F., Tillmann, R., Reimer, D., Xu, K., Holzinger, R., Bernard, F., Zhou, L., Brown, S., Fuchs, H., and Crowley, J.: Chamber Studies of NO3 reactivity during the oxidation of isoprene, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4597, https://doi.org/10.5194/egusphere-egu2020-4597, 2020.

EGU2020-5475 | Displays | AS3.12

Importance of isomerization reactions for the OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR

Anna Novelli, Luc Vereecken, Birger Bohn, Hans-Peter Dorn, Georgios Gkatzelis, Andreas Hofzumahaus, Frank Holland, David Reimer, Franz Rohrer, Simon Rosanka, Domenico Taraborrelli, Ralf Tillmann, Robert Wegener, Zhujun Yu, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs

Theoretical, laboratory and chamber studies have shown fast regeneration of hydroxyl radical (OH) in the photochemistry of isoprene largely due to previously disregarded unimolecular reactions which were previously thought not to be important under atmospheric conditions. Based on early field measurements, nearly complete regeneration was hypothesized for a wide range of tropospheric conditions, including areas such as the rainforest where slow regeneration of OH radicals is expected due to low concentrations of nitric oxide (NO). In this work the OH regeneration in the isoprene oxidation is directly quantified for the first time through experiments covering a wide range of atmospheric conditions (i.e. NO between 0.15 and 2 ppbv and temperature between 25 and 41°C) in the atmospheric simulation chamber SAPHIR. These conditions cover remote areas partially influenced by anthropogenic NO emissions, giving a regeneration efficiency of OH close to one, and areas like the Amazonian rainforest with very low NO, resulting in a surprisingly high regeneration efficiency of 0.5, i.e. a factor of 2 to 3 higher than explainable in the absence of unimolecular reactions. The measured radical concentrations were compared to model calculations and the best agreement was observed when at least 50% of the total loss of isoprene peroxy radicals conformers (weighted by their abundance) occurs via isomerization reactions for NO lower than 0.2 parts per billion (ppbv). For these levels of NO, up to 50% of the OH radicals are regenerated from the products of the 1,6 α-hydroxy-hydrogen shift (1,6-H shift) of Z-δ-RO2 radicals through photolysis of an unsaturated hydroperoxy aldehyde (HPALD) and/or through the fast aldehyde hydrogen shift (rate constant ~10 s-1 at 300K) in di-hydroperoxy carbonyl peroxy radicals (di-HPCARP-RO2), depending on their relative yield. The agreement between all measured and modelled trace gases (hydroxyl, hydroperoxy and organic peroxy radicals, carbon monoxide and the sum of methyl vinyl ketone, methacrolein and hydroxyl hydroperoxides) is nearly independent on the adopted yield of HPALD and di-HPCARP-RO2 as both degrade relatively fast (< 1 h), forming OH radical and CO among other products. Taking into consideration this and earlier isoprene studies, considerable uncertainties remain on the oxygenated products distribution, which affect radical levels and organic aerosol downwind of unpolluted isoprene dominated regions.

How to cite: Novelli, A., Vereecken, L., Bohn, B., Dorn, H.-P., Gkatzelis, G., Hofzumahaus, A., Holland, F., Reimer, D., Rohrer, F., Rosanka, S., Taraborrelli, D., Tillmann, R., Wegener, R., Yu, Z., Kiendler-Scharr, A., Wahner, A., and Fuchs, H.: Importance of isomerization reactions for the OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5475, https://doi.org/10.5194/egusphere-egu2020-5475, 2020.

EGU2020-2922 | Displays | AS3.12

Structure-activity relationships for unimolecular reactions of peroxy radicals, RO2, at atmospheric temperatures

Luc Vereecken, Giang H. T. Vu, and Hue M. T. Nguyen

The oxidation of most organic matter emitted to the atmosphere proceeds by radical reaction steps, where peroxy radicals, ROO, are critical intermediates formed by addition of O2 molecules to carbon-based radicals. The chemistry of these RO2 radicals in high-NOx conditions is well-known, forming alkoxy radicals and NO2. In low-NOx and pristine conditions, the RO2 radicals react with HO2 and other R'O2 radicals, but can have a sufficiently long lifetime to also undergo unimolecular reactions. Hydrogen atom migration, forming a hydroperoxide (-OOH) and a new peroxy radical site after addition of an additional O2 on the newly formed radical site, has been studied extensively in some compounds, such as isoprene where it was shown to be the a critical step in OH radical regeneration. RO2 ring closure reactions have likewise been studied, where for β-pinene it has been shown to be a critical step governing the yield of the decomposition products such as acetone and nopinone.

Despite the interest in RO2 unimolecular reactions, and the potential impact on atmospheric chemistry, no widely applicable structure-activity relationships (SARs) have been proposed to allow systematic incorporation of such unimolecular reactions in gas phase atmospheric kinetic models. In this work, we present a series of systematic theoretical predictions on the site-specific rate coefficients for such reactions for a wide range of molecular substitutions. Combined with extensive literature data this allows for the formulation of a SAR for RO2 unimolecular reactions, covering aliphatic, branched, and unsaturated RO2 with oxo, hydroxy, hydroperoxy, nitrate, carboxylic acid, and ether substitutions.

The predictions are compared to experimental and theoretical data, including multi-functionalized species. Though some molecular classes are well represented in the training set (e.g. aliphatic RO2), other classes have little data available and additional work is needed to enhance and validate the reliability of the SAR. Direct experimental data is scarce for all RO2 classes. The fastest H-migrations are found to be for unsaturated RO2, with the double bond outside the H-migration TS ring. Ring closure of unsaturated RO2 are likewise fast if the product radical carbon is exocyclic to the newly formed peroxide ring.

How to cite: Vereecken, L., Vu, G. H. T., and Nguyen, H. M. T.: Structure-activity relationships for unimolecular reactions of peroxy radicals, RO2, at atmospheric temperatures, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2922, https://doi.org/10.5194/egusphere-egu2020-2922, 2020.

EGU2020-9638 | Displays | AS3.12

a-pinene autoxidation at sub-second time-scales

Matti Rissanen, Shawon Barua, Jordan Krechmer, Theo Kurtén, and Siddharth Iyer

Atmospheric aerosols impact climate and health. Most of the smallest atmospheric nanoparticles are formed by oxidation of volatile organic compounds (VOC) and subsequent condensation of resulting low-volatile vapors. Biogenic terpenes are the largest atmospheric secondary organic aerosol (SOA) source, and among these, a-pinene likely the single most important compound.

 Recently, autoxidation changed the paradigm of long processing time-scales in the formation of SOA [1, 2]. Previous experiments with cyclic unsaturated compounds have indicated the autoxidation to be very rapid, forming compounds with even 10 O-atoms infused to the carbon structure in a few seconds timeframe [3-6]. Berndt et al. noted that the whole process was apparently finished already at about 1.5 seconds reaction time in cyclohexene ozonolysis initiated autoxidation, indicated by the “frozen” peroxy radical product distribution beyond this reaction time [4].

Here we performed sub-second time-scale flow reactor experiments of a-pinene ozonolysis initiated autoxidation under ambient atmospheric conditions to constrain the timeframe needed to form the first highly-oxidized reaction products, and to inspect the peroxy radical dynamics at significantly shorter reaction times than have been previously possible. The shortest achievable reaction time was around 0.1 seconds and was enabled by the new Multi-scheme chemical IONization (MION) inlet setup [7]. Nitrate and bromide were used as reagent ions in this work.

 

References:

  1. J. D. Crounse, et al. Autoxidation of Organic Compounds in the Atmosphere, J. Phys. Chem. Lett., 2013, 4, 3513-3520.
  2. M. Ehn, et al. A large source of low-volatility secondary organic aerosol, Nature, 2014, 506, 476-479.
  3. M. P. Rissanen, et al. The formation of highly oxidized multifunctional products in the ozonolysis of cyclohexene, J. Am. Chem. Soc., 2014, 136, 15596-15606.
  4. T. Berndt, et al. Gas-Phase Ozonolysis of Cycloalkenes: Formation of Highly Oxidized RO2 Radicals and Their Reactions with NO, NO2, SO2, and Other RO2 Radicals, J. Phys. Chem. A, 2015, 119, 10336-10348.
  5. M. P. Rissanen, et al. Kulmala, Effects of Chemical Complexity on the Autoxidation Mechanisms of Endocyclic Alkene Ozonolysis Products: From Methylcyclohexenes toward Understanding α-Pinene, J. Phys. Chem. A, 2015, 119, 4633-4650.
  6. T. Kurtén, et al. Computational Study of Hydrogen Shifts and Ring-Opening Mechanisms in α-Pinene Ozonolysis Products, J. Phys. Chem. A, 2015, 119, 11366-11375.
  7. M. P. Rissanen, et al. Multi-scheme chemical ionization inlet (MION) for fast switching of reagent ion chemistry in atmospheric pressure chemical ionization mass spectrometry (CIMS) applications, Atmos. Meas. Tech., 2019, 12, 6635-6646.

How to cite: Rissanen, M., Barua, S., Krechmer, J., Kurtén, T., and Iyer, S.: a-pinene autoxidation at sub-second time-scales, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9638, https://doi.org/10.5194/egusphere-egu2020-9638, 2020.

EGU2020-4329 | Displays | AS3.12

Highly oxygenated molecules and their chemistry in polluted urban environments

Qi Chen, Xi Cheng, Yongjie Li, Yan Zheng, Keren Liao, Guancong Huang, Ying Liu, Tong Zhu, and Manjula R. Canagaratna

Highly oxygenated molecules (HOMs) are important atmospheric oxidation products that may contribute to new particle formation and initial particle growth. Thousands of such compounds were quantified in both winter and summer of 2016 in Beijing by using online nitrate ion chemical ionization time-of-flight mass spectrometry. Positive-matrix factorization of the time series of the high-resolution mass spectra identified at least 10 major groups of gaseous HOMs in Beijing. We compared these PMF factors with the HOMs produced in a Potential Aerosol Mass (PAM) flow reactor in the laboratory from the oxidation of typical biogenic and aromatic precursors under various oxidation conditions. Our results show that four of the ten PMF factors perhaps correspond to biogenic precursors, and another four factors are likely related to aromatic precursors. The chemistry of these aromatic HOMs are discussed based on the results from the PAM experiments.

How to cite: Chen, Q., Cheng, X., Li, Y., Zheng, Y., Liao, K., Huang, G., Liu, Y., Zhu, T., and Canagaratna, M. R.: Highly oxygenated molecules and their chemistry in polluted urban environments, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4329, https://doi.org/10.5194/egusphere-egu2020-4329, 2020.

EGU2020-15188 | Displays | AS3.12

Eddy covariance (EC) fluxes of monoterpene oxidation products from a boreal forest canopy

Lejish Vettikkat, Arttu Ylisirniö, Iida Pullinen, Luís Miguel Feijó Barreira, Pasi Miettinen, and Siegfried Schobesberger

Oxidation of volatile organic compounds (VOC) by ozone (O3), hydroxyl radicals (OH) and nitrogen oxide radicals (NO3, NOx) reduces their volatility and leads to the formation of secondary organic aerosols (SOA) through gas-particle partitioning. Recent studies have shown that monoterpene (C10H16) oxidation products can participate in all stages of aerosol formation, especially in forested boreal environments. However, deposition of these semi-volatile and (extremely) low-volatility organic compounds (SVOC, LVOC, ELVOC) to surfaces in the canopy directly competes with the gas-particle partitioning and has a substantial effect (~50%) on organic aerosol loading. Hence understanding the fate of these oxidation products is crucial in determining the organic aerosol budget and thereby constraining their contribution to climate-relevant processes such as new-particle formation and cloud formation.

Oxidation products of monoterpenes were measured at the station for measuring ecosystem atmosphere relations (SMEAR II), a boreal forest research station in Hyytiälä, Finland, in spring/summer 2019. The forest is dominated by Scots pine (Pinus sylvestris L.) and Norway spruce (Picea abies (L.) H. Karst) which are well known high monoterpene emitters. Eddy covariance (EC) flux measurements of oxygenated organic compounds in the gas phase were performed using an iodide-adduct high-resolution time-of-flight chemical ionization mass spectrometer (I-CIMS) with high frequency (5 Hz) co-located with a sonic anemometer (METEK USA-1) on a tower, 35 m above the forest floor. The ion-molecule reaction (IMR) chamber of I-CIMS was actively humidified to mitigate the dependence of the sensitivity of the measurements on the ambient relative humidity. The EC data were analysed following standard correction procedures like lag correction, coordinate rotation and uncertainty analysis. VOCs and oxygenated VOCs were also measured at ground level using a Vocus proton-transfer-reaction time-of-flight mass spectrometer (Vocus PTR-MS), which is sensitive also to the majority of compounds measured by I-CIMS.

We present the first continuous I-CIMS dataset at high time resolution (5 Hz) from a tall tower and calculate the Eddy covariance fluxes of a wide range of monoterpene oxidation products during the primary plant-growth season in a boreal forest. Bidirectional fluxes for formic acid (HCOOH) were observed at a higher temporal resolution than reported in earlier studies. We found an increasing trend in the deposition velocity for heavier monoterpene oxidation products which enables us to constrain the net flow of organics between the atmosphere and the canopy layer using the continuity/mass balance equation. When coupled to ground-based measurements using Vocus-PTR, our EC flux measurements will give further insight about the abundance of organics above the canopy vs near ground-level. We also plan to integrate our observations with a chemical transport model containing details of monoterpene oxidation chemistry (ADCHEM) to simulate the sources and sinks and to derive parameterizations for representing the dry deposition rates of monoterpene oxidation products in the boreal forested environments.

How to cite: Vettikkat, L., Ylisirniö, A., Pullinen, I., Feijó Barreira, L. M., Miettinen, P., and Schobesberger, S.: Eddy covariance (EC) fluxes of monoterpene oxidation products from a boreal forest canopy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15188, https://doi.org/10.5194/egusphere-egu2020-15188, 2020.

EGU2020-10708 | Displays | AS3.12

HOM cluster decomposition in APi-TOF mass spectrometers

Tommaso Zanca, Jakub Kubečka, Evgeni Zapadinsky, Monica Passananti, Theo Kurtén, and Hanna Vehkamäki

Recent developments in mass spectrometry have brought huge advancements to the field of atmospheric science. For example, mass spectrometers are now able to detect ppq-level (10-15) concentrations of both clusters and precursor vapours in atmospheric samples (Junninen et al., 2010; Jokinen et al., 2012), as well as directly explore the chemistry of new particle formation (NPF) in the atmosphere (Kulmala et al., 2014; Bianchi et al., 2016; Ehn et al., 2014). One of the most common mass spectrometers used to measure online cluster composition and concentration in the atmosphere is the Atmospheric Pressure interface Time Of Flight Mass Spectrometer (APi-TOF MS).
Identification of atmospheric molecular clusters and measurement of their concentrations by APi-TOF may be affected by systematic error due to possible decomposition of clusters inside the instrument. Indeed, the detection process in the APi-TOF involves energetic interactions between the carrier gas and the clusters, possibly leading to their decomposition, and thus altering the measurement results.
Here we use a theoretical model to study in detail the decomposition of clusters involving so-called Highly-Oxygenated organic Molecules (HOM), which have recently been identified as a key contributor to NPF (Bianchi et al., 2019). HOM are molecules formed in the atmosphere from Volatile Organic Compounds (VOC). Some VOC with suitable functional groups can undergo an autoxidation process involving peroxy radicals, generating polyfunctional low-volatility vapors (i.e. HOM) that subsequently condense onto pre-existing particles. 
Our study involves a specific kind of representative HOM (C10H16O8) in the APi. This elemental composition corresponds to one of the most common mass peaks observed in experiments on ozone-initiated autoxidation of α-pinene, which also fulfills the “HOM” definition of Bianchi et al. (2019). The precise molecular structure was adopted from Kurtén et al. (2016), and corresponds to the lowest-volatility structural isomer of the three C10H16O8 compounds investigated in that study.
The main scope of this work is to determine to what extent we are able to perform measurements of atmospheric cluster concentrations using APi-TOF mass spectrometers. More specifically, we want to determine whether decomposition can possibly be responsible for the lack of observations of some HOM-containing clusters in an APi-TOF. Here, we predict both an upper bound for decomposition energy necessary for decomposition in the APi-TOF, and a lower bound for new-particle formation in the atmosphere given realistic vapor concentrations.
Our results show that decomposition is highly unlikely for the considered clusters, provided their bonding energy is large enough to allow formation in the atmosphere in the first place.

How to cite: Zanca, T., Kubečka, J., Zapadinsky, E., Passananti, M., Kurtén, T., and Vehkamäki, H.: HOM cluster decomposition in APi-TOF mass spectrometers, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10708, https://doi.org/10.5194/egusphere-egu2020-10708, 2020.

Chemical characterization of oxygenated organic compounds in gas-phase and particle-phase in the Pearl River Delta using Iodide-CIMS with FIGAERO

Chenshuo Ye1, Yi Lin2, Zelong Wang2, Tiange Li2, Caihong Wu2, Chaomin Wang2, Weiwei Hu3, Shan Huang2, Wei Song3, Xinming Wang3, Bin Yuan2*, Min Shao2,1**

1 College of Environmental Sciences and Engineering, Peking University, Beijing

2 Institute for Environmental and Climate Research, Jinan University, Guangzhou

3 Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou

* e-mail: byuan@jnu.edu.cn

** e-mail: mshao@pku.edu.cn

Abstract

The Pearl River Delta region (PRD) is a highly industrialized and urbanized area in southeastern China, strongly influenced by both anthropogenic and biogenic emissions. The atmospheric processes in PRD involves the interactions between organics and inorganics, anthropogenic pollutants and natural emissions, leading to the formation of various  secondary products. The iodide chemical ionization time-of-flight mass spectrometer installed with FIGAERO inlet was applied at an urban site in PRD region during the autumn of 2018, to measure a number of oxygenated organic compounds in both gas phase and particle phase. Using the dataset, we find: (1) Oxygenated organic compounds and N-containing organics accounted for the majority of detected species. The most abundant organics were formic acid and multifunctional organics containing 3-6 oxygens. Nitrophenols, dinitrophenols and organic nitrates derived from isoprene and monoterpenes made a substantial contribution to N-containing organics. (2) Isoprene oxidation products peaked in the afternoon, while monoterpene oxidation products and oxidized aromatics had various diurnal patterns due to their different chemical pathways during their formation processes. (3) We detected many biomass burning tracers previously described in the literature, among which levoglucosan, along with other monosaccharide derivatives and serval guaiacol derivatives, were highly correlated with each other, with their concentrations peaked during the harvest season for local crops. (4) Photochemical processes generally create smaller products of higher oxidation states, whereas nighttime chemistry plays an important role in producing larger molecule but less oxidized products particularly nitrogen-containing oxygenated organics. The variations of dominant atmospheric processes as well as the emissions of precursors lead to the variations of the bulk properties of secondary products.

How to cite: Ye, C.: Chemical characterization of oxygenated organic compounds in gas-phase and particle-phase in the Pearl River Delta using iodide-CIMS with FIGAERO, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12127, https://doi.org/10.5194/egusphere-egu2020-12127, 2020.

EGU2020-18854 | Displays | AS3.12

Characterization of gaseous and particulate phase organic compounds during a winter-time air pollution event

Julien Kammer, Niall O’Sullivan, Elena Gomez Alvarez, Stig Hellebust, and John Wenger

 Abstract

Atmospheric particles are known to cause adverse health effects and premature deaths in European cities. To improve air quality, a detailed understanding of particle sources is thus essential in order to reduce their emissions. Secondary organic aerosols (SOA) produced from the oxidation of volatile organic compounds emitted by anthropogenic sources such as road vehicles and solid fuel combustion is an important air pollution source in urban areas. It is demonstrated that SOA contribute significantly to the atmospheric particle loading, and could even be the major contributor at specific locations. Yet, state of the art models are still not able to reproduce SOA formation despite recent advances. Clearly, further work is needed to improve our understanding of the processes related to SOA formation.

In this context, a field campaign has been conducted at a monitoring station in Cork City, Ireland during winter 2019 (26th January to 8th February). The chemical composition of organic compounds in both gas and particle phases was investigated online using a Time-of-Flight Chemical Ionisation Mass Spectrometer (ToF-CIMS) coupled with a Filter Inlet for Gases and Aerosols (FIGAERO). PM2.5 concentration, ozone and nitrogen oxides (NOx) were also monitored during the campaign, as well as meteorological parameters. Finally, air mass backward trajectories were computed using the HYSPLIT model.

A strong night-time air pollution event was observed during the field campaign, characterized by PM2.5 concentrations up to 180 µg m-3. Using iodide as reagent, the FIGAERO-ToF-CIMS detected hundreds of ions simultaneously in gas and particulate phases. Among the identified compounds were a range of well-known atmospheric tracers of solid fuel burning, including phenolic compounds such as guaiacol and catechol, and numerous oxygenated polycyclic aromatic hydrocarbons (OPAHs). A number of nitrated aromatic compounds were also detected. In this work, the gas/particle partitioning of some of these key compounds has been investigated to provide information on phase transfer of solid fuel emissions over time. The thermograms produced by the FIGAERO analysis are also used to determine the volatility of the species detected. Finally, the FIGAERO-ToF-CIMS data is used to explore the extent to which oxidation of the gaseous emissions by the nitrate radical (NO3) leads to the formation of nitrated compounds in the particulate phase. This work thus provides unique insights into the night-time oxidation processes that can lead to SOA formation from anthropogenic sources.

 

Acknowledgments

This work was supported by the Irish Research Council (GOIPG/2017/1364) and by the European Union’s Horizon 2020 research and innovation programme (EUROCHAMP-2020, grant no. 730997; Marie Skłodowska-Curie grant agreement No. 751527).

How to cite: Kammer, J., O’Sullivan, N., Gomez Alvarez, E., Hellebust, S., and Wenger, J.: Characterization of gaseous and particulate phase organic compounds during a winter-time air pollution event, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18854, https://doi.org/10.5194/egusphere-egu2020-18854, 2020.

EGU2020-8093 | Displays | AS3.12

Secondary Organic Aerosol Formation from On-road Gasoline Vehicles in China

Hui Wang, Rongzhi Tang, Ruizhe Shen, Ying Yu, Kefan Liu, Rui Tan, Wenbin Zhang, Zhou Zhang, Shijin Shuai, and Song Guo

Organic aerosol (OA) constitutes a significant fraction of the atmospheric fine particulate matter that influences both air quality and climate. Secondary organic aerosol (SOA), which is formed through photo-oxidation of organic vapors in the atmosphere, is a major component of OA. There are some studies indicating the major role of vehicles emissions in SOA formation in urban cities of China. However, SOA formation is complex and uncertain.

Historically, the China fleet has been dominated by vehicles equipped with port-fuel injected (PFI), but the market share of vehicles equipped with gasoline direct injection engines (GDI) has increased dramatically. And 10% of renewable energy ethanol (E10) may be added to the gasoline of China market in the future. Go-PAM is one kind of potential aerosol mass for simulating SOA formation, which is designed and made by the University of Gothenburg.

In this study, we focus on the influence of ethanol content (0% or 10%), engine types (GDI or PFI) and different engine loads (idling or constant velocity) to the SOA formation potential from gasoline motor cars emissions. We exposed the diluted emissions to a range of oxidation (O3 and OH) concentrations in the Go-PAM, resulting different OH exposures. We observed variations of different cases in SOA formation.

Firstly, compared to PFI engine, GDI engine at idling loading has larger SOA mass concentrations. The peak SOA production of PFI engine at idling load occurred at equivalent photochemical age (EPA) of 3.8 days, which peak point occurred at larger EPA (4.8 days) for GDI engines. Secondly, there is no large difference between E10 and gasoline. Thirdly, OA enhancement is more obvious at idling (about 30-180 times) than at constant velocity (about 3-4 times) whatever engine is used. Generally, densities of particles at size of 70nm,140nm and 200nm keep growing from about 1.25 up to 1.45 g/cm3.

The results of this study highlight the utility of Go-PAM for studying SOA formation potential from vehicle exhaust, and provide indications of the influence of ethanol content and different engines to SOA formation in China.

How to cite: Wang, H., Tang, R., Shen, R., Yu, Y., Liu, K., Tan, R., Zhang, W., Zhang, Z., Shuai, S., and Guo, S.: Secondary Organic Aerosol Formation from On-road Gasoline Vehicles in China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8093, https://doi.org/10.5194/egusphere-egu2020-8093, 2020.

Unexpectedly high daytime concentrations of nitrous acid (HONO) measured by field observations cannot be explained by theoretical calculations, implying that there may be a missing source of HONO in the daytime (Pmissing). The value of Pmissing near the ground (PGmissing) is different from that measured higher in the atmosphere (PHmissing) according to previous field studies, but the contribution of the vertical Pmissing profile in the atmospheric boundary layer (ABL) to air quality remains unknown. We derived a new formula PGmissing = 0.180 × J(NO2) [ppb s-1] based on field measurements near the ground, where J(NO2) is the photolysis frequency of NO2, and used the value of PHmissing inferred from Zeppelin measurements in the troposphere to parameterize Pmissing in the ABL. This parameterization was incorporated into the Weather Research and Forecasting model with Chemistry (WRF-Chem) to quantify the vertical effects of Pmissing on the concentrations of HONO, O3 and secondary organic aerosols (SOAs) in eastern China. Our results showed that PGmissing and PHmissing together further narrowed the gap between the simulations and observations, leading to a daytime increase in HONO concentrations of about 160 ppt near the ground compared with PGmissing only, an increase in the daytime concentrations of O3 of 8–37 ppb within the ABL in almost all of the studied domain in summer (1–19 ppb in winter and 4–21 ppb in autumn) and the largest hourly increase in the concentration of SOAs of 22.5 (18.6) μg m-3 in winter (summer). The results indicated that HONO sources near the ground have a limited effect on the HONO concentrations in the upper ABL even in summer in the presence of strong convective activities, while the HONO increase in the upper ABL can affect the concentration of HONO near the ground. When PGmissing was inserted into each model layer in the ABL, the concentrations of HONO higher in the atmosphere were substantially overestimated, suggesting that observations of the vertical distribution of HONO in the ABL are required in polluted areas.

How to cite: Guo, Y., An, J., Zhang, J., and Qu, Y.: Effect of vertical parameterization of a missing daytime source of HONO on concentrations of HONO, O3 and secondary organic aerosols in eastern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6301, https://doi.org/10.5194/egusphere-egu2020-6301, 2020.

AS3.14 – Atmospheric methane measurements - bridging anthropogenic emissions and mitigation

EGU2020-4469 | Displays | AS3.14

Attempt to estimate historical methane emissions from the oil and natural gas sector

Dieter Franke, Andreas Bahr, Johannes Gütschow, Martin Blumenberg, Stefan Ladage, Rüdiger Lutz, and Martin Pein

The worldwide operating petroleum industry is considered as one of the major contributors to global anthropogenic methane emissions. However, not only absolute numbers of methane emissions from oil and natural gas production and distribution vary greatly in different global inventories, also the relative contribution of the oil and the gas sector is under discussion. In different studies, the majority of methane emissions are assigned either to natural gas or to the oil sector. For the climate emission origins are of course irrelevant, however, for the climate budget of natural gas usage it is important to know which emissions are attributable to natural gas and what number is related to oil production with its associated natural gas.

Here we use the Federal Institute of Geosciences and Natural Resources’ (BGR) worldwide database on natural oil and gas production and consumption, dating back to 1900, and compare it to global bottom-up methane emission inventories. We will present and discuss several regression approaches that fit the global data reasonably well. In addition, methane emissions of country groups are compared to natural oil and gas production and consumption data. This study finds that the emission factors that relate to gas production released during oil and gas extraction likely vary over the time and across different production areas in the world.

How to cite: Franke, D., Bahr, A., Gütschow, J., Blumenberg, M., Ladage, S., Lutz, R., and Pein, M.: Attempt to estimate historical methane emissions from the oil and natural gas sector, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4469, https://doi.org/10.5194/egusphere-egu2020-4469, 2020.

EGU2020-11640 | Displays | AS3.14 | Highlight

Environmental Defense Fund Permian Basin Campaign: a science and advocacy-based approach to quantify and mitigate methane emissions from the oil and gas industry

David Lyon, Mark Omara, Ritesh Gautam, Kate Roberts, Beth Trask, Colin Leyden, Isabel Mogstad, Daniel Zavala-Araiza, and Steven Hamburg

The Permian Basin in west Texas and southeast New Mexico (United States) is one of the most productive oil and gas (O&G) basins in the world, but little methane emissions data have been collected from the region.  Environmental Defense Fund (EDF) is leading a year-long science and advocacy campaign to measure O&G methane emissions in the Permian Basin and quickly communicate the data to stakeholders including the public and O&G operators to facilitate emission reductions. EDF and our scientific partners are using three primary approaches to repeatedly quantify emissions at different spatial scales during the campaign. Pennsylvania State University is estimating regional methane emissions on a quarterly basis with atmospheric transport modeling of data collected from a network of five tower-based instruments. University of Wyoming is deploying a mobile laboratory on public roads to measure site-level emissions of methane and volatile organic compounds with EPA Other Test Method 33A and the transect approach.  Scientific Aviation is performing aerial mass balance flights to quantify emissions from small clusters of sites, gridded areas, and larger regions.  Additionally, EDF is collaborating with several groups using remote sensing approaches to quantify methane emissions including TROPOMI, AVIRIS-NG, GAO, and MethaneAIR.  Emissions data including site identities will be published on a custom public website as quickly as possible to educate stakeholders about the magnitude of emissions and facilitate the mitigation of detected emission sources. Following the campaign, data will be analyzed to understand patterns and trends in emissions.  Furthermore, we will discuss the potential for implementing similar monitoring approaches in other O&G basins to provide scientifically-rigorous, actionable data that supports effective mitigation of methane emissions.

How to cite: Lyon, D., Omara, M., Gautam, R., Roberts, K., Trask, B., Leyden, C., Mogstad, I., Zavala-Araiza, D., and Hamburg, S.: Environmental Defense Fund Permian Basin Campaign: a science and advocacy-based approach to quantify and mitigate methane emissions from the oil and gas industry, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11640, https://doi.org/10.5194/egusphere-egu2020-11640, 2020.

EGU2020-10810 | Displays | AS3.14

Can non-Methane hydrocarbons inform oil and gas emissions studies?

Scott Herndon, Conner Daube, Jordan Krechmer, Francesca Majluf, Edward Fortner, Christoph Dyroff, and Tara Yacovitch

Recently, the Aerodyne Mobile Laboratory quantified emissions of methane from oil and gas production sites in two very different oil and gas “plays”. The emission profile of non-methane hydrocarbons shows differences that are associated with the geologic source itself. Further analysis reveals that variations in the non-methane hydrocarbon profile can be exploited to pinpoint the specific piece of equipment that is emitting methane.  The mobile lab was outfitted with tunable infrared laser direct absorption spectrometers and a high resolution Vocus proton transfer reaction mass spectrometer.    This presentation will illustrate the key points with empirical examples and examine methods to attribute observed methane emission sources.      

How to cite: Herndon, S., Daube, C., Krechmer, J., Majluf, F., Fortner, E., Dyroff, C., and Yacovitch, T.: Can non-Methane hydrocarbons inform oil and gas emissions studies?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10810, https://doi.org/10.5194/egusphere-egu2020-10810, 2020.

EGU2020-18801 | Displays | AS3.14 | Highlight

ROMEO - ROmanian Methane Emissions from Oil and Gas

Thomas Röckmann and the The ROMEO team

According to UNFCCC statistics, in 2015 Romania was the country in the European Union that reported the highest emissions of CH4 from the oil and gas sector to the atmosphere, in particular related to methane production and end use. Limiting these oil and gas-related emissions could provide an attractive greenhouse gas emission reduction target for the EU. However, the reported estimates are derived using standard emission factors and there are only very few observations which investigate whether the reported emissions are realistic. The ROMEO project was designed to provide experimental quantification of methane emissions from the oil and gas sector in Romania. This may strengthen the scientific basis for establishing effective emission mitigation measures. ROMEO is part of the international Climate and Clean Air Coalition's (CCAC's) Methane Science Studies. In August 2019, the first  phase of ROMEO was a city campaign in Bucharest and Ploiesti, where methane emissions were quantified at the street level, using three vehicles. Source attribution was carried out by isotopic analysis and measurement of the ethane-methane ratio. The main ROMEO campaign took place in October 2019, using as campaign base the Strejnicu airfield near Ploiesti. Eight ground measurement teams visited more than 1000 individual facilities and performed methane measurements by stationary and mobile measurements from vehicles, using tracer release approaches and by plume mapping from drones. Very low wind speeds during the campaign period made emission quantification challenging, but about 200 quantifications were attempted. An optical gas imaging team visited many facilities in order to investigate the origin of the emissions at the component scale. Our project partner OMV-Petrom provided information on the facilities and site access where needed. Sites for emissions quantification were selected independent of the operator. To connect the facility scale to the regional scale, two research aircraft from INCAS and Scientific Aviation Inc. performed more than 20 research flights to identify and quantify methane emissions from individual facilities, facility clusters and extended regions. Ground-based in situ and total column measurements provide additional information on the background levels of CH4. Various models are used for emission quantification, from plume dispersion and mass balance models for individual facilities to atmospheric chemistry and transport models for interpretation of the larger scale aircraft measurements. The final goal of ROMEO is to provide a combined bottom-up and top-down approach to quantify CH4 emissions related to oil and gas exploration, natural gas distribution and gas use from Romania. I will present the overall setup of the ROMEO project, interesting examples from individual facilities and preliminary results from ground and airborne measurements.

How to cite: Röckmann, T. and the The ROMEO team: ROMEO - ROmanian Methane Emissions from Oil and Gas , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18801, https://doi.org/10.5194/egusphere-egu2020-18801, 2020.

EGU2020-13643 | Displays | AS3.14

Isotopic characterisation of methane emissions from oil and gas operation in Romania

Malika Menoud, Carina van der Veen, Hossein Maazallahi, Julianne Fernandez, Piotr Korben, Andreea Calcan, James France, David Lowry, Martina Schmidt, and Thomas Röckmann

Reducing methane emissions is an important goal of climate change mitigation policies. Recent studies focused on emissions from oil and gas industry, because fixing gas leaks presents a "no-regret" mitigation solution. Yet, uncertainties regarding the fossil fuel emission rates and locations, as well as temporal and spatial variability, are still large for individual source processes, in particular in regions without regular measurements. The Romanian Methane Emissions from Oil and gas (ROMEO) project brought 13 research teams to Romania in order to quantify emissions from this sector. Methane stable isotopes are widely used for source characterisation, but measurement data is lacking from many important geographical locations, such as Eastern Europe. 

A total of 380 air samples were collected in urban areas and around oil and gas extraction sites, from ground level vehicles and from an aircraft. There were measured for δ13C-CH4 and δD-CH4 using a continuous flow isotope ratio mass spectrometry (CF-IRMS) system. The results were analysed using the Keeling plot approach to derive source signatures at each sampled site. The source signatures obtained for 76 individual oil and gas operation sites range from -70.5 to -22.4 ‰ V-PDB, and from -252 to -144‰ V-SMOW, for δ13C and δD respectively. They show a large heterogeneity in δ13C, and more regularity in δD values. Variations are affected by the maturity of hydrocarbon deposits, and by different contributions from microbial and thermogenic gas. We will present how the signatures measured at the surface relate to the signatures found for larger plumes sampled from the aircraft. The results of the campaign in Bucharest city reveal a larger contribution from the waste system than fossil fuel fugitive emissions. 

The isotopic characterisation of methane emissions in this region will help to constrain the methane budget on a regional scale, and to improve national inventories.

How to cite: Menoud, M., van der Veen, C., Maazallahi, H., Fernandez, J., Korben, P., Calcan, A., France, J., Lowry, D., Schmidt, M., and Röckmann, T.: Isotopic characterisation of methane emissions from oil and gas operation in Romania, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13643, https://doi.org/10.5194/egusphere-egu2020-13643, 2020.

EGU2020-16633 | Displays | AS3.14

Characterization of methane emissions from oil and gas production in Mexico: Linking measurements to mitigation

Daniel Zavala-Araiza, Mark Omara, Ritesh Gautam, Mackenzie Smith, Stephen Conley, Sudhanshu Pandey, Sander Houweling, and Ilse Aben

A wide body of research has characterized methane emissions from the oil and gas supply chain in the US, with recent efforts gaining traction in Canada and Europe. In contrast, empirical data is limited for other significant oil and gas producing regions across the global south. Consequently, measuring and characterizing methane emissions across global oil and gas operations is crucial to the design of effective mitigation strategies.

Several countries have announced pledges to reduce methane emissions from this sector (e.g., North America, Climate and Clean Air Coalition [CCAC] ministers). In the case of Mexico, the federal government recently published regulations supporting a 40-45% reduction of methane emissions from oil and gas. For these regulations to be effective, it is critical to understand the current methane emission patterns.

We present results from multi-scale empirical estimates of methane emissions from Mexico’s major oil and gas production regions (both offshore and onshore), based on a set of airborne-based measurement campaigns, analysis of satellite data (TROPOMI), and development of spatially explicit inventories. Our results provide a revised estimate of total emissions in the sampled regions and highlight the importance of empirically based characterization as a basis for prioritization in terms of emission reduction opportunities.

Finally, we highlight how these measurements –as well as similar policy-relevant studies- connect into action, based on the current needs from relevant stakeholders (e.g., inventory builders, regulators and industry).

How to cite: Zavala-Araiza, D., Omara, M., Gautam, R., Smith, M., Conley, S., Pandey, S., Houweling, S., and Aben, I.: Characterization of methane emissions from oil and gas production in Mexico: Linking measurements to mitigation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16633, https://doi.org/10.5194/egusphere-egu2020-16633, 2020.

EGU2020-20416 | Displays | AS3.14

A top-down approach for quantifying methane and speciated VOC emissions from North Sea oil and gas facilities

Shona Wilde, Ruth Purvis, James Lee, James Hopkins, Alastair Lewis, Stuart Young, Ralph Burton, Ioana Colfescu, Dominika Pasternak, Stephen Mobbs, and Stephane Bauguitte

The North Sea is home to around 200 offshore platforms that extract oil and natural gas from beneath the sea. Total offshore emissions (carbon dioxide (CO2), nitrogen oxides (NO + NO2 = NOx), nitrous oxide (N2O), sulphur dioxide (SO2), carbon monoxide (CO), methane (CH4) and total VOCs) from upstream oil and gas production in the UK increased by 7 % from 2016 to 2017. Therefore, the accurate measurement and analysis of leakage is critical for global emissions inventories and in terms of mitigating climate change. A recent study (Riddick et al., 2019) showed that on average methane leakage during normal operations is more than double what is reported to the UK National Emissions Inventory (NAEI) for each installation. Here we provide a top-down emissions estimation methodology from which emissions of CH4 and up to 30 individual volatile organic compounds (VOCs) can be estimated for point-source platforms. We apply a direct integration technique, and use VOC measurements obtained within downwind plumes as a tool for source identification. A total of 16 research flights were conducted as part of a joint project between the UK National Centre for Atmospheric Science (NCAS), BEIS, the UK Offshore Petroleum Regulator for Environment and Decommissioning (OPRED) and Ricardo Energy & Environment to characterise emissions from platforms in the North Sea. The hydrocarbon to ethane enhancement ratio within downwind plumes, measured under well-mixed boundary layer conditions, was used to scale a 1 Hz ethane measurement from the aircraft to other hydrocarbons collected using whole air samplers and measured using GC-FID. This allowed individual VOC emission rates to be calculated and compared to existing inventories. This work highlights how a top down technique can be used to quantify emissions and also provide insight into specific emission sources, in contrast to existing methods which often fail to achieve both simultaneously.

How to cite: Wilde, S., Purvis, R., Lee, J., Hopkins, J., Lewis, A., Young, S., Burton, R., Colfescu, I., Pasternak, D., Mobbs, S., and Bauguitte, S.: A top-down approach for quantifying methane and speciated VOC emissions from North Sea oil and gas facilities, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20416, https://doi.org/10.5194/egusphere-egu2020-20416, 2020.

EGU2020-20729 | Displays | AS3.14

Methane emissions from shale gas production sites in Sichuan, China

Ming Xue, Yi-wei Zhao, Jun-xin Fan, and Dong-dong Cao

We performed ground-based methane emission measurements (downwind OTM33A method, on site methane measurements) from shale gas production sites in Sichuan province, China (Changning-Weiyuan region, 18 facilities with 81 wells). The mountainous geological location of the sites, and the limited road access has guaranteed only 2 to 3 downwind OTM-33A measurements. A backpack type high-sensitivity methane analyzer was applied to identify methane emissions and map the atmospheric methane distribution inside the gas facilities. The results showed that: the methane level along the fence line of the 16 facilities kept stable at background concentration, with the other 2 enhanced by less than 2 ppm. Inside the 10 facilities putting into production after 2016, pneumatic controllers from the three-phase separator showed no emission since they were running on electricity. Flowback water tanks were the major methane sources with concentration around 354 to 500ppm. Occasionally, the loose venting outlet of the actuator had leakage with methane concentration around 45 ppm. The application of high-sensitivity methane analyzer inside the facility has provided more detailed emission characteristics which could not be found by infrared camera before. This study could provide insights to the emission behavior from components and the distribution patterns of methane inside the shale gas facilities in Sichuan, China. For sites with a non-favored conditions for downwind measurements, other detection methods such as drone-based might be better to implement.

How to cite: Xue, M., Zhao, Y., Fan, J., and Cao, D.: Methane emissions from shale gas production sites in Sichuan, China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20729, https://doi.org/10.5194/egusphere-egu2020-20729, 2020.

EGU2020-19899 | Displays | AS3.14

Methane emission measurements at the North Sea

Ilona Velzeboer, Arnoud Frumau, Pim van den Bulk, and Arjan Hensen

In July and November 2018 measurements campaigns were performed at the North Sea. This campaign was aimed to assess independently total methane emissions of a selected group offshore oil and gas platforms using concentration measurements at multiple distances from the source in combination with meteorological conditions and dispersion calculations. This measurement set-up is in line with methane measurements carried out near onshore gas production locations in 2016-2017.

First observations with tracer experiments showed different behavior of the plumes offshore, compared to onshore plume behavior.

The Gaussian Plume model was modified with the methodology of the Offshore and Coastal Dispersion (ODC) model, to incorporate the effect of the sea surface and the building effect of the offshore installations on the dilution and mixing of the plume. Together with the performed tracer experiments, this resulted in more reliable calculations of the source strength of methane emissions from the installations.

How to cite: Velzeboer, I., Frumau, A., van den Bulk, P., and Hensen, A.: Methane emission measurements at the North Sea, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19899, https://doi.org/10.5194/egusphere-egu2020-19899, 2020.

EGU2020-15165 | Displays | AS3.14

Methane emissions from coal mines ventilation shafts in Upper Silesia, Poland

Mila Stanisavljevic, Jaroslaw Nęcki, Piotr Korbeń, Hossein Maazallahi, Malika Menoud, Sara Defratyka, Katarina Vinkovic, Carina van der Veen, Łukasz Chmura, Damian Zieba, Martina Schmidt, Wojciech Wołkowicz, Thomas Röckmann, Julia Wietzel, and Justyna Swolkień

Atmospheric methane is the second most important anthropogenic greenhouse gas after carbon dioxide. On the global scale, methane emissions are reasonably well constrained but the contributions from individual sources are highly uncertain (Saunois, 2016). According to bottom-up estimates, methane emissions from underground coal mining excavation contribute 11% to all anthropogenic methane sources (Saunois, 2016). However, there is a lack of in situ measurement to verify these estimates. Here we present results from measurements of the methane mole fraction over the Polish part of the Upper Silesian Coal Basin (USCB). Methane mole fraction was measured using vehicles equipped with high precision laser-based instruments (Picarro G2201-i CRDS, Picarro G2301- CRDS). Basic meteorological data (wind speed, wind direction) and GPS location data were collected on the roof of the vehicles. In order to obtain emission estimates, we attempted to cross the plumes from the coal mine shafts using public roads approximately perpendicular to plume downwind from the source. When possible, the plumes were intersected several times at different distances in order to have a closer look at uncertainties. A Gaussian plume model was used to calculate the release rate from the methane single source.

In addition to methane mole fraction measurements, we collected air samples for isotopic characterization (δ13C and δD) using isotope ratio mass spectrometry. We observed significant variation in measured methane isotopic composition over USCB (the results are in a range of -321 to -142 ‰ SMOW for δD and -31 to -58 ‰ VPDB for δ13CH4). The results indicated a much larger variability of the isotopic composition of methane emitted from coal mines than assumed previously, which may complicate the distinction of methane emissions from different sources by isotopic characterization.

Keywords: Methane, Greenhouse Gases, Clime Change, Coal Mine Ventilation Shafts, Methane Isotopic Compositions

Reference:

Saunois, M., Bousquet, P., Poulter, B., et al., 2016a. The global methane budget, 2000–2012. Earth Syst. Sci. Data 8, 697–751. https://doi.org/10.5194/essd-8-697-2016. www.earth-syst-sci-data.net/8/697/2016/.

This work is part of the Marie Sklodowska-Curie Initial Training Network MEMO2 , which enable us to extend these measurements to other European locations

How to cite: Stanisavljevic, M., Nęcki, J., Korbeń, P., Maazallahi, H., Menoud, M., Defratyka, S., Vinkovic, K., van der Veen, C., Chmura, Ł., Zieba, D., Schmidt, M., Wołkowicz, W., Röckmann, T., Wietzel, J., and Swolkień, J.: Methane emissions from coal mines ventilation shafts in Upper Silesia, Poland, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15165, https://doi.org/10.5194/egusphere-egu2020-15165, 2020.

EGU2020-19119 | Displays | AS3.14

Emissions of CH4, CO2, C2H6, CO and isotopic signatures in the Upper Silesian Coal Basin, Poland

Alina Fiehn, Julian Kostinek, Maximilian Eckl, Michal Galkowski, Jinxuan Chen, Christoph Gerbig, Thomas Röckmann, Hossein Maazallahi, Martina Schmidt, Piotr Korben, Jarek Necki, Norman Wildmann, Christian Mallaun, Theresa Klausner, Rostyslav Bun, Andreas Fix, and Anke Roiger

The Upper Silesian Coal Basin (USCB) represents one of the largest European CH4 emission source regions, with a total sum of 500 Gg CH4/a released by individual coal mine ventilation shafts. During the CoMet (Carbon Dioxide and Methane Mission) campaign in late spring 2018, airborne in-situ measurements were carried out aboard the DLR research aircraft Cessna Caravan. The Cessna was equipped with a cavity ring-down and a quantum cascade laser system to measure CH4 and CO2, as well as related tracers such as CO and C2H6. Additionally, air samples were collected and analyzed for greenhouse and trace gases, including isotopic ratios of CH4 and CO2. Meteorological parameters were measured with a boom mounted sensor package.

During nine research flights, CH4 emissions were studied by using an airborne Mass Balance Approach. Depending on the wind situation, different areas of the USCB region were targeted. To account for the lower part of the plume not accessible by the aircraft, a number of vans with mobile in-situ measurement systems conducted ground-based measurements in a coordinated manner. The derived methane emission estimate agrees well with bottom-up inventories like the Emission Database for Global Atmospheric Research (EDGAR) and the European Pollutant Release and Transfer Register (E‑PRTR). The CO2 emission estimate is at the lower end of the inventories. The CO emission estimate is higher than inventory values.

From simultaneous methane and ethane measurement the emission ratios of different subregions of the USCB could be determined. The emission ratios range from 19 to 290 CH4/C2H6 and are, thus, quite variable within this coal basin. From the analysis of collected flask air samples the isotopic composition of CH4 emissions was determined. Isotopic signatures of Polish USCB CH4 emissions are between -52.7‰ and -49.4‰ for δ13C and between -241‰ and -178‰ for δD. Samples taken in the Czech part of the USCB had a δD isotopic ratio of around -309‰, hinting at a larger influence of biogenic sources in this region.

How to cite: Fiehn, A., Kostinek, J., Eckl, M., Galkowski, M., Chen, J., Gerbig, C., Röckmann, T., Maazallahi, H., Schmidt, M., Korben, P., Necki, J., Wildmann, N., Mallaun, C., Klausner, T., Bun, R., Fix, A., and Roiger, A.: Emissions of CH4, CO2, C2H6, CO and isotopic signatures in the Upper Silesian Coal Basin, Poland, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19119, https://doi.org/10.5194/egusphere-egu2020-19119, 2020.

EGU2020-3363 | Displays | AS3.14

Urban greenhouse gas emissions from the Berlin area: A case study using airborne CO2 and CH4 in situ observations in summer 2018

Theresa Klausner, Mariano Mertens, Heidi Huntrieser, Michal Galkowski, Gerrit Kuhlmann, Robert Baumann, Alina Fiehn, Patrick Jöckel, Magdalena Pühl, and Anke Roiger

Urban areas are recognised as a significant source of greenhouse gas emissions (GHG), such as carbon dioxide (CO2) and methane (CH4). The total amount of urban GHG emissions, especially for CH4, however, is not well quantified. Here we report on airborne in situ measurements using a Picarro G1301-m analyser aboard the DLR Cessna Grand Caravan to study GHG emissions downwind of the German capital city Berlin. In total, five aircraft-based mass balance experiments were conducted in July 2018 within the Urban Climate Under Change [UC]2 project. The detection and isolation of the Berlin plume was often challenging because of comparatively small GHG signals above variable atmospheric background concentrations. However, on July 20th enhancements of up to 4 ppm CO2 and 21 ppb CH4 were observed over a horizontal extent of roughly 45 to 65 km downwind of Berlin. These enhanced mixing ratios are clearly distinguishable from the background and can partly be assigned to city emissions. The estimated CO2 emission flux of 1.39 ± 0.75 t s-1 is in agreement with current inventories, while the CH4 emission flux of 5.20 ± 1.61 kg s-1 is almost two times larger than the highest reported value in the inventories. We localized the source area with HYSPLIT trajectory calculations and the high resolution numerical model MECO(n) (down to ~1 km), and investigated the contribution from sewage-treatment plants and waste deposition to CH4, which are treated differently by the emission inventories. Our work highlights the importance of a) strong CH4 sources in the surroundings of Berlin and b) a detailed knowledge of GHG inflow mixing ratios to suitably estimate emission rates.

How to cite: Klausner, T., Mertens, M., Huntrieser, H., Galkowski, M., Kuhlmann, G., Baumann, R., Fiehn, A., Jöckel, P., Pühl, M., and Roiger, A.: Urban greenhouse gas emissions from the Berlin area: A case study using airborne CO2 and CH4 in situ observations in summer 2018, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3363, https://doi.org/10.5194/egusphere-egu2020-3363, 2020.

EGU2020-4611 | Displays | AS3.14

Quantifying urban methane emissions in the city of Stuttgart

Carolina Nelson, Martina Schmidt, André Butz, and Anke Roiger

Even if methane (CH4) is one of the most important anthropogenic greenhouse gases, its sources in urban areas are quantitatively highly uncertain. Plant et al. (2019) highlights that current urban inventories probably substantially underestimate real methane emissions. Bottom-up estimates from the German Environmental Agency show uncertainties in urban sources even higher than 300 % (LUBW 2014). Yet for decision makers it is essential to know the strength of potential sources in order to prioritise and perform mitigation actions.

Baden-Württemberg is amongst the regions with the highest estimated methane emission in Germany[i]. Its capital town Stuttgart with more than 600.000 inhabitants is not only the biggest town but also an important industrial centre of the region. As the city centre is located in a deep circular valley the geographical conditions of Stuttgart favour high air pollution and emission stresses. Therefore, the need of emission reduction is strong and of high political interest. Using the example of Stuttgart, this work empirically targets the gap of knowledge about urban methane emission to provide a scientific base for effective local policy measures. More precisely, this study aims to exemplarily quantify typical urban source like waste water treatment plants and natural gas distribution and storage systems in the city of Stuttgart, Germany, by drive-by in-situ measurements and applied plume diffusion models.

Within this study, two optical instruments are used in a mobile setup in a van to measure CH4, CO2, H2O, Ethane and δ13CH4 isotopes: a cavity ring-down spectrometer (CRDS, Picarro G2201-I) and Trace Gas Analyzer (OF-CEAS, LiCor LI-7810). Simultaneous 2D wind data and recorded weather conditions allow the application of dispersion models. Our research group used this technique and successfully tested a gaussian plume model on rural sources like dairy farms around Heidelberg, Germany. With the help of the isotopic composition and the Ethane concentrations, thermogenic sources and biogenic sources can be differentiated.

In August and December 2019, two short campaigns have been performed to identify potentially big sources in Stuttgart. The wastewater treatment plant in Mühlhausen and the natural gas storage facility in Gaisberg have been selected as representative targets. A next campaign is planned in spring 2020, including probably 3D-wind measurements and elaborated dispersion models. By taking advantage of inversion weather conditions, which are typical for Stuttgart, mass balance models can possibly be applied. So far, the results promise to allow quantifying emission rates of the target sources.

LUBW 2014: Luftschadstoff-Emissionskataster Baden-Württemberg 2014, Landesanstalt für Umwelt, Messungen und Naturschutz Baden-Württemberg (LUBW)

Plant et al. 2019: Large Fugitive Methane Emissions From Urban Center Along the U.S. East Coast, Genevieve Plant, Eric A. Kort, Cody Floerchinger, Alexander Gvakharia, Isaac Vimont and Colm Sweeney, Geophysical Research Letters 2019

[i] https://www.statistikportal.de/de/ugrdl/ergebnisse/gase/ch4

 

How to cite: Nelson, C., Schmidt, M., Butz, A., and Roiger, A.: Quantifying urban methane emissions in the city of Stuttgart, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4611, https://doi.org/10.5194/egusphere-egu2020-4611, 2020.

EGU2020-21759 | Displays | AS3.14

Characteristics of urban street level methane emissions in Bucharest, Romania

Julianne Fernandez, James France, Malika Menoud, Hossein Maazallahi, Marius-Paul Corbu, Thomas Röckmann, Rebecca Fisher, and Dave Lowry

Romania has a complex geological history resulting in a very hydrocarbon rich region that is heavily exploited and utilised. Romania’s Fourth Biennial Report under the UNFCCC states that methane (CH4) emissions have decreased by 61% between 1989 and 2017, which is a result of decreases in fugitive fossil fuel and livestock emissions. Although there is a decreasing trend of CH4 levels in most of Europe, we still see an overall increase in atmospheric CH4 concentrations. As atmospheric CH4 continues to increase and the mitigation of greenhouse gases becomes more of a concern, it is important to address CH4 emissions from large cities.  Here we ask the question: What are the major sources of urban methane emissions in Romania’s city capital, Bucharest? Together, street level continuous measurements of CH4 and ethane (C2H6), and δ13C-CH4 & δ2H-CH4 of high concentration plumes assist in the identification of emissions, both for major point sources and small leaks from the natural gas distribution system.

 

Urban focused surveys were conducted in Bucharest during August of 2019. Three continuously-measuring instruments were used, including an LGR Ultraportable CH4/C2H6 analyzer, allowing for the separation of natural gas leaks from other source category emissions. CH4 and C2H6 have been mapped to find locations of elevated mixing ratios above background. Air samples were collected from an inlet on the vehicle bumper (60 cm above ground) that is connected to a bag pump, filling 3L Flexfoil bags.  Samples were then analyzed for δ13C-CH4 & δ2H-CH4 using an IsoPrime Trace Gas continuous flow gas chromatograph isotope ratio mass spectrometer (CF GC-IRMS) at Royal Holloway, University of London and a Thermo Fisher Delta Plus XP, at Utrecht University. Background baselines of CH4 and isotopic ratios were statistically determined while traveling and distinguished from the various plumes of high concentrations. Point source signatures were then calculated using Keeling plot analysis. C2:C1 ratios from specific emissions types were compared with the correlated δ13CCH4 values.

 

Detailed urban methane mapping and the use of high precision isotopic source signature measurements provide an efficient approach to identifying and sourcing small gas leaks in urban cities. These results will be useful in future government regulation of greenhouse gas emissions in urban areas as the EU continues to work on the reduction of greenhouse gases.

How to cite: Fernandez, J., France, J., Menoud, M., Maazallahi, H., Corbu, M.-P., Röckmann, T., Fisher, R., and Lowry, D.: Characteristics of urban street level methane emissions in Bucharest, Romania, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21759, https://doi.org/10.5194/egusphere-egu2020-21759, 2020.

EGU2020-4930 | Displays | AS3.14

Atmospheric satellite-based and in situ surface observations on summertime trace gases (CO, CO2, CH4) over the metropolitan area of Bucharest

Marius-Paul Corbu, Andreea Calcan, Ioana Vizireanu, Denisa Elena Moaca, Robert-Valentin Chiritescu, Thomas Roeckmann, Hossein Maazallahi, Julianne Mae Fernandez, James France, and Gabriela Iorga

Although anthropogenic emissions of trace gases have decreased over the last decades in Europe, strong additional reductions are required to reach the goals of the Paris climate agreements. In addition, air pollution is an issue of great concern for the inhabitants of the metropolitan area of Bucharest, as the local air quality is often poor. The rapid development of the city, increased traffic volume from a mixed vehicle fleet (different technologies and fuels), and other factors are strong contributors of emissions of greenhouse gases and air pollutants in Bucharest.

The goal of this research was the assessment of CO, CO2 and CH4 concentrations in Bucharest, identification of potential emissions hotspots and their causes (anthropogenic or natural/biogenic, local or distant) and determination of the background values.

Measurements were performed in summer 2019 in four districts of Bucharest covering about two thirds of the metropolitan area during the Romanian Methane Emissions from Oil&gas (ROMEO) campaign with high resolution (1 sec). These data sets were complemented with satellite observations of CO and CH4 from Copernicus Sentinel-5P at a resolution of 7 km2.

Hourly meteorological data, temperature, relative humidity, wind speed and direction, and atmospheric pressure were added to the air pollutant data set because synoptic conditions can strongly influence the levels of pollution. Air mass origins were investigated by computing backward air mass trajectories using the HYSPLIT (Hybrid Single-Particle Lagrangian Integrated Trajectory) model for 72 hours back.

Points of high concentrations of CO, CO2, CH4 near the surface were identified which are, most likely, linked to local anthropogenic activities in the nearby surroundings. We identified a variation of concentrations of CO from 0.01 to 101 ppm, of CO2 from 388 to 6556 ppm, and of CH4 from 1.89 to 246 ppm, while background levels are as follows: 0.071±0.042 ppm CO, 392.68±3.01 ppm CO2, and 1.93±0.016 ppm CH4.

Results of our study provide an up to date quantitative image of CO, CO2, CH4 hotspots in the Bucharest area, which is important for modeling air quality and may also help to improve the relationships between column integrated air pollution data with in situ ground observations.

Acknowledgement:

This research is supported by ROMEO project, developed under UNEP’s financial support PCA/CCAC/UU/DTIE19-EN652. Partial financial support from UB198/Int project is also acknowledged.

The authors acknowledge the free use of tropospheric CO and CH4 column data from TROPOMI (Sentinel-5P) sensor from https://s5phub.copernicus.eu and the NOAA Air Resources Laboratory for the provision of the HYSPLIT transport model available at READY website https://www.ready.noaa.gov

Special thanks to all INCAS technical staff for their support in performing the campaigns.

How to cite: Corbu, M.-P., Calcan, A., Vizireanu, I., Moaca, D. E., Chiritescu, R.-V., Roeckmann, T., Maazallahi, H., Fernandez, J. M., France, J., and Iorga, G.: Atmospheric satellite-based and in situ surface observations on summertime trace gases (CO, CO2, CH4) over the metropolitan area of Bucharest, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4930, https://doi.org/10.5194/egusphere-egu2020-4930, 2020.

EGU2020-19995 | Displays | AS3.14

Using atmospheric in situ mobile measurements to monitor urban methane emissions

Sebastien Ars, Debra Wunch, Tazeen Ajmeri, Colin Arrowsmith, Genevieve Beauregard, Rica Cruz, Lawson Gillespie, Sajjan Heerah, Emily Knuckey, Juliette Lavoie, Cameron Macdonald, Nasrin Mostafavi Pak, Sheryl Nguyen, Jaden L. Phillips, and Felix Vogel

Despite the Paris Agreement, greenhouse gas (GHG) concentrations in the atmosphere continue to increase because of the anthropogenic activities, and this is inducing catastrophic effects. Past studies revealed that urban areas are responsible of a large part of these emissions and many cities already started to implement climate actions to reduce their GHG emissions and address climate change. The effectiveness of these actions depends on accurate knowledge of the many sources of GHG in each city, so that efforts are focused on the sources whose emission reduction would be the most effective. Atmospheric measurements are useful to locate and characterize these sources and to monitor the evolution of their emissions. Different approaches have been developed during the past decades including stationary and mobile surface-based in situ measurements, remote sensing of solar absorption spectra from space and from the ground, or aircraft-based observations. All these techniques are complementary and provide information about urban GHG emissions at different scales.

In situ mobile measurements of methane mixing ratios have been performed in the two largest cities of Canada using 1) a high-precision gas analyzer providing continuous measurements, 2) a weather station measuring wind speed and direction, and 3) a GPS recording coordinates during the campaigns. These mobile surveys allow rapid screening of large areas, the revisit of specific sites to monitor the evolution of their emissions over time, and can therefore improve our understanding of the emissions at local scale. Methane emissions of the Greater Toronto Area (GTA) have been intensively investigated since 2018 with a total of 84 days of measurements corresponding to a distance of about 8,000 km. A one-week campaign has also been realized in November 2019 in Montreal corresponding to a distance of about 1,100 km. Methane enhancements observed during these surveys have been identified, classified into three categories depending on their magnitudes and areas, and attributed to potential sources, several of which are not catalogued in FLAME-GTA, the point source level inventory developed for the Toronto metropolitan area. Important methane sources in the GTA have been surveyed regularly since 2018 and their emissions have been estimated using an inverse modeling framework with a Gaussian model and compared to the inventory-based estimates of FLAME-GTA.

 

How to cite: Ars, S., Wunch, D., Ajmeri, T., Arrowsmith, C., Beauregard, G., Cruz, R., Gillespie, L., Heerah, S., Knuckey, E., Lavoie, J., Macdonald, C., Mostafavi Pak, N., Nguyen, S., Phillips, J. L., and Vogel, F.: Using atmospheric in situ mobile measurements to monitor urban methane emissions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19995, https://doi.org/10.5194/egusphere-egu2020-19995, 2020.

EGU2020-745 | Displays | AS3.14

Global Methane Emissions Through an Isotopic Lens

Alice Drinkwater, Tim Arnold, and Paul Palmer

Changes in atmospheric methane (CH4) are mainly driven by natural, anthropogenic and pyrogenic emissions and oxidation by OH.

There is no consensus about the underlying explanations about hemispheric-scale changes in atmospheric methane (CH4). This is partly due to sparse data that do not exclusively identify individual changes in surface emissions and surface and atmospheric losses of CH4. This challenge represents a major scientific weakness in our understanding of this potent greenhouse gas, with implications for meeting global climate policy obligations.  A confounding challenge is that the regional importance of individual emission sources change with time due to, for example, innovations in agricultural practices, climate-sensitive wetlands, and political decisions associated with climate friendlier transitional fuels.  


Here we use bulk isotope ratios δ13C and δD of CH4 that have been previously shown to provide effective constraints on source apportionment: different CH4 sources have characteristic isotope ratios. One of the key challenges associated with using these data is that region-specific isotope ratios change with time due to varying source prevalance, in addition to source signatures having inherent uncertainties. We use the GEOS-Chem global 3-D chemical transport model to describe the spatial and temporal isotopic behaviour of atmospheric CH4. We develop a Maximum A-Posteriori inverse method to simultaneously infer time dependent CH4 emissions and isotope ratios from in situ data. 

We will report the magnitude, distribution and source attribution of CH4 emissions from 2004 to 2017, inferred from in situ measurements of total atmospheric CH4 mole fraction and the corresponding measurements of δ13C and δD. We will compare our results with previous studies.

How to cite: Drinkwater, A., Arnold, T., and Palmer, P.: Global Methane Emissions Through an Isotopic Lens, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-745, https://doi.org/10.5194/egusphere-egu2020-745, 2020.

EGU2020-18829 | Displays | AS3.14

Simulation of methane point source emissions and their isotopic signatures using the global/regional climate model MECO(n).

Anna-Leah Nickl, Franziska Winterstein, Mariano Mertens, Astrid Kerkweg, Alina Fiehn, Christoph Gerbig, Michal Galkowski, and Patrick Jöckel

Methane is the second most important anthropogenic greenhouse gas. The globally averaged dry mole fraction has increased considerably since pre-industrial times and its growth even accelerated in 2014, with an annual rise of 12.7 ± 6 ppb. Fossil fuel emissions are one of the primary sources. However, the quantification of methane sources and sinks is still under debate and estimates of anthropogenic emissions show large uncertainties on global and regional scales. Comprehensive measurement campaigns, such as CoMet 1.0 (May-June 2018), are therefore important for assessing climate change mitigation options. CoMet aimed to quantify point source emissions in the Upper Silesian Coal Basin (USCB), where roughly 502 kt/yr of methane are emitted due to coal mining. Differences in isotopic methane source signatures δ13C and δD can further help to constrain different source contributions (e.g. thermogenic or biogenic). We simulate methane isotopologues from localized coal mine emissions in the USCB using the on-line three times nested global regional chemistry climate model MECO(n). We use a submodel extension, which includes the kinetic fractionation and make different assumptions on the isotopic source signatures in the USCB. Here we show first results of these simulations and a comparison to flask samples taken during CoMet 1.0.

How to cite: Nickl, A.-L., Winterstein, F., Mertens, M., Kerkweg, A., Fiehn, A., Gerbig, C., Galkowski, M., and Jöckel, P.: Simulation of methane point source emissions and their isotopic signatures using the global/regional climate model MECO(n)., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18829, https://doi.org/10.5194/egusphere-egu2020-18829, 2020.

EGU2020-6760 | Displays | AS3.14

MEMO2: MEthane goes MObile – MEasurements and Modelling

Sylvia Walter and Thomas Röckmann and the MEMO2 team

Reaching the targets of the Paris Agreement requires massive reductions of greenhouse gas emissions. CH4emissions are a major contributor to Europe’s global warming impact and emissions are not well quantified yet. There are significant discrepancies between official inventories of emissions and estimates derived from direct atmospheric measurement. Effective emission reduction can only be achieved if sources are properly quantified, and mitigation efforts are verified. New advanced combinations of measurement and modelling are needed to archive such quantification.

MEMO2is a European Training Network with more than 20 collaborators from 7 countries. It is a 4-years project and will contribute to the targets of the EU with a focus on methane (CH4). The project will bridge the gap between large-scale scientific estimates from in situmonitoring programs and the ‘bottom-up’ estimates of emissions from local sources that are used in the national reporting by I) developing new and advanced mobile methane (CH4) measurements tools and networks, II) isotopic source identification, and III) modelling at different scales. Within the project qualified scientists will be educated in the use and implementation of interdisciplinary knowledge and techniques that are essential to meet and verify emission reduction goals. MEMO2facilitates intensive collaboration between the largely academic greenhouse gas monitoring community and non-academic partners who are responsible for evaluating and reporting greenhouse gas emissions to policy makers.

We will present the project, its objectives and the results so far to foster collaboration and scientific exchange.

How to cite: Walter, S. and Röckmann, T. and the MEMO2 team: MEMO2: MEthane goes MObile – MEasurements and Modelling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6760, https://doi.org/10.5194/egusphere-egu2020-6760, 2020.

EGU2020-9673 | Displays | AS3.14

Methane emission rates from water infrastructures derived from mobile surveys along the final course of the Llobregat basin

Roger Curcoll, Carme Estruch, Jordi Freixas, and Josep-Anton Morgui

The final course of the Llobregat river (south-west of Barcelona, Spain) is surrounded by densely populated cities, industrial areas and agricultural lands. Multiple water infrastructures where anaerobic processes may be expected are present in the basin: three wastewater treatment plants, a drinking water treatment plant, several irrigation channels and a desalination plant. Other likely methane emission infrastructures as waste processing plants or gas refilling stations are present, together with natural methane potential sources as wetlands.

Multiple mobile measurements were performed during 2019 along the final course of the Llobregat basin to study the variability of methane emissions throughout the year. The surveys were carried out in different days at different times with a car equipped with a flight-ready CO2/CH4/H2O cavity ring-down spectrometer.

Emissions of different infrastructures and its variability throughout the year has been determined using a statistical approach from the georeferenced data. Local winds and plume modeling has been used to better pinpoint the sources and estimate the emissions. Finally methane concentrations and emissions variability have been related with meteorological factors as temperature or pressure. These factors, together with human-related management of the water infrastructures, may drive the methane emissions significantly far from inventory estimations.

How to cite: Curcoll, R., Estruch, C., Freixas, J., and Morgui, J.-A.: Methane emission rates from water infrastructures derived from mobile surveys along the final course of the Llobregat basin, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9673, https://doi.org/10.5194/egusphere-egu2020-9673, 2020.

EGU2020-10993 | Displays | AS3.14

Estimating Methane Emissions in the Surat Basin, Australia, including turbulent vertical Fluxes

Bruno Neininger, Jorg M. Hacker, and Wolfgang Lieff

Last year we described the campaign and the first results (Kelly et al., 2019; Neininger et al., 2019).

This year we will give an update on methods applied for estimating the regional methane emissions on a scale of about 10'000 km2, and sub-regions of about 2'500 km2.

Two approaches were applied:

  1. The classical mass balance, where the inflow and the outflow of an imaginary box was calculated, based on almost perfect Lagrangian cross-sections (following the air mass).
  2. A mass balance for the part of the boundary layer, where flight tracks were available (below 300 m above ground), supplemented by vertical turbulent fluxes to above this height.

In the best case, the two methods are leading to similar emission rates. The advantage of method (2) is, that the long flight legs can be limited to the lower boundary layer, which is especially useful when a convective boundary layer is reaching up to typically 2 km or higher above the surface.

The method worked quite well for water vapour, CO2 and sensible heat, where fully resolved turbulent fluxes could be calculated based on 10 Hz measurements along the flight legs. Since CH4 could only be measured with a temporal resolution of about two seconds (0.5 Hz), these a-priori results of the turbulent vertical fluxes are less consistent. However, by applying factors of turbulent versus advective fluxes from the other species, the agreement between the two methods was improved. The turbulent transport to above the 300-metre-layer during the convective conditions was about equal to the accumulation in this layer.

Since estimating the height of the convective boundary layer and the assumption that the mixing is perfect for approach (1) has many limitations, using method (2) has the advantage that less assumptions on homogeneity of the atmosphere above the densely observed layer has to be made. Even when the concentration profiles and the wind are known from vertical soundings (excursions to above the convective boundary layer), the horizontal inhomogeneity remains unknown. When using the vertical turbulent fluxes into this unknown volume above the lower layer, inhomogeneous mixing is not a problem.

The challenge of method (2) is to measure fast and precise enough for the quantification of the vertical fluxes. When concentrating on this, one could save time by omitting high soundings, improving the horizontal coverage, and therefore the statistics for the vertical fluxes.

References

Kelly et al.: Direct Measurement of Coal Seam Gas and Agricultural Methane Emissions in the Surat Basin, Australia. EGU 2019.

Neininger, B., J. M. Hacker and W. Lieff: Airborne Measurements for estimating Methane Emissions in the Surat Basin, Australia. EGU 2019.

How to cite: Neininger, B., Hacker, J. M., and Lieff, W.: Estimating Methane Emissions in the Surat Basin, Australia, including turbulent vertical Fluxes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10993, https://doi.org/10.5194/egusphere-egu2020-10993, 2020.

EGU2020-12508 | Displays | AS3.14

Methane Source Attribution Challenges in the Surat Basin, Australia

Xinyi (Lexie) Lu, Stephen J. Harris, Rebecca E. Fisher, Dave Lowry, James L. France, Jorg Hacker, Bruno Neininger, Thomas Röckmann, Carina van der Veen, Malika Menoud, Stefan Schwietzke, and Bryce F.J. Kelly

One of the case study sites for the Climate and Clean Air Coalition (CCAC) Methane Science Studies is the coal seam gas (CSG) field in the Surat Basin, Queensland, Australia, where there are over 6000 CSG wells and associated gas and water processing infrastructure. Previous bottom-up estimates suggest that the major source of methane in the region is cattle, not CSG (Katestone, 2018, Luhar et al. 2018).

In September 2018, an airborne measurement campaign was undertaken to provide a top-down estimate of regional methane emissions. Modelling of the airborne methane mole fraction data has produced a defensible total methane emissions estimate. However, there are challenges with proportioning the top-down estimates provided by the airborne data, because of adjacent sources with similar d13C-CH4 isotopic chemistry, rapid mixing of adjacent sources and substantial dilution of the plumes at the airborne measurement sampling height. We present how we will overcome these challenges.

At each gas production well, tens of thousands of litres of water are produced daily in association with the methane extracted from the coal measures. This water is stored in ponds and is also used as a water supply for cattle feedlots, which are located throughout and adjacent to the CSG wells and processing facilities. Power stations are also located within the CSG field. This arrangement makes it challenging to obtain clean top-down estimates of the emissions from CSG production. Quantifying methane emissions associated with CSG production is further complicated by numerous other sources of methane in the region immediately adjacent to the CSG field. These sources include grazing cattle, abattoirs, more power production facilities, coal mines, wetlands, natural gas seeps, and small urban centres with associated sewage treatment plants and landfills. Grab bag air samples were collected at each of these sources and analysed for d13C-CH4, d13C-CO2 and dD-CH4.

The airborne measurement campaign was undertaken under warm daytime spring conditions. This caused rapid uplift and mixing of the methane plumes. The maximum difference between the lowest and highest methane mole fraction from 90 airborne collected grab bag air samples was only 0.03 ppm. Even at this low mole fraction, by implementing quality management protocols we were able to extract trends in the isotope data sets. This presentation will outline the quality management procedures and how the measurements of d13C-CH4, d13C-CO2 and dD-CH4 will be used to assist with methane source attribution.

Reference

Katestone Environmental Pty Ltd (2018) Surat Basin Methane Inventory 2015 - Summary Report. Prepared for CSIRO March 2017 (D15193-11).

Luhar, A., Etheridge, D., Loh, Z., Noonan, N., Spencer, D., Day, S. (2018). Characterisation of Regional Fluxes of Methane in the Surat Basin, Queensland. Final report on Task 3: Broad scale application of methane detection, and Task 4: Methane emissions enhanced modelling. Report to the Gas Industry Social and Environmental Research Alliance (GISERA). Report No. EP185211, October 2018. CSIRO Australia.

How to cite: Lu, X. (., Harris, S. J., Fisher, R. E., Lowry, D., France, J. L., Hacker, J., Neininger, B., Röckmann, T., van der Veen, C., Menoud, M., Schwietzke, S., and Kelly, B. F. J.: Methane Source Attribution Challenges in the Surat Basin, Australia, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12508, https://doi.org/10.5194/egusphere-egu2020-12508, 2020.

EGU2020-13176 | Displays | AS3.14

Emissions of methane from temperate artificial reservoirs – what is already known

Jaroslava Frouzova and Jan Bašta

Methane is assumed to belong to the most  important greenhouse gases, however factors affecting methane production and emission are still not satisfactory elucidated. Artificial reservoirs which are critical resources to obtain water and hydropover in many countries are  one of the methane sources which received only limited attention so far.   We reviewed existing information about methane emissions from them.  Emissions  are combination of diffusion, ebullition and degassing under dam, but not all pathway must be presented. Nineteen studies, mainly from North America and Europe were compared, Only small portion of the studies was focusing on all pathways of methane release. Spatio-temporal variability, which is especially high for ebullition (ebullition is probably responsible for the most of the methane emissions), was covered in 3 reservoirs only. For this purposes is newly used acoustical method good tool, hydroacoustics cover mainly spatial variability of ebullition, which is poorly couth by traditional bubble traps. The most of the  studies was performed in summer period only and for low number of localities.  Future studies should use more uniform design covering better all potential pathway of methane emissions and  taking care of spatio-temporal variability of ebullition.  More systematic studies covering effect of climate and landscape variables as well as reservoir properties (morphology management etc.) are needed.

How to cite: Frouzova, J. and Bašta, J.: Emissions of methane from temperate artificial reservoirs – what is already known, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13176, https://doi.org/10.5194/egusphere-egu2020-13176, 2020.

EGU2020-14778 | Displays | AS3.14

Estimating local methane sources from drone-based laser spectrometer measurements by mass-balance method

Randulph P. Morales, Jonas Ravelid, Killian P. Brennan, Béla Tuzson, Lukas Emmenegger, and Dominik Brunner

Methane from facility-scale sources (e.g. landfills and oil and gas production facilities) are prone to leakage giving rise to highly uncertain emission flux estimates. To assess the overall impact of these sources, quantification from a representative set of individual sources – from which bottom-up inventories are generated - is necessary. An attractive approach to quantify emissions from diffusive and leaky sources involves deploying an unmanned aerial vehicle (UAV) equipped with a methane sensor which allows complete mapping of the spatial and temporal variability of emission plumes within a short period of time.

Atmospheric methane concentrations were measured using a Quantum Cascade Laser Absorption Spectrometer (QCLAS) developed in-house. The spectrometer reaches in-flight precision of a few ppb at 1s time resolution, and its lightweight and compact footprint (~ 2.0 kg, ~ 15.0 x 45.0 x 25.0 cm) allows it to be mounted and flown on a commercial drone.

We quantify methane emission fluxes from local sources by applying the mass balance method using the drone-based QCLAS system. The drone was flown downwind of a given source perpendicular to the main wind direction at different altitudes above ground, while geostatistical interpolation (Kriging) of the measured methane molar fractions was performed to spatially fill the gaps. The interpolated concentrations were multiplied by the cross-sectional area and the mean stream-wise wind profile obtained from a 3D sonic anemometer to get an emission flux.

We report on the analysis of how well known emissions can be reproduced using this quantification setup based on controlled release experiments. Furthermore, we discuss the sensitivity of different measurement configurations, and provide recommendations for an optimal sampling and quantification strategy. We demonstrate the suitability and flexibility of the quantification method in investigating a wide range of facility-scale sources, which are not attainable with measurements from conventional ground-based sensors.

How to cite: Morales, R. P., Ravelid, J., Brennan, K. P., Tuzson, B., Emmenegger, L., and Brunner, D.: Estimating local methane sources from drone-based laser spectrometer measurements by mass-balance method, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14778, https://doi.org/10.5194/egusphere-egu2020-14778, 2020.

EGU2020-17468 | Displays | AS3.14

Improved isotopic characterisation of methane emissions from biomass burning

Rebecca Fisher, Euan Nisbet, James France, Amber Riddle, David Lowry, Mathias Lanoiselle, Xinyi Lu, and Bryce Kelly

Emissions of methane from combustion sources are typically distinguished by being enriched in 13C and 2H, causing a large isotopic shift to atmospheric methane δ13C and δD measurements downwind of fires.

The isotopic composition of the plant material being burnt has a strong effect on the isotopic composition of methane, with combustion of C4 plant material producing methane more enriched in 13C than C3 plant combustion. Characterisation of the bulk isotopic signature of methane emitted from large areas of biomass burning is required to improve our ability to use isotopes in global models and ascertain the extent to which fire emissions influence interannual variations in the methane budget.

Two approaches have been used to collect air samples from large areas of biomass burning for isotopic characterisation of methane emitted from the fires. In campaigns in Senegal, Uganda, Zambia and Finland, the UK’s FAAM research aircraft flew through fire plumes and onboard measurement of methane concentration allowed targeted sampling within the plumes. This work was carried out as part of the NERC highlight Global Methane Budget project (MOYA). Ground based sampling downwind of fires around Sydney, New South Wales in late 2019/early 2020 has allowed isotopic characterisation of those plumes. All air samples were measured by isotope ratio mass spectrometry at Royal Holloway University of London and Keeling plots used to identify source signatures, e.g. δ13C for fires in Senegal in March 2017 was -28.5 ± 0,8 , typical of C3 burning.

In this work we compare the isotopic signatures of methane from burning in these particular regions and discuss the extent to which the regional variability of the isotopic composition of fire emissions should be taken into account in global models using isotopes to constrain the global methane budget.

How to cite: Fisher, R., Nisbet, E., France, J., Riddle, A., Lowry, D., Lanoiselle, M., Lu, X., and Kelly, B.: Improved isotopic characterisation of methane emissions from biomass burning, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17468, https://doi.org/10.5194/egusphere-egu2020-17468, 2020.

EGU2020-5651 | Displays | AS3.14

Methane emission to the atmosphere from landfills in the Canary Islands

Eleazar Padrón, María Asensio-Ramos, Nemesio M. Pérez, Daniel Di Nardo, Violeta T. Albertos-Blanchard, Mar Alonso, Franco Tassi, Brunella Raco, and Dina López

Methane (CH4) is an important greenhouse gas, and is increasing in the atmosphere by 0.6% (10 ppb) each year. Important sources of this gas are landfills; in fact more than 10% of the total anthropogenic emissions of CH4 are originated in them by anaerobic degradation of organic matter. Even after years of being closed, a significant amount of landfill gas can be released to the atmosphere through its surface as diffuse or fugitive degassing.

Many landfills currently report their CH4 emissions to the atmosphere using model-based methods, which are based on the rate of production of CH4, the oxidation rate of CH4 and the amount of CH4 recovered (Bingemer and Crutzen, 1987). This approach often involves large uncertainties due to inaccuracies of input data and many assumptions in the estimation. In fact, the estimated CH4 emissions from landfills in the Canary Islands published by the Spanish National Emission and Pollutant Sources Registration (PRTR-Spain) seem to be overestimated due to the use of protocols and analytical methodologies based on mathematical models. For this reason, direct measurements to estimate CH4 emissions in landfills are essential to reduce this uncertainty.

In order to estimate the CH4 emissions to the atmosphere from landfills in the Canary Islands, 34 surveys have been performed since 1999 to the present. Each survey implies hundreds of CO2 and CH4 efflux measurements covering the landfill surface area. Surface landfill CO2 efflux measurements were carried out at each sampling site by means of a portable non-dispersive infrared spectrophotometer (NDIR) model LICOR Li800 following the accumulation chamber method. Samples of landfill gases were taken in the gas accumulated in the chamber and CO2 and CH4 were analyzed using a double channel VARIAN 4900 micro-GC. The CH4 efflux measurement was computed combining CO2 efflux and CH4/CO2 ratio. To quantify the diffuse or fugitive CO2 and CH4 emission, gas efflux contour maps were constructed using sequential Gaussian simulation (sGs) as interpolation method. Considering that (a) there are 6 controlled landfills in the Canary Islands, (b) the average area of the 34 studied cells is 0.15 km2 and (c) the mean value of the CH4 emission estimated for the studied cells range between 6.2 and 7.2 kt km-2 y-1, the estimated CH4 emission to the atmosphere from landfills in the Canary Islands showed a range of 5.7-6.7 kt y-1 (mean value of 6.2 kt y-1). On the contrary, and for the same period of time, the PRTR-Spain estimates the CH4 emission in the order of 6.4-16.4 kt y-1 (mean value of 9.2 kt y-1), nearly 46% more than our estimated value. This result demonstrates the need to perform direct measurements to estimate the surface fugitive emission of CH4 from landfills.

Bingemer, H. G., and P. J. Crutzen (1987), J. Geophys. Res. 92, 2182-2187.

How to cite: Padrón, E., Asensio-Ramos, M., Pérez, N. M., Di Nardo, D., Albertos-Blanchard, V. T., Alonso, M., Tassi, F., Raco, B., and López, D.: Methane emission to the atmosphere from landfills in the Canary Islands, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5651, https://doi.org/10.5194/egusphere-egu2020-5651, 2020.

EGU2020-17839 | Displays | AS3.14

Characterization and Quantification of Methane Emissions from Waste in the UK

semra Bakkaloglu, David Lowry, Rebecca Fisher, James France, Mathias Lanoiselle, and Julianne Fernandez

Mitigation of climate change is a key scientific and societal challenge. CH4 emissions are a major contributor to global warming impact and these are not well quantified yet. There are significant discrepancies between official inventories of emissions and estimates derived from direct atmospheric measurement. Effective emission reduction can only be achieved if sources are properly quantified, and mitigation efforts are verified.

CH4 from waste is dominantly of biogenic origin and its levels can vary with temperature and production process, which results in variation of emissions with time of day and time of year. Selected waste streams are now commonly sent to biogas plants, where the waste is digested to produce methane, which may be utilised directly, or combusted to provide power. Different waste streams, such as maize stubble or paper products, are characterized by distinct δ13C-CH4 signatures.  Emissions from each stage of the biogas production process can be identified by analysing the methane isotopic composition.

This study focuses on identification and quantification of CH4 emissions from waste sources in the UK from 2018-2020 using laser-based mobile surveys downwind of landfills, biogas plants and wastewater treatment plants. Air samples were collected and analysed for isotopic characterization using high precision Gas Chromatography Isotopic Ratio Mass Spectrometry. Survey data were used to map concentration excess over background, identify isotopic composition and estimate fugitive emissions from selected sources.

Average carbon isotopic signatures for new data on methane sources in the UK are -53 ‰ for wastewater treatment plants and -55 ‰ for biogas plants. CH4 emissions range from 6.2 to 50 g/h depending on size and operating conditions of plants. Also, isotopic signature of methane emission from active sites in the landfill are in the range -60 to -58 ‰ with 2 - 10% oxidation rate, which is characteristically more depleted than closed sites.

 

How to cite: Bakkaloglu, S., Lowry, D., Fisher, R., France, J., Lanoiselle, M., and Fernandez, J.: Characterization and Quantification of Methane Emissions from Waste in the UK, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17839, https://doi.org/10.5194/egusphere-egu2020-17839, 2020.

EGU2020-13389 | Displays | AS3.14

Quantification of methane emissions from waste water treatment plants

Marcel Bühler, Christoph Häni, Thomas Kupper, Christof Ammann, and Stefan Brönnimann

Quantification of gaseous emissions from waste water treatment plants (WWTPs) is challenging due to the heterogeneity of the emissions in space and time. The inverse dispersion method (IDM) using concentration and turbulence measurements in combination with a backward Lagrangian stochastic (bLS) dispersion model based on Flesch et al. (2004) is a promising option. It is  increasingly used to determine gaseous emissions from confined sources (Flesch et al., 2009; VanderZaag et al., 2014), as it offers high flexibility at reasonable costs. For the application on WWTPs the bLS model assumption of spatially homogeneous turbulence, which implies absence of obstacles as buildings and trees that disturbe the flow, is often not fulfilled. However, studies showed that with the correct instrument setup and data filtering the bLS can be used for emission estimates. Methane emissions from two WWTPs of different type and size were quantified using the IDM with the bLS model. Methane concentrations were analysed with open-path tunable diode laser spectrometers (GasFinder, Boreal Laser, Inc., Edmonton, Alberta, Canada) placed up- and downwind of the source. At each site at least 20 days of measurements averaged to 30-minutes intervals are available. Here we present first results from these two WWTPs emission estimates.

 

References

Flesch, T. K., Wilson, J. D., Harper, L. A., Crenna, B. P., and Sharpe, R. R.: Deducing ground-to-air emissions from observed trace gas concentrations:
A field trial, J. Appl. Meteorol., 43, 487–502, doi:10.1175/1520-0450(2004)043<0487:DGEFOT>2.0.CO;2, 2004.

Flesch, T. K., Harper, L. A., Powell, J. M., and Wilson, J. D.: Inverse-dispersion calculation of ammonia emissions from Wisconsin dairy farms, Trans. ASABE, 52, 253–265, doi:10.13031/2013.25946, 2009.

VanderZaag, A. C., Flesch, T. K., Desjardins, R. L., Baldé, H., and Wright, T.: Measuring methane emissions from two dairy farms: Seasonal and manure-management effects, Agricultural and Forest Meteorology, 194, 259–267, doi:10.1016/j.agrformet.2014.02.003, 2014.

How to cite: Bühler, M., Häni, C., Kupper, T., Ammann, C., and Brönnimann, S.: Quantification of methane emissions from waste water treatment plants, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13389, https://doi.org/10.5194/egusphere-egu2020-13389, 2020.

EGU2020-20405 | Displays | AS3.14

Assessment of methane emissions from Danish livestock production practices using a tracer gas dispersion method

Nathalia dos Reis Vechi, Antonio Delre, and Charlotte Scheutz

One of the largest methane anthropogenic sources worldwide is livestock production. In Denmark, this contribution reached 81.1% of total anthropogenic methane, divided into both enteric fermentation and manure management emissions (Nielsen et al., 2019). Numerous factors can influence methane emissions from livestock production. The development of strategies to measure and monitor this anthropogenic activity allows the identification of efficient mitigation actions. The dynamic tracer gas dispersion method (TDM) is a ground-based remote sensing method, which combines a controlled release of tracer gas from the target source with concentration measurements downwind of the same source. TDM has been compared to other remote sensing techniques and widely applied for methane quantification from many facilities (Samuelsson et al., 2018). Previous studies found that this method is very likely to reached up to only 20% of error (Fredenslund et al., 2019). For livestock methane quantification, TDM has been used before releasing a strong greenhouse gas (SF6) with mostly stationary point sampling setup. The aim is to verify the suitability of the method for these facilities and identify the differences between farming approaches. Furthermore, the comparison of the measured emissions with inventory estimation could show the accuracy of the later.

This study uses acetylene as tracer gas and measurements performed with a fast responding and highly sensitive gas analyzer by Picarro. On this project, emissions from six livestock facilities (dairy cows and swine production) were investigated along one year.

Dairy farms were the largest methane emitters per head (Around 40 gCH4/head/h). Results show that management practices might cause different methane emissions from dairy farms. Similar result was observed analyzing emissions from pig facilities (Around 6 gCH4/head/h), with an influence of animal life stage. The sow’s farm had the highest methane emission factor when compared to fattening pigs, while manure acidification treatment might have a positive impact on reducing methane emission.

The successful application in this study of the TDM showed that this method is a valuable tool to support Danish farming strategies to meet ambitious GHG emission reduction targets.

 

 

Fredenslund, A. M., Rees-White, T. C., Beaven, R. P., Delre, A., Finlayson, A., Helmore, J., … Scheutz, C. (2019). Validation and error assessment of the mobile tracer gas dispersion method for measurement of fugitive emissions from area sources. Waste Management, 83, 68–78.

Nielsen, O.-K., Plejdrup, M. S., Winther, M., Nielsen, M., Gyldenkærne, S., Mikkelsen, M. H., … Hansen, M. G. (2019). Denmark’s National Inventory Report 2019 (Emission I).

Samuelsson, J., Delre, A., Tumlin, S., Hadi, S., Offerle, B., & Scheutz, C. (2018). Optical technologies applied alongside on-site and remote approaches for climate gas emission quantification at a wastewater treatment plant. Water Research, 131, 299–309.

How to cite: dos Reis Vechi, N., Delre, A., and Scheutz, C.: Assessment of methane emissions from Danish livestock production practices using a tracer gas dispersion method, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20405, https://doi.org/10.5194/egusphere-egu2020-20405, 2020.

EGU2020-20442 | Displays | AS3.14

Methane emission from dairy farm located in north of Heidelberg

Piotr Korben, Johannes Kammerer, Julia Wietzel, and Martina Schmidt

The three major anthropogenic CH4 (methane) sources in Germany are ruminants (53%), waste and waste water treatment (22%) and transport and storage of natural gas (25%). In order to quantify these emissions on a facility scale, we used a CH4 analyser installed in vehicle. Mobile measurements are performed on regular campaigns including measurements of the concentration and isotopic composition of methane. During this study we visited  11 times a Dairy Farm in Weinheim, north of Heidelberg. The farm has a livestock of about 320 - 340 dairy cows with an average milk production of 29 l per cow and day. A biogas plant is located next to the cowshed. To determine the temporal and spatial variability of emissions, collected data are analysed with Gaussian plume model to obtain emissions from dairy cows and biogas plant. For each mobile measurements campaign, we analysed 10 -40  transects (driving the car forward and backward). The first estimations of the emissions  (cows and biogas included) shows strong variabilities and up to 8 times higher values, than expected when comparing to IPCC reported emission values for dairy cows . As our measurements represent the whole farm emission, including  biogas plant and liquid manure, we have to distinguish these sources and quantify the contribution of each. .

How to cite: Korben, P., Kammerer, J., Wietzel, J., and Schmidt, M.: Methane emission from dairy farm located in north of Heidelberg, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20442, https://doi.org/10.5194/egusphere-egu2020-20442, 2020.

AS3.15 – Remote Sensing of Atmospheric Carbon Dioxide and Methane

Anthropogenic CO2 and NO2 emissions from combustion processes usually have the same sources but different emission ratios. Because of their similar sources, combustion emissions of CO2 and NO2 are correlated in space and time. Or in other words: combustion emissions of NO2 will generally be accompanied by CO2 emissions, and vice versa.

This concept can be used for converting satellite-based emissions of NO2 into CO2 emissions by multiplying known emission ratios of CO2 over NO2 from established emission databases with satellite-derived NO2 emissions.

As part of the H2020 CHE project (“CO2 Human Emissions”) we have applied this method to TROPOMI/S5P NO2 emission data and “bottom-up” emission databases from Dutch TNO. TROPOMI/S5P emissions using the inversion algorithm DECSO were derived for the Iberian Peninsula in Europe and an area over South America.

We find that, after accounting for naturally occurring soil NOx emissions, the spatial distribution of DECSO-TROPOMI based CO2 emissions over the Iberian Peninsula and the South America region overall are very realistic, and within uncertainties CO2 emissions budgets from both methods are not dissimilar.

We will also present and discuss some additional aspects and uncertainties of this ratio-method, including the influence of uncertainties in the TNO bottom-up emission database, like inter-country differences, and the relevance of applying emission ratios representative for the same time period as the TROPOMI/S5P measurements. We will also provide some recommendations for further improving this method.

Overall, at minimum this method appears to provide a “sanity check” for bottom-up (reported) CO2 emissions, but potentially more than that, also evidenced by several new satellite mission proposals to combine direct measurements of CO2 with direct measurements of NO2 from the same satellite platform.

How to cite: de Laat, J. and van der A, R.: Deriving anthropogenic CO2 emissions for combustion by application of the emission-ratio method to TROPOMI/S5P NO2 emission data., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5535, https://doi.org/10.5194/egusphere-egu2020-5535, 2020.

EGU2020-5966 | Displays | AS3.15

Interannual variability in North American ecosystems

Brendan Byrne, Junjie Liu, A. Anthony Bloom, Kevin Bowman, Zachary Butterfield, Joanna Joiner, Gretchen Keppel-Aleks, Nicholas Parazoo, and Yi Yin

Semi-arid ecosystems have been recognized as an important driver of interannual variability (IAV) in the growth rate of atmospheric CO2. However, the importance of these ecosystems for IAV in gross primary productivity (GPP) and net ecosystem exchange (NEE) over North America is not well characterized. In this study, we examine IAV over temperate North America using NEE constrained by surface-based and space-based atmospheric CO2 measurements over 2010–2015 and upscaled GPP from FluxSat over 2001–2017. We show that the arid west of North America provides a larger contribution to IAV in GPP and NEE than the more productive eastern half of North America. This occurs because flux anomalies in western North America are temporally coherent across the growing season leading to an amplification of GPP and NEE for wet years. In contrast, IAV in eastern North America shows seasonal compensation effects, wherein positive anomalies during April–June are compensated for by negative anomalies during July–September.

How to cite: Byrne, B., Liu, J., Bloom, A. A., Bowman, K., Butterfield, Z., Joiner, J., Keppel-Aleks, G., Parazoo, N., and Yin, Y.: Interannual variability in North American ecosystems, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5966, https://doi.org/10.5194/egusphere-egu2020-5966, 2020.

EGU2020-6225 | Displays | AS3.15

An Overview of the First Year of the OCO-3 Mission

Annmarie Eldering, Christopher O’Dell, Peter Somkuti, Thomas Taylor, Matthäus Kiel, Robert Nelson, Gary Spiers, Brendan Fisher, Ryan Pavlick, Thomas Kurosu, Gregory Osterman, Joshua Laughner, Robert Rosenberg, Graziela Keller-Rodrigues, Shanshan Yu, Yuliya Marchetti, David Crisp, and Paul Wennberg

The Orbiting Carbon Observatory 3 (OCO-3) was installed on the International Space Station (ISS) in May 2019 and will continue the observation of global CO2 and solar-induced chlorophyll fluorescence (SIF) observations using the flight spare instrument from OCO-2. This talk will focus on the science data products, early operations, abd a few highlights from early mission data.

The low-inclination ISS orbit lets OCO-3 sample the tropics and sub-tropics across the full range of daylight hours with dense observations at northern and southern mid-latitudes (+/- 52º). The combination of these dense CO2 and SIF measurements provides continuity of data for global flux estimates as well as a unique opportunity to address key deficiencies in our understanding of the global carbon cycle. The instrument utilizes an agile, 2-axis pointing mechanism (PMA), providing the capability to look towards the bright reflection from the ocean and validation targets. The PMA also allows for the collection of dense datasets over 80km by 80km areas called snapshot area maps (SAMs).

The in-orbit check out of the instrument was conducted through July 2019. In this phase the engineering team verified the performance of all systems, the calibration team began collecting the needed calibration data, and the mission operations team verified the performance of all measurement modes and the mission operations planning tools. Since August 2019, OCO-3 has been collecting routine nadir, glint, target, and SAM data.

Target mode observations over surface-based Total Carbon Column Observing Network (TCCON) sites help to identify and minimize potential instrument biases in the OCO-3 data. Other validation activities include direct comparisons to XCO2 estimates from OCO-2 and comparisons to predictions from near-real-time models. These comparisons will be discussed and early results will be presented. In addition, several hundred SAMs have been collected over (mega-)cities, powerplants, volcanos, and other terrestrial carbon focus areas.  The steadily growing number of SAM observations provides a unique dataset for scientific studies on local scales. We discuss the potential of these observations, alone and in conjunction with simultaneous observations from other space-based sensors, to yield greater insights into carbon cycle science.

How to cite: Eldering, A., O’Dell, C., Somkuti, P., Taylor, T., Kiel, M., Nelson, R., Spiers, G., Fisher, B., Pavlick, R., Kurosu, T., Osterman, G., Laughner, J., Rosenberg, R., Keller-Rodrigues, G., Yu, S., Marchetti, Y., Crisp, D., and Wennberg, P.: An Overview of the First Year of the OCO-3 Mission, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6225, https://doi.org/10.5194/egusphere-egu2020-6225, 2020.

EGU2020-6477 | Displays | AS3.15

Long-term column-averaged greenhouse gas observations using a COCCON spectrometer at a high surface albedo site in Namibia

Matthias Frey, Thomas Blumenstock, Darko Dubravica, Frank Hase, Frank Goettsche, Jochen Gross, Folke Olesen, Petrus Amadhila, Martin Handjaba, Gillian Maggs-Koelling, Eugene Marais, Roland Mushi, Isamu Morino, Kei Shiomi, Martine de Maziere, and Mahesh Kumar Sha

Precise and accurate observations of anthropogenic greenhouse gases (GHGs), especially carbon dioxide (CO2) and methane (CH4), are of utmost importance for the estimation of their emission strengths, flux changes and long-term monitoring. Furthermore, these measurements can be directly used for the verification of climate mitigation actions as demanded by the Paris COP21 agreement. Satellite observations are well suited for this task as they provide global coverage. However, like all measurements these need to be validated, particularly to avoid potential biases. The Total Carbon Column Observing Network (TCCON) performs ground-based observations of GHGs with reference precision using high-resolution Fourier Transform infrared (FTIR) spectrometers. TCCON data are of high accuracy as TCCON uses species dependent scaling factors derived from in-situ reference measurements to be calibrated to the World Meteorological Organization (WMO) reference scale. For several satellites measuring GHGs TCCON data are the main validation source.

Recently, in an effort to further improve the global coverage of ground-based FTIR spectrometers and complement TCCON in remote areas, the COllaborative Carbon Column Observing Network (COCCON) was established. This network utilizes the EM27/SUN FTIR spectrometer, a compact solar-viewing low-resolution instrument. Even though a COCCON spectrometer has recently been used in combination with two TCCON instruments to validate the Orbiting Carbon Observatory-2 (OCO-2) satellite, until now the main focus of COCCON was on the quality control of EM27/SUN spectrometers and dedicated campaigns to estimate emission strengths of CO2 and CH4 from local and regional sources, e.g. from cities, fracking areas, volcanoes or mining sites.

Here we present long-term observations with a spectrometer from the COCCON network. In 2015 the instrument was installed at the Gobabeb Namib Research Center in Namibia. Gobabeb is located at the center of the hyperarid Namib desert. Moreover, Gobabeb is situated next to the Kuiseb river, which marks the sharp transition zone between the gravel plains to the north and the sand desert to the south of the station. This high albedo site is especially interesting for satellite validation, as ground-based FTIR data with these characteristics are sparse. Furthermore, it is the first ground-based FTIR instrument measuring CO2 and CH4 on the African mainland.

We show long-term COCCON observations from Gobabeb and compare them to results obtained from the TCCON instrument at Reunion Island. Finally, we present a comparison with target mode observations from the Greenhouse Gases Observation Satellite GOSAT.

How to cite: Frey, M., Blumenstock, T., Dubravica, D., Hase, F., Goettsche, F., Gross, J., Olesen, F., Amadhila, P., Handjaba, M., Maggs-Koelling, G., Marais, E., Mushi, R., Morino, I., Shiomi, K., de Maziere, M., and Sha, M. K.: Long-term column-averaged greenhouse gas observations using a COCCON spectrometer at a high surface albedo site in Namibia, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6477, https://doi.org/10.5194/egusphere-egu2020-6477, 2020.

EGU2020-7345 | Displays | AS3.15

Mobile ground-based remote sensing of atmospheric CO2, CH4, and CO column densities above the Pacific Ocean

Marvin Knapp, Ralph Kleinschek, Benedikt Hemmer, Ralph Pfeifer, Frank Hase, Anna Agustí-Panareda, Antje Inness, Jerome Barre, Stefan Kinne, and André Butz

Validation opportunities for model data and satellite observations in the short-wave infra-red spectral range are still sparse above the oceans. To provide such opportunities, we qualify a Fourier-transform spectrometer (FTS) for the regular use on ships. We use the EM27/SUN FTS [1] in direct-sunlight measurement geometry to retrieve total column densities of carbon dioxide (CO2), methane (CH4), and carbon monoxide (CO) [2] with solar absorption spectroscopy.
Performing direct-sunlight measurements from a moving platform poses significant challenges to the solar tracking. We use a solar tracker that compensates the vessel's movements in real time, keeping the pointing of the instrument relative to the center of the sun better than 0.05° for more than 99 % of the time [3]. The solar tracker is part of a newly developed enclosure that allows automated measurements and withstands environmental factors such as rain, humidity, and sea spray.
The instrument was deployed on board the German research vessel RV Sonne during the MORE-2 (Measuring Oceanic REferences 2) campaign on a longitudinal transect from Vancouver (Canada) to Singapore in June 2019. During the campaign we recorded 33800 direct sunlight spectra from which column-averaged dry-air mole fractions of CO2, CH4, and CO are retrieved. Our results are calibrated against World Meteorological Organization standards and the columns achieve a relative precision of 0.06 %, 0.06 %, and 1.02 % for CO2, CH4, and CO, respectively.
We compare our records to coincident observations of the Greenhouse gases Observing SATellite (GOSAT), the Orbiting Carbon Observatory-2 (OCO-2), and the TROPOspheric Monitoring Instrument (TROPOMI). Our CO2 records show a mean offset of -3.2 ± 1.1 ppm to OCO-2 and -1.4 ± 1.7 ppm to GOSAT observations. Furthermore, we find a mean CH4 offset of 17 ± 6 ppb to GOSAT and a mean CO offset of 3.5 ± 2.6 ppb to TROPOMI. The Copernicus Atmosphere Monitoring Service (CAMS) provided us with model data of CH4 and CO. We could show that the CO data agree well with our measurements, showing an offset of 3.5 ± 3.6 ppb.


[1] Gisi, M. et al.: XCO2-measurements with a tabletop FTS using solar absorption spectroscopy, Atmos. Meas. Tech., 5, 2969-2980, 2012
[2] Hase, F. et al.: Addition of a channel for XCO observations to a portable FTIR spectrometer for greenhouse gas measurements, Atmos. Meas. Tech., 9, 2303-2313, 2016
[3] Klappenbach, F. et al.: Accurate mobile remote sensing of XCO2 and XCH4 latitudinal transects from aboard a research vessel, Atmos. Meas. Tech., 8, 5023–5038, 2015

How to cite: Knapp, M., Kleinschek, R., Hemmer, B., Pfeifer, R., Hase, F., Agustí-Panareda, A., Inness, A., Barre, J., Kinne, S., and Butz, A.: Mobile ground-based remote sensing of atmospheric CO2, CH4, and CO column densities above the Pacific Ocean, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7345, https://doi.org/10.5194/egusphere-egu2020-7345, 2020.

EGU2020-11404 | Displays | AS3.15

Daily Satellite Observations of Methane from Oil and Gas Production Regions in the United States

Pieternel Levelt, Pepijn Veefkind, Esther Roosenbrand, John Lin, Jochen Landgraf, Barbara Dix, and Joost de Gouw

Production of oil and natural gas in North America is at an all-time high due to the development and use of horizontal drilling and hydraulic fracturing. Methane emissions associated with this industrial activity are a concern because of the contribution to climate radiative forcing. We present new measurements from the space-based TROPOspheric Monitoring Instrument (TROPOMI) launched in 2017 that show methane enhancements over production regions in the United States. Using methane and NO2 column measurements from the new TROPOMI instrument, we show that emissions from oil and gas production in the Uintah and Permian Basins can be observed in the data from individual overpasses. This is a vast improvement over measurements from previous satellite instruments, which typically needed to be averaged over a year or more to quantify trends and regional enhancements in methane emissions. In the Uintah Basin in Utah, TROPOMI methane columns correlated with in-situ measurements, and the highest columns were observed over the deepest parts of the basin, consistent with the accumulation of emissions underneath inversions. In the Permian Basin in Texas and New Mexico, methane columns showed maxima over regions with the highest natural gas production and were correlated with nitrogen-dioxide columns at a ratio that is consistent with results from in-situ airborne measurements. The improved detail provided by TROPOMI will likely enable the timely monitoring from space of methane and NO2 emissions associated with regular oil and natural gas production.

How to cite: Levelt, P., Veefkind, P., Roosenbrand, E., Lin, J., Landgraf, J., Dix, B., and de Gouw, J.: Daily Satellite Observations of Methane from Oil and Gas Production Regions in the United States, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11404, https://doi.org/10.5194/egusphere-egu2020-11404, 2020.

EGU2020-11747 | Displays | AS3.15

Observations of Methane Emissions from California Dairies from Ground and Space: New Top-Down Constraints at Regional Scales

Manvendra K. Dubey, Sajjan Heerah, Isis Frausto-Vicencio, Seongeun Jeong, Marc Fischer, and Francesca Hopkins

California has made reducing methane (CH4) from its dairy industry, which accounts for nearly 50% of its inventoried CHemissions, a key part of its climate change mitigation plan. However, in situ atmospheric measurement-based estimates suggest that the state-wide dairy source may be underestimated by up to a factor of 2.  Furthermore, emissions at the local scales important to mitigation policy (10’s km) are very uncertain. Ground based measurements of atmospheric column averaged methane concentrations (XCH4) can provide useful constraints on local to regional methane fluxes. Additionally, the high spatial and temporal resolution XCHobservations by the space-based TROPOMI and GOSAT instruments provide an excellent opportunity to measure CH4 fluxes at these scales. We report field measurements of XCH4 gradients across the dairy intensive region (500 dairies, 330 Gg/yr CH4 emissions inventory) in the San Joaquin Valley (SJV) using two EM27/SUN solar spectrometers. With our EM27’s we observed several days of sustained downwind-upwind XCH4 enhancements of over 40 ppb, placing these signals well above TROPOMI and GOSAT’s precision level and among the highest reported XCHenhancements. We compare TROPOMI and GOSAT spatial XCHenhancements to our EM27 data to validate it in an area of high signal and to demonstrate its utility for observing localized sources. We also use GOSAT and TROPOMI’s data to characterize the wider SJV’s CH4 sources and to fill in temporal gaps between our field campaigns. Finally, we perform inverse optimizations using WRF-STILT simulations demonstrating that top-down observationally constrained dairy emissions are a factor of 2 larger than reported inventories.  This work illustrates how ground and space-based measurements can complement each other to improve our understanding of CH4 sources at scales relevant to mitigation policy.

How to cite: Dubey, M. K., Heerah, S., Frausto-Vicencio, I., Jeong, S., Fischer, M., and Hopkins, F.: Observations of Methane Emissions from California Dairies from Ground and Space: New Top-Down Constraints at Regional Scales, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11747, https://doi.org/10.5194/egusphere-egu2020-11747, 2020.

EGU2020-12559 | Displays | AS3.15

Satellite-derived Indian methane emission sources with TROPOMI retrievals and a high-resolution modelling framework: Initial comparison with WRF-GHG model results

Dhanyalekshmi Pillai, Monish Deshpande, Julia Marshall, Christoph Gerbig, Oliver Schneising, and Michael Buchwitz

In accordance with the Global stocktake under Article 14 of Paris Agreement, each county estimates its own greenhouse gas (GHG) emissions based on standardised bottom-up management methods. However, the accuracy of these methods along with the standards differs from country to country, resulting in large uncertainties that make it difficult to implement effective climate change mitigation strategies. India plays an important role in global methane emission scenario, necessitating the accurate quantification of its sources at the regional and the local levels. However, the country lacks sufficient long term, continuous and accurate observations of the atmospheric methane which are required to quantify its source, to understand changes in the carbon cycle and the climate system. Recent technological advancements in the use of satellite remote-sensing dedicated to the greenhouse gases enforce international standards for the observation methods; hence enabling those high-resolution-high-density observations to be utilised for this quantification purpose. This study focuses on exploring the use of such dedicated observations of the column-averaged dry-air mixing ratio of methane (XCH4) retrieved from TROPOMI onboard Sentinel-5 Precursor to quantify the major CH4 anthropogenic and natural emission fluxes over India.

Our inverse modelling approach at the mesoscale includes a high-resolution atmospheric modelling framework consisting of the Weather Research and Forecasting model with greenhouse gas module (WRF-GHG) and a set of prior emission inventory model data. We use TROPOMI retrievals derived using the Weighting Function Modified Differential Optical Absorption Spectroscopy (WFM-DOAS) retrieval algorithm. WRF-GHG simulations are performed in hourly time intervals at a horizontal resolution of 10 km ×10 km for a month. In order to compare our CH4 simulations with the satellite column data, we have also taken into account the different vertical sensitivities of the instrument by applying the averaging kernel to the model simulations. To demonstrate the model performance, our simulations are also compared with the CAMS reanalysis product based on ECMWF (European Centre for Medium-Range Weather Forecasts) numerical weather prediction reanalysis data available at a horizontal resolution of 0.25o × 0.25o. Our comparison of these modelling results against unique satellite dataset indicates high potential of using TROPOMI retrievals in distinguishing the major CH4 anthropogenic and natural sources over India via inverse modelling. The results will help to objectively investigate the claims of emission reductions and the efficiency of reduction countermeasures, as well as the establishment of standards and advancement of technology. The details about our approach and preliminary results based on our analysis using above satellite measurements and WRF-GHG simulations over India will be presented.  

 

How to cite: Pillai, D., Deshpande, M., Marshall, J., Gerbig, C., Schneising, O., and Buchwitz, M.: Satellite-derived Indian methane emission sources with TROPOMI retrievals and a high-resolution modelling framework: Initial comparison with WRF-GHG model results, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12559, https://doi.org/10.5194/egusphere-egu2020-12559, 2020.

EGU2020-17662 | Displays | AS3.15

The distribution and trends in Chinese methane emissions, 2010-2017

Sihong Zhu, Liang Feng, Paul Palmer, and Yi Liu

We use satellite observations of methane (CH4) from the Japanese Greenhouse gases Observing SATellite (GOSAT) to study the temporal and spatial changes in Chinese CH4 emissions from 2010 to 2017. We use v12.5.0 of the GEOS-Chem model of atmospheric chemistry and transport, driven by prior emission inventories, to describe observed variations of atmospheric CH4. To infer fluxes from North, central, South, East, northeast, northwest and southwest China we use an established ensemble Kalman filter method in conjunction with the GEOS-Chem model. We find that annual nationwide CH4 emissions decreased from 53 Tg in 2010 to 49 Tg in 2012, but then increased to 54 Tg in 2017. Emissions from eastern China represent the largest regional contribution to the nationwide total, accounting for 22%, while southern and northeast China each represent the smallest regional contributions of 7%. We find that emission trends of various regions are very different. Generally, regional CH4 emissions are smallest during January and peak in July. We report a downward trend during Spring over southwest and southern regions but find no significant trend in northern and northwest China.  By analyzing the seasonal maximum and minimum values over each region, we find that annual mean trends are driven by changes in seasonal peak values, with no obvious trend in the seasonal minimum. We will discuss how changes in coal mine emissions may have impacted nationwide trends after 2013.

How to cite: Zhu, S., Feng, L., Palmer, P., and Liu, Y.: The distribution and trends in Chinese methane emissions, 2010-2017, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17662, https://doi.org/10.5194/egusphere-egu2020-17662, 2020.

EGU2020-20213 | Displays | AS3.15

The GeoCarb Mission

Sean Crowell and Berrien Moore

The community has been measuring greenhouse gases from space for two decades, starting with SCIAMACHY and proceeding through GOSAT, OCO-2, TROPOMI, GOSAT-2, OCO-3, with many more to come in the future. The GeoCarb mission was selected in 2016 under the Earth Venture Mission program by NASA.  GeoCarb will measure CO2, CH4, and CO from geostationary orbit aboard a commercial communications satellite as a hosted payload starting in 2023.  In this presentation, we will discuss mission technical progress and program updates, including the recent passage into Phase C on Jan 1, 2020 and plans moving forward with integration and test and eventual launch.    Additionally, we will discuss plans for how best to proceed in this brave new world of a true constellation of greenhouse gas sensors, including cross-calibration and use of the data for flux determination.

How to cite: Crowell, S. and Moore, B.: The GeoCarb Mission, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20213, https://doi.org/10.5194/egusphere-egu2020-20213, 2020.

EGU2020-19044 | Displays | AS3.15

Towards space-borne monitoring of localized CO2 emissions: an instrument concept and first performance assessment

Johan Strandgren, Jonas Wilzewski, David Krutz, Carsten Paproth, Ilse Sebastian, Kevin Gurney, Jianming Liang, Anke Roiger, and André Butz

Independent verification of reported carbon dioxide (CO2) emissions is a corner stone for advancing towards emission accounting and reduction measures agreed upon in the Paris agreement. Here, we present the concept and first performance assessment of a compact space-borne imaging spectrometer that could support the task of "monitoring, verification, reporting'' (MVR) of CO2 emissions worldwide. With a ground resolution of 50m x 50m, the goal is to estimate the CO2 emissions from localized sources down to a source strength of approx. 1 MtCO2/yr, hence complementing other planned CO2 monitoring missions, like the European Carbon Constellation (CO2M).

Such fine ground resolution requires a trade-off towards coarse spectral resolution in order to achieve sufficient noise performance. Since fine ground resolution also implies limited ground coverage, a fleet of satellites, each carrying such an instrument is envisioned, requiring a relatively low-cost and simple design, e.g. by restricting the spectrometer to a single spectral window. To demonstrate that column-averaged dry-air mole-fractions of CO2 (XCO2) can be reliably retrieved with a single spectral window and at the required coarse spectral resolution, we use degraded GOSAT short-wave infrared spectra of the CO2 bands near 1.6 and 2.0 µm, respectively.

Through radiative transfer simulations, including a realistic instrument noise model and a global trial ensemble covering various geophysical scenarios, it is further shown that an instrument noise error of 1.1 ppm (1sigma) can be achieved for the XCO2 retrieval. Despite the limited amount of information from a single spectral window and a relatively coarse spectral resolution, scattering by atmospheric aerosol and cirrus can be partly accounted for, with deviations of at most 4.0 ppm from the true abundance for 68 % of the scenes in the global trial ensemble.

Finally we simulate the ability of the proposed instrument concept to observe CO2 plumes from single power plants in an urban environment using high-resolution CO2 emission and surface albedo data for the city of Indianapolis. Given the preliminary instrument design and the corresponding instrument noise error, emission plumes from point sources with an emission rate down to the order of 0.3 MtCO2/yr can be resolved, i.e. well below the target source strength of 1 MtCO2/yr. Hence, some margin for additional error sources like scattering particles and complex meteorology exists.

How to cite: Strandgren, J., Wilzewski, J., Krutz, D., Paproth, C., Sebastian, I., Gurney, K., Liang, J., Roiger, A., and Butz, A.: Towards space-borne monitoring of localized CO2 emissions: an instrument concept and first performance assessment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19044, https://doi.org/10.5194/egusphere-egu2020-19044, 2020.

EGU2020-20532 | Displays | AS3.15

Anthropogenic CO2 monitoring satellite mission: the need for multi-angle polarimetric observations

Stephanie P. Rusli, Otto Hasekamp, Joost aan de Brugh, Guangliang Fu, Yasjka Meijer, and Jochen Landgraf

Scattering due to aerosols and cirrus has long been identified as one of main sources of uncertainties in retrieving XCO2 from solar backscattered radiation. In this work, we investigate the added value of multi-angle polarimeter (MAP) measurements in the context of Copernicus candidate mission for anthropogenic CO2 monitoring (CO2M). To this end, we compare aerosol-induced XCO2 errors from standard retrievals using spectrometer only (without MAP) with those from retrievals using both MAP and spectrometer. MAP measures radiance and degree of linear polarization (DLP) simultaneously at multiple wavelengths and at multiple viewing angles; these observations are expected to provide information about aerosols that is useful for improving XCO2 accuracy. Using an ensemble of 500 synthetic scenes over land, we show that the standard XCO2 retrieval approach that makes no use of MAP observations returns XCO2 errors with an overall bias of 1.04 ppm, and a spread (equivalent to standard deviation for a normal distribution) of 2.07 ppm. The latter is far higher than the required XCO2 accuracy (0.5 ppm) and precision (0.7 ppm) of the CO2M mission. Moreover, these XCO2 errors exhibit a significantly larger bias and scatter at high aerosol optical depth, high aerosol altitude, and low solar zenith angle, which suggest a worse performance in retrieving XCO2 from polluted areas where CO2 and aerosols are co-emitted. Given the CO2M mission requirements, we proceed to derive MAP instrument specifications in terms of measurement uncertainties, number of viewing angles, and the wavelength range. Two different MAP instrument concepts are considered in this requirement analysis. We find that for either concept, MAP measurement uncertainties on radiance and degree of linear polarization should be no more than 3% and 0.003, respectively. Adopting the derived MAP requirements, a retrieval exercise on the 500 synthetic scenes using both MAP and spectrometer measurements delivers XCO2 errors with an overall bias of -0.09 ppm and a spread of 0.57 ppm, indicating compliance with the CO2M mission requirements. For the test ensemble, we find effectively no dependence of the XCO2 errors on aerosol optical depth, altitude of the aerosol layer, and solar zenith angle. These results represent a significant improvement in the retrieved XCO2 accuracy compared to the standard retrieval approach, which may lead to a higher data yield, better global coverage, and a more comprehensive determination of CO2 sinks and sources. As such, this outcome underscores the contribution of, and therefore the need for, a MAP instrument onboard the CO2M mission.

How to cite: Rusli, S. P., Hasekamp, O., aan de Brugh, J., Fu, G., Meijer, Y., and Landgraf, J.: Anthropogenic CO2 monitoring satellite mission: the need for multi-angle polarimetric observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20532, https://doi.org/10.5194/egusphere-egu2020-20532, 2020.

EGU2020-10787 | Displays | AS3.15

Impact of model resolution and transport uncertainties on the representation of CO2 emission plumes by global and regional atmospheric transport models

Dominik Brunner, Jean-Matthieu Haussaire, Julia Marshall, Arjo Segers, Hugo Denier van der Gon, Joe McNorton, and Anna Agusti-Panareda

Emissions of carbon dioxide (CO2) will have to be drastically reduced in the coming decades to reach the goal of the Paris Agreement to limit the global temperature increase to no more than 2°C. To support this process, Europe is planning to establish a CO2 anthropogenic emission monitoring system, which will assist countries, cities and facility operators in monitoring their emissions and evaluating the progress towards their reduction targets. The system will combine measurements from ground-based networks with observations from a new constellation of CO2 satellites, which will provide high-resolution images of total column CO2 allowing tracking the plumes of large emission sources. A suite of atmospheric transport modelling systems will assimilate these observations and inversely estimate emissions from the continental to the country scale and down to the scale of individual cities and power plants.

In the European project "CO2 Human Emissions" (CHE), the components of such a modelling framework are explored, which includes the generation of a library of realistic atmospheric CO2 simulations. These "nature runs" are obtained by running global and regional atmospheric transport models at the highest possible resolution affordable today and using state-of-the-art inputs of anthropogenic emissions and natural CO2 fluxes. The library includes global simulations at 9 km x 9 km resolution with the CAMS-IFS model, European simulations at 5 km x 5 km resolution with WRF-GHG, COSMO-GHG and LOTOS-EUROS, and high-resolution simulations at 1 km x 1 km over the city of Berlin and several power plants with COSMO-GHG and LOTOS-EUROS.

Here we analyse and compare the model simulations to address the following questions: How realistically are atmospheric gradients in CO2 caused by spatial and temporal variations in biospheric and anthropogenic fluxes and by atmospheric dynamics represented at the different model resolutions? What resolution is required to resolve the plumes of individual cities and power plants? How large are the differences in near surface and total column CO2 due to uncertainties in atmospheric transport including uncertainties in vertical mixing? Information on transport uncertainties is derived from an ensemble of CAMS-IFS simulations and from the spread between the individual models.

Answering these questions is critical for the design of a future operational capacity to monitor anthropogenic CO2 emissions, which should optimally support decision makers at facility, city, and country scale as well as the global stocktake process of the Paris Agreement.

How to cite: Brunner, D., Haussaire, J.-M., Marshall, J., Segers, A., Denier van der Gon, H., McNorton, J., and Agusti-Panareda, A.: Impact of model resolution and transport uncertainties on the representation of CO2 emission plumes by global and regional atmospheric transport models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10787, https://doi.org/10.5194/egusphere-egu2020-10787, 2020.

EGU2020-22158 | Displays | AS3.15

Urban fossil fuel CO2 emissions from space: lessons learned from the OCO missions

Thomas Lauvaux, Sha Feng, Ruixue Lei, Tomohiro Oda, Alexandre Danjou, Gregoire Broquet, Andrew Schuh, Ryan Pavlick, and Annmarie Elderling

Pledges from nations and cities to reduce their carbon footprints have reinforced the needs for accurate and transparent reporting of fossil fuel emissions at various scales, with the ultimate goal of the establishments of carbon stocktake as defined by the Paris Agreement. But the assessment of anthropogenic emissions results primarily in collecting socio-economic indicators and emission factors, hence difficult to evaluate, track, or compare without a more standardized and robust methodology. Atmospheric measurements of greenhouse gases are of particular interests by offering an independent and global source of information thanks to satellite platforms observing continuously the atmospheric content of the major gases responsible for human-induced climate change.

Based on lessons learned from the NASA Orbiting Carbon Observatory (OCO)-2 mission, we present the potential of satellite-based approaches to monitor greenhouse gas emissions from large metropolitan areas across the world (Riyadh, Lahore, Los Angeles). After exploring the technical aspects and challenges of the approach, potential aerosol contamination (CALIPSO), and model requirements, we introduce the upcoming capabilities from the follow-up mission, OCO-3, dedicated in part to urban emissions with the Snapshot Area Mapping mode, the first imagery of atmospheric CO2 concentrations for hundreds of targeted cities and power plants. Early snapshots are examined with high-resolution simulations over a handful of cities. The ongoing development of assimilation systems to inform policy makers about current trends and inter-annual variations is presented and discussed. We finally examine the potential roles and objectives of satellite missions by exploring recent trends in fossil fuel emissions along with proxies of air quality (MODIS) as a unique opportunity to track not only greenhouse gas emissions but more generally the evolution of urban environments.

How to cite: Lauvaux, T., Feng, S., Lei, R., Oda, T., Danjou, A., Broquet, G., Schuh, A., Pavlick, R., and Elderling, A.: Urban fossil fuel CO2 emissions from space: lessons learned from the OCO missions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22158, https://doi.org/10.5194/egusphere-egu2020-22158, 2020.

EGU2020-21289 | Displays | AS3.15

Two diode lasers with different wavelengths resonantly pumped Er:YAG ceramic single-frequency laser

Lei Wang, Yefei Mao, Miaomiao Lin, and Fengrui Zhang

Single-frequency solid-state lasers have important applications in laser remote sensing, such as Doppler lidar, differential absorption lidar (DIAL), gravitational wave detection and so on. In recent ten years, highly stable and narrow spectrum single-frequency Q-switched 1.6 μm lasers are widely applied in coherent Doppler wind detection liar and CH4 DIAL. For applications in space-based wind lidar and DIAL, high output energy of the lasers is essential. In order to obtain a single-frequency laser with high energy, a common method is to inject a stable single-frequency seed laser into a high-energy Q-switched slave laser. Energy upconversion is the main factor which affects the energy enhancement of Er:YAG laser at 1.6μm. We report a Er:YAG ceramic single-frequency pulsed laser at 1645nm dual-end-pumped by two diode lasers with different wavelengths. Compared to a laser pumped by the two same wavelength diode lasers, the laser has higher slope efficiency because the energy upconversion is weakened. Otherwise, ceramic materials have many advantages compared with single crystals, such as ease of fabrication large-size ceramic material, short fabrication time, low cost and good thermo-mechanical properties. Uniform dopant can be realized in ceramic materials, which are much tougher and stronger than single crystals. All the advantages of ceramic materials mentioned above contribute to scalability to high energy laser. In this letter, we report a single frequency pulse ceramic laser with output energy of more than 10 mJ and pulse-width of more than 150 ns at a repetition rate of 500 Hz, which is pumped by two diode lasers with the wavelengths of 1470 nm and 1532 nm, respectively. This single-frequency pulse laser is a potential candidate as a seed laser for a slab laser amplifier system, which is an ideal source for space-based DIAL and Doppler wind lidar.

How to cite: Wang, L., Mao, Y., Lin, M., and Zhang, F.: Two diode lasers with different wavelengths resonantly pumped Er:YAG ceramic single-frequency laser, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21289, https://doi.org/10.5194/egusphere-egu2020-21289, 2020.

In this study, we apply the nonlinear least squares four-dimensional variational (NLS-4DVar) method to the retrieval of the column-averaged dry air mole fraction of carbon dioxide (XCO2 ) from the Orbiting Carbon Observatory-2 (OCO-2) satellite observations. The NLS-4DVar method avoids the computation of the tangent linear and adjoint models of the forward model, which reduces the computational and implementation complexity greatly. We use the forward model from the Atmospheric CO2 Observations from Space (ACOS) XCO2 retrieval algorithm. The inverse model is constructed of two parts, generating samples and minimizing the cost function. For the CO2 profile, we apply an improved sampling algorithm based on ensemble singular value decomposition (SVD). For the other elements in the state vector, we apply a sampling algorithm based on normal distributions, and values of standard deviations of normal distributions are vital to the accuracy of retrieval. To minimize the cost function, the NLS-4Dvar method rewrite it into a nonlinear least squares problem, and solve it by a Gauss-Newton iterative method. We have tested our method in summer and winter at four sites through observing system simulation experiments, which are Lamont, Bremen, Wollongong and an ocean site in the North Pacific respectively. All the four sites show an improved XCO2 and CO2 profile after the retrieval.

How to cite: Jin, Z. and Tian, X.: Carbon dioxide retrieval from OCO-2 satellite observations using the nonlinear least squares four-dimensional variational method: observing system simulation experiments, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4109, https://doi.org/10.5194/egusphere-egu2020-4109, 2020.

EGU2020-17522 | Displays | AS3.15

Toward high precision XCO2 retrievals from TanSat observations

Hartmut Boesch, Dongxu Yang, Yi Liu, and Peter Somkuti

TanSat is the 1st Chinese carbon dioxide measurement satellite, launched in 2016. Preliminary TanSat XCO2 retrievals have been introduced in previous studies based on the 1.6 m weak CO2 band. In this study, the University of Leicester Full Physics (UoL-FP) algorithm is implemented for TanSat nadir mode XCO2 retrievals. We develop a spectrum correction method to reduce the retrieval errors by an online fitting of an 8th order Fourier series. The model and a priori is developed by analyzing the solar calibration measurement. This correction provides a significant improvement to the O2 A band retrieval. Accordingly, we extend the previous TanSat single CO2 weak band retrieval to a combined O2 A and CO2 weak band retrieval. A Genetic Algorithm (GA) has been applied to determine the threshold values of post-screening filters. In total, 18.3% of the retrieved data is identified as high quality compared. The same quality control parameters have been used in the bias correction due to the stronger correlation with the XCO2 retrieval error. A footprint independent multiple linear regression is applied to determine the sounding XCO2 retrieval error and bias correction. Twenty sites of the Total Column Carbon Observing Network (TCCON) have been selected to validate our new approach of the TanSat XCO2 retrieval. We show that our new approach produces a significant improvement of the XCO2 retrieval accuracy and precision when compared with TCCON with an average bias and RMSE of -0.08 and 1.47 ppm respectively. The methods used in this study, such as continuum correction, can help to improve the XCO2 retrieval from TanSat and subsequently the Level-2 data production, and hence will be applied in the TanSat operational XCO2 processing.

How to cite: Boesch, H., Yang, D., Liu, Y., and Somkuti, P.: Toward high precision XCO2 retrievals from TanSat observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17522, https://doi.org/10.5194/egusphere-egu2020-17522, 2020.

EGU2020-4612 | Displays | AS3.15

Carbon dioxide and methane RemoTeC retrievals from GOSAT (2009-2019) and GOSAT-2 (2019)

Markus Haun, Hiroshi Suto, and André Butz

The Japanese Greenhouse gases Observing SATellite (GOSAT), in orbit since January 2009, and its successor GOSAT-2, in orbit since October 2018, are dedicated to enhancing our knowledge of the carbon cycle. We use our RemoTeC full-physics algorithm to infer atmospheric concentrations and auxiliary parameters from the measured solar SWIR radiances backscattered at the earth´s atmosphere and surface. Accuracy requirements are a major challenge for these space-based measurements of column-averaged dry-air mole fractions of carbon dioxide and methane (XCO2 and XCH4).

Here we present 1) a consolidated ten years GOSAT XCO2 and XCH4 dataset and 2) first results for GOSAT-2 XCO2 and XCH4 retrievals. For GOSAT, 4.8 % of all measurements pass our cloud filter, based on the O2 A-band signal and several quality filters. For validation and bias-correction, we use collocated measurements from ground-based stations of the Total Carbon Column Observing Network (TCCON). The dataset shows a scatter of well below 1 %. For GOSAT-2, we are able to reliably process measurements in land nadir and ocean glint geometry. In addition to the retrieval windows implemented for GOSAT, we use the spectral ranges at 4290 - 4328 cm-1 and 4354 - 4441 cm-1 to retrieve carbon monoxide and nitrous oxide concentrations. We evaluate instrument performance and precision by comparing XCO2 and XCH4 retrievals to both collocated GOSAT and ground-based TCCON measurements.

How to cite: Haun, M., Suto, H., and Butz, A.: Carbon dioxide and methane RemoTeC retrievals from GOSAT (2009-2019) and GOSAT-2 (2019), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4612, https://doi.org/10.5194/egusphere-egu2020-4612, 2020.

EGU2020-3576 | Displays | AS3.15

Toward CO2 and CH4 measurements by ground based observations of surface-scattered sunlight: Radiative transfer modeling

Christin Proß, Benedikt Hemmer, Constanze Wellmann, Julian Kostinek, and André Butz

Precise knowledge of sources and sinks in the carbon cycle is desired to understand
its sensitivity to climate change and to account and verify man-made emissions. An
important role herein play extended sources like urban areas. While in-situ measure-
ments of carbon dioxide (CO2) and methane (CH4) are highly accurate but localized,
satellites measure column-integrated concentrations over an extended footprint. Our
innovative measurement technique aims at determining CO2 and CH4 concentrations
near to the ground on the scale of a few kilometers and therefore fills the sensitivity
gap between in-situ and satellite measurements.
Using a modified EM27/SUN Fourier transform spectrometer we are able to record
spectra of surface scattered sunlight in the range of 4000 − 11000 cm−1 . To accurately
retrieve CO2 and CH4 concentrations an advanced retrieval method is required that
includes the simultaneous estimation of atmospheric scattering properties.
Based on our radiative transfer and retrieval software RemoTeC, we built a simulation
environment that includes atmospheric scattering processes. With this tool we can
generate and retrieve synthetic scattered light observations. Here we present our
simulation environment, first results and ongoing developments.

How to cite: Proß, C., Hemmer, B., Wellmann, C., Kostinek, J., and Butz, A.: Toward CO2 and CH4 measurements by ground based observations of surface-scattered sunlight: Radiative transfer modeling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3576, https://doi.org/10.5194/egusphere-egu2020-3576, 2020.

EGU2020-5342 | Displays | AS3.15

A model setup for simulations of ground-based scattered sunlight measurements

Constanze Wellmann, Christin Proß, Katja Bigge, and André Butz

How to cite: Wellmann, C., Proß, C., Bigge, K., and Butz, A.: A model setup for simulations of ground-based scattered sunlight measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5342, https://doi.org/10.5194/egusphere-egu2020-5342, 2020.

EGU2020-7479 | Displays | AS3.15

Toward CO2 and CH4 measurements by ground-based observations of surface-scattered sunlight: Instrumentation and experiments

Benedikt Hemmer, Philip Holzbeck, Ralph Kleinschek, Marvin Knapp, Julian Kostinek, Robin Müller, Christin Proß, Frank Hase, and André Butz
Precise knowledge of sources and sinks in the carbon cycle is desired to understand its sensitivity to climate change, and to account and verify man-made emissions. An important role herein play extended sources like urban areas. While in-situ measurements of carbon dioxide (CO2) and methane (CH4) are highly accurate but localized, satellites measure column-integrated concentrations over an extended footprint. Our innovative measurement technique aims at determining CO2 and CH4 concentrations on the scale of a few kilometers near the ground, and therefore fills the sensitivity gap between in-situ and satellite measurements.
 
Our development starts out from the EM27/SUN Fourier transform spectrometer, which is a reliable, mobile and commercially available spectrometer for the measurement of CO2 and CH4 column densities using direct sunlight spectra. We increased the radiometric sensitivity of the instrument by enhancing optical throughput and replacing the detector module by a thermoelectrically cooled detector. This enables the measurement of surface scattered sunlight spectra in the range of 4000 - 11000 cm-1 under various viewing directions. Our setup is independent of sun position and exhibits a high sensitivity to the concentrations in the lower boundary layer, due to the near ground horizontal path component.
 
Here, we report progress on our instrumental developments, as well as first retrievals of column averaged CO2 and CH4 mole fractions from ground-scattered sunlight spectra recorded with this setup. We present the instrument modifications and extensions to the experimental setup: A Lambertian reflector allows for reference measurements without horizontal path component, a coaligned camera enables specific targeting and the motorized tracking system facilitates automated alternation between multiple targets. We characterize the setup with a spectral resolution of 0.54 ± 0.03 cm-1 a signal to noise ratio above 200 for solar zenith angles < 85°, and precision of 1.8 ppm and 9 ppb regarding the inferred column averaged CO2 and CH4 mole fractions obtained from retrievals with a simple radiative transfer model, neglecting atmospheric scattering.

How to cite: Hemmer, B., Holzbeck, P., Kleinschek, R., Knapp, M., Kostinek, J., Müller, R., Proß, C., Hase, F., and Butz, A.: Toward CO2 and CH4 measurements by ground-based observations of surface-scattered sunlight: Instrumentation and experiments, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7479, https://doi.org/10.5194/egusphere-egu2020-7479, 2020.

EGU2020-7547 | Displays | AS3.15

Towards long open-path FTIR spectrometry of CO2 and CH4 in an urban environment

Tobias Schmitt, Ralph Kleinschek, Dominic Batzler, Stefan Schmitt, Frank Hase, David W. T. Griffith, and André Butz

Quantifying sources and sinks, as well as photochemical activity of trace gases in the lower troposphere, requires accurate measurements of the concentrations of the species of interest. While there exist in-situ measurement techniques, which are highly accurate, point-like measurements tend to suffer from insufficient representativeness, especially true for high-gradient environments, e.g., an urban setting. Hence, measuring those concentrations averaged on the length scales of a few kilometers is desirable. Further, quantifying emissions requires combining the concentration measurements with regional transport models, which cover a comparable spatial resolution.

Here, we present a long open-path setup that aims at delivering concentration averages on these scales in the urban boundary layer. Our setup is based on an IFS 125 HR Fourier transform spectrometer, which is a commercially available, high precision spectrometer for the IR to near UV regime. We use an artificial light source, which is modulated within the interferometer of the instrument. The modulated beam is then sent towards an array of retro-reflectors 1.5 km away. Sending of the initial beam and collecting of the reflected light is accomplished by a single telescope, which is coupled to the instrument via an optical fiber. The collected light is measured using an InGaS detector. In a first feasibility study, we aim at measuring CO2 and CH4 above Heidelberg to quantify the achievable precision and accuracy. Here we present our setup, first measurements, and ongoing developments.

How to cite: Schmitt, T., Kleinschek, R., Batzler, D., Schmitt, S., Hase, F., Griffith, D. W. T., and Butz, A.: Towards long open-path FTIR spectrometry of CO2 and CH4 in an urban environment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7547, https://doi.org/10.5194/egusphere-egu2020-7547, 2020.

EGU2020-9844 | Displays | AS3.15

Early Comparison of OCO-3 XCO2 Measurements with TCCON

Matthaeus Kiel, Joshua Laughner, Annmarie Eldering, Brendan Fisher, Thomas Kurosu, Ryan Pavlick, Gergory Osterman, Robert Nelson, Christopher O'Dell, Peter Somkuti, Thomas Taylor, and Coleen Roehl

The Orbiting Carbon Observatory-3 (OCO-3) was successfully launched on May 4, 2019 from Kennedy Space Center via a Space-X Falcon 9. One week later, the instrument was installed as an external payload on the International Space Station (ISS). OCO-3 extends NASA’s study of carbon and measures the dry-air mole fraction of column carbon dioxide (XCO2) in the Earth’s atmosphere from space.

These space-based measurements are compared to ground-based observations from the Total Carbon Column Observing Network (TCCON). TCCON is a global network of high-resolution ground-based Fourier Transform Spectrometers that records spectra of the sun in the near-infrared spectral region. From these spectra, accurate and precise column-averaged abundances of atmospheric constituents including CO2 are retrieved. TCCON data are tied to the WMO scale and serve as the link between calibrated surface in situ measurements and OCO-3 measurements.

OCO-3’s agile 2-D pointing mirror assembly (PMA) allows the instrument to stare at a TCCON station as it passes overhead - providing information about the quality, biases, and errors in the OCO-3 data. Here, we show early comparisons between the OCO-3 XCO2 dataset collected during target mode observations and coincident TCCON measurements and discuss site-dependent biases and its potential origins.

How to cite: Kiel, M., Laughner, J., Eldering, A., Fisher, B., Kurosu, T., Pavlick, R., Osterman, G., Nelson, R., O'Dell, C., Somkuti, P., Taylor, T., and Roehl, C.: Early Comparison of OCO-3 XCO2 Measurements with TCCON , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9844, https://doi.org/10.5194/egusphere-egu2020-9844, 2020.

EGU2020-12628 | Displays | AS3.15

Travels with an EM27, measurements of CO2 and CH4 below 45 degrees south.

David F. Pollard, Dan Smale, Hue Tran, Jamie McGaw, Frank Hase, and Thomas Blumenstock

During 2016 and again during 2019 through 2020 an EM27/SUN portable near infrared solar absorption Fourier Transform Spectrometer of the Karlsruhe Institute of Technology was transported first to Lauder, New Zealand (45.034S, 169.68E, alt. 370 m) and then to the Arrival Heights laboratory, Ross Island Antarctica (77.82S, 166.65E, 200 m). On the first occasion the EM27/SUN made the first ever near infrared solar absorption retrievals of carbon dioxide and methane in Antarctica over a period of two weeks. The second deployment had the aim of making retrievals in Antarctica throughout the 2019-2020 Austral summer.

We report on the comparison of retrievals of carbon dioxide and methane from the EM27 spectra with those made by the Total Carbon Column Observing Network (TCCON) stations at both Karlsruhe and Lauder and compare with similar comparisons made throughout the Collaborative Carbon Column Observing Network (COCCON), as well as the latitudinal extension of these measurements to Antarctica.

Further comparisons with observations from TROPOMI instrument on the Sentinel 5 precursor satellite will be discussed.

How to cite: Pollard, D. F., Smale, D., Tran, H., McGaw, J., Hase, F., and Blumenstock, T.: Travels with an EM27, measurements of CO2 and CH4 below 45 degrees south., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12628, https://doi.org/10.5194/egusphere-egu2020-12628, 2020.

EGU2020-13106 | Displays | AS3.15

Atmospheric Carbon Dioxide and Methane measurements at Sodankylä, Finland

Rigel Kivi, Huilin Chen, Juha Hatakka, Pauli Heikkinen, Tuomas Laurila, and Hannakaisa Lindqvist

Carbon dioxide and methane column measurement at the Finnish Meteorological Institute’s Sodankylä facility in northern Finland started in early 2009. The measurements have been taken by a Fourier Transform Spectrometer (FTS) in the near-infrared spectral region. From the spectra column-averaged abundances of CO2, CH4 and other gases are derived. The instrument participates in the Total Carbon Column Observing Network (TCCON).  Here we present long-term ground based FTS measurements of carbon dioxide and methane and comparisons with satellite borne observations. We find that CO2 column amounts have increased by 2.2 ± 0.1 ppm/year since the start of the measurements in 2009 and CH4 column amounts have increased by 7 ± 0.4 ppb/year. The measurements are in good agreement with multi-year measurements by the Greenhouse Gases Observing Satellite (GOSAT): the relative difference in XCH4 has been -0.07 ± 0.02 % and the relative difference in XCO2 has been 0.04 ± 0.02 %. Finally we use balloon borne AirCore observations at the Sodankylä site to provide comparisons between FTS and in situ observations during all seasons.

How to cite: Kivi, R., Chen, H., Hatakka, J., Heikkinen, P., Laurila, T., and Lindqvist, H.: Atmospheric Carbon Dioxide and Methane measurements at Sodankylä, Finland , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13106, https://doi.org/10.5194/egusphere-egu2020-13106, 2020.

EGU2020-18678 | Displays | AS3.15

Ground-based atmospheric measurements from CHRIS for satellite validation.

El Kattar Marie-Thérèse, Auriol Frédérique, and Herbin Hervé

EGU2020-6398 | Displays | AS3.15

Temporal and Spatial Variations of Atmospheric CO2 Growth reproduced by Ground-Based Remote Sensing and CO2 Inverse Modelling

Lev Labzovskii, Samuel Takele Kenea, Jinwon Kim, Young-Hwa Byun, Tae-Young Goo, Haeyoung Lee, Shanlan Li, and Young-Suk Oh

Atmospheric CO2 growth rate is the primary driver of the global warming and a valuable indicator of the interannual changes in carbon cycle. We broaden the knowledge about temporal and spatial variations of annual CO2 growth (AGR) by using CO2 observations from the Total Column Observing Network (TCCON), CO2 simulations from Carbon Tracker (CT) and Copernicus Atmospheric Monitoring System (CAMS) models together with the global-scale AGR references from Global Carbon Budget (GCB) and satellite data (SAT) for 2004-2019 years. TCCON and the CO2 models reveal temporal AGR variations (AGRTCCON = 1.71 – 3.35 ppm, AGRCT = 1.59 – 3.30 ppm, AGRCAMS = 1.66 – 3.13 ppm) of the similar magnitude to the global-scale CO2 growth references (AGRGCB = 1.59 – 3.23 ppm, AGRSAT = 1.55 – 2.92 ppm). However, TCCON estimates of global AGR agree well with the referenced AGR growth only during the 2010s since the network has considerably improved its spatial coverage after 2009. Moreover, TCCON-based AGRs reasonably agree (r = 0.67) with strength of El Nino Southern Oscillations (ENSO) in the 2010s. The highest atmospheric CO2 growth (2015-2016) driven by the very strong El-Nino event is accurately reproduced by TCCON that provided AGR of 2015-2016 years (3.29 ± 0.98 ppm) in very close agreement to the SAT reference (3.23 ± 0.50 ppm). We validate CAMS and CT simulations of AGR versus the newly-acquired TCCON-based AGR (as the point-location reference) for an every single TCCON site and low agreement (r < 0.50) is evidenced only at 3 out of 20 stations. This minor caveat has not affected the accuracy of simulated global AGR since it exhibits high agreement with SAT, GCB (r = 0.74 – 0.78) and TCCON (r > 0.65) references at global scales. Moreover, the correlation of AGR simulations across all grid cells (3 x 2 degree) between CAMS and CT is nearly perfect (r = 0.95) for the modeling period (2004-2016). Similarly, land-wise AGR intercomparison between CAMS and CT yields in perfect correlation (r ≧ 0.90) for 15 out of 20 MODIS land classes where the least vegetated areas exhibit the highest agreement. From spatial perspective, the highest AGR estimates (> 20% from the median value) are observed in the regions with intense combustion (East Asia) or with frequent biomass burning (Amazon, Central Africa). The slight disagreement of AGR spatial variability simulated by CT and CAMS is likely driven by the latter two regions of SH where drier conditions during El-Nino events allegedly increase the probability for divergence between the models. In overall, the current estimates of global AGR are consistent across a wide range of the data sources and strengthening of CO2 observational infrastructure should further improve the accuracy of AGR estimates on global and fine spatial scales.

How to cite: Labzovskii, L., Takele Kenea, S., Kim, J., Byun, Y.-H., Goo, T.-Y., Lee, H., Li, S., and Oh, Y.-S.: Temporal and Spatial Variations of Atmospheric CO2 Growth reproduced by Ground-Based Remote Sensing and CO2 Inverse Modelling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6398, https://doi.org/10.5194/egusphere-egu2020-6398, 2020.

EGU2020-17637 | Displays | AS3.15

High-resolution inversion of methane fluxes using in-situ and satellite measurements over Africa

Amir Hossein Abdi, Julia Marshall, Christian Rodenbeck, Frank-Thomas Koch, and Christoph Gerbig

EGU2020-5341 | Displays | AS3.15

Quantify the regional methane emissions based on a new SCIAMACHY data set

Mengyao Liu, Ronald Van der A, Haiyue Tan, Christian Frankenberg, Ilse Aben, Hao Kong, Jiyunting Sun, Jieying Ding, and Lin Zhang

Methane (CH4) is the most important anthropogenic greenhouse gas after carbon dioxide, and it keeps increasing globally since 2007 after a period of relative stability, which is well-documented by surface measurements and satellites. Although satellites provide long-term global observations of CH4, the interpretation of column-averaged mixing ratios (xCH4) is difficult due to the influence of elevated terrains (i.e. mountain areas) and less abundant methane in the stratosphere. The lack of data over the ocean further limits global insights. Here we build a long-term global CH4 data set at a resolution of 0.25° × 0.25°  from SCIAMACHY, including the areas over the ocean, with the help of FRESCO cloud data. We dynamically consider the influence of elevations and contributions from the stratosphere through converting xCH4 to tropospheric xCH4 (trop_xCH4) by applying the daily ratios of tropospheric to stratospheric xCH4 in GEOS-Chem model.

The large increases occur in Trop_xCH4 over the source regions and mountain areas. The trend of SCIAMACHY Trop_xCH4 over the global ocean is comparable to the trend of NOAA globally averaged marine monthly mean data, showing the capability of SCIAMACHY in monitoring the ocean. After removing the latitudinally independent background concentration based on SCIAMACHY data over the ocean, we quantify the regional sources. A significant trend in Trop_ xCH4 relating to the background in Eastern China, India, tropical Africa, and tropical South America is further found from 2003 to 2011. 

How to cite: Liu, M., Van der A, R., Tan, H., Frankenberg, C., Aben, I., Kong, H., Sun, J., Ding, J., and Zhang, L.: Quantify the regional methane emissions based on a new SCIAMACHY data set, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5341, https://doi.org/10.5194/egusphere-egu2020-5341, 2020.

EGU2020-10076 | Displays | AS3.15

Kriging-based Mapping of Space-borne CO2 Measurements by Combining Emission Inventory and Atmospheric Transport Modeling

Shrutilipi Bhattacharjee, Jia Chen, Li Jindun, and Xinxu Zhao

Atmospheric CO2 measurement has proven its appositeness for different applications in carbon cycle science. Many satellites are currently measuring the atmospheric CO2 concentration worldwide, for example, NASA’s Orbiting Carbon Observatory-2 (OCO-2), Exploratory Satellite for Atmospheric CO2 (TanSat), Japanese Greenhouse gases Observing SATellite (GOSAT), and Environmental Satellite (ENVISAT). The OCO-2 measures the column-averaged CO2 dry air mole fractions (XCO2) in the atmosphere as contiguous parallelogram footprints, each having area up to about 3 km2. The problem associated with this measurement is its narrow swath of approximately 10.6 km width which results in limited spatial coverage.

A number of research works have been reported to spatially map the available XCO2 samples on a regional scale or globally in different temporal scale and spatial resolution. Kriging, a family of geostatistical interpolation method, has been a popular choice for this mapping. In our recent research, we have shown that the univariate kriging methods are not able to produce a pragmatic surface of XCO2 and require the incorporation of more covariates. We have studied the OCO-2’s XCO2 observations and mapped them on a regional scale including multiple covariates, such as Open-source Data Inventory for Anthropogenic CO2 (ODIAC) and the Emissions Database for Global Atmospheric Research (EDGAR) emission estimates and land use and land cover (LULC) information. It is observed that the inclusion of these covariates is able to produce more accurate mapping compared to their baseline alternatives.

However, the CO2 concentration is usually highly influenced by the transportation of the emission particles through the wind. A larger temporal measurement window may ignore its effect by assuming that the wind direction is constantly changing. However, for regional mapping of space-borne XCO2 in a time instance, it is essential to model. This work has developed a novel multivariate kriging-based framework to map OCO-2’s XCO2 measurements including Stochastic Time-Inverted Lagrangian Transport-(STILT)-based atmospheric transport modeling. This model could be coupled with the biospheric flux models and emission estimates to map their local scale distributions.

In this framework, every unmeasured location that is required to be estimated is considered as the receptor point in the STILT simulation. The emission particles are tracked backward in time from each of these receptor points to simulate possible routes from their upstream locations. A footprint map is then generated which is regarded as the influence of other points to the receptor point in the whole study region. The footprint map, being combined with the emission estimates, will produce a prior CO2 concentration map. This STILT-generated prior concentration map is inserted into the multivariate kriging framework. The output map, i.e., the interpolated XCO2 surface is more pragmatic to include the influence of atmospheric transport for the prediction of XCO2. The accuracy of the framework is proven by comparing the estimated data with ground-based measurements. This work is one of the initial attempts to generate a Level-3 XCO2 surface on a local scale by combining STILT with a multivariate kriging method.

How to cite: Bhattacharjee, S., Chen, J., Jindun, L., and Zhao, X.: Kriging-based Mapping of Space-borne CO2 Measurements by Combining Emission Inventory and Atmospheric Transport Modeling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10076, https://doi.org/10.5194/egusphere-egu2020-10076, 2020.

EGU2020-20599 | Displays | AS3.15

Spaceborne monitoring of CO2 emissions from large cities and the impact of aerosols

Sander Houweling, Jochen Landgraf, Friedemann Reum, Hein van Heck, Wei Tao, Yafang Cheng, Tim Vlemmix, and Piet Stammes

International agreements to reduce CO2 emissions call for an independent mechanism for evaluating the compliance with emission reduction targets. Atmospheric measurements can provide important information in support of this goal. However, to do this globally requires a drastic expansion of the existing monitoring network, using a combination of surface measurements and satellites. CO2 sensing satellites can deliver the required spatial coverage, filling in the gaps that are difficult to cover on ground. However, to reach the accuracy that is required for monitoring CO2 from space is a challenge, and even more so for anthropogenic CO2.

The European space agency is preparing for the launch of a constellation of satellites for monitoring anthropogenic CO2 within the Copernicus program, starting in 2025. Scientific support studies have been carried out to define this mission in terms of payload and observational requirements. We report on the AeroCarb study, which investigated the impact retrieval errors due to aerosols in CO2 plumes downwind of large cities, and the potential benefit of an onboard aerosol sensor to help mitigate such errors. In this study, CO2 and aerosol plumes have been simulated at high-resolution for the cities of Berlin and Beijing. The impact of aerosol scattering on spaceborne CO2 measurements has been assessed using a combined CO2-aerosol retrieval scheme, with and without the use of an onboard multi-angular spectropolarimeter (MAP) for measuring aerosols. The results have been used to quantify the accuracy at which the CO2 emissions of Berlin and Beijing can be quantified using inverse modelling and the impact of aerosols depending on the chosen satellite payload. 

In this presentation we summarize the outcome of this study, and discuss the implications for the space borne monitoring of anthropogenic CO2 emissions from large cities.

How to cite: Houweling, S., Landgraf, J., Reum, F., van Heck, H., Tao, W., Cheng, Y., Vlemmix, T., and Stammes, P.: Spaceborne monitoring of CO2 emissions from large cities and the impact of aerosols, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20599, https://doi.org/10.5194/egusphere-egu2020-20599, 2020.

EGU2020-22133 | Displays | AS3.15

Student-led investigation of TROPOMI data for the US

Dorit Hammerling, Lewis Blake, William Daniels, Aidan Dykstal, and Sean Crowell

The TROPOspheric Monitoring Instrument (TROPOMI) is the satellite instrument on board the Copernicus Sentinel-5 Precursor satellite launched on 13 October 2017.  Data products include column estimates of ozone, nitrogen dioxide, methane, carbon monoxide, among others, and feature unprecedent high spatial resolution. These new data products provide opportunities to gain detailed insights into emissions and their sources on scales previously not feasible. We present results from five student teams investigating TROPOMI observations in a semester-long statistical and machine learning analysis practicum under the joint guidance of an atmospheric scientist and statistician. The analysis follows agile practices, where initial results inform the next analysis step. The focus is on the United States, specifically the investigation of methane emissions from natural gas production in key geological basins.

How to cite: Hammerling, D., Blake, L., Daniels, W., Dykstal, A., and Crowell, S.: Student-led investigation of TROPOMI data for the US, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22133, https://doi.org/10.5194/egusphere-egu2020-22133, 2020.

EGU2020-11936 | Displays | AS3.15

CH4 variability over India derived from the GOSAT/TANSO-FTS TIR observations and simulated by MIROC4-ACTM model

Dmitry Belikov, Naoko Saitoh, Prabir K. Patra, and Naveen Chandra

We examine CH4 variability over different regions of India and the surrounding oceanic regions using thermal infrared (TIR) band observations by the Thermal And Near-infrared Sensor for carbon Observation-Fourier Transform Spectrometer (TANSO-FTS) onboard the Greenhouse gases Observation SATellite (GOSAT) and simulated by the updated MIROC4.0-based Atmospheric Chemistry Tracer Model (ACTM) for the period 2009-2014. GOSAT TIR provides data coverage and density captures detailed features of CH4 distributions at height levels from the top of the boundary layer to the upper troposphere even in the cloudy conditions, which is very common for the region with a monsoon climate. Analysis of transport and emission contributions to CH4 variabilities suggests that the CH4 seasonal cycle over India is controlled by the heterogeneous distribution of surface emissions under the influence of the monsoonal divergent wind circulations. Distinct seasonal variations of CH4 are observed over northern and southern regions of India corresponding to the southwestern monsoon (July–September) and early autumn (October–December) seasons. In summer, three principal circulations pumping CH4 upward over South Asia: the lateral (the cross-equatorial circulation) and transverse (flows between the arid regions of North Africa and the Near East and South Asia) monsoons, and the Walker Circulation extends across the Pacific Ocean. GOSAT TIR derives CH4 profiles due to retrieval of signal from 22 vertical levels. In general, the mean ACTM (no averaging kernel incorporated)-GOSAT misfit is within 50 ppb, excepting the level of 150 hPa and upward, where the GOSAT TIR sensitivity becomes too low. Due to the use of MIROC4.0 AGCM performance of ACTM in the upper troposphere and lower stratosphere has been improved. The GOSAT-ACTM misfit above the level of 150 hPa is likely to arise from a priori model for TIR retrievals. Convolution of the modeled profiles with retrieval a priori and averaging kernels reduces the misfit to below uncertainty. However, the weight of the a priori profiles becomes too large with such smoothing. Overall, the ACTM simulations of CH4 in the Indian regions compare favorably with the GOSAT TIR samplings, in terms of seasonality and regional variability. However, the GOSAT-ACTM inconsistencies indicate opportunities for further flux optimization and emission uncertainty reduction by inverse modeling methods.

How to cite: Belikov, D., Saitoh, N., K. Patra, P., and Chandra, N.: CH4 variability over India derived from the GOSAT/TANSO-FTS TIR observations and simulated by MIROC4-ACTM model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11936, https://doi.org/10.5194/egusphere-egu2020-11936, 2020.

EGU2020-9660 | Displays | AS3.15

Significant fluxes of methane over tropical wetlands and their associated δ13C isotopic source signatures

James L. France, Anna Jones, Tom Lachlan-Cope, Alex Weiss, Marcos Andrade, Isabel Moreno, Rebecca Fisher, Dave Lowry, Mathias Lanoiselle, Euan Nisbet, and Mark Lunt

Tropical wetlands have been proposed as a potential driver for the recent rise in global atmospheric methane. However, direct access and quantification of emissions is difficult. In March 2019, a pilot study was given permission to overfly the Bolivian Llanos de Moxos wetlands to measure atmospheric mixing ratios of methane and collect spot samples for isotopic analysis. Combined with this was a short ground campaign to collect isotopic samples directly above the wetland edge to compare with the integrated atmospheric signature.

Atmospheric mixing ratios of methane reached a maximum of 2400 ppb (500 ppb above baseline concentrations) in the well mixed boundary layer flying at 400m above the wetland. Upwind and downwind transects were a maximum of 300 km, and methane mixing ratios increased roughly linearly with distance downwind. The isotopic data from the airborne surveys and ground surveys give a bulk isotopic signature for δ13CCH4 of ~-59 ‰ ± 4, which is less negative than Amazon floodplain work focusing on emission of methane through trees, but match well with bulk isotopic values from the Amazon Basin. Ground based wetland samples taken concurrently near Trinidad, Bolivia, gave a source signature of -56 ‰ ± 4 re-enforcing the likelihood that the atmospheric enhancements measured are related to the wetland emissions. For comparison, tropical wetlands measured at ground level during a recent Ugandan and Zambian campaign gave heavier δ13CCH4 isotopic source signatures of -50 to -54 ‰. Based on this snap shot study, flux estimations suggest that the Bolivian wetlands could be emitting ~10mg CH4 m-2 h-1. The observed mole fractions will be compared to model simulations to determine how well the Bolivian wetland methane fluxes are represented.

How to cite: France, J. L., Jones, A., Lachlan-Cope, T., Weiss, A., Andrade, M., Moreno, I., Fisher, R., Lowry, D., Lanoiselle, M., Nisbet, E., and Lunt, M.: Significant fluxes of methane over tropical wetlands and their associated δ13C isotopic source signatures, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9660, https://doi.org/10.5194/egusphere-egu2020-9660, 2020.

AS3.16 – Satellite observations of tropospheric composition and pollution, analyses with models and applications

EGU2020-11042 | Displays | AS3.16 | Highlight

Quantifying NOx emissions from a city and a small country with the TROPOMI and OMI satellite instruments

Folkert Boersma, Marina Zara, Alba Lorente, Henk Eskes, and Maarten Krol

The TROPOMI and OMI satellite sensors provide an exciting perspective on the sources, dispersion, and fate of air pollution, and in particular on nitrogen dioxide (NO2). Yet it is still difficult to relate satellite observations of tropospheric NO2 columns to the underlying NOx emissions and their trends. Robust interpretation of satellite data relies on a good understanding of the accuracy and representativeness of the satellite data itself, but also on the relationship between NOx emissions and the observable NO2 amount. This relationship is influences by local chemistry, mixing and dispersion, and by the NO2 amount in the free troposphere. We address these issues via two examples:

(1) Direct estimation of NOx emissions from the satellite-observed build-up of pollution over the city of Paris. After validating NO2 measurements from TROPOMI over the heart of Paris, we analyse the observed build-up of NO2 pollution over the city along with the wind. Over the city, recently emitted NOx has been oxidized to limited degree, facilitating the use of TROPOMI data to directly determine the strength and distribution of emissions from the city. From the observed build-up of NO2 pollution, we find highest NOx emissions on cold weekdays in February 2018, and lowest emissions on warm weekend days in spring 2018.

(2) Trends in NO2 over The Netherlands. We use the QA4ECV OMI NO2 record to investigate trends in tropospheric NO2 columns over Europe, and in particular over The Netherlands between 2005 and 2018. In spite of the differences in metrics and sampling techniques, the NO2 measured in the Dutch atmosphere from space and from the ground follows a trend that is consistent with predictions by emission inventories. Surface NO2 is reduced by 32% in 2018 relative to 2005, OMI NO2 by 35%, and NOx emissions by 32%-38% depending on the inventory. Interestingly, the Dutch surface concentrations reveal an upward trend in the NO2:NO ratio in line with O3 increases. This suggests that the NO2 makes up an increasing share of the NOx in the lower atmosphere as NOx emissions decline. This needs to be accounted for when interpreting NO2 trends as proxy for NOx trends.

How to cite: Boersma, F., Zara, M., Lorente, A., Eskes, H., and Krol, M.: Quantifying NOx emissions from a city and a small country with the TROPOMI and OMI satellite instruments, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11042, https://doi.org/10.5194/egusphere-egu2020-11042, 2020.

EGU2020-3974 | Displays | AS3.16

Estimating Lightning NOx Production Using NO2 Columns from the TROPOMI Instrument and Flashes from the Geostationary Lightning Mappers

Kenneth Pickering, Dale Allen, Eric Bucsela, Jos van Geffen, Henk Eskes, Pepijn Veefkind, William Koshak, and Nickolay Krotkov

Nitric oxide (NO) is produced in lightning channels and quickly comes into equilibrium with nitrogen dioxide (NO2) in the atmosphere.  The production of NOx (NO + NO2) leads to subsequent increases in the concentrations of ozone (O3) and the hydroxyl radical (OH) and decreases in the concentration of methane (CH4), thus impacting the climate system.  Global production of NOx from lightning is uncertain by a factor of four.  NOx production by lightning will be examined using NO2 columns from the TROPOspheric Monitoring Instrument (TROPOMI) on board the Copernicus Sentinel-5 Precursor Satellite with an overpass time of approximately 1330 LT and flash rates from the Geostationary Lightning Mapper (GLM) on board the NOAA GOES-16 (75.2° W) and GOES-17 (137.2° W) satellites.  Where there is overlap in coverage of the two GLM instruments, the greater of the two flash counts is used.  Two approaches have been undertaken for this analysis:  a series of case studies of storm systems over the United States, and a gridded analysis over the entire contiguous United States, Central America, northern South America, and surrounding oceans.  A modified Copernicus Sentinel 5P TROPOMI NO2 data set is used here for the case-study analysis to improve data coverage over deep convective clouds.  In both approaches, only TROPOMI pixels with cloud fraction > 0.95 and cloud pressure < 500 hPa are used.  The stratospheric column is removed from the total slant column, and the result is divided by air mass factors appropriate for deep convective clouds containing lightning NOx (LNOx).  Case studies have been selected from deep convective systems over and near the United States during the warm seasons of 2018 and 2019.  For each of these systems, NOx production per flash is determined by multiplying a TROPOMI-based estimate of the mean tropospheric column of LNOx over each system by the storm area and then dividing by a GLM-based estimate of the flashes that contribute to the column.  In the large temporal and spatial scale analysis, the TROPOMI data are aggregated on a 0.5 x 0.5 degree grid and converted to moles LNOx*.  GLM flash counts during the one-hour period before TROPOMI overpass are similarly binned. A tropospheric background of LNOx* is estimated from grid cells without lightning and subtracted from LNOx* in cells with lightning to yield an estimate of freshly produced lightning NOx, designated LNOx.  Results of the two approaches are compared and discussed with respect to previous LNOx per flash estimates.

 

How to cite: Pickering, K., Allen, D., Bucsela, E., van Geffen, J., Eskes, H., Veefkind, P., Koshak, W., and Krotkov, N.: Estimating Lightning NOx Production Using NO2 Columns from the TROPOMI Instrument and Flashes from the Geostationary Lightning Mappers, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3974, https://doi.org/10.5194/egusphere-egu2020-3974, 2020.

EGU2020-7633 | Displays | AS3.16

Connecting the dots: NOx emissions along a West Siberian natural gas pipeline.

Ronald van der A, Jos de Laat, Henk Eskes, and Jieying Ding

New TROPOMI (Sentinel 5P) high quality satellite measurements of nitrogen dioxide (NO2) over snow-covered regions of Siberia reveal previously undocumented but significant nitrogen oxides (NOx = NO + NO2) emissions associated with the natural gas industry in Western Siberia. Besides gas drilling and natural gas power plants, also gas compressor stations for the transport of natural gas are sources of high amounts of NOx emissions, which are emitted in otherwise pristine regions. The emissions from these remote gas compressor stations are at least an order of magnitude larger than those reported for North American gas compressor stations, possibly related to less stringent environmental regulations in Siberia compared to the United States. This discovery was made possible thanks to a newly developed technique for discriminating snow covered surfaces from clouds, which for the first time allows for satellite measurements of tropospheric NO2 columns over large boreal snow-covered areas. This results in 23% more TROPOMI observations on an annual basis. Furthermore, these observations have a precision four times better than nearly any TROPOMI observation over other areas and surfaces around the world. These new results highlight the potential of TROPOMI on Sentinel 5P as well as future satellite missions for monitoring small-scale emissions

How to cite: van der A, R., de Laat, J., Eskes, H., and Ding, J.: Connecting the dots: NOx emissions along a West Siberian natural gas pipeline., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7633, https://doi.org/10.5194/egusphere-egu2020-7633, 2020.

Prolonged exposure to high concentrations of nitrogen dioxide (NO2) and ozone (O3) at ground level could be harmful to human health. In-situ air pollutant concentration data observed from ground monitoring stations are limited in providing spatially continuous information. Since there are only a few stations installed above the sea, it is difficult to monitor the concentrations of air pollutants over the sea. In this study, machine learning-based models were developed to estimate ground-level NO2 and O3 concentrations using satellite-based remote sensing data and model-based meteorological and emission data over East Asia during 2015-2017, to overcome such limitations. NO2 and O3 vertical column density products from the Aura Ozone Monitoring Instrument (OMI) were used as essential predictors to estimate NO2 and O3 concentrations. Missing pixels of OMI products due to row anomalies were filled using a temporal convolution approach to generate the spatiotemporally continuous distribution of NO2 and O3 concentrations. In order to estimate the air pollutant concentrations in both land and ocean, specific values were assigned to the ocean for land-only variables. Random forest (RF) was used to develop the estimation models for NO2 and O3 concentrations. The RF-based models showed the results with R2 values of 0.72 and 0.75, and RMSEs of 6.24 ppb and 10.56 ppb for NO2 and O3, respectively. The estimated results over the ocean were validated using coastal stations that are located within a 1 km distance from the coast. Compared to the model without land-only variables, the models using all variables had slightly better results. The satellite-based NO2 and O3 vertical column density were identified as significant variables in both models. Besides, urban land cover ratio, wind-related variables such as wind vectors, and stacked maximum wind speed had relatively high variable importance. The spatial variation of NO2 and seasonal variation of O3 were well shown in the estimated spatiotemporal distribution.

How to cite: Shin, M. and Im, J.: Estimating surface nitrogen dioxide and ozone concentrations using satellite-based and numerical model-based data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13635, https://doi.org/10.5194/egusphere-egu2020-13635, 2020.

EGU2020-18569 | Displays | AS3.16

IASI observations at the city scale

Sarah Safieddine, Maya George, Cathy Clerbaux, Ana Paracho, Anne Boynard, Juliette Hadji-Lazaro, Lieven Clarisse, Simon Whitburn, and Pierre-Francois Coheur

IASI is a versatile mission, allowing the measurement of both meteorological parameters such as temperature and atmospheric composition for infrared absorbing species. With its long observation record and frequent overpasses, IASI is able to follow changes at different spatial scales. We studied IASI’s capability to track the anthropogenic signature associated with large cities, both in terms of temperature fingerprint (urban heat islands) and carbon monoxide (CO) content, a good tracer of human activity (transport, heating, and industrial activities). For this study we averaged the IASI data available since the launch of the first IASI, in order to increase the signal to noise, and allow discriminating the city from its surroundings. For skin temperatures we show that some cities experience much warmer temperatures than nearby rural areas, with day and night differences, whereas other urban areas appear as cold urban islands when surrounded by deserts Examples will be shown and compare with MODIS observations. For CO emitted by human activities, we identified some cities that stand out from their background, and were able to compare their CO associated signatures with measurements provided by other available spaceborne instruments such as Mopitt and TROPOMI.

How to cite: Safieddine, S., George, M., Clerbaux, C., Paracho, A., Boynard, A., Hadji-Lazaro, J., Clarisse, L., Whitburn, S., and Coheur, P.-F.: IASI observations at the city scale, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18569, https://doi.org/10.5194/egusphere-egu2020-18569, 2020.

EGU2020-10509 | Displays | AS3.16 | Highlight

Satellite monitoring of ammonia: from point sources to long-term trends

Lieven Clarisse, Martin Van Damme, Bruno Franco, Simon Whitburn, Juliette Hadji-Lazaro, Daniel Hurtmans, Cathy Clerbaux, and Pierre-François Coheur

IASI satellite ammonia (NH3) measurements are used to identify, categorise and quantify world's NH3 emission hotspots. In particular, applying spatial oversampling and supersampling techniques on more than 10 years of IASI measurements, we are able to track-down more than 500 localized point sources of agricultural, industrial (fertilizer, coking, soda ash, geothermal and explosives industries), urban and natural origin. We present an on-line global NH3 point sources catalogue, consisting of an interactive global map, visualizing the distribution, type and time evolution of the different point sources (http://www.ulb.ac.be/cpm/NH3-IASI.html). Calculated satellite-based emissions of NH3 suggest a drastic underestimation of point sources in bottom-up inventories, especially those of industrial emitters. Temporal analysis revealed rapid shifts in anthropogenic activities, such as the opening or closure of industrial plants. These results demonstrate that using NH3 satellite data will be hugely beneficial for improving bottom-up emission inventories.

A recently obtained homogeneous data record of NH3 total columns from IASI (ANNI-NH3-v3R) is also used to derive trends over the last decade. We apply a bootstrap resampling method to determine the trends and to assess whether the calculated values are significant or not. We obtain the first global distribution (0.5°×0.5°) of atmospheric NH3 trends based on 11 years (2008-2018) of IASI/Metop-A observations. Distinct temporal patterns are extracted and are analysed in light of anthropogenic activities and biomass burning events. National absolute and relative trends are also calculated and discussed.

How to cite: Clarisse, L., Van Damme, M., Franco, B., Whitburn, S., Hadji-Lazaro, J., Hurtmans, D., Clerbaux, C., and Coheur, P.-F.: Satellite monitoring of ammonia: from point sources to long-term trends, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10509, https://doi.org/10.5194/egusphere-egu2020-10509, 2020.

EGU2020-11445 | Displays | AS3.16

A space-based perspective of trends in air quality in major cities in the UK and India

Karn Vohra, Eloise Marais, Louisa Kramer, William Bloss, Peter Porter, Martin Van Damme, Lieven Clarisse, and Pierre-François Coheur

Air pollution is one of the leading global causes of premature mortality, necessitating routine monitoring of air quality in cities where most (55%) people now reside. Surface monitors are sparse and costly to operate, whereas satellites provide global coverage of a multitude of pollutants spanning more than 2 decades. Here we make use of the dynamic range of satellite products to understand long-term changes in air quality in target cities in the UK (London and Birmingham) and India (Kanpur and Delhi). These include nitrogen dioxide (NO2) from OMI for 2005-2018, formaldehyde (HCHO) from OMI for 2005-2016 to monitor non-methane volatile organic compounds (NMVOCs), ammonia (NH3) from IASI for 2008-2017 and aerosol optical depth (AOD) from MODIS for 2005-2018 to monitor PM2.5. Where surface observations are available (almost exclusively the UK), we first evaluate the ability of the satellite observations to reproduce variability in surface air pollution. We find temporal consistency for most pollutants (R >= 0.5), with the exception of MODIS AOD and surface PM2.5 (R = 0.3), but the decline in AOD (3.0% a-1) and surface PM2.5 (2.8% a-1), so far only evaluated for London, is similar. Inconsistencies result from seasonal variability in the planetary boundary layer, differences in sampling footprint between the satellite and surface monitors, and interferences in the surface measurements (as is the case for NO2). We find a decrease in all pollutants in Birmingham and London and an increase in all pollutants in Delhi and Kanpur, over the analysis period, but not all trends are significant. Birmingham and London NO2 both declined by 2.5% a-1, whereas Delhi NO2 increased by 2.0% a-1, so that by the end of 2018 Delhi and London have the same tropospheric column concentrations of NO2. Only Delhi exhibits a significant NMVOCs trend (increase) of 1.8% a-1. NH3 trends are not significant in any of the four cities, consistent with bottom-up inventories and lack of direct controls on emissions of this pollutant, mostly from agriculture. These data show no evidence of air quality improvements in Delhi, despite rollout of strict controls on industry and vehicles.

How to cite: Vohra, K., Marais, E., Kramer, L., Bloss, W., Porter, P., Van Damme, M., Clarisse, L., and Coheur, P.-F.: A space-based perspective of trends in air quality in major cities in the UK and India, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11445, https://doi.org/10.5194/egusphere-egu2020-11445, 2020.

EGU2020-11011 | Displays | AS3.16 | Highlight

14 years of OMI HCHO observations reveal VOC emission trends over large cities worldwide

Maite Bauwens, Jenny Stavrakou, Jean-François Müller, Isabelle De Smedt, and Nellie Elguindi

Formaldehyde (HCHO) observations from satellites have been widely used to constrain volatile organic compound (VOC) emission estimates. The oxidation of anthropogenic organic compounds accounts for only a small fraction(~7%) of the total HCHO column on global average (Stavrakou et al., 2009). Therefore, the use of satellite observations to infer information about anthropogenic VOC emissions is generally very challenging . However, the relative contribution of anthropogenic VOCs in and around metropolitan centers is expected to be significant. In this study, we use HCHO column data retrieved from the OMI sensor between 2005 and 2018, and calculate monthly averages for every city of more than 500,000 inhabitants based on data within 20 km of the city centers. Because of the dependence of the background and especially of the biogenic VOC source on temperature and solar radiation, and because these contributions might be significant even around large cities, it is not possible to directly infer the anthropogenic contribution to the long-term observed HCHO trends based on HCHO data. To remove these non-anthropogenic contributions, we first regress the monthly averaged columns either onto the monthly maximum surface temperature, obtained by ECMWF reanalysis data, or onto the monthly isoprene flux, calculated with the MEGAN-MOHYCAN model (Guenther et al., 2012, Stavrakou et al. 2018). Only cities for which anthropogenic emissions are estimated to exceed biogenic emission by more than a factor of 3 are considered. In this way, positive trends of up to 3% yr-1 are found over many Asian cities, especially in China and in the Indo-gangetic Plain, whereas over European cities, South Africa and South America negative trends up to -2% yr-1 are derived. The deduced trends are compared to the corresponding trends of global bottom-up anthropogenic VOC emission inventories and are found to be in good overall agreement. Model simulations are further needed to quantify the relationship between anthropogenic emission trends and HCHO columns, accounting for the effect of non-anthropogenic emissions and potential changes in the oxidizing capacity.

How to cite: Bauwens, M., Stavrakou, J., Müller, J.-F., De Smedt, I., and Elguindi, N.: 14 years of OMI HCHO observations reveal VOC emission trends over large cities worldwide, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11011, https://doi.org/10.5194/egusphere-egu2020-11011, 2020.

EGU2020-19214 | Displays | AS3.16 | Highlight

Characterization of OVOC emission from wildfires using observations from Sentinel-5 Precursor

Leonardo M. A. Alvarado, Andreas Richter, Mihalis Vrekoussis, Andreas Hilboll, Anna B. Kalisz Hedegaard, and John P. Burrows

Oxygenated volatile organic compounds (OVOCs) are released to the atmosphere from biogenic, anthropogenic, and pyrogenic sources. The role and importance of OVOCs in ambient atmospheric composition and their role in climate change was established many years ago. Another topical issue is the formation of secondary organic aerosols (SOA), which potentially are relevant for cloud formation, heterogeneous chemistry, and can also contribute to the long-term transport of volatile organic compounds. OVOCs can be detected from space-borne observations using the Differential Optical Absorption Spectroscopy (DOAS) method. Here, measurements from the TROPOMI instrument, which was launched on the Sentinel-5 Precursor (S5P) platform in October 2017, are used. 

During the year 2019, large wildfires occurred in North America, Amazonia, Siberia, and Australia. These fires created elevated amounts of many different gases, e.g. CO, NOx, OVOC, O3, SO2, CO, HONO, CH3CO.O2.NO2 (PAN) and other toxic species as well as aerosols affecting air quality. During the transport of plumes from fires, photochemical transformation of emitted species occurs. Overall, polluted air is transported to regions where the plumes are dispersed. For many of the fires, unexpectedly high amounts of OVOCs are detected in plumes as consequence of continued emission and conversion of some OVOCs. The amounts of OVOCs emitted were found to depended on the type of biomass burned and the location of the fires. 

Here, a characterization of OVOC emissions from fires is performed by using OVOC S5P observations, in combination with forward trajectories simulated with the FLEXPART model and proxies of vegetation types, leading to new insights in the emissions of OVOCs from fires.

How to cite: Alvarado, L. M. A., Richter, A., Vrekoussis, M., Hilboll, A., Kalisz Hedegaard, A. B., and Burrows, J. P.: Characterization of OVOC emission from wildfires using observations from Sentinel-5 Precursor, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19214, https://doi.org/10.5194/egusphere-egu2020-19214, 2020.

EGU2020-9127 | Displays | AS3.16 | Highlight

Identifying source regions at the Princes Elisabeth station in Antarctica, using dispersion modelling tools: a case study

Karen De Causmaecker, Alexander Mangold, Christophe Walgraeve, Preben Van Overmeiren, Nadine Mattielli, Stefania Gili, and Andy W. Delcloo

During the time period December 2019 – January 2020, a lot of biomass burning has been ongoing in the Southern Hemisphere. This led to a large amount of fine dust being emitted and transported into the atmosphere of the Southern Hemisphere.

With the dispersion model FLEXPART, we will simulate these fires, using the CAMS Global Fire Assimilation System (GFAS) which assimilates fire radiative power (FRP) observations from satellite-based sensors in order to reproduce daily estimates of biomass burning emissions. Also information on the injection height is available.

Aerosol fluxes and sources in Antarctica and its closely associated Southern Ocean are poorly constrained, in particular the particle chemistry. A detailed understanding of present-day atmospheric transport pathways of particles and of volatile organic compounds (VOC) from source to deposition in Antarctica remains essential to document biogeochemical cycles and the relative importance of natural and anthropogenic compounds. Within the CHASE project (chase.meteo.be), the Royal Meteorological Institute of Belgium, Ghent University and the Université Libre de Bruxelles are doing research at the Belgian research station Princess Elisabeth (71.9°S, 23.3°E; East Antarctica, Dronning Maud Land) on the physical-chemical composition of both atmospheric particles, particles in surface snow particles as well as of VOCs. Since 2018, samples are taken both near the Belgian research station Princess Elisabeth (active sampling with pumps) and on a transect to the coast (passive samplers and surface snow samples).

In this contribution we will thoroughly investigate the atmospheric transport pathways of the recent biomass burning plumes, and in particular to what extent parts of these plumes have reached Antarctica. The measured chemical signatures of atmospheric particles and VOCs will help to constrain the simulations of the dispersion model.

How to cite: De Causmaecker, K., Mangold, A., Walgraeve, C., Van Overmeiren, P., Mattielli, N., Gili, S., and Delcloo, A. W.: Identifying source regions at the Princes Elisabeth station in Antarctica, using dispersion modelling tools: a case study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9127, https://doi.org/10.5194/egusphere-egu2020-9127, 2020.

EGU2020-10342 | Displays | AS3.16

Satellite-based observations of ground-level fine particulate matter and comparison to a regional air quality model

Jana Handschuh, Frank Baier, Thilo Erbertseder, and Martijn Schaap

Particulate matter and other air pollutants have become an increasing burden on the environment and human health. Especially in metropolitan and high-traffic areas, air quality is often remarkably reduced. For a better understanding of the air quality in specific areas, which is of great environment-political interest, data with high resolution in space and time is required. The combination of satellite observations and chemistry-transport-modelling has proven to give a good database for assessments and analyses of air pollution. In contrast to sample in-situ measurements, satellite observations provide area-wide coverage ​​of measurements and thus the possibility for an almost gapless mapping of actual air pollutants. For a high temporal resolution, chemistry-transport-models are needed, which calculate concentrations of specific pollutants in continuous time steps. Satellite observations can thus be used to improve model performances.

There are no direct satellite-measurements of fine particulate matter (PM2.5) but ground-level concentrations of PM2.5 can be derived from optical parameters such as aerosol optical depth (AOD). A wide range of methods for the determination of PM2.5 concentrations from AOD measurements has been developed so far, but it is still a big challenge. In this study a semi-empirical approach based on the physical relationships between meteorological and optical parameters was applied to determine a first-guess of ground-level PM2.5 concentrations for the year 2018 and the larger Germany region. Therefor AOD observations of MODIS (Moderate Resolution Imaging Spectroradiometer) aboard the NASA Aqua satellite were used in a spatial resolution of 3km. First results showed an overestimation of ground-level aerosols and quiet low correlations with in-situ station measurements from the European Environmental Agency (EEA). To improve the results, correction factors were calculated using the coefficients of linear regression between satellite-based and in-situ measured particulate matter concentrations. Spatial and seasonal dependencies were taken into account with it. Correlations between satellite and in-situ measurements could be improved applying this method.

The MODIS 3km AOD product was found to be a good base for area-wide calculations of ground-level PM2.5 concentrations. First comparisons to the calculated PM2.5 concentrations from chemistry-transport-model POLYPHEMUS/DLR showed significant differences though. Satellite observations will now be used to improve the general model performance, first by helping to find and understand regional and temporal dependencies in the differences. As part of the German project S-VELD funded by the Federal Ministry of Transport and Digital Infrastructure BMVI, it will help for example to adjust the derivation of particle emissions within the model.

How to cite: Handschuh, J., Baier, F., Erbertseder, T., and Schaap, M.: Satellite-based observations of ground-level fine particulate matter and comparison to a regional air quality model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10342, https://doi.org/10.5194/egusphere-egu2020-10342, 2020.

EGU2020-12059 | Displays | AS3.16 | Highlight

Advances in operational air quality and aerosol prediction at NOAA/National Weather Service

Ivanka Stajner and the Global Aerosol and Regional Air Quality Prediction Team

NOAA is developing the Unified Forecast System (UFS) (https://ufscommunity.org/) as the source system for operational numerical weather prediction applications.  The UFS will be a coupled, comprehensive Earth modeling system with community contributions. The UFS is designed to streamline and simplify NOAA/National Weather Service operational modeling suite.  Integration of air quality predictions into the UFS began with testing of the Community Multiscale Air Quality modeling system (CMAQ) predictions driven by the operational version of the Global Forecast System (GFS), which includes the Finite-Volume Cubed-Sphere (FV3) dynamical core since June 2019.  In addition to system integration, this testing allows us to extend ozone and PM2.5 predictions to 72 hours (from 48 hours that operational predictions currently cover).  Integration of global aerosol prediction based on the Goddard Chemistry Aerosol Radiation and Transport (GOCART) scheme into the UFS begun by including it into one member of the Global Ensemble Forecast System (GEFS-Aerosol). GEFS-Aerosol predictions demonstrate a substantial improvement for both composition and variability of aerosol distributions over those from the currently operational standalone global aerosol prediction system.

The use of satellite observations in atmospheric composition and air quality predictions is increasing at NOAA.  Real-time estimates of biomass burning emissions for predictions are based on satellite data.  Challenges for these emissions involve detection of fires, the strength and composition of the emissions, altitude of the plume rise, temporal distribution of the emissions and the uncertainty in persistence or change of emissions during the forecast period. Representation of changing fire emissions in the model becomes more important with increasing prediction length.  Assimilation of Suomi National Polar-orbiting Partnership (SNPP) Visible Infrared Imaging Radiometer Suite (VIIRS) and Moderate Resolution Imaging Spectroradiometer (MODIS) aerosol optical depth (AOD) observations is under development to constrain aerosol distribution in the global system. Initial testing shows promise for improvement of predictions as well as limitations indicating a need for refinements in quality control, data assimilation impacts on aerosol composition and vertical distribution, as well as a need for bias correction of satellite observations.   Plans for the next-generation regional system include assimilation of satellite retrievals of VIIRS AOD and Sentinel-5 Precursor Tropospheric Ozone Monitoring Instrument (S5P TROPOMI) NO2. Satellite data also play an important role in verification of aerosol predictions. Additional uses of satellite data include verification and evaluation of model predictions such as aerosol vertical profile with TROPOMI aerosol layer height product as well as efforts to constrain and update anthropogenic emissions.

This presentation will overview advances and challenges in model development and the use of satellite data for operational atmospheric composition and air quality predictions at NOAA.

How to cite: Stajner, I. and the Global Aerosol and Regional Air Quality Prediction Team: Advances in operational air quality and aerosol prediction at NOAA/National Weather Service, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12059, https://doi.org/10.5194/egusphere-egu2020-12059, 2020.

EGU2020-6025 | Displays | AS3.16

AEROCOM/AEROSAT: use of satellite observations in evaluating global aerosol models

Nick Schutgens and the AEROCOM & AEROSAT teams

In contrast to most aerosol species, black carbon and dust absorb visual light and may heat the atmosphere. However, their overall effect is highly uncertain. In this study we explore the use of novel satellite AAOD (Absorptive Aerosol Optical Depth) measurements in evaluating global (AEROCOM) models.  

Two POLDER retrieval products, and one product each from OMI and a CALIOP/MODIS combination are intercompared and evaluated with AERONET ("truth") data. While all products have skill in measuring AAOD, there are substantial biases amongst the products. In particular, we note a bias between the two POLDER products of 0.04 in SSA (Single Scattering Albedo), independent of AOD (Aerosol Optical Depth). Identification of the cause of this bias would allow a substantial improvement in AAOD observations. However, we show that even with such biases, consistent evaluation of global models with satellite products is possible.

In particular we show that there can be substantial under- and over-estimates of AAOD, depending on model. Furthermore, in recent years, models have diverged amongst themselves. This can be traced to different emission inventories, and we show that satellite AAOD may be used to provide constraints on these emissions. At the same time, models still differ in their particle properties, and we show that this can, to some extent, be evaluated with observations as well.

In addition, we will introduce a similar study for an ensemble of 14 satellite products of AOD. This larger ensemble allows us to study AOD diversity between the products in detail. In particular, we show that this diversity is a pretty good predictor of AOD uncertainty (versus "truth" data) in multi-year averages. This provides us with uncertainty estimates even in the absence of truth data, which allows many exciting applications (to be discussed).

These studies are the fruit of collaboration between the AEROCOM (AEROsol Comparisons between Observations and Models, https:// aerocom.met.no) and AEROSAT (International Satellite Aerosol Science Network, https://aero-sat.org) communities.

How to cite: Schutgens, N. and the AEROCOM & AEROSAT teams: AEROCOM/AEROSAT: use of satellite observations in evaluating global aerosol models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6025, https://doi.org/10.5194/egusphere-egu2020-6025, 2020.

EGU2020-6002 | Displays | AS3.16

Global atmospheric carbon monoxide budget 2000–2017 inferred from multi-species atmospheric inversions

Bo Zheng, Frederic Chevallier, Yi Yin, Philippe Ciais, Audrey Fortems-Cheiney, Merritt Deeter, Robert Parker, Yilong Wang, Helen Worden, and Yuanhong Zhao

Atmospheric carbon monoxide (CO) has been decreasing since 2000 as observed by both satellite- and ground-based instruments, but global bottom-up emission inventories surprisingly estimate increasing anthropogenic CO emissions concurrently. In this study, we use a multi-species atmospheric Bayesian inversion approach to attribute satellite-observed atmospheric CO variations to its sources and sinks in order to achieve full closure of the global CO budget during 2000–2017. Our observation constraints include satellite retrievals of the total column mole fraction of CO from MOPITT, formaldehyde (HCHO) from OMI, and methane (CH4) from GOSAT, which are all major components of the atmospheric CO cycle. Three inversions are performed to use the observation data to the maximum extent possible as they become available and assess the consistency of inversion results to the assimilation of more trace gas species. We identify a declining trend in the global CO budget since 2000 (three inversions are broadly consistent), driven by reduced anthropogenic emissions in the U.S. and Europe (both likely from the transport sector), and in China (likely from industry and residential sectors), as well as by reduced biomass burning emissions globally, especially in Equatorial Africa (associated with reduced burned areas). We show that the trends and drivers of the inversion-based CO budget are not affected by the inter-annual variation assumed for prior CO fluxes. All three inversions estimate that surface CO emissions contradict the global bottom-up inventories in the world’s top two emitters for the sign of anthropogenic emission trends in China (e.g., here −0.8 ± 0.5% yr−1 since 2000 while the prior gives 1.3 ± 0.4% yr−1) and for the rate of anthropogenic emission increase in South Asia (e.g., here 1.0 ± 0.6% yr−1 since 2000 smaller than 3.5 ± 0.4% yr−1 in the prior inventory). The comparison of the three inversions with different observation constraints further suggests that the most complete constrained inversion that assimilates MOPITT CO, OMI HCHO, and GOSAT CH4 has a good representation of the global CO budget, therefore matches best with independent observations, while the inversion only assimilating MOPITT CO tends to underestimate both the decrease in anthropogenic CO emissions and the increase in the CO chemical production.

How to cite: Zheng, B., Chevallier, F., Yin, Y., Ciais, P., Fortems-Cheiney, A., Deeter, M., Parker, R., Wang, Y., Worden, H., and Zhao, Y.: Global atmospheric carbon monoxide budget 2000–2017 inferred from multi-species atmospheric inversions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6002, https://doi.org/10.5194/egusphere-egu2020-6002, 2020.

EGU2020-2720 | Displays | AS3.16 | Highlight

Detection of extreme events with IASI observations

Adrien Vu Van, Anne Boynard, Pascal Prunet, Dominique Jolivet, Olivier Lezeaux, Patrice Henry, Claude Camy-Peyret, and Cathy Clerbaux

The 3 IASI instruments on-board the Metop satellites have been sounding the atmospheric composition since 2006. Up to ~30 atmospheric gases can be measured from IASI spectra, allowing monitoring of weather, atmospheric chemistry, and climate.

Extreme events such as fires, high pollution episodes, volcanic eruptions, industrial accidents, etc., that impact on the population and the environment have become a major political issue. With IASI providing global observations twice a day in near real time, a new way for the systematic and continuous detection of exceptional atmospheric events to support operational decisions is possible.

In this work, we explore and improve an automatic system for the detection and characterization of extreme events, which relies on the principal component analysis (PCA) method. We assess this PCA-based system by analysing IASI raw and compressed spectra along with their differences (residuals) for various past and documented extreme events. The benefits and limitations of this method will be discussed. A new method based on the refined analysis of residuals for the whole year 2019 is proposed, that could be used as an automatic detection method for unexpected events. Finally, we investigate the potential of deep learning methods as a way to compare residuals with a database of extreme event in order to better characterize detected events.

How to cite: Vu Van, A., Boynard, A., Prunet, P., Jolivet, D., Lezeaux, O., Henry, P., Camy-Peyret, C., and Clerbaux, C.: Detection of extreme events with IASI observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2720, https://doi.org/10.5194/egusphere-egu2020-2720, 2020.

EGU2020-10486 | Displays | AS3.16

Multiscale observations of NH3 around Toronto, Canada

Shoma Yamanouchi, Camille Viatte, Kimberly Strong, Dylan B. A. Jones, Cathy Clerbaux, Martin Van Damme, Lieven Clarisse, and Pierre Francois Coheur

Ammonia (NH3) is a major source of nitrates in the atmosphere, and a major source of fine particulate matter. As such, there have been increasing efforts to monitor NH3. This study examines long-term measurements of NH3 around Toronto, Canada, derived from three multiscale datasets: 16 years of total column measurements using ground-based Fourier transform infrared (FTIR) spectroscopy, three years of surface in-situ measurements, and ten years of total columns from the Infrared Atmospheric Sounding Interferometer (IASI) sensor onboard the Metop satellites. These datasets were used to quantify NH3 temporal variabilities (trends, inter-annual, seasonal) over Toronto to assess the observational footprint of the FTIR measurements, and two case studies of pollution events due to transport of biomass burning plumes.

All three timeseries showed increasing trends in NH3 over Toronto: 3.34 ± 0.44 %/year from 2002 to 2018 in the FTIR columns, 8.88 ± 2.49 %/year from 2013 to 2017 in the surface in-situ data, and 8.78 ± 0.84 %/year from 2008 to 2018 in the IASI columns. To assess the observational footprint of the FTIR NH3 columns, correlations between the datasets were examined. The best correlation between FTIR and IASI was found for coincidence criterion of ≤ 50 km and ≤ 20 minutes, with r = 0.66 and a slope of 0.988 ± 0.058. The FTIR column and in-situ measurements were standardized and correlated, with 24-day averages and monthly averages yielding correlation coefficients of r = 0.72 and r = 0.75, respectively.
FTIR and IASI were also compared against the GEOS-Chem model, run at 2° by 2.5° resolution, to assess model performance and investigate correlation of the model output with local column measurements (FTIR) and measurements on a regional scale (IASI). Comparisons on a regional scale (domain spanning from 35°N to 53°N, and 93.75°W to 63.75°W) resulted in r = 0.62, and thus a coefficient of determination, which is indicative of the predictive capacity of the model, of r2 = 0.38, but comparing a single model grid point against the FTIR resulted in a poorer correlation, with r2 = 0.26, indicating that a finer spatial resolution is needed to adequately model the variability of NH3. This study also examines two case studies of NH3 enhancements due to biomass burning plumes, in August 2014 and May 2016. In these events, enhancements in both the total columns and surface NH3, were observed.

How to cite: Yamanouchi, S., Viatte, C., Strong, K., Jones, D. B. A., Clerbaux, C., Van Damme, M., Clarisse, L., and Coheur, P. F.: Multiscale observations of NH3 around Toronto, Canada, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10486, https://doi.org/10.5194/egusphere-egu2020-10486, 2020.

EGU2020-17924 | Displays | AS3.16

Utilizing satellite ammonia observations to better understand ammonia variability

Rui Wang, Xuehui Guo, Da Pan, Kang Sun, Fabien Paulot, Lieven Clarisse, Martin Van Damme, Simon Whitburn, Pierre-François Coheur, and Mark Zondlo

Ammonia (NH3) is a key precursor to fine particulate matter (PM2.5) and has remarkable impacts on air quality, climate, and ecosystem diversity. Satellite NH3 observations from the Infrared Atmospheric Sounding Interferometer (IASI) provide long-term measurements of ammonia globally since 2007 and have been validated by both ground based and airborne measurements. In this study, IASI Level 2 NH3 columns were oversampled at high-resolution (0.02°×0.02°) from 2008 to 2017 to yield monthly NH3 maps covering the two top agricultural exporting regions in the world, the contiguous U.S. (CONUS) and Europe. K-means clustering was applied to identify NH3 seasonality observations. The U.S. and Europe showed large temporal variabilities that differed by region and agricultural activities. For example, in the U.S., areas dominated by livestock waste emissions had peak NH3 column abundances in the summer, while cropland-dominated regions tended to have spring peak and sometimes a fall shoulder. We also compared IASI NH3 column amounts to NH3 surface concentrations provided by the Ammonia Monitoring Network (AMoN) in the CONUS. Since IASI provides column NH3 at ~ 9:30 LST while AMoN provides biweekly averaged surface NH3, different factors were examined to find out the most important factors for the comparison between the two datasets (spatial window, temporal coverage, data averaging). We found that IASI data temporal coverage of the 2-week AMoN sampling period was the key factor in improving correlations. The r value increased from 0.38 to 0.73 when at least 80% of the two-week AMoN period had concurrent satellite measurements within a 25 km radius of the site. Neglecting interannual variability, the r value of multiyear monthly averaged AMoN and IASI NH3 is 0.68, indicating the importance of temporal averaging. The good agreement between AMoN and IASI NH3 concentrations demonstrates the feasibility of utilizing satellite NH3 retrievals to better understand NH3 variability in these agricultural intensive regions. With the global coverage and long data record, satellite measurements are likely to be a cost-effective approach as a supplemental source of information for understanding NH3 variability, as well as guiding the locations of future sites within ground monitoring network. Finally, IASI NH3 spatiotemporal variabilities will be compared to AM3 model output with bottom-up emission inventory (Magnitude And Seasonality of Agricultural Emissions model for NH3, MASAGE_NH3).

How to cite: Wang, R., Guo, X., Pan, D., Sun, K., Paulot, F., Clarisse, L., Van Damme, M., Whitburn, S., Coheur, P.-F., and Zondlo, M.: Utilizing satellite ammonia observations to better understand ammonia variability, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17924, https://doi.org/10.5194/egusphere-egu2020-17924, 2020.

EGU2020-11346 | Displays | AS3.16

Ammonia measurements from space with the Cross-track Infrared Sounder (CrIS): characteristics and applications

Mark Shephard, Chris McLinden, Enrico Dammers, Shailesh Kharol, Karen Cady-Pereira, Junhua Zhang, Shabtai Bittman, Evan Chow, and Evan White

Satellite data are helping to fill monitoring gaps in order to better inform decision makers and assess the impact of ammonia-related policies.  Presented is an overview demonstrating the current capabilities of the ammonia (NH3) data product derived from the CrIS satellite instrument for monitoring, air quality forecast model evaluation, dry deposition estimates, and emissions estimates.  This includes examples of daily, seasonal, and annual observations of CrIS ammonia that demonstrate the spatiotemporal variability of ammonia globally. These results further demonstrate the ability of CrIS to observe regional changes in ammonia concentrations, such as spring maximum values over agricultural regions from the fertilizing of crops.  Also shown is the importance contribution of wildfires, especially in regions where there is little or no agriculture sources, such as the northern latitudes in North America during summer.  Initial comparisons of CrIS NH3 satellite observations with air quality model simulations show that while there is general agreement on the spatial distribution of the anthropogenic hotspots, some areas are markedly different.  Some key findings are that dry deposition estimates of NH3 and NO2 from CrIS and the Ozone Monitoring Instrament (OMI), respectively, indicate that the NH3 dominates over most regions across North America. Their 2013 annual ratio shows NH3 accounting for ~82% and ~55 % of the combined reactive nitrogen dry deposition from these two species over Canada and the U.S.  Furthermore, we show the use of CrIS satellite observations to estimate annual and seasonal emissions over Concentrated Animal Feeding Operations (CAFOs).  These results are used to evaluate the seasonal and temporal emissions profiles used in bottom-up inventories over an agriculture hotspot, which are often underreported

How to cite: Shephard, M., McLinden, C., Dammers, E., Kharol, S., Cady-Pereira, K., Zhang, J., Bittman, S., Chow, E., and White, E.: Ammonia measurements from space with the Cross-track Infrared Sounder (CrIS): characteristics and applications, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11346, https://doi.org/10.5194/egusphere-egu2020-11346, 2020.

In this study, we used long-term (2003–2018) aerosol datasets acquired from Modern-Era Retrospective Analysis for Research and Applications, version 2 (MERRA-2),  along with two products of MODerate resolution Imaging Spectroradiometer (MODIS)/Terra and Aqua, Collection 6.1(C6.1) and Level 2 (L2), to conduct a comprehensive validation of Aerosol Optical Depth (AOD) using 9 AERONET sites with continuous observations for at least 1 year over the Eastern Mediterranean (EM) region. In order to reduce the number of missing cells from the satellite instruments and produce a near-daily dataset, the “Dark _Target _Deep_Blue_AOD _550_Combined” (DTDB) for both Tera and Aqua at 550 nm were merged, and named as MODIS AOD. The MODIS and MERRA-2 AODs at high spatial resolution (10 km × 10 km and 50 km× 62.5 km, respectively) were resampled to 100 km spatial grid, using the nearest neighbor interpolation technique to overlap the pixels of each other, and to match the full field view of AERONET.Using the 9 collected AERONET observations, the overall performance of the daily MODIS and MERRA-2 AODs over the EM region was validated first. The results showed a significant spatial agreement between these AODs and ground-based AOD, with an acceptable bias (For MODIS: R=0.71, RMSE=0.12, MAE= 0.09, MFE= 40.3% and IOA= 0.81), (For MERRA-2: R=0.75, RMSE=0.10, MAE= 0.06, MFE= 32.1% and IOA=0.83) Moreover, the monthly mean of these AODs were also validated using the monthly mean of the AERONET observations.  The results also showed significant spatial agreement, with an acceptable bias (For MODIS: R=0.78, RMSE=0.06, MAE= 0.05, MFE= 23.7% and IOA =0.79) and (For MERRA-2: R=0.83, RMSE=0.04, MAE= 0.03, MFE= 19.5% and IOA=0.86).The obvious over estimation of daily and monthly mean in the performance of MODIS AOD [i.e., (for daily; RMB=1.2, FGE=24.4%) and (for monthly; RMB=1.21, FGE=20.1%)], and the under estimation of MERRA-2 AOD [ i.e., (for daily; RMB=0.86, FGE=-9.34% ) and (for monthly RMB=0.87, FGE=-13.2%)], should not be overlooked. Due to these systematic under-over estimation error, a new merged AOD product of MERRA-2 and MODIS named as MERRA-2 MODIS Merged AOD (MMM) was generated, on daily time series data during the years 2003-2018 using the combination method. The MMM performance results not only indicated an agreement between the MMM AOD and AERNONT AOD higher than MODIS and MERRA-2 [ i.e., (for daily; R=0.77, RMSE=0.09, MAE= 0.05, MFE= 31.3% and IOA=0.86) and (for monthly; ( R=0.86, RMSE=0.04, MAE= 0.02, MFE= 14.03% and IOA=0.92)] , but also it showed an efficient estimation closer to line1:1 [ i.e., (for daily; RMB=0.99 and FGE=6.6%) and (for daily; RMB=1.03 and FGE=5.5%)]. 

How to cite: Shaheen, A.: A New MODIS C6.1 and MERRA-2 Merged Aerosol Products: Validation over The Eastern Mediterranean Region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-639, https://doi.org/10.5194/egusphere-egu2020-639, 2020.

Based on CALIPSO level 2 aerosol profile data and surface meteorological observation data,aerosol extinction feature in haze was statistically analysed along Huaihe River. Using backward trajectory and cluster analysis method, pollution sources were investigated. Then vertical feature mask data(VFM) and ERA Interim data were used to analyse aerosol type, vertical distribution characteristics and typical weather patterns. The results showed that aerosol extinction coefficient along Huaihe River was largest near the ground with extinction coefficient 0.53 and decreased obviously along with high. Local pollution was primary source with contribution ratio of 46%. Furth more, pollution transmission from Yangtze River delta pollution zone and Beijing-tianjin-hebei was very important for the pollution event in Huai River basin. During stagnant synoptic situation, thermal inversion layer caused by warm advection at 850 hPa resulted in local air pollution, which was composed of continental aerosol. Weak upward motion in the surface layer transported pollutants to 0.4~0.8 km, where aerosol concentration was higher than that on the ground. When subtropical anticyclone 5880 isopiestic line location moves northward and westward, Yangtze River delta was controlled by high pressure through whole layer of the atmosphere, which lead to polluted dust aerosol accumulation. Due to downdraft, extinction effect was strongest near surface and decreased with height. In the early stage of cold air south down, cold north-west airstream caused by cold advection at 850 hPa brought Beijing-tianjin-hebei pollution to Huai River basin. Polluted continental aerosol and dust aerosol was main type of pollutants. The transport height of aerosols may be higher than 2 km with maximum transport being 1~2 km.

How to cite: yu, C.: The analysis of aerosol type and vertical distribution characteristics along Huaihe River based on CALIOP satellite measuring, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6903, https://doi.org/10.5194/egusphere-egu2020-6903, 2020.

EGU2020-3067 | Displays | AS3.16

Remote Sensing of Particulate Matter Air Quality using Geostationary and low earth orbiting satellite data

Sundar Christopher, Zhixin Xue, and Pawan Gupta

Satellite imagery over the last several decades have provided spectacular views of dust storms, biomass burning smoke, and pollution aerosols near and far downwind of source regions. However, the effect on tropospheric aerosols near the surface is perhaps the most pressing issue, especially PM2.5 which is particulate matter with aerodynamic diameters less than 2.5 µm. In fact, the Global Burden of Disease (GBD) project of the Institute for Health Metrics and Evaluation (IHME) ranks ambient PM2.5 as the 6th-highest risk factor for early death. Also, the World Health Organization assessments indicate that more than 2 million deaths occur each year due to outdoor and indoor air pollution and more than half of this population lives in developing nations. Traditionally, PM2.5 is measured from ground-based instruments such as the Tapered Element Oscillating Microbalance (TEOM). Even though some nations have a good network of ground monitors they still cannot provide adequate coverage especially in regions that are not well populated. In most countries, monitoring is probably not a priority and measurements could vary from non-existent to very few monitors although recently there is a proliferation of low-cost sensors. However, it is indeed promising that the number of ground monitors have increased over the last decade and there are nearly 4000 monitors across the globe for which data are publicly available. The research community has long recognized that ground monitors alone are inadequate for providing a global picture of PM2.5 especially since a vast of population centers have no ground-monitoring networks. Therefore, other data sets are used to fill the gaps and complement the ground monitors. Satellite data by far offers the best solution for monitoring global air quality at spatial and temporal scales that are not possible by other means. Converting the column AOD to surface PM2.5 has been a subject of numerous studies and methods range from simple liner regression to complex statistical methods and machine learning approaches. We will use low earth orbiting and geostationary data sets coupled with meteorological data sets and ancillary information to demonstrate the progress and potential of satellite data for estimating PM2.5.

 

How to cite: Christopher, S., Xue, Z., and Gupta, P.: Remote Sensing of Particulate Matter Air Quality using Geostationary and low earth orbiting satellite data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3067, https://doi.org/10.5194/egusphere-egu2020-3067, 2020.

EGU2020-8354 | Displays | AS3.16

Impact of emissions and long-range transport on Air Quality in Delhi

Ailish Graham, Richard Pope, Martyn Chipperfield, and Ellen Stirling

Delhi is the world’s most polluted capital city, with annual mean concentrations of PM2.5, O3 and NO2 well above the safe legal limits for Europe. Exposure to these pollutants over short and long-time scales is associated with increases in diseases such as heart disease, stroke and lower respiratory tract infections. Local NO2 concentrations vary by month and season and are controlled by both emissions and meteorology. Locally, vehicle pollution contributes to 67% of the total air pollution load and 48% of NOx. The vehicle population has increased substantially in recent years due to an increase in the number of vehicles travelling into Delhi each day from surrounding areas. High pollution episodes, especially in winter, also contribute to the high annual mean observed. This may be due to the trapping of pollutants in a shallow, stable boundary layer or through the long-range transport of pollutants from surrounding regions to Delhi under favourable wind directions. However, the relative contribution of local vs regional emissions has not been quantified previously. This inhibits the introduction of targeted policies to reduce concentrations in the city.

We use observational datasets to quantify the relative contribution of local and regional emissions to local NO2 air quality in Delhi rather than running a computationally expensive atmospheric chemistry transport model (Stirling et al., 2020). We combine satellite data from the TROPOMI instrument on the Sentinel 5 – Precursor (S5P) platform with back-trajectories, from the Reading Offline Trajectory Model (ROTRAJ). This allows us to investigate how different wind directions affect the relative contributions of local and regional NO2 pollution to Delhi NO2. We will then quantify the contribution of different regions and sectors to NO2 in Delhi by combining the back-trajectories with a high resolution emission inventory for India and Delhi. This method also allows us to consider future emission control scenarios and quantify their impacts on air quality in Delhi.

 

How to cite: Graham, A., Pope, R., Chipperfield, M., and Stirling, E.: Impact of emissions and long-range transport on Air Quality in Delhi, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8354, https://doi.org/10.5194/egusphere-egu2020-8354, 2020.

EGU2020-9908 | Displays | AS3.16

The potential of satellite data to calculate the global OH distribution using simplified steady state approximations

Matilda Pimlott, Martyn Chipperfield, Richard Pope, Brian Kerridge, and Richard Siddans

The hydroxyl radical (OH) is one of the most important species in atmospheric chemistry. It plays a dominant role in the oxidation of many other species in the troposphere, such as anthropogenic pollutants. Direct in-situ and satellite measurements of OH are scarce due to its short lifetime (around 1 second) and low abundance. Other indirect methods of inferring global mean OH have been established, such as using methyl chloroform as a tracer. However because of its recent phase out there is a demand for another method of calculating the global OH abundance. It is therefore useful to explore indirect methods for calculating OH. In particular, global satellite data can provide a means for estimating mean OH within large atmospheric regions. An improved understanding of the global distribution of OH will allow a better understanding of atmospheric chemistry, especially the distributions of anthropogenic pollutants.  

Due to the short lifetime of OH, a steady-state approximation can be used to model its concentration. This allows the OH distribution to be calculated using a simple equation and the accuracy of the estimate depends on the number of source/sink terms which can be included in the equation. In this work, a steady state approximation has been applied to the global OH budget as defined in the TOMCAT 3-D model. The full steady-state equation (based on all reactions in the model) has been simplified in various ways to include only the major sources and sinks of OH that can be observed directly by satellite, such as carbon monoxide (CO), methane (CH4), water vapour (H2O) and ozone (O3). 

Recent satellite observations of these species is then applied to the steady-state approximation to derive an estimate of the global OH distribution. We use the 3-D model to determine where the simplified steady-state approximation is likely to be most valid. The overall potential of this method to calculate an accurate OH distribution, bearing in mind satellite observation errors, is discussed. 

How to cite: Pimlott, M., Chipperfield, M., Pope, R., Kerridge, B., and Siddans, R.: The potential of satellite data to calculate the global OH distribution using simplified steady state approximations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9908, https://doi.org/10.5194/egusphere-egu2020-9908, 2020.

EGU2020-4459 | Displays | AS3.16

spatial and temporal changes in SO2 over China in the recent decade and the Impacts of emissions and meteorology

Ting Wang, Pucai Wang, Nicolas Theys, Dan Tong, François Hendrick, Qiang Zhang, and Michel Van Roozendael

The spatial and temporal changes of SO2 regimes over China during 2005 to 2016 and their associated driving mechanism are investigated based on a state-of-the-art retrieval dataset. Climatological SO2exhibits pronounced seasonal and regional variations, with higher loadings in wintertime and two prominent maxima centered in the North China Plain and the Cheng-Yu District. In the last decade, overall SO2 decreasing trends have been reported nationwide, with spatially varying downward rates according to a general rule—the higher the SO2 loading, the more significant the decrease. However, such decline is in fact not monotonic, but instead four distinct temporal regimes can be identified by empirical orthogonal function analysis. After an initial rise at the beginning, SO2 in China undergoes two sharp drops in the periods 2007-2008 and 2014-2016, amid which 5-year moderate rebounding is sustained. Despite spatial coherent behaviors, different mechanisms are tied to North China and South China. In North China, the same four regimes are detected in the time series of emission that is expected to drive the regime of atmospheric SO2, with a percentage of explained variance amounting to 81%. In contrast to North China, SO2 emissions in South China exhibit a continuous descending tendency, due to the coordinated cuts of industrial and household emissions. As a result, the role of emissions only makes up about 45% of the SO2 variation, primarily owing to the decoupled pathways of emission and atmospheric content during 2009 to 2013 when the emissions continue to decline but atmospheric content witnesses a rebound. Unfavorable meteorological conditions, including deficient precipitation, weaker wind speed and increased static stability, outweigh the effect of decreasing emissions and thus give rise to the rebound of SO2 during 2009 to 2013.

How to cite: Wang, T., Wang, P., Theys, N., Tong, D., Hendrick, F., Zhang, Q., and Van Roozendael, M.: spatial and temporal changes in SO2 over China in the recent decade and the Impacts of emissions and meteorology, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4459, https://doi.org/10.5194/egusphere-egu2020-4459, 2020.

EGU2020-1757 | Displays | AS3.16

Remote sensing of air pollution from satellite and MAX-DOAS network in China

Cheng Liu, Qihou Hu, Haoran Liu, Chengxin Zhang, Wei Tan, Chengzhi Xing, Wenjing Su, Xiangguang Ji, and Hua Lin

With the fast industrialization and urbanization in China, environmental pollution has become more serious and complex. Precise and real-time monitoring is the prerequisite for knowing the distribution characteristics and the evolution mechanism of the atmospheric pollutants. Over the last few years, we have successfully monitored atmospheric composition by using remote sensing from different platform, including satellite, ground and mobile vehicle, which have been validated to have good performance.

Remote sensing by satellite can describe the global distribution of various pollutants, which can also locate the emission point sources, such as factories etc. Ground-based MAX-DOAS monitor the vertical evolutions of these trace gases and aerosol at a fixed position, the column density of pollutants was divided into different layers, so we could detect transport plum in all altitude. Up to now, we have established a notional monitoring network with more than 30 MAX-DOAS, which could provide sufficient validation for satellite products and conduct scientific researches. Combining these two methods, which could provide precise horizontal and vertical distribution of pollutant, we could get a 3-D distribution of pollutants and the transport flux. Here, we analyzed the spatial distribution and temporal trends of satellite-observed air pollutants over eastern China during 2005–2017. We found significant decreasing trends in NO2 and SO2 since 2011 over most regions. Furthermore, we used the generalized additive models to clarify the relative contribution of local emissions and meteorological conditions. Our results show that meteorological determines daily changes in pollutants, while long-term, inter annual changes are determined by emissions. Emission reduction has played a decisive role in the recent reduction of the pollution!

How to cite: Liu, C., Hu, Q., Liu, H., Zhang, C., Tan, W., Xing, C., Su, W., Ji, X., and Lin, H.: Remote sensing of air pollution from satellite and MAX-DOAS network in China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1757, https://doi.org/10.5194/egusphere-egu2020-1757, 2020.

EGU2020-9325 | Displays | AS3.16

Validation of tropospheric NO2 columns measurements from GOME-2, OMI and TROPOMI using MAX-DOAS and direct-sun network observations with focus on dilution effects

Gaia Pinardi, Michel Van Roozendael, François Hendrick, Nicolas Theys, Steven Compernolle, Jean-Christopher Lambert, Pieter Valks, Song Liu, Folkert Boersma, and Henk Eskes and the NIDFORVAL NO2 team

Ground-based remote sensing MAX-DOAS and Pandora direct-sun instruments measuring in the UV-Vis spectral region are nowadays widely used to monitor atmospheric NO2 columns. Owing to the multiple geometries used, these techniques can differentiate total, tropospheric and stratospheric NO2 content and  therefore provide an appropriate source of correlative data for the validation of satellite instruments such as GOME-2, OMI and TROPOMI.

In this study we combine ground-based remote sensing correlative measurements available from over 40 sites distributed worldwide to address the validation of GOME-2, OMI and TROPOMI data products. For GOME-2, we concentrate on the GDP operational product generated within the EUMETSAT AC SAF project and on the climate data record generated within the EU QA4ECV project, while for OMI we address both the TEMIS and QA4ECV data products. Regarding TROPOMI, the operational OFFL product is considered. To derive tropospheric NO2 columns from direct-sun total NO2 data, we use estimates of the stratospheric contribution available from each satellite data product.

A negative bias is generally found between the different satellite data products and the ground-based tropospheric NO2 measurements, which is mostly prominent in urban sites characterized by strong localized emission sources (up to about -32% to -45%, e.g. for OMI TEMIS and GOME-2 GDP vs MAX-DOAS ensemble). In an attempt to quantify and correct for the horizontal dilution happening around urban stations (due to diffusion and transport and to the spatial averaging of high resolution structures), we use high-resolution gridded NO2 maps obtained from one year of QA4ECV data. Results from applying this dilution correction show a clear improvement of the agreement between GOME-2 and OMI data at polluted urban locations. Further, the impact of the satellite ground pixel size (GOME-2 40x80km², OMI 13x24km²) and site location is investigated.

How to cite: Pinardi, G., Van Roozendael, M., Hendrick, F., Theys, N., Compernolle, S., Lambert, J.-C., Valks, P., Liu, S., Boersma, F., and Eskes, H. and the NIDFORVAL NO2 team: Validation of tropospheric NO2 columns measurements from GOME-2, OMI and TROPOMI using MAX-DOAS and direct-sun network observations with focus on dilution effects, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9325, https://doi.org/10.5194/egusphere-egu2020-9325, 2020.

EGU2020-8150 | Displays | AS3.16

Impact of albedo and cloud retrievals on the NO2 tropospheric column derived from Sentinel-5P TROPOMI observations

Henk Eskes, Maarten Sneep, Jos van Geffen, Folkert Boersma, Ping Wang, and Pepijn Veefkind

Sentinel-5P, with the TROPOMI instrument, was launched in October 2017 and is providing unique high-quality and high-resolution (5 km) observations of trace gas pollutants with a daily global coverage. In our contribution we will discuss the retrieval of nitrogen dioxide (NO2). A major contributions to the total uncertainty of these measurements are the TROPOMI retrievals of cloud fraction and effective cloud pressure (or altitude). Several cloud retrieval algorithms have been implemented, deriving cloud height information from the near-infrared O2-A band, O2-B band or the O2-O2 absorption feature near 477nm. In our presentation we will show the importance of a consistent treatment of clouds and albedo as input for the retrieval radiative transfer calculations. The impact of the different cloud products on the retrieved NO2 is demonstrated for a new implementation of the FRESCO O2-A band cloud retrieval algorithm and an implementation of the O2-O2 retrievals for TROPOMI. A recipe to make optimal use of the available cloud information is presented.

How to cite: Eskes, H., Sneep, M., van Geffen, J., Boersma, F., Wang, P., and Veefkind, P.: Impact of albedo and cloud retrievals on the NO2 tropospheric column derived from Sentinel-5P TROPOMI observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8150, https://doi.org/10.5194/egusphere-egu2020-8150, 2020.

EGU2020-10604 | Displays | AS3.16

Assessment of the quality of TROPOMI high-spatial-resolution NO2 data products

Xiaoyi Zhao, Debora Griffin, Vitali Fioletov, Chris McLinden, Alexander Cede, Martin Tiefengraber, Moritz Müeller, Kristof Bognar, Kimberly Strong, Folkert Boersma, Henk Eskes, Jonathan Davies, Akira Ogyu, and Sum Chi Lee

The TROPOspheric Monitoring Instrument (TROPOMI) on-board the Sentinel-5 Precursor satellite (launched on 13 October 2017) is a nadir-viewing spectrometer measuring reflected sunlight in the ultraviolet, visible, near-infrared, and shortwave infrared spectral ranges. The measured spectra are used to retrieve total columns of trace gases, including nitrogen dioxide (NO2). In this study, Pandora NO2 measurements made at three sites located in or north of the Greater Toronto Area (GTA) are used to evaluate the TROPOMI NO2 data products, including the standard Royal Netherlands Meteorological Institute (KNMI) NO2 data product and a research data product developed by Environment and Climate Change Canada (ECCC) using a high-resolution regional air quality forecast model (used in the airmass factor calculation).

TROPOMI pixels located upwind and downwind from the Pandora sites were analyzed using a new wind-based validation method that increases the number of coincident measurements by about a factor of five compared to standard techniques. Using this larger number of coincident measurements, this work shows that both TROPOMI and Pandora instruments can reveal detailed spatial patterns (i.e., horizontal distributions) of local and transported NO2 emissions, which can be used to evaluate regional air quality changes. The TROPOMI ECCC NO2 research data product shows improved agreement with Pandora measurements compared to the TROPOMI standard tropospheric NO2 data product, demonstrating the benefit of using the high-resolution regional air quality forecast model to derive NO2 airmass factors.

How to cite: Zhao, X., Griffin, D., Fioletov, V., McLinden, C., Cede, A., Tiefengraber, M., Müeller, M., Bognar, K., Strong, K., Boersma, F., Eskes, H., Davies, J., Ogyu, A., and Lee, S. C.: Assessment of the quality of TROPOMI high-spatial-resolution NO2 data products, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10604, https://doi.org/10.5194/egusphere-egu2020-10604, 2020.

EGU2020-10121 | Displays | AS3.16

Variability of nitrogen oxide lifetimes and emission fluxes estimated by Sentinel-5P observations

Kezia Lange, Andreas Richter, and John P. Burrows

Satellite observations of the high-resolution instrument TROPOMI on Sentinel-5P make it possible to measure nitrogen dioxide (NO2) at city level and even to quantify the variability of NOx emissions and lifetimes on a seasonal and daily basis.
NO2 is an air pollutant and especially in cities of particular importance due to the large number and strength of emission sources in combination with people living nearby exposing their health to the polluted air. To quantify nitrogen oxide emissions and lifetimes with their variability in space and time, satellite data is especially suited as it provides daily global coverage and large number of measurements. The TROPOspheric Monitoring Instrument (TROPOMI) on Sentinel-5P, launched in October 2017, provides, thanks to its higher spatial resolution when compared to previous satellite instruments, the possibility of detailed investigations on lifetimes and emissions of air pollutants.
Two years of TROPOMI NO2 data with a spatial resolution of up to 3.5 km x 5.5 km together with ECMWF ERA5 wind data are analyzed. The NO2 data around a source is linked to the ERA5 wind data and rotated to a uniform wind direction to get clear emission patterns. Out of these two-dimensional maps of the mean NO2 distribution, one dimensional line densities are calculated by integration across wind direction. Lifetimes and emission fluxes are calculated for different NOx sources such as cities and power plants distributed over the world. They are compared among each other and to bottom-up emission inventories. Seasonal variability and weekday versus weekend effects in lifetimes and emissions are discussed.

How to cite: Lange, K., Richter, A., and Burrows, J. P.: Variability of nitrogen oxide lifetimes and emission fluxes estimated by Sentinel-5P observations , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10121, https://doi.org/10.5194/egusphere-egu2020-10121, 2020.

EGU2020-13877 | Displays | AS3.16

What can we learn from TROPOMI observations of biomass burning NO2?

Andreas Richter, Kezia Lange, Miriam Latsch, and John P. Burrows

Most of the anthropogenic emissions of nitrogen oxides (NOx = NO2 + NO) are linked to burning of fossil fuels for energy production, transportation or industrial processes. However, biomass burning and in particular large wild fires in tropical and sub-tropical regions can also be important sources of nitrogen oxides, at least locally. Depending on the size of the fires, particles and gases are lifted into the free troposphere and even higher, increasing the atmospheric lifetime of NOx in these plumes and enabling long range transport.

The TROPOMI instrument on board of Sentinel 5 precursor (S5p) is a nadir viewing UV/vis imaging spectrometer launched in October 2017 and operationally providing data since July 2018. One of the main products that can be retrieved from TROPOMI spectra is tropospheric and total column NO2. Compared to previous UV/vis satellite instruments such as GOME, SCIAMACHY, GOME2 and OMI, TROPOMI has a higher spatial resolution of 3.5 x 5.5 km2. This reduced foot print size enables detection and evaluation of more localised sources such as individual fires and their plumes, and better separation of different contributions to the overall NO2 loading.

In this presentation, IUP-Bremen TROPOMI NO2 retrievals are evaluated for biomass burning signatures during 2018 and 2019, two years with very different burning seasons. The amounts and spatial distributions of NO2 from fires are compared between the two years and between different fire regions, and their impact on regions downwind of the sources is investigated.

How to cite: Richter, A., Lange, K., Latsch, M., and Burrows, J. P.: What can we learn from TROPOMI observations of biomass burning NO2?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13877, https://doi.org/10.5194/egusphere-egu2020-13877, 2020.

EGU2020-11790 | Displays | AS3.16

Reconstruction of spatially continuous OMI tropospheric NO2 columns over China by combining GOME-2 products

Qin He, Kai Qin, Diego Loyola, Ding Li, Jincheng Shi, and Yong Xue

Measurements of nitrogen dioxide (NO2) are essential for understanding air pollution and evaluating its impacts, and satellite remote sensing is an essential approach for obtaining tropospheric NO2 columns over wide temporal and spatial ranges. However, Ozone Monitoring Instrument (OMI) onboard Aura is affected by a loss of spatial coverage (around one-third of 60 viewing positions) commonly referred to as row anomaly since June 25th, 2007, and especially after June 5th, 2011. Global Ozone Monitoring Experiment-2 (GOME-2) onboard MetOp-A/B provides data with a maximum swath width of 1920 km, and it needs one and a half days to cover the globe. Therefore, it is challenging to obtain diurnal spatially continuous vertical column densities (VCDs) of tropospheric NO2, which is limited by the performance of the instruments. Besides, the presence of clouds generates numerous missing and abnormal values that affect the application of VCDs data. To fill data gaps due to the above two reasons, this study proposes a framework for reconstructing OMI (afternoon overpass) tropospheric NO VCDs over China by combining GOME-2 (morning overpass) products. First, we investigated the ground-based hourly NO2 concentration to characterize the diurnal variations, thus deriving the underlying factors that cause the difference between morning VCDs and afternoon ones. Then, the eXtreme Gradient Boosting (XGBoost) method was applied to estimate the missing values of OMI QA4ECV tropospheric NO2 VCDs from GOME-2 GDP offline products and other ancillary variables. The spatial coverage of OMI grids (binned to 0.25°) over China from 2015 to 2018 increased from 22% to 63% averagely. Furthermore, for those grids that are null in both products, we utilized an adaptive weighted temporal fitting method to fill missing data that the previous step produced. The reconstructed data set shows spatial and temporal patterns that are coherent with the adjacent areas. Our approach has great potential for reconstructing spatially continuous tropospheric NO2 columns, which are critical for daily air quality monitoring.

How to cite: He, Q., Qin, K., Loyola, D., Li, D., Shi, J., and Xue, Y.: Reconstruction of spatially continuous OMI tropospheric NO2 columns over China by combining GOME-2 products, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11790, https://doi.org/10.5194/egusphere-egu2020-11790, 2020.

EGU2020-19775 | Displays | AS3.16

Evaluating Tropospheric Nitrogen Dioxide over South and East Asia in UKCA using OMI Satellite data

Alok Pandey, David Stevenson, Alcide Zhao, Richard Pope, and Krishan Kumar

We compare tropospheric nitrogen dioxide (NO2) in the United Kingdom Chemistry and Aerosol (UKCA) model v11.0 with satellite measurements from NASA Earth Observing System (EOS) Aura satellite Ozone Monitoring Instrument (OMI) troposphere NO2 data over South and East Asia (S/A). UKCA is the atmospheric composition component of the UK Earth System Model (UKESM). UKCA has been run on ARCHER (UK National Supercomputing Service) with (a) nudged hourly outputs over S/A as well as monthly outputs globally and (b) free run monthly globally output for 2005-2015. OMI satellite Averaging Kernels (AK) has been applied on the model hourly outputs for accurate model satellite comparison for 2005 - 2015. OMI and UKCA data has been analysed spatially and temporally. Background UKCA and OMI tropospheric column NO2 typically ranges between 0-3 x 1015 molecules/cm2. Model is overestimating tropospheric NO2 over the S/A predominantly during winter by a factor of ~2.5. 

How to cite: Pandey, A., Stevenson, D., Zhao, A., Pope, R., and Kumar, K.: Evaluating Tropospheric Nitrogen Dioxide over South and East Asia in UKCA using OMI Satellite data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19775, https://doi.org/10.5194/egusphere-egu2020-19775, 2020.

EGU2020-16968 | Displays | AS3.16

TROPOMI/S5P MLS/BASCOE tropospheric ozone product and TROPOMI observation of ozone precursors

Klaus-Peter Heue, Diego Loyola, Fabian Romahn, Walter Zimmer, Christophe Lerot, Michel van Roozendael, Isabelle de Smedt, Nicolas Theys, Simon Chabrillat, Quentin Errera, Yves Christophe, Henk Eskes, and Jos van Geffen

Sentinel 5 Precursor (S5P) satellite was launched into a polar orbit in October 2017, carrying the TROPOMI instrument. S5P has sun synchronous orbit with an equator crossing time of 13:30 LT; TROPOMI achieves an almost daily coverage, due to the wide swath width of 2600 km. Based on the observed spectra in the UV-Vis range the trace gases ozone, formaldehyde and nitrogen dioxide are retrieved. We developed a research tropospheric ozone product based on the operational total column from S5P and the stratospheric column obtained from Aura MLS assimilated ozone profiles using the BASCOE system. The enhanced tropospheric ozone columns are observed at several places and often collocate with locale enhancements of NO2 and HCHO. Both these trace gases are known to be involved in the tropospheric ozone formation.

The tropospheric ozone product will be briefly presented; the focus will be on large scale enhancements of tropospheric ozone and collocated HCHO and NO2 observations. In addition examples of enhancemnets of HONO or Glyoxal may be stduied. The large fires in the Amazonian forest and Australia cause an enhancement compared to previous years. Over the southern US both HCHO and tropospheric ozone are enhanced in summer time. Some transport of ozone and its’ precursors can be found in East Asia.

How to cite: Heue, K.-P., Loyola, D., Romahn, F., Zimmer, W., Lerot, C., van Roozendael, M., de Smedt, I., Theys, N., Chabrillat, S., Errera, Q., Christophe, Y., Eskes, H., and van Geffen, J.: TROPOMI/S5P MLS/BASCOE tropospheric ozone product and TROPOMI observation of ozone precursors, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16968, https://doi.org/10.5194/egusphere-egu2020-16968, 2020.

EGU2020-20978 | Displays | AS3.16

Validation of GEMS L2 products using ground-based remote sensing data including PANDORA measurements

KangHo Bae, Chang-Keun Song, Sang-Seo Park, Sang-Woo Kim, Jhoon Kim, Chang-Seok Lee, Jong-Min Yoon, and Limseok Chang

Launch of the Geostationary Environmental Monitoring Spectrometer (GEMS) is scheduled in early 2020 to support public service and science related to air quality and climate by providing diurnal variation of concentrations of trace gases and aerosols with high spatial/temporal resolution over Asian region. We will introduce GEMS validation methodology in parallel with a strategy for integration of existed independent measurements like as low-orbit satellite, ground-based remote sensing, and ambient surface observation data. As collections of nearly real-time and quality-assured data from existing ground-based networks are still in great needs for GEMS validation, efforts to expand observational infra-structure have been going on. Currently, two PANDORA instruments started to be in operation at Seoul and Ulsan in Korea, and PANDORA Asian Network initiated by NIER, Korea will be expanded into South East Asian region beyond Korea, China and Japan in addition. In this study, we especially try to validate the initial L2 product of GEMS gathered during IOT period by utilizing PANDORA data and other ground remote sensing data as well so that availability and feasibility of those ground observations could be assessed for GEMS validation.

 

Keywords: GEMS validation, ground-based remote sensing data, PANDORA

How to cite: Bae, K., Song, C.-K., Park, S.-S., Kim, S.-W., Kim, J., Lee, C.-S., Yoon, J.-M., and Chang, L.: Validation of GEMS L2 products using ground-based remote sensing data including PANDORA measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20978, https://doi.org/10.5194/egusphere-egu2020-20978, 2020.

The Geostationary Environment Monitoring Spectrometer (GEMS) will be launched in February 2020 and will provide hourly observations of atmospheric compositions in the daytime. Prior to the GEMS launch, we explore an application of GEMS data as constraints for estimating anthropogenic volatile organic compound (AVOC) emissions in South Korea using formaldehyde (HCHO) vertical column densities observations from the Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) onboard the B200 aircraft during the KORUS-AQ campaign. Our top-down estimates of total AVOC emissions are higher by a factor of four over the petrochemical industries compared to the bottom-up emissions. However, the national AVOC emissions from the top-down estimates are by 37% lower than those of the bottom-up emission inventory in South Korea. We also show that hourly column observations of HCHO can improve not only the total magnitude of AVOC emissions but also their diurnal variation, which is poorly constrained and used in air quality models. Our hourly estimates of AVOC emissions may, thus, improve air quality model simulations in which the simulated ozone sensitivity to AVOC emission changes are also investigated.

How to cite: Park, R., Kwon, H.-A., and Oak, Y.: Preview of the future application of the environmental geo-satellites data using aircraft platform: Estimation of anthropogenic VOC emissions from formaldehyde columns, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12587, https://doi.org/10.5194/egusphere-egu2020-12587, 2020.

EGU2020-20243 | Displays | AS3.16 | Highlight

Large VOC enhancements in recent massive wildfires observed from space

Bruno Franco, Lieven Clarisse, Juliette Hadji-Lazaro, Daniel Hurtmans, Gilles Lecomte, Solène Turquety, Cathy Clerbaux, and Pierre-François Coheur

Massive wildfires erupted in Amazonia and through the subarctic region in summer 2019, and in Australia in winter 2019-2020. During such biomass burning events, sizeable amounts of volatile organic compounds (VOCs) can be emitted directly by the fires as well as rapidly produced in plumes via the degradation of short-lived gas precursors. The VOCs have a significant impact on tropospheric chemistry by, e.g., affecting the oxidative capacity of the atmosphere. Nadir-viewing infrared sensors onboard meteorological satellites provide global and spatially dense observations that are very useful to track biomass burning events throughout the globe and to provide trace gas quantification in fire plumes.

We apply a general retrieval framework, based on an artificial neural network, to derive the integrated abundance (total column) of several major VOCs from the infrared radiance spectra recorded by IASI (Infrared Atmospheric Sounding Interferometer) embarked on the Metop platforms. Quasi-global distributions of methanol (CH3OH), formic (HCOOH) and acetic (CH3COOH) acids, PAN, acetone (CH3COCH3), acetylene (C2H2) and hydrogen cyanide (HCN) column abundance are produced twice-daily from the a.m. and p.m. overpasses of the satellite instrument. In particular, we use the IASI data to produce daily regional snapshots over biomass burning areas of interest and to quantify the VOC enhancements in the plumes from the recent Amazonian, Australian and subarctic wildfires. Finally, the abundance ratios of these VOCs to IASI carbon monoxide (CO) are presented and discussed.

How to cite: Franco, B., Clarisse, L., Hadji-Lazaro, J., Hurtmans, D., Lecomte, G., Turquety, S., Clerbaux, C., and Coheur, P.-F.: Large VOC enhancements in recent massive wildfires observed from space, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20243, https://doi.org/10.5194/egusphere-egu2020-20243, 2020.

An emission inverse modeling system to estimate wildfire smoke source strength, vertical distribution, and temporal variations by assimilating satellite observations with the HYSPLIT dispersion model for smoke forecasting has been built. In this so-called HEIMS-fire system, a cost function is defined to quantify the differences between the satellite smoke products and their model counterparts, weighted by the model and observation uncertainties. Smoke sources that minimize this cost function provide the optimal smoke emission estimates. It has been successfully applied to hindcast smoke distribution during a Southeast US wildfire event in 2016 using GOES GASP products. A new Advanced Baseline Imager (ABI) sensor onboard GOES-16 has become fully operational since December 2017. The ABI smoke products have better spatial and temporal resolutions than those from its predecessors. In this study, the ABI observations during the 2018 Camp Fire event in California USA are tested in the HEIMS-fire system. Hindcasts using the emission estimates by the HEIMS-fire system will be performed. Comparison between this new emission estimation system and other emission estimates will be conducted. In addition, the impact of additional observations including the tailored ones will be investigated.

How to cite: Chai, T., Kim, H., Stein, A., Tong, D., Li, Y., and Kondragunta, S.: A case study of the 2018 Camp Fire event using HYSPLIT-based emission inverse modeling system with GOES Advanced Baseline Imager (ABI) observations and other measurements for wildfire smoke forecasts, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12525, https://doi.org/10.5194/egusphere-egu2020-12525, 2020.

EGU2020-21303 | Displays | AS3.16

A global perspective on Bromine monoxide composition in volcanic plumes derived from S5-P/TROPOMI

Simon Warnach, Holger Sihler, Christian Borger, Nicole Bobrowski, Stefan Schmitt, Moritz Schöne, Steffen Beirle, Ulrich Platt, and Thomas Wagner

Bromine monoxide (BrO) is a halogen radical altering the atmospheric ozone chemistry, e. g. in polar regions, the stratosphere as well as volcanic plumes. In particular, the molar bromine to sulphur ratio in volcanic gas emissions is characteristic to the magmatic composition of a volcano.

The high spatial resolution of S5-P/TROPOMI (up to 3.5x5.5km²) and daily coverage offer the potential to detect BrO even during minor eruptions and determine BrO/SO2 ratios during continuous passive degassing.

Here, we present a global overview of BrO/SO2 molar ratios in volcanic plumes derived from a systematic investigation of two years (2018 and 2019) of TROPOMI data.

We retrieved BrO column densities as well as SO2 column densities using Differential Optical Absorption Spectroscopy (DOAS) and calculated mean BrO/SO2 molar ratios for each volcano. The calculated BrO/SO2 molar ratios differ strongly between different volcanoes ranging between several 10-5 and 10-4. The data are classified and discussed with regard to several volcanic parameters –  more specific the volcanic region, volcano type (i. e. subduction zone, hotspot etc.) as well as activity level.

How to cite: Warnach, S., Sihler, H., Borger, C., Bobrowski, N., Schmitt, S., Schöne, M., Beirle, S., Platt, U., and Wagner, T.: A global perspective on Bromine monoxide composition in volcanic plumes derived from S5-P/TROPOMI, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21303, https://doi.org/10.5194/egusphere-egu2020-21303, 2020.

EGU2020-20775 | Displays | AS3.16

Separating tropospheric and stratospheric BrO columns over the Arctic using TROPOMI data

Moritz Schöne, Holger Sihler, Simon Warnach, Christian Borger, Steffen Beirle, Thomas Wagner, and Ulrich Platt

Halogen radicals can drastically alter the atmospheric chemistry. In the polar regions, this is made evident, among others, by the almost complete destruction of boundary layer ozone during polar springs. These recurrent episodes of catalytic ozone depletion, referred to as Ozone Depletion Events (ODE), are caused by enhanced concentrations of reactive bromine compounds. The proposed mechanism by which these are released into the atmosphere is called bromine explosions -  reactive bromine is formed autocatalytically from the condensed phase. Enhanced bromine oxide concentrations have been observed by ground-based measurements as well as from aircraft and satellite, where the large spatial coverage allows to study the spatial extent of the phenomenon and its correlation with meteorological data as well as climate change.

The spatial resolution of S-5P/TROPOMI of 3,5 km x 7 km allows improved localization of these events and to resolve finer structures compared to previous satellite measurements. Together with the better than daily coverage over the polar regions, this allows investigations of the spatio-temporal variability of enhanced BrO levels and their relation to different possible bromine sources and release mechanisms.

We present tropospheric BrO column densities retrieved from TROPOMI data using Differential Optical Absorption Spectroscopy (DOAS). Building on methods from statistical data analysis and machine learning, we separate the tropospheric partial column from the total column using solely data (BrO, O3 and NO2) measured by satellite. The observations are discussed with regards to sea ice coverage and meteorological influences.

How to cite: Schöne, M., Sihler, H., Warnach, S., Borger, C., Beirle, S., Wagner, T., and Platt, U.: Separating tropospheric and stratospheric BrO columns over the Arctic using TROPOMI data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20775, https://doi.org/10.5194/egusphere-egu2020-20775, 2020.

EGU2020-17183 | Displays | AS3.16

Retrieval quality and column densities of iodine monoxide from multiple satellite sensors – from SCIAMACHY to TROPOMI

Anja Schoenhardt, Andreas Richter, Anne-Marlene Blechschmidt, Astrid Bracher, and John P. Burrows

Iodine compounds are mainly emitted from the oceans through organic and inorganic pathways followed by photolysis and reaction with ozone to create iodine monoxide (IO) molecules. Emission sources of iodine species include the sea surface, phytoplankton and macroalgae as well as volcanic eruptions. IO is an indicator of active iodine chemistry, which may be relevant for tropospheric composition due to its impact on ozone levels, the NO/NO2 ratio and potential particle formation. Rapid changes in Polar sea ice coverage and conditions may have an impact on iodine levels in Polar Regions with respective consequences for tropospheric composition in the Arctic and Antarctic.

Differential Optical Absorption Spectroscopy is used to retrieve IO column densities from various satellite sensors, including SCIAMACHY (2002 to 2012), GOME-2 (since 2006) and TROPOMI (since 2017). Case studies are presented with a focus on the intercomparison of the retrieval quality and IO column densities from the applied instruments. Previous satellite studies have shown slightly enhanced IO column densities mainly above the Antarctic Region and within one occasion of a strong volcanic plume, while IO column densities in the Arctic remain mostly below the detection limit of the applied instruments.

Reported column densities of tropospheric IO, as previously measured from ground and from space, are fairly small and close to the detection limits of current and former satellite sensors. Optical depth values of IO absorption are on the order of a few times 10-4. Individual satellite spectra allow trace gas retrievals with residual RMS values which lie around and often above the expected IO absorption optical depth. This is a challenge for the identification of optimal retrieval settings, especially the choice of an adequate wavelength window. Several aspects for quality control are discussed. In addition to the immediate retrieval RMS, the IO standard deviation in areas with expected low IO absorption, consistency checks with other retrieval parameters as well as plausibility of IO column density results are considered.

How to cite: Schoenhardt, A., Richter, A., Blechschmidt, A.-M., Bracher, A., and Burrows, J. P.: Retrieval quality and column densities of iodine monoxide from multiple satellite sensors – from SCIAMACHY to TROPOMI, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17183, https://doi.org/10.5194/egusphere-egu2020-17183, 2020.

EGU2020-12230 | Displays | AS3.16

A new approach to HDO/H2O ratio profile retrieval in the atmosphere from TANSO-FTS/GOSAT-2 spectrum data by using TIR and SWIR spectral ranges simultaneously: method and software

Zadvornykh Ilya, Gribanov Konstantin, Zakharov Vyacheslav, Denisova Nina, Imasu Ryoichi, and Werner Martin

Global monitoring of isotopic composition of water vapor in the atmosphere provides information regarding atmospheric hydgrological cycle in the Earth’s climate system. The observed HDO to H2O ratio (δD) in atmospheric water vapor gives information on origin and history of air masses in the atmosphere.

In this study we present a method, software tool and some results on δD ratio retrieval from spectra, measured simultaneously in the thermal (TIR) and short wave infrared (SWIR) spectral ranges. The TANSO-FTS high spectral resolution spectrometer on board GOSAT-2 satellite is unique to perform simultaneous measurements in TIR and SWIR spectral bands. A method of simultaneous using of these both bands can improve vertical resolution of δD retrieved profile.

We applied conventional optimal estimation method to solve inverse problem. The output data of atmospheric general circulation model ECHAM5-wiso were used as a statistical ensemble of HDO and H2O a priori profiles. The averaging kernels, a posteriori covariance matrices and degrees of freedom are calculated. The retrieval algorithm is implemented using original FIRE-ARMS software and VLIDORT radiation transfer model.

This study is supported by the Russian Science Foundation grant No. 18-11-00024.

How to cite: Ilya, Z., Konstantin, G., Vyacheslav, Z., Nina, D., Ryoichi, I., and Martin, W.: A new approach to HDO/H2O ratio profile retrieval in the atmosphere from TANSO-FTS/GOSAT-2 spectrum data by using TIR and SWIR spectral ranges simultaneously: method and software, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12230, https://doi.org/10.5194/egusphere-egu2020-12230, 2020.

AS3.18 – Understanding the formation of high ozone pollution in the troposphere

China has suffered from increasing levels of ozone pollution in urban areas despite the implementation of various stringent emission reduction measures since 2013. In this study, we conducted numerical experiments with an up-to-date regional chemical transport model to assess the roles of changes in meteorology and anthropogenic emission in summer ozone variations from 2013 to 2017 over China. The model can faithfully reproduce the observed meteorological parameters and air pollutant concentrations and capture the increasing trend in the surface maximum daily 8-hour average (MDA8) ozone (O3) from 2013 to 2017. An increase of 0.46 ppbv a-1 (p=0.001) and a slight decrease of 0.17 ppbv a-1 (p=0.005) in MDA8 O3 levels were simulated from 2013 to 2017 in urban and rural areas, respectively. The meteorological influence on the ozone trend varied by region and by year and could be comparable with or even larger than the impact of changes in anthropogenic emissions. The variation in biogenic emissions during summer varied across regions and was mainly affected by temperature. China’s midlatitude areas (25°N to 40°N) experienced a significant decrease in MDA8 O3 due to a decline in biogenic emissions, while higher temperatures in northern (north of 40°N) and southern (south of 25°N) China after 2013 led to an increase in MDA8 O3 concentrations via an increase in biogenic emissions. We assessed the effects of changes in individual meteorological factors on ozone levels from 2013 to 2017. The results show that the wind field change made a significant contribution to the increase in surface ozone over China by transporting the ozone downward from the upper troposphere and the lower stratosphere. The long-range transport of ozone and its precursors outside the modeling domain also contributed to the increase in MDA8 O3 on the Tibetan Plateau. The effects of changes in individual pollutant emissions on ozone were simulated. The reduction of NOx emission increased ozone in urban areas due to non-linear NOx-VOCs chemistry and decreased aerosol effects; the slight increase in VOCs emission enhanced ozone levels; the reduction of particulate matter(PM) emission increased ozone concentrations by enhancing the photolysis rates and reducing the loss of reactive gases on aerosol surfaces; the reduction of SO2 emission resulted in a drastic decrease in sulfate concentrations which increase ozone levels through the aerosol effects. In contrast, the reduction of CO emissions helped decrease ozone levels in the past years. On the effects of decreasing levels of aerosol, the drop in heterogeneous uptake of reactive gasses, mainly HO2 and O3, was found to be more important than the increase in photolysis rates. The adverse effect on ozone of the reductions of NOx, SO2 and PM emissions would have been avoided with ~20% reduction of VOCs emission from 2013 to 2017. Our analysis revealed that the NOx reduction in the past years has helped to contain the total ozone production in China. However, in order to decrease ozone concentrations in major urban and industrial areas, VOCs emission control should be added to the current NOx-SO2-PM policy.

How to cite: Liu, Y. and Wang, T.: Worsening urban ozone pollution in China from 2013 to 2017: The roles of meteorology and anthropogenic emission, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11046, https://doi.org/10.5194/egusphere-egu2020-11046, 2020.

EGU2020-12047 | Displays | AS3.18

In situ measurement for tropospheric OH radical by Laser Induced Fluorescence technique during STORM campaign

Fengyang Wang, Renzhi Hu, Pinhua Xie, Yihui Wang, Shengrong Lou, Keding Lu, Guoxian Zhang, Jianguo Liu, and Wenqing Liu

Hydroxyl (OH) play an essential role in atmospheric chemistry. OH radical is an indicator of atmospheric oxidation and self-purification, which determines the removal of most trace gases in the atmosphere, such as CO, SO2, NO2, CH4 and other volatile organic compounds (VOCs). A ground-based system for measurement of tropospheric OH radical by Laser Induced Fluorescence technique (AIOFM-LIF) was developed and integrated into a mobile observation platform for field observation. Ambient air expands through a 0.4 mm nozzle to low pressure. OH radical is irradiated by the 308 nm laser pulse at a repetition rate of 8.5 kHz, accompanying the release fluorescence of the A2Σ+(v’=0)—X2Πi(v’’=0) transition at 308 nm with the resultant fluorescence being detected by gated photon counting. The detection sensitivity of AIOFM-LIF system was calibrated by a portable standard OH radical source based on water photolysis-ozone actinometry. Following laboratory and field calibrations to characterise the instrument sensitivity, OH radical detection limits were (1.84±0.26) × 105 cm-3 and (3.69±0.52) × 105 cm-3 at night and noon, respectively. During “A comprehensive STudy of the Ozone foRmation Mechanism in Shenzhen” (STORM) campaign, AIOFM-LIF system was deployed in Shenzhen, China, and OH radical concentration was obtained validly except for the rainy days. Mean diurnal variation of HOx radical concentration was obtained, and the peak was 6.6×106 cm-3 which appeared around 12:00 at noon. A general good agreement of OH radical concentration with j(O1D) was observed with a high correlation (R2 =0.77), which illustrates that photolysis of ozone is an important source of OH radical during this campaign. A box model was applied to simulate the concentrations of OH at this field site, the primary production of OH radical was generally dominated by photolysis of O3, HONO, HCHO, while the other production was contributed by calculated species (OVOCs).

How to cite: Wang, F., Hu, R., Xie, P., Wang, Y., Lou, S., Lu, K., Zhang, G., Liu, J., and Liu, W.: In situ measurement for tropospheric OH radical by Laser Induced Fluorescence technique during STORM campaign, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12047, https://doi.org/10.5194/egusphere-egu2020-12047, 2020.

EGU2020-12068 | Displays | AS3.18

Vertical distribution of ozone in summer and autumn in Guangdong Province, Southern China

Xinqi Wang, Tianshu Zhang, Yan Xiang, and Lihui Lv

A differential absorption lidar was used to study the vertical structure of ozone in Jiangmen city and Yangjiang city, Guangdong Province, Southern China in summer and autumn of 2019, and analyze the two typical pollution characteristics and spatial-temporal distribution characteristics of atmospheric ozone local pollution and regional transport. The results show that the vertical concentration of ozone in Jiangmen city in the summer and autumn seasons is characterized by a single peak of ozone in the afternoon. It is mainly distributed below 600 m in summer and mainly distributed within 1.0 km in autumn. There is ozone residual in Yangjiang city in summer at night. In summer, the differences between the average ozone values in Jiangmen city and Yangjiang city are small, being 92.22 μg/m3 and 82 μg/m3, respectively. In autumn, the average ozone concentration in Jiangmen city is 1.58 times the ozone concentration in Yangjiang city, which is 122.27 μg/m3 and 77.36 μg/m3. In the process of local pollution, high-concentration ozone is mainly concentrated near the ground, and the ozone concentration of 1.5-2km tends to be uniformly distributed. In regional transport, the transport heights of the two stations are mainly in two height intervals, ranging from 0.7 to 1.1 km and above 1.1 km. And use TrajStat to perform trajectory clustering analysis on the main airflows that affect Jiangmen city and Yangjiang city in summer and autumn, the dominant directions of ozone transport at the two cities in summer and autumn are analyzed. In addition, we studied two typical pollution processes, on August 24, the lidar of both cities detected the presence of ozone input and sedimentation at a height of about 1.5 km, and found that the ozone transport came from the northeast through the backward trajectory. During September 28-30, the two cities were locally polluted by ozone and there were obvious ozone residues at night.

Keywords: Differential absorption lidar;Ozone;Local pollution;Regional transport

 

How to cite: Wang, X., Zhang, T., Xiang, Y., and Lv, L.: Vertical distribution of ozone in summer and autumn in Guangdong Province, Southern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12068, https://doi.org/10.5194/egusphere-egu2020-12068, 2020.

EGU2020-12174 | Displays | AS3.18

Regional source apportionment of ozone and PM2.5 during the EXPLORE-YRD campaign in the Yangtze River Delta region of China

Jianlin Hu, Lin Li, Jingyi Li, Xueying Wang, and Kangjia Gong

Although the air quality in China has been improved by collaborative efforts dedicating to mitigate the haze pollution, PM2.5 concentrations still remain high levels and the issue of increasing O3 concentration has attracted more attention of the public. The YRD region has been suffering from both the PM2.5 and O3 pollution problems. To investigate the formation mechanisms and sources of PM2.5 and O3 in this region, a comprehensive EXPLORE-YRD campaign (EXPeriment on the eLucidation of theatmospheric Oxidation capacity and aerosol foRmation, and their Effects inYangtze River Delta) was carried out in May - June 2018. In this study, we investigate the contributions of different source categories to PM2.5 and O3. A source-oriented 3-D air quality model (CMAQ) was applied to analyze contributions of different emission sources to PM2.5 and O3 in the YRD region. Emissions were divided into eight source categories: industry, power, transportation, residential, agriculture, biogenic, wildfire, and other countries. Contribution from individual source category was quantified. The importance of anthropogenic and natural sources to PM2.5 and O3 was discussed.

How to cite: Hu, J., Li, L., Li, J., Wang, X., and Gong, K.: Regional source apportionment of ozone and PM2.5 during the EXPLORE-YRD campaign in the Yangtze River Delta region of China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12174, https://doi.org/10.5194/egusphere-egu2020-12174, 2020.

EGU2020-12767 | Displays | AS3.18

Observed variability of Surface Ozone (O3) and its Precursors over the Indian Capital region

Ravi Kumar Kunchala, Anshika Chandel, Raju Attada, Ramesh K Vellore, and Vijay K Soni

Ozone (O3) is a greenhouse gas which plays different roles in stratosphere and troposphere. It also has an important role in radiative and chemical balance of the atmosphere, and thus the changes in O3 have greater climatic implications. Although O3 is present in trace amounts in troposphere, it is adequate to govern the oxidation processes in the Earth’s atmosphere by forming OH radicals, as the atmospheric lifetime of many gases is controlled by OH radicals. Rapidly developing countries in tropics and subtropics have realized the importance of tropospheric O3 studies as these regions have very limited measurements of ozone and its precursor gases. Understand the variability of the surface O3 and their association with precursors are extremely important for the policy decisions to mitigate the impacts of ozone on human health and crops and ozone air quality management issues in the region. This study investigates the variability of surface ozone (O3) its association with its precursors (NO, NO2, NOX, CO) at time scales of annual, seasonal and diurnal scales for the duration of three years using ground-based observations from IMD Ayanagar, IMD Lodhi road, CRRI, CV Raman, IGI Palam stations in the Indian Capital region. Further, we will present the back-trajectory analysis to elucidates the transport mechanisms/ pathways on the variability of ozone for the study region.

How to cite: Kunchala, R. K., Chandel, A., Attada, R., Vellore, R. K., and Soni, V. K.: Observed variability of Surface Ozone (O3) and its Precursors over the Indian Capital region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12767, https://doi.org/10.5194/egusphere-egu2020-12767, 2020.

EGU2020-12773 | Displays | AS3.18

Emissions and chemistry of volatile organic compounds (VOCs) in urban air: important contributions from oxygenated compounds

Bin Yuan, Caihong Wu, Chaomin Wang, Sihang Wang, Wenjie Wang, Jipeng Qi, Baolin Wang, Shengrong Lou, Hongli Wang, Wei Song, Xinming Wang, Weiwei Hu, and Min Shao

EGU2020-12898 | Displays | AS3.18

OH reactivity in three major city clusters of China in ozone seasons: insights for regional ozone formation

Shengrong Lou, Xiangsen Shen, Xin Li, Qian Wang, and Shuoying Liu

OH radical is the key driver of the photochemical process and closely related to ozone formation. OH reactivity is the quantification of OH radical sink in ambient air. In this study, in-situ OH reactivity measurements are carried out in Shenzhen, Chengdu and Changzhou, three typical cities in major city clusters of China, during their ozone pollution seasons. The measured OH reactivity is ranging from 5~35 s-1 under various meteorological conditions and trace gas concentrations. Aldehydes such as HCHO and acetaldehyde, mainly from the secondary formation of VOCs, are the principal contributors at day time. Primary VOCs such as toluene and biogenic VOCs such as isoprene play different roles in three measurement locations. The missing OH reactivity, which is defined as the OH reactivity that cannot be explained by trace gas measurements, are evaluated by in-situ measurement results as well as an observation-based model. Gas-phase secondary pollutants could be the main source of the missing OH reactivity. The sensitivity tests by the OBM model show ozone production in all areas is mainly VOC-limited but the key precursors of ozone are not identical, leading to different control strategies.

How to cite: Lou, S., Shen, X., Li, X., Wang, Q., and Liu, S.: OH reactivity in three major city clusters of China in ozone seasons: insights for regional ozone formation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12898, https://doi.org/10.5194/egusphere-egu2020-12898, 2020.

EGU2020-12969 | Displays | AS3.18

Measurement of tropospheric HO2 radical using fluorescence assay by gas expansion with low interferences

Yihui Wang, Renzhi Hu, Pinhua Xie, Fengyang Wang, Jianguo Liu, and Wenqing Liu

    An instrument to detect atmospheric HO2 radicals using fluorescence assay by gas expansion (FAGE) technique has been developed. HO2 is measured by reaction with NO to form OH and subsequent detection of OH by laser-induced fluorescence at low pressure. The system performance has been improved by optimizing the expansion distance and pressure, and the influence factors of HO2 conversion efficiency are also studied. The interferences of RO2 radicals produced from OH plus some typical organic compounds were investigated by determining the conversion efficiency of RO2 to OH during the measurement of HO2. The dependence of the conversion of HO2 on NO concentration was investigated, and low HO2 conversion efficiency was selected to realize the ambient HO2 measurement, where the conversion efficiency of RO2 derived by propane, ethene, isoprene and methanol to OH has been reduced to no more than 6%. Furthermore, no significant interferences from PM2.5 and NO were found in the ambient HO2 measurement. The detection limits for HO2 (S/N=2) are estimated to 4.8×105 cm-3 and 1.1×106 cm-3 (the conversion efficiency of HO2 to OH, =20%) under night and noon conditions, with 60s signal integration time. The instrument was successfully deployed during STORM-2018 field campaign at Shenzhen graduate school of Peking University. The diurnal variation of HOx concentration shows that the OH maximum concentration of those days is about 5.5×106 cm-3 appearing around 12:00, while the HO2 maximum concentration is about 5.0×108 cm-3 appearing around 13:30.

How to cite: Wang, Y., Hu, R., Xie, P., Wang, F., Liu, J., and Liu, W.: Measurement of tropospheric HO2 radical using fluorescence assay by gas expansion with low interferences, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12969, https://doi.org/10.5194/egusphere-egu2020-12969, 2020.

EGU2020-13292 | Displays | AS3.18

The First Observation of HOx radicals in the Chengyu Urban Agglomeration

Xinping Yang, Keding Lu, Xuefei Ma, and Yuanhang Zhang

A comprehensive field campaign was carried out in summer 2019 in Chengdu, which obtained the first complete radical dataset of Chengyu Urban Agglomeration. Observed daily concentration maxima of radicals by the laser-induced-fluorescence (LIF) technique were in the range of (2-10)×106 cm-3 for OH and (4-15)×108 cm-3 for HO2. During daytime, OH reactivities were generally high (5-32 s-1). The missing reactivity was not be observed within uncertainty, and inorganics, observed VOCs and the calculated oxidation products contributed about one-third in total reactivity, respectively.

The chemical box model RACM 2 was used to interpret the observed radical concentrations. The model over-predicted OH and HO2 at noon during the O3 polluted episode. Constraining the model by the observed HO2 concentration, the overestimation of OH can be explained almost by the overestimation of HO2. Besides, as in the previous field campaigns (e.g. Pennsylvania, Mexico City, New York and so on), the underestimation of the net conversion of OH into HO2 enlarged with the increasing NO concentration, indicating the conversion of HO2 into OH still need to be studied based on the discussion above. Different schemes to improve the agreement between observed and modelled HO2 were explored in this work. The sensitivity tests indicated observed and modelled HO2 can be agreed well by reducing the HO2 yield in the reaction of OH and HCHO a half.

The oxidation rate of primary pollutants dominated by OH radicals was significantly higher than that in winter Beijing, which contributes significantly to secondary pollution, especially O3. Besides, the atmospheric self-cleaning ability and recycling efficiency both peaked for about 600 pptv of NO, indicating small amounts of NO can help to maintain the atmospheric oxidation. The campaign emphasizes the important role of HO2 yield in the reaction channels of OH and VOCs especially, and the need for further laboratory experiments of the HO2 yield measurement in order to understand radical chemistry in VOC-rich air.

How to cite: Yang, X., Lu, K., Ma, X., and Zhang, Y.: The First Observation of HOx radicals in the Chengyu Urban Agglomeration, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13292, https://doi.org/10.5194/egusphere-egu2020-13292, 2020.

EGU2020-16374 | Displays | AS3.18

Summertime surface ozone variation over East Asia in CCMI

Jieun Wie, Hyo-Jin Park, Hyomee Lee, and Byung-Kwon Moon

The concentration of surface ozone in East Asia is high due to strong solar radiation, but decreases in areas affected by summer monsoons. This study analyzes the summer surface ozone variations in East Asia using meteorological and atmospheric chemistry variables in 12 models participating in Chemistry-Climate Model Initiative (CCMI) for the period of 1979 to 2010. The concentration of 850 hPa ozone was identified two modes by Empirical Orthogonal Functions (EOF) analysis. The first mode is an increase in all regions over East Asia, mainly in eastern China. This mode was associated with downward wind, weak horizontal wind speed, increase in temperatures, decrease in precipitation. The second mode showed high ozone concentrations in eastern China and low in northern Japan. In eastern China, temperatures and precipitation are decreased, and shortwave radiation reaches the surface is increased. In addition, the concentration of nitrogen oxides and carbon monoxide and the net ozone production are increased. The second mode was highly correlated with El Nino-Southern Oscillation (ENSO) and western North Pacific subtropical high (WNPSH) indices and was found to be closely associated with East Asian summer monsoons.

 

Acknowledgements: This work was supported by a National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIT) (No. 2019R1A2C1008549). We acknowledge the modeling groups for making their simulations available for this analysis, the joint WCRP SPARC/IGAC Chemistry–Climate Model Initiative (CCMI) for organizing and coordinating the model simulations and data analysis activity, and the British Atmospheric Data Centre (BADC) for collecting and archiving the CCMI model output.

How to cite: Wie, J., Park, H.-J., Lee, H., and Moon, B.-K.: Summertime surface ozone variation over East Asia in CCMI, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16374, https://doi.org/10.5194/egusphere-egu2020-16374, 2020.

Surface ozone (O3) pollution became the main cause of atmospheric pollution over industrial regions in China since 2013, due to the effective mitigation of fine particulate matter (PM2.5) by stringent emission controls by Air Pollution Prevention and Control Action Plan (APPCAP). O3, as a secondary photochemical pollutant, poses a challenge to control due to its non-linear chemical relationship to precursors – nitrogen oxides (NOx), carbon monoxide (CO) and volatile organic compounds (VOCs).

We hence investigated the differences of atmospheric chemistry environment in the main industrial regions with high emissions – North China Plain (NCP), Yangtze River Delta (YRD), Pearl River Delta (PRD) and Chongqing - in summer 2016, China by using a global climate-chemistry model, based on United Kingdom Chemistry and Aerosol (UKCA). Anthropogenic Multi-resolution Emission Inventory for China (MEIC) 2013 and Hemispheric Transport of Air Pollution (HTAP) emissions 2010 for the rest of globe were used but scaled to 2016 regionally and nationally separately. In addition, we improved the gas-phase chemistry scheme by adding more highly reactive VOC tracers to better simulate regional pollution. Diurnal cycles of O3 and NOx have been evaluated and the results show very good model-observation comparisons after modifying the gas-phase chemistry scheme. Radical (OH, RO2 and HO2), NOx and VOC concentrations have also been examined. O3 production rates and budgets calculated based on these show the highest production rate in YRD and the lowest in PRD due to different NOx and VOC concentration levels.

To investigate the O3 sensitivity — VOC limited or NOx limited, we quantified the O3 response to VOCs and NOx in total 64 scenarios by scaling NOx and VOCs emissions. O3 isopleths suggest that most regions are VOC limited, but the sensitivities vary. O3 in YRD is more sensitive to NOx emission change but PRD can be effectively controlled by decreasing VOC emissions. The ratio of H2O2 to HNO3 is applied to provide a quick examination method of O3 sensitivity. The contribution of O3 from China to the global O3 burden compared with other continents has also been quantified. The results show that the relatively higher O3 concentration in Asia is mainly contributed by China, and O3 becomes more sensitive to VOCs. The model allows us to provide a quantitative assessment of different emission controls on mitigating O3 over China and the impacts of Chinese emissions on the global O3 burden.

How to cite: Liu, Z., M. Doherty, R., Wild, O., and M. O’Connor, F.: Different atmospheric O3 chemical environment in industrial regions of China, 2016: implications for emission control strategies and impacts on the globe in the future, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18148, https://doi.org/10.5194/egusphere-egu2020-18148, 2020.

EGU2020-18314 | Displays | AS3.18

Characterization and sources of volatile organic compounds (VOCs) during ozone pollution events in Chengdu plain, Southwest China

Mengdi Song, Xin Li, Suding Yang, Xuena Yu, Shiyi Chen, Huabin Dong, Shengrong Lou, Sihua Lu, Liming Zeng, Keding Lu, and Yuanhang Zhang

Since 2015, the annual average ozone (O3) concentration in Chengdu has shown significant positive trends and reached a maximum of 55.2 ppb in 2018. By 2019, the annual average O3 value has slightly decreased to 52.9 ppb, but it is still at the highest level in the Sichuan Basin. In order to illuminate VOCs characteristics, identify critical ozone precursors and explore potential sources during ozone pollution events in Chengdu plain, we performed a comprehensive field observation campaign from 9 August to 14 September 2019. During the campaign, the averaged O3 concentration was 29.1 ppb, and mean values of ozone precursors NOx and TVOC were 14.9 ppb and 31.3 ppb, respectively. Two severe ozone pollution events occurred in Chengdu during the observation period. In ozone pollution event 1, the ratios of the average O3, NOx, NMHCs, and OVOCs concentration on the polluted days relative to the clean days were 4.1, 0.3, 0.6, and 1.4, respectively. In ozone pollution event 2, the ratios of the average O3, NOx, NMHCs, and OVOCs concentration on the polluted days relative to the clean days were 3.4, 0.4, 0.6 and 2.1, respectively. The difference of the ratios indicates that there are secondary conversions of NMHCs and NOx and secondary formation of O3 and OVOCs during the pollution period. Isoprene, Acetaldehyde, Methyl Vinyl Ketone, m/p-Xylene and 1-Butene constitute a large fraction of the LOH during polluted days.  In this study, air mass cluster analysis, the potential source contribution function (PSCF), and positive matrix factorization (PMF) receptor models were used in combination to analyze the sources and potential source areas of VOCs during O3 pollution events.

How to cite: Song, M., Li, X., Yang, S., Yu, X., Chen, S., Dong, H., Lou, S., Lu, S., Zeng, L., Lu, K., and Zhang, Y.: Characterization and sources of volatile organic compounds (VOCs) during ozone pollution events in Chengdu plain, Southwest China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18314, https://doi.org/10.5194/egusphere-egu2020-18314, 2020.

EGU2020-20812 | Displays | AS3.18

Investigation of long-term variation of atmospheric oxidation in background areas of China

Junhua Wang, Baozhu Ge, Bo Yao, Weili Lin, Ying Liu, and Zifa Wang

The atmospheric oxidizing capacity (AOC) is closely related to the self-cleaning ability of the atmosphere in which the air pollutants were removed through reacting with oxidations such as OH radical. The level of OH radical is a dominant indicator to the AOC in clean regions characterized as low levels of NOx which is another factor that influences AOC. Due to a lack of VOCs-related mechanisms in model simulation and high cost of the direct observations of OH radical, the long-term trend of OH radical in China is still unclear, especially under the circumstance of significant reduction of Chinese emissions in recent years. In this study, three methods based on a proxy gas CH3CCl3 from 5 regional background stations in China have been developed to investigate the long-term variation of OH radical in China. The concentration of OH radical in the background area of China is approximately (0.8±0.1)*106 molecular/cm3, lower than the results in other background regions of the world. This could be explained by the larger depletion of OH radical in China due to the higher concentrations of polluted gases (i.e., NOx, CO and CH4). The different methods showed almost consistent results for the long-term trends of OH radical in China. From 2006 to 2017, the annual averaged OH concentration showed a slow downward but insignificant trend with the anomalous annual changes ranging from -0.1% to 0.15%. However, significant inter-annual fluctuations were also detected concurrently with a period about two years. This is consistent with the 2-3 years Quasi-biennial Oscillation (QBO) in the long-term variation of surface O3 concentrations. These results provide the new insights into the annual variation of OH radical in China, which could help improve our understanding of the long-term characteristics of atmospheric oxidation in background areas of China.

How to cite: Wang, J., Ge, B., Yao, B., Lin, W., Liu, Y., and Wang, Z.: Investigation of long-term variation of atmospheric oxidation in background areas of China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20812, https://doi.org/10.5194/egusphere-egu2020-20812, 2020.

AS3.19 – New (Sentinel-5 Precursor) and Evolving (e.g. Sentinel-4) Capabilities to Measure Atmospheric Composition from Space

EGU2020-6895 | Displays | AS3.19

Sentinel 5 Precursor: Status of TROPOMI and the Operational Data Products

Pepijn Veefkind, Ilse Aben, Angelika Dehn, Quintus Kleipool, Diego Loyola, Andreas Richter, Michel van Roozendael, Richard Siddans, Thomas Wagner, Claus Zehner, and Pieternel Level

The Copernicus Sentinel 5 Precursor (S5P) is the first of the Sentinel satellites dedicated to the observation of the atmospheric composition, for climate, air quality and ozone monitoring applications. The payload of S5P is TROPOMI (TROPOspheric Monitoring Instrument), a spectrometer covering spectral bands in ultraviolet, visible, near infrared and shortwave infrared, which was developed by The Netherlands in cooperation with the European Space Agency (ESA). TROPOMI has a wide swath of 2600 km, enabling daily global coverage, in combination with a high spatial resolution of about 3.5 x 5.5 km2 (7 x 5.5 km2 for the SWIR band).

S5P was successfully launched on 13 October 2017 and following a six-month commissioning phase, the operational data stream started at the end of April 2018. All of the TROPOMI operational data products have been released, with the exception of the ozone profile, which is planned to become available with the next major release[AR1]  of the Level 1B data. In addition to the operational data products, new research products are also being developed.

In this contribution, the status of TROPOMI and its data products will be presented. Results for observations of recent events will be provided, along with an outlook on the next release of the data products.

 

How to cite: Veefkind, P., Aben, I., Dehn, A., Kleipool, Q., Loyola, D., Richter, A., van Roozendael, M., Siddans, R., Wagner, T., Zehner, C., and Level, P.: Sentinel 5 Precursor: Status of TROPOMI and the Operational Data Products, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6895, https://doi.org/10.5194/egusphere-egu2020-6895, 2020.

EGU2020-9963 | Displays | AS3.19

Comparison of TROPOMI/Sentinel-5 Precursor NO2 product with ground-based observations in Helsinki and first societal applications

Iolanda Ialongo, Henrik Virta, Henk Eskes, Jari Hovila, and John Douros

We evaluate the satellite-based TROPOMI (TROPOspheric Monitoring Instrument) NO2 products against ground-based observations in Helsinki (Finland). TROPOMI NO2 total (summed) columns are compared with the measurements performed by the Pandora spectrometer during April–September 2018. The mean relative and absolute bias between the TROPOMI and Pandora NO2 total columns is about 10 % and 0.12 × 1015 molec. cm-2 respectively. 

We find high correlation (r = 0.68) between satellite- and ground-based data, but also that TROPOMI total columns underestimate ground-based observations for relatively large Pandora NO2 total columns, corresponding to episodes of relatively elevated pollution. This is expected because of the relatively large size of the TROPOMI ground pixel (3.5 × 7 km) and the a priori used in the retrieval compared to the relatively small field-of-view of the Pandora instrument. On the other hand, TROPOMI slightly overestimates relatively small NO2 total columns. Replacing the coarse a priori NO2 profiles with high-resolution profiles from the CAMS chemical transport model improves the agreement between TROPOMI and Pandora total columns for episodes of NO2 enhancement. 

In order to evaluate the capability of TROPOMI observation for monitoring urban air quality, we also analyse the consistency between satellite-based data and NO2 surface concentrations from the local air quality station. We find similar day-to-day variability between TROPOMI and in situ measurements, with NO2 enhancements observed during the same days. Both satellite- and ground-based data show a similar weekly cycle, with lower NO2 levels during the weekend compared to the weekdays as a result of reduced emissions from traffic and industrial activities (as expected in urban sites). The TROPOMI NO2 maps reveal also spatial features, such as the main traffic ways, the airport and other industrial areas, as well as the effect of the prevailing south-west wind patterns. 

These first results confirm that TROPOMI NO2 products are valuable to complement the traditional ground-based in situ data for monitoring urban air quality and are already tested by local and national authorities as well as private companies to monitor pollution sources in the Helsinki region (e.g., emissions from traffic, energy production or oil refineries). For example, TROPOMI NO2 products are already used by the oil refinery company NESTE in their sustainability report and by the Finnish Ministry of Environment to map the air pollution levels in Finland.

Ialongo, I., Virta, H., Eskes, H., Hovila, J., and Douros, J.: Comparison of TROPOMI/Sentinel 5 Precursor NO2 observations with ground-based measurements in Helsinki, Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2019-329, accepted for publication, 2020.

How to cite: Ialongo, I., Virta, H., Eskes, H., Hovila, J., and Douros, J.: Comparison of TROPOMI/Sentinel-5 Precursor NO2 product with ground-based observations in Helsinki and first societal applications, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9963, https://doi.org/10.5194/egusphere-egu2020-9963, 2020.

EGU2020-14709 | Displays | AS3.19

First estimate of NO2 in the upper troposphere from TROPOMI

Eloise Marais, Joanna Joiner, and Sungyeon Choi

Nitrogen oxides (NO x = NO + NO2) in the upper troposphere (~10-12 km) are effective at producing ozone in the upper troposphere where ozone is a potent greenhouse gas. Observations of NOx in the upper troposphere are limited in time to a few intensive research aircraft campaigns and in space to commercial aircraft campaigns. There are satellite-derived observations of NO2 in the upper troposphere from the Ozone Monitoring Instrument (OMI), but these are at very coarse resolutions (seasonal, > 2,000 km). The high-resolution Sentinel-5P/TROPOMI instrument offers higher spatial resolution and better cloud-resolving capability than OMI. Here we use synthetic columns of NO2 from the GEOS-Chem chemical transport model to assess feasibility of deriving NO2 in the upper troposphere using partial columns of NO2 above cloudy scenes (the so-called cloud-slicing technique). The model is also used to quantify errors induced by uncertainties in cloud-top height and to determine whether NO2 over cloudy scenes is representative of all-sky conditions (the "truth"). We find that the cloud-slicing approach is spatially consistent (R =0.5) with the "truth", but with a small (10 pptv) bias in background NO2. Cloud-slicing is then applied to TROPOMI total columns of NO2 to derive near-global observations of NO2 in the upper troposphere and assessed against the existing OMI products and aircraft observations from NASA DC8 aircraft campaigns.

How to cite: Marais, E., Joiner, J., and Choi, S.: First estimate of NO2 in the upper troposphere from TROPOMI , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14709, https://doi.org/10.5194/egusphere-egu2020-14709, 2020.

EGU2020-4814 | Displays | AS3.19

Quantifying burning efficiency in Megacities using NO2/CO ratio from the Tropospheric Monitoring Instrument (TROPOMI)

Srijana Lama, Sander Houweling, Folkert Boersma, Ilse Aben, Hugo Denier van der Gon, Maarten Krol, A.J.(Han) Dolman, Tobias Borsdorff, and Alba Lorente

Economic development and rapid urbanization have increased the consumption of fossil fuel in megacities degrading the local air quality. Burning efficiency is a major factor determining the impact of fuel burning on the environment. It varies with environmental conditions and influences the ratio at which pollutants are emitted, as expressed by the emission factor. Emission factors are an important source of uncertainty in global emission inventories.

To improve the quantification of burning efficiency and emission factors, this study investigates co-located NO2 and CO satellite retrievals from TROPOMI over the megacities of Tehran, Mexico City, Cairo, Riyadh, Lahore and Los Angeles. The TROPOMI instrument was successfully launched by the European Space Agency on 13 October, 2017. It measures atmospheric trace gases with daily coverage and a spatial resolution of 7x7 km2. At this resolution, TROPOMI detects hotspots of CO and NO2 pollution over megacities in single satellite overpasses. The Upwind Background and Plume rotation methods are applied to quantify and evaluate TROPOMI derived ∆NO2/∆CO ratios. TROPOMI derived ∆NO2/∆CO ratios show a strong correlation (r = 0.85 and 0.7) with emission ratios from the Emission Database for Global Atmospheric Research (EDGAR v4.3.2) and Monitoring Atmospheric Chemistry and Climate and CityZen (MACCity) 2018, with the highest ratio for Riyadh and lowest for Lahore. Inventory-derived emission ratios are larger than TROPOMI-derived total column ratios by 60 to 80%. As we will show, this can largely be explained by the limited lifetime of NO2 and the different vertical sensitivity of the TROPOMI NO2 and CO column retrievals. Taking this into account, TROPOMI retrieved emission ratios are generally within 10 to 25% of MACCity. However, larger differences, up to 80%, are found with EDGAR. For Los Angeles, both inventories overestimate NO2/CO ratios compared with TROPOMI. Validation using the air quality monitoring network of Los Angeles supports the lower ∆NO2/∆CO ratios inferred from TROPOMI, indicating that burning efficiencies in Los Angeles are indeed poorer than indicated by the inventories.

 

How to cite: Lama, S., Houweling, S., Boersma, F., Aben, I., Denier van der Gon, H., Krol, M., Dolman, A. J. (., Borsdorff, T., and Lorente, A.: Quantifying burning efficiency in Megacities using NO2/CO ratio from the Tropospheric Monitoring Instrument (TROPOMI), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4814, https://doi.org/10.5194/egusphere-egu2020-4814, 2020.

EGU2020-7861 | Displays | AS3.19 | Highlight

Sentinel-5 Precursor methane and carbon monoxide column retrievals and assessments related to localized emission sources

Michael Buchwitz, Oliver Schneising, Stefan Noel, Maximilian Reuter, Steffen Vanselow, Heinrich Bovensmann, and John P. Burrows

The Sentinel-5 Precursor (S-5P) spectral radiance measurements in the shortwave-infrared (SWIR) spectral region permit the retrieval of atmospheric methane (CH4) and carbon monoxide (CO) columns with high spatial resolution and nearly daily coverage. Methane is an important greenhouse gas with increasing atmospheric concentrations contributing to global warming. Carbon monoxide is an air pollutant with emissions originating from, for example, fossil fuel combustion and biomass burning. We have adjusted and optimized the scientific retrieval algorithm WFM-DOAS to retrieve methane and carbon monoxide columns and column-averaged mixing ratios (XCH4 and XCO) from the S-5P spectra. The retrieval algorithm is based on linear-least squares fitting simulated radiance spectra to the observed spectra. For each single ground pixel we determine a quality flag using a Random Forest based machine learning approach and a similar method is also used to bias correct the retrieved methane columns to enhance the accuracy. We present an overview of the WFM-DOAS retrieval algorithm and resulting initial methane and carbon monoxide scientific data products covering the first two years of the S-5P mission including validation and comparisons with the operational data products. We focus on methane and present details on scenes showing elevated atmospheric concentrations originating from localized emission sources. In particular, we present first results from a method developed to automatically identify methane enhancements originating from localized gas, oil and coal emission sources.

How to cite: Buchwitz, M., Schneising, O., Noel, S., Reuter, M., Vanselow, S., Bovensmann, H., and Burrows, J. P.: Sentinel-5 Precursor methane and carbon monoxide column retrievals and assessments related to localized emission sources, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7861, https://doi.org/10.5194/egusphere-egu2020-7861, 2020.

EGU2020-16074 | Displays | AS3.19

Detection of methane enhancements over the Eastern United States with improved TROPOMI retrievals

Alba Lorente, Tobias Borsdorff, Joost aan de Brugh, Andre Butz, Mahesh Kumar Sha, Bavo Langerock, Mark F. Lunt, Enrico Dammers, Otto Hasekamp, and Jochen Landgraf

The TROPOspheric Monitoring Instrument (TROPOMI) aboard of the Sentinel 5 Precursor (S5P) has provided methane measurements for more than two years. The high accuracy together with the exceptional spatial resolution (7 x 7 km2, 7 x 5.2 km2 since August 2019) and temporal coverage (daily) of TROPOMI provides a unique perspective on local to regional methane enhancements. In this contribution, we discuss observations of enhanced methane concentrations over the United States. We analyse in detail temporal and spatial variability of methane over wetlands and agricultural areas along the Mississippi river and in Florida. To understand the observed CH4 anomalies regarding both natural and anthropogenic sources and transport at regional scales, we support our analysis with simulations from the GEOS-Chem atmospheric chemistry and transport model. We also investigate the possibility to use other datasets as a proxy for CH4 emissions (e.g. NO2 for agricultural areas, land surface temperature for wetlands). These results are based on an improved TROPOMI methane product that features among others a new bias correction that is fully independent of any reference measurements. The verification of the TROPOMI XCH4 data with ground-based measurements by the TCCON network yields a station-to-station variability of the XCH4 error below 10 ppb, in agreement with the comparison with the proxy methane product from the Japanese GOSAT and GOSAT-2 missions. The improved TROPOMI methane product is planned as a future update of the operational TROPOMI processor.

 

 

How to cite: Lorente, A., Borsdorff, T., aan de Brugh, J., Butz, A., Kumar Sha, M., Langerock, B., F. Lunt, M., Dammers, E., Hasekamp, O., and Landgraf, J.: Detection of methane enhancements over the Eastern United States with improved TROPOMI retrievals, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16074, https://doi.org/10.5194/egusphere-egu2020-16074, 2020.

EGU2020-12584 | Displays | AS3.19

Verifying methane emission estimates from agricultural regions in Eastern Ontario using TROPOMI product

Jiangui Liu, Ray Desjardins, Andrew VanderZaag, Douglas Worthy, and Devon worth

The two main sources of CH4 from the agricultural sector are enteric fermentation and manure management systems. Canada uses the IPCC Tier-II methodology to estimate CH4 for its national inventory report of GHG emissions to UNFCCC, which is based on a bottom-up approach using activity data and emission factors obtained through site level experimental measurements. However, because of the presence of wetlands in some agricultural regions, it has been challenging to obtain accurate CH4 emission estimates at a regional scale.

This study explores the usefulness of S5P methane product for verifying methane emission estimates in eastern Ontario agricultural land. We investigated the spatiotemporal variability of total column methane mixing ratio, as well as other detailed data layers in the TROPOMI product, such as averaging kernels and a prior profiles. The spatial temporal patterns of wetland methane emission derived from the global WetCHARTs dataset, and a prior knowledge of livestock distribution in the region, are used to interpret S5P methane product. Results showed that TROPOMI methane product provides great spatiotemporal coverage that can be used to verify CH4 emissions from agricultural landscape. This will be useful to reduce methane estimation uncertainties at the regional and national scales.

How to cite: Liu, J., Desjardins, R., VanderZaag, A., Worthy, D., and worth, D.: Verifying methane emission estimates from agricultural regions in Eastern Ontario using TROPOMI product, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12584, https://doi.org/10.5194/egusphere-egu2020-12584, 2020.

EGU2020-4862 | Displays | AS3.19

The use of TROPOMI retrievals in the operational CAMS forecast and data assimilation system

Antje Inness, Melanie Ades, Anna Agusti-Parareda, Jerome Barre, Richard Engelen, Johannes Flemming, Sebastien Garrigues, Zak Kipling, Mark Parrington, Vincent-Henri Peuch, Roberto Ribas, and Martin Suttie

The Copernicus Atmosphere Monitoring Service (CAMS, atmosphere.copernicus.eu) led by ECMWF is one of the major users of TROPOMI data. TROPOMI ozone retrievals have been routinely assimilated in the operational CAMS system since December 2018 and help CAMS to provide good quality daily ozone analyses and 5-day forecasts. CO, NO2, HCHO and SO2 retrievals from TROPMI are currently monitored in the operational CAMS system and CH4 in the CAMS GHG system. This means that the data are routinely compared with the CAMS atmospheric composition fields, but do not influence the CAMS analyses yet. Howerver, assimilation tests with TROPOMI CO, NO2, SO2 and CH4 data are ongoing and it is hoped that the routine assimilation of these species in the  CAMS system can begin later this year.

In this presentation we will give an update on the use or TROPOMI data in the CAMS system and show the latest results from the monitoring and asimilation tests carried out with the TROPOMI data by CAMS.

How to cite: Inness, A., Ades, M., Agusti-Parareda, A., Barre, J., Engelen, R., Flemming, J., Garrigues, S., Kipling, Z., Parrington, M., Peuch, V.-H., Ribas, R., and Suttie, M.: The use of TROPOMI retrievals in the operational CAMS forecast and data assimilation system, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4862, https://doi.org/10.5194/egusphere-egu2020-4862, 2020.

EGU2020-5269 | Displays | AS3.19 | Highlight

TROPOMI's potential for ocean applications

Julia Oelker, Svetlana Losa, Mariana Altenburg Soppa, Andreas Richter, and Astrid Bracher

The backscattered light from within the ocean carries information about surface ocean optical constituents, e.g., phytoplankton and the amount of light in the ocean. Global quantified insight in these parameters is important for estimating primary productivity and heat budget, and for a better understanding and modeling of biogeochemical cycles. Atmospheric sensors such as SCIAMACHY and GOME-2 have proven to yield valuable information on phytoplankton diversity, sun-induced marine fluorescence, and the underwater light field. As commonly used for the retrieval of atmospheric trace gases, the oceanic parameters are inferred from differential optical absorption spectroscopy combined with radiative transfer modeling. Within the ESA Sentinel-5p+ Innovation themes, we explore TROPOMI's potential for deriving the diffuse attenuation coefficient, quantification of different phytoplankton groups and the fluorescence signal of phytoplankton. Here we present results on deriving the diffuse attenuation coefficient from the vibrational Raman scattering signal in backscattered radiances measured by TROPOMI. The diffuse attenuation coefficient describes how fast the incoming radiation in the ocean is diminished with depth. Retrieval results in three spectral regions covering the ultraviolet and blue region of the solar spectrum are presented and intercompared. In future, we will explore if information on sources of colored dissolved organic matter and ultraviolet-absorbing phytoplankton pigments can be inferred from these data sets.

How to cite: Oelker, J., Losa, S., Altenburg Soppa, M., Richter, A., and Bracher, A.: TROPOMI's potential for ocean applications, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5269, https://doi.org/10.5194/egusphere-egu2020-5269, 2020.

EGU2020-4674 | Displays | AS3.19

Total column water vapor retrieval for TROPOMI/S5P observations in the visible blue band

Ka Lok Chan, Sander Slijkhuis, Pieter Valks, Claas Köhler, and Diego Loyola

We present a new total column water vapor (TCWV) retrieval algorithm in the visible blue band for the TROPOspheric Monitoring Instrument (TROPOMI) on board the Sentinel 5 Precursor (S5P) satellite. Retrieving water vapor columns in the blue band has numerous advantages over longer wavelengths. Measurements in the blue band are more sensitive at lower troposphere over oceans due to higher surface albedo at this wavelength band. In addition, no correction for spectral saturation effects is required as water vapor is optically thin in this spectral band. The blue band algorithm uses the differential optical absorption spectroscopic (DOAS) technique to retrieve water vapor slant columns. The measured water vapor slant columns are converted to vertical column using air mass factors (AMFs). The new algorithm has an iterative optimization module to dynamically find the optimal a priori water vapor profile. The dynamic a priori algorithm makes use of the fact that the vertical distribution of water vapor is strongly correlated to the total column. This makes it better suited for climate studies than usual satellite retrievals with static a priori or vertical profile information from chemistry transport model (CTM).

The new algorithm is applied to TROPOMI observations to retrieve TCWV. Due to the long measurement record of GOME-2, the new algorithm is also used to retrieve TCWV from GOME-2. The TCWV data set is validated by comparing to the GOME-2 TCWV operational product retrieved in the red spectral band, MODIS and SSMIS satellite observations. In addition, the new TCWV data set is also compared to ground based sun-photometer and radiosonde measurements. Water vapor columns retrieved in the blue band are in good agreement with the other data sets, indicating that the new algorithm derives precise results. Therefore, it was selected for the S5P Processor Algorithm Laboratory (PAL) project as a future operational product. This algorithm can also be used for the forthcoming Copernicus Sentinel S4 and S5 missions.

How to cite: Chan, K. L., Slijkhuis, S., Valks, P., Köhler, C., and Loyola, D.: Total column water vapor retrieval for TROPOMI/S5P observations in the visible blue band, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4674, https://doi.org/10.5194/egusphere-egu2020-4674, 2020.

EGU2020-19158 | Displays | AS3.19

Surface and aerosol retrieval from S5P and S4: baseline requirements and expected performance

Pavel Litvinov, Oleg Dubovik, Cheng Chen, Anton Lopatin, Tatyana Lapionak, David Fuertes, Yana Karol, Christoph Holter, Verena Lanzinger, Lukas Bindreiter, Andreas Hangler, Martin De Graaf, Gijsbert Tilstra, Piet Stammes, and Christian Retscher

Sentinel-4 and Sentinel-5p instruments provide hyperspectral measurements in UV, VIS and infrared spectral range. Though the main purpose of the satellites is trace gas characterization, both instruments are capable of aerosol and surface characterization. In particular, S4 and S5p measurements in UV have unique information about absorption and elevation properties of aerosol. Moreover, measurements in wide spectral range are very sensitive to aerosol size and surface type. On one hand, aerosol and surface characteristics are important input parameters for different trace gases such as ozone, NO2, BrO, CH2O, H2O, CO2, CO, and CH4. On another hand, aerosol and surface characteristics are very important on their own for climate studies, air pollution and surface monitoring.

The quantitative characterization of aerosol (AOD (Aerosol Optical Depth), aerosol type) and surface properties (BRDF (Bidirectional Reflectance Distribution Function)) from Sentinel-4 and Sentinel-5p instruments is a topic for several ESA/EUMETSAT projects. In particular, in the framework of S5P+I AOD/BRDF project an innovative algorithm will be developed which integrates the advanced GRASP algorithm (Dubovik et al. 2011, 2014) with the heritage AOD and DLER algorithm previously applied to TOMS, GOME(-2), SCIAMACHY and OMI sensors (Tilstra et al., 2017). Innovative GRASP algorithm is expected to provide surface BRDF and AOD with the accuracy required by most trace gas retrieval algorithms.

Here the requirements on aerosol and surface characterization from S4 and S5p instruments will be analyzed. On the basis of inversion results from the synthetic (S4) and real (S5p) measurements we discuss how expected AOD and BRDF accuracy from the innovative and GRASP/S4 algorithms meet these requirements. New advanced possibility of aerosol and surface characterization with GRASP from S5p instrument will be discussed.

References

  1. Dubovik, O., et al., “Statistically optimized inversion algorithm for enhanced retrieval of aerosol properties from spectral multi-angle polarimetric satellite observations”, Atmos. Meas. Tech., 4, 975-1018, 2011.
  2. Dubovik, O., et al. “GRASP: a versatile algorithm for characterizing the atmosphere”, SPIE: Newsroom, doi:10.1117/2.1201408.005558, Published Online: http://spie.org/x109993.xml, September 19, 2014.
  3. Tilstra, L. G., et al., “Surface reflectivity climatologies from UV to NIR determined from Earth observations by GOME-2 and SCIAMACHY”, J. Geophys. Res. Atmos., 122, 4084–4111.

How to cite: Litvinov, P., Dubovik, O., Chen, C., Lopatin, A., Lapionak, T., Fuertes, D., Karol, Y., Holter, C., Lanzinger, V., Bindreiter, L., Hangler, A., De Graaf, M., Tilstra, G., Stammes, P., and Retscher, C.: Surface and aerosol retrieval from S5P and S4: baseline requirements and expected performance, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19158, https://doi.org/10.5194/egusphere-egu2020-19158, 2020.

EGU2020-8861 | Displays | AS3.19

TROPOMI SO2 column retrievals: validation, inter-comparison with other satellite data sets and algorithm evolution

Nicolas Theys, Can Li, Nickolay Krotkov, Isabelle De Smedt, Christophe Lerot, Huan Yu, Jonas Vlietinck, Vitali Fioletov, Pascal Hedelt, Diego Loyola, Thomas Wagner, and Michel Van Roozendael

Since nearly two years, the operational SO2 product from the TROPOspheric Monitoring Instrument (TROPOMI) onboard Sentinel-5 Precursor (S5P) platform has provided important information on volcanic and anthropogenic SO2 emissions, with an unprecedented level of details. In this presentation, we critically discuss the advantages and disadvantages of the current operational algorithm in light of the validation results obtained so far, and present how the retrieval scheme could evolve in the future.

In the first part, we briefly present the main algorithm features and an overview of the SO2 product validation. One challenge in this respect is the current lack of ground-based SO2 measurements for anthropogenic source regions. We therefore rely largely on comparisons with other satellite datasets (e.g., OMI and OMPS). The main lesson learnt is that satellite SO2 retrievals generally agree very well for large SO2 columns (mostly volcanic) while persisting differences exist for low columns when different algorithms are compared. This motivates the second part of the presentation which aims at extensively comparing the results from existing S5P SO2 operational and scientific algorithms, notably DOAS and PCA retrievals (or other alternative approaches). Here, all configuration settings and auxiliary data (e.g. absorption cross-sections) are aligned in order to better understand the differences through sensitivity tests. This effort is not only important to improve the TROPOMI SO2 results but it is also particularly relevant in the context of the forthcoming Sentinel-4 mission that will mainly probe weak anthropogenic SO2 sources. The last part of the presentation gives a general overview of new features planned for the next versions of the operational SO2 algorithm.

How to cite: Theys, N., Li, C., Krotkov, N., De Smedt, I., Lerot, C., Yu, H., Vlietinck, J., Fioletov, V., Hedelt, P., Loyola, D., Wagner, T., and Van Roozendael, M.: TROPOMI SO2 column retrievals: validation, inter-comparison with other satellite data sets and algorithm evolution, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8861, https://doi.org/10.5194/egusphere-egu2020-8861, 2020.

EGU2020-19452 | Displays | AS3.19

FP_ILM: Extremely fast volcanic SO2 plume height retrieval based on S5P/TROPOMI data using inverse learning machines

Dmitry Efremenko, Pascal Hedelt, Diego Loyola, and Robert Spurr

We present here a novel method for the precise and extremely fast retrieval of volcanic SO2 layer height (LH) based on S5P/TROPOMI data. We have developed the Full-Physics Inverse Learning Machine (FP_ILM) algorithm using a combined principal components analysis (PCA) and neural network approach (NN) to extract the information about the volcanic SO2 LH from high-resolution UV backscatter measurement of TROPOMI aboard Sentinel-5 Precursor.

The SO2 LH is essential for accurate determination of SO2 emitted by volcanic eruptions. So far UV based SO2 plume height retrieval algorithms are very time-consuming and therefore not suitable for near-real-time applications. The FP_ILM approach however enables for the first time to extract the SO2 LH information in a matter of seconds for an entire S5P orbit and thus applicable in NRT application.

The FP_ILM SO2 LH product is developed as part of ESA’s ‘Sentinel-5p+ Innovation - SO2 Layer Height project’ (S5P+I: SO2 LH) project, dedicated to the generation of an SO2 LH product and its extensive verification with collocated ground- and space-born measurements.

How to cite: Efremenko, D., Hedelt, P., Loyola, D., and Spurr, R.: FP_ILM: Extremely fast volcanic SO2 plume height retrieval based on S5P/TROPOMI data using inverse learning machines, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19452, https://doi.org/10.5194/egusphere-egu2020-19452, 2020.

EGU2020-13707 | Displays | AS3.19

Retrievals of glyoxal tropospheric vertical columns from TROPOMI observations

Christophe Lerot, Isabelle De Smedt, Nicolas Theys, Huan Yu, Jonas Vlietinck, Jenny Stavrakou, Jean-François Müller, Martina Friedrich, François Hendrick, Michel Van Roozendael, Leonardo Alvarado, Andreas Richter, and Christian Retscher

Since its launch in October 2017, TROPOMI records earthshine radiances in spectral ranges from the ultraviolet to the shortwave infrared regions at an unprecedented spatial resolution (3.5 x 7 km² and 3.5 x 5.5 km² after August 2019). A suite of L2 operational products provide key information for the understanding and monitoring of the Earth-atmosphere system, and more particularly of aspects related to ozone layer protection, air quality and climate change.

The ESA S5p+ Innovation activity aims at further exploiting the capability of the TROPOMI instrument by supporting the development of a number of additional scientific products, including glyoxal tropospheric column retrievals. The latter provide information on VOC emissions as glyoxal is mainly released in the atmosphere as an intermediate product of VOC oxidation, but also directly emitted from biomass burning events.

We present here the BIRA-IASB S5p glyoxal product relying on a DOAS approach and its main features. We show how the large amount of TROPOMI data and its high resolution helps to better identify and localize VOC sources. The many intense fire events that occurred in the last years, e.g. in Northern America in 2018 or in Australia in 2019/2020, led to extreme levels of pollution and unprecedentedly high glyoxal columns are measured accordingly. We also highlight the excellent consistency between the TROPOMI and OMI glyoxal products, allowing thus to combine them in a 15-year data record. The validation of satellite glyoxal retrievals is difficult due to the scarcity of independent data and their own limitations caused by the low glyoxal optical depth. Nevertheless, a few ground-based data sets have been collected and preliminary comparisons with the S5p glyoxal product are presented.

How to cite: Lerot, C., De Smedt, I., Theys, N., Yu, H., Vlietinck, J., Stavrakou, J., Müller, J.-F., Friedrich, M., Hendrick, F., Van Roozendael, M., Alvarado, L., Richter, A., and Retscher, C.: Retrievals of glyoxal tropospheric vertical columns from TROPOMI observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13707, https://doi.org/10.5194/egusphere-egu2020-13707, 2020.

EGU2020-7027 | Displays | AS3.19

The Copernicus atmospheric Mission Sentinel-4: Status of algorithm developments for the L1b and L2 processors

Grégory Bazalgette Courrèges-Lacoste, Norrie Wright, Ben Veihelmann, Berit Ahlers, Olivier Le Rille, Sebastian Gimeno Garcia, and Marcel Dobber

The Copernicus missions Sentinel-4 (S4) and Sentinel-5 (S5) will carry out atmospheric composition observations on an operational long-term basis to serve the needs of the Copernicus Atmosphere Monitoring Service (CAMS) and the Copernicus Climate Change Service (C3S).

Building on the heritage from instruments such as GOME, SCIAMACHY, GOME-2, and OMI, S4 is an imaging spectrometer instruments covering wide spectral bands in the ultraviolet and visible wavelength range (305-500nm) and near infrared wavelength range (750-775 nm). S4 will observe key air quality parameters with a pronounced temporal variability by measuring NO2, O3, SO2, HCHO, CHOCHO, and aerosols over Europe with an hourly revisit time.

A series of two S4 instruments will be embarked on the geostationary Meteosat Third Generation-Sounder (MTG-S) satellites. S4 establishes the European component of a constellation of geostationary instruments with a strong air quality focus, together with the NASA mission TEMPO and the Korean mission GEMS.

This paper will address the development status of the L1b Operational Processor (L1OPS) by EUMETSAT and the supporting L1b reference processor (L1RP) developed by ESA; In dedicated cases (e.g. CTI, Non-linearity signal loss, ...) the algorithms input from the S4 Industrial Prime have been used. The paper will also provide an overview of the status of the Level 2 processor developed by ESA for integration into the EUMETSAT MTG-S ground segment.

How to cite: Bazalgette Courrèges-Lacoste, G., Wright, N., Veihelmann, B., Ahlers, B., Le Rille, O., Gimeno Garcia, S., and Dobber, M.: The Copernicus atmospheric Mission Sentinel-4: Status of algorithm developments for the L1b and L2 processors, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7027, https://doi.org/10.5194/egusphere-egu2020-7027, 2020.

EGU2020-12167 | Displays | AS3.19

Breaking the temporal barrier in air quality monitoring over Europe with Sentinel-4

Diego Loyola, Michael Aspetsberger, Oleg Dubovik, Daniele Fantin, Yves Govaerts, Andreas Richter, Michel Van Roozendael, Richard Siddans, Pepijn Veefkind, Ben Veihelmann, Thomas Wagner, and Norrie Wright

European UVN satellite missions deliver global measurements for air quality and climate applications from Low Earth Orbit (LEO) satellites since over two decades. Currently we have in the morning data from GOME-2 on the three MetOp satellites and in the early afternoon data from OMI/Aura and TROPOMI/Sentinel-5 Precursor.

The temporal barrier imposed by LEO satellites, providing only one daily observation, can be broken using Geostationary Equatorial Orbit (GEO) satellites. The Sentinel-4 (S4) mission on-board the MTG-S GEO satellite will focus on monitoring of trace gas column densities and aerosols over Europe with an hourly revisit time, thereby covering the diurnal variation of atmospheric constituents.

We present the algorithm, verification, and processor work being performed as part of the ESA Sentinel-4 Level 2 (S4-L2) project responsible for developing the operational S4-L2 products: O3 total and tropospheric column, NO2 total and tropospheric column, SO2, HCHO, CHOCHO columns, aerosol and cloud properties as well as surface reflectance.

 

How to cite: Loyola, D., Aspetsberger, M., Dubovik, O., Fantin, D., Govaerts, Y., Richter, A., Van Roozendael, M., Siddans, R., Veefkind, P., Veihelmann, B., Wagner, T., and Wright, N.: Breaking the temporal barrier in air quality monitoring over Europe with Sentinel-4, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12167, https://doi.org/10.5194/egusphere-egu2020-12167, 2020.

EGU2020-7989 | Displays | AS3.19

Validation of Sentinel-5p retrieved cloud height data using ground-based radar/lidar measurements from the CLOUDNET network

Steven Compernolle, Athina Argyrouli, Ronny Lutz, Maarten Sneep, José Granville, Daan Hubert, Arno Keppens, Tijl Verhoelst, Ann Mari Fjaeraa, Diego Loyola, Ewan O'Connor, and Jean-Christopher Lambert

Satellite measurements of tropospheric or total column trace gas species, including those from Sentinel-5p TROPOMI, are affected by the presence of clouds. Therefore, cloud data products retrieved with the same sensor play an essential role, as they allow the data provider to take an estimated cloud impact on the trace gas retrieval into account. Examples are the modification of the radiative transfer and associated quantities such as the air mass factor, and the partial masking of the measurement scene. Evidently, the accuracy of these corrections relies on the accuracy of the retrieved cloud properties, like radiometric cloud fraction (CF), cloud top height (CTH) or cloud height (CH), and cloud optical thickness (COT) or cloud albedo (CA).

We consider here three S5p TROPOMI-based cloud products: (i) L2_CLOUD OCRA/ROCINN CAL (Optical Cloud Recognition Algorithm/Retrieval of Cloud Information using Neural Networks; Clouds-As-Layers), (ii) L2_CLOUD OCRA/ROCINN CRB (Clouds-as Reflecting Boundaries), and (iii) the S5p support product FRESCO-S (Fast Retrieval Scheme for Clouds from Oxygen absorption bands). These are input to the S5p operational processors for several trace gas products, including ozone columns and profile, total and tropospheric NO2, formaldehyde, sulfur dioxide. The quality assessment of these cloud products is carried out within the framework of ESA’s Sentinel-5p Mission Performance Centre (MPC) with support from AO validation projects focusing on the respective trace gases.

In this work, cloud height (from S5p CLOUD CRB and S5p FRESCO algorithms) and cloud top height (from S5p CLOUD CAL) S5p data is validated with radar/lidar-based cloud profile information from the ground-based networks CLOUDNET and ARM at 17 sites. For some sites the comparison is difficult due to e.g., orography or snow/ice cover. S5P and CLOUDNET report similar cloud height variations at several sites, and the correlation between the S5p cloud products and CLOUDNET can be high (Pearson R up to 0.9). However, there is a site-dependent negative bias of the S5p cloud (top) height with respect to the CLOUDNET data: up to -2.5 km for S5p CLOUD CAL cloud top height and -1.5 km for S5p CLOUD CRB and S5p FRESCO cloud height. The dependence on other parameters measured by S5p and CLOUDNET (e.g., radiometric cloud fraction, cloud phase,…) is investigated.

How to cite: Compernolle, S., Argyrouli, A., Lutz, R., Sneep, M., Granville, J., Hubert, D., Keppens, A., Verhoelst, T., Fjaeraa, A. M., Loyola, D., O'Connor, E., and Lambert, J.-C.: Validation of Sentinel-5p retrieved cloud height data using ground-based radar/lidar measurements from the CLOUDNET network, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7989, https://doi.org/10.5194/egusphere-egu2020-7989, 2020.

EGU2020-8380 | Displays | AS3.19

MICRU effective cloud fractions for S-5P/TROPOMI

Holger Sihler, Sreffen Beirle, Christian Borger, and Thomas Wagner

How to cite: Sihler, H., Beirle, S., Borger, C., and Wagner, T.: MICRU effective cloud fractions for S-5P/TROPOMI, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8380, https://doi.org/10.5194/egusphere-egu2020-8380, 2020.

EGU2020-11184 | Displays | AS3.19

Meter-scale retrieval of industrial methane emission using GHGSat’s satellite constellation

Mathias Strupler, Dylan Jervis, Jason McKeever, Daniel Varon, David Gains, Ewan Tarrant, Joannes D. Maasakkers, Sudhanshu Pandey, Sander Houweling, Ilse Aben, tia Scarpelli, Daniel J. Jacob, and Stephane Germain

To reduce green house gases emissions, it is crucial to be able to give actionable feedback to industrial facility operators on their emissions. For this purpose GHGSat is building a constellation of satellites capable of monitoring and quantifying emissions from individual sites.

In 2016, GHGSat launched a demonstration satellite called GHGSat-D. It is the first and only satellite able to retrieve the methane column with a spatial resolution of less than 50 meters. We will present examples of detection and quantification of methane leaks in Central Asia using GHGSat-D. The retrieved methane column density shows plumes originating from known source locations and aligned with the local wind direction.  The largest and most persistent of those sources was estimated to have an emission rate of 10-42 tons.h-1, a magnitude comparable to the Aliso Canyon and Ohio blowouts. The complementarity of GHGSat's observations with other satellites observations will be highlighted using a comparison of GHGSat-D and Sentinel-5P in the same Central Asia region.

We will provide an update of GHGSat's constellation, with news from GHGSat-C1 (launch March 2020) and GHGSat-C2 (launch summer 2020). Lessons learned and improvements to the new satellites will be discussed. The anticipated vertical column density precision of GHGSat-C1 and C2 are 2% and 1% of background methane concentration respectively, compared to 13% for GHGSat-D. We will also introduce  the data calibration and validation plans for the new satellites.

How to cite: Strupler, M., Jervis, D., McKeever, J., Varon, D., Gains, D., Tarrant, E., Maasakkers, J. D., Pandey, S., Houweling, S., Aben, I., Scarpelli, T., Jacob, D. J., and Germain, S.: Meter-scale retrieval of industrial methane emission using GHGSat’s satellite constellation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11184, https://doi.org/10.5194/egusphere-egu2020-11184, 2020.

EGU2020-19643 | Displays | AS3.19

The TANGO mission: A satellite tandem to measure major sources of anthropogenic greenhouse gas emissions

Jochen Landgraf, Stephanie Rusli, Ryan Cooney, Pepijn Veefkind, Tim Vemmix, Zeger de Groot, Andrew Bell, James Day, Anton Leemhuis, and Bernd Sierk

In this contribution, we present the Twin ANthropogenic Greenhouse Gas Observers (TANGO) mission, which is one of four candidate missions of ESA’s SCOUT program for the rapid prototyping and demonstration of observation techniques and science application using small-satellites. Over the period 2024-2027, TANGO will provide the unique opportunity for the global and independent monitoring of the major emission sources of the anthropogenic greenhouse gases CH4 and CO2. It will demonstrate a distributed monitoring system that can pave the way for future larger constellations of small-satellites allowing for enhanced coverage and temporal resolution. The TANGO mission consists of two agile small-satellites, each carrying one spectrometer flying in conjunction with the Copernicus Sentinel 5 mission. Regular joint TANGO and Sentinel 5 observations will be used to enhance the radiometric accuracy of the TANGO spectrometers. The first satellite measures spectral radiances in the shortwave infrared part of the solar spectrum (1.6 µm) to determine moderate to strong emissions of CH4 (≥ 10 Kt/yr) and CO2 (≥ 5 Mt/yr). The instrument has a field of view of 30 x 30 kmat spatial resolutions small enough to monitor individual large industrial facilities (300 x 300 m2), with an accuracy to determine emissions on the basis of a single observation. Using the same strategy, the second satellite yields collocated NO2 observations from radiance measurements in the visible spectral range, supporting plume detection and exploiting the use of CO2/NO2 ratio observations to estimate CO2 emissions from offshore NO2 sources. TANGO will provide surface fluxes of specific emission types based on the combination of CH4, CO2 and NO2 observations at a high spatial resolution. In doing so, TANGO aims to uniquely complement the large current and planned Copernicus monitoring missions like Sentinel-5(P) and the CO2M High Priority Candidate Mission (HPCM) by providing unrivalled high-resolution monitoring of the major anthropogenic greenhouse gas emissions at a regular basis.

How to cite: Landgraf, J., Rusli, S., Cooney, R., Veefkind, P., Vemmix, T., de Groot, Z., Bell, A., Day, J., Leemhuis, A., and Sierk, B.: The TANGO mission: A satellite tandem to measure major sources of anthropogenic greenhouse gas emissions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19643, https://doi.org/10.5194/egusphere-egu2020-19643, 2020.

EGU2020-10247 | Displays | AS3.19

CHAPS: A Compact Hyperspectral Imager for Air Pollution Remote Sensing

William Swartz, Nickolay Krotkov, Lok Lamsal, Frank Morgan, Philip Huang, Joseph Linden, Pieternel Levelt, and Pepijn Veefkind

Air pollution is responsible for ~7 million premature deaths every year.  Current and planned low Earth orbit and geostationary satellite instruments have long provided global surveys, revealing pollution characteristics and trends.  We need a robust, sustainable observing strategy, however, for measuring the distribution of air pollution at high spatial and high temporal resolution.  The Compact Hyperspectral Air Pollution Sensor (CHAPS) incorporates technologies enabling a sustainable approach to air pollution observation from space.  CHAPS is a hyperspectral imager using freeform optics in a form factor suitable for accommodation on a small satellite or hosted payload.  It will make measurements of air pollution at unprecedented spatial resolution from low Earth orbit (1 x 1 km2) and will characterize, quantify, and monitor emissions from urban areas, power plants, and other anthropogenic activities.  The compact size and relatively lower cost of CHAPS makes a constellation feasible for the first time, with unprecedented spatiotemporal sampling of global point pollution sources.  NASA recently funded the development of a CHAPS–Demonstrator (CHAPS-D), which will result in an airborne demonstration of a CHAPS prototype instrument.  CHAPS derives heritage from the TROPOspheric Monitoring Instrument (TROPOMI) on the Sentinel-5 Precursor, which uses a freeform mirror telescope.  Freeform optics has potentially huge advantages over traditional optical designs, including fewer optical surfaces, less mass and volume, and improved image quality.  CHAPS-D combines a radiometrically calibrated freeform hyperspectral imager (300–500 nm @ 0.5-nm resolution) with associated detector and payload electronics within the design constraints of a 6U CubeSat.  We present the measurement requirements and preliminary design of CHAPS-D.

How to cite: Swartz, W., Krotkov, N., Lamsal, L., Morgan, F., Huang, P., Linden, J., Levelt, P., and Veefkind, P.: CHAPS: A Compact Hyperspectral Imager for Air Pollution Remote Sensing, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10247, https://doi.org/10.5194/egusphere-egu2020-10247, 2020.

EGU2020-4330 | Displays | AS3.19

Exploration of Atmospheric Compositions by TROPOMI on Sentinel-5P

Jian Zeng, Irina Gerasimov, Jennifer Adams, Paul Huwe, Jennifer Wei, and David Meyer

Since its launch in October 2017, the Sentinel-5 Precursor (Sentinel-5P), one of the European Commission’s new Copernicus family – Sentinels, has continuously proven to be successful, enhanced, and upgraded to its predecessor missions. The sole payload on Sentinel-5P is the TROPOspheric Monitoring Instrument (TROPOMI), which is a nadir-viewing 108 degree Field-of-View push-broom grating hyperspectral spectrometer, covering the wavelength of ultraviolet-visible (270 nm to 495 nm), near infrared (675 nm to 775 nm), and shortwave infrared (2305 nm - 2385 nm). Sentinel-5P is currently providing measurements of total column ozone, tropospheric nitrogen dioxide and formaldehyde, sulfur dioxide, methane, carbon monoxide, aerosol index and cloud at very high spatial resolutions. Ozone vertical profile products are scheduled to become available in April 2020. In addition, S5P/TROPOMI spectral design provides the possibility of developing other atmospheric composition products such as BrO, aerosol optical depth, sun-induced fluorescence, etc..

 

The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) is one of the 12 Distributed Active Archive Centers (DAACs) within NASA's Earth Observing System Data and Information System (EOSDIS). The GES DISC archives and supports over a thousand data collections in the Focus Areas of Atmospheric Composition, Water & Energy Cycles, and Climate Variability. Under the End User License Agreement between NASA, European Space Agency (ESA) and European Commission (Copernicus Programme), GES DISC is curating S5P/TROPOMI Level-1B and Level-2 products and providing information services through enhanced tools and services that offer convenient solutions for complex Earth science data and applications. This presentation will demonstrate up-to-date TROPOMI products and their applications, as well as various efficient yet straightforward methods to access, visualize and subset TROPOMI data at GES DISC.

How to cite: Zeng, J., Gerasimov, I., Adams, J., Huwe, P., Wei, J., and Meyer, D.: Exploration of Atmospheric Compositions by TROPOMI on Sentinel-5P, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4330, https://doi.org/10.5194/egusphere-egu2020-4330, 2020.

EGU2020-6101 | Displays | AS3.19

NASA’s TropOMI Aerosol Products: Algorithm and Preliminary Evaluation Results

Changwoo Ahn, Omar Torres, Glen Jaross, Hiren Jethva, Xiaoguang Xu, Jun Wang, and Ramaswamy Tiruchirapalli

EGU2020-7720 | Displays | AS3.19

Geophysical validation of two years of Sentinel-5p tropical tropospheric ozone columns

Daan Hubert, Tijl Verhoelst, Steven Compernolle, Arno Keppens, José Granville, Jean-Christopher Lambert, Klaus-Peter Heue, Diego Loyola, Kai-Uwe Eichmann, Mark Weber, Anne M. Thompson, Marc Allaart, Ankie Piters, Bryan J. Johnson, Henry B. Selkirk, Holger Vömel, Francisco R. da Silva, Maznorizan Mohamad, Christian Félix, and René Stübi

Tropospheric ozone damages ecosystems and causes human health problems. The high spatial and temporal variability of ozone concentrations in the troposphere challenges global observing systems to monitor ozone at all relevant scales. TROPOMI is a nadir-viewing UV-Vis-NIR-SWIR sensor that combines a high spatial resolution, a large swath width and the spectral measurement characteristics required to deliver trace gas data records at unprecedented detail. The first tropospheric data product was publicly released in Fall 2018, a year after launch on the Sentinel-5p platform (S5p). It is based on the convective-cloud differential technique (CCD) to infer 0.5°x1° resolved daily maps of 3-day moving mean values of the tropospheric ozone column (surface to 270 hPa) between 20°S and 20°N in clear-sky conditions. This makes it the highest resolved tropospheric ozone data set currently available for the tropical belt. About two years of data have been collected since the end of the commissioning phase in April 2018.

We present an assessment of the quality of the Sentinel-5p TROPOMI convective-cloud differential tropospheric ozone column data products (O3_TCL OFFL v01.01.05-01.01.07), carried out within the context of ESA’s Sentinel-5p Mission Performance Center (MPC) and the S5PVT AO project CHEOPS-5p. Our assessment of the first two years of TROPOMI data is based on comparisons with (a) quality-assured co-located in-situ measurements by the SHADOZ ozonesonde network, and, (b) satellite data by the GOME-2 and OMI sensors. These well-characterized observational data records serve as references to evaluate the bias and the dispersion of S5p data, and their dependence on influence quantities. Additional visual inspections of the S5p tropospheric ozone maps unveiled non-geophysical structures introduced by the sampling pattern of sensor and clouds. We conclude by assessing the compliance of S5p tropospheric ozone data with respect to mission and user requirements for key data applications.

How to cite: Hubert, D., Verhoelst, T., Compernolle, S., Keppens, A., Granville, J., Lambert, J.-C., Heue, K.-P., Loyola, D., Eichmann, K.-U., Weber, M., Thompson, A. M., Allaart, M., Piters, A., Johnson, B. J., Selkirk, H. B., Vömel, H., da Silva, F. R., Mohamad, M., Félix, C., and Stübi, R.: Geophysical validation of two years of Sentinel-5p tropical tropospheric ozone columns, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7720, https://doi.org/10.5194/egusphere-egu2020-7720, 2020.

EGU2020-8109 | Displays | AS3.19

2.5 years of TROPOMI S5P total ozone column data: geophysical global ground-based validation and inter-comparison with other satellite missions

Katerina Garane, Maria-Elissavet Koukouli, Tijl Verhoelst, Christophe Lerot, Klaus-Peter Heue, Dimitrios Balis, Alberto Redondas, Andrea Pazmino, Ariane Bazureau, Fabian Romahn, Walter Zimmer, Jian Xu, Jean-Christopher Lambert, Diego Loyola, Michel Van Roozendael, Florence Goutail, and Jean-Pierre Pommereau

The Sentinel-5 Precursor (S5P) mission, launched in October 2017, carries the TROPOspheric Monitoring Instrument (TROPOMI), which provides a daily global coverage at a spatial resolution as high as 5.5 km x 3.5 km and will extend the European atmospheric composition record initiated with GOME/ERS-2 in 1995. Due to the ongoing need to understand and monitor the recovery of the ozone layer, as well as the evolution of tropospheric pollution, ozone remains one of the leading species of interest during this mission.

In this work, two and a half years of TROPOMI near real time (NRTI) and offline (OFFL) total ozone column (TOC) products are presented and compared to daily and individual, globally distributed, ground-based quality assured Brewer and Dobson TOC measurements. The daily ground-based ozone measurements used here are deposited in the World Ozone and Ultraviolet Radiation Data Centre (WOUDC). The individual Brewer measurements are made available by the European Brewer Network (Eubrewnet). Furthermore, twilight zenith-sky measurements obtained with ZSL-DOAS (Zenith Scattered Light Differential Optical Absorption Spectroscopy) instruments, which form part of the SAOZ network (Système d’Analyse par Observation Zénitale), are used for the validation.

The quality of the TROPOMI TOC data is evaluated in terms of the influence of various geophysical quantities such as location, solar zenith angle, viewing angle, season, effective temperature, surface albedo and clouds. The overall statistical analysis of the global comparison shows that the mean bias and the mean standard deviation of the percentage difference between TROPOMI and ground-based TOC is within 0 –1.5% and 2.5 %–4.5 %, respectively. Moreover, based on the full available dataset, a first attempt is made for a drift investigation.

Additionally, the TROPOMI OFFL and NRTI products are evaluated against already known spaceborne sensors, namely, the Ozone Mapping Profiler Suite, on board the Suomi National Polar-orbiting Partnership (OMPS/Suomi-NPP), NASA, and the Global Ozone Monitoring Experiment 2 (GOME-2), on board the Metop-A (GOME-2/Metop-A) and Metop-B (GOME-2/Metop-B) satellites. This analysis shows a very good agreement for both TROPOMI products with well-established instruments, with the absolute differences in mean bias and mean standard deviation being below +0.7% and 1%, respectively.

How to cite: Garane, K., Koukouli, M.-E., Verhoelst, T., Lerot, C., Heue, K.-P., Balis, D., Redondas, A., Pazmino, A., Bazureau, A., Romahn, F., Zimmer, W., Xu, J., Lambert, J.-C., Loyola, D., Van Roozendael, M., Goutail, F., and Pommereau, J.-P.: 2.5 years of TROPOMI S5P total ozone column data: geophysical global ground-based validation and inter-comparison with other satellite missions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8109, https://doi.org/10.5194/egusphere-egu2020-8109, 2020.

EGU2020-7868 | Displays | AS3.19

Validation of TROPOMI nadir ozone profile retrievals: Methodology and first results

Arno Keppens, Daan Hubert, Jean-Christopher Lambert, Steven Compernolle, Tijl Verhoelst, Sander Niemeijer, Ann Mari Fjaeraa, Mark ter Linden, Maarten Sneep, Johan De Haan, and Pepijn Veefkind and the CHEOPS-5p validation team

Part of the space segment of EU’s Copernicus Earth Observation programme, the Sentinel-5 Precursor (S5P) mission is dedicated to global and European atmospheric composition measurements of air quality, climate and the stratospheric ozone layer. On board of the S5P early afternoon polar satellite, the imaging spectrometer TROPOMI (TROPOspheric Monitoring Instrument) performs nadir measurements of the Earth radiance within the UV-visible and near-infrared spectral ranges, from which atmospheric ozone profile data are retrieved. Developed at the Royal Netherlands Meteorological Institute (KNMI) and based on the optimal estimation method, TROPOMI’s operational ozone profile retrieval algorithm has recently been upgraded. With respect to early retrieval attempts, accuracy is expected to have improved significantly, also thanks to recent updates of the TROPOMI Level-1b data product. This work reports on the initial validation of the improved TROPOMI height-resolved ozone data in the troposphere and stratosphere, as collected both from the operational S5P Mission Performance Centre/Validation Data Analysis Facility (MPC/VDAF) and from the S5PVT scientific project CHEOPS-5p. Based on the same validation best practices as developed for and applied to heritage sensors like GOME-2, OMI and IASI (Keppens et al., 2015, 2018), the validation methodology relies on the analysis of data retrieval diagnostics – like the averaging kernels’ information content – and on comparisons of TROPOMI data with reference ozone profile measurements. The latter are acquired by ozonesonde, stratospheric lidar, and tropospheric lidar stations performing network operation in the context of WMO's Global Atmosphere Watch and its contributing networks NDACC and SHADOZ. The dependence of TROPOMI’s ozone profile uncertainty on several influence quantities like cloud fraction and measurement parameters like sun and scan angles is examined and discussed. This work concludes with a set of quality indicators enabling users to verify the fitness-for-purpose of the S5P data.

How to cite: Keppens, A., Hubert, D., Lambert, J.-C., Compernolle, S., Verhoelst, T., Niemeijer, S., Fjaeraa, A. M., ter Linden, M., Sneep, M., De Haan, J., and Veefkind, P. and the CHEOPS-5p validation team: Validation of TROPOMI nadir ozone profile retrievals: Methodology and first results, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7868, https://doi.org/10.5194/egusphere-egu2020-7868, 2020.

EGU2020-8301 | Displays | AS3.19

Evaluating the Potential of Satellite Measurements in Air Quality Monitoring: A Project for the Finnish Ministry of the Environment

Henrik Virta, Anu-Maija Sundström, Iolanda Ialongo, and Johanna Tamminen

We present the results of a project for the Finnish Ministry of the Environment that aimed to assess the potential of satellite measurements in complementing traditional in situ air quality measurements. Co-located NO2 measurements from the TROPOspheric Monitoring Instrument (TROPOMI) and several traditional air quality stations (measuring in µg/m3) in Finland and Europe between April 2018 and June 2019 are compared to determine their correlation. We find that the correlation of individual air quality stations with TROPOMI is dependent on the location of the station, but is more reliable when all stations in a city centre are studied as a group. This is expected due to the spatial averaging of satellite measurements. We also find that NO2 measurements between different cities in Finland and Europe in general correlate well.

We also analyse TROPOMI’s and the Ozone Monitoring Instrument’s (OMI) ability to study the spatial distribution of NO2 over Finland and the Helsinki metropolitan area using gridded maps. Oversampled TROPOMI measurements are able to distinguish relatively small sources such as roads and airports, and the difference in concentrations between weekdays and weekends. TROPOMI is also able to detect emissions from different sources of NO2 such as cities, mining sites and industrial areas. Long time series measurements from OMI show decreasing NO2 levels over Finland between 2005 and 2018.

Finally, we convert air quality station measurements to vertical column densities using boundary layer height data, and study the effect that this has on their correlation with TROPOMI measurements.

This study was conducted on behalf of the Finnish Ministry of the Environment, and showcases how satellite measurements can be used reliably alongside traditional air quality measurements to provide a better picture of current pollution levels. Launched in 2017, TROPOMI is currently the highest-resolution air quality sensing satellite, and its societal uses are only beginning to be realized. Future Sentinel missions, especially the geosynchronous Sentinel-4, will provide an even more comprehensive view of the daily air quality situation.

How to cite: Virta, H., Sundström, A.-M., Ialongo, I., and Tamminen, J.: Evaluating the Potential of Satellite Measurements in Air Quality Monitoring: A Project for the Finnish Ministry of the Environment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8301, https://doi.org/10.5194/egusphere-egu2020-8301, 2020.

EGU2020-8888 | Displays | AS3.19

Evaluation of TROPOMI cloud products for NO2 retrievals

Miriam Latsch, Andreas Richter, John P. Burrows, Thomas Wagner, Holger Silher, Michel van Roozendael, Diego Loyola, Pieter Valks, Athina Argyrouli, Ronny Lutz, Pepijn Veefkind, Henk Eskes, Maarten Sneep, Ping Wang, and Richard Siddans

The first European Sentinel satellite for monitoring the composition of the Earth’s atmosphere, the Sentinel 5 Precursor (S5p), carries the TROPOspheric Monitoring Instrument (TROPOMI) on board to map trace species of the global atmosphere at high spatial resolution. Retrievals of tropospheric trace gas columns from satellite measurements are strongly influenced by clouds. Thus, cloud retrieval algorithms were developed and implemented in the trace gas processing chain to consider this impact.

In this study, different cloud products available for NO2 retrievals from TROPOMI data are analyzed. The TROPOMI level 2 OCRA/ROCINN (Optical Cloud Recognition Algorithm/Retrieval of Cloud Information using Neural Networks) cloud products CRB (cloud as reflecting boundaries) and CAL (clouds as layers) as well as the FRESCO (Fast Retrieval Scheme for Clouds from Oxygen absorption bands) cloud product are compared with regard to e. g. cloud fraction, cloud height, cloud albedo/optical thickness, flagging and quality indicators. In particular, difficult situations such as snow or ice, sun glint, and high aerosol load are investigated.

The eventual aim of this study is to better understand TROPOMI cloud products and their quantitative impacts on trace gas retrievals. Here, we present first results of a statistical analysis on a limited data set comparing currently existing cloud products and their approaches focusing on NO2.

How to cite: Latsch, M., Richter, A., Burrows, J. P., Wagner, T., Silher, H., van Roozendael, M., Loyola, D., Valks, P., Argyrouli, A., Lutz, R., Veefkind, P., Eskes, H., Sneep, M., Wang, P., and Siddans, R.: Evaluation of TROPOMI cloud products for NO2 retrievals, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8888, https://doi.org/10.5194/egusphere-egu2020-8888, 2020.

EGU2020-9116 | Displays | AS3.19

Ozone in the Tropical Troposphere from Sentinel-5P TROPOMI data: CCD and CSL results

Kai-Uwe Eichmann, Mark Weber, Klaus-Peter Heue, and John P. Burrows

The TROPOspheric Monitoring Instrument (TROPOMI), on board the Sentinel 5 precursor (S5p) satellite, was launched in October 2017. The TROPOMI instrument has high spatial resolution and daily coverage of the Earth. About two years of level 2 data (version 1.1.5/1.1.7) of ozone and cloud properties (fraction and height) are available. Using the OFFL GODFIT ozone and OCRA/ROCINN CRB cloud dataset, we derived tropical tropospheric ozone using the convective cloud differential method for tropical tropospheric column ozone (TTCO) [DU] and the cloud slicing method for upper tropospheric ozone volume mixing ratios (TUTO) [ppbv].

The CCD algorithm was optimized for TROPOMI with respect to the reference sector Above Cloud Column Ozone field (ACCO). It was adjusted in time and latitude space in order to reduce data gaps in the daily ACCO vectors. Also, daily total ozone maps were used to minimize the error in stratospheric ozone differences.

The CHOVA algorithm (Cloud Height induced Ozone Variation Analysis) was developed to fully exploit with the S5p instruments characteristics. A temporal sampling of cloud/ozone data is not necessary for the high amount of S5p measurements. The spatial sampling is 2° latitude/longitude grid boxes. CHOVA results are quality checked based on the statistical properties of cloud, ozone and retrieval parameters to exclude unreliable TUTO values.

Comparisons with ozone sondes show a good agreement for both methods taking into account the principal differences between a sonde point measurement and a satellite sampled mean value. 

The work on TROPOMI/S5P geophysical products is funded by ESA and national contributions from the Netherlands, Germany, Belgium, and Finland.

How to cite: Eichmann, K.-U., Weber, M., Heue, K.-P., and Burrows, J. P.: Ozone in the Tropical Troposphere from Sentinel-5P TROPOMI data: CCD and CSL results, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9116, https://doi.org/10.5194/egusphere-egu2020-9116, 2020.

EGU2020-11831 | Displays | AS3.19

OClO as observed by TROPOMI on Sentinel 5P

Janis Pukite, Christian Borger, Steffen Dörner, and Thomas Wagner

The TROPOspheric Monitoring Instrument (TROPOMI) is an UV-VIS-NIR-SWIR instrument on board of Sentinel-5P satellite developed for monitoring the Earth’s atmosphere. It was launched on 13 October 2017 in a near polar orbit. It measures spectrally resolved earthshine radiances at an unprecedented spatial resolution of around 3.5x7.2 km2 (3.5x5.6 km2 starting from 6 Aug 2019) (near nadir) with a total swath width of ~2600 km on the Earth's surface providing daily global coverage. From the measured spectra high resolved trace gas distributions can be retrieved by means of differential optical absorption spectroscopy (DOAS).

Chlorine dioxide (OClO) is a by-product of the ozone depleting halogen chemistry in the stratosphere. Although being rapidly photolysed at low solar zenith angles (SZAs) it plays an important role as an indicator of the chlorine activation in polar regions during polar winter and spring at twilight conditions because of the nearly linear relation of its formation to chlorine oxide (ClO).

Here we present a new DOAS retrieval algorithm of the slant column densities (SCDs) of chlorine dioxide (OClO) and correlate this TROPOMI OClO signal with meteorological data for both Antarctic and Arctic regions.

How to cite: Pukite, J., Borger, C., Dörner, S., and Wagner, T.: OClO as observed by TROPOMI on Sentinel 5P, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11831, https://doi.org/10.5194/egusphere-egu2020-11831, 2020.

EGU2020-13715 | Displays | AS3.19

Retrieval of chlorine dioxide columns from Sentinel-5p observations

Andreas Carlos Meier, Andreas Richter, Gaia Pinardi, Michel Van Roozendael, and John Philip Burrows

The Sentinel-5-precursor (S5p) satellite with the TROPOMI payload was launched on 13 October 2017. It is part of the European Copernicus program and provides a set of operational products of atmospheric constituents related to air quality and climate change with almost daily global coverage. The good signal to noise ratio of the instrument enables precise measurements despite the fine spatial resolution of 3.5 x 5.5 km2. 


The ESA S5p+ Innovation activity aims at extending the list of S5p products with scientific products, which are not yet part of the operational processor, to exploit the potential of the Sentinel-5p mission’s capabilities beyond its primary objectives. The retrieval of chlorine dioxide (OClO) from S5p is among the seven funded sub projects. Chlorine dioxide is an indicator for chlorine activation in the stratosphere and thus of importance for the understanding of stratospheric ozone chemistry, in particular in the polar vortex. Chlorine dioxide was retrieved from heritage instruments (GOME, SCIAMACHY, GOME2, OMI) and the S5p OClO product will act as a continuation of these time-series.


Here we present the current status of the IUP-Bremen S5p OClO product developed within the ESA S5p+ Innovation framework. The new S5p product will be put into context with products from previous and current (e.g. GOME-2c) satellite missions as well as ground-based measurements used for validation.

How to cite: Meier, A. C., Richter, A., Pinardi, G., Van Roozendael, M., and Burrows, J. P.: Retrieval of chlorine dioxide columns from Sentinel-5p observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13715, https://doi.org/10.5194/egusphere-egu2020-13715, 2020.

EGU2020-15056 | Displays | AS3.19

Comparison of one year of XCH4 and XCO measurements using a EM27/SUN low resolution FTIR spectrometer to S5P/TROPOMI methane and carbon monoxide columns at Thessaloniki, Greece

Chrysanthi Topaloglou, Marios Mermigkas, Maria-Elissavet Koukouli, Dimitrios Balis, Frank Hase, Jochen Landgraf, and Ilse Aben

The column-averaged dry air mole fractions of carbon dioxide (XCO2), methane (XCH4) and carbon monoxide (XCO) have been measured for the first time for a whole year in Thessaloniki, Greece, using the portable Bruker EM27/SUN ground-based low-resolution Fourier Transform spectrometer, provided by the Karlsruhe Institute of Technology. The EM27/SUN is a reliable, easy-to-deploy, mobile, low-cost supplement to the Bruker IFS 125HR, a high-resolution spectrometer used in the Total Carbon Column Observing Network (TCCON). Approximately 30 of the EM27/SUN instruments constitute the Collaborative Carbon Column Observing Network (COCCON), with stations around the globe for the quantification of local sinks and sources, working as an important supplement of TCCON to increase the global density of column-averaged greenhouse gas observations

One year of measurements of XCH4 and XCO are presented for Thessaloniki, Greece. The station is located in the center of the city. The data are compared to collocated measurements from S5P/TROPOMI using 50km and ±30 min as criteria. For the XCH4 comparisons, the ground based XCH4 is constantly found to be lower than the satellite product. However, for ground based retrievals of XCH4 using the TROPOMI algorithm and IR band, the comparison with the satellite data shows a percentage difference lower than ±2%, well within product requirements. Satellite XCO is also compared to ground observations to examine if EM27/SUN concentrations are reproduced by S5P/TROPOMI and whether the temporal variations are captured

 

 

Aknowledgments

This work was co-funded by ESA within the Contract No. 4000117151/16/l-LG “Preparation and Operations of the Mission Performance Centre (MPC) for the Copernicus Sentinel-5 Precursor Satellite”. The satellite data were obtained through Sentinel-5P Expert Users Data Hub (https://s5pexp.copernicus.eu/).

This research was co-funded by the project "PANhellenic infrastructure for Atmospheric Composition and climatE change" (MIS 5021516) which is implemented under the Action "Reinforcement of the Research and Innovation Infrastructure", funded by the Operational Programme "Competitiveness, Entrepreneurship and Innovation" (NSRF 2014-2020) and co-financed by Greece and the European Union (European Regional Development Fund).

How to cite: Topaloglou, C., Mermigkas, M., Koukouli, M.-E., Balis, D., Hase, F., Landgraf, J., and Aben, I.: Comparison of one year of XCH4 and XCO measurements using a EM27/SUN low resolution FTIR spectrometer to S5P/TROPOMI methane and carbon monoxide columns at Thessaloniki, Greece, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15056, https://doi.org/10.5194/egusphere-egu2020-15056, 2020.

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Retrieval of Stable Water Vapour Isotopologues from the TROPOMI Instrument

Tim Trent, Hartmut Boesch, Peter Somkuti, Matthias Schneider, Farahnaz Khosrawi, Christopher Diekmann, and Harald Sodemann

Atmospheric moisture is a crucial factor for the redistribution of heat in the atmosphere, with a strong coupling between atmospheric circulation and moisture pathways which are responsible for most climate feedback mechanisms. Conventional satellite and in situ measurements provide information on water vapour content and vertical distribution; however, observations of water isotopologues make a unique contribution to a better understanding of this coupling.

In recent years, observations of water vapour isotopologue from satellites have become available from nadir thermal infrared measurements (TES, AIRS, IASI) which are sensitive to the free troposphere and from shortwave-infrared (SWIR) sensors (GOSAT, SCIAMACHY) that provide column-averaged concentrations including sensitivity to the boundary layer. The TROPOMI instrument on-board Sentinel 5P (S5p) measures SWIR radiance spectra that allow retrieval of water isotopologue columns but with much improved spatial and temporal coverage compared to other SWIR sensors promising a step-change for scientific and operational applications.

Here we present the development of the retrieval algorithm for water isotopologues from TROPOMI as part of the ESA S5p Innovation programme.  We also discuss the validation of these type of satellite products with fiducial in situ measurements and challenges when comparing with other satellite measurements. Finally, we outline the roadmap for assessing the impact of TROPOMI data against state-of-the-art isotope enabled models.

How to cite: Trent, T., Boesch, H., Somkuti, P., Schneider, M., Khosrawi, F., Diekmann, C., and Sodemann, H.: Retrieval of Stable Water Vapour Isotopologues from the TROPOMI Instrument, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16046, https://doi.org/10.5194/egusphere-egu2020-16046, 2020.

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Retrieving H2O/HDO above clouds using TROPOMI SWIR measurements

Andreas Schneider, Tobias Borsdorff, Joost aan de Brugh, Alba Lorente Delgado, and Jochen Landgraf

The current scientific H2O/HDO data product from short-wave infrared reflectance measurements by the Tropospheric Monitoring Instrument (TROPOMI) is retrieved using a profile-scaling approach with a forward model which ignores scattering. Since water is too dark in the short-wave infrared, the coverage is limited to clear-sky scenes over land. Clouds are relatively bright in this spectral region, thus retrievals over low clouds will greatly enlarge the coverage. To do so, retrievals using a forward model which accounts for scattering and fitting effective cloud parameters additionally to the trace gases are examined. Inferred effective cloud parameters are compared with measurements by the Visible Infrared Imaging Radiometer Suite (VIIRS) to optimise the cloud model. Furthermore, the impact on the validation of the retrieved H2O/HDO columns with collocated measurements by the Total Carbon Column Observing Network (TCCON) is discussed.

How to cite: Schneider, A., Borsdorff, T., aan de Brugh, J., Lorente Delgado, A., and Landgraf, J.: Retrieving H2O/HDO above clouds using TROPOMI SWIR measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5878, https://doi.org/10.5194/egusphere-egu2020-5878, 2020.

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Total Column Water Vapour Retrieval from S-5P/TROPOMI in the Visible Blue Spectral Range

Christian Borger, Steffen Beirle, Steffen Dörner, Holger Sihler, and Thomas Wagner

Atmospheric water plays a key role for the Earth’s energy budget and temperature distribution via radiative effects (clouds and vapour) and latent heat transport. Thus, the distribution and transport of water vapour are closely linked to atmospheric dynamics on different spatio-temporal scales. In this context, global monitoring of the water vapour distribution is essential for numerical weather prediction, climate modeling and a better understanding of climate feedbacks.

Here, we present a total column water vapour (TCWV) retrieval using the absorption structures of water vapour in the visible blue spectral range. The retrieval consists of the common two-step DOAS approach: first the spectral analysis is performed within a linearized scheme. Then, the retrieved slant column densities are converted to vertical column densities (VCDs) using an iterative scheme for the water vapour a priori profile shape which is based on an empirical parameterization of the water vapour scale height.  

We apply this novel retrieval to measurements of the TROPOspheric Monitoring Instrument (TROPOMI) onboard ESA‘s Sentinel-5P satellite and compare our retrieved H2O VCDs to a variety of different reference data sets. Furthermore we present a detailed characterization of this retrieval including theoretical error estimations for different observation conditions. In addition we investigate the impact of different input data sets (e.g. surface albedo) on the retrieved H2O VCDs.  

How to cite: Borger, C., Beirle, S., Dörner, S., Sihler, H., and Wagner, T.: Total Column Water Vapour Retrieval from S-5P/TROPOMI in the Visible Blue Spectral Range, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3408, https://doi.org/10.5194/egusphere-egu2020-3408, 2020.

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Validation of the S5P Formaldehyde L2 product using MAX-DOAS network observations

Isabelle De Smedt, Gaia Pinardi, Corinne Vigouroux, Steven Compernolle, Kai Uwe Eichman, Bavo Langerock, Christophe Lerot, Nicolas Theys, Jonas Vlietinck, Huan Yu, Fabian Romahn, Pascal Hedelt, Zhibin Cheng, Jean-Christopher Lambert, Diego Loyola, and Michel Van Roozendael and the NIDFORVAL HCHO team

The Sentinel-5 Precursor (S5P) was launched on the 13th of October 2017, with on board the TROPOspheric Monitoring Instrument (TROPOMI). The formaldehyde (HCHO) L2 product is operational since the end of 2018. The prototype of the tropospheric HCHO retrieval algorithm is developed at BIRA-IASB and implemented at the German Aerospace Center (DLR) in the S5P operational processor (De Smedt et al., 2018).

In this work, we investigate the quality of the HCHO tropospheric column product and its validation within the MPC framework (Mission Performance Center) and the S5PVT NIDFORVAL project (S5P NItrogen Dioxide and FORmaldehyde VALidation). Within NIDFORVAL, the S5P HCHO product has been validated using the full FTIR and MAXDOAS dataset. Validation results have been assessed against reported product uncertainties taking into account the full comparison error budget, showing that the product quality reaches its requirements.

Here, we focus on satellite-satellite comparison based on the OMI QA4ECV HCHO product and on ground-based validation using MAX-DOAS and Pandora network observations. About 15 HCHO measuring stations are involved, providing data corresponding to a wide range of observation conditions at mid and low latitudes, and covering remote, sub-urban, and urban polluted sites. Comparison results show usually negative biases for large HCHO columns, while a positive offset is observed for the lowest columns. For the MAX-DOAS stations providing vertical profile retrievals, the impact of a priori profiles on the comparison is assessed. The dataset allows to discuss validation results as a function of emission source. Seasonal and diurnal variations are compared. Long term variation are also monitored using the OMI and MAX-DOAS QA4ECV dataset.

How to cite: De Smedt, I., Pinardi, G., Vigouroux, C., Compernolle, S., Eichman, K. U., Langerock, B., Lerot, C., Theys, N., Vlietinck, J., Yu, H., Romahn, F., Hedelt, P., Cheng, Z., Lambert, J.-C., Loyola, D., and Van Roozendael, M. and the NIDFORVAL HCHO team: Validation of the S5P Formaldehyde L2 product using MAX-DOAS network observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18189, https://doi.org/10.5194/egusphere-egu2020-18189, 2020.

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Sentinel-4 Instrument Data Simulator

Nan Hao and Sebastian Gimeno Garcia

The Sentinel-4 (S4) mission, the first imaging spectrometer instrument to be flown on Meteosat Third Generation Sounding (MTG-S) satellite in geostationary orbit, will provide accurate data on an hourly basis of trace gases and aerosols over Europe and Northern Africa for climate, air quality, ozone and surface UV applications. It features bands in the ultraviolet (305-400 nm), and visible (400-500 nm) with a spectral resolution of 0.5 nm and in the near-infrared (750-775 nm) ranges with a spectral resolution of 0.12 nm.

To provide simulated S4-UVN instrument data, we are working to prepare the Instrument Data Simulator (IDS). IDS is supposed to provide test data for the L1b Processor and provide capability for instrument performance and calibration monitoring. The IDS consists of two main blocks: the Scene Generator (SG) simulates the radiance/irradiance at the entrance of the instrument and the Instrument Simulator (IS) simulates the response of the instrument on the input signal. The S4-UVN IS follows as much as possible the instrument forward model and will be developed using a ’travelling spectrum’ approach. In this approach, the flux in the instrument or signal and noise is modified step-by-step by a series of algorithms representing the effects of the different components of the instrument on signal when flowing through the instrument. The IDS architecture, instrument forward model and the preliminary output of IDS will be introduced.

How to cite: Hao, N. and Gimeno Garcia, S.: Sentinel-4 Instrument Data Simulator, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20489, https://doi.org/10.5194/egusphere-egu2020-20489, 2020.

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Independent a priori information for reduced intercomparison errors between TROPOMI and TCCON retrievals of methane and carbon monoxide

Johannes Lutzmann, Ralf Sussmann, Huilin Chen, Frank Hase, Rigel Kivi, Kimberly Strong, Aki Tsurata, and Thorsten Warneke

Ground-based column measurements of trace gases by FTIR spectrometers within the Total Carbon Column Observing Network (TCCON) provide accurate ground reference for the validation of the nadir-viewing hyperspectral Tropospheric Monitoring Instrument (TROPOMI) on-board the ESA satellite Sentinel 5 Precursor (S-5P). In such intercomparisons of two independent remote soundings, errors can occur as the a priori profiles used in the respective retrievals are i) differing from each other, and ii) both different from the true atmospheric state at the moment of observation. In certain conditions of atmospheric dynamics, e.g. polar vortex subsidence or stratospheric intrusions, which strongly alter the shape of vertical concentration profiles, these intercomparison errors can become considerable (Ostler et al., 2014).

In our work funded by the German Space Agency DLR and performed as part of the ESA AO project TCCON4S5P, we search for potential sources of realistic common a priori profiles for S-5P and TCCON CH4 and CO measurements which reduce these large errors. We examine the performance of a number of chemical transport models and data assimilation systems in reproducing dynamical effects and in minimizing intercomparison errors. In-situ profiles measured by AirCores are used as validation where they are available. We present the status and results of our ongoing work.

Reference:

Ostler, A., Sussmann, R., Rettinger, M., Deutscher, N. M., Dohe, S., Hase, F., Jones, N., Palm, M., and Sinnhuber, B.-M.: Multistation intercomparison of column-averaged methane from NDACC and TCCON: impact of dynamical variability, Atmos. Meas. Tech., 7, 4081–4101, doi:10.5194/amt-7-4081-2014, 2014. Ostler, A., Sussmann, R., Rettinger, M., Deutscher, N. M., Dohe, S., Hase, F., Jones, N., Palm, M., and Sinnhuber, B.-M.: Multistation intercomparison of column-averaged methane from NDACC and TCCON: impact of dynamical variability, Atmos. Meas. Tech., 7, 4081–4101, doi:10.5194/amt-7-4081-2014, 2014.

How to cite: Lutzmann, J., Sussmann, R., Chen, H., Hase, F., Kivi, R., Strong, K., Tsurata, A., and Warneke, T.: Independent a priori information for reduced intercomparison errors between TROPOMI and TCCON retrievals of methane and carbon monoxide, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19764, https://doi.org/10.5194/egusphere-egu2020-19764, 2020.

EGU2020-20883 | Displays | AS3.19

TROPOMI Aerosol Index: detailed aerosol plume tracking and plans for future development

Deborah Stein Zweers, Maarten Sneep, Maurits Kooreman, Piet Stammes, Gijsbert Tilstra, Erwin Loots, and Thomas Wagner

The aerosol index (AER_AI) as calculated using data from the Tropospheric Monitoring Instrument (TROPOMI) onboard the ESA Sentinel 5 Precursor (S5P) platform was publically released in July 2018. The operational AER_AI dataset is available from May 2018 through the present. It is a useful data product not only for tracking ultraviolet (UV) absorbing aerosol plumes of desert dust, volcanic ash, and smoke from biomass burning but also for monitoring the quality of the TROPOMI Level 1b (L1b) data since the AER_AI calculation is very sensitive to the absolute calibration of irradiance and radiance. The aim of this work is first to highlight the new level of detail seen in aerosol plume events based on the recent switch to a reduced pixel size of 3.5 x 5.5 km. Such high spatial resolution also presents specific challenges as non-Lambertian cloud features and 3-D effects of clouds are now visible in the TROPOMI AER_AI data. Plans for an approach to flag and correct these features in future AER_AI updates will be given. Secondly this work will include an overview of the impacts on AER_AI due to observed degradation in the TROPOMI measured irradiance and wavelength-dependent features in the radiance. As a result of these L1b effects, there is a steadily increasing negative bias in the global mean AER_AI value. Examples are given how the new version of the L1b data (2.0.0) will be used to correct for this degradation-driven bias. Recommendations are also given to guide data users looking to perform trend analysis or those using AER_AI as a filter for aerosol removal or detection in other L2 data products.  

How to cite: Stein Zweers, D., Sneep, M., Kooreman, M., Stammes, P., Tilstra, G., Loots, E., and Wagner, T.: TROPOMI Aerosol Index: detailed aerosol plume tracking and plans for future development, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20883, https://doi.org/10.5194/egusphere-egu2020-20883, 2020.

EGU2020-21731 | Displays | AS3.19

Atmospheric Mission Data Packaging (AMiDA)

Stefano Natali, Clemens Rendl, Daniel Santillan, Marcus Hirtl, Barbara Scherllin-Pirscher, Andreas Hangler, Alexander Cede, Axel Kreuter, and Christian Retscher

The scientific and industrial communities are handling continuously increasing amounts of data from Earth Observation (EO) satellite missions and related instruments. This is in particular the case for the atmospheric sciences communities, with the recently launched Copernicus Sentinel-5 Precursor, the upcoming Sentinel-4, -5, and ESA’s Earth Explorers scientific satellites ADM-Aeolus and EarthCARE, but also heritage missions such as ENVISAT, MetOp and OMI Aura. However, the challenge is not only to manage the large volume of data generated by each mission / sensor, but also to manage the data variety. Tools are needed to be able to rapidly and trustfully identify, from all available datasets of a specific region for a specific timeframe, all available products for a selected field (e.g. ozone, trace gases) and prepare these data into a format that is ready to be extracted and used /analyzed (Analysis-Ready Data, ARD). Exploiting potential synergies to maximise the use of data from various sources will be key to harness the full potential of the available information. In summary, there is a need of an “intelligent” packaging of subsets of the available data tailored to the users’ needs.

The scope of the “Atmospheric Mission Data Packaging” (AMiDA) project is to design, implement, and demonstrate the functionalities of an infrastructure for access and distribution of a wide variety of EO data in the field of atmospheric sciences: heritage, current, and future missions will be managed by the platform, to allow the users accessing, visualizing, and downloading a meaningful subset of this growing data stream.

AMiDA (https://amida.adamplatform.eu/en/) makes use of the baseline functionalities provided by the TOP platform (http://top-platform.eu/) that already allows accessing and manipulating a large variety of satellite, model, and non-satellite remotely sensed data. TOP is empowered with spatial and temporal homogenization and packaging capabilities to create, from heterogeneous data sources (e.g., SO2 total column data from different satellites and numerical models) a single data structure (local data cube) for simultaneous exploitation of various data sources. The data cube can be exploited through the TOP tools (web application, Jupyter notebook and APIs) and downloaded by the user.

A comprehensive demonstration campaign will be performed through five main use cases to demonstrate the capability of AMiDA.

AMiDA is currently in its final development phase, thus the scope of the contribution is to present the initiative, preliminary results, and stimulate the discussion with potential users, analyzing their needs and see if and how they can use AMiDA to facilitate their everyday professional life.

How to cite: Natali, S., Rendl, C., Santillan, D., Hirtl, M., Scherllin-Pirscher, B., Hangler, A., Cede, A., Kreuter, A., and Retscher, C.: Atmospheric Mission Data Packaging (AMiDA), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21731, https://doi.org/10.5194/egusphere-egu2020-21731, 2020.

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ACTRIS efforts for Sentinel 5 Precursor validation

Lucia Mona, Nikolaos Papagiannopoulus, Gelsomina Pappalardo, Ulla Wandinger, Giuseppe D'Amico, Vassilis Amiridis, Lucas-Alados Arboledas, Doina Nicolae, Arnoud Apituley, Ewan O'Connor, and Jana Pressler

The Sentinel 5 Precursor products, call for an accurate validation. Europe can be nowadays regarded as a leader in ground-based vertical profiling observations. ACTRIS (Aerosols, Clouds, and Trace gases Research InfraStructure Network) is an EC funded infrastructure integrating European ground-based stations equipped with advanced atmospheric equipment. Among these, EARLINET (European Aerosol Research Lidar NETwork) and Cloudnet are well-established networks providing vertical profiles of aerosol and clouds with high vertical and temporal resolution. A network of ground-based stations has the ability to provide the spatio-temporal development of aerosol and cloud fields and offers a unique opportunity for the validation of observations from space. In this project, state-of-the-art instrumentations for observing aerosol and clouds will be used for validation purposes: multi-wavelength lidar (EARLINET) and Doppler cloud radar (Cloudnet).

Characterization of aerosol and cloud fields over the stations is provided by the use of EARLINET and Cloudnet data. Additional information is provided by AERONET data where available. Differences will be reported as a function of aerosol load, aerosol and cloud height, aerosol type, cloud type and underneath surface.

First results of validation efforts performed within ACTRIS in terms of a quantitative evaluation of the accuracy of S5P aerosol and cloud products will be reported. This activity is done under the EC-ACTS: Earlinet and Cloudnet - Aerosol and Clouds Teams for Sentinel-5P Validation unfunded project, which comprises 3 EARLINET/Cloudnet stations [Potenza (IT), Leipzig (DE) and Cabauw (NL)]; 3 EARLINET stations [Granada (ES), Athens (GR) and Bucharest (RO)] and 2 Cloudnet sites [Mace Head (IE) and Sodankylä (FI)].

In particular, the first results will be about the S5P Aerosol Layer Height (mandatory product) and Aerosol Optical Depth (optional product) and whenever available the AAI-based columnar Aerosol Type product.

How to cite: Mona, L., Papagiannopoulus, N., Pappalardo, G., Wandinger, U., D'Amico, G., Amiridis, V., Arboledas, L.-A., Nicolae, D., Apituley, A., O'Connor, E., and Pressler, J.: ACTRIS efforts for Sentinel 5 Precursor validation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21815, https://doi.org/10.5194/egusphere-egu2020-21815, 2020.

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Technology and atmospheric mission platform - OPerations (TOP)

Stefano Natali, Clemens Rendl, Gerhard Triebnig, Daniel Santillan, Marcus Hirtl, and Barbara Scherllin-Pirscher

The ongoing rise in missions to observe Earth from space, especially the various Copernicus’ Sentinel systems not only increases the volume of data daily, but also contributes to the variety of data, the velocity of data availability, and its veracity. In this scenario, Sentinel 5P has already changed the way in which chemical atmospheric components are monitored daily, providing data with global coverage and a very detailed spatial resolution.

The discipline of atmospheric sciences poses an additional difficulty in efficiently accessing and analysing all available data: the variety is high as the source of atmospheric data is threefold with data coming from EO systems, models as well as in-situ measurements. The heterogeneity and multidimensionality of the so-called data triangle (EO, model, and in-situ data) make an efficient exploitation of the full potential of the available information even more challenging.

Following the successful experience of the Technology and Atmospheric Mission Platform (TAMP), TOP (http://top-platform.eu/ ) implements the concept of operational Virtual Research Environment (VRE), allowing data users to access, visualize, process, and download heterogeneous, multidimensional data.

Based on the ADAM datacube technology (https://adamplatform.eu), TOP allows exploiting the following datasets: Sentinel 5P Level 2 products (NO2 and O3 tropospheric columns, SO2, CO, and CH4 total columns, and aerosol index); Copernicus Atmosphere Monitoring Service (CAMS) global (surface PM10, total column NO2, SO2, and O3) and regional (surface PM10, NO2, SO2 and O3) analysis and forecast fields; European Environmental Agency (EEA) measurements (CO, NO2, PM10, SO2).

Users can visualize and process all available data through a web application user interface (Data Analysis and Visualization Environment – DAVE), through a Jupyter notebook interface, and using the ADAM APIs and libraries to directly access available data.

TOP is deployed on the Mundi DIAS infrastructure (https://mundiwebservices.com/). This allows accessing always most recent satellite products (reprocessed, offline, near real time), model output (analyses and forecasts – up to 5 days) and station measurements (full archive, updated daily).

TOP is the first operational platform with the data triangle implemented. By creating an atmospheric multi-source data cube, it stimulates a multi-disciplinary scientific approach and significantly facilitates scientific professional life.

How to cite: Natali, S., Rendl, C., Triebnig, G., Santillan, D., Hirtl, M., and Scherllin-Pirscher, B.: Technology and atmospheric mission platform - OPerations (TOP), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19392, https://doi.org/10.5194/egusphere-egu2020-19392, 2020.

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Comparisons between Sentinel-5P TROPOMI NO2 and the European ensemble air quality forecasts of CAMS

John Douros, Henk Eskes, and Pepijn Veefkind

How to cite: Douros, J., Eskes, H., and Veefkind, P.: Comparisons between Sentinel-5P TROPOMI NO2 and the European ensemble air quality forecasts of CAMS, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8514, https://doi.org/10.5194/egusphere-egu2020-8514, 2020.

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New-generation OMI NO2 Standard Product: Algorithm description and initial results

Lok Lamsal, Nickolay Krotkov, Alexander Vasilkov, Sergey Marchenko, Joanna Joiner, Wenhan Qin, Eun-Su Yang, William Swartz, Sungyeon Choi, Zachary Fasnacht, David Haffner, and Bradford Fisher

We present our new and improved version (version 4.0) of the NASA standard nitrogen dioxide (NO2) product from the Ozone Monitoring Instrument (OMI) on the Aura satellite. This version incorporates the most important improvements proposed for regional OMI NO2 products by expert users, and enhances NO2 data quality on a global scale through improvements in the Air Mass Factors (AMFs) in several ways. The algorithm is based on a conceptually new, geometry-dependent Lambertian surface equivalent reflectivity (GLER) operational product. GLER is calculated using the vector radiative transfer model VLIDORT, which uses as input high–resolution bidirectional reflectance distribution function (BRDF) information from NASA’s Aqua MODIS instrument over land and the wind-dependent Cox–Munk wave-facet slope distribution over water, the latter with a contribution from the water-leaving radiance. The GLER and our corresponding, consistently retrieved effective cloud fraction and O2-O2 optical centroid cloud pressures provide inputs to the new NO2 AMF algorithm, which increases tropospheric NO2 by up to 50% in highly polluted areas; the differences include both cloud and surface BRDF effects as well as biases between the MODIS and OMI-based surface reflectance data sets. We assess the new product using independent observations from ground-based and airborne instruments. The improved NO2 data record could be beneficial for studies related to emissions and trends of nitrogen oxides (NOx) and co-emitted gases.

How to cite: Lamsal, L., Krotkov, N., Vasilkov, A., Marchenko, S., Joiner, J., Qin, W., Yang, E.-S., Swartz, W., Choi, S., Fasnacht, Z., Haffner, D., and Fisher, B.: New-generation OMI NO2 Standard Product: Algorithm description and initial results, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10230, https://doi.org/10.5194/egusphere-egu2020-10230, 2020.

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Copernicus Sentinel-5 Precursor Routine Validation

Angelika Dehn, Claus Zehner, Lidia Saavedra De Miguel, Jean-Christopher Lambert, Pepijn Veefkind, and Diego Loyola

Copernicus Sentinel-5 Precursor (S-5P) is the first of a series of atmospheric chemistry missions within the European Commission’s Copernicus Programme, launched successfully in October 2017 and since end April 2018 in its operational phase. S-5P provides continuity in the availability of global atmospheric data products between its predecessor missions SCIAMACHY (Envisat) and OMI (AURA) and the future Sentinel-4 and -5 series. S-5P delivers unique data regarding the sources and sinks of trace gases with a focus on the lower Troposphere including the planet boundary layer due to its enhanced spatial, temporal and spectral sampling capabilities as compared to its predecessors.

The S-5P satellite carries a single payload, namely TROPOMI (TROPOspheric Monitoring Instrument) that was jointly developed by The Netherlands and ESA. Covering spectral channels in the UV, visible, near- and short-wave infrared, it measures various key species including tropospheric/stratospheric ozone, NO2, SO2, CO, CH4, CH2O as well as cloud and aerosol parameters.

The geophysical validation and characterization of the TROPOMI data products during the phase E2 is conducted by ESA at different levels. The so-called Mission Performance Center carries out the routine validation throughout the mission life-time and rely on the availability of independent data sets for example from ground-based measurements or the so-called Fiducial Reference Measurement data sets, as well as the contributions from independent national Validation Teams coordinated by ESA under the Sentinel 5 Precursor Validation Team (S5PVT).

The current status of the ESA S-5P routine Validation activities will be discussed in this paper.

How to cite: Dehn, A., Zehner, C., Saavedra De Miguel, L., Lambert, J.-C., Veefkind, P., and Loyola, D.: Copernicus Sentinel-5 Precursor Routine Validation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16568, https://doi.org/10.5194/egusphere-egu2020-16568, 2020.

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Assessment of the S-5P tropospheric NO2 product based on coincident airborne APEX observations over polluted regions

Frederik Tack, Alexis Merlaud, Marian-Daniel Iordache, Gaia Pinardi, Ermioni Dimitropoulou, Henk Eskes, Bart Bomans, and Michel Van Roozendael

Sentinel-5 Precursor (S-5P), launched in October 2017, is the first mission of the Copernicus Programme dedicated to the monitoring of air quality and climate. Its characteristics, such as the fine spatial resolution, introduce many new opportunities and challenges, requiring to carefully assess the quality and validity of the generated data products by comparison with independent reference observations.

In the presented study, the S-5P/TROPOMI tropospheric nitrogen dioxide (NO2) L2 product (3.5 x 7 km2 at nadir observations) has been validated over strongly polluted urban regions based on comparison with coincident high-resolution airborne remote sensing observations (~100 m2). Airborne imagers are able to map the horizontal distribution of tropospheric NO2, as well as its strong spatio-temporal variability, at high resolution and with high accuracy. Satellite products can be optimally assessed based on airborne observations as a large amount of satellite pixels can be fully mapped in a relatively short time interval, reducing the impact of spatiotemporal mismatches. Additionally, such data sets allow to study the TROPOMI subpixel variability and impact of signal smoothing due to its finite satellite pixel size, typically coarser than fine-scale gradients in the urban NO2 field.

In the framework of the S5PVAL-BE campaign, the Airborne Prism EXperiment (APEX) imaging spectrometer has been deployed during four mapping flights (26-29 June 2019) over the two largest urban regions in Belgium, i.e. Brussels and Antwerp, in order to map the horizontal distribution of tropospheric NO2. Per flight, 15 to 20 TROPOMI pixels were fully covered by approximately 5000 APEX measurements for each TROPOMI pixel. Mapping flights and ancillary ground-based measurements (car-mobile DOAS, MAX-DOAS, CIMEL, ceilometer, etc.) were conducted in coincidence with the overpass of TROPOMI (typically between noon and 2 PM UTC). The TROPOMI and APEX NO2 vertical column density (VCD) retrieval schemes are similar in concept. Retrieved NO2 VCDs were georeferenced, gridded and intercompared. As strongly polluted areas typically exhibit strong NO2 vertical gradients (besides the strong horizontal gradients), a custom TROPOMI tropospheric NO2 product was computed and compared as well with APEX by replacing the coarse 1° x 1° a priori NO2 vertical profiles from TM5-MP by NO2 profile shapes from the CAMS regional CTM ensemble at 0.1° x 0.1°.

Overall for the ensemble of the four flights, the standard TROPOMI NO2 VCD product is well correlated (R= 0.94) but biased low (slope = 0.73) with respect to APEX NO2 retrievals. When replacing the TM5-MP a priori NO2 profiles by CAMS-based profiles, the slope increases to 0.88. When calculating the NO2 VCD differences, the bias is on average -1.3 ± 1.2 x 1015 molec cm-2 or -16% ± 11% for the difference between APEX NO2 VCDs and the standard TROPOMI NO2 VCD product. The bias is substantially reduced when replacing the coarse TM5-MP a priori NO2 profiles by CAMS-based profiles, being -0.1 ± 1.1  x 1015 molec cm-2 or -0.1% ± 11%. Both sets of retrievals are well within the accuracy requirement of a maximum bias of 25-50% for the TROPOMI tropospheric NO2 product for all individual compared pixels.

How to cite: Tack, F., Merlaud, A., Iordache, M.-D., Pinardi, G., Dimitropoulou, E., Eskes, H., Bomans, B., and Van Roozendael, M.: Assessment of the S-5P tropospheric NO2 product based on coincident airborne APEX observations over polluted regions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19261, https://doi.org/10.5194/egusphere-egu2020-19261, 2020.

EGU2020-15036 | Displays | AS3.19

Quality assessment of two years of Sentinel-5p TROPOMI NO2 data

Tijl Verhoelst, Steven Compernolle, José Granville, Arno Keppens, Gaia Pinardi, Jean-Christopher Lambert, Kai-Uwe Eichmann, Henk Eskes, Sander Niemeijer, Ann Mari Fjæraa, Andrea Pazmoni, Florence Goutail, Jean-Pierre Pommereau, Alexander Cede, and Martin Tiefengraber

For more than two years now the first atmospheric satellite of the Copernicus EO programme, Sentinel-5p (S5P) TROPOMI, has acquired spectral measurements of the Earth radiance in the visible range, from which near-real-time (NRTI) and offline (OFFL) processors retrieve operationally the total, tropospheric and stratospheric  column abundance of atmospheric NO2.  In support of these routine operations, the S5P Mission Performance Centre (MPC) performs continuous QA/QC of these data products and produces key Quality Indicators enabling users to verify the fitness-for-purpose of the S5P data. Quality Indicators are derived from comparisons to ground-based reference data, both station-by-station in monitoring mode in the S5P Automated Validation Server (AVS) and globally in more complex in-depth analyses.  Complementary quality information is obtained from product intercomparisons (NRTI vs. OFFL) and from satellite-to-satellite comparisons.  After two years of successful operation we present here a consolidated overview of the quality of the S5P TROPOMI NO2 data products delivered publicly.

S5P NO2 data are compared routinely to ground-based network measurements collected through either the ESA Validation Data Centre (EVDC) or network data archives (NDACC, PGN). Direct-sun measurements from the Pandonia Global Network (PGN) serve as a reference for total NO2 validation, Multi-Axis DOAS network data for tropospheric  NO2 validation, and NDACC zenith-scattered-light DOAS network data for stratospheric NO2 validation.  Comparison methods are optimized to limit spatial and temporal mismatch to a minimum (information-based spatial co-location strategy, photochemical adjustment to account for local time measurement difference). Comparison results are analyzed to derive Quality Indicators and to conclude on the compliance w.r.t. the mission requirements. This include estimates of: (1) the bias, as proxy for systematic errors, (2) the dispersion of the differences, which combines random errors with seasonal and irreducible mismatch errors, and (3) the dependence of bias and dispersion on key influence quantities (surface albedo, cloud cover…)

Intercomparison of S5P products (NRTI vs. OFFL) and comparison to other satellite data, including a similar processing of OMI measurements, complement the ground-based validation with relative biases and spatio-temporal patterns/artefacts related to instrumental issues (e.g. striping) and to the sensitivity to geophysical features (e.g. clouds and sea/ice albedo contrast).  

Overall, the MPC quality assessment of S5P NO2 data concludes to an excellent performance for the stratospheric column data (bias2 vs. ground-based data. This dispersion larger than the mission requirement on data precision can partly be attributed to comparisons errors such as those due to differences in horizontal resolution. Total column data are found to be biased low by 20%, with a 30% station-to-station scatter. After gridding to monthly means on a 0.8°x0.4° grid, comparisons to OMI data yield a much smaller dispersion (within the requirement of 0.7Pmolec/cm2), and a minor relative bias. NRTI and OFFL perform similarly, even if they occasionally differ in specific cases of direct comparisons.       

How to cite: Verhoelst, T., Compernolle, S., Granville, J., Keppens, A., Pinardi, G., Lambert, J.-C., Eichmann, K.-U., Eskes, H., Niemeijer, S., Fjæraa, A. M., Pazmoni, A., Goutail, F., Pommereau, J.-P., Cede, A., and Tiefengraber, M.: Quality assessment of two years of Sentinel-5p TROPOMI NO2 data , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15036, https://doi.org/10.5194/egusphere-egu2020-15036, 2020.

EGU2020-1895 | Displays | AS3.19

Evaluation of TROPOMI Tropospheric NO2 VCDs over China

Kai Qin, Qin He, and Jincheng Shi

The Tropospheric Monitoring Instrument (TROPOMI) with a higher spatial resolution is a push broom UVIS spectrometer carried on the S5P satellite which was launched on October 13th, 2017.  But compared to the widely used OMI and GOME-2, TROPOMI NO2 products have not been extensively used in China. To evaluate the TROPOMI NO2 products, we present a comparison between TROPOMI NO2 products and MAX-DOAS observations in Xuzhou, eastern China from April 2018 to September 2019. We find a high correlation, but a clear underestimation. We find that solar zenith angle, viewing zenith angle, the cloud fraction and wind speed will affect the evaluation results. We examine the retrievals of TROPOMI tropospheric NO2 over China, contrasting them with the retrievals of OMI. We find that TROPOMI has better ability to resolve smallscale plumes and distinguish the distribution of NO2 concentration on a city scale. Our goal is to support the application of TROPOMI for NO2 observations and deriving emissions from urban or industrial facilities over China.

How to cite: Qin, K., He, Q., and Shi, J.: Evaluation of TROPOMI Tropospheric NO2 VCDs over China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1895, https://doi.org/10.5194/egusphere-egu2020-1895, 2020.

EGU2020-17626 | Displays | AS3.19

Impact of 3D cloud structures on tropospheric NO2 column measurements from UV-VIS sounders

Huan Yu, Arve Kylling, Claudia Emde, Bernhard Mayer, Kerstin Stebel, Michel Van Roozendael, and Ben Veihelmann

Operational retrievals of tropospheric trace gases from space-borne spectrometers are made using 1D radiative transfer models. To minimize cloud effects generally only partially cloudy pixels are analysed using simplified cloud contamination treatments based on radiometric cloud fraction estimates and photon path length corrections based on oxygen collision pair (O2-O2) or O2A-absorption band measurements. In reality, however, the impact of clouds can be much more complex, involving scattering of clouds in neighbouring pixels and cloud shadow effects. Therefore, to go one step further, other correction methods may be envisaged that use sub-pixel cloud information from co-located imagers. Such methods require an understanding of the impact of clouds on the real 3D radiative transfer. We quantify this impact using the MYSTIC 3D radiative transfer model. The generation of realistic 3D input cloud fields, needed by MYSTIC (or any other 3D radiative transfer model), is non-trivial. We use cloud data generated by the ICOsahedral Non-hydrostatic (ICON) atmosphere model for a region including Germany, the Netherlands and parts of other surrounding countries. The model simulates realistic liquid and ice clouds with a horizontal spatial resolution of 156 m and it has been validated against ground-based and satellite-based observational data.

As a trace gas example, we study NO2, a key tropospheric trace gas measured by the atmospheric Sentinels. The MYSTIC 3D model simulates visible spectra, which are ingested in standard DOAS retrieval algorithms to retrieve the NO2 column amount. Spectra are simulated for a number of realistic cloud scenarios, snow free surface albedos, and solar and satellite geometries typical of low-earth and geostationary orbits. The retrieved NO2 vertical column densities (VCD) are compared with the true values to identify conditions where 3D cloud effects lead to significant biases on the NO2 VCDs. A variety of possible mitigation strategies for such pixels are then explored.

How to cite: Yu, H., Kylling, A., Emde, C., Mayer, B., Stebel, K., Van Roozendael, M., and Veihelmann, B.: Impact of 3D cloud structures on tropospheric NO2 column measurements from UV-VIS sounders, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17626, https://doi.org/10.5194/egusphere-egu2020-17626, 2020.

EGU2020-19372 | Displays | AS3.19

The Complete Data Fusion as a ready to use tool for the exploitation of atmospheric Sentinel ozone profiles

Nicola Zoppetti, Simone Ceccherini, Flavio Barbara, Samuele Del Bianco, Marco Gai, Gabriele Poli, Cecilia Tirelli, and Ugo Cortesi

Remote sounding of atmospheric composition makes use of satellite measurements with very heterogeneous characteristics. In particular, the determination of vertical profiles of gases in the atmosphere can be performed using measurements acquired in different spectral bands and with different observation geometries. The most rigorous way to combine heterogeneous measurements of the same quantity in a single Level 2 (L2) product is simultaneous retrieval. The main drawback of simultaneous retrieval is its complexity, due to the necessity to embed the forward models of different instruments into the same retrieval application. To overcome this shortcoming, we developed a data fusion method, referred to as Complete Data Fusion (CDF), to provide an efficient and adaptable alternative to simultaneous retrieval. In general, the CDF input is any number of profiles retrieved with the optimal estimation technique, characterized by their a priori information, covariance matrix (CM), and averaging kernel (AK) matrix. The output of the CDF is a single product also characterized by an a priori, a CM and an AK matrix, which collect all the available information content. To account for the geo-temporal differences and different vertical grids of the fusing profiles, a coincidence and an interpolation error have to be included in the error budget.
In the first part of the work, the CDF method is applied to ozone profiles simulated in the thermal infrared and ultraviolet bands, according to the specifications of the Sentinel 4 (geostationary) and Sentinel 5 (low Earth orbit) missions of the Copernicus program. The simulated data have been produced in the context of the Advanced Ultraviolet Radiation and Ozone Retrieval for Applications (AURORA) project funded by the European Commission in the framework of the Horizon 2020 program. The use of synthetic data and the assumption of negligible systematic error in the simulated measurements allow studying the behavior of the CDF in ideal conditions. The use of synthetic data allows evaluating the performance of the algorithm also in terms of differences between the products of interest and the reference truth, represented by the atmospheric scenario used in the procedure to simulate the L2 products. This analysis aims at demonstrating the potential benefits of the CDF for the synergy of products measured by different platforms in a close future realistic scenario, when the Sentinel 4, 5/5p ozone profiles will be available.
In the second part of this work, the CDF is applied to a set of real measurements of ozone acquired by GOME-2 onboard the MetOp-B platform. The quality of the CDF products, obtained for the first time from operational products, is compared with that of the original GOME-2 products. This aims to demonstrate the concrete applicability of the CDF to real data and its possible use to generate Level-3 (or higher) gridded products.
The results discussed in this presentation offer a first consolidated picture of the actual and potential value of an innovative technique for post-retrieval processing and generation of Level-3 (or higher) products from the atmospheric Sentinel data.

How to cite: Zoppetti, N., Ceccherini, S., Barbara, F., Del Bianco, S., Gai, M., Poli, G., Tirelli, C., and Cortesi, U.: The Complete Data Fusion as a ready to use tool for the exploitation of atmospheric Sentinel ozone profiles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19372, https://doi.org/10.5194/egusphere-egu2020-19372, 2020.

EGU2020-11221 | Displays | AS3.19

Ground-based and satellite measurements of the SO2 plume from the eruption of Raikoke volcano in June 2019

Vitali Fioletov, Chris Sioris, Xiaoyi Zhao, Debora Griffin, Chris McLinden, Michael Brohart, Sum Chi Lee, Simon Carn, Kristof Bognar, Kimberly Strong, Jingqiu Mao, Nicolas Theys, Diego Loyola, Pascal Hedelt, Nickolay Krotkov, Can Li, and Chris Boone

The eruption of the Raikoke volcano (Kuril Islands) on June 21-22, 2019, created a large plume of sulfur dioxide (SO2) that reached the upper troposphere and lower stratosphere. The plume persisted in the atmosphere over the middle and high latitudes of the Western Hemisphere for more than a month creating a rare validation opportunity with multiple collocated measurements from ground and space both revealing enhanced SO2 vertical column densities (VCDs). Moreover, since the plume was often located over high latitudes, multiple orbits per day from the polar orbiting satellites could be utilized. Pandora sunphotometer measurements at Edmonton and Eureka, Canada, and at Fairbanks, Alaska, and Brewer spectrophotometer measurements at seven Canadian sites (Saturna, Edmonton, Churchill, Resolute, Eureka, and Alert) reported SO2 values up to 15 Dobson Units (DU, where 1 DU = 2.69 × 1016 molecules/cm²). These measurements were compared with satellite SO2 VCDs obtained by the Sentinel 5p TROPOspheric Monitoring Instrument (TROPOMI), AURA Ozone Monitoring Instrument (OMI), and Suomi NPP Ozone Mapping Profiling Suite (OMPS). Back-trajectory Lagrangian model analysis and satellite SO2 profile measurements by the Atmospheric Chemistry Experiment mission Fourier transform spectrometer (ACE/FTS) on board the Canadian satellite SCISAT demonstrated that the volcanic plume was located at 8-25 km. In general, ground-based and satellite measurements show a very good agreement. However, the exact ground-based and satellite viewing geometry should be considered when such measurements are taken near the edge of the plume.

How to cite: Fioletov, V., Sioris, C., Zhao, X., Griffin, D., McLinden, C., Brohart, M., Lee, S. C., Carn, S., Bognar, K., Strong, K., Mao, J., Theys, N., Loyola, D., Hedelt, P., Krotkov, N., Li, C., and Boone, C.: Ground-based and satellite measurements of the SO2 plume from the eruption of Raikoke volcano in June 2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11221, https://doi.org/10.5194/egusphere-egu2020-11221, 2020.

EGU2020-10480 | Displays | AS3.19

Atmospheric methane monitoring and analysis using tropOMI retrievals at ECMWF.

Jerome Barre, Ilse Aben, Melanie Ades, Anna Agusti-Panareda, Gianpaolo Balsamo, Nicolas Bousserez, Margarita Choulga, Richard Engelen, Johannes Flemming, Antje Inness, Zak Kipling, Jochen Landgraf, Alba Lorente-Delgado, Sebastien Massart, Joe McNorton, Mark Parrington, and Vincent-Henri Peuch

The European Union’s Copernicus Atmosphere Monitoring Service (CAMS) operationally provides daily forecasts of global atmospheric composition. It uses the ECMWF Integrated Forecasting System (IFS), which includes meteorological and atmospheric composition variables, such as reactive gases, greenhouse gases and aerosols, for its global forecasts and reanalyses. The current green-house gases operational suite monitors CH4 and CO2 and assimilates TANSO and IASI retrievals for both species. The TROPOspheric Monitoring Instrument (TROPOMI) on board the Sentinel-5 Precursor (S5P) satellite launched in October 2017 yields a wealth of atmospheric composition data, including CH4 retrievals at unprecedented high horizontal resolution (7km) and up to daily revisit time. We used the IFS to perform monitoring experiments at different horizontal resolutions (25 km and 9 km). We also performed first data assimilation experiments at 25 km horizontal resolution.

This first set of monitoring experiments shows the potential of the TROPOMI CH4 retrievals to correct known biases that exist in the current CAMS analyses and forecasts. Assimilation experiments of TROPOMI CH4 shows that adding the instrument in the operational chain would significantly improve the analysis and forecasts. Detection of CH4 sources seen by TROPOMI compared to CAMS also shows the potential of the instrument to inform on and infer anthropogenic and natural sources. For example, discrepancies between TROPOMI retrievals and CAMS fields in the CH4 levels associated with oil and gas extraction activities show very promising perspectives for monitoring and analysis of CH4 concentration and emissions. We will finally discuss the challenges and progress made towards performing inversions using the IFS operational system.  

How to cite: Barre, J., Aben, I., Ades, M., Agusti-Panareda, A., Balsamo, G., Bousserez, N., Choulga, M., Engelen, R., Flemming, J., Inness, A., Kipling, Z., Landgraf, J., Lorente-Delgado, A., Massart, S., McNorton, J., Parrington, M., and Peuch, V.-H.: Atmospheric methane monitoring and analysis using tropOMI retrievals at ECMWF., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10480, https://doi.org/10.5194/egusphere-egu2020-10480, 2020.

AS3.20 – Halogens in the Troposphere

EGU2020-19391 | Displays | AS3.20

Global observation of iodic acid (HIO3)

Xucheng He, Tuija Jokinen, Nina Sarnela, Lisa Beck, Heikki Junninen, Matti Rissanen, Wei Nie, Chao Yan, Deniz Kemppainen, Douglas Worsnop, Mikko Sipilä, and Markku Kulmala

Trace iodine vapours have a significant impact on atmospheric chemistry, influencing catalytic ozone destruction and the HOx / NOx cycles. Oxidized iodine species also form aerosols in coastal and polar regions (O’Dowd et al, 2002), playing a direct role in Earth’s radiation balance. It was recently shown that iodic acid (HIO3) has a significant impact on coastal new particle formation processes (Sipilä et al., 2016). However, neutral HIO3 molecules have only been measured in two sites (Sipilä et al., 2016).

In this study, a global observation of HIO3 has been carried out in ten sites around the globe, including city sites, Arctic and Antarctica sites, a remote island site, a coastal site and a boreal forest site. While the existence of HIO3 is unambiguously revealed in all of the sites, its concentration varies significantly among them. Dedicated laboratory experiments are required to examine the particle formation rates from iodine-containing species to be able to predict their global importance in particle formation, and further, in cloud condensation nuclei formation.

 

O’Dowd, C. D. et al. Marine aerosol formation from biogenic iodine emissions. Nature 417, 632–6 (2002)

Sipilä, M. et al. Molecular-scale evidence of aerosol particle formation via sequential addition of HIO3. Nature 537, 532–534 (2016).

 

How to cite: He, X., Jokinen, T., Sarnela, N., Beck, L., Junninen, H., Rissanen, M., Nie, W., Yan, C., Kemppainen, D., Worsnop, D., Sipilä, M., and Kulmala, M.: Global observation of iodic acid (HIO3), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19391, https://doi.org/10.5194/egusphere-egu2020-19391, 2020.

EGU2020-2870 | Displays | AS3.20

The first steps of iodine gas-to-particle conversion as seen in the lab: constraints on the role of iodine oxides and oxyacids

Juan Carlos Gomez Martin, Tom Lewis, Manoj Kumar, John Plane, Joseph Francisco, and Alfonso Saiz-Lopez

The photooxidation of gas phase iodine-bearing molecules emitted by marine biota leads to intense particle nucleation events in the coastal and polar marine boundary layer1-3. The ubiquity of iodine in the marine atmospheric environment4-7 has suggested that this may be a previously unrecognized global source of new aerosol particles8. Atmospheric modeling is required in order to evaluate the importance of this process, but a substantial lack of understanding of the gas-to-particle conversion mechanism is hindering this effort, especially regarding the gas phase chemistry of the nucleating molecules (iodine oxides9,10 and/or oxyacids7) and the formation kinetics of molecular clusters. To address this problem, we have conducted new flow tube laboratory experiments where pulsed laser photolysis or continuous broad-band photolysis of I2/O3 mixtures  in air are used to generate iodine radicals in the presence of atmospherically representative mixing ratios of water vapor. The molecular reactants and the resulting molecular products are detected by time-resolved VUV laser photo-ionization time-of-flight mass spectrometry. High-level quantum chemistry and master equation calculations and gas kinetics modelling are used to analyse the experimental data. In this presentation we discuss our results and their implications for the interpretation of field meassurements and for the implementatiion of an iodine oxide particle formation mechanism in atmospheric models.

References:

1. Hoffmann, T., O'Dowd, C. D. & Seinfeld, J. H. Iodine oxide homogeneous nucleation: An explanation for coastal new particle production. Geophys. Res. Lett. 28, 1949-1952 (2001).

2. McFiggans, G. et al. Direct evidence for coastal iodine particles from Laminaria macroalgae - linkage to emissions of molecular iodine. Atmos. Chem. Phys. 4, 701-713 (2004).

3. O'Dowd, C. D. et al. Marine aerosol formation from biogenic iodine emissions. Nature 417, 632-636 (2002).

4. Prados-Roman, C. et al. Iodine oxide in the global marine boundary layer. Atmos. Chem. Phys. 15, 583-593, doi:10.5194/acp-15-583-2015 (2015).

5. Schönhardt, A. et al. Simultaneous satellite observations of IO and BrO over Antarctica. Atmos. Chem. Phys. 12, 6565-6580, doi:10.5194/acp-12-6565-2012 (2012).

6. Mahajan, A. S. et al. Concurrent observations of atomic iodine, molecular iodine and ultrafine particles in a coastal environment. Atmos. Chem. Phys. 10, 27227-27253 (2010).

7. Sipilä, M. et al. Molecular-scale evidence of aerosol particle formation via sequential addition of HIO3. Nature 537, 532-534, doi:10.1038/nature19314 (2016).

8. Saiz-Lopez, A. et al. Atmospheric Chemistry of Iodine. Chem. Rev. 112, 1773–1804, doi:DOI: 10.1021/cr200029u (2012).

9. Gómez Martín, J. C. et al. On the mechanism of iodine oxide particle formation. Phys. Chem. Chem. Phys. 15, 15612-15622, doi:10.1039/c3cp51217g (2013).

10. Saunders, R. W., Mahajan, A. S., Gómez Martín, J. C., Kumar, R. & Plane, J. M. C. Studies of the Formation and Growth of Aerosol from Molecular Iodine Precursor. Z. Phys. Chem. 224, 1095-1117 (2010).

How to cite: Gomez Martin, J. C., Lewis, T., Kumar, M., Plane, J., Francisco, J., and Saiz-Lopez, A.: The first steps of iodine gas-to-particle conversion as seen in the lab: constraints on the role of iodine oxides and oxyacids, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2870, https://doi.org/10.5194/egusphere-egu2020-2870, 2020.

EGU2020-16783 | Displays | AS3.20

A novel spectroscopic approach for detection of chlorine reservoir species: HCl-TILDAS

John Halfacre, Pete Edwards, Scott Herndon, Joseph Roscioli, Christoph Dyroff, Tara Yacovitch, Nicholas Marsden, Thomas Bannan, Carl Percival, Hugh Coe, Patrick Veres, and Steven Brown

Atomic chlorine radicals are known to affect atmospheric oxidation and pollutant lifetimes, but are challenging to detect due to their low ambient concentrations.  A lack of field observations limits useful assessments of the impacts of tropospheric chlorine oxidation on important atmospheric processes, such as regional ozone production, reactive nitrogen loss, and global methane removal.  In the last decade, instrumental innovations have enabled detection and speciation of much more stable chlorine atom reservoir species, such as nitryl chloride, through techniques such as cavity ring down spectroscopy and mass spectrometry.  HCl is the most abundant and long-lived tropospheric chlorine reservoir species, yet few observations exist.  Here, we present a specific method for detection of HCl via Tunable Laser Infrared Direct Absorption Spectrometer (TILDAS), which has been further extended for the detection of nitryl chloride.  This analytical method has several advantages over current observational techniques (e.g. chemical ionisation mass spectrometry), and will provide a much needed constraint on the tropospheric chlorine atom budget.

How to cite: Halfacre, J., Edwards, P., Herndon, S., Roscioli, J., Dyroff, C., Yacovitch, T., Marsden, N., Bannan, T., Percival, C., Coe, H., Veres, P., and Brown, S.: A novel spectroscopic approach for detection of chlorine reservoir species: HCl-TILDAS, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16783, https://doi.org/10.5194/egusphere-egu2020-16783, 2020.

EGU2020-9439 | Displays | AS3.20

Direct Detection of Atmospheric Atomic Bromine Leading to Mercury and Ozone Depletion

Kerri Pratt, Siyuan Wang, Stephen McNamara, Christopher Moore, Daniel Obrist, Alexandra Steffen, Paul Shepson, Ralf Staebler, and Angela Raso

Bromine atoms play a central role in atmospheric reactive halogen chemistry, depleting ozone and elemental mercury, thereby enhancing deposition of toxic mercury, particularly in the Arctic near-surface troposphere. Yet, direct bromine atom measurements have been missing to date, due to the lack of analytical capability with sufficient sensitivity for ambient measurements. Here we present direct atmospheric bromine atom measurements, conducted in the springtime Arctic near Utqiagvik, Alaska in March 2012. Measured bromine atom levels reached up to 14 ppt (4.2×108 atoms cm-3) and were up to 3-10 higher than estimates using previous indirect measurements not considering the critical role of molecular bromine. Observed ozone and elemental mercury depletion rates are quantitatively explained by the measured bromine atoms, providing field validation of highly uncertain mercury chemistry. Following complete ozone depletion, elevated bromine concentrations are sustained by photochemical snowpack emissions of molecular bromine and nitrogen oxides, resulting in continued atmospheric mercury depletion. This study shows that measured bromine atoms, resulting from photochemical snowpack production of molecular bromine, can quantitatively explain ozone and mercury loss in the near-surface polar atmosphere.

How to cite: Pratt, K., Wang, S., McNamara, S., Moore, C., Obrist, D., Steffen, A., Shepson, P., Staebler, R., and Raso, A.: Direct Detection of Atmospheric Atomic Bromine Leading to Mercury and Ozone Depletion, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9439, https://doi.org/10.5194/egusphere-egu2020-9439, 2020.

EGU2020-3091 | Displays | AS3.20

Reactive bromine chemistry in the Rann of Kachchh salt desert

Jonas Kuhn, Vinod Kumar, Thomas Wagner, Simon Warnach, and Ulrich Platt

The Rann of Kachchh is a salt desert in the southern border area of India and Pakistan. Recently, high amounts of bromine monoxide (BrO) were observed there in satellite measurements of the Ozone Monitoring Instrument (OMI). Release mechanisms of reactive bromine, dominating chemical processes, the influence of the ambient atmosphere and transport processes, etc. are not well understood in general. Furthermore, due to their short time scales these processes are difficult to assess with satellite instruments, which only offer a single measurement per day with limited spatial resolution.

Here, we present BrO, HCHO and nitrogen dioxide (NO2) measurements from ground-based MAX DOAS performed at two different locations in the Rann of Kachchh salt desert in Gujarat, India during three weeks in March and April 2019. We observe large amounts of BrO building up during daytime reaching maxima of several tens of ppt in the late afternoon. Additional mobile measurements performed directly over the salt gave similar results to the measurements at 5-15 km distance from the salt surface, suggesting that the BrO formation time scale and effective life times during daytime are at least of the order of several minutes to a few hours. Additional in-situ ozone measurements indicate ozone depletion events linked to the episodes of high BrO abundance. This indicates that BrO is formed by bromine atoms reacting with ozone and then being recycled via BrO self-reaction and heterogeneous processes involving aerosol surfaces, as proposed for other environments (Polar Regions, volcanic plumes).

While we found high but steady HCHO levels, the observed NO2 levels showed a distinct anti-correlation to BrO, indicating coupling of bromine- and NOx-chemistry and thereby the influence of the pollution level of the ambient atmosphere. Formation of bromine nitrate probably delays the formation of large BrO amounts, but might also support the recycling of bromine atoms through heterogeneous chemistry.

How to cite: Kuhn, J., Kumar, V., Wagner, T., Warnach, S., and Platt, U.: Reactive bromine chemistry in the Rann of Kachchh salt desert, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3091, https://doi.org/10.5194/egusphere-egu2020-3091, 2020.

EGU2020-10892 | Displays | AS3.20

Using WRF-Chem Volcano to model the in-plume halogen chemistry of Etna’s 2018 eruption

Luke Surl, Simon Warnach, Thomas Wagner, Tjarda Roberts, and Slimane Bekki

Volcanic eruptions emit halogen-containing species in varying quantities, with their emission ratio to tracer species such SO2 varying between volcanoes, eruptions, and even phases of an eruptive event.

The bromine explosion is known to occur within volcanic plumes, converting bromine from HBr – the primary form in which it is emitted – to other forms, including the spectroscopically detectable BrO. Measurements of BrO have been made in the plumes of many volcanoes from both ground-based and satellite-based instruments. There also exist a small number of measurements of OClO.

We present results from WRF-Chem Volcano (WCV), a modified version of the three-dimensional regional atmospheric chemistry and transport model WRF-Chem and associated utilities. We have simulated the Christmas 2018 eruptive event of Mount Etna using a nested implementation the model at maximum lateral resolution of 1km, as well as a weaker emission plume representing Etna’s more common quiescent degassing state. The plume of this 2018 eruption was observed remotely by the TROPOMI instrument.

WCV is able to model the transport and dispersion of the plume. We compare these model outputs to the satellite observations and use this to estimate the volcanic emission column height.

In terms of chemistry, WCV is able to reproduce the bromine explosion and the major features of the satellite observation – including a cross-plume variation in the BrO/SO2 column ratio. We find that variations in the BrO/SO2 ratio are primarily caused by variations in the concentration of ozone. Ozone is consumed by bromine chemistry and is replenished by the mixing in of ozone-rich background air. This creates a zone of low ozone in the core of the plume which is consequently low in BrO and surrounded by a higher-ozone edge with a higher BrO/SO2 ratio.

For the temporal evolution of the plume, we find that the bromine-chemistry of a concentrated emission plume can be divided into four phases, also governed by ozone availability. In the last phase ozone limitation is minimal and the proportion of bromine in the form of BrO (and the BrO/SO2 ratio) is approximately stable. We find this stable regime also with a simulation of a weaker emission plume. These results could facilitate the use of remote-sensing BrO measurements as a means of quantifying total bromine emissions from volcanoes.

Oxidized forms of chlorine are modelled to be formed within the plume due to the heterogenous reaction of HOBr with HCl, forming BrCl that photolyzes and produces Cl radicals. We also investigate the extent to which mercury could be oxidized by halogens within the plume.

How to cite: Surl, L., Warnach, S., Wagner, T., Roberts, T., and Bekki, S.: Using WRF-Chem Volcano to model the in-plume halogen chemistry of Etna’s 2018 eruption, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10892, https://doi.org/10.5194/egusphere-egu2020-10892, 2020.

EGU2020-5355 | Displays | AS3.20 | Highlight

Natural halogens buffer tropospheric ozone in a changing climate

Fernando Iglesias-Suarez, Alba Badia, Rafael P. Fernandez, Carlos A. Cuevas, Douglas E. Kinnison, Simone Tilmes, Jean-François Lamarque, Mathew C. Long, Ryan Hossaini, and Alfonso Saiz-Lopez

Reactive atmospheric halogens destroy tropospheric ozone (O3), an air pollutant and greenhouse gas. The primary source of natural halogens is emissions from marine phytoplankton and algae, as well as abiotic sources from ocean and tropospheric chemistry, but how their fluxes will change under climate warming –and the resulting impacts on O3– are not well known. Here we use an Earth system model to estimate that natural halogens deplete approximately 13 % of tropospheric O3 in the present-day climate. Despite increased levels of natural halogens through the twenty-first century, this fraction remains stable due to compensation from hemispheric, regional, and vertical heterogeneity in tropospheric O3loss. Notably, this halogen-driven O3 buffering is projected to be greatest over polluted and populated regions, mainly due to iodine chemistry, with important implications for air quality.

How to cite: Iglesias-Suarez, F., Badia, A., Fernandez, R. P., Cuevas, C. A., Kinnison, D. E., Tilmes, S., Lamarque, J.-F., Long, M. C., Hossaini, R., and Saiz-Lopez, A.: Natural halogens buffer tropospheric ozone in a changing climate, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5355, https://doi.org/10.5194/egusphere-egu2020-5355, 2020.

EGU2020-990 | Displays | AS3.20

Iodine chemistry in the tropical and remote open ocean marine boundary layer

Swaleha Inamdar, Liselotte Tinel, Rosie Chance, Lucy Jane Carpenter, Sabu Prabhakaran, Racheal Chacko, Sarat Chandra Tripathy, Anvita Ulhas Kerkar, Alok Kumar Sinha, Bhaskar Parli Venkateswaran, Amit Sarkar, Rajdeep Roy, Tomas Sherwen, Carlos Alberto Cuevas, Alfonso Saiz-Lopez, Kirpa Ram, and Anoop Sharad Mahajan

Iodine chemistry plays an essential role in controlling the radiation budget by changing various atmospheric parameters. Iodine in the atmosphere is known to cause depletion of ozone via catalytic reaction cycles. It alters the atmospheric oxidation capacity, and lead to ultrafine particle formation that acts as potential cloud condensation nuclei. The ocean is the primary source of iodine; it enters the atmosphere through fluxes of gaseous reactive iodine species. At the ocean surface, seawater iodide reacts with tropospheric ozone (gas) to form inorganic iodine species in gaseous form. These species namely, hypoiodous acid (HOI) and molecular iodine (I2) quickly photolyse to release reactive iodine (I) in the atmosphere. This process acts as a significant sink for tropospheric ozone contributing to ~16% ozone loss throughout the troposphere. Reactive iodine released in the atmosphere undergoes the formation of iodine monoxide (IO) or higher oxides of iodine (IxOx) via self-recombination reactions. It is known that inorganic iodine fluxes (HOI and I2) contribute to 75% of the detected IO over the Atlantic Ocean. However, we did not observe this from ship-based MAX-DOAS studies between 2014-2017. At present, there are no direct observations of inorganic iodine (HOI; few for I2) and are estimated via empirical methods derived from the interfacial kinetic model by Carpenter et al. in 2013. Based on the kinetic model, estimation of HOI and I2 fluxes depends on three parameters, namely, ozone concentration, surface iodide concentration, and the wind speed. This parameterisation for inorganic fluxes assumes a sea surface temperature (SST) of 293 K and has limiting wind speed conditions. Since the parameterisation conditions assumed SST of 293 K higher uncertainties due to errors in activation energy creeps in the estimation of HOI flux compared to I2 as the flux of HOI is ~20 times greater than that of I2. For three consecutive expeditions in the Indian and Southern Ocean, we detected ~1 pptv of IO in the marine boundary layer. These levels are not explained by the calculated inorganic fluxes by using observed and predicted sea surface iodide concentrations. This method of iodine flux estimation is currently used in all global models, along with the MacDonald et al. 2014 iodide estimation method. Model output using these parameterisations have not been able to match the observed IO levels in the Indian and Southern Ocean region. This discrepancy suggests that the process of efflux of iodine to the atmosphere may not be fully understood, and the current parametrisation does not do justice to the observations. It also highlights that the flux of organic iodine may also play a role in observed IO levels, especially in the Indian Ocean region. A correlation of 0.7 was achieved above the 99% confidence limit for chlorophyll-a with observed IO concentration in this region. There is a need to carry more observations to improve the estimation technique of iodine sea-air flux thus improving model predictions of IO in the atmosphere.

How to cite: Inamdar, S., Tinel, L., Chance, R., Jane Carpenter, L., Prabhakaran, S., Chacko, R., Chandra Tripathy, S., Ulhas Kerkar, A., Kumar Sinha, A., Parli Venkateswaran, B., Sarkar, A., Roy, R., Sherwen, T., Alberto Cuevas, C., Saiz-Lopez, A., Ram, K., and Sharad Mahajan, A.: Iodine chemistry in the tropical and remote open ocean marine boundary layer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-990, https://doi.org/10.5194/egusphere-egu2020-990, 2020.

EGU2020-3004 | Displays | AS3.20

Potential Effect of Halogens on Atmospheric Oxidation in China

Qinyi Li, Alba Badia, Tao Wang, Golam Sarwar, Xiao Fu, Li Zhang, Qiang Zhang, Jimmy Fung, Carlos A. Cuevas, Shanshan Wang, Bin Zhou, and Alfonso Saiz-Lopez

Air pollution has been a hazard in China over recent decades threatening the health of half a billion people. Much effort has been devoted to mitigating air pollution in China leading to a tremendous reduction in primary pollutants emissions from 2013 to 2017, while a continuously worsening trend of surface ozone (O3, a secondary pollutant and greenhouse gas) was observed over the same period. Atmospheric oxidation, dominated by daytime reactions involving hydroxyl radicals (OH), is the critical process to convert freshly-emitted compounds into secondary pollutants, and is underestimated in current models of China’s air pollution. Halogens (chlorine, bromine, and iodine) are known to profoundly influence oxidation chemistry in the marine environment; however, their impact on atmospheric oxidation and air pollution in China is unknown. In the present study, we report for the first time that halogens substantially enhance the total atmospheric oxidation capacity in polluted areas of China, typically 10% to 20% (up to 87% in winter) and mainly by significantly increasing OH level. The enhanced oxidation along the coast is driven by oceanic emissions of bromine and iodine, and that over the inland areas by anthropogenic emission of chlorine. The extent and seasonality of halogen impact are largely explained by the dynamics of Asian monsoon, location and intensity of halogen emissions, and O3 formation regime. The omission of halogen emissions and chemistry may lead to significant errors in historical re-assessments and future projections of the evolution of atmospheric oxidation in polluted regions.

How to cite: Li, Q., Badia, A., Wang, T., Sarwar, G., Fu, X., Zhang, L., Zhang, Q., Fung, J., Cuevas, C. A., Wang, S., Zhou, B., and Saiz-Lopez, A.: Potential Effect of Halogens on Atmospheric Oxidation in China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3004, https://doi.org/10.5194/egusphere-egu2020-3004, 2020.

EGU2020-3022 | Displays | AS3.20

Atmospheric iodine chemistry from molecular level to 0D/3D simulations: applications to Fukushima nuclear accident

Florent Louis, Sonia Taamalli, Valérie Fèvre-Nollet, Qinyi Li, Carlos A. Cuevas, and Alfonso Saiz-Lopez

In the case of a hypothetical nuclear accident, fission products are released into the environment. Simulation tools are commonly used to predict the radiological consequences on populations. After the Fukushima accident, significant differences have been observed between measured and modeled concentrations for iodine 131. This can be attributed to the high reactivity of iodine in the atmosphere not considered in the current dispersion crisis tools.

To address this, a new gas-phase mechanism of atmospheric iodine chemistry was developed containing 248 reactions. In parallel, missing thermokinetic data were determined by molecular-scale simulations for iodous and iodic acids. The 0D simulation results showed a partial and rapid transformation of these iodinated gaseous compounds. The influence of several parameters (air quality, quantity and nature of iodine released) was evaluated. For all simulations, iodine is quickly found in the form of iodine oxides and nitroxides or gaseous iodinated organic compounds. The latter may be the cause of iodinated aerosols formation and deposition.

Results from the 3D chemistry-climate model CAM-Chem will be compared to iodine Fukushima deposits measurements. Implications for atmospheric chemistry (air quality and climate) will be discussed.

How to cite: Louis, F., Taamalli, S., Fèvre-Nollet, V., Li, Q., Cuevas, C. A., and Saiz-Lopez, A.: Atmospheric iodine chemistry from molecular level to 0D/3D simulations: applications to Fukushima nuclear accident, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3022, https://doi.org/10.5194/egusphere-egu2020-3022, 2020.

Ice is ubiquitous and one of the most important environmental reaction media on earth. Generally, chemical reactions take place slowly when temperature decreases according to Arrhenius Equation(k=A·e-EA/RT). Recently, it has been found that several chemical processes are accelerated by freezing compared to those in aqueous phase. Reactive iodine species (I, I2, IO, OIO, HOI) in atmosphere are related to ozone depletion event (ODE) and new particle formation (NPF) in polar troposphere, and finally affect climate change. It was reported that the high concentration of halogen compounds(IO, BrO) in austral spring in Antarctica but the exact mechanism and sources are not fully understood. The biological production of halogens are regarded as the major source of organic and I2. However, the (photo)chemical reactions to produce reactive iodine species are also regarded as possible mechanism to explain the high atmospheric iodine budget. In this presentation, I want to introduce enhanced chemical reaction with laboratory experimental results such as 1)accelerated oxidation of iodide(I-) in ice to produce molecular iodine(I2) and tri-iodide(I3-), 2)nitrite-induced activation of iodate(IO3-) into molecular iodine in frozen solution. The detailed experimental conditions and mechanism will be discussed in the presentation.

How to cite: Kim, K.: Redox chemical processes of iodine species with inorganic compounds in ice, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3179, https://doi.org/10.5194/egusphere-egu2020-3179, 2020.

EGU2020-3520 | Displays | AS3.20

The history of Holocene atmospheric iodine over the North Atlantic

Carlos Alberto Cuevas, Juan Pablo Corella, Niccolo Maffezzoli, Paul Vallelonga, Andrea Spolaor, Giulio Cozzi, Juliane Müller, Bo Vinther, Carlo Barbante, Helle Astrid Kjaer, Ross Edwards, and Alfonso Saiz-Lopez

How to cite: Cuevas, C. A., Corella, J. P., Maffezzoli, N., Vallelonga, P., Spolaor, A., Cozzi, G., Müller, J., Vinther, B., Barbante, C., Kjaer, H. A., Edwards, R., and Saiz-Lopez, A.: The history of Holocene atmospheric iodine over the North Atlantic, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3520, https://doi.org/10.5194/egusphere-egu2020-3520, 2020.

EGU2020-5035 | Displays | AS3.20

Tropospheric Ozone Depletion Events in the Arctic Spring of 2009: Modeling and Observations

Maximilian Herrmann, Holger Sihler, Ulrich Platt, and Eva Gutheil

Ozone is an important atmospheric pollutant in the troposphere due to its high oxidation potential. In the Arctic troposphere, ozone mainly originates from transport and photo-chemical reactions involving nitrogen oxides and volatile organic compounds, resulting in a background mixing ratio of 30 to 50 nmol/mol. During polar spring, so-called tropospheric ozone depletion events (ODEs) are regularly observed, in which ozone mixing ratios in the boundary layer drop to almost zero levels coinciding with a surge in reactive bromine levels on the time scale of hours to days. The source of the reactive bromine is sea salt, i.e. aerosol and deposits on the ice. However, it is not fully understood how the salt bromide is oxidized and reactive bromine is released into the air. The most widely accepted emission mechanism is autocatalytic and termed “bromine explosion”. ODEs strongly change the lifetime of ozone and organic gases, they cause the removal and deposition of mercury as well as the transport of reactive bromine into the free troposphere. In order to model ODEs, the software package WRF-Chem is employed to simulate the meteorology and the emission, the transport, mixing, chemical reactions of trace gases as well as aerosols. For this purpose, the MOZART chemical reaction mechanism coupled with the MOSAIC aerosol model is extended to include bromine and chlorine chemistry. A resolution of 20 km for a 5,000 km x 5,000 km region in horizontal directions is employed, enabling the comparison of the simulation results to satellite GOME-2 BrO with a larger resolution. In vertical direction, 64 non-linear grid cells are used with a finer resolution near the ground. The simulation domain is centered north of Barrow (Utqiaġvik), Alaska and covers most of the Arctic region. The time from February 1 to May 1, 2009 is simulated. Improvements and differences to existing models include more complex bromine chemistry, the inclusion of chlorine chemistry, MOSAIC aerosols, and nudging of meteorological fields to ERA-INTERIM data.The simulations reveal that the first bromine explosions occur in early February in the Bering Sea and then extend to the Beaufort Sea in the middle of February, with further bromine explosions in the Arctic region through the end of the simulation. Simulations results are compared with the GOME-2 BrO measurements and in-situ ozone observations at Barrow (Utqiaġvik), Alaska. The comparison shows good agreement with respect to occurrence and location of ODEs. The simulations indicate that the existence and replenishment of bromine in the sea ice is necessary for the ODEs to occur throughout the observation time. Inclusion of direct release of bromine by the deposition of ozone is essential for the proper prediction of the frequent recurrence of ODEs as found through observations. The largest uncertainty in the model is the strength of the bromine deposition and emission from the ice/snow surface as well as the amount of available bromine in the sea salt, which is varied in a parameter study.

How to cite: Herrmann, M., Sihler, H., Platt, U., and Gutheil, E.: Tropospheric Ozone Depletion Events in the Arctic Spring of 2009: Modeling and Observations , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5035, https://doi.org/10.5194/egusphere-egu2020-5035, 2020.

EGU2020-8752 | Displays | AS3.20

Towards an operational CAPRAM multiphase halogen and DMS chemistry treatment in the chemistry transport model COSMO-MUSCAT

Erik Hans Hoffmann, Andreas Tilgner, Roland Schrödner, Ralf Wolke, and Hartmut Herrmann

Oceans are the general emitter of dimethyl sulfide (DMS), the major natural sulfur source, and halides and cover approximately 70 % of Earth’s surface. The main DMS oxidation products are SO2, H2SO4 and methyl sulfonic acid (MSA). Hence, DMS is very important for formation of non-sea salt sulfate (nss‑SO42-) aerosols and secondary particulate matter and thus global climate. Reactive halogen compounds, activated by multiphase chemistry processes, are known to effectively deplete ozone, oxidise VOCs (especially DMS under marine conditions) and remove NOx from the atmosphere by conversion into particulate nitrate. Despite many previous model studies, a detailed representation of the multiphase chemistry occurring in aqueous aerosols and cloud droplets in CTMs is still missing.

To develop a detailed representation, a manual reduction of near-explicit multiphase chemistry mechanisms by means of detailed box model studies has been performed. The mechanism has been developed from the near-explicit DMS and halogen multiphase chemistry mechanism, CAPRAM DM1.0 and CAPRAM HM3. The reduced mechanism is evaluated by process model studies. Comparisons of simulations performed with the explicit and reduced mechanism reveals that the deviations are below 5 % for key inorganic and organic air pollutants and oxidants under pristine ocean and polluted coastal conditions, respectively.

Subsequently, the reduced mechanism has been implemented into the chemical transport model COSMO-MUSCAT and tested by 2D-simulations. Simulations are performed for two different meteorological scenarios mimicking unstable and stable weather conditions over the pristine ocean. The simulations demonstrate that the modelled concentrations of important halogen compounds such as HCl and BrO agree with ambient measurements demonstrating the applicability of the mechanism for tropospheric modelling investigations.

The 2D studies with the reduced mechanism are carried out to examine the oxidation pathways of DMS in a cloudy marine atmosphere in detail. They have shown that clouds have both a direct and an indirect photochemical effect on the multiphase processing of DMS and its oxidation products. The direct photochemical effect is related to in-cloud chemistry that leads to high DMSO oxidation rates and subsequently an enhanced formation of methane sulfonic acid compared to aerosol chemistry. The indirect photochemical effect is characterised by cloud shading, particularly in the case of stratiform clouds. The lower photolysis rates below the clouds affects strongly the activation of Br atoms and lowers the formation of BrO radicals. The corresponding DMS oxidation flux is particularly lowered under thick optical clouds. Besides, high updraft velocities lead to a strong vertical mixing of DMS into the free troposphere predominately under convective conditions. Furthermore, clouds reduce the photolysis of hypohalogeneous acids (HOX, X=Cl, Br, I) resulting in higher HOX-driven sulfite oxidation rates in aqueous aerosol particles below clouds.

How to cite: Hoffmann, E. H., Tilgner, A., Schrödner, R., Wolke, R., and Herrmann, H.: Towards an operational CAPRAM multiphase halogen and DMS chemistry treatment in the chemistry transport model COSMO-MUSCAT, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8752, https://doi.org/10.5194/egusphere-egu2020-8752, 2020.

Titanium dioxide (TiO2) is extensively used with the process of urbanization and potentially inflfluences atmospheric chemistry, which is yet unclear. In this work, we demonstrated strong production of Cl2 from illuminated KCl-coated TiO2 membranes and suggest an important daytime source of chlorine radicals. We found that water and oxygen were required for the reactions to proceed, and Cl2 production increased linearly with the amount of coated KCl, humidity of the carrier gas, and light intensity. These results suggested that water promotes the reactivity of coated KCl via interaction with the crystal lattice to release free chloride ions (Cl). The free Cl transfer charges to O2 via photoactivated TiO2 to form Cl2 and probably the O2 radical. In addition to Cl2, ClO and HOCl were also observed via the complex reactions between Cl/Cl2 and HOx. An intensive campaign was conducted in Shanghai, during which evident daytime peaks of Cl2 were observed. Estimated Cl2 production from TiO2 photocatalysis can be up to 0.2 ppb/h when the TiO2-containing surface reaches 20% of the urban surface, and this is highly correlated to the observed Cl2. Our results suggest a non-negligible role of TiO2 in atmospheric photochemistry via altering the radical budget.

How to cite: Yuanyuan, L.: Photoinduced Production of Chlorine Molecules from Titanium Dioxide Surfaces Containing Chloride, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8841, https://doi.org/10.5194/egusphere-egu2020-8841, 2020.

EGU2020-8996 | Displays | AS3.20

Measurements of bromine monoxide over four halogen activation seasons in the Canadian high Arctic

Kristof Bognar, Xiaoyi Zhao, Kimberly Strong, Rachel Y.-W. Chang, Udo Frieß, Patrick L. Hayes, Audra McClure-Begley, Sara Morris, Samantha Tremblay, and Andy Vicente-Luis

Bromine explosions and corresponding ozone depletion events (ODEs) are common in the Arctic spring. The snowpack on sea ice and sea salt aerosols (SSA) are both thought to release bromine, but the relative contribution of each source is not yet known. Furthermore, the role of atmospheric conditions is not fully understood. Long-term measurements of bromine monoxide (BrO) provide useful insight into the underlying processes of bromine activation. Here we present a four-year dataset (2016-2019) of springtime BrO partial columns retrieved from Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements in Eureka, Canada (80.1° N, 86.4° W). Due to the altitude of the measurement site (610 m), the measurements often represent BrO above the shallow boundary layer, and the strength of the temperature inversion has limited impact on the BrO partial columns. When the boundary layer is deep, however, the effects of the enhanced vertical mixing manifest as an increase in the minimum BrO values (and reduced ODE frequency) for wind speeds of ~8 m/s or greater. We find that BrO events show two modes differentiated by local wind direction and air mass history. Longer time spent in first-year sea ice areas corresponds to increased BrO for one of these modes only. We argue that snow on multi-year ice (salted and acidified by Arctic haze) might also contribute to bromine release. The MAX-DOAS measurements show that high aerosol optical depth is required to maintain lofted BrO. In situ measurements indicate that accumulation mode aerosols (mostly Arctic haze) have no direct correlation with BrO. The presence of coarse mode aerosols, however, is a necessary and sufficient condition for observing enhanced BrO at Eureka. The measurements of coarse mode aerosols are consistent with SSA generated from blowing snow. The good correlation between BrO and coarse mode aerosols (R2 up to 0.57) supports the view that SSA is a direct source of bromine to the polar troposphere.

How to cite: Bognar, K., Zhao, X., Strong, K., Chang, R. Y.-W., Frieß, U., Hayes, P. L., McClure-Begley, A., Morris, S., Tremblay, S., and Vicente-Luis, A.: Measurements of bromine monoxide over four halogen activation seasons in the Canadian high Arctic, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8996, https://doi.org/10.5194/egusphere-egu2020-8996, 2020.

EGU2020-11132 | Displays | AS3.20

Experimental and theoretical study on the capture/desorption of gaseous methyl iodide on sea salt aerosols

Céline Toubin, Hanaa Houjeij, Maxime Infuso, Gregoire Anne-Cécile, Le Bourdon Gwenaelle, Cantrel Laurent, Taamalli Sonia, Louis Florent, Duflot Denis, and Sobanska Sophie

Iodine-131, when released into the environment during severe nuclear power plant accident can have a high radiological impact on the population at short term [1]. Interaction between gaseous Iodine compounds and aerosols was not considered by the current post-accident management. In this context, this work was focused on investigating the influence of sea salt aerosols on the transport of gaseous methyl iodide (CH3I). The identification of uptake processes as well as the formation of new products at the particle surfaces was the main objectives.

We have studied the interaction between NaCl particles as surrogate of sea salt particles and CH3I in various humidity conditions to reproduce the atmospheric conditions.

The nature of this interaction was investigated by Infrared Spectroscopy (DRIFTS, Diffuse Reflectance Infrared Fourier Spectroscopy). Solid NaCl was exposed to CH3I (1000 and 500 ppm) with a relative humidity (RH) ranging between 0 and 80%.

DRIFTS results clearly evidenced adsorbed CH3I on NaCl particles surface under both dry and humid conditions. The adsorption process can be fitted with First-order Langmuir adsorption isotherm model and exhibited very low uptake coefficients in all the experimental conditions.

Additionally, to the CH3I absorption bands, the DRIFT spectrum evidenced typical absorption bands that could be assigned either to the CH2 deformation of CH2I2 or to CH3 degenerate rocking of CH3Cl. The formation of new bands appears only when CH3I is in presence of halogenated salts. However, at RH = 80%, the water layer at the particle surface inhibits the interaction between gaseous CH3I and NaCl surface due to the low solubility of CH3I in water.

Theoretical calculations are carried out to complement the experimental results. Isolated hydrated clusters of CH3I are characterized by means of electronic structure calculations and ab initio molecular dynamics is used to mimic the CH3I / salt system at various humidities.

Although the uptake and accommodation coefficients of CH3I are quite low, a coverage of particle surface with CH3I-derived compounds may affect the reactivity of the particles and in term the cycling life of Iodine in the atmosphere.

Reference

[1] Lebel, L. S.; Dickson, R. S.; Glowa, G. A. J. Environ. Radioact. 2016, 151, 82–93.

We acknowledge support by the French government through the Program “Investissement d'avenir” through the Labex CaPPA (contract ANR-11-LABX-0005-01) and I-SITE ULNE project OVERSEE (contract ANR-16-IDEX-0004), CPER CLIMIBIO (European Regional Development Fund, Hauts de France council, French Ministry of Higher Education and Research) and French national supercomputing facilities (grants DARI x2016081859 and A0050801859).

How to cite: Toubin, C., Houjeij, H., Infuso, M., Anne-Cécile, G., Gwenaelle, L. B., Laurent, C., Sonia, T., Florent, L., Denis, D., and Sophie, S.: Experimental and theoretical study on the capture/desorption of gaseous methyl iodide on sea salt aerosols, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11132, https://doi.org/10.5194/egusphere-egu2020-11132, 2020.

EGU2020-12946 | Displays | AS3.20

Significant production of ClNO2 and possible source of Cl2 from N2O5 uptake at a suburban site in eastern China

Men Xia, Tao Wang, Xiang Peng, Weihao Wang, Chuan Yu, Peng Sun, Yuanyuan Li, Yuliang Liu, Zhengning Xu, Zhe Wang, Zheng Xu, Wei Nie, and Aijun Ding

ClNO2 and Cl2 can affect atmospheric oxidation and thereby the formation of ozone and secondary aerosols, yet their sources and production mechanisms are not well understood or quantified. In this study we present field observations of ClNO2 and Cl2 at a suburban site in eastern China during April 2018. Persistent high levels of ClNO2 (maximum ~3.7 ppbv; 1 min average) were frequently observed at night, due to the high ClNO2 yield (φ(ClNO2), 0.56 ± 0.20) inferred from the measurements. The φ(ClNO2) value showed a positive correlation with the [Cl-]/[H2O] ratio, and its parameterization was improved by the incorporation of [Cl-]/[H2O] and the suppression effect of aerosol organics. ClNO2 and Cl2 showed a significant correlation on most nights. We show that the Cl2 at our site was likely a co-product with ClNO2 from N2O5 uptake on aerosols that contain acidic chloride, rather than being produced by ClNO2 uptake, as previously suggested. The Cl2 yield (φ(Cl2)) derived from the N2O5 uptake hypothesis exhibited significant correlations with [Cl-] and [H+], based on which a parameterization of φ(Cl2) was developed. The derived parameterizations of φ(ClNO2) and φ(Cl2) can be used in models to quantify the nighttime production of ClNO2 and Cl2 and their impact on the next day’s photochemistry.

How to cite: Xia, M., Wang, T., Peng, X., Wang, W., Yu, C., Sun, P., Li, Y., Liu, Y., Xu, Z., Wang, Z., Xu, Z., Nie, W., and Ding, A.: Significant production of ClNO2 and possible source of Cl2 from N2O5 uptake at a suburban site in eastern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12946, https://doi.org/10.5194/egusphere-egu2020-12946, 2020.

EGU2020-13602 | Displays | AS3.20

Effect of nitryl chloride chemistry on oxidants concentrations during the KORUS-AQ campaign

Hyeonmmin Kim, Rokjin Park, Jaein Jeong, Saewung Kim, Daun Jeong, Xiao Fu, and Seogju Cho

Nitryl chloride (ClNO2) plays an important role as a night-time reservoir of NOX and the source of Cl radical during the daytime, which consequently affects the ozone photochemistry. Its impacts on regional air quality in East Asia, however, are not fully understood so far. We here use extensive observations during the international KORea-US cooperative Air Quality field study in Korea (KORUS-AQ), which occurred in May-June 2016, with a 3-D chemistry transport model to examine the impacts of ClNO2 chemistry on radical species and total nitrate concentrations in East Asia. We first update the model by implementing chlorine chemistry and latest anthropogenic chlorine emissions of China and South Korea. We conduct model simulations for May-June, 2016 and validate the model by comparing against the observations from the KORUS-AQ campaign. We find that the ClNO2 chemistry in the model results in an increase of ozone by ~1.4 ppbv (~2.5%), Cl radical by ~ 4.6x103 molec cm-3 (~3600%), OH ~8.2x104 molec cm-3 (~5.3%), HO2 ~6.6 molec cm-3 (~3.0%), a decrease of TNO3 (HNO3 + nitrate aerosol) concentrations by ~2 μg m-3 on a daily mean basis during the campaign. Overall, the enhanced conversion of NO to NO2 driven by ClNO2 chemistry contributes to higher oxidant concentrations in the model. As a result, the updated model shows a better agreement with the observations in Korea during the KORUS-AQ campaign.

How to cite: Kim, H., Park, R., Jeong, J., Kim, S., Jeong, D., Fu, X., and Cho, S.: Effect of nitryl chloride chemistry on oxidants concentrations during the KORUS-AQ campaign, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13602, https://doi.org/10.5194/egusphere-egu2020-13602, 2020.

The oxidative capacity, usually represented by the concentration of OH radicals in the troposphere, regulates the lifetime of reactive compounds injected into the atmosphere by the biosphere and by anthropogenic activities. Recently, naturally emitted halogenated species (I, Br, Cl) have been showed to play a significant role in the consumption of global tropospheric ozone, a primary precursor of the hydroxyl radical. So far, the state-of-the-art chemistry of iodine, bromine, and chlorine has been implemented in a few global chemistry-transport models (GEOS-CHEM, CAM-Chem, TOMCAT, WRF-Chem). The 3D global chemistry-climate model (LMDz-INCA) has been recently updated to consider the chemistry of halogens. We present here the impact of this chemistry on the global oxidant budgets as well as the lifetime of chemically active species. We discuss how this chemistry affects the self-regulation of radicals in present low-polluted atmospheres as well as pre-industrial and future climate scenarios.

How to cite: Karam, C. and Szopa, S.: The role of halogens in the regulation of the oxidative capacity of the Earth’s troposphere in low-polluted environments, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15450, https://doi.org/10.5194/egusphere-egu2020-15450, 2020.

EGU2020-16908 | Displays | AS3.20

Observation of HClO3 and HClO4 in the Arctic atmosphere

Yee Jun Tham, Nina Sarnela, Carlos A. Cuevas, Iyer Siddharth, Lisa Beck, Alfonso Saiz-Lopez, and Mikko Sipilä

Atmospheric halogens chemistry like the catalytic reaction of bromine and chlorine radicals with ozone (O3) has been known to cause the springtime surface-ozone destruction in the polar region. Although the initial atmospheric reactions of chlorine with ozone are well understood, the final oxidation steps leading to the formation of chlorate (ClO3-) and perchlorate (ClO4-) remain unclear due to the lack of direct evidence of their presence and fate in the atmosphere. In this study, we present the first high-resolution ambient data set of gas-phase HClO3 (chloric acid) and HClO4 (perchlorate acid) obtained from the field measurement at the Villum Research Station, Station Nord, in high arctic North Greenland (81°36’ N, 16°40’ W) during the spring of 2015. A state-of-the-art chemical ionization atmospheric pressure interface time-of-flight mass spectrometer (CI-APi-TOF) was used in negative ion mode with nitrate ion as the reagent ion to detect the gas-phase HClO3 and HClO4. We measured significant level of HClO3 and HClO4 only during the springtime ozone depletion events in the Greenland, with concentration up to 9x105 molecule cm-3. Air mass trajectory analysis shows that the air during the ozone depletion event was confined to near-surface, indicating that the O3 and surface of sea-ice/snowpack may play important roles in the formation of HClO3 and HClO4. We used high-level quantum-chemical methods to calculate the ultraviolet-visible absorption spectra and cross-section of HClO3 and HClO4 in the gas-phase to assess their fates in the atmosphere. Overall, our results reveal the presence of HClO3 and HClO4 during ozone depletion events, which could affect the chlorine chemistry in the Arctic atmosphere.

How to cite: Tham, Y. J., Sarnela, N., Cuevas, C. A., Siddharth, I., Beck, L., Saiz-Lopez, A., and Sipilä, M.: Observation of HClO3 and HClO4 in the Arctic atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16908, https://doi.org/10.5194/egusphere-egu2020-16908, 2020.

Arctic Amplification, the rapid increase of air temperature in higher latitudes over the last decades, is expected to have drastic impacts on all the sub-systems of the Arctic ecosystem. Bromine Oxides play a key role in the atmospheric composition of the Arctic. During polar spring, bromine molecules are released from young sea ice covered regions.  A rapid chemical chain reaction starts, the -so called 'bromine explosion', which depletes ozone, alters the production of OH, and thereby eventually changes the oxidizing capacity of the troposphere. Halogens oxidize elemental to gaseous mercury, which may then be deposited and harm the ecosystem. Based on current literature, there is considerable uncertainty on the impact of Arctic Amplification on halogen evolution. On one hand, the melting of multi-year sea ice should result in formation of more young sea ice, which favors bromine release. On the other hand, BrO explosion events are triggered by low temperatures, an effect expected to be reduced due to Arctic Amplification. Moreover, changes of other meteorological drivers, such as cyclone frequency and wind speed may impact on BrO amounts in the Arctic troposphere.

In this study, a long-term time-series of tropospheric BrO derived from 4 UV-VIS instruments (GOME, SCIAMACHY, GOME-2A, GOME-2B) is used as a basis, in order to investigate the impact of Arctic Amplification on BrO amounts in the Arctic. The long-term BrO data is being compared to sea ice age (NSIDC) and meteorological (air temperature, mean sea level pressure, wind speed and boundary layer height from ERA-5 & ASR-2) data. Our results focus on determining the relation between tropospheric BrO and its drivers, and especially on how the drivers impact on the formation of BrO plumes. Different cases studies throughout the 22 years of the BrO dataset were performed and evaluated. The changes in the tropospheric BrO abundances come in general agreement with changes in the drivers of BrO explosion events.

 

We gratefully acknowledge the funding by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) – Projektnummer 268020496 – TRR 172, within the Transregional Collaborative Research Center “ArctiC Amplification: Climate Relevant Atmospheric and SurfaCe Processes, and Feedback Mechanisms (AC)³”.

How to cite: Bougoudis, I., Blechschmidt, A.-M., Richter, A., Seo, S., and Burrows, J.: Investigating the Relation of Arctic Tropospheric Bro Derived by Satellite Remote Sensing to Sea Ice Age and Meteorological Driving Mechanisms Under the Impact of Arctic Amplification, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16914, https://doi.org/10.5194/egusphere-egu2020-16914, 2020.

Chlorinated Very Short-Lived Substances (Cl-VSLS) are now recognised as a significant source of inorganic chlorine in both the troposphere and stratosphere (e.g. Hossaini et al., 2016, 2019). The most abundant Cl-VSLS are dichloromethane (CH2Cl2), chloroform (CHCl3), perchloroethylene (C2Cl4) and 1,2−dichloroethane (C2H4Cl2), all of which have significant – but poorly constrained – industrial sources. Global surface observations have shown that the tropospheric abundance of CH2Cl2 and CHCl3 has increased significantly in recent years. For instance, the global surface abundance of CH2Cl2 has more than doubled since the early 2000s and in 2018 was ~42 ppt. Despite this, there has been no recent attempt to create a consistent set of gridded Cl-VSLS emissions with which global models can use to study their impacts. Here, we describe and evaluate a new set of gridded time-varying global emissions of CH2Cl2, CHCl3, C2Cl4 and C2H4Cl2, informed by novel bottom-up industrial emission data. The performance of the emission inventories in the TOMCAT chemical transport model are assessed using data from both long-term surface monitoring networks and a range of tropospheric aircraft campaigns. We use the model to quantify regional variability in Cl-VSLS throughout the troposphere and outline further plans for a new model intercomparison effort to examine the impacts of VSLS in the troposphere and stratosphere.

How to cite: Hossaini, R., Bednarz, E., and Chipperfield, M.: Chlorinated Very Short-Lived Substances: development + evaluation of gridded emissions for global models and on recent emission trends, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20311, https://doi.org/10.5194/egusphere-egu2020-20311, 2020.

AS3.21 – Air Pollution Modelling

EGU2020-529 | Displays | AS3.21

Benefits of Recent Clean Air Actions in China on Global Air Quality and Climate Change

Yuqiang Zhang, Drew Shindell, Karl Seltzer, Lu Shen, Qiang Zhang, Bo Zheng, Jia Xing, Zhe Jiang, and Lei Zhang

Significant emission reductions have been observed in China recently, especially after the the ‘Air Pollution Prevention and Control Action Plan’ in 2013. Major air pollutants, such as NOx, CO, SO2, are found to reach their peak in 2012 or 2013. Few studies attempted to investigate how the recent emission reductions in China will affect global air quality and climate change. Here, by using global climate-chemistry models and health impact functions, we investigate how the contrasting emission changes in China from 2010 to 2017 will affect global air quality, mortality burden and climate change. We calculate that compared with the year 2010, 4800 deaths were avoided due to ozone reductions in 2017 globally, while 65% of the avoided deaths happen in China, and the other 35% worldwide. In 2017, 109,000 deaths were avoided due to PM2.5 reductions, while 92% of the avoided deaths happen in China, and the other 8% worldwide. We also find that the cooling effect from the emission reductions of SO2 in China has been compensated by the warming effect from the emission reductions of black carbon at the same time in China, which is the opposite trend as found in the developed countries in previous decades.

How to cite: Zhang, Y., Shindell, D., Seltzer, K., Shen, L., Zhang, Q., Zheng, B., Xing, J., Jiang, Z., and Zhang, L.: Benefits of Recent Clean Air Actions in China on Global Air Quality and Climate Change, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-529, https://doi.org/10.5194/egusphere-egu2020-529, 2020.

EGU2020-17941 | Displays | AS3.21

Evolution of the CAMS global air quality forecasting system

Zak Kipling, Melanie Ades, Anna Agusti-Panareda, Jérôme Barré, Nicolas Bousserez, Juan-José Dominguez, Richard Engelen, Johannes Flemming, Sebastien Garrigues, Vincent Huijnen, Antje Inness, Luke Jones, Mark Parrington, Miha Razinger, Vincent-Henri Peuch, Samuel Rémy, Roberto Ribas, and Martin Suttie

As part of the Copernicus Atmosphere Monitoring Service (CAMS), operated by ECMWF on behalf of the European Commission, global analyses and forecasts of atmospheric composition have been produced operationally since 2015. These were built on many years of previous work under the GEMS and MACC projects, which began producing regular forecasts in 2007.

Since the transition to an operational service, there have continued to be many new developments and improvements to the system in five major upgrades, including increased horizontal and vertical resolution, updated emissions and paramterisations, additional species such as nitrate aerosol, as well as updates to the underlying meteorological model and data assimilation. The components of this system (aerosols, gas-phase chemistry, meteorology and the ocean) are also now coupled more tightly via active feedbacks then ever before.

In this interactive presentation, we will demonstrate the impact of a number of these developments on the performance of the resulting global air quality forecasts, alongside the continuing evolution of our approaches to assessing model improvement against independent in-situ and remote-sensing observations from a variety of platforms.

Because the continuing evolution of an operational system can make the analysis of long-term trends problematic, we will also contrast this with the CAMS global reanalysis product, which (while not using the very latest version of the model) do provide a consistent long-term dataset from 2003 onwards.

How to cite: Kipling, Z., Ades, M., Agusti-Panareda, A., Barré, J., Bousserez, N., Dominguez, J.-J., Engelen, R., Flemming, J., Garrigues, S., Huijnen, V., Inness, A., Jones, L., Parrington, M., Razinger, M., Peuch, V.-H., Rémy, S., Ribas, R., and Suttie, M.: Evolution of the CAMS global air quality forecasting system, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17941, https://doi.org/10.5194/egusphere-egu2020-17941, 2020.

EGU2020-6772 | Displays | AS3.21

Insights into the EMEP emissions inventory dataset

Sabine Schindlbacher, Christine Brendle, Katarina Mareckova, Bradley Matthews, Marion Pinterits, Melanie Tista, Bernhard Ullrich, and Robert Wankmüller

Under the Convention on Long-range Transboundary Air Pollution (CLRTAP), 51 northern hemisphere countries are obliged to regularly report their national emissions inventories for selected anthropogenic air pollutants to the United Nations Economic Commission for Europe (UNECE). The EMEP Centre on Emissions Inventories and Projections (CEIP) of the Convention is tasked with administering, archiving and reviewing these data and compiling the EMEP emissions dataset, a complete and gridded inventory for the area between 30 and 82 °N and 30 °W and 90°E.

The reported national emissions inventories and the EMEP emissions dataset are often used by the scientific community as input drivers of air pollution models or as priors for inverse estimation of emissions. However, interpreting model outputs, validation and uncertainties may be restricted by limited knowledge of the peculiarities of such reported data. The purpose of this conference contribution by CEIP is to provide atmospheric modellers with further insight into these reported emissions data. The presentation will introduce the Convention and discuss how complexities of this international agreement have led to diversified reporting requirements and heterogeneity in the frequency and quality of the reported inventories. Current issues with respect to emissions of particulate matter (e.g. reporting of condensable particulate matter and black carbon) will furthermore be discussed and the presentation will also provide perspectives on how the recently agreed long-term strategy for Convention may impact future emissions reporting over the next decade and beyond.

How to cite: Schindlbacher, S., Brendle, C., Mareckova, K., Matthews, B., Pinterits, M., Tista, M., Ullrich, B., and Wankmüller, R.: Insights into the EMEP emissions inventory dataset, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6772, https://doi.org/10.5194/egusphere-egu2020-6772, 2020.

EGU2020-6445 | Displays | AS3.21

A new modeling framework for air pollution forecasting in South America

Angel Vela, Debora Alvim, Eder Vendrasco, Dirceu Herdies, Nilo Figueroa, and Jayant Penharkar

Biomass burning episodes are quite common in the central region of South America and represent the dominant aerosol sources during the dry/burning, between August and October. Large amounts of trace gases and aerosols injected into the atmosphere from these fire events can then be efficiently transported to urban areas in southeastern South America, thus affecting air quality over those areas. Observational data have been of fundamental importance to understand the evolution and interaction of biomass burning products with meteorology and chemistry. However, supplementing this information with the use of a comprehensive air quality modeling system in order to anticipate very acute air pollution episodes, and thus avoiding severe impacts on human health, is also required. Considering this, a new regional air pollution modeling framework for South America is being implemented by the Center for Weather Forecasting and Climate Studies (CPTEC), the National Weather Service of Brazil. This new system, based on the Weather Research and Forecasting with Chemistry model (WRF-Chem; Grell et al., 2005), is being run experimentally and its operational implementation is underway. The forecasts were driven by global forecast data from the GFS-FV3 model for meteorology and from the WACCM model for chemistry, both data sets provided every 6 hours. WACCM forecasts are employed to map gas and aerosol background concentrations to the WRF-Chem initial and boundary conditions, according to the MOZCART chemical mechanism. Two experiments of 48-hour real-time forecast simulations were performed, on a daily basis, during August and September of 2018 and 2019. The experiment for 2019 includes the very strong 3-week forest fire event when the Metropolitan Area of São Paulo, the largest metropolitan area in South America, plunged into darkness on August 19, with day turning into night. Model results are in good domain-wide agreement with satellite data and also with in situ measurements. Besides forecasts of meteorological parameters, this new system provides forecasts of regional distributions of primary chemical species (CO, SO2, NOx, particulate matter including black carbon), of secondary species (ozone, secondary organic aerosols) and air pollution related health indices, all parameters with a resolution of 20 km and for the next 72 hours.

How to cite: Vela, A., Alvim, D., Vendrasco, E., Herdies, D., Figueroa, N., and Penharkar, J.: A new modeling framework for air pollution forecasting in South America, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6445, https://doi.org/10.5194/egusphere-egu2020-6445, 2020.

EGU2020-5191 | Displays | AS3.21

On the initial-state assimilation for limited-area air-quality forecasts

Rostislav Kouznetsov and Mikhail Sofiev

An ensemble of 9 regional Air Quality models is being run operationally within CAMS-50 project providing the 3D fields of air-pollutant distribution over Europe. The models are initialized from their previous-day's forecasts for 00Z and run for 4 days forward. The same models are used for near-real-time reanalysis of the previous day involving the air-quality observations to adjust the modelled  fields via data assimilation methods, such as 3D-var or optimal-interpolation procedures.  In this set-up the observed near-real-time data do not affect the forecasts.  Development of a method to improve the forecast quality by using the assimilated fields from the previous-day analysis is one of the goals for the CAMS-61 project.

As a prototype evaluation for this study, we made several tests with SILAM model (http://silam.fmi.fi) initializing the simulations from the assimilated or non-assimilated states and evaluated the evolution of the model skill scores along the forecast lead time. The tests were made for summer and winter seasons and for initialization time of 00Z vs 12Z.  In order to generalize the results, and make them independent on particular implementation of 3D-VAR in SILAM, the tests were made also with initialization from the analyses made with other CAMS-50 models.  That experiment utilized the list of species and vertical available in the CAMS-50 product catalog. 

The results of the simulation corroborated with our earlier studies that showed a quite quick relaxation of the scores for runs initialized from analyses to the free-run state: with certain variability between the species, the runs converged to the free-run trajectory generally within several hours.  We also investigated the issues connected with initialization from the incomplete set of species and sparse vertical, which might make the scores of the forecast initialized from the incomplete assimilated model state being worse than the ones from the free-run model.

 

How to cite: Kouznetsov, R. and Sofiev, M.: On the initial-state assimilation for limited-area air-quality forecasts , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5191, https://doi.org/10.5194/egusphere-egu2020-5191, 2020.

EGU2020-14913 | Displays | AS3.21

Air quality modelling studies in Germany and Europe across scales

Marc Barra, Joachim Fallmann, and Holger Tost

The problem of health risks associated with poor air quality in cities and metropolitan areas is rising in the perception of society. In order to improve air quality, a thorough understanding of different emission sources concerning transport, origin and composition as well as the microphysical and chemical processes involved is of crucial importance.

To assess air quality related issues, we set up a simulation system using the global to regional model system MECO(n), which allows entangling of chemical and physical interactions using a dynamical coupling approach from a global to regional domains down to a resolution of ∼7km. This provides us with a detailed picture of air quality in urbanised regions whilst maintaining a consistent representation and implementation of processes across the scales.

The model setup is evaluated using measurement data from the aerosol robotic network (AERONET) and satellite data from VIIRS instrument on board the polarorbiting Suomi NPP satellite. Moreover we compare our model to ground based measurements of gas species and particulate matter, which are taken from the databases of the Environmental Protection Agency of Rhineland-Palatinate. In this context the limits of the model with respect to aerosol processes especially in the boundary layer are discussed and the resulting limitations in comparing our model output to ground based measurements of particulate matter, specifically PM2.5 and PM10 are shown.

To demonstrate the flexibility of the model system two model applications relevant for air pollution issues in the Rhine-Main region are presented. The first investigates the direct influence of a localised reduction in anthropogenic emissions on the surrounding regions and the reducing region itself. The second explores deposition regions of kerosene, which is released by aircrafts during emergency fuel dumping event.

How to cite: Barra, M., Fallmann, J., and Tost, H.: Air quality modelling studies in Germany and Europe across scales, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14913, https://doi.org/10.5194/egusphere-egu2020-14913, 2020.

EGU2020-9445 | Displays | AS3.21

Changes in European surface ozone air quality over the 21st century

Christoph Stähle, Harald Rieder, and Monika Mayer

Surface ozone is a criteria air pollutant, formed by photochemical reactions involving nitrogen oxides (NOx) and volatile organic compounds (VOCs). Despite recent reductions in the surface ozone burden following precursor emission controls (predominantly concerning NOx) the recent European air quality report published by the European Environment Agency (EEA) highlights that to date still 17 EU member states are reporting ozone concentrations that exceed the target value set for the protection of human health (120 µg/m³, maximum daily 8-hour average (MDA8) not to be exceeded more than 25 times per year (3-year average)). In total, 20 percent of all ozone monitoring sites showed ozone concentrations exceeding the EU target value for the protection of human health, and only 5% of monitoring sites showed ozone concentrations in compliance with the more stringent WHO target value. Here we focus on past and future changes in European surface ozone abundances in a set of simulations performed with the Geophysical Fluid Dynamics Laboratory (GFDL) chemistry-climate model CM3. First, we evaluate the general model performance for the recent past by comparing model output to observations available from the EEA Airbase database. The evaluation is performed on the basis of interpolation of the historic site level observations to a grid of 2.5° x 2°, matching the dimensions of the CM3 model. Our results for the recent past show that the modelled ozone abundances are biased high compared to observations. Therefore, we apply a suite of correction techniques (quantile mapping, delta function) to obtain modelled ozone fields in agreement with observations. Emanating from remediated model data the correction functions derived are applied to transient (2006-2100) simulations following selected Representative Concentration Pathways (RCPs). Using these bias-corrected future simulations we illustrate next potential changes in future European surface ozone air pollution over the course of the 21st century.

How to cite: Stähle, C., Rieder, H., and Mayer, M.: Changes in European surface ozone air quality over the 21st century, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9445, https://doi.org/10.5194/egusphere-egu2020-9445, 2020.

EGU2020-13535 | Displays | AS3.21

Evaluation of O3 forecasts of ALARO-CAMx and WRF-Chem

Claudia Flandorfer, Marcus Hirtl, and Barbara Scherllin-Pirscher

ZAMG runs two models for air-quality forecasts operationally: ALARO-CAMx and WRF-Chem.

ALARO-CAMx is a combination of the meteorological model ALARO and the photochemical dispersion model CAMx and is operated at ZAMG since 2005. The emphasis of this modeling system is to predict ozone peaks in the north-eastern Austrian flatlands. The outer model grid covers Central Europe with a resolution of 13.8 km, the inner domain is centered over Austria with a resolution of 4.6 km. The model runs twice per day for a period of 48 hours.

The second operational air quality model at ZAMG is the on-line coupled model WRF-Chem. Meteorology is simulated simultaneously with the emission, turbulent mixing, transport, transformation as well as the fate of trace gases and aerosols. Two modeling domains are used for these simulations. The mother domain covers Europe with a resolution of 12 km. The inner, nested domain covers the Alpine region with a horizontal resolution of 4 km. The model runs two times per day for a period of 72 hours and is initialized with ECMWF forecasts.

The evaluation of both models is conducted for the period from January to September 2019 with the focus on ozone. The summer 2019 was the 2nd warmest summer since the beginning of the meteorological measurements in Austria more than 200 years ago. Although this summer had favorable conditions for Ozone production (sunny and hot weather, less rain), only a few air quality stations in Eastern Austria have measured exceedances of the ozone information threshold (180 µg/m³) on overall 5 days. The measurements of the air-quality stations are compared with the area forecasts for every province of Austria. Besides the evaluation, air quality forecasts of ALARO-CAMx and WRF-Chem are compared.

How to cite: Flandorfer, C., Hirtl, M., and Scherllin-Pirscher, B.: Evaluation of O3 forecasts of ALARO-CAMx and WRF-Chem, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13535, https://doi.org/10.5194/egusphere-egu2020-13535, 2020.

EGU2020-11624 | Displays | AS3.21

Site-scale estimation of Ozone in Northern Bavaria using Gradient Boosting Machines, Deterministic Regional Air Quality Models and a Hybrid Model

seyed omid nabavi, Anke Nölscher, Leopold Haimberger, Juan Cuesta, Christoph Thomas, Andreas Held, and Cyrus Samimi

This study is part of the Mitigation of Urban Climate and Ozone Risks (MiSKOR) project. MiSKOR aims to use a collection of tools to mitigate the problems of the urban heat island effect and ozone (O3) pollution in and around medium sized cities in northern Bavaria (NB).  In this study, we developed modelling tools to estimate (hindcast), classify (O3 >= 120 ug/m3 or O3 < 120 ug/m3), and forecast hourly O3 concentrations at nine unmonitored sites in NB. Three machine learning algorithms (MLAs) including linear- and tree-based eXtreme Gradient Boosting Machines (MLR-XGBM and Tree-XGBM) and logistic regression (LR) are used for O3 modelling. MLAs are trained by using hourly observations of O3 and its chemical and meteorological precursors from seven monitored sites in NB. In addition, the daily average of surface O3 observations along 6-hour back trajectories, produced by HYSPLIT model, is fed into MLAs to provide a rough estimation of O3 transport in a local scale. MLAs are compared with two state of the art regional deterministic models (DMs) namely the ECMWF Copernicus Atmosphere Monitoring Service (CAMS) regional air quality model for Europe (CAMS-EU) and the DLR WRF-POLYPHEMUS air quality system (used only for O3 forecast purpose). Finally, we created a new hybrid model by combining the O3 estimations from the best MLA model and the regional air quality model CAMS-EU.

According to averaged metrics from leave-one-site-out cross-validation (LOOCV), MLR-XGBM outperformed other models in the estimation of O3. This model yielded summertime RMSE and Spearman correlation coefficient (SCC) of 13.6 µg/m3 and 0.91 respectively. Interestingly, the hybrid model significantly improved the accuracy of O3 estimations. It reduced the summertime seasonal RMSE to 11.4 µg/m3 and increased the lowest seasonal SCC to 0.95. MLR-XGBM also yielded the best performance in O3 forecast compared to CAMS-EU and WRF-POLYPHEMUS. With regard to O3 classification LR outperformed other models. We also found that using remotely sensed lower troposphere O3, from IASI/GOME2, improves the classification of high extreme O3 in summertime.

How to cite: nabavi, S. O., Nölscher, A., Haimberger, L., Cuesta, J., Thomas, C., Held, A., and Samimi, C.: Site-scale estimation of Ozone in Northern Bavaria using Gradient Boosting Machines, Deterministic Regional Air Quality Models and a Hybrid Model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11624, https://doi.org/10.5194/egusphere-egu2020-11624, 2020.

Comprehensive measurements were conducted at the summit of Mount (Mt.) Huang, a rural site located in eastern China during the summer of 2011. They observed that ozone showed pronounced diurnal variations with high concentrations at night and low values during daytime. The Weather Research and Forecasting with Chemistry (WRF-Chem) model was applied to simulate the ozone concentrations at Mt. Huang in June 2011. With processes analysis and online ozone tagging method we coupled into the model system, the causes of this diurnal pattern and the contributions from different source regions were investigated. Our results showed that boundary layer diurnal cycle played an important role in driving the ozone diurnal variation. Further analysis showed that the negative contribution of vertical mixing was significant, resulting in the ozone decrease during the daytime. In contrast, ozone increased at night owing to the significant positive contribution of advection. This shifting of major factor between vertical mixing and advection formed this diurnal variation. Ozone source apportionment results indicated that approximately half was provided by inflow effect of ozone from outside the model domain (O3-INFLOW) and the other half was formed by ozone precursors (O3-PBL) emitted in eastern, central, and southern China. In the O3-PBL, 3.0% of the ozone was from Mt. Huang reflecting the small local contribution (O3-LOC) and the non-local contributions (O3-NLOC) accounted for 41.6%, in which ozone from the southerly regions contributed significantly, for example, 9.9% of the ozone originating from Jiangxi, representing the highest geographical contributor. Because the origin and variation of O3-NLOC was highly related to the diurnal movements in boundary layer, the similar diurnal patterns between O3-NLOC and total ozone both indicated the direct influence of O3-NLOC and the importance of boundary layer diurnal variations in the formation of such distinct diurnal ozone variations at Mt. Huang.

How to cite: Gao, J.: Diurnal variations and source apportionment of ozone at the summit of Mount Huang, a rural site in Eastern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8483, https://doi.org/10.5194/egusphere-egu2020-8483, 2020.

EGU2020-1934 | Displays | AS3.21

Comparison of regional chemistry-modelled NO2 tropospheric columns and profiles with TROPOMI observations and 4-azimuth MAX-DOAS measurements

Vinod Kumar, Julia Remmers, Benedikt Steil, Astrid Kerkweg, Jos Lelieveld, Steffen Beirle, Yang Wang, Sebastian Donner, Andrea Pozzer, and Thomas Wagner

Regional chemistry-transport models typically simulate the physical and chemical state of the atmosphere at a high spatial resolution, e.g. of less than 7 km. At this relatively high spatial resolution, air quality and relevant processes within cities can be assessed to facilitate strategic mitigation planning. Comparison of regional models with satellite and ground-based observations helps validate the models and evaluate emission inventories, as well as satellite retrieval algorithms. For example, an underestimation of atmospheric trace gases (like often found for NO2) by satellite observations can be improved by providing high-resolution input fields from regional models.

MECO(n), a global-to-regional chemistry climate modeling system, in which the finer resolved domains receive their initial and boundary conditions on-line from the next coarser model instance, was set-up with Germany as focus. 1-way nested MECO(3)  simulations were performed for May 2018 with spatial resolution up to ~2.2 km × 2.2 km in the finest domain. Model simulations accounting separately for both TNO MACC III and EDGAR 4.3.2 anthropogenic emissions are evaluated against TROPOMI observations. A diurnal factor was applied to road transport emissions to account for their temporal variation. For the comparison with TROPOMI data, we applied a novel method of online sampling of model fields along the satellite overpass by also accounting for the difference in local solar time across the swath width, which can be up to 90 minutes. Modified airmass factors in the TROPOMI data product, using the model calculated NO2 a priori profiles and taking into account averaging kernels, resulted in an improved agreement of the spatial pattern of NO2 vertical column density (VCD) between model and satellite.

NO2 VCDs over Mainz, calculated using model output at the finest model resolution, were compared against MAX-DOAS observations for the simulation period. Vertical profiles of NO2 were also retrieved in 4 azimuth directions around Mainz by profile inversion of MAX-DOAS measurements. The temporal (e.g. day-to-day and diurnal) variation of the 3-D NO2 field derived from the model was evaluated against the MAX-DOAS observations. For the cloud-free days, the model is able to reproduce the temporal development with satisfactory temporal correlation (slope=0.7, r=0.5) of the NO2 VCDs. For a direct comparison of measured slant column densities of NO2, height-resolved 2-D box airmass factors were calculated using McArtim (Monte Carlo Atmospheric radiative transfer model) and applied to the modelled trace gas profiles along individual elevation angles of the measurements. This comparison procedure accounts for the complex dependency of the MAX-DOAS column densities on the 3D (vertical and horizontal) trace gas distribution in the measurement direction.

How to cite: Kumar, V., Remmers, J., Steil, B., Kerkweg, A., Lelieveld, J., Beirle, S., Wang, Y., Donner, S., Pozzer, A., and Wagner, T.: Comparison of regional chemistry-modelled NO2 tropospheric columns and profiles with TROPOMI observations and 4-azimuth MAX-DOAS measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1934, https://doi.org/10.5194/egusphere-egu2020-1934, 2020.

Rulan Verma1,Salim Alam2, William Bloss2, Prashant Kumar3, Mukesh Khare1*

 1 Department of Civil Engineering, Indian Institute of Technology Delhi, India

 2 School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, United Kingdom

3 Global Centre for Clean Air Research (GCARE), Department of Civil and Environmental Engineering, University of Surrey, Guilford, United Kingdom

                                                 mukeshk@civil.iitd.ac.in

 

ABSTRACT

The Delhi-National Capital Region of India is home to approximately 46 million people. With rapid development, this region is experiencing widespread urbanization and industrialization. It is expected to become the most populous region in the world by 2027 (World Population Prospects 2019, UN). With rapid growth, the region is facing severe challenges of air pollution. Delhi-NCR is amongst the most polluted regions in the world. PM2.5 is recognized as a prominent pollutant in the region. Ambient air pollution is recognized as a class I carcinogen and is one of the highest risk factors for premature deaths worldwide.  Understanding the effects of local and global meteorology would help in the identification of source pathways and source areas of pollutant dispersion. This paper presents a methodology for modelling and assessment of PM2.5 over the Indian subcontinent using NOAA’s Hybrid Single-Particle Lagrangian Integrated Trajectory Model (HYSPLIT). To develop the approach, PM2.5 data collected over a period of 32 days at IIT Delhi supersite (28.54°N,77.19°E) were utilized.  PM2.5 mass concentrations were monitored using PM2.5 samplers and a TEOM (Tapered Element Oscillating Microbalance) monitor. Meteorological data were obtained through the Global Data Assimilation System (GDAS) which places observations into a gridded model space.770 air mass back trajectories were generated and clustered into mean trajectories using the cluster analysis function of HYSPLIT. PM2.5 monitored during winters (15/01/2018-15/02/2018) was correlated with clustered back trajectories to understand the effect of local and global meteorology. The time-series of PM2.5 were correlated with different clusters to understand the impact of winds coming from different regions and heights. Major advection source pathways for PM2.5 were identified. The study found that 59% of the time, PM2.5 transport was affected by wind movements from north-west of supersite moving through Pakistan-Punjab-Haryana-supersite. During this period PM2.5 concentration at supersite were 169±73 μg/m3. The highest PM2.5 concentration of 237±81 μg/m3 were observed when the winds were recirculating locally. Wind roses produced using meteorological data obtained from  Indian Meteorological Department stations conforms with the wind flow in GDAS. This methodology can be utilized in other regions for quantifying the major source pathways and source areas for air pollutant dispersion. This understanding would help in framing hotspot and airshed based interventions and mitigation strategies to control air pollution.

 

KEYWORDS: PM2.5; AIR POLLUTION; HYSPLIT; MONITORING; DISPERSION; SOURCE PATHWAYS; METEOROLOGY; MODELLING; SOURCE REGIONS

How to cite: Verma, R.: HYSPLIT Modelling Approach for the Assessment of PM2.5 over Indian Subcontinent, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-574, https://doi.org/10.5194/egusphere-egu2020-574, 2020.

With the intensification of Chinese source control of air pollution, there is an urgent need for refined and rapid source apportionment techniques. A refined source apportionment method was constructed based on an off-line sampling dataset using a receptor model coupled with a source-oriented model, and the method was implemented in Shijiazhuang during the heating period. The refined results for source apportionment mainly included temporal, spatial, and source-category refinement data. The results indicated that the mean concentration of PM2.5 during the heating period was 96 μg/m3. Organic carbon (OC) and NO3- were found to be the dominant species of PM2.5 during the study. A high correlation was detected between elemental carbon (EC) and NO3 on polluted days, which was suggestive of the stagnant condition that accumulates EC and nitrate simultaneously. Secondary particle formation greatly promoted the occurrence of haze events. Secondary sources (34.9%), vehicle exhaust (18.6%), coal combustion (20.0%), industrial emissions (9.2%), crustal dust (9.7%), and biomass burning (7.6%) were the major sources during the heating period. The contributions of secondary sources and vehicle exhaust increased on polluted days, while those of coal combustion, industrial emissions and crustal dust decreased significantly. The contribution percentage of secondary sources from the southeast direction was basically the highest, while those of vehicle exhaust from the northwest or southeast directions were relatively higher as well, likely due to the distribution of traffic arteries. Based on the refined results for the source-category assessment, we found that the heating boilers (17.0%), non-road mobile (13.8%), diesel vehicles (10.4%), residential combustion (6.7%), road dust (5.5%), and architectural material industry (4.9%) were the major contributors to PM2.5. There was some uncertainty in the distribution proportions of the refined results, which were derived based on the emission inventory and the results of CALPUFF model.

How to cite: Liu, B., Zhang, Y., Feng, Y., Dai, Q., and Song, C.: A refined source apportionment study of atmospheric PM2.5 during winter heating period in Shijiazhuang, China, using a receptor model coupled with a source-oriented model , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2523, https://doi.org/10.5194/egusphere-egu2020-2523, 2020.

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PM2.5 temporal source apportionment analysis over the Pearl River Delta region

Yiang Chen, Jimmy Chi-Hung Fung, and Xincheng Lu

The Pearl River Delta (PRD) region is one of the most developed city clusters in China, and it is also the area that suffers from severe air pollution. A key problem in addressing pollution is to find out where the pollutants come and how to control them. Most of the previous studies focused on the source area, and source category contribution analysis, but fewer studies paid attention to the temporal contribution, which is also an important factor in policymaking. Therefore, in this study, based on the CAMx-PSAT model, we extended the model to track the contribution of the sources emitted at different periods. The updated PSAT can reflect the temporal correlation between the source and receptor and provide scientific support to efficient control policymaking. The simulation result of a high PM2.5 episode shows that the emission outside the PRD region is the major contributor to PM2.5 over the PRD region. PM2.5 mainly comes from the emission within the current two days. Under the control of the high-pressure system, low wind speed hinders the diffusion of PM2.5 and paves the way for the accumulation of the pollutants. The emission two days ago can still have a considerable contribution during the high concentration period. The results suggest that emission control measurements should be implemented in advance when adverse meteorology condition is predicted.

How to cite: Chen, Y., Fung, J. C.-H., and Lu, X.: PM2.5 temporal source apportionment analysis over the Pearl River Delta region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13076, https://doi.org/10.5194/egusphere-egu2020-13076, 2020.

Aiming at evaluating the impact of coal-fired power plants on urban air quality and human health, a one-month intensive observation campaign was conducted in a typical polluted city located in “2+26” city cluster in China North Plain in December 2017. The observation results illustrated that coal-fired plant can increase the PM2.5 concentration by ~5% on monthly average in city scale. The impacts differed under various diffusion conditions. A three-dimensional Nested Air Quality Perdition Model (NAQPMS) with source apportionment was employed to reveal the impacts. The results indicated that the power plant had the greatest effect on regional air quality during severe pollution period while it was ignorable during the excellent dissipation period under the robust wind. PM2.5 contributed by the power plant was below 150 m, 100 km far away, and about 5 μg m-3 during light pollution period. When it came to accumulation period, the plume reached 500 m height, diffused to downwind area about 100 km away within half a day, and with a maximum contribution of 40 μg m-3 to PM2.5. The affected area extended further to 250 km in severe pollution period and the contribution to PM2.5 was at least 10 μg m-3 in different distances. The affected height was up to about 500 m with more than 10 μg m-3 PM2.5 mainly constrained below 150 meters. Overall, regional integrated control strategies should be taken for power plants in “2+26” city cluster during pollution episodes to further improve the air quality.

How to cite: Chen, X., Yang, T., Wang, Z., and He, L.: Investigating the impacts of coal-fired power plants on ambient PM2.5 by a combination of chemical transport model and receptor model , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4031, https://doi.org/10.5194/egusphere-egu2020-4031, 2020.

High concentrations of atmospheric aerosols with aerodynamic diameter below 2.5 mm (PM2.5) are frequently observed in several Central European countries during the heating season (October – March). Poland belongs to a group of EU countries with the highest concentrations of PM2.5, according to the European Environmental Agency. Large exposure to atmospheric pollutants leads to significant number of premature deaths attributable to adverse air quality in Poland.

Coal combustion for residential heating is one of the main sources of PM2.5 in Poland. The quality of this fuel is often unknown, and this increases the uncertainty of national emission inventories and makes the modelling of PM2.5 concentrations challenging. Second, daily temporal emission profile (i.e. hours of the day when emission is released to the atmosphere) in residential heating sector is also rather uncertain. In this work, we developed a daily temporal emission profile using available measurements of PM2.5 and PM10 concentrations from the 2017-2018 heating season. The profile was compared with the existing profile proposed within the INERIS project. New profile has longer peak of afternoon and night time emission, if compared to INERIS, and the morning peak is significantly lower. It means that more emission is released to the atmosphere during unfavorable meteorological conditions such as calm winds and temperature inversions, which are frequently observed during the afternoon and night.

We have run two simulations using the EMEP4PL model with new and old (INERIS) emission profile. The simulations covered three heating seasons of 2015-2016, 2017-2018 and 2018-2019. Application of the new emission profile results in increased model – measurements correlation and reduced model bias.

How to cite: Kryza, M., Werner, M., and Dudek, J.: Improving PM2.5 modelling results through development of the new hourly temporal emission profile – a case study of Poland, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4771, https://doi.org/10.5194/egusphere-egu2020-4771, 2020.

Some European countries in Eastern or Central Europe, such as Poland, have serious problems with air quality. High concentrations of particulate matter (PM) in winter are often related to high coal and wood combustion for residential heating. Meteorological conditions, i.e. low air temperature and anticyclones, provide favourable conditions for the accumulation of air pollution, rendering it harmful to people.  PM concentrations during the warmer period are much lower, however there are episodes with elevated concentrations related to e.g. long-range transport of pollutants from biomass burning areas. Policy makers in Poland put a lot of effort to improve air quality as well as inform and aware people on harmful effects of air pollution. One of the relevant tools which provides information on the past, current and future state of the air pollution are chemical transport models.

In this study we aim for validation of PM10 and PM2.5 concentrations from two different chemical transport models – WRF-Chem and EMEP4PL and two different emission databases – a) a regional EMEP database, and b) a local database provided by the Chief Inspectorate of Environmental Pollution. Modelled PM10 and PM2.5 concentrations were compared with observations from Polish stations for the year 2018. The results show a clear seasonal variation of the models performance with the lowest correlation coefficients in summer. Higher seasonal variability is observed for WRF-Chem than EMEP, which is probably related to differences in calculations of boundary layer height. Application of local database improves the results for both models. For several months, the performance of WRF-Chem and EMEP is clearly different, which shows that an ensemble approach with an application of these two models could improve the modelling results. The differences in the model performance significantly influence the results of the population exposure assessment.

 

How to cite: Werner, M., Kryza, M., and Dudek, J.: Two models and two emission databases – evaluation of the PM10 and PM2.5 concentrations modelled with WRF-Chem and EMEP4PL, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3768, https://doi.org/10.5194/egusphere-egu2020-3768, 2020.

EGU2020-16133 | Displays | AS3.21

A data fusion method to improve winter PM10 concentration predictions in Budapest based on the CAMS air quality models

Adrienn Varga-Balogh, Ádám Leelőssy, István Lagzi, and Róbert Mészáros

Winter air pollution in Budapest is a major environmental issue, caused by an interaction of residential heating, urban traffic and large-scale transport. Increasing public and political demand are present to achieve more accurate air quality predictions to support both real-time public health measures and long-term mitigation policies.  Atmospheric chemistry and transport models of the Copernicus Atmospheric Monitoring Service (CAMS) provide near-real-time air quality forecasts for Europe. The validation of these model predictions for Budapest showed that although large-scale processes are well captured, the complex interaction of large-scale plumes with significant and highly variable local residential emissions leads to the underestimation of winter PM10 concentrations. Furthermore, CAMS models are not expected to fully predict the non-representative concentrations at specific urban monitoring locations, which, on the other hand, serve as the legal basis of all public policies and measures. Therefore, obtaining a relationship between monitoring site observations and CAMS model predictions is of primary importance. 

In this study, we used observed PM10 concentration data from 12 air quality monitoring sites within Budapest, as well as 24-hour predictions from 7 of the 9 CAMS models to produce an optimal linear combination of models that best matched, in terms of RMSE, the observed time series. A zero-degree term to correct the model bias was also applied. The applied data fusion method was cross-validated on urban monitoring sites not used in fitting the model, and found to improve PM10 forecast validation statistics compared to the pointwise model median (CAMS ensemble) as well as each of the 7 single models. The presented fusion of CAMS models can therefore provide an improved prediction of PM10 concentrations at urban monitoring sites in Budapest.  

How to cite: Varga-Balogh, A., Leelőssy, Á., Lagzi, I., and Mészáros, R.: A data fusion method to improve winter PM10 concentration predictions in Budapest based on the CAMS air quality models , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16133, https://doi.org/10.5194/egusphere-egu2020-16133, 2020.

In the past years, the PM2.5 concentration in Beijing decreases from 89 ug/m3 in 2013 to 42 ug/m3 in 2019, especially in the recent three years, that the PM2.5 concentration rapidly decreases from 73 ug/m3 in 2016 decreases to 42 ug/m3. An air quality modeling system, based on WRF-SMOKE-CMAQ model, was established before APEC 2014 to forecast daily air quality and assess future air quality improvement plans, which plan expects Beijing’s PM2.5 would reach to 53 ug/m3 in 2020, and reach to 35 ug/m3 in 2030. Actually, the PM2.5 concentration in Beijing has fallen faster than expected, that the annual PM2.5 concentration is 42 ug/m3 in 2019. So how much influence do meteorological factors and emission control have on the annual PM2.5 concentration? The WRF-SMOKE-CMAQ modeling system has been used to re-build the PM2.5 concentration characteristics of Beijing from 2013 to 2019 to distinguish these two factors. Preliminary results show that under the same emission scenarios, the annual average concentration of PM2.5 in Beijing in 2013 was 68.6 ug/m3, and the average annual concentration of PM2.5 in 2017 was 69.4 ug/m3. More detailed model results will be presented.

How to cite: Wu, Q. and Xu, Q.: Numerical Study of the impact of Meteorological and Emission control on the decreasing of PM2.5 concentration in Beijing by WRF-SMOKE-CMAQ model system, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19694, https://doi.org/10.5194/egusphere-egu2020-19694, 2020.

EGU2020-13479 | Displays | AS3.21

Estimation of winter PM2.5 concentrations in East Asia associated with climate variability

Jaein Jeong, Rokjin Park, Sang-Wook Yeh, and Joon-Woo Roh

Interannual variability in large circulations associated with climate connections, such as monsoon and El Niño, have a significant impact on winter PM2.5 concentrations in East Asia. In this study, we use the global 3D chemical transport model (GEOS-Chem) over the last 35 years to investigate the relationship between major climate variability and winter PM2.5 concentrations in East Asia. First, the model is evaluated by comparing the simulated and observed aerosol concentrations with the ground and satellite-based aerosol concentrations. The results indicate that this model well reproduces the variability and magnitude of aerosol concentrations observed in East Asia. Sensitivity simulations are then used with fixed anthropogenic emissions to investigate the effects of meteorological variability on changes in aerosol concentrations in East Asia. The variability of winter PM2.5 concentrations in northern East Asia was found to be closely correlated with ENSO and Siberian high position. To predict PM2.5 concentrations using key climate indices, we develop multiple linear regression models. As a result, the predicted winter PM2.5 concentrations using the key climate index are well reproduced in the simulated PM2.5 concentrations, especially in northern East Asia.

How to cite: Jeong, J., Park, R., Yeh, S.-W., and Roh, J.-W.: Estimation of winter PM2.5 concentrations in East Asia associated with climate variability, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13479, https://doi.org/10.5194/egusphere-egu2020-13479, 2020.

EGU2020-8290 | Displays | AS3.21

Substantial degradation in Air Quality due to Saddleworth Moor Wildfire

Ailish Graham, James McQuaid, Stephen Arnold, Kirsty Pringle, Richard Pope, Martyn Chipperfield, Luke Conibear, Ed Butt, Laura Kiely, and Christoph Knote

On June 24th 2018 one of the largest UK wildfires in recent history broke out on Saddleworth Moor, close to Manchester, in north-west England. June 2018 was anomalously hot and dry across the UK which led to the peat on the moor drying out and becoming suscpetible to ignition. Since wildfires close to large populations in the UK have been relatively small and rare in the past, there is little knowledge about the impacts. This has prevented the development of effective strategies to reduce them. This paper uses a high-resolution coupled atmospheric-chemistry model to assess the impact of the fires on particulate matter with a diameter less than 2.5 µm (PM2.5) air quality (AQ) across the north-west region and the subsequent impact on health from short-term exposure. We find that the fires substantially degraded AQ across the north-west. PM2.5 concentrations increased by more than 300% in Oldham and Manchester and up to 50% in areas up to 80 km away such as Liverpool, Wigan and Warrington. This led to a third of the population (4.7 million people) in the simulation domain (-4.9-0.7°E and 53.0-54.4°N) being exposed to moderate PM2.5 concentrations on at least one day, according to the Daily Air Quality Index (36-53 µg m-3), between June 23rd and 30th 2018. This equates to 4.5 million people being exposed to PM2.5 above the WHO 24-hour safe-limit exposure of 25 µg m-3 on at least one day. Using a concentration-response function we calculate the short-term health impact which indicates that up to 60% of excess mortality between June 23rd and 30th 2018 was attributable to the fires. This represents up to a 165% increase in excess mortality across the region compared to a simulation with no fires. We find the impact of mortality due to PM2.5 from the fires on the economy was also substantial (£5.5m). Thus, our results indicate the need to introduce legislation and education to both reduce the likelihood of wildfires and reduce the population’s exposure to harmful air pollutants during their occurrence. This is particularly relevant given that wildfires are projected to become more common in the future through climate change and land-use change.

How to cite: Graham, A., McQuaid, J., Arnold, S., Pringle, K., Pope, R., Chipperfield, M., Conibear, L., Butt, E., Kiely, L., and Knote, C.: Substantial degradation in Air Quality due to Saddleworth Moor Wildfire , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8290, https://doi.org/10.5194/egusphere-egu2020-8290, 2020.

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Street Scale Air Pollution Modelling in Antalya on Mediterranean Coast of Turkey

ahmet mustafa tepe, Matthias Ketzel, Ulaş Im, and Güray Doğan

Antalya is a city at the Turkish Riviera located on Mediterranean coast of southwestern Turkey and it is the fifth populated city in Turkey. The city has a downtown population of over 2 million. Agriculture and tourism activities are the most important sources of income in the region. Antalya is a very important tourism destination and welcomes more than 10 million tourists every year.

Nowadays, with the rapid increase in urbanization, air pollution has been one of the most important environmental problems especially in big cities. In order to solve the pollution problems as soon as possible, the largest air pollution sources must be determined first. Air quality models are used extensively in air quality studies as they allow these problems to be identified quickly, cheaply and effectively. The semi-parameterized Operational Street Pollution Model (OSPM®) has been widely used around the globe to determine levels of air pollution on local or street-scale for urban street canyons (Berkowicz 2000, Ketzel et al. 2012).

For this study; four street canyons along the main roads in central Antalya were selected (100. Yıl Avenue, Yener Ulusoy Avenue, Adnan Menderes Avenue, Kızılırmak Street).  Modeling has been carried out for a period of one year (July 2014 – July 2015) for the pollutants PM2.5 and PM2.5-10.

The urban background concentrations for particulate matter (PM2.5 and PM2.5-10) were collected using stack filter unit system. Total of 169 samples were collected once in a two-day period between July 2014 and July 2015 (Tepe 2016). Meteorological parameters and traffic data used in this study were obtained from Turkish State Meteorological Service and Turkish Statistical Institute, respectively.

REFERENCES

Berkowicz, R. OSPM - A Parameterised Street Pollution Model. Environ. Monit. Assess. 65, 323 331 (2000)

Ketzel M, Jensen SS, Brandt J, Ellermann T, Olesen HR, Berkowicz R and Hertel O. Evaluation of the Street Pollution Model OSPM for Measurements at 12 Streets Stations Using a Newly Developed and Freely Available Evaluation Tool. J Civil Environ Eng, S1:004 (2012)

Tepe, A. Investigation of Concentrations and Source Apportionment of Metals Attached to PM2.5 and PM10 in Antalya Ambient Air (Unpublished master’s thesis). Akdeniz University, Antalya, Turkey (2016)

How to cite: tepe, A. M., Ketzel, M., Im, U., and Doğan, G.: Street Scale Air Pollution Modelling in Antalya on Mediterranean Coast of Turkey, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14671, https://doi.org/10.5194/egusphere-egu2020-14671, 2020.

The organic aerosols (OA) contribute significantly to fine particulate mass in the atmosphere, however, most global climate models do not include elaborate treatment associated with the production of secondary organic aerosols (SOA) involving complex chemical processes to save computational time. As a result, the concentrations of SOA simulated by these climate models are often highly uncertain. Moreover, very limited research has been done on SOA and its precursors, particularly on the contribution of individual sources towards the SOA concentrations across India. In this study, we investigate the sensitivity of the production of SOA from different VOC sources and different atmospheric oxidants by the Community Atmospheric Model version 4 coupled with an extensive interactive atmospheric chemistry module (CAM4-Chem). The main objective of our present research is to understand the contribution of individual sources of VOCs towards the production and distribution of SOA across the Indian region. We carried out a series of systematically designed simulations using the CAM4-Chem model to understand the sensitivity of simulated SOA over the Indian region to changes in only emissions of VOCs from anthropogenic, biogenic, and biomass burning emissions from preindustrial (PI) to present-day (PD) period. In order to avoid the influence of changes in meteorology from PI to PD on the production of SOA, all simulations are performed for the same period from 2004 to 2014 with identical meteorology prescribed to the model based on MERRA2 data, while the VOC emissions from anthropogenic, biogenic, and biomass burning sources are allowed to change from PI to PD in different simulations. Our results show that the simulated distribution of SOA over the Indian region in PD is linked to the significant changes in the emissions of VOCs from anthropogenic, biogenic, and biomass burning emissions sources from PI to PD. We find that the changes in emissions of VOCs from biogenic sources from PI to PD associated with land use and land cover changes contribute significantly along with the changes in emissions from anthropogenic sources towards the total changes in SOA distribution over the Indian region over the same period.  The global annual mean burden of SOA from our sensitivity simulations vary in the range of 0.65Tg to 0.80Tg due to variations in emission of different VOCs that are precursors to the production of SOA in the atmosphere. These sensitivity simulations improve our understanding of atmospheric chemistry and specifically about the formation of SOA from different precursor gases originating from diverse anthropogenic, biogenic, and biomass burning emissions sources. More results with greater detail will be presented.

How to cite: Vats, P., Ganguly, D., and Biswas, A.: Investigating the sensitivity in production of SOA from its precursor VOCs with different sources of emissions using an interactive chemistry climate model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19207, https://doi.org/10.5194/egusphere-egu2020-19207, 2020.

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Simulation of SOA formation in the Landes pine forest in south-western France, relative weight of initial ozone, NO3 and OH attack ?

Arineh Cholakian, Matthias Beekmann, Isabelle Coll, Pierre-Marie Flaud, Emilie Perraudin, and Eric Villenave

Organic aerosol (OA) still remains one of the most difficult components of the aerosol to simulate, given the multitude of its formation precursors, the uncertainty of its formation pathways and the lack of measurements of its detailed composition. The LANDEX project (The LANDes Experiment), during its intensive field campaign in summer 2017, gives us the opportunity to compare a detailed list of measurements (VOC, NOx, radicals including NO3, aerosol components, …) obtained within and above the Landes forest canopy, to simulations performed with CHIMERE, a regional Chemistry-Transport Model. The Landes forest is situated in the south-western part of France, and is one of the largest anthropized forest in Europe (1 million ha), composed by a majority of maritime pine trees, strong terpene emitters, providing a large potential for biogenic SOA formation.

In order to simulate organic aerosol build-up in this area, the set-up of a specific model configuration, adapted to local peculiarities, was necessary. As the forest is inhomogeneous, with interstitial agricultural fields, high-resolution 1 km simulations over the forest area were performed, imbedded into a 5 km resolved French and a 25 km resolved European domains. BVOC emissions were predicted by MEGAN, but specific land cover needed to be used, chosen from the comparison of several high-resolution land-cover databases. Also, the tree species distribution needed updated for the specific conditions of the Landes forest. In order to understand the canopy effect in the forest, sensitivity tests were also performed and the diffusivity between the first two layers were changed. The impact of each of these refinements with respect to the standard model set-up on the concentration changes of biogenic VOCs and organic aerosol was calculated and compared to observations. In addition, the sensitivity of SOA build-up with respect to the organic aerosol scheme (standard scheme within CHIMERE, VBS schemes with updated yields for OA formation from BVOCs, …) was assessed.

The ensemble of simulations allowed tracing back the origin of BSOA build-up within and above the Landes forest canopy. Above the canopy, the major simulated pathway of SOA formation is monoterpene oxidation by NO3, while within the canopy, for sufficiently low mixing during nighttime, the NO3 radical is suppressed and only little contributes to SOA build-up. This is in accordance to observations and reactivity considerations which show that within the canopy, ozone attack on sesquiterpenes is the major nighttime SOA source.  

How to cite: Cholakian, A., Beekmann, M., Coll, I., Flaud, P.-M., Perraudin, E., and Villenave, E.: Simulation of SOA formation in the Landes pine forest in south-western France, relative weight of initial ozone, NO3 and OH attack ?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19763, https://doi.org/10.5194/egusphere-egu2020-19763, 2020.

EGU2020-16878 | Displays | AS3.21

Spatial and temporal variability of benzo[a]pyrene over Poland based on modelling and observations

Jacek W. Kaminski, Joanna Struzewska, Pawel Durka, Grzegorz Jeleniewicz, and Marcin Kawka

Benzo[a]pyrene is relatively stable in the atmosphere and can be transported on a regional scale. Benzo[a]pyrene concentrations exceed standard limits in many regions of the world. It is proved that this compound is harmful to the environment and human health.

According to the CAFÉ Directive (2008/50/EC), the objective is to achieve a concentration of B[a]P below 1ng/m3 in PM10 aerosol. Observed B[a]P concentration in Poland is among the highest in Europe. These exceedances are attributed to the emission from individual heating, where many old installations are still in operation. Major B[a]P emissions are due to low-quality fuels and non-reported municipal waste burning.

To support the Chief Inspectorate of Environmental Protection in the frame of the annual assessment for 2018 and five-year assessment for the period 2014-2018, the spatial distribution of B[a]P was calculated using the GEM-AQ model (Kaminski et al. 2008). A new national high-resolution bottom-up emission inventory was used for the entire area of Poland. The results at the resolution of 2.5 km were compared with observations from over 100 stations from the National Measurement Network. We will discuss the spatial and seasonal variability od B[a]P concentrations as well as year-to-year changes related to meteorological conditions.

 

How to cite: Kaminski, J. W., Struzewska, J., Durka, P., Jeleniewicz, G., and Kawka, M.: Spatial and temporal variability of benzo[a]pyrene over Poland based on modelling and observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16878, https://doi.org/10.5194/egusphere-egu2020-16878, 2020.

EGU2020-13640 | Displays | AS3.21

Air pollution and cloud-interaction over Europe in 1985 and today

Roland Schrödner, Christa Genz, Bernd Heinold, Holger Baars, Silvia Henning, Montserrat Costa Surós, Odran Sourdeval, Cintia Carbajal Henken, Nils Madenach, Ina Tegen, and Johannes Quaas

Aerosol concentrations over Europe and Germany were simulated for the years 1985 and 2013 using the aerosol-chemistry transport model COSMO-MUSCAT. The aerosol fields from the two simulations were used in a high-resolution meteorological model for a sensitivity study on cloud properties. The modelled aerosol and cloud variables were compared to a variety of available observations, including satellites, remote sensing and in-situ observations. Finally, the radiative forcing of the aerosol could be estimated from the different sensitivity simulations.

Due to reduction of emissions the ambient aerosol mass and number in Europe was strongly decreased since the 1980s. Hence, today’s number of particles in the CCN size range is smaller. The HD(CP)2 (High Definition Clouds and Precipitation for Climate Prediction) project amongst others aimed at analysing the effect of the emission reduction on cloud properties.

As a pre-requiste, the aerosol mass, number, and composition over Germany were simulated for 1985 and 2013 using the regional chemistry-transport-model COSMO-MUSCAT. The EDGAR emission inventory was used for both years.

The model results were compared to observations from the two HD(CP)2 campaigns that took place in 2013 (HOPE, HOPE-Melpitz) as well as the AVHRR aerosol optical thickness product, which is available from 1981 onwards. Despite the fact, that emissions of the 1980s are very uncertain, the modelled AOD is in good agreement with observations. The modelled mean CCN number concentration in 1985 is a factor of 2-4 higher than in 2013.

Within HD(CP)2, the ICON weather forecast model was applied in a configuration allowing for large-eddy simulations. In these simulations, the time-varying CCN fields for the year 1985 and 2013 calculated with COSMO-MUSCAT were used as input for ICON-LEM. In the present-day simulation, the cloud droplet number agrees with observations, whereas the perturbed (1985) simulation does not with droplet numbers about twice as high as in 2013. Also, for other cloud variables systematic changes between the two scenarios were observed.

How to cite: Schrödner, R., Genz, C., Heinold, B., Baars, H., Henning, S., Costa Surós, M., Sourdeval, O., Carbajal Henken, C., Madenach, N., Tegen, I., and Quaas, J.: Air pollution and cloud-interaction over Europe in 1985 and today, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13640, https://doi.org/10.5194/egusphere-egu2020-13640, 2020.

In December 2015, the Beijing-Tianjin-Hebei (BTH) region in China experienced several episodes of heavy air pollution. The government issued emergency control measures immediately to reduce the pollution, which provided a good opportunity to explore impact of emission reduction on aerosol-radiation interaction. In this study, four tests were conducted, including the BASE1 simulation with emission reduction and aerosol-radiation interaction on, BASE2 simulation with emission reduction and aerosol-radiation interaction off, SEN1 simulation without emission reduction and aerosol-radiation interaction on and SEN2 simulation without emission reduction and aerosol-radiation interaction off. Results show that the aerosol-radiation interaction reduced downward shortwave radiation, temperature at 2 m and boundary layer height in region, but increased the relative humidity at 2 m, which were favorable for pollution accumulation. The interaction effect due to emission reductions increased downward shortwave radiation by 0~5 W/m2 on average, leading to a weak decrease of surface temperature by 0~0.05 °C, a weak decrease of the daytime boundary layer height by 0~8 m, and a weak increase of daytime mean relative humidity at 2m by 0.5%. If there were with aerosol-radiation interaction, it would enhance the effectiveness of emission control measures on air pollution control. The enhancement of PM2.5, PM10, and NO2 emission reduction effects reaches by 7.62%, 6.90%, 11.62% over region, respectively.

How to cite: Guo, C. and Wen, W.: Impact of emission reduction on aerosol-radiation interaction during heavy pollution periods over Beijing-Tianjin-Hebei region in China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-68, https://doi.org/10.5194/egusphere-egu2020-68, 2020.

EGU2020-17502 | Displays | AS3.21

Estimation of Contribution to PM2.5 from Ship Emissions over Korea

Jihyun Seo and Nankyoung Moon

In order to manage fine particulate matter, class 1 carcinogen, various policies are being prepared by the government. The government announced a set a policy measures to confront pollution issues in November 2019. Diesel cars classified as grade 5 will be banned and maximum 27 coal power plants would be plugged off from December to March when fine particulate matter usually worsen to curtail air pollution by more than 20 percent. Despite such efforts, however, it is difficult to improve the concentration of fine particulate matter. In particular, as fine particulate matter management policies are biased toward the management of coal power plants or diesel cars, port and ship emissions management are relatively insufficient.

In the case of major Korea’s port cities such as Busan and Incheon, the impacts of fine particulate matter from ship emissions are analyzed to be significant. In particular, the use of low-grade fuel such as bunker C oil, which has high sulfur content, generates a large amount of fine particulate matter and other air pollutants. As such, for fine particulate matter management in port areas, the impact of ships, cargo handling equipment and cargo trucks, which are major sources of emissions, needs to be quantitatively understood.

Under this background, the emission characteristics of ship emissions were identified by using national air pollutants emissions data in 2015, which improved the calculation method of ship emission sources and the contribution concentration of PM2.5 was analyzed using WRF and CMAQ/BFM. The modelling period is one year in 2016, and the resolution of 9km modeling was applied to Korea.

As one of the main results, the annual mean PM2.5 contribution concentration from domestic ship emission sources was analyzed to be 0.57μg/㎥, and the PM2.5 contribution concentration by local governments was calculated to be most affected by the 1.39μg/㎥ in Busan. The results of this study have not taken into account additional sources of emissions such as cargo handling equipment and cargo trucks using ports, and if this is taken into account, the actual contribution concentration of PM2.5 in port areas is expected to be higher.

The results of this research can be used as basic data when establishing policies for reducing fine particulate matter by major emission sources by local governments.

How to cite: Seo, J. and Moon, N.: Estimation of Contribution to PM2.5 from Ship Emissions over Korea, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17502, https://doi.org/10.5194/egusphere-egu2020-17502, 2020.

EGU2020-21786 | Displays | AS3.21

Intercomparison of ship emission data models for the North and Baltic Sea region

Ronny Petrik, Kristina Deichnik, Daniel Schwarzkopf, Volker Matthias, and Armin Aulinger

International ship traffic is steadily increasing since many years. The associated emission of pollutants like sulphur and nitrogen compounds has strong effects on the coastal air quality and the environment. For instance, investigations of Sofiev et al. (2018) show that the ships contribute about 20 % to the sulphur dioxide and 9 % to the global emission of nitrogen oxides. Thus, shipping is also important for climate change  through emissions of greenhouse gases and aerosol particles and the input of acidifying and eutrophying substances into coastal waters.

Therefore, an accurate estimation of ship emissions and their spatio temporal distribution is an important key to understand and investigate coastal ecosystems. The major prerequisite is a precise record of ship movements and related pollutant emissions. In our contribution we present an intercomparison between different ship emission data models for the North and Baltic Sea region. That is the inventory of the Bundesamt für Schiffahrt und Hydrography (EMMA) and the inventory of the HZG (HiMEMO-Ship, Aulinger 2016) are compared against a reference inventory from the Finnish Meteorological institute (STEAM, Jalkanen 2012). The HiMEMO-Ship is a highly flexible tool under ongoing development and allows for temporally and spatially highly-resolved ship emission data (>=30min and >=500 m) of 9 chemical species including aerosols. The tool is designed to consider also adaptation scenarios (e.g. MARPOL Annex VI regulation).
The uncertainty of the derived emissions are discussed on the basis of two means: a) a multi-parameter ensemble generated with the HZG-model and b) a multi-model ensemble using the 3 afore-mentioned approaches (“EMMA”, ”STEAM” and “HiMEMO-Ship”). The results imply that a large portion of emissions are related to ships with actually only insufficiently known characteristics, which thus cause a large range of uncertainty regarding their emission factors. Moreover, a large spread for mean NOx emissions is detected between inventories for the North Sea region. Because of complex manoeuvers and machine handling in the busy port areas, we also observe significant differences in emissions in that regions. Finally, a strategy is presented for treating the afore-mentioned issues with ship emission data in the framework of atmospheric chemistry transport modelling, i.e. deposition of pollutants
from the air.

How to cite: Petrik, R., Deichnik, K., Schwarzkopf, D., Matthias, V., and Aulinger, A.: Intercomparison of ship emission data models for the North and Baltic Sea region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21786, https://doi.org/10.5194/egusphere-egu2020-21786, 2020.

EGU2020-2905 | Displays | AS3.21

Characterizing the vertical concentration profiles of ship plumes with a microscale model - is it all Gaussian?

Ronny Badeke, Volker Matthias, David Grawe, and Heinke Schlünzen

Accurate modeling of ship emissions is a topic of increasing interest due to the ever-growing global fleet and its emission of air pollutants. With the increasing calculation power of modern computers, numerical grid models can nowadays be used to analyze effects of shipping emissions from global to local scales. However, modeling entire ports and larger domains still requires a good representation for the vertical concentration profile of single ship plumes. As the shape of the plume strongly varies depending on parameters like plume temperature, ship-induced turbulence and meteorological conditions, the plume dilution does not always appear to be represented by a simple Gaussian distribution. In this work, the microscale model MITRAS is used to calculate vertical concentration profiles of ship plumes under varying technical and meteorological scenarios. The resulting curves are fitted with different mathematical curves (e.g. Gaussian, Polynomial and Gamma distribution) by a least square minimization approach and the best representations for individual scenarios are discussed.

How to cite: Badeke, R., Matthias, V., Grawe, D., and Schlünzen, H.: Characterizing the vertical concentration profiles of ship plumes with a microscale model - is it all Gaussian?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2905, https://doi.org/10.5194/egusphere-egu2020-2905, 2020.

AS3.22 – Urban Air Quality and Greenhouse Gases

EGU2020-12648 | Displays | AS3.22

Land use regression modelling of ambient air pollutants in Hong Kong

Zhiyuan Li, Steve Hung Lam Yim, and Kin-Fai Ho

Land use regression (LUR) models estimate air pollutant concentrations for areas without air quality measurements, which provides valuable information for exposure assessment and epidemiological studies. In the present study, we developed LUR models for ambient air pollutants in Hong Kong, China, a typical high-density and high-rise city. Air quality measurements at sixteen air quality monitoring stations, operated by the Hong Kong Environmental Protection Department, were collected. Moreover, five categories of predictor variables, including population distribution, traffic emissions, land use variables, urban/building morphology, and meteorological parameters, were employed to establish the LUR models of various air pollutants. Then the spatial distribution of air pollutant concentrations at 1 km × 1 km grid cells were plotted. Taking fine particle (PM2.5) as an example, the developed LUR model explained 89% of variability of PM2.5 concentrations, with a leave-one-out-cross-validation R2 of 0.64. LUR modelling results for other air pollutants will be presented. In addition, further improvements on the development of LUR models will be discussed. This study can help to assess long-term exposures to air pollutants for high-density and high-rise urban areas like Hong Kong.

How to cite: Li, Z., Yim, S. H. L., and Ho, K.-F.: Land use regression modelling of ambient air pollutants in Hong Kong , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12648, https://doi.org/10.5194/egusphere-egu2020-12648, 2020.

EGU2020-5068 | Displays | AS3.22 | Highlight

Impacts of air pollution related to fine particulate matter on present and future European urban mortality: a renewable energy mitigation scenario

Patricia Tarín-Carrasco, Ulas Im, Laura Palacios-Peña, and Pedro Jiménez-Guerrero

Cities are hotspots for exposure to air pollution worldwide. The impact of atmospheric pollutants on human health is a main topic of concern related to health issues in urban areas; and there evidence that this problem will become worse under future climate change scenarios. One of the main anthropogenic pollutants released at cities that

impacts human mortality is particulate matter (PM). The riskiness of PM resides in both its composition and size. In particular, this study is focused on fine particles (particles with a diameter of 2.5μm or less, PM2.5). PM2.5 can reach lungs, pulmonary alveoli or even bloodstream being transported through the entire human body. In this sense, the emission of PM2.5 from combustion processes coming from energy production in cities can be a major health problem needing for mitigation policies regarding anthropogenic regulatory pollutants. In this sense, a bet for renewables energies can help the definition of mitigation strategies and can contribute to a better future urban air quality.

Henceforth, this study assesses the impacts of present (1991-2010) and future (RCP8.5,2031-2050) urban air pollution by fine particles on several Non-Communicable Diseases (NCD) mortality causes (Lung Cancer, Chronic Obstructive Pulmonary Disease, Ischaemic Heart Disease, Stroke, Lower Respiratory Infection and All diseases). Climate change scenarios were run by using the WRF-Chem online-coupled meteorological/chemistry model in framework of the Spanish REPAIR and ACEX projects, operated over an Euro-CORDEX compliant simulation domain. For the future scenarios, two alternatives under the RCP8.5 climate change scenarios are analysed: (1) business-as-usual energy production system and emissions, and (2) an scenario in which 80% of the European energy is obtained from renewable sources. The emission factors for energy production (g/GJ) were obtained from EMEP/EEA air pollutant emission inventory guidebook–2016.

The differences between both scenarios (future vs. present approach) provide the changes in future mortality caused by air pollution. We estimated the mortalities by using non-linear exposure-response functions. Furthermore, a novel contribution of this work is that changes in future population for the 2050 horizon have been taken into account. Different risk ratio and baseline mortalities for each pathology have been estimated in every age range (25-29, 30-34, 35-39, 40-44, 45-49, 50-54, 55-59, 60-64, 65-69, 70-74, 75-79, +80 and all ages). Data was obtained from Institute for Health Medicine.

The results obtained indicate that almost 900,000 deaths per year in Europe are caused by PM2.5 for the present scenario. Generally, the mortality will increase for both future scenarios. The total mortality on the future RCP8.5 scenario accounts for 1,500,000 deaths for the business-as-usual energy production scenario and 1,480,000 for the future scenario considering 80% of renewable energy production. Eastern Europe is the area most benefited with the change of energy production on the future because the number of deaths will be lower. Stroke is the cause which count with high of deaths in Europe.

 

Acknowledgments: Project ACEX (CGL-2017-87921-R) of the Spanish Ministry of Economy and Competitiveness, Fundación Biodiversidad of the Spanish Ministry for the Ecological Transition, and FEDER European program, for support to conduct this research.

How to cite: Tarín-Carrasco, P., Im, U., Palacios-Peña, L., and Jiménez-Guerrero, P.: Impacts of air pollution related to fine particulate matter on present and future European urban mortality: a renewable energy mitigation scenario, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5068, https://doi.org/10.5194/egusphere-egu2020-5068, 2020.

EGU2020-13006 | Displays | AS3.22

The effects of anthropogenic heat fluxes on regional meteorology and air quality in typical city clusters of China

Min Xie, Tijian Wang, Jie Shi, Mengmeng Li, Da Gao, and Chenchao Zhan

Anthropogenic heat (AH) can affect regional meteorology and air quality. The spatial distributions of AH fluxes in the typical city clusters of China are estimated. Moreover, in order to study their impacts on regional atmospheric environment, these heat fluxes are incorporated into the modified WRF/Chem with the seasonal and the diurnal variation. The modeling results show that AH fluxes over YRD and PRD have been growing in recent years. The high values of AH can reach 113.5 W/m2 in YRD and 60 W/m2 in PRD, respectively. AH fluxes can significantly change the urban meteorology. In YRD, 2-m air temperature (T2) increases by 1.6 °С in January and 1.4°С in July, the planetary boundary layer height (PBLH) rises up by 140m in January and 160m in July, and 10-m wind speed (W10) is intensified by 0.7 m/s in January and 0.5 m/s in July. More moisture can be transported to higher levels, and increase the accumulative precipitation by 15-30% in July of YRD. In PRD, T2 rises up by 1.1°С in January and over 0.5°С in July, the PBLH increases by 120m in January and 90m in July, W10 is enhanced over 0.35 m/s in January and 0.3 m/s in July, and the accumulative precipitation is intensified by 20-40% in July. These changes in meteorology can influence the distribution of air pollutants as well. Due to the increase of PBLH, surface wind speed and upward movement, the concentrations of primary air pollutants decrease near surface and increase at the upper layers over the cities. Chemical effects can play a significant role in ozone changes over the urban areas of YRD, so ozone concentrations increase at surface and decrease at the upper layers. In PRD cities, however, the chemical effects play a significant role in ozone changes in winter, while the vertical movement can be the dominant effect in summer. Thus, ozone concentrations in big cities increase in January, but decrease at the lower layers and increase at the upper layers in July. In all, AH fluxes should not be ignored in urban meteorology and air quality assessments.

How to cite: Xie, M., Wang, T., Shi, J., Li, M., Gao, D., and Zhan, C.: The effects of anthropogenic heat fluxes on regional meteorology and air quality in typical city clusters of China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13006, https://doi.org/10.5194/egusphere-egu2020-13006, 2020.

EGU2020-7379 | Displays | AS3.22

The development of a multi-scale modelling system for evaluation of urban NOx levels in Modena (Italy)

Giorgio Veratti, Sara Fabbi, Alessandro Bigi, Aurelia Lupascu, Gianni Tinarelli, Sergio Teggi, Giuseppe Brusasca, Tim M. Butler, and Grazia Ghermandi

In order to support environmental policies, epidemiological studies and urban mobility planning, a multi-scale modelling system was developed to provide hourly NO(NO + NO2) concentration fields at a building-resolving scale in the urban area of Modena, a city in the middle of the Po Valley (Italy). The modelling system relied on two different models: the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem), which is able to compute concentration fields over regional domain by considering specific emission scenarios, and Parallel Micro SWIFT SPRAY (PMSS), a Lagrangian particle model accounting for dispersion phenomena within the urban area. PMSS was used to simulate at building-scale resolution the NOdispersion produced by urban traffic flows in the city of Modena. Conversely, WRF-Chem was selected to estimate the NObackground concentrations over three nested domains with resolution of 15, 3 and 1 km in order to take into account emissions both at regional and local scale by excluding traffic emissions sources over the city of Modena. The estimation of traffic emissions in the urban area of Modena was based on a bottom-up approach relying on the Emission Factors suggested by the European Monitoring and Evaluation Programme (EMEP/EEA) and traffic fluxes estimated by the PTV VISUM model. By contrast, other anthropogenic emissions were taken from the TNO-MACC III inventory at the scales resolved by the WRF-Chem model.

Simulation was performed between 28 October and 8 November 2016, the same period whereby a direct vehicle flow measurement campaign was carried out continuously, with 4 Doppler radar counters in a four-lane road in Modena, to reproduce the hourly modulation rates of the emissions. The performances of the model chain were finally assessed by comparing modelled NOconcentrations with observations at two air quality monitoring stations located inside the urban domain.

Simulated and observed NOhourly concentrations exhibit a large agreement, in particular for urban traffic site where detailed traffic emissions estimation (real traffic modulation combined with a bottom-up approach) proved to be very successful in reproducing the observed NOpattern. At the urban background station, notwithstanding a general underestimation of the observed concentrations (more pronounced than at the urban traffic site), the analysis of hourly daily modelled concentrations shows that PMSS combined with WRF-Chem provided a daily pattern in line with observations. These features highlight the strength of this modelling chain in representing urban air quality, in particular at traffic sites, whose concentration levels make them the most critical area of the city; characteristics that chemical transport models alone cannot express, due to the coarser resolution to which they operate and to their inability to reproduce street canyons and urban structures.

How to cite: Veratti, G., Fabbi, S., Bigi, A., Lupascu, A., Tinarelli, G., Teggi, S., Brusasca, G., Butler, T. M., and Ghermandi, G.: The development of a multi-scale modelling system for evaluation of urban NOx levels in Modena (Italy), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7379, https://doi.org/10.5194/egusphere-egu2020-7379, 2020.

EGU2020-11611 | Displays | AS3.22

Mapping Air Pollution eMissions (MAPM)

Stefanie Kremser, Sara Mikaloff-Fletcher, Brian Nathan, Ethan Dale, Jordis Tradowsky, Leroy Bird, Greg Bodeker, Dongqi Lin, Guy Coulson, Marwan Katurji, Gustavo Olivares, Tim Mallett, Laura Revell, and Ian Longley

The growth of megacities from global urbanization has degraded urban air quality sufficient to impede economic growth and create a public health hazard. Emissions of particulate matter, photochemically reactive gases, and long-lived greenhouse gases, contribute to the urban environmental footprint with concomitant economic and social costs. Mitigation actions rely critically on knowing where these emissions occur. In response to this challenge, our team has developed a new method, MAPM (Mapping Air Pollution eMissions), to generate near real-time surface emissions maps of particulate matter pollution. Surface particulate matter (PM 2.5) emission maps will be derived from atmospheric measurements of particulate matter using an inverse model in conjunction with a state-of-the-art mesoscale atmospheric model.

The MAPM methodology is validated and refined using particulate matter measurements made during a field campaign that took place in Christchurch, New Zealand from June to September 2019. Key questions that MAPM aims to answer include:

  • How do uncertainties on the PM 2.5 measurements affect the quality of the emissions maps we extract from our inverse model.
  • How do uncertainties in the meteorological data affect the quality of the emissions maps we extract from our inverse model.
  • How does the spatial and temporal resolution of the air pollution concentration measurements affect the uncertainties in the retrieved pollution emissions maps?

Here we will not only present the measurements made during the winter field campaign but also present the first derived PM 2.5 emissions maps for the city of Christchurch.

How to cite: Kremser, S., Mikaloff-Fletcher, S., Nathan, B., Dale, E., Tradowsky, J., Bird, L., Bodeker, G., Lin, D., Coulson, G., Katurji, M., Olivares, G., Mallett, T., Revell, L., and Longley, I.: Mapping Air Pollution eMissions (MAPM), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11611, https://doi.org/10.5194/egusphere-egu2020-11611, 2020.

In most European cities, the key air pollutants driving adverse health outcomes are nitrogen dioxide (NO2) and fine particulate matter (PM2.5), with 64% of new paediatric asthma cases in urban centres attributed to elevated NO2 levels (Achakulwisut et al., 2019). In the complex landscape of a city, a synthesis of techniques to quantify air pollution is required to account for variations in traffic, meteorology, and urban geometry.

Here, we present the results from a comparison study between measured air pollutant data collected at Marylebone Road, London and the output from a three-stage modelling chain. This site was chosen due to the availability of road-side air quality data collected within a street canyon (aspect ratio approximately equal to 1) and daily traffic flow in excess of 70,000 motor vehicles. The modelling chain consists of: 1) real-time traffic information of vehicle journey times, 2) speed-related emission calculations, and 3) air quality box-model to simulate the interaction of pollutants within the environment.

While the transport sector accounts for much of the outdoor air pollution in UK cities, a limiting factor of current techniques is that traffic is approximated at coarse temporal and spatial resolutions. In this study, we present a novel technique that helps to ‘fill in’ the gaps in our traffic data by harnessing the power of real-time queries to Google Maps to obtain travel times between fixed locations, enabling the derivation of average vehicle speeds. This dataset can then be used to determine more accurate emission factors for NOx. Total emissions are then calculated with the aid of traffic flow data and vehicle fleet characteristics. The air quality box model simulates photochemical reactions that form NO2, the exchange of pollutants with the background air aloft, and advection of pollutants along the street.

Hourly travel times and total vehicle flow data were collected between July and October 2019, totalling 905 observations and calculated emissions values. Meteorological data from Heathrow airport and background air quality from the Kensington AURN site were used as supporting inputs to the air quality box model. Each observation was treated as a starting point of the box model, and the simulation was run for 1 hour, with mixing due to advection occurring every 60 seconds. Results are promising; when using the full model chain modelled and measured NO2 concentrations are significantly correlated (r = 0.467, p < 0.000). In comparison, when a constant speed of 30 mph is used to calculate total emissions, therefore excluding the impact of congestion, the strength of the correlation decreases (r = 0.362, p < 0.000) and the model underestimates pollutant concentrations.

The applications of this model chain are vast. For any street that is covered by a suitable mapping platform and has available data on vehicle numbers, it would be possible to provide a real-time estimation of pollutant concentrations at a high temporal resolution. This could be utilised in several ways, such as: assessing policy implementation, and providing a high resolution input for air quality modelling and health exposure studies.

How to cite: Pearce, H., Gong, Z., Cai, X., and Bloss, W.: From Google Maps to Air Quality: a big data approach to modelling real-time NO2 concentrations in an urban street canyon from road traffic data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4768, https://doi.org/10.5194/egusphere-egu2020-4768, 2020.

EGU2020-1314 | Displays | AS3.22

Statistical modelling of combined ozone-temperature events in Europe

Sally Jahn and Elke Hertig

Air pollution as well as high air temperature both pose a large risk to human health in Europe. High temperature levels are associated with an exceptionally high mortality rate, only representing the extreme end of a wide range of possible health effects. Tropospheric ozone, a secondary air pollutant, is primarily built by photochemical reactions under solar radiation with the involvement of precursor gases including nitrogen oxides, carbon monoxide, methane, and non-methane volatile organic compounds. Due to the specific characteristics of ozone formation, high levels of ozone and temperature often coincide, posing an even intensified threat to human health.

The current scientific work focuses on the co-occurrence of these two health stressors as well as their underlying meteorological conditions. A subset of European ozone (AirBase_v8, EEA) and temperature (ECA&D) stations is selected for analysis based on individual station locations and data coverage. Taking into account different settings of air substances concentrations (urban, outer conurbation area, rural regions), these stations are classified and grouped by station type and area type resulting in five distinct station classes: urban traffic, urban background, suburban background, rural background and rural industrial.

Maximum daily 8-hour average ozone values (MDA8O3, EEA), observed daily maximum air temperatures (TX, ECA&D) and meteorological variables (from ERA5, ECMWF) form the data basis for model building. Current thresholds and extreme definitions e.g. based on WHO air quality guidelines or high percentiles (75th and 90th) are examined and discussed to describe elevated levels of these variables and to finally define combined ozone-temperature events.

Possible regional patterns as well as disparities between urban and rural areas regarding the specific settings for ozone formation as well as varying meteorological mechanisms for the occurrence of combined ozone-temperature events are closely examined. The methodological focus is primary on statistical modelling, the application and comparison of varying multivariate statistical approaches and different machine learning methods, e.g. various regression analyses using shrinkage methods or random forests. Consequently, statistical models are generated to analyse the influence of meteorological conditions on the occurrence of combined ground-level ozone and temperature events along with the identification of primary key factors (e.g. ozone persistence or larger-scale air temperature and wind conditions) at each specific location.

Furthermore, frequency and intensity changes of combined ozone-temperate events in the scope of global warming are assessed. Thus, projections of these co-occurring events under the constraints of ongoing climate change until the end of the 21st century are analysed by integrating projections of general circulation models into the statistical modelling process.

How to cite: Jahn, S. and Hertig, E.: Statistical modelling of combined ozone-temperature events in Europe , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1314, https://doi.org/10.5194/egusphere-egu2020-1314, 2020.

EGU2020-7523 | Displays | AS3.22

Measuring Spatial and Temporal Patterns of Urban NO2 Concentrations by combining mobile and stationary DOAS instruments

Mark Wenig, Ying Zhu, Sheng Ye, Ka Lok Chan, Jia Chen, Florian Dietrich, Xiao Bi, and Gerrit Kuhlmann

In many cities around the world the NO2 concentration levels exceed WHO guideline limits. Urban air quality is typically monitored using a relatively small number or monitoring stations that follow certain guidelines in terms of inlet height and location relative to streets. However, the question remains how a limited number of point measurements can represent the city-wide air quality and capture spatial patterns. Measurement campaigns in Hong Kong and Munich were conducted, using a combination of mobile in-situ and stationary remote sensing differential optical absorption spectroscopy (DOAS) instruments. In order to separate spatial and temporal patterns, we developed an algorithm based on a combination of mobile and stationary data sets that corrects for the diurnal cycle in the mobile measurements.  We constructed pollution maps from the corrected measurements that represent daily average NO2 exposure. The maps have been used to identify pollution hot spots, determine the spatial dependency of long-term changes, and capture the weekly cycles of on-road NO2 levels in Hong Kong and Munich. Since our method can also be used to determine the spatial representativeness of the monitoring stations in cities, it is very valuable tool for identifying suitable locations for air quality monitoring stations.

How to cite: Wenig, M., Zhu, Y., Ye, S., Chan, K. L., Chen, J., Dietrich, F., Bi, X., and Kuhlmann, G.: Measuring Spatial and Temporal Patterns of Urban NO2 Concentrations by combining mobile and stationary DOAS instruments, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7523, https://doi.org/10.5194/egusphere-egu2020-7523, 2020.

EGU2020-11337 | Displays | AS3.22

Observation of NO2 air pollution distribution maps in cities with mobile ICAD bicycle measurements

Denis Pöhler, Oliver Fischer, Martin Weinreich, Sven Riedner, Martin Horbanski, Johannes Lampel, Stefan Schmitt, and Ulrich Platt

Nitrogen Dioxide (NO2) is currently the most critical air pollutant in Europe. The main source is traffic, especially diesel engines, and its concentration is highly variable. However, NO2 levels are only measured in larger cities at few measurement points. Passive samplers can provide a better spatial coverage but contain no temporal information about the NO2 variability at that location. Electrochemical sensors require a lot of manpower and additional parameters to be measured simultaneously to achieve sufficient accuracy and are thus not practical.

We apply the mobile, low power and high precision ICAD NO2 / NOx instrument (Airyx GmbH) to observe the distribution of NO2 concentration in a city or in industrial facilities. For example, smaller cities are of interest where so far no information about air pollution levels and possible hot spots are available. Measurements are conducted on a bicycle at ~1.6m height and beside the road-line (with a time resolution of 2s and 1ppb accuracy) to be comparable to data from permanent measurement stations. Along a predefined route through the city, covering different street types, repeated measurements at different days and times are performed.

We present results from measurements in multiple cities with focus on the small city of Walldorf in South-West Germany. An NO2 distribution map was derived from mobile bicycle measurements over a period of 3 months. Locations with increased air pollution levels are clearly identified. Additionally, extrapolated annual average NO2 level and its distribution were estimated by comparison with an urban air monitoring station in 6km distance. The method for this annual mean extrapolation will be described. For two hot spot locations the derived extrapolated annual mean concentration was validated in a second campaign with intensive stationary measurements using the same instrument in a small trailer. The annual mean concentrations agreed within ~10% and prove the mobile measurement results, not only for these locations, but also in general for this method. Due to the high time resolution of the data additional emission sources can be identified.

This example shows that it is possible to derive reliably annual mean NO2 air pollution distribution maps with few repeated mobile measurements and thus increase our understanding of real air pollution levels on a broad scale in a city.

Mobile measurements were also performed in industrial facilities like mines. An example of such measurements will be presented.

How to cite: Pöhler, D., Fischer, O., Weinreich, M., Riedner, S., Horbanski, M., Lampel, J., Schmitt, S., and Platt, U.: Observation of NO2 air pollution distribution maps in cities with mobile ICAD bicycle measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11337, https://doi.org/10.5194/egusphere-egu2020-11337, 2020.

EGU2020-2822 | Displays | AS3.22

Assessment of heterogenity of air pollution within an urban canopy

Vivien Voss, K. Heinke Schlünzen, and David Grawe

Air pollution is an important topic within urban areas.  Limit values as given in the European Guidelines are introduced to reduce negative effects on humans and vegetation.  Exceedances of the limit values are to be assessed using measurements.  In case of found exceedances of the limit values, the local authorities need to act to reduce pollution levels. Highest values are found for several pollutants (NOx, NO2, particles) within densely build-up urban areas with traffic emissions being the major source and dispersion being very much impacted by the urban structures.  The quality assured measuring network used by the authorities is often too coarse to determine the heterogeneity in the concentration field. Low cost sample devices as employed in several citizen science projects might help to overcome the data sparsity. Volunteers measure the air quality at many sites, contribute to the measurement networks and provide the data on the web. However, the questions arising are: a) Are these data of sufficient high quality to provide results comparable to those of the quality assured networks? b) Is the network density sufficient to determine concentration patterns within the urban canopy layer?
One-year data from a citizen science network, which measures particulate matter (PM10, PM2.5) were compared to measurements provided by the local environmental agency, using two hot-spot areas in the city of Hamburg as an example. To determine how well the measurements agree with each other, a regression analyses was performed dependent on seasonal and diurnal cycles. Additionally, model simulations with the microscale obstacle resolving model MITRAS were performed for two characteristic building structures and different meteorological situations. The model results were used to determine local hot spots as well as areas where measurements might represent the concentration of particles for the urban quarter. The low cost sensor measurements show a general agreement to the city’s measurements, however, the values per sensor differ. Moreover, the measurements of the low-cost-sensor show an unrealistic dependence on relative humidity, resulting in over- or underestimations in certain cases. The model results clearly show that only a few sites allow measurements to be representative for a city quarter. The measurements of the citizen science project can provide a good overview about the tendencies of the air quality, but are currently not of sufficient quality to provide measurements calling for legal action.

The model results were used for the project AtMoDat. AtMoDat is an attempt to create a data standard for obstacle resolving models based on the existing Climate and Forecast (CF) conventions. A web-based survey is developed to get information on the requirements for the data standard. The next step is to extend the collection of model characteristics and eventually to provide a generic scheme.

Acknowledgements
This work contributes to project “AtMoDat” funded by the Federal Ministry of Education and Research under the funding number 16QK02C. Responsibility for the content of this publication lies with the authors.

How to cite: Voss, V., Schlünzen, K. H., and Grawe, D.: Assessment of heterogenity of air pollution within an urban canopy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2822, https://doi.org/10.5194/egusphere-egu2020-2822, 2020.

EGU2020-9172 | Displays | AS3.22

Networks of Air Quality Sensors and Their Use for High-resolution Mapping of Urban Air Quality

Philipp Schneider, Nuria Castell, Paul Hamer, Sam-Erik Walker, and Alena Bartonova

One of the most promising applications of low-cost sensor systems for air quality is the possibility to deploy them in relatively dense networks and to use this information for mapping urban air quality at unprecedented spatial detail. More and more such dense sensor networks are being set up worldwide, particularly for relatively inexpensive nephelometers that provide PM2.5 observations with often quite reasonable accuracy. However, air pollutants typically exhibit significant spatial variability in urban areas, so using data from sensor networks alone tends to result in maps with unrealistic spatial patterns, unless the network density is extremely high. One solution is to use the output from an air quality model as an a priori field and as such to use the combined knowledge of both model and sensor network to provide improved maps of urban air quality. Here we present our latest work on combining the observations from low-cost sensor systems with data from urban-scale air quality models, with the goal of providing realistic, high-resolution, and up-to-date maps of urban air quality.

In previous years we have used a geostatistical approach for mapping air quality (Schneider et al., 2017), exploiting both low-cost sensors and model information. The system has now been upgraded to a data assimilation approach that integrates the observations from a heterogeneous sensor network into an urban-scale air quality model while considering the sensor-specific uncertainties. The approach further ensures that the spatial representativity of each observation is automatically derived as a combination of a model climatology and a function of distance. We demonstrate the methodology using examples from Oslo and other cities in Norway. Initial results indicate that the method is robust and provides realistic spatial patterns of air quality for the main air pollutants that were evaluated, even in areas where only limited observations are available. Conversely, the model output is constrained by the sensor data, thus adding value to both input datasets.

While several challenging issues remain, modern air quality sensor systems have reached a maturity level at which some of them can provide an intra-sensor consistency and robustness that makes it feasible to use networks of such systems as a data source for mapping urban air quality at high spatial resolution. We present our current approach for mapping urban air quality with the help of low-cost sensor networks and demonstrate both that it can provide realistic results and that the uncertainty of each individual sensor system can be taken into account in a robust and meaningful manner.

 

Schneider, P., Castell N., Vogt M., Dauge F. R., Lahoz W. A., and Bartonova A., 2017. Mapping urban air quality in near real-time using observations from low-cost sensors and model information. Environment international, 106, 234-247.

How to cite: Schneider, P., Castell, N., Hamer, P., Walker, S.-E., and Bartonova, A.: Networks of Air Quality Sensors and Their Use for High-resolution Mapping of Urban Air Quality, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9172, https://doi.org/10.5194/egusphere-egu2020-9172, 2020.

EGU2020-14358 | Displays | AS3.22

AQSens: An Interoperable Platform Integrating Citizen Science and Authoritative Air Quality Data

Simon Jirka, Eike Hinderk Jürrens, Benedikt Gräler, Carsten Hollmann, Alexander Kotsev, Michel Gerboles, Annette Borowiak, and Sven Schade

Over the last few years there have been many activities to evaluate and use air quality measurements gathered by lower cost devices. This is especially intended to complement the coverage of official air quality measurement networks that deliver authoritative air quality data. Examples of such activities include the AirSensEUR project of the Joint Research Centre (JRC), luftdaten.info, or hackAIR. Combining the data from multiple sources remains a challenge for utilising the full potential of those developments.

With this presentation we aim to introduce the development of an interoperable data platform that allows to integrate both authoritative as well as citizen science air quality measurements. Our presentation will cover especially the following aspects:

Interoperability: For sharing the collected data and to avoid the creation of isolated data silos, it is important to use open interfaces and data encodings. In case of the AQSens project, this comprises the provision of INSPIRE-compliant Download Services based on the SensorThings API (STA) and Sensor Observation Service (SOS) standards of the Open Geospatial Consortium.

Data analytics: Besides providing access to the raw data, different types of data analysis are necessary. On the one hand this comprises the validation of incoming citizen science data in conjunction with corresponding authoritative data sources. On the other hand, the aim is to provide a tool for further data analysis on top of the collected data. For this purpose we show, how the R programming language can be linked to the Sensor Web Server via a dedicated R package (sos4R).

Data visualisation: Finally, for enabling the visual exploration of the collected data, a Web-based client application will be provided. This allows users to connect to the published air quality Data Download Services (in this case the OGC SensorThings API) and to request graph-based time series visualisations combining data from potentially different sources.

In summary, our presentation will show how existing interoperability standards as well as Web technologies can be used for building a Cloud-ready data platform (i.e. relying on Docker) that enables the collection, management, analysis, and visualisation of both Citizen Science and authoritative air quality data.

How to cite: Jirka, S., Jürrens, E. H., Gräler, B., Hollmann, C., Kotsev, A., Gerboles, M., Borowiak, A., and Schade, S.: AQSens: An Interoperable Platform Integrating Citizen Science and Authoritative Air Quality Data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14358, https://doi.org/10.5194/egusphere-egu2020-14358, 2020.

EGU2020-2852 | Displays | AS3.22

Sensor network for traffic-related pollutant monitoring in urban public transport interchanges

Li Sun, Peng Wei, Jieqing He, Dane Westerdahl, and Zhi Ning

EGU2020-10942 | Displays | AS3.22 | Highlight

MOPGA/Make Air Quality Great Again: Filling in the air quality data gap in Africa using lower-cost RAMP monitors

Ramachandran Subramanian, Matthias Beekmann, Carl Malings, Anais Feron, Paola Formenti, Michael Giordano, Beatrice Marticorena, Corinne Galy-Lacaux, Catherine Liousse, Joseph Adesina, Stuart Piketh, Kofi Amegah, Julien Bahino, Véronique Yoboué, Laouali Dungall, Rebecca M Garland, Jimmy Gasore, Vincent Madadi, and Jean-Louis Rajot

Ambient air pollution is a leading cause of premature mortality across the world, with an estimated 258,000 deaths in Africa (UNICEF/GBD 2017). These estimated impacts have large uncertainties as many major cities in Africa do not have any ground-based air quality monitoring. The lack of data is due in part to the high cost of traditional monitoring equipment and the lack of trained personnel. As part of the “Make Air Quality Great Again” project under the “Make Our Planet Great Again” framework (MOPGA), we propose filling this data gap with low-cost sensors carefully calibrated against reference monitors.

Fifteen real-time affordable multi-pollutant (RAMP) monitors have been deployed in Abidjan, Côte d'Ivoire; Accra, Ghana; Kigali, Rwanda; Nairobi, Kenya; Niamey, Niger; and Zamdela, South Africa (near Johannesburg). The RAMPs use Plantower optical nephelometers to measure fine particulate matter mass (PM2.5) and four Alphasense electrochemical sensors to detect pollutant gases including nitrogen dioxide (NO2) and ozone (O3).

Using a calibration developed in Créteil, France, the deployments thus far reveal morning and evening spikes in combustion-related air pollution. The median hourly NO2 in Accra and Nairobi for September-October 2019 was about 11 ppb; a similar value was observed across November-December 2019 in Zamdela. However, a previous long-term deployment of the RAMPs in Rwanda showed that, for robust data quality, low-cost sensors must be collocated with traditional reference monitors to develop localized calibration models. Hence, we acquired regulatory-grade PM2.5, NO2, and O3 monitors for Abidjan and Accra. We also collocated RAMPs with existing reference monitors in Zamdela, Kigali, Abidjan, and Lamto (a rural site in Côte d'Ivoire). In this talk, we will present results on spatio-temporal variability of collocation-based sensor calibrations across these different cities, source identification, and challenges and plans for future expansion.

How to cite: Subramanian, R., Beekmann, M., Malings, C., Feron, A., Formenti, P., Giordano, M., Marticorena, B., Galy-Lacaux, C., Liousse, C., Adesina, J., Piketh, S., Amegah, K., Bahino, J., Yoboué, V., Dungall, L., Garland, R. M., Gasore, J., Madadi, V., and Rajot, J.-L.: MOPGA/Make Air Quality Great Again: Filling in the air quality data gap in Africa using lower-cost RAMP monitors, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10942, https://doi.org/10.5194/egusphere-egu2020-10942, 2020.

EGU2020-7241 | Displays | AS3.22

Brown carbon aerosol in urban Beijing: Significant contributions from biomass burning and secondary formation

Ting Wang, Rujin Huang, Lu Yang, Wei Yuan, and Yuquan Gong

Atmospheric brown carbon (BrC) has significant impact on Earth’s radiative budget. However, due to our very limited knowledge about the relationship between BrC light absorption and the associated sources, the estimation for radiative effects of BrC is still largely constrained. In this study, we combine ultraviolet−visible (UV−vis) spectroscopy measurements and chemical analyses of BrC samples collected from January to December 2015 in urban Beijing, to investigated the sources of atmospheric BrC. The multiple liner regression model was applied to apportion the contributions of individual primary and secondary organic aerosol (OA) source components to light absorption of BrC. Our results indicated that biomass burning emission and secondary formation are highly absorbing up to 500 nm, and their contributions increased with the wavelengths. In contrast, the contribution of traffic emission and coal combustion to total absorption decreased with the wavelength and the large contributions were mostly found at shorter wavelengths. Then the mass absorption efficiency (MAE) of major light-absorbing components were estimated, which can provide a support to estimate the impact of BrC from these sources on the climate. The positive matrix factorization model were also used to verify the contributions of different source components of BrC absorption at 365 nm. The results consistently demonstrate that the biomass burning and secondary formation contributes significantly to the overall absorption, followed by coal combustion and traffic emission.

How to cite: Wang, T., Huang, R., Yang, L., Yuan, W., and Gong, Y.: Brown carbon aerosol in urban Beijing: Significant contributions from biomass burning and secondary formation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7241, https://doi.org/10.5194/egusphere-egu2020-7241, 2020.

To investigate the sources and formation mechanisms of carbonaceous aerosols, a major contributor to severe particulate air pollution, radiocarbon (14C) measurements were conducted on aerosols sampled from November 2015 to November 2016 in Xi'an, China. Based on the 14C content in elemental carbon (EC), organic carbon (OC) and water-insoluble OC (WIOC), contributions of major sources to carbonaceous aerosols are estimated over a whole seasonal cycle: primary and secondary fossil sources, primary biomass burning, and other non-fossil carbon formed mainly from secondary processes. Primary fossil sources of EC were further sub-divided into coal and liquid fossil fuel combustion by complementing 14C data with stable carbon isotopic signatures.

The dominant EC source was liquid fossil fuel combustion (i.e., vehicle emissions), accounting for 64 % (median; 45 %–74 %, interquartile range) of EC in autumn, 60 % (41 %–72 %) in summer, 53 % (33 %–69 %) in spring and 46 % (29 %–59 %) in winter. An increased contribution from biomass burning to EC was observed in winter (∼28 %) compared to other seasons (warm period; ∼15 %). In winter, coal combustion (∼25 %) and biomass burning equally contributed to EC, whereas in the warm period, coal combustion accounted for a larger fraction of EC than biomass burning. The relative contribution of fossil sources to OC was consistently lower than that to EC, with an annual average of 47±4 %. Non-fossil OC of secondary origin was an important contributor to total OC (35±4 %) and accounted for more than half of non-fossil OC (67±6 %) throughout the year. Secondary fossil OC (SOCfossil) concentrations were higher than primary fossil OC (POCfossil) concentrations in winter but lower than POCfossil in the warm period.

Fossil WIOC and water-soluble OC (WSOC) have been widely used as proxies for POCfossil and SOCfossil, respectively. This assumption was evaluated by (1) comparing their mass concentrations with POCfossil and SOCfossil and (2) comparing ratios of fossil WIOC to fossil EC to typical primary OC-to-EC ratios from fossil sources including both coal combustion and vehicle emissions. The results suggest that fossil WIOC and fossil WSOC are probably a better approximation for primary and secondary fossil OC, respectively, than POCfossil and SOCfossil estimated using the EC tracer method.

How to cite: Ni, H., Huang, R.-J., and Dusek, U.: Sources and formation of carbonaceous aerosols in Xi'an, China: primary emissions and secondary formation constrained by radiocarbon, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12245, https://doi.org/10.5194/egusphere-egu2020-12245, 2020.

EGU2020-19547 | Displays | AS3.22

Spatial Patterns and Spatial Modeling of Primary Organic Aerosol Concentrations in Three North American Cities

Provat Saha, Ellis Robinson, Wenwen Zhang, Steven Hankey, Allen Robinson, and Albert Presto

We measure highly spatially resolved primary organic aerosol (POA) concentrations in three North American cities (Oakland, Pittsburgh, and Baltimore) using an aerosol mass spectrometer deployed on a mobile laboratory. We conduct between 10 and 20 days of repeated mobile sampling in each city, covering a wide range of urban land use attributes. We derive two POA factors using positive matrix factorization of the measured organic mass spectra: cooking OA (COA) and traffic-related OA (hydrocarbon-like OA; HOA). Both the COA and HOA concentrations vary substantially within and between cities. The COA and HOA concentrations in Oakland are about a factor of 2-4 higher than Pittsburgh and Baltimore. Within a city, the concentrations vary by a factor of 2-5. The COA concentrations are higher than the HOA in each city, indicating that cooking is an important POA source in the US. In each city, the concentrations are higher in the downtown and near large sources, showing the linkage between land-use activities and POA concentrations. We develop land-use regression (LUR) models for COA and HOA using the measured concentrations and available land-use covariates. We find that a similar set of land-use covariates explain the variability of measured POA in each city. The LUR models are moderately transferable between sampling cities. An external validation effort using literature data shows that our models predict the previous point measurements in six North American cities reasonably well. We are applying our LUR models for a national prediction of the concentration surfaces of COA and HOA. We plan to apply the national estimates for the epidemiologic and environmental justice analysis of POA in the United States.

How to cite: Saha, P., Robinson, E., Zhang, W., Hankey, S., Robinson, A., and Presto, A.: Spatial Patterns and Spatial Modeling of Primary Organic Aerosol Concentrations in Three North American Cities, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19547, https://doi.org/10.5194/egusphere-egu2020-19547, 2020.

EGU2020-7440 | Displays | AS3.22

Summertime and wintertime atmospheric processes of secondary aerosol in Beijing

Jing Duan, Rujin Huang, Chunshui Lin, Haiyan Ni, and Meng Wang

Secondary aerosol constitutes a large fraction of fine particles in urban air of China. However, its formation mechanisms and atmospheric processes remain largely uncertain despite considerable studies in recent years. To elucidate the seasonal variations of fine particles composition and secondary aerosol formation, an Aerodyne quadrupole aerosol chemical speciation monitor (Q-ACSM) combined with other online instruments were used to characterize the submicron particulate matter (diameter < 1 μm, PM1) in Beijing during summer and winter 2015. Our results suggest that the photochemical oxidation was the major pathway for sulfate formation during summer, whereas aqueous-phase reaction became an important process for sulfate formation during winter. High concentration of nitrate (17% of the PM1 mass) was found during winter explained by enhanced gas-to-particle partitioning at low temperature, while high nitrate concentration (19%) was also observed under the conditions of high relative humidity (RH) during summer likely due to the hydrophilic property of NH4NO3 and hydrolysis of N2O5. As for SOA formation, photochemical oxidation perhaps played an important role for summertime oxygenated OA (OOA) formation and wintertime less oxidized OOA (LO-OOA) formation. The wintertime more oxidized OOA (MO-OOA) showed a good correlation with aerosol liquid water content (ALWC), indicating more important contribution of aqueous-phase processing than photochemical production to MO-OOA. Meanwhile, the dependence of LO-OOA and the mass ratio of LO-OOA to MO-OOA on atmospheric oxidative tracer (i.e., Ox) both degraded when RH were greater than 60%, suggesting that RH or aerosol liquid water may also affect the LO-OOA formation.

How to cite: Duan, J., Huang, R., Lin, C., Ni, H., and Wang, M.: Summertime and wintertime atmospheric processes of secondary aerosol in Beijing, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7440, https://doi.org/10.5194/egusphere-egu2020-7440, 2020.

EGU2020-18919 | Displays | AS3.22

Methane Emission Source Attribution and Quantification for Munich Oktoberfest

Jia Chen, Florian Dietrich, Sebastian Lober, Konstantin Krämer, Graham Legget, Hugo Denier van der Gon, Ilona Velzeboer, Carina van der Veen, and Thomas Röckmann

Up to now, festivals have not been considered a significant methane (CH4) emission source and events with a limited duration were not included in the emission inventories. We have intensively investigated the Munich Oktoberfest, the world’s largest folk festival, for two consecutive years. Oktoberfest is a potential source for CH4 as a high amount of natural gas (about 200,000 m³) for cooking and heating is used.

The results from our 2018 investigation show that CH4 emissions at Oktoberfest not only come from human biogenic emissions. It is more likely that fossil-fuel related emissions are the major contributors to the Oktoberfest emissions (Chen et al. 2019). In 2019, our goal was to look closer into the source attribution. We used both a portable gas measurement system (LI-COR LI‑7810 Trace Gas Analyzer) in a backpack to measure the CH4 concentrations, and air sampling bags to examine the ethane/methane ratio and isotopic composition of the exhaust gas (δ13C, δD).

We walked around the perimeter of Oktoberfest to measure the CH4 concentration upwind and downwind of the Oktoberfest premises for several hours each day during the two-week festival. In addition, we entered the festival with our instrument to investigate the emission hotspots, i.e. tents and booths, thoroughly. The measurements were carried out both during and after the time of the festival to compare the differences in emission strength and distribution.

The backpack measurements around the Oktoberfest perimeter show enhancements up to several hundred ppb compared to background values and measurements performed after the festival. The concentration enhancements on the premises were even higher: up to 3,000 ppb for hotspot regions. The ethane/methane ratios and isotopic measurements show clear indications that the emission sources are thermogenic.

Furthermore, a CFD (Computational Fluid Dynamics) simulation was developed to simulate the gas dispersion within and around the terrain. The simulation uses Reynolds-Averaged Navier-Stokes equations and the k-ε turbulence model for the fluid flow. Wind speed and direction measurements taken close to the festival area were used as the boundary conditions. The dispersion of methane is solved afterwards using the unsteady convection-diffusion equation.

We will present the strengths and spatial/temporal distributions of the Oktoberfest emissions, assessed using the backpack measurements combined with a CFD model. Further, a comparison between the results of two consecutive years will be given. 

 

Chen, J., Dietrich, F., Maazallahi, H., Forstmaier, A., Winkler, D., Hofmann, M. E. G., Denier van der Gon, H., and Röckmann, T.: Methane Emissions from the Munich Oktoberfest, Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-709, in review, 2019

How to cite: Chen, J., Dietrich, F., Lober, S., Krämer, K., Legget, G., Denier van der Gon, H., Velzeboer, I., van der Veen, C., and Röckmann, T.: Methane Emission Source Attribution and Quantification for Munich Oktoberfest, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18919, https://doi.org/10.5194/egusphere-egu2020-18919, 2020.

EGU2020-20377 | Displays | AS3.22

Monitoring ffCO2 emission hotspots using atmospheric 14CO2 measurements

Samuel Hammer, Christoph Rieß, Fabian Maier, Tobias Kneuer, Julian Della Coletta, Susanne Preunkert, Ute Karstens, and Ingeborg Levin

Reliable estimates of fossil fuel CO2 (ffCO2) emissions from high-emission regions or urban areas are currently in demand from a wide range of players. On the one hand, cities and municipalities themselves are interested in an independent validation of their ffCO2 emissions. On the other hand, there is an increased interest in atmospheric science to merge independent emission estimate methods over different scales [Pinty et al. 2019]. 14CO2 has become the gold standard when it comes to the experimental splitting of atmospheric CO2 concentration into its biogenic and fossil components [e.g. Levin et al. 2003; 2011 or Turnbull et al. 2009].

Here we report on the identification of ffCO2 emitted from the Mannheim/Ludwigshafen metropolitan region in the upper Rhine valley, Germany. Quantification of the regional ffCO2 component requires knowledge of the composition of the background air. Thus, the emission area has been sampled by an upwind and a downwind station. We will discuss the advantages and disadvantages of using local background measurements conducted at a dedicated upwind station of the emission area and compare this realisation of background estimate to regional background estimates derived from measurements at classical remote background sites. All CO2 and 14CO2 observations have been performed as part of the European RINGO project. Furthermore, we investigate the suitability of using the total-CO2 difference between the two stations as a proxy for fossil fuel CO2 and the seasonal applicability of such a surrogate tracer. Finally, the observations of the total-CO2 surrogate tracer will be compared with the predictions from STILT forward model runs.

 

Ref.:

Levin, I., B. Kromer, M. Schmidt and H. Sartorius, 2003. A novel approach for independent budgeting of fossil fuels CO2 over Europe by 14CO2 observations. Geophys. Res. Lett. 30(23), 2194, doi. 10.1029/2003GL018477.

Levin, I., S. Hammer, E. Eichelmann, F. Vogel, 2011. Verification of greenhouse gas emission reductions: The prospect of atmospheric monitoring in polluted areas. Philosophical Transactions A 369, 1906-1924, doi:10.1098/rsta.2010.0249.

Pinty B., P. Ciais, D. Dee, H. Dolman, M. Dowell, R. Engelen, K. Holmlund, G. Janssens-Maenhout, Y. Meijer, P. Palmer, M. Scholze, H. Denier van der Gon, M. Heimann, O. Juvyns, A. Kentarchos and H. Zunker (2019) An Operational Anthropogenic CO₂ Emissions Monitoring & Verification Support Capacity – Needs and high level requirements for in situ measurements, doi: 10.2760/182790, European Commission Joint Research Centre, EUR 29817 EN

Turnbull, J., Rayner, P., Miller, J., Naegler, T., Ciais, P., & Cozic, A. (2009). On the use of 14CO2 as a tracer for fossil fuel CO2: Quantifying uncertainties using an atmospheric transport model. Journal of Geophysical Research: Atmospheres, 114(D22).

How to cite: Hammer, S., Rieß, C., Maier, F., Kneuer, T., Della Coletta, J., Preunkert, S., Karstens, U., and Levin, I.: Monitoring ffCO2 emission hotspots using atmospheric 14CO2 measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20377, https://doi.org/10.5194/egusphere-egu2020-20377, 2020.

EGU2020-9944 | Displays | AS3.22

Single Instrument Solution for Air Quality and Greenhouse Gas Monitoring in Cities

Morten Hundt, Oleg Aseev, and Herbert Looser

Observation of air pollutants and greenhouse gases with high selectivity and sensitivity is of great importance for our understanding of their sources and sinks. For air pollution modelling and validation of emission inventories measurements at various spatial and temporal scales are required. Infrared laser absorption spectroscopy is often the method of choice, offering outstanding performance and reliability. Most frequently, however, this technology is used in a “one-species-one-instrument” solution because of the narrow spectral coverage of DFB-lasers. This can be overcome by combining several Quantum Cascade Lasers (QCLs), providing unique solutions in compact laser absorption spectrometers for environmental monitoring of multiple species in a single instrument.

We combined multiple DFB-QCLs into a single, compact laser absorption spectrometer to measure up to ten different compounds. We present simultaneous atmospheric measurements of the greenhouse gases CO2, N2O, H2O and CH4, and the pollutants CO, NO, NO2, O3, SO2 and NH3 with a single instrument. Furthermore, the instrument performance, first field results and comparison to standard air-quality and greenhouse gas monitoring instrumentation are discussed. The results demonstrate that spectrometers using QCLs can serve as an all-in-one solution for environmental monitoring stations replacing up to seven instruments at once. Furthermore, due to their reduced size and robustness, they can be used on mobile platforms, opening up new applications of air quality and greenhouse gas monitoring in cities.

How to cite: Hundt, M., Aseev, O., and Looser, H.: Single Instrument Solution for Air Quality and Greenhouse Gas Monitoring in Cities, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9944, https://doi.org/10.5194/egusphere-egu2020-9944, 2020.

The air quality of indoor environments has increased in significance over the last few decades, particularly as contemporary estimates suggest that, on average, people spend 90% of their time indoors. This creates a growing requirement to understand the chemical composition of indoor atmospheres, and what factors influence absolute concentrations.  

 

Whole-air canister sampling techniques were used to collect three-day integrated air samples in a cohort of UK homes (n = 60). Each household was sampled three times in winter and three times in summer, plus a further three households were randomly selected each week to also collect an outdoor air sample. Sampling was performed over nine-week periods - between February and April 2019 and July and September 2019. Samples were subject to chemical analysis using a combination of GC-FID and GC-TOF-MS, allowing quantification of VOCs over the range C2 – C12, including nonmethane hydrocarbons, OVOCs, monoterpenes, siloxanes and halocarbons. A digitised survey (completed on iPad) was completed by each household, containing questions regarding property information, residence occupancy and demographics, and a daily log of solvent-containing product usage (including cosmetics and personal care, cleaning, decorative and hobby, smoking, fires, candles, and insecticides). Product usage was determined by how often residents recorded a given product category during the three-day sampling period.

 

Highest concentrations were seen in winter, with n-butane being the most abundant VOC (median value = 61.6 ppb), whilst tetrachloroethylene was the lowest concentration species quantified (median = <0.1 ppb) in this study. In terms of absolute concentration, VOCs derived from aerosol propellants were most significant, plus ethanol and acetone: general purpose solvents from many different product types. Median concentrations for terpenoids ranged from 0.17 ppb p-cymene to 0.65 ppb limonene.  A positive correlation existed internally between different terpenoid species and between alkene species. However, more generally, most individual VOCs did not correlate with each other, highlighting the wide range of uncorrelated sources that contribute to individual concentrations.

 

With the exception of aerosol usage, and n and i butane, indoor ambient VOC concentrations had no statistically significant relationship with product usage frequency, indicating that other factors, such as ventilation rates, VOCs released per dose, variability in product emissions, and other behavioural aspects were potentially more significant influencing factors. This highlights the great challenges in attempting to model indoor exposure to VOCs at a population scale, since it is not readily predictable based on behavioural use of solvents.

How to cite: Heeley-Hill, A.: Relating concentrations of indoor volatile organic compounds to occupant use of solvent-containing products, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22486, https://doi.org/10.5194/egusphere-egu2020-22486, 2020.

EGU2020-17119 | Displays | AS3.22

Seasonal Variation of Aerosol Oxidative Potential in Beijing, China during the APHH Campaign

Steven J. Campbell, Battist Utinger, Kate Wolfer, Joe Westwood, Sarah S. Steimer, Tuan V. Vu, Zongbo Shi, Nicholas Straw, Mark R. Miller, Steven Thomson, William J. Bloss, Roy M. Harrison, and Markus Kalberer

The negative effects of air pollution on human health has been subject to a number of epidemiological studies that consistently link respiratory and cardiovascular diseases to exposure to particulate matter (PM) (Englert, 2004). It is estimated that up to 0.3 million premature deaths per year in Europe and 2.1 million deaths worldwide are the result of exposure to particles with an aerodynamic diameter less than 2.5 μm (PM2.5) (Andersson, 2009). However, identifying the specific particle properties responsible for these health effects, such as their physical and physicochemical characteristics, as well as their chemical composition, remains a challenge.

One of the leading hypotheses for how particles cause harm is by inducing oxidative stress and inflammation, which can subsequently lead to disease (Øvrevik, 2015). In particular, reactive oxygen species (ROS), which typically refer to a range of species including hydrogen peroxide (H2O2) possibly including organic peroxides, the hydroxyl radical (.OH) and superoxide radical (O2.-), may substantially contribute to the oxidative potential (OP) of PM and hence influence their toxicity. An excess of ROS in the lung, introduced or generated via particle exposure, leads to an imbalance of the oxidant-antioxidant ratio in favour of the former, which can subsequently promote oxidative stress. There are a number of acellular methods used routinely to measure aerosol OP, including the dithiothreitol assay (DTT), ascorbic acid assay (AA), 2,7-dichlorofluoroscein/hydrogen peroxidase assay (DCFH/HRP), and electron paramagnetic resonance (EPR) spectroscopy.

In this work, the OP of aerosol collected in Beijing, China, in the winter 2016 and summer 2017 during the Atmospheric Pollution and Human Health in a Chinese Megacity (APHH) campaign is quantified, with 30 24-hr aerosol filter samples analysed for each season. We use the four aforementioned methods to measure OPAA, OPDTT, OPDCFH and OPEPR, and to extensively characterise the seasonal variation of aerosol OP in a megacity. All OP measurements show a significantly stronger correlation with PM2.5 mass in the winter compared to summer. Furthermore, the OPAA, OPDTT, OPDCFH and OPEPR were correlated using univariate and multivariate analysis with a variety of other measurements such as meteorological data, trace gas measurements and aerosol composition measurements including organic aerosol components and x-ray fluorescence elemental analysis.  

These results emphasise that the four OP methods applied in this study capture different aspects of aerosol OP between the seasons. As an example, OPAA normalised to account for aerosol mass show that aerosol OPAA in the winter is higher on average and more variable compared to the summer, whereas OPDCFH is more consistent between the winter and summer seasons. OPAA also showed a strong correlation with PM2.5 mass in the winter (r2 = 0.91) but correlated poorly in the summer months (r2 = 0.09), suggesting different aerosol components affect OPAA in summer and winter.

Englert, N. Toxicol. Lett. 149, 235–242 (2004).

Andersson, C., et al., Atmos. Environ. 43, 3614–3620 (2009).

Øvrevik, J., et al., Biomolecules 5, 1399–1440 (2015).

How to cite: Campbell, S. J., Utinger, B., Wolfer, K., Westwood, J., Steimer, S. S., Vu, T. V., Shi, Z., Straw, N., Miller, M. R., Thomson, S., Bloss, W. J., Harrison, R. M., and Kalberer, M.: Seasonal Variation of Aerosol Oxidative Potential in Beijing, China during the APHH Campaign , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17119, https://doi.org/10.5194/egusphere-egu2020-17119, 2020.

EGU2020-19756 | Displays | AS3.22

Effect of metal speciation on the oxidative potential and cytotoxicity of airborne particles

Sara DAronco, Chiara Giorio, Federica Chiara, Roberta Seraglia, Valerio Di Marco, and Andrea Tapparo

Aerosol particle components can mix and interact with oxidants and organic compounds present in the atmosphere. How these chemical components interact and how the interactions affect the Earth’s climate, particle toxicity and human health is largely unknown. In the case of trace metals, the main focus so far has been the determination of the total amount while much less attention has been directed towards the metal speciation. Aqueous phase processing of aerosol can lead to substantial modifications of aerosol chemical and physical properties [1] by promoting the formation of metal-organic ligand complexes in atmospheric aqueous phases, like fog/cloud droplets and deliquescent aerosol. Such process can increase the solubility of metals, therefore their bioavailability [2], and affect their capability to generate reactive oxygen species.

We investigated the formation of metal-organic ligand complexes, especially those involving small dicarboxylic acids, in urban aerosol collected in the city centre of Padua (Italy), in the Po Valley. We assessed the effects of metal-ligand complexes formation on the solubility and solubilisation kinetic of metals from the particles to aqueous solutions simulating fog/cloud water. We found that solubilisation kinetics of many metals depended on the chemical form in which they were present in the aerosol and they were influenced by the environmental conditions during the campaign. Changes in oxidative potential (OP) and cytotoxicity of particles due to the formation of metal-ligand complexes were investigated by performing acellular and cellular in vitro tests, respectively. Preliminary results showed that metals and their complexed forms are both characterized by different OP and cellular toxicity.

 

References

[1] Decesari, S., Sowlat, M. H., Hasheminassab, S., Sandrini, S., Gilardoni, S., Facchini, M. C., Fuzzi, S., and Sioutas, C. Atmos. Chem. Phys., 17, 7721‑7731 (2017).

[2] Okochi, H., and Brimblecombe, P. Sci. World J., 2, 767–786(2002).

How to cite: DAronco, S., Giorio, C., Chiara, F., Seraglia, R., Di Marco, V., and Tapparo, A.: Effect of metal speciation on the oxidative potential and cytotoxicity of airborne particles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19756, https://doi.org/10.5194/egusphere-egu2020-19756, 2020.

EGU2020-21812 | Displays | AS3.22

How atmospheric simulation chambers can help to investigate the impact of air quality on health

Patrice Coll, Mathieu Cazaunau, Jean-Francois Doussin, Edouard Pangui, Aline Gratien, Isabelle Coll, Gilles Foret, Cécile Gaimoz, Vincent Michoud, Claudia DiBiagio, Elie Al Marj, Marion Blayac, Zhuyi Lu, Audrey Der Vatanian, Stéphane Jamain, Geneviève Derumeaux, Maria Pini, Frédéric Relaix, Jorge Boczkowski, and Sophie Lanone

Summary

Using CESAM, an atmospheric simulation chamber (cesam.cnrs.fr), we have developed a totally innovative platform for exposing mice to realistic atmospheric conditions. Here we present the first toxicological analyses of the organs of these mice after 48 hours to several days of exposure, carried out as part of feasibility experiments aimed at testing this experimental concept. This platform has received funding from the European Union’s Horizon 2020 research and innovation programme through the EUROCHAMP-2020 Infrastructure Activity under grant agreement N° 730997, and is now supporting the new REMEDIA H-2020 project (call H2020 “Exposome”)

 

Introduction

The World Health Organization (WHO) estimated that there were 3.7 million premature deaths due to air pollution in 2014, and confirmed that air pollution is the greatest environmental risk to health (responsible for a loss of more than 3% of productivity).

The studies conducted so far show that the effects of air pollution on health depend not only on the quality of the surrounding air, but also on the subjects exposed and their individual vulnerability (asthma, obesity, period of life, etc.). Despite the evidence on the adverse health effects of exposure to air micro-pollutants, there are still uncertainties about the nature of these effects, and progress need to be made on their quantification. This limitation of knowledge is mainly attributed to the complexity of the polluted atmospheres, and to the great difficulty to model the impact of realistic situations of exposure.

 

Methodology

The innovative approach we set up is to realistically simulate, at the laboratory, the atmospheric mixture in all its complexity, thus keeping the ability to control, reproduce and carefully characterize the experimental conditions. We used the CESAM chamber (4.2 m3 stainless steel atmospheric simulation, evacuable down to a few 10-7 atm, temperature controlled between +15°C and +60°C) in order to study the myriad of products arising from the atmospheric oxidation of primary organic compounds.

The experimental protocol consists in the continuous injection of relevant mixtures of primary pollutants (mainly nitrogen oxides, organic compounds from a representative mix of anthropogenic emissions, sulphur dioxide, soot, inorganic salts and potentially mineral dust particles if needed - e.g. to simulate Beijing’s atmosphere) at low concentrations (ppb levels) in air in the CESAM simulation chamber operated as a slow flow reactor. The residence time of simulated air parcels in the experimental volume is fixed to 4 hours, in order to represent air masses of regional scale. During this time the synthetic mixture is exposed to an artificial solar irradiation, allowing secondary pollutants such as ozone, nitric acid, formaldehyde, peroxyacetyl nitrate as well as complex polyfunctional organics including SOA to be produced and to reach their chemical steady state. Mice are exposed to constant flows of such a mixture during time scales of week to address their effects on health.

 

Conclusions

Here we present the first toxicological analyses related to organs/tissue of these mice after exposure of 48h to several day, carried out with a representative atmosphere of Beijing or a representative atmosphere of Paris.

 

References

Coll P. et al., 2018, WIT Transactions on Ecology and the Environment, 230.

How to cite: Coll, P., Cazaunau, M., Doussin, J.-F., Pangui, E., Gratien, A., Coll, I., Foret, G., Gaimoz, C., Michoud, V., DiBiagio, C., Al Marj, E., Blayac, M., Lu, Z., Der Vatanian, A., Jamain, S., Derumeaux, G., Pini, M., Relaix, F., Boczkowski, J., and Lanone, S.: How atmospheric simulation chambers can help to investigate the impact of air quality on health, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21812, https://doi.org/10.5194/egusphere-egu2020-21812, 2020.

EGU2020-16202 | Displays | AS3.22

Assessment of the human health risk due to the exposure to air pollution using air quality ensemble modelling data

Lorenza Gilardi, Thilo Erbertseder, Frank Baier, and Michael Bittner

Several World Health Organization (WHO) studies have shown that air pollution is likely associated with an increased rate of premature mortality and morbidity, mainly attributable to respiratory and cardiovascular diseases [1]. The species normally considered for the evaluation are: PM10, PM2.5, O3 and NO2. All these compounds are typical sub products of processes of combustion and other anthropogenic activities and their presence in highly densely populated areas is commonly observed. As a result, a significant proportion of the European population is exposed to annual average concentrations of these pollutants exceeding the WHO Air Quality Guidelines (WHO-AQG), as the European Environment Agency (EEA)  reports for the year 2016 [1].  Data of air pollutants concentrations at high temporal resolution and on a large spatial scale are currently available from satellite remote sensing and air quality models. The data from the multi-year reanalysis of the Copernicus Atmospheric Monitoring Service (CAMS) and from the DLR / POLYPHEMUS, together with the health Relative Risk (RR) values provided by the WHO, are used as input-source for the method developed by Sicard [2] to estimate an overall increase in health risk due to short-term exposure to air pollution. With this operation it is possible to obtain a geographical representation of the Aggregate Risk Index (ARI). This approach allows for various estimates of the spatial distribution of the increased health risk for several health endpoints, in terms of ARI, and its temporal behavior. The Sicard’s method is tested by (spatial) correlation to a real-world health data base. We especially investigate the validity of the linear additive approach for different mixtures of pollutants.

References:

[1] European Environmental Agency, 2019, Air quality in Europe 2019 report, pages 61-70.

[2] Sicard, P.,et al., 2012. The Aggregate Risk Index: An intuitive tool providing the health risks of air pollution to health care community. Atm Env, 46, 11-16.

How to cite: Gilardi, L., Erbertseder, T., Baier, F., and Bittner, M.: Assessment of the human health risk due to the exposure to air pollution using air quality ensemble modelling data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16202, https://doi.org/10.5194/egusphere-egu2020-16202, 2020.

EGU2020-2576 | Displays | AS3.22

A novel approach for dynamic population activity in urban-scale exposure estimates

Martin Otto Paul Ramacher, Matthias Karl, Eleni Athanasopolou, Anastasia Kakouri, Orestis Speyer, and Volker Matthias

Population exposure estimates are used in epidemiological studies to evaluate health risks associated with impacts of air pollution on human health. Traditional approaches in exposure modelling assume that air pollutants' concentrations at the residential address of the study population are representative of overall exposure. This approach is acknowledged to introducing bias in the quantification of human health effects, as individual and population-level mobility is non-existent. To sufficiently model population numbers for exposure estimates, the dynamic population activity (DPA) must be known. Information on DPA is mostly derived from national or municipal surveys and is scarce.

We developed a generic approach to model DPA integrating the Copernicus Urban Atlas land use and land cover product with literature based and microenvironment-specific diurnal activity data (Ramacher et al. 2019) and moreover taking into account gridded monthly day- and night-time populations as derived in the ENACT project (https://ghsl.jrc.ec.europa.eu/enact.php), while also considering indoor and outdoor environments. This approach produces maps with distribution of citizens in various microenvironments (MEs) and hours of the day. These maps can consequently be used to calculate population-level outdoor exposure when paired with consistent spatio-temporal air pollution concentration fields. In this study, we applied the generic DPA approach to the cities of Hamburg (DE) and Athens (GR). Hourly, urban-scale pollutant concentrations were produced by the Chemistry Transport Model (CTM) EPISODE-CityChem (Karl et al. 2019) driven by detailed local emission inventories, 4D meteorological fields and regional pollutant boundary conditions for 2015. Both the concentrations for NOx, O3 and PM2.5 as well as the DPA maps for Hamburg and Athens were simulated on a 100 m horizontal resolution grid, and were then combined to calculate population exposure. We additionally used gridded population densities (based on residential addresses) to calculate population exposure, i.e. following a static population approach. We compared the exposures from the two approaches to capture the effect of a population moving in space and time. 

The presented approach to account for dynamic instead of static population activity in urban population exposure calculations is beneficial for cities in European regions where relevant population data are missing. It is found that by taking into account movement of population through different urban environments as well as commuting per se, the overall exposure estimates are elevated when compared to a static approach. Furthermore, we have shown that by considering infiltration of outdoor concentrations to indoor environments there are substantial decreases in population exposure estimates. This approach and the implications on exposure estimates is believed to be of interest to air pollution health studies.

How to cite: Ramacher, M. O. P., Karl, M., Athanasopolou, E., Kakouri, A., Speyer, O., and Matthias, V.: A novel approach for dynamic population activity in urban-scale exposure estimates, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2576, https://doi.org/10.5194/egusphere-egu2020-2576, 2020.

Air pollution has been gaining increasing global attention. The public is concerned about urban pollution levels including both in- and outdoor air quality. A handheld Air Quality Inspection Box (Airquix) was developed in order to monitor air pollutants in real-time, and determine individual exposure to different pollutants in different environments. The Airquix is equipped with air quality sensors: electrical chemical NO2, O3, NO sensors, NDIR CO2 sensor, OPC-N3 PM sensor; environment sensor (T, RH, P), GPS sensor and a raspberry pi for data logging, processing and display. To achieve a relatively high accuracy, e.g. +/- 5ppb at 5 seconds time resolution for the NO2 concentration, the pre- and post- calibration for the Airquix were performed by comparison with high-end air monitoring instruments. In this study, several Airquixes were distributed to different persons to assess individual exposure. The daily activities were distinguished by different commutes, in- and outdoor behaviors, the personal habits and potential episodes. The resulting data set can be used for the assessment of health impacts.

How to cite: Ye, S. and Wenig, M.: Human exposure assessment to air pollutants: application of a new portable air monitoring instrument, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9075, https://doi.org/10.5194/egusphere-egu2020-9075, 2020.

EGU2020-20087 | Displays | AS3.22

Volatile Organic Compounds in the atmosphere of the Great Athens area: The case of a port site close to Piraeus, Greece

Eleni Liakakou, Anastasia Panopoulou, Georgios Grivas, Stéphane Sauvage, Theodora Kritikou, Evangelos Gerasopoulos, and Nikolaos Mihalopoulos

VOCs are key atmospheric constituents for both health and climate issues and further knowledge is still needed about their sources and fate. The presence of volatile organic compounds in ambient air is strongly dependent on the site characteristics and a harbor area undergoes many source typologies such as road transport, ship emissions and contaminants of commercial activities, the shipbuilding zone and other operating facilities. The current work was implemented at the recently established Atmospheric Pollution Monitoring Station of the Municipality of Keratsini-Drapetsona located in the close vicinity of the Piraeus port. Since December 2018 an automatic gas chromatograph with flame ionization detector (FID) continuously monitors at a 30 minutes time resolution non methane hydrocarbons (NMHCs) focusing on hazardous compounds (aromatics) and strong precursors (aromatics, monoterpenes) of secondary pollutants like ozone and secondary organic aerosols. High levels of benzene were observed, especially during the morning to noon period, and the mean concentration of both benzene and toluene were two-folded in summer (July and August 2019) compared to winter (January and February 2019). Ethylbenzene follows the same pattern, whereas xylenes presented comparable levels during the cold and warm periods. Preliminary results based on source apportionment techniques are presented. In general terms the NMHC levels present their maximum under the impact of low wind speed, addressing thus the role of local emission sources, which are further investigated by the ratios used as tracking tools of processes of different origin (e.g. the traffic related ratio of toluene/benzene).

How to cite: Liakakou, E., Panopoulou, A., Grivas, G., Sauvage, S., Kritikou, T., Gerasopoulos, E., and Mihalopoulos, N.: Volatile Organic Compounds in the atmosphere of the Great Athens area: The case of a port site close to Piraeus, Greece, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20087, https://doi.org/10.5194/egusphere-egu2020-20087, 2020.

EGU2020-15266 | Displays | AS3.22

Study of the variability of physicochemical characteristics of surface aerosol in Moscow under atypical weather conditions in 2019

Dina Gubanova, Andrey Skorokhod, Nikolai Elansky, Vyacheslav Minashkin, and Mikhail Iordanskii

In recent years, interest in studying the physicochemical parameters of atmospheric aerosols, which is associated with their active influence on the air pollution, optical characteristics of the atmosphere and the Earth’s climate has increased. Climatic changes cause the occurrence of atypical weather conditions and dangerous meteorological phenomena that affect changes in the properties of aerosol particles. In large industrial megacities frequent atypical meteorological situations change aerosols behavior and complicate the predictive model assessment of the air quality and thermal regime of the atmosphere.

We consider the results of studies of the daily and seasonal variability of the chemical composition, microphysical parameters, and mass concentration of surface aerosols in Moscow under atypical weather conditions prevailing in summer (June 10-July 10) and in autumn (October 10-November 7) of 2019. In the second half of June 2019, strong cyclonic activity was observed, and air masses of Arctic origin dominated, bringing intense rainfall, cleansing the atmosphere of contaminants and significant decrease in air temperature. October was characterized by air temperature above the climatic norm, insignificant precipitation and frequent strong gusts of wind of western direction.

Under such conditions, abnormally low aerosol PM2.5 and PM10 concentrations were found, and in the summer average monthly concentrations were 1.5 times lower than in the autumn period what is untypical for aerosols. Usually aerosols annual course is characterized by broad maximum in summer, and by minimum in October-November. In addition, comparison with the results of observations of previous years showed that in 2019 aerosol concentration was 3-5 times lower during both summer and autumn. In particular, the average monthly calculated concentration of  submicron fraction in the study period was: 273 particles/cm3 in the summer and 405 particles/cm3 in the autumn; mass concentration of PM2.5 particles: 3.9 and 5.4 μg/m3, respectively. For comparison, multiyear average mass concentrations of PM2.5 are 15-30 μg/m3. The day-to-day variability and weekly cyclicity of atmospheric aerosols also underwent changes as a result of synoptic and meteorological factors. Under these conditions, the contribution of urban anthropogenic sources, including traffic leveled, in particular, due to such intensive processes as leaching and weathering of aerosols from the atmosphere.

Simultaneously with the measurement of microphysical parameters, the elemental composition of aerosol samples was determined by inductively coupled plasma mass spectrometry. It showed that atmospheric aerosol particles are characterized by a high content of sulfur, heavy metals (Cd, Cu, Zn, Mo, W, Ti, Au, Hg, Pb, Ag, Mn, Fe, Co, As), and metalloids (Bi, Sb, B, P, As, Sn), mainly of anthropogenic nature. Such harmful substances are accumulated in the fine fractions of particles that are part of the PM2.5 aerosol and most dangerous for human health.

Large amplitudes of variations in the disperse composition and concentration of aerosol particles in the atmospheric surface layer, recorded during seasonal observations under atypical weather conditions, characterize strong inhomogeneities of aerosol parameters in space and time, which can significantly affect the chemical and optical properties of aerosols, as well as lower atmosphere state in general.

The reported study was funded by RFBR, projects ## 05-19-00352 and 05-19-50088.

How to cite: Gubanova, D., Skorokhod, A., Elansky, N., Minashkin, V., and Iordanskii, M.: Study of the variability of physicochemical characteristics of surface aerosol in Moscow under atypical weather conditions in 2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15266, https://doi.org/10.5194/egusphere-egu2020-15266, 2020.

EGU2020-402 | Displays | AS3.22

The air quality in the Municipality of Piatra Neamt from the North Eastern Region, Romania

Constantin Rosu, Dumitru Mihaila, and Petrut-ionel Bistricean

The analysis of the air quality represents an essential component of the tourist resources evaluation in a city declared a tourist resort of national interest, as Piatra Neamt is, also called the Pearl of Moldova. The chemical particularities of the urban atmosphere are being influenced, in different extents, by the size of the city, the anthropic activities and are modulated by the geographical peculiarity of the place. Piatra Neamt is located in the NE of Romania in an area of depressive widening of Bistrita valley, at 345 m altitude. The coniferous vegetation, the presence of the water reservoirs along Bistrita river, the climate of shelter and so on are elements that contribute to the self-purification of the air. The city had 85,055 inhabitants according to the 2011 census, being an important economic and tourist center of the NE region of Romania.

The aims of the study conducted has as goal the evaluation of the air quality in the Municipality of Piatra Neamt, on the basis of the hourly data from the station NT1 (urban background) from the interval January 2009 - October 2019, relying on five chemical indicators: Nitrogen dioxide (NO2), Sulfur dioxide (SO2), Carbon monoxide (CO), Ozone (O3) and PM10 sedimentable particles.

The main objectives aimed at the identification of the variations in time of the average hourly or daily concentrations of these pollutants, with the outlining of their daily or annual progress, with the explanation of their causality and with the identification of some episodes of pollution, but also at the releasing of some accurate assessments based on data, observations and findings of duration which to include the air inhaled by the inhabitants of the city and by the tourists in different intervals of quality.

The results obtained show that in Piatra Neamt the concentrations of NO2 (with 94.36% of the hours of observations with indices of air quality evaluated as excellent), SO2 (with 99.59% of the hours of observations with excellent indices of air quality) and CO (with 99.78% of the hours of observations with indices of air quality also excellent) do not cause real problems to human health. For the O3 in 0.8% of the hours of observation from NT1, the concentration of this gas has exceeded the threshold of 120 μg / mc which, according to the European directives, is the target value for the protection of human health. Neither the concentration of PM10 sedimentable particles causes problems (the amount of time with exceedings of the daily limit value for the protection of human health being on average 2.8 days a year-1). The October-March interval, with thermal inversions, with radiation fog and persistent stratiform clouds is more favorable for keeping this pollutant in suspension.

Conclusion.. The quality of the air from the city of Piatra Neamt atmosphere is excellent. The sedative-indifferent bioclimate and the sanogenous atmosphere of this city at the contact between the Eastern Carpathians - Subcarpathians of Moldova increase the tourist assets of the municipality.

How to cite: Rosu, C., Mihaila, D., and Bistricean, P.: The air quality in the Municipality of Piatra Neamt from the North Eastern Region, Romania, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-402, https://doi.org/10.5194/egusphere-egu2020-402, 2020.

EGU2020-1268 | Displays | AS3.22

Evaluation of air quality in Suceava, Romania

Dumitru Mihăilă, Petruț Ionel Bistricean, Alin Prisacariu, and Mihaela Țiculeanu – Ciurlică

In cities the chemical parameters of the urban atmosphere are being influenced, mainly negatively, by the daily human activities. The urban agglomeration of Suceava (from the NE of Romania) amounted to 116404 inhabitants as per the census from 2011. Their quality of life depends directly on the quality of the air inhaled, and this is being affected by the variable emissions of the transport and industrial sectors and by the household activities. The Municipality of Suceava is an important commercial center and, at the same time, a tourist city.

The general objective of the study consists in the evaluation of the air quality of Suceava Municipality, on the basis of the hourly data from the stations SV1 (urban background) and SV2 (industrial background) from the interval January 2009 - October 2019, on the basis of five chemical indicators: NO2, SO2, CO, O3 and PM10. The main objectives are: i) the identification of the fluctuations in time of the daily or hourly average concentrations of these emissions with the outlining of their daily or annual regime; ii) the comparison of the air quality in the neighbourhoods with residential function from the central and central-southern areas (Zamca, Marasesti, George Enescu, Areni, Obcini and so on) with the one from the industrial platform vicinity, and iii) the releasing of some accurate evaluations based on data from monitoring, which to classify in different levels of quality the air breathed in by humans.

Results. In Suceava the concentrations of NO2 (with hourly indices of quality evaluated as being excellent in 96,51% of cases at SV1 and 93,51% of cases at SV2), SO2 (with hourly indices of quality evaluated as being excellent in 99,79% of cases at SV1 and 99,03% of cases at SV2) and CO (with indices of excellent quality of the air in 99,78% of the hours of observations at SV1 and 97,32% at SV2) are not capable to raise real problems from the perspective of their impact on human health. In the case of O3, in 1,67% of the hours of observations from SV1 the concentration of this gas exceeded the target value for the protection of human health (120 μg/mc). The situation is not alarming due to the reduce percentage held by these situations and to the limitation of the areal to a single monitoring point. In the case of PM10 the concentration does not raise problems at SV1 station where the proportion of time with exceedings of the daily limit value for human health protection is on average 1,3 days/year-1, but at SV2 the daily limit values are being exceeded in 35 day/year1. The interval October - March, with thermal inversions, persistent fog and low stratiform clouds, is the critical one related to this pollutant.

Conclusions. On the background of the industrial decline that followed after 1989, the quality of the air from the atmosphere of Suceava has increased. The problem of the particles in the areal of the industrial platform and Burdujeni neighbourhood stays a current one. 

How to cite: Mihăilă, D., Bistricean, P. I., Prisacariu, A., and Țiculeanu – Ciurlică, M.: Evaluation of air quality in Suceava, Romania, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1268, https://doi.org/10.5194/egusphere-egu2020-1268, 2020.

EGU2020-1566 | Displays | AS3.22

A self-organizing maps methodology for developing a composite air quality and climatic parameters classification

Anastasios Alimissis, Chris G. Tzanis, Constantinos Cartalis, Kostas Philippopoulos, and Ioannis Koutsogiannis

Urban climate change affects important aspects of urban life (health, urban environment and infrastructure) through considerable fluctuations in the values of both climatic and air quality parameters. At the same time, in recent years, the networks of atmospheric pollution and climatic parameters monitoring stations have become denser, leading to more information which, if presented correctly, can guide policy makers to achieve sustainable solutions. Compοsite environmental classifications are a credible tool to describe in an easily comprehensible manner the complex interactions of gaseous and particulate pollutants with climatic parameters in different land use types and urban topography. The aim of this study is the development and implementation of a composite climate - air quality classification in order to describe and study their combined effects on living conditions and quality of life in urban environments. By employing pollutant observations from surface stations and climatic gridded data from reanalysis databases, the available data will be converted into groups of cases through a process which is based on a non-linear method of clustering and categorization. An artificial neural network methodology and in particular, self-organizing maps will be used to convert non-linear statistical associations of input data into simple geometric relationships of points in a low dimensional map. This method can create classifications of air pollutants and climatic parameters that group days which follow specific patterns, hidden due to non-linear interactions. The results can contribute to finding a relationship between ambient air quality and climatic variables and subsequently gaining important knowledge in this field.

How to cite: Alimissis, A., Tzanis, C. G., Cartalis, C., Philippopoulos, K., and Koutsogiannis, I.: A self-organizing maps methodology for developing a composite air quality and climatic parameters classification, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1566, https://doi.org/10.5194/egusphere-egu2020-1566, 2020.

EGU2020-2708 | Displays | AS3.22

Energy and air pollution benefits of household fuel policies in northern China

Wenjun Meng, Qirui Zhong, Yilin Chen, Huizhong Shen, and Shu Tao

In addition to many recent actions taken to reduce emissions from energy production, industry, and transportation, a new campaign substituting residential solid fuels with electricity or natural gas has been launched in Beijing, Tianjin, and other 26 municipalities in northern China, aiming at solving severe ambient air pollution in the region. Quantitative analysis shows that the campaign can accelerate residential energy transition significantly, and if the planned target can be achieved, more than 60% of households are projected to remove solid fuels by 2021, compared with less than 20% without the campaign. Emissions of major air pollutants will be reduced substantially. With 60% substitution realized, emission of primary PM2.5 and contribution to ambient PM2.5 concentration in 2021 are projected to be 30% and 41% of those without the campaign. With 60% substitution, average indoor PM2.5 concentrations in living rooms in winter are projected to be reduced from 209 (190-230) μg/m3 to 125 (99-150) μg/m3. The population-weighted PM2.5 concentrations can be reduced from 140 μg/m3 in 2014 to 78 μg/m3 or 61 μg/m3 in 2021 given that 60% or 100% substitution can be accomplished. Although the original focus of the campaign was to address ambient air quality, exposure reduction comes more from improved indoor air quality because approximately 90% of daily exposure of the population is attributable to indoor air pollution. Women benefit more than men.

How to cite: Meng, W., Zhong, Q., Chen, Y., Shen, H., and Tao, S.: Energy and air pollution benefits of household fuel policies in northern China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2708, https://doi.org/10.5194/egusphere-egu2020-2708, 2020.

The megacities of the world are experiencing a punishing level of air pollution where primary sources of emissions are industrial, residential and transportation. Delhi is also no exception and had been worst performing in terms of air quality and air pollution. In this backdrop, a high-resolution emission inventory becomes an essential tool to predict and forecast pollutant concentration along with the assessment of the impact of various government policies. This study aims to prepare a high-resolution gridded emission inventory (1km*1km) of criteria air pollutants (PM10, PM2.5, NO2, SO2 and CO) for Delhi-NCT (National Capital Territory).  The bottom-up gridded emission inventory has been prepared taking account of population density, land use pattern and socio-economic status. The emission from all the primary sectors has been taken into accounts such as transport, residential burning, industries, power plants, and municipal solid waste burning.  The emissions are estimated using emission factors and activity data for each sector. The emission factor for various fuel type burning is taken from CPCB (Central Pollution Control Board) reports and previous literature. Data corresponding to various sectors such as the amount of fuel consumed, population density, road density, traffic congestion points, industrial location, unauthorized colonies, slums, and total solid waste generation has been acquired from various government bodies, reports, and literature. The result reveals that the total estimated emissions from transportation, industries and domestic sector contribute nearly 72%, 60%, 52% of NOx, SO2 and PM10 emission respectively.  The transport sector has been found as the bulk contributor towards CO and NOx emissions. Domestic sector and Power plant emission have been found to be a bulk contributor of CO and SO2. Later, the spatial distribution of the emission is done using GIS technique (Arc-GIS). For spatial distribution of emission, district-wise population data, road density data, power plant location and digitization of the road network was carried out.

How to cite: Chaurasia, R. and Mohan, M.: Gridded Emission Inventory of Criteria Air Pollutants for National Capital Territory, Delhi, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22571, https://doi.org/10.5194/egusphere-egu2020-22571, 2020.

EGU2020-4026 | Displays | AS3.22

Timely information on birch and grass pollen levels in Belgium

Willem W. Verstraeten, Nicolas Bruffaerts, Rostislav Kouznetsov, Marijke Hendrickx, Mikhail Sofiev, and Andy W. Delcloo

Air pollution has tremendous effects on mortality and the quality of life. Air pollution is not restricted to anthropogenic contaminants only, since also natural sources (soils, lakes, marshes, vegetation, volcanoes, etc) may emit substantial amounts of unhealthy pollutants (VOCs, SOX, NOX, aerosols, etc). Releases of biogenic aerosols such as pollen affect the public health badly, putting additional distress on people already suffering from cardiovascular and respiratory diseases. In Belgium, ~10% of the people is estimated to suffer from allergies due to pollen released by the birch family trees and ~15% due to pollen emitted by grasses. In some European countries the prevalence is up to 40%.

To date, the only available airborne pollen level data in Belgium are retrieved by Sciensano at five stations that monitor off-line daily concentrations of grass and birch pollen among other species. Patients suffering from rhinitis have therefore no access to detailed real-time spatial information and warnings on forthcoming exposures.

Chemistry Transport Models (CTM) can both quantify as well as forecast the spatial and temporal distribution of airborne birch and grass pollen concentrations if accurate and updated maps of birch and grass pollen emission sources are available, and if the large inter-seasonal variability in emissions is considered.

Here we show the results of the modelled spatio-temporal distributions of grass and birch pollen over Brussels and other locations in Belgium using the CTM SILAM. This CTM is driven by ERA5 meteorological reanalysis data from ECMWF, an updated MACC-III birch tree fraction map, based on local information, and a grass pollen emission map showing the spatial distribution of the potential pollen sources. Pollen release is based on the temperature degree days approach. Inter-seasonal variability in birch pollen release was taken into account by using spaceborne MODIS vegetation activity (Gross Primary Productivity, GPP). For grass pollen this approach does not fit, therefore we use average temperature and precipitation of the previous year in a first approach.

SILAM modelled and observed time series of daily birch pollen levels of 50 birch pollen seasons at multiple sites in Belgium correlate well for the period 2008-2018 with an increased R² of up to ~50% compared to the reference run. What is more, SILAM is able to capture the allergy thresholds of 50 and 80 pollen grains m-³ exposure from the observations for birch trees. Grass pollen simulations are in progress.

How to cite: Verstraeten, W. W., Bruffaerts, N., Kouznetsov, R., Hendrickx, M., Sofiev, M., and Delcloo, A. W.: Timely information on birch and grass pollen levels in Belgium, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4026, https://doi.org/10.5194/egusphere-egu2020-4026, 2020.

EGU2020-21074 | Displays | AS3.22 | Highlight

Contribution of urban park to thermal comfort and CO2 mitigation in a hot-humid environment

Keunmin Lee, Je-Woo Hong, Jeongwon Kim, and Jinkyu Hong

Urban parks provide a wide range of services for healthcare and social welfare. In particular, they function as a key link connected to urban ecosystems, mitigating various environmental problems such as urban heat island effect and greenhouse emission. It is, therefore, urgent to improve our understanding of the role of the urban park in regulating their surrounding environment. We observed surface turbulent fluxes at an artificially constructed Seoul Forest Park (SFP) in Seoul, for two years from June 2013 to May 2015. The objectives of the study are to 1) quantify water, energy and CO2 exchanges from urban park into the atmosphere and 2) quantify the effect of the urban park on microclimate through comparison before and after the park construction and comparison with urbanized surrounding areas and 3) identify abiotic and biotic factors controlling the temperature reduction and CO2 offset.

Our analysis shows that SFP in summer daytime has cooler surface air temperature up to -0.6 ℃ with a Bowen ratio of 0.15 than surrounding commercial-residential zone in Seoul. SFP also acts as local sinks, and its carbon uptake gives economic benefits in terms of a carbon tax and reduction of heatwaves. Our findings indicate the important role of urban parks in mitigating urban heat island intensity and CO2 emission from urban areas and in providing eco-social benefits with us.

How to cite: Lee, K., Hong, J.-W., Kim, J., and Hong, J.: Contribution of urban park to thermal comfort and CO2 mitigation in a hot-humid environment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21074, https://doi.org/10.5194/egusphere-egu2020-21074, 2020.

EGU2020-922 | Displays | AS3.22

Polyalthia longifolia (False Ashoka) is an ideal choice for better air quality at kerbside locations

Vidit Parkar, Savita Datta, Haseeb Hakkim, Ashish Kumar, Muhammed Shabin, Vinayak Sinha, and Baerbel Sinha

Tropospheric ozone is a major pollutant and it is harmful for humans at sustained exposures of 40 ppb or more in ambient air. In this study we calibrate the deposition of ozone for stomatal exchange (DO3SE) model for Polyalthia longifolia (False Ashoka), a tree that accounts for 5-20% of the urban plantations in Indian cities and subsequently use the model to estimate not only the stomatal O3 uptake by this tree but also its capability to sequester other criteria air pollutants. We discuss the impact of planting this tree on ozone precursors NOx and VOCs in a roadside plantation scenario for mitigating air pollution.

Stomatal conductance of Polyalthia longifolia was measured, using a SC-1 Leaf Porometer, at IISER Mohali-Punjab in the NW-IGP (Northwest Indo-Gangetic Plane) which has a sub-tropical dry climate. Stomatal conductance was measured during all the four (Summer, Monsoon, Post-Monsoon, Winter) seasons, while BVOC emission fluxes were quantified using a dynamic plant cuvette during post monsoon, winter and summer season. We use ambient mixing ratios of ozone, NO, NO2, SO2 and O3 in combination with the meteorological parameters such as temperature, RH, soil moisture and photosynthetically active radiation (PAR) from the IISER Mohali Atmospheric chemistry facility to quantify Polyalthia longifolia roadside plantations’ impact on urban air quality through stomatal uptake of air pollutants (primarily NO, NO2 and O3) and BVOC emissions. Polyalthia longifolia displays a number of very interesting characteristics that include being a low isoprene and monoterpene emitter, having an extremely high leaf area index thanks to its height, straight shape and dense canopy. It displays extreme resistance to drought and high vapour pressure deficits in summer allowing stomatal uptake of pollutants and evaporative cooling to continue even under unfavourable meteorological conditions.

How to cite: Parkar, V., Datta, S., Hakkim, H., Kumar, A., Shabin, M., Sinha, V., and Sinha, B.: Polyalthia longifolia (False Ashoka) is an ideal choice for better air quality at kerbside locations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-922, https://doi.org/10.5194/egusphere-egu2020-922, 2020.

EGU2020-11776 | Displays | AS3.22

Biogenic characteristics of microparticles in big cities: structure of microbial community, pathogenicity and driving factors (MicroAir).

Olga Gavrichkova, Kristina Ivashchenko, Pavel Konstantinov, Maria Korneykova, Claudia Mattioni, Andrej Novikov, Paola Pollegioni, Olesya Sazonova, Gregorio Sgrigna, Anna Vetrova, Alexej Yaroslavtsev, and Viacheslav Vasenev

Particulate matter (PM) is recognized among the most harmful pollutants for the human health in cities and mega cities with particles smaller than 10 µm being considered as the most dangerous. European Environmental Agency attributes up to 1150 premature deaths per millions of habitants to harmful exposure to PM. Given that, the causes of the toxicity of PM exposure are not well addressed till now. Recently, biogenic fraction connected to airborn PM was proposed among one of the potential causes alongside physico-chemical composition. Among this fraction could be named pathogenic and allergenic bacteria, viruses, fungi and pollens. Few available results suggest that particulate in the air is characterized by a big biological specific richness and possess a considerable variability in space and time. Environmental factors involved in shaping the airborne microbial community are many and necessitates ulterior evaluation.

The project aims to conduct a comprehensive multidisciplinary study of the biological and physico-chemical characteristics of PM in urban environments characterized by different climatic characteristics. Particularly, MicroAir will address how chemical and biological characteristics of PM are linked to each other, to the distance from the source of pollution and presence of the green infrastructure and to the climatic particularities of the city and mircoclimate of the sampling place. Competencies in the field of microbiology, molecular biology, chemistry, climatology, urban ecology, plant and soil biology will be involved in the project realization with effective combination of modern and classical experimental approaches.  

According to the proposed aims, to be involved in the project there were chosen three cities situated in different climatic regions:  Murmansk (Subarctic, av. annual temperature 0.6°C), Moscow (Temperate, av. annual temperature 5.8°C), Turin (Mediterranean, av. annual temperature 12.5°C). In each city a network of samplers will be collecting the PM in the locations, different in terms of the distance to the pollution source (traffic roads) and in control non contaminated area. In each site will be characterized the seasonal variation of PM sampled in the air, on leaf surfaces and sealed surfaces in terms of quantity and quality with detailed physico-chemical and biological characterization. 

MicroAir is in its initial stage and will have a 3 year duration. The obtained data will serve to characterize the role of the green infrastructure, anthropogenic load, climate and seasonality in shaping chemical and microbiological characteristic of particulate matter and hence in determining the quality of the air in the cities. Will be identified the distribution and activity of potentially-pathogenic and allergenic agents and evaluated whether their presence in PM is linked to the typical seasonal peaks in the registration of certain health disturbances. These knowledge will serve to develop measures for the improvement of the air quality in urban environment and to support decision-making in the field of environmental design, planning and sustainable development of the cities.  

The project was funded by RFBR, project number 19-05-50112.

How to cite: Gavrichkova, O., Ivashchenko, K., Konstantinov, P., Korneykova, M., Mattioni, C., Novikov, A., Pollegioni, P., Sazonova, O., Sgrigna, G., Vetrova, A., Yaroslavtsev, A., and Vasenev, V.: Biogenic characteristics of microparticles in big cities: structure of microbial community, pathogenicity and driving factors (MicroAir)., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11776, https://doi.org/10.5194/egusphere-egu2020-11776, 2020.

The main objective of this research work is to demonstrate the potential of using Geographic Information System (GIS) in exposure, risk assessment and emission predictions for Khartoum state. One of the objectives of this study is to develop a digital GIS model; that can evaluate, predict and visualize Carbon Monoxide (CO) levels in Khartoum state. To achieve these aims, sample data had been collected, processed and managed to generate a dynamic GIS model of Carbon Monoxide levels in the study area.

  GIS and geostatistical models were found to be valuable tools for creating interactive and dynamic models to enhance the visualization and analysis of Carbon Monoxide emissions in Khartoum state. Parametric data collected from the field and analysis carried throughout this study show that (CO) emissions were much lower than the allowable ambient air quality standards released by National Environment Protection Council (NEPC) for 1998. However, this pilot study has found emissions of (CO) to be unevenly distributed geographically as well as temporally; with Omdurman city exhibiting highest (CO) levels. This pilot study shows that GIS and geostatistical modeling can be used as a powerful tool to produce maps of exposure to enhance exposure assessment in environmental studies.               

How to cite: Alhuseen, A.: Geostatistical Modeling of Carbon Monoxide Levels in Khartoum State-GIS Based Study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20495, https://doi.org/10.5194/egusphere-egu2020-20495, 2020.

EGU2020-5111 | Displays | AS3.22

Neighbourhood-scale flow regimes and pollution transport in cities

Ed Bannister, Xiaoming Cai, Jian Zhong, and Rob MacKenzie

Cities intimately intermingle people and air pollution. However, is very difficult to assess the efficacy of air pollution policy. Permanent in-situ observations are usually too sparsely spaced to monitor transport processes within a city. The post-processing and maintenance costs associated with calibrated low-cost sensors remains too high for them simply to fill the gaps in permanent networks. The behaviour of pollutants around the scale of a neighbourhood (1-2km) remains particularly difficult to interpret and model. This gap in our understanding is unfortunate because neighbourhood-scale processes disperse pollutants from peaks beside busy roads to levels treated as the ‘urban background’, and may link urban pollution models with weather forecasts.

Urban areas can be treated as patches of porous media to which the wind adjusts by changing its mean and turbulent components. Most cities around the world are made up of lots of neighbourhoods of differing form, density and land use – e.g. commercial centres interspaced with low-rise residential neighbourhoods. For cities whose urban form varies in this way, we formulated two neighbourhood-scale flow regimes, based on the size and density of the different neighbourhood patches.

We used large-eddy simulation to investigate how these two dynamical regimes emerge in patchy neighbourhoods, and their implications for pollution policy and research. We found that these flow regimes distribute pollutants in counter-intuitive ways, such as producing pollution ‘hot spots’ in less dense patches. The flow regimes also provide: (a) a quantitative definition of the ‘urban background’, which can be used for more precisely targeted pollution monitoring; and (b) a conceptual basis for neighbourhood-scale air pollution problems and transport of fluid constituents in other porous media.

How to cite: Bannister, E., Cai, X., Zhong, J., and MacKenzie, R.: Neighbourhood-scale flow regimes and pollution transport in cities, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5111, https://doi.org/10.5194/egusphere-egu2020-5111, 2020.

EGU2020-7878 | Displays | AS3.22

Simple solutions for the concentration fluctuations of a passive scalar

Carlo Camporeale, Matteo Bertagni, Massimo Marro, and Pietro Salizzoni

The dispersion dynamics of a contaminant released in the atmosphere is crucial for risk assessments and environmental analyses. Yet, because of the unsolved problem of turbulence, analytical solutions physically-derived are currently limited to the Gaussian models for the mean concentration field. In this work, we have obtained simple solutions for the concentration statistics of a passive scalar released from a punctual source. The main result is a novel analytical solution for the passive scalar variance, which is obtained from the contaminant transport equation. We have verified this solution against wind-tunnel data, and further adopted it in a simple stochastic model to provide closed relationships for the temporal statistics of concentration (e.g., the mean duration and occurrence of the peak events). These results may serve as a rapid and practical way to estimate the intensity and duration of the concentration fluctuations of a pollutant released in the atmosphere.

How to cite: Camporeale, C., Bertagni, M., Marro, M., and Salizzoni, P.: Simple solutions for the concentration fluctuations of a passive scalar, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7878, https://doi.org/10.5194/egusphere-egu2020-7878, 2020.

With increasing interest in air pollution, the installation of air quality monitoring networks for regular measurement is considered a very important task in many countries. However, operation of air quality monitoring networks requires much time and money. Therefore, the representativeness of the locations of air quality monitoring networks is an important issue that has been studied by many groups worldwide. Most such studies are based on statistical analysis or the use of geographic information systems (GIS) in existing air quality monitoring network data. These methods are useful for identifying the representativeness of existing measuring networks, but they cannot verify the need to add new monitoring stations. With the development of computer technology, numerical air quality models such as CMAQ have become increasingly important in analyzing and diagnosing air pollution. In this study, PM2.5 distributions in Busan were reproduced with 1-km grid spacing by the CMAQ model. The model results reflected actual PM2.5 changes relatively well. A cluster analysis, which is a statistical method that groups similar objects together, was then applied to the hourly PM2.5 concentration for all grids in the model domain. Similarities and differences between objects can be measured in several ways. K-means clustering uses a non-hierarchical cluster analysis method featuring an advantageously low calculation time for the fast processing of large amounts of data. K-means clustering was highly prevalent in existing studies that grouped air quality data according to the same characteristics. As a result of the cluster analysis, PM2.5 pollution in Busan was successfully divided into groups with the same concentration change characteristics. Finally, the redundancy of the monitoring stations and the need for additional sites were analyzed by comparing the clusters of PM2.5 with the locations of the air quality monitoring networks currently in operation.

This research was supported by Basic Science Research Program through the National Research Foundation of Korea(NRF) funded by the Ministry of Education(2017R1D1A3B03036152).

How to cite: Jung, W.-S. and Do, W.-G.: A Cluster Analysis of PM2.5 Using CMAQ Model Results for Representativeness of Air Quality Monitoring Networks in Busan, Korea, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3189, https://doi.org/10.5194/egusphere-egu2020-3189, 2020.

EGU2020-13164 | Displays | AS3.22

A semi-operational near-real-time Modelling Infrastructure for assessing GHG emissions in Munich using WRF-GHG

Xinxu Zhao, Jia Chen, Julia Marshall, Michal Galkowski, Christoph Gerbig, Stephan Hachinger, Florian Dietrich, Lijuan Lan, Christoph Knote, and Hugo Denier van der Gon

Since the establishment of the firstly fully-automatic urban greenhouse gas (GHG) measurement network in Munich in 2019 [1], we are building a high-resolution modeling infrastructure which will be the basis for a quantitative understanding of the processes responsible for the emission and consumption of CO2, CH4, and CO in Munich. The results of our near-real-time modeling are expected to also provide guidance for local emission reduction strategies.

The precision of our transport modeling framework is assessed through comparison with surface and column measurements in August and October 2018, and the contributions from different emissions tracers are quantified to understand the sources and sinks of atmospheric carbon in the Munich area. A differential column approach [3] is applied for comparing models to observations independently of the biases from background concentration fields (Zhao, X. et al, 2019). Various tracers are separately included in the simulation to further analyze the contribution from different emission processes (e.g., biogenic emissions from wetlands, fossil fuel emissions, and biofuel emissions). Surface emissions are taken from TNO-GHGco v1.1 emission inventory at a resolution of 1 km (cf. Super, I. et al, 2019). Biogenic fluxes of CO2 are calculated online using the diagnostic VPRM model driven by MODIS indices. The initial and lateral tracer boundary conditions are implemented using Copernicus Atmosphere Monitoring Service (CAMS) data, with a spatial resolution of 0.8° on 137 vertical levels, with a temporal resolution of 6 hours.

The precision of our transport modeling framework is assessed through comparison with surface and column measurements in August and October 2018, and the contributions from different emissions tracers are quantified to understand the sources and sinks of atmospheric carbon in the Munich area. A differential column approach [3] is applied for comparing models to observations independently of the biases from background concentration fields (Zhao, X. et al, 2019).

[1] Dietrich, F. et al.: First fully-automated differential column network for measuring GHG emissions tested in Munich. In Geophysical Research Abstracts. 2019.

[2] Zhao, X. et al.: Analysis of total column CO2 and CH4 measurements in Berlin with WRF-GHG, Atmos. Chem. Phys., 19, 11279–11302, https://doi.org/10.5194/acp-19-11279-2019, 2019. 

[3] Chen, J. et al: Differential column measurements using compact solar-tracking spectrometers, Atmos. Chem. Phys., 16, 8479–8498, https://doi.org/10.5194/acp-16-8479-2016, 2016.

How to cite: Zhao, X., Chen, J., Marshall, J., Galkowski, M., Gerbig, C., Hachinger, S., Dietrich, F., Lan, L., Knote, C., and Denier van der Gon, H.: A semi-operational near-real-time Modelling Infrastructure for assessing GHG emissions in Munich using WRF-GHG, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13164, https://doi.org/10.5194/egusphere-egu2020-13164, 2020.

Improper ventilation of buildings may lead to an accumulation of pollutants indoors. In the case of a room with forced air ventilation and external air intake like most centralized and some home air conditioning units, this study will show CFD simulations of various indoor air quality conditions based on different forced ventilation AC unit intake conditions like common in housing situations like Hong Kong. Especially when close to roadways or other external pollution sources, the positioning of the air intake shows up to have a high significance for the infiltration rate resulting as influence for the indoor air quality as previous research shows (e.g. Zheming Tong et al., 2016). The same is the case for a forced ventilation case like air conditioning units with outside air intake. Research like earlier referenced paper has not been conducted with higher buildings or forced air intake yet. Parametrized CFD-based air quality models with using OpenFoam will be employed to quantify the impact of the air intake location and rate in a 2-dimensional interface on the indoor air quality of a forced ventilated section of a building. The findings of the CFD simulation will be simplified as average indoor air pollution and other external factors. As an approach to predict the estimate indoor infiltration rate, an ANN (Artificial Neuronal Network) will be used, trained and validated with said data. The neural network is supposed to predict the pollutant intake based on fewer and as easier to obtain meteorological parameters and air pollution data. Finally, the ANN predictions of the models will be verified with real life data from other papers. Results will show that a major part of indoor pollutants may emerge indoors and cannot be neglected. In comparison with real life data, it seems the model lacks significant input to predict with high accuracy. 

How to cite: Nieborowski, F.: Coupled Computational Fluid Dynamics (CFD) and Artificial Neural Network (ANN) for Prediction of Traffic-related Air Pollution Infiltration Effects in Hong Kong, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8169, https://doi.org/10.5194/egusphere-egu2020-8169, 2020.

EGU2020-8795 | Displays | AS3.22

Test of chemistry boundary conditions large-eddy simulations in urban areas

Renate Forkel, Basit Khan, Johannes Werhahn, Sabine Banzhaf, Edward C. Chan, Farah Kanani-Sühring, Klaus Ketelsen, Björn Maronga, Matthias Mauder, Siegfried Raasch, and Matthias Sühring

Large-Eddy Simulation (LES) allow to simulate pollutant dispersion at a fine-scale turbulence-resolving scale with explicitly resolved turbulent transport around building structures and in street canyons. The microscale urban climate model with atmospheric chemistry PALM-4U (i.e. PALM for Urban applications; Maronga et al., 2019, Met. Z., https://doi.org/10.1127/metz/2019/0909) has been developed within the collaborative project MOSAIK (Model-based city planning and application in climate change). With such a large-eddy simulation (LES) model, pollutant dispersion around buildings and within street canyons can be simulated, with explicitly resolving the turbulent transport in urban environments.

Cyclic boundaries are frequently applied in LES in order to obtain lateral boundary conditions for the turbulent quantities. In addition to the default cyclic boundary conditions, PALM-4U allows also time-dependent boundary conditions from regional models to account for variable weather conditions and regional scale pollutant transport. Turbulent fluctuations, which are not included in the boundary conditions from the regional simulation but are needed as additional boundary conditions for the LES model are produced by a turbulence generator (Maronga et al, 2019, GMDD, https://doi.org/10.5194/gmd-2019-103).

PALM-4U simulations with and without time dependent boundary conditions from regional simulations with WRF-Chem are performed for different setups in order to test the impact of the domain configuration. The simulations indicate that cyclic boundary conditions can lead to unrealistic accumulation of pollutants over urban areas with strong sources, which is not the case when time-dependent boundary conditions are applied. However, even though a turbulence generator is applied, explicit setting of time-dependent boundary conditions requires large model domains, in order to obtain fully developed turbulence within the domain of interest, increasing the computational demand of the simulation.

How to cite: Forkel, R., Khan, B., Werhahn, J., Banzhaf, S., Chan, E. C., Kanani-Sühring, F., Ketelsen, K., Maronga, B., Mauder, M., Raasch, S., and Sühring, M.: Test of chemistry boundary conditions large-eddy simulations in urban areas, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8795, https://doi.org/10.5194/egusphere-egu2020-8795, 2020.

EGU2020-21296 | Displays | AS3.22

Development of a high-resolution air quality forecasting system, based on WRF-Chem model, for the greater area of Thessaloniki, Greece

Irene Zyrichidou, Stavros Solomos, Stylianos Kotsopoulos, Panagiota Syropoulou, and Evangelos Kosmidis

Air pollution models play an important role in science because of their capability to give a description of the air quality problem including an analysis of factors and causes (emission sources, meteorological processes, and physical and chemical changes). Real-time forecast of urban air quality is highly important to the public as advanced information for both air quality and safety assessment. This study presents the development of a regional scale high-resolution modeling system for simulating air quality and forecasting changes in urban pollution levels. The air quality system based on the state-of-the-art Weather Research and Forecasting model coupled with chemistry (WRF-Chem) has been applied over the greater area of Thessaloniki, Greece. The model performance, in terms of simulated surface major air pollutants’ concentrations, is evaluated using ground-based measurements during the operational implementation period in winter-spring 2020. Our study highlights the importance of resolving local scale atmospheric conditions such as surface wind flow and boundary layer properties for describing the pollutants’ concentrations and the importance of constraining emissions over the study area.

 

How to cite: Zyrichidou, I., Solomos, S., Kotsopoulos, S., Syropoulou, P., and Kosmidis, E.: Development of a high-resolution air quality forecasting system, based on WRF-Chem model, for the greater area of Thessaloniki, Greece, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21296, https://doi.org/10.5194/egusphere-egu2020-21296, 2020.

Along with the development of new cities, the construction of LNG cogeneration plant in urban areas is being promoted, and the facility has been pointed out as one of the major air pollution sources along with many vehicles in urban areas. For example, the construction of a new administrative city in Korea has led to the relocation of major government buildings and the influx of more than 300,000 people. The city has a 530 MW power plant + 391 Gcal/h district heating facility. The facility released 294,835 kg and 325,381 kg of NOx annually in 2017 and 2018, respectively. When examining the impact, we analyzed the impact of air pollutants (PM2.5, O3, NO2, etc.) through CMAQ modeling. In addition, the impact prediction using AERMOD related to the release of carcinogenic air pollutants is estimated to be no more than 10-5 (risk level), but measurement and verification are required. In addition to concentration-based risk assessments, health impact assessments are needed that consider the number of populations exposed. In this study, QGIS was used to calculate population. In conclusion, even if the same LNG power plant is constructed, the LNG cogeneration plant located adjacent to a large residential facility requires air pollutant management measures according to the exposure population by radius of influence

 

How to cite: Kim, Y.: Status of Air Pollutant Emissions and Health Impact of LNG Cogeneration Plant in Administrative City, Republic of Korea, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7626, https://doi.org/10.5194/egusphere-egu2020-7626, 2020.

EGU2020-6574 | Displays | AS3.22

Healthy synergies of carbon mitigation under climate policy in China

Jing Zhao and Haikun Wang

As the largest carbon emitter in the world, China shoulders weighty responsibility for carbon emission reduction. Recent evidence shows that carbon emission in China has the potential to peak ahead of schedule (2030). Analysis of both economic and environmental outcomes of the acceleration of carbon emission reduction will provide important implications for the better design and implementation of climate policies in China and other countries. However, there is a lack of research.

In this study, we focus on carbon emission paths and assess health impacts related to the synergistic emission reduction of atmospheric pollutants and conduct a cost-benefit assessment. We adopte the simulated emission of different Shared Socioeconomic Pathways and climate policy scenarios based on Global Change Assessment Model (GCAM) to quantify co-reduction of air pollution. Using the WRF-Chem chemical transport model and MEIC emission inventory, we simulate the change of air pollutant concentrations and calculate the related health benefit using the IER model and monetize it using the VSL model.

Our analysis shows that carbon emission in China could peak before 2030 in stringent climate policy. Meanwhile, cleaner developing pathways or stricter climate strategies can help to alleviate the pressure of carbon emission reduction. Climate policy will bring additional emission mitigations to atmospheric pollutants, especially for SO2, and NOx, but NH3 emission increases. Climate policies aimed at reducing carbon emissions will also bring different degrees of improvements in air quality and health benefits across China in 2030 and 2050, respectively.

How to cite: Zhao, J. and Wang, H.: Healthy synergies of carbon mitigation under climate policy in China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6574, https://doi.org/10.5194/egusphere-egu2020-6574, 2020.

EGU2020-22364 | Displays | AS3.22

Personal exposure to PM2.5 during commuting in Shanghai

Li Peng, Yanling Shen, and Jing Cai

The impact of microenvironment on public health has received increasing attention, especially in the traffic and living microenvironment. This study shows a comparative research of PM2.5 exposure concentrations associated with five commuting modes (i.e., walking, bicycling, car, bus and subway) in haze and non-haze periods in Shanghai, China. On the days of observation, the experimenter carried portable instruments to measure personal PM2.5 exposure concentrations, commuting by different transport modes, following designated routes round Century Park in Shanghai. Fixed observations of indoor and background concentrations of PM2.5 were also taken for comparison in a three-story building nearby. We found that the choice of different commuting modes will result in different personal PM2.5 exposure levels. During the haze periods in winter, cyclists followed by pedestrians had the highest PM2.5 exposure than those who commuted by subway, bus and car with controlled ventilation settings. During the non-haze periods, subway commuters had the highest PM2.5 exposure. By contrast with personal exposure, the hourly inhaled dose of PM2.5 was higher among active commuters than among commuters who used motorised transport such as subway, bus and car. Our results may provide information to help develop exposure mitigation strategies for public health protection.

How to cite: Peng, L., Shen, Y., and Cai, J.: Personal exposure to PM2.5 during commuting in Shanghai, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22364, https://doi.org/10.5194/egusphere-egu2020-22364, 2020.

EGU2020-12322 | Displays | AS3.22

Population aging might mask the health benefit from China’s 2013 Clean Air Action

Yifan Liu, Xiaojing He, Zixiao Zhao, Ge Zhu, Clive Sabel, Zongwei Ma, Ziheng Jiao, Jing Zhao, and Haikun Wang

Ambient PM2.5 (fine particulate matter) pollution in China has been greatly reduced in recent years, especially since the implementation of Clean Air Action in 2013. Analysis of variations in the pollution related health burden and the driving factors has important implications for the policymakers to further improve the health benefit of air pollution controls. Here we adopted an annual population distribution estimate, disaggregated by age structure, together with PM2.5 concentration and incidence data, to better estimate total PM2.5 attributable mortality considering the effect of changing population size and age structure. We then quantified the contribution of each factor to the total variation of PM2.5 attributable mortality both nationally and regionally. Our analysis showed that national PM2.5 attributable mortality generally increased from 861,140 (95% confidence interval: 525,860~1,161,550) in 2004 to 932,500 (546,590~1,300,160) in 2017. In most 2nd- and higher-tier cities in China, which stand for highly developed cities like Beijing, Shanghai, Guangzhou, etc., the PM2.5 health burden increased. Meanwhile, the decrease in city-level PM2.5 health burden mainly happened in 3rd- and lower-tier cities, where local developments were relatively smaller. The effect of exposure to PM2.5 on air pollution-related mortality has altered from aggravating to mitigating since 2012, and the abated PM2.5 exposure resulted in a reduction of 19.7% of PM2.5 attributable mortality between 2012 and 2017. However, such benefit was almost masked by the effect of the population aging, which brought an increase of 18.4% to the health burden. Our results implied that the increasing trend in China’s PM2.5 health burden since 2006 was halted after 2012 due to the pollution control policies, and population aging impeded it from declining further. For future air pollution control and public health affairs, growing cities in China should focus attention on old-age care, where the growth of attributable mortality might occur.

How to cite: Liu, Y., He, X., Zhao, Z., Zhu, G., Sabel, C., Ma, Z., Jiao, Z., Zhao, J., and Wang, H.: Population aging might mask the health benefit from China’s 2013 Clean Air Action, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12322, https://doi.org/10.5194/egusphere-egu2020-12322, 2020.

EGU2020-2669 | Displays | AS3.22

Health-relevant influences of air substances and meteorological conditions

Stephanie Koller, Christa Meisinger, Markus Wehler, and Elke Hertig

For a long time it has been known that exceptionally strong and long-lasting heat waves have negative health effects on the population, which is expressed in an intensification of existing diseases and over-mortality of certain risk groups (Kampa, Castanas 2008). Often associated with heat are stagnant airflow conditions that cause a large increase in the concentration of certain air substances (Ebi, McGregor 2008). Many of these air substances have a strong adverse effect on the human organism (Kampa, Castanas 2008).

The aim of the project is to investigate the actual hazard potential of health-relevant air pollution- and climatological variables by quantifying the effects on human health of increased exposure to air constituents and temperature extremes. Different multivariate statistical methods such as correlation analysis, regression models and random forests, extreme value analysis and individual case studies are used.

As a medical data basis for this purpose, the emergency department data of the University Hospital Augsburg are regarded. In addition to the diagnosis, supplementary information such as age, gender, place of residence and pre-existing conditions of the patients are used. Among the air constituents, the focus is on ozone, nitrogen dioxide and particulate matter. In the meteorological part, the focus is primarily on temperature, which is not only a direct burden but, as in the case of ozone, also has a decisive influence on the formation of ozone molecules. However, a large number of other meteorological parameters such as precipitation, relative humidity and wind speed as well as the synoptic situation also play a major role in the formation, decomposition process and the distribution of pollutants (Ebi, McGregor 2008).

The first major question to answer is whether air-pollution and meteorological stress situations are visible in the emergency department data. Further in-depth questions are which factors have the greatest negative impact, what is the most common environment-related disease, which weather conditions carry a higher than average risk and what are the health risks of climate change.

Ideally, the analysis may also provide a short-term forecast from which to derive whether or not there will be an above or below average number of visits to the emergency department.

The project is funded by the German Federal Foundation for Environment (DBU) and the German Research Foundation (DFG) - project number 408057478.

Literature

Ebi K., McGregor G. (2008): Climate Change, Tropospheric Ozone and Particulate Matter, and Health Impacts. doi: 10.1289/ehp.11463

Kampa M., Castanas E. (2008): Human health effects of air pollution. In: Environmental Pollution 151(2): 362-367. doi: 10.1016/j.envpol.2007.06.012

How to cite: Koller, S., Meisinger, C., Wehler, M., and Hertig, E.: Health-relevant influences of air substances and meteorological conditions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2669, https://doi.org/10.5194/egusphere-egu2020-2669, 2020.

EGU2020-13601 | Displays | AS3.22

Analysis of urban air quality in 6 European cities by lower cost sensors, Lagrangian urban dispersion modelling and traffic flow modelling: the TRAFAIR project

Ohad Zivan, Alessandro Bigi, Giorgio Veratti, José Antonio Souto González, Lorena Marrodán, Chiara Bachechi, Sara Fabbi, David Cartelle Fernández, Xabier Diz Gerpe, Grazia Ghermandi, Giovanni Gualtieri, Raquel Trillo Lado, Javier Cacheiro López, Ángel Rodríguez López, Paolo Nesi, Michela Paolucci, Stefano Bilotta, José Ramón Rı́os Viqueira, Alessandro Zaldei, and Laura Po

Most of worldwide population lives in urban areas, demanding for air quality information with a high spatio-temporal resolution. The most promising approaches for estimating urban air quality within the complex urban topography are small sensor networks and simulation models.

The TRAFAIR project focuses on understanding the role of traffic emissions on urban air quality by the combination of dispersion modelling, space- and time-resolved gas monitoring by lower cost sensors and realistic traffic flow rates by dynamic traffic model based on real time traffic data. Test cities of TRAFAIR are Modena, Florence, Pisa, Livorno, Zaragoza and Santiago de Compostela.

Depending on the size of the urban area, from 6 to 13 sensors units are deployed across each city since August 2019, providing estimates of NO, NO2, CO and O3, along with RH and temperature. Metal oxide sensors are deployed in Tuscany (Florence, Pisa, Livorno) and electrochemical cells are used elsewhere. The units are calibrated on a regular basis by co-location at the air quality regulatory stations and subsequently deployed across the town to monitor several representative locations (e.g. Low Emission Zones, hospital surroundings). For each sensor the raw readings (e.g. mV for electrochemical cells) are collected and a regression model (e.g. Random Forest) is applied to derive a calibration function, exploiting the data from the regulatory stations during co-location periods; for instance in Modena, the first short-term calibration provided a model with a Mean Absolute Error between 5 – 6 ppb and 2 – 4 ppb for NO and NO2 respectively.

The sensors are used for both real-time urban air quality mapping and to test and validate the 24hr forecast service of NOx by the microscale lagrangian dispersion model GRAL. The simulation domains, covering the urban area of each TRAFAIR city, have a horizontal resolution of 4 m and allow to account for the presence of buildings. The dispersion model mainly focuses on NOx by traffic emissions, although domestic heating will be also included in the analysis. Vehicular emissions are based either upon historical traffic data (e.g. induction loops), or upon previously available traffic flow simulation, or upon traffic pattern reconstruction using a traffic flow model followed by a cluster analysis to group streets with similar pattern.

The final goal of the project is the development of a tool to support local policymakers and to inform citizenship about the quality of air and the impact of urban emission sources, particularly traffic. A secondary goal of the project is the development of a valuable QA/QC protocol for small sensor units and the optimization of the modelling chain for the forecast of traffic and domestic heating impact on local air quality at the urban scale.

How to cite: Zivan, O., Bigi, A., Veratti, G., Souto González, J. A., Marrodán, L., Bachechi, C., Fabbi, S., Cartelle Fernández, D., Diz Gerpe, X., Ghermandi, G., Gualtieri, G., Trillo Lado, R., Cacheiro López, J., Rodríguez López, Á., Nesi, P., Paolucci, M., Bilotta, S., Rı́os Viqueira, J. R., Zaldei, A., and Po, L.: Analysis of urban air quality in 6 European cities by lower cost sensors, Lagrangian urban dispersion modelling and traffic flow modelling: the TRAFAIR project , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13601, https://doi.org/10.5194/egusphere-egu2020-13601, 2020.

EGU2020-8891 | Displays | AS3.22

Improvement of a low-cost CO2 commercial NDIR sensor for UAV atmospheric profiling applications

Yunsong Liu, Jean-Daniel Paris, Mihalis Vrekoussis, Panayiota Antoniou, Marios Argyrides, Christos Constantinides, Dylan Desbree, Neoclis Hadjigeorgiou, Christos Keleshis, Olivier Laurent, Andreas Leonidou, Carole Philippon, Panagiotis Vouterakos, Pierre-Yves Quehe, Philippe Bousquet, and Jean Sciare

Unmanned Aerial Vehicles (UAVs) have the potential to fill in gaps in greenhouse gases (GHG) observations by providing high-resolution vertical profiling, horizontal mapping of fluxes and 3D measurements close to the ground. UAVs can ultimately allow better characterizing the spatial distribution of various GHG sources and sinks. To achieve these goals, important efforts are currently put towards the development of compact, lightweight, low powered and highly accurate GHG sensors on UAVs.

This study aims to develop and validate a UAV-CO2 sensor system to map specific source emissions close to the ground. The CO2 sensor used here is the High-Performance Platform (HPP 3.2, SenseAir AB) of a total weight 1058g including battery. Prior to its integration in the UAV, the CO2 sensor accuracy and linearity tests were performed in the laboratory. Allan Deviation showed the sensor precision to be within ±1ppm at 1 Hz. Corrections due to temperature and pressure changes were performed using specific formulas obtained from chamber experiments. Field (manned aircraft) tests were performed, where the P/T correction equations were evaluated for two CO2 sensors which were compared against an airborne reference instrument (Picarro G2401-m). After laboratory tests and field deployment, the HPP CO2 sensor was integrated into a small fixed-wing UAV with a wingspan of 1.83m and customized avionics and payload developed by the Unmanned Systems Research Laboratory of the Cyprus Institute performed successful atmospheric profiling below/above the boundary layer, at an agricultural site in Cyprus. This HPP CO2 sensor is also to be integrated in a quad-copter for vertical take-off & landing (VTOL) in urban environments to execute intensive (every 20-min) atmospheric profiling (0-1km altitude) over the city of Nicosia (Cyprus). These flights provide us with useful insights into the CO2 vertical distribution within the planetary boundary layer (and above) for different (remote/urban) regions in Cyprus.

How to cite: Liu, Y., Paris, J.-D., Vrekoussis, M., Antoniou, P., Argyrides, M., Constantinides, C., Desbree, D., Hadjigeorgiou, N., Keleshis, C., Laurent, O., Leonidou, A., Philippon, C., Vouterakos, P., Quehe, P.-Y., Bousquet, P., and Sciare, J.: Improvement of a low-cost CO2 commercial NDIR sensor for UAV atmospheric profiling applications, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8891, https://doi.org/10.5194/egusphere-egu2020-8891, 2020.

EGU2020-11858 | Displays | AS3.22

CO2 and CH4 observations surrounding Beijing to to distinguish possible emission processes and locations

J. William Munger, Shuxiao Wang, Chris Nielsen, and Michael B. McElroy

CO2 and CH4 are radiatively important trace gases closely associated with human activity particularly in urban emission hotspots. Through rapid development and economic growth China has become a major source of CO2. CO2 emission inventories for China are becoming increasingly accurate. CH4 emissions in China are not as well characterized, though for various reasons, including; Chinese policies mandating conversion from coal to natural gas for district heating, intensification of agriculture, and the large volumes of urban waste that must be managed, it is likely CH4 emissions from Chinese urban centers could be significant. As part of an ongoing Tsinghua – Harvard collaboration we have set up a pair of atmospheric observatories to the north and south of Beijing. The northern site (Miyun) is 75km NNE and the southern site, Dashiwo, is 63 km SSW of the center of Beijing. Miyun has been in semi continuous operation since 2005. Miyun was located to sample Beijing urban outflow as well as clean airmasses depending on wind direction. Dashiwo is located primarily to capture the polluted air coming into Beijing from Hebei province, though it will also be influenced at times by cleaner airmasses coming over the mountains on the western edge of the basin. The high accuracy and precision measurements of CO2 and CH4 that are the focus of this presentation started in May 2018. Observations at Dahsiwo started in November 2019.For this presentation we focus on quantifying the magnitudes of CO2 and CH4 in urban-influenced air masses and their enhancements relative to clean background air. The correlations between CO2 and CH4 and their relationships to other air pollutant tracers including SO2, NOx/NOy, and CO provide constraints on potential sources for these gases. Through back trajectory analysis the source regions can be distinguished. As expected, both sites have enhanced mixing ratios of CO2 and CH4. Median CO2 during the overlapping period Nov. Dec. 2019 is 430, and 459 ppm at Miyun and Dashiwo. Median CH4 is 2036 and 2228 ppb. Outside the growing season when CO2 is influenced by vegetation uptake the CH4:CO2 ratio is 6.1 ppb:ppm. The Dashiwo data are bounded by the same slope, but have more scatter due to periods with elevated CH4 but not CO2. A tight correlation for CO2 and CH4 at Miyun suggests a single predominant combustion or respiration source type, while variability in the Dashiwo observations suggests multiple sources including some rich in CH4 that are not combustion or respiration. Identification of major CH4 sources is a starting point for choosing mitigation options.

How to cite: Munger, J. W., Wang, S., Nielsen, C., and McElroy, M. B.: CO2 and CH4 observations surrounding Beijing to to distinguish possible emission processes and locations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11858, https://doi.org/10.5194/egusphere-egu2020-11858, 2020.

EGU2020-12475 | Displays | AS3.22

Urban Methane Surveys – A Case Study Where Isotope Measurements Guided Source Attribution

Bryce F.J. Kelly, Xinyi (Lexie) Lu, Zoë M. Loh, and Rebecca E. Fisher

Methane (CH4) is the second most important anthropogenic greenhouse gas after carbon dioxide (CO2) in the atmosphere1. Human activities are estimated to contribute ~50% of total CH4 emissions globally2. With 68% of the population projected to live in urban areas by 20503, there is a need to better quantify CH4 emissions from urban sources and to develop mitigation plans. Major potential urban sources include: the gas distribution network, landfills, the sewerage network, appliances in houses (heaters, stoves, hot-water systems), wood burning heaters, and urban wetlands.

This study aimed to determine the major CH4 sources in Melbourne (Australia’s second largest city with a population approaching 5 million people). Melbourne has grown rapidly since it was founded ~200 years ago and this has left legacy potential CH4 sources. For example, the gas distribution system has piping ranging from modern to 100 years old (common in unrenovated houses from early last century); landfills that use to be on the city fringe are now surrounded by new housing developments. 

To map the location of major CH4 sources throughout Melbourne we conducted a mobile survey, measuring the CH4 mole fraction ([CH4]) at a height of 3 m using a Los Gatos Research ultra-portable greenhouse gas analyser. An air inlet was attached to the roof of the car and the location of the measurements were georeferenced using a Hemisphere GPS system as we drove around the city. The day and night-time surveys were undertaken from the 26th – 27th July 2019 (winter).  When a major CH4 plume was detected 10 air samples were collected and stored 3 litre FlexFoil bags. These samples were analysed for [CH4], δ13C-CH4, [CO2], δ13C-CO2 using a Picarro G2201-i cavity ring-down spectrometer (CRDS). To determine the δ13C-CH4 signature of the plume each set of bags was analysed using a Miller-Tans plot and Bayesian regression. The combination of potential observable sources and the δ13C-CH4 signature was then used to attribute the source of the CH4 plume. We show that the δ13C-CH4 signatures of the CH4 plumes are needed to reduce the risk of attributing a plume to the wrong source. We present an example of separating domestic wood fires from a ‘super-emitter’ leak from the gas distribution system, and we also show how we traced a landfill plume for a distance of over 5 km using δ13C-CH4 measurements.

Our research demonstrates that mobile [CH4] surveys coupled with δ13C-CH4 analyses is a cost-effective workflow for mapping both diffuse CH4 emissions and ‘super-emitters’. Such surveys could be systematically undertaken in cities worldwide to delineate and prioritise targets for CH4 emission reduction. 

 

References

(1)      Myhre, G. et al. Cambridge University Press, 2013; Vol. 9781107057, pp 659–740.

(2)      Saunois, M. et al. Earth Syst. Sci. Data Discuss. 2019, 1–138.

(3)      United Nations. World Urbanization Prospects The 2018 Revision (ST/ESA/SER.A/420). 2019.

How to cite: Kelly, B. F. J., Lu, X. (., Loh, Z. M., and Fisher, R. E.: Urban Methane Surveys – A Case Study Where Isotope Measurements Guided Source Attribution, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12475, https://doi.org/10.5194/egusphere-egu2020-12475, 2020.

EGU2020-12030 | Displays | AS3.22

Using the Aerodyne Mobile Laboratory to characterize industrial emissions in Southern California
not presented

Conner Daube, Christoph Dyroff, Edward Fortner, Jordan Krechmer, Francesca Majluf, Tara Yacovitch, and Scott Herndon

During late 2019, the Aerodyne Mobile Laboratory sampled numerous industrial areas primarily in the County of Los Angeles, California, USA. Commercial and laboratory-grade instruments were used to analyze the gaseous and particulate composition of ambient air samples while operating in mobile and stationary modes. Measurements of CO2, CH4, and N2O were collected in addition to several specific hazardous air pollutants. Short-lived plumes from a wide variety of industries and broader regional trends were observed. Multi-day measurements at identified sources and overnight sampling added depth and context to these findings. Results from this characterization of industrial emission sources, including analysis of both greenhouse gases and pollutants in the urban environment, will be presented.

How to cite: Daube, C., Dyroff, C., Fortner, E., Krechmer, J., Majluf, F., Yacovitch, T., and Herndon, S.: Using the Aerodyne Mobile Laboratory to characterize industrial emissions in Southern California, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12030, https://doi.org/10.5194/egusphere-egu2020-12030, 2020.

Urban air pollution remains a key pressure on public health. With the megatrend of urbanization and its forcing on emissions and exposure, effective monitoring tools in cities are at the center of prevention efforts.

Air Quality Monitoring Stations (AQMS) are traditionally used for regulatory efforts and, increasingly, as publicly available information sources. Facing high levels of air pollution heterogeneity in complex urban environments, a simple spatial approach is often misleading when choosing an AQMS that represents local street-level conditions the best. Model-based calculation of representativeness areas are rare for the urban scale (e.g. Rodriguez et al., 2019), and suffer from short model times, low model correlations and a lack of external validation by observation data. Moreover, as both health impacts and air-pollution episodes are influenced by environmental factors, the sensitivity of representativeness areas to wind impacts and during different seasons are a further point of interest not covered well by previous literature.

For the high-density environment of geographically complex Hong Kong, we used a full year (2019) of high-resolution air quality modelling (ADMS-Urban) data to establish representativeness areas for the territory’s 16 AQMS. We constructed representativeness areas for key air-pollutants for the full period and based on season and wind speed. We parameterized the effects of wind and geography on the size and shape of the representativeness areas. Furthermore, we validated our findings by a series of week-long outdoor measurements aimed to cover the whole territory of Hong Kong.

Our results show that Hong Kong’s AQMS network covering the territory well for a PM2.5, PM10 and O3, where the mean CSF (hourly Concentration Similarity Frequency with a target of ±20%) of each grid-cell to the best matching AQMS lies at around 60%. Both NO2 and SO2 are less well represented, with a CSF of around 30%. Moreover, we show that representativeness areas calculated from similarity-based metrices as CSF and percentage difference represent the impact of geographical features on pollution dispersion better than correlation-based metrices (R2 and ioa). It was further found that AQMS represent upwind areas better than downwind areas, especially in areas exposed to open wind-flow, and that the represented areas change strongly over the course of a year.

In this study, we showcase the ability of high-resolution urban air-pollution modelling to guide the public with information on AQMS representativeness. Furthermore, we report that representativeness areas are non-static, changing with seasons and under the influence of wind. High-resolution urban modelling can further be used to gauge the quality of AQMS networks and assess the need and location of additions to an existing network.

 

Rodriguez, D., Valari, M., Payan, S., & Eymard, L. (2019). On the spatial representativeness of NOX and PM10 monitoring-sites in Paris, France. Atmospheric Environment: X, 1, 100010.

How to cite: Hohenberger, T. L.: Influences of Season and Geography on Urban Air Quality Monitoring Stations (AQMS) Representativeness Areas by High Resolution Air Quality Monitoring, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13652, https://doi.org/10.5194/egusphere-egu2020-13652, 2020.

EGU2020-18946 | Displays | AS3.22

Low cost sensors and crowd-sourced data to map air pollution in urban areas

Rodrigo Carbajales, Massimiliano Iurcev, and Paolo Diviacco

Low cost sensors and crowd-sourcing data could potentially revolutionise the way air pollution measurements are collected providing high density geolocated data. In fact, so far data have been collected mostly using dedicated fixed position monitoring stations. These latter rely on high quality instrumentation, well established practices and well trained personnel, which means that, due to its costs, this paradigm entails limitations in the resolution and extension of geographic sampling of an area.

The combination of low costs sensors and volunteer-based or opportunistic acquisition of data can, instead, possibly turn the cost issue into an advantage. This approach, however, introduces other limitations since low cost sensors provide less reliable data and crowd source acquisition are subjects to data gaps in space and time.

In order to overcome these issues redundant data from multiple platforms have to be made available. On one hand this allows statistics to be applied to identify and remove anomalous values, and on the other hand when multiple platforms are used, the chances to have a better coverage and more reliable data  increases.

To implement this approach OGS developed the full suite of tools that has been named COCAL that allow to follow the full path from the acquisition, transmission, storage, integration and real time visualization of the crowdsourced data.

Low cost sensors for the detection of suspended particulate matter size 2.5 and 10 µm, together with atmospheric pressure, humidity and temperature, have been combined with GPS positioning and transmission (being able to opt for GSM, WiFi or LoRaWAN transmission) unit in a black box that can be attached to any moving vehicle travelling in an area. This way large areas can be sampled with high geographic resolution.

Atmospheric data are collected in an InfluxDB database, which allows easy integration with TheThingsNetwork for LoRaWAN network management and directly with GSM and WiFi connections. Public users are provided with a real-time web interface based on OpenLayers for map visualization. Server based processing and conversion scripts generate both filtered data and aggregate data, by computing averages on a spatial and temporal grid.. Finally, automatic interpolation techniques like Inverse Distance Weighting or Natural Neighbours may provide detailed online maps with contouring and boundary definition. All products are available in near real-time through OGC compliant web services, suited for an easy integration with other repositories and services.

How to cite: Carbajales, R., Iurcev, M., and Diviacco, P.: Low cost sensors and crowd-sourced data to map air pollution in urban areas, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18946, https://doi.org/10.5194/egusphere-egu2020-18946, 2020.

EGU2020-19276 | Displays | AS3.22

Low-Cost Air Quality Sensor Network in Munich

Daniel Zollitsch, Jia Chen, Florian Dietrich, Benno Voggenreiter, Luca Setili, and Mark Wenig

As the number of official monitoring stations for measuring urban air pollutants such as nitrogen oxides (NOx), particulate matter (PM) or ozone (O3) in most cities is quite small, it is difficult to determine the real human exposure to those pollutants. Therefore, several groups have established spatially higher resolved monitoring networks using low-cost sensors to create a finer concentration map [1-3].

We are currently establishing a low-cost, but high-accuracy network in Munich to measure the concentrations of NOx, PM, O3, CO and additional environmental parameters. For that, we developed a compact stand-alone sensor systems that requires low power, automatically measures the respective parameters every minute and sends the data to our server. There the raw data is transferred into concentration values by applying the respective sensitivity function for each sensor. These functions are determined by calibration measurements prior to the distribution of the sensors.

In contrast to the other existing networks, we will apply a recurring calibration method using a mobile high precision calibration unit (reference sensor) and machine learning algorithms. The results will be used to update the sensitivity function of each single sensor twice a week.  With the help of this approach, we will be able to create a calibrated real-time concentration map of air pollutants in Munich.

[1] Bigi et al.: Performance of NO, NO2 low cost sensors and three calibration approaches within a real world application, Atmos. Meas. Tech., 11, 3717–3735, 2018

[2] Popoola et al., “Use of networks of low cost air quality sensors to quantify air quality in urban settings,” Atmos. Environ., 194, 58–70, 2018

[3] Schneider et al.: Mapping urban air quality in near real-time using observations from low-cost sensors and model information, Environ. Int., 106, 234–247, 2017

How to cite: Zollitsch, D., Chen, J., Dietrich, F., Voggenreiter, B., Setili, L., and Wenig, M.: Low-Cost Air Quality Sensor Network in Munich, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19276, https://doi.org/10.5194/egusphere-egu2020-19276, 2020.

 

As urbanization has spread, increased energy consumption, complicated built environments, and dense road networks cause spatiotemporal heterogeneity of air pollutant distributions even in an intra-community scale. High spatiotemporal heterogeneity of air pollutant distributions can affect pedestrian and/or traffic users’ exposure to air pollutants according to where and when they are, potentially forming air pollution hotspots. Thus, it is important to understand the characteristics of spatiotemporal distributions in air pollutants in various micro-built environments in populated urban areas. However, current air quality monitoring performed by the government cannot capture these highly heterogeneous distributions of air pollutants due to the limitations of financial and human resources. In this respect, cost-effective sensors have great potential to build highly spatially dense air quality monitoring networks to address the low spatial resolution issue of conventional air quality monitoring stations.

In this study, we built a highly dense air quality monitoring network consisting of 30 sets of sensor nodes in an 800 m ´ 800 m spatial domain to understand the characteristics of air pollutant distributions in various urban microenvironments. The domain includes urban street canyon with moderate traffic, a mixture of high and low buildings with high traffic, an open space with minimal traffic, and others. The sensor node consists of sensors (for CO, NO2, O3, PM2.5, and PM10, temperature, and humidity) and communication/data storage parts (wifi, interface for smartphone connection, and SD card). We also conducted inter-sensor comparison among sensor nodes and intercomparison tests between the sensor node and conventional reference instruments.

Intra-community air quality monitoring with a sensor network was conducted for a couple of weeks in two distinct weather conditions (humid and hot summer and dry and cold winter) in 2017 and 2018. During the observation periods, the concentration distribution analyses for air pollutants (except CO, PM) showed significant heterogeneity in their distributions in space. In addition, the correlation analysis with the meteorological factors showed that CO concentrations were affected by wind speed (winter, R2=0.22-0.25), but the other air pollutants were not directly correlated. We also examined the effects of land-use and building configuration on air pollution distributions. More details concerning these results are presented.

Keywords: Sensor network, low-cost sensor, spatial heterogeneity, micro-built environments

How to cite: Park, Y., Park, H.-S., and Choi, W.: Intra-community air quality monitoring in various urban microenvironments in South Korea: based on observations from highly dense cost-effective sensor network, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19324, https://doi.org/10.5194/egusphere-egu2020-19324, 2020.

This research investigated the hazardous air pollutants (HAPs), also known as air toxics, emission profiles and the potential health risks in Tainan City in Taiwan. Emission profiles of HAPs were derived by source test data and speciation data bank. Emissions from stationary source, mobile source, and area source were estimated in this study. Airborne concentration of target HAPs had been simulated by Models-3/CMAQ simulation and followed by cancer risk assessments for control priority assessment.

Five species of air toxics were selected as target component in this study, which included benzene, formaldehyde, acetaldehyde, acrolein, and 1,3-butadiene, by weighting the emissions and toxicity factors. Emission estimation indicated that these target air toxics were released by stationary sources with 34.5, 35.0, 5.0, 72.3, 94.5 %, respectively. Emissions of these 5 air toxics from mobile sources were 62.8, 45.4, 94.7. 27.5, 3.5 %, respectively. Area sources contributed less fraction in the city. The simulated annual average concentrations of target air toxics indicated the hot zone of various HAPs present in different location in the city. The airborne concentration of benzene and acetaldehyde in hot zone were mainly caused by mobile source emissions. Concentrations of formaldehyde in hot zone was caused by various sources. Airborne concentrations of acrolein and 1,3-butadiene in hot zone were mainly caused by area sources. The potential health risk assessment imposed by these target air toxics were evaluated by simulated exposure concentrations and with inhalation unit risk factor (cancer risk) and reference concentration level (non-cancer risk), respectively. The results showed 1,3-butadiene would pose the highest carcinogenic potential in the city which were mainly released by area sources. Acrolein had the highest non-carcinogenic potential. The cancer burden, by considering population density and exposure concentration, was higher in downtown area. Formaldehyde was the critical HAP which would impose the highest impacts on people caused by dense emission from mobile sources.

How to cite: Tsai, J.-H. and Tsai, H.-H.: Characteristics and Control Priority of Hazardous Air Pollutants in the Metropolitan Areas : A Case Study in Tainan, Taiwan, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22492, https://doi.org/10.5194/egusphere-egu2020-22492, 2020.

EGU2020-2198 | Displays | AS3.22

The vertical distribution of PM2.5 and boundary-layer structure during winter haze in Nanjing

Jun Zou, Jianning Sun, Zixuan Xiang, Xiaomen Han, and Qiuji Ding

At the end of November 2018, a heavy air pollution event was recorded by many meteorological stations in the Yangtze River Delta (YRD), China. The local PM2.5 concentration exceeding to 200 µg m-3. This is the heaviest, longest and most widespread heavy-polluted weather in Jiangsu Province since 2018. Meanwhile, there has been severe foggy weather in Jiangsu Province, with visibility less than 200 meters in most parts of the province. In order to study the interaction between PM2.5 concentration and boundary layer height in the haze event, and the effect of fog on pollutant aggregation, the boundary layer structure of the continuous haze process was analyzed by using the SORPES Observation of Nanjing University's Xianlin Campus. The results of the analysis show that:
1, The PM2.5 concentration in the boundary layer is inversely correlated with the boundary layer height, the higher the PM2.5 concentration, the lower the boundary layer height during the day. By absorbing and scattering solar radiation, atmospheric aerosols affect the balance of surface energy and reduce the sensitive heat flux, thereby inhibiting the development of the boundary layer. While inhibited development of the boundary layer will limit the diffusion of atmospheric aerosols, thereby increasing the concentration of atmospheric aerosols in the boundary layer. In addition, nocturnal atmospheric aerosols absorb heat, leading to strong grounding inversion temperature the next day, further inhibiting the development of the daytime boundary layer. 
2, The fog-top inversion is very strong, far stronger than the inversion caused by atmospheric aerosols. Therefore, the heights of the boundary layer of fog days are much lower than that of non-fog days under the same pollution conditions.
3, During the fog, the PM2.5 concentration significantly reduced. And after the fog dissipated, due to the sun, the air moisture evaporation, PM2.5 concentration quickly reverted to the pre-fog state. Fog has limited wet removal of PM2.5.
4, Fog can inhibit the development of the boundary layer, with the continuation of the fog process, the pollution in the boundary layer continues to increase. At the same time, due to the inhibition of the development of the boundary layer, the diffusion of water vapor in the air is also affected, resulting in the boundary layer water vapor content is always in a high state, thus promoting the production of fog.

How to cite: Zou, J., Sun, J., Xiang, Z., Han, X., and Ding, Q.: The vertical distribution of PM2.5 and boundary-layer structure during winter haze in Nanjing, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2198, https://doi.org/10.5194/egusphere-egu2020-2198, 2020.

EGU2020-21032 | Displays | AS3.22

Extreme concentrations of fine particulate matter and black carbon during commute

Veronika S. Brand, Thiago Nogueira, Prashant Kumar, and Maria de Fatima Andrade

Commuters are vulnerable to traffic air pollutants, especially to fine particulate matter (PM2.5) and black carbon (BC) because of their proximity to on-road vehicles. Both pollutants have been extensively associated to adverse health effects (i.e., stroke, diabetes, cardiovascular and respiratory diseases, and cancer). Therefore, this work aims to investigate the extreme concentrations of PM2.5 and BC occurrence in commuters in the megacity of São Paulo, Brazil. We carried out a field campaign measuring the commuter exposure to PM2.5 and BC concentrations inside buses, cars and undergrounds in São Paulo during morning and evening peak-hours. We fitted an Extreme Value Distribution to the collected data to investigate the behavior of the extreme values in the different transport modes and periods of the day. The results suggest that higher concentrations of PM2.5 and BC occur more frequently inside buses, followed by cars and undergrounds. Extreme concentrations for both pollutants are more likely to happen during morning peak-hours when compared to evening peak-hours. Our findings add further evidence that the transport mode and period of the day affect substantially the PM2.5 and BC exposure in commuters. Furthermore, the results are quite useful for supporting urban policies that consider the improvement of the efficiency of air filtering systems inside public transport and private cars.

How to cite: S. Brand, V., Nogueira, T., Kumar, P., and Andrade, M. D. F.: Extreme concentrations of fine particulate matter and black carbon during commute, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21032, https://doi.org/10.5194/egusphere-egu2020-21032, 2020.

Nitrated aromatic compounds (NACs) are an important chromophore component of atmospheric brown carbon (BrC) and can affect both the urban air quality and global climate. However, the compositions, sources of NACs in atmospheric particulate matter and its impact on the optical properties of BrC are still of very limited understood. In this study, the concentrations of 10 NACs and their light absorption contributions to BrC were investigated based on daily aerosol fine particle filter samples collected in Xi’an, Northwest China from 2015 to 2016. Both the concentrations and constitutions of NACs show distinct seasonal differences with average concentration of 2.05, 1.06, 12.90 and 56.32 ng m-3 in spring, summer, fall and winter, respectively, which could be ascribed to the differences in emission sources and formation processes. The contributions of NACs to light absorption of BrC at wavelength between 300 to 500 nm was wavelength dependent and varied greatly over different seasons, with high contribution even at wavelength > 350 nm in fall and winter and contribution mainly at wavelength < 350 nm in spring and summer, which could be related to the differences in the composition of NACs and the specific light absorbing properties of each NAC. The mean contributions of NACs to the light absorption of BrC at wavelength of 365 nm were 0.14, 0.09, 0.36 and 0.91% during spring, summer, fall and winter, respectively, about 3-5 times higher than their corresponding mass fraction in total organic carbon. Further, the sources of NACs were achieved by positive matrix factorization (PMF) receptor model. The results show that the sources of NACs varies among different seasons. Specifically, vehicular emission and secondary formation are dominant sources in summer (~80%), while biomass burning and coal combustion are major sources in winter (~75%).

How to cite: Yuan, W., Huang, R., and Yang, L.: Seasonal composition and source apportionment of nitrated aromatic compounds in atmospheric fine particulate matter in northern China over one year, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7517, https://doi.org/10.5194/egusphere-egu2020-7517, 2020.

Aerosol particles have significant impacts on climate, air quality, and human health. Their characteristics are especially important in urban atmospheres during heat waves. Therefore, we conducted a 4-week measurement campaign at an urban kerbside in the city of Karlsruhe in southwest Germany during a heat wave period in July 2019. A high resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) was deployed in the container to measure non-refractory aerosol compositions of PM2.5 online. Filter samples were also collected during the campaign, and characterized for oxygenated organic molecular compounds using a chemical ionization mass spectrometer (FIGAERO-CIMS). In addition, a small box with low cost particle sensors and meteorological sensors (solar radiation, temperature, and humidity) was used for spatial resolved measurements employing a bicycle. During our measurement, the total organics, sulfate, nitrate, ammonium, chloride and black carbon contributed on average 58.9%, 17.3%, 5.9%, 5.5%, 0.2% and 12.3% to the particle mass comprising non-refractory components plus black carbon. Positive matrix factorization (PMF) analysis for the AMS organic aerosol (OA) data resolved three factors including hydrocarbon-like OA (HOA), semi-volatile oxygenated OA (SV-OOA) and low-volatility oxygenated OA (LV-OOA). Meteorological effects on aerosol compositions were investigated. Low wind speeds during the whole campaign correspond to major contributions from local emissions. During heat waves, high temperature and low humidity suppressed the formation of nitrate, but facilitated the formation of sulfate and organics. In particular, SV-OOA and LV-OOA showed positive correlations with temperature. The ratios of LV-OOA to SV-OOA strongly correlated with temperature and odd oxygen (Ox = O3 + NO2), suggesting fast photochemical transformation of SV-OOA to LV-OOA during heat waves. Furthermore, the relationships between organic aerosol factors and typical organic markers were investigated to study the relative influences of biogenic and anthropogenic emissions on OA formation. Besides, bicycle measurements point to important hot spots of particle pollution. This contribution will discuss the interaction of urban air pollution and heat islands.

How to cite: Song, J., Gao, L., and Saathoff, H.: Characteristics of PM2.5 aerosol particles during a heat wave in an urban atmosphere in southwest Germany, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7257, https://doi.org/10.5194/egusphere-egu2020-7257, 2020.

EGU2020-2146 | Displays | AS3.22

Distinct particle properties between ultrafine and accumulation modes under clean and polluted urban environments

Yuying Wang, Zhanqing Li, Renyi Zhang, Xiaoai Jin, and Qiuyan Wang

In this study, we report a phenomenon of fast changing in aerosol hygroscopicity between clean and pollution periods observed frequently in urban Beijing during winter using a hygroscopicity tandem mobility analyzer (H-TDMA). The cause of this phenomenon and the formation process of particles in different modes are discussed. During clean periods, ultrafine mode particles (Nucleation and Aitken modes) mainly stem from nucleation events with subsequent growth. During heavy pollution periods, they originate chiefly from primary emissions. Coarser-mode particles like accumulation mode particles are mainly from primary emission during clean periods and aqueous reactions during pollution periods. This finding based on H-TDMA measurement can make up the deficiency of mass-dependent instruments in analyzing sources and chemical processes of ultrafine mode particles.

How to cite: Wang, Y., Li, Z., Zhang, R., Jin, X., and Wang, Q.: Distinct particle properties between ultrafine and accumulation modes under clean and polluted urban environments, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2146, https://doi.org/10.5194/egusphere-egu2020-2146, 2020.

EGU2020-12478 | Displays | AS3.22

Size-segregated ions and carbonaceous fractions of ambient aerosol in Bogota

Lady Mateus, Kelly Burbano, Rodrigo Jimenez, and Nestor Rojas

Elemental and Organic Carbon (EC/OC) make up a significant fraction of particulate matter emitted by combustion process and water-soluble ions provide an important information about the origin of ambient aerosols. The sized-segregated chemical characterization of ambient aerosol is useful to understand its sources and formation mechanisms and complements well the information obtained from the bulk aerosol composition. Previous studies in Bogota determined the chemical composition and source contribution of PM10 in Bogota, as well as the temporal and spatial variability of polycyclic aromatic hydrocarbons (PAH) in the same city. However, the size-segregated chemical composition of ambient particles has not been studied in Colombian cities. This work aims to better understand the variability of size-segregated PM chemical composition in Bogota, one of the main Latin American megacities. Eight sets of samples were collected using an Andersen 8-stage cascade impactor in the southwest area of the city, where the highest concentrations of PM2.5 usually occur, over two periods in 2018. The concentration of OC/EC and ions (ammonium, sodium, potassium, magnesium, calcium, chloride, nitrate, sulfate and oxalate) were quantified. The average PM1 concentration was 30.3 mg/m3 (75% of PM2.5). The mass size distribution was bimodal, with a coarse mode between 5.8 and 4.7 mm aerodynamic diameter and an accumulation mode between 0.43 and 0.65mm. Most of the mass (75%) of PM1 consists of carbonaceous species, being EC the main constituent. The main inorganic ions in PM1 were sulfate, nitrate and ammonium. These and other results from this work will contribute to the validation of models within the PAPILA (Prediction of Air Pollution In Latin America and the Caribbean) project, funded by the EU MSCA action for research and innovation staff exchange (GA 777544).

How to cite: Mateus, L., Burbano, K., Jimenez, R., and Rojas, N.: Size-segregated ions and carbonaceous fractions of ambient aerosol in Bogota, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12478, https://doi.org/10.5194/egusphere-egu2020-12478, 2020.

Brc Carbon is a class of light-absorbing organic species, playing important roles on solar radiation budget and therefore influences climate forcing over regional and even global scales. We analyzed and evaluated the light absorption and radiative forcing of BrC in Chongqing, Wanzhou (Three Gorges Reservoir region), and Chengdu in the Sichuan Basin of Southwest China. The light-absorbing properties were evaluated, including mass absorption efficiency, absorption Ångström exponent, and contributions to radiative forcing. The sources of BrC are also identified, including the contribution of secondary aerosol formation and primary emissions. This study contributes to the understandings of sources and the impact of brown carbon in the Sichuan Basin, southwestern China.

How to cite: Chen, Y.: Characterization and light absorption of Brown Carbon in Sichuan Basin, Southwestern China: Impacts of biomass burning and secondary formation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12517, https://doi.org/10.5194/egusphere-egu2020-12517, 2020.

EGU2020-12845 | Displays | AS3.22

Classification of precursory weather patterns prior to high PM10 events over the Korean Peninsula

Ho-young Ku, Baek-min Kim, and Wonsik Choi

In this study, we investigated precursory regional weather patterns prior to the high PM10 events over Korean Peninsula. The criterion for high-concentration PM10 events was set at 150 ug/m3 per day, referring to the “bad” among air environmental standards. In order to examine the regional weather pattern prior to the high PM10 events, the pressure fields of upper-level and lower-level were simply synthesized expecting the existence of clear signature of stagnant weather pattern. However, the resulting patterns were statistically insignificant around East Asia. We further investigated a possibility of existence of multiple precursory patterns partly offsetting each other.  Through the synoptic analysis of each case, we found that precursory weather patterns can be easily partitioned as two groups: 1) pre-existing persistent ridge and 2) Decaying east Asian cold-surge. In the case 1), persistent ridge embedded in an overall positive AO pattern sustains over East Asia both before and after the high PM10 event causing long-term accumulation of fine dusts over Korean Peninsula. In this case, warm surface temperature dominates before and after the high PM 10 event. In the case 2), upper-level trough over east Asia rapidly moves eastward along with cold-surge evolution and stagnant high pressure system sits in over Korean peninsula just after the timing of high PM event. Surface temperature suddenly changes from cold to warm dramatically.

How to cite: Ku, H., Kim, B., and Choi, W.: Classification of precursory weather patterns prior to high PM10 events over the Korean Peninsula, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12845, https://doi.org/10.5194/egusphere-egu2020-12845, 2020.

EGU2020-18479 | Displays | AS3.22

Aerosol sources identification in Kaunas city using stable carbon isotope and polycyclic aromatic hydrocarbons analysis

Andrius Garbaras, Inga Garbariene, Agne Masalaite-Nalivaike, Darius Ceburnis, Edvinas Krugly, Vidmantas Remeikis, and Dainius Martuzevicius

The main idea of this research was to combine carbon stable isotope ratio (δ13C) analysis and polycyclic aromatic hydrocarbons (PAH) diagnostic ratios for the identification of pollution sources in Kaunas city, Lithuania. Aerosol particle sampling was performed in wintertime simultaneously in outdoor and indoor environments using cascade impactors.

Due too low mass not all impactors stages were analysed, especially in the indoor environment. It was determined that total carbon concentrations were higher in outdoor samples in the most cases. The outdoor δ13C values varied from -27.5 to -24.5 ‰. The indoor δ13C values varied from -28.5 to -25.8 ‰ and were close to δ13C values reported for biomass burning [1].

δ13C and PAH analysis revealed that main aerosol sources were biomass combustion and traffic emissions. Also coal combustion was identified as common source for aerosol particles in one location.

 

[1] A. Garbaras et al., “Stable carbon fractionation in size-segregated aerosol particles produced by controlled biomass burning,” J. Aerosol Sci., 2015.

How to cite: Garbaras, A., Garbariene, I., Masalaite-Nalivaike, A., Ceburnis, D., Krugly, E., Remeikis, V., and Martuzevicius, D.: Aerosol sources identification in Kaunas city using stable carbon isotope and polycyclic aromatic hydrocarbons analysis, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18479, https://doi.org/10.5194/egusphere-egu2020-18479, 2020.

EGU2020-19816 | Displays | AS3.22

Aerosol size distribution and metal constituents in three sites in Bangkok

James Matthews, Panida Navasumrit, Krittinee Chaisatra, Chalida Chompoobut, Matthew Wright, Mathuros Ruchirawat, and Dudley Shallcross

Airborne particulate matter is known to be deleterious to human health and exceeds exposure limits in many large cities. Some heavy metals and metalloids are known carcinogens and have been measured as constituents of PM in Bangkok air. There is growing interest in the sub-micron and ultrafine (< 100 nm) fractions due to their deeper penetration in the lung. Identifying distribution of metals over the size range can provide information on the metals source as well as providing information on the likely exposure to those particles.

Three sites, owned and managed by the Thailand Pollution Control Department, were identified to provide contrasting particulate samples in a measurement campaign during 2018. The Ayutthaya site was located within the grounds of a school, 80 km to the north of Bangkok. The site was chosen as concentrations due to city traffic would be lower and could be considered a reference site. The Bang Phli site was situated in an industrial area 50 km to the south-east of Bangkok, in an area near industry. The Chok Chai site was in central Bangkok near to a busy road.

At each site, three 3-day weekend and 3-day weekday gravimetric samples of size differentiated mass were drawn using an Electrical Low Pressure Impactor (ELPI; Dekati, Finland) over 12 size fractions in six different study visits. These were chosen to enable three measurements over the rainy season and three in the dry season. Each size fraction was weighed and then analysed by inductively coupled plasma mass spectroscopy to find the concentration of 17 elements (Mg, Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Mo, Cd, Sb, Ba and Pb). The ELPI also measured particle number concentration at 1 Hz. 

The number concentration of aerosol was highest in the Chok Chai roadside site, and lowest in the Ayutthaya background site. Al concentration was the highest in all three locations, with an average concentration over all measurements of 1909, 1012 and 1576 ng m-3 in Ayutthaya, Bang Phli and Chok Chai respectively. Concentrations of Al, Cr, Mg and Fe were typically higher than 100 ng m-3 in all sites, Cu and Zn higher than 10 ng m-3 and the rest lower.

The shape of the metal distributions was consistent across all three sites for specific metals. Mg, Al, Cr, Mo, Ni and Cu could be described as having a flat distribution across all measured size distributions V, Mn, Cd, Sb, Pb, Zn As and Se had a peak in the sub-micron range, while Fe, Ba and Co peaked above 1 µm.

Some seasonal effects could be seen across all three locations, these included an increase in Al, Cr and Fe during four measurements in dry season (November, 2018). This was particularly observed at Ayutthaya, where total measurements of Al were between 4862 and 5961 ng m-3, when all other measurements were between 98 and 264 ng m-3, suggesting a strong local source.

How to cite: Matthews, J., Navasumrit, P., Chaisatra, K., Chompoobut, C., Wright, M., Ruchirawat, M., and Shallcross, D.: Aerosol size distribution and metal constituents in three sites in Bangkok , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19816, https://doi.org/10.5194/egusphere-egu2020-19816, 2020.

Severe wintertime PM2.5 pollution in Beijing has been receiving increasing worldwide attention, yet the decadal variations remain relatively unexplored. Combining field measurements and model simulations, we quantified the relative influences of anthropogenic emissions and meteorological conditions on PM2.5 concentrations in Beijing overwinters of 2002-2016. Between the winters of 2011 and 2016, stringent emission control measures resulted in a 21% decrease in mean mass concentrations of PM2.5 in Beijing, with 7 fewer haze days per winter on average. Given the overestimation of PM2.5 by model, the effectiveness of stringent emission control measures might have been slightly overstated. With fixed emissions, meteorological conditions over the study period would have led to an increase of haze in Beijing, but the strict emission control measures have suppressed the unfavorable influences of recent climate. The unfavorable meteorological conditions are attributed to the weakening of the East Asia Winter Monsoon associated particularly with an increase in pressure associated with the Aleutian low.

How to cite: Gao, M., Lin, K., Zhang, S., and Yung, K. K. L.: China’s emission control strategies have suppressed unfavorable influences of climate on wintertime PM2.5 concentrations in Beijing since 2002, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6424, https://doi.org/10.5194/egusphere-egu2020-6424, 2020.

AS3.23 – Impacts of emissions from major population centres on tropospheric chemistry and composition

EGU2020-19474 | Displays | AS3.23

EMeRGe - the Effect of Megacities on the transport and transformation of pollutants on the Regional and Global scales

John P. Burrows, Maria D. Andrés Hernández, Mihalis Vrekoussis, Charles C.-K. Chou, Pao K. Wang, Hans Schlager, Helmut Ziereis, Andreas Zahn, Johannes Schneider, Klaus Pfeilsticker, Ulrich Platt, and Yugo Kanaya

At the industrial revolution (1750-1800), the population of the earth was around 1 Billion and less than 5% of population lived in urban areas. In 1950, when the population reached about 2.9 billion, there were two megacities New York/Newark and Tokyo. In 2020, the earth’s population is around 7.8 Billion, more than 50% live in urban areas and there are now approximately 38 around the world. Since 2007, more than 50% of the population live in urban areas and the earth’s population has now reached 7.8 Billion. Anthropogenic activity to sustain and feed MPC is now one of the most important sources of pollution, modifying atmospheric chemistry, air quality and climate.  To assess the impact of MPC emissions locally and regionally requires knowledge of the transport and transformation of the MPC plumes. The EMeRGe project was proposed to address this need and investigate the transport and transformation of the chemical composition of MPC plumes. Secondary objectives include the improvement of our understanding of the impact of biomass burning, which mixes with the plumes from MPC. EMeRGe selected European and Asian MPC as targets, where the regulations on emissions are significantly different.

EMeRGe assumes that the nature of the local emissions, the meteorology and photochemistry/chemistry determines the transport and transformation of the plumes from MPCs. To test this hypothesis, the following scientific questions are addressed:
a) which transport and dispersion processes dominate the MPC outflows in Europe and Asia during the selected measurement periods;
b) which oxidation or other processes determine the chemical transformation of MPC emissions;
c) what are the regional impacts of the emission by the selected European and Asian MPCs;
d) what is the relevance of emission from European and Asian MPCs for radiative forcing and climate change;
e) do our chemical models adequately simulate of transport and transformation processes of European and Asian MPC outflows.

An integrating focus of EMeRGe were the measurement campaigns exploiting the capabilities of the German HALO research were undertaken during EMeRGe, which investigated the outflow from: i) European MPCs in July 2017; ii) MPCs in East and South East Asia during March and April 2018. In addition to the HALO aircraft measurements, the EMeRGe International scientists contributed studies of the measurement from instrumentation from ground based, airborne and satellite platforms. For example in EMeRGe in Europe the UK NERC FAAM (https://nerc.ukri.org/research/sites/facilities/aircraft/) "ERA - CNR - ISAFOM" (https://www.eufar.net/aircrafts/44) were deployed to make measurements around London and Rome respectively. In EMeRGe in Asia, measurement were made ground based and Lidar measurements were made by EMeRGe partners from Taiwan, Japan, the Philippines, Thailand and China. EMeRGe benefited from the support by iCACGP (international Commission on Atmospheric Chemistry and Global Pollution). This presentation will provide an overview of the objectives, the planning, the measurements and some highlights from the EMeRGe HALO campaigns.

 

How to cite: Burrows, J. P., Andrés Hernández, M. D., Vrekoussis, M., Chou, C. C.-K., Wang, P. K., Schlager, H., Ziereis, H., Zahn, A., Schneider, J., Pfeilsticker, K., Platt, U., and Kanaya, Y.: EMeRGe - the Effect of Megacities on the transport and transformation of pollutants on the Regional and Global scales , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19474, https://doi.org/10.5194/egusphere-egu2020-19474, 2020.

Taiwan is a subtropical island with an area of only about 36,000 km2 and yet packed with high density of mountains. There are 268 peaks that are taller than 3000 m in elevation and, as a result, the mountains are extremely rugged. Such rugged orography will certainly have great influence on the local circulation and consequently impact on the transport of air pollutants. It is thus necessary to understand the impact of the orography on air flow before we can interpret the measured data during the EMeRGe-Asia campaign in March-April 2018 correctly.

For the above purpose, we performed high resolution numerical simulations of the flow around Taiwan region for two cases using the Weather Research and Forecast (WRF) model. The first one is a highly stagnant case where Taiwan was under the influence of a high pressure system occurring on 10 November 2018. Two horizontal resolutions are used: 1 km and 2 km, both show very similar flow and cloud patterns as revealed by satellite images of the day. Detailed analysis of the simulated results including the flow pattern and isentropic analysis will be shown to illustrate that low level pollutants can be transported upward to at least 1 km altitude even under such calm weather.

The second one is the 20 March 2018 case which occurred during the EMeRGe-Asia campaign. Unlike the above stagnant case, this was a more turbulent situation when a typhoon was approaching from the east and a southerly flow carried air pollutants from SE Asia. The 1 km resolution simulation shows good match with satellite observation. The simulation results show a substantial concentration of VOC at ~ 3000 m altitude near Taiwan whereas the VOC was very low near the surface. The model reproduces this feature well and hence it appears that the model’s predictions are credible. More detailed analyses are being performed and comparison of the results with combined ground and aircraft observations to illustrate the impact of the orography on the transport of pollutants.  

How to cite: Wang, P. K. and Lin, C.-Y.: The Impact of Taiwan’s Rugged Orography on Air Pollutant Transport and the Numerical Modeling of 20 March 2018 Case, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19122, https://doi.org/10.5194/egusphere-egu2020-19122, 2020.

EGU2020-16820 | Displays | AS3.23

Air mass characterization based on VOC measurements downstream of European and Asian Major Population Centers (MPC) during the research aircraft campaign EMeRGe (2017/2018)

Eric Förster, Harald Bönisch, Marco Neumaier, Florian Obersteiner, Michael Lichtenstern, Andreas Hilboll, Anna B. Kalisz Hedegaard, Mihalis Vrekoussis, and Andreas Zahn

EMeRGe (Effect of Megacities on the Transport and Transformation of Pollutants on the Regional to Global Scales) aims to investigate the impact of MPC emissions on air pollution and chemical processing at local, regional and hemispheric scales by making dedicated airborne measurements using the German research aircraft HALO. Transects and vertical profiling for diverse MPCs (e.g. Rome, London, Taipei, Manila) were performed to determine the composition and transformation of various pollution plumes in Europe and Asia.

To characterize air masses we evaluate different volatile organic compounds (VOCs), measured by a Proton-Transfer-Reaction Mass Spectrometer (PTR-MS), with different or similar sources and different lifetimes. We use the specific tracer acetonitrile to identify air masses influenced by biomass burning (BB), the aromatic compound benzene to tag anthropogenic pollution plumes (e.g. from traffic or industry) and short-lived isoprene as indicator for fresh biogenic influences. Back trajectories based on FLEXTRA (FLEXible TRAjectory model) are used to determine potential source regions of BB affected air and anthropogenic pollution plumes.

Results show that in Europe only minor BB influenced air masses were sampled. However, in Southern France fresh BB close to the source was detected. In contrast to Europe, numerous plumes affected by BB were identified in Asia originating mostly from Southeast Asia.

Air masses with enhanced concentrations in benzene and low concentrations in acetonitrile, indicating anthropogenic pollution, were sampled in Europe over the Po-Valley, Rome, Barcelona and the English Channel. In Asia, plumes were identified along the west coast of Taiwan, the East China Sea and Manila originating from local sources as well as transported from Mainland China.

Significant fresh biogenic influence was found in Europe, as the measurements were performed mostly in summer over land in contrast to Asia were just a minor influence was detected.

How to cite: Förster, E., Bönisch, H., Neumaier, M., Obersteiner, F., Lichtenstern, M., Hilboll, A., Kalisz Hedegaard, A. B., Vrekoussis, M., and Zahn, A.: Air mass characterization based on VOC measurements downstream of European and Asian Major Population Centers (MPC) during the research aircraft campaign EMeRGe (2017/2018), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16820, https://doi.org/10.5194/egusphere-egu2020-16820, 2020.

EGU2020-7597 | Displays | AS3.23

Stable Carbon Isotope Ratios in Atmospheric VOC during the EMeRGe-EU and ASIA campaigns

Marc Krebsbach and Ralf Koppmann

VOC (volatile organic compounds) play a critical role in the chemistry of the atmosphere. The formation of many important secondary pollutants in the atmosphere, such as ozone, peroxides, aldehydes, and peroxyacyl nitrates and secondary organic particulate matter depends critically on the availability of VOC as their precursors. Many of them have strong direct adverse effects on our environment. The assessment of the impact of VOC on the atmosphere can be significantly improved by measuring their stable carbon isotope ratios. The isotopic composition of compounds emitted by natural or anthropogenic activities vary for emissions from different sources. In almost all atmospheric processes, e.g. chemical reactions, photolytic processes, transport and dilution, diffusion, and phase transitions, the isotopic ratio in VOC is altered. Studying the isotope ratios of both precursors and products makes it possible to distinguish between freshly emitted VOC and photochemically processed compounds, to increase our knowledge of transport versus chemistry, to study the ultimate fate of oxidation products, and to help assess the impact of emissions, e.g. from large population centres (MPCs), on local, regional and even global pollution.
The automated high volume air sampling system MIRAH has been deployed during several missions with the German High Altitude – Long-range research aircraft (HALO). Here we focus on the campaigns EMeRGe-EU and -ASIA (Effect of Megacities on the transport and transformation of pollutants on the Regional and Global scales). The objectives were to measure the pollution emitted, transported and transformed from the MPCs London, BeNeLux, Rhine-Ruhr and Po Valley for the European Part. The second part of EMeRGe was conducted from Taiwan with the goal to investigate the pollution outflow from Asian MPCs such as Taipei, Hongkong, Shanghai, Beijing, Manila, Seoul and Tokio. In both parts a key experiment was the identification of the source of the air masses by collecting whole air samples on ground prior and during particular flights in specific metropolitan regions. On 7 flights in Europe and 12 flights in Asia, mostly below 6 km altitude, more than 140 air samples were collected on HALO during each campaign, and additional 46 samples at specific ground sides. The whole air samples were analysed for mixing ratios and stable carbon isotope ratios of selected aldehydes, ketones, alcohols, and aromatics. This allowed investigating air masses of different origin, characteristic, and atmospheric processing. In this presentation we will give an overview of the data and show exemplary results.


This work was supported by the German Research Foundation (Deutsche Forschungsgemeinschaft, DFG Priority Program SPP 1294) under grant-No. KR3861/1-1.

How to cite: Krebsbach, M. and Koppmann, R.: Stable Carbon Isotope Ratios in Atmospheric VOC during the EMeRGe-EU and ASIA campaigns, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7597, https://doi.org/10.5194/egusphere-egu2020-7597, 2020.

EGU2020-18635 | Displays | AS3.23

Investigation of the photochemical activity in different MPC outflows during EMeRGe

Midhun George, Maria Dolores Andrés Hernández, Yangzhuoran Liu, Vladyslav Nenakhov, John Philip Burrows, Birger Bohn, Eric Förster, Andreas Zahn, Hans Schlager, Helmut Ziereis, Benjamin Schreiner, and Klaus Pfeilsticker

Since peroxy radicals are closely involved in a number of tropospheric chemical processes like O3 budget, hydrocarbon oxidation and acid formation, the accurate measurement of these radicals can provide essential information to improve our understanding of processing and transformation of polluted outflows from megacities and Major Population Centres (MPCs).

Airborne measurements of the total sum of peroxy radicals, RO2*  = HO2 + ∑ RO2, where R is an organic group, were conducted in Europe in summer 2017 and in East Asia in spring 2018 within the EMeRGe (Effect of Megacities on the Transport and Transformation of Pollutants on the Regional to Global Scales) project by using the PeRCEAS instrument (Peroxy Radical Chemical Enhancement and Absorption Spectrometer), on board of the HALO research aircraft (www.halo.dlr.de).

Over the course of both measurement campaigns different MPC outflows were investigated including among others, London, Rome, Manila and Taipei. Polluted air masses of different origin and composition were probed. Overall the peroxy radical mixing ratios were of the same order of magnitude in the air masses probed in Europe and in East Asia. The variations in the photochemical activity were studied by taking into account simultaneous observations of radical precursors and photolysis rates, while applying known oxidation mechanisms. Radical precursors, photolysis rates and aerosol load were generally higher in Asia, which might indicate higher radical loss reactions on the aerosol surface than in Europe. Moreover this study shows a clear deviation in the photostationary state for MPC outflows close to the emission sources. Based on this information, this presentation will focus on the actual understanding of the photochemical processing in the probed air masses.

How to cite: George, M., Andrés Hernández, M. D., Liu, Y., Nenakhov, V., Philip Burrows, J., Bohn, B., Förster, E., Zahn, A., Schlager, H., Ziereis, H., Schreiner, B., and Pfeilsticker, K.: Investigation of the photochemical activity in different MPC outflows during EMeRGe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18635, https://doi.org/10.5194/egusphere-egu2020-18635, 2020.

EGU2020-13607 | Displays | AS3.23

Aircraft measurements of nitrous acid in excess of model predictions in the boundary layer and free troposphere

Benjamin Schreiner, Klaus Pfeilsticker, Flora Kluge, Meike Rotermund, Andreas Zahn, Helmut Ziereis, Birger Bohn, Johannes Schneider, Katharina Kaiser, Andrea Pozzer, and Mariano Mertens

Middle and long-term  photo-chemical effects of local and regional pollution are not well quantified and are an area of active study. NOx (here defined as NO, NO2, and HONO) is a regional pollutant, which influences atmospheric oxidation capacity and ozone formation. Airborne measurements of atmospheric trace gases from the HALO (High Altitude Long Range) aircraft, particularly of NO, NO2, and HONO were performed as part of the EMeRGe (Effect of Megacities on the Transport and Transformation of Pollutants on the Regional to Global Scales) campaign over continental Europe and southeast Asia in July 2017 and April 2018, respectively. NO (and NOY), O3, and the photolysis frequencies of NO2 and HONO were measured in-situ. NO2 and HONO were inferred from Limb measurements of the mini-DOAS (Differential Optical Absorption Spectroscopy) instrument, using the novel scaling method (Hüneke et al., 2017). These measurements were compared with simulations of the MECO/EMAC models. In relatively polluted air-masses in the boundary layer and free troposphere, HONO measured in excess of model predictions (and previous measurements) suggests an in-situ formation and a significant source of OH as well as a pathway for re-noxification. Aerosol composition simultaneously measured  by the C-Tof-AMS instrument may reveal potential reaction mechanisms to explain the discrepancy. 

How to cite: Schreiner, B., Pfeilsticker, K., Kluge, F., Rotermund, M., Zahn, A., Ziereis, H., Bohn, B., Schneider, J., Kaiser, K., Pozzer, A., and Mertens, M.: Aircraft measurements of nitrous acid in excess of model predictions in the boundary layer and free troposphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13607, https://doi.org/10.5194/egusphere-egu2020-13607, 2020.

Today, the majority of humanity lives in urban areas. Accordingly, major population centers are a significant source of a multitude of atmospheric emissions from human activity such as traffic, heating, industry or power generation. Pollutants directly impact the local inhabitant's health, but are also transported to neighbouring areas, undergo chemical evolution and can have an impact on climate. To understand and assess effective measures for reducing the effects, it is important to determine the source locations and strengths as well as relevant chemical processes.

Aircraft-based measurements can cover the gap between long-term ground-based and globe-covering satellite instruments with its high temporal and spatial coverage during flight time. Remote sensing methods in particular allow a fast and wide-spread probing of atmospheric trace gas distributions. Within this context, the HAIDI (Heidelberg Airborne Imaging DOAS Instrument) instrument was designed to provide data of extremely high temporal and spatial resolution (40m x 40m at 1.5 km flight altitude, 266m x 266m at 10 km flight altitude, at 10 ms temporal resolution) in 2D and 3D during overflight.

During the EMeRGe (Effect of Megacities on the Transport and Transformation of Pollutants on the Regional to Global Scales) missions HAIDI was part of the comprehensive set of measurement equipment installed on the research airplane HALO (High Altitude and LOng range re-search aircraft) of the DLR (German Aerospace Center). The EMeRGe missions targeted the emission outflows of megacities to investigate their compositions and the atmospheric impact of urban pollution. One mission part was conducted in Europe (July 2017) and aimed at areas around Paris, London, the Po area, Madrid and the Benelux area. For contrast, the second mission part was based in Taiwan (March 2018) and investigated Taiwan cities, Bangkok, Manila, Japanese cities and China outflow.

HAIDI derived a number of trace gases such as NO2, SO2, BrO and HCHO. Due to large concentrations present, for NO2 and SO2 in particular it was possible to obtain high-resolution 2D data of megacity areas and plumes of megacities, powerplants and ships and estimate their emissions. We will present results of the HAIDI measurements during the EMeRGe mission.

How to cite: Bigge, K., Pöhler, D., Frieß, U., and Platt, U.: Aircraft-based 2- and 3D Trace Gas Measurements with HAIDI (Heidelberg Airborne Imaging DOAS Instrument) - Results of the EMeRGe Missions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1093, https://doi.org/10.5194/egusphere-egu2020-1093, 2020.

EGU2020-17372 | Displays | AS3.23

Exploring NOx Emission from the Ground and the Air in London, UK

Will Drysdale, Adam Vaughan, Freya Squires, Beth Nelson, Joseph Pitt, Stefan Metzger, David Durden, Natchaya Pingintha-Durden, Sue Grimmond, Ruth Purvis, and James Lee

NOx (the sum of NO + NO2) is emitted during most combustion processes. NO2 is a well-known air pollutant detrimental to human health, critical in the formation of tropospheric ozone and its concentration is regulated in many cities. London is a megacity which often finds itself in breach of these air quality regulations. Emission inventories are used in air quality forecast models to predict current and future air pollution levels and to guide abatement strategy. The National Atmospheric Emissions Inventory (NAEI) has been shown to underestimate NOx emission in London (Lee et al. 2012, Vaughan et al. 2016). Top down measurements allow assessment of emissions help understand the difference between measurement and model.

During March – June 2017 NOx emissions were measured using the eddy covariance method sampling from a height of 180 m at the British Telecom (BT) tower in Central London. In July of 2017 measurements of NOx by the UK’s Facility for Airborne Atmospheric Measurement (FAAM) were made as a part of the Effect of Megacities on the Transport and Transformation of Pollutants on the Regional to Global Scales (EMeRGe). A mass balance approach (after O’Shea et al. 2014 and Pitt et al. 2019) has been applied to these measurements producing a measurement of bulk emission of NOx from Greater London and surrounding areas.

Through comparison of these measurements with the NAEI we present an exploration of NOx emission from London and assess how this is captured in the emissions inventory.

 

Lee et al., Environmental Science & Technology, 2015, 49, 1025-1034

Vaughan et al., Faraday Discussions, 2016, 189, 455-472

O’Shea et al., J. Geophys. Res. Atmos., 2014, 119, 4940–4952

Pitt et al., Atmos. Chem. Phys., 2019, 19, 8931-8945

How to cite: Drysdale, W., Vaughan, A., Squires, F., Nelson, B., Pitt, J., Metzger, S., Durden, D., Pingintha-Durden, N., Grimmond, S., Purvis, R., and Lee, J.: Exploring NOx Emission from the Ground and the Air in London, UK, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17372, https://doi.org/10.5194/egusphere-egu2020-17372, 2020.

EGU2020-6595 | Displays | AS3.23

Hourly elemental concentrations in ambient aerosols in four cities in Asia and Europe – comparison and source apportionment

Markus Furger, Pragati Rai, Jay G. Slowik, Sachchida N. Tripathi, Junji Cao, Jaroslaw Necki, Suzanne Visser, André S. H. Prévôt, and Urs Baltensperger

Megacities worldwide are suffering from elevated air pollution due, e.g., to continuously increasing urbanization, and a sizeable amount of the population in such areas is exposed to particulate matter (PM) concentrations exceeding the WHO limits. Huge efforts are therefore undertaken to characterize the air pollution situation and to reduce or mitigate the impact on the population and the environment. Modern instrumentation allows for a quantitative determination of aerosol concentration and composition with high time resolution (minutes to hours), and subsequent source apportionment.

We collected PM10 and PM2.5 aerosols alternatingly with an online X-ray fluorescence (XRF) spectrometer in the cities of New Delhi (India) in 2019, Beijing (China) in 2017, and Krakow (Poland) in 2018, with time resolutions from 30 to 120 min, and in London (UK) in 2012 with 3-stage rotating drum impactors and subsequent offline SR-XRF analysis. Campaigns lasted for two to seven weeks in fall and winter. Elements from Al to Bi were analyzed in near-real time, except for London.

Our results show that some of the cities experience episodic extreme events, whereas extremely high elemental concentrations are chronic in others. Toxic metals are shown to be strongly location-dependent, and may occur in extreme plumes. Meteorological conditions also play an important role and will be discussed. The regional influence of fine PM, in comparison to the more local origin of coarse PM will be evaluated. The differences among the four cities, with substantially higher concentrations in the Asian cities than the European ones will be discussed. Highly time-resolved size-segregated sampling allowed for a rough classification of elements into five groups and will be described in detail. We demonstrate that the use of size information on toxic elements, diurnal patterns of targeted emissions, and local vs. regional effects are advantageous for formulating effective environmental policies to protect public health.

How to cite: Furger, M., Rai, P., Slowik, J. G., Tripathi, S. N., Cao, J., Necki, J., Visser, S., Prévôt, A. S. H., and Baltensperger, U.: Hourly elemental concentrations in ambient aerosols in four cities in Asia and Europe – comparison and source apportionment, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6595, https://doi.org/10.5194/egusphere-egu2020-6595, 2020.

In wintertime, high background concentrations of atmospheric fine particulate matter (PM2.5) are commonly observed in the metropolitan area of Santiago, Chile. Although the frequency of alert events has been decreasing in the recent years, two short-lived peak events reaching up to 600µg/m3 for a few hours were observed in the city on June 18th and June 26th 2016, triggering emergency measures for the next day.

The observed meteorological conditions at the time of these peaks are not unusual. In addition, a high-resolution meteorology and chemistry-transport simulation with the WRF meteorological model and the CHIMERE chemistry-transport model reproduces fairly well the meteorology and levels of PM for June 2016, except for those two particular events that are not captured by the model. The combination of these elements leads to the conclusion that sporadic strong emissions are at play.

The analysis of recorded concentration ratios of PM2.5, NOx and CO points to a specific source, departing significantly from the average signal for the season. Based on the literature and HTAP emission ratios, usual sources of PM such as traffic, residential heating and industry can be ruled out. The temporal correlation of the events with soccer games of the Chilean team and the recorded chemical footprint lead to conclude to the dominant contribution of massive barbecue cooking at the peak times.

Following the source identification via surface stations analysis, the next question was to quantify the potential transport and impact of such pollution peaks in the Santiago Metropolitan area. An additional source term was added in the chemistry-transport simulation, and maps of PM changes were analyzed. For both events, the same region in the Southwest of Santiago was impacted by the plume.

A natural continuation of this work is the study through modeling of the dispersion patterns of polluted plumes outside of the Santiago basin on a longer time scale. In particular, significant deposition of light-absorbing particles has been measured on glaciers near the capital city, without a clear identification of their source or the underlying processes of transport.

How to cite: Lapere, R., Menut, L., Mailler, S., and Huneeus, N.: Combining air quality network data and chemistry-transport modeling for the attribution of extreme pollution events: a case study of Santiago, Chile, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3596, https://doi.org/10.5194/egusphere-egu2020-3596, 2020.

EGU2020-8430 | Displays | AS3.23

The emission and photochemistry of a large industrial facilities near megacities - a case study in South Korea

Saewung Kim, Anne Mielnik, Gracie Wong, Chinmoy Sarkar, and Alex Guenther

In this presentation, we will discuss the top down emission estimates of SO2 and volatile organic compounds using mass spectrometers integrated on a research aircraft with a fast-meteorological sensor. The study area is four coal power plants, one steel mill, and one petrochemical industrial facility, located in the Tae-ahn Peninsular in South Korea 50 km away from the southern tip of the Seoul Metropolitan Area. We conducted 20 research flights to closely monitor emissions from each facility.  We will present detailed analysis of instantaneous emission rates to verify emission inventories to proceed their impacts to regional air quality, particularly towards the Seoul Metropolitan Area with a population of 25 millions, using a semi-Lagrangian photochemical box model.

 

How to cite: Kim, S., Mielnik, A., Wong, G., Sarkar, C., and Guenther, A.: The emission and photochemistry of a large industrial facilities near megacities - a case study in South Korea, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8430, https://doi.org/10.5194/egusphere-egu2020-8430, 2020.

We carried out 14 days of Car MAX-DOAS experiments on the 6th Ring Rd of Beijing in January, September and October, 2014. The tropospheric vertical column densities (VCD) of NO2 are retrieved and used to estimate the emissions of NOx. The offline LAPS-WRF-CMAQ model system is used to simulate wind fields by assimilation of observational data and calculate the NO2 to NOx concentration ratios. The NOX emissions in Beijing for different seasons derived from Car MAX-DOAS measurements are compared with the multi-resolution emission inventory in China for 2012 (MEIC 2012), and impacts of wind field on estimated emissions and its uncertainties are also investigated. Results show that the NO2 VCD is higher in January than other two months and it is typically larger at the southern parts of the 6th Ring Road than the northern parts of it. Wind field has obvious impacts on the spatial distribution of NO2 VCD, and the mean NO2 VCD with south wind at most sampling points along the 6th Ring Rd is higher than north wind. The journey-to-journey variation pattern of estimated NOX emissions rates (ENOX) is consistent with that of the NO2 VCD, and ENOX is mainly determined by the NO2 VCD. In addition, the journey-to-journey ENOX in the same month is different and it is affected by wind speed, the ratio of NO2 and NOx concentration and the decay rate of NOX from the emission sources to measured positions under different meteorological condition. The ENOX ranges between 6.46×1025 and 50.05×1025 molec s-1. The averaged ENOX during every journey in January, September and October are respectively 35.87×1025, 20.34×1025, 8.96×1025 molec s-1. The estimated ENOX after removing the simulated error of wind speed and observed deviation of NO2 VCD are found to be mostly closer to the MEIC 2012, but sometimes ENOX is lower or higher and it indicates that the MEIC 2012 might be overestimate or underestimate the true emissions. The estimated ENOX on January 27 and September 19 are obviously higher than other journeys in the same month because the mean NO2 VCD and Leighton ratio during these two periods are larger, and corresponding wind speeds are smaller. Additionally, because south wind may affect the spatial distribution of mean NO2 VCD in Beijing which is downwind of south-central regions of Hebei province with high source emission rates, the uncertainty of the estimated ENOX with south wind will be increased.

How to cite: Cheng, X.: Quantification of NOX Emissions Based on Car MAX-DOAS Measurements over Beijing and Impacts of Wind Field, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12459, https://doi.org/10.5194/egusphere-egu2020-12459, 2020.

EGU2020-21005 | Displays | AS3.23

Characterization and Source Apportionment of Organic Aerosols in Delhi, India

Varun kumar, David Bell, Sophie Haslett, Deepika Bhattu, Yandong Tong, Stamatios Giannoukos, Suneeti Mishra, Atinderpal Singh, Pawan Vats, RV Satish Kumar, Urs Baltensperger, Dilip Ganguly, Neeraj Rastogi, Claudia Mohr, Sachchida N. Tripathi, Andre S.H. Prevot, and Jay G. Slowik

Delhi is one of the world’s most polluted city and experiences very high levels of particulate matter throughout the year. It significantly affects radiative forcing, increases mortality, and causes other deleterious effects on human health. Generally, there is a lack of consensus on the dominant sources of organic aerosol driving these high aerosol concentrations. In particular, there is a need to elucidate the relative importance of primary vs. secondary sources and formation mechanisms of secondary aerosols. In order to answer questions pertaining to the sources, formation mechanisms, and atmospheric transformations of organic aerosol, we deployed for the first time in Delhi, the recently developed extractive electrospray ionization long-time-of-flight mass spectrometer (EESI-TOF) in Delhi. This was deployed along with a high-resolution long-time-of-flight aerosol mass spectrometer (AMS), and a Chemical Ionisation Mass Spectrometer fitted with a Filter Inlet for Gases and AEROsols (FIGAERO-CIMS). These measurements were further supported by measurements of black carbon and gaseous species such as CO, NOx etc.

The EESI-TOF provides in real-time information on the chemical composition at the near-molecular level without thermal desorption and fragmentation (Lopez-Hilfiker et al., 2019). It was operated in Delhi from December to February 2019. Measurements by the AMS showed persisting high levels of particulate matter. We attributed the relative contributions of different sources to total non-refractory PM mass by performing source apportionment analysis by means of positive matrix factorization (PMF). A strong day-night variability was clearly seen in all the AMS species. High levels of secondary sources during daytime e.g., low-volatility oxygenated organic aerosol (LVOOA) and an increase of factors associated with primary sources i.e., hydrocarbon-like organic aerosol (HOA) and aerosol from solid fuel combustion (SFC) during morning and evening hours was observed. A similar trend as for the primary aerosol was seen for the semi-volatile oxygenated organic aerosol (SVOOA) mainly due to increased temperature during daytime which may leads to evaporation of semi-volatile species. A unique feature observed was a significant contribution of chloride to the non-refractory (NR) PM2.5 mass. On average, chloride contributed 18-20% to total NR-mass. Similar trends have also been seen in a recent study (Gani et al., 2018). The effect of these high chlorine concentrations during the night and early morning on atmospheric chemistry as well as on secondary organic aerosol formation will be presented.

How to cite: kumar, V., Bell, D., Haslett, S., Bhattu, D., Tong, Y., Giannoukos, S., Mishra, S., Singh, A., Vats, P., Kumar, R. S., Baltensperger, U., Ganguly, D., Rastogi, N., Mohr, C., Tripathi, S. N., Prevot, A. S. H., and Slowik, J. G.: Characterization and Source Apportionment of Organic Aerosols in Delhi, India, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21005, https://doi.org/10.5194/egusphere-egu2020-21005, 2020.

Black and brown carbon (BC and BrC) are potent climate forcing agents with pronounced effects on global climate and tropospheric chemistry. Given the large heterogeneities in BC emission inventories from India and the paucity of studies on BrC characteristics, field-based measurements of BC and BrC sources and optical properties are essential to understand their impacts on regional climate. To address this issue, we report the first ground-based measurements of BC and BrC from a rural location in the highly polluted eastern Indo-Gangetic Plain (IGP) during May-November 2018 encompassing the photochemistry-dominated summer (May-June) and regional biomass burning (BB)-dominated post-monsoon (October-November) periods. A 7-wavelength Aethalometer was used for time-resolved measurements of BC mass and was supplemented by UV-Vis and fluorescence measurements of time-integrated (24 h) aqueous and organic BrC fractions, and measurements of OC, EC, WSOC, and ionic species.
The daily averaged BC increased 4 times during the BB regime (12.3 ± 3.9 μg m-3) as compared to summer (4.2 ± 0.8 μg m-3), while aqueous and organic BrC fractions demonstrated light absorption (babs_365) enhancements of 3-5 times during BB. For aqueous BrC, the averaged AE of 5.9-6.2 and a prominent fluorescence peak at ~420 nm suggested the presence of humic-like substances (HULIS), potentially from secondary photochemical formation during summer and primary emission during BB periods. Fluorescence and UV-Vis spectra also indicated the presence of nitroaromatic compounds, presumably from OH oxidation in summer and nighttime NO3- oxidation in the presence of enhanced NOx and precursor emission during BB. The latter was supported by the strong association between water-soluble organic carbon (WSOC; a proxy for aqueous BrC) and aerosol NO3- (r=0.70, p<0.05). During BB, the fraction of water-insoluble (i.e., organic) BrC increased from 41% at 330 nm to 59 % at 550 nm while during the photochemistry-dominated summer period, the water-insoluble BrC fraction decreased from 73% at 400 nm to 41% at 530 nm, possibly due to photobleaching in the presence of OH. The BB-related BrC aerosol was also characterized by higher aromaticity and increased molecular weights of organic components as evidenced by mass absorption efficiency (MAE) ratios (MAE250/MAE365). Overall, this study established that BrC is a significant component of light-absorbing aerosol in the eastern IGP and that BrC optical properties may vary significantly in this region depending on the relative dominance of aerosol emissions and atmospheric processes.

How to cite: Rana, A., Dey, S., and Sarkar, S.: Optical properties of atmospheric brown carbon (BrC) for photochemical and biomass burning-dominated aerosol regimes in India., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-611, https://doi.org/10.5194/egusphere-egu2020-611, 2020.

EGU2020-9426 | Displays | AS3.23

Modeling of Southeast Asia biomass burning pollutants to Taiwan during EMeRGe campaigns in Asia

Chuan-yao Lin, Wan-chin Chen, Yang-fan sheng, Win-Mei Chen, and Yi-Yun Chien

In springtime happens to be the biomass burning season in Indochina. Under favor weather conditions, the products of biomass burning pollutants could be transported easily to Taiwan and even East Asia. Actually, the complex interactions of these air pollutants and aerosols features in the boundary layer and aloft have resulted in complex characteristics of air pollutants and aerosols distributions in the lower troposphere. The project “Effect of Megacities on the transport and transformation of pollutants on the Regional and Global scales (EMeRGe)” aims to improve our knowledge and prediction of the transport and transformation patterns of European and Asian megacities pollutant outflows. During the EMeRGe campaign in Asia, the composition of the plumes of pollution entering and leaving Asia measured by the new High Altitude and LOng Range (HALO) aircraft research platform. The HALO aircraft performing optimized transects and vertical profiling in Asia during 12 March and 7 April in 2018. To identify the transportation of biomass burning products, a high resolution (9 km) numerical study by Weather Research Forecast coupled with chemistry model (WRF-Chem) was performed during the campaigns. The long-range transport of biomass burning organic aerosol to Taiwan measured by HALO could be more than 2 ug/m3 at the elevation of 2500 m on 20 March, 2018. Model performances and results will discuss in this meeting. Overall, this series of studies significantly fill the gap of our understanding on air pollutants transformation and transport to Taiwan and East Asia, and show the potential directions of future studies.

How to cite: Lin, C., Chen, W., sheng, Y., Chen, W.-M., and Chien, Y.-Y.: Modeling of Southeast Asia biomass burning pollutants to Taiwan during EMeRGe campaigns in Asia, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9426, https://doi.org/10.5194/egusphere-egu2020-9426, 2020.

        Sentinel-5 Precursor (S5P) is a new generation environmental satellite, and provides trace gases concentrations along with cloud and aerosol information for global coverage. In this study, we focus on a regional scale nitrogen oxide (NOx) which is not only mainly air pollutant but also the precursors of secondary aerosol and ozone. However, the atmospheric NOx is primary in the form of Nitrogen dioxide (NO2). To understand the chemical properties and air pollution of NO2 from S5P in Taiwan, this study accesses the tropospheric NO2 which is retrieved from the TROPOMI onboard S5P, in conjunction with in-situ surface NO2 concentration observation from Environmental Protection Administration (EPA) of Taiwan. The temporal period is from June 2018 to May 2019, and surface observation is collocated with daily revisit of S5P spatiotemporally. The data are analyzed in 15 sub-regions of Taiwan for the relationship between tropospheric vertical column and surface concentration of NO2.

        The preliminary results reveal high correlation between surface NO2 and tropospheric NO2 in North Taiwan (Taipei/New Taipei City/Keelung), Yunlin, Tainan and Kaohsiung. Relative low correlation in Yilan, Hualian because of broad area with less ground-based stations. On the other hand, in order to avoid the impact of short-term factors, monthly mean concentration of NO2 is applied for further statistics. The results indicate high relationship in most of counties, except Hsinchu and Taitung. This suggests that the tendency of surface NO2 is similar to the tropospheric NO2 in most of countries in Taiwan in the monthly scale. Therefore, in order to monitor and analysis of NO2 concentration, spaceborne TROPOMI on S5P might be an alternative choice for conducting related research in Taiwan.

How to cite: Cai, Y.-J., Liu, C.-Y., and Chou, C.: Spatiotemporal Characteristics of Tropospheric and Surface NO2 from Sentinel-5 Precursor (S5P) and in-situ Observations in Taiwan, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2802, https://doi.org/10.5194/egusphere-egu2020-2802, 2020.

EGU2020-6387 | Displays | AS3.23

Influence of Upslope Fog on Hygroscopicity and Chemical Composition of Aerosols at a Forest Site in Taiwan

Chia-Li Chen, Ting-Yu Chen, Hui-Ming Hung, Ping-Wen Tsai, Wei-Nai Chen, and Charles C.-K. Chou

This study investigated the influence of upslope fog formation on the chemical composition and single hygroscopicity parameter (κ) of rural aerosols. The compositions were monitored using a mini compact time-of-flight aerosol mass spectrometer (mini-C-ToF-AMS), and a scanning mobility particle sizer (SMPS) from Dec. 1st to Dec. 24th, 2018 at the Xitou forest site (23.40°N, 120.47°E, 1,178 m asl) in Taiwan. Ambient wet aerosol particles were collected by a 13-stage nano-MOUDI II impactor (micro-orifice uniform deposit impactors) and analyzed using a Fourier-transform infrared spectrometer with an attenuated total reflectance accessory (FTIR-ATR). The single hygroscopicity parameter (κ) of aerosols derived from the comparison of AMS pToF size distribution using the κ-Köhler equation and FTIR-ATR measurement. The moderate correlation (r = 0.73) between the oxidized oxygenated organic aerosol (OOA) and CO evidenced the upstream anthropogenic emission transport by sea/land breezes. The decreasing (aerosol mass)/CO ratio with decreasing visibility trends during in-fog periods at two dense foggy events indicated that the fog activation scavenging mechanism dominated the aerosol particle removal. The inconsistency of online real-time AMS and offline FTIR-ATR measurement for submicrometer particles indicated that the evaporation loss of HNO3 or NH4NO3 particles during MOUDI filter sampling could lead to the unavailable κ retrieval for nitrate-containing particles at non-foggy daytime and the discrepancy of aerosol acidity. Similar κ ranges of organic carboxylic acid group particles (0.1 < κp-org < 0.3), ammonium-containing, and sulfate-containing particles (0.2 < κp-NH4 or κp-SO4< 0.5) but ambiguous nitrate-containing particles (0.4 < κp-NO3 < 0.6 or 0.6 < κp-NO3 < 0.8) were observed at foggy daytime, suggesting that ammonium sulfate and organic carboxylic acid compounds were more likely internal mixture particles with similar hygroscopicity and physicochemical mixing state influenced by upslope fog. However, the distinct κ ranges of sulfate-containing particles (0.5 < κp-SO4 < 0.7 or 0.6 < κp-SO4 < 0.8) and organic carboxylic acid group particles (0.1 < κp-org < 0.2) revealed the different chemical and physical properties of external mixture particles at non-foggy daytime.

 

 

How to cite: Chen, C.-L., Chen, T.-Y., Hung, H.-M., Tsai, P.-W., Chen, W.-N., and Chou, C. C.-K.: Influence of Upslope Fog on Hygroscopicity and Chemical Composition of Aerosols at a Forest Site in Taiwan, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6387, https://doi.org/10.5194/egusphere-egu2020-6387, 2020.

EGU2020-7979 | Displays | AS3.23

Validation and improvement of Taiwan Emission inventory for air quality modeling

Ming-Tung Chuang, Charles C.-K Chou, and Chuan-Yao Lin

The performance of air quality modeling (AQM) depends largely on the uncertainty of emission inventory. Since the emission data is an important input for AQM, this study tried to validate the controversial emission inventory. The Taiwan EPA (TEPA) has released the latest TEDS10.0 (Taiwan Emission Database System, version 10.0) based on 2016. This emission has attracted high arguments among governments and academics. This study applied the SMOKE v4.6 (Sparse Matrix Operator Kerner Emissions) to process the TEDS. The study used the CEMS (Continuous Emission Monitoring System) data and replaced temporalized large point source which accounts for 70% of all point source emissions, updated the biogenic emission calculation, improved the temporal profile of NH3, several area sources, and all mobile sources. Then we utilized the CMAQ (Community Modeling and Analysis System) model to simulate a PM2.5 event. However, the performance of the abovementioned improvement for emission processing is still not satisfactory. Therefore, this study tried to adjust the emission inventory according to the comparison of simulations and observations. The performance of air quality modeling has been improved after adjustment.  Meanwhile, this study provided suggestions of several aspects to be improved to the TEPA.

How to cite: Chuang, M.-T., Chou, C. C.-K., and Lin, C.-Y.: Validation and improvement of Taiwan Emission inventory for air quality modeling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7979, https://doi.org/10.5194/egusphere-egu2020-7979, 2020.

In ASEAN (Southeast Asia) countries, anthropogenic emissions have increased significantly over the last two decades from a variety of sources, including power and heating, industries, road-transportation, residential, and agricultural activities. In this study, we analyzed different emission inventories (i.e., MICS-Asia, REAS, EDGAR) to provide the integrated emissions for ASEAN during the period 2000-2010. The study found that anthropogenic emission contribution from ASEAN countries to the total Asian emission was notable during that period. For instance, from the MIX-Asian EI, our analysis shows that the average contribution was the highest from the transportation sector (34%), followed by residential (29%), power (24%), and industrial sector (14%), respectively in 2010. However, similar to the sector-specific emission contribution in 2000 in ASEAN countries, residential sector was the most significant contributor for CO (53%), PM10 (48%), PM2.5 (63%), BC (76%), OC (79%) in 2010, although it is in decreasing trend compared to other sectors. On the contrary, emission contribution of SO2 was the highest from the industrial sector (47%), followed by power (36%), while NOx and NMVOC were contributed mainly by transportation sector (55% and 45%, respectively). Spatially, the emission intensities of SO2, CO, NOx, NMVOC, PM10, PM2.5, BC, OC, and CO2 were high in the major urban cities of Thailand, Vietnam, Malaysia, Philippines, and Indonesia except CH4, N2O, and NH3, which were high in the rural areas of ASEAN countries.

How to cite: Lam, Y. F., Roy, S., and Chui, K. W.: Southeast Asian anthropogenic emission changes: An analysis from regional and global emission inventories, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12495, https://doi.org/10.5194/egusphere-egu2020-12495, 2020.

EGU2020-6549 | Displays | AS3.23

Air pollutant dispersion altered by urban-rural breeze and urban sprawl

Yung-Chang Chen, Gong-Do Hwang, Wei-Nai Chen, and C.-K. Charles Chou

Air pollution becomes a serious issue due to the population growing up and residential area sprawl in decades. Residential area is not only a major source of air pollutants but also an impact to generate an urban-rural thermal wind and to alter the dispersion of air pollutants. However, the urban-rural breeze caused by a metropolitan is not the only impact on the dispersion of air pollutants. Generally, a synoptic weather condition is the major impact to dominate how the air pollutant exactly diffuses. The most metropolitans are located in the coastal regions. Therefore, a naturally thermal wind, sea-land-breeze, plays also commonly an essential role to transfer the air pollutant. Additionally, topography and natural obstacle are unable to be ignored as an impact to obstruct flow streaming which brings the air pollutant away.

Overall, synoptic weather conditions, local sea-land-breeze patterns, and natural obstacles are three major natural impactors to influence air pollutant dispersion. The urban-rural-breeze pattern and the roughness of the urban area are regarded as the two anthropogenic factors to alter the large breeze system and thereby affecting the spreading pathway of the air pollutant. To analysis the interaction of above mentioned five impactors could be regarded as a comprehensive approach to consider how the air pollutant transfer from a metropolitan to air pollution suffering areas.

In this study, we apply either computational or measurement tools to consider the effects of metropolitan, Taichung, which is located in middle Taiwan, in the heat island effect and modification of the roughness to alter the natural breeze and also the dispersion of the air pollutant. Several intensive observation periods of 3-dimensional wind field network in boundary layer have been proposed as the evidences to discuss the impacts of urban sprawl on the breeze circulation in Taichung. Otherwise, a large-eddy-simulation model, Parallel-Large-Eddy-Simulation Model (PALM) is applied in the study initially to realize the influence of synoptic weather conditions and topography on air pollutant dispersion. Thereafter, the impacts of the heat fluxes and the roughness changing due to the urban sprawl are proposed in the study. Overall, the altering of metropolitan on the natural breeze is a slight but significant impact and could change the air pollutant dispersion.

 

Key Words: Boundary Layer, Wind field, Large-Eddy-Simulation, PALM, Urban Sprawl, Heat Island Effect, Thermal Wind

How to cite: Chen, Y.-C., Hwang, G.-D., Chen, W.-N., and Chou, C.-K. C.: Air pollutant dispersion altered by urban-rural breeze and urban sprawl, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6549, https://doi.org/10.5194/egusphere-egu2020-6549, 2020.

EGU2020-12255 | Displays | AS3.23

Aerosol Composition, Physiochemical Properties, and Source Apportionment at a Forest Site in Taiwan

Ting-Yu Chen, Chia-Li Chen, Hui-Ming Hung, Yi-Chi Chen, Haojia Ren, Wei-Nai Chen, and Charles C. -K. Chou

To investigate the interaction between local circulation and aerosol major chemical composition and hygroscopicity, a series of studies in Xitou Experimental Forest of National Taiwan University (23.40°N, 120.47°E, 1,178 m asl) in December 2018 was conducted. The isotopes of δ15N and δ18O from the filter samples were applied to identify the possible formation pathways. The single hygroscopicity parameter, κ, of aerosols between 9-437 nm in diameter was derived from the measurements of a cloud condensation nuclei counter (CCNc), an ultrafine condensation particle counter (UCPC) and a scanning mobility particle sizer (SMPS) using the κ-Köhler equation. Filter samples collected by a multi-orifice uniform deposit impactor (MOUDI) were applied to quantify the major aerosol composition based on the absorbance of selected functional groups (NH4+, SO42-, NO3-, elemental carbon) by a Fourier transform infrared spectroscopy with an attenuated total reflection accessory (FT-IR-ATR). The δ15N of particulate NH4+ (p-NH4+) and particulate NO2- or NO3- (p-NOx-) and the δ18O of p-NOx- were analyzed by an isotopic ratio mass spectroscopy (IR-MS) to infer the source and chemical pathway of aerosols. The mean κ value of aerosol is mostly between 0.07 and 0.22 during the field study period. The aerosol concentration shows a significant correlation with the local circulation, sea-land breeze combined with the mountain-valley circulation, and is significantly higher in the daytime than that in the nighttime. The foggy period has revealed a higher concentration of NH4+, SO42-, NO3-, and elemental carbon (or black carbon, BC), which may be caused by the lower boundary layer and weaker upward turbulent mixing during the foggy period. Aerosols containing NH4+, SO42- shifted to the larger size distribution during the foggy period and that is likely due to the hygroscopic growth of aerosols containing these functional groups at higher RH. The observed stable and high NO3- concentration of aerosol in the diameter of 0.56-1 µm during foggy periods is likely caused by the partition of HNO3 in the aqueous phase under a basic condition or further stabilized by the dissolved ammonium to form particulate NO3-. The daily mass-weighted δ15N of p-NH4+ is ranged from +3.7‰ to +16.3‰ and δ15N of p-NOx- from +1.5‰ to +5.2‰, indicating that p-NH4+ and p-NOx- are likely contributed from anthropogenic sources such as coal-burning and traffic. The δ18O of p-NOx- is in the range of +70‰ to +80‰, similar to the result of southeast Asia in winter. The observed high δ18O might be contributed through the pathways of the oxidation of NO with O3 to form NO2, which is further oxidized by OH radicals to form HNO3.

How to cite: Chen, T.-Y., Chen, C.-L., Hung, H.-M., Chen, Y.-C., Ren, H., Chen, W.-N., and Chou, C. C.-K.: Aerosol Composition, Physiochemical Properties, and Source Apportionment at a Forest Site in Taiwan, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12255, https://doi.org/10.5194/egusphere-egu2020-12255, 2020.

EGU2020-18247 | Displays | AS3.23

Comparison of Airborne Peroxy Radical Measurements with MECO(n) model simulation during EMeRGe in Europe

Yangzhuoran Liu, Mariano Mertens, Maria Dolores Andrés Hernández, Midhun George, Vladyslav Nenakhov, Astrid Kerkweg, Patrick Jöckel, and John P. Burrows

Observations of tropospheric peroxy radicals are a key point for interpretation of the processing and transformation of polluted outflows from major populated centres (MPCs). A series of European MPCs are investigated by the project EMeRGe (Effect of Megacities on the transport and transformation of pollutants on the Regional and Global scales). With this objective two airborne campaigns using the research platform HALO (High Altitude and LOng range aircraft) were carried out over Europe in summer 2017 and over east Asia in the intermonsoon period in 2018. The Institute of Environmental Physics (IUP) in Bremen (Germany) participated in both EMeRGe campaigns with the airborne measurement of the total sum of peroxy radicals, RO2*, by using  the home made PeRCEAS instrument based on the combination of the PERCA (peroxy radical chemical amplification)  and CRDS (cavity ring down spectroscopy) techniques. One of the main purposes of the campaigns was the investigation of the characteristics and chemical transformation of MPC outflows at the local and regional scales.

During the EMeRGe campaign in Europe, air masses of different photochemical activity were measured, where RO2* mixing ratios up to 100pptv being observed. In the present study the RO2* observations for six measurement flights of EMeRGe in Europe have been compared with RO2 (here defined as the sum of HO2 + CH3O2 + ISOOH + CH3CO3 + CH3COCH2O2) simulated by using the MECO(n) model.

MECO(n) (MESSy-fied ECHAM and COSMO models nested n times), is  a global/regional chemistry-climate model developed by the MESSy consortium, which couples on-line the global chemistry-climate model EMAC with the regional chemistry-climate model COSMO-CLM/MESSy. The same anthropogenic emission inventory (EDGAR 4.3.1) as well as the same solver for chemical kinetics, involving complex tropospheric and stratospheric chemistry, are applied in EMAC and COSMO-CLM/MESSy.

Overall, the agreement between the measurements and model is reasonable for RO2* observations below 40 pptv. Events with higher mixing ratios seem not to be well reproduced by the model but underestimated. Further details on the modelling and the result of the comparison will be presented.

How to cite: Liu, Y., Mertens, M., Andrés Hernández, M. D., George, M., Nenakhov, V., Kerkweg, A., Jöckel, P., and Burrows, J. P.: Comparison of Airborne Peroxy Radical Measurements with MECO(n) model simulation during EMeRGe in Europe , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18247, https://doi.org/10.5194/egusphere-egu2020-18247, 2020.

EGU2020-16941 | Displays | AS3.23

Representation of emissions from European major population centeres in MECO(n) - Lessons learned from EMeRGe-EU

Mariano Mertens, Astrid Kerkweg, Patrick Jöckel, Markus Kilian, Lisa Eirenschmalz, Volker Grewe, Theresa Klausner, Hans Schlager, Helmut Ziereis, Maria D. Andrés Hernández, and John P. Burrows

Comprehensive regional chemistry-climate or chemistry transport models are important tools to study the impact of emissions from major population centres (MPC) and/or investigate potential mitigation options for MPC emissions. Before such models can be employed it is important to investigate how well the models represent observed atmospheric conditions. This comparison helps not only in judging the performance of the models, but allows to test our understanding of chemical and physical processes in the atmosphere. A prerequisite for an extensive evaluation of models are the availability of temporally and spatially high resolved observational data. Such a data set was obtained during the EMeRGe-Europe campaign of the HALO research aircraft in July 2017, which targeted the outflow of different MPC in Europe.

We used the data of the EMeRGe-EU campaign together with ground based observations to evaluate the representation of European MPC emissions in the MECO(n) model system. MECO(n) is a global/regional chemistry-climate model which couples the regional chemistry-climate model COSMO-CLM/MESSy on-line (i.e., during runtime) with the global chemistry climate-model EMAC. The dynamics of EMAC is nudged against ERA-Interim reanalysis data. We performed three nesting steps from 300 km on the global scale to 50 km, 12 km and 7 km on the regional scale. In our evaluation we focus on tropospheric ozone (O3) and related precursors, methane (CH4) and sulphur dioxide (SO2). 

Generally, the comparison between the measurements and the model results shows a good representation of European MPC emissions in MECO(n). In detail, however, the measured mixing ratios of carbon monoxide (CO) and reactive nitrogen (NOy)  are underestimated, while O3 and SO2 are overestimated by the model. Potential reasons for these differences are too efficient vertical mixing, and underestimation of MPC emissions. 

To test hypotheses for potential model improvements we performed additional sensitivity studies with different nudging data for EMAC and an alternative anthropogenic emission inventory. The differences of the model results to the observations, however, are only slightly influenced by these changes. Accordingly, further hypotheses for potential model improvements needs to be investigated.  While the simulated mixing ratios differ only slightly between the sensitivity studies, the ozone source apportionment results (using a tagging approach) show much larger differences. This indicates the large uncertainty of  source apportionment analyses caused by uncertainties of emission inventories and model dynamics and requires further analysis in the future. 

How to cite: Mertens, M., Kerkweg, A., Jöckel, P., Kilian, M., Eirenschmalz, L., Grewe, V., Klausner, T., Schlager, H., Ziereis, H., Andrés Hernández, M. D., and Burrows, J. P.: Representation of emissions from European major population centeres in MECO(n) - Lessons learned from EMeRGe-EU, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16941, https://doi.org/10.5194/egusphere-egu2020-16941, 2020.

EGU2020-18315 | Displays | AS3.23

Aerosol microphysical properties for selected case studies during the EMeRGe-EU and EMeRGe-Asia campaigns

Jennifer Wolf, Daniel Sauer, Lisa Eirenschmalz, Theresa Klausner, and Hans Schlager

Aerosols can have a great impact on air quality and human health. In addition they can affect air transport by causing damage in aircraft engines.

To study the transport and transformation of anthropogenic pollutants from major population centers, two airborne measurement campaigns were conducted in the framework of the EMeRGe (Effect of Megacities on the transport and transformation of pollutants on the Regional to Global scales) Project using the German High Altitude-Long-Range (HALO) research aircraft. The aircraft was equipped with a wide range of instrumentation to measure atmospheric constituents. Here we report on results from the measurements characterizing aerosol microphysical properties. Measurements included particle number concentration and size distributions in a size range between 10 nm and ~3 µm as well as absorption properties. Aerosols were measured in the outflow of major population centers in Europe in summer 2017 (EMeRGe-EU) and along the Asian Pacific coast in spring 2018 (EMeRGe-Asia). In selected case studies we investigated detected aerosol layers, their likely source regions and transport paths. Case studies include the pollution along the west coast of Taiwan as well as the outflows of Manila (Philippines) and London (United Kingdom). Differences and similarities between Europe and Asia and the correlations with trace gases such as SO2, CO2 and CH4 are discussed.

How to cite: Wolf, J., Sauer, D., Eirenschmalz, L., Klausner, T., and Schlager, H.: Aerosol microphysical properties for selected case studies during the EMeRGe-EU and EMeRGe-Asia campaigns, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18315, https://doi.org/10.5194/egusphere-egu2020-18315, 2020.

EGU2020-20218 | Displays | AS3.23

Cloud condensation nuclei (CCN) measurements with the HALO aircraft during EMeRGe in European and Asian airspace

Mira L. Pöhlker, Ovid O. Krüger, Bruna A. Holanda, Christopher Pöhlker, Thomas Klimach, Hang Su, Yafang Cheng, Vladyslav Nenakhov, Maria D. Andrés Hermándes, John P. Burrows, and Ulrich Pöschl

During the EMeRGe campaign we employed a cloud condensation nuclei counter (CCNC) on board the research aircraft HALO. The instrument was located in the CCN-Rack probing together with a single particle soot photometer (SP2) and a multi-impactor for sampling different air masses on silica nitrate substrates. The aerosol particles were sampled through the HALO Aerosol Submicrometer Inlet (HASI). The measurements have been performed with a two column continuous-flow longitudinal thermal-gradient instrument (CCN-200) manufactured by DMT. The CCN-200 measures the CCN number concentration as a function of water vapor supersaturation (S). These measurements are performed by changing S within one column from 0.10 % up to 1.00 % using 12 different supersaturations and keeping S constant within the second column (S = 0.38 %) to ensure baseline data with 1 Hz time resolution. The different supersaturations are created by changing the flow while setting a fixed temperature difference.

Purpose of EMeRGe is to quantify and qualify outflows of megacities, as well as their transport and transformation in the atmosphere. Therefore, measurement flights were performed in the European airspace in 2017, probing aerosol properties over cities like London, Barcelona and Rome. In March 2018, the same set of instruments was probing the outflows of Asian megacities like Taipei, Manila and aged pollution from China Mainland. Furthermore, Japanese and South Korean outflows could be probed. The measurements took place in altitudes between 0.3 km and 13 km ASL. The scientific objective is to investigate the effect of different pollution states on aerosol and CCN properties.

How to cite: Pöhlker, M. L., Krüger, O. O., Holanda, B. A., Pöhlker, C., Klimach, T., Su, H., Cheng, Y., Nenakhov, V., Andrés Hermándes, M. D., Burrows, J. P., and Pöschl, U.: Cloud condensation nuclei (CCN) measurements with the HALO aircraft during EMeRGe in European and Asian airspace, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20218, https://doi.org/10.5194/egusphere-egu2020-20218, 2020.

EGU2020-4932 | Displays | AS3.23

What drives seasonal variations of organic aerosol over the Indo Gangetic Plain?

Caterina Mogno, Paul Palmer, and Christoph Knote

The Indo Gangetic Plain (IGP), home to more than 400 million people, encompasses most of northern and eastern India, the most populated parts of Pakistan, and Bangladesh. Cities in the IGP are among the most polluted in the world, with levels of particulate matter with diametres smaller than 2.5 microns (PM2.5), often far exceeding human health recommendations. Seasonal changes in the physical and chemical environment over the IGP are dominated by the large-scale South Asian monsoon system, but also by seasonal sources such as lifting of dust from the Thar desert and agricultural stubble burning at the end of the growing seasons. Organic aerosol (OA) represents a major contribution to PM2.5. They exist in a complex mixture, comprising of thousands of individual organic compounds. OA is made up of primary OA (POA), emitted directly to the atmosphere, and by secondary OA (SOA) formed by the gas-phase oxidation of volatile organic compounds. We use the WRF-Chem regional atmospheric chemistry model to study seasonal changes in the chemical properties of fine particulate matter over the IGP. In particular, we use the Volatility Basis Set (VBS) model in WRF-Chem to study both POA and SOA seasonal variations, and to quantify the importance of seasonal sources of OA to PM2.5 over the IGP. We evaluate the model using satellite observations of aerosol optical properties.

How to cite: Mogno, C., Palmer, P., and Knote, C.: What drives seasonal variations of organic aerosol over the Indo Gangetic Plain?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4932, https://doi.org/10.5194/egusphere-egu2020-4932, 2020.

EGU2020-3472 | Displays | AS3.23

Assessment of Air Pollution in the Middle East Using Reanalyses Products and High-resolution WRF-Chem Simulations

Alexander Ukhov, Suleiman Mostamandi, Johannes Flemming, Arlindo DaSilva, Nick Krotkov, Can Li, Yasser Alshehri, Anatolii Anisimov, Vitali Fioletov, Chris McLinden, Illia Shevchenko, and Georgiy Stenchikov

The Middle East is notorious for high air pollution that affects both air-quality and regional climate. The Middle East generates about 30% of world dust annually and emits about 10% of anthropogenic SO2. In this study we use Modern-Era Retrospective analysis for Research and Applications v.2 (MERRA-2), Copernicus Atmosphere Monitoring Service Operational Analysis (CAMS-OA) data assimilation products, and a regional Weather Research and Forecasting model (10 km resolution) coupled with Chemistry (WRF-Chem) to evaluate natural and anthropogenic air pollution in the ME. The SO2 anthropogenic emissions used in WRF-Chem are updated using the independent satellite SO2 emission dataset obtained from the Ozone Monitoring Instrument (OMI) observations onboard NASA EOS Aura satellite. Satellite and ground-based aerosol optical depth (AOD) observations, as well as Particulate Matter (PM) and SO2 in situ measurements for 2015-2016, were used for validation and model evaluation. 

Although aerosol fields in regional WRF-Chem and global assimilation products are quite consistent, WRF-Chem, due to its higher spatial resolution and novel OMI SO2 emissions, is preferable for analysis of regional air-quality over the ME. We found that conventional emission inventories (EDGAR-4.2, MACCity, and HTAP-2.2) have uncertainties in the location and magnitude of SO2 sources in the ME and significantly underestimate SO2 emissions in the Arabian Gulf. CAMS reanalysis tends to overestimate PM2.5 and underestimate PM10 concentrations. In the coastal areas, MERRA2 underestimates sulfate and tends to overestimate sea salt concentrations. The WRF-Chem’s PM background concentrations exceed the World Health Organization (WHO) guidelines over the entire ME. The major contributor to PM (~75–95%) is mineral dust. In the ME urban centers and near oil recovery fields, non-dust aerosols (primarily sulfate) contribute up to 26% into PM2.5. The contribution of sea salt into PM can rich up to 5%. The contribution of organic matter into PM prevails over black carbon. SO2 surface concentrations in major ME cities frequently exceed European air-quality limits.

How to cite: Ukhov, A., Mostamandi, S., Flemming, J., DaSilva, A., Krotkov, N., Li, C., Alshehri, Y., Anisimov, A., Fioletov, V., McLinden, C., Shevchenko, I., and Stenchikov, G.: Assessment of Air Pollution in the Middle East Using Reanalyses Products and High-resolution WRF-Chem Simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3472, https://doi.org/10.5194/egusphere-egu2020-3472, 2020.

In recent years, reactive nitrogen concentration and potentiality has been of environmental concern. India being the second largest populated country in world, huge amount of NH3+ emissions are expected from various activities of humans, agriculture and individual sources. This work has been carried out to calculate wet deposition fluxes of Nr species in rain water and to understand their scavenging behaviour at a typical residential site under semiarid tropical region. For this purpose, sequential sampling of rain events has been performed for determining Nr levels during monsoon 2015 and 2016. Samples were analysed for reactive nitrogen species. The wet deposition flux was observed to be 2.13 kg ha-1year-1 for NH4+-N and 3.62 kg ha-1year-1 for NO3- -N in 2015. However, significant increase in NO3--N was observed in 2016 where as there was no remarkable change for NH4+. This clearly indicates towards dynamic behaviour pattern showing sources of reactive nitrogen in air over the region. Scavenging patterns confirmed the presence of NH4NO3 showing co-variations of NH4+ and NO3- along with the rainfall intensity. Thereby, confirming the possible forms in which these Nr species are being deposited over the study area.

How to cite: Chaturvedi, M. and Kulshrestha, U.: Reactive nitrogen fluxes and scavenging patterns through sequential sampling over Mathura, India. , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21779, https://doi.org/10.5194/egusphere-egu2020-21779, 2020.

EGU2020-20875 | Displays | AS3.23

Coupling of two methods to obtain pollutant emission factors from biomass burning in small combustion sources

Zuhelen Padilla Barrera, Ricardo Torres Jardón, Luis Gerardo Ruiz, Telma Castro, Oscar Peralta, Omar Macera, and Luisa Molina

The estimation of emissions inventories of climate forcing species and air pollutants from activities such as the burning of biomass from cooking food in rural environments in Mexico presents some degree of uncertainty due to the lack of locally obtained emission factors; emissions estimates were generally obtained with other types of biomass and cookstoves. The relevance of these pollutants to Mexico is mainly due to their contribution to air pollution, global warming and negative impacts on human health. This study presents an assembly of a series of theoretical-experimental procedures for the estimation of emission factors in improved stoves and other biomass burning processes. The design is based on the use of a controlled dilution system from which samples are obtained for the determination of PM2.5 and the content of organic carbon and elemental carbon. The flow of diluted samples is conditioned for continuous monitoring of polluting gases (NOx, CO, NHMC, and SO2), in addition to climate forcing gases such as CO2 and CH4 with a mobile laboratory equipped with instrumentation for air quality measurements. The new sampling design allows the determination of gaseous and particle matter emission factors through the application of two procedures: carbon mass balance and concentration ratios with respect to CO2 and CO. The proposed design was evaluated for three improved cookstoves (Patsari, Onil, Ecoestufa) using a water boiling test protocol and white oak as fuel, the proposed controlled dilution sampling design can be a reliable method for the determination of emission factors from small combustion sources when biomass is used as fuel and also by using the carbon balance to obtain the emission factors, we reduce the inherent uncertainties of the process due to the difficulty associated with the sampling of this type of emissions under isokinetic conditions in low flow exhaust conditions such as those of small emission sources. The final emission factor consists of a weighted range of the factors determined for each species with respect to the amount of oxidized carbon in each of them. The feasibility of the experimental design is demonstrated by an application of using white oak wood as fuel in three improved cookstoves and one three stones. The ranges of emission factors obtained for the three improved cookstoves in g/kg of wood consumed were: CO2, 1309-1375; CH4, 3-4; EC, 0.16 – 0.71; OC 1.94-2.89; CO, 63 - 103; y PM2.5, 3.17 – 4.12, while for the three stones the ranges of emission in g/kg of wood consumed were: CO2, 1141- 1232; CH4, 4.15-4.71; EC, 1.06 – 1.78; OC, 4.79-6.03; CO, 124 - 170; y PM2.5, 7.47 – 10.18 g/kg.

How to cite: Padilla Barrera, Z., Torres Jardón, R., Ruiz, L. G., Castro, T., Peralta, O., Macera, O., and Molina, L.: Coupling of two methods to obtain pollutant emission factors from biomass burning in small combustion sources, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20875, https://doi.org/10.5194/egusphere-egu2020-20875, 2020.

EGU2020-21630 | Displays | AS3.23

Do local urban emissions influence ambient meteorology?

Jan Karlický

The WRF-Chem model was used to analyze three different 14-day periods during 2016–2017 in Prague, Czech Republic. Specifically a summertime high-level ozone episode, a summertime convective episode and a wintertime episode with high concentrations of aerosol pollutants have been analyzed in great detail. Simulations were run on a 2 km grid domain covering the center of the Czech Republic with the capital Prague, which was nested into a 10 km domain covering Central Europe. For the analysis of the meteorological impact of the reduction of urban induced emissions, two model simulations were performed for each episode; one simulation with full anthropogenic emissions and a second idealized simulation where emissions over the Prague urban area were reduced to the background level. In this presentation we discuss the differences and similarities between these simulations for chemical species (gas and particle pollutants) but also meteorological variables (e.g., downward solar radiation, temperature, boundary layer height).

How to cite: Karlický, J.: Do local urban emissions influence ambient meteorology?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21630, https://doi.org/10.5194/egusphere-egu2020-21630, 2020.

Sources and Sinks of Nitrated Phenols: Application of an Observation-based Model

Yuwen Peng1, Sihang Wang1, Caihong Wu1, Jipeng Qi1, Chaomin Wang1,
Wei Song2, Xinmin Wang2, Bin Yuan1,*, Min Shao1,**

1 Institute for Environmental and Climate Research, Jinan University, 511443 Guangzhou, China

2 Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, China

* byuan@jnu.edu.cn

** mshao@pku.edu.cn

 

Abstract: Nitrated phenols are one of the intermediate products of aromatics oxidation that has been proved to be phytotoxic, mutagenic and important components of brown carbon and SOA in the atmosphere. Although its sources and sinks have been reported, high-time-resolution measurements of nitrophenols and the evaluation of reported rate constants insufficient. In this paper, we measured the concentration of nitrated phenols at an urban site in Guangzhou, then we use an observation-based model to compare different photolysis frequencies of nitrophenol and analyze its budget. The primary emission of traffic seems to be the dominant factor when considering its diurnal profile. Photolysis has proved to be the dominant sink of nitrophenol in the atmosphere.

How to cite: Peng, Y.: Sources and Sinks of Nitrated Phenols: Application of an Observation-based Model , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12915, https://doi.org/10.5194/egusphere-egu2020-12915, 2020.

EGU2020-22223 | Displays | AS3.23

Cluster analysis for dispersion patterns near nuclear power plants in South Korea

Hyunha Lee, Chunsil Jin, and Chunji Kim

  Clustering analysis using air parcel trajectories is actively used to investigate transport patterns of pollutants. To estimate the impact of nuclide dispersion from nuclear accident, comprehensive information based on long-term meteorological data is required to eatablish a complete and efficient public protection plan. Most of nuclear plants in South Korea are located in a complex terrain near coastal area that involves complicated meteorological phenomenon such as sea breezes and mountain-valley breezes. Robust approach based on long-term climatrological data is required to fully resolve the impacts near Korean nuclear power plants.

  In this study, we assessed the impacts of potential nuclear accident in South Korea by clustering dispersion patterns using 10-year meteorological data. Flow patterns are clustered using trajectory cluster analysis, and then combined with dispersion simulations to demonstrate the clustered dispersion patterns by each season and nuclear power plant.

  The long-term meteorological simulations from 2007 to 2016 were used to evaluate the potential impact of nuclear accidents in Korea, and the modeling framework was designed to show the impact map according to the flow patterns near each nuclear power plant. NOAA HYSPLIT modeling additional clustering analysis suggests that two or three cluster patterns for each power plant can be used. A total of 38 flow patterns are classified near the four nuclear plants in the previous season based on a 10-year wind field analysis. Korea has very complex terrain and coastal areas, and more sophisticated modeling efforts are needed to fully understand the more realistic dispersion characteristics of air masses. In terms of space-time resolution, updating land use information for simulation is very important for weather simulation near the surface of Korea.

  The results of this study can be used as a guideline for constructing a modeling framework for nuclide diffusion simulations, but given these complex simulation configurations, the results demonstrated in the current study are should be interpreted with caution.

 

How to cite: Lee, H., Jin, C., and Kim, C.: Cluster analysis for dispersion patterns near nuclear power plants in South Korea, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22223, https://doi.org/10.5194/egusphere-egu2020-22223, 2020.

AS3.24 – Polar Ozone and Polar Stratospheric Clouds

EGU2020-2280 | Displays | AS3.24

Chlorine partitioning near the polar vortex edge observed with ground-based FTIR and satellites at Syowa Station, Antarctica in 2007 and 2011

Hideaki Nakajima, Isao Murata, Yoshihiro Nagahama, Hideharu Akiyoshi, Takeshi Kinase, Yoshihiro Tomikawa, and Nicholas Jones

We retrieved lower stratospheric vertical profiles of O3, HNO3, and HCl from solar spectra taken with a ground-based Fourier-Transform infrared spectrometer (FTIR) installed at Syowa Station, Antarctica (69.0°S, 39.6°E) from March to December 2007 and September to November 2011.  This was the first continuous measurements of chlorine species throughout the ozone hole period from the ground in Antarctica.  We analyzed temporal variation of these species combined with ClO, HCl, and HNO3 data taken with the Aura/MLS (Microwave Limb Sounder) satellite sensor, and ClONO2 data taken with the Envisat/MIPAS (The Michelson Interferometer for Passive Atmospheric Sounding) satellite sensor at 18 and 22 km over Syowa Station.  HCl and ClONO2 decrease occurred from the end of May at both 18 and 22 km, and eventually in early winter, both HCl and ClONO2 were almost depleted.  When the sun returned to Antarctica in spring, enhancement of ClO and gradual O3 destruction were observed.  During the ClO enhanced period, negative correlation between ClO and ClONO2 was observed in the time-series of the data at Syowa Station.  This negative correlation was associated with the relative distance between Syowa Station and the edge of the polar vortex.  We used MIROC3.2 Chemistry-Climate Model (CCM) results to investigate the behavior of whole chlorine and related species inside the polar vortex and the boundary region in more detail.  From CCM model results, rapid conversion of chlorine reservoir species (HCl and ClONO2) into Cl2, gradual conversion of Cl2 into Cl2O2, increase of HOCl in winter period, increase of ClO when sunlight became available, and conversion of ClO into HCl, was successfully reproduced.  HCl decrease in the winter polar vortex core continued to occur due to both transport of ClONO2 from the subpolar region to higher latitudes, providing a flux of ClONO2 from more sunlit latitudes into the polar vortex, and the heterogeneous reaction of HCl with HOCl.  Temporal variation of chlorine species over Syowa Station was affected by both heterogeneous chemistries related to Polar Stratospheric Cloud (PSC) occurrence inside the polar vortex, and transport of a NOx-rich airmass from the polar vortex boundary region which can produce additional ClONO2 by reaction of ClO with NO2.  The deactivation pathways from active chlorine into reservoir species (HCl and/or ClONO2) were confirmed to be highly dependent on the availability of ambient O3.  At 18 km where most ozone was depleted, most ClO was converted to HCl.  At 22km where some O3 was available, additional increase of ClONO2 from pre-winter value occurred, similar as in the Arctic.

How to cite: Nakajima, H., Murata, I., Nagahama, Y., Akiyoshi, H., Kinase, T., Tomikawa, Y., and Jones, N.: Chlorine partitioning near the polar vortex edge observed with ground-based FTIR and satellites at Syowa Station, Antarctica in 2007 and 2011, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2280, https://doi.org/10.5194/egusphere-egu2020-2280, 2020.

EGU2020-2451 | Displays | AS3.24

Mountain-wave Induced Polar Stratospheric Clouds with ICON-ART: An Example at the Antarctic Peninsula

Michael Weimer, Jennifer Schröter, Lars Hoffmann, Oliver Kirner, Roland Ruhnke, and Peter Braesicke

Polar Stratospheric Clouds (PSCs) play a key role in explaining ozone depletion on large
scales as well as on regional scales. Mountain waves can be formed in the lee of a mountain
in a stably stratified atmosphere. They can propagate upwards into the stratosphere and
induce temperature changes in the order of 10 to 15 K. Thus, large PSCs localised around the
mountain ridge can be formed, leading to increased chlorine activation and subsequently to
a larger ozone depletion. It was estimated that 30 % of the southern hemispheric PSCs can
be explained by mountain waves. However, for the direct simulation of mountain-wave
induced PSCs, the mountains have to be represented adequately in global chemistry climate
models which was a challenge in the past due to too low horizontal resolution.


The ICOsahedral Nonhydrostatic (ICON) modelling framework with its extension for Aerosols
and Reactive Trace gases (ART) includes a PSC scheme coupled to the atmospheric chemistry
in the model. The PSC scheme calculates the formation of all three PSC types independently
resulting in the calculation of the heterogeneous reaction rates of chlorine and bromine
species on the surface of PSCs. ICON-ART provides the possibility of local grid refinement
with two-way interaction. With this, the grid around a mountain can be refined so that
mountain waves can be directly simulated in this region with a feedback to the coarser
global resolution.


In this study, we show the formation of mountain-wave induced PSCs with ICON-ART for the
example of a mountain wave event in July 2008 around the Antarctic Peninsula. It is
evaluated with satellite measurements of AIRS and CALIOP and its impact on chlorine and
bromine activation as well as on the ozone depletion in the southern hemisphere are
analysed. We demonstrate that the effect of mountain-wave induced PSCs can be
represented in the coarser global grid by using local grid refinement with two-way
interaction. Thus, this study bridges the gap between directly simulated mountain-wave
induced PSCs and their representation in a global simulation.

How to cite: Weimer, M., Schröter, J., Hoffmann, L., Kirner, O., Ruhnke, R., and Braesicke, P.: Mountain-wave Induced Polar Stratospheric Clouds with ICON-ART: An Example at the Antarctic Peninsula, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2451, https://doi.org/10.5194/egusphere-egu2020-2451, 2020.

EGU2020-3571 | Displays | AS3.24 | Highlight

Total ozone loss during the 2019/20 Arctic winter and comparison to previous years

Florence Goutail, Jean-Pierre Pommereau, Andrea Pazmino, Franck Lefevre, Cathy Clerbaux, Anne Boynard, Juliette Hadji-Lazaro, Martyn Chipperfield, Wuhu Feng, Michel Van Roozendael, Nis Jepsen, Georg Hansen, Rigel Kivi, Kristof Bognar, Kimberly Strong, and Kaley Walker

The amplitude of ozone depletion in the Arctic is monitored every year since 1990 by comparison between total ozone measurements of SAOZ / NDACC UV-Vis spectrometers deployed in the Arctic and 3-D chemical transport model simulations in which ozone is considered as a passive tracer.

When SAOZ measurements are missing for various reasons, lack of sunlight, station closed or instrument failure, they are replaced since 2017 by IASI/Metop overpasses above the station. These measurements in the thermal Infrared are available all year around, at all latitudes even in the polar night. IASI data have been compared to SAOZ and to 3-D CTM REPROBUS and the agreement is better than 3% at the latitude of the polar circle.

The method allows determining the evolution of the daily rate of the ozone destruction and the amplitude of the cumulative loss at the end of the winter. The amplitude of the destruction varies between 0-10% in relatively warm and short vortex duration years up to 25-39% in colder and longer ones.

Since a strong and large vortex centred at the North Pole, PSCs and activated chlorine are still present at all levels in the lower stratosphere on January 9, 2020, there is a good probability that a significant O3 loss may happen in 2020. But since, as shown by the unprecedented depletion of 39% in 2010/11, the loss depends on the vortex duration, strength and possible re-noxification, it is difficult to predict in advance the amplitude of the cumulative loss at the end of the winter.

Shown in this presentation will be the evolution of ozone loss and re-noxification in the Arctic vortex during the winter 2019/20 compared to previous winters and REPROBUS and SLIMCAT CTM simulations.

How to cite: Goutail, F., Pommereau, J.-P., Pazmino, A., Lefevre, F., Clerbaux, C., Boynard, A., Hadji-Lazaro, J., Chipperfield, M., Feng, W., Van Roozendael, M., Jepsen, N., Hansen, G., Kivi, R., Bognar, K., Strong, K., and Walker, K.: Total ozone loss during the 2019/20 Arctic winter and comparison to previous years, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3571, https://doi.org/10.5194/egusphere-egu2020-3571, 2020.

EGU2020-3969 | Displays | AS3.24 | Highlight

CALIOP PSC observations from 2006-2019

Michael Pitts and Lamont Poole

Even though the role of polar stratospheric clouds (PSCs) in stratospheric ozone depletion is well established, important questions remain unanswered that have limited our understanding of PSC processes and how to accurately represent them in global models.  This has called into question our prognostic capabilities for future ozone loss in a changing climate.  A more complete picture of PSC processes on polar vortex-wide scales has emerged from the CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) instrument on the CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations) satellite that has been observing PSCs at latitudes up to 82 degrees in both hemispheres since June 2006.  In this paper, we present a state-of-the-art climatology of PSC spatial and temporal distributions and particle composition constructed from the more than 14-year CALIOP spaceborne lidar dataset.  The climatology also includes estimates of particulate surface area density and volume density to facilitate comparisons with in situ data and measurements by other remote sensors, as well as with theoretical models relating PSCs to heterogeneous chemical processing and ozone loss. Finally, we compare the CALIOP PSC data record with the 1979-1989 SAM II (Stratospheric Aerosol Measurement II) solar occultation PSC record to investigate possible multi-decadal changes in PSC occurrence.

How to cite: Pitts, M. and Poole, L.: CALIOP PSC observations from 2006-2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3969, https://doi.org/10.5194/egusphere-egu2020-3969, 2020.

EGU2020-5086 | Displays | AS3.24

Influence of Arctic stratospheric ozone on surface climate in CCMI models

Ohad Harari, Chaim Garfinkel, and Shlomi Ziskin

The Northern Hemisphere and tropical circulation response to interannual variability in Arctic stratospheric ozone is analyzed in a set of the latest model simulations archived for the Chemistry-Climate Model Initiative (CCMI) project. All models simulate a connection between ozone variability and temperature/geopotential height in the lower stratosphere similar to that observed. A connection between Arctic ozone variability and polar cap surface air pressure is also found, but additional statistical analysis suggests that it is mediated by the dynamical variability that typically drives the anomalous ozone concentrations. While the CCMI models also show a connection between Arctic stratospheric ozone and the El Niño–Southern Oscillation (ENSO), with Arctic stratospheric ozone variability leading to ENSO variability 1 to 2 years later, this relationship in the models is much weaker than observed and is likely related to ENSO autocorrelation rather than any forced response to ozone. Overall, Arctic stratospheric ozone is related to lower stratospheric variability. Arctic stratospheric ozone may also influence the surface in both polar and tropical latitudes, though ozone is likely not the proximate cause of these impacts and these impacts can be masked by internal variability if data are only available for years.

 
Harari, O., Garfinkel, C. I., Ziskin Ziv, S., Morgenstern, O., Zeng, G., Tilmes, S., Kinnison, D., Deushi, M., Jöckel, P., Pozzer, A., O'Connor, F. M., and Davis, S.: Influence of Arctic stratospheric ozone on surface climate in CCMI models, Atmos. Chem. Phys., 19, 9253–9268, https://doi.org/10.5194/acp-19-9253-2019, 2019.

How to cite: Harari, O., Garfinkel, C., and Ziskin, S.: Influence of Arctic stratospheric ozone on surface climate in CCMI models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5086, https://doi.org/10.5194/egusphere-egu2020-5086, 2020.

EGU2020-6303 | Displays | AS3.24

Seventeen Years of the Canadian Arctic ACE/OSIRIS Validation Project at PEARL

Kaley Walker, Kimberly Strong, Pierre Fogal, and James R. Drummond

Ground-based measurements provide critical data to validate satellite retrievals of atmospheric trace gases and to assess the long-term stability of these measurements.  As of February 2020, the Canadian-led Atmospheric Chemistry Experiment (ACE) satellite mission has been making measurements of the Earth's atmosphere for nearly sixteen years and Canada's Optical Spectrograph and InfraRed Imager System (OSIRIS) instrument on the Odin satellite has been operating for over sixteen years.  As ACE and OSIRIS continue to operate far beyond their planned two-year missions, there is an ongoing need to validate the trace gas profiles from the ACE-Fourier Transform Spectrometer (ACE-FTS), the Measurement of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation (ACE-MAESTRO) and OSIRIS.  In particular, validation comparisons are needed during Arctic springtime to understand better the measurements of species involved in stratospheric ozone chemistry.

To this end, seventeen Canadian Arctic ACE/OSIRIS Validation Campaigns have been conducted during the spring period (February - April in 2004 - 2020) at the Polar Environment Atmospheric Research Laboratory (PEARL) in Eureka, Nunavut (80N, 86W). For more than a decade, these campaigns have been undertaken in collaboration with the Canadian Network for the Detection of Atmospheric Change (CANDAC). The spring period coincides with the most chemically active time of year in the Arctic, as well as a significant number of satellite overpasses. A suite of as many as 13 ground-based instruments, as well as frequent balloon-borne ozonesonde and radiosonde launches, have been used in each campaign. These instruments include: a ground-based version of the ACE-FTS (PARIS - Portable Atmospheric Research Interferometric Spectrometer), a terrestrial version of the ACE-MAESTRO, a SunPhotoSpectrometer, two CANDAC zenith-viewing UV-visible grating spectrometers, a Bomem DA8 Fourier transform spectrometer, the CANDAC Bruker 125HR Fourier transform spectrometer, an EM27/SUN Fourier transform spectrometer, a Systeme d’Analyse par Observations Zenithales (SAOZ) instrument, a Pandora spectrometer, and several Brewer spectrophotometers. In the past several years, these results have been used to validate the measurements by the ACE-FTS, ACE-MAESTRO, and OSIRIS instruments as well as the TANSO-FTS instrument on the Japanese Greenhouse Gases Observing Satellite (GOSAT) and the TROPOMI instrument on the Sentinel 5 Precursor. This presentation will focus on an overview of the measurements made by the ground-based, balloon-borne and satellite-borne instruments during the recent ACE/OSIRIS Arctic Validation campaigns and highlight how these have been used for satellite validation.

How to cite: Walker, K., Strong, K., Fogal, P., and Drummond, J. R.: Seventeen Years of the Canadian Arctic ACE/OSIRIS Validation Project at PEARL, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6303, https://doi.org/10.5194/egusphere-egu2020-6303, 2020.

EGU2020-8103 | Displays | AS3.24

Using machine learning method to classify polar stratospheric cloud types from Envisat MIPAS observations

Rocco Sedona, Lars Hoffmann, Reinhold Spang, Gabriele Cavallaro, Sabine Griessbach, Michael Höpfner, Matthias Book, and Morris Riedel

Polar stratospheric clouds (PSC) play a key role in polar ozone depletion in the stratosphere. Improved observations and continuous monitoring of PSCs can help to validate and enhance chemistry-climate models that are used to predict the evolution of the polar ozone hole. Here we present the results of our study in which we explored the potential of applying machine learning (ML) methods to classify PSC observations of infrared limb sounders. Two datasets have been considered. The first dataset is a collection of infrared spectra captured in Northern Hemisphere winter 2006/2007 and Southern Hemisphere winter 2009 by the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) instrument onboard ESA's Envisat satellite. The second dataset is the cloud scenario database (CSDB) of simulated MIPAS spectra. We first performed an initial analysis to assess the basic characteristics of these datasets and to decide which features to extract from them. More than 10,000 Brightness temperature differences (BTDs) features have been generated and fed as input to the ML methods instead of directly using the infrared spectra. Next, we assessed the use of ML methods for the reduction of the dimensionality of this large feature space using principal component analysis (PCA) and kernel principal component analysis (KPCA) as well as the classification with the random forest (RF) and support vector machine (SVM) techniques. All methods were found to be suitable to retrieve information on the composition of PSCs. Of these, RF seems to be the most promising method, being less prone to overfitting and producing results that agree well with established results based on conventional classification methods.

How to cite: Sedona, R., Hoffmann, L., Spang, R., Cavallaro, G., Griessbach, S., Höpfner, M., Book, M., and Riedel, M.: Using machine learning method to classify polar stratospheric cloud types from Envisat MIPAS observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8103, https://doi.org/10.5194/egusphere-egu2020-8103, 2020.

EGU2020-8918 | Displays | AS3.24

Impact of ECMWF ERA-Interim and ERA5 reanalysis on the simulated tracer transport and polar ozone loss using a chemical transport model TOMCAT/SLIMCAT 

Wuhu Feng, Martyn Chipperfield, Sandip Dhmose, Florence Goutail, Michelle Santee, Benni Birner, Ralph Keeling, and Gabriele Stiller

Three-dimensional chemical transport models (CTMs) have been widely used in a wide variety of scientific studies (e.g., to obtain a better understanding of tracer transport and to study the dynamical and chemical processes which control polar ozone losses etc). However, there are still some uncertainties in the model simulations and indeed in our understanding. For example, the accuracy of ozone simulations largely depends on the transport, chemistry and treatment of PSCs in the model as well as the forcing files. 

Here we have used a  CTM model TOMCAT/SLIMCAT with a detailed description of stratospheric and tropospheric chemistry forced by differnt wind fields (ECMWF ERA-Interim and ERA5 reanalysis datasets) to investigate the different dynamical fields on the simulated tracer transport, ozone and other chemical species. Both simulations have been run from 1979 to 2018. First we will assess the impact of different reanalysis data on the idealised tracers when the model includes additional process of the gravitational separation of gases (e.g., Ar/N2) and compare the model results with dataset of gravitational fractionation of Ar/N2 and AoA observations made on flask samples from three airborne research projects. Modelled AoA will be also compared with MIPAS data.  Then we will focus on the polar ozone loss from late 1990 to 2018 and quntify
the amount of chemical ozone loss using both models and satellite observations as well as  SAOZ measurements. The year-to-year variation of polar ozone depletion will also be discussed, in particular for the recent years of decreasing stratospheric chlorine loading. 

How to cite: Feng, W., Chipperfield, M., Dhmose, S., Goutail, F., Santee, M., Birner, B., Keeling, R., and Stiller, G.: Impact of ECMWF ERA-Interim and ERA5 reanalysis on the simulated tracer transport and polar ozone loss using a chemical transport model TOMCAT/SLIMCAT , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8918, https://doi.org/10.5194/egusphere-egu2020-8918, 2020.

EGU2020-9630 | Displays | AS3.24

Analysis of multi-year near-surface ozone observations at the WMO/GAW “Concordia” station, Antarctica

Davide Putero, Rita Traversi, Angelo Lupi, Francescopiero Calzolari, Maurizio Busetto, Laura Tositti, Stefano Crocchianti, and Paolo Cristofanelli

In this work, eight years (2006–2013) of continuous measurements of near-surface ozone (O3) at the WMO/GAW contributing station “Concordia” (DMC, 75°06’S, 123°20’E, 3280 m a.s.l.) are presented, and the role of specific atmospheric processes in affecting O3 variability is investigated. In particular, during the period of highest data coverage (i.e., 2008–2013), O3 enhancement events (OEEs) were systematically observed at DMC, affecting 11.6% of the dataset. As deduced by a statistical selection methodology, the OEEs are affected by a significant interannual variability, both in the average and in the frequency of O3 values. To explain part of this variability, OEEs were analyzed as a function of: (i) total column of O3 and UV-A irradiance variability, (ii) long-range transport of air masses over the Antarctic plateau (by using LAGRANTO), and (iii) occurrence of “deep” stratospheric intrusion events (by using STEFLUX). The overall O3 concentrations are controlled by a day-to-day variability, which indicates the dominating influence of processes occurring at “synoptic” scales rather than “local” processes. Despite previous studies indicated an inverse relationship between OEEs and TCO, we found that the annual frequency of OEEs was higher when TCO values at DMC were higher than usual. The annual occurrence of OEEs at DMC was also related to the total time spent by air masses over the Antarctic plateau before their arrival at DMC, suggesting that the accumulation of photochemically-produced O3 during the transport dominated the local O3 production. Lastly, the influence of “deep” stratospheric intrusion events at DMC was analyzed, and it was observed that this contribution played only a marginal role (the highest frequency observed was 3% of the period, in November).

This latter point, i.e., the frequency and seasonality of stratosphere-to-troposphere (STE) events, and the relative influence of specific transport mechanisms, as well as snow chemistry, are still under debate. These topics will be investigated in the STEAR (Stratosphere-to-Troposphere Exchange in the Antarctic Region) project, starting in 2020 and funded by the Italian Antarctic Research Program (PNRA). In particular, STEAR will provide an assessment of STE events in Antarctica, by using both continuous observations (e.g., O3 and Beryllium-7) at DMC, and modeling outputs. In addition to DMC measurements, simultaneous atmospheric composition datasets will be analyzed at Antarctic coastal observatories, i.e., the Mario Zucchelli (MZS) and Jang Bogo (JBS) stations.   

How to cite: Putero, D., Traversi, R., Lupi, A., Calzolari, F., Busetto, M., Tositti, L., Crocchianti, S., and Cristofanelli, P.: Analysis of multi-year near-surface ozone observations at the WMO/GAW “Concordia” station, Antarctica, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9630, https://doi.org/10.5194/egusphere-egu2020-9630, 2020.

EGU2020-11367 | Displays | AS3.24

Solar activity influence on the ozone vertical distribution from SBUV data

Gennadi Milinevsky, Asen Grytsai, Oleksandr Evtushevsky, Yury Yampolsky, Andrew Klekociuk, and Yuke Wang

Ozone content in the terrestrial atmosphere is dependent on chemical and dynamical factors including catalytic destruction under the influence of chlorine and bromine, Brewer–Dobson circulation, and large-scale atmospheric waves. The appearance of ozone molecules in the stratosphere is caused by solar ultraviolet radiation as well. Therefore solar activity variations can influence ozone content. The 11-year solar cycle had been earlier identified in the upper stratosphere. Satellite ozone observations were begun from the 1970s are almost continuous from 1979 including the vertical ozone distribution, in particular with the use of Solar Backscattered UltraViolet (SBUV) instruments. These data cover the troposphere and stratosphere layers, from the surface to near 50 km. Vertical ozone distribution over the Ukrainian Antarctic station Akademik Vernadsky (65.25°S, 64.27°W) and in the corresponding latitudinal range 60–65°S is studied in this work with the following analysis of possible solar activity display in other latitudinal belts. Sunspot numbers have been considered as the simplest characteristics of solar activity. We have considered SBUV yearly data paying main attention to the time range from 1979 when the measurements are most reliable. Periodicity in the series of ozone layer content has been studied with use of wavelet transform. Processing of the SBUV data over Vernadsky has shown a dominating period near 10–11 years at the heights 18–31 km. In the troposphere and lower stratosphere, this period is unclear. A similar situation is observed above 31 km indicating the upper altitudinal threshold in the presence of the 10–11-year periodicity in the ozone data. The solar cycle influence on the ozone vertical distribution in the Antarctic region has been studied. From our analysis, the solar cycle plays an important role in the decadal variability of the mid-stratospheric ozone over Vernadsky Station with decrease of the effect both in the troposphere – lower stratosphere and in the upper stratosphere. A similar analysis is also realized for zonal mean ozone at the 60–65°S latitudes belt and for the region of zonal ozone maximum (Casey), where the solar cycle was indicated at the heights 31–37 km. Thus, zonal asymmetry in the heights of the maximum solar cycle effect in the Antarctic ozone exists. Periods close to 11 years are observed in the lower stratosphere of equatorial latitudes exhibiting seasonal dependency. At altitudes, 25–30 km, the southern stratosphere has more evident signs of solar cycle periods than the northern one. The summer upper stratosphere with a high flux of direct solar radiation is also a region with prominent quasi-11 year periods. In sum, three main regions with solar activity influence (tropical lower stratosphere, west Antarctic middle stratosphere, and east Antarctic upper stratosphere) are identified. The asymmetry between solar cycle influence (i) in the northern and southern hemisphere mid-stratosphere and (ii) zonal ozone maximum and minimum over Antarctica is denoted for the first time.

This work was partly supported by the project 19BF051-08 Taras Shevchenko National University of Kyiv and by the International Center of Future Science, Jilin University.

How to cite: Milinevsky, G., Grytsai, A., Evtushevsky, O., Yampolsky, Y., Klekociuk, A., and Wang, Y.: Solar activity influence on the ozone vertical distribution from SBUV data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11367, https://doi.org/10.5194/egusphere-egu2020-11367, 2020.

Polar stratospheric clouds (PSCs) have an important influence on the spatial and temporal
evolution of different trace gases, (e.g. ozone, HNO3) in the polar vortex in winter due to direct
and indirect processes (e.g. activation of chlorine, redistribution of HNO3). Thus, the detection
of PSCs and a detailed distinction between the different PSCs types Nitric Acid Trihydrade
(NAT), Supercooled Ternary Solution (STS), and ice are important as they build a basis for
model comparisons to reduce uncertainties in the representation of PSCs in models. Infrared
limb sounder are well suited for this purpose as they enable both, the detection of clouds and
the discrimination between the different types.
The CRISTA-NF instrument, an airborne infrared limb sounder, observed a new spectral fea-
ture during measurements inside PSCs within the RECONCILE aircraft campaign. In contrast
to the previously known feature at 820 cm-1, which has been used in former studies for the
detection of NAT PSCs, the new feature was detected at about 816 cm-1. We performed a
large set of radiative transfer simulations for different PSC situations (varying PSC altitude
and thickness, PSC type, number density and median radius of the particle size distribution)
for the airborne viewing geometry of CRISTA-NF. The simulation results show that under the
assumption of spherical NAT particles the spectral feature transforms from the original feature
at 820 cm-1 to a shifted version (peak shifts to smaller wavenumbers) and finally to a step-like
feature with increasing median radius. Based on this behaviour we defined different colour ra-
tios to detect PSCs containing NAT particles and to subgroup them into three sizes regimes:
small NAT, medium size NAT, and large NAT. In addition, we used the simulation results to
adopt a method, which has been used to detect ice in MIPAS-ENV observations, to the airborne
geometry and to refine the corresponding threshold values.
We applied all methods of cloud detection and type discrimination to the CRISTA-NF observa-
tions during the RECONCILE campaign. The new defined NAT detection method is capable
to detect the shifted NAT feature, which is clearly visible in the radiance spectra.

How to cite: Kalicinsky, C., Grießbach, S., and Spang, R.: Radiative transfer simulations and observations of airborne infrared emission spectra in the presence of PSCs: Detection of clouds and discrimination of cloud types, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13750, https://doi.org/10.5194/egusphere-egu2020-13750, 2020.

EGU2020-17874 | Displays | AS3.24

What controls nucleation of ice and nitric acid hydrates by meteoric material?

Alexander James, Sebastien N. F. Sikora, Mark Holden, Graham W. Mann, John M. C. Plane, and Benjamin J. Murray

Nucleation of crystalline ice and nitric acid hydrates in Polar Stratospheric Clouds (PSC) is important for the destruction of ozone, both through changing the rate of activation of ozone destroying species and through the removal by sedimentation of nitric acid, which can deactivate ozone destroying species. Nucleation is thought to proceed heterogeneously on fragmented meteoric materials, leading to formation of ice and nitric acid trihydrate. The heterogeneous nature of meteoric materials and the potential to form multiple crystalline phases makes this system particularly complex. In particular, the characteristics of meteoric fragments which allow them to nucleate crystallisation in PSCs are unknown. We have investigated the nature of nucleation of nitric acid solutions on meteorite thin section surfaces. We find that nucleation occurs on a range of sites on the surface without significant reproduction in repeat freezing experiments. Electron microscopy showed significant diversity in the type of surface features present in regions where nucleation was observed. This is in contrast to recent studies of ice nucleation on K-feldspar and quartz surfaces, where particular sites were found to dominate nucleation. We also observed a range of different crystalline phases forming competitively, some of which are not represented on the HNO3 / H2O equilibrium phase diagram. The results reinforce the complexity of nucleation in PSC and do not support simplifying assumptions commonly made in the literature e.g. around the order in which phases form. In order to facilitate a predictive capacity of future trends in ozone loss significant work is required in understanding the nucleation of nitric acid hydrates by meteoric material.

How to cite: James, A., Sikora, S. N. F., Holden, M., Mann, G. W., Plane, J. M. C., and Murray, B. J.: What controls nucleation of ice and nitric acid hydrates by meteoric material?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17874, https://doi.org/10.5194/egusphere-egu2020-17874, 2020.

EGU2020-18176 | Displays | AS3.24

10 years of Polar Stratospheric Clouds lidar measurements at the French antarctic station Dumont d’Urville

Florent Tencé, Julien Jumelet, Alain Sarkissian, Slimane Bekki, and Philippe Keckhut

Polar Stratospheric Clouds (PSCs) play a primary role in polar stratospheric ozone depletion processes. Aside from recent improvements in both spaceborne PSCs monitoring as well as investigations on PSCs microphysics and modeling, there are still uncertainties associated to solid particle formation and their denitrification potential. In that regard, groundbased instruments deliver detailed and valuable measurements that complement the global spaceborne coverage.

Operated since 1989 at the French antarctic station Dumont d’Urville (DDU) in the frame of the international Network for the Detection of Atmospheric Composition Change (NDACC), the Rayleigh/Mie/Raman lidar provides over the years a solid dataset to feed both process and classification studies, by monitoring cloud and aerosol occurrences in the upper troposphere and lower stratosphere. Located on antarctic shore (66°S - 140°E), the station has a privileged access to polar vortex dynamics. Measurements are weather-dependent with a yearly average of 130 nights of monitoring. Expected PSC formation temperatures are used to evaluate the whole PSC season occurrences.

We hereby present a consolidated dataset from 10 years of lidar measurements using the 532nm backscatter ratio, the aerosol depolarisation and local atmospheric conditions to help in building an aerosol/cloud classification. Using the different PSC classes and associated optical properties thresholds established in the recent PSC CALIOP classification, we build a picture of the 2007-2019 events, from march to october.

Overall, the DDU PSC pattern is very consistent with expected typical temperature controlled microphysical calculations. Outside of background sulfate aerosols and anomalies related to volcanic activity (like in 2015), Supercooled Ternary Solution (STS) particles are the most observed particle type, closely followed by Nitric Acid Trihydrate (NAT). ICE clouds are less but regularly observed. ICE clouds also have to be cleary separated from cirrus clouds, raising the issue of accurate dynamics tropopause calculations.

Validation of the spaceborne measurements as well as multiple signatures of volcanic or even biomass originated aerosol plumes strengthens the need for groundbased monitoring especially in polar regions where instrumental facilities remain sparse.

How to cite: Tencé, F., Jumelet, J., Sarkissian, A., Bekki, S., and Keckhut, P.: 10 years of Polar Stratospheric Clouds lidar measurements at the French antarctic station Dumont d’Urville, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18176, https://doi.org/10.5194/egusphere-egu2020-18176, 2020.

EGU2020-18407 | Displays | AS3.24 | Highlight

Airborne in situ tracer observations in the 2019 Springtime Antarctic UTLS during the HALO SouthTRAC campaign

C. Michael Volk, Valentin Lauther, Andrea Rau, Fridolin Hader, and Svetlana Cvetkova

During the recent SouthTRAC (Transport and composition of the Southern Hemisphere UTLS) campaign the German High Altitude and LOng range research aircraft (HALO) intensively probed the bottom of the Antarctic vortex and the adjacent mid to high latitude upper troposphere / lower stratosphere (UTLS) throughout late winter and spring 2019.  A main goal of this mission was to study dynamics, transport and composition of this region, and particularly to assess the impact of the Antarctic vortex on the southern hemisphere UTLS.  The Antarctic winter 2019 was extraordinary with respect to dynamics, with a sudden stratospheric warming (only the second one ever observed) leading to a less stable and unusually warm polar vortex. The campaign consisted of two phases based in Rio Grande, Argentina (54°S) and comprised a total of 27 science flights including transfer flights to/from Argentina and 13 local flights from Rio Grande in September/early October and in November 2019.  A number of these flights penetrated into the lower Antarctic vortex, others crossed streamers or thin filaments shed from the vortex by frequent Rossby wave breaking events.

We present observations obtained on board of HALO by the University of Wuppertal's High Altitude Gas Analyzer –V (HAGAR-V), a 5-channel in-situ tracer instrument recently developed for HALO to study the chemical composition, dynamics, and transport in the UTLS.  HAGAR-V combines i) a fast CO2 measurement by NDIR analyzer (every 3 s), ii) a 2-channel GC/ECD-system measuring the long-lived tracers CFC-12, SF6 (every 40 s), CFC-11, CFC-113 and Halon-1211 (every 80s), and iii) a 2-channel GC/MS system measuring a large suite of further long-lived (e.g. HFCs) and short-lived halogenated tracers, including further chlorine source gases (e.g. CCl4, CH2Cl2, CHCl3, C2Cl4, HCFCs) every 2-4 minutes.  We will discuss the unusually active dynamics and associated tracer transport in the vicinity of the 2019 Antarctic vortex reflected by these measurements, and show the temporal development of vertical distributions and tracer correlations throughout the spring.  We will also compare the tracer distributions during SouthTRAC with those observed from the M55 Geophysica aircraft during the 1999 Antarctic campaign APE-GAIA.

How to cite: Volk, C. M., Lauther, V., Rau, A., Hader, F., and Cvetkova, S.: Airborne in situ tracer observations in the 2019 Springtime Antarctic UTLS during the HALO SouthTRAC campaign, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18407, https://doi.org/10.5194/egusphere-egu2020-18407, 2020.

EGU2020-18952 | Displays | AS3.24

Observing System Simulation Experiment (OSSE) of future ALTIUS ozone profiles

Quentin Errera, Jonas Debosscher, Emmanuel Dekemper, Philippe Demoulin, Didier Fussen, Didier Piroux, Filip Vanhellemont, and Nina Mateshvili

ALTIUS (Atmospheric Limb Tracker for the Investigation of the Upcoming Stratosphere) is a satellite mission dedicated to continue Earth limb measurements for atmospheric sciences (Fussen et al., JQSRT, 2019). It is an element of the ESA Earth Watch programme and is expected to be launched in 2024 on a low earth polar orbit. The instrument is based on three spectral imagers that will measure in UV-vis-NIR wavelength range and will operate in different viewing geometry: limb scattering and occultation of the sun, the moon, the planets and the stars. ALTIUS will retrieve vertical profiles of ozone, nitrogen dioxide, aerosol extinction, among others.

In this study, we present an Observing System Simulation Experiment (OSSE) of ALTIUS ozone profiles that we have compared with the existing observations from Aura Microwave Limb Sounder (MLS). For this purpose, we have created a stratospheric ozone reference dataset between June and September 2008 based on the assimilation of MLS data with the Belgian Assimilation System for Chemical Observations (BASCOE). During the MLS assimilation experiment, the ozone state is saved in the space of ALTIUS previously determined with the ALTIUS orbit simulator, then perturbed according to the ALTIUS error budget, which creates ALTIUS synthetic observations. The assimilation of these ALTIUS ozone profiles agrees well with those of MLS. The assimilation of the different modes of ALTIUS reveals that all modes are necessary to constrain ozone during the polar night: solar and stellar occultations are the most constraining during the June-August period while limb scattering profiles are the most constraining from September onward.

 

How to cite: Errera, Q., Debosscher, J., Dekemper, E., Demoulin, P., Fussen, D., Piroux, D., Vanhellemont, F., and Mateshvili, N.: Observing System Simulation Experiment (OSSE) of future ALTIUS ozone profiles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18952, https://doi.org/10.5194/egusphere-egu2020-18952, 2020.

EGU2020-19315 | Displays | AS3.24

Comparison of ozone profiles from the Ozone Mapping and Profiles Suite with ozonesonde measurements over Antarctica during 2012-2019

Edgardo Sepulveda, Raúl Cordero, Alessandro Damiani, and Penny Rowe

The Ozone Mapping and Profiles Suite (OMPS), in orbit since October 2011 as a part of the Suomi National Polar-orbiting Partnership (Suomi NPP) Satellite includes three different spectral instruments for retrieving ozone distributions globally. One of those is the Limb Profiler (LP), which has made measurements since February 2012. The LP retrieves ozone profiles between approximately 12 km and 55 km of height.

Here we compare the OMPS LP version 2.5 ozone profiles with Electrochemical Concentration Cell (ECC) ozonesonde measurements from three Antarctic stations during the period 2012-2019: Marambio Station (-64.2413, -56.6266) on the Antarctic Peninsula, and Syowa Station (-68.3040, 49.6443) and Davis Station (-68.3110, 75.0222) in East Antarctica. The ozonesonde profiles include ozone concentration from the surface to an altitude of about 30 km. Thus, our comparisons are for altitudes of about 12 to 27 km.

During the period of highest ozone concentration (December – April), mean relative differences between OMPS LP and ozonesonde concentration typically change with height, ranging from -10% at 12-17 km altitude to 10% at 27 km altitude with slight variation between the three sites (e.g. Marambio has a higher standard deviation of 35% at 12 km). A mean relative difference of -5% is found for Syowa from about 15 km to 24 km, unlike Marambio and Davis, which have no clear difference at these heights.

Relative differences were also examined in September, when ozone concentrations are significantly lower due to the formation of the ozone hole, except for September 2019, which is excluded because a sudden stratospheric warming effect occurred. A mean relative difference of almost 30% is found in Marambio and Davis from about 12 km to 21 km, with a standard deviation of 100% at 18 km. The mean relative difference at Syowa is similar except that the relative difference peaks at almost 60% at 16 km. Marambio and Davis have similar biases above 21 km (10%), where the bias at Syowa is -5%.

How to cite: Sepulveda, E., Cordero, R., Damiani, A., and Rowe, P.: Comparison of ozone profiles from the Ozone Mapping and Profiles Suite with ozonesonde measurements over Antarctica during 2012-2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19315, https://doi.org/10.5194/egusphere-egu2020-19315, 2020.

EGU2020-19322 | Displays | AS3.24

Study of mountain-wave-induced stratospheric cooling over the Antarctic Peninsula using a parameterisation scheme in the UM-UKCA chemistry climate model

Andrew Orr, Scott Hosking, Aymeric Delon, Tracy Moffat-Griffin, Lars Hoffman, Reinhold Spang, Luke Abrahams, James Keeble, and Peter Braesicke

An important source of polar stratospheric clouds (PSCs), which play a crucial role in controlling polar stratospheric ozone depletion, is from the temperature fluctuations induced by mountain waves, enabling stratospheric temperatures to fall below the threshold value for PSC formation in the cold phases of these waves even if the synoptic-scale temperatures are too high. However, this formation mechanism is usually missing in chemistry–climate models because these temperature fluctuations are neither resolved nor parameterised. Here, we investigate the representation of parameterised stratospheric mountain-wave-induced temperature fluctuations over the Antarctic Peninsula from a 30-year run of the global chemistry-climate configuration of the UM-UKCA model against climatologies of Atmospheric Infrared Sounder (AIRS) radiance measurements and high-resolution radiosonde temperature soundings from Rothera. The results demonstrate that the local mountain wave-induced cooling phases computed by the scheme are in relatively good agreement with both sets of observations. For example, the scheme is able to capture the observed probability distribution of the temperature fluctuations, particularly the cold tails of the distribution that are critical for exceeding the temperature threshold for PSC formation. Further analysis shows that the increased stratospheric cooling induced by the scheme results in a large increase in total PSC ‘pseudo-volume’ of the area over the Antarctic Peninsula where the model temperature exceeds the temperature threshold of formation of PSCs.

How to cite: Orr, A., Hosking, S., Delon, A., Moffat-Griffin, T., Hoffman, L., Spang, R., Abrahams, L., Keeble, J., and Braesicke, P.: Study of mountain-wave-induced stratospheric cooling over the Antarctic Peninsula using a parameterisation scheme in the UM-UKCA chemistry climate model , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19322, https://doi.org/10.5194/egusphere-egu2020-19322, 2020.

AS4.2 – Large Ensemble Climate Models Simulations as Tools for Exploring Natural Variability, Change Signals, and Impacts

EGU2020-19303 | Displays | AS4.2 | Highlight

Using large ensembles to investigate the impacts of climate extremes

Nathalie Schaller

Large ensembles are key to investigate climate and weather extremes and their impacts, as they, by definition, rarely occur. One field that relies heavily on them is probabilistic event attribution, i.e. where one tries to quantify how human influence affects the probability of occurrence of the extreme event in question. An ensemble of over 130’000 members allowed us to quantify that human influence increased the probability of heavy precipitation by around 40% in the January 2014 floods in southern England. By using a hydrological model, we could then quantify that the probability of 30-day peak river flows of the Thames river was increased by around 20%. However, it was unclear whether the number of properties at risk in the catchment was affected. This study also showed how uncertainty increases at each step of the modelling chain and how some factors, like the characteristics of the Thames catchment in this case, might play a bigger role in assessing impacts than potentially the size of the ensemble.

Large ensembles are also useful to understand the physical mechanisms behind extreme events. In another study about the relationship between atmospheric blocking and heatwaves, we used three large ensembles from different climate models. While we found that the 2003 European heatwave and blocking conditions were well contained within the 3 ensembles’ envelope, and that the models simulated even more extreme events, the 2010 Russian event was outside the ensembles’ envelope, except for one single ensemble member.

Finally, I will present two projects, one on floods in Norway and one about the health impacts of having a heatwave combined with high air pollution, where large ensembles would be useful, but are competing with the need for high spatial resolution for computational resources.

How to cite: Schaller, N.: Using large ensembles to investigate the impacts of climate extremes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19303, https://doi.org/10.5194/egusphere-egu2020-19303, 2020.

EGU2020-18105 | Displays | AS4.2 | Highlight

The challenge of estimating high return levels with short records under large internal variability

Joel Zeder and Erich M. Fischer

The scientific understanding of changes in climate extremes is mostly limited to moderate definitions of extreme events occurring every few years, due to a lack of long-term observational daily data sets. In order to estimate return levels beyond observed time periods and event magnitudes, extreme events are typically modelled statistically based on extreme value theory. This is challenging since the short observational record may be affected by low-frequency natural internal variability and limits the block size that can be used.

Here we test some common assumptions in the statistical modelling of extremes based on indices of climatic extremes (Tx7d, Rx1d, Rx5d) using long pre-industrial control runs and initial-condition large ensembles with thousands of years of model data.

The tail of a distribution fitted to temperature and precipitation maxima is known to be highly sensitive to the compliance with statistical assumptions and choices such as the block size. Typically, 1-year block maxima are extracted from observational time series due to short record length. It is unclear whether these maxima are already in the domain of true extremes suitable for an extreme value analysis. Furthermore, the observational record is too short to sample low-frequency regional variability and potential transient changes in the mean climate. Standard uncertainty estimates (confidence intervals and hypothesis tests) are generally not accounting for potential biases introduced by a dominant mode of climate variability or violated modelling assumptions.

Based on a 4700-year pre-industrial control simulation and an 84-member ensemble performed with CESM 1.2.2 model, we systematically extend the statistical modelling of temperature and precipitation extremes to larger block-sizes and longer synthetic observational periods. This analysis reveals a considerable influence of climate variability on tail estimates. Furthermore, the use of too small block sizes can induce substantial random as well as systematic biases. Statistical model complexity and thus uncertainty further increases for extremes retrieved from transient large-ensemble members, as non-stationarity has to be accounted for in the model formulation. Thus, the potential of spatial pooling or conditioning on further climatic variables as proxies for a specific climatic mode to derive more robust tail estimates is also evaluated. Findings based on the CESM ensemble are compared with pre-industrial control runs performed with other models in CMIP6 and other initial-condition large ensembles of the CLIVAR large ensemble working group.

How to cite: Zeder, J. and Fischer, E. M.: The challenge of estimating high return levels with short records under large internal variability, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18105, https://doi.org/10.5194/egusphere-egu2020-18105, 2020.

EGU2020-13843 | Displays | AS4.2

How large does a large ensemble need to be?

Sebastian Milinski, Nicola Maher, and Dirk Olonscheck

Initial-condition large ensembles with ensemble sizes ranging from 30 to 100 members have become a commonly used tool to quantify the forced response and internal variability in various components of the climate system. However, there is no consensus on the ideal or even sufficient ensemble size for a large ensemble.

Here, we introduce an objective method to estimate the required ensemble size. This method can be applied to any given application. We demonstrate its use on the examples that represent typical applications of large ensembles: quantifying the forced response, quantifying internal variability, and detecting a forced change in internal variability.

We analyse forced trends in global mean surface temperature, local surface temperature and precipitation in the MPI Grand Ensemble (Maher et al., 2019). We find that 10 ensemble members are sufficient to quantify the forced response in historical surface temperature over the ocean, but more than 50 members are necessary over land at higher latitudes. 

Next, we apply our method to identify the required ensemble size to sample internal variability of surface temperature over central North America and over the Niño 3.4 region. A moderate ensemble size of 10 members is sufficient to quantify variability over North America, while a large ensemble with close to 50 members is necessary for the Niño 3.4 region.

Finally, we use the example of September Arctic sea ice area to investigate forced changes in internal variability. In a strong warming scenario, the variability in sea ice area is increasing because more open water near the coastlines allows for more variability compared to a mostly ice-covered Arctic Ocean (Goosse et al., 2009; Olonscheck and Notz, 2017). We show that at least 5 ensemble members are necessary to detect an increase in sea ice variability in a 1% CO2 experiment. To also quantify the magnitude of the forced change in variability, more than 50 members are necessary.

These numbers might be highly model dependent. Therefore, the suggested method can also be used with a long control run to estimate the required ensemble size for a model that does not provide a large number of realisations. Therefore, our analysis framework does not only provide valuable information before running a large ensemble, but can also be used to test the robustness of results based on small ensembles or individual realisations.

References
Goosse, H., O. Arzel, C. M. Bitz, A. de Montety, and M. Vancoppenolle (2009), Increased variability of the Arctic summer ice extent in a warmer climate, Geophys. Res. Lett., 36(23), 401–5, doi:10.1029/2009GL040546.

Olonscheck, D., and D. Notz (2017), Consistently Estimating Internal Climate Variability from Climate Model Simulations, J Climate, 30(23), 9555–9573, doi:10.1175/JCLI-D-16-0428.1.

Milinski, S., N. Maher, and D. Olonscheck (2019), How large does a large ensemble need to be? Earth Syst. Dynam. Discuss., 2019, 1–19, doi:10.5194/esd-2019-70.

How to cite: Milinski, S., Maher, N., and Olonscheck, D.: How large does a large ensemble need to be?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13843, https://doi.org/10.5194/egusphere-egu2020-13843, 2020.

EGU2020-4524 | Displays | AS4.2 | Highlight

A weighting scheme to incorporate large ensembles in multi-model ensemble projections

Anna Merrifield, Lukas Brunner, Ruth Lorenz, and Reto Knutti

Multi-model ensembles can be used to estimate uncertainty in projections of regional climate, but this uncertainty often depends on the constituents of the ensemble. The dependence of uncertainty on ensemble composition is clear when single model initial condition large ensembles (SMILEs) are included within a multi-model ensemble. SMILEs introduce new information into a multi-model ensemble by representing region-scale internal variability, but also introduce redundant information, by virtue of a single model being represented by 50–100 outcomes. To preserve the contribution of internal variability and ensure redundancy does not overwhelm uncertainty estimates, a weighting approach is used to incorporate 50-members of the Community Earth System Model (CESM1.2.2), 50-members of the Canadian Earth System Model (CanESM2), and 100-members of the MPI Grand Ensemble (MPI-GE) into an 88-member Coupled Model Intercomparison Project Phase 5 (CMIP5) multi-model ensemble. The weight assigned to each multi-model ensemble member is based on the member's ability to reproduce observed climate (performance) and scaled by a measure of historical redundancy (dependence). Surface air temperature (SAT) and sea level pressure (SLP) diagnostics are used to determine the weights, and relationships between present and future diagnostic behavior are discussed. A new diagnostic, estimated forced trend, is proposed to replace a diagnostic with no clear emergent relationship, 50-year regional SAT trend.

The influence of the weighting is assessed in estimates of Northern European winter and Mediterranean summer end-of-century warming in the CMIP5 and combined SMILE-CMIP5 multi-model ensembles. The weighting is shown to recover uncertainty obscured by SMILE redundancy, notably in Mediterranean summer. For each SMILE, the independence weight of each ensemble member as a function of the number of SMILE members included in the CMIP5 ensemble is assessed. The independence weight increases linearly with added members with a slope that depends on SMILE, region, and season. Finally, it is shown that the weighting method can be used to guide SMILE member selection if a subsetted ensemble with one member per model is sought. The weight a SMILE receives within a subsetted ensemble depends on which member is used to represent it, reinforcing the advantage of weighting and incorporating all initial condition ensemble members in multi-model ensembles.

How to cite: Merrifield, A., Brunner, L., Lorenz, R., and Knutti, R.: A weighting scheme to incorporate large ensembles in multi-model ensemble projections, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4524, https://doi.org/10.5194/egusphere-egu2020-4524, 2020.

EGU2020-19202 | Displays | AS4.2

What can we learn from single model initial-condition large ensembles (SMILEs)? A Comparison of Multiple SMILEs for Precipitation

Raul R. Wood, Flavio Lehner, Angeline Pendergrass, Sarah Schlunegger, and Keith Rodgers

Identifying anthropogenic influences on climate amidst the “noise” of internal climate variability is a central challenge for the climate research community. In recent years, several modeling groups have produced single-model initial-condition large ensembles (SMILE) to analyze the interplay of the forced climate change and internal climate variability under current and future climate conditions. These simulations help to improve our understanding of climate variability, including extreme events, and can be employed as test-beds for statistical approaches to separate forced and internal components of climate variability.

So far, most studies have focused on either an individual or a  limited number of SMILEs. In this work we compare seven large ensembles to disentangle the influence of internal variability and model response uncertainty for multiple precipitation indices (e.g. wettest day of the year, precipitation with a return period of 20 years). What can we learn from intercomparison of SMILEs, how similar are they in terms of spatial patterns and forced response, and what if they aren’t? How does the forced response of an ensemble of SMILEs compare to the CMIP5 multi-model ensemble? By assessing multiple SMILEs we can identify robust signals for regional and global precipitation properties and revealing anthropogenic responses that are inherent to our current representations of the Earth system.

How to cite: Wood, R. R., Lehner, F., Pendergrass, A., Schlunegger, S., and Rodgers, K.: What can we learn from single model initial-condition large ensembles (SMILEs)? A Comparison of Multiple SMILEs for Precipitation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19202, https://doi.org/10.5194/egusphere-egu2020-19202, 2020.

EGU2020-7674 | Displays | AS4.2 | Highlight

Current Risk of Extreme Monsoon Rainfall over India using Large Ensemble Simulations

Shipra Jain, Adam A Scaife, Nick Dunstone, Doug Smith, Saroj K Mishra, and Ruth Doherty

India suffers from severe social-economic losses due to floods and droughts during boreal summer (June-September) and therefore there is a growing interest in the current risk of extreme monsoon rainfall. In this analysis, we estimate the risk of flood, drought and unprecedented (outside the range of present observational record) rainfall over India using UNprecedented Simulated Extremes using ENsembles (UNSEEN) method. The UNSEEN is a statistical framework under which the risk of unprecedented rainfall extremes can be estimated using a large ensemble of initialized climate simulations to sample a broad range of internal variability. This is the first application of the method to the hindcasts from multiple coupled atmosphere-ocean models. Under this method, we first test individual models against the observed rainfall record over India and select models that are statistically indistinguishable from observations. The risk of floods, droughts and unprecedented rainfall is then estimated using a large ensemble of summer precipitation simulated by the selected set of models. We note that in present climate the risk of drought is higher than the flood, with droughts being more frequent and intense than the floods. This asymmetry in rainfall extremes is found to be partly due to the asymmetry in El-Nino Southern Oscillation (ENSO) phase, with El Nino reaching higher magnitude more frequently than La Nina. The current risk of record breaking drought (>23% deficit w.r.t climatological mean) is 1.6% whereas the risk for record-breaking flood (>16% excess) is 2.6%. There is even a risk of 30% rainfall deficit that could occur around once in two centuries, which is not yet seen in observations and would have a catastrophic influence on India.

How to cite: Jain, S., Scaife, A. A., Dunstone, N., Smith, D., Mishra, S. K., and Doherty, R.: Current Risk of Extreme Monsoon Rainfall over India using Large Ensemble Simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7674, https://doi.org/10.5194/egusphere-egu2020-7674, 2020.

EGU2020-2180 | Displays | AS4.2 | Highlight

Inherent Uncertainty Disguises Attribution of Reduced Atmospheric CO2 Growth to Mitigation for up to a Decade

Aaron Spring, Tatiana Ilyina, and Jochem Marotzke

On inter-annual time scales the growth rate of atmospheric CO2 is largely driven by the response of the land and ocean carbon sinks to climate variability. Therefore, climate mitigation in terms of emission reductions can be disguised by internal variability.
However, the probability that emission reductions induced by a policy change caused reductions in atmospheric CO2 growth trend is unclear.
We use 100 historical MPI-ESM simulations and interpret mitigation in 2020 as a policy shift from Representative Concentration Pathway 4.5 to 2.5 in a comprehensive causation attribution framework.
Here we show that five-year CO2 trends are higher in 2021-2025 than over 2016-2020 in 30% of all realizations in the mitigation scenario, compared to 52% in the non-mitigation scenario. Therefore, mitigation is sufficient or necessary to cause these trends by 42% or 31%, respectively and therefore far from certain.
A stronger increase in atmospheric CO2 trends despite emission reductions is possible when the global carbon cycle triggered by internal climate variability releases more CO2 than mitigation saves. Such trends might occur for of up to ten years. Certainty that mitigation causes trend reductions is only reached after ten or fifteen years, respectively of the type of causation.
Our analysis showcases the inherent uncertainty of near-term CO2 projections. Assessments of the efficacy of mitigation in the near term are incomplete without quantitatively considering internal variability.

How to cite: Spring, A., Ilyina, T., and Marotzke, J.: Inherent Uncertainty Disguises Attribution of Reduced Atmospheric CO2 Growth to Mitigation for up to a Decade, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2180, https://doi.org/10.5194/egusphere-egu2020-2180, 2020.

Surface air temperature outputs from 16 global climate models (GCMs) participating in the sixth phase of the Coupled Model Intercomparison Project (CMIP6) were used to evaluate agreement with observations over the global land surface for the period 1901–2014. Projections of Bayesian model averaging (BMA) multi-model ensembles under four different Shared Socioeconomic Pathways (SSPs) were also examined. The results reveal that the majority of models reasonably capture the dominant features of the spatial changes in observed temperature with a pattern correlation typically greater than 0.98. However, most models underestimate annual temperature over northeastern North America and overestimate it over central Eurasia. In addition, most CMIP6 models overestimate the warming trend in most regions. The BMA multi-model ensembles show more agreement than individual models do in simulating the spatial patterns of the temperature, but with less spatial variability compared with the observations. In the 21st century, temperature is generally projected to increase over the global land surface under all four SSP scenarios. By the end of the 21st century, temperature is projected to increase by 1.35 °C/100 yr, 3.61 °C/100 yr, 6.39 °C/100 yr and 8.03 °C/100 yr under the SSP1-2.6, SSP2-4.5, SSP3-7.0 and SSP5-8.5 scenarios, respectively, with greater warming projected over the high latitudes of the northern hemisphere and weaker warming over the tropics and the southern hemisphere.

How to cite: Fan, X.: Global surface air temperatures in CMIP6: Historical performance and future, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5436, https://doi.org/10.5194/egusphere-egu2020-5436, 2020.

Recent studies indicated that the internal climate variability plays an important role in various aspects of projected climate changes on regional and local scales. Here we present results of the spreads in projected trends of wintertime North American surface air temperature and extremes indices of warm and cold days over the next half-century, by analyzing a 50-member large ensemble of climate simulations conducted with CanESM2. CanESM2 simulations confirm the important role of internal variability in projected surface temperature trends as demonstrated in previous studies. Yet the spread in North American warming trends in CanESM2 is generally smaller than those obtained from CCSM3 and ECHAM5 large ensemble simulations. Despite this, large spreads in the climate means as well as climate change trends of North American temperature extremes are apparent in CanESM2, especially in the projected cold day trends. The ensemble mean of forced climate simulations reveals high risks of warm days over the western coast and north Canada, as well as a weakening belt of cold days extending from Alaska to the northeast US. The individual ensemble members differ from the ensemble mean mainly in magnitude of the warm day trends, but depart from the ensemble mean in conspicuous ways, including spatial pattern and magnitude, of the cold day trends. The signal-to-noise ratio pattern of the warm day trend resembles that of the surface air temperature trend; with stronger signals over north Canada, Alaska, and the southwestern US than the midsection of the continent. The projected cold day patterns reveal strong signals over the southwestern US, north Canada, and the northeastern US. In addition, the internally generated components of temperature and temperature extreme trends exhibit spatial coherences over North America, and are comparable to the externally forced trends. The large-scale atmospheric circulation-induced temperature variability influences these trends. Overall, our results suggest that climate change trends of North American temperature extremes are likely very uncertain and need to be applied with caution.

How to cite: Yu, B., Li, G., Chen, S., and Lin, H.: The role of internal variability in climate change projections of North American surface air temperature and temperature extremes in CanESM2 large ensemble simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5854, https://doi.org/10.5194/egusphere-egu2020-5854, 2020.

EGU2020-21864 | Displays | AS4.2

Partitioning uncertainty components of an incomplete ensemble of climate projections using data augmentation

Benoit Hingray, Guillaume Evin, Juliette Blanchet, Nicolas Eckert, Samuel Morin, and Deborah Verfaillie

The quantification of internal variability and model uncertainty sources in Multi-scenario Multi-model Ensembles of climate experiments (MMEs) is a key issue. It is expected to both help decision makers to identify robust adaptation measures and scientists to identify where their efforts are needed to narrow uncertainty. The setup of available MMEs makes however uncertainty analyses difficult. In the popular single-time ANOVA approach for instance, a precise estimate of internal variability requires multiple members for each simulation chain (e.g. each emission scenario/climate model combination) but multiple members are typically available for a few chains only (Hingray et al. 2019). In almost all ensembles also, the matrix of available scenario/models combinations is incomplete making a precise estimate of the main effects of each model difficult (e.g. projections are typically missing for some GCM/RCM combinations) (Evin et al. 2019).

We present QUALYPSO, a Bayesian approach developed to assess the different sources of uncertainty in incomplete MMEs (Evin et al. submitted). It is based on the quasi-ergodic assumption for transient climate projections and uses data augmentation (Hingray and Said, 2014). The climate response of each available simulation chain is first estimated with a trend model fitted to raw climate projections. Residuals from the climate change response are used to estimate the internal variability of the chain. Scenario uncertainty and the different components of model uncertainty (e.g. GCM uncertainty, RCM uncertainty) are then estimated with a Bayesian ANOVA model applied to the climate change responses of all available chains. The different parameters of the ANOVA model and the missing quantities associated to the missing chains (e.g. missing scenario/GCM/RCM combinations) are jointly estimated using data augmentation techniques.

QUALYPSO presents many advantages over classical estimation approaches. It first exploits all available experiments, avoiding a dramatic loss of information (the classical case when standard approaches are applied; where the typical solution is to select a complete subset of climate experiments). Along with the estimation of missing data, it also provides an assessment of the estimation uncertainty and adequately propagates the uncertainty due to missing chains. With the explicit treatment of missing experiments, it is then expected to produce unbiased estimates of all parameters, in contrast to direct empirical estimates.

QUALYPSO can be applied to any kind of climate variable and any kind of MMEs. We present examples of application for different hydroclimatic variables from different ensembles of projections including EUROCORDEX and CORDEX-Africa.

Hingray, B., Saïd, M., 2014. Partitioning internal variability and model uncertainty components in a multimodel multireplicate ensemble of climate projections. J.Climate.

Hingray, B., Blanchet, J., Evin, G. Vidal, J.P. 2019. Uncertainty components estimates in transient climate projections. Precision of estimators in the single time and time series approaches. Clim.Dyn.

Evin, G., Hingray, B., Blanchet, J., Eckert, N., Morin, S., Verfaillie, D. 2019. Partitioning uncertainty components of an incomplete ensemble of climate projections using data augmentation. J.Climate.

Evin, G., Hingray, B. Blanchet, J., Eckert, N., Menegoz, M. Morin, S. (revision). Partitioning uncertainty components of an incomplete ensemble of climate projections using smoothing splines. J.Climate.

How to cite: Hingray, B., Evin, G., Blanchet, J., Eckert, N., Morin, S., and Verfaillie, D.: Partitioning uncertainty components of an incomplete ensemble of climate projections using data augmentation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21864, https://doi.org/10.5194/egusphere-egu2020-21864, 2020.

EGU2020-6081 | Displays | AS4.2

Which climate models capture the variability and forced response in observed temperatures: a large ensemble comparison

Nicola Maher, Laura Suarez-Gutierrez, and Sebastian Milinski

We evaluate how large ensembles of ten coupled climate models represent the observed internal variability and response to external forcings in historical surface temperatures based on a novel methodological framework. This framework allows us to directly attribute whether discrepancies between models and observations arise due to biases in the simulated internal variability or rather in the forced response, without relying on assumptions to separate both signals in the observations. The largest discrepancies occur due to overestimated forced warming in some models during recent decades. The areas where most models, a maximum of nine, adequately simulate observed temperatures are the North Atlantic, Tropical Eastern Pacific, and the Northern Hemisphere land areas. In contrast, none of the models considered offers an adequate representation over the Southern Ocean. Our evaluation shows that CESM-LE, GFDL-ESM2M, and MPI-GE perform best at representing the internal variability and forced response in observed surface temperatures both globally and regionally. 

How to cite: Maher, N., Suarez-Gutierrez, L., and Milinski, S.: Which climate models capture the variability and forced response in observed temperatures: a large ensemble comparison, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6081, https://doi.org/10.5194/egusphere-egu2020-6081, 2020.

EGU2020-5991 | Displays | AS4.2

Partitioning climate projection uncertainty with multiple Large Ensembles and CMIP5/6

Flavio Lehner, Clara Deser, Nicola Maher, Jochem Marotzke, Erich Fischer, Lukas Brunner, Reto Knutti, and Ed Hawkins

Partitioning uncertainty in projections of future climate change into contributions from internal variability, model response uncertainty, and emissions scenarios has historically relied on making assumptions about forced changes in the mean and variability. With the advent of multiple Single-Model Initial-Condition Large Ensembles (SMILEs), these assumptions can be scrutinized, as they allow a more robust separation between sources of uncertainty. Here, we revisit the framework from Hawkins and Sutton (2009) for uncertainty partitioning for temperature and precipitation projections using seven SMILEs and the Climate Model Intercomparison Projects CMIP5 and CMIP6 archives. We also investigate forced changes in variability itself, something that is newly possible with SMILEs. The available SMILEs are shown to be a good representation of the CMIP5 model diversity in many situations, making them a useful tool for interpreting CMIP5. CMIP6 often shows larger absolute and relative model uncertainty than CMIP5, although part of this difference can be reconciled with the higher average transient climate response in CMIP6. This study demonstrates the added value of a collection of SMILEs for quantifying and diagnosing uncertainty in climate projections.

How to cite: Lehner, F., Deser, C., Maher, N., Marotzke, J., Fischer, E., Brunner, L., Knutti, R., and Hawkins, E.: Partitioning climate projection uncertainty with multiple Large Ensembles and CMIP5/6, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5991, https://doi.org/10.5194/egusphere-egu2020-5991, 2020.

EGU2020-7807 | Displays | AS4.2

Understanding the distribution of multi-model ensembles

Bo Christiansen

Ensembles of model experiments have become the standard tool both in studies of climate change and in studies of prediction on many different time-scales. When analyzing such ensembles the mean of the ensemble is often interpreted as the best estimate and the spread of the ensemble as an estimate of the uncertainty.  Naively we might argue that the error of the ensemble mean would approach zero as the size of the ensemble increases. However, this argument is based on the assumption that the ensemble is centered around the observations - the truth-plus-error interpretation. A competing assumption - the indistinguishable interpretation -- holds that the observations and the models are all drawn from the same distribution.

The rationale for the truth centered interpretation is that it is the situation that would be expected after calibration of statistical models. However, for multi-model ensembles of climate models there is an increasing amount of evidence pointing towards the indistinguishable interpretation. But why should the indistinguishable interpretation hold for an ensemble that basically is a representation of our incomplete knowledge of the climate system?

Here we analyze CMIP5 ensembles focusing on three measures that separate the two interpretations: the error of the ensemble mean relative to the error of individual models, the decay of the ensemble mean error for increasing ensemble size, and the correlations of the model errors. To get more freedom in our analysis we use a simple statistical model where observations and models are drawn from distributions with different variances and which include a bias. The two interpretations can be found as limits of this more comprehensive model  for which analytical results can be found using the simplifying properties of high dimensional space (the blessing of dimensionality).

We find that the indistinguishable interpretation becomes an increasingly better assumption when the errors are based on smaller and smaller temporal and spatial scales. Building on this, we present a simple conceptual mechanism for the indistinguishable interpretation based on the assumption that the climate models are calibrated or tuned on large scale features such as, e.g., annual means or global averages.

How to cite: Christiansen, B.: Understanding the distribution of multi-model ensembles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7807, https://doi.org/10.5194/egusphere-egu2020-7807, 2020.

Weather or climate extreme events disproportionately affect societies and ecosystems. Physical understanding of the impact of global climate change on the occurrence of such extreme events is therefore crucial. Here we separate changes in the occurrence of high-temperature and heavy-precipitation events in a part caused by climatic changes of the mean state and a part caused by climatic changes in variability. We extend the frequently used Probability Ratio (PR) framework, used to quantify changes in the occurrence of extreme events, such that it produces a 'PRmean' value for changes due to a change in mean climate and a 'PRvar' value for changes due to changes in climate variability. Large ensemble climate model simulations are used to quantify changes in extreme events in a 2C warmer world. It is found that the increased occurrence of high-temperature extremes is predominantly caused by the increase of mean temperatures, with a much smaller role for changes in variability (PRmean >> PRvar). The spatial differences are considerable, however, with the polar regions standing out as regions where changes in temperature variability do have a considerable limiting effect on extreme event occurrence. Changes in heavy-precipitation extremes are generally due to changes in both mean climate and variability (PRvar ≈ PRmean). Despite complex feedbacks in the global climate system, the ratio of PRmean to PRvar is largely independent of the event threshold and the climate scenario. These results help to quantify robustness of projected changes in climate extremes, given that projections of changes in the mean state are in many cases much better constrained than projections of changes in variability.

How to cite: van der Wiel, K. and Bintanja, R.: Contribution of climatic changes in means and variability to temperature and precipitation extremes, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7852, https://doi.org/10.5194/egusphere-egu2020-7852, 2020.

EGU2020-7119 | Displays | AS4.2

Comparing inter-annual variabilities in three regional single model initial-condition large ensembles (SMILE) over Europe

Fabian von Trentini, Emma E. Aalbers, Erich M. Fischer, and Ralf Ludwig

Single model large ensembles are widely used model experiments to estimate internal climate variability (here: inter-annual variability). The underlying assumption is that the internal variability of the chosen model is a good approximation of the observed natural variability. In this study, for the first time over Europe, we test this assumption based on the comparison of three regional climate model large ensembles (16 members of an EC-EARTH-RACMO ensemble, 21 members of a CESM-CCLM ensemble, 50 members of a CanESM-CRCM ensemble) for four European domains (British Isles, France, Mid-Europe, Alps). Simulated inter-annual variability is evaluated against E-OBS and the inter-annual variability and its future change are compared across the ensembles. Analyses comprise seasonal temperature and precipitation, as well as indicators for dry periods and heat waves. Results show a large consistency of all three ensembles with E-OBS data for most indicators and regions, validating the abilities of these ensembles to represent natural variability on the annual scale. EC-EARTH-RACMO shows the highest inter-annual variability for winter temperature and precipitation, whereas CESM-CCLM shows the highest variability for summer temperature and precipitation, as well as for heatwaves and dry periods. Despite these model differences, the sign of the future changes in internal variability is largely the same in all models: for summer temperature, summer precipitation and the number of heat waves, the internal variability increases, while it decreases for winter temperature. While dry periods reveal a tendency to increase in variability, the changes of winter precipitation remain less conclusive. The overall consistency across single model large ensembles and observations strengthens the concept of large ensembles, and underlines their great potential for understanding and quantifying internal climate variability and its role in climate change dynamics.

How to cite: von Trentini, F., Aalbers, E. E., Fischer, E. M., and Ludwig, R.: Comparing inter-annual variabilities in three regional single model initial-condition large ensembles (SMILE) over Europe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7119, https://doi.org/10.5194/egusphere-egu2020-7119, 2020.

EGU2020-6015 | Displays | AS4.2

Unprecedented Expansion of the Azores High due to Anthropogenic Climate Change

Nathaniel Cresswell-Clay, Caroline C. Ummenhofer, Diana L. Thatcher, Alan D. Wanamaker, and Rhawn F. Denniston

The Azores High is a subtropical high-pressure ridge in the North Atlantic. During boreal winters, anticyclonic winds rotate around the Azores High, transporting moisture to Western Europe. Variability in the size and intensity of the Azores High thus corresponds to variability in hydroclimate across Western Europe. We use the Last Millennium Ensemble (LME), which is run using the Community Earth System Model (CESM) and features thirteen transient simulations covering the period 850 to 2005 A.D. with prescribed external forcing (e.g. greenhouse gas, solar, volcanic, land use, orbital, and aerosol). The LME is shown to accurately simulate the variability and trends in the Azores High when compared to observational records from the 20th century. The Azores High has grown in size during the Industrial Era. This growth is most dramatic when observing the frequency of winters during which the Azores High is extremely large. The LME shows more winters with an extremely large Azores High in the past 100 years than any other 100-year period in the last millennium. Using LME as well as other simulations from the Paleoclimate Modelling Intercomparison Project Phase III, the recent expansion of the Azores High is shown to be well outside the range of natural variability since 850 A.D. Individual forcing simulations within the LME provide smaller ensembles in which only one external forcing is varied. These experiments attribute Azores High expansion to the recent increase in atmospheric greenhouse gas concentrations. Recent hydroclimatic signals across Western Europe consistent with the Azores High variability are also discussed.

How to cite: Cresswell-Clay, N., Ummenhofer, C. C., Thatcher, D. L., Wanamaker, A. D., and Denniston, R. F.: Unprecedented Expansion of the Azores High due to Anthropogenic Climate Change, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6015, https://doi.org/10.5194/egusphere-egu2020-6015, 2020.

EGU2020-17931 | Displays | AS4.2

Future changes of circulation types associated with extremes over Sweden

Felicitas Hansen, Danijel Belusic, and Klaus Wyser

The large-scale atmospheric circulation is one of the most important factors influencing weather and climate conditions on different timescales. Its short- and long-term changes considerably determine both mean and extreme values of surface parameters like temperature or precipitation rates. Future changes of circulation patterns are of particular interest as these may significantly alter or amplify the expected thermodynamic changes due to changing concentrations of greenhouse gases, albedo and land use. We analyse both historical as well as future climate simulations of the SMHI large ensemble (S-LENS) performed with the EC-Earth3 global climate model to examine large-scale circulation situations and their association to extremes in precipitation and temperature over Sweden. Various methods exist to classify mostly sea level pressure or geopotential height fields into characteristic circulation types, and we compare several of these methods for their applicability to represent precipitation and temperature variability over our region of interest. S-LENS consists of a 50-member ensemble for a historical period (1970-2014) and four 50-member climate change scenario ensembles covering the 21st century differing in terms of assumptions made for future radiative forcing development. We study the efficiency of circulation types in the historical period to give rise to extremes, and examine further the frequency and within-type changes of those circulation types associated with extremes by the middle and the end of the 21st century under the different climate change scenarios. S-LENS with its comparatively large number of both multi-decadal scenarios and realizations for each scenario serves as a perfect testbed to study potential changes in events of low frequency within the environment of a single model.

How to cite: Hansen, F., Belusic, D., and Wyser, K.: Future changes of circulation types associated with extremes over Sweden, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17931, https://doi.org/10.5194/egusphere-egu2020-17931, 2020.

EGU2020-8760 | Displays | AS4.2 | Highlight

A consistent multi-method global extreme event attribution framework

Karsten Haustein, Benjamin Strauss, Sihan Li, and Friederike Otto

In order to streamline observational and global climate model based extreme event attribution techniques, we propose a multi-method framework which drastically increases the robustness of rapid attribution studies, hence further facilitating the communication of extreme weather related risks across the globe.

We use advanced observational datasets for temperature (Berkeley Earth) and rainfall (CPC), together with CMIP5 simulations and the large HadRM3P ensemble from the weather@home project (W@H) Recent (Climatology) and current/future warming scenarios (1°C, 1.5°C, 2°C, 3°C and 4°C) are juxtaposed to pre-industrial (Natural) baseline conditions.

Two scaling approaches are applied to the observational data to estimate the statistics of future warming scenarios. One in which percentiles of the metric of interest (Tmax, Tmin, Precip) are scaled with Global Mean Surface Temperature (GMST) and another in which the mean is scaled against GMST. Model subsetting (similar to the HAPPI experiment) as function of GMST is applied to the CMIP5 data in order to assign the warming thresholds. W@H scenarios are prescribed to achieve the desired warming threshold. We analyse the results in terms of classes of events, using percentiles, absolute and return-time based thresholds. Before the subsetting, model biases are removed means of quantile-mapping (both for CMIP5 and W@H).

The results between both scaling methods and model subsetting are mostly consistent across many regions and virtually for all temperature thresholds under consideration. The percentile-based scaling method does, however, reveal that the tail of the distributions (highest Tmax, lowest Tmin) has potentially widened with warming. Overall, we find that historically rare extreme events become increasingly common in the future as far as Tmax and Precip is concerned. In contrast, cold extremes become increasingly rare.

How to cite: Haustein, K., Strauss, B., Li, S., and Otto, F.: A consistent multi-method global extreme event attribution framework, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8760, https://doi.org/10.5194/egusphere-egu2020-8760, 2020.

EGU2020-7855 | Displays | AS4.2 | Highlight

The extreme warm summer 2018 in Sweden - set in a historical context

Renate Wilcke, Erik Kjellström, Anders Moberg, and Changgui Lin

Long-lasting high-pressure dominated weather resulting in remarkably warm and dry conditions in large parts of northern Europe during summer 2018. As a consequence, Sweden experienced a very long warm period with an unusual high number of warm days, which could be felt in many parts of the society. Groundwater shortage, many extensive forest fires (requiring assistance on European scale), health impacts on people, drought related shortage of food for livestock leading to emergency slaughter in many regions.According to SMHIs weather observations the average over Sweden for the four-month period May-August was on average 3.3K warmer than the 1961-1990 climatological mean.

Here, we evaluate climate conditions in Sweden during the summer 2018 in relation to the historical climate, reaching back to pre-industrial times. Basing the evaluation on long observation time series (150 years for some station across Sweden, and 250 years for Stockholm) as well as on 5 large ensembles from different global models, we want to assess to what extent an extreme event like the summer of 2018 may have changed as a result of global warming.

To grasp the character of summer 2018, not only daily values are considered, but also periods of heat days and heat indices describing the amplitude and length of an event.

With the extended length of the summer season, on account of an exceptional warm May, 2018 sets its record for many heat related indices and would have very unlikely been observed in pre-industrial times according to the given model data.

How to cite: Wilcke, R., Kjellström, E., Moberg, A., and Lin, C.: The extreme warm summer 2018 in Sweden - set in a historical context, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7855, https://doi.org/10.5194/egusphere-egu2020-7855, 2020.

EGU2020-9835 | Displays | AS4.2

Crossbreeding Earth System Models with an Emulator for Regionally-optimized Land Temperature Projections

Lea Beusch, Lukas Gudmundsson, and Sonia I. Seneviratne

Earth System Models (ESMs) are invaluable tools to study the climate system’s response to a specific greenhouse gas emission scenario, but their projections are associated with internal climate variability and model uncertainty. To account for these uncertainties, large single-model initial-condition ensembles and multi-model ensembles are created and observations are used to constrain their projections. However, ensemble size is usually limited since ESM simulations are computationally costly. Climate change impact and integrated assessment models, on the other hand, could profit from more realizations which are consistent with observations and the associated improved sampling of the constrained phase space.

Here, we employ MESMER, a Modular Earth System Model Emulator with spatially Resolved output, to generate stochastic realizations of land temperature field time series at a yearly resolution at a negligible computational cost (Beusch et al., 2019). MESMER successfully approximates large multi-model initial-condition ensembles on grid-point to regional scales if it is trained with runs from each contained ESM. Here, we create 1000 emulations per ESM for models of the 6th phase of the Coupled Model Intercomparison Project (CMIP6) covering the historical time period and the high-end emission scenario SSP585 (1870 – 2100) (Beusch et al., submitted). The resulting ensemble is referred to as a “superensemble”.

The modular framework of MESMER opens new avenues for validating and constraining ESM ensembles (Beusch et al., submitted). Within the emulator, the local warming signal is expressed as a combination of the global mean temperature trend and the local response to this global trend. These two features can be validated separately by comparison to observations. It is found that ESMs which perform well in terms of global mean temperature trend do not necessarily perform well in terms of local response and vice versa. Additionally, different ESMs perform well in different regions. The most naive approach would be to base temperature projections solely on ESMs which perform well on both global and regional scales. However, this would result in discarding valuable information from many ESMs which perform well at only one of the scales. To circumvent this issue, we therefore propose to use MESMER to combine all global mean temperature trends with all local modules that are consistent with observations. Thereby, we obtain a regionally-optimized “crossbred” superensemble which constitutes a large recombined multi-model initial-condition ensemble and makes full use of all ESM features which are consistent with observations. The regionally diverse behavior of the crossbred superensemble highlights the importance of considering spatially resolved temperature projections.

 

L. Beusch, L. Gudmundsson, and S. I. Seneviratne: Emulating Earth System Model Temperatures: from Global Mean Temperature Trajectories to Grid-point Level Realizations on Land, doi: 10.5194/esd-2019-34, 2019 (accepted for ESD).

L. Beusch, L. Gudmundsson, and S. I. Seneviratne: Crossbreeding CMIP6 Earth System Models with an Emulator for Regionally-optimized Land Temperature Projections, submitted.

How to cite: Beusch, L., Gudmundsson, L., and Seneviratne, S. I.: Crossbreeding Earth System Models with an Emulator for Regionally-optimized Land Temperature Projections, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9835, https://doi.org/10.5194/egusphere-egu2020-9835, 2020.

The ClimEx-project ("Climate change and hydrological extreme events"; www.climex-project.org) provides a single-model initial-condition ensemble that is unprecedented in terms of size, resolution and domain coverage: 50 members of the Canadian Earth System Model version 2 (CanESM2 Large Ensemble, 2.8° spatial resolution) are downscaled using the Canadian Regional Climate Model version 5 (CRCM5 Large Ensemble, 0.11° spatial and up to hourly temporal resolution) over two domains, Europe and northeastern North America. The high-resolution climate information serves as input for hydrological simulations to investigate the impact of internal variability and climate change on hydrometeorological extremes.

This study evaluates the downscaling of a teleconnection which affects northern hemisphere climate variability, the North Atlantic Oscillation (NAO), within the nested single-model large ensemble of the ClimEx project. The overall goal of this study is to assess whether the range of NAO internal variability is represented consistently between the driving global climate model (GCM, i.e., the CanESM2) and the nested regional climate model (RCM, i.e., the CRCM5).

The NAO pressure dipole is quantified in the CanESM2-LE; responses of mean surface air temperature and total precipitation sum to changes in the NAO index are evaluated within a Central European domain in both the CanESM2-LE and the CRCM5-LE. NAO–response relationships are expressed via Pearson correlation coefficients and the change per unit index change for historical (1981–2010) and future (2070–2099) winters.

Results show that statistically robust NAO patterns are found in the CanESM2-LE under current forcing conditions, and reproductions of the NAO flow pattern present in the CanESM2-LE produce plausible temperature and precipitation responses in the high-resolution CRCM5-LE. The NAO–response relationship is more strongly evolved in the CRCM5-LE than in the CanESM2-LE, but the inter-member spread shows no significant differences: thus internal variability expressed as inter-member spread can be seen as being represented consistently between the GCM and RCM. NAO–response relationships weaken in the future period in both the CanESM2-LE and CRCM5-LE, suggesting that the NAO influence on Central European temperature and precipitation decreases.

The results stress the advantages of a single-model ensemble regarding the evaluation of internal variability. They also strengthen the validity of the nested ensemble for further impact modelling using RCM data only, since important large-scale teleconnections present in the driving GCM propagate properly to the fine scale dynamics in the RCM.

How to cite: Böhnisch, A., Ludwig, R., and Leduc, M.: Using a nested single-model large ensemble to assess the internal variability of the North Atlantic Oscillation and its climatic implications for Central Europe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4925, https://doi.org/10.5194/egusphere-egu2020-4925, 2020.

In this study, a methodology that uses super ensemble simulation with appropriate bias correction for river planning was proposed. The Database for Policy Decision-Making for Future Climate Change (d4PDF) is a super ensemble experiments that comprise over 1000-year output have been conducted. The d4PDF provides regional downscaling simulation that focuses around Japan. It is expected that the impact assessments of climate changes on various fields considering uncertainly are conducted.

The impact of climate change on floods is a serious issue. In Japan, all class A river has design rainfall for the river planning that is defined considering historical observations of precipitation that happens once in several hundred years, which the planning year is different depending on the situation of a river. The design rainfall provides the fundamental information for planning river management.  The Ministry of Land, Infrastructure, Transportation and Tourism defines the value of the rainfall in the planning year in each class A river basin by considering the hydro-meteorological and social characteristics of each basin. As the design rainfall was defined in the mid-1900s for most of the rivers, the method to estimate precipitation in the planning year was conducted with limited observation data using extreme statistical value. The super ensemble simulation data is expected to contribute for the decision making with appropriate setting of design rainfall.

We proposed a method to correct the bias of super ensemble simulation and estimated the design rainfall in 47 river basins selected from class A river basins. The estimated design rainfall was compared between the one estimated with super ensemble simulation and the one estimated with conventional approach. The spread of results oriented from super ensemble simulation indicated that uncertainly of design rainfall estimated with conventional approach was so high that the consideration of uncertainty is necessary for river planning. The experiments indicated that the use of super ensemble simulation with appropriate bias correction could provide knowledge that aids us in understanding the hydrological extremes.

How to cite: Watanabe, S.: An application of super ensemble simulation with appropriate bias correction for river planning in Japan, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12875, https://doi.org/10.5194/egusphere-egu2020-12875, 2020.

EGU2020-10895 | Displays | AS4.2

Multi-thousand member ensemble atmospheric simulations with global 60km resolution using climateprediction.net

Peter Watson, Sarah Sparrow, William Ingram, Simon Wilson, Drouard Marie, Giuseppe Zappa, Richard Jones, Daniel Mitchell, Tim Woollings, and Myles Allen

Multi-thousand member climate model simulations are highly valuable for showing how extreme weather events will change as the climate changes, using a physically-based approach. However, until now, studies using such an approach have been limited to using models with a resolution much coarser than the most modern systems. We have developed a global atmospheric model with 5/6°x5/9° resolution (~60km in middle latitudes) that can be run in the climateprediction.net distributed computing system to produce such large datasets. This resolution is finer than that of many current global climate models and sufficient for good simulation of extratropical synoptic features such as storms. It will also allow many extratropical extreme weather events to be simulated without requiring regional downscaling. We will show that this model's simulation of extratropical weather is competitive with that in other current models. We will also present results from the first multi-thousand member ensembles produced at this resolution, showing the impact of 1.5°C and 2°C global warming on extreme winter rainfall and extratropical cyclones in Europe.

How to cite: Watson, P., Sparrow, S., Ingram, W., Wilson, S., Marie, D., Zappa, G., Jones, R., Mitchell, D., Woollings, T., and Allen, M.: Multi-thousand member ensemble atmospheric simulations with global 60km resolution using climateprediction.net, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10895, https://doi.org/10.5194/egusphere-egu2020-10895, 2020.

EGU2020-12061 | Displays | AS4.2

The forced response of the El Niño–Southern Oscillation-Indian monsoon teleconnection in ensembles of Earth System Models

Tamas Bodai, Gabor Drotos, Matyas Herein, Frank Lunkeit, and Valerio Lucarini

We study the teleconnection between the El Niño–Southern Oscillation (ENSO) and the Indian summer monsoon (IM) in large ensemble simulations, the Max Planck Institute Earth System Model (MPI-ESM) and the Community Earth System Model (CESM1). We characterize ENSO by the JJA Niño 3 box-average SST and the IM by the JJAS average precipitation over India, and define their teleconnection in a changing climate as an ensemble-wise correlation. To test robustness, we also consider somewhat different variables that can characterize ENSO and the IM. We utilize ensembles converged to the system’s snapshot attractor for analyzing possible changes in the teleconnection. Our main finding is that the teleconnection strength is typically increasing on the long term in view of appropriately revised ensemble-wise indices. Indices involving a more western part of the Pacific reveal, furthermore, a short-term but rather strong increase in strength followed by some decrease at the turn of the century. Using the station-based SOI as opposed to area-based indices leads to the identification of somewhat more erratic trends, but the turn-of-the-century “bump” is well-detectable with it. All this is in contrast, if not in contradiction, with the discussion in the literature of a weakening teleconnection in the late 20th century. We show here that this discrepancy can be due to any of three reasons: ensemble-wise and temporal correlation coefficients used in the literature are different quantities; the temporal moving correlation has a high statistical variability but possibly also persistence; MPI-ESM does not represent the Earth system faithfully.

How to cite: Bodai, T., Drotos, G., Herein, M., Lunkeit, F., and Lucarini, V.: The forced response of the El Niño–Southern Oscillation-Indian monsoon teleconnection in ensembles of Earth System Models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12061, https://doi.org/10.5194/egusphere-egu2020-12061, 2020.

The availability of a large ensemble enables one to evaluate empirical orthogonal functions (EOFs) with respect to the ensemble without relying on temporal variability at all. Variability across the ensemble at any given time is supposed to represent the most relevant probability distribution for climate-related studies, and this distribution is presumably subject to temporal changes in the presence of time-dependent forcing. Such changes may be observable in spatial patterns of ensemble-based EOFs and associated eigenvalues. Unfortunately, estimates of these changes come with a considerable error due to the finite size of the ensemble, so that associating a significance level with the presence of a change (with respect to a null hypothesis about the absence of any change) should be the first step of analyzing the time evolution.

It turns out, however, that the conditions for the applicability of usual hypothesis tests about stationarity are not satisfied for the above-mentioned quantities. What proves to be feasible is to estimate an upper bound on the significance level for nonstationarity. This means that the true significance level would ideally be lower or equal to what is estimated, which would prevent unjustified confidence in the detection of nonstationarity (i.e., falsely rejecting the null hypothesis could not become more probable than claimed). Most importantly, one would avoid seriously overconfident conclusions about the sign of the change in this way. Notwithstanding, the estimate for the upper bound on the significance level is also affected by the finite number of the ensemble members. It nevertheless becomes more and more precise for increasing ensemble size and may serve as a first guidance for currently available ensemble sizes.

The details of the estimation are presented in the example of the EOF-based analysis of the El Niño–Southern Oscillation (ENSO) as it appears in the historical and RCP8.5 simulations of the Max Planck Institute Grand Ensemble. A comparison between results including and excluding ensemble members initialized with an incomplete spinup in system components with a long time scale is also given.

How to cite: Drotos, G.: On associating significance levels with temporal changes in empirical orthogonal function analysis: a case study for ENSO, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20730, https://doi.org/10.5194/egusphere-egu2020-20730, 2020.

The summer 2018 was extremely dry and hot in Germany and many parts of Europe. We investigate to which extend SST increases in the North Atlantic Ocean and sea ice extent decreases in the polar sea influence such extremes. We simulate in total the four years 1998, 2003, 2014 and 2015 as years with cool, extremely warm, warm and average SST by multiple integrations of the Model for Prediction Across Scales (MPAS). For each year we perform 30 global MPAS runs in approximately 60 km resolution with SST and sea ice extent from ERA-Interim data as boundary condition. The runs are initialized on different days in December and run until the following September 1st.

The contribution investigates the results obtained from the total of 120 simulations. It discusses the resulting probability density functions (PDF) and changes in the summer precipitation and temperature in connection to changes in the summer North Atlantic Oscillation (sNAO). The results indicate that the SST and sea ice extent influence the range and mean values of the precipitation and temperature distribution functions.  Extreme values, however, occur with both cool and warm SST.

How to cite: Smiatek, G. and Kunstmann, H.: Influence of the SST increase and sea ice extent decrease on extreme summer temperatures and precipitation in Central Europe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19888, https://doi.org/10.5194/egusphere-egu2020-19888, 2020.

The question, whether ocean dynamics are relevant for basin-scale North Atlantic decadal temperature variability is subject of ongoing discussions. Here, we analyze a set of simulations with a single climate model, consisting of a 2000-year pre-industrial control experiment, a 100-member historical ensemble, and a 100-member ensemble forced with an incremental CO2 increase by 1%/year. Compared to previous approaches, our setup offers the following advantages: First, the large ensemble size allows to robustly separate internally and externally forced variability and to robustly detect statistical links between different quantities. Second, the availability of different scenarios allows to investigate the role of the background state for drivers of the
variability. We find strong evidence that ocean dynamics, particularly ocean heat transport variations, form an important contribution to generate the Atlantic Multidecadal Variability (AMV) in the Max Planck Institute Earth System Model (MPI- ESM). Particularly the Northwest North Atlantic is substantially affected by ocean circulation for the historical and pre-industrial simulations. Anomalies of the Labrador Sea deep ocean density precede a change of the Atlantic Meridional Overturning Circulation (AMOC) and heat advection to the region south of Greenland.
Under strong CO2 forcing the AMV-SST regression pattern shows crucial changes: SST variability in the north western part of the North Atlantic is strongly reduced, so that the AMV pattern in this scenario is dominated by the low-latitude branch. We found a connection to changes in the deep water formation, that cause a strong reduction of the mean AMOC and its variability. Consequently, ocean heat transport convergence becomes less important for the SST variability south of Greenland.

How to cite: Hand, R., Bader, J., Matei, D., Ghosch, R., and Jungclaus, J.: Changes of decadal SST Variations in the subpolar North Atlantic under strong CO2 forcing as an indicator for the ocean circulation’s contribution to Atlantic Multidecadal Variability, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10091, https://doi.org/10.5194/egusphere-egu2020-10091, 2020.

The recently started PALAEO-RA project aims at creating a new global monthly 3-dimensional reanalysis dataset of the past 600 years' climate. Large spatial and temporal gaps in the available historical data on these time scale make the climate history being an under-determined problem when using observations only. In PALAEO-RA we will addionally use information from an ensemble of simulations with an atmospheric general circulation model (AGCM). The model offers additional physical constraints. The model reproduces teleconnection patterns and reflects typical large-scale modes of variability to set the historical data into a physically consistent regional to global context.

In brief, the method that we plan to use consists of two steps: First, we are currently producing an  ensemble of historical simulations with the atmospheric general circulation model ECHAM6. Once finished, it will have a size of ca. 30 members, covering the period fom 1420 to present. The ensemble is supposed to reflect the range of realistic climate states under prescribed historical radiative forcings (based on the PMIP4 setup) and ocean boundary conditions (HadISST.2 & SST reconstructions by Samakinwa et al., see abstract EGU2020-8744).

Secondly, we will apply Ensemble Kalman Fitting, a technique for the offline assimilation of historical observations (instrumental observations, documentary data, tree ring width and other proxies), basing on the assumption that the occurrence of a distinct observation has a different probability depending on the meso- and large-scale circulation patterns of the atmosphere.

Our poster will give a brief overview on the project with a focus on introducing the AGCM ensemble, also to allow for discussions on further applications of the latter.

How to cite: Brönnimann, S., Hand, R., Franke, J., and Martynov, A.: PALAEO-RA: Combining an intermediate-size AGCM ensemble with historical observations and proxies to create a new dataset of the past 600 years of climate history, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21389, https://doi.org/10.5194/egusphere-egu2020-21389, 2020.

Different teleconnection index time series are obtained even within a single member of a large ensemble simulation if different base periods are chosen. This also has an effect on the apparent strength of teleconnections. In this study, the reasons behind this caveat are discussed analytically and exemplified for the Arctic Oscillation (AO). Additionally, a solution is presented in the so-called snapshot framework using large ensemble simulations.

The AO is the leading mode of atmospheric variability in the Northern Hemisphere winter. Traditionally, its loading pattern is defined as the leading mode of the empirical orthogonal function (EOF) analysis of sea-level pressure (SLP) from 20° to 90° N for a given base period. The AO index (AOI) time series is constructed by projecting the SLP anomalies on this loading pattern and is standardized for the base period. The strength of the linkages related to AO is generally defined by a correlation coefficient between time series of the AOI and another meteorological variable.

Using the CESM-LE and the MPI-GE, we show that the utilization of different base periods within a single member often results in AOI time series differing by as much as 0.5–0.8. We reveal why such differences can arise in any EOF-based quantity: (1) The loading pattern represents a standing oscillation pattern, treated as constant within the studied time interval, and the time evolution of the corresponding index (e.g. AOI) shows how this pattern oscillates in time. However, when the climate changes, stationarity cannot be assumed: whether the oscillation pattern and its amplitude remain the same within the given time interval is dubious. (2) Any shift in the index time series originates from a change in the mean state of the climate system, e.g., from the change in the temporal mean of the SLP field, which is the center of the oscillation described by a given EOF mode. Beyond the meteorological reasons we also give analytically derived results for the shift and for the change in the oscillation amplitude.

To avoid the problems resulting from the assumption of a constant pattern and climatological mean, the traditional EOF-based description should be replaced by the recently developed snapshot EOF (SEOF) analysis if an ensemble is available (Haszpra et al. 2019). This method carries out the EOF analysis across the ensemble at each time instant, instead of the time dimension within each member. As a consequence, instantaneous anomalies originating from internal variability are compared only to the set of states permitted by the climate system at the given time instant. Therefore, beyond a correct characterization at each time instant, the time-dependence of an oscillation pattern and the corresponding amplitude can also be monitored. Furthermore, instantaneous correlation coefficients between the instantaneous index and another variable can be computed across the ensemble to reveal the correct teleconnection strengths and their time-dependence. 

Haszpra et al. 2019: On the time evolution of the Arctic Oscillation and related wintertime phenomena under different forcing scenarios in an ensemble approach. J. Clim. (submitted)

How to cite: Haszpra, T., Drótos, G., Topál, D., and Herein, M.: The role of the base period in evaluating teleconnection indices and strengths, and how to eliminate it in the snapshot framework using large ensembles, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2894, https://doi.org/10.5194/egusphere-egu2020-2894, 2020.

AS4.6 – The atmospheric water cycle: processes, dynamics and characteristics

EGU2020-12010 | Displays | AS4.6

Ultra-high-resolution future coupled model projections of atmospheric rivers

Arjun Nellikkattil, Bin Guan, June-Yi Lee, Axel Timmermann, Sun-Seon Lee, Duane Waliser, and Jung-Eun Chu

Atmospheric rivers (ARs) are narrow, elongated structures, transporting large amounts of water vapor from the tropics towards polar regions. These synoptic scale features play an important role in the global hydrological cycle and for extreme precipitation events. To study how ARs will change in response to greenhouse warming we use a series of century-long fully coupled ultra-high-resolution simulations conducted with CESM 1.2.2 with an approximate horizontal resolution of ~25 km in the atmosphere and 10 km in the ocean. The simulations were carried out for present-day, 2xCO2 and 4xCO2 conditions. In this high atmospheric resolution, we obtain a much more realistic representation of complex orographic features (such as the Rocky Mountains), which can greatly influence the extreme precipitation often associated with ARs. Results from the present-day simulation are compared with ERA-Interim data to validate the model's fidelity in representing ARs. Our analysis focuses on future greenhouse-warming induced changes in AR frequency, geometry, landfalling latitude and strength. We find a global increase in the frequency of ARs amounting to ~0.5% for 2xCO2 and 0.9% for 4xCO2 respectively. In subtropical areas, such as the southwestern part of the United States AR frequencies increase by up to 7%. The presentation will further document the underlying processes for this increase.

How to cite: Nellikkattil, A., Guan, B., Lee, J.-Y., Timmermann, A., Lee, S.-S., Waliser, D., and Chu, J.-E.: Ultra-high-resolution future coupled model projections of atmospheric rivers, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12010, https://doi.org/10.5194/egusphere-egu2020-12010, 2020.

EGU2020-10022 | Displays | AS4.6

Influence of mid-latitude oceanic fronts on the atmospheric water cycle

Fumiaki Ogawa and Thomas Spengler

      Midlatitude oceanic fronts play an important role in the air-sea coupled weather and climate system. Created by the confluence of warm and cool oceanic western boundary currents, the strong sea-surface temperature (SST) gradient is maintained throughout the year. The climatological mean turbulent air-sea heat exchange maximizes along these SST fronts and collocates with the major atmospheric storm tracks. A recent study identified that the air-sea heat exchange along the SST front mainly occurs on sub-weekly time scales, associated with synoptic atmospheric disturbances. This implies a crucial role of air-sea moisture exchange along the SST fronts on the atmospheric water cycle through the intensification of atmospheric cyclones and the associated precipitation.  

      In this study, we investigate this influence of the SST front on the atmospheric water cycle by analyzing the atmospheric response to different prescribed SST in the Atmospheric general circulation model For the Earth Simulator (AFES). Changing the latitude of the prescribed zonally symmetric SST in aqua-planet configuration, we find a distinctive response in convective and large-scale precipitation, surface latent and sensible heat fluxes, as well as diabatic heating and moistening with respect to the latitude of SST front. Upward surface latent heat flux and convective precipitation always maximize along the equatorward flank of SST front. On the other hand, large-scale precipitation is always located on the poleward flank of the SST front, in correspondence with the maximum atmospheric moisture flux convergence. The moisture flux convergence is mainly associated with midlatitude eddies and not with the time mean transport. This highlights the influence of mid-latitude SST fronts on the atmospheric water cycle through the organization of atmospheric storm track.

How to cite: Ogawa, F. and Spengler, T.: Influence of mid-latitude oceanic fronts on the atmospheric water cycle , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10022, https://doi.org/10.5194/egusphere-egu2020-10022, 2020.

EGU2020-13131 | Displays | AS4.6

Key controls of water vapour isotopes during oceanic evaporation and their global impact

Martin Werner, Jean-Louis Bonne, Alexandre Cauquoin, and Hans Christian Steen-Larsen

Stable water isotopes are employed as hydrological tracers to quantify the diverse implications of atmospheric moisture for climate. In a recent study based on several years of in-situ isotope measurements in water vapour of the marine boundary layer it was shown that the isotope signal during evaporation is not modulated by wind speed, contrary to the commonly used theory, but controlled by relative humidity and sea surface temperature, only (Bonne et al., 2019). In sea ice covered regions, the sublimation of deposited snow on sea ice was found as another key process controlling the local water vapour isotopic composition. Here, we evaluate how these new findings will impact the stable water isotope signal both in vapour and precipitation on a global scale. For this purpose, the newly suggested parametrisations are included in two versions of the isotope-enabled atmospheric model ECHAM-wiso (Werner et al., 2016; Cauquoin et al., 2019) and a set of simulations is performed to disentangle the effects of the various controlling factors. Model results are evaluated against a compilation of short-term measurements of the isotopic composition in the marine boundary layer (Benetti et al., 2017), as well as data sets from several coastal stations (Steen-Larsen et al., 2014; 2015; 2017). In addition, the implications of the suggested parameterization changes for the interpretation of various isotope records in paleo-records will be discussed.

How to cite: Werner, M., Bonne, J.-L., Cauquoin, A., and Steen-Larsen, H. C.: Key controls of water vapour isotopes during oceanic evaporation and their global impact, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13131, https://doi.org/10.5194/egusphere-egu2020-13131, 2020.

EGU2020-10979 | Displays | AS4.6

Stable water isotopes as a tool to investigate tropospheric moisture transport pathways over the eastern subtropical North Atlantic

Fabienne Dahinden, Franziska Aemisegger, Sabine Barthlott, Emanuel Christner, Christoph Dyroff, Frank Hase, Peter Knippertz, Heini Wernli, Matthias Schneider, and Stephan Pfahl

The subtropical atmospheric water cycle is a key component in the climate system. Free-tropospheric humidity and low-level cloud cover over the subtropical oceans strongly affect the global radiative balance via the greenhouse and albedo effects. However, the complex interaction of dynamical processes controlling the subtropical tropospheric moisture budget is still not fully understood. Stable water isotopes have proven to be highly useful to investigate the physical mechanisms involved in the atmospheric water cycle. These natural tracers of water phase changes capture the moist diabatic history experienced by air parcels. Additionally, due to the distinct fingerprints of air masses with different origin, the isotopic composition of water vapor can further provide information about atmospheric processes that do not involve phase changes, for instance, turbulent mixing or large-scale water vapor transport. To enhance the understanding of the mechanisms controlling the subtropical tropospheric humidity, we performed dedicated high-resolution simulations with the isotope-enabled regional weather and climate prediction model COSMOiso. Comparison with ground-based remote sensing (Fourier transform infrared spectroscopy) and aircraft-based in situ isotope observations from the project MUSICA enables us to evaluate and constrain the representation of relevant physical processes in the model.

Our simulations confirm the current state of knowledge about the contrasting moisture transport conditions over the eastern subtropical North Atlantic, resulting from an interplay between humid, isotopically enriched air primarily coming from Africa on the one hand and dry, depleted air mainly originating from the upper-level extratropical North Atlantic on the other hand. Additionally, we show that North African air masses that are affected by the Saharan heat low (SHL) and air masses which come from the Sahel region further south are associated with a distinct isotope signature. This difference is mainly due to the fact that air masses from the Sahel region have experienced moist convection and cloud processing, whereas the Saharan air layer is a well-mixed air mass with a more homogenous isotope composition. We systematically assess the dynamical drivers behind these contrasting conditions. In particular, we investigate the importance of the SHL dynamics on moistening the free troposphere over the eastern subtropical North Atlantic. In summer, the SHL induces low-level convergence of air masses from different sources, which are then convectively lifted to higher altitudes and are eventually transported within the Saharan air layer across the North Atlantic, where they mix with dry, descending free tropospheric air. Detailed analysis of isotopic signals along kinematic back- trajectories of different air masses arriving over the Canary Islands allows to disentangle governing physical processes and relevant moisture sources that affect the free tropospheric humidity. The adopted Lagrangian isotope perspective notably enhances our understanding of air mass mixing and offers a sound interpretation of the free tropospheric humidity and isotopic variability on time scales of hours to days in contrasting atmospheric conditions over the eastern subtropical North Atlantic.

How to cite: Dahinden, F., Aemisegger, F., Barthlott, S., Christner, E., Dyroff, C., Hase, F., Knippertz, P., Wernli, H., Schneider, M., and Pfahl, S.: Stable water isotopes as a tool to investigate tropospheric moisture transport pathways over the eastern subtropical North Atlantic, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10979, https://doi.org/10.5194/egusphere-egu2020-10979, 2020.

EGU2020-2315 | Displays | AS4.6 | Highlight

Moisture sources of extreme Vb-floods in Central Europe

Amelie Krug, Franziska Aemisegger, Michael Sprenger, Cristina Primo, and Bodo Ahrens

River floods are the most common and devastating natural hazard in Europe. In this study, we focus on a specific flood type which is associated with so-called Vb-cyclones. These extratropical cyclones are defined by their pathway from the western Mediterranean Sea north-eastward over northern Italy along the eastern fringe of the Alps towards Central Europe. Prominent examples of Vb-floods are the July 1954 and the August 2002 floods in the Elbe and Danube catchments as well as the Odra flooding during May/June 2010.

Only a few Vb-cyclones cause extreme flooding in Central Europe, even though about 2-5 follow the Vb pathway on average per year. The processes which intensify these flood triggering Vb-cyclones are only partly understood. One potential mechanism could be the soil-precipitation feedback over the continent. Moreover, the resulting latent heat release could re-enforce the atmospheric blocking conditions, e.g., over eastern Europe, that foster cyclones to follow the Vb-like pathway.

Our study aims to increase knowledge about potential feedback mechanisms by quantifying the role of specific moisture sources. We analysed the moisture uptake for selected extreme events in the 20th century based on backward trajectories in dynamically downscaled ERA-20C reanalysis. The downscaling was performed over Europe with a high-resolution and interactively coupled atmosphere-ocean model setup (COSMO-CLM+NEMO). The Mediterranean Sea contributed to rainfall in the affected river catchments often at the event start. Throughout the events, other main moisture uptake regions were the European continent pointing towards an important role of the soil-moisture precipitation feedback, but also other oceanic sources such as the North Atlantic, the North Sea, and the Baltic Sea were identified. The large variety of the identified sources highlights the complex dynamical interplay of different airmasses leading to convergence of moisture during particularly severe flood producing heavy precipitation events.

How to cite: Krug, A., Aemisegger, F., Sprenger, M., Primo, C., and Ahrens, B.: Moisture sources of extreme Vb-floods in Central Europe, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2315, https://doi.org/10.5194/egusphere-egu2020-2315, 2020.

EGU2020-5690 | Displays | AS4.6

Extreme precipitation events in the Mediterranean area. A contrasting Lagrangian and Eulerian approach for moisture evaporation sources identification.

Sara Cloux González, A. Daniel Garaboa Paz, Damian Insua Costa, Vicente Perez Muñuzuri, and Gonzálo Miguez Macho

Concern about heavy precipitation events has increasingly grown in the last years in the South of Europe, especially in the Mediterranean region. These occasional episodes can result in more than 200 mm of rainfall in less than 24 h, producing flash floods with very high social and economic losses.  

To improve their predictability, the correct identification of the origin of the moisture must be done. The Eulerian and Lagrangian models provide a good approach to detect moisture sources. However, they show some limitations. 

Here, we present a comparison between both methods through a case study of an extreme precipitation event on the region of the Mediterranean coast which take place in 1982. Using the Lagrangian model FLEXPART-WRF to backtrack the moisture, we identify the evaporation sources. Then, we compare it with the results obtained through Eulerian WRF-WVT method [1]. Also, we evaluate the accuracy of E-P balance in contrast to Evaporation patterns. Finally, we implemented a further identification of moisture uptake method which enables us to directly compare results from both strategies [2]. 

 

[1] Insua-Costa, D., Miguez-Macho, G., and Llasat, M. C.: Local and remote moisture sources for extreme precipitation: a study of the two catastrophic 1982 western Mediterranean episodes, Hydrol. Earth Syst. Sci., 23, 3885–3900, https://doi.org/10.5194/hess-23-3885-2019, 2019. 

[2] Sodemann, Harald, C. Schwierz, and Heini Wernli.: Interannual variability of Greenland winter precipitation sources: Lagrangian moisture diagnostic and North Atlantic Oscillation influence. Journal of Geophysical Research: Atmospheres 113.D3 (2008). 

How to cite: Cloux González, S., Garaboa Paz, A. D., Insua Costa, D., Perez Muñuzuri, V., and Miguez Macho, G.: Extreme precipitation events in the Mediterranean area. A contrasting Lagrangian and Eulerian approach for moisture evaporation sources identification., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5690, https://doi.org/10.5194/egusphere-egu2020-5690, 2020.

The high-elevation eastern Anatolian plateau, located in eastern Mediterranean basin, is cold and snowy in winter, and functions as a water tower in providing water to Mesopotamia through Euphrates and Tigris rivers. These rivers are snow-fed, as much of their discharges occurs in spring when the seasonal warming melts the snowpack. The anomalous warming over the eastern Anatolia in early March 2004 resulted in unprecedented snowmelt runoff in the Euphrates and Tigris basin together with the accompanying rainfall. This study explores an atmospheric river (AR) leading to the extreme hydrometeorological events in the headwaters regions of the Euphrates and Tigris basins in early March 2004, and its possible linkage to the strength of the East Asian trough (EAT). In the analyses, we used reanalysis data, gridded products of surface temperature and snow cover, river discharge data and satellite imagery. We employed an intensity index for the EAT and a trough displacement index for the Mediterranean trough (MedT) to explore the relationship between the strength of the EAT and the displacement of the MedT at pentad resolution. We show that there is a strong relationship between the strength of the EAT and the zonal displacements of the Mediterranean upper layer trough on the 13th pentad of the year, which corresponds to early days of March. In 2004, which appears to be an extreme year for this phenomenon, the MedT is positioned and deepened in the central Mediterranean (about10−15◦E), and extended towards central Africa during the early days of March. This synoptic pattern provided favorable conditions for the development of AR with a southwest-northeast orientation, carrying warm tropical African air towards the eastern Mediterranean and Anatolian highlands resulting in rapid melting of the snowpack as well as severe precipitation, and thus, flooding events, in the eastern Anatolia. A key finding in our analysis is that the strengthening of the EAT was instrumental to the increased amplitude of the ridge-trough system over the Euro-Mediterranean region in the early days of 2004 late winter. A further analysis is ongoing to provide a basis to analyze past individual AR events over the region, especially those associated with extreme precipitation events and snowmelt.

How to cite: Sen, O. L., Bozkurt, D., and Ezber, Y.: Tropical air intrusions over the eastern Mediterranean and Mesopotamia: An atmospheric river case study and role of the East Asian trough , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11354, https://doi.org/10.5194/egusphere-egu2020-11354, 2020.

EGU2020-4638 | Displays | AS4.6 | Highlight

Causes of future Mediterranean precipitation decline depend on the season

Roman Brogli, Silje Lund Sørland, Nico Kröner, and Christoph Schär

The Mediterranean is among the global 'hot-spots' of climate change, where severe consequences of climate change are expected. Changes in the atmospheric water cycle are among the leading causes of the vulnerability of the Mediterranean to greenhouse gas-driven warming. Specifically, precipitation is projected to decrease year-round, which is expected to have major impacts on hydrology, biodiversity, agriculture, hydropower, and further economic sectors that rely on sufficient water supply.

We investigate possible causes of the Mediterranean drying in regional climate simulations. To isolate the influence of multiple large-scale drivers on the drying, we sequentially add the respective drivers from global models to regional climate model simulations. We show that the causes of the Mediterranean drying depend on the season. We will present in detail how the summer drying is driven by the land-ocean warming contrast, lapse-rate and other thermodynamic changes, while it only weakly depends on circulation changes. In contrast, changes in the circulation are the primary driver for the projected winter precipitation decline. Since land-ocean contrast, thermodynamic and lapse-rate changes are more robust in climate simulations than circulation changes, the uncertainty associated with the projected drying should be considered smaller in summer than in winter.

Reference: Brogli, R., S. L. Sørland, N. Kröner, and C. Schär, 2019: Causes of future Mediterranean precipitation decline depend on the season. Environmental Research Letters, 14, 114017, doi:10.1088/1748-9326/ab4438.

How to cite: Brogli, R., Sørland, S. L., Kröner, N., and Schär, C.: Causes of future Mediterranean precipitation decline depend on the season, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4638, https://doi.org/10.5194/egusphere-egu2020-4638, 2020.

Dry intrusion (DI) is the slantwise descent of dry air from the extratropical upper troposphere to the mid/lower troposphere of the lower latitudes. When reaching the tropical regions, DIs substantially change the overall amount of available moisture, ocean surface fluxes into the atmosphere, as well as the atmospheric stability to vertical motion and the 3-dimensional flow and associated dynamics. However, the occurrence of such events has not been quantified systematically. Here, we quantify the climatological occurrence of DIs that extend from the extratropics to tropical regions. Specifically, we focus on events that host subsequent cross-equatorial flow. Using 6-hourly ERA-Interim reanalysis data with a Lagrangian approach, we show that during the summer monsoon season (June to September) DIs enter the tropical region from the southern hemisphere with peaks that exceed 10 % frequency in time. DI arrival into the tropics is associated with dry and cold lower-tropospheric anomalies, and consequently induced ocean evaporation and sensible heat flux into the atmosphere. Although cross-equatorial DIs are rare, a hotspot of such DIs is evident in the Indian Ocean, having a potential role for Indian summer monsoon (ISM) water cycle. The dominance of the ISM for the annual rainfall over India implies that small changes in the evaporation and moisture pathways may influence the ISM precipitation downstream significantly. Indeed, we demonstrate the connection between ISM rainfall and the preceding water-cycle interaction under DI conditions, and further show that DIs entering the Indian subcontinent modify the low-level jets. 

How to cite: Rai, D. and Raveh-Rubin, S.: Cross-equatorial dry intrusions and their impact on Indian summer monsoon-associated water cycle , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4545, https://doi.org/10.5194/egusphere-egu2020-4545, 2020.

EGU2020-8343 | Displays | AS4.6

Combined event-based tritium and air mass back-trajectory analysis of Mediterranean precipitation events

Tobias Juhlke, Jürgen Sültenfuß, Katja Trachte, Frédéric Huneau, Emilie Garel, Sébastien Santoni, Johannes A. C. Barth, and Robert van Geldern

Climate models are in need of improved constraints for water vapor transport in the atmosphere and tritium can serve as a powerful tracer in the hydrological cycle. Although general principles of tritium distribution and transfer processes within and between the various hydrological compartments are known, variation on short timescales and aspects of altitude dependence are still under debate. To address questions for tritium sources, sinks and transfer processes, sampling of individual precipitation events in Corte on the island of Corsica in the Mediterranean Sea was performed between April 2017 and April 2018. Tritium concentrations of 46 event samples were compared to their moisture origin and corresponding air mass history. Air mass back-trajectories were generated from the novel high-resolution ERA 5 data set of the ECMWF (European Centre for Medium-Range Weather Forecasts). Geographical source regions of similar tritium concentrations were predefined using generally known tritium distribution patterns, such as a ‘continental effect’, and from data records derived at long-term measurement stations of tritium in precipitation across the working area. Our model-derived source region tritium concentrations agreed well with annual mean station values. Moisture that originated from continental Europe and the Atlantic Ocean was most distinct regarding tritium concentrations with values up to 8.8 TU and near 0 TU, respectively. Seasonality of tritium values ranged from 1.6 TU in January to 10.1 TU in May and exhibited well-known elevated concentrations in spring and early summer due to increased stratosphere-troposphere exchange. However, this pattern was interrupted by extreme events. The average altitude of trajectories correlated with tritium concentrations in precipitation, especially in spring and early summer and if outlier values of extreme tritium concentrations were excluded. However, in combination with the trajectory information, these outlier values proved to be valuable for the understanding of tritium movement in the atmosphere. Our work shows how event-based tritium research can advance the understanding of its distribution in the atmosphere.

How to cite: Juhlke, T., Sültenfuß, J., Trachte, K., Huneau, F., Garel, E., Santoni, S., Barth, J. A. C., and van Geldern, R.: Combined event-based tritium and air mass back-trajectory analysis of Mediterranean precipitation events, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8343, https://doi.org/10.5194/egusphere-egu2020-8343, 2020.

Northeast Greenland is predicted to be one of the most sensitive terrestrial areas of the Arctic to anthropogenic climate change, resulting in an increase in temperature that is much greater than the global average. Associated with this temperature rise, precipitation is also expected to increase as a result of increased evaporation from an ice-free Arctic Ocean. In recent years, numerous palaeoclimate projects have begun working in the region with the aim of improving our understanding of how this highly-sensitive region responds to a warmer world. However, a lack of meteorological stations within the area makes it difficult to place the palaeoclimate records in the context of modern climate.

This study aims to improve our understanding of precipitation and moisture source dynamics over a small arid region located at 80 °N in Northeast Greenland. This region hosts many speleothem-containing caves that are being studied in the framework of the Greenland Caves Project (greenlandcavesproject.org). The origin of water vapour for precipitation over the study site is detected by a Lagrangian moisture source diagnostic, which is applied to reanalysis data from the European Centre for Medium-Range Weather Forecasts (ERA-Interim) from 1979 to 2017.

While precipitation amounts are relatively constant during the year, the regional moisture sources display a strong seasonality. The most dominant winter moisture sources are the ice-free North Atlantic ocean above 45 °N, while in summer the patterns shift towards more local and North Eurasian continental sources. During positive North-Atlantic Oscillation (NAO) phases evaporation and moisture transport from the Norwegian Sea is stronger, resulting in larger and more variable precipitation amounts. Although the annual mean temperature in the study region has increased by 0.7 °C dec -1 (95% confidence interval [0.4, 1.0] °C dec -1 ) according to ERA-Interim data, we do not detect any change in the amount of precipitation with the exception of autumn where precipitation increases by 8.2 [0.8, 15.5] mm dec -1 over the period. This increase is consistent with future predicted Arctic precipitation change.

How to cite: Schuster, L., Maussion, F., Langhamer, L., and Moseley, G. E.: Lagrangian detection of moisture sources for an arid region in Northeast Greenland: relations to the North-Atlantic Oscillation and temporal trends from 1979 to 2017, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11507, https://doi.org/10.5194/egusphere-egu2020-11507, 2020.

EGU2020-20146 | Displays | AS4.6

What drives the isotopic composition of vapor, precipitation and surface snow in a coastal site of East Anrctica: Adelie Land

Christophe Leroy-Dos Santos, Amaelle Landais, Elise Fourre, Cecile Agosta, Mathieu Casado, Anais Orsi, Gregoire Aufresne, Olivier Jossoud, and Frederic Prié

Studying the drivers of the water stable isotopic composition at coastal Antarctic sites is useful for the interpretation of coastal ice-core signal or the analysis of recent mass balance evolution. In addition to the classical fingerprint of temperature, the water isotopic composition in water vapor and snow carries a fingerprint of the humidity transport pathway, from evaporation to precipitation. Blowing snow in very windy coastal regions is also expected to carry a particular signature affected by snow-air exchanges as observed for surface snow on the East Antarctic plateau.

Since November 2018, we have been continuously measuring the water stable isotopic composition of vapor at Dumont D’Urville station (Adélie Land) using laser spectrometers in addition to isotopic composition of precipitation, blowing snow and surface snow samples. We present here the full 2019 data series. We focus on the two main weather regimes, in summer and winter, that affect the local hydrological cycle. In summer, temperature and specific humidity signals are characterized by large diurnal cycles due to katabatic winds. Winter variability is largely influenced by large scale synoptic events. We also investigate a few specific cases of precipitation/sublimation and compare two summer periods with opposite sea-ice conditions.

How to cite: Leroy-Dos Santos, C., Landais, A., Fourre, E., Agosta, C., Casado, M., Orsi, A., Aufresne, G., Jossoud, O., and Prié, F.: What drives the isotopic composition of vapor, precipitation and surface snow in a coastal site of East Anrctica: Adelie Land, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20146, https://doi.org/10.5194/egusphere-egu2020-20146, 2020.

EGU2020-22376 | Displays | AS4.6

Isotopic equilibrium between precipitation and water vapor in Northern Patagonia and its consequences on δ18Ocellulose estimate

Tiphaine Penchenat, Françoise Vimeux, Valérie Daux, Olivier Cattani, Maximiliano Viale, Ricardo Villalba, Ana Srur, and Clément Outrequin

Modelling of the oxygen isotopic composition (δ18O) of tree-ring cellulose rely on the isotopic equilibrium assumption between the atmospheric water vapor and the tree source water, which is frequently assimilated to integrated precipitation. We explore the veracity of this assumption based on observations collected (δ18O of rain, rivers, leaves, tree-rings) or monitored (δ18O of water vapor) during a field campaign in Río Negro province, Argentina, in late summer 2017 (February-March). We examine, firstly, how the δ18O of water vapor deviate from the equilibrium with precipitation and, secondly, what is the impact of the isotopic equilibrium assumption on the calculation of the isotopic composition of tree-ring cellulose.

For oxygen, the isotopic disequilibrium between rain and vapor range between -2.0 and 4.1‰. Rain drops re-evaporation during their fall, evaporation of soil water and vegetation transpiration (resulting in transpired water accounting for 14 to 29% of ambient water vapor) could produce this disequilibrium. The small value of the disequilibrium at the study site is likely due to the high level of relative humidity (from 70 to 96%) favoring the isotopic diffusive exchanges between the two water phases and thus promoting the isotopic equilibrium.

A perfect agreement between observed and calculated isotopic composition of cellulose is obtained if the source water is assumed to be in isotopic equilibrium with the measured water vapor. This hypothetical source water has a significantly higher δ18O than the expected averaged isotopic composition of precipitation over the growing period or than the groundwater (river value). The veracity of the hypothesis of the isotopic equilibrium between water vapor and source water in tree-ring paleoclimate studies is discussed in light of these results.

How to cite: Penchenat, T., Vimeux, F., Daux, V., Cattani, O., Viale, M., Villalba, R., Srur, A., and Outrequin, C.: Isotopic equilibrium between precipitation and water vapor in Northern Patagonia and its consequences on δ18Ocellulose estimate, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22376, https://doi.org/10.5194/egusphere-egu2020-22376, 2020.

EGU2020-4527 | Displays | AS4.6

Testing isotopologues as diabatic heating proxy for atmospheric data analyses

Farahnaz Khosrawi, Kinya Toride, Kei Yoshimura, Christopher Diekmann, Benjamin Ertl, and Matthias Schneider

The strong coupling between atmospheric circulation, moisture pathways and atmospheric diabatic heating is a great challenge in atmospheric research since this coupling is responsible for most climate feedback mechanisms and controls the evolution of severe weather events. Although diabatic heating rates are the major driving force of atmospheric circulation on weather and climate time scales, the diabatic heating rates obtained from current meteorological reanalyses show significant inconsistencies. This is mainly indebted to the fact that diabatic heating rates cannot be directly observed. Isotopologue observations assimilated into meteorological reanalyses can make an invaluable contribution since the isotopologue composition depends on the history of phase transition. Therefore, isotopologue observations can provide information that is closely linked to latent heating processes. Here, we analyse idealized experiments performed with the isotopes-incorporated General Spectral Model (IsoGSM) to investigate whether the additional assimilation of isotopologue observations can improve the diabatic heating rates. To do so, we use a Local Transform Ensemble Kalman Filter (LETKF) for data assimilation, and mock the high-density isotopologue MUSICA IASI observational data. The MUSICA IASI data apply the retrieval recipe of MUSICA (MUlti-platform remote Sensing of Isotopologues for investigating the Cycle of Atmospheric water) to the thermal nadir spectra recorded by the IASI (Infrared Atmospheric Sounding Interferometer) satellite instrument. The mocked isotopologue observations are then assimilated into the model in addition to temperature, humidity and wind profiles obtained from radiosonde and satellite data. By comparing the ensemble runs with and without the additional assimilation of the isotopologue data we can reveal the potential of MUSICA IASI isotopologue data for constraining uncertainties in diabatic heating rates.

How to cite: Khosrawi, F., Toride, K., Yoshimura, K., Diekmann, C., Ertl, B., and Schneider, M.: Testing isotopologues as diabatic heating proxy for atmospheric data analyses , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4527, https://doi.org/10.5194/egusphere-egu2020-4527, 2020.

EGU2020-16029 | Displays | AS4.6

Changes in the empirical distribution of global precipitation

Yannis Markonis, Simon Michael Papalexiou, Marta Martinkova, and Martin Hanel

EGU2020-22688 | Displays | AS4.6

Relationship between surface and tropospheric water vapor variation on interannual timescale: A revisit

Mengmiao Yang, De-Zheng Sun, and Guang J. Zhang

It is an old question whether tropospheric water vapor at different levels changes consistently in response to the enhanced greenhouse gas in the atmosphere. Earlier studies using older versions of climate models and available data revealed a significant difference between models and observations. Water vapor changes in the interior of the tropical troposphere have been found to be more strongly coupled to changes at the surface in climate models than in observations. We reexamine this issue using four leading CMIP5 models (CCSM4, HadGEM2-A, GFDL-CM3 and MPI-ESM-MR) and more updated observational datasets (ERA-Interim and NCEP reanalysis). Focusing on the Tropics, we have calculated the correlations between interannual variation of specific humidity in all levels of the troposphere with that at the surface. It is found that the previously noted biases in the strength of the coupling between water vapor changes in the interior of the troposphere and those at the surface still exist in the updated models—the change in the tropical averaged tropospheric water vapor is more strongly correlated with the change in the surface, especially in the middle troposphere. It is argued that the vertical profile of water vapor correlations in observations is more consistent with the “hot tower” concept for tropical convections. Zonal mean correlation results and those from the moisture regime sorting method are consistent with each other, both of which indicate the role of deep convection as a mechanism to couple the middle tropospheric water vapor and that in the surface and that an inaccurate representation of deep convection as a possible cause for the discrepancies between models and observations in the coupling between middle tropospheric water vapor and those at the surface.

How to cite: Yang, M., Sun, D.-Z., and Zhang, G. J.: Relationship between surface and tropospheric water vapor variation on interannual timescale: A revisit, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22688, https://doi.org/10.5194/egusphere-egu2020-22688, 2020.

EGU2020-10401 | Displays | AS4.6 | Highlight

Rising Temperatures Increase Importance of Oceanic Evaporation as a Source for Continental Precipitation

Kirsten Findell, Patrick Keys, Ruud van der Ent, Benjamin Lintner, Alexis Berg, and John Krasting

Understanding vulnerabilities of continental precipitation to changing climatic conditions is of critical importance to society at large. Terrestrial precipitation is fed by moisture originating as evaporation from oceans and from recycling of water evaporated from continental sources. In this study, continental precipitation and evaporation recycling processes in the Earth system model GFDL-ESM2G are shown to be consistent with estimates from two different reanalysis products. The GFDL-ESM2G simulations of historical and future climate also show that values of continental moisture recycling ratios were systematically higher in the past and will be lower in the future.

Global mean recycling ratios decrease 2%–3% with each degree of temperature increase, indicating the increased importance of oceanic evaporation for continental precipitation. Theoretical arguments for recycling changes stem from increasing atmospheric temperatures and evaporative demand that drive increases in evaporation over oceans that are more rapid than those over land as a result of terrestrial soil moisture limitations. Simulated recycling changes are demonstrated to be consistent with these theoretical arguments. A simple prototype describing this theory effectively captures the zonal mean behavior of GFDL-ESM2G.

Key sources of terrestrial evaporation, notably the interior of the Amazon basin and parts of the Ganges-Brahmaputra and Indus River basins, may experience reductions in moisture recycling. This has implications for key sink regions of terrestrial recycled precipitation, especially in rain-fed agricultural regions where crop yields will become increasingly soil moisture limited, such as the La Plata River basin, the corn producing regions of North America, southern Africa and the Sahel.

The results presented here have been published last year in Journal of Climate dx.doi.org/10.1175/JCLI-D-19-0145.1

 

How to cite: Findell, K., Keys, P., van der Ent, R., Lintner, B., Berg, A., and Krasting, J.: Rising Temperatures Increase Importance of Oceanic Evaporation as a Source for Continental Precipitation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10401, https://doi.org/10.5194/egusphere-egu2020-10401, 2020.

EGU2020-20963 | Displays | AS4.6

Long-term change of warm-season precipitation climatology in South Korea

Hyeon-seok Do and Joowan Kim

This study examines long-term changes of precipitation characteristics in South Korea focusing on warm season (June-September). Daily precipitation data are obtained from 15 surface stations that have continuously observed precipitation for 58 years (1961 – 2018). Precipitation characteristics and their long-term changes are examined including trend, amount, and intensity. The warm- season precipitation in South Korea is largely affected by the East Asian Summer Monsoon, which causes rainy season in late July and mid August (these are called “Changma” and “Post-Changma” seasons in Korea). Thus, these characteristics are also analyzed focusing on Changma season.

The warm-season precipitation increased roughly by 1.0 mm per day for the last thirty years. The change is particularly pronounced during Changma season, and it shows 1.6 mm of daily precipitation increase. Trend analysis for the 58 years also showed a consistent and significant result. The precipitation change is mostly founded in the intensity of 30 – 110 mm per day implying that the precipitation intensity is increasing in warm season. Multiple regression analysis further suggests that this change is more related to precipitation intensity than precipitation frequency. Global precipitation data reveals the similar change in precipitation over central eastern China presenting a band-like precipitation increase extending to the Korean peninsula. These results are likely caused by near-surface temperature and moisture increase in a warming climate.

How to cite: Do, H. and Kim, J.: Long-term change of warm-season precipitation climatology in South Korea, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20963, https://doi.org/10.5194/egusphere-egu2020-20963, 2020.

There has been growing interest in studying precipitation recycling and identifying relationships between moisture sources and receptors. The network built upon the relationships is crucial for the knowledge of the atmospheric water cycle, weather prediction, and adaptation to hydroclimatic disasters. This study aims to provide an interesting perspective of a Source-to-Receptor (SR) network to study the dynamics of the East Asian Summer Monsoon (EASM). By prescribing 24 sources and 6 EASM subregions, the SR network during the wet season is quantified using the two-dimensional physically-based Dynamical Recycling Model (DRM). Results reveal that in addition to oceanic sources, land sources including the often-overlooked plateau regions play an important role in supplying moisture to most EASM subregions. A seesaw relationship of the Indian Ocean/South Asia sector from April to June and the Pacific Ocean/East Asia sector from July to September is evidenced in the intraseasonal variation of the SR network for EASM subregions including South China coast and Taiwan, Yangtze River basin, South Japan and Korean Peninsula. Conversely, weaker intraseasonal variation is seen in the SR network for the Yellow River basin and North China. During heavy rainfall days, the zonal oscillation of western North Pacific Subtropical High (WNPSH) is deemed crucial to modulate the SR network through enhanced contributions from Bay of Bengal, Indochina, Indian subcontinent and Southwest China (the Philippine Sea and western North Pacific) during the positive (negative) phase. Coupled circulations such as two distinct pressure dipoles and coherent upper-level wave trains from mid-latitudes are responsible for bridging the moisture routes. Lastly, preceding winter/springtime El Niño is likely associated with the enhanced (weakened) moisture supply from the southwesterly (Pacific Ocean) sources. Longer-term variabilities such as the Pacific Decadal Oscillation is also considered influential to the SR network. We believe that the attributable atmospheric bridges and the SR network itself can offer insights to the current understanding of EASM and model simulations of the monsoon systems and the water cycles.

How to cite: Cheng, T. F. and Lu, M.: Moisture Source-to-Receptor Network for East Asian Summer Monsoon and the Associated Atmospheric Bridges, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-375, https://doi.org/10.5194/egusphere-egu2020-375, 2020.

EGU2020-257 | Displays | AS4.6

Spatio-Temporal Dynamics of East Asia Atmospheric Rivers and their Atmospheric Steering and Climatic Regulation

Mengxin Pan, Mengqian Lu, Upmanu Lall, and Qizhen Dong

The identification, climatic modulation and hydrological impact of Atmospheric Rivers (ARs) is an emergent scientific topic in recent years. ARs are important and yet understudied for East Asia (EA). We use our new AR identification algorithm (Pan & Lu, 2019), to build up a comprehensive AR catalog for this region for the first time.  Interesting patterns are found: (1) there is a dominant AR route, originating from the Arabian Sea, crossing over the Bay of Bengal and Indochina, South China Sea (SCS) and Southeast China (SEC), and terminating in the western North Pacific; and (2) a nine-stage annual pattern in the climatological frequency is revealed.  Stage 1: mid-Mar to mid-May, the formation of Western North Pacific Subtropical Height (WNPSH) near the SCS steers and confines AR in its northwest flank over SEC.  Stages 2-5: during the monsoon season from mid-May to late-Aug, the evolution of AR follow the intra-seasonal progression of Asia-Pacific monsoon (including South Asian monsoon, East Asian monsoon and western North Pacific monsoon. Stages 6-9: late-Aug to mid-Mar, ARs leave EA and only occur over the North Pacific. Over all stages, we find the contribution of AR grows significantly with more extreme rainfall (i.e., from the annual rainfall, heavy rainfall, persistent heavy rainfall to large spatial extent persistent heavy rainfall), especially in spring and early-monsoon season. This emphasizes ARs’ significant role in extreme or catastrophic rainfall events. Intriguingly, divergence of AR trajectories (also in their characteristics) occurs along the extratropical direction, and such divergent features have spatially heterogenous dependence on the leading modes of a collection of steering atmospheric and regulating climatic signals. Large divergence indicates high sensitivity of AR to transient steering; while small divergence promises high predictability of ARs, thus their associated hydrological impacts.

How to cite: Pan, M., Lu, M., Lall, U., and Dong, Q.: Spatio-Temporal Dynamics of East Asia Atmospheric Rivers and their Atmospheric Steering and Climatic Regulation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-257, https://doi.org/10.5194/egusphere-egu2020-257, 2020.

EGU2020-240 | Displays | AS4.6

A novel global AR identification algorithm

Mengqian Lu and Mengxin Pan

Atmospheric river (AR), which is defined as long, narrow and transient corridor with enhanced moisture transport, received more and more scientific attention because of its crucial roles in the global water cycle, water resource management and hydrometeorological extremes. In recent years, dozens of AR identification algorithms are proposed to detect and quantify ARs. However, limitations still exist. In this study, a novel global AR identification algorithm is developed to address some limitations among all the state-of-the-art AR algorithms. First, in the AR pathway detection, a coupled quantile and Gaussian kernel smoothing technique is implemented to define the IVT threshold to make a balance in capturing the spatiotemporal variation of IVT climatology and avoiding largely biased estimation. Second, in spite of the variety of AR shape, orientation and curvature, more reliable AR metrics (e.g., length and width) can be determined based on the smooth AR trajectory, which is generated by modifying and integrating the concept of local regression and K-nearest-neighbors. Third, a robust and resilient criterion is developed to filter the tropical moisture swell. Four, an exquisite metric (turning angle series) is proposed, which is helpful to distinguish the tropical cyclone-like (TC-like) features and quantify the AR curvature which may bridge the ARs to the atmospheric circulation system. Last but not least, another novel metric () is developed to measure the localized IVT coherence on the AR pathway. For each grid, the  is defined as the inter-decile range of the IVT direction of its neighbor grids. The IVT coherent/discordant segments on the AR pathway are extracted by an image segmentation algorithm according to their spatial pattern and  values. The coherent segments are more likely to carry on long-distance moisture transport,  governed by the persistent and large-scale circulation system and related to hydrometeorological extreme, while discordant segments are more likely to be corresponding to the localized turbulence, low pressure system or TC-like features. So, flagging the segments into different categories will be significant in the study of the climatic modulation of AR occurrence, intensity, spatial pattern and the associated rainfall predictability. We believe that this algorithm with various metric will facilitate further quantitative investigations by the AR research community in terms of water resource management, hydrometeorological extreme predictability and climate change projections.

How to cite: Lu, M. and Pan, M.: A novel global AR identification algorithm, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-240, https://doi.org/10.5194/egusphere-egu2020-240, 2020.

EGU2020-18794 | Displays | AS4.6

A portrayal of an orographic Warm Conveyor Belt using observations from aircraft, lidar and radar

Maxi Boettcher, Andreas Schäfler, Harald Sodemann, Michael Sprenger, Stefan Kaufmann, Christiane Voigt, Hans Schlager, Donato Summa, Paolo Di Girolamo, Daniele Nerini, Urs Germann, and Heini Wernli

Warm conveyor belts (WCBs) are important airstreams in extratropical
cyclones, leading to the formation of intense precipitation
and the transport of substantial amounts of water vapour upward and
poleward. This study presents a scenario of a WCB that ascended from
western Europe towards the Baltic Sea using aircraft, lidar and
radar observations from the field experiments HyMeX and
T-NAWDEX-Falcon in October 2012.
Trajectories based on the ensemble data assimilation
system of the ECMWF are used to quantify probabilistically
the occurrence of the WCB and Lagrangian matches
between different observations. Despite severe limitations
for research flights over Europe, the DLR Falcon successfully
sampled WCB air masses during different phases of
the ascent. The overall picture of the WCB trajectories revealed
measurements in several WCB branches: trajectories
that ascended from the East Atlantic over northern France
while others had their inflow in the western Mediterranean
region and passed across the Alps. For the latter ones, Lagrangian
matches coincidentally occurred between lidar water
vapour measurements in the inflow of the WCB south,
radar measurements during the ascent at and its outflow
north of the Alps during a mid-tropospheric flight leg over
Germany.
The comparison of observations and ensemble analyses
reveals a moist bias of the analyses in parts of the WCB inflow
and an underestimation of cloud water species in the
WCB during ascent. In between, the radar instrument measured
strongly precipitating WCB air mass with embedded
linking trajectories directly above the melting layer while
orographically ascending at the southern slops of the Alps.
An inert tracer air mass could confirm the long pathway
of WCB air from the inflow in the marine boundary layer
until the outflow in the upper troposhpere near the Baltic
sea several hours later. This case study illustrates the complexity
of the interaction of WCBs with the Alpine topography,
which leads to (i) various pathways over and around
the Alpine crest and (ii) locally steep WCB ascent with increased
cloud content that might result in enhancement
of precipitation where the WCB flows over the Alps. The
combination of observational data and detailed ensemble-based
trajectory calculations reveals important aspects of
orographically-modified WCBs.

How to cite: Boettcher, M., Schäfler, A., Sodemann, H., Sprenger, M., Kaufmann, S., Voigt, C., Schlager, H., Summa, D., Di Girolamo, P., Nerini, D., Germann, U., and Wernli, H.: A portrayal of an orographic Warm Conveyor Belt using observations from aircraft, lidar and radar, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18794, https://doi.org/10.5194/egusphere-egu2020-18794, 2020.

EGU2020-3665 | Displays | AS4.6

The L-WAIVE campaign over the Annecy lake: An analysis of water vapor variability in complex terrain

Patrick Chazette, Elsa Dieudonné, Anne Monod, Harald Sodemann, Julien Totems, Alexandre Baron, Céline Diana, Pascal Doira, Amandine Durand, Fabienne Maignan, Sylvain Ravier, Andrew Seidl, and Cyrille Flamant

The vertical structure of the water vapor field in the lower troposphere is only sparsely documented in mountainous regions and particularly above Alpine lakes. This may in part due to the complexity of the system, being intimately linked to the orography surrounding the lakes and the forcing of the topography-induced winds. The question arises as to how the vertical extent of evaporation processes over the lakes and how these are influenced by larger scale forcing, in particularly with regard to the vertical dimension.

In order to gain understanding on the vertical structure of atmospheric water vapour above mountain lakes, the L-WAIVE (Lacustrine-Water vApor Isotope inVentory Experiment) field campaign was conducted in the Annecy valley in the French Alps in June 2019. This campaign was based on a synergy between ground-based lidar measurements and ship-borne as well as airborne observations. Two ultra-light aircraft (ULA) were equipped with remote sensing and in-situ instruments to characterize the vertical distribution of the main water vapour isotopes. One ULA embarked a backscatter lidar to monitor the horizontal evolution of the vertical structure of the lower troposphere above and around the lake, and the other one carried an L2130-i Picarro isotope analyser for the in-situ measurement of the H216O, H218O and HDO concentrations, an iMet probe for the measurement of thermodynamic properties (T, RH, p), as well as a pre-cleaned Caltech Active Strand Cloud Water Collector which was modified to efficiently collect cloud water at the speed of the ULA. Offset calibration of the Picarro analyser was carried out for each flight before take-off and after landing. Three-dimensional explorations of the lake environment up to 4 km above the mean sea level (~3.5 km above the ground level) were conducted with the ULAs. Simultaneous vertical profiles of water vapour, temperature, aerosols and winds were acquired from two co-located ground-based lidars installed on the shore of the southern part of the Annecy Lake named “petit lac”, in the commune of Lathuile (45°47' N, 6°12' E). Finally, ship-borne profile measurements of the lake water temperature, pH, conductivity and dissolved O2 as well as water sampling for isotopic analyses were accrued out across the lake of Annecy.

The campaign period included several cases of weather events leading to variability between dry and humid conditions, cloudy and cloud-free conditions, and regimes dominated by weak and strong winds. Flight patterns have been repeated at several times in the day to capture the diurnal evolution as well as variation between different weather regimes. Additional flights have been conducted to map the spatial variability of the water vapour isotope composition with regard to the lake and topography. The scientific strategy of the experiment will be presented, and the first observational results will be described with emphasis on the vertical structure of the lower troposphere and its relationship to orography, including the characterisation of the water vapour isotopologues variability in, above and around the Annecy lake.

How to cite: Chazette, P., Dieudonné, E., Monod, A., Sodemann, H., Totems, J., Baron, A., Diana, C., Doira, P., Durand, A., Maignan, F., Ravier, S., Seidl, A., and Flamant, C.: The L-WAIVE campaign over the Annecy lake: An analysis of water vapor variability in complex terrain, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3665, https://doi.org/10.5194/egusphere-egu2020-3665, 2020.

EGU2020-17782 | Displays | AS4.6

Water vapour and precipitation isotope measurements from different platforms during the IGP campaign, Iceland, in 2018 connect evaporation sources to precipitation sinks

Harald Sodemann, Alexandra Touzeau, Chris Barrell, John F. Burkhart, Andrew Elvidge, Þorsteinn Jónsson, Thomas A. Lachlan-Cope, Jean-Lionel Lacour, Mika Lanzky, Heidi Midtgarden Golid, Rósa Ólafsdóttir, Lukas Papritz, Ian A. Renfrew, Hans Christian Steen-Larsen, Árny Sveinsbjörnsdóttir, and Yongbiao Weng

The water cycle in atmospheric and coupled models is a major contributor to model uncertainty, in particular at high-latitudes, where contrasts between ice-covered regions and the open ocean fuel intense heat fluxes. However, observed atmospheric vapour concentrations do not allow us to disentangle the contributions of different processes, such as evaporation, mixing, and cloud microphysics, to the overall moisture budget. As a natural tracer, stable water isotopes provide access to the moisture sources and phase change history of atmospheric water vapour and precipitation.

Here we present a unique dataset of stable isotope measurements in water vapour and precipitation from the IGP (Iceland Greenland Seas Project) field campaign that took place during February and March 2018. The dataset includes simultaneous measurements from three platforms (a land-station at Husavik, Iceland, the R/V Alliance, and a Twin Otter aircraft) during winter conditions in the Arctic region. Precipitation was collected on an event basis on the research ship, and along two north-south transects in Northern Iceland, and analysed at two stable isotope laboratories. Airborne vapour isotope data was obtained from 10 flights covering a large geographic range (64 °N to 72 °N). Careful data treatment was applied to all stable isotope measurements to ensure sufficient data quality in a challenging measurement environment with predominantly cold and dry conditions, and characterised by strong isotope and humidity gradients. Data quality was confirmed by inter-comparison of the vapour isotope measurements both between ship and aircraft, and between the aircraft and Husavik station.

We exemplify the value of the observations from the analysis of several flights dedicated to the study of the atmosphere-ocean interactions, from low-levels legs and vertical sections across the boundary layer during Cold Air Outbreak (CAO) conditions. The precipitation in Northern Iceland collected at the precipitation sampling network shows clear co-variation with the upstream water vapour measurements at Husavik station, indicative of the wider spatial representativeness of the isotope signals. The land-based snow and vapour measurements are furthermore consistent with the isotope composition in upstream ocean regions sampled by the research vessel, and as linked from aircraft measurements.

How to cite: Sodemann, H., Touzeau, A., Barrell, C., Burkhart, J. F., Elvidge, A., Jónsson, Þ., Lachlan-Cope, T. A., Lacour, J.-L., Lanzky, M., Midtgarden Golid, H., Ólafsdóttir, R., Papritz, L., Renfrew, I. A., Steen-Larsen, H. C., Sveinsbjörnsdóttir, Á., and Weng, Y.: Water vapour and precipitation isotope measurements from different platforms during the IGP campaign, Iceland, in 2018 connect evaporation sources to precipitation sinks, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17782, https://doi.org/10.5194/egusphere-egu2020-17782, 2020.

EGU2020-18719 | Displays | AS4.6

Links between the moisture origin and isotopic signature in water vapour, snowfall and snow pack at Finse Alpine Research Center (1222m) in Southern Noway

Mika Lanzky, Alexandra Touzeau, John F. Burkhart, Simon Filhol, Yongbiao Weng, and Harald Sodemann

Seasonal snow cover is a crucial resource for hydropower in Norway. Understanding water sources and processes related to inter-annual snow cover variability is therefore of fundamental societal relevance. The stable water isotope composition of precipitation provides a natural, integrated tracer of the condensation history during atmospheric water transport. The main parameters dD and d18O along with the secondary quantity d-excess give information about the origin and transport history of moisture from its source to its sink. When snow falls and deposits on the ground as a sediment, it creates a record in the form of the seasonal snow pack.

Here we utilize data acquired during a field campaign in the winter season of 2018-2019 at the Finse Alpine Research Station Center (1222m, 60.6N, 7.5E) in Norway, in order to investigate the transfer of the isotopic signal of source and transport conditions from vapour to snowfall, and to the snow pack.

Over a main period of two months, snowfall was sampled daily, while the water vapour was continuously measured from ambient air guided through a heated inlet to a Picarro L2130i infrared spectrometer, with daily calibration runs. During five periods with intense snowfall, we carried out higher frequency sampling down to 15 minute intervals. Covering the entire winter season, five snowpits were sampled for isotopic analysis as well as detailed stratigraphy. In total more than 400 snow samples where taken and analysed for their isotopic composition, accompanied by routine meteorological observations over the winter season at the site. In addition, we compare the variations in the observed isotope signal at Finse with one derived from moisture source analysis using the Lagrangian diagnostic WaterSip, based on the FLEXPART model and ERA Interim reanalysis data.

To investigate to what degree moisture source information is archived in the snow pack, and how it evolves during the season, we compare snow observations at different time resolution (daily and high frequency snowfall samples) with the record of the snow pack, aided by the snow model CROCUS. The meteorological observations supply context for understanding the snow formation conditions. In particular, deviations from isotopic equilibrium between vapour and precipitation at ambient temperature conditions provide insight into the dominant condensation regime during different intense observation periods.

How to cite: Lanzky, M., Touzeau, A., Burkhart, J. F., Filhol, S., Weng, Y., and Sodemann, H.: Links between the moisture origin and isotopic signature in water vapour, snowfall and snow pack at Finse Alpine Research Center (1222m) in Southern Noway, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18719, https://doi.org/10.5194/egusphere-egu2020-18719, 2020.

EGU2020-11413 | Displays | AS4.6

Statistical relationship between the air moisture source and stable isotope composition of precipitation in Hungary

Emese Bottyán, Erzsébet Kristóf, Krisztina Kármán, László Haszpra, Tamás Weidinger, and György Czuppon

This study presents a detailed statistical analysis on the relationship of precipitation water origin and its stable hydrogen and oxygen isotope compositions for six sites in Hungary. We carried out a moisture source diagnostic by analyzing backward trajectories as it has become a common method for identifying moisture uptake locations. For providing 96 hours long precipitation-event based backward trajectories, we used the NOAA HYSPLIT model on daily basis for six sites of three elevation, 500 m, 1500 m and 3000 m. The moisture uptake regions were determined by calculating specific humidity along the trajectories. Five possible moisture source regions for precipitation were defined: Atlantic Ocean, North European Seas, Mediterranean Sea, Black Sea, Carpathian Basin and European continental areas excluding the Carpathian Basin. The main water vapor source areas are in order the continental regions following by the Mediterranean Sea and the Atlantic Ocean. However, there are spatial differences among the sampling sites reflecting the importance of the geographical locations. Principal component analysis based on the d-excess value of precipitation events showed that source regions such as the Carpathian Basin, the Atlantic Ocean and Mediterranean Sea are separated on the plain determined by the first two principal components. In order to evaluate the impact of the moisture source region on the d-excess value of precipitation events, we carried out ANOVA on the precipitation-event based macrosynoptic classification (Hess-Brezowsky and Péczely). Our results suggest that there are significant differences between amount-weighted d-excess values belonging to different macrosynoptic patterns and these types are related to precipitation events from different moisture source regions. Cluster analysis confirmed the differences in precipitation stable isotope values according to the moisture sources. The observations (precipitation events) were projected on the plain outspreaded by the first two principal components. The coordinates of the observations in this coordinate-system are separated according to the three main moisture source regions. Cluster analysis was also carried out based on d-excess values. The investigation showed that lower d-excess values are related to the Atlantic Ocean, while higher values to the Mediterranean Sea. Thus, we can conclude that the moisture source has strong impact on the stable isotope composition of precipitation water even relative far from the marine regions. The research was supported by the ÚNKP-19-3 New National Excellence Program of the Ministry for Innovation and Technology, the National Research, Development and Innovation Office (project No. OTKA NK 101664, PD 121387) and the AgroMo project (GINOP-2.3.2-15-2016-00028).

How to cite: Bottyán, E., Kristóf, E., Kármán, K., Haszpra, L., Weidinger, T., and Czuppon, G.: Statistical relationship between the air moisture source and stable isotope composition of precipitation in Hungary, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11413, https://doi.org/10.5194/egusphere-egu2020-11413, 2020.

EGU2020-15241 | Displays | AS4.6

Multi-year water vapor isotopes (δ18O/ δ2H) reveal dynamic drivers of moisture source and transport in the Barents Region

Hannah Bailey, Kaisa-Riikka Mustonen, Eric Klein, Pete Akers, Ben Kopec, Moein Mellat, Alun Hubbard, Douglas Causey, and Jeffrey Welker

Stable isotope ratios (δ18O and δ2H) in precipitation (P) and atmospheric water vapor (V) can provide mechanistic information about water cycle processes such as moisture evaporation, transport and recycling dynamics. Such insight is valuable in the Arctic where declining sea ice is amplifying atmospheric temperature and humidity, leading to complex seasonal patterns of synoptic climate and atmospheric moisture transport. Here, we present two years of continuous water vapor isotope data from Pallas-Yllästunturi National Park, northern Finland, to investigate moisture source and transport processes in the Barents Region of the Arctic. High-resolution (1-sec) measurements obtained between December 2017 and December 2019 are coupled with on-site automated weather station data – including air temperature, humidity, solar flux, wind speed and direction – as well as event-based precipitation sampling and stable isotope data over the same interval. Over the two-years, mean vapor δ18OV, δ2HV and d-excessV values are -24.50‰, -181.49‰ and 14.49‰, respectively. These values are strongly correlated and define a local vapor line for Pallas where δ2HV = 7.6 x δ18OV + 5.9 (R2=0.98). We observe a mean offset of 10.9 ‰ between Pallas δ18OV and δ18OP, and d-excess is -4.8 ‰ lower in δ18OP. There is a larger offset between vapor and precipitation d-excess during summer (-8.4‰) compared to winter (0.1‰) that may reflect varying fractionation coefficients between solid and liquid cloud-precipitation phases. The timeseries exhibits strong seasonality characterized by lower δ18OV2HV and higher d-excess during winter, and the reverse during summer. In winter these broad patterns are primarily driven by synoptic-scale processes that influence the source and transport pathway of atmospheric moisture, and three dominant oceanic evaporative source regions are identified: the Barents, Norwegian, and Baltic Seas. Yet on diurnal timescales we observe distinct summer diel cycles that correlate with local fluctuations in specific humidity (q). These seasonal relationships are explored in context of spatial-temporal patterns in sea ice and snow cover distribution, as well as evapotranspiration processes across northern Eurasia. Finally, to better understand how current changes in the Arctic hydrologic cycle relate to inherent variability of the polar jet stream and related synoptic-scale weather, our isotope data are examined in context of dynamic circulation modes of the North Atlantic Oscillation (NAO) and Arctic Oscillation (AO).

How to cite: Bailey, H., Mustonen, K.-R., Klein, E., Akers, P., Kopec, B., Mellat, M., Hubbard, A., Causey, D., and Welker, J.: Multi-year water vapor isotopes (δ18O/ δ2H) reveal dynamic drivers of moisture source and transport in the Barents Region, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15241, https://doi.org/10.5194/egusphere-egu2020-15241, 2020.

EGU2020-16042 | Displays | AS4.6

Identification of source-sink relationships in southern Africa by stable water isotopes analysis and Lagrangian moisture source diagnostics

Marielle Geppert, Stephan Pfahl, Ulrich Struck, Ingo Kirchner, Elisha Shemang, Kai Hartmann, and Frank Riedel

Many palaeoclimate reconstructions are based on the fact that stable water isotopes are conserved in different highly resolved paleo-archives such as ice cores or calcium carbonates. Stable water isotopes are tracers of moisture in the atmosphere because they record information about evaporation and condensation processes during the transport of air parcels. These processes cause isotopic fractionation that leads to isotopic enrichment or depletion. The isotopic composition of precipitation is strongly correlated with altitude above sea level, distance to the coast and local surface air temperature. Knowledge on the source and transport of moisture is thus crucial for the interpretation of stable isotopes in precipitation and in palaeo-archives.
Studies analysing the linkage between stable water isotope measurements and moisture sources in southern Africa are scarce. Yet, as changes in the transport pattern can influence precipitation patterns and amounts, in a semi-arid region like southern Africa that is threatened by droughts, this knowledge is of particular interest. Thus, the aims of this study are (1) to reveal the principal moisture source areas and transport routes of specific target areas in southern Africa, (2) to assess the influence of different transport patterns on the isotopic composition of precipitation and by this (3) to create a modern analogue for palaeoclimate studies in this region.
About 200 water samples, mainly from headwaters of rivers, but also from precipitation events, springs and lakes, were collected throughout southern Africa and the stable water isotope composition (δ2H and δ18O) was analysed. To detect moisture sources for this set of isotope measurements, backward air parcel trajectories were calculated from the sample location, using the LAGRANTO tool based on ERA5 reanalysis data. Variations in specific humidity along the trajectories were then used to detect moisture uptake.
The analysis reveals main transport patterns related to the Intertropical Convergence Zone and easterly winds as well as the effects of topographical forcing, which is, for example, very pronounced above Lesotho. The results provide detailed insights into the relationships between atmospheric circulation and δ2H and δ18O values of precipitation over southern Africa, which is a prerequisite for the interpretation of isotopic records that are used for palaeoclimatic reconstructions.

How to cite: Geppert, M., Pfahl, S., Struck, U., Kirchner, I., Shemang, E., Hartmann, K., and Riedel, F.: Identification of source-sink relationships in southern Africa by stable water isotopes analysis and Lagrangian moisture source diagnostics, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16042, https://doi.org/10.5194/egusphere-egu2020-16042, 2020.

EGU2020-13001 | Displays | AS4.6

Drivers of stable water isotope variability in the cold and warm sector of extratropical cyclones from two case studies in the Southern Ocean

Iris Thurnherr, Franziska Aemisegger, Lukas Jansing, Katharina Hartmuth, Josué Gehring, Stephan Pfahl, Maxi Böttcher, Alexis Berne, and Heini Wernli

Dynamical processes in the atmosphere strongly influence the large temporal and spatial variability of the atmospheric branch of the water cycle. For instance, the advection of air masses by synoptic-scale weather systems induces air-sea moisture fluxes such as evaporation, precipitation and dew deposition. It is important to better investigate and quantify this linkage between dynamical phenomena and details of the atmospheric water cycle. In addition, one of the big challenges in monitoring the atmospheric water cycle is the measurement of turbulent moisture fluxes over the ocean. Stable water isotopes (SWIs) serve as a tool to trace atmospheric processes which shape the atmospheric water cycle and, thus, provide important insights into moist processes associated with weather systems, in particular air-sea fluxes.

In this study, we investigate the impact of air-sea moisture fluxes on the variability of SWI signals in the marine boundary layer. Measurements of the second-order isotope variable deuterium excess in the marine boundary layer of the Southern Ocean show positive/negative anomalies in the cold/warm sector, respectively, of extra-tropical cyclone due to opposing moisture fluxes and non-equilibrium fractionation processes in the two sectors. The drivers of these contrasting SWI signals are analysed using the isotope-enabled Consortium for Small-Scale Modelling model for two case studies. The simulated isotope signals during the case studies show excellent agreement with ship-based isotope measurements from the Southern Ocean performed during the Antarctic Circumnavigation expedition in January and February 2017.

The main driver of SWI variability in the cold sector is enhanced ocean evaporation which substantially modifies the advected SWI signal from the Antarctic continent during a cold air outbreak. In the warm sector, dew deposition on the ocean surface and cloud formation are mainly driving the observed negative deuterium excess anomaly, which can be conserved and advected over several 100 km in the warm sector of an extratropical cyclone.

The results of this study illustrate the strong dependence of the isotopic composition of water vapour in the marine boundary layer on the predominant atmospheric large-scale flow situation. In particular in the storm track regions, the variability of SWIs in marine boundary layer water vapour is largely shaped by the sign and strength of air-sea fluxes induced by the meridional transport of air masses.

How to cite: Thurnherr, I., Aemisegger, F., Jansing, L., Hartmuth, K., Gehring, J., Pfahl, S., Böttcher, M., Berne, A., and Wernli, H.: Drivers of stable water isotope variability in the cold and warm sector of extratropical cyclones from two case studies in the Southern Ocean, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13001, https://doi.org/10.5194/egusphere-egu2020-13001, 2020.

EGU2020-21964 | Displays | AS4.6

North Atlantic SST variability and high impact storms affecting the Iberian Peninsula

Fátima Ferreira, Margarida L. R. Liberato, Alexandre M. Ramos, and Raquel Nieto

The Iberian Peninsula has experienced on recent years an increasing number of high impact cyclones (e.g. Klaus, 23-24 January 2009 and Xynthia, 27-28 February 2010; Liberato et al. 2011; 2013) associated with extreme precipitation events, flooding and damage to infrastructure. Recent examples are cyclones Elsa and Fabien, on December 2019, which forced more than 250 people to be evacuated from their homes in Mondego region villages, in central Portugal, due to rising river waters and infrastructure disruption .

However until now not enough evidence has been gathered to confirm a general and significant increase in the frequency and intensity of these events in the north-eastern Atlantic. In fact, according to Karremann et al. (2016) the maximum in recent years is comparable to other stormy periods in the 1960s and 1980s, suggesting that their frequency of occurrence undergoes strong multi-decadal variability.

In this study a high impact extratropical cyclones dataset developed in the framework of project “WEx-Atlantic - Weather Extremes in the Euro Atlantic Region: Assessment and Impacts” is used to assess the variability in frequency and intensity of these events over the last decades in the Iberian Peninsula. A ranking of daily precipitation days for the Iberian Peninsula taking into account not only the area affected but also its average intensity (Ramos et al. 2014) is also used. Additionally, a spatio-temporal variability of sea surface temperature (SST) is performed in the North Atlantic, using ECMWF ERA5 reanalysis data for the period 1979-2019. Finally the relevance of the North Atlantic SST variability on the intensity of these extreme events affecting the Iberian Peninsula on recent winter seasons is discussed.  

Acknowledgements

The authors would like to acknowledge the financial support by Fundação para a Ciência e a Tecnologia, Portugal (FCT), through projects PTDC/CTA-MET/29233/2017 and UIDB/50019/2020 – IDL. A.M. Ramos is supported by Scientific Employment Stimulus 2017 from FCT (CEECIND/00027/2017).

References

Karremann et al. (2016) Atmos. Sci. Let., 17: 354-361 DOI: 10.1002/asl.665

Liberato et al. (2011) Weather, 66: 330-334 DOI: 10.1002/wea.755

Liberato et al. (2013) Nat. Hazards Earth Syst. Sci., 13: 2239-2251 DOI: 10.5194/nhess-13-2239-2013

Ramos et al. (2014) Atmos. Sci. Let., 15: 328–334, DOI: 10.1002/asl2.507

How to cite: Ferreira, F., Liberato, M. L. R., Ramos, A. M., and Nieto, R.: North Atlantic SST variability and high impact storms affecting the Iberian Peninsula, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21964, https://doi.org/10.5194/egusphere-egu2020-21964, 2020.

EGU2020-1354 | Displays | AS4.6

Moisture recycling over the Iberian Peninsula. The impact of 3DVAR data assimilation

Santos J. González-Rojí, Jon Sáenz, Javier Díaz de Argandoña, and Gabriel Ibarra-Berastegi

The moisture recycling is defined as the fraction of precipitation over a delimited region that comes from the evaporation over that region. Its importance lies in the fact that it is an approximated measurement of a regional feedback between the atmosphere and the surface. Thus, this study estimates the spatio-temporal distribution of moisture recycling over the Iberian Peninsula (IP), and focuses on the impact of the use of 3DVAR data assimilation during the modeling stage.

For that purpose, two different simulations were run using the Weather and Research Forecasting (WRF) model with a horizontal resolution of 15 km over the IP. The first simulation (WRF N) was nested inside ERA-Interim as usual in numerical downscaling exercises, with information passed to the domain through the boundaries. The second run (WRF D) presents the same configuration as WRF N, but it also includes 3DVAR data assimilation step every six hours (at 00, 06, 12 and 18 UTC). Sea surface temperature was updated daily, and observations in PREPBUFR format included in the NCEP ADP Global Upper Air and Surface Weather Observations dataset were used for the data assimilation step. Only those inside a 120-minute window centered at the analysis times were assimilated. Both simulations cover the period 2010-2014, but the experiment WRF D was extended later until 2018.

The lowest values of moisture recycling (around 3 %) are obtained from November to February, while the most remarkable values are observed in spring (around 16 %) in both simulations. The moisture recycling is confined to the southeastern corner of the IP during winter. However, during spring and summer, a gradient of higher values towards the northeastern corner of the IP are observed in both simulations. The differences between simulations, associated to the dryness of the soil in the model, are highlighted during summer and autumn. WRF D presents a lower bias and produces more reliable results because of a better representation of the atmospheric moisture.

A Cross-Correlation Function (CCF) based analysis was performed for each combination of moisture recycling, accumulated precipitation and mean soil moisture over the IP. For the common period (2010-2014), the results show that the WRF D experiment extends the lifespan of moisture over the IP. The CCF analysis for soil moisture against precipitation also shows an unphysical negative lag (-1 month) for WRF N, whilst for WRF D both variables are simultaneous. For the extended WRF D simulation (2010-2018), it was found that the delay between precipitation and moisture recycling over the IP is five months.

How to cite: González-Rojí, S. J., Sáenz, J., Díaz de Argandoña, J., and Ibarra-Berastegi, G.: Moisture recycling over the Iberian Peninsula. The impact of 3DVAR data assimilation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1354, https://doi.org/10.5194/egusphere-egu2020-1354, 2020.

AS4.38 – Applications of meteorology and climatology to agriculture

EGU2020-372 | Displays | AS4.38

Comparison between forecasts of reference evapotranspiration and ETo values calculated using data from different climatic conditions

Ghaieth Ben Hamouda, Francesca Ventura, Daniele Zaccaria, Khaled M. Bali, and Richard L. Snyder

Evapotranspiration is the transfer of water from the earth's surface to the atmosphere. It comprises the sum of water losses to atmosphere due to the processes of evaporation of moisture from soil, water bodies and wet plant canopies, and the transpiration of water from plants. Forecasts of this crucial component of the hydrologic cycle can be very valuable for growers, farm managers, irrigation practitioners, water resource planners and managers, and reservoir operators for their planning, allocation, delivery and scheduling decisions, as well as to hydrologic scientists for research purposes. Verifying the reliability of models’ forecasts is among the critical tasks for development and performance evaluation of physical models. In fact, the verification allows understanding the models’ behavior, and evaluating their applicability and dependability. The US National Weather Service (NWS) has released a product that provides forecasts of reference evapotranspiration (FRET) at 2.5-km grid resolution for the entire continental US. In this study, a comparison is made between ETo estimates from FRET and ETo values calculated by the California Irrigation Management Information System (CIMIS) for 68 days during summer 2019. Both the FRET forecasts and ETo values were obtained from NWS and CIMIS, respectively, on the basis of 15 CIMIS locations that are representative of different climatic conditions in California. In addition, air temperature, dew point temperature, relative humidity, wind speed, and vapor pressure deficit (VPD) data were also collected/calculated from the NWS and CIMIS websites to analyze the sensitivity of FRET forecasts to predictions of these parameters. All FRET forecasts were performed with timescales of 1, 3, 5 and 7 days. Statistical indices were calculated to assess the dependability of FRET values. They showed a good correlation of the FRET model outputs with CIMIS ETo data, with some differences depending on the climatic characteristics of selected weather stations’ locations, suggesting that FRET data could be valuable for anticipating near-future water demand and improve irrigation management in California.

How to cite: Ben Hamouda, G., Ventura, F., Zaccaria, D., M. Bali, K., and L. Snyder, R.: Comparison between forecasts of reference evapotranspiration and ETo values calculated using data from different climatic conditions, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-372, https://doi.org/10.5194/egusphere-egu2020-372, 2020.

The aim of the ADAPTER project (www.adapter-projekt.de) of the Helmholtz Association of German Research Centres is to develop products and usable information that help improve agriculture’s resilience to extreme weather conditions and climate change in Germany. One of the main hydrometeorological impacts on agriculture is the soil water budget. Here, we use the Terrestrial Systems Modelling Platform (TSMP) in forecast mode forced by ECMWF forecast data over a domain covering most of North-Rhine Westfalia (NRW, Germany). TSMP is a fully-coupled regional Earth system model with COSMO at 1km spatial resolution as the atmospheric component, with the Community Land Model (CLM) for the land surface interface, and ParFlow for the surface and sub-surface part of the water cycle, both models at 500m resolution. This allows a representation of the closed water budget, including three-dimensional sub-surface and groundwater flow. Here, we demonstrate the usefulness of the fully coupled TSMP for agriculture applications, by focussing on two fundamental parameters of the soil water budget: First, in the context of the droughts that affected Europe, and particularly Germany, over the summers 2018 and 2019, one major parameter for estimating and monitoring the water stress of plants is the fraction of plant available water (fPAW). The pressure head simulated by ParFlow is used to calculate fPAW, on the basis of soil parameters like porosity and the Van Genuchten equation. fPAW is calculated over different soil depths from 0.1m to 3m, to provide information about the water stress of plants with different rooting depths. Our results show that the succession of extremely dry summers in 2018 and 2019, when the meteorological drought evolved into an agricultural and eventually into a hydrological drought, has led to very dry soils showing a fPAW below 30-50% over most of NRW, meaning that it became stressful for plants to extract water from the soil. This did not only affect the upper soil layers, as in 2018, but also deeper layers became very dry, thus no longer only impacting shallow root crops, but also plants with a higher root depth like trees. The wetter 2019 autumn allowed a recovery of the soil water content around the field capacity for the upper layers over a major part of the domain, while the deeper soil remains abnormally dry, especially in the south-western part of the domain. Second, knowing the amount of seepage water over a given period is not only important to monitor the groundwater recharge, which has become a major issue in the context of the past two summers, but also to estimate the leakage of nutrients and pollutants from the upper soil to deeper layers or even the groundwater in the context of certain environmental compliance issues. In accordance with the results obtained for fPAW, TSMP simulated seepage water flux during autumn 2019 only for the upper soil layers; this excessive water is only gradually percolating into deeper soil layers, which still remain clearly below the field capacity over a significant part of the domain.

How to cite: Belleflamme, A., Goergen, K., Wagner, N., Bathiany, S., Rechid, D., and Kollet, S.: Forecasts of plant available and seepage water for agricultural usage during recent extreme hydrometeorological conditions in western Germany using a convection-permitting regional Earth-system model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4704, https://doi.org/10.5194/egusphere-egu2020-4704, 2020.

EGU2020-8495 | Displays | AS4.38

Ammonia-biosphere interaction from IASI and ERA5

Rimal Abeed, Sarah Safieddine, Lieven Clarisse, Martin Van Damme, Pierre-François Coheur, and Cathy Clerbaux

The global concentration of reactive nitrogen (e.g. NH3, NOx and N2O) has intensely increased since the pre-industrial era. Ammonia (NH3) is one of the main sources of reactive nitrogen in the atmosphere and plays a crucial role in the formation of inorganic particulate matter, which harms health and deteriorates air quality. In addition to that, the wet/dry deposition of ammonia derivatives affects ecosystems through acidification and eutrophication of soil and water bodies; leading to a loss in biodiversity and intensification of the response to climate change. NH3 is mainly emitted by biomass burning and agricultural activities. Agriculture contributes to air pollution and is affected by atmospheric composition, meteorology and climate change.

Several studies proved the efficiency of the IASI instrument aboard Metop satellites in measuring ammonia from space. For the last ten years, hotspots of ammonia point sources have been identified and categorized around the world.

In this poster, we explore the interaction of atmospheric ammonia with land, meteorological, and leaf conditions. We look at the temporal variability of ammonia in different regions of the world. The relationship land-ammonia volatilization is assessed by comparing the variability of surface soil moisture and the skin temperature products from the ECMWF latest reanalysis (ERA5) with IASI NH3 total columns. The meteorology-ammonia relation is examined, by looking at air temperature, humidity, precipitation, planetary boundary layer height, and wind speed/direction. Agricultural seasons in studied regions are detected from space in matter of leaf area per ground area. The crop-ammonia relation is assessed by looking at the Leaf Area Index (LAI) products. The regions examined have been identified as point sources and/or hotspots of ammonia of agricultural and industrial sources (mainly fertilizer industry).

The result of this work will improve our understanding of biosphere-atmosphere interactions, in particular, the relationship between ammonia on the one hand and land, meteorology and crops on the other hand, in different regions in the world.

How to cite: Abeed, R., Safieddine, S., Clarisse, L., Van Damme, M., Coheur, P.-F., and Clerbaux, C.: Ammonia-biosphere interaction from IASI and ERA5, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8495, https://doi.org/10.5194/egusphere-egu2020-8495, 2020.

EGU2020-8573 | Displays | AS4.38

Predicting vineyard's evolution with the crop model IVINE driven by meteorological model forecasts: preliminary results.

Valentina Andreoli, Claudio Cassardo, and Massimiliano Manfrin

The crop growth model IVINE (Italian Vineyard Integrated Numerical model for Estimating physiological values) was developed at our Dept. of Physics in FORTRAN language as a research model in order to evaluate the environmental forcing effects on vine growth, being vines generally strongly sensitive to meteorological conditions, and with the idea of using it for assessing climate change effects on grape growth. IVINE requires a set of hourly meteorological and soil data as boundary conditions. Input data that are more relevant for the model to correctly simulate the plant growth are air temperature and soil moisture. Among the principal IVINE outputs, we mention: the main phenological stages (dormancy exit, bud-break, fruit set, veraison, and harvest), the Leaf Area Index, the yield, the berry sugar concentration and the predawn leaf water potential. IVINE model requires to set some experimental parameters depending on the cultivar; at present, IVINE is optimized for Nebbiolo and other northern Italy autocthonous and common varieties. In order to use the model for forecasting purposes, the set of input data required by IVINE must be retrieved by the simulation's outputs of a mesoscale model, in turn driven by a Global Circulation Model simulation. In our Department, a voluntary meteorological forecasting service has been working for several years; for this task four daily 5-days simulations are performed over Piedmont Italian region with WRF (Weather Research and Forecast) mesoscale model driven by the GFS (Global Forecast System). Taking advantage of these runs, we have organized a system able to extract, for each simulation, the hourly values of the parameters needed by IVINE. The input dataset is updated every six hours using the values coming by the new simulation, while considering past values acquired. Since IVINE simulation must start from the previous season, in order to correctly simulate the dormancy exit, we have carried out several simulations with IVINE by starting in the same date (January 1st 2018) and ending at the fifth day of the last available WRF simulation. In this way, we were able to made a sort of temporal ensemble meteogram for the last five days; where the results of the most recent simulation were displayed with those of previuos runs and the number of simulations was gradually decreasing from 20 to 1 with the progress of the time.

The simulations were performed for the whole 2019 year over 156 WRF grid points distributed in the Langhe, Roero and Monferrato wine areas of Piedmont. Here some pheno-physiological variables in vineyards are analyzed, relative to some significant points and events, and the main results are discussed.

How to cite: Andreoli, V., Cassardo, C., and Manfrin, M.: Predicting vineyard's evolution with the crop model IVINE driven by meteorological model forecasts: preliminary results., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8573, https://doi.org/10.5194/egusphere-egu2020-8573, 2020.

EGU2020-8852 | Displays | AS4.38

Soil moisture and the water cycle in the UK Climate Projections

Jennifer Pirret, Fai Fung, John. F.B. Mitchell, and Rachel McInnes

Soil moisture is a key environmental factor for plant cultivation: too little and plant growth is restricted due to drought conditions; too much and soil becomes water-logged. It is important to understand how well climate models can represent current soil moisture processes as well as how soil moisture will respond to a changing climate, to inform adaptation of plant cultivation to future climate change. We explore current and future climate soil moisture conditions alongside water cycle processes such as evaporation and run-off in the latest UK Climate Projections (UKCP). Three model ensembles are available: UKCP Global, Regional and Local, with horizontal resolutions of 60km, 12km and 2.2km respectively. These each contain the Joint UK Land Environment Simulator (JULES) model as their land surface component. This suite of models offers the opportunity to understand the effects of parameter uncertainty and spatial resolution. Firstly, we assess the performance of the Global and Regional simulations by evaluating results from the baseline period (1981-2010) in terms of soil moisture (and the overall water balance) by comparing it to observations and to JULES driven by observations. Secondly, we assess how the water balance responds to a high future greenhouse gas concentration pathway. We find that soil moisture is likely to be lower in the summer and early autumn and spends a longer time below levels optimal for plant growth. The potential drivers of this change are explored, including future changes in precipitation and evaporation.

How to cite: Pirret, J., Fung, F., Mitchell, J. F. B., and McInnes, R.: Soil moisture and the water cycle in the UK Climate Projections , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8852, https://doi.org/10.5194/egusphere-egu2020-8852, 2020.

EGU2020-9780 | Displays | AS4.38

What will be the consequences of the climate change on soft wheat in Normandy (France) in 2050-2100 ? Prospective impact study based on ALADIN-Climate model

François Beauvais, Olivier Cantat, Philippe Madeline, Patrick Le Gouee, Sophie Brunel-Muguet, and Mohand Medjkane

France is the fifth largest producer worldwide of soft wheat. Every year over 35 million tons of wheat are harvested (average 2011-2017, data from France AgriMer) on the territory. Hence, the cereal sector occupies an important place in the French agricultural economy.

However, because of its high dependence on the atmospheric conditions, wheat production is vulnerable to climate change. Since the mid-1990s, a stagnation of yield has already been observed. According to the agronomists, the main cause is climate change. Water deficit during the production and days of scalding during the filling of the grains. By 2050-2100, these extreme events are expected in the most likely scenario (i.e. warmer springs and summers). Hence, it is of importance to know if the shortening of the plant cycle resulted from the rise in the global temperature could prevent these extreme events from happening and if other related impacts could occur.

This study illustrates 2 agricultural plains containing open fields in the Normandie area, located in the north-west part of France. In this region, wheat locally occupies more than 50% of the agricultural land. These two areas are the plain of Caen which is under the influence of an oceanic climate and the plain of Evreux where the climate is slightly more continental.

The aim of this communication if to present what the climatic conditions for the soft wheat in 2050 and 2100 would be and to compare these projected periods with the ones of the reference period (1976-2005). The reported results were obtained by the means of a simulation of  the phenology to which is grafted the occurrence of climatic hazards such as water deficit, thermal exhaustion, frost days, vernalization, low temperatures and radiation deficit. Indeed, those hazards are able to generate consequences to the agricultural yield. The climatic data are extracted from ALADIN-Climate (data from CNRS-2014) in the case of three RCP scenarii of IPSS, available on the website of Drias Les futurs du climat.

In the context of pronounced climate change, along with unchanged sowing dates by 2050 and 2100, the increase in temperatures would lead to shorten the crop cycle, and hence to a date shift in the plant phenology. Consequently, there would be a shorter overlap between the end of the crop cycle and the summer period and, usually characterized by heat waves and water stress events which are expected to occur more often. Thus high temperature triggered scalding would not be observed as much as expected and the cumulated water limitation would be also lower. However, because of this precocity, emerging consequences might be expected regarding deleterious effects of lower temperatures during meiosis, and decrease of solar radiation at the onset of stem elongation. Mild winters would also reduce the days of vernalization, limiting cold requirements during tillering. This study demonstrates the use of bioclimatic models to unravel the crop phenology modifications, expected to occur by the end of the century, under the main environmental climatic drivers.

How to cite: Beauvais, F., Cantat, O., Madeline, P., Le Gouee, P., Brunel-Muguet, S., and Medjkane, M.: What will be the consequences of the climate change on soft wheat in Normandy (France) in 2050-2100 ? Prospective impact study based on ALADIN-Climate model , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9780, https://doi.org/10.5194/egusphere-egu2020-9780, 2020.

EGU2020-10563 | Displays | AS4.38

Effects of inter-annual climate variability on grape harvest timing in rainfed hilly vineyards of Piedmont (NW Italy)

Danilo Rabino, Marcella Biddoccu, Giorgia Bagagiolo, Guido Nigrelli, Luca Mercalli, Daniele Cat Berro, Federico Spanna, Giorgio Capello, and Eugenio Cavallo

Historical weather data represent an extremely precious resource for agro-meteorology for studying evolutionary dynamics and for predictive purposes, to address agronomical and management choices, that have economic, social and environmental effect. The study of climatic variability and its consequences starts from the observation of variations over time and the identification of the causes, on the basis of historical series of meteorological observations. The availability of long-lasting, complete and accurate datasets is a fundamental requirement to predict and react to climate variability. Inter-annual climate changes deeply affect grapevine productive cycle determining direct impact on the onset and duration of phenological stages and, ultimately, on the grape harvest and yield. Indeed, climate variables, such as air temperature and precipitation, affect evapotranspiration rates, plant water requirements, and also the vine physiology. In this respect, the observed increase in the number of warm days poses a threat to grape quality as it creates a situation of imbalance at maturity, with respect to sugar content, acidity and phenolic and aromatic ripeness.

A study was conducted to investigate the relationships between climate variables and harvest onset dates to assess the responses of grapevine under a global warming scenario. The study was carried out in the “Monferrato” area, a rainfed hillslope vine-growing area of NW Italy. In particular, the onset dates of harvest of different local wine grape varieties grown in the Vezzolano Experimental Farm (CNR-IMAMOTER) and in surrounding vineyards (affiliated to the Terre dei Santi Cellars) were recorded from 1962 to 2019 and then related to historical series of climate data by means of regression analysis. The linear regression was performed based on the averages of maximum and minimum daily temperatures and sum of precipitation (1962–2019) calculated for growing and ripening season, together with a bioclimatic heat index for vineyards, the Huglin index. The climate data were obtained from two data series collected in the Experimental farm by a mechanical weather station (1962-2002) and a second series recorded (2002-2019) by an electro-mechanical station included in Piedmont Regional Agro-meteorological Network. Finally, a third long-term continuous series covering the period from 1962 to 2019, provided by Italian Meteorological Society was considered in the analysis.

The results of the study highlighted that inter-annual climate variability, with a general positive trend of temperature, significantly affects the ripening of grapes with a progressive anticipation of the harvest onset dates. In particular, all the considered variables excepted precipitation, resulted negatively correlated with the harvest onset date reaching a high level of significance (up to P< 0.001). Best results have been obtained for maximum temperature and Huglin index, especially by using the most complete dataset. The change ratios obtained using datasets including last 15 years were greater (in absolute terms) than results limited to the period 1962-2002, and also correlations have greater level of significance. The results indicated clearly the relationships between the temperature trend and the gradual anticipation of harvest and the importance of having long and continuous historical weather data series available.

How to cite: Rabino, D., Biddoccu, M., Bagagiolo, G., Nigrelli, G., Mercalli, L., Cat Berro, D., Spanna, F., Capello, G., and Cavallo, E.: Effects of inter-annual climate variability on grape harvest timing in rainfed hilly vineyards of Piedmont (NW Italy), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10563, https://doi.org/10.5194/egusphere-egu2020-10563, 2020.

EGU2020-18259 | Displays | AS4.38

Validation of IVINE crop growth model using MACSUR2 project measurements in a few European vineyards.

Claudio Cassardo, Valentina Andreoli, and Federico Spanna

The numerical crop growth model IVINE (Italian Vineyard Integrated Numerical model for Estimating physiological values) was originally developed at the dept. of Physics, Univ. of Torino, as a research model with the aim to simulate grapevine phenological and physiological processes. Since vines are generally strongly sensitive to meteorological conditions, the model should be able to evaluate the environmental forcing effects on vine growth and, eventually, on its production. IVINE model requires a set of hourly meteorological and soil data as boundary conditions; the more relevant input for the model to correctly simulate the plant growth are: air temperature and soil moisture. Among the principal IVINE outputs, we mention: the main philological stages (dormancy exit, bud-break, fruit set, veraison, and harvest), the leaf development, the yield, the berry sugar concentration, and the predawn leaf water potential. The IVINE requires to set some experimental parameters depending on the cultivar; at present, IVINE is optimized for Nebbiolo and other common varieties (such as, for example, cvs. Barbera, Vermentino, Cannonau, etc for Italy), but validation experiments have been performed only for Nebbiolo variety, due to the difficulty to gather all required measurements useful to drive the model and to compare its outputs for several consecutive years in the same vineyard. In the frame of the second part of the EU JPI-FACCE project named MACSUR (Modelling European Agriculture with Climate Change for Food Security), some data relative to vineyards displaced in several European countries were made available, thus we tried to execute simulations with IVINE in those vineyards. Since input data required by IVINE were not all present, we decided to extract input data from the international GLDAS database in the nearest grid point to the experimental vineyard, and to run the trusted land surface model UTOPIA on those points in order to evaluate soil variables required by IVINE. The main results obtained by those simulations, as well as the few possible validations with experimental observations, will be shown and commented. As a summary, we can say that the simulation carried out with IVINE seems able to well account for the interannual variability of the meteorological conditions, and the used settings seems able to allow a sufficiently valid simulation of the pheno-physiological conditions of the vineyards, but the approximation in the input data causes departures larger than if local measurements would be used.

How to cite: Cassardo, C., Andreoli, V., and Spanna, F.: Validation of IVINE crop growth model using MACSUR2 project measurements in a few European vineyards., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18259, https://doi.org/10.5194/egusphere-egu2020-18259, 2020.

EGU2020-22680 | Displays | AS4.38

Crop response to climate change: SPAR facilities, capabilities and tools

Vangimalla Reddy and Mura Jyostna Devi

Environmental stress factors have far‐reaching implications on global food security and significantly impact crop production through their effects on soil fertility, carbon sequestration, plant growth, and productivity.  Several approaches have been used to assess the effects of environmental stress factors on crops and to evaluate possible solutions. One such approach is the use of crop simulation models to explore the impact of climate stresses on crop plants will be discussed in this presentation, to provide a more accurate understanding of climate change effects on agriculture in the coming decades. Crop models, based on appropriate concepts and processes, have the predictive capability under new environments and can be used either alone or with other emerging newer technologies to disseminate plant growth and development information. Crop models such as GOSSYM, a cotton simulation model was used to evaluate crop responses to factors such as weather, irrigation, and fertilization by simulating the growth and production of crops from planting to harvest. The presentation also discusses the SPAR (Soil-Plant-Atmosphere Research) system to generate data required to understand various facets of growth and developmental processes and to build process-level models for managing the cotton crop to abiotic stresses. The SPAR units are optimized for the measurement of a plant and canopy-level physiological responses such as photosynthesis and transpiration under precisely controlled, but naturally lit, environmental conditions and to relate the basic processes directly to the environment. Various validation efforts of the GOSSYM cotton simulation model and its uses in multiple applications such as climate change impacts, technology transfer, hypothesis testing in research, farm management, and policymaking decisions will be discussed.

How to cite: Reddy, V. and Jyostna Devi, M.: Crop response to climate change: SPAR facilities, capabilities and tools, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22680, https://doi.org/10.5194/egusphere-egu2020-22680, 2020.

AS5.4 – Coupled modelling and data assimilation of dynamics and chemistry of the atmosphere

EGU2020-20058 | Displays | AS5.4

Global Air quality Forecast and Information Systems (GAFIS) - a new WMO - GAW initiative

Johannes Flemming, Okasna Tarasova, Lu Ren, Alexander Baklanov, and Greg Carmichael

Air pollution is the single largest environmental risk factor to health globally; it contributes to climate change, is detrimental for ecosystems, damages property, impacts visibility and can threaten food and water security. A wide variety of Air Quality (AQ) systems operate at different spatial and temporal scales to provide information required to mitigate the impact of or to reduce air pollution. 

Recognising the importance to support the transition of scientific efforts into useful services, the Global Atmosphere Watch Programme (GAW) of the World Meteorological Organisation (WMO) has started an initiative on Global Air quality Forecast and Information Systems (GAFIS). GAFIS aims to become a network for the development of good practices for air quality forecasting and monitoring services using  diverse approaches. GAFIS will closely interact with existing GAW efforts on air pollution forecasting and dust strom prediction, and it intends to build strong links with the international health community. As a major first step, GAFIS will carry out and maintain a survey of AQ information systems and identify areas and regions with a lack of adequate AQ services. GAFIS aims to improve access to air quality observations and to encourage better quality control and meta-data provision.  GAFIS will initiate coordinated evaluation activities of air quality services using a harmonized evaluation protocol. Finally,  promoting operational applications of atmospheric composition feedbacks in Numerical Weather Prediction is a further objective of GAFIS.

In the presentation we will introduce GAFIS to the scientific community and invite collaboration within its framework. 

How to cite: Flemming, J., Tarasova, O., Ren, L., Baklanov, A., and Carmichael, G.: Global Air quality Forecast and Information Systems (GAFIS) - a new WMO - GAW initiative, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20058, https://doi.org/10.5194/egusphere-egu2020-20058, 2020.

EGU2020-3487 | Displays | AS5.4

Update on European Regional Air Quality Forecast in the Copernicus Atmosphere Monitoring Service (CAMS)

Augustin Colette, Gaelle Collin, and Jérôme Barré

 

The Copernicus Atmosphere Monitoring Service (CAMS) delivers a wealth of information on atmospheric composition change over short to long timescales. One of the core products of CAMS regards short term air quality forecasts with a three days lead time as well as reanalyses over the past years for the European region.

This service is covered by the CAMS_50 project which is now operational since 2015. It relies on a distributed production of 9 individual air quality models, consolidated by a centralised regional production unit at Météo-France before delivery to the European Centre on Medium Range Meteorological Forecasts, which implements the CAMS service.

Each model is operated by its own development team across Europe, all of them deliver air quality forecasts covering the whole continent at 10km resolution. The modelling team currently operational are at present: CHIMERE (France), DEHM (Denmark), EMEP/MSC-W (Norway), EURAD-IM (Germany), GEM-AQ (Poland), LOTOS-EUROS (The Netherlands), MATCH (Sweden), MOCAGE (France), SILAM (Finland). Two additional models are now applying to join the ensemble: MINNI (Italy), and MONARCH (Spain).

Such an ensemble of different models offers excellent complementarity in model capabilities as demonstrated by the performances of the ENSEMBLE product. It also leads to substantial challenges in coordinated model development. We will present the main recent achievements, status, and future plans for the validation and development of models underlying the service.

 

How to cite: Colette, A., Collin, G., and Barré, J.: Update on European Regional Air Quality Forecast in the Copernicus Atmosphere Monitoring Service (CAMS), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3487, https://doi.org/10.5194/egusphere-egu2020-3487, 2020.

EGU2020-11807 | Displays | AS5.4

Improving global chemical weather forecast with modern online-coupled models for the U.S. Next Generation Global Prediction System (NGGPS)

Raffaele Montuoro, Georg Grell, Li Zhang, Stuart McKeen, Gregory Frost, Ravan Ahmadov, Judy Henderson, Jeff McQueen, Li Pan, Partha Bhattacharjee, Jack Kain, Barry Baker, Ivanka Stajner, Jun Wang, Cecelia DeLuca, Jon Pleim, and David Wong

Significant progress has been made within the last couple of years towards developing online coupled systems aimed at providing more accurate descriptions of atmospheric chemistry processes to improve performance of global aerosol and air quality forecasts. Operating within the U.S. National Weather Service (NWS) research-to-operation initiative to implement the fully-coupled Next Generation Global Prediction System (NGGPS), cooperative development efforts have delivered two integrated online global prediction systems for aerosols (GEFS-Aerosols) and air quality (FV3GFS-AQM). These systems include recent advances in aerosol convective transport and wet deposition processes introduced into the SAS scheme of the National Center for Environmental Prediction’s (NCEP) latest Global Forecast System (GFS) based on the Finite-Volume cubed-sphere dynamical core (FV3). GEFS-Aerosols is slated to become the new control member of the NWS Global Ensemble Forecast System (GEFS). The model features an online-coupled version of the Goddard Chemistry Aerosol Radiation and Transport (GOCART) model with a biomass-burning, plume-rise model and recent advances from NOAA Earth System Research Laboratory (ESRL), along with a state-of-the-art FENGSHA dust scheme from NOAA Air Resource Laboratory (ARL). FV3GFS-AQM incorporates a coupled, single-column adaptation of the U.S. Environmental Protection Agency’s (EPA) Community Multiscale Air Quality (CMAQ) model to improve NOAA’s current National Air Quality Forecast Capability (NAQFC). Both coupled systems’ design and development benefited from the use of the National Unified Operational Prediction Capability (NUOPC) Layer, which provided a common model architecture for interoperable, coupled model components within the framework of NOAA’s Environmental Modeling System (NEMS). Results from each of the described coupled systems will be discussed.

How to cite: Montuoro, R., Grell, G., Zhang, L., McKeen, S., Frost, G., Ahmadov, R., Henderson, J., McQueen, J., Pan, L., Bhattacharjee, P., Kain, J., Baker, B., Stajner, I., Wang, J., DeLuca, C., Pleim, J., and Wong, D.: Improving global chemical weather forecast with modern online-coupled models for the U.S. Next Generation Global Prediction System (NGGPS), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11807, https://doi.org/10.5194/egusphere-egu2020-11807, 2020.

EGU2020-6160 | Displays | AS5.4

MUSICA - Modeling for Chemistry, Weather and Climate

Gabriele Pfister, Andrew Conley, Mary Barth, Louisa Emmons, Forrest Lacey, and Rebecca Schwantes

Current chemical transport models inadequately account for the two-way coupling of atmospheric chemistry with other Earth System components over the range of urban/local to regional to global scales and from the surface up to the top of the atmosphere.  To meet future challenges, future modeling systems need to have the ability to (1) change spatial scales in a consistent manner, (2) resolve multiple spatial scales in a single simulation, (3) couple model components which represent different Earth system processes, and (4) easily mix-and-match model components. This is the motivation behind MUSICA - the Multi-Scale Infrastructure for Chemistry and Aerosols, which we develop together with the atmospheric chemistry community. MUSICA will allow simulation of large-scale atmospheric phenomena while still resolving chemistry at scales relevant for representing societal and scientific critical phenomena (e.g. urban air quality, or convection in monsoon regions) and also enable connections to other components of the earth system by fully coupling to land and ocean models. MUSICA objectives will be achieved through development of a global modeling system capable of regional refinement and the new Model Independent Chemistry Module (MICM). We will discuss the infrastructure and show preliminary results of atmospheric chemistry simulations being conducted in a global model with regional refinement: the Community Atmosphere Model with chemistry using spectral element grids that refine from one-degree resolution to ~14 km resolution over the conterminous United States. These early results confirm that model resolution does matter for representing regional air quality and that the two-way feedback between the local and global scale can play an important role.

How to cite: Pfister, G., Conley, A., Barth, M., Emmons, L., Lacey, F., and Schwantes, R.: MUSICA - Modeling for Chemistry, Weather and Climate, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6160, https://doi.org/10.5194/egusphere-egu2020-6160, 2020.

EGU2020-20982 | Displays | AS5.4

Canadian Air Quality Forecasting and Information Systems

Radenko Pavlovic, Jacinthe Racine, Marika Egyed, Serge Lamy, and Pierre Boucher

Canadian Air Quality Forecasting and Information Systems

Environment and Climate Change Canada (ECCC) has been in charge of the national air quality program for more than 20 years. As of today, air pollution remains one of the most important environmental risk factors to health, in addition to hazardous effects on climate change, ecosystems, properties, and food and water chain.

Currently, Canadian air quality forecasting and information systems with observational and modeling components are a key element for policy and mitigation measures, which are used to reduce the negative impacts of air pollution. The operational ECCC’s air quality program provides immediate adaptive measures based on early warning services. In addition to this operational service, the air quality scenario and policy modelling is essential for implementing cost-effective emission reduction strategies and local planning to ensure compliance with air quality standards.

Canadian air quality forecasting and information systems also enable access to air quality data at different temporal and spatial scales. This is done through coordination of national activities to facilitate seamless provision of atmospheric composition information at various scales. This work will present Canadian air quality forecasting and information systems, components, collaboration, application and data streaming, as an example that can be helpful in building the WMO GAFIS initiative.

How to cite: Pavlovic, R., Racine, J., Egyed, M., Lamy, S., and Boucher, P.: Canadian Air Quality Forecasting and Information Systems, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20982, https://doi.org/10.5194/egusphere-egu2020-20982, 2020.

EGU2020-4061 | Displays | AS5.4

Ex-hurricane Ophelia and air quality impacts over Europe in CAMS forecast systems

Dimitris Akritidis, Eleni Katragkou, Aristeidis K. Georgoulias, Prodromos Zanis, Stergios Kartsios, Johannes Flemming, Antje Inness, and Henk Eskes

Within the framework of the Copernicus Atmosphere Monitoring Service (CAMS) element CAMS-84 (Global and regional a posteriori evaluation and quality assurance), we analyze and evaluate the performance of CAMS forecast systems during the passage of ex-hurricane Ophelia in mid-October 2017, carrying Saharan dust and Iberian fire smoke over several Western European regions. To this end, day-1 forecasts from CAMS-global (ECMWF Integrated Forecast System; IFS) and CAMS-regional (ensemble of seven regional air quality models) products are compared against satellite retrievals (MODIS/Terra and Aqua, CALIPSO) and ground-based measurements. The analysis indicates that dust and smoke are injected into the warm sector of Ophelia, lying in the vicinity of the warm and cold front, respectively, gradually affecting the air quality and atmospheric composition over France, the Netherlands and Great Britain. The distinct pattern of enhanced aerosol optical depth (AOD) over Western coastal Europe seen in satellite retrievals is well reproduced by the CAMS near-real time forecast. The observed implications for air quality (PM10 and PM2.5) are satisfactorily forecasted in qualitative terms by both CAMS-global and CAMS-regional systems, while in quantitative terms, the CAMS-regional system exhibits a better performance in predicting surface PM concentrations (higher correlation and lower bias) compared to the global.

How to cite: Akritidis, D., Katragkou, E., Georgoulias, A. K., Zanis, P., Kartsios, S., Flemming, J., Inness, A., and Eskes, H.: Ex-hurricane Ophelia and air quality impacts over Europe in CAMS forecast systems , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4061, https://doi.org/10.5194/egusphere-egu2020-4061, 2020.

EGU2020-5165 | Displays | AS5.4

WRF-GC: online two-way coupling of WRF and GEOS-Chem for regional atmospheric chemistry modeling

Xu Feng, Haipeng Lin, and Tzung-May Fu

We developed the two-way version of the WRF-GC model, which is an online coupling of the Weather Research and Forecasting (WRF) mesoscale meteorological model and the GEOS-Chem chemical transport model, for regional air quality and atmospheric chemistry modeling. WRF-GC allows the two parent models to be updated independently, such that WRF-GC can stay state-of-the-science. The meteorological fields and chemical variables are transferred between the two models in the coupler to simulate the feedback of gases and aerosols to meteorological processes via interactions with radiation and cloud microphysics. We used the WRF-GC model to simulate surface PM2.5 concentrations over China during January 22 to 27, 2015 and compared the results to the outcomes from classic GEOS-Chem nested-grid simulations as well as the surface observations. For PM2.5 simulations, both models were able to reproduce the spatiotemporal variations, but the WRF-GC (r = 0.68, bias = 29%) performing better than GEOS-Chem (r = 0.72, bias = 55%) especially over Eastern China. For ozone simulations, we found that including aerosol-chemistry-cloud-radiation interactions reduced the mean bias of simulated surface ozone concentrations from 34% to 29% compared to observed afternoon ozone concentrations. WRF-GC is computationally efficient, with the physical and chemical variables managed in distributed memory. At similar resolutions, WRF-GC simulations were three times faster than the classic GEOS-Chem nested-grid simulations, due to the more efficient transport algorithm and the MPI-based parallelization provided by the WRF software framework. We envision WRF-GC to become a powerful tool for advancing science, serving the public, and informing policy-making.

How to cite: Feng, X., Lin, H., and Fu, T.-M.: WRF-GC: online two-way coupling of WRF and GEOS-Chem for regional atmospheric chemistry modeling, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5165, https://doi.org/10.5194/egusphere-egu2020-5165, 2020.

EGU2020-4019 | Displays | AS5.4

A NLS-4Dvar Assimilation System of Surface PM2.5 with WRF-CMAQ Model : Observing System Simulation Experiments

Shan Zhang, Xiangjun Tian, Hongqin Zhang, Xiao Han, and Meigen Zhang

        While complete atmospheric chemical transport models have been developed to understanding the complex interactions of atmospheric chemistry and physics, there are large uncertainties in numerical approaches. Data assimilation is an efficient method to improve model forecast of aerosols with optimized initial conditions. We have developed a new framework for assimilating surface fine particulate matter (PM2.5) observations in coupled Weather Research and Forecasting (WRF) model and Community Multiscale Air Quality (CMAQ) model, based on nonlinear least squares four-dimensional variational (NLS-4DVar) data assimilation method. The NLS-4DVar approach, which does not require the tangent and adjoint models, has been extensive used in meteorological and environmental areas due to the low computational complexity. Two parallel experiments were designed in the observing system simulation experiments (OSSEs) to evaluate the effectiveness of this system. Hourly PM2.5 observations over China be assimilated in WRF-CMAQ model with 6-h assimilation window, while the background state without data assimilation is conducted as control experiment. The results show that the assimilation significantly reduced the uncertainties of initial conditions (ICs) for WRF-CMAQ model and leads to better forecast. The newly developed PM2.5 data assimilation system can improve PM2.5 prediction effectively and easily. In the future, we expect emission to be optimized together with concentrations, and integrate meteorological assimilation into aerosol assimilation system.

How to cite: Zhang, S., Tian, X., Zhang, H., Han, X., and Zhang, M.: A NLS-4Dvar Assimilation System of Surface PM2.5 with WRF-CMAQ Model : Observing System Simulation Experiments, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4019, https://doi.org/10.5194/egusphere-egu2020-4019, 2020.

EGU2020-9449 | Displays | AS5.4

Data assimilation of FY-4A dust aerosol observations for the CUACE/dust forecasting system

Tao Niu, Xiaoye Zhang, Shanling Gong, Yaqiang Wang, Hongli Liu, and Chunhong Zhou

A data assimilation system (DAS) was developed for the Chinese Unified Atmospheric Chemistry Environment– Dust (CUACE/Dust) forecast system and applied in the operational forecasts of sand and dust storm (SDS) in spring in Asia. The system is based on a three dimensional variational method (3D-Var) and uses extensively the measurements of surface visibility (phenomena) and dust loading retrieval from the Chinese geostationary satellite FY-2C. By a number of case studies, the DAS was found to provide corrections to both under- and over-estimates of SDS, presenting a major improvement to the forecasting capability of CUACE/Dust in the short-term variability in the spatial distribution and intensity of dust concentrations in both source regions and downwind areas.  By now The DAS was upgrade to assimilate FY-4A dust aerosol observations. The seasonal mean Threat Score (TS) over the East Asia in spring increased when DAS was used. The forecast results with DAS usually agree with the dust loading retrieved from FY and visibility distribution from surface meteorological stations, which indicates that the 3D-Var method is very powerful by the unification of observation and numerical model to improve the performance of forecast model.

How to cite: Niu, T., Zhang, X., Gong, S., Wang, Y., Liu, H., and Zhou, C.: Data assimilation of FY-4A dust aerosol observations for the CUACE/dust forecasting system, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9449, https://doi.org/10.5194/egusphere-egu2020-9449, 2020.

EGU2020-11090 | Displays | AS5.4

Assimilation of Aerosol Observations in the NASA GEOS model

Virginie Buchard, Arlindo da Silva, Dan Holdaway, and Ricardo Todling

In the GEOS near real-time system, as well as in MERRA-2 which is the latest reanalysis produced at NASA’s Global Modeling Assimilation Office (GMAO), the assimilation of aerosol observations is performed by means of a so-called analysis splitting method. The prognostic model is based on the GEOS model radiatively coupled to GOCART aerosol module and includes assimilation of bias-corrected Aerosol Optical Depth (AOD) at 550 nm from various space-based remote sensing platforms.

Along with the progress made in the JCSDA-Joint Effort for Data Assimilation Integration (JEDI) framework, we have developed a prototype including GEOS aerosols as a component of the JEDI framework. Using members produced by the GEOS hybrid meteorological data assimilation system, we are updating the aerosol component of our assimilation system to a variational ensemble type of scheme. In this talk we will examine the impact of replacing the current analysis splitting scheme with this new approach. By including the assimilation of satellite-based single and multi-channel retrievals; we will discuss the impact of this aerosol data assimilation technique on the 3D aerosol distributions by means of innovation statistics and verification against independent datasets such as the Aerosol Robotic Network (AERONET) and surface PM2.5.

How to cite: Buchard, V., da Silva, A., Holdaway, D., and Todling, R.: Assimilation of Aerosol Observations in the NASA GEOS model, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11090, https://doi.org/10.5194/egusphere-egu2020-11090, 2020.

EGU2020-2804 | Displays | AS5.4

Improving air quality forecasting with the assimilation of GOCI AOD retrievals

Soyoung Ha and Zhiquan Liu

The Korean Geostationary Ocean Color Imager (GOCI) satellite has monitored the East Asian region in high temporal and spatial resolution every day for the last decade, providing unprecedented information on air pollutants over the upstream region of the Korean peninsula. In this study, the GOCI Aerosol optical depth (AOD), retrieved at 550 nm wavelength, is assimilated to ameliorate the analysis quality, thereby making systematic improvements on air quality forecasting in South Korea. For successful data assimilation, GOCI retrievals are carefully investigated and processed based on data characteristics. The preprocessed data are then assimilated in the three-dimensional variational data assimilation (3DVAR) technique for the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem). Over the Korea-United States Air Quality (KORUS-AQ) period (May 2016), the impact of GOCI AOD on the accuracy of air quality forecasting is examined by comparing with other observations including Moderate Resolution Imaging Spectroradiometer (MODIS) sensors and fine particulate matter (PM2.5) observations at the surface. Consistent with previous studies, the assimilation of surface PM2.5 concentrations alone systematically underestimates surface PM2.5 and its positive impact lasts mainly for about 6 h. When GOCI AOD retrievals are assimilated with surface PM2.5 observations, however, the negative bias is diminished and forecasts are improved up to 24 h, with the most significant contributions to the prediction of heavy pollution events over South Korea. The talk will be finished with an introduction of our ongoing efforts on developing the assimilation capability for more sophisticated aerosol schemes such as Model for Simulating Aerosol Interactions and Chemistry (MOSAIC) and the Modal Aerosol Dynamics Model for Europe (MADE)-Volatility basis set (VBS).

How to cite: Ha, S. and Liu, Z.: Improving air quality forecasting with the assimilation of GOCI AOD retrievals, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2804, https://doi.org/10.5194/egusphere-egu2020-2804, 2020.

EGU2020-12876 | Displays | AS5.4

Development of a high-resolution (400 m) operational air quality early warning system for Delhi, India through integrated chemical data assimilation

Sachin D Ghude, Chinmay Jena, Rajesh Kumar, Sreayshi Debnath, Vijay Soni, Ravi S Nanjundiah, and Madhavan Rajeevan

Managing air quality levels in the National Capital Region (NCR), especially Delhi, India has emerged as a complicated task. It is now a matter of top priority to develop meaningful policy options. Short-term air quality forecasts can provide timely information about forthcoming air pollution episodes that the decision-makers can use to implement temporary emission control measures and reduce public exposure to extreme air pollution events. Although India has developed air quality forecasting systems for NCR, it was challenging to predict acute air pollution episodes during which hourly PM2.5 concentrations exceed 300 µg/m3. In this perspective, a very high-resolution (400 m) operational air quality prediction system has been developed to predict extreme air pollution events in Delhi and issue timely warnings. This modeling framework consists of a high-resolution fully coupled state-of-the-science Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) and three-dimensional Variational (3DVAR) framework of the community Gridpoint Statistical Interpolation (GSI) system. The system assimilates satellite aerosol optical depth (AOD) retrievals at 10 km resolution, real-time crop residue burring at 1km resolution, surface PM2.5 data from 43 air quality monitoring stations, and uses high-resolution dynamical emissions (400 m) from various anthropogenic sources. The chemical data assimilation is further integrated with dynamical downscaling to obtain improved chemical conditions for the 400 m resolution domain. This paper summarizes the performance of the model forecasts for the winter season 2019-2020 and the evaluation of the model against the observations. Here, we demonstrate that the assimilation of chemical data in a coupled weather-air quality model improved the overall accuracy of PM2.5  forecasts in New Delhi by about 70 % during the winter season 2019-2020. Results show that the skill score for the poor (AQI 200-300), very-poor (AQI 300-400) and sever pollution (AQI 400-500) days is relatively promising for the hit rate with a value of 0.74 for (very-poor). This indicates that the model has reasonable predictive accuracy for air quality events. False Alarm rate (0.19), missing rate (0.32) are low, and the probability of detection is relatively high (0.67), indicating that the performance of the real-time forecast is better for both very poor events and no-very poor events.

How to cite: Ghude, S. D., Jena, C., Kumar, R., Debnath, S., Soni, V., Nanjundiah, R. S., and Rajeevan, M.: Development of a high-resolution (400 m) operational air quality early warning system for Delhi, India through integrated chemical data assimilation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12876, https://doi.org/10.5194/egusphere-egu2020-12876, 2020.

EGU2020-19221 | Displays | AS5.4

A full forecast system of air quality for the South East of the Iberian Peninsula.

Juan Pedro Montavez, Antonio Juarez-Martinez, Alejandro García-López, Amar Halifa-Marin, Enrique Pravia-Sarabia, and Pedro Jimenez-Guerrero

Air pollution forecasting can be used to alert about dangerous health effects caused by airborne pollutants and, in consequence, to take  actions to reduce pollutant concentrations (i.e reducing traffic, control industrial activities, etc..). Therefore, the development of reliable  air quality forecast systems is a of great interest.

The system consist of two main branchs. A statistical method based on  Neural Networks is used to forecast (10 days) several dayily air quality
index at the sites were historical data is available (i.e. pollution  measurement stations). A dynamical method based on WRF-CHEM to forecast hourly (48h) values of a large variety of species in a high resolution  domain (2km). Both subsystems use GFS and ECMWF forecasts as driving  conditions. The  dynamical subsystem incorporates 4DVAR data assimilation  of meteorological data (first 12 hours of forecast), and dynamical  emissions. The dynamical  emissions consist in changing the emissions of  large factories and trafficc. The emissions data are obtained by machine  learning methods based on historical series and meteorological conditions (mainly big energy factories). The WRF-CHEM configuration consist of several domains one way nested. The mother domain covers the entire Saharian desert in order to incorporante the dust transport contribution to particulate matter concentration. In addition, the base emission data is continuously updated.    The system also incorporates a module for automatic verification by comparing forecast with observed data, and analysis runs (in order to minimize meteorological forecast uncertainty). This verification process permit us to construct a MOS (Model Output statistics) in order to correct
possible model bias.

How to cite: Montavez, J. P., Juarez-Martinez, A., García-López, A., Halifa-Marin, A., Pravia-Sarabia, E., and Jimenez-Guerrero, P.: A full forecast system of air quality for the South East of the Iberian Peninsula., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19221, https://doi.org/10.5194/egusphere-egu2020-19221, 2020.

Air pollution is severely focused due to its distinct effect on climate change and adverse effect on human health, ecological system, etc. Eastern China is one of the most polluted areas in the world and many actions were taken to reduce air pollution. Numerical forecast of air quality was proved to be one of the effective ways to help to deal with air pollution. This abstract will present the advance, uncertainty and thinking about the future of the numerical air quality forecast emphasized in eastern China region. Brief history of numerical air quality modeling in Shanghai Meteorological Serveice (SMS) will be reviewed. The operational regional atmospheric environmental modeling system for eastern China (RAEMS) and its performance on forecasting the major air pollutants over eastern China region will be introduced. And uncertainty will be analyzed meanwhile challenges and actions to be done in the future are to be suggested for better service of numerical air quality forecast.

How to cite: Zhou, G.: Numerical Air Quality Forecast over East China: Advance, Uncertainty and Future, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1711, https://doi.org/10.5194/egusphere-egu2020-1711, 2020.

The biomass burning season in South America is mainly concentrated between July and October, period characterized by dry conditions associated with the decay phase of the South American monsoon system. The dry season in South America starts at the end of March and beginning of April when the maximum convection starts its shift to northward South America. The climatological dryness condition over central South America during July to October increases the occurrence of vegetation fires. The number of active fires detected by the AQUA satellite from 1998 to November 2019 in South America indicate fires abruptly increase from July to August, reaching a peak in September. Fires convert vegetation used as fuel into a series of combustion products that can remain in burned places or can be transported to other places by the atmospheric circulation. The 2019 dry season in South America was characterized by an abnormal high occurrence of intense and persistent fire episodes that injected tons of aerosols into the atmosphere. The present study aims to perform a comparative assessment of the four last South American biomass burning seasons. To compare the 2019 biomass burning season with 2016, 2017 and 2018 season, in this paper it is presented the fire active data compiled by the National Institute for Space Research (INPE) for the periods of analysis, the climatological aspects associated with each season and finally the validation of the operational integrated meteorology/air quality forecasting system Brazilian developments on the Regional Atmospheric Modeling System of the Center for Weather Forecasting and Climate Studies (CPTEC/INPE), for the considered periods.

How to cite: Frassoni, A.: The 2019 biomass burning season in South America: climate diagnostics, fire monitoring and air quality forecasting, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20086, https://doi.org/10.5194/egusphere-egu2020-20086, 2020.

AS5.9 – Lagrangian cloud microphysics: progress and prospects

EGU2020-1997 | Displays | AS5.9

Collection/Aggregation in a Lagrangian cloud microphysical model: Insights from column model applications

Simon Unterstrasser, Fabian Hoffmann, and Marion Lerch

Lagrangian cloud models (LCMs) are considered the future of cloud microphysical modeling. However, LCMs are computationally expensive due to the typically high number of simulation particles (SIPs) necessary to represent microphysical processes such as collection/aggregation successfully. In this study, the representation of collection/aggregation is explored in one-dimensional column simulations, allowing for the explicit consideration of sedimentation, complementing the authors' previous study on zero-dimensional collection in a single grid box. Two variants of the Lagrangian probabilistic all-or-nothing (AON) collection algorithm are tested that mainly differ in the assumed spatial distribution of the droplet ensemble: The first variant assumes the droplet ensemble to be well-mixed in a predefined three-dimensional grid box (WM3D), while the second variant considers explicitly the vertical coordinate of the SIPs, reducing the well-mixed assumption to a two-dimensional, horizontal plane (WM2D). Both variants are compared to established Eulerian bin model solutions. Generally, all methods approach the same solutions, and agree well if the methods are applied with sufficiently high accuracy (foremost the number of SIPs, timestep, vertical grid spacing). However, it is found that the rate of convergence depends on the applied model variant.  Most importantly, the study highlights that results generally require a smaller number of SIPs per grid box for convergence than previous box simulations indicated. The reason is the ability of sedimenting SIPs to interact with an effectively larger ensemble of particles when they are not restricted to a single grid box. Since sedimentation is considered in most commonly applied three-dimensional models, the results indicate smaller computational requirements for successful simulations than previously assumed, encouraging a wider use of LCMs in the future.

How to cite: Unterstrasser, S., Hoffmann, F., and Lerch, M.: Collection/Aggregation in a Lagrangian cloud microphysical model: Insights from column model applications, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1997, https://doi.org/10.5194/egusphere-egu2020-1997, 2020.

EGU2020-2097 | Displays | AS5.9

Predicting the morphology of ice particles in deep convection using the super-droplet method

Shin-ichiro Shima, Yousuke Sato, Akihiro Hashimoto, and Ryohei Misumi

In this presentation, we summarize the main results of Shima et al. (2019). The super-droplet method (SDM) is a particle-based numerical algorithm that enables accurate cloud microphysics simulation with lower computational demand than multi-dimensional bin schemes. Using SDM, we developed a detailed numerical model of mixed-phase clouds in which ice morphologies are explicitly predicted without assuming ice categories or mass-dimension relationships. Ice particles are approximated as porous spheroids. The elementary cloud microphysics processes considered are advection and sedimentation; immersion/condensation and homogeneous freezing; melting; condensation and evaporation including cloud condensation nuclei activation and deactivation; deposition and sublimation; collision-coalescence, -riming, and -aggregation. To evaluate the model's performance, we conducted a 2D large-eddy simulation of a cumulonimbus. The results well capture characteristics of a real cumulonimbus. The mass-dimension and velocity-dimension relationships the model predicted show a reasonable agreement with existing formulas. Numerical convergence is achieved at a super-particle number concentration as low as 128/cell, which consumes 30 times more computational time than a two-moment bulk model. Although the model still has room for improvement, these results strongly support the efficacy of the particle-based modeling methodology to simulate mixed-phase clouds. 

Shima, S., Sato, Y., Hashimoto, A., and Misumi, R.: Predicting the morphology of ice particles in deep convection using the super-droplet method: development and evaluation of SCALE-SDM 0.2.5-2.2.0/2.2.1, Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2019-294, 1-83, 2019.

How to cite: Shima, S., Sato, Y., Hashimoto, A., and Misumi, R.: Predicting the morphology of ice particles in deep convection using the super-droplet method, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2097, https://doi.org/10.5194/egusphere-egu2020-2097, 2020.

The Lagrangian Cirrus Module (LCM) is a Lagrangian (also known as particle-based) ice microphysics code that is fully coupled to the large-eddy simulation (LES) code EULAG. The ice phase is described by a large number of simulation particles (order 106 to109) which act as surrogates for the real ice crystals. The simulation particles (SIPs) are advected and microphysical processes like deposition/sublimation and sedimentation are solved for each individual SIP. More specifically, LCM treats ice nucleation, crystal growth, sedimentation, aggregation, latent heat release, radiative impact on crystal growth, and turbulent dispersion. The aerosol module comprises an explicit representation of size-resolved non-equilibrium aerosol microphysical processes for supercooled solution droplets and insoluble ice nuclei.

First, an general introduction to particle-based microphysics coupled to a grid-based (Eulerian) LES model is given.
In the following, emphasis is put on highlighting the benefits of the Lagrangian approach by presenting a variety of simulation examples.

How to cite: Unterstrasser, S.: The Lagrangian ice microphysics code LCM: Introduction, current developments and benefits, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2307, https://doi.org/10.5194/egusphere-egu2020-2307, 2020.

This paper discusses a comparison of simulations applying either a traditional Eulerian bin microphysics or a novel particle-based Lagrangian approach to represent CCN activation and cloud droplet growth. The Eulerian microphysics solve the evolution equation for the spectral density function, whereas the Lagrangian approach follows computational particles referred to as super-droplets. Each super-droplet represents a multiplicity of natural droplets that makes the Lagrangian approach computationally feasible. The two schemes apply identical representation of CCN activation and use the same droplet growth equation; these make direct comparison between the two schemes practical. The comparison, the first of its kind, applies an idealized simulation setup motivated by laboratory experiments with the Pi Chamber and previous model simulations of the Pi Chamber dynamics and microphysics. The Pi Chamber laboratory apparatus considers interactions between turbulence, CCN activation, and cloud droplet growth in moist Rayleigh-Bénard convection. Simulated steady-state droplet spectra averaged over the entire chamber are similar, with the mean droplet concentration, mean radius, and spectral width close in Eulerian and Lagrangian simulations. Small differences that do exist are explained by the inherent differences between the two schemes and their numerical implementation. The local droplet spectra differ substantially, again in agreement with the inherent limitations of the theoretical foundation behind each approach. There is a general agreement between simulations and Pi Chamber observations, with simplifications of the CCN activation and droplet growth equation used in the simulations likely explaining specific differences.

How to cite: Grabowski, W. W.: Comparison of Eulerian bin and Lagrangian particle-based schemes in simulations of Pi Chamber dynamics and microphysics, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2472, https://doi.org/10.5194/egusphere-egu2020-2472, 2020.

EGU2020-3940 | Displays | AS5.9

PySDM: Pythonic particle-based cloud microphysics package

Piotr Bartman, Michael Olesik, Sylwester Arabas, and Shin-ichiro Shima

In the poster, we will present a new open-source cloud microphysics simulation package PySDM (https://github.com/atmos-cloud-sim-uj/PySDM). The package core is a Pythonic implementation of the Super-Droplet Method (SDM) Monte-Carlo algorithm for representing aerosol/cloud/rain collisional growth.

PySDM design features separation of a backend layer responsible for number-crunching tasks. The developed backend implementations based on Numba, Pythran and ThrustRTC leverage three different Python acceleration techniques dubbed just-in-time, ahead-of-time and runtime compilation, respectively. As a result, PySDM offers high performance with little trade-offs with respect to such advantages of the Python language as succinct and readable source code and portability (seamless interoperability between Windows, OSX and Linux). We will exemplify further advantages that result from embracement of the Jupyter platform which allowed us to equip PySDM with interactive examples and tutorials swiftly executable via web browser through cloud-computing platforms.

Example simulations of the warm-rain process in a kinematic two-dimensional framework mimicking stratoculumus deck will be presented and used as a basis for scalability analysis and discussion of parallelisation nuances of the SDM algorithm.

How to cite: Bartman, P., Olesik, M., Arabas, S., and Shima, S.: PySDM: Pythonic particle-based cloud microphysics package, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3940, https://doi.org/10.5194/egusphere-egu2020-3940, 2020.

While the use of Lagrangian cloud microphysical models dates back as far as the 1950s, the integration of this framework into fully-coupled, three-dimensional dynamical models is only possible for about 10 years. In addition to the highly accurate and detailed representation of cloud microphysical processes, these so-called Lagrangian Cloud Models (LCMs) also allow for new ways of representing subgrid-scale dynamical processes and their effects on the microphysical development of clouds, typically neglected or only crudely parameterized due to computational constraints.

In this talk, I will present a new approach in which supersaturation fluctuations on the subgrid-scale of a large-eddy simulation (LES) model are represented by an economical, one-dimensional model that represents turbulent compression and folding. With a resolution comparable to direct numerical simulation (DNS), inhomogeneous and finite rate mixing processes are explicitly resolved. Applications of this modeling approach for warm-phase shallow cumuli and stratocumuli, and first applications for mixed-phase clouds will be discussed. Generally, clouds susceptible to inhomogeneous mixing show a reduction in the droplet number concentration and stronger droplet growth, in agreement with theory. Stratocumulus entrainment rates tend to be lower using the new approach compared to simulations without it, indicating a more appropriate representation of the entrainment-mixing process. Finally, the Wegner-Bergeron-Findeisen-Process, leading to a rapid ice formation in mixed-phase clouds, is decelerated.

All in all, this new modeling framework is capable of bridging the gap between LES and DNS, i.e., it enables representing all scales relevant to cloud physics, from entire cloud fields to the smallest turbulent fluctuations, in a single model, allowing to study their interactions explicitly and granting new insights.

How to cite: Hoffmann, F.: Beyond Cloud Microphysics: Representing Subgrid-Scale Processes in Lagrangian Cloud Models, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4245, https://doi.org/10.5194/egusphere-egu2020-4245, 2020.

EGU2020-5016 | Displays | AS5.9

On the droplet spectral broadening numerics

Michael Olesik, Piotr Bartman, Sylwester Arabas, Gustavo Abade, Manuel Baumgartner, and Simon Unterstrasser

Owing to its key role in determining both the droplet collision probabilities and the radiative-transfer-relevant spectrum characteristics, the evolution of droplet spectral width has long been the focus of cloud modelling studies. Cloud simulations with detailed treatment of droplet microphysics face a twofold challenge in prognosing the droplet spectrum width. First, it is challenging to model and numerically represent the subtleties of condensational growth, even more so when considering the interplay between particle population dynamics and supersaturation fluctuations. Second, the discretisation strategies employed in representing the particle size spectrum and its evolution are characterised by inherent limitations. 

In the poster, we will present results of both Eulerian and Lagrangian numerical representations of spectrum width evolution. In the case of Lagrangian approach, we will discuss the differences in numerical integration procedures between (a) the sophisticated solvers typically used in parcel-model frameworks with moving-sectional spectrum representation and (b) the simpler solvers typically used in mathematically-analogous particle-based (super-droplet) microphysics representations used in multi-dimensional models.

In the case of Eulerian (bin microphysics) approach, we will present condensational growth simulations performed with the MPDATA numerical scheme using the newly developed MPyDATA package (http://github.com/atmos-cloud-sim-uj/MPyDATA/). The MPDATA family of numerical schemes for solving advective transport problems has been in continuous development for almost four decades. MPDATA features a variety of options allowing to pick an algorithm variant appropriate to the problem at hand. We will focus on the importance the MPDATA algorithm variant choice and the grid setup for the resultant numerical diffusion.

In the case of Lagrangian approach, we will present simulations performed using the newly developed PySDM package (https://github.com/atmos-cloud-sim-uj/PySDM) that features a set of cloud microphysics algorithms including condensational growth solvers. In the discussion, we will focus on: (a) the numerical realisability of the Ostwald ripening process (i.e. the growth of larger particles at the expense of water content of the smaller ones) and (b) the numerical approaches available for integrating stochastic fluctuations of ambient thermodynamic properties that drive the water vapour saturation.

How to cite: Olesik, M., Bartman, P., Arabas, S., Abade, G., Baumgartner, M., and Unterstrasser, S.: On the droplet spectral broadening numerics, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5016, https://doi.org/10.5194/egusphere-egu2020-5016, 2020.

EGU2020-17034 | Displays | AS5.9

Can Large Precipitating Cloud Hydrometeors Generate Secondary Cloud Droplets in its Wake?

Taraprasad Bhowmick, Yong Wang, Gholamhossein Bagheri, and Eberhard Bodenschatz

Atmospheric clouds play a very important role in the evolution of global atmosphere and climate through various interactive physical processes dynamically active over a huge range of scales [Devenish et al. QJRMS 2012, Grabowski and Wang. ARFM 2013]. However, many of such processed are yet to be understood; and in such context, we attempt to understand such a scientific question: whether large precipitating cloud drops can generate secondary droplets in it’s wake. Motivated by experimental investigation of large sedimenting cloud droplets [∼ mm radius] which showed presence of secondary cloud droplets in it’s wake [Prabhakaran et al. PRL 2017, ArXiv 2019]; we conduct direct numerical simulations of such precipitating hydrometeors using Lattice-Boltzmann method (LBM) to simulate cloud like ambient solving the evolution of the supersaturation field in the wake of the hydrometeor, and to investigate it’s impact on the nucleation of cloud aerosols. In our simulation results, we found various flow regimes based on the Reynolds number (Re = Droplet Diameter * Droplet Velocity / Kinematic Viscosity) in compliance with past researches. Steady axisymmetric wake for Re up to ∼ 220, after that steady oblique wake up to Re ∼ 280, then a transient oscillating nature of the wake up to Re ∼ 350, and beyond that Re, the wake is observed to become chaotic and turbulent. Comparison of drag coefficient, recirculation length and separation angles for fluid velocity at various Re shows good agreement with existing numerical and experimental simulations. The temperature profiles also fit well with other researches for similar Prandtl number (ratio of kinematic viscosity to thermal diffusivity). Evolution of the density of water vapor is similar to the temperature field, since both the equations show similar structure and the mass diffusivity of water vapor is almost same to the thermal diffusivity for atmospheric clouds. Distribution of the supersaturation field is computed using Clausius-Clapeyron Equation which gives saturation vapor pressure depending on temperature. In such simulations with background flow at -15o C temperature with 60% relative humidity (RH) and with the hydrometeor as a warm cloud droplet at 4o C temperature and 100% RH at it’s surface, the wake shows symmetric regions of supersaturation in the near vicinity of the hydrometeor at Re = 200. Whereas, at Re = 273, the wake is observed to become oblique, so the supersaturated region. Small pockets of supersaturated warm air parcels are observed to travel in the downstream direction when the hydrometeor started shedding vortices at higher Re. However, while traveling downstream, such supersaturated pockets also lost its’ excess of water vapor depending on the ambient cloud conditions. Due to higher supersaturation at the near vicinity of the warm hydrometeor, the cloud aerosols trapped inside the wake can be activated. However, whether such activated aerosols can become a drizzle drop, or may evaporate its liquid water content in subsaturated region, is to be understood by Lagrangian tracking of such aerosol tracers.

How to cite: Bhowmick, T., Wang, Y., Bagheri, G., and Bodenschatz, E.: Can Large Precipitating Cloud Hydrometeors Generate Secondary Cloud Droplets in its Wake?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17034, https://doi.org/10.5194/egusphere-egu2020-17034, 2020.

EGU2020-18460 | Displays | AS5.9

Giant aerosols increase precipitation in marine cumulus and stratocumulus clouds

Piotr Dziekan, Jorgen Jensen, Wojciech Grabowski, and Hanna Pawłowska

Sea-salt aerosols with radii exceeding 1 μm have been observed over the oceans. Cloud droplets formed on these giant aerosols can quickly grow to drizzle sizes through condensation of water vapor. Therefore giant aerosols, although not numerous, have been speculated to increase the amount of precipitation produced in clouds. Testing this hypothesis in LES simulations has been difficult, because Eulerian microphysics models are not well suited to model growth of droplets on giant aerosols. On the contrary, Lagrangian microphysics models, which are an emerging alternative to the Eulerian bin microphysics models, can model giant aerosols in a straightforward manner.

LES simulations performed using the University of Warsaw Lagrangian Cloud Model (UWLCM) will be presented. In UWLCM, the Lagrangian super-droplet microphysics model is used. We will assess how giant aerosols affect precipitation formation in marine cumulus (setup based on the RICO campaign) and stratocumulus clouds (setup based on the research flight 2 of the DYCOMS campaign). It will be discussed how the impact of giant aerosols changes with the concentrations of giant and regular aerosols. The results are of importance also for cloud seeding experiments, in which giant sea-salt aerosols can be released into a cloud.

How to cite: Dziekan, P., Jensen, J., Grabowski, W., and Pawłowska, H.: Giant aerosols increase precipitation in marine cumulus and stratocumulus clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18460, https://doi.org/10.5194/egusphere-egu2020-18460, 2020.

EGU2020-18503 | Displays | AS5.9

Fractal reconstruction of the subgrid scales in turbulence models in applications to cloud microphysics

Emmanuel Akinlabi, Marta Waclawczyk, and Szymon Malinowski

Modelling of small-scale turbulence in the atmosphere play a significant role in improving our understanding of cloud processes, thereby contributing to the development of better parameterization of climate models. One of the important problems is related to the transport of cloud particles, their activation and growth, which are influenced by small-scale turbulence motions. The idea presented in this work is to use fractal interpolation to reconstruct structures which are typically not resolved in the Large Eddy Simulations (LES) of clouds. Known filtered values of velocities on LES are basis of the reconstruction. The reconstructed small scales depend on the stretching parameter d, which is related to the fractal dimension of the signal. In many previous studies, the stretching parameter values were assumed to be constant in space and time. We modify this approach by treating the stretching parameter as a random variable with a prescribed probability density function (pdf). This function can be determined from a priori analysis of numerical or experimental data and within a certain range of wavenumbers it has a universal form, independent of the Reynolds number. We show, such modification leads to improvement in terms of reconstruction of two-point statistics of turbulent velocities. Preliminary results of simulations with Lagrangian particles (superdroplets) in the reconstructed field show the fractal model properly mimics the turbulent mixing processes at subgrid scales.

How to cite: Akinlabi, E., Waclawczyk, M., and Malinowski, S.: Fractal reconstruction of the subgrid scales in turbulence models in applications to cloud microphysics, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18503, https://doi.org/10.5194/egusphere-egu2020-18503, 2020.

EGU2020-20398 | Displays | AS5.9

Lagrangian stochastic microphysics at unresolved scales in turbulent cloud simulations

Gustavo Abade, Marta Waclawczyk, Wojciech W. Grabowski, and Hanna Pawlowska

Turbulent clouds are challenging to model and simulate due to uncertainties in microphysical processes occurring at unresolved subgrid scales (SGS). These processes include the transport of cloud particles, supersaturation fluctuations, turbulent mixing, and the resulting stochastic droplet activation and growth by condensation. In this work, we apply two different Lagrangian stochastic schemes to model SGS cloud microphysics. Collision and coalescence of droplets are not considered. Cloud droplets and unactivated cloud condensation nuclei (CCN) are described by Lagrangian particles (superdroplets). The first microphysical scheme directly models the supersaturation fluctuations experienced by each Lagrangian superdroplet as it moves with the air flow. Supersaturation fluctuations are driven by turbulent fluctuations of the droplet vertical velocity through the adiabatic cooling/warming effect. The second, more elaborate scheme uses both temperature and vapor mixing ratio as stochastic attributes attached to each superdroplet. It is based on the probability density function formalism that provides a consistent Eulerian-Lagrangian formulation of scalar transport in a turbulent flow. Both stochastic microphysical schemes are tested in a synthetic turbulent-like cloud flow that mimics a stratocumulus topped boundary layer. It is shown that SGS turbulence plays a key role in broadening the droplet-size distribution towards larger sizes. Also, the feedback on water vapor of stochastically activated droplets buffers the variations of the mean supersaturation driven the resolved transport. This extends the distance over which entrained CNN are activated inside the cloud layer and produces multimodal droplet-size distributions.

How to cite: Abade, G., Waclawczyk, M., Grabowski, W. W., and Pawlowska, H.: Lagrangian stochastic microphysics at unresolved scales in turbulent cloud simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20398, https://doi.org/10.5194/egusphere-egu2020-20398, 2020.

EGU2020-22539 | Displays | AS5.9

Impact of turbulence on cloud microphysics of water droplets population

Mina Golshan, Mattia Tomatis, Shahbozbek Abdunabiev, Federico Fraternale, Marco Vanni, and Daniela Tordella

This work focuses on the turbulent shearless mixing structure of a cloud/clear air interface with physical parameters typical of cumulus warm clouds. We investigate the effect of turbulence on the droplet size distribution, in particular, we focus on the distribution's broadening and on the collision kernel. We performed numerical experiments via Direct Numerical Simulations(DNS) of turbulent interfaces subject to density stratification and vapor density  fluctuation. Specifically, an initial supersaturation around 2 % and a dissipation rate of turbulent kinetic energy of 100 cm2/s3 are set in the DNSs. Taylor's Reynolds number is between 150 and 300. The total number of particles is around 5-10 millions, matching an initial liquid water content of 0.8 g/m3. Through these experiments, we provide a measure of the collision kernel and compare it with literature models [Saffman & Turner,1955], which is then included in a drops Population Balance Equation model (PBE). The PBE includes both processes of drops growth by condensation/evaporation and aggregation.

How to cite: Golshan, M., Tomatis, M., Abdunabiev, S., Fraternale, F., Vanni, M., and Tordella, D.: Impact of turbulence on cloud microphysics of water droplets population, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22539, https://doi.org/10.5194/egusphere-egu2020-22539, 2020.

AS5.11 – Atmospheric gases and particles: metrology, quality control and measurement comparability

EGU2020-8518 | Displays | AS5.11

Comparison of isotope ratio measurement capabilities for CO2: Sample preparation and characterization by Isotope Ratio Infrared Spectroscopy

Edgar Flores, Philippe Moussay, Eric Mussell Webber, Ian Chubchenko, Francesca Rolle, Tiqiang Zhang, and Robert Ian Wielgosz

This paper will describe the characteristics and performance of a system to prepare up to ten 50 mL samples of pure CO2 with on-demand 13C/12C ratios, together with an optimized calibration system for measurements by Isotope Ratio Infrared Spectroscopy (IRIS) that has allowed measurement of δ13C and δ18O values with 0.02 ‰ reproducibility (1 σ).

The needs for improved quality infrastructure and appropriate reference gases for CO2 isotope ratio measurements has been a driver for recent research and development activities within the National Metrology Institutes, and the decision of the Gas Analysis Working Group of the CCQM to plan an international comparison (CCQM-P204) of capabilities of measurements of these quantities. The comparison will be coordinated by the BIPM, which has the mission of preparing the comparison samples, and the IAEA, who will assign their isotopic composition on reference scales. The BIPM has developed a preparation facility based on blending of different pure CO2 sources of very different isotopic compositions, followed by cryogenic trapping and transfer to ten 50 mL cylinders. The target isotopic ratio 13C/12C can be adjusted by accurate flow measurements.

A Carousel sampling system with bracketing reference gas calibration and dilution system has been designed at the BIPM to allow rapid and accurate analysis of prepared gas mixtures by IRIS. A key feature of the calibration system is to maintain identical treatment of sample and reference gases allowing two-point calibration of up to 14 samples, and appropriate flushing protocols to remove any biases from memory effects of previously sampled gases. Measurements are performed by the IRIS analyzer at a mole fraction of nominally 700 μmol/mol CO2 in air, by dilution of pure CO2 gas controlled by individual low-flow mass flow controllers (0.07 ml/min), and with a feedback loop to control mole fractions to ensure that differences between references and sample gas mole faction stay below 2 μmol/mol. This level of control is necessary to prevent biases in measured isotope ratios, the magnitude of which has also been studied with a sensitivity study that is also reported.

The Carousel and IRIS measurements have been validated using pure CO2 samples prepared with the gas blending facility, covering a range in delta values of -1 ‰ to -45 ‰ vs VPDB, and in all cases measurement reproducibility over several days of testing of 0.02‰ or better (1 σ) were achieved for both δ13C and δ18O, with negligible memory effects.

Samples produced and characterized with the facility will be distributed to institutes participting in the CCQM-P204 comparison exrecise, with measurements foreseen in the first quarter of 2020.

How to cite: Flores, E., Moussay, P., Mussell Webber, E., Chubchenko, I., Rolle, F., Zhang, T., and Wielgosz, R. I.: Comparison of isotope ratio measurement capabilities for CO2: Sample preparation and characterization by Isotope Ratio Infrared Spectroscopy , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8518, https://doi.org/10.5194/egusphere-egu2020-8518, 2020.

EGU2020-3539 | Displays | AS5.11

Improving inter-laboratory compatibility of atmospheric carbon dioxide and methane isotope measurements.

Heiko Moossen, Sylvia Englund Michel, Peter Sperlich, Michael Rothe, and Willi A. Brand

 

Around the world laboratories that are part of the Global Atmospheric Watch (GAW) community conduct atmospheric trace gas measurements under the auspices of the World Meteorological Organisation (WMO). The GAW-WMO defines the inter-laboratory compatibility goals for these measurements, that is the maximum tolerable bias these measurements may have in order to still be useful for modelling and flux studies. The GAW-WMO network compatibility goals for δ13C- and δ18O-CO2(atm) measurements are 0.01 ‰ and 0.05 ‰ respectively, and for δ13C- and δ2H-CH4(atm) measurements they are 0.02 ‰ and 1 ‰, respectively. It has to be noted that these goals are very ambitious and at the precision limit of current analytical techniques. Nevertheless, in particular the isotopic measurements of atmospheric methane have suffered from considerable inter-laboratory biases of up to 0.5 ‰ and 13 ‰ for δ13C- and δ2H-CH4(atm) measurements in the past (Umezawa et al., 2018).

These inter-laboratory measurement biases have been, and still are in part due to the different standardisation strategies that are used in different laboratories. In order to tackle this problem the stable isotope laboratory at the Max-Planck-Institute for Biogeochemistry (BGC-IsoLab) developed the Jena Reference Air Scale (JRAS-06) that has been in use since 2006. JRAS-06 is the scale realisation of the VPDB-CO2 scale, and its use is recommended by the GAW-WMO community to standardise δ13C- and δ18O-CO2(atm) measurements. The JRAS-06 scale is based on CO2 in air standards where the CO2 is evolved from standard calcium carbonates (e.g. NBS 19). Using an example dataset of δ13C- and δ18O-CO2(atm) measurements we show the improved inter-laboratory compatibility that results from using the JRAS-06 standards and scale at two laboratories, the stable isotope laboratory at the Institute of Arctic and Alpine Research (INSTAAR) and BGC-IsoLab.

The BGC-IsoLab is now collaborating with the National Institute of Water and Atmospheric Research (NIWA) in New Zealand in order to develop standards and a unifying scale for δ13C- and δ2H-CH4(atm) measurements analogous to the JRAS-06 scale realisation. Here we show the first results of this collaborative effort towards a JRAS-M(ethane) scale that aims to improve the inter-laboratory compatibility and closely link δ13C- and δ2H-CH4(atm) measurements to the international VPDB-CO2 and VSMOW scales, respectively.

How to cite: Moossen, H., Englund Michel, S., Sperlich, P., Rothe, M., and Brand, W. A.: Improving inter-laboratory compatibility of atmospheric carbon dioxide and methane isotope measurements., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3539, https://doi.org/10.5194/egusphere-egu2020-3539, 2020.

EGU2020-18389 | Displays | AS5.11 | Highlight

Progress towards atmospheric isotope ratio carbon dioxide and nitrous oxide reference materials that meet the WMO-GAW data quality objectives for compatibility

Ruth Hill-Pearce, Eric Mussell Webber, Aimee Hillier, Heiko Moossen, David Worton, and Paul Brewer

Widely available reference materials that are traceable and consistent with international stable isotope scales are necessary in order to create a robust and sustainable global measurement infrastructure for isotope ratio of CO2 and N2O.

We report on progress towards the production and certification of atmospheric amount fraction greenhouse gas reference materials with isotope ratios spanning the full atmospheric range. Reference materials are produced with a chosen delta value with uncertainties aiming to achieve the WMO GAW data quality objectives for extended compatibility of delta value of of ∂13C-CO2 and ∂18O-CO2 of 0.1‰ (northern hemisphere) and amount fraction of 0.2 µmolmol-1 for CO2 and 0.3 nmolmol-1 for N2O at atmospheric amount fraction ranges.

To illustrate the work towards these challenging goals we present studies of sampling technique and isotope ratio stability with storage, pressure and cylinder passivation. The precision of blending and dilution of source gases is presented alongside studies of measurement instrument precision and drift. Contributing factors from matrix gases are also discussed. 

How to cite: Hill-Pearce, R., Mussell Webber, E., Hillier, A., Moossen, H., Worton, D., and Brewer, P.: Progress towards atmospheric isotope ratio carbon dioxide and nitrous oxide reference materials that meet the WMO-GAW data quality objectives for compatibility , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18389, https://doi.org/10.5194/egusphere-egu2020-18389, 2020.

EGU2020-18624 | Displays | AS5.11

N2O isotope research: development of reference materials and metrological characterization of OIRS analyzers within the SIRS project

Joachim Mohn, Joanna Rupacher, Heiko Moossen, Sakae Toyoda, Christina Biasi, Jan Kaiser, Stephen Harris, Jesper Liisberg, Benjamin Wolf, Longlong Xia, Matti Barthel, Longfei Yu, Kristýna Kantnerová, Jing Wei, Ruth Pearce, Eric Mussell Webber, Bryce Kelly, Thomas Blunier, Naohiro Yoshida, and Paul Brewer and the Additional co-authors

Measurements of the four most abundant stable isotopocules of N2O (14N14N16O, 15N14N16O, 14N15N16O, and 14N14N18O) can provide a valuable constraint on source attribution of atmospheric N2O. N2O isotopocules at natural abundance levels can be analyzed by isotope-ratio mass-spectrometry (IRMS) [1] and more recently optical isotope ratio spectroscopy (OIRS) [2]. OIRS instruments can analyze the N2O isotopic composition in gaseous mixtures in a continuous-flow mode, providing real-time data with minimal or no sample pretreatment, which is highly attractive to better resolve the temporal complexity of N2O production and consumption processes. Most importantly, OIRS laser spectroscopy is selective for position-specific 15N substitution due to the existence of characteristic rotational-vibrational spectra.

By allowing both in-situ application and measurements in high temporal resolution, laser spectroscopy has established a new quality of data for research on N2O in particular and N cycling in general. However, applications remain challenging and are still scarce as a metrological characterization of OIRS analyzers, reporting factors limiting their performance is still missing. In addition, only since recently two pure N2O isotopocule reference materials have been made available through the United States Geological Survey (USGS), which however, only offer a small range of δ15N and δ18O values (< 1 ‰) and are therefore not suited for a two-point calibration approach [3].

This presentation will highlight the recent progress achieved within the framework of the EMPIR project “Metrology for Stable Isotope Reference Standards (SIRS)”, namely:

  • (1) The development of pure and diluted N2O reference materials (RMs), covering the range of isotope values required by the scientific community. These gaseous standards are available as pure N2O or N2O diluted in whole air. N2O RMs were analyzed by an international group of laboratories for δ15N, δ18O (MPI-BGC, Tokyo Institute of Technology, UEA), δ15Nα, δ15Nß (Empa, Tokyo Institute of Technology) and δ17O (UEA) traceable to the existing isotope ratio scales.
  • (2) The metrological characterization of the three most common commercial N2O isotope OIRS analyzers (with/without precon QCLAS, OA-ICOS and CRDS) for gas matrix effects, spectral interferences of enhanced trace gas concentrations (CO2, CH4, CO, H2O), short-term and long-term repeatability, drift and dependence of isotope deltas on N2O concentrations [4].

In summary, the authors suggest to include appropriate RMs following the identical treatment (IT) principle during every OIRS measurement to retrieve compatible and accurate results. Remaining differences between sample and reference gas composition have to be corrected, by applying analyzer-specific correction algorithms.

 

[1] Toyoda, S. and N. Yoshida (1999). "Determination of nitrogen isotopomers of nitrous oxide on a modified isotope ratio mass spectrometer." Anal. Chem. 71(20): 4711-4718.

[2] Brewer, P. J. et al. (2019). "Advances in reference materials and measurement techniques for greenhouse gas atmospheric observations." Metrologia 56(3).

[3] Ostrom, N. E. et al. (2018). "Preliminary assessment of stable nitrogen and oxygen isotopic composition of USGS51 and USGS52 nitrous oxide reference gases and perspectives on calibration needs." Rapid Commun. Mass Spectrom. 32(15): 1207-1214.

[4] Harris, S. J., J. Liisberg et al. (2019). "N2O isotopocule measurements using laser spectroscopy: analyzer characterization and intercomparison." Atmos. Meas. Tech. Discuss. (in review).

 

How to cite: Mohn, J., Rupacher, J., Moossen, H., Toyoda, S., Biasi, C., Kaiser, J., Harris, S., Liisberg, J., Wolf, B., Xia, L., Barthel, M., Yu, L., Kantnerová, K., Wei, J., Pearce, R., Webber, E. M., Kelly, B., Blunier, T., Yoshida, N., and Brewer, P. and the Additional co-authors: N2O isotope research: development of reference materials and metrological characterization of OIRS analyzers within the SIRS project, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18624, https://doi.org/10.5194/egusphere-egu2020-18624, 2020.

EGU2020-6069 | Displays | AS5.11 | Highlight

Intercomparison of nitrogen monoxide and nitrogen dioxide measurements in the atmosphere simulation chamber SAPHIR during the MetNO2 campaign

Robert Wegener and the The MetNO2 SAPHIR intercomparison team

Nitrogen dioxide (NO2) and nitrogen monoxide (NO) govern the photochemical processes in the troposphere. Although nitrogen oxides have been measured for decades, their quantification remains challenging. The MetNO2 (Metrology for Nitrogen Dioxide) project of the European Metrology Programme for Innovation and Research (EMPIR) aims to improve the accuracy of NO2 measurements.

In total 15 instruments were intercompared at the World Calibration Centre for nitrogen oxides (WCC-NOx) in Jülich in autumn 2019 within the project. In addition to chemiluminescence detectors (CLD), the instruments encompassed Quantum Cascade Laser Absorption Spectrometers (QCLAS), Iterative CAvity-enhanced Differential optical absorption spectrometers (ICAD) and Cavity Attenuated Phase Shift (CAPS) spectrometers.

During the campaign, air from a gas phase titration unit, air from the environmental chamber SAPHIR or outside air was provided to the instruments via a common inlet line. The participants calibrated their instruments prior and after the campaign with their own calibration procedures. During the campaign, the common inlet line was used for daily calibration to compare standards, calibration techniques and sensitivity drifts of the instruments. NO2 for calibration was provided either by gas phase titration from NO, from permeation tubes or from gas mixtures produced within the MetNO2 project.

It was observed that measurements by chemiluminescence or CAPS instruments are prone to interferences from humidity and ozone. However, in most cases data can be corrected. Alkyl nitrates and reactive alkenes were also observed to cause interferences in some instruments, while isobutyl nitrite was found to be photolyzed by photolytic converters.

Finally, measurements in ambient air were compared. The nitrogen oxide observations were accompanied with measurements of hydroxyl radical (OH) reactivity and reactive nitrogen species as nitrous acid (HONO), dinitrogen pentoxide (N2O5), and chloryl nitrate (ClNO2). Detailed results of the intercomparison will be presented.

How to cite: Wegener, R. and the The MetNO2 SAPHIR intercomparison team: Intercomparison of nitrogen monoxide and nitrogen dioxide measurements in the atmosphere simulation chamber SAPHIR during the MetNO2 campaign, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6069, https://doi.org/10.5194/egusphere-egu2020-6069, 2020.

EGU2020-21718 | Displays | AS5.11

FTIR-based spectral line data of the v3 band of NO2 at 6.3 µm and multi-component impurity analysis of NO2 reference gases within the scope of the EMPIR MetNO2 project

Gang Li, Viktor Werwein, Alexandra Lüttschwager, Mi Eon Kim, Javis Nwaboh, Olav Werhahn, and Volker Ebert

Air pollution causes hundreds of thousands of premature deaths every year in Europe [1]. Traffic related Nitrogen dioxide (NO2) is a key contributor whose concentration is legislated by the Ambient Air Quality Directive (EU, 2008) [2] and the air quality guidelines (AQGs) set by the World Health Organization (WHO). Atmospheric NO2 concentration has been widely measured by national, regional and global monitoring networks using different instrumentations. SI-traceability is essential to assure data comparability across networks, underpinning long term trend of ambient NO2.

Traceable and accurate spectral line data [3,4] of NO2 is essential for optical sensing of NO2 using in situ [5] and satellite-based equipment. In particular, it is essential for cost-effective light-weight systems with payload restrictions (e.g. TDLAS system [6], e.g. when installed on drones and balloons for which real time calibration using gas cylinders quickly becomes a burden). Within the scope of the EMPIR (The European Metrology Programme for Innovation and Research) MetNO2 project [7], spectroscopic measurements of the selected NO2 CRM (certified reference material) has been carried out using the FTIR infrastructure at PTB to a) derive traceable line data of NO2; b) quantify the amount of impurities, such as HNO3, N2O4, NO, N2O, CO, H2O, etc. Here, we report the line intensity and air-broadening coefficients of the 6.3µm v3 band of NO2. FTIR-based impurity analysis including their temporal evolution will also be presented.

Acknowledgement

MK and GL thank for technical support from Kai-Oliver Krauss. This work has received funding from the EMPIR programme co-financed by the Participating States and from the European Union's Horizon 2020 research and innovation programme. PTB is member of the European Metrology Network for Climate and Ocean Observation (https://www.euramet.org/european-metrology-networks/climate-and-ocean-observation/).

References

[1] Air quality Europe – 2019 report.  EEA Report No 10/2019. https://www.eea.europa.eu/publications/air-quality-in-europe-2019

[2] Directive 2008/50/EC of the European Parliament and of the Council of 21 May 2008 on ambient air quality and cleaner air for Europe. https://www.eea.europa.eu/policy-documents/directive-2008-50-ec-of

[3] V. Werwein, J. Brunzendorf, G. Li, A. Serdyukov, O. Werhahn, V. Ebert.  Applied Optics 56 (2017)

[4] V. Werwein, G. Li, J. Brunzendorf, A. Serdyukov, O.Werhahn, V. Ebert. Journal of Molecular Spectroscopy 348, 68-78(2017).

[5] O. Werhahn O, J.C. Petersen (eds.) 2010 TILSAM technical protocol V1_2010-09-29. Available from:                     http://www.euramet.org/fileadmin/docs/projects/934_METCHEM_Interim_Report.pdf.”

[6] J. A. Nwaboh, Z. Qu, O. Werhahn and V. Ebert, Applied Optics 56, E84-E93 (2017)

[7] EMPIR project 16ENV02, “Metrology for Nitrogen Dioxide (MetNO2)”, http://em-pir.npl.co.uk/metno2/

How to cite: Li, G., Werwein, V., Lüttschwager, A., Kim, M. E., Nwaboh, J., Werhahn, O., and Ebert, V.: FTIR-based spectral line data of the v3 band of NO2 at 6.3 µm and multi-component impurity analysis of NO2 reference gases within the scope of the EMPIR MetNO2 project, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21718, https://doi.org/10.5194/egusphere-egu2020-21718, 2020.

EGU2020-13471 | Displays | AS5.11

Spark discharge aerosol generator for field calibration of absorption photometers: Aerosol properties and stability

Jorge Saturno, Andreas Nowak, Matthias Jahn, Tobias Klein, Thomas Müller, and Volker Ebert

Atmospheric aerosol particles can significantly impact the atmospheric radiative balance by scattering and absorbing incoming solar radiation. Additionally, they are known to strongly affect human health. Given the strong variations in geographical distribution of atmospheric aerosols there is a high need for ubiquitous measurements, while the variable chemical composition generates several technical and metrological challenges. Absorption photometers are commonly used to measure the atmospheric mass concentration of light‑absorbing particles like equivalent black carbon (BCe), which is the most important radiative forcer among aerosol particles due to its strong infrared to visible spectral absorption. Although BC measurements have been done since decades, a reliable metrological aerosol absorption standard to ensure traceable calibration has not been established so far. Due to the wide field implementation there is strong need for a portable, metrological generator of BC-like aerosol particles for in‑field calibration of aerosol absorption photometers. Spark discharge volatilization is an interesting candidate for a BC particle generator, given its robust operation principle and the reduced media requirements.

The spark discharge aerosol generator (SDAG) produces graphitic, BC-like aerosol particles. Most important is the lack of any organic coatings, known from spray or combustion generators, which usually alter the optical properties of the BC particles. The SDAG consists of a chamber purged with an inert gas (usually nitrogen or argon), which houses two graphite electrodes, which are connected to a pulsed high-voltage source with variable pulse frequency and amplitude. In this study, a PALAS DNP 3000 (PALAS GmbH, Germany) has been used for generating graphitic particles and measure their optical properties, aerosol number size distribution and particle morphology by scanning electron microscopy in transmission mode (TSEM). The SDAG was operated by using inert N2 only (avoiding dilution air), in order to facilitate the transportability and in-field operation. The N2 flow rate was fixed to 10 l/min. The spark discharge frequency spanned 60 to 600 Hz. The voltage was varied from 2500 to 5000 V.

The mobility count mean diameter (CMD) of the particles produced could be varied from 28 to 80 nm, using the different set points described above. The single scattering albedo of the aerosol particles was almost constant for all operation modes with an average 0.11 ± 0.03. A repeatability analysis over 9 days was done using a single setting mode (140 Hz, 3500 V), which produced particles of 45 nm CMD with a variability of 6 nm CMD (2σ). The total particle number concentration ranged from 8 to 11 x 106 cm-3 and varied within 8% (1σ) within the different days. Hence, the SDAG is a promising source of stable, nascent and uncoated, graphitic BC particles and thus has good potential to improve field BC calibration.

This research is part of an international project that aims to establish a BC reference material and calibration procedure (EMPIR 16ENV02 ”Black Carbon”, http://www.empirblackcarbon.com/).

How to cite: Saturno, J., Nowak, A., Jahn, M., Klein, T., Müller, T., and Ebert, V.: Spark discharge aerosol generator for field calibration of absorption photometers: Aerosol properties and stability, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13471, https://doi.org/10.5194/egusphere-egu2020-13471, 2020.

Optical isotope ratio spectroscopy (OIRS) has recently gained popularity and maturity in isotope research because it simplifies the measurement process and makes isotope ratio measurements in atmospheric greenhouse molecule gases, e.g. CO2, N2O, CH4, more accessible to field research and monitoring networks. OIRS is advantageous in terms of high time resolution, possibility of in-situ measurements and simplified sampling process. However, compared to traditional, high accurate isotope ratio mass spectrometry (IRMS), spectroscopic methods are not yet well established for the highest precision quantification of delta values and agreed recommendations for best practices are still missing. From a metrological point of view, the concept of uncertainty assessment in OIRS field measurements needs to be reported in accordance to the terms of the “Guide to the expression of uncertainty in measurement” (GUM, ISO/IEC Guide 98-3:2008). GUM compliant uncertainty estimation is necessary to assess the metrological comparability of OIRS measurement results. 

In this study we discuss calibration strategies for δ13C-CO2 and δ18O-CO2 measurements with commercial mid-IR OIRS instrumentation (Thermo Scientific Delta Ray), an uncertainty budget for OIRS measurements estimated according to the GUM, and compare the calibration strategies recommended by the manufacturer with our new metrological calibration procedure, which considers aspects so far limiting the accuracy as, e.g., matrix gas effects, CO2 concentration dependence, instrumental drift corrections, and isotope calibration gas uncertainties.

Acknowledgments. This study has received funding from the European Metrology Programme for Innovation and Research (EMPIR) co-financed by the EURAMET Participating States and from the European Union's Horizon 2020 research and innovation programme as of the SIRS project (16ENV06).  PTB is a member of the European Metrology Network for Climate and Ocean Observation.

How to cite: Prokhorov, I., Chubchenko, I., Werhahn, O., and Ebert, V.: Metrological calibration strategies and uncertainty assessments for spectroscopic mid-IR isotope ratio measurements in carbon dioxide, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-221, https://doi.org/10.5194/egusphere-egu2020-221, 2020.

During liquid-vapor phase transition, CO2 can undergo isotopic fractionation in both C and O.  This phase transition can occur during routine cylinder handling, such as gas expansion or while subjecting the cylinder to cold temperatures without allowing the cylinders to come to thermal equilibrium prior to use. 

This work examines the isotope changes for both C and O in a series of controlled experiments on dual phase (liquid-vapor) and single-phase (vapor only) carbon dioxide contained in pressurized gas cylinders at sub-freezing, ambient and elevated temperatures.  The isotopic values were measured during the temperature equilibration from either cold or elevated temperatures to room temperature.  Isotopic values were observed to vary when the gas was at sub-freezing temperatures but not from elevated temperatures.  Stable isotope practitioners, who rely on pressurized carbon dioxide as a working IRMS laboratory reference gas, will find this work useful.

How to cite: Jacksier, T. and Socki, R.: Carbon and Oxygen Isotope Fractionation of Pressurized CO2 as a Function of Temperature, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1473, https://doi.org/10.5194/egusphere-egu2020-1473, 2020.

      Our process-based understanding of stable isotope signals, as well as technological developments, has progressed significantly, opening new frontiers in marine interdisciplinary research. This has promoted the broad utilisation of carbon and oxygen isotope applications to gain insight into carbon cycling in marine ecosystems and their interaction with the atmosphere.

Our study was performed in the Gulf of Trieste in the N Adriatic where the influence of biological processes, riverine loads and local climate conditions on the atmosphere-water CO2 exchange and on the carbonate system equilibrium was investigated, in order to elucidate what drives the CO2 exchange and to estimate the vulnerability of the Gulf of Trieste to acidification processes. On an annual scale, the Gulf of Trieste clearly acts as a sink of CO2, strongly controlled by the seasonal variability of water temperature, biological processes, wind speed and riverine inputs. The calculated air-sea CO2 flux was estimated to be -1.47 ± 1.41 mol C m-2 yr-1. The sink was generally stronger during the winter months, whereas during early summer and autumn the CO2 fluxes were lower. It was interesting to note that the atmospheric CO2 concentrations exhibited large fluctuations on a daily basis, as well as on a seasonal time scale. The average atmospheric CO2 concentration during our study in 2013 was 438 ± 16 ppm. This is significantly higher than the global average, which, at the time was around 400 ppm. Further The isotopic composition of carbon in atmospheric carbon dioxide (δ13CCO2,air) values panned from -12.7‰ to -9.1‰ with an average value of -10.8 ± 0.9‰. This is considerably different to the “background” value of -8‰ (from NOAA/ESRL) and can most probably be attributed to the presence of fossil fuel emissions. The results are comparable with the data obtained in the Adriatic between Ravenna and Otranto.

The presented study indicate that the quality and comparability of datasets is critical to improve the estimation of processes that influence the carbon dynamics in marine environment. Thus, the implementation of the principle in our laboratory, the monitoring of our measurement quality, validation and status of newly developed gas CO2 reference materials (SIRS1, SIRS2 and SIRS3) as a part of SIRS project will be also presented.

How to cite: Krajnc, B., Tamše, S., and Ogrinc, N.: The importance of appropriate isotope reference standards for determination of the isotopic composition of C and O in atmospheric CO2, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18746, https://doi.org/10.5194/egusphere-egu2020-18746, 2020.

EGU2020-21827 | Displays | AS5.11

DEVELOPING STATIC AND DYNAMIC STABLE ISOTOPE REFERENCE GAS MIXTURES OF CO2 AT 400 µmol/mol

Aylin Boztepe, Tanıl Tarhan, Zeynep Gülsoy Şerif, and Adnan Şimşek

Climate change is one of the most urgent issues facing humanity today. Humans have been rapidly changing the balance of gases in the atmosphere which causes global warming. Burning fossil fuels like coal and oil, farming and forestry, agriculture and cement manufacture cause to release water vapor, carbon dioxide (CO2), methane (CH4), ozone and nitrous oxide (N2O) known as the primary greenhouse gases. According to Intergovernmental Panel on Climate Change (IPCC), carbon dioxide is the most common greenhouse gas absorbing infrared energy emitted from the earth, preventing it from returning to space. It is necessary to separate man-made (anthropogenic) emissions from natural contributions in the atmosphere to obtain accurate emission data [1-4]. Since it could not be achieved with the existing metrological infrastructure, it is required to develop the measurements and references of stable isotopes of CO2. In this study, static and dynamic reference materials for pure CO2 at 400 µmol/mol in air matrix were prepared and it was provided to simulate CO2 gas in the atmosphere.

The static gas mixtures were prepared gravimetrically in accordance with the ISO 6142-1 standard. In order to obtain CO2 gas at desired isotopic compositions, commercial CO2 gases were also supplied from abroad. Their isotopic compositions were measured by using GC-IRMS. Before filling, aluminum cylinders were evacuated until the pressure of 10-7 mbar using turbo-molecular vacuum pump. Isotopic compositions of reference materials were determined in a way that covering the range -42 ‰ to +1 ‰ vs VPDB for d13C-CO2 and -35 ‰ to -8 ‰ vs VPDB for d18O. In order to develop static and dynamic reference materials of CO2 at 400 µmol/mol in air with the uncertainty targets of d13C-CO2 0.1 ‰ and d18O-CO2 0.5 ‰, previously prepared pure CO2 reference gases were used. Dynamic dilution system with the high accuracy was constructed to generate dynamic reference gas mixture of CO2 at 400 µmol/mol. System contains 3 electronic pressure controllers, 3 thermal mass flow controllers with various capacities and 3 molbloc-L flow elements commanded with 2 Molboxes. The isotopic compositions of dynamic reference gas mixtures of CO2 at 400 µmol/mol were aimed to be same with the previously prepared pure CO2 reference gases. The whole dilution system were calibrated at INRIM to achieve lower uncertainties around 0.07-0.09%. At the measurement stage, CRDS and GC-IRMS equipments are operated simultaneously to determine the concentrations and isotopic compositions of the gas mixtures. The amount of substance fractions of the dynamic reference mixtures are calculated according to ISO 6145-7 standard. It will be checked that whether the isotopic compositions of the gravimetrically prepared pure CO2 reference gases and the dynamic reference gas mixtures of CO2 at 400 µmol/mol were same or not.

REFERENCES

[1] Calabro P. S., “Greenhouse gases emission from municipal waste management: The role of separate collection”, Waste Management, Volume 29:7, 2178-2187, 2009.

[2] Sources of Greenhouse Gas Emissions, United States Environmental Protection Agency, https://www.epa.gov/ghgemissions/sources-greenhouse-gas-emissions, 2019.

[3] Schwartz, S.E., “The Greenhouse Effect and Climate Change”, 2017.

[4] Climate Change, The Intergovernmental Panel on Climate Change, https://www.ipcc.ch/report/ar4/wg1, 2019.

How to cite: Boztepe, A., Tarhan, T., Gülsoy Şerif, Z., and Şimşek, A.: DEVELOPING STATIC AND DYNAMIC STABLE ISOTOPE REFERENCE GAS MIXTURES OF CO2 AT 400 µmol/mol, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21827, https://doi.org/10.5194/egusphere-egu2020-21827, 2020.

EGU2020-14771 | Displays | AS5.11

Development and characterization of a high precision QCLAS for selective NO2 measurement

Nicolas Sobanski, Beat Schwarzenbach, Béla Tuzson, Lukas Emmenegger, Dave R. Worton, Naomi Farren, Tatiana Mace, and Christophe Sutour

   Nitrogen dioxide (NO2) is an atmospheric pollutant whose emissions are mostly linked to anthropogenic activities. It is, with nitric oxide (NO), the most abundant member of the nitrogen oxides family in tropospheric urban air (mixing ratios up to hundreds of ppbv), with a lifetime ranging from hours to days. NO2 is well known for its role as a boundary layer ozone and organic nitrates precursor and for affecting the oxidation capacity of the atmosphere. It has thus been subject to emissions mitigation policies and ambient air amount fraction monitoring for a few decades. The latter fully relies on the Chemiluminescence Detection technique (CLD), which is an indirect method measuring NO2 after conversion to NO.
   Recent advances in spectroscopy led to the development of direct and more selective ways to measure NO2. The currently running European Metrology for Nitrogen Dioxide (MetNO2) project, involving more than 15 European academic and industrial partners, promises to fill the gap in reliable and complete datasets for laboratory and field testing of those measurement techniques.
Here we present the results of a performance investigation of a high precision Quantum Cascade Laser Absorption Spectrometer (QCLAS) for the selective measurement of NO2 performed in the frame of the MetNO2 project. This instrument is based on a mid-IR QCL emitting at 6 μm and a custom-made, low noise astigmatic Herriott type multipass cell with an effective optical path length of 100 m to measure NO2 concentration in the low pptv range. We focus on determining precision, long-term stability and potential biases related to sampling conditions such as ambient pressure, temperature and humidity. The QCLAS device is then compared to other direct spectroscopic (CAPS, CRDS, IBBCEAS) and indirect (CLD) techniques. We also report on the results of a three weeks side-by-side field comparison at an urban air monitoring station of the Swiss National Air Pollution Monitoring Network (NABEL), involving the newly developed QCLAS, and commercial CAPS and CLD instruments.
   We show that the QCLAS is well suited for monitoring of NO2 concentration in ambient air and its performances in term of precision and stability surpass those of the CLD device and compete well with other direct measurement techniques.

How to cite: Sobanski, N., Schwarzenbach, B., Tuzson, B., Emmenegger, L., Worton, D. R., Farren, N., Mace, T., and Sutour, C.: Development and characterization of a high precision QCLAS for selective NO2 measurement, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14771, https://doi.org/10.5194/egusphere-egu2020-14771, 2020.

EGU2020-17866 | Displays | AS5.11

A thermal dissociation CAPS for detection of NOy species within the MetNO2 project

Annika Kuß, Dagmar Kubistin, Robert Holla, Christian Plaß-Dülmer, Erasmus Tensing, Felix Utschneider, Maximilian Prosteder, David R. Worton, Stefan Persijn, Maitane Iturrate-Garcia, and Robert Wegener

As a toxic and reactive gas, nitrogen dioxide (NO2) influences air quality and health, the self-cleaning power of the atmosphere and photochemical smog formation. Reliable scientific data with high quality and comparability are required for national and international decision-makers. The quality of the NO2 measurements is crucially dependent on the quality of the calibration standards. In order to achieve the quality goals required, the MetNO2 project within the EMPIR (European Metrology Program for Innovation and Research) program aims to provide accurate and stable NO2 calibration standards for operational use at air quality stations.

To characterise the impurities of the newly developed standards a Thermal Dissociation - Cavity Attenuated Phase Shift (TD - CAPS) system has been set up, based on the design from Sadanaga et al. (2016). The device includes four heated channels for the differentiation of NO2, peroxy and alkyl nitrates and HNO3. In parallel, a gold converter coupled with a chemiluminescence detector was deployed for detection of the total sum of NOy. First results of the performance of the TD-CAPS used for impurity analysis of NO2 standards will be presented.

 

Reference: Sadanaga et al. Review of Scientific Instruments 87.7 (2016), 074102

How to cite: Kuß, A., Kubistin, D., Holla, R., Plaß-Dülmer, C., Tensing, E., Utschneider, F., Prosteder, M., Worton, D. R., Persijn, S., Iturrate-Garcia, M., and Wegener, R.: A thermal dissociation CAPS for detection of NOy species within the MetNO2 project, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17866, https://doi.org/10.5194/egusphere-egu2020-17866, 2020.

EGU2020-19259 | Displays | AS5.11

Diode laser spectrometer for NO2 quantification: Absolute laser spectroscopic and direct NO2 concentration measurements for atmospheric monitoring within the EMPIR project MetNO2

Javis A. Nwaboh, Zhechao Qu, Gang Li, Mi Eon Kim, Jan C. Petersen, David Balslev-Harder, Olav Werhahn, and Volker Ebert

Nitrogen dioxide (NO2) is an atmospheric pollutant that needs to be accurately measured for air quality control. The standard reference method (SRM, as laid down in EN 14211:2012 [1]) for NO2 emissions is based on chemiluminescence, where NO2 is only indirectly measured. Due to the fact that NO2 is the only air pollutant that is indirectly measured and because of some shortcomings in SRM-based measurements, there are attempts to develop methods also for direct NO2 quantifications that are accurate and reliable [2, 3]. Laser spectroscopic techniques such as direct tunable diode laser absorption spectroscopy (dTDLAS [4]), which has been demonstrated for direct and absolute measurements of a variety of atmospheric molecules (H2O, NH3, CO2 and CO) [4-7], provide excellent options for direct atmospheric NO2 measurements. Based on the experience with other species, a test method for direct NO2 measurements based on dTDLAS was found to be a promising alternative as compared to the SRM.

We present a measurement method based on dTDLAS for direct and absolute NO2 concentration measurements compatible to [8] and complying with metrological principles of SI-traceability. The approach was realized by two independent, newly developed mid infrared (ICL, QCL) laser spectrometers (one aiming at compact and field-deployable system integration). Results of directly measured NO2 concentrations are presented, addressing traceability to the SI, to demonstrate the capability of the measurement method. Guide to the expression of uncertainty in measurement (GUM) compliant uncertainty budgets are reported to show the current data quality. A first principles laser spectroscopic system which does not need calibration by gaseous reference material and which is validated for concentration results that are directly traceable to the SI shall be referred to as an “optical gas standard”, (OGS). We present validations in the concentration range 100 µmol/mol to 1000 µmol/mol. A discussion on current limitations and potentials for an upscaling of these new NO2 systems to be operated as OGSs towards ambient air concentrations will be part of this presentation, too.

This work has received funding from the EMPIR programme co-financed by the Participating States and from the European Union's Horizon 2020 research and innovation programme. PTB is member of the European Metrology Network for Climate and Ocean Observation (https://www.euramet.org/european-metrology-networks/climate-and-ocean-observation/).

References

[1] European Standard: “Ambient air - Standard method for the measurement of the concentration of nitrogen dioxide and nitrogen monoxide by chemiluminescence”, EN 14211:2012

[2] EMPIR project 16ENV02, “Metrology for Nitrogen Dioxide (MetNO2)”, http://em-pir.npl.co.uk/metno2/

[3] P. Morten Hundt, Michael Müller, Markus Mangold, Béla Tuzson, Philipp Scheidegger, Herbert Looser, Christoph Hüglin, Lukas Emmenegger, Atmos. Meas. Tech., 11, 2669–2681 (2018)

[4] J. A. Nwaboh, Z. Qu, O. Werhahn, V. Ebert, Appl. Opt. 56, E84-E93 (2017)

[5] B. Buchholz, N. Böse, V. Ebert, Appl. Phys. B 116, 883-899, (2014)

[6] J.A. Nwaboh, J. Hald, J.K. Lyngsø, J.C. Petersen, O. Werhahn, Appl. Phys. B 110:187–194 (2013)

[7] A. Pogány, O. Werhahn, V. Ebert, Imaging and Applied Optics 2016, DOI: 10.1364/3D.2016.JT3A.15

[8] Werhahn O, Petersen J C (eds.) 2010 TILSAM technical protocol V1_2010-09-29 (http://www.euramet.org/fileadmin/docs/projects/934_METCHEM_Interim_Report.pdf)

 

How to cite: Nwaboh, J. A., Qu, Z., Li, G., Kim, M. E., Petersen, J. C., Balslev-Harder, D., Werhahn, O., and Ebert, V.: Diode laser spectrometer for NO2 quantification: Absolute laser spectroscopic and direct NO2 concentration measurements for atmospheric monitoring within the EMPIR project MetNO2 , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19259, https://doi.org/10.5194/egusphere-egu2020-19259, 2020.

EGU2020-18995 | Displays | AS5.11

Assessment of on-line and off-line instruments for the measurement of polyfunctional oxygenated organic volatile compounds (OVOCs) under controlled conditions

Amalia Munoz, Mila Rodenas, Alexander Brenan, Inmaculada Colmenar, Julian Dellen, Aline Gratien, Tatiana Gomez, Eetu Kari, Vicent Michoud, Anke Mutzel, Mike Newland, David Reimer, Andrew Rickard, Paul Seakins, Marvin Shaw, Thomas Speak, Ralf Tillmann, Teresa Vera, Annele Virtanen, and Sergej Wedel

EGU2020-8833 | Displays | AS5.11

Comparison of Formaldehyde Measurements by HANTZSCH, CRDS and DOAS instruments in the SAPHIR Chamber

Marvin Glowania, Hendrik Fuchs, Franz Rohrer, Hans-Peter Dorn, Frank Holland, and Ralf Tillmann

Three instruments using different measurement techniques were used to measure formaldehyde (HCHO) concentrations during experiments in the atmopshere simulation chamber SAPHIR at the Forschungszentrum Juelich. An AL4021 instrument by Aero Laser GmbH uses the wet-chemical Hantzsch reaction for efficient gas stripping, chemical conversion and fluorescence measurement. An internal permeation gas source provides daily calibrations characterized by sulfuric acid titration. A G2307 analyzer by PICARRO INC. uses Cavity Ring-Down Spectroscopy (CRDS) technique to determine concentrations of HCHO, water and methane. A high-resolution laser differential optical absorption spectroscopy (DOAS) instrument provided HCHO measurements along the central chamber axis using an optical multiple reflection cell. The measurements were conducted from June to December 2019 in experiments when ambient air was flowed through the chamber and also in photochemical experiments in synthetic air with mixtures of different reactants, water vapour, nitrogen oxides, and ozone concentrations. Results demonstrate the importance for a linear base line interpolation between zero measurements for the Hantzsch instrument. In addition, a strong water dependence of the baseline of CRDS measurements was found. After correction for the baselines, the correlation analysis of measurements demonstrate good agreement (R > 0.98) between the instruments.

How to cite: Glowania, M., Fuchs, H., Rohrer, F., Dorn, H.-P., Holland, F., and Tillmann, R.: Comparison of Formaldehyde Measurements by HANTZSCH, CRDS and DOAS instruments in the SAPHIR Chamber, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8833, https://doi.org/10.5194/egusphere-egu2020-8833, 2020.

EGU2020-7161 | Displays | AS5.11

Traceability of real-time reference gas generation for reactive gaseous compounds

Timo Rajamäki and Sari Saxholm

For reactive gaseous compounds, limited availability of bottled standard gases often limits their measurement accuracy and comparability. Typically, an available reference gas concentration range for the specific compounds may be limited to even orders of magnitude higher than the levels normally measured at atmospheric measurements and most often only dry reference gases in inert matrices, typically nitrogen, are available. This means that when applying test gases from cylinders humidity in measurement system may cause significantly longer measurement response than in normal operation.

 

A real-time reference gas generation is an effective method to circumvent these obstacles. Controlled evaporation of the reference solution enables flexible and reliable generation of test gases in wide concentration and flow ranges as well as in different gas matrices. The method is useable in field conditions and it may provide cost savings since necessary consumables include solely pure carrier gas and solution of the studied chemical with know concentration.

 

We validate this method for different reactive gaseous compounds and key impurities. For mercury chloride, the most typical form of oxidised mercury in process emissions and atmosphere, reference gas with concentration ranging from sub-ng/m3 to tens of µg/m3 is generated. In case of typical base and acid trace impurities, ammonia, hydrogen chloride and hydrogen fluoride, the reference gases are generated in (bio-) methane and air matrices. In all cases studied, the stabilization time of generating gas flow is no longer, than some minutes. Accuracy and traceability of the generated gas concentration are estimated based on full uncertainty calculation as well as comparison with traceable reference gas standards.

How to cite: Rajamäki, T. and Saxholm, S.: Traceability of real-time reference gas generation for reactive gaseous compounds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7161, https://doi.org/10.5194/egusphere-egu2020-7161, 2020.

EGU2020-10511 | Displays | AS5.11

Fast Airborne Extractive Electrospray Mass Spectrometry (EESI) Measurements of the Chemical Composition of Biomass Burning Organic Aerosol

Demetrios Pagonis, Pedro Campuzano-Jost, Hongyu Guo, Douglas Day, Wyatt Brown, Melinda Schueneman, Benjamin Nault, Felix Piel, Tomas Mikoviny, Laura Tomsche, Armin Wisthaler, and Jose Jimenez

Fast measurements of the chemical composition of organic aerosol (OA) at the molecular level are essential to furthering the understanding of the sources and evolution of ambient particulate matter. To that end, we carried out airborne in-situ extractive electrospray time-of-flight mass spectrometry (EESI) measurements of aerosol in a large set of wildland and agricultural fire smoke plumes during the Fire Influence on Regional to Global Environments and Air Quality (FIREX-AQ) campaign in summer 2019. We present the methodology that allowed for stable, quantitative measurements of targeted analytes up to altitudes of 7 km. Optimization of electrospray solvent, fine control of electrospray capillary position, pre- and post-flight calibrations, and tightly regulated inlet pressure all contributed to extending airborne EESI measurements to these altitudes.

The EESI was operated with both positive and negative ion polarity during the study, and we report 1-Hz aerosol concentrations of levoglucosan for EESI(+) and nitrocatechol for EESI(-). Campaign-averaged 1-second detection limits for each compound were 720 and 17 ng m-3 during low-altitude sampling. Intercomparison of EESI with an Aerodyne high-resolution Aerosol Mass Spectrometer (AMS) flown during FIREX-AQ shows the fast response time of EESI in concentrated aerosol plumes. Total EESI signal was well correlated with AMS OA for both EESI(+) and EESI(-) measurements, and we present bulk EESI OA sensitivities. We also compare EESI measurements of levoglucosan to a CHemical Analysis of aeRosol ONline Proton-Transfer Reaction Mass Spectrometer (CHARON PTR-MS) flown during FIREX-AQ, demonstrating quantitative agreement between the two instruments. We also compare compounds detected in-situ by EESI with offline electrospray ionization (ESI) of filter samples collected during FIREX-AQ, showing overlap in the detected spectra of the two techniques.

Positive matrix factorization (PMF) of EESI data shows that the chemical composition of biomass burning OA evolves as it is transported downwind, with production of some species and loss of others. This evolution occurs while dilution-corrected OA concentrations remain roughly constant, suggesting that there is a balance between processes that increase and reduce OA concentrations. 

How to cite: Pagonis, D., Campuzano-Jost, P., Guo, H., Day, D., Brown, W., Schueneman, M., Nault, B., Piel, F., Mikoviny, T., Tomsche, L., Wisthaler, A., and Jimenez, J.: Fast Airborne Extractive Electrospray Mass Spectrometry (EESI) Measurements of the Chemical Composition of Biomass Burning Organic Aerosol, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10511, https://doi.org/10.5194/egusphere-egu2020-10511, 2020.

EGU2020-11863 | Displays | AS5.11

Evaluating the Consistency of All Submicron Aerosol Mass Measurements (Total and Speciated) for the NASA Atmospheric Tomography Aircraft Mission (ATom)

Hongyu Guo, Pedro Campuzano-Jost, Benjamin Nault, Douglas Day, Christina Williamson, Agnieszka Kupc, Charles Brock, Gregory Schill, Karl Froyd, Daniel Murphy, Eric Scheuer, Jack Dibb, Joseph Katich, and Jose Jimenez

The Aerodyne Aerosol Mass Spectrometer (AMS) is a widely used instrument to quantify the composition of non-refractory submicron aerosol, in particular, organic aerosol (OA). Past comparisons, particularly of aircraft data in continental areas, have shown good overall agreement with other chemical and optical sensors. Recently, theoretically-based concerns have been raised regarding the overall AMS calibration uncertainties (particularly for OA), although there is no evidence that those apply to aircraft datasets.

The ATom mission sampled the remote marine troposphere from 87S to 82N and from 0 to 12.5 km over the course of four aircraft deployments over the space of 2 years, carrying an advanced aerosol payload that included particle sizing instruments operated by NOAA ESRL, as well as several chemical sensors: UNH Mist Chamber and Filters for inorganic aerosol, NOAA SP2 for black carbon measurements, NOAA PALMS instrument for single particle composition and the CU aircraft high-resolution AMS for non-refractory submicron mass. This provides a unique opportunity to explore the agreement of the different instruments over a very large range of conditions and calibration regimes, and improve our understanding of the various instrumental uncertainties in field data.

Special attention was paid to characterize the AMS size-dependent transmission with in-field calibrations; this provided crucial context when comparing with instruments with very different size cuts. Excellent agreement was found between the AMS calculated volume (including black carbon from the SP2) and the PM1 volume derived from the NOAA particle sizing measurements over three orders of magnitude (slope 0.94). The comparisons for sulfate, OA, and seasalt (the three main components of the remote PM1 aerosol) measured by AMS with the PALMS instrument showed similar consistency once differences in particle detection at different sizes were accounted for. Similarly, comparisons with sulfate from filters showed good consistency once episodes with large supermicron mass were filtered out. Comparisons of the AMS with the mist chamber sulfate were affected by the variable time response of the latter instrument but were overall consistent. Overall, no evidence for AMS calibration artifacts or unknown sources of error was found for these datasets. A comprehensive evaluation of the different sources of uncertainty and their impact on the comparisons was performed, and factors to be considered for performing such intercomparisons and improving the reliability of submicron mass quantification in the future are discussed.

How to cite: Guo, H., Campuzano-Jost, P., Nault, B., Day, D., Williamson, C., Kupc, A., Brock, C., Schill, G., Froyd, K., Murphy, D., Scheuer, E., Dibb, J., Katich, J., and Jimenez, J.: Evaluating the Consistency of All Submicron Aerosol Mass Measurements (Total and Speciated) for the NASA Atmospheric Tomography Aircraft Mission (ATom), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11863, https://doi.org/10.5194/egusphere-egu2020-11863, 2020.

Air pollution and extreme weather patterns have become serious issues over the world, especially in highly urbanized areas.  In order to detailed study the atmospheric environmental change, the capability to perform high spatiotemporal resolution atmospheric environmental data collection is highly desired.  In this research, we develop a cost-effective air quality monitoring system based on as open-source electronics platform (Arduino Uno Rev3) with multiple environmental sensing modules including particulate matter (PM) concentration, temperature, humidity, and sound sensors.  An integrated monitoring system with one weather station (precipitation and wind sensors) and two sets of environmental sensors set up in different heights from the ground costs less than USD$300.  The entire system is powered by a battery for portability, and all the data can be stored in a secure digital (SD) memory card for long-term monitoring. The cost-effectiveness makes it feasible for large-scale field tests with three-dimensional (3D) spatial resolution.  In the experiments, the system is tested in urban areas, and the data collection performance has been confirmed.  The results show that the data with single minute resolution can be successfully achieved in real-world scenarios with high air temperature (> 38oC) and rain conditions for more than 65 hours with a single-time battery setup.  In addition, the data collected from different heights have shown distinct atmospheric environmental patterns suggesting that it is critical to perform 3D high spatiotemporal measurement and modeling for city-scale studies.

How to cite: Tung, Y.-C., Chang, D.-M., and Kuo, C.-Y.: Cost-Effective Air Quality Monitoring System Based on an Open-Source Electronics Platform for Three-Dimensional Atmospheric Environmental Data Collection, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8307, https://doi.org/10.5194/egusphere-egu2020-8307, 2020.

AS5.12 – Advanced Spectroscopic Measurement Techniques for Atmospheric Science

EGU2020-12396 | Displays | AS5.12

Measurement of VOCs using open-path mid-infrared dual comb spectroscopy

Kevin Cossel, Eleanor Waxman, Fabrizio Giorgetta, Esther Baumann, Jacob Friedlein, Daniel Herman, Gabriel Ycas, Ian Coddington, and Nathan Newbury

Open-path measurements of atmospheric gas species over km-scale path lengths are well suited to quantify emissions from sources like oil and gas, forest fires, and industry. is a relatively new technique that combines high-resolution and broad spectral coverage with no instrument lineshape and near perfect frequency calibration. These features have enabled open-path DCS to provide accurate measurements of multiple trace gas species simultaneously in the near-infrared across path lengths ranging from 100 m to several km. However, in order to reach the sensitivity necessary to detect many atmospheric trace constituents, including volatile organic compounds (VOCs), operation in the mid-infrared (or UV/Vis) is required.

Here, we show a mid-infrared open-path dual comb spectrometer operating in the 3-4 and 4.5-5 μm spectral regions. We have used this spectrometer to measure methane, ethane, and propane (arising primarily from oil and gas activity) across a 1-km-long path in Boulder, CO for 1 week with an ethane sensitivity of ∼0.1 ppb for a 2-minute time resolution. In addition, we show quantitative measurements of intentionally released acetone and isopropanol with a 1-σ sensitivity of 5.7 ppm·m and 2.4 ppm·m, respectively. In the 4.5-5 μm region, we have used this system to detect N2O, CO, and O3. Finally, we have developed a second-generation instrument in the 3-4 μm region that is more compact and has improved stability. This system was recently deployed in a van at an active oil and gas drilling operation. We present preliminary measurements of methane, ethane, and higher hydrocarbons from this deployment as well as initial efforts at emissions quantification.

How to cite: Cossel, K., Waxman, E., Giorgetta, F., Baumann, E., Friedlein, J., Herman, D., Ycas, G., Coddington, I., and Newbury, N.: Measurement of VOCs using open-path mid-infrared dual comb spectroscopy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12396, https://doi.org/10.5194/egusphere-egu2020-12396, 2020.

EGU2020-13775 | Displays | AS5.12

Towards operational monitoring of ship emissions using Long Path Differential Optical Absorption Spectroscopy

Stefan Schmitt, Denis Pöhler, Andreas Weigelt, Folkard Wittrock, André Seyler, Kai Krause, Lisa Kattner, Barbara Mathieu-Üffing, Johannes Lampel, and Ulrich Platt

In contrast to land-based sources of air pollution, which have been regulated and reduced since several decades, NOx and SOx emissions from ships were only recently identified as significant sources of air pollution. As one consequence the sulphur content of ship fuel used within the so-called Sulphur Emission Control Areas (SECA) was recently regulated to a maximum of 0.1% (m/m) (MARPOL Annex VI). Therefore, especially monitoring the emission of sulphur compounds is of particular interest.

Within a 6-week measurement campaign in July and August of 2016, ship emissions were measured at the river Elbe in Germany, near Hamburg using the Long Path (LP)-DOAS technique. The measurements were carried out within the framework of the project MeSMarT (MEasurements of Shipping emissions in the MARine Troposphere), which investigates the influence of ship emissions on chemical processes in the atmosphere. Currently, monitoring of ship emission plumes is typically achieved by a combination of in situ trace gas monitors and meteorological sensors. In contrast to that the LP-DOAS technique is capable of simultaneously measuring signatures of multiple trace gases along an absorption path across a well-frequented waterway close to the ship exhaust-pipes and thus directly in the emission plume at a time resolution of a few seconds.

For our study, a LP-DOAS instrument was set up side by side to an in situ MeSMarT measurement station at the river Elbe at Wedel (15 km downriver of Hamburg harbour) where NO2 and SO2 emission signatures of a total of 5037 ship passes (of 1044 individual ships) were monitored. While the in situ method detected 16% of the ships, the LP-DOAS was able to assign emission plumes to 41% of all passing ships. With meteorology mainly limiting the in situ detection yield, the major limitation for the LP-DOAS was found to be due to the high traffic density and thus the difficulty to unambiguously assign recorded plumes to particular vessels, rather than to the sensitivity to the emission plume itself.

Based on the results of this feasibility study, we present a newly designed LP-DOAS system fulfilling the requirements for operational ship emission monitoring (robust mechanical setup, broad-band long-lifetime light source, compact sealed housing, automized alignment and data acquisition). This new system is now operated continuously to measure the ship emissions on the river Elbe.

How to cite: Schmitt, S., Pöhler, D., Weigelt, A., Wittrock, F., Seyler, A., Krause, K., Kattner, L., Mathieu-Üffing, B., Lampel, J., and Platt, U.: Towards operational monitoring of ship emissions using Long Path Differential Optical Absorption Spectroscopy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13775, https://doi.org/10.5194/egusphere-egu2020-13775, 2020.

EGU2020-15843 | Displays | AS5.12

Night-time vertical profiles of nitrate radical concentrations in urban environment (Paris, France)

Manuela Cirtog, Vincent Michoud, Axel Fouqueau, Mathieu Cazaunau, Antonin Bergé, Franck Maisonneuve, Pascal Zapf, Edouard Pangui, Xavier Landsheere, Jerôme Giacomoni, Matthieu Gobbi, Loïk Hanottel, Alain Paris, Nicolas Roulier, Paola Formenti, Abdelwahid Mellouki, Christopher Cantrell, Jean-François Doussin, and Bénédicte Picquet-Varrault

The NO3 radical is the main atmospheric oxidant at night. The night period is favorable to the formation and accumulation of NO3 radicals in the atmosphere. On the one hand, it is formed by the reaction of nitrogen dioxide with ozone while, on the other hand, NO3 being highly photosensitive, it cannot accumulate significantly during the day (S. S. Brown and J. Stutz, Chem. Soc. Rev. 2012). In addition, the reaction between NO and NO3 is very fast and so, urban environment is considered so far, being not favorable to the occurrence of NO3 radicals. However, atmospheric nitrogen chemistry near the earth surface is strongly linked to the dynamics of the boundary layer and in summer NO is rapidly depleted by ozone. A large variability of the mixing ratios for NO3 as a function of height above the ground is thus expected with non-negligible concentrations in altitude (Brown et al., Atmos. Chem. Phys., 2007). The contribution of NO3 radical to the atmospheric evolution of VOCs in urban and sub-urban areas may therefore also be influenced by this vertical distribution.

To demonstrate the potential importance of NO3 radical even in urban environment, a field campaign was carried out at night during July 2018 inside Paris. A newly developed field instrument dedicated to the measurement of NO3 radical was deployed on a high payload touristic tethered balloon located in Paris 15th district that was used as vertical vector. The NO3 instrument is a compact, robust and easily deployable on field instrument based on the IBB-CEAS (Incoherent Broad band Cavity Enhanced Absorption Spectroscopy) technique. NO3 measurements were completed by ground and airborne measurements of NO (chemiluminescence analyzer), NO2 (CAPS cavity) and O3 (absorption analyzer) concentrations as well as particle number concentrations (OPC GrimmTM) and 355 nm lidar (Leosphere ALS300) measurement for mixing layer probing.

Vertical profiles from 0 to up to 300 m were obtained at night characterized by high concentrations of ozone and moderate humidity. In this presentation, vertical profiles of the species measured and implications for VOC oxidation in urban environment will be discussed.

How to cite: Cirtog, M., Michoud, V., Fouqueau, A., Cazaunau, M., Bergé, A., Maisonneuve, F., Zapf, P., Pangui, E., Landsheere, X., Giacomoni, J., Gobbi, M., Hanottel, L., Paris, A., Roulier, N., Formenti, P., Mellouki, A., Cantrell, C., Doussin, J.-F., and Picquet-Varrault, B.: Night-time vertical profiles of nitrate radical concentrations in urban environment (Paris, France), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15843, https://doi.org/10.5194/egusphere-egu2020-15843, 2020.

EGU2020-11798 | Displays | AS5.12

Airborne ammonia measurements with a fiber-coupled quantum cascade laser

Mark Zondlo, Hongming Yi, Lei Tao, Da Pan, James McSpiritt, and Xuehui Guo

Free tropospheric ammonia plays critical roles in aerosol nucleation and ammonium nitrate formation with significant impacts on the Earth’s radiative forcing and tropospheric photochemistry. Remote sensing measurements on aircraft and satellite report large values (> 1 ppbv) in the upper troposphere in the outflow of deep convection over source regions. Accurate, in-situ “point” ammonia measurements from aircraft in the free troposphere are non-existent because of surface adsorption effects on existing instrument surfaces and inlets. Such higher spatiotemporal resolution measurements are needed to better deduce the processes that impact the transport of ammonia into the free troposphere from biomass burning and deep convection and its subsequent transformation into particulate ammoniated aerosols. To this end, we are developing an open-path, airborne-based ammonia instrument for the NASA DC-8 aircraft in order to measure ammonia without sampling biases throughout the troposphere. Development of such an instrument requires characteristics of fast response (10 Hz) and low detection limits (10 pptv), requiring instrument attributes of high-stability and high sensitivity. Complicating matters, these measurement attributes have to occur under a wide range of temperatures (210-310 K), pressures (150-1013 hPa), absolute humidities (ppmv to %), and environmental sampling challenges (high airspeed, vibrations, aerodynamic stresses) over the flight envelope (e.g. for vertical profiles for satellite validation). To avoid thermal management issues with the laser under the extreme temperatures experienced by the sensor, a 9.06 micron, distributed feedback quantum cascade laser (c-mount) is mounted inside a custom housing and located inside the aircraft cabin. The laser light is coupled into a 200 micron hollow core fiber for single mode operation and passed through the fuselage of the aircraft to a Herriott cell mounted 35 cm above the fuselage. The fiber and laser housing are continuously purged with dry nitrogen filtered by an ammonia scrubber to avoid interstitial absorption of ammonia in the optical path internal to the Herriott cell. Light emanating from the back facet of the laser is passed through a reference cell of ethylene and ammonia at 50 hPa to ensure appropriate linelocking and laser tuning characterization. The Herriott cell (61 m) consists of polished, aluminum mirrors held together by invar rods to minimize thermal effects on the mirror spacing (55 cm).  The mirrors are heated slightly above ambient by 50 W heaters to avoid water and ice condensation. Allan deviation experiments of the instrument show a precision of 80 pptv (1 Hz) and 13 pptv (60 s), and drift of the calibration is much less than these values up to 3000 s. Wavelength modulation spectra are fit to reference conditions over the range of the flight envelope with accuracies of fit to better than 10%. Field tests of the instrument will be shown, particularly at cold temperatures representative of the upper troposphere. The instrument was test fit onto the NASA DC-8 in summer 2019 and test flights are planned for 2020. The design attributes needed for such measurements – particularly in an aircraft platform - and laboratory and field data supporting the instrument performance will be demonstrated.

 

How to cite: Zondlo, M., Yi, H., Tao, L., Pan, D., McSpiritt, J., and Guo, X.: Airborne ammonia measurements with a fiber-coupled quantum cascade laser, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11798, https://doi.org/10.5194/egusphere-egu2020-11798, 2020.

EGU2020-8353 | Displays | AS5.12

A new snapshot interferometric imaging spectrometer: a first comparison with a classical grating spectrometer.

Aneline Dolet, Daniele Picone, Silvère Gousset, Mauro Dalla Mura, Etienne Le Coarer, and Didier Voisin

Atmospheric gas monitoring is of major importance for climate change and air quality. Indeed, emissions regulations and control rely on the detection and quantification of the concentration of gases such as CO2, CH4, NO2, O3, etc. Good control on emissions is key to reduce those gases impacts on climate change and people’s health.

The accuracy and relevance of such measurements depend on higher spatial, spectral and temporal resolutions. To this end, conventional dispersive hyperspectral imaging systems are typically used. However, these sensors are submitted to compromises in terms of price, spectral and spatial resolutions and temporal acquisition frequency. To overcome these compromises, a new ground-breaking device is currently developed under the name Imaging Spectrometer on Chip (ImSPOC). It is based on an interferometric imaging system that allows real time acquisition with significant spatial and spectral resolutions. The device, which takes the volume of a matches’ box, could in the future be a building block for Nano-satellites, drone, or ground based measurements platforms. The particularity of this device is the snapshot acquisition of an interferometer by pixel of the imaged scene instead of a spectrum. This is obtained by using a matrix of Fabry-Perot interferometers with different thicknesses placed in front of a photodetector. ImSPOC is then of great interest for real-time acquisitions. However, the acquisition of interferometers requires signal processing developments to reconstruct the corresponding spectra. This reconstruction relies typically on the resolution of an inverse problem. Some models of the device have been proposed to this end.

To validate the efficiency of this new device and to test the developed algorithms, acquisitions were conducted tracking the sun during a whole day using our device and a conventional diffraction grating based spectrometer. In this way, the reconstructed spectra from our device can be compared to the classical spectrometer ones. Particularly, the absorption peaks are compared (their central wavelengths, amplitude, etc.). To go further, the gas characterization from both devices will be compared (gas detection, evolution over time of the vertical concentration profiles, etc.). These results allow the validation of our device to this application and highlight the signal processing improvements that could be done in the future to have more accurate measurements.

How to cite: Dolet, A., Picone, D., Gousset, S., Dalla Mura, M., Le Coarer, E., and Voisin, D.: A new snapshot interferometric imaging spectrometer: a first comparison with a classical grating spectrometer., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8353, https://doi.org/10.5194/egusphere-egu2020-8353, 2020.

EGU2020-19075 | Displays | AS5.12

GRIPS-HI - a Novel Interferometer for Measuring Two-Dimensional Temperature Distributions at the Mesopause

Johannes Stehr, Peter Knieling, Friedhelm Olschewski, Martin Kaufmann, Klaus Mantel, and Ralf Koppmann

The NDMC (Network for the Detection of Mesopause Change) is a global network of ground based observatories with the objective of monitoring key parameters of the mesopause region. For temperature monitoring GRound-based Infrared P-branch Spectrometers (GRIPS) are widely deployed. These spectrometers allow for the retrieval of the mesopause temperature from the OH* P-band emission lines around 1530 nm. A common technology for GRIPS instruments are spectrometers based on diffraction gratings. To overcome the limitations of conventional grating spectrometers, a new type of spectrometer is being developed within the project Metrology for Earth Observation and Climate - 3 (MetEOC-3) which is coordinated by the European Metrology Project for Innovation and Research (EMPIR). The new spectrometer shall improve the quality and traceability of the atmospheric data obtained by the NDMC. It is intended to serve as a reference instrument with significantly smaller measurement uncertainties. It is also designed to identify temperature trends of 1K/decade. A Spatial Heterodyne Interferometer (SHI) was chosen as the most promising technology, offering several advantages. Compared to conventional grating spectrometers, the throughput and resolution of the interferometer is one order of magnitude larger. The use of a two-dimensional detector array in combination with an imaging optics enables the detection of spatial temperature distributions in the mesopause region, as caused by dynamical processes like gravity waves. The talk gives an introduction to the technology of spatial heterodyne interferometry, and the new instrument design and calibration results are presented.

How to cite: Stehr, J., Knieling, P., Olschewski, F., Kaufmann, M., Mantel, K., and Koppmann, R.: GRIPS-HI - a Novel Interferometer for Measuring Two-Dimensional Temperature Distributions at the Mesopause, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19075, https://doi.org/10.5194/egusphere-egu2020-19075, 2020.

EGU2020-15888 | Displays | AS5.12

Monitoring rain rate with proximal gamma-ray spectroscopy

Virginia Strati, Matteo Albéri, Carlo Bottardi, Enrico Chiarelli, Michele Montuschi, Kassandra Giulia Cristina Raptis, Andrea Serafini, and Fabio Mantovani

We present an exhaustive study of the gamma activity increase measured at ground level for the atmospheric radon daughter 214Pb. We demonstrate the effectiveness of proximal gamma-ray spectroscopy in continuously gathering reliable measurements of rain-induced 214Pb gamma signal related to the rain intensity and amount. Since every impulse of rain produces a sudden increase of gamma signal, we study such transient activity to obtain information on precipitations and rain formation.

A novel spectroscopic instrument specifically tailored for gathering reliable and unbiased estimates of atmospheric and terrestrial gamma emitters has been developed. After seven months of continuous acquisition, we analyze the temporal evolution of the 214Pb net count rate with an innovative and reproducible mathematical model for extracting information on this radon daughter’s content in the rain water. The effectiveness of the model is proved by an excellent coefficient of determination (r2 = 0.91) between measured and reconstructed 214Pb count rates. We observe that the impulsive increase of 214Pb count rates ΔC is clearly related to the rain rate R by the power law dependence ΔC = A·R0.50 ± 0.03, where the parameter A is equipment dependent. This means that the expected increase of atmospheric 214Pb activity measured at ground level during a rain event is proportional to the square root of the rain rate √R.

We observe that the 214Pb abundance (G) of the rain water is inversely related to the rain rate G ∝ 1/R0.48 ± 0.03 and to the rain median volume diameter λm with G ∝ 1/ λm2.2.  We proved that, for a fixed rainfall amount, the longer is the rain duration (i.e. the lower is the rainfall intensity and the smaller is the mean raindrop volume), the higher is the 214Pb content of the rain water.

Since the developed algorithm is detector independent, it can be used for analysing the data collected by the networks of thousands of gamma sensors distributed around the Earth, typically utilised for monitoring the air radioactivity in case of a nuclear fallout. From this spectroscopic technique we shall learn a lot more about the rain formation and scavenging mechanisms which are responsible for the attachment of 214Pb to rain droplets in-cloud. Finally, our research provides a comprehensive characterization of the background radiation assessments relevant for radioprotection, earthquake predictions, cosmic rays research and anthropic radiation monitoring.

How to cite: Strati, V., Albéri, M., Bottardi, C., Chiarelli, E., Montuschi, M., Raptis, K. G. C., Serafini, A., and Mantovani, F.: Monitoring rain rate with proximal gamma-ray spectroscopy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15888, https://doi.org/10.5194/egusphere-egu2020-15888, 2020.

EGU2020-20533 | Displays | AS5.12

HITRAN2020: An overview of what to expect

Robert Hargreaves, Iouli Gordon, Laurence Rothman, Robab Hashemi, Ekaterina Karlovets, Frances Skinner, Eamon Conway, Yan Tan, Christian Hill, and Roman Kochanov

The HITRAN database is an integral component of numerous atmospheric radiative transfer models and it is therefore essential that the database contains the most appropriate up-to-date spectroscopic parameters. To this end, the HITRAN2020 database is scheduled to be released at the end of this year.  The compilation of this edition (as is the tradition for the HITRAN database) exemplifies the efficiency and necessity of worldwide scientific collaborations. It is a titanic effort of experimentalists, theoreticians and atmospheric scientists, who measure, calculate and validate the HITRAN data.

The HITRAN line-by-line lists for almost all 49 molecules have been updated in comparison to HITRAN2016 (Gordon et al., 2017), the previous compilation. The extent of these updates depend on the molecule, but range from small adjustments for a few lines of an individual molecule to complete replacements of line lists and the introduction of new isotopologues. Many new vibrational bands have been added to the database, thereby extending the spectral coverage and completeness of the datasets. In addition the accuracy of the parameters for major atmospheric absorbers has been substantially increased, often featuring sub-percent uncertainties.

Furthermore, the amount of parameters has also been significantly increased. For example, HITRAN2020 will now incorporate non-Voigt line profiles for many gases, broadening by water vapour (Tan et al., 2019), as well as updated collision induced absorption sets (Karman et al., 2019). The HITRAN2020 edition will continue taking advantage of the new structure and interface available at www.hitran.org (Hill et al., 2016) and the HITRAN Application Programming Interface (Kochanov et al., 2016).

This talk will provide a summary of these updates, emphasizing details of some of the most important or drastic improvements.

References:

Gordon, I.E., .et al., (2017), JQSRT 203, 3–69.  (doi:10.1016/j.jqsrt.2017.06.038)

Hill, C., et al., (2016), JQSRT 177, 4–14.  (doi:10.1016/j.jqsrt.2015.12.012)

Karman, T., et al. (2019), Icarus 328, 160–175.  (doi:10.1016/j.icarus.2019.02.034)

Kochanov, R.V., et al.,( 2016), JQSRT 177, 15–30.  (doi:10.1016/j.jqsrt.2016.03.005)

Tan, Y., et al., (2019), J. Geophys. Res. Atmos. 124, 11580-11594. (doi:10.1029/2019JD030929)

 

How to cite: Hargreaves, R., Gordon, I., Rothman, L., Hashemi, R., Karlovets, E., Skinner, F., Conway, E., Tan, Y., Hill, C., and Kochanov, R.: HITRAN2020: An overview of what to expect, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20533, https://doi.org/10.5194/egusphere-egu2020-20533, 2020.

EGU2020-3775 | Displays | AS5.12

A high resolution ultraviolet spectroradiometer and its application in solar radiation measurement

Qilong Min, Bangsheng Yin, Jerry Berdnt, Harrison Lee, and Lei Zhu

An ultraviolet (UV) spectroradiometer is refurbished and upgraded with a fore-optical module. In addition to measuring total UV irradiance, the UV spectroradiometer can measure solar direct beam and sky radiance at any preset azimuth and elevation angle. This double Czerny-Turner spectroradiometer, with an ion-etched holographic grating operating in the first order with 3600 lines per mm, enables wavelength scanning range from 290 nm to 410 nm, with a nominal bandwidth of 0.1 nm.  It can operate with a step-size of 0.0005 nm and a full width at half maximum of 0.1 nm. It has an out-of-band rejection ratio of approximately 10–10. This high resolution spectroradiometer can be used as a reference instrument for UV radiation measurements and to monitoring atmospheric gases (O3, SO2, NO2). Recently laboratory work suggests that water vapor displays structured absorption features over 290-350 nm region with maximum and minimum cross-sections of 8.4×10-25 and 1.4×10-25 cm2/molecule. To investigate the water vapor absorption features in UV region in real atmosphere, we did a series of field observations by using this high resolution spectroradiometer. A residual analysis method is developed to analyze the absorption of atmospheric components and to retrieve the atmospheric optical depth. The residual spectra of multiple cases have spectral features similar to that of in-lab measured water vapor absorption in some wavelength regions, and the inferred ozone amount from residual analysis agrees with OMI retrievals. Through multiple case studies, the magnitude of residual optical depth from observed UV spectra is sensitive to the atmospheric water vapor amount. The greater the water vapor path, the larger the difference between observational spectra and calculated spectra without considering water vapor absorption.

How to cite: Min, Q., Yin, B., Berdnt, J., Lee, H., and Zhu, L.: A high resolution ultraviolet spectroradiometer and its application in solar radiation measurement, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3775, https://doi.org/10.5194/egusphere-egu2020-3775, 2020.

EGU2020-20831 | Displays | AS5.12

Novel, real-time measurements of VOCs using a Cavity Ring-Down Spectrometer (CRDS)

Gregor Lucic, Chris Rella, John Hoffnagle, Kai Skog, and Laurie McHale

Measurements of volatile organic compounds (VOCs) are important in a wide variety of scientific disciplines, including air quality, biogeochemistry, hydrology, plant and animal physiology, human health, and petrochemistry. Generally, these measurements are performed with expensive laboratory-based mass spectrometers, slow gas chromatographs, non-speciated flame- or photo-ionization detectors, or insensitive Fourier transform infrared spectrometers. Laser-based spectrometers based upon cavity enhanced techniques like cavity ring-down spectroscopy (CRDS) would in principle provide significant advantages over these methods in sensitivity, speed of response, simplicity, stability, and portability, as has been demonstrated in the last decade for the quantification of simple molecules like carbon dioxide, methane, or ammonia.  However, the majority of these instruments are based upon narrowly tunable lasers.  These lasers cannot tune across the broad spectral features, characteristic of VOCs.  In this paper we present a novel CRDS instrument based upon a broadband laser source that can in principle span more than hundred nanometers.  We show early measurements of ethylene oxide and BTEX (benzene, toluene, ethylbenzene, and xylene) at parts per billion and even parts per trillion levels.  Though our initial work has focused on measurements of hazardous air pollutants, there is future potential for speciated detection of other VOCs as well as greenhouse gases. These systems can be deployed on a bench-top and/or vehicle, and with per-second measurement intervals, are ideal for correlation with weather data for accurate source attribution. The analyzers are being developed to meet indoor and outdoor air quality requirements and may be deployed near sources (stack or fenceline monitoring) or far from sources (community monitoring). 

How to cite: Lucic, G., Rella, C., Hoffnagle, J., Skog, K., and McHale, L.: Novel, real-time measurements of VOCs using a Cavity Ring-Down Spectrometer (CRDS), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20831, https://doi.org/10.5194/egusphere-egu2020-20831, 2020.

EGU2020-12284 | Displays | AS5.12

Thermal dissociation cavity enhanced absorption spectrometer for detecting ANs and PNs in the atmosphere

Chunmeng Li, Keding Lu, Haichao Wang, Xiaorui Chen, Tianyu Zhai, Shiyi Chen, Xin Li, and Limin Zeng

We have developed a thermal dissociation cavity enhanced absorption spectroscopy (TD-CEAS) for in situ measurement of NO2, total peroxy nitrates (PNs) and total alkyl nitrates (ANs) in the atmosphere. The instrument uses one optical cavity for measuring NO2 absorption at 435 - 455 nm. Three channels with heating modules are set before the detecting cell in parallel, for measuring ANs, PNs and NO2 by stabilizing the temperature of 653 K, 453 K and normal, respectively. Three-channel cycle measurement is realized by dynamic switching design with the cycle time of 3 min, by assuming the air mass change is negligible when measuring on adjacent channels in each cycle. Therefore, the instrument is feasible in relative stable air masses, such as the chamber studies or field campaigns away from the emission source regions. The limit of detection (LOD) is estimated to be 97 pptv (1σ) at 6 s intervals for NO2. The measurement uncertainty of NO2 is estimated to be 8%, which mainly originates from effective cavity length, mirror reflectivity, and NO2 absorption cross section. The uncertainty of PNs and ANs measurement should be enlarged due to the sampling loss and the thermal dissociation efficiency. This instrument had been successfully applied in a field observation in China. Up to 3 ppbv PNs and ANs were observed during ozone pollution episodes. The inter-comparison of NO2 with that measured by PL-CLD, as well as PNs with that measured by GC-ECD will be presented. 

How to cite: Li, C., Lu, K., Wang, H., Chen, X., Zhai, T., Chen, S., Li, X., and Zeng, L.: Thermal dissociation cavity enhanced absorption spectrometer for detecting ANs and PNs in the atmosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12284, https://doi.org/10.5194/egusphere-egu2020-12284, 2020.

EGU2020-6561 | Displays | AS5.12

Sensitive Detection of Ambient Formaldehyde by Incoherent Broadband Cavity Enhanced Absorption Spectroscopy

Jingwei Liu, Xin Li, Yiming Yang, Haichao Wang, Cailing Kuang, Yuan Zhu, Mindong Chen, Jianlin Hu, Limin Zeng, and Yuanhang Zhang

Formaldehyde (HCHO) is the most abundant atmospheric carbonyl compound and plays an important role in the troposphere. However, HCHO detection via traditional incoherent broadband cavity enhanced absorption spectroscopy (IBBCEAS) is limited by short optical path lengths and weak light intensity. Thus, a new light-emitting diode (LED)-based IBBCEAS was developed herein to measure HCHO in ambient air. Two LEDs (325 and 340 nm) coupled by a Y-type fiber bundle were used as an IBBCEAS light source, which provided both high light intensity and a wide spectral fitting range. The reflectivity of the two cavity mirrors used herein was 0.99965 (1 – reflectivity = 350 ppm loss) at 350 nm, which corresponded with an effective optical path length of 2.15 km within a 0.84 m cavity. At an integration time of 30 s, the measurement precision (1σ) for HCHO was 380 parts per trillion volume (pptv) and the corresponding uncertainty was 8.3%. The instrument was successfully deployed for the first time in a field campaign and delivered results that correlated well with those of a commercial wet-chemical instrument based on Hantzsch fluorimetry (R2 = 0.769). The combined light source based on Y-type fiber bundle overcomes the difficulty of measuring ambient HCHO via IBBCEAS in near-ultraviolet range, which may extend IBBCEAS technology to measure other atmospheric trace gases with high precision.

How to cite: Liu, J., Li, X., Yang, Y., Wang, H., Kuang, C., Zhu, Y., Chen, M., Hu, J., Zeng, L., and Zhang, Y.: Sensitive Detection of Ambient Formaldehyde by Incoherent Broadband Cavity Enhanced Absorption Spectroscopy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6561, https://doi.org/10.5194/egusphere-egu2020-6561, 2020.

EGU2020-3857 | Displays | AS5.12

Quantitative measurement of OH radical using Faraday rotation spectroscopy at 2.8 µm

Weixiong Zhao, Bo Fang, Nana Wei, Nana Yang, Weijun Zhang, and Weidong Chen

Hydroxyl (OH) radicals play a vital role in the degradation of trace gases and pollutants in the troposphere and in controlling the atmospheric oxidation capacity. Due to its short lifetime and low concentration, interference-free high sensitivity in situ OH monitoring by laser spectroscopy represents a challenge. In this presentation, we will report the development of Faraday rotation spectroscopy (FRS) instruments operating at 2.8 µm for quantitative measurement of OH concentrations in an atmospheric simulation chamber and the total atmospheric OH reactivity (k’OH). The Q (1.5) double lines (2Π3/2 (ν=1<-0)) at 3568 cm-1 were selected for the detection. Different detection methods have been studied. The FRS technology relies on the particular magneto-optic effect observed for paramagnetic species (including most radicals and some compounds with unpaired electrons), which can significantly reduce excess laser noise and makes it capable of enhancing the detection sensitivity and mitigation of spectral interferences from diamagnetic species in the atmosphere. With the use of a multipass enhanced FRS, a detection limit of 3.2 × 106 OH/cm3 (2σ, 4s) was achieved with an absorption path length of 108 m. We demonstrated that FRS method provides a unique method for atmospheric chemistry research.

How to cite: Zhao, W., Fang, B., Wei, N., Yang, N., Zhang, W., and Chen, W.: Quantitative measurement of OH radical using Faraday rotation spectroscopy at 2.8 µm, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3857, https://doi.org/10.5194/egusphere-egu2020-3857, 2020.

EGU2020-10574 | Displays | AS5.12

Photophoresis used for measurements of light absorption by a single particle

Nir Bluvshtein and Ulrich Krieger

The contribution of light absorption by brown carbon aerosols to the Earth’s energy balance still poses a significant uncertainty in our understanding of climate forcing. As a result, one of the main open questions regarding organic aerosols in atmospheric chemistry is related to the formation and degradation of light-absorbing compounds during aging processes. Towards this goal, we explore the use of photophoresis for high sensitivity measurements of light absorption by a single levitated particle in an experimental setup that facilitates realistic atmospheric gas concentrations and aging time.

Photophoresis occurs when the surface of an illuminated, light-absorbing particle is unevenly heated relative to its surroundings. The temperature difference between the illuminated and the ‘dark’ side of the particle results in an uneven momentum transfer from colliding gas-phase molecules. This leads to a net photophoretic force, acting on the particle in the direction of the momentum transfer gradient. The photophoretic force is related to the complex refractive index of the particle and to its size parameter through the distribution of internal electric fields. As such, it may lead to a net force away from (positive) or towards (negative) the light source.

Using this phenomenon, we were able to retrieve the imaginary part of the complex refractive index (k) of a single particle levitated in an electrodynamic balance (EDB) at 473 nm wavelength. Extremely low values of k from 10-4 to 10-5 were successfully retrieved with uncertainty of less than 35% during a photo-bleaching experiment of a slightly absorbing organic particle used as a model for atmospheric brown carbon.    

An advantage of the EDB is that heterogeneous chemistry and photochemistry experiments are performed on a single particle that is levitated for days and weeks allowing for realistic atmospheric gas concentrations and aging times. In such experiments, measurements of the particle’s light absorption properties using photophoresis would add valuable information on the evolution of light absorption by the aging of organic aerosols.

A future study will implement this approach in an EDB-MS system where the EDB will be coupled with a soft ionization mass spectrometer. This will allow the identification of the molecular species responsible for light absorption as it evolves.  

How to cite: Bluvshtein, N. and Krieger, U.: Photophoresis used for measurements of light absorption by a single particle , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10574, https://doi.org/10.5194/egusphere-egu2020-10574, 2020.

We describe the continued development of a new laser heterodyne radiometry (LHR) technique:  Precision Heterodyne Oxygen-Calibration Spectrometry, or PHOCS. The prototype instrument is equipped with two active laser channels for oxygen and water (measured near 1.28 µm) and carbon dioxide (near 1.57 µm) determination. The latter may be substituted by a heterodyne receiver module equipped with a laser to monitor atmospheric methane near 1.65 µm). Oxygen measurements provide dry gas corrections and – more importantly – determine accurate temperature and pressure profiles that, in turn, improve the precision of the CO2 and H2O column retrievals. Vertical profiling is enabled by interrogating the very low-noise, absorption lines shapes collected by the O(10-3 cm-1) instrument. The presentation will describe (1) the continued development of column concertation retrieval protocols and (2) the results of initial tests performed at the Smithsonian Environmental Research Center in Edgewater, Maryland during the summer/fall of 2019 and spring of 2020.

How to cite: Miller, J. H., Flores, M., and Bomse, D.: Precision Heterodyne Oxygen-Calibration Spectrometry: Vertical Profiling of Water and Carbon Dioxide in the Troposphere and Lower Stratosphere, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18961, https://doi.org/10.5194/egusphere-egu2020-18961, 2020.

EGU2020-1254 | Displays | AS5.12

Importance of Spectroscopic Effects in Laser-based Flux Measurements

George Burba, Tyler Anderson, and Anatoly Komissarov

A significant portion of the production and consumption of trace gases (e.g. CO2, CH4, N2O, NH3, etc.) occurs in areas without sufficient infrastructure or easily available grid power to run traditional closed-path flux stations. Open-path analyzer design allows such measurements with power consumption 10-150 times below present closed-path technologies, helping to considerably expand the global coverage and improve the estimates of gas emissions and budgets, informing the remote sensing and modeling communities and policy decisions, all the way to IPCC reports. Broad-band NDIR devices have been used for open-path CO2 and H2O measurements since the late 1970s, but since recently, a growing number of new narrow-band laser-based instruments are being rapidly developed.

The new design comes with its own challenges, specifically: (i) mirror contamination, and (ii) uncontrolled air temperature, pressure and humidity, affecting both the gas density and the laser spectroscopy of the measurements. While the contamination can be addressed via automated cleaning, and density effects can be addressed via the Webb-Pearman-Leuning approach, the spectroscopic effects of the in-situ temperature, pressure and humidity fluctuations on laser-measured densities remain a standing methodological question.

Here we propose a concept accounting for such effects in the same manner as Webb et al. (1980) proposed to account for respective density effects. Derivations are provided for a general case of flux of any gas, examined using a specific example of CH4 fluxes from a commercially available analyzer, and then tested using "zero-flux" experiment.

The proposed approach helps reduce errors in open-path, enclosed, and temperature- or pressure-uncontrolled closed-path laser-based flux measurements due to the spectroscopic effects from few percent to multiple folds, leading to methodological advancement and geographical expansion of the use of such systems providing reliable and consistent results for process-level studies, remote sensing and Earth modeling applications, and GHG policy decisions.

How to cite: Burba, G., Anderson, T., and Komissarov, A.: Importance of Spectroscopic Effects in Laser-based Flux Measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1254, https://doi.org/10.5194/egusphere-egu2020-1254, 2020.

EGU2020-22368 | Displays | AS5.12

Laser heterodyne radiometers (LHR) for in situ ground-based remote sensing of greenhouse gases in the atmospheric column

Jingjing Wang, Fengjiao Shen, Tu Tan, Zhensong Cao, Xiaoming Gao, Pascal Jeseck, Yao Te, and Weidong Chen

Measurements of vertical concentration profiles of greenhouse gases (GHGs) is extremely important for our understanding of regional air quality and global climate change trends. In this context, laser heterodyne radiometer (LHR) technique has been developed [1-5] for ground-based remote measurements of GHGs in the atmospheric column.

Solar radiation undergoing absorption by multi-species in the atmosphere is coupled into a LHR instrument where the sunlight is mixed with a local oscillator (LO), being usually a tunable laser source, in a fast photodetector. Beating note at radio frequency (RF) resulted from this photomixing contains absorption information of the LO-targeted molecules. Scanning the LO frequency across the target molecular absorption lines allows one to extract the corresponding absorption features from the total absorption of the solar radiation by all molecules in the atmospheric column. Near-IR (~1.5 µm) and mid-IR (~8 µm) [6] LHRs have been recently developed in the present work. Field campaigns have been performed on the roof of the platform of IRENE in Dunkerque (51.05°N/2.34°E).

The developed LHR instruments as well as the preliminary results of their applications to the measurements of CH4, N2O, CO2 (including 13CO2/12CO2), H2O vapor (and its isotopologue HDO) in the atmospheric column will be presented and discussed.

Acknowledgments The authors thank the financial supports from the LABEX CaPPA project (ANR-10-LABX005), the MABCaM (ANR-16-CE04-0009) and the MULTIPAS (ANR-16-CE04-0012) contracts, as well as the CPER CLIMIBIO program. S. F. thanks the program Labex CaPPA and the "Pôle Métropolitain de la Côte d’Opale" (PMCO) for the PhD fellowship support.

References

[1] R. T. Menzies, and R. K. Seals, Science 197 (1977) 1275-1277

[2] D. Weidmann, T. Tsai, N. A. Macleod, and G. Wysocki, Opt. Lett. 36 (2011) 1951-1953

[3] E. L. Wilson, M. L. McLinden, and J. H. Miller, Appl. Phys. B 114 (2014) 385-393

[4] A. Rodin, A. Klimchuk, A. Nadezhdinskiy, D. Churbanov, and M. Spiridonov, Opt. Express 22 (2014) 13825-13834

[5] J. Wang, G. Wang, T. Tan, G. Zhu, C. Sun, Z. CAO, W. Chen, and X. Gao, Opt. Express 27 (2019) 9600-9619

[6] F. Shen, P. Jeseck, Y. Te, T. Tan, X. Gao, E. Fertein, and W. Chen, Geophys. Res. Abstracts, 20 (2018) EGU2018-79

How to cite: Wang, J., Shen, F., Tan, T., Cao, Z., Gao, X., Jeseck, P., Te, Y., and Chen, W.: Laser heterodyne radiometers (LHR) for in situ ground-based remote sensing of greenhouse gases in the atmospheric column, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22368, https://doi.org/10.5194/egusphere-egu2020-22368, 2020.

EGU2020-6294 | Displays | AS5.12

Water vapor isotopic abundance measurement in Tibetan Plateau based on portable laser heterodyne radiometer

Xingji Lu, Jun Huang, Zhensong Cao, Yinbo Huang, Dandan Liu, Tu Tan, and Ruizhong Rao

Tibet Plateau is known as the third pole of the world, the environmental changing in this area profoundly impacts on east Asian or even global climate. HDO is the stable isotope of water vapor and is the ideal tracer of water cycle, which has been applied to atmospheric circulation and climatic studies. For monitoring the water vapor isotopic abundance in Tibetan Plateau and providing reliable information for environmental and climatic studies, a portable laser heterodyne radiometer was operated at Golmud (Qinghai Province) in summer 2019. The radiometer adopted a narrow linewidth 3.66 μm DFB laser as the local oscillator and performed high resolution(~0.009 cm-1) and high signal-to-noise ratio(~160). Furthermore, the absorption spectra of atmospheric HDO and H2O were obtained and the retrieval algorithm of water vapor isotopic abundance was discussed. The optimal estimation method based on LBLRTM was chosen for retrieving, the ratio of HDO/H2O at Golmud is 185±7×10-6 during the observation, the value is less than the Vienna Standard Mean Ocean Water (VSMO, 311.5×10-6) but larger than Standard Light Antarctic Precipitation (SLAP, 178.2×10-6).

How to cite: Lu, X., Huang, J., Cao, Z., Huang, Y., Liu, D., Tan, T., and Rao, R.: Water vapor isotopic abundance measurement in Tibetan Plateau based on portable laser heterodyne radiometer, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6294, https://doi.org/10.5194/egusphere-egu2020-6294, 2020.

EGU2020-4213 | Displays | AS5.12

Prism-based Broadband Optical Cavity (400 – 1600 nm) for High-Sensitivity Trace Gas Sensing by Cavity Enhanced Absorption Spectroscopy

Weidong Chen, Gaoxuan Wang, Lingshuo Meng, Qian Gou, Azer Yalin, Tong Nguyen Ba, Cécile Coeur, and Alexandre Tomas

The use of high reflectivity dielectric mirrors to form a high finesse optical cavity allows one to achieve long optical path lengths of up to several kilometres for high-sensitivity spectroscopy applications [1]. However, the high reflectivity of a dielectric mirror is achieved via constructive interference of the Fresnel reflection at the interfaces produced by multilayer coatings of alternate high and low refractive index materials. This wavelength-dependent coating limits the bandwidth of the mirror's high reflectivity to only a few percent of the designed central wavelength [2].

In this paper, we report on the development of a novel optical cavity based on prism used as cavity reflector through total internal reflection combined with Brewster angle incidence [3], which offers a high-finesse optical cavity operating in a broadband wavelength region from 400 to longer than 1600 nm. Cavity Enhanced Absorption Spectroscopy (CEAS) of NO2, NO3, and H2O vapor was applied to determine the achieved prism reflectivity over a broad spectral range from 400 nm to 1600 nm.

Experimental details and preliminary results will be presented. The developed prism-based cavity is specifically adapted for the needs of broadband measurement of multi-molecular absorber or/and wavelength-dependent extinction coefficient of aerosols over a broad spectral region.

Acknowledgments. This work is supported by the French national research agency (ANR) under the CaPPA (ANR-10-LABX-005), the MABCaM (ANR-16-CE04-0009) and the MULTIPAS (ANR-16-CE04-0012) contracts. The authors thank the financial support from the CPER CLIMIBIO program.

REFERENCES

[1] S. S. Brown, "Absorption spectroscopy in high-finesse cavities for atmospheric studies", Chem. Rev. 103 (2003) 5219-5238.

[2] G.R. Fowles, Introduction to Modern Optics, 2nd ed. (Rinehart and Winston, 1975), p. 328.

[3] B. Lee, K. Lehmann, J. Taylor and A. Yalin, "A high-finesse broadband optical cavity using calcium fluoride prism retroreflectors", Opt. Express 22 (2014) 11583-11591.

How to cite: Chen, W., Wang, G., Meng, L., Gou, Q., Yalin, A., Nguyen Ba, T., Coeur, C., and Tomas, A.: Prism-based Broadband Optical Cavity (400 – 1600 nm) for High-Sensitivity Trace Gas Sensing by Cavity Enhanced Absorption Spectroscopy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4213, https://doi.org/10.5194/egusphere-egu2020-4213, 2020.

EGU2020-10923 | Displays | AS5.12

Mid-IR Laser Spectrometer for Balloon-borne Lower Stratospheric Water Vapor Measurements

Manuel Graf, Philipp Scheidegger, Herbert Looser, André Kupferschmid, Thomas Peter, Lukas Emmenegger, and Béla Tuzson

Water vapor is the dominant greenhouse gas, and its abundance in the upper tropospheric/lower stratospheric region (UTLS, 8-25 km altitude) is of great importance to the Earth's radiative balance. Reliable predictions of the climate evolution as well as the understanding of cloud-microphysical processes require the accurate and frequent measurement of water vapor concentrations at these altitudes. The only established method for high-accuracy UTLS water vapor measurements aboard of meteorological balloons is cryogenic frost-point hygrometry (CFH). However, the cooling agent required for its operation (CHF3) is to be phased out due to its strong global warming potential. It is, therefore, a major, worldwide challenge to ensure the continuation of the observation of this key Environmental Climate Variable (ECV) of the World Meteorological Organization (WMO). As an alternative method, we present a compact and lightweight instrument based on quantum cascade laser absorption spectroscopy (QCLAS) that reduces systematic errors by contactless and contamination-minimized measurements. Its construction addresses the stringent constraints posed by the harsh environmental conditions found in the UTLS. This is achieved by a fundamental reconsideration of main components of the spectrometer. We developed a highly versatile segmented circular multipass cell (SC-MPC) which supports compact and well-controlled beam folding [1]. The SC-MPC consists of a monolithic aluminum ring with 10.8 cm inner radius, containing 57 quadratic, spherically curved segments, seamlessly shaped into the internal ring surface. The collimated mid-IR beam (λ = 6 µm) from the distributed feedback quantum cascade laser (DFB-QCL) is directly coupled to the MPC without the need for additional beam-shaping optics. This leads to a resilient optical setup suitable for mobile applications and rough environmental conditions. Water vapor amount fractions of <10 ppmv can be measured with a precision better than 1% at 1 Hz. Measuring in open-path mode ensures quick response and minimal interference by water desorbing from surfaces. The instrument weighs less than 4 kg (including battery) and has an average power consumption of 15 W. An elaborate thermal management system that comprises phase change materials and thermoelectric cooling ensures excellent internal temperature stability despite an outside temperature difference of up to 80 K. Specifically developed hard- and software guarantee autonomous operation for the duration of flight [2]. Extensive stability assessments in climate chambers as well as validation experiments using dynamically generated, SI-traceable water vapor mixtures were performed in collaboration with the Swiss Federal Institute of Metrology (METAS). In cooperation with the German Weather Service (DWD) in Lindenberg, the instrument was successfully tested and compared to CFH in two consecutive balloon-ascents in December 2019 up to 28 km altitude, experiencing temperatures and pressures as low as –65°C and 16 hPa, respectively. The drastic reduction in mass and size of a laser absorption-spectrometer and its successful deployment under harshest conditions represents a paradigm change in portable laser spectroscopy and opens the door to previously inaccessible applications.

[1] Graf, M.; Emmenegger, L.; Tuzson, B. Opt. Lett. 2018, 43, 2434-2437

[2] Liu, C. et al., L. Rev. Sci. Instrum. 2018, 89 (6), 065107 (9 pp.)

How to cite: Graf, M., Scheidegger, P., Looser, H., Kupferschmid, A., Peter, T., Emmenegger, L., and Tuzson, B.: Mid-IR Laser Spectrometer for Balloon-borne Lower Stratospheric Water Vapor Measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10923, https://doi.org/10.5194/egusphere-egu2020-10923, 2020.

We described an open-path cavity enhanced absorption spectroscopy (OP-CEAS) technique for ambient measurement of nitrate radical (NO3) near 662 nm. Compared with the close type CEAS system with a sampling line, the OP-CEAS is featured with high accuracy due to free of quantifying NO3 loss in the sampling line and cavity. Based on a 0.84 m long open path cavity, the effective absorption length of ~5 kilometers is achieved by a coupled high reflectivity mirrors with the reflectivity of 0.99985 at 662 nm. The detection limit of OP-CEAS for NO3 measurement is 3.0 pptv (2σ) in 30 seconds. The uncertainty is 11.2% and dominated by the cross section of NO3. The instrument was successfully applied in a field measurement at low particulate matter (PM) loading condition. As the sensitive would be decreased due to the strong PM extinctions under heavy PM pollution condition, we highlight the feasibility of this OP-CEAS configuration in the field application under the low PM condition, such as the forest region affected by anthropogenic emissions. This technique also appropriates to be expended in the field detection of other reactive trace gases in future studies.

How to cite: Wang, H. and Lu, K.: Monitoring Ambient Nitrate Radical by Open Path Cavity Enhanced Absorption Spectroscopy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18725, https://doi.org/10.5194/egusphere-egu2020-18725, 2020.

EGU2020-22371 | Displays | AS5.12

High-sensitivity measurement of OH radicals using multi-pass enhanced Faraday Rotation Spectroscopy

Tong Nguyen Ba, Weixiong Zhao, Jiajin Chen, Kun Liu, Xiaoming Gao, Eric Fertein, and Weidong Chen

The hydroxyl radical (OH) is considered as a primary agent responsible to remove a majority of trace gas in the atmosphere [1]. It is also responsible to initiate the reactions leading to the formation of a wide range of secondary species such as ozone (O3) and secondary organic aerosols (SOAs) [2]. Reliable and real-time assessment of the OH radical concentration change and related chemical process in the atmosphere is a key factor to understand and determinate the oxidation capacity of the atmosphere. Because of its very high reactivity, very short lifetime (≤ 1 s) associated with very low atmospheric concentration (~106 OH/cm3), the development of optical instrument allowing accurate, interference-free and ultra-high sensitivity in-situ direct measurement of OH concentration presents a great challenge for atmospheric science and climate change research.We report in this paper our recent development of an OH sensor based on Faraday Rotation Spectroscopy (FRS) [3]. FRS exploits magnetic circular birefringence (MCB) observed in the vicinity of Zeeman split absorption line of paramagnetic species such as O2, NO, NO2, OH. The Q(1,5e) and Q(1,5f) double lines of OH at 3568,52 cm-1 and 3568,41 cm-1 were chosen for quantification of OH radicals [4,5]. In order to enhance the detection sensitivity, multi-pass absorption approach was coupled to FRS. A 1σ (SNR=1) detection limit of about 5×107 OH/cm3 was achieved.

The experimental detail and the preliminary results will be presented and discussed. 

Acknowledgments

The authors thank the financial supports from the CPER CLIMIBIO program and the Labex CaPPA project (ANR-10-LABX005).

 References

[1] D.E. Heard, M.J. Pilling, Chem. Rev. 103 (2003) 5163-5198.

[2] D. Stone, L.K. Whalley, and D.E. Heard, Chem. Soc. Rev. 41 (2012) 6348-6404.

[3] G. Litfin, C.R. Pollock, R.F. Curl, F.K. Tittel, J. Chem. Phys. 72 (1980) 6602-6605.

[4] W. Zhao, G. Wysocki, W. Chen, et al., Opt. Express 19, (2011) 2493-2501.

[5] W. Zhao, G. Wysocki, W. Chen, W. Zhang, Appl. Phys. B 109 (2012) 511-519.

How to cite: Nguyen Ba, T., Zhao, W., Chen, J., Liu, K., Gao, X., Fertein, E., and Chen, W.: High-sensitivity measurement of OH radicals using multi-pass enhanced Faraday Rotation Spectroscopy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22371, https://doi.org/10.5194/egusphere-egu2020-22371, 2020.

EGU2020-6306 | Displays | AS5.12

The Measurement of Nitrophenols by Integrated Spectrum and TD-IBBCEAS

Meng Wang, Jun Chen, Shengrong Lou, and Dean Venables

Atmospheric Brown Carbon (BrC) is an important component of aerosol particles that Influences the climate through interactions with incoming solar and emitted terrestrial radiation. BrC can be generated from a variety of primary emissions (such as traffic, coal combustion, biomass burning) and secondary formation. Nitrophenols are classified as Brown Carbon due to their strong absorption in near-ultraviolet and visible regions.

A heated single path absorption spectroscopy system is been built to measure the cross section of nitrophenols. Due to its semi-volatility, the nitrophenols were introduced into the cell by N2. The cross section of nitrophenols is obtained by calculating the integrated absorption.

A Thermal Decomposition - Incoherent Broadband Cavity-Enhanced Absorption Spectroscopy (TD-IBBCEAS) system was setup for atmospheric measurement. This instrument covered the spectral region from 320 to 440nm which could contain the interested absorption of nitrophenols. A thermal decomposition device was used to heating the sample.  The system was characterized based in laboratory experiment.

How to cite: Wang, M., Chen, J., Lou, S., and Venables, D.: The Measurement of Nitrophenols by Integrated Spectrum and TD-IBBCEAS, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6306, https://doi.org/10.5194/egusphere-egu2020-6306, 2020.

EGU2020-1861 | Displays | AS5.12

Aerosol optical absorption and spectral dependence measurement with photoacoustic spectroscopy

Yuan Cao, Kun Liu, Weidong Chen, and Xiaoming Gao

Light-absorbing carbonaceous aerosols mainly generated from the combustion of biomass and fossil fuels, play an important role in the global environment [1]. Multi-wavelength in-situ measurement of carbonaceous aerosol optical absorption is important both for reduce errors in assessing radiative forcing and component identification or source appointment of aerosols (such as biomass burning and diesel soot) with absorption Ångström exponent (AAE) [2]. A differential photoacoustic spectrometer (PAS) using a 438 nm laser diode was developed for simultaneously measure the aerosol optical absorption coefficient and the concentration of NO2. In order to evaluate the reliability of the differential photoacoustic spectrometer, we compared the NO2 concentration measured by PAS with the data from environmental monitoring station and showed good consistency. In the actual atmospheric measurement process, we observed a good correlation between the light absorption characteristics of aerosols and the concentration of NO2 within a certain time range. In addition, a novel multi-wavelength photoacoustic spectrometer (MW-PAS) was developed to measure the aerosol optical absorption coefficients and its wavelength-dependent characteristics in the UV-VIS-NIR bands (405, 638, 808 nm). The performance of MW-PAS was evaluated by measuring the light absorption characteristics of kerosene soot aerosol. The measurement results are agreed with the results reported in literatures [3].

 

Reference

[1] J.G. Radney, R. You, M.R. Zachariah, C.D. Zangmeister, Direct in-situ mass specific absorption spectra of biomass burning particles generated from smoldering hard and softwoods. Environ. Sci. Technol. 51, 5622-5629 (2017)

[2] T. Ajtai, N. Utry, M. Pintér, B. Major, G. Szabó, A method for segregating the optical absorption properties and the mass concentration of winter time urban aerosol. Atmos. Environ.122, 313-320 (2015)

[3] M. Gyawali, W.P. Arnott, R.A. Zaveri, C. Song, H. Moosmüller, L. Liu, M.I. Mishchenko, L.-W.A. Chen, M.C. Green, J.G. Watson, and J.C. Chow, Photoacoustic optical properties at UV, VIS, and near IR wavelengths for laboratory generated and winter time ambient urban aerosols. Atmos. Chem. Phys. 12, 2587-2601 (2012)

How to cite: Cao, Y., Liu, K., Chen, W., and Gao, X.: Aerosol optical absorption and spectral dependence measurement with photoacoustic spectroscopy, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1861, https://doi.org/10.5194/egusphere-egu2020-1861, 2020.

EGU2020-2932 | Displays | AS5.12

Calibration of Photoacoustic Spectrometers at Reduced Pressure Using Aerosols or Ozone-Laden Gas

Michael Cotterell, Kate Szpek, David Tiddeman, Jim Haywood, and Justin Langridge

The scattering and absorption of light by atmospheric aerosols are constrained poorly in climate models. In particular, there is large uncertainty in aerosol light absorption arising from a lack of accurate measurements for absorbing aerosols. Photoacoustic spectroscopy (PAS) is the technique of choice for contact-free light absorption measurements by aerosol particles. In PAS instruments, the light intensity of a laser source is modulated periodically at typical frequencies in the range 1 – 2 kHz and the light absorbing species of interest absorbs energy from this modulated light. The absorbed energy is subsequently transferred to translational degrees-of-freedom of the surrounding bath gas through collisional relaxation and generates an acoustic pressure wave that is detected by a sensitive microphone. The recorded amplitude of the microphone response is related directly to the sample absorption coefficient, while the phase shift of the microphone response with respect to the laser power modulation provides information on the timescale for energy transfer to the bath gas.

Recent years have seen PAS instruments deployed in the field on aircraft measurement platforms. These airborne studies facilitate spatially-resolved measurements of aerosol light absorption, including with variation in altitude. The accuracy of the resulting aerosol absorption measurements depends chiefly on the calibration of the PAS microphone response. Moreover, this calibration for microphone response varies with pressure, with an increased sample pressure dampening the microphone membrane motion to a greater extent. This pressure-dependent microphone sensitivity is particularly pertinent to measurements from aircraft platforms that sample at varying pressures typically over the range 400 – 1000 mbar. Largely, field instruments have used ozone-laden gas to calibrate PAS instruments operating at visible wavelengths, and repeated this calibration for several values of absolute pressure.

In this contribution, we report photoacoustic amplitude and phase shift measurements which demonstrate ozone-laden gas is a poor calibrant of PAS instruments operating at visible wavelengths and at pressures reduced from those at ambient conditions (~1000 mbar). The nascent photodissociation products following photoexcitation of O3 do not liberate their energy to the surrounding bath gas on a fast timescale compared to the photoacoustic modulation frequency regardless of the bath gas composition. Instead, we show that the PAS instrument can be calibrated at ambient pressure and then a miniature speaker can be used to excite an acoustic response for calibrating the pressure sensitivity in the microphone response. In this way, we show that we accurately measure aerosol absorption at reduced pressure for sub-micrometre diameter aerosols consisting of dyed polystyrene latex spheres or nigrosin dye. These results will be of utmost interest to those measuring aerosol absorption using PAS from airborne platforms or those calibrating PAS instruments for ground based or laboratory measurements.

How to cite: Cotterell, M., Szpek, K., Tiddeman, D., Haywood, J., and Langridge, J.: Calibration of Photoacoustic Spectrometers at Reduced Pressure Using Aerosols or Ozone-Laden Gas, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2932, https://doi.org/10.5194/egusphere-egu2020-2932, 2020.

Atmospheric aerosols influence radiative forcing through interaction with solar radiation and indirectly by acting as cloud condensation nuclei and have a negative impact on air quality especially in urban scenarios. With socio-economic models suggesting that in a growing global population, 70% of the humans will live in urban areas by 2050, the adverse impact on urban air quality is a prominent societal and health issue, expected to become more and more severe in the future. In order to introduce effective mitigation strategies and monitor their effect, the state and characteristics of pollution need to be characterized and main sources identified. Offline-analysis of particulate matter (PM) collected on filter samples offers such insight. However, PM chemical composition is highly complex, and its comprehensive characterization and quantification requires advanced instrumentation and data analysis techniques and strategies.

Here, we present the development and application of a novel analytical nondestructive method. We acquired Fourier-transform infrared spectroscopy (FTIR) spectra of ambient PM collected on Teflon filters at various locations in Italy. FTIR allows to obtain high-resolution spectral data non-destructively and therefore to detect and quantify functional groups of organic and inorganic species present in the aerosol PM. The spectral dataset was analyzed by applying partial least squares regression (PLS regression) methods in order to allow quantification of ammonium, sulphate and nitrate ionic PM components. This statistical method allowed to disentangle the inner complexity of the PM sample and to train a statistical model for each of the three ionic species. In our conference contribution, the so developed models are discussed and compared with the more traditional analytical method, ionic chromatography (IC).

 

References:

Cuccia, et al. (2011). Atmospheric Environment, 45(35), 6481–6487. https://doi.org/10.1016/j.atmosenv.2011.08.004

Piazzalunga, A., et al. (2013). Analytical and Bioanalytical Chemistry, 405(2–3), 1123–1132. https://doi.org/10.1007/s00216-012-6433-5

Russell, L. M., et al. (2009). Atmospheric Environment, 43(38), 6100–6105. https://doi.org/10.1016/j.atmosenv.2009.09.036

How to cite: Molteni, U., Piazzalunga, A., and Fermo, P.: Non-destructive method based on infrared spectroscopy and partial least square regression for the quantification of the ionic component of atmospheric particulate matter, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16412, https://doi.org/10.5194/egusphere-egu2020-16412, 2020.

EGU2020-7278 | Displays | AS5.12

Experimental evidence of the lensing effect suppression for atmospheric black carbon containing brown coatings

Vaios Moschos, Martin Gysel-Beer, Robin L. Modini, Joel C. Corbin, Dario Massabò, Camilla Costa, Silvia G. Danelli, Athanasia Vlachou, Kaspar R. Daellenbach, Paolo Prati, André S.H. Prévôt, Urs Baltensperger, and Imad El Haddad

Accounting for the wavelength- and source-dependent optical absorption properties of the abundant light-absorbing organic (brown) carbon (BrC) and the mixing state of atmospheric black carbon (BC) are essential to reduce the large uncertainty in aerosol radiative forcing. Estimation of BrC absorption online by subtraction is highly uncertain and may be biased if not decoupled from the potential BC absorption enhancement (lensing) due to non-refractory (organic and inorganic) coating acquisition.

Here, the reported total particulate absorption is based on long-term, filter-based seven-wavelength Aethalometer (AE33 model) data, corrected for multiple scattering effects with Multi-Wavelength Absorbance Analyzer (5λ MWAA) measurements. Using ultraviolet-visible spectroscopy absorbance measurements along with particle size distributions obtained by a scanning mobility particle sizer, we have conducted Mie calculations to assess the importance of source-specific extractable particulate BrC (Moschos et al., 2018) versus BC absorption.

For the species-specific optical closure, the wavelength dependence of bare BC absorption is estimated using MWAA measurements upon successive filter extractions to remove the influence of BrC/coatings. The lensing contribution, supported by observations from field-emission scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy, is estimated at longer wavelengths using a refined proxy for the BC coating thickness. The approach is validated independently by applying a novel positive matrix factorization-based approach on the calibrated total AE33 absorption data.

Based on the observational constraints established in this study, we demonstrate for various distinct case studies that the interplay between lensing and BrC absorption results in lower than expected BC absorption at shorter wavelengths. This indicates that the volume additivity assumption is not valid for particulate absorption by internally mixed heterogeneous atmospheric aerosol populations. These comprehensive experimental analyses verify the BC lensing suppression predicted for simplified core-shell structures containing moderately absorbing BrC (Lack & Cappa, 2010). The implications discussed in this work are relevant for co-emitted species from biomass burning or aged plumes with high BrC to BC mass/absorption ratio.

 

References

Moschos, V., Kumar, N. K., Daellenbach, K. R., Baltensperger, U., Prévôt, A. S. H., and El Haddad, I.: Source apportionment of brown carbon absorption by coupling ultraviolet-visible spectroscopy with aerosol mass spectrometry, Environ. Sci. Tech. Lett., 5, 302-308, https://doi.org/10.1021/acs.estlett.8b00118, 2018.

Lack, D. A. and Cappa, C. D.: Impact of brown and clear carbon on light absorption enhancement, single scatter albedo and absorption wavelength dependence of black carbon, Atmos. Chem. Phys., 10, 4207–4220, https://doi.org/10.5194/acp-10-4207-2010, 2010.

How to cite: Moschos, V., Gysel-Beer, M., Modini, R. L., Corbin, J. C., Massabò, D., Costa, C., Danelli, S. G., Vlachou, A., Daellenbach, K. R., Prati, P., Prévôt, A. S. H., Baltensperger, U., and El Haddad, I.: Experimental evidence of the lensing effect suppression for atmospheric black carbon containing brown coatings, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7278, https://doi.org/10.5194/egusphere-egu2020-7278, 2020.

Climate models which predict the Earth’s temperature and which are a basis for estimating climate change have large uncertainties induced by the lack of understanding of aerosol effects. Polarimetry is the most promising technique to gain information about aerosols and to understand their effect on the climate.

The airborne multispectral sunphotometer and polarimeter (AMSSP) can measure complete polarization information, including circular polarization for the visible spectral range. The transformation of intensity measurements measured by the AMSSP to polarization information is only possible with a sufficient calibration of the instrument. Laboratory calibration measurements resulted in calibration parameters that convert the intensity measurements to accurate polarization information with only small deviations.

On the basis of recent experiences during a previous field campaign, an improved ground-based polarimeter is going to be developed. A Pan-Tilt tracking system allows direct measurements of the sun which enables the optimization of the relative adjustments of the optical paths. The ground-based system allows a flexible measurement geometry within the upper hemisphere without additional mirrors. With this, the impact and uncertainty of the previously used mirror sytsem are eliminated. In addition, it is planned to optimize the optical components of the polarimeter.

The new setup will be tested during the measurement campaign ASKOS in Cape Verde in summer 2020.

 

 

How to cite: Jänicke, L. and Ruhtz, T.: Advancement of the AMSSP for Ground-Based Measurements of the Complete Stokes Vector , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4955, https://doi.org/10.5194/egusphere-egu2020-4955, 2020.

 

Anusanth Anantharajaha, Fridolin Kwabia Tchanaa, Jean-Marie Flauda , Pascale Royb and Laurent Manceronb,c

  • a- Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), UMR CNRS 7583,
    Université de Paris et Université Paris-Est Créteil, Institut Pierre Simon Laplace,
    61 Avenue du Général de Gaulle, 94010 Créteil Cedex, France.
  • b- Synchrotron SOLEIL, AILES Beamline, L’Orme des Merisiers, Saint-Aubin F-91192, France.
  • c-  Sorbonne Université, CNRS, MONARIS, UMR 8233, 4 place Jussieu, F-75005 Paris, France. 

 

Nitryl chloride (ClNO2) and Chlorine Nitrate are molecules of great interest for atmospheric chemistry since these are produced by heterogeneous reactions, in the marine troposphere, between NaCl sea-salt aerosols or ClO and gaseous N2O5 [1,2], and on polar stratospheric clouds, between N2O5 and solid HCl [3,4].

 

Many high-resolution spectroscopic studies in the microwave and mid-infrared regions are available. However, these molecules present low-lying vibrational levels and thus numerous hot bands in the regions of the NOx stretching and bending mode absorptions in the 8-12 µm atmospheric transparency window which could serve for remote sensing and quantification of these species.

Fourier Transform Spectrometry is a useful technique to observe broad band high resolution spectra (0.001 cm-1) of these molecules and a significant advantage is gained by combining interferometry with the high brightness of a synchrotron source [5]. At SOLEIL we have developed specific instrumentation to study such reactive molecules and a few results concerning chlorine-containing compounds will be presented.

  1. B. J. Finlayson-Pitts, M. J. Ezell, and J. N. Pitts Jr, Nature 337, 241-244 (1989).
  2. W. Behnke, V. Scheer, and C. Zetzsch, J. Aerosol Sci. 24, 115-116 (1993).
  3. . M. A. Tolbert, M. J. Rossi, and D. M. Golden, Science 240, 1018-1021 (1988).
  4. M. T. Leu, Geophys. Res. Lett. 15, 851-854 (1988).
  5.  J-M. Flaud, A. Anantharajah, F. Kwabia Tchana, L. Manceron, J. Orphal, G. Wagner, and M. Birk, J Quant Spectrosc Radiat Transf 224, 217-221 (2019).

 

How to cite: Manceron, L.: Synchrotron radiation and long path cryogenic cells: New tools and results for modelling chlorinated compounds absorption in the 8-12µm atmospheric window, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8639, https://doi.org/10.5194/egusphere-egu2020-8639, 2020.

EGU2020-17199 | Displays | AS5.12

ANIR, a tool for analysis of Infrared spectra

Mila Ródenas, Bénédicte Picquet-Varrault, and Amalia Munoz

AS5.13 – MAX-DOAS and other scattered light DOAS systems: instruments, techniques and applications

EGU2020-14832 | Displays | AS5.13

Spatial and temporal distributions of NO2 and aerosols over the urban environment of Vienna during the VINDOBONA project (2017-2019)

Stefan Schreier, Andreas Richter, Tim Bösch, Kezia Lange, Michael Revesz, Andreas Hilboll, Enno Peters, Mihalis Vrekoussis, Philipp Weihs, Alois Schmalwieser, and John Burrows

Within the scope of the VINDOBONA (VIenna horizontal aNd vertical Distribution OBservations Of Nitrogen dioxide and Aerosols) project, spectral UV/vis measurements at selected viewing directions are performed with three MAX-DOAS (Multi AXis Differential Optical Absorption Spectroscopy) instruments, which are located in the northeast, northwest, and south of the city center of Vienna, Austria. The selection of viewing directions of the three instruments was chosen in a way to provide data for the retrieval of horizontal and vertical trace gas and aerosol distributions, in particular over the urban core.

In the present work, the profile retrieval algorithm BOREAS (Bremen Optimal estimation REtrieval for Aerosols and trace gaseS) is used to retrieve aerosol and NO2 vertical profiles as well as accompanying parameters aerosol optical depth, tropospheric NO2 vertical columns (TVC NO2), and near-surface NO2 on days with cloudless conditions. The retrieval results are compared with co-located ceilometer, sun photometer, surface air quality, and TVC NO2 measurements, with the latter being obtained by applying the geometrical approximation and converting zenith-sky NO2 measurements.

How to cite: Schreier, S., Richter, A., Bösch, T., Lange, K., Revesz, M., Hilboll, A., Peters, E., Vrekoussis, M., Weihs, P., Schmalwieser, A., and Burrows, J.: Spatial and temporal distributions of NO2 and aerosols over the urban environment of Vienna during the VINDOBONA project (2017-2019), EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14832, https://doi.org/10.5194/egusphere-egu2020-14832, 2020.

EGU2020-20558 | Displays | AS5.13

Title: Urban air pollution monitoring at micro-, local and meso- scales using Pandora instrument

Elena Spinei, Jeffrey Geddes, Taylor Adams, Moritz Müller, and Manuel Gebetsberger

Increasing urbanization worldwide raise serious concerns about urban air quality and its effects on large human populations. This study presents application of the Differential Optical Absorption Spectroscopy technique to multi scale urban air quality (NO2) monitoring. A Pandora spectroscopic instrument (SciGlob Inc) has been deployed on top of a 30 m building in Boston, MA, USA, since September 2019. It performs over the roof sky scans (local to meso scales), into the street canyon "target" (micro-scale), and direct sun measurements. In situ NO2 measurements are also being conducted on top of the roof (co-located with Pandora) and at the street level near the "target" building. NO2 spatial and temporal heterogeneity within different scales is discussed.

How to cite: Spinei, E., Geddes, J., Adams, T., Müller, M., and Gebetsberger, M.: Title: Urban air pollution monitoring at micro-, local and meso- scales using Pandora instrument, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20558, https://doi.org/10.5194/egusphere-egu2020-20558, 2020.

EGU2020-1464 | Displays | AS5.13

Estimating real driving emissions from MAX-DOAS measurements at the A60 motorway near Mainz

Bianca Lauster, Steffen Dörner, Sebastian Donner, Katharina Uhlmannsiek, Sergey Gromov, Steffen Beirle, and Thomas Wagner

Nitrogen oxides (NOx = NO + NO2) have a direct and indirect impact on human health. Therefore, the World Health Organization recommends limiting the concentration of nitrogen dioxide (NO2) in the atmosphere. Nevertheless, these limits are regularly exceeded. Especially, fossil fuel combustion from road traffic is a major contributor to the emission of NOx.

Multi Axis-Differential Optical Absorption Spectroscopy (MAX-DOAS) is able to measure trace gases in the lower troposphere. Here, this remote sensing method was used to measure NOx emissions at a highly frequented motorway. Two MAX-DOAS instruments were set up on both sides of the A60 motorway close to Mainz, Germany. The parallel viewing direction allows measuring the background signal at the upwind side and the background plus traffic emissions on the downwind side. Together with the effective wind speed perpendicular to the motorway, it is thus possible to retrieve the total traffic emissions. Compared to the expected emissions calculated from the European emission standards, the derived emissions of NOx are by a factor 7±4 higher.

In this study, first measurement results are presented and the method is evaluated with regard to the practicability and error margin.

How to cite: Lauster, B., Dörner, S., Donner, S., Uhlmannsiek, K., Gromov, S., Beirle, S., and Wagner, T.: Estimating real driving emissions from MAX-DOAS measurements at the A60 motorway near Mainz, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1464, https://doi.org/10.5194/egusphere-egu2020-1464, 2020.

Oxygen-oxygen collision induced absorption accounts for significant absorption of solar radiation in the atmosphere. It needs to be considered in the interpretation of spectra in absorption spectroscopy. If not represented correctly, it interferes in the retrieval of other trace gases. Quantitative measurements of oxygen-oxygen collision induced absorption, combined with the oxygen concentration vertical profile, allow to constrain radiative transfer processes in the atmosphere. No spectrally resolved cross section data of the bands below 335 nm wavelength and at 420 nm have been available. This study presents spectrally resolved gas-phase laboratory measurements of the oxygen-oxygen collision induced absorption in the ultraviolet and blue spectral range (308 – 495 nm), including the 315, 328, and 421 nm bands, acquired with Cavity Enhanced Absorption Spectroscopy under atmospherically relevant conditions. While the newly acquired data generally agree with existing data on the strong bands, significant differences consist in a higher signal to noise ratio, a non-zero baseline between bands, and a different band shape of the 344 nm band. This presentation discusses the laboratory setup and analysis scheme used to determine the cross section, and first applications of the cross section to atmospheric data sets.

How to cite: Finkenzeller, H. and Volkamer, R.: Spectrally resolved laboratory measurements of oxygen-oxygen collision induced absorption in the 308 – 495 nm range, including the 315, 328, and 421 nm bands, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10089, https://doi.org/10.5194/egusphere-egu2020-10089, 2020.

EGU2020-10182 | Displays | AS5.13

The information content of skylight polarisation in MAX-DOAS trace gas and aerosol profiling applications

Jan-Lukas Tirpitz, Udo Frieß, and Ulrich Platt

Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) is a well-established ground-based measurement technique for the detection of atmospheric aerosol and trace gases: ultra-violet and visible radiation spectra of skylight are analyzed to obtain information on different atmospheric parameters. An appropriate set of spectra recorded under different viewing geometries ("Multi-Axis") allows retrieval of aerosol and trace gas vertical distributions by applying numerical inversion methods. Currently one of the method’s major limitations is the limited information content in the measurements that reduces the sensitivity particularly at higher altitudes.

It is well known but not yet used in MAX-DOAS profile retrievals that measuring skylight of different polarisation directions provides additional information: the degree of polarisation for instance strongly depends on the atmospheric aerosol content and the aerosol properties and – since the light path (?) differs for light of different polarisation -  the set of geometries available for the inversion is extended. We present a novel polarization-sensitive MAX-DOAS instrument and a corresponding inversion algorithm, capable of using polarization information. Further, in contrast to existing MAX-DOAS algorithms consisting of separate aerosol and trace gas retrieval modules, our novel inversion scheme simultaneously retrieves aerosol and trace gas profiles of several species in a single step. The improvement over “unpolarised” MAX-DOAS approaches will be discussed, based on both, synthetic data and real measurements.

How to cite: Tirpitz, J.-L., Frieß, U., and Platt, U.: The information content of skylight polarisation in MAX-DOAS trace gas and aerosol profiling applications, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10182, https://doi.org/10.5194/egusphere-egu2020-10182, 2020.

EGU2020-19148 | Displays | AS5.13

ESA FRM4DOAS: Towards the launch of the NDACC MAX-DOAS Central Processing Service

Francois Hendrick, Caroline Fayt, Martina M. Friedrich, Steffen Beirle, Udo Frieẞ, Andreas Richter, Tim Bösch, Karin Kreher, Ankie Piters, Thomas Wagner, Jan-Lukas Tirpitz, Alkis Bais, Cristina Prados Roman, Olga Puentedura, Alexander Cede, Elena Lind, Angelika Dehn, Jonas von Bismarck, Stefano Casadio, and Michel Van Roozendael

Since it provides vertically-resolved information on atmospheric gases at a horizontal scale approaching the one from nadir backscatter satellite sensors, the ground-based MAX-DOAS technique has been recognized as a valuable source of correlative data for validating space-borne observations of air-quality-related species such as NO2, HCHO, SO2, O3, etc. In this context, the ESA Fiducial Reference Measurements for Ground-Based DOAS Air-Quality Observations (FRM4DOAS) project is aiming at developing a near-real-time (6-24h latency) central processing system for the delivery of harmonized, quality-controlled, and fully traceable data products from MAX-DOAS instruments. The first phase of the project has been dedicated to the development of a prototype version of this processing system for 3 key products (NO2 vertical profiles, total O3 columns, and tropospheric HCHO profiles) and its demonstration at 11 project partners MAX-DOAS stations.

In this presentation we will describe the efforts carried out during the last months to develop the first MAX-DOAS central processing service to be operated within the Network for the Detection of Atmospheric Composition Change (NDACC). The main aspects of the service development will be presented, like the FRM4DOAS prototype algorithm optimisation, operationalisation, and validation, and the establishment of MAX-DOAS NDACC instrument and data retrieval certification procedures, user data policy, datasets DOI, etc. This operational service is expected to be launched in Spring 2020 for a limited number (5-10) of NDACC-certified MAX-DOAS instruments. Corresponding data sets will be stored in the NDACC and ESA EVDC data handling facilities.

This activity and its future upscaling in terms of stations and data products will ensure that MAX-DOAS observations at a FRM quality level will be made available for the validation of present and future satellite missions like the Copernicus atmospheric Sentinels (5p, 4, 5).

How to cite: Hendrick, F., Fayt, C., Friedrich, M. M., Beirle, S., Frieẞ, U., Richter, A., Bösch, T., Kreher, K., Piters, A., Wagner, T., Tirpitz, J.-L., Bais, A., Prados Roman, C., Puentedura, O., Cede, A., Lind, E., Dehn, A., von Bismarck, J., Casadio, S., and Van Roozendael, M.: ESA FRM4DOAS: Towards the launch of the NDACC MAX-DOAS Central Processing Service, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19148, https://doi.org/10.5194/egusphere-egu2020-19148, 2020.

EGU2020-21242 | Displays | AS5.13

Advanced mobile-DOAS techniuqes for locating and identifying urban area emission sources

Zhaokun Hu, Ang Li, and Pinhua Xie

Pollutant concentration distribution and emission are important ways to understand regional pollution. To investigate the distribution characteristics and identify individual sources rapidly, a new mobile passive differential optical absorption spectroscopy (DOAS) instrument has been developed, which set two angle telescopes (90°,30°) to receive the scattered light respectively, and set two mechanical shutters to switch the optical path quickly in the mobile platform. The instrument collected the zenith scattered light in the UV or visible region and it was used to derive the vertical column density of trace gases above the measurement route. The slant column density in two different viewing directions were detected, and combined with the geometric approximation, the vertical column density of trace gas was obtained. After obtaining the column concentration distribution, the data were analyzed by semi variance analysis combined with geographical information. Monte Carlo simulation was used to reconstruct the high spatial resolution pollutant concentration distribution, combined the wind field data during the observation, the high spatial resolution emission flux in the area can be quickly obtained. A field experiment was performed in Beijing and some industrial area. The distribution information of vertical column density along the route in Beijing was derived, the concentration distribution of NO2 at 200m *200m resolution and the 0.01° *0.01°resolution emission flux data are obtained further. The new mobile multi light DOAS instrument were operated on a car. The NO2 column density spatial distribution and the emission flux spatial distribution are obtained with the maximum value of 8.57×1016 molec./cm2 and 34.8 ug/m2/s over the Beijing fifth ring road area. The scheme can provide a new method to verify pollutant concentration distribution and emission inventory.

How to cite: Hu, Z., Li, A., and Xie, P.: Advanced mobile-DOAS techniuqes for locating and identifying urban area emission sources, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21242, https://doi.org/10.5194/egusphere-egu2020-21242, 2020.

EGU2020-700 | Displays | AS5.13

MAX-DOAS NO2 profile retrieval over Minsk: 3 years of observation

Ilya Bruchkouski, Siarhei Barodka, and Yang Wang

For NO2 monitoring by MAX-DOAS method, the automated instrument MARS-B based on the spectrograph ORIEL MS257 with a Peltier-cooled CCD-array detector Andor Technology DV-420 OE (number of active pixels is 1024×256, working temperature is -40 ºC) has been employed. The MARS-B instrument records the spectra of scattered sunlight in the range of elevation angles 0º – 90º within vertical angle aperture of 1.3º in spectral range 340-400 nm with FWHM = 0.32 nm and is operating without mechanical shutter. Radiation input system is working without optical fiber and spectrograph unit has open-air design, spectrograph unit is temperature-stabilized at level 40 ± 0.5 ºC. The MARS-B instrument successfully took part in MAD-CAT (2013) and CINDI-2 (2016) international inter-comparison campaigns.

Since 2017 MARS-B instrument is performing spectra registering over Minsk (National Ozone Monitoring Research and Education Centre, Minsk, Belarus) using multi-axis geometry of observations during daytime and zenith geometry in twilights. More than 4.5 millions of day-time spectra aiming to retrieve differential slant columns of ozone, nitrogen dioxide and oxygen dimer have been processed by DOAS method. Total nitrogen dioxide columns have been retrieved by PriAM algorithm which is based on optimal estimation method.

Continuous 3-year MAX-DOAS measurements (nitrogen dioxide vertical column, near-surface nitrogen dioxide concentrations, aerosol optical depth) over Minsk in period of 2017 - 2019 will be presented, compared with data of impact gas analyzers and satellite data, analyzed and discussed. Also, zenith twilights measurements will be processed aiming to retrieve stratospheric nitrogen dioxide and ozone columns for comparison with different parameters of solar activity.

How to cite: Bruchkouski, I., Barodka, S., and Wang, Y.: MAX-DOAS NO2 profile retrieval over Minsk: 3 years of observation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-700, https://doi.org/10.5194/egusphere-egu2020-700, 2020.

EGU2020-1031 | Displays | AS5.13

DOAS measurements of NO2 and H2CO at Kinshasa and Comparisons with Satellites Observations

Rodriguez Yombo Phaka, Alexis Merlaud, Gaia Pinardi, Caroline Fayt, Martina Friedrich, François Hendrick, Lars Jacob, Michel Van Roozendael, Emmanuel Mahieu, and Jean-Pierre Mbungu

Africa experiences a fast urban inhabitants growth, caused by the largest population boom in the world, combined with rural exodus. Many cities are heavily affected by air pollution. It is therefore essential to monitor the concentrations of the various polluting species such as NO2, HCHO, O3 and aerosols, which have a direct impact on the population health. The sources of pollutant in Africa are different from those found in Europe. For example, forest fires and household cooking largely contribute to the NO2 and HCHO burdens in Central Africa. However, many large African cities, such as the City of Kinshasa, capital of the Democratic Republic of Congo, do not have atmospheric measurement instruments.

In order to tackle the lack of measurements in Kinshasa, the Royal Belgian Institute of Space Aeronomy (BIRA-IASB) has, in collaboration with the University of Kinshasa (UniKin), installed an optical remote sensing instrument on the UniKin site (-4.42°S, 15.31°E). Installed in May 2017, the instrument has been in operation until today and provides data to measure the column amounts  of several polluting species in the atmosphere of Kinshasa. The instrument is based on a compact AVANTES  spectrometer covering the spectral range 290 - 450 nm with 0.7 nm resolution. The spectrometer is a Czerny-Turner type with an entry slit of 50 μm wide, and an array of 1200 l/mm. A 10 m long and 600 μm diameter optical fiber is connected to the spectrometer to receive the incident light beam from the sky. Measurements were mainly made by looking in a fixed direction until November 2019. Since then, a Multi-Axis geometry (MAX-DOAS) has been implemented.

The measurements provided by this DOAS instrument allowed us to start studying the atmosphere of Kinshasa using the QDOAS software, which allows us to find the oblique columns of different observed species.  This poster will present the instrument, the database and  the procedure used to convert these oblique columns into vertical columns, using the air mass factors calculated with the radiative transfer model. We also present our first MAX-DOAS results, analyzed using the retrieval tools of the ESA FRM4DOAS project. The study of current results clearly shows the signature of polluting species such as NO2, HCHO in the atmosphere of Kinshasa. We also use simulations by the GEOS-Chem chemistry transport model to evaluate the magnitude of the emissions needed to explain the observed column amounts. These observations made in Kinshasa could contribute to the validation of satellite products and the refinement of models. We present a first comparison of Kinshasa's ground-based observations with those of the OMI and TROPOMI satellites

How to cite: Yombo Phaka, R., Merlaud, A., Pinardi, G., Fayt, C., Friedrich, M., Hendrick, F., Jacob, L., Van Roozendael, M., Mahieu, E., and Mbungu, J.-P.: DOAS measurements of NO2 and H2CO at Kinshasa and Comparisons with Satellites Observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1031, https://doi.org/10.5194/egusphere-egu2020-1031, 2020.

EGU2020-3323 | Displays | AS5.13

One year of MAX-DOAS measurements of tropospheric trace gases and aerosols in the suburban area of London

Sebastian Donner, Steffen Dörner, Joelle Buxmann, Steffen Beirle, David Campbell, Detlef Müller, Julia Remmers, Samantha M. Rolfe, and Thomas Wagner

Multi-AXis (MAX)-DOAS instruments record spectra of scattered sun light under different elevation angles. From such measurements tropospheric vertical column densities (VCDs) and vertical profiles of different atmospheric trace gases and aerosols can be determined for the lower troposphere. These measurements allow a simultaneous observation of multiple trace gases (e.g. HCHO, CHOCHO, NO2, etc.) with the same measurement setup. Since November 2018, a MAX-DOAS instrument is operated at the Bayfordbury Observatory, which is located approximately 30 km north of London. This measurement site is operated by the University of Hertfordshire and equipped with an AERONET station, a LIDAR and multiple instruments to measure meteorological quantities and solar radiation. Depending on the prevailing wind direction the air masses at the measurement site can be dominated by the pollution of London (SE to SW winds) or rather pristine air (northerly winds). Therefore, this measurement site is well suited to study the influence of anthropogenic pollution on the atmospheric composition and chemistry at a rather pristine location in the vicinity of London, a major European capital with 9.8 million inhabitants and 4 major international airports.

In this study, trace gas and aerosol profiles are retrieved using the MAinz Profile Algorithm MAPA (Beirle et al., 2018) with a focus on tropospheric formaldehyde (HCHO) which plays an important role in tropospheric chemistry. The HCHO results are combined with the results of other trace species such as NO2, CHOCHO and aerosols in order to identify different chemical regimes and pollution levels.

How to cite: Donner, S., Dörner, S., Buxmann, J., Beirle, S., Campbell, D., Müller, D., Remmers, J., Rolfe, S. M., and Wagner, T.: One year of MAX-DOAS measurements of tropospheric trace gases and aerosols in the suburban area of London, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3323, https://doi.org/10.5194/egusphere-egu2020-3323, 2020.

Atmospheric pollution has a well-known impact on the human life, thus observing the emissions of trace gases is an important part of monitoring the atmospheric composition. This paper aims to determine the vertical column densities (VCDs) of Nitrogen Dioxide (NO2) and Sulfur Dioxide (SO2). These quantities will be used to calculate emissions of these pollutants quantified using a ground based mobile remote sensing technique that relies on scattered light DOAS (Differential Optical Absorption Spectroscopy) measurements. This method will be implemented using the SWING (Small Whiskbroom Imager for atmospheric compositioN monitorinG). The instrument is designed to perform airborne measurements, but for the purpose of this paper it was adapted for ground-based use by the National Institute for Aerospace Research (INCAS) in Bucharest, Romania. The source aimed to be quantified is the city of Bucharest, specifically the total emissions generated by the traffic and industry within the city. The measurements will be performed during the Spring of 2020 between February and April. The experimental setup consists of the SWING that will be mounted on the roof of a car, which allows to perform measurements along the ring road of Bucharest. There will be presented results from several days of measurements from a total of 150 hours of driving in terms of differential slant column densities (DSCDs), vertical column densities (VCDs) and quantified emissions of NO­2 and SO2. This study will also be used for the fine tuning of the SWING operational parameters for use on UAV platforms in future measurement campaigns.

How to cite: Iancu, S.: Quantification of Nitrogen Dioxide and Sulfur Dioxide emissions from Bucharest using a mobile-DOAS setup, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3616, https://doi.org/10.5194/egusphere-egu2020-3616, 2020.

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Quantitative comparison of measured and simulated O4 absorption for one day with extremely low aerosol load over the tropical Atlantic

Thomas Wagner, Steffen Dörner, Sebastian Donner, Steffen Beirle, and Stefan Kinne

Measurements of the atmospheric absorption of the oxygen dimer O4 are often used to characterize the atmospheric light paths, e.g. to derive properties of clouds and aerosols. Some recent studies indicated discrepancies between measurements and simulations of the atmospheric O4 absorption, while others found exact quantitative agreement. One difficulty in these studies was to correctly represent the aerosol properties in the radiative transfer simulations, e.g. due to lack of information about the vertical profiles or scattering properties.

In this study we investigate MAX-DOAS measurements of the atmospheric O4 absorption during a ship cruise in April and May 2019 over the tropical Atlantic. The elevation angle of the instruments telescope is automatically stabilized in order to compensate the motion of the sea. We select measurements on one day (2 May 2019) with extremely low aerosol optical depth (between about 0.03 and 0.05 at 360 nm). For such conditions the atmospheric scattering processes are dominated by Rayleigh scattering on air molecules.

Besides the MAX-DOAS measurements, also measurements by a ceilometer and sun photometer are available, which are used to constrain the atmospheric aerosol properties. The radiative transfer simulations are carried out with the full spherical radiative transfer model MCARTIM.

How to cite: Wagner, T., Dörner, S., Donner, S., Beirle, S., and Kinne, S.: Quantitative comparison of measured and simulated O4 absorption for one day with extremely low aerosol load over the tropical Atlantic, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4237, https://doi.org/10.5194/egusphere-egu2020-4237, 2020.

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Development of a versatile portable MAX-DOAS instrument

Wolfgang Kausch, Stefan Kimeswenger, Norbert Przybilla, and Stefan Noll

Multi-AXis Differential Optical Absorption Spectroscopy has become a versatile and mature measurement technique for determining various components of the Earth’s atmosphere, e.g. O3, SO2, NO2 properties. Since the concentration of these trace gases might strongly vary locally and in time, easy in-situ measurements with a mobile device are highly desirable.

We are currently developing a portable MAX-DOAS instrument setup consisting of three small telescopes with a diameter of 50mm. Each of these telescopes is equipped with an individual fiber-fed low-resolution spectrograph (Stellarnet Blue Wave devices, 2048 pixel CCD) to enable simultaneous measurements ranging from 300 to 1000nm in one shot. The entire wavelength range is therefore covered by three spectral arms: (a) The UV arm, equipped with a Stellarnet BLUE-Wave UV2 spectrograph ranging from 300 to 500nm; (b) the VIS arm consisting of a NIR4 device (500…700nm), and (c) The NIR arm, based on a Stellarnet NIR2 ranging from 600 to 1000nm. All spectrographs are fed with wavelength-optimised fibers and equipped with the smallest possible slit (14 µm slit width) to maximise the throughput and the spectral resolving power (λ-dispersion UVB + VIS: 0.2nm; NIR: 0.4nm).

The three telescopes are aligned in parallel and installed on a small astronomical azimuthal mount (Skywatcher AZ-EQ5, powered by a mobile 12V Lithium-Polymer battery) to enable measurements in all directions. The mount control software will be based either on the ASCOM or the INDILIB platform. For the control of the spectrographs we use the programme SpectraWiz (by Stellarnet). As DOAS analysis software we have chosen QDOAS, provided by the Royal Belgian Institute for Space Aeronomy. All software is freely available and is installed on a Dell Latitude 5450 Rugged laptop, which is optimised for outdoor applications.

The chosen setup enables a mobile usage easily transportable by a small car. Since the development is currently ongoing, especially with respect to the automation of the measurements and the data processing, we report on the status of the project in this presentation.

How to cite: Kausch, W., Kimeswenger, S., Przybilla, N., and Noll, S.: Development of a versatile portable MAX-DOAS instrument, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4552, https://doi.org/10.5194/egusphere-egu2020-4552, 2020.

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Estimating aircraft emissions at Frankfurt airport using the DOAS technique

Katharina Uhlmannsiek, Bianca Lauster, Steffen Dörner, Sebastian Donner, Steffen Beirle, and Thomas Wagner

For the last decades, civil aviation traffic increased rapidly. At Frankfurt airport more than 700 flights depart per day (5h to 23h) i.e., take-offs take place approximately every two minutes. Like many other engines, an airplane’s engine uses fossil fuel primarily emitting carbon dioxide (CO2) and water vapour (H2O). However, high combustion temperatures also lead to a significant amount of nitrogen oxide (NOx) emission. NOx has a large impact on atmospheric chemistry and is harmful to human health. As airports are usually built in highly populated areas, these pollutants affect the health of the inhabitants in the region. Only few measurements have directly investigated emissions of airplanes under real atmospheric conditions during take-off as these measurements are typically difficult to perform.

In this work, we show the applicability and first results using Multi AXis Differential Absorption Spectroscopy (MAX-DOAS) measurements to directly determine airplane emissions during take-off at Frankfurt airport. Therefore, the MAX-DOAS instrument is mounted in extension of the runway, about 500 m below the typical altitude of the departing aircrafts to measure a spectrum of scattered sun light through the exhaust plume. Using a wide aperture of the entrance optics at one fixed elevation instead of scanning across the plume allows capturing the whole plume with one simultaneous measurement. In that way, the induced NO2 emission of each passing aircraft can be determined. The obtained NO2 emissions are then used to estimate the total emissions of nitrogen oxides. 

How to cite: Uhlmannsiek, K., Lauster, B., Dörner, S., Donner, S., Beirle, S., and Wagner, T.: Estimating aircraft emissions at Frankfurt airport using the DOAS technique, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6671, https://doi.org/10.5194/egusphere-egu2020-6671, 2020.

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Tropospheric trace gas slant column densities derived from MAX-DOAS measurements on pacific transit cruises of the German research vessel Sonne in 2019

Steffen Dörner, Thomas Ruhtz, Sebastian Donner, Steffen Beirle, Stefan Kinne, and Thomas Wagner

Between January and July 2019 the German research vessel Sonne was on several cruises in the Pacific, crossing the ocean from Suva, Fiji to Manzanillo, Mexico in February (SO267-2) and from Vancouver, Canada to Singapore in June (SO268-3). A Multi Axis-Differential Optical Absorption Spectroscopy (MAX-DOAS) instrument was in operation outside the national exclusive economic zone (EEZ) regions allowing for profile measurements of trace gases and aerosol on the open seas under background conditions. Both transit cruises cover a wide range of marine biomes and climatic zones affecting the trace gas and particle composition of the atmosphere.

Ship measurements of Nitrogen Dioxide (NO2) and Sulphur Dioxide (SO2) are especially important for the validation of satellite measurements as the remote Pacific Ocean is typically used as a reference region. Off the coast of North America an enhanced signal of halogen species, i.e. bromine oxide (BrO) and iodine oxide (IO) was observed. The abundance of formaldehyde (HCHO) and its interrelation with the marine bio-activity could also be observed.

How to cite: Dörner, S., Ruhtz, T., Donner, S., Beirle, S., Kinne, S., and Wagner, T.: Tropospheric trace gas slant column densities derived from MAX-DOAS measurements on pacific transit cruises of the German research vessel Sonne in 2019, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6980, https://doi.org/10.5194/egusphere-egu2020-6980, 2020.

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A two-camera instrument for highly resolved Gas Correlation Spectroscopy measurements of NO2

Leon Kuhn, Jonas Kuhn, Thomas Wagner, and Ulrich Platt

Imaging of atmospheric trace gases is becoming an increasingly important field of remote sensing. Conventional methods (like imaging-DOAS) typically use dispersive elements and wavelength mapping (at moderate to high spectral resolution) and need intricate optical setup. Therefore, they are limited in spatio-temporal resolution.

Some atmospheric trace gases can, however, be detected only by using a few carefully selected spectral channels, specific to the selected trace gas. These can be filtered using non-dispersive spectral filters without spatial mapping of continuous spectra, vastly increasing the spatio-temporal resolution. This has become a routine in volcanic SO2 flux analysis, where band-pass filters provide the spectral filtering.

We propose fast imaging of spatial Nitrogen Dioxide (NO2) distributions employing Gas Correlation Spectroscopy (GCS) in the visible wavelength range. Two spectral channels are used, one with a gas cell that is filled with a high amount of NO2 in the light path and one without. An additional band-pass filter preselects a wavelength range containing structured and strong NO2 absorption (e.g. 430 - 450 nm). The NO2 containing gas cell serves as a NO2 specific spectral filter, almost blocking the light at wavelengths of the strong NO2 absorption bands within the preselected wavelength range. Absorption by atmospheric NO2 has therefore a lower impact on the channel with gas cell compared to the channel without gas cell. This difference is used to generate NO2 images.

NO2 plays a major role in urban air pollution, where it is primarily emitted by point sources (power plants, vehicle internal combustion engines), before undergoing chemical conversions. The corresponding spatial gradients can neither be resolved with the established in-situ techniques nor with the widely used DOAS remote sensing method.

Recent advances in the physical implementation of a GCS-based NO2 camera suggest, that the quality of the measurement may be vastly enhanced in a two-detector (two-camera) set-up. Here, individual cameras are used for the two spectral channels. Not only does this double the photon budget available, but it also allows for synchronized exposure in both channels. This is critical for the quality of the measurement, since dynamic gas or intensity features on time scales smaller than the exposure delay of a one-camera system can induce strong false signals.

A proof of concept measurement was carried out, where test cells with NO2 column densities ranging from 1E16 to 4E18 molecules cm-2 were measured both with DOAS and our camera. The results coincided within their uncertainties and allow for camera calibration based on an instrument forward model.

How to cite: Kuhn, L., Kuhn, J., Wagner, T., and Platt, U.: A two-camera instrument for highly resolved Gas Correlation Spectroscopy measurements of NO2, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-7194, https://doi.org/10.5194/egusphere-egu2020-7194, 2020.

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A method for retrieving the spatial distribution of trace gases using measurements of three ground-based MAX-DOAS instruments

Michael Revesz, Stefan F. Schreier, Philipp Weihs, Tim Bösch, Kezia Lange, Andreas Richter, Mihalis Vrekoussis, and Alois W. Schmalwieser

Within the project VINDOBONA (VIenna horizontal aNd vertical Distribution OBservations Of Nitrogen dioxide and Aerosols), a method was developed to retrieve the spatial distribution of trace gases using data from three ground based MAX-DOAS instruments and was applied on the example of NO2. At three different locations in Vienna (Austria) MAX-DOAS instruments were installed performing measurements in the visible and UV spectral range. Currently, each instrument is set up to determine the column densities in different azimuthal directions and low elevation angles within approximately a horizontal plane. The different lines of sight of the three instruments intersect horizontally and can be used to estimate the horizontal spatial distribution of trace gases. With the knowledge of vertical profiles, even the vertical distribution can be estimated using this method. 

The intersections of the different lines of sight define segments along the slant columns for which the mass concentrations can be estimated. Knowledge about the vertical profiles for a chosen trace gas can be used to correct the retrieved trace gas concentration to specific altitudes above ground. Such corrections are also required since the three instruments were set up at different heights above ground, at different altitudes relative to sea level and with different elevation angles of the lowest viewing direction. One open issue for the retrieval process is the terrain in Vienna in combination with the prevailing wind condition that impacts the horizontal and vertical trace gas distribution and make the retrieval challenging. 

How to cite: Revesz, M., Schreier, S. F., Weihs, P., Bösch, T., Lange, K., Richter, A., Vrekoussis, M., and Schmalwieser, A. W.: A method for retrieving the spatial distribution of trace gases using measurements of three ground-based MAX-DOAS instruments, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8792, https://doi.org/10.5194/egusphere-egu2020-8792, 2020.

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The Airyx 2D SkySpec instrument: MAX-DOAS measurements of tropospheric NO2 and HCHO in Munich and the comparison to satellite observations

Johannes Lampel, Ka Lok Chan, Denis Pöhler, Matthias Wiegner, Carlos Alberti, Ulrich Platt, and Mark Wenig

We present the Airyx 2D SkySpec Instrument: A commercially available two-dimensionally scanning Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) setup for the observations of trace gases using spectral measurements of scattered sun light and optionally also direct sun light. The waterproof design of the scanner unit is designed for long-term outdoor deployment. Temperature stabilisation of the spectrometers and automatic calibration spectra measurement are used to ensure high-quality measurement data over months and years of observations.

We show 2.5 years of measurements in Munich. Vertical columns and vertical distribution profiles of aerosol extinction coefficient, NO2 and HCHO are retrieved from the 2D MAX-DOAS observations. The measured surface aerosol extinction coefficients and NO2 mixing ratios are compared to in-situ monitor data. The retrieved surface NO2 mixing ratios show good agreement with in-situ monitor data with a Pearson correlation coefficient (R) of 0.91. Good agreement (R= 0.80) is also found for AOD when compared to sun-photometer measurements. Tropospheric vertical column densities (VCDs) of NO2 and HCHO derived from the MAX-DOAS measurements are also used to validate OMI and TROPOMI satellite observations. Monthly averaged data show good correlation, however, satellite observations are on average 30% lower than the MAX-DOAS measurements. Furthermore, the 2D MAX-DOAS observations are used to investigate the spatio-temporal characteristic of NO2 and HCHO in Munich. Analysis of the relations among aerosol, NO2 and HCHO show higher aerosol to HCHO ratios in winter indicating a longer atmospheric lifetime of aerosol and HCHO. The analysis also suggests that secondary aerosol formation is the major source of aerosols in Munich.

How to cite: Lampel, J., Chan, K. L., Pöhler, D., Wiegner, M., Alberti, C., Platt, U., and Wenig, M.: The Airyx 2D SkySpec instrument: MAX-DOAS measurements of tropospheric NO2 and HCHO in Munich and the comparison to satellite observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8941, https://doi.org/10.5194/egusphere-egu2020-8941, 2020.

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Estimation of NOx, SO2 and HCHO emissions from the megacity of Lahore, Pakistan using car MAX-DOAS observations and comparison with regional model and TROPOMI satellite data

Maria Razi, Steffen Dörner, Vinod Kumar, Sebastian Donner, Noor Ahmad, Steffen Beirle, Muhammad Fahim Khokhar, and Thomas Wagner

Lahore, megacity of Pakistan with more than 11 million inhabitants is a strong emission source of atmospheric pollutants. We present results of a top-down emission procedure for NOx and SO2 for Lahore, based on car multi-axis differential optical absorption spectroscopy (car-MAX-DOAS) observations. Additionally, the total flux of HCHO from the city is determined which can be seen as an indicator for VOC emissions. Results from two extensive campaigns, which took place in summer 2017 and spring 2018 will be presented. From the measured spectra, we retrieve the vertically integrated concentration (the so-called tropospheric vertical column density, VCD) of the trace gases along the driving route by using the so-called geometric approximation method. By combining these observations with ECMWF Re-Analysis wind data, the total fluxes of NOx, SO2 and HCHO from the city of Lahore are estimated. From both measurement campaigns, we also analyzed the seasonal variability of the above-mentioned species.

Derived NOx and SO2 emissions are compared to the bottom-up emission inventory EDGAR. Spatial disributions of the tropospheric NO2 and SO2 VCDs observed by car MAX-DOAS are compared with those simulated using a coupled regional-global model system (MECO(n)). We find that, the model is able to account for the spatial variablity but the VCDs are systematically underestimated by the regional model. Finally, derived NOx emissions are also compared to the emissions estimated from TROPOMI satellite observations.

How to cite: Razi, M., Dörner, S., Kumar, V., Donner, S., Ahmad, N., Beirle, S., Khokhar, M. F., and Wagner, T.: Estimation of NOx, SO2 and HCHO emissions from the megacity of Lahore, Pakistan using car MAX-DOAS observations and comparison with regional model and TROPOMI satellite data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9265, https://doi.org/10.5194/egusphere-egu2020-9265, 2020.

MAX-DOAS observations was carried out from March 1, 2019 to December 31, 2019 in Qingdao, China, to measure the O4, NO2, SO2 and H2O absorption, to retrieve AOD and the troposphere vertical column concentration of NO2, SO2 and H2O.We use PriAM algorithm which based on the optimal estimation to calculating volume mixing ratio profile of trace gases, aerosol and water vapor during 0 ~ 4 km. The correlation between AOD and H2O VCD was analyzed in every month, the results showed that the AOD and H2O VCD has good linear relationship in each month., illustrate the increase of water vapor concentration will lead to the increase of moisture absorption of aerosol. The seasonal variation of the four seasonal correlation slopes in the order of summer < autumn < spring < winter. The influence of concentration change of NO2 VCD, SO2 VCD, H2O VCD and AOD is discussed in a haze episodes occurred in December 2019. Discovery that the H2O VCD and AOD was increased at the same time in the haze pollution incident, but with the increase of water vapor concentration, the concentration of NO2 and SO2 decreases, indicated that due to the increase of concentration of water vapor, NO2 and SO2 heterogeneous reaction will happen to generate nitrate and sulfate aerosols, so that the concentration of NO2 and SO2 concentration was decreased. The relationship between NO2, SO2, AOD and water vapor mixing ratio of 50m, 200m, 400m and 600m during haze pollution period was also studied, and it was indicated that phenomenon aerosol extinction increased with the increase of water vapor mixing ratio, while NO2 and SO2, on the contrary, were more obvious at 50m and 200m near the ground.

How to cite: Ren, H., Li, A., Hu, Z., Huang, Y., Xu, J., and Xie, P.: The seasonal correlation between atmospheric water vapor and aerosol extinction and the relationship between aerosol, NO2, SO2 and water vapor during haze pollution in Qingdao, China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12714, https://doi.org/10.5194/egusphere-egu2020-12714, 2020.

Atmospheric aerosols range in diameter from a few nanometers to tens of micrometers, and they have direct or indirect effects on atmospheric radiation assessments, global climate change, local air quality and visibility, and human health. In particular, during the high season of haze in autumn and winter, atmospheric aerosols are more conducive to transform and accumulate. In this paper, we used the aerosol optical thickness (AOD) and aerosol profile obtained by MAX-DOAS instrument to study the characteristics of aerosol-type, vertical distribution characteristics of near-surface aerosol, and pollution source analysis. From December 30, 2018, to January 27, 2019, we conducted MAX-DOAS observations on Sanmenxia Environmental Protection Bureau. According to the relative humidity data and ion chromatography data, we analyzed the correlation between AOD and PM2.5, the result show that aerosols are mainly fine particles, and most of them are nitrates. The near-surface aerosol extinction coefficient obtained by MAX-DOAS was compared with the PM2.5 and PM10 concentrations measured by unmanned aerial vehicle (UAV). Aerosol particles showed an increasing trend from the ground to 500 m. Combined with the wind field information and the backward trajectory of the air mass during the haze, we found that the continuous heavy pollution was caused by the transportation of polluted air masses in the northeast, along with local industrial emissions and other sources of emissions, which resulted in a wide range and long-term accumulation of pollutants under continuous and steady conditions.

How to cite: Li, X., Xie, P., and Li, A.: Study of aerosol-type characteristics and sources using MAX-DOAS measurement during haze at an urban site in the Fenwei Plain, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12726, https://doi.org/10.5194/egusphere-egu2020-12726, 2020.

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Tropospheric NO2 and HCHO derived from dual-scan MAX-DOAS measurements in Uccle (Belgium) and application to S5P/TROPOMI validation

Ermioni Dimitropoulou, Francois Hendrick, Martine M. Friedrich, Gaia Pinardi, Frederik Tack, Alexis Merlaud, Caroline Fayt, Christian Hermans, Frans Fierens, and Michel Van Roozendael

Ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements of aerosols, tropospheric nitrogen dioxide (NO2) and formaldehyde (HCHO) have been carried out in Uccle, Brussels, during two years (March 2018 – March 2020). The MAX-DOAS instrument has been operating in both UV and visible (Vis) wavelength ranges in a dual-scan configuration consisting of two sub-modes: (1) an elevation scan in a fixed viewing azimuthal direction (the so-called main azimuthal direction) pointing and (2) an azimuthal scan in a fixed low elevation angle (2o). By applying a vertical profile inversion algorithm in the main azimuthal direction and an adapted version of the parameterization technique proposed by Sinreich et al. (2013) in the other azimuthal directions, near-surface  concentrations (VMRs) and vertical column densities (VCDs) are retrieved in ten different azimuthal directions.

The present work focuses on the seasonal horizontal variation of NO2 and HCHO around the measurement site. The observations show a clear seasonal cycle of these trace gases. An important application of the dual-scan MAX-DOAS measurements is the validation of satellite missions with high spatial resolution, such as TROPOMI/S5P. Measuring the tropospheric  VCDs in different azimuthal directions is shown to improve the spatial colocation with satellite measurements leading to a better agreement between both datasets. By using  vertical profile information derived from the MAX-DOAS measurements, we show that a persistent systematic underestimation of the TROPOMI  data can be explained by uncertainties in the a-priori NO2 profile shape in the satellite retrieval. A similar validation study for TROPOMI HCHO is currently under progress and preliminary results will be presented.

References:

Sinreich, R., Merten, A., Molina, L., and Volkamer, R.: Parameterizing radiative transfer to convert MAX-DOAS dSCDs into near-surface box-averaged mixing ratios, Atmos. Meas. Tech., 6, 1521–1532, https://doi.org/10.5194/amt-6-1521-2013, 2013.

How to cite: Dimitropoulou, E., Hendrick, F., Friedrich, M. M., Pinardi, G., Tack, F., Merlaud, A., Fayt, C., Hermans, C., Fierens, F., and Van Roozendael, M.: Tropospheric NO2 and HCHO derived from dual-scan MAX-DOAS measurements in Uccle (Belgium) and application to S5P/TROPOMI validation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17181, https://doi.org/10.5194/egusphere-egu2020-17181, 2020.

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Polarisation preservation in multi-mode optical quartz fibres and implications for MAX-DOAS observations

Verena Oehmke, Jan-Lukas Tirpitz, Udo Frieß, and Ulrich Platt

In many spectroscopic applications, optical fibres are an essential part of the instrumental setup. One of such applications is Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS), which is a remote sensing technique to detect atmospheric aerosol and trace gases by analysing spectra of scattered skylight. Typically, multi-mode quartz fibres (MMQF) of > 100 µm in diameter are used in MAX-DOAS instruments to interconnect the telescope unit with a grating spectrometer. Besides acting as a light guide giving more freedom in the spatial arrangement of telescope and spectrometer and homogenizing the illumination of the spectrometer entrance slit, such fibres have depolarising properties originating predominantly from manufacturing induced birefringent effects. This property is particularly desirable in MAX-DOAS applications, since the incoming partially polarized skylight should ideally be depolarized before entering the polarisation sensitive spectrometer. The behaviour of polarised light in mono-mode fibres is well investigated and even utilized in telecommunications, whereas equivalent literature on multi-mode fibres is scarce.

We measured the depolarisation capabilities of a set of 20 MMQF of different age, length and diameter as typically used in MAX-DOAS applications. Independent of the fibre diameter, we found that in some recently manufactured (in 2018) fibres polarisation is well preserved with a decrease in total degree of polarisation (DOLP) to 1/e of its initial value at a fibre length Le > 10 m at 450 nm, while in older fibres (> 10 years in age) Le ≈ 1 m was found. This is probably due to improvements in the manufacturing process in the recent years. We further investigated the dependence of Le on wavelength, on the polarisation orientation of the ingoing light and on additional birefringence induced by applying external strain (bending) to the fibres. The results are presented and discussed with regard to their implications for MAX-DOAS observations.

How to cite: Oehmke, V., Tirpitz, J.-L., Frieß, U., and Platt, U.: Polarisation preservation in multi-mode optical quartz fibres and implications for MAX-DOAS observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18047, https://doi.org/10.5194/egusphere-egu2020-18047, 2020.

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Mobile MAX-DOAS and in situ measurements of atmospheric trace gases and aerosols

Folkard Wittrock, Kai Krause, Kezia Lange, André Seyler, Andreas Richter, and John P. Burrows

As part of the German project MeSMarT (Measurements of shipping emissions in the marine troposphere, a cooperation between the University of Bremen and the German Federal Maritime and Hydrographic Agency) and the EU LIFE project CLINSH (Clean Inland Shipping,) numerous mobile measurements of atmospheric trace gases and aerosols have been carried out.

For both projects one main objective is to investigate the general impact of shipping emissions on the air quality in regions with high marine traffic. In order to do this in areas where no permanent monitoring systems are available, in 2015 a mobile lab has been set up, which includes among other instrumentation for air pollution and meteorological parameters a scientific-grade MAX-DOAS system as well as in situ instruments for nitrogen oxides, ozone, carbon monoxide and sulfur dioxide (trace level).

In this study we present intercomparison results between the different instruments onboard the mobile lab as well as the interpretation of the results using complementary data sets at different locations including the Lower Rhine and Waal area and several regions in Northern Germany. For some places close to the banks of the Rhine more than 70% of the nitrogen oxides are related to shipping emissions. Emission factors for different ship types have been calculated and compared to recent studies and emission inventories.

How to cite: Wittrock, F., Krause, K., Lange, K., Seyler, A., Richter, A., and Burrows, J. P.: Mobile MAX-DOAS and in situ measurements of atmospheric trace gases and aerosols, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20025, https://doi.org/10.5194/egusphere-egu2020-20025, 2020.

EGU2020-20796 | Displays | AS5.13

MAX-DOAS measurements of atmospheric rural and urban NO2 gradients during the TROLIX'19 campaign

Karin Kreher, Elena Spinei, Ankie Piters, Arnoud Apituley, Alkis Bais, Steffen Doerner, Caroline Fayt, Martina Friedrich, Arnoud Frumau, Francois Hendrick, Christian Hermans, Dimitris Karagkiozidis, Richard Querel, Michel Van Roozendael, Jan Vonk, and Thomas Wagner

As part of the TROLIX'19 (TROpomi vaLIdation eXperiment) campaign (2 September to 4 October 2019), measurements of tropospheric NO2 columns and surface concentrations were made using the MAX-DOAS (Multi-AXis Differential Optical Absorption Spectroscopy) technique. To characterise any TROPOMI sub pixel (less than 3.5 km x 7 km) heterogeneity, four MAX-DOAS instruments were deployed at rural locations close to Cabauw (51.97°N, 4.93°E) and further six instruments were operated within the highly industrialized area of Rotterdam (51.92°N, 4.48°E) in the Netherlands. All instruments performed sky scanning from the horizon (from approximately 1°) to the zenith. In addition, two of the MAX-DOAS instruments (Pandoras) also measured total NO2 columns in direct sun mode.

Here we present first results focusing on the measurements of NO2 spatial gradients made at sites within approximately 3-10 km distance in a rural and an urban environment. The data analysis was done in two steps. Differential slant column densities were calculated using the data processing procedures established during the CINDI-2 intercomparison campaign (Kreher et al., in review, 2019) in UV and VIS spectral ranges. Tropospheric columns, near surface concentrations and profiles were then calculated using the Pandora real time algorithm as well as the NDACC UV-Vis Central Processing system developed in the ESA FRM4DOAS project. Local heterogeneity at the surface level was evaluated using in-situ NO2 measurements available from several routine monitoring stations within the area of interest. The local NO2 heterogeneity effect on TROPOMI validation is also discussed.

Reference:

Kreher, K. et al.: Intercomparison of NO2, O4, O3 and HCHO slant column measurements by MAX-DOAS and zenith-sky UV-Visible spectrometers during the CINDI-2 campaign, Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2019-157, in review, 2019.

 

How to cite: Kreher, K., Spinei, E., Piters, A., Apituley, A., Bais, A., Doerner, S., Fayt, C., Friedrich, M., Frumau, A., Hendrick, F., Hermans, C., Karagkiozidis, D., Querel, R., Van Roozendael, M., Vonk, J., and Wagner, T.: MAX-DOAS measurements of atmospheric rural and urban NO2 gradients during the TROLIX'19 campaign, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20796, https://doi.org/10.5194/egusphere-egu2020-20796, 2020.

EGU2020-21086 | Displays | AS5.13

Research on measurement and source distribution of atmospheric NO2 concentration by ground-based MAX-DOAS system in Nanjing, China

Bo ren, Pinhua Xie, jin Xu, Ang Li, Xin Tian, Zhaokun Hu, and Xiaomei Li

Nanjing, as one of the important cities in the Yangtze River Delta of China, has a developed economy and a large population. Although the concentration of air pollutants in Nanjing has declined with the introduction of China’s strict air pollution prevention and control policies, the situation of air pollution is still severe. Therefore, understanding the source and distribution of atmospheric pollutants has an important role in implementing the prevention and controlling of atmospheric pollutants. In this study, we observed the vertical distribution characteristics of tropospheric NO2 by used the ground-based Multi Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) technique in Nanjing. The contribution of transregional transport to NO2 in different seasons and different altitudes (200m, 500m, and 1000m) was analyzed by combining the potential source distribution model (PSCF). The analysis results showed that the distribution of NO2 sources were obvious seasonal changes. Due to the lower wind speed in spring, the distribution of NO2 sources at all altitudes was not obvious. In summer and autumn, the source of NO2 in the lower altitudes (200m) was concentrated in the urban area of ​​Nanjing and central Jiangsu Province. But for the winter, the NO2 concentrations of lower altitudes were seriously affected by Chuzhou and Ma'anshan area. The sources distribution in the middle and upper altitude were relatively scattered and the WPSCF value was smaller than lower altitudes, which may be caused by the NO2 concentrated in the near ground.

How to cite: ren, B., Xie, P., Xu, J., Li, A., Tian, X., Hu, Z., and Li, X.: Research on measurement and source distribution of atmospheric NO2 concentration by ground-based MAX-DOAS system in Nanjing, China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-21086, https://doi.org/10.5194/egusphere-egu2020-21086, 2020.

AS5.14 – Remote Sensing of Clouds and Aerosols: Techniques and Applications

EGU2020-16090 | Displays | AS5.14

Towards a consistent retrieval of cloud/aerosol single scattering properties and surface reflectance

Marta Luffarelli, Yves Govaerts, Sotiris Sotiriadis, Carsten Brockmann, Grit Kirches, Thomas Storm, and Simon Pinnock

The CISAR (Combined Inversion of Surface and AeRosols) algorithm is exploited in the framework of the ESA-SEOM CIRCAS (ConsIstent Retrieval of Cloud Aerosol Surface) project, aiming at providing a set of atmospheric (cloud and aerosol) and surface reflectance products derived from S3A/SLSTR observations using the same radiative transfer physics and assumptions. CISAR is an advance algorithm developed by Rayference originally designed for the retrieval of aerosol single scattering properties and surface reflectance from both geostationary and polar orbiting satellite observations.  It is based on the inversion of a fast radiative transfer model (FASTRE). The retrieval mechanism allows a continuous variation of the aerosol and cloud single scattering properties in the solution space.

Traditionally, different approaches are exploited to retrieve the different Earth system components, which could lead to inconsistent data sets. The simultaneous retrieval of different atmospheric and surface variables over any type of surface (including bright surfaces and water bodies) with the same forward model and inversion scheme ensures the consistency among the retrieved Earth system components. Additionally, pixels located in the transition zone between pure clouds and pure aerosols are often discarded from both cloud and aerosol algorithms. This “twilight zone” can cover up to 30% of the globe. A consistent retrieval of both cloud and aerosol single scattering properties with the same algorithm could help filling this gap.

The CIRCAS project ultimately aims at overcoming the need of an external cloud mask, letting the CISAR algorithm discriminate between aerosol and cloud properties. This would also help reducing the overestimation of aerosol optical thickness in cloud contaminated pixels. The surface reflectance product is delivered both for cloud-free and cloudy observations.

Results from the processing of S3A/SLSTR observations will be shown and evaluated against independent datasets.

How to cite: Luffarelli, M., Govaerts, Y., Sotiriadis, S., Brockmann, C., Kirches, G., Storm, T., and Pinnock, S.: Towards a consistent retrieval of cloud/aerosol single scattering properties and surface reflectance, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16090, https://doi.org/10.5194/egusphere-egu2020-16090, 2020.

EGU2020-4554 | Displays | AS5.14

Infrared limb sounding of cirrus clouds: state of knowledge, recent progress, and future prospects

Reinhold Spang, Irene Bartolome, Jörn Ungermann, Sabine Griessbach, Lars Hoffmann, Martina Krämer, Michael Höpfner, Binaca Dinelli, Tiziano Maestri, Richard Siddans, Rolf Müller, and Martin Riese

Cirrus clouds are the highest altitude clouds in the troposphere and play an important role in the climate system. They can either have a cooling or heating effect in radiation balance around of the planet, depending on which altitude and temperature they appear. Despite the importance of this type of clouds for the radiation budget there are still big gaps of knowledge regarding their micro and macro physical properties (e.g. particle sizes, ice water content, occurrence and coverage at the upper troposphere and lower stratosphere), especially for optically very thin cirrus in the tropopause region, which are difficult to detect even for active lidar measurements. Due to the long path length through the atmosphere and good vertical resolution passive infrared limb measurements are especially well suited to observe this type of clouds. The presentation will highlight the current status in infrared limb sounding and corresponding particle parameter retrievals with respect to recent and future space and airborne sensors (e.g. CRISTA, MIPAS, and IR limb-imaging instruments).

How to cite: Spang, R., Bartolome, I., Ungermann, J., Griessbach, S., Hoffmann, L., Krämer, M., Höpfner, M., Dinelli, B., Maestri, T., Siddans, R., Müller, R., and Riese, M.: Infrared limb sounding of cirrus clouds: state of knowledge, recent progress, and future prospects, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4554, https://doi.org/10.5194/egusphere-egu2020-4554, 2020.

EGU2020-9036 | Displays | AS5.14

Antarctic cloud detection and classification from far and mid infrared downwelling radiance spectra: performances optimization and results

Davide Magurno, Tiziano Maestri, William Cossich, Gianluca Di Natale, Luca Palchetti, Giovanni Bianchini, and Massimo Del Guasta

This work aims at determining the best performing mid and far-infrared (MIR and FIR) joint spectral interval to identify and classify clouds in the Antarctic region by mean of a machine learning algorithm.

About 1700 spectral-resolved radiances, collected during 2013 by the ground based Radiation Explorer in the Far InfraRed-Prototype for Applications and Development, REFIR-PAD (Palchetti et al., 2015) at Dome C, Antarctic Plateau, are selected in coincidence with the co-located with backscatter and depolarization profiles derived from a tropospheric lidar system (Ricaud et al., 2017) to pre-classify clear sky, ice clouds, or mixed phase clouds.

A machine learning cloud identification and classification algorithm named CIC (Maestri et al., 2019), trained with a pre-selected set of REFIR-PAD spectra, is applied to this dataset by assuming that no other information than the spectrum itself is known.

The CIC algorithm is applied by considering different spectral intervals, in order to maximize the classification results for each class (clear sky, ice clouds, mixed phase clouds). A CIC "threat score" is defined as the classification true positives divided by the sum of true positives, false positives, and false negatives. The maximization of the threat score is used to assess the algorithm performances that span from 58% to 96% in accordance with the selected interval. The best performing spectral range is the 380-1000 cm-1. The result, besides suggesting the importance of a proper algorithm calibration in accordance with the used sensor, highlights the fundamental role of the FIR part of the spectrum.

The calibrated CIC algorithm is then applied to a larger REFIR-PAD dataset of about 90000 spectra collected from 2012 to 2015. Some results of the full dataset cloud classification are also presented.

The present work contributes to the preparatory studies for the Far-infrared Outgoing Radiation Understanding and Monitoring (FORUM) mission that has recently been selected as ESA’s 9th Earth Explorer mission, scheduled for launch in 2026. 

 

References:

Maestri, T., Cossich, W., and Sbrolli, I., 2019: Cloud identification and classification from high spectral resolution data in the far infrared and mid-infrared, Atmos. Meas. Tech., 12, pp. 3521 - 3540

Palchetti, L., Bianchini, G., Di Natale, G., and Del Guasta, M., 2015: Far infrared radiative properties of water vapor and clouds in Antarctica. Bull. Amer. Meteor. Soc., 96, 1505–1518, doi: http://dx.doi.org/10.1175/BAMS-D-13-00286.1.

Ricaud, P., Bazile, E., del Guasta, M., Lanconelli, C., Grigioni, P., and Mahjoub, A., 2017: Genesis of diamond dust, ice fog and thick cloud episodes observed and modelled above Dome C, Antarctica, Atmos. Chem. Phys., 17, 5221–5237, https://doi.org/10.5194/acp-17-5221-2017.

How to cite: Magurno, D., Maestri, T., Cossich, W., Di Natale, G., Palchetti, L., Bianchini, G., and Del Guasta, M.: Antarctic cloud detection and classification from far and mid infrared downwelling radiance spectra: performances optimization and results, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9036, https://doi.org/10.5194/egusphere-egu2020-9036, 2020.

EGU2020-10117 | Displays | AS5.14

Recent advances and new features in the operational cloud products of Sentinel-5 Precursor and prospects for Sentinel-4

Ronny Lutz, Athina Argyrouli, Fabian Romahn, Diego Loyola, and Richard Siddans

The measurement of atmospheric composition from space requires also a precise knowledge regarding the appearance of clouds within the observed scene, and if present, a quantification of cloud properties such as cloud fraction, cloud height and cloud optical thickness/cloud albedo. The Copernicus mission Sentinel-5 Precursor, being operational since 2 years, covers the UV/VIS/NIR/SWIR spectral region. By covering the spectral region of the Oxygen A-band in the NIR, it provides an excellent prerequisite to retrieve the cloud parameters mentioned above. The same holds true for the anticipated Sentinel-4 mission (foreseen launch in 2023). In this contribution we present the most recent advances in the algorithms for retrieving the operational cloud products from TROPOMI onboard Sentinel-5 Precursor and from the future Sentinel-4/UVN onboard MTG-S. The applied cloud retrieval algorithms OCRA (Optical Cloud Recognition Algorithm) and ROCINN (Retrieval of Cloud Information using Neural Networks) have their heritage with GOME/ERS-2 and GOME-2 on MetOp-A/B/C, where they have already been successfully implemented in an operational environment. OCRA uses a broad band color space approach in the UV/VIS in combination with a set of cloud-free reflectance background composite maps to determine a radiometric cloud fraction while the ROCINN algorithm retrieves the cloud top height, cloud optical thickness and cloud albedo from NIR measurements in and around the oxygen A-band, taking as a priori input the cloud fraction computed by OCRA. ROCINN includes two different cloud models. One which treats clouds more realistically as layers of scattering water droplets (clouds-as-layers, CAL) and another one which treats clouds as simple Lambertian reflectors (clouds-as-reflecting boundaries, CRB). Substantial improvements to the algorithms have been implemented recently, some of which will be presented here, e.g. improved background maps, inclusion of cloud phase, retrieval of surface properties using machine learning. Further validation efforts via satellite-to-satellite comparisons with VIIRS on Suomi-NPP have been carried out and consolidate the product quality.

How to cite: Lutz, R., Argyrouli, A., Romahn, F., Loyola, D., and Siddans, R.: Recent advances and new features in the operational cloud products of Sentinel-5 Precursor and prospects for Sentinel-4, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10117, https://doi.org/10.5194/egusphere-egu2020-10117, 2020.

EGU2020-22389 | Displays | AS5.14

Hyperspectral A-band retrievals of cloud droplet number concentration from OCO-2

Mark Richardson, Matthew D. Lebsock, and Graeme L. Stephens

NASA’s Orbiting Carbon Observatory-2 (OCO-2) includes a hyperspectral (Dl~0.02 nm) oxygen A-band sensor, and the depth of its absorption features is related to the photon path length. Photon path length increases above a cloud if it is lower (i.e. higher Ptop), and within a cloud if its droplets are farther apart (i.e. lower N­d). This is a novel approach for retrieving Nd that is independent of MODIS-like retrievals, which take an a priori vertical cloud structure and assume that non-adiabatic processes such as precipitation or entrainment affect clouds uniformly. Our last product, OCO2CLD-LIDAR-AUX, used CALIPSO Ptop to help separate the above- and within-cloud path length. Here we show progress in an updated OCO-2 only retrieval of marine boundary layer clouds, including using neural networks for cloud identification and phase classification, additional retrieval of re, and how cloud vertical structure can bias retrieved Ptop and Nd. Successfully addressing this bias would provide a new and independent Nd retrieval that should capture changes due to non-adiabatic processes, and therefore provide a new test of aerosol cloud effects.

How to cite: Richardson, M., Lebsock, M. D., and Stephens, G. L.: Hyperspectral A-band retrievals of cloud droplet number concentration from OCO-2, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22389, https://doi.org/10.5194/egusphere-egu2020-22389, 2020.

EGU2020-3397 | Displays | AS5.14

A CrIS Cloud Detection Method Based on CrIS and ATMS Measurements

Li Guan and Qiumeng Xue

The Suomi National Polar-orbiting Partnership (SNPP) satellite carrying the Cross-track Infrared Sounder (CrIS) and the Advanced Technology Microwave Sounder (ATMS) instruments can provide high quality hyperspectral infrared (IR) data and microwave (MW) measurements. It is very important to ensure the accuracy of cloud detection in the infrared hyperspectral measurements before they are used for geophysical retrievals or data assimilation. Therefore, a cloud detection method using the CrIS hyperspectral radiances at longwave (709.5-746.0 cm-1) and shortwave (2190-2250 cm-1) bands and the ATMS measurements is introduced in this paper. Four steps are included in this algorithm: identifying clear FOV, estimating the number of cloud formations, thermal contrast, and cloud mask classification. Specifically, each CrIS field-of-view (FOV) is preliminarily assigned as clear or cloudy by comparing the measured IR radiances and simulated IR clear radiances which are generated from the MW-retrieved geophysical state vector based on a physical inversion method. Secondly, the number of cloud formations within one CrIS field-of-regard (FOR) is estimated using the principal component analysis (PCA). Next, CrIS radiances at longwave channels and shortwave bands are used to evaluate the thermal contrast within the FOR. Based on the above informations each FOR will finally be assigned a cloud mask classification. The cloud mask results derived from this technique are also analyzed.

How to cite: Guan, L. and Xue, Q.: A CrIS Cloud Detection Method Based on CrIS and ATMS Measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3397, https://doi.org/10.5194/egusphere-egu2020-3397, 2020.

EGU2020-10381 | Displays | AS5.14

Monitoring precipitation convective clouds with collocated hyperspectral infrared sounder and imager measurements

Xinya Gong, Jun Li, Zhenglong Li, and Christopher C. Moeller

Typically, DCCs are identified by 11 µm band brightness temperature (BT11) lower than a fixed BT threshold. Another method of combining the brightness temperature difference (BTD) between a water vapor absorption channel and a window channel to its measurement noise ratio (BNR) is adopted and applied to DCC identification. This BNR method improves the DCC detections over the legacy method because it is less contaminated with high clouds not thick and bright enough. BNR detects fewer DCCs than BT11, but with more confidence. 

Using observations of the collocated Cross-track Infrared Sounder (CrIS) and the Visible Infrared Imaging Radiometer Suite (VIIRS) onboard the Suomi National Polar-orbiting Partnership (SNPP) from 2017 to 2018, the results show BNR has better performances than BT11 for identifying the DCC and monitoring reflective solar bands. When comparing to BT11, BNR has more robust and invariant time series of monthly reflectance for all RSBs. Because BNR affects more on the left tails (less reflective) of the histograms than the mode reflectance, the improvement is more significant on the mean values than the modes. This method can be applied to other imagers with collocated advanced infrared sounders for detecting DCCs and monitoring the calibration stabilities of RSBs. 

Recently, the hyperspectral infrared atmospheric sounders onboard China’s next-generation FengYun satellites, i.e. the Geosynchronous Interferometric InfraRed Sounder (GIIRS) on the FengYun-4 geostationary satellite series and the Hyperspectral Infrared Atmospheric Sounder (HIRAS) on the FengYun-3 polar orbiting meteorological satellite series, are in operation. Flown onboard the same platforms, the collocated (consistent in time and space) infrared sounders and imagers, provide mount of match-up measurements for the study of methodology and process for synergistic use of both infrared sounder and imager for multiple applications. The findings will provide scientific evidences for further enhancements and applications of future FengYun satellites and its observing system.

How to cite: Gong, X., Li, J., Li, Z., and Moeller, C. C.: Monitoring precipitation convective clouds with collocated hyperspectral infrared sounder and imager measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10381, https://doi.org/10.5194/egusphere-egu2020-10381, 2020.

EGU2020-13685 | Displays | AS5.14

Merging regional and global AOD records from major available satellite products

Larisa Sogacheva and the AEROSAT team

Satellite instruments provide a vantage point for studying aerosol loading consistently over different regions of the world. However, the typical lifetime of a single satellite platform is on the order of 5-15 years; thus, for climate studies, the use of multiple satellite sensors should be considered.

We introduce a gridded monthly AOD merged product for the period 1995-2017 obtained by combining 12 major available monthly AOD products, which provides a long-term perspective on AOD changes over different regions of the world. Different approaches for merging the individual AOD products (median, weighted according to the evaluation results) are tested. We show that the quality of the merged product is as least as good as that of individual products.

We also introduce an approach to combine the merged AOD product with the AOD time series available over land (TOMS) and ocean (AVHRR) from early 1980th.

The evaluation of the modelled AOD products with the satellite AOD product shows that the agreement between modelled and merged AOD product is closer than one between modelled and individual satellite AOD products.

How to cite: Sogacheva, L. and the AEROSAT team: Merging regional and global AOD records from major available satellite products, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13685, https://doi.org/10.5194/egusphere-egu2020-13685, 2020.

EGU2020-9141 | Displays | AS5.14

A statistical analysis method estimating dust aerosol-ice cloud interactions using global circulation model and satellite data

Thomas Offenwanger, Christoph Beck, Thomas Popp, Johannes Hendricks, and Mattia Righi

A statistical analysis method to quantify dust aerosol interactions with ice cloud properties using IASI satellite data has been developed and published by L. Klüser et al. 2017. Key components of analyzing cloud properties are their classification by aerosol load and their normalization in respect to the meteorological state using a Bayes-approach. Comparing histograms of cloud properties for different aerosol classes gives then insight in statistical changes of their distribution. Using the same method twice on IASI-IMARS satellite retrieval and EMAC-MADE3 global circulation model data yields valuable insights on changes in cloud forming and lifecycle behavior inflicted by dust aerosol pollution. Overcoming scale differences between observation and simulation data sets has been a major obstacle as they have evident impact on the analysis results. Therefore, a statistical downscaling method has been customized to EMAC-MADE3 model data that focuses on preservation of critical processes while still approximating fine-scale patterns below model resolution. Both statistical analysis results for model and satellite data show clear aerosol impact on cloud property distributions with varying magnitudes and demonstrate the necessity of downscaling. More detailed analysis conducted with an increased number of aerosol classes shows quantifiable trends in aerosol impact on cloud properties.

How to cite: Offenwanger, T., Beck, C., Popp, T., Hendricks, J., and Righi, M.: A statistical analysis method estimating dust aerosol-ice cloud interactions using global circulation model and satellite data, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-9141, https://doi.org/10.5194/egusphere-egu2020-9141, 2020.

EGU2020-17479 | Displays | AS5.14

Characterization of dust aerosol over United Arab Emirates

Mika Komppula, Maria Filioglou, Xiaoxia Shang, Eleni Giannakaki, Anne Hirsikko, and Sami Romakkaniemi

One-year of ground-based Raman lidar observations have been conducted in order to characterize the aerosol properties over United Arab Emirates (UAE). In total, over 1000 aerosol layers were detected during the one-year campaign period which was carried between March 2018 and February 2019. We found that the measurement site is a receptor of frequent dust events but predominantly the dust is mixed with anthropogenic and/or aerosol of marine origin. With our multiwavelength PollyXT Raman lidar we are able to retrieve the backscatter coefficients (at 355, 532 and 1064 nm), extinction coefficients (at 387 and 607nm), particle depolarization ratios (at 355 and 532 nm), water vapour concentration (at 407 nm), and further on lidar ratios and Ångström exponents to characterize the aerosols properties in detail. In general, the average lidar ratios and linear particle depolarization ratios already showed strong presence of dust aerosols. Since the region is both a source and a receptor of mineral dust, we have also explored the pure mineral dust properties in the region. The findings suggest that the mineral dust properties over the Middle East and western Asia, including the observation site, are comparable to those of the African mineral dust regarding the particle depolarization ratios but not the lidar ratios. The lower lidar ratio values are attributed to different geochemical characteristics of the under-study region compared to soil originating from Northern Africa.

How to cite: Komppula, M., Filioglou, M., Shang, X., Giannakaki, E., Hirsikko, A., and Romakkaniemi, S.: Characterization of dust aerosol over United Arab Emirates, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17479, https://doi.org/10.5194/egusphere-egu2020-17479, 2020.

Aerosol optical depth (AOD) is an important factor to estimate the effect of aerosol on light, and an accurate retrieval of it can make great contribution to monitor atmosphere. Therefore, retrieval of AOD has been a frontier topic and attracted much attention from researchers at home and abroad. However, the spatial resolution of AOD, based on Moderate-resolution Imaging Spectroradiometer (MODIS), is low, and hard to meet the needs of regional air quality fine monitoring. In 2018, China launched Gaofen-6 satellite, which set up a network with Gaofen-1 enabling two-day revisited observations in China's land area, improving the scale and timeliness of remote sensing data acquisition and making up for the shortcomings of lacking multi-spectral satellite with medium and high spatial resolution. Along with advancement of the Earth Observation System and the launch of high-resolution satellites, it is of profound significance to give full play to the active role of high-scoring satellites, in monitoring atmospheric environmental elements such as atmospheric aerosols and particulate matter concentrations, and achieve high-resolution retrieval of AOD through Gaofen satellites.

In this paper the data of Gaofen-6 and Gaofen-1 was used to retrieve the AOD. based on the Synergetic Retrieval of Aerosol Properties (SRAP) algorithm. This algorithm can retrieve the surface reflectance and AOD synchronously through constructing a closed equation based on double star observations. It can be applied to various types of surface reflectance which extends the coverage of the retrieval of AOD inversion effectively. Experimental data includes the satellite data of New South Wales and eastern Queensland on November 21, 2019, which have been suffered from unprecedented large-scale forest fires for over 2 months. The retrieval of AOD during the time with the satellite data is benefit for the prevention and monitoring of forest fire. The experimental results are compared with the AERONET ground observation data for preliminary validation. The correlation coefficient is about 0.7. The experimental results show that the method have higher accuracy, and further validation work is continuing.

How to cite: Xue, Y.: Retrieval of High Spatial Resolution Aerosol Optical Depth from Chinese gAofen Data for Australian bushfire, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3986, https://doi.org/10.5194/egusphere-egu2020-3986, 2020.

Two episodes with heavy air pollution in Nanjing, China, one in the summer and another one in the winter of 2017, were selected to study aerosol properties using sun photometer and ground-based measurements, together with source region analysis. The aerosol properties, the meteorological conditions, and the source regions during these two episodes were very different. The episodes were selected based on the air quality index (AQI), which reached a maximum value of 193 during the summer episode (26 May–3 June) and 304 during the winter episode (21–31 December). The particulate matter (PM) concentrations during the winter episode reached maximum values for PM2.5/10 of 254 μg m−3 and 345 μg m−3, much higher than those during the summer (73 and 185 μg m−3). In contrast, the value of aerosol optical depth (AOD) at 500 nm was higher during the summer episode (2.52 ± 0.19) than during that in the winter (1.38 ± 0.18). A high AOD value does not necessarily correspond to a high PM concentration but is also affected by factors, such as wind, Planetary Boundary Layer Height (PBLH), and relative humidity. The mean value of the Ångström Exponent (AE) varied from 0.91–1.42, suggesting that the aerosol is a mixture of invaded dust and black carbon. The absorption was stronger during the summer than during the winter, with a minimum value of the single scattering albedo (SSA) at 440 nm of 0.86 on 28 May. Low values of asymmetry factor (ASY) (0.65 at 440 nm and 0.58 at 1020 nm) suggest a large number of anthropogenic aerosols, which are absorbing fine-mode particles. The Imaginary part of the Refractive Index (IRI) was higher during the summer than during the winter, indicating there was absorbing aerosol during the summer. These differences in aerosol properties during the summer and winter episodes are discussed in terms of meteorological conditions and transport. The extreme values of PM and AOD were reached during both episodes in conditions with stable atmospheric stratification and low surface wind speed, which are conducive for the accumulation of pollutants. Potential source contribution function (PSCF) and concentration weighted trajectory (CWT) analysis show that fine mode absorbing aerosols dominate during the summer season, mainly due to emissions of local and near-by sources. In the winter, part of the air masses was arriving from arid/semi-arid regions (Shaanxi, Ningxia, Gansu, and Inner Mongolia provinces) covering long distances and transporting coarse particles to the study area, which increased the scattering characteristics of aerosols.

How to cite: Wang, J. and de Leeuw, G.: Contrasting Aerosol Optical Characteristics and Source Regions During Summer and Winter Pollution Episodes in Nanjing, China , EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1862, https://doi.org/10.5194/egusphere-egu2020-1862, 2020.

EGU2020-8797 | Displays | AS5.14

Land aerosol retrieval from MERSI onboard Chinese Fengyun-3

Leiku Yang, Xiuqing Hu, Han Wang, Pei Liu, Xingwei He, Weibing Du, and Anjian Deng

The MEdium Resolution Spectral Imager (MERSI) onboard Chinese Fengyun-3 (FY-3) satellite is designed similar to MODIS and VIIRS, which would be an important supplement for multi-sensor measuring aerosol temporal and spatial distribution. But, there is no reliable aerosol product from MERSI by now. The plan of FY-3 missions is a sequence of eight satellites. Four have been launched, FY-3A in 2008, FY-3B in 2010, FY-3C in 2013, and recent FY-3D in the end of 2017. As the sensor MERSI becomes more mature, the demand of quantitative product is very urgent. Here, we apply MODIS land dark target (DT) algorithm to MERSI to test the quantitative ability of aerosol retrieval. Considering the sensor difference between MODIS and MERSI, we modified the process of gas absorption, cloud/snow/inland-water mask, pixel aggregation, and the most important part of band ratio for surface reflectance estimation. The global MERSI/FY-3C data of a whole year has been tested for retrieval. And the AEROENT data are used for ground validation. The scattering plot shows that MERSI AOD (aerosol optical depth) agrees well with AERONET observation that 70.7% collocations fall within expected error EE=±(0.05+0.15τ), which is even better than MODIS/TERRA AOD that 66.6% fall within EE. The global maps of monthly mean AOD are also consistent as well as MODIS. Finally, we made test to MERSI-II/FY-3D of 2 years data, the preliminary results also have a good validation and agree well with MODIS. The results of this talk indicates that the MERSI sensor has the quantitative ability for aerosol retrieval, and would be an important member of multi-sensor for aerosol measurements.

How to cite: Yang, L., Hu, X., Wang, H., Liu, P., He, X., Du, W., and Deng, A.: Land aerosol retrieval from MERSI onboard Chinese Fengyun-3, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8797, https://doi.org/10.5194/egusphere-egu2020-8797, 2020.

Aerosol single scattering albedo is a critical optical parameter that determines aerosol radiative effect. However, most existing passive satellite sensors such as MODIS and VIIRS only measures the intensity of reflected solar radiation and can only retrieve aerosol optical depth, while aerosol single scattering albedo needs to be assumed in the retrieval algorithm. On the other hand, if aerosol optical depth is known, it would be possible to retrieve aerosol single scattering albedo using satellite sensors.  In this study, we develop a machine learning based algorithm that retrieves aerosol single scattering albedo using joint visibility and satellite measurements. Combined with meteorology variables including relative humidity and boundary layer height, surface visibility can be converted to column aerosol optical depth. Then combining this converted aerosol optical depth with VIIRS measured TOA apparent reflectance, we retrieve aerosol single scattering albedo at over 2000 stations worldwide. The results compare well with AERONET retrieved SSA. However, compared with AERONET, visibility is recorded at every WMO meteorology station and has much more extensive coverage. We also applied our method to surface PM2.5 measurements obtained satisfactory results. Our work provides an aerosol single scattering albedo dataset with extensive coverage over land, which can be used for aerosol radiative forcing calculations and model validation.

How to cite: Li, J. and Dong, Y.: Retrieval of aerosol single scattering albedo using joint satellite and surface visibility measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11075, https://doi.org/10.5194/egusphere-egu2020-11075, 2020.

Recently, China successfully launched the new-generation geostationary (GEO) meteorological satellites, Fengyun-4A (FY-4A) in the year of 2016. In general, many mature and useful level-2 science product of Advanced Geostationary Radiation Imager (AGRI) onboard FY-4A were well developed in advance for satellite data users. Cloud top properties (CTP, including cloud top height, temperature, and pressure) product as an important science product is always used to monitor the rapid changes of typhoon and weather systems in the operational application. Unfortunately, we still find some invalid retrievals in CTP product of FY-4A/AGRI, which seriously impact on the use of this product (get some complaints from users). After comparing the invalid pixels with valid pixels and the same CTP product of Japanese Himawari-8 satellite and radiative transfer simulations, we find that the radiometric calibration bias of infrared band at 13.5μm is the primary impact factor on this fault. The pixels with brightness temperature lower than 200K show a bias larger than 7-8K, which directly induce the invalid retrieval process in the CTP product of FY-4A/AGRI. However, this fault in CTP also inspire us to use the invalid CTP pixel to monitor the on-orbit radiometric calibration bias of infrared band in the future.

How to cite: Min, M., Wang, F., and Xu, N.: Invalid cloud top properties product of Fengyun-4A satellite imager induced by infrared calibration bias, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1312, https://doi.org/10.5194/egusphere-egu2020-1312, 2020.

Low-level warm clouds are a major component in multilayered cloud systems and are generally hidden from the top-down view of satellites with passive measurements. By using spaceborne radar data with fine vertical resolution, this study conducts an investigation on oceanic warm clouds embedded in multilayered structures. The occurrences of warm cloud overlapping and the geometric features of several kinds of warm cloud layers are examined. It is found that there are three main types of cloud systems that involve warm cloud layers, including warm single layer clouds, cold-warm double layer clouds and warm-warm double layer clouds. The two types of double layer clouds account for 23% and in the double layer occurrences warm-warm double layer subsets contribute about 13%. The global distribution patterns of these three types differ from each other. Single-layer warm clouds and the lower warm clouds in the cold-warm double layer system have nearly identical geometric parameters, while the upper and lower layer warm clouds in the warm-warm double layer system are distinct from the previous two forms of warm cloud layers. In contrast to the independence of the two cloud layers in cold-warm double layer system, the two kinds of warm cloud layers in the warm-warm double layer system may be coupled. The distance between the two layers in the warm-warm double layer system is weakly dependent on cloud thickness. Given the upper and lower cloud layer with moderate thickness around 1 km, the cloudless gap reaches its maximum exceeding 600 m. As the two cloud layers become even thinner or thicker, the cloudless gap decreases in thickness. It is believed that such knowledge on cloud overlapping is critical for fully understanding the distribution of warm clouds in three-dimensional space. The results derived in this study could help validating cloud results of numerical models, which are indeed three-dimensional in nature. They could also be used to improve the estimation of cloud radiative forcing, since it is affected by cloud occurrences and especially their vertical structures. It should be pointed out that solid explanations for the above cloud features cannot be presented by only using these satellite data themselves. 

How to cite: Liu, Q., Ding, Y., and Lao, P.: Oceanic warm cloud layers within multilevel cloud systems observed by satellite measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6311, https://doi.org/10.5194/egusphere-egu2020-6311, 2020.

EGU2020-6364 | Displays | AS5.14

Investigation of aerosol absorption with dual-polarization lidar observations

Zhongwei Huang, Siqi Qi, Tian Zhou, Qingqing Dong, Xiaojun Ma, Shuang Zhang, Jianrong Bi, and Jinsen Shi

Polarization lidar has been widely used in recent decades to observe the vertical structures of aerosols and clouds in the atmosphere. To obtain more information from polarization lidar measurements, we developed a dual-polarization lidar system that can detect polarization measurements simultaneously at both 355 nm and 532 nm. The vertical distributions of atmospheric aerosols and clouds over northern China were successfully observed by the developed lidar. Observational data during two typical cases (dust events and haze episodes) were used for the analysis in this study. The results showed that for dust-dominated aerosols, the depolarization ratio (DR) at 532 nm was larger than that at 355 nm, but that for air pollutants was smaller. Our results also show that dual-polarization measurements can be used to largely improve aerosol classification. Moreover, we found that there is a good relationship between the absorption coefficient of aerosols and the ratio of DRs at 532 nm and 355 nm for dust aerosols. These results confirm that the absorption characteristics of dust aerosols cause a difference in DR at the UV and VIS wavelengths, and implying that aerosol absorption may be determined by polarization lidar at the ultraviolet and visible wavelengths.

How to cite: Huang, Z., Qi, S., Zhou, T., Dong, Q., Ma, X., Zhang, S., Bi, J., and Shi, J.: Investigation of aerosol absorption with dual-polarization lidar observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6364, https://doi.org/10.5194/egusphere-egu2020-6364, 2020.

EGU2020-6408 | Displays | AS5.14

The improved thin cloud detection using BRDF model based background reflectance from GOCI geostationary satellite imagery

Jong-Min Yeom, Hye-Won Kim, Jeongho Lee, Seonyoung Park, and Sangcherl Lee

In this study, the improved algorithm of thin cloud detection for geostationary ocean color imager (GOCI) satellite was developed to classify the thin cloud area over land area. The new cloud mask approach of GOCI satellite is required to expand its ocean dedicated application to other applications such for vegetation in land or aerosol optical properties (AOPs) in atmosphere due to its attractive shortwave wavelength bands of ocean color sensors. However, when trying to apply the advantages of the ocean color bands to the land area, only visible spectral bands of GOCI make it difficult to expand the land application the other way due to its limitation of cloud detection for relatively bright land surface. Furthermore, the geostationary of GOCI satellite has highly sensitive to geometry location of sun, meaning that high effective (Bidirectional Reflectance Distribution Function) BRDF effects make it also difficult to detect cloud mask in land surface due to its anisotropically scattered surface reflectance. In this paper, cloud mask algorithm of GOCI is proposed to consider those limitations by mainly using background surface reflectance from BRDF model. Therefore, minimum difference in reflectance between TOA and land as baseline of clear atmosphere and background surface reflectance underneath cloud were estimated from BRDF model. In conclusion, our new thin cloud detection is effectively detect the thin cloud over land surface area under limited ocean color bands of GOCI. The improved thin cloud detection algorithm of GOCI will be not only useful for following on instruments such as GOCI-II of Geo-KOMPSAT-2B and Sentinel 3 Ocean and Land Color Instrument (OLCL), but also applicable for existing geostationary satellites such as Geo-KOMPSAT-2A AMI, Himawari, and GOES-R as alternative cloud masking approach.

How to cite: Yeom, J.-M., Kim, H.-W., Lee, J., Park, S., and Lee, S.: The improved thin cloud detection using BRDF model based background reflectance from GOCI geostationary satellite imagery, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6408, https://doi.org/10.5194/egusphere-egu2020-6408, 2020.

EGU2020-8679 | Displays | AS5.14

SEAWIFS4MERIS adaptation to OLCI

Diana Dermann, Miriam Kosmale, and Thomas Popp

SeaWIFS4Meris is retrieving AOD at 550nm by fitting reflectance spectra at TOA to those measured by the MERIS instrument (ENVISAT). The OLCI instrument on Sentinel 3 is the successor of MERIS. The SeaWiFS4Meris Algorithm for AOD retrieval has been subsequently adapted to process OLCI data. Compared to AATSR/SLSTR OLCI and MERIS offer a better coverage due to a wider swath (1150km for OLCI and MERIS compared to 512km for AATSR).

We present aerosol retrieval results for the second half of 2019 together with their validation.

Based on the validation, next steps for improving the algorithm are defined. First, the albedo will be recalculated based on OLCI data - currently the albedo data calculated from MERIS data of 2008 is used. Secondly, possibilities for updating the cloud mask algorithm will be analyzed using the additional bands of OLCI. Lastly, the treatment of aerosol types will be inspected.

How to cite: Dermann, D., Kosmale, M., and Popp, T.: SEAWIFS4MERIS adaptation to OLCI, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8679, https://doi.org/10.5194/egusphere-egu2020-8679, 2020.

EGU2020-10867 | Displays | AS5.14

The fog/low stratus clouds in the Arctic: detection with multispectral satellite imagery

Daria Tatsii and Natalia Fedoseeva

            The safe operation of aviation and shipping, particularly in areas of insufficient coverage of automatic meteorological stations in the Arctic requires accurate interpretation of satellite images. Operational detection of fog and low stratus clouds and recognizing of them on the background of snow and ice cover and cloudiness of the upper layer is very important challenge. 

           The verified images obtained by Aqua and Terra satellites with a scanning radiometer MODIS, which operates in 36 spectral bands, with wavelengths from 0.4 µm to 14.4 µm, were collected.  With the Beam VISAT 5.0 software, which was designed to work with satellite data in raster format, thematic digital techniques of satellite multispectral information, based on difference in the values of the integral brightness of the images, both in optical and far-infrared ranges of the spectrum, have been developed.  These techniques, models of additive color synthesis, improve the quality of interpretation of fogs and low stratus clouds in terms of the complex structure of cloudiness and underlying surface in polar regions. Developed RGB combinations, which are based on the selected MODIS bands are:

  1. RGB (1.6 µm; 0.8 µm; 0.6 µm)
  2. RGB (0.8 µm; 3.9-8.7 µm; 10.8 µm)
  3. RGB (0.8 µm; 1.6 µm; 3.9-8.7 µm)
  4. RGB ((0-12)-(0-11) µm, (0-11)-(0-3.8) µm, (0-11) µm)

          Analysis of the obtained images has shown that the developed models of color synthesis help to distinguish the fog/low stratus clouds under different conditions of cloudiness and underlying surface accurately.

Key words: remote sensing, satellite imagery, additive color synthesis, fog, low stratus clouds, polar regions

How to cite: Tatsii, D. and Fedoseeva, N.: The fog/low stratus clouds in the Arctic: detection with multispectral satellite imagery, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-10867, https://doi.org/10.5194/egusphere-egu2020-10867, 2020.

EGU2020-11416 | Displays | AS5.14

Evaluation of simulated clear sky O2 A-band measurements from GOSAT over different surfaces - a sensitivity study

Beke Kremmling, Steffen Beirle, and Thomas Wagner

We present a follow-up study on previous investigations of photon path lengths distributions in cloudy atmospheres using O2 A-band measurements from the GOSAT TANSO-FTS satellite instrument (Kremmling, B., Investigation of photon path length distributions derived from oxygen A-band measurements of the GOSAT satellite instrument, PhD thesis, 2018). The original study used TANSO-FTS measurements of high spectral resolution over cloud covered ocean areas and compared them to radiative transfer simulations using the Monte Carlo model McArtim. The comparison is based on a fitting process, allowing spectral alignment as well as an adjustment of the simulated O2 absorption. A systematic overestimation of 5-10% of the simulated O2 absorption was found for the considered case studies. Despite the investigation of different sensitivity studies, the cause of this overestimation remained unresolved.

The consequence of these finding was the thorough investigation of clear sky measurements from TANSO-FTS between 2009 and 2015. The analysis includes the retrieval of the surface albedos and their comparison to those included in the TANSO-FTS data products as well as the subsequent fitting results of the simulated spectra. The analysis is applied to two datasets, both consisting of measurements passing different clear sky and quality criteria. Dataset 1 additionally has information from independent lidar measurements of CALIOP (CALIPSO) and is limited to the northern hemisphere due to the spatial and temporal collocation criteria. Dataset 2 has no independent collocation measurements but a more uniform distribution in space and time.

While the retrieved surface albedos compare well, an overestimation of the simulated O2 absorption by about 5% is found for measurements over ocean. Good agreement is found for the land cases.

In order to better understand these observations, different sensitivity studies as well as fit settings are investigated. The sensitivity studies include parameters such as SZA, surface albedo, NDVI values as well as the polarization of the TANSO-FTS radiances. The presentation shows the outcome of these studies.

How to cite: Kremmling, B., Beirle, S., and Wagner, T.: Evaluation of simulated clear sky O2 A-band measurements from GOSAT over different surfaces - a sensitivity study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11416, https://doi.org/10.5194/egusphere-egu2020-11416, 2020.

EGU2020-14410 | Displays | AS5.14

Error Analysis for the Himawari-8 Aerosol Optical Depth Basing on Parts of Aerosol Model and Sun Position over Wuhan, Central China

Yingying Ma, Ming Zhang, Yifan Shi, Wei Gong, and Shikuan Jin

Aerosols attract great attention as having critical influence on the Earth’s energy budget and human health. Geostationary satellites like Himawari-8 process advantages on temporal resolution that allows rapidly changing weather phenomena tracking and aerosol monitoring. This work aims at providing a novel error analysis for the Advanced Himawari Imager (AHI) aerosol optical depth (AOD) retrieval from the aspect of aerosol model and sun position combing with the high quality ground-based observation in Wuhan, central China. Three-year co-located AOD dataset from AHI and sun-photometer are used. AHI underestimates AOD in all the seasons. Aerosol size distributions and phase functions are discussed as parts of aerosol model to explain the underestimation of AOD. AHI sets a low fine-mode particle median radius comparing with the in-site measurement in Wuhan that increases backscattering, and finally leads to the underestimation of AOD. Sun position also affects AHI AOD retrieval, and we use solar zenith angle (SZA) and scattering angle to represent sun position. Geostationary satellites get fixed satellite position for one site that provides convenience to the discussion. SZA influences AOD retrieval mainly through the length of transfer path and higher percent of samples within expected error often appears at low SZAs. Scattering angle also has obvious influence on AOD retrieval through the simulation of phase function and causes the difference of correlation performance between AHI and sun-photometer in aspect of SZA in morning and afternoon. Finally, we applied the dark target method to retrieve AHI AOD. The comparison of AODs reveals that the retrieval method of AHI performs better in Wuhan. The better performance of AHI AOD may be due to high aerosol loading and lack of enough prior information of aerosol properties in Wuhan. Our work could also be performed on other areas or other geostationary satellites, and help us to further understand the controlling factors that affect AOD retrieval accuracy, then contribute to better AOD retrieval.

How to cite: Ma, Y., Zhang, M., Shi, Y., Gong, W., and Jin, S.: Error Analysis for the Himawari-8 Aerosol Optical Depth Basing on Parts of Aerosol Model and Sun Position over Wuhan, Central China, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-14410, https://doi.org/10.5194/egusphere-egu2020-14410, 2020.

EGU2020-15259 | Displays | AS5.14

Determination of aerosol optical depth and particulate matter concentrations using routine web cam measurements

Philipp Weihs, Anita Frisch-Niggemeyer, and Stefan Schreier

 

Visibility and visual contrast depend on several factors such as aerosol concentration, fog attenuation and humidity as well as gas characteristics. Usually, visibility is determined by observers or by visiometers. Routine web cam photographs of Vienna  have been performed for  2 years from the meteorological measurement platform situated on the roof of one of the buildings of University of Natural resources and Life Sciences overlooking the whole city of Vienna. Photographs are taken every 30 minutes in 6 different azimuthal directions. In the following study, we used routine web cam photographs digitalization to study the correlation between the ratio of some RGB channels as well as intensity fluctuations and the aerosol optical depth and on site particulate matter measurements. We first selected only photographs taken on clear sky days

For ground truth data, we used CIMEL sun photometer data of aerosol optical depth and liquid water content, relative humidity from routine measurements from our measurement platform as well as in situ measurements of particulate matter (PM10) performed by the air quality monitoring network of the city of Vienna.

First, the correlation between the contrast in a horizontal line and the aerosol amounts in the atmosphere and particulate matter concentration as a function of time of the day and azimuthal direction was investigated. We then examined the correlation between the blue to red ratio in a vertical and horizontal line with the aerosol amounts and particulate matter concentration in the atmosphere.

Results obtained showed at some azimuth angles and time of the day correlation coefficient R squared of up to 0.85 between horizontal line contrast and in situ PM 10 and between vertical line blue to red ratio and CIMEL aerosol optical depths measurements.

 

How to cite: Weihs, P., Frisch-Niggemeyer, A., and Schreier, S.: Determination of aerosol optical depth and particulate matter concentrations using routine web cam measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15259, https://doi.org/10.5194/egusphere-egu2020-15259, 2020.

EGU2020-15893 | Displays | AS5.14

Cloud amount uncertainty in merged CloudSat-CALIPSO radar-lidar observations

Andrzej Kotarba and Mateusz Solecki

Three dimensional structure of cloud cover is one of the Essential Climate Variable required for accurate monitoring of the state and change of global climate. Joint CloudSat-CALIPSO space mission have provided the most reliable and comprehensive 3D information on cloud distribution worldwide to date. However, the data resulted from observations collected every 16 days – sampling interval which can be considered infrequent for most of climate-oriented applications. The reliability of the data also depends on cloud regime, and area (grid cell size) over which the data are aggregated, further complicating the uncertainty aspect of lidar-radar profiling missions. The important question related to the CloudSat-CALIPSO dataset is whether 16-day revisit period for CloudSat-CALIPSO mission is sufficient to provide a climate characteristics at high statistical significance? We address that problem evaluating the full CloudSat-CALIPSO record (2006-2011), available to the scientific community as 2B-GEOPROF-LIDAR product. The analysis focuses on two aspects. First, we perform a point estimation to determine the minimum significance level at which the lidar-radar data (mean value) is statistically significant. Second, using a bootstrap approach we calculate confidence intervals for the mean value at fixed .95 and .99 thresholds. Therefore we reveal how wide is the actual uncertainty range at 16-day revisit. The analysis accounts for grid box size over which individual lidar-laser profiles were aggregated. The study was founded by National Science of Poland under the contract no. UMO-2017/25/B/ST10/01787.

How to cite: Kotarba, A. and Solecki, M.: Cloud amount uncertainty in merged CloudSat-CALIPSO radar-lidar observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-15893, https://doi.org/10.5194/egusphere-egu2020-15893, 2020.

EGU2020-16980 | Displays | AS5.14

Oriented particles in microwave and submillimeter radiative transfer simulations of ice clouds

Manfred Brath, Robin Ekelund, Patrick Eriksson, Oliver Lemke, and Stefan A. Buehler
Observations of Global Precipitation Measurement Microwave Imager (GMI) at 166 GHz consistently show polarized scattering signals of ice clouds. Conceptual models indicate that these signals emerge from oriented ice particles. Existing databases of scattering data of realistically shaped ice crystals for microwave and submillimeter typically assume total random orientation of ice particles. This is often a very reasonable assumption, but cannot explain the polarized ice cloud signals. Only few works considering oriented ice crystals exist, but they only consider microwave. With the upcoming Ice Cloud Imager (ICI) on board of Metop-SG B satellite, there will be additional dual-polarization measurements at 243 GHz and 664 GHz. These measurements will deliver new insights about clouds and their structure, if we know the scattering properties of oriented and realistically shaped ice crystals.
We provide publicly available scattering data for 51 different sized hexagonal plates and 18 different sized plate aggregates for 35 frequencies between 1 GHz and 864 GHz. The ice particles are assumed to be azimuthally randomly oriented with a fixed but arbitrary tilt angle. The scattering data for azimuthal random orientation is much more complex than for total random orientation. The scattering data of azimuthally randomly oriented particles depends in general on the incidence angle and two scattering angles compared to only one scattering angle for total random orientation. The scattering data is based on discrete dipole approximation simulations in combination with a self-developed orientation averaging approach.
We present detailed radiative transfer simulations of polarized GMI observations at 166 GHz and ICI observations at 243 GHz and at 664 GHz using our scattering data. The simulations of GMI recreate the observed polarization patterns. Analysis shows that not only orientation affects the polarization signal but also the hydrometeor composition. Furthermore, particle orientation also affects single polarized observations. Ignoring orientation can cause a negative bias for vertically polarized observations and a positive bias for horizontally polarized observations.

How to cite: Brath, M., Ekelund, R., Eriksson, P., Lemke, O., and Buehler, S. A.: Oriented particles in microwave and submillimeter radiative transfer simulations of ice clouds, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16980, https://doi.org/10.5194/egusphere-egu2020-16980, 2020.

EGU2020-17111 | Displays | AS5.14

The potential of a synergestic lidar and sunphotometer retrieval for the characterization of a dust event over Finokalia and for aerosol model evaluation

Dimitra Konsta, Alexandra Tsekeri, Stavros Solomos, Anton Lopatin, Philippe Goloub, Oleg Dubovik, Vassilis Amiridis, and Panagiotis Nastos

The ability of three-dimensional dust models to accurately represent the dust life cycle is crucial for describing dust effects on radiation and clouds and for reducing the uncertainties on these processes. To improve the reliabilty of dust models, it is therefore imperative to carry out thorough evaluations of the dust properties. Dust optical and microphysical properties are accurately accessed through groundbased observations: multiwavelength lidars and sunphotometers. In this study we use the Generalized Retrieval of Atmospheric and Surface Properties (GRASP) data algorithm that combines the lidar and sunphotometer data to retrieve dust properties. GRASP is applied on a Saharan dust episode over Finokalia, Crete in Greece, on 14 May 2017. More precisely the measurements from PollyXT lidar participating in the European Aerosol Research Network (EARLINET) and the CIMEL sunphotometer participating in Aerosol Robotic Network (AERONET) are synergetically combined using the GRASP algorithm. The dust event is fully characterised through the retrieval of dust optical and microphysical properties. The retrieved properties are found to be in good agreement with the initial measurements from the AERONET sunphotometer and the lidar. Then the aforementioned tools are used to evaluate the performance of the regional dust model NMME-DREAM that has been developed to simulate and predict the atmospheric cycle of mineral dust aerosols. It is shown that the model has problems in simulating the high dust concentration values at low levels, probably due to the low spatial resolution of the model that causes difficulties in capturing the orography and the downdrafts winds.

How to cite: Konsta, D., Tsekeri, A., Solomos, S., Lopatin, A., Goloub, P., Dubovik, O., Amiridis, V., and Nastos, P.: The potential of a synergestic lidar and sunphotometer retrieval for the characterization of a dust event over Finokalia and for aerosol model evaluation, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17111, https://doi.org/10.5194/egusphere-egu2020-17111, 2020.

EGU2020-17445 | Displays | AS5.14

Cloud vertical structure studied with synergetic measurements of Radiosonde, ceilometer and Ka-band radar in Munich

Qiang Li, Florian Ewald, Silke Groß, Martin Hagen, Eleni Tetoni, and Bernhard Mayer

Clouds play an important role in the radiation budget of the Earth’s atmosphere. The radiative heating and/or cooling by cloud vertical sturcture including cloud top and base, number and thickness of cloud layers, and the vertical distribution of multi-layer clouds couple strongly with the atmospheric thermodynamics, general circulation, and the hydrological cycle. Unfortunately, however, inadequate understanding of cloud properties and their vertical distributions still leads to high uncertainties in global climate models. In this study, we present the vertical distributions of multi-layer clouds derived from synergetic measurements of radiosonde and collocated ceilometer and the miraMACS Ka-band cloud radar on the roof of the Meteorological Institute Munich. Balloon-borne radiosondes penetrate the cloud layers and thus provide in-situ measurements. The profiles of temperature, relative humidity and pressure with radiosonde are used to derive cloud layers by identifying saturated levels in the atmosphere. The ceilometer is very efficient in detecting clouds and can provide a reliable estimate of the height of cloud base. The miraMACS cloud radar operating continuously in a vertical pointing mode provide radar reflectivities by hydrometeors within the radar beam. The radar observations allow for the determination of cloud layers with high temporal and vertical resolutions. Doing these exercises to the measurements of an entire year in 2018, we are able to evaluate the cloud layer retrieval methods with different instruments and to derive the statistical properties of cloud vertical structure in Munich.

How to cite: Li, Q., Ewald, F., Groß, S., Hagen, M., Tetoni, E., and Mayer, B.: Cloud vertical structure studied with synergetic measurements of Radiosonde, ceilometer and Ka-band radar in Munich, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17445, https://doi.org/10.5194/egusphere-egu2020-17445, 2020.

EGU2020-18209 | Displays | AS5.14

Global OMI Aerosol Single Scattering Albedo evaluation using ground-based AERONET

Periklis Drakousis, Marios-Bruno Korras-Carraca, Hiren Jethva, Omar Torres, and Nikos Hatzianastassiou

Aerosol measurements are carried out worldwide in order to reduce the uncertainties about the impact of aerosols on climate. Over the past two decades, different methods (ground- or satellite-based) for measuring aerosol properties have been developed, covering a variety of approaches with different temporal and spatial scales, which can be considered complementary. Aerosol optical properties are essential for assessing the effects of aerosols on radiation and climate. Aerosol single scattering albedo (SSA), along with optical depth and asymmetry parameter, is one of the three key optical properties that are necessary for radiation transfer and climate models. At the same time, SSA strongly depends on different aerosol types, thus enabling the identification of these different aerosol particles. However, despite the strong need for aerosol SSA products with global and climatological coverage, and the significant progress in retrieving SSA from satellite measurements, the satellite SSA retrievals are still subjected to uncertainties.

In this study, we perform an evaluation of the OMAERUVd (PGE Version V1.8.9.1) daily L3 (1° x 1° latitude-longitude) aerosol SSA data, which are based on the enhanced two-channel OMAERUV algorithm that essentially uses the ultraviolet radiance data from Aura/Ozone Monitoring Instrument (OMI), through comparisons against daily SSA products from 541 globally distributed Aerosol Robotic Network (AERONET) stations for a 15-year period (2005-2019). The comparison is performed between the available OMAERUVd SSA data at 354 nm, 388 nm, and 500 nm, and the AERONET SSA data at 440 nm (or 443 nm). The comparison is made on an annual and seasonal basis in order to reveal possible seasonally dependent patterns, as well as on a climatological and a year-to-year basis. The statistical metrics, such as Coefficient of Correlation (R) and Bias, are computed for individual AERONET stations as well as for all stations. The effect of availability of common OMI and AERONET data pairs on the comparison is assessed by making comparisons when at least 10, 50 and 100 common pairs are available.

The results show that about 50% (75%) of OMI-AERONET matchups agree within the absolute difference of ±0.03 (±0.05) for the 500 nm OMI SSA and the 440 nm (or 443 nm) AERONET SSA. The corresponding percentage for the 388 nm OMI SSA and the 440 nm (or 443 nm) AERONET SSA increases to 58% (81%), while the corresponding numbers for the 354 nm SSA OMI and the 440 nm (or 443 nm) AERONET are 43% (67%). It is found that in overall, OMI tends mainly to overestimate (underestimate) SSA for the 500 nm (354 nm) products in comparison to AERONET 440 nm (or 443 nm) with a total bias of 0.025 (-0.024), or 2.7% (2.6%) in relative percentage terms with respect to AERONET (mean AERONET value equal to 0.908), and an overall R value of 0.399 (0.386). At 388 nm, OMI tends to retrieve higher SSA over regions where biomass burning occurs, against lower SSA values elsewhere, with overall bias and R values equal to -0.002 (0.22%) and 0.395, respectively.

How to cite: Drakousis, P., Korras-Carraca, M.-B., Jethva, H., Torres, O., and Hatzianastassiou, N.: Global OMI Aerosol Single Scattering Albedo evaluation using ground-based AERONET, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18209, https://doi.org/10.5194/egusphere-egu2020-18209, 2020.

EGU2020-18695 | Displays | AS5.14

Validation of JAXA Himawari-8 Aerosol Optical Depth Products over China with AERONET and CARSNET Observations

Ling Gao, Chengcai Li, Lin Chen, Jun Li, and Huizheng Che

The performance of JAXA Himawari-8 Advanced Himawari Imager (AHI) aerosol optical depth (AOD) products over China is evaluated with ground-based AErosol RObotic NETwork (AERONET) and Sun-Sky Radiometer Observation Network (CARSNET) observations as well as the Moderate Resolution Imaging Spectroradiometer (MODIS) AOD products. Considering the quality and quantity of valid data, the study was limited to AOD products from AHI with a Quality Assurance Flag (QA_Flag) of “good” and “very good.” The spatial distribution of the AHI AOD product is similar to that of the MODIS AOD product. The AOD correlation between AHI and MODIS is better in the morning than in the afternoon after March, however, using MODIS AOD as a reference resulted in underestimation in the morning and overestimation in the afternoon. The bias is also larger in spring and autumn than in summer and winter. Validation with sun-photometer observations indicates good correlation between AHI AOD and ground-based observations with correlation coefficients larger than 0.75 (N>1000) when barren and sparsely vegetated surfaces are excluded. At 02:30 UTC, 53% of the collocated AHI AOD observations fall in the expected error (EE) range and at 5:30 UTC, 59.3% fall above the EE. The AHI AOD overestimation was apparent at the Northern China stations in April and after October, whereas the underestimation was apparent in southern China throughout the year. The temporal variations of AHI and AERONET AOD also show that the overestimation occurred in the afternoon and underestimation occurred in the morning.

The assumption that the solar geometries were nearly identical and the surface reflectance unchanged for a month causes the surface reflectance underestimation and leads to the AOD overestimation for barren surfaces in autumn and winter. Because background aerosols were neglected, the surface reflectance was overestimated, leading to AOD underestimation in vegetated surfaces.

Overall, the JAXA AOD provides a reliable and high temporal resolution aerosol product for environmental and climate research and the aerosol retrieval algorithm requires improvement.

How to cite: Gao, L., Li, C., Chen, L., Li, J., and Che, H.: Validation of JAXA Himawari-8 Aerosol Optical Depth Products over China with AERONET and CARSNET Observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18695, https://doi.org/10.5194/egusphere-egu2020-18695, 2020.

This contribution presents a technique for the machine-learning-based retrieval of cloud liquid water path. Cloud effects are among the major uncertainties in climate models for estimating and predicting the Earth’s energy budget. The study of cloud processes requires information on cloud physical properties, such as the liquid water path (LWP), which is commonly retrieved from satellite sensors using look-up table approaches. However, the accuracy of LWP varies temporally and spatially, also due to assumptions inherent in any physical retrieval. The aim of this study is to improve the accuracy of LWP and analyze quantitatively the accuracy and its errors. To this end, a statistical LWP retrieval was developed using spectral information from geostationary satellite channels (Meteosat Spinning-Enhanced Visible and Infrared Imager, SEVIRI), and satellite viewing geometry. The machine-learning method chosen is gradient-boosted regression trees (GBRTs), which is an ensemble of decision trees but more effective than traditional tree-based models. This study reports on first results, as well as a comparison between the GBRT-derived LWP estimates and those from the SEVIRI-based products of the Climate Monitoring Satellite Application Facility (CM-SAF, CLAAS-A2), as well as MODIS products. We use case studies for individual in-situ measurement sites in Europe under varying meteorological conditions to determine the factors influencing LWP retrieval quality.

How to cite: Kim, M., Cermak, J., Andersen, H., Fuchs, J., and Stirnberg, R.: Intercomparisons of liquid water path based on SEVIRI images and gradient boosting regression trees with in-situ observations and satellite-derived products, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-18806, https://doi.org/10.5194/egusphere-egu2020-18806, 2020.

Mineral dust has far reaching impact on atmospheric dynamics and the biosphere, altering both the hydrological and the carbon cycle, as well as on human health and the economy. Scattering and absorption effects of dust are enhanced in the terrestrial infrared due to the Si-O resonance bands and thus dust remote sensing with infrared sounders such as IASI (Infrared Atmospheric Sounding Interferometer) is well motivated. This work pertains to current updates on the Infrared Mineral Aerosol Retrieval Scheme (IMARS) on IASI hyperspectral data. IMARS algorithm estimates probabilistically the atmospheric state with respect to desert dust and ice clouds based on simulations of the observed signal for various dust and ice cloud properties.

A preprocessor compresses IASI radiance data in three pseudo-channels exploiting their high redundancy and accounting for the unequal distribution of their information content. From these, four distinct  brightness temperatures differences (BTD) are formed with respect to these channels, which reflect the spectral variation of dust or cloud or surface signal. By varying dust particle size distributions (s), mineralogical compositions (c), infrared optical depths (τ) and layer heights(h) we construct a simulation database constituting 6000 brightness temperature difference sets. The deviation of simulated and observed BTDs by means of a Gaussian metric yields a probability distribution function (PDF), with which the state vector as well as its probability and uncertainty are determined. The calculation of aerosol optical depth (AOD), dust layer temperature, dust effective radius, and other dust properties follows from correspondingly adding contributions (s, c, τ, h) weighted by this PDF. The ice cloud retrieval is realized in the same manner using cloud optical properties from a range of parameterizations found in literature. The distinction between dust and cloud is generally based on quality flagging in terms of the emission temperature relative to the approximated surface temperature and its expected range, and the (dust/cloud) probabilities and uncertainties with stricter criteria for the so-called dust belt. Finally, the IMARS pixel-wise product offers four levels of quality filtering in terms of probabilities, uncertainties, quality flags and information entropy.

Preliminary evaluation of IMARS AOD against AERONET coarse mode AOD obtained by the Spectral Deconvolution Algorithm, is done with data of mild level quality filtering restricted in the dustbelt and using Barnes objective analysis. Results show an overall moderate correlation (and small bias) and a stronger one for focused AERONET stations.

How to cite: Samaras, S. and Popp, T.: A probabilistic approach for the retrieval of mineral dust properties from infrared spaceborne observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-19290, https://doi.org/10.5194/egusphere-egu2020-19290, 2020.

AS5.24 – Advances in emission estimation based on observations and inversion techniques

EGU2020-1905 | Displays | AS5.24

Evaluating anthropogenic CO2 emissions of China estimated from atmospheric inversions of “proxy” species against ground CO2 measurements

Wei He, Fei Jiang, Shuzhuang Feng, Ngoc Tu Nguyen, Hengmao Wang, and Weimin Ju

Accurate estimation of anthropogenic CO2 emissions (ACE) is of great importance for climate change mitigation, however, it is quite challenging.  Co-emitted gases, e.g. CO and NOx, have been reported to be useful for tracking ACE. Here we estimated ACE of China based on “proxy” species (i.e. CO and NOx) inversions with emission ratios of CO2 and the “proxy” species and evaluated the estimates using ground CO2 measurements of three tower stations in population-dense areas based on the Stochastic Time-Inverted Lagrangian Transport (STILT) modeling driven by the Global Data Assimilation System (GDAS) meteorology. An ensemble of ACE of China were estimated from different combinations of anthropogenic CO or NOx flux estimates and emission ratios, where the CO or NOx fluxes were estimated from in-situ measured concentration data or satellite column concentration data, and the emission ratios were derived from two emission inventory datasets, i.e. multi-resolution emission inventory for China (MEIC) and Peking University global emission inventories (PKU-FUEL). We found all CO2 simulations with “proxy” based ACE estimates (either using in-situ or satellite data) in one year clearly fitted better to observations than those with inventory datasets did, especially during winter and early spring. Meanwhile, large mismatches between simulations and observations were found for some periods, which indicated the use of CO or NOx to track ACE may be not suitable for a whole year. Our preliminary result demonstrates the potential to use atmospheric “proxy” species to track anthropogenic CO2 emissions in China.

 

How to cite: He, W., Jiang, F., Feng, S., Nguyen, N. T., Wang, H., and Ju, W.: Evaluating anthropogenic CO2 emissions of China estimated from atmospheric inversions of “proxy” species against ground CO2 measurements, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-1905, https://doi.org/10.5194/egusphere-egu2020-1905, 2020.

EGU2020-2684 | Displays | AS5.24

UAV-based gas monitoring systems for the underpinning of urban, agricultural and industrial emission roadmaps – a methodological approach

Simon Leitner, Wendelin Feichtinger, Stefan Mayer, Florian Mayer, Dustin Krompetz, Rebecca Hood-Nowotny, and Andrea Watzinger

Currently sampling of the atmosphere for gas emission measurements involves building towers or hiring airplanes - capital-intensive methods. Easy access to unmanned aerial vehicles (UAV) has opened-up new opportunities for remote gas sampling. The project Iso-2-Drone aims to develop and produce a modular UAV-based gas monitoring system for emission measurements to substitute current technologies. A key feature of the UAV-attached gas sampler design was the ready-to-use nature of the system. This meant that the system was designed to mesh with commonly available equipment, using collection vessels which can be easily and immediately measured by common continuous flow - isotope ratio mass spectrometer (CF-IRMS) instrumentation. The target compounds comprise the three major natural greenhouse gases CH4, CO2 and N2O to be measured at natural isotopic abundance and ambient levels.

We use 20 mL headspace vials for CH4 and CO2 sampling. Vials can be conditioned on-sight with our sample preparation prototype using repeatedly evacuating and synthetic air refilling cycles to prevent ambient air contamination. On the UAV-attached sampler atmospheric air is sampled passively by pressure compensation of the vacuum. N2O is sampled actively via adsorption tubes, filled with Molecular Sieve 5Å and conditioned in the lab. Both a prototype device and two UAV-attached samplers have been designed, built and are currently tested.

The measurement setup in the lab comprises of two autosamplers, a purge & trap system (VSP 4000, IMT Innovative Maschinentechnik GmbH) and a headspace sampler (CTC CombiPal, Chromtech GmbH) in order to switch from ppb range necessary for CH4 and N2O to a ppm range for CO2. For CO2 measurements the CTC injects 600 µl of sampled air to a Restek Micropacked Column (Shin Carbon ST 100/120, 2m x 1mm ID and 1/16” OD) within a Thermo Scientific Trace GC Ultra heated up from 40°C to 110°C, maintained for 5 min, before heating up to 180°C by 12°C per minute. Thereby CO2 is properly separated from the potentially interfering N2O. For CH4 the residual air sample is cryo-focused at -140°C in a HayeSep D filled trap, transferred to the GC and targeted with a Poraplot Q (30m x 0.32mm) held at 35°C. Using the similar GC method and autosampler N2O is desorbed after switching the autosampler to thermal desorption mode. All three analytes pass an oxidation/reduction reactor (1030°C) before they are introduced into the IRMS (Thermo Scientific DeltaV Advantage) via a universal gas interface (Thermo Scientific Conflo IV). The IRMS continuously scans the intensity of the mass-to-charge ratios of mass 44, 45, 46 for CH4 and CO2 and 28, 29 for N20 converted to N2. δ13C and δ15N are referenced against calibrated laboratory reference gases.

We are currently tuning the methods and testing the prototypes and will present the lasted results and open questions at the conference.

How to cite: Leitner, S., Feichtinger, W., Mayer, S., Mayer, F., Krompetz, D., Hood-Nowotny, R., and Watzinger, A.: UAV-based gas monitoring systems for the underpinning of urban, agricultural and industrial emission roadmaps – a methodological approach, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-2684, https://doi.org/10.5194/egusphere-egu2020-2684, 2020.

EGU2020-3649 | Displays | AS5.24

Global catalog of NOx point sources derived from the divergence of the NO2 flux

Steffen Beirle, Christian Borger, Steffen Dörner, and Thomas Wagner

Satellite observations of NO2 provide valuable information on the location and strength of NOx emissions, but spatial resolution is limited by horizontal transport and smearing of temporal averages due to changing wind fields. The divergence (spatial derivative) of the mean horizontal flux, however, is highly sensitive for point sources like power plant exhaust stacks.

In a previous study, point source emissions have been identified and quantified exemplarily for Riyadh, South Africa, and Germany with a detection limit of about 0.11 kg/s down to 0.03 kg/s for ideal conditions, based on TROPOMI NO2 columns and ECMWF wind fields (Beirle et al., Science Advances, 2019).

Here we extend this study and derive a global catalog of NOx emissions from point sources. The specific challenges for e.g. high latitudes (longer NOx lifetime) or coastlines (potentially persistent diurnal wind patterns) are investigated.

How to cite: Beirle, S., Borger, C., Dörner, S., and Wagner, T.: Global catalog of NOx point sources derived from the divergence of the NO2 flux, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3649, https://doi.org/10.5194/egusphere-egu2020-3649, 2020.

EGU2020-3959 | Displays | AS5.24

High-resolution mapping of NOx emissions from the Canadian Oil Sands from TROPOMI

Chris McLinden, Vitali Fioletov, Debora Griffin, and Enrico Dammers

Direct estimates of air pollution emissions using a combination of satellite observations and meteorological reanalyses are becoming increasingly advanced and widely used. In this presentation, a new such methodology, able to resolve NOx emissions from multiple, adjacent emissions sites of varying sizes, but still applicable over larger scales, is presented. This method was applied to TROPOMI NO2 observations over the entirety of the Canadian oil sands, deriving emissions from small-to-large surface and in-situ mining operations. Initial comparisons with best available bottom-up emissions estimates show good consistency, and that TROPOMI is able to discern NOx emissions at the 1 kt[NO2]/yr level.

How to cite: McLinden, C., Fioletov, V., Griffin, D., and Dammers, E.: High-resolution mapping of NOx emissions from the Canadian Oil Sands from TROPOMI, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3959, https://doi.org/10.5194/egusphere-egu2020-3959, 2020.

EGU2020-4781 | Displays | AS5.24

Reducing uncertainty in emission estimates using perturbed emissions ensembles and novel observations: A focus on Beijing

Le Yuan, David Carruthers, Christina Hood, Roderic L. Jones, Olalekan A.M. Popoola, Jenny Stocker, and Alexander T. Archibald

The time lag between the occurrence of emissions and the compilation of an inventory is inevitable. When an emissions inventory is used to simulate air quality, uncertainties in the emissions are propagated into uncertainties in the modelled pollutant concentrations. Such uncertainties can be particularly high in regions undergoing rapid emission changes. Beijing, for instance, has implemented a series of pollution control measures over the past several years and various studies have confirmed significant decreases in the emissions of pollutants such as CO and NOX. Hence, it is crucial to quantify and constrain the uncertainties in existing emission estimates for this region.

We sample the uncertainties in an emissions inventory for Beijing using a high-resolution advanced Gaussian dispersion model with perturbed emissions ensembles (PEEs), and constrain these uncertainties using a comprehensive set of in situ observations, including vertically resolved measurements made from a tower in central Beijing using low-cost sensors. We first construct a PEE by varying key emission parameters including source sectors, vertical and diurnal profiles within their uncertainty ranges estimated through expert elicitation. By removing the baseline contribution to the concentrations, we are able to evaluate the performance of the PEE in simulating the local signal. Based on knowledge gained from the initial PEE, we design a second PEE with optimised uncertainty ranges with which we constrain the uncertainties in the base emission estimates.

Our study shows the applicability of perturbed emissions ensembles and high-resolution, three-dimensional observations in systematically sampling and constraining emission uncertainties. This method has wide implications for air quality modelling, particularly in regions with rapid emission changes or for studies in which emissions inventories are out-dated.

How to cite: Yuan, L., Carruthers, D., Hood, C., Jones, R. L., Popoola, O. A. M., Stocker, J., and Archibald, A. T.: Reducing uncertainty in emission estimates using perturbed emissions ensembles and novel observations: A focus on Beijing, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-4781, https://doi.org/10.5194/egusphere-egu2020-4781, 2020.

EGU2020-5594 | Displays | AS5.24

Monitoring CO emissions from urban districts in Mexico City using about 2 years of TROPOMI CO observations

Tobias Borsdorff, Agustin Garcia Reynoso, Wolfgang Stremme, Joost aan de Brugh, Michel Grutter, and Jochen Landgraf

The Tropospheric Monitoring Instrument (TROPOMI) on ESA Copernicus Sentinel-5P satellite (S5-P) monitors the total column concentration of carbon monoxide (CO) as one of its primary targets.  In this study, we present an approach to analyze the large amount of TROPOMI CO data and to estimate urban emissions on sub-city scales for metropolises like Mexico City. The results demonstrate the advance in using TROPOMI observations for monitoring regional air quality. To this end, we analyze about two years of TROPOMI CO measurements with 551 overpasses over Mexico City using tracer simulations of the regional Weather Research and Forecasting (WRF) model. Ten separate CO tracers for emissions of the districts Tula, Pachuca, Tulancingo, Ciudad de Mexico, Toluca, CDMX, Cuernavaca, Cuautla, Tlaxcala, and Puebla are used to conclude on the emissions of different urban districts. A regularized source inversion minimizes the difference with respect to a prior emission estimate. Here, the degree of freedom of the inferred sources is a powerful tool to filter on measurement information and forward model errors e.g. due to erroneous wind fields. We compare the estimated emissions with those of the national inventory ``Inventario Nacional de Emisiones de Contaminantes Criterio'' (INEM) multiplied by 0.48 to make it applicable for the years 2017 to 2019. Overall, TROPOMI confirms the total INEM CO emissions form the area but indicates clear differences in relative distribution of the emissions between the districts. For example, TROPOMI yields 0.11 Tg/yr and 0.10 Tg/yr CO emissions for the urban districts Tula and Pachuca in the North of Mexico City, which exceeds the INEM emissions of <0.008 Tg/yr. Also, for the central part of Mexico City (CDMX) the TROPOMI estimate with 0.14 Tg/yr differs significantly from the inventory with 0.25 Tg/yr. Moreover, we found that the retrieved emissions for CDMX and Ciudad de Mexico follow a clear weakly cycle with a minimum during the weekend in agreement with ground-based in situ measurements of the ``Secretaria del Medio Ambiente'' (SEDEMA) and column measurements of a Fourier Transform Spectrometer in Mexico City operated by the National Autonomous University of Mexico (UNAM). To improve further the TROPOMI CO data exploitation, our study clearly indicates the need for improvements of regional models like WRF, in particular with respect to the prediction of the local wind fields.

How to cite: Borsdorff, T., Garcia Reynoso, A., Stremme, W., aan de Brugh, J., Grutter, M., and Landgraf, J.: Monitoring CO emissions from urban districts in Mexico City using about 2 years of TROPOMI CO observations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-5594, https://doi.org/10.5194/egusphere-egu2020-5594, 2020.

A six-year long high-resolution Chinese air quality reanalysis datasets (CAQRA) covering the period 2013-2018 has been developed in this study by assimilating over 1000 surface air quality monitoring sites from China National Environmental Monitoring Centre (CNEMC) based on the ensemble Kalman filter (EnKF) and the Nested Air Quality Prediction Modeling System (NAQPMS). This reanalysis provides the surface fields of six conventional air pollutants in China, namely PM2.5, PM10, SO2, NO2, CO and O3, at high spatial (15km×15km) and temporal (1 hour) resolutions. This paper aims to document this dataset by providing the detailed descriptions of the assimilation system and presenting the first validation results for the reanalysis fields of air pollutants in China. A twenty-fold cross validation (CV) method was used to assess the quality of CAQRA. The CV results show that the CAQRA has excellent performances in reproducing the magnitude and variability of the air pollutants in China with the biases (normalized mean bias) of the reanalysis data about -2.6 (-4.9%) μg/m3 for PM2.5, -6.8 (-7.6%) μg/m3 for PM10, -2.0 (-8.5%) μg/m3 for SO2, -2.3 (-6.9%) μg/m3 for NO2, -0.06 (-6.1%) mg/m3 for CO and -2.3 (-4.0%) μg/m3 for O3. The interannual changes of the air quality in China were also well represented by the CAQRA in terms of the six air pollutants. Comparisons with previous datasets of daily PM2.5, SO2 and NO2 concentrations indicate that the CAQRA is more accurate with smaller RMSE values. We also compared our reanalysis dataset to the CAMSRA (The Copernicus Atmosphere Monitoring Service reanalysis) produced by ECMWF (European Centre for Medium-Range Weather Forecasts), which suggests that the CAQRA has higher accuracy in representing the surface air pollutants in China due to the assimilation of surface observations. This reanalysis dataset can provide us comprehensive pictures of the air quality in China from 2013 to 2018 with a complete spatial and temporal coverage, which can be used in the assessment of health impacts of air pollution, validation of model simulations and providing training data for the statistical or AI (Artificial Intelligence) based forecast.

How to cite: Kong, L., Tang, X., Zhu, J., Wang, Z., Wu, H., and Li, J.: Developing High-resolution Air Quality Reanalysis Dataset over China for Years 2013-2018 Based on Ensemble Kalman Filter and Surface Observations from CNEMC, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-6848, https://doi.org/10.5194/egusphere-egu2020-6848, 2020.

EGU2020-8043 | Displays | AS5.24

Quantifying South Eastern Europe NOx and SO2 emissions using S5P/TROPOMI; from the urban to the regional scale.

Maria-Elissavet Koukouli, Ioanna Skoulidou, Arjo Segers, Astrid Manders-Groot, Jeroen Kuenen, Jos van Geffen, Henk Eskes, Pascal Hedelt, Diego Loyola, Tzenny Stavrakou, Voula Tzoumaka, Apostolos Kelessis, Dimitris Karagkiozidis, and Dimitris Balis

Even though the actual levels of anthropogenic pollution around South Eastern Europe do not reach the ones experienced in numerous Central and Western locations such as the Po Valley, the Benelux regions, the English Channel, etc., both nitrogen and sulphur oxides remain a cause for concern for air quality issues in the area. S5P/TROPOMI offers a high enough spatial resolution of 3.5x7km2 (x5.5km2 since August 2019) coupled with a high signal-to-noise to allow the monitoring of air quality levels, as well as the calculation of emissions, around the overpass time of the satellite. In that respect, LOTOS-EUROS Chemical Transport Model (CTM) simulations for year 2018 will be used in conjunction to the S5P/TROPOMI NO2 v01.03.02 and SO2 v01.01.07 columns to update the current emission inventory used in CAMS, provided recently by TNO for year 2015.

The process is validated at every step; the CTM surface concentrations are being compared to the European Environmental Agency E1a & E2a in situ air quality station data while the satellite vertical columns are compared to MAX-DOAS ground-based measurements. The diurnal variability of the NO2 depicted by the in situ and the CTM is examined, as a source of understanding the effect of the apriori emission fields, the OH radical chemistry, the planetary boundary layer definition, etc., within the model structure. The seasonal variability of the SO2 columns observed by the satellite and ground-based instruments reveals the amount of insufficiently filtered power plants and smelting activities in the area, including transboundary transport around the Balkan Peninsula.

Area sources, such as cities and industrial regions, as well as shipping plumes around the Aegean Sea, the Bosporus Strait and the Eastern Mediterranean, will be characterized vis-à-vis their updated emissions and discussed.

Acknowledgements:

We acknowledge support of this work by the project “PANhellenic infrastructure for Atmospheric Composition and climatE change” (MIS 5021516) which is implemented under the Action “Reinforcement of the Research and Innovation Infrastructure”, funded by the Operational Programme "Competitiveness, Entrepreneurship and Innovation" (NSRF 2014-2020) and co-financed by Greece and the European Union (European Regional Development Fund). This work was co-funded by ESA within the Contract No. 4000117151/16/l-LG “Preparation and Operations of the Mission Performance Centre (MPC) for the Copernicus Sentinel-5 Precursor Satellite”.

How to cite: Koukouli, M.-E., Skoulidou, I., Segers, A., Manders-Groot, A., Kuenen, J., van Geffen, J., Eskes, H., Hedelt, P., Loyola, D., Stavrakou, T., Tzoumaka, V., Kelessis, A., Karagkiozidis, D., and Balis, D.: Quantifying South Eastern Europe NOx and SO2 emissions using S5P/TROPOMI; from the urban to the regional scale., EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-8043, https://doi.org/10.5194/egusphere-egu2020-8043, 2020.

Since 2000 there have been two significant changes impacting loadings of aerosols and trace gasses on the troposphere. First, there has been a rapid expansion of urbanization and access to energy sources, coupled with significant deforestation, all leading to a rapid increase in emissions and a change in its distribution in space and time. Secondly, we now have access to multiple daily to weekly measurements of aerosols and related trace gasses on a global scale. Combining the data from these different remotely sensed platforms in space and on the ground, coupled with an understanding of the basic physical and chemical differences of different sources and substances should allow us to understand and begin to quantify how the emissions have changed over time. However, we have serious issues when it comes to analyzing changes which are rapid in either space or time, with traditional Kalman filters and 3D/4D variance techniques tending to smooth out such changes.

The approach uses the rate in the change of the difference of the variance  of the loadings of NO2 (from OMI) which is short-lived, CO (from MOPITT) which is long-lived, and AOD (from MISR) which is short-lived in the presence of rain, and intermediate-lived under dry conditions. This combination is used to generate new a priori, which in turn have a significantly different spatial, temporal resolution than currently existing emission datasets. The magnitudes are then scaled by using a simple forward-inverse modeling framework based on an approximation of an EnKF approach, using measurements not used in the a priori fitting: AOD from AERONET and MODIS, surface measurements of trace gasses from various national and international projects, and other sources.

Our results of this new approach demonstrate that these rapidly varying sources in space and time can contribute from an additional 10% to up to 500% of emissions over these various rapidly changing regions, as compared with existing present-day inventories. The results seem to be robust for changes occurring over time scales from a week to two months, and spatial scales of 25km x 25km and larger. The technique is able to capture significant single events, inter-annual and intra-annual variation. In specific, we observe clear decreases in sources from urban North America and urban Western Europe, both increases and decreases over East Asia, and significant increase in biomass burning sources from North America, and both biomass burning and urban sources from Southeast Asia, Africa, and regions of South America.

Finally, weaknesses in the model assumptions associated with vertical transport, mis-characterized removal and in-situ processing, remotely sensed measurement biases (i.e. cloud cover), and the mathematics of sampling of the differences of the variance are discussed. In some cases, uncertainties in emissions can be expanded to cover these observations, and in other cases are highlighted for future work.

How to cite: Cohen, J.: Using Multiple Satellites with a New Forward Variance Maximization and Coupled Inverse Filter Method to Quantify the Emissions of Biomass Burning and Urban Sources which have Changed Dramatically Over the Past 2 Decades, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-12769, https://doi.org/10.5194/egusphere-egu2020-12769, 2020.

EGU2020-13077 | Displays | AS5.24

Improved Inversion of Monthly Ammonia Emissions in China Based on the Chinese Ammonia Monitoring Network and Ensemble Kalman Filter

Xiao Tang, Lei Kong, Jiang Zhu, Zifa Wang, Yuepeng Pan, Huangjian Wu, Lin Wu, Qizhong Wu, Yuexin He, Shili Tian, Yuzhu Xie, Zirui Liu, Wenxuan Sui, Lina Han, and Greg Carmichael

Ammonia (NH3) emission inventories are an essential input in chemical transport models and are helpful for policy-makers to refine mitigation strategies. However, current estimates of Chinese NH3 emissions still have large uncertainties. In this study, an improved inversion estimation of NH3 emissions in China has been made using an ensemble Kalman filter and the Nested Air Quality Prediction Modeling System. By first assimilating the surface NH3 observations from the Ammonia Monitoring Network in China at a high resolution of 15 km, our inversion results have provided new insights into the spatial and temporal patterns of Chinese NH3 emissions. More enhanced NH3 emission hotspots, likely associated with industrial or agricultural sources, were captured in northwest China, where the a posteriori NH3 emissions were more than twice the a priori emissions. Monthly variations of NH3 emissions were optimized in different regions of China and exhibited a more distinct seasonality, with the emissions in summer being twice those in winter. The inversion results were well-validated by several independent datasets that traced gaseous NH3 and related atmospheric processes. These findings highlighted that the improved inversion estimation can be used to advance our understanding of NH3 emissions in China and their environmental impacts.

How to cite: Tang, X., Kong, L., Zhu, J., Wang, Z., Pan, Y., Wu, H., Wu, L., Wu, Q., He, Y., Tian, S., Xie, Y., Liu, Z., Sui, W., Han, L., and Carmichael, G.: Improved Inversion of Monthly Ammonia Emissions in China Based on the Chinese Ammonia Monitoring Network and Ensemble Kalman Filter, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-13077, https://doi.org/10.5194/egusphere-egu2020-13077, 2020.

EGU2020-16082 | Displays | AS5.24

Estimating emissions of methane and carbon dioxide sources using analytical Bayesian inversion system based on WRF-GHG tagged tracer simulations

Michał Gałkowski, Julia Marshall, Frank-Thomas Koch, Jinxuan Chen, Alina Fiehn, Anke Roiger, Maximilian Eckl, Julian Kostinek, Justyna Swolkień, and Christoph Gerbig

During May and June 2018, the intensive campaign CoMet (Carbon dioxide and Methane mission) made atmospheric measurements of greenhouse gases over Europe, with the upper Silesian coal basin (USCB) in southern Poland as a specific focus area. CoMet aimed at characterising the distribution of CH4 and CO2 over significant regional sources with the use of a fleet of research aircraft, as well as to validate remote sensing measurements from state-of-the-art instrumentation installed on-board against a set of independent in-situ observations.

In order to link atmospheric mixing ratios to source emission rates, high-resolution simulations with WRF-GHG v 3.9.1.1. (10 km x10 km Europe + nested 2 km x 2 km domain over the USCB), driven by short-term meteorological forecasts from the ECMWF IFS model and forecasts from CAMS (Copernicus Atmospheric Monitoring Service) for initial and lateral tracer boundary conditions were performed. Biogenic fluxes of CO2 were calculated online using the VPRM model driven by MODIS indices. Anthropogenic emissions over Europe were taken from the database of TNO, Department of Climate, Air and Sustainability (7 km x 7 km), augmented with an internal emissions database developed within CoMet that uses coal mine ventilation shaft emission measurements in combination with recent updates of the E-PRTR (European Pollutant Release and Transfer Register).

Tagged tracers were used to simulate a robust set of over 100 distinct anthropogenic sources of CH4 and CO2 from the study area, and these forward simulations were then used as the transport operator in an analytical Bayesian inversion system. Here we discuss the results of an analysis performed with the use of selected in-situ data measured over the course of the three-week campaign, including results and sensitivity tests.

How to cite: Gałkowski, M., Marshall, J., Koch, F.-T., Chen, J., Fiehn, A., Roiger, A., Eckl, M., Kostinek, J., Swolkień, J., and Gerbig, C.: Estimating emissions of methane and carbon dioxide sources using analytical Bayesian inversion system based on WRF-GHG tagged tracer simulations, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-16082, https://doi.org/10.5194/egusphere-egu2020-16082, 2020.

EGU2020-17942 | Displays | AS5.24

Rapid growth of NOx emissions in India observed from Space

Jieying Ding, Ronald van der A, and Bas Mijling

Since the last decade, India has encountered severe problems in air quality and became the most air polluted country in the world.  With satellite observations, we can monitor the changes of NO2 column concentrations in India. However, the information on emissions is very limited. In this study, we use the KNMI DECSO (Daily emission Estimates constrained by Satellite Observation) algorithm to estimate NOx emissions from OMI observations from 2007 to 2018. The results show that NOx emissions have increased by about 40% in the last 12 years. We compare NOx emissions from DECSO and the HTAP bottom-up NOx emissions with the location and capacity of power plants in India. The comparison between DECSO and HTAP shows that the emissions estimated from satellite are more accurate on spatial and temporal scale. We also run the CHIMERE v2013 model with emissions from DECSO and HTAP respectively and compare the model simulations with NO2 in-situ measurements of the Indian national network. The comparison shows that model simulation with DECSO has lower bias and better correlation with in-situ observations than that with HTAP.  

How to cite: Ding, J., van der A, R., and Mijling, B.: Rapid growth of NOx emissions in India observed from Space, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-17942, https://doi.org/10.5194/egusphere-egu2020-17942, 2020.

EGU2020-20387 | Displays | AS5.24

Optimizing CO emissions from the 2018 Californian fires using S5P – an inverse modelling study

Johann Rasmus Nüß, Nikos Daskalakis, Oliver Schneising, Michael Buchwitz, Maarten C. Krol, and Mihalis Vrekoussis

A clear understanding of carbon monoxide (CO) emissions is important at various scales. On the local scale CO is toxic to living organisms, and on the global scale CO plays in role in the budget of  the hydroxyl radical (OH). OH, in turn, is important for the oxidizing capacity of the atmosphere. Additionally, CO is a precursor of the greenhouse gases ozone and carbon dioxide, hence CO influences also climate on a global scale.

Approximately one quarter of the global atmospheric CO load emanates from wildfires. However, these emissions are sometimes underrepresented in the emission datasets. Among the reasons for this discrepancy are clouds and smoke plumes hampering observations of land cover and active fires and uncertainties in emission factors. These issues are less relevant for top-down approaches like inverse modeling, which allow tracing back an atmospheric signal to its source even if it is only observed days after emission.

In this study, we attempt to improve the emission estimates of an existing inventory by applying an inverse modeling approach to the CO emissions of the California wildfires in 2018, that devastated more than 7500 square kilometers of forested and residential area. More specifically, we used the Fire Emission Inventory from NCAR (FINN) together with the CO observations from the TROPOMI instrument onboard the Sentinel 5 Precursor (S5P) satellite and the TM5-4dvar inverse model. The high resolution of the TROPOMI observations enables better spatial constraints compared to previous instruments. Preliminary results suggest significant positive emission increments compared to FINN.

How to cite: Nüß, J. R., Daskalakis, N., Schneising, O., Buchwitz, M., Krol, M. C., and Vrekoussis, M.: Optimizing CO emissions from the 2018 Californian fires using S5P – an inverse modelling study, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-20387, https://doi.org/10.5194/egusphere-egu2020-20387, 2020.

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